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I ! IranEporter "|~~[ TSD SDMS Document 115530 RCRA Enforcement Interim Report- No Analysis data Berlex Laboratories St. Croix, VI VID980651095 March 13, 1986 P a r t i c i p a t i n g Personnel: Report prepared by: Approved for the Director by: Environmental Protection Agency^- Carol P r i c e , Environmental S c i e n t i s t Joseph Cosentino, Environmental Scienti Steven Hale, Env. Protection S p e c i a l i s t Michael Glogower, Life S c i e n t i s t Berlex Laboratories (ICC) Allan Kyles, Vice-President, Enviro-Sciences, Inc.(ESI) Raymond Hays, E a c i l i t y Handyman Raymond Hays, Eac] Carol Price, Environmenta] Source do'l^toring Sec Richard a. Spear, Ct Surveillance & Monitoring Branch 100001 Table of Content.s Summary Objective .' ...''. .'.. .^ T';; Findings emd Recommendations • i Discussion Purpose of survey * j;1 Facility history 1 Facility areas/treatment units inspected 2 Sampling procedures 4 Results of analysis 5 List of Figures and Tables Figure 1 - Map of facility: contaminated areas Figure 2 - Drums in storage Figure 3 - Map of sampling points Table 1 - Organic compounds analyzed Table 2 - Results of organic analysis- organic ccaspounds detected Table 3 - Results of metals scan analysis List of Attachments Attachment 1 - Report of September 9, 1985 Inspection Attachment 2 - Copies of manifests Attachment 3 - Chain of custody and sampling paperwork 100002 Berlex Laboratories (ICC) St. Croix, VI Summary Objective This RCRA enforcement inspection was conducted of Berlex Laboratories (ICC) at the request of the Solid Waste Branch in order to gather information necessary to determine tbe facility's complifmce with applicable RCRA regrulations. Findings and Recommendations 1. Drums of hazardous material are being stored on the Berlex (ICC) site. Environmental Sciences, Inc. (ESI), the facility's contractor claims t^hat these drums of chemicals have not been declared "waste" yet and so are not subject to accumulation and storage requirements. Most of the drums are the property of Virgin Islamd Chemical;.no representative of this company was present on the site. ESI claims that thirty-three of the driuns in storage belong to Berlex (ICC). The other drums (approximately 155) ESI says belong to Virgin Island Chemical. The attached inventory (Attachment 2), prepared by a Virgin Island Chemical representative but given to EPA by ESI, contains a listing of the drums in storage. The number In the Inventory does not match the number counted by EPA. 2. A Btorm sewer that collects run-off from the facility discharges into a intermittent stream behind the Berlex (ICC) property. The facility does not have a MPDES permit. 3. The results of the analyses for organics, metals, and PCB's.revealed the following: " Phthalates appeared In all of the samples remging from 1000 ug/kg to 17,000 ug/kg in the soil samples and 3.9 ug/l to 280 ug/l in the water sample. • Orgamics contamination was higher In the sample taken from the gut sediments at the point of the drainage pit discharge than in the other samples . This contamination consisted of xylene, dl-n-octyl phthalate, 1,4-dichlorobenzene, 1,2-dichlorobenzene, napthalene, flourene, phenanthrene, and aliphatic and aromatic hydrocarbons. * Chloroform appeeured In the on-site well at a level of 130 ug/l. * PCB's were detected below the detection limit In all six of the sanples. * The metals arsenic (estimated value), beryllium (estimated value), chromium (ranging from 10 ug/kg to 52 ug/kg), copper (ranging from 40 ug/kg to 58 ug/kg), lead (estimated value), nickel (ranging from 19 ug/kg to 32 ug/kg), antimony (rimging from 8.4 ug/kg to 10 ug/kg), selenium (estimated value), and zinc (ranging from 63 ug/kg to 360 ug/kg) were all detected in the sediment samples. Arsenic, beryllium, cadmium, chromium, copper, mercury, antimony, and zinc were all detected In the water seunple at estimated values. 100003 B e r l e x L a b o r a t o r i e s (ICC) VJ-UJOI^UJ . u^, S t . C r o i x , VI Purpose of Survey A RCRA e n f o r c e m e n t i n s p e c t i o n was conducted a t Berlex L a b o r a t o r i e s ( o t h e r w i s e kno%m a s I s l a n d Chemical Company o r ICC ) , S t . C r o i x , V I . The s u r v e y was c o n d u c t e d a t t h e r e q u e s t of the S o l i d Waste Branch t o g e n e r a t e a d d i t i o n a l i n f o r m a t i o n n e c e s s a r y t o d e t e r m i n e t h e f a c i l i t y ' s compliance w i t h RCRA r e g u l a t i o n s . The e l e m e n t s of t h e s u r v e y i n c l u d e d a r e v i e w of t h e f a c i l i t y ' s h i s t o r y ; i n s p e c t i o n of t h e f a c i l i t y ; and t h e sampling of t h e s t r e a m s e d i m e n t s behind t h e p l a n t , t h e l a b o r a t o r y waste p i t , and an o n - s i t e w e l l . Facility History The Berlex (ICC) facility has undergone many changes in ownership since it opened. The owner of the land itself, that the facility is built on, has remained constant. A local landowner originally leased the land on a 99 year lease. The first operator of the plant was Pierell America, Inc., who started operations in 1972. There were several other owners of the facility until 1979, when Berlex Laboratories (ICC) obtained the facility, having merged with the then current o%mer, Cooi>er Laboratories. Berlex Laboratories (ICC), a subsidiary of Schearing, began operating in Noveml>er 1979. Ttieir process involved taking quinidine (found in the eucalyptus tree) and changing isomers in the substance to convert it to quinine. This process continued through late 1982. In October 1982 Berlex (ICC) notified EPA of the forthcoming closure and removal of waste materials and excess chemicals (xylene, toluene) to Inland Chemical of Puerto Rico. EPA assigned Berlex (ICC) the RCRA identification number VID80651095. Prior to this removal, Berlex (ICC) was operating as a small quantity generator. In 1984 Berlex (ICC) sold the facility to Virgin Island Chemical. Virgin Island Chemical planned to produce benzyl acetate at the site by reacting benzyl chloride with acetic acid. This process was in operation for approximately 6-8 months, but ceased when the market price of benzyl acetate plummeted. As part of the sales contract with Virgin Island Chemical, Berlex (ICC) was required to clean up any contamination present at the site. Berlex (ICC) hired Enviro-Sciences, Inc, (ESI) of Denville, NJ, to survey the site and certify it as environmentally clean. ESI's sampling survey disclosed four areas of contamination. Tvo areas, bet%#een tanks 8 and 9 and concrete slab #3 (see Figure 1) were found to be contaminated, primarily with toluene. TSiis contamination was thought to be from process spills. The other two areas, along trench #9 and underneath the concrete loading dock, were contaminated primarily with pyridine, thought to be from a leaking laboratory drain. T»ie quantity of contaminants was estimated at 125 pounds of toluene and 120 pounds of pyridine. ESI recommended on-site treatment of this contaminated soil. The toluene contaminated soil was to be placed in a drying oven equipped with carbon filters, so that emission rates did not exceed the 200 ppm TLV for toluene. 100004 -2- The pyridine contaminated soil was to be treated by cutting the concrete pad and tilling the soil every 2-3 days to allow the soil to aerate. A structure was to be built over the area to prevent soil saturation from rainfall. ESI reported by letter on May 15, 1985 that this clean-up would be initiated on June 6, 1985. The Environmental Services Division conducted an inspection of Berlex Laboratories (ICC) on September 9, 1985. The findings of this inspection are summarized in the attached report (Attachment 1) . On October 10, 1985, 192 fifty-five gallon drums of waste were shipped from Berlex (ICC) to Chemical Waste Management in Alabama (see Attachment 2 - Hazardous waste manifests). This waste included: *> Toluene contaminated soil which had been treated in the drying oven * Process pit water and sludge *> Drums and soil from the wastewater drainage line The pyridine cont£iminated soil reatained in place. As of March 13, 1986, Virgin Island Chemical is not operating the facility. A warehouse full of drum^' exists on the site. ESI claims that approximately 33 of these drums belong to Berlex (ICC). According to ESI the drums contain mostly laboratory reagents, washings, and miscellaneous materials. O^ese have been sampled by ESI and analysis is currently underway. The remaining drums belong to Virgin Island Chemical. These drums contain raw materials, product, and other incidentals used in the Virgin Island Chemical process. A count of these drums yielded a number of approximately 155. According to an inventory of drums by Virgin Island Chemical, which ESI possessed, the number should have been approximately 208. According to ESI, this inventory may have not been accurate because some of the materials may have been re-sold on the island. A representative of Virgin Island Chemical was not present during the inspection. A listing of the drum inventory is provided as Figure 2. Presently, plans are being developed for U.S. Resources, Inc. to lease the site from Virgin Island Chemical. A representative of U.S. Resources was present on the site on the day of the inspection and some of the company's equipment was present on-site. U.S. Resources, Inc. plans to operate the facility as an alcohol conversion plant. The process involves dehydrating alcohol contaminated with water, which is then used to make gasohol. Facility areas/treatment units inspected During -the March 13**^ Inspection the following areas were inspected and/ or sampled: "Process pit The process pit is an 8,000 gallon underground concrete pit that was used to contain process wastewater and sludge that settled from this wastewater. This pit was cleaned out in 1982 when Berlex (ICC) shut do%m operations. The sludge and wastewater present in the tank were 100005 -3- disposed of locally. In 1985 ESI tested water which was found accumulating in the tank. The results from this analysis showed contamination consist- ing of benzyl chloride and some heavy metals. The pit was cleaned again and the contents were shipped to Chemical Waste Management in Alabama as •hazardous waste liquid, N.O.S". This tank was not sampled during the March 13^^ inspection, as originally planned, because it was sealed with concrete after the 1985 clean-out. "Toluene drying oven The oven used for the treatment of toluene contaminated soil was found to be empty during the March 13"* inspection (see photos 1 and 2). According to ESI's representative, the soil present <3uring EPA's September 9, 1985 inspection was shipped to Chemical Waste Management in October 1985. "Pyridine contaminated pad The concrete pad located behind the Berlex (ICC) facility was the area of pyridine contamination. The pad was broken up and the soil tilled every 2-3 days as treatment for the removal of pyridine as specified In ESI's vforkplan. At the time of the March 13"^ inspection the area was uncovered, and according to ESI, had not been tilled recently. Two samples, #085254 and #085255, were taken from this area. A composite of the soil from the surface to a three foot depth was obtained. A seunple, #085252, v&s also taken from a suspected area of seepage Into the intermittent stream behind the Berlex (ICC) plant. Ihis soil sample was a composite from the surface to approximately 10 inches in depth. A background soil sample, #085251, was also taken upstream of the Berlex property for comparison purposes. "Storm water sewer According to ESI, the original storm water sewer at the facility consisted . of old, clean toluene drums welded together and attached to a concrete line. In October 1985 the line %ras excavated and the drums were found to be corroded. Sludge was found to be accumulated in the bottom of the line. Ihe drums, sludge, and two feet of soil were removed and shipped out. A new PVC line was installed (see photo 3). Although this storm water sewer discharges into an intermittent stream located at the edge of the property, the facility does not possess a NPDES permit. Sampling done earlier in this area by ESI revealed higher than background levels of zinc, cadmium, chromium, and lead. A soil sample, #085253, was taken at the point of discharge to the intermittent stream. During sampling, a tropical rainstorm developed, and water was observed discharging from the pipe (see photos 4 and 5). "Production well During the inspection a production well was discovered on-site. The well was not In use at the time, but was still operable. ESI had no knowledge 100006 -4- of thi ^:»urpose, depth, or construction of the well or which owner of the facility had installed or used it. A water sample, #085256, was taken from this %»ell (see photo 6). "Drum storage area A variety of chemicals are presently being stored in a vrarehouse located on the Berlex (ICC) property. According to ESI, the drums contain raw materials, product, and incidentals from Virgin Island Chemical and Berlex (ICC) . Approxi- mately 188 drums were found to be stored during the March 13^^ inspection (see photos 7, 8, 9, and 10 ). Attachment 2 lists the name and quantity of waste stored, according to Virgin Island Chemical's inventory and ESI's statements. Sampling procedures A total of six samples were taken from the Berlex (ICC) facility (see Figure 2- Map of sampling points). Three of the six samples were taken from the intermittent stream (known as the "gut") that runs along the edge of the Berlex (ICC) property. The first sample taken, #085251, was a background soil sample to be used as a comparison to the other samples taken from the gut. The sample was taken from the surface mud using polyethylene scoops and mixed on Benchkote paper to insure repesentative split samples. The sample was analyzed for purgeable organics (POA's), non-volatile organics (NVOA's), PCB's, and setals. The second and third samples, #065252 and #085253, ifere soil samples taken from areas of the gut directly behind the Berlex (ICC) facility. Sample #085252 was taken from an area behind the laboratory drainage pit where drainage •ay have seeped into the gut. Sample #085253 was taken from the area of the gut where the storm sewer discharges. Both of these soil samples were taken from the surface to a depth of 10" using a stainless steel hand auger. The first core from the auger was discarded to minimize cross-contamination; the remaining cores were mixed on Benchkote paper in order to obtain a well- mixed representative sample. Both of the samples were analyzed for POA's, NVOA's, PCB's and metals. Two soil samples were obtained from the laboratory waste drainage pit. The first sample, #085254, was taken approximately 10 feet from the building, and the second,#085255, approxiaately 20 feet from the building. The stainless steel bucket auger (rinsed with water and deionized water) was used to obtain cores to a depth of 3 feet. The cores were mixed on Benchkote paper in order to obtain a representative and well-mixed sample. Both of the sanples %»ere analyzed for POA's, NVOA's, PCB's, and metals. The sixth sample, #085256, was obtained from the production well located on the site. Since the well was of indeterminate diameter and depth, a precise determination of the volume of water to be removed could not be made. By considering the average depth to groundwater in the area of the Berlex (ICC) facility, and the apparent size of the well casing, it was estimated that purging 150 gallons from the well would remove 3-5 times the well volume and samples representative of the groundwater would be obtained. Consequently, the well was pumped for 6 minutes and 20 seconds, removing 170 gallons of water. The sample was then taken directly form the plastic hose attached to the well head to minimize damage to the tfell head. 100007 -5- All samples were split, with ESI acting for the facility. The Seunples were collected in appropriate containers and preserved according to EPA protocol. All samples were shipped on Ice the following day to EPA's Edison laboratory. Results of Analysis The results of the analysis of the sediment and water samples are summarized on three titbles. Table 1 presents a list of organic compounds for which analyses i«fere conducted. This list does not Include compounds which the laboratory may have identified as major peaks. Table 2 shows the organic compounds that viere Iden-tlfied In the samples collected. Tetble 3 lists the results of the metal scan analysis. Most of the samples showed some organics contamination. All of the samples. Including the background sample taken in the gut, contained phthalates, chiefly di-n-octyl phthalate, with butyl benzyl phthalate and bis(2-ethyl hexyl phthalate also appearing in a few samples. These values ranged from 1000 ug/kg to 17,000 ug/kg In the soil samples and 3.9 ug/l to 280 ug/l In the water sample. The results from the sample taken In the gut, at the point where the drainage line discharges (#085253), showed more contamination. This sample contained xylene, 1,4-dichlorobenzene, 1,2-dichlorobenzene, di-n-octyl phthalate, napthalene, flourene, phenanthrene, and aliphatic and aromatic hydrocarbons. The on-site well results showed contamination with chloroform. The PCB analysis results showed the presence of PCB's below the detection limit In all of the samples. The results of the metals analyses, for the sediment samples, showed varying levels of arsenic, beryllium, chromium, copper, lead, nickel, antimony, selenium, and zinc. VRxe results of the metals analyses for the water seunple showed estimated levels of arsenic, beryllitim, cadmium, chromium, copper, mercury, antimony, and zinc. The value for chromium In the sediment samples increased from the background level of 10 ug/kg to 52 ug/kg at the point of the drainage pit discharge, finally leveling off to 25 and 27 ug/kg in the lab waste pit. The value for copper remained fairly constant through all the samples. The value for zinc decreased from background to the point nfhere the lab waste pit seeped Into the gut, but increased to a high of 360 ug/kg at the point where the drainage pit discharged into the gut. The value leveled off to 79 and 80 ug/kg in the lab waste pit. The value for nickel was also higher at the point where the drainage pit discharged into the gut, with as value of 32 ug/kg. 100008 Berlex Laboratories St. Croix, VI VID980651095 2. Former toluene drying oven. 1. Oven formerly used for the drying of toluene contaminated earth. -6- 100009 Berlex Laboratories (ICC) S t . Croix, VI VID980651095 3. Polyethylene storm sever line replacedin 1985. 4. Storm sewer discharge into intermittent stream behind Berlex property during tropical storm. -7- 100010 Berlex Laboratories (ICC) St. Croix, VI VID980651095 5 . Sampling of i n t e r m i t t e n t stream bed during discharge of storm sewer. 6 . Production well located o n - s i t e . - 8 - 100011 Berle-. :•.--. .^ St. Crc:^:-, v'l .o..ies (ICC) VID980651095 7. Warehouse used for drum storage- first room of drums • 6. Warehouse used for drum storage- second room of drums -9- 100012 Bt^rlcx Lalx>ratuiia£ ClCC) St. Croix, VI VID980651095 9. Lab pack drums stored in warehouse. 10. Close-up of drums of benzyl chloride in warehouse. -10- 100013 V 1 2 1 0 FARM Figure 1 - Map"of facility; Contaminated areas (B) tOAO»«0 OOCKfe^lgfS I •rafttHAwiC Aift CAMt. DD ^1. 4ooncAk a.^ieLfJ©;^ •At& cnM».' crMteAtac AIOI •KM I S • u « « «»arm& 3 •kOC. / S.« |H»iT AM* y \ . »<ac r u M 9 TRENCHES ' 1 1-12 0 SO" IOC L-i u-i l U t - l I—1 I SCALE ISLAND CHEMICAL PLOT PLAN 100014 Figure 2 - Drums in storage Virgin Island Chemical drums: Type of material Anti-freeze Miscellaneous detergent Salt Toluene Lube oil Modul Herbicide Benzyl chloride Methyl isobutyl carbonyl Salicylic acid Sodium hydroxide Acetic acid Triethylamine (TEA) Acetone Methyl isobutyl ketone Sulfanic acid Sodium acetate Sodium hexametaphosphate Benzyl acetate Toluene-acetone mix Methanol Sodium hydroxide (solid) Waste # U220 P028 U002 U161 U002,U220 Si: 55 20 35 55 55 35 55 55 55 55 55 55 55 55 55 55 35 35 55 55 55 55 se of drum gallon gallon. gallon gallon gallon gallon gallon gallon gallon gallon gallon gallon gallon gallon gallon gallon gallon gallon gallon gallon gallon gallon 15 gallon (fiber) (fiber, steel) (plastic) (fiber) (plastic) (fiber) ^lantity 19 13 2 10 5 2 1 28 12 27 33 18 3 22 2 4 2 208 Chloroform drums (empty) 55 gallon Berlex (ICC) drvims: Type of material Lab chemicals (Aceto-nitrate, Acetic acid) Washings Cut up drums Miscellaneous materials Crystallized material Quantity 33 ( t o t a l ) 100015 Figure 3 ^1^ of .sanpUng points ' ^ O ^ ' S ^ S l s* O'S'S'S^S^ ' ^ + C r rri,-flcr.-f , j ^O'iSiSiS-fi * * * > , ' rACU-ITY n.OT P\.tM SHOWMO >C _ AREAS or CONTAMINATION > V y ^ • • t t>*a&Mir MLANO CtCMICAL n.OT n.AN X = Sampling point • = Production \vell Not to scale. 100016 3urw^ili Table 1 - Organic corpourwlPor v^ich analysis was- conducted to I o o o Acid (>in|KNtrKis 2 ^ 4 , fi-J r I c M < >ronl »>inol_ P^^cFtl o r o - H- c r c s n i 2-£)0oi-p|)lwriol J^ 2,4-ti lc|ilor<nilM?noi 2 , ^ - i \ line! by I nliotiol , T-_n 11 rOJ )i K!nc > I 4 - n i l rc»i>l»cnol J , f i - t i l i > h r o - « > - c r o s o l "^ |irnldc)iif>rfi|4M>i)r>i |ll«OIM>i |iaB<>/N(Mjlial (nuKHincIs aconajiltl iHrm; i»on7. l<l]iio 1,2,4-1 r i r t i i o r o l i e n z o n o r»OKarr» I o n ll M'nzPiie iieKacl»i<>rn<»i htiiM! hisi 2-t'liloM»oi hyl^elher 2-cii1c>i-(i«in|iiilhalone 1,2-<il<:i»if>r<»lK!nzei^>e ^ _ 1,1-<ll<:li]orfil)otizcne~ 1,4-«IUJ»ioicil>cnzeno 3 , 1 ' <ili:i«loif)lH»nzltllne 2,4-<llnlii<>ic»lli*^no ~ / ^ 2 , f i - i i l n l l loiciiiiorK' i ,2-«il|»iH«nyihyiii a z l n e i a a d7cilN*it74>iM>) f innrnnilioiM! 4-cl»li>ro)iiM>fiyi |ihoityl r l l m r Ha.se/NeuJral^ CamxHindg 4-l»ron>opl»eityl nitenyl ether I»18-|r2-cl>ioroisopropyllelher I»I B{ 2-cH1oroethoKy)roRthane"" ItexachioroliulacrTeiw lH?Kat?hlorocyclopenta(llene" ] I Sfwiltorone ^ iia|>lil.bal«ne n I i rohenzene " ^ fi^n I i r o w x l tpltenyl amine N •nitros<>cTI-n-pro|wlHwlne b l s T J ^ i liy^Vw^^y^^'^>^ l i a l a l e twiiy] y>cnzyl fihlhalale <ll-n-huty1 r^tKaijaJ*^ dl-n-octyT pl^irhalale t i V n i l i y l j i i r i h a l a T e ^ " <Htnolhy1 i J i l T t a l a l e ''_ ln'nzol a) an! hrocene IwMizol a^pyrcno 1,4 - l i e n z o f l urjranibene ix'nzoTlt) f I iJoranOteiie c h r y s c n e af:cna£hii)yiei)e n n i l i r a c e n c IwMizol g h l l ^ i e r y l ene f iiir)re»K» |>iicnanl-.t>rane < I i I KJiizo ( a j \ 0 anthracene i m ionor r, 2 , l-aX) |>yrene |»yrene^ _ V o l a t i l e s a c r o l e i n ftcrylonFt rTJ[e lx»nzene carbon tetrachlorjdo chlorolienzei^e \ , 2-7llciiloroerKane 1,1 »l-tr Icfiloroelhane 1 , 1 - d l c h I o r o e t i t a n e r j T , 2- t r rcliJ<)roei liane \ , \ , 2 , 2 , - t e < rachloroetltano cfijoroetlianc 2 - c h l o r o n l i i y f v I n y I e t h e r c l i l o r o f o n w I jjj^cij^iiToroetTiene _ 1,2;-trans-<TI<?KiorontKene 1,2-cllclilor«\>r«ip«ine i ,_3-djc)«lc)i«>|»ropiene r t h y l hen zone _ _ _ iBuTnylene c l i l o r l d e cTiiorrnMiihano hrcmoetliane h r o n o f o i i n tflchTort^iranfmetTianc ./t r I clilblxjFI»ioraneijiane d I c T i i o r o i f I f l i o r i i n e t l i a n e ~ c l i i o r o d n>r« JIK niethane t e t r a c T i l o i o e l l i y l e n e iohiene^ t r l c l i i o r o t ' l h y l e n e \ v i n y l c l i l o r l f l e I'osI i r h l o s a l t h h i i U o i n r l n ^ " 11 f i l l o n lane 4,i'-i)l« " ' ^,VAiii// 4,4'"-i)()l> ^ 1 1 eiMlosiiiran I CrndoBiiI f an I I eiwio-SMlfan B u r f a l o e i w l r l n f r m i r l n alcMiyilo l»r»pl ai.hlor i M ' p i a c h i ^ r e|ir.M« liln N k ' - A l p l i a r ] ^ ^ _ i M J r l V ' l a ^ i i i k ' j ) n n a " iw«'-(M-«ia iviV 1 2 4 2 ^ ^ in'nl2^>4^ i'(li-i22i^_ ' / Hii-1212 " ivi} l2in^ \^\\^\im ' hr:iVMli6_ J lt>»(aj)lifne DIONIIIS 2 , l , 7 , n l o l i i n h l o i i |>-(liox i n List does not include oofTX>unds identified a other major peaks. BjWal BerleJ^Caboratories St. CroiX/ Virgin Islands V1D9806510951 Table 2 - Results of Organic Analysis- Organic Compounds Detected Comt)ound name Sample location/Sample # VOA Xylene Qiloroform NVOA Butyl benzyl phthalate pi-n-octyl phthalate 1,4 dichlorobenzene 1,2 dichlorobenzene Napthalene Flourene Phenanthrene Bi8(2-ethylhexyl)phthalate Aliphatic & aromatic hydrocarbons PCB PCB-1016 PCB-1232 PCB-1242 PCB-1248 PCB-1254 PCB-1260 Gut Back- ground* #085251 1000 17000 1000K 1000K 1000K 1000K 1000K 1000K 1000K Lab waste pit seep #085252 9000 1000K 1000K 1000K 1000K 1000K 1000K 1000K Drainage pit disch. #085253 470 7700 870 2900 2100 2000 2400 M 1000K 1000K 1000K 1000K 1000K 1000K 1000K Lab waste pit # 1 #085254 4900 100 OK 1000K 1000K 1000K 1000K 1000K 1000K tab waste pit » 2 #085255 3200 1000K 1000K 1000K 1000K 1000K 1000K 1000K 0n-8it« well (ug/l) #085256 130 2K 3.9 280 IK IK IK IK IK IK IK *A11 values in ug/kg except where otherwise stated. K " Actual value known to be less than value given. M = Presence of material verified but not quantified. Blank space means compound was not detected in sample analysis. H O o o l-» VO Be St JCTBJI X Laboratories Croix, Virgin Islands Vlb98 0^1^95 Table 3 - Results of Metals Scan Analysis Compound name Sample location/Sample # Silver Arsenic Beryllium Cadmium Chromium Copper Mercury Lead Nickel Antimony Selenium Thallitjm Zinc Gut Back- ground* #085251 2J 10 40 19 IJ 100 Lab waste pit seep #085252 IJ 7J 22 45 20 J 10 63 Drainage pit disch. #085253 0.8J 8J 52 52 30J 32 IJ 360 Lab waste pit # 1 #085254 0.8J 7J 27 55 25 8.4 0.8J 80 Lab waste pit # 2 #085255 2J 7J 26 58 27 0.8J 79 On-site well (ug/l) #085256 2J 5J 3J 7J 8J 0.6J 3J 20J *A11 values in mg/kg except where otherwise stated. J « Estimated value. M - Presence of material verified but not quantified. Blank space means compound was not detected in sample analysis. Attachment 1; ESD Report of September 9, 1985 Berlex Laboratories (ICC) VID980651095 March 13, 1986 100020 |XI Generator I I Transporter RCRA Enforcement Berlex Laboratories, (a subsidiary of Island Chemical Co., Inc.) St. Croix, Virgin Islands VID80651095 September 9, 1985 Participating Personnel: U.S. Environmental Protection Agency Louis DiGuardia, (Geologist Carol Price, Environmental Scientist Darvene Adams, Environmental Scientist Berlex Laboratories, (ICC) Report Prepared by: Approved for the Director by: Alec A. Smith, Vice President of Operations Raymond Hays Armando Morales, Process Engineer ^ ^ • n J l Louis DiGuardia, Geologist Source Monitoring Section Richard DJ Spear, Chief Surveilla)^ce & Monitoring Branch 100021 TABLE OF CONTENTS SUMMARY Objective i Findings i DISCUSSION Applicable Regulations 1 Purpose of Study 1 Facility History 1 Facility Description and Operation 2 Water Usage and Treatment 3 Waste Streams 3 Treatment Methodology 4 Waste Storage 5 Manifested Shipments 6 Sampling Procedures 6 Sample Results 7 Reference Documents 9 ATTACHMENTS Attachment I - Receipt for Samples Attachment II - Chain of Custody Form Attachment III - Sample Data Sheets Attachment IV - Waste Manifests PHOTOGRAPHS 100022 TABLE Table I - Results of Organics Analysis on Samples LIST OF FIGURES Figure 1 - Facility Location Map Figure 2 - Berlex (Island Chemical) Plot plan Showing Areas of Contamination Figure 3 - Berlex (Island Chemical) Plot plan Showing Location of Dryer Figure 4 - Sample Location Map - Drying Oven Figure 5 - Sample Location Map - Lab Waste Drainage Area 100023 Berlex Laboratories (ICC) V1D80651095 St. Croix, VI SUMMARY Objective This compliance evaluation and sampling inspection was conducted at the request of the Solid Waste Branch to support and verify the decontamina- tion and removal by Berlex (ICC), St. Croix, VI of soil contaminated with toluene and pyridine. Findings 1) Sampling results indicate: " Organic analysis on samples #087001 and #087002 (drying oven) detected the following organic compounds ranging in values from 460 ppb to 15000000 ppb: toluene, flourene, bis(2-ethylhexyl) phthalate, benzophenone and di-n-octyl phthalate (detected only in sample #087002). "' Organics analysis on samples #087003, #087004, #087005, and #067006 (lab waste drainage area) detected the following organic compounds ranging in values from 360 ppb to 75,000 ppb: toluene, bis(2-ethylhexyl) phthalate, di-n-octyl phthalate, chloroform, benzene and di-n-butyl phthalate. From the results, the toluene values were found to be within the acceptable level range of 2 ppm (reference document #2). Due to the late arrival of guidance protocol from EPA Research Laboratories, Cincinnati, no analysis of pyridine was performed. 2) Confirmation of on-site treatment of soil by Berlex (ICC) for toluene and pyridine was made. • Toluene The drying oven was employed for the volatilization of toluene from the soil, but the necessary charcoal filters to absorb the volatil- ized material were not observed. • Pyridine The contaminated soil was tilled and aerated using a backhoe and then covered over by a large synthetic liner. No permanent structure had been built to prevent future saturation of the soil from rainfall. The present liner was not owned by Berlex but rented. 100024 -11- 3) No data on the sampling performed by Berlex was ever received by the USEPA, Environmental Services Division, Edison, NJ to confirm the clean-up by Berlex. 4) The re-routing of existing laboratory discharges to a self-contained unit and portable toilet facilities was not observed. 5) On October 10, 1985, Dr. A. L. Kyles, Vice President, Enviro-Sciences, the consultant %*orking with Berlex (ICC) informed me that 192, 55- gallon drums of waste was removed from Berlex for disposal. The material consisted of the following: » Process pit water and sludge. " Drums and soil from the wastewater drainage line. " 1, 55-gallon drum of water/toluene. " Toluene contaminated soil. No manifest copies were received to confirm this shipment. 6) Hazardous material was stored on-site for greater than 90 days and in quantities greater than 1000 kg. Berlex is then subject to the regulations 40 CFR Parts 262 and 264. None of these regulations were observed to have been followed. 7) In review, a question is raised that a possible source of contam- ination is that of the dry creek bed. Process wastewater was dis- charged via a drainage line to the creek bed. Since the drainage line and soil associated with the line was found contaminated, the possibility of soil contamination in the creek is likely and should be investigated. 100025 Berlex Laboratories (ICC) VID80651095 St. Croix, VI DISCUSSION Applicable Regulations 40 CFR Parts 262 and 264. Purpose of Survey A RCRA compliance evaluation and sampling inspection (CEl) was con- ducted at Berlex Laboratories (ICC), St- Croix, VI on September 9, 1985. The survey was conducted at the request of the Solid Waste Branch to support and verify Berlex's decontamination and removal of soil contaminated with toluene and pyridine. The elements of the survey Included a compliance record review, site survey and sampling. Facility History The Berlex Laboratories, Inc. plant, under the name Island Chemical Company (ICC), produced quinidine from November, 1979 after purchasing the site from Cooper Laboratories, until late 1982. In October 1982, Berlex notified EPA of the forthcoming closure and removal of waste materials and excess chemicals (xylene, toluene) from the site to Island Chemical of Puerto Rico. EPA assigned Berlex the ID No. VID8065I095. Prior to the removal, Berlex was operating as a small quantity generator. Berlex sold the site In September 1984, 21 months after the shut-down of operations to Virgin Island Chemical Co. The sales contract for the site called for the contractor Enviro-Sciences, Inc. (ESI), 19 (k>peland Road, Denville, NJ to survey the site and certify it as environmentally clean. An ESI sampling survey Initiated in September 1984 disclosed two areas of soil contamination, vlth the compounds of concern being toluene and pyridine. On December 21, 1984 Enviro-Sciences, Inc. delivered a progress report describing ESI's sampling and analysis of soil at the Berlex site on St. Croix and included recommendation for treatment of the pyridine (U196) and toluene (D220) contaminated areas. The recommended on-site treatment was selected by ESI as a more economi- cal method than the alternative off-site shipment of drummed soil to the U.S. mainland for placement in an approved landfill. The proposed method of clean-up Includes the drying of toluene contaminated soil (which Is presently stored at the facility in drums) and degratlon of pyridine contaminated soil. This would occur by exposure to ambient air causing soil aeration. Soil saturation by rainfall would be prevented by covering the area with a synthetic liner. 100026 The toluene contamination resulted from soil leaks/spills at a tank site and pyridine contamination from leaks from a laboratory drain line. The estimated quantity of the two materials (toluene and pyridine) are less than 245 pounds. On May 15, 1985, ESI reported the Intended Initiation of clean-up activ- ities on June 6, 1985. Facility Description and Operation The Berlex Laboratories, Inc. (Berlex) plant under the name Island Chemical Co. (ICC), located In St. Croix, Virgin Island started producing quinidine gluconate in November 1979 and operated for 2 years. During operations Berlex employed 215 people on a 2 shift, 5 day/week, work schedule. Maximum production output vas estimated at 50 tons/year, but this level was never reached. The first production batch by Berlex was November 1, 1979 (see Site Location Map, Figure 1). Berlex (ICC), St. Croix, VI manufactured as their sole product quinidine gluconate. The basic raw materials used In production Included quinine sulfate, toluene, and methanol. Production Involved the conversion of quinine sulfate Into quinine gluconate by the addition of toluene in a reaction vessel. The liquid was then distilled vlth methanol to produce the cystalllne solid, quinidine gluconate. Vithln the production area, the facility housed the following reaction vessels: Reaction Vessels Number of Vessels Material Construction Capacity 4 Stainless Steel 1200-1500 gallons 1 Carbon Steel 1200 gallons 1 Glass Lined 3000 gallons 1 Glass Lined 2000 gallons 3 Glass Lined (Receivers) 2000 gallons Bulk raw materials arrived in tank trucks and were stored on-site In 14, 8000 gallon raw material tanks (see photograph #1). 100027 -3- Water Usage and Treatment Groundwater was the primary source of water used in production. Approximately 20,000 gallons were used, of which, 10,000 gallons were recovered. Water was pretreated by filtering and adjusting pH (with sulfuric acid) due to the high carbonate concentration in the groundwater. The facility also housed the following systems (and tanks) : Number of Tanks Capacity Systems 1 15,000 gallons Boiler System 1 15,000 gallons Drinking Water (rainwater) 4 50,000 gallons Recirculated Cooling Water 1 20,000 gallons Reduction/Oxidation Unit I 250,000 gallons Firetank Wastewater from production operations (primarily cooling water) was collected in a 17,000 gallon underground concrete, process pit. No treatment was applied but prior to discharge, the pit was sampled to see if any product was released by accident. If nothing showed in the sampling, the water.was discharged via an underground pipe to a dry creek adjacent to facility property. Waste Streams Hazardous wastes at Berlex (ICC) were generated frcan the following sources: 1) Process Pit Water and Sludge The 17,000 gallon underground concrete pit used to contain pro- duction wastewater and accumulate settled sludge from this waste- water. 2) Former Main Wastewater Drainage Line The underground pipe (constructed of welded 55-gallon drums) from the process pit to dry creek bed. The pipeline was excavated due to the finding of numerous leaks and punctures from which waste- water had contaminated the soil (see Figure 2, areas of contamination). 3) Contaminated Soil Due to Drainage Line Leakage A) Contaminated soil associated with the excavation of the main wastewater drainage line. B) Contaminated soil due to drainage line leakage from the lab- oratory drain. 100028 -4- 4) Contamihated soil from raw material spillage - toluene, pyridine. The spills associated with material transfer and tank or line leakage. Includes soil under the concrete surface loading dock, along trench number 4, under concrete slab number 3, between tanks numbered 8 and 9, and along trench number 9 (see Figure 2, areas of contamination). 5) Contaminated or off-specification raw materials which could neither be reworked nor sold. Prior to the facility's shutdown, Berlex (ICC) was said to be operating as a small quantity generator. What Berlex did with waste prior to the requested hazardous waste shipment (October 27, 1982) is unknown. Treatment Methodology As a result of sampling performed by Enviro-Science, Inc. (ESI) to certify how environmentally clean the site was, ESI disclosed two areas of soil contamination by toluene and pyridine (see figure #2, Plot Plan Showing Areas of Contamination). In response to such a disclosure, ESi recommended on-site'"treatment as an alternative to the economically unfeasible transport of the waste to the U.S. mainland. Reference document #1, contained the following methodology of treatment which was to be followed: * Toluene The toluene contaminated soil would be placed on trays in a dryer located within the facility (see Figure 3, location of drying oven). Soils with low and high toluene concentration were permitted to be mixed to insure uniform drying. The empty drums from which the excavated material was stored would be washed with a nonphosphate detergent, rinsed with tap water and then air dried. Drum washings would be collected and later evaporated in the dryer. These same drums would be used to store the air-dried soil until laboratory analysis indicates that it is free of toluene or has very low concentration. If the soil is found to be free of toluene or at very low levels (2 ppm, reference document #2), it will be redis- tributed on the site. Prior to beginning the drying operation, calculations will be made using the fan speed, oven temperature, and stack diameter to insure that emission rates for toluene do not exceed 200 ppm TLV. This concentraion in air is not flammable. If calculations show that this control rate is marginal, then a carbon pot will be added to insure this limit would not be exceeded (see photographs #4 & #5). 100029 -5- » Pyridine The pyridine contaminated area would be treated in a 3 step approach. 1) The pyridine conteuninated area would be covered over to prevent the saturation of soil from rainfall (see photograph #6). 2) The concrete surface loading dock in the vicinity of the pyridine contaminated areas would be removed using a backhoe and hauled to a landfill or used to stabilize the bank along the dry river bed. The Department of Public Works would be contacted for permission to do the latter. 3) The pyridine contaminated soil would be tilled and aerated using a backhoe at 2-3 day intervals. Soil turning would allow exposure of the contaminated soil to ambient air. Samples would be taken at the beginning of the cleaning operation and continue at weekly intervals until acceptable pyridine levels are reached (2 ppm, reference document #2). When the pyridine level has decreased to zero or an acceptable level the area will be restored and resurfaced according to the owner's requirements. Waste Storage Berlex at the time of inspection was storing waste material in two areas: 1) Outside Fenced Storage Area During facility operations, this was used as a raw material storage area. It consists of a 50' x 20' concrete pad surrounded by a chain-link fence. At the time of inspection, 1, 55-gallon drum containing approximately 40 gallons of a water/toluene mixture was being stored. Other empty 55-gallon drums were also present (see photograph #2 & #3, Outside Drum Storage Area). 2) Warehouse Storage This area was used by Berlex as their major raw material storage area. At the time of inspection, 20, 55-gallon drums of toluene contaminated soil were being stored prior to treatment in the drying oven (see photographs #12, #13, & #14). Large numbers of 55-gallon drums containing raw materials used in production were also being stored in the warehouse. 100030 -6- Manifested Shipments After the shutdown of plant operations in late 1982, the raw materials which remained on-site in the facility's above-ground storage tank were removed (including toluene and xylene). The transporters and TSD used for these shipments were as follows: Transporters Trailer Marine Transport Corp. PRD980644579 Isla Grande, Puerto Rico Transporte Diaz PRD980526834 Zona Portuaria, Puerto Nuevo, San Juan, Puerto Rico TSD Island Chemical of P.R. Inc. PRD090399718 Km 51, Highway #2, Manati, Puerto Rico The manifests are enclosed as Attachment IV. According to Dr. A. L. Kyles, Vice President of Enviro-Science, the consultant working with Berlex (ICC), 192, 55 - gallon drums of waste was removed from the Berlex (ICC) facility on October 10, 1985. The drum contents consisted of the following material: " Process pit water and sludge " Drums and soil from the wastewater drainage line " 1, 55-gallon drum of water/toluene • Toluene contaminated soil No manifest copies were ever received on the shipments frcwn Dr. Kyles. Sampling Procedures On September 9, 1985 samples were taken at Berlex (ICC), St. Croix, Virgin Island from the following areas: • Composite soil sample from the drying oven (left side). Sample #087001 • Composite soil sample from the drying oven (right side). Sample #087002 • Surface soil ccanposite from the north side of the Lab Waste Drainage Area. Sample #087003 100031 -7- » Subsurface soil composite from the north side of the Lab Waste Drainage Area. Sample #087004 * Surface soil composite from the south side of the Lab Waste Drainage Area. Sample #087005 * Subsurface soil composite from the south side of the Lab Waste Drainage Area. Sample #087006 Attachment III contains copies of the sample data sheets. Within the drying oven, the soil was placed on steel trays and stacked in 13, 20 tray bins. A division of the dryer into the left side and right side was made and a composite sample was taken from a represen- tative number of trays. See Figure 4, for sample locations. Photographs #4 and #5, show the location of the drying oven. To take a more representative sample of the Lab Waste Drainage Area, the area was divided into two sections: north and south. Surface soil samples were taken using trowels and subsurface soil samples (approx. 3 foot depth) were taken using dedicated bucket augers. Due to the very resistant nature of the soil (impermeable clay) only a sample depth of three feet could be obtained. See Figure 5, for sample locations. Photographs #7, #8, #9, #10, and #11, shows the areas of sampling. Sampling equipment and containers were prepared according to EPA stan- dard procedures prior to sampling. A total of six samples were taken. The samples were analyzed for purgeable (POA) and non-volatile (NVOA) organic priority pollutants. All analyses were performed in EPA's Edison, New Jersey laboratory. EPA standard procedures were followed for the collection of samples throughout the survey. Samples were not split with facility representatives. Receipt for samples (Attachment I) and chain-of- custody methods forms (Attachment II) were employed for all 62unples taken. Sample Results Sample results are given in Table I. Organic analysis on samples #087001 and #087002 (drying oven) detected the following organic compounds ranging in values from 4 60 ppb to 15,000,000 ppb: toluene, flourene, bis(2-ethyl hexyl) phthal, benzphenone and di-n-octyl phthalate (detected only in sample #087002). 100032 -6- Organic analysis on samples #087003, #087004, #087005 and- #087006 (lab waste drainage area) detected the following organic compounds ranging in values from 360 ppb to 75,000 ppb: toluene, bis(2-ethylhexyl) phthalate, di-n-octyl phthalate, chloroform, benzene and di-n-butyl phthalate. From the results the toluene values were found within the acceptable range of 2 ppm. No laboratory analysis was performed for pyridine due to late arrival of guidance on pyridine protocol from EPA Research Laboratories, Cincinnati. 100033 Reference Documents 1) Enviro-Science Inc., Progress Report, Island Chemical Company, Inc. (Berlex), April 4, 1985. 2) U.S. Environmental Protection Agency, Review of a Report on Pro- posed Soil Decontamination by Enviro-Sciences, Inc. 3) U.S. Environmental Protection Agency, Fact Sheet, Requests to Treat Contaminated Soil at St. Croix Plant Site, February 5, 1985. 4) U.S. Environmental Protection Agency, ICC/Berlex Plant Site, St. Croix Fact Sheet Including Preliminary Analytical Results on Nearby Well Fields. 100034 Berlex Labs, Inc. St. Croix, VI V J-UOUU J X U 3 J Table 1 Results of Organics Analysis on Samples 1 j Organic Compounds Toluene Flourene Bis(2-ethylhexyl)Phtha- -late 1Benzophenone Di-n-octyl Phthalate Chloroform Benzene pi-n-butyl Phthalate Sampled 087001 ug/kg 460 9200 13000 15000000 ... Sample// 087002 ug/kg 560 1300 4700 2600000 500J Sample* 087003 ug/kg 420 16000 Sampled 087004 ug/kg 440 1900 4200 200K 200K Sample// 087005 ug/kg 360 51000 600J Sample// | 087006 ug/kg 400 36000 2000 75000 Sample #087001 - Aerated Soil Composite from Storage Soom (left side) Sample #087002 - Aerated Soil Composite from Storage Room (right side) Sample #087003 - Surface Soil Composite from North Side of Lab Waste Drainage Area Sample #087004 - Subsurface Soil Composite from North Side of Lab Waste Drainage Area Sample #087005 - Surface Soil Composite from South Side of Lab Waste Drainage Area Sample #087006 - Subsurface Soil Composite from South Side of Lab Waste Drainage Area K > Actual value known to be less than value given J ' Estimated value Blank Space - Material Analyzed but not detected 100035 ' I ' FIGURE 1 FACILITY LOCATION MAP 0 5.000 10.000 FF.ET FACILITY LOCATION o o o S O U R C E : C O M P R E H e N S I V E WATER RESOURCES M A N A G E M E N T P L A N FOR THE UNITED S T A T E S V t R O I N I S L A N D S . 1 9 8 3 . CONCRETE PADDING i_n 7 e 6 4 2 1 TANK FARM FIGURE 5k ' A t t M A w I t iM •»»*cc» Iffl M i l l .1 CAf. Al& CAMr. t e n b IMC iN 'MVf^ ^^. 4 A o n 6AL "n;© ft ©.. •Aia c n M P . ' CrNttA^Oft A t o t i i a i D *X9 ftCTtC / AI4A 12 • a w a i t AM* C U ftTtb. . — . _ ! ceMcrarm.^ TRENCHES 1 1 1-12 0 50' IOC L-J u ^ >—I t~H t-H=J SCALE vtAxr f«<Tc^*icr ISLAND CHEMICAL PLOT PLAN 100037 1 CONCRETE PADDING 5 ^ n FlCsOf^t 3 W^kHT Ct«TCAticr ISLAND CHEMICAL PLOT PLAN 100038 Berlex Laboratories St. Croix, VI VID 80651095 DRYING CfVEN - toluene cxsntaminated soil Right Side (North Side) ' ( Top View ) • 1 ! J door I-eft Side (South Side) NOKCH door Corrposite soil sanple frcm drying oven *» #087001 - left side (south side) » #087002 - right side (north side) ( Not to Scale ) * Each rectangle represents one bin containing a stack of twsnty trays. Figure 4 - Sasrple Location Map - Drying Oven 100039 Berlex Laboratories St. Croix, VI VXiJ C5UDOXU3D lAB WASTE DRAINAGE AREA - pyridine contaminated soil Build.ing ® ® ® ® ® ® ® ® (former loading dock area) NORTH ^ ) - Sanple locations for ccrposite Soil sanple f ran north side of the Lab Waste Drainage Area * Surface - #087003 * Subsurface - #087004 Soil sanple frcm south side of the Lab Waste Drainage Area • Surface - #087005 " Subsurface - #087006 ( Not to Scale ) Figure 5 - Sanple Location Map - Lab Waste Drainage Area 100040 ATTACHMENT I Receipt For Samples Berlex Laboratories St. Croix. VI September 9, 1985 100041 ^IIAIN Or-CUSIODV ItfC-eRD mVltONMfNIAl riOTICTlON AOENCr - tlOtON H Environmental Services Division tOltON, NEW JEIIET MI17 hk «) h lis Niiab*' NvBbar • I Daacrl^iaK af Saarlai I \ V \ f a n * * AtuiMiMg' ••s»**tlbUity <*r Saapla: Tin* Oat. t * « » l * M>ab*r Hm» Oat* K*m*it lar Chaai* al Caitarir Saa^U Maabar *d »r: t*c*i«*4 tr: Tia* Dal* ftaataa lar Chani* al Cviiadr t a a a U Naakar o4 t r : C*(*i**d ty: Tia* Da»* (•at** lar Clia*|* al Caitady Saapl* Maakar l*c*ir»4 By: Tta* Oat* • • • t a a l*f Chant* al Cvilady Pmtt M*. 100042 ATTACHMENT II Chain of Custody Form Berlex Laboratories St. Croix. VI September 9, 19 85 100043 CHAIN OF ;US'' DV ^SCORD INVIIONMENTAl riOTECTION AGENCY - lEOION II Environmental Services IHvislon tDISON. NEW JEISEY 01117 • • • *l UH'H a n d Arfdr*i>: i - ^ . ^ 5^ Crovx. ^ VTa^^XiUJcL us;^ ^ VXD^ot^^^"^^ Saaal* Hymhf Niiab*r * l C**fain*ri OaMfi^ia* al SaapUt Q A ~ 3 ^ « - I ^ V f e f t W \ ^ G:^. '^i.t- >*Vcft at Ace. GtV. X r »>*v^ft u>Ac«. SLi. To<- f*^C.ft U»Au5. Qk.IK^c V>Ucf\ wA<i«- 0?7cfel 7K>t ' & " \ I a, SEE. fmrtaa Aa>«ai*i •••a***lbilitr ta' iaapl*: Ttat 0*1* l ^ i h b s S*aal* Nvab*r 5S7oo( To 7wi/»^ riPu!^ t*<*iv*d l y : /D:0O prh Bat* ?/-^i •aatan iar Chaa(* al C*it*4y motii •to Balm^viiKarf Br^ /n^(^>»- F T M I A ^ lauivad >y: lQ^i\0M Tia* Oat* • ^ 7 y 7-^ Raatan iar Ciia*|* al CaUady Saapl* Nuabar -To • * i i * ll*c*i**d (y: t J ^ J ^ f?y!^iM^ Ti»t Oal* • • • * * • far Ckaaa* al Cvttady Mr ^^ ^^^-t^* Saapl*.- ^4lir*b*> ha/ m2nk ^imc^^ Tia* 3 ^ Oal* l*aiaK lar Chani* al Cailady ?//^ On ?e^ OM^6)i;o^awu!i^ » • • • Na. 100044 ATTACHMENT III Sample Data Sheets Berlex Laboratories St. Croix. VI September 9, 1985 100045 FIELD DATA SHEET ENVIRONMENTAL PROTECTION AGENCY - Region tl, Eel; c :, • ENVIRONMENTAL SERVICES DIVISION ;'.v Jersey • Project Name ^ >- 1 ^ >t U ^ h l i ^ ' ^ < • S I d r r-i?||prtn'-(^l p . 6 - c* q r c4 i ^ Affiliation ^ i > ^ L>. ^ P Affiliation _ i i X _ £ _ E ^ .vr SAMPLING METHOD (Circle) Kemmerer DretSge Ponar Manual Niskin Net Seine Trawl Bucket X^rowSj) Cream Dipper Automatic Other LDMSCOOE DATA BASE CODE. STA. TYPE C O D E - SUBSTRATE TYPE (Circle) Aqueous Sediment kludge Oil biological Solvent Extract ( ^ ^ ^ S o t ) ) BOb — Seed Supplied D Yes D No Source: Sample Preparation (Cwcte) Confaifler [[ass Jar»- i ^ Plastic Jar Metal >A Vial - 2 Cubitalner Acetate Core Paper Cap ^ e t i o n L j ^ Foil Cap Ott»er Preservation Acid Solvent Ojemical. Q^^Jc|> Dry Ice Ambient Other Cleanino Procedure j)etergent Wash"^ fater Rinsg kCid Rinse Solvent Rinse: Acetone Hexane t»-*Weth7iene cniorB Othflr tSpecity): Leachate Drum Test Well Depth: ^ Other: Santpte Source Type (Circle) Landfill Storage Tank Top Middle Bottom Truck Drum Tank Other. Wells Monitoring Production Drinking Private Industrial Effluent Process Stream Holding Pond Drum Waste Pile Municipal Treatment influent Effluent-CI Effluent-Non a Sludge Ambient Lake Stream Pond Ocean Estuary Sample Location Description: r \ ^ 4 s i d ( ) Remarks: ^ - S o / ^ P ^ ^ ^ 1 ^p Fonii: FTB RPD-11'a3-2 ; 4jBb>iumber 8anrv>les to B a c t j j fiio C h ^ other Stationtlo. » ^ ^ ^ O ^ O G S / U T 5" Sample Depth (Ft.)/Fac. Loc. Code 087001 Type of Sample Crab Composite Time ^ {Collection Ending) Date vrir~Mo~T~Oay~ Ending Time C24 Hr) \\i\m Beginning Date ?T5 O i l Oav Beginning Tinw g * Hr) i b l S 3 pH Sample Tamp. (*C) : DO (mg/l) I Cond. (uMHOS/CM) Salin>ty(%*) Sample Spilt D Yes " ^ N o If Yes With Whom? Receipt O Yes O No 100046 FIELD DATA SHEET ENVIRONMENTAL PROTECTION AGENCY - Region ll, Ec;>or., N K * iarsr ENVIRONMENTAL SERVICES DIVISION 0£ r' ~m R f < r 'i. L ^ b-^..^.^or.rr t l t ^c^A y ^ T^^• ..i Z r H ^ ' ' " ^ Project Name Collector(s) j ! /> y ^ r A o .Affiliation. ^t^f^'hyi> SAMPLING METHOD (Circle) Kemmerer Dredge Ponar Niskin Net Seine Trawl / ^ r o w ^ Cream Dipper AuTomatic Other Manual Bucket LDMSCODE DATA BASE CODE. STA. TYPE CODE _ SUBSTRATE TYPE (Circle) Aqueous Sohrent Sediment Exlf act -Sludge Oil fiioiogical ) BOD — Seed Supplied D Yes D No Source: Sample Preparation fCircle) Container Solvent Rinse: Preservation Acid. Solvent Chemical. ^^l~icS, DtyTce Ambient Other Qeaning Procedure Aoetor)e [ethylene ChlorldeJ Other (Specify): Laachate Drum Test Welt Depth: Other Sample Source Type (Circle) Landfill Effluent Process Stream Holding Pond . Drum Waste Pile Storage Tank Top Middle Bottom Truck Drum Tank Other. Wells Monitoring Production Drinking Private Industrial Municipal Treatment Influent Effluent-CI Effluent-Non Ct Sludge Ambient Uke Stream Pond Ocean Estuary Sample Location Description: »p<0^«i^ T l <sC,i\ ( c n m ^ r/^cr>) r err\ 'iiaef Remarks: '.r Torm: FTB RPD-1ia2-2 Samples to: •act j Sio Chem Other StatkwMo. V ^ - ?0'.. r* / - f f \ * Sample Depth (Ft.)/Fac. Loc. Code 3.;^ D / lab Numt>er 087002 Type of Sample Crab Composite Time ^ 2 S » Collection (Ending) Date _Yr _ Mo Day Ending Time (24 Hr) \ ( t B Beginning Date Yr,^ Mo_ Oay_ Beginning Time (24 Hr) I t 0 0 pH Sample Temp. (*C) DO (mg/l) Cond. (uMHOS/CM) Saltnlty(V*,) I Sample Split O Y«S ^ No If Yes With Whom? Receipt O Yes D No 100047 FIELD DATA SHEET ENVIRONMENTAL PROTECTION AGENCY - Region 11, Ediison, New Jersey ENVIRONMENTAL SERVICES DIVISION iJES= M. Project n a m t i f ^ ^ \ r i i L < < b v , l r > t : . i ^ ^ v C r U l K ^ ^ ^ Coliector(s). D I 6 i I C r J , *? . Affiliation. O ^ g ^ P ^ SAMPLING METHOD (Circle) Kemmerer Dredge Ponar Manual Niskin Net Seine Trawl Bucket r^otief\ Cream Dipper Automatic Other LDMSCODE DATA BASE CODE. STA. TYPE CODE _ SUBSTRATE TYPE (Circle) Aqueous Sediment Sludge Oil Biological Solvent -Extract y'6theX( ^ ^ . \ ) BOD — Seed Supplied O No Source: Sample Location Description: 3 L « < •^CC C 3ek> I CO 3 i d c o f iobo*'«» i l - ^ 4 ' r O n r ' v n o Z - ^ K " / i - * < 9 i ^ ci<Q, r^y^ Remarks: C \ k ^ i c ^j^y ^ u i j ^ so^'^c *-^^«?-^ «^*^ f Form: FTB im>-1ia2-2 Samples to: Bact Bio A . oy Other Station Mo. V A^t O u> s i O ^ b w Sample Daptt)<Ft.)/Fac. Loc. Code 3 P o zi Lab Number 087003 Type of Sample Grab Composite Time V Collection (Ending) Date Yr Mo Day Ending Time (24 Hr) ) P o o Beginning Date Yr Mo Day Oil. Beginning Time (24 Hr) \_\_±0 pH Sample Temp. CC) DO (mg/l) C^ond. (uMHOS/CM) Salinlty(%,) Sample Split O Vas ^ N o If Yes With Whom? Receipt O Yes D No 100048 FIELD DATA SHEET ENVIRONMENTAL PROTECTION AGENCY - Region 11, Edison, New Jersey ENVIRONMENTAL SERVICES DIVISION O E ^ LaV>e>* ffVPr « 0 < ^ C . • C ^ t r . l ^ / ^ Cvxnn^^ ^ O } il Project Namj Collector(s) L- C" J>!>T o^ . Affiliation fc: PA ' £Sb SAMPLING METHOD (Circle/ Kemmerer Dredge Ponar . Manual Njsisjn Net Seine Trawl Bucket C^owB) Cream Dipper Automatic Other LDMSCODE DATA BASE CODE. STA. TYPE CODE _ SUBSTRATE TYPE (Circle) Aqueous Sediment Sludge Oil Biological Solvent Extract ^ h ^ ( ^ o < I ) BOD — Seed Supplied D Yes • No Source: Sample Preparation (Circle) Preservation Acid Solvent Chemical. ^ e H c ^ Dry Ice Ambient Other CleflTiing Procedure Hexan C Methylene ChloridJ) Other (Specify): Sample Source Type (Orcte) LandlitI Leachate Drum Test Well Depth: Other; Effluent Process Stream Holding Pond Drum Waste Pile Storage Tank Top Middle Bottom Truck Drum Tank Other. Wells Monitoring Prbduction Drinking Private Industrial Municipal Treatment Influent Effluent-CI Effluent-Non Cl Sludge Ambient Lake Stream Pond Ocean Estuary Sample Location Description: ^ O b «, w< •i.-> cr ,\ y.) • ' ^ ^ - S.Cl*7ip \ i 4 r c r r p likJcC^^'citi^O . o f t Remarks: \ A c ' ii <-^ LJO* I Fonn: FTB RPD-11-ft2-2 Samples to: Bact Bio C t ^ Other Button No. ^ 1 ^ ^ 0 ^ £ t o 1 • Sample Depth (Ft.)/Fac. Loc. Code ^ [ ^ k>U Lab Number 087004 Type of Sample -Grab Composite Time Spa^e Coliection (Ending) Date rr Mo Day PJ5- Ertding Time (24 Hr) nrr^ Beginning Date Yr Mo Of, Day Beginning Time (24 Hr) / / VO pH Sample Temp. (*C) I DO (mgn) Cond. (uMHOS/CM) Salinity(V.,) Sample Split D Vas ^ No If Yes With Whom? Receipt D Yes D No 100049 FIELD DATA SHEET ENVIRONMENTAL PROTECTION AGENCY - Region II, Edison, New Jersey ENVIRONMENTAL SERVICES DIVISION -0 Project U«m« G > r r < f ) ( U ^ t o S . ' J . ^ . ^ C c o W \ J T Collector(s) Q » CM.., t., A . *K Affiliation ^ ^ C ^ ^ (J^P SAMPLING METHOD (Circle) Kemmerer Dredge Ponar Niskin Net Seine Trawl ^ T r o w e i ^ Cream Dipper Automatic Other Manual Bucket LOMS CODE DATA BASE (X>DE. STA. TYPE CODE _ SUBSTRATE TYPE (Circle) Aqueous Sediment Sludge Oil Biological Solvent Extract ^ t h e ^ S o ^ ) ) BOD — Seed Supplied D Yes D No Source: Sample Preparation (Circle) Container ^ t g s s Jar * l . i ^ Plastic Jar Metal. J»OA Vial " ^ ^ Cubitalner Acetate Core Paper Cap Feflon C a ^ Foil Cap' Other Preservation Acid Ambient Other Cleanino ^occdurc Acid Rinse Solvent Rinse: Acetone Hexane CC*JTethylene Chlori^^ Other (Specify): Sample Source Type (Circle) Landfill Leachate Drum Test Well Depth: Other: Storage Tank Top Middle Bottom Truck Drum Tank Other. Wells Monitoring Production Drinking Private industrial Effluent Process Stream Holding Pond Drum Waste Pile Municipal Treatment Influent Effluent-CI Effluent-Non Cl Sludge Ambient U k e Stream Pond Ocean Estuary Sample Location Description: ..J Remarks: I- c^-l- AJ\Jo/^ i t C ( Form: FTB RPO-1ia2-2 Samples to: Bact Bio t/ Other Station No. /r]l5(?o U> S | O ^ % Sample Depth (Ft.)/Fac. Loc. Code 3P OV Lab Numt>er 087005 Type of Sample Grab Composite Time S ^ e Collection (Ending) Date Yr Mo Day tf?\o\i Ion Ending Ttnrte (24 Hr) I I 5 5- Beginning Date Yr Mo Day 0|<7 Beginning Time (24 Hr) i l i o pH Sample Temp. rC) I DO (mg/l) Cond. (uMHOS/CM) Salinity(V..) Sample Split t s Vas ^ No If Yes With Whom? Receipt D Yes D No 100050 FIELD DATA SHEET ENVIRONMENTAL PROTECTION AGENCY • Region II, Edison, New Jersey ENVIRONMENTAL SERVICES DIVISION U e F nn "7Bg ' ^ t L.r. t r ^^Ho. i Q 3 ,^c. . i ^ A m . v ^ ^ (.V.(tfy\-rfi.\ Ctj ]) I ' . {:-.>r.t{i,'... Affiliation L f'/- ' L l L, Project Name Collector(s). SAMPLING METHOD (Circle) Kemmerer Dredge Ponar Manual Ni5i(in Net Seine Trawl Bucket Qrowel) Cream Dipper Automatic Other : LOMS CODE DATA BASE CODE. STA. TYPE CODE _ SUBSTRATE TYPE (Circle) Aqueous Sediment Sludge Oil Bioiogical Solvent Extract ^ t h ^ ^ » > ^ ) BOD — Seed Supplied D Yes D No Source: Sample Preparation (Circle) Container Preservation Add Solvent Chemical. ^ i e H S h orylSe Ambient Other Cleaning Procedure Btergent Wash ater Rin'Sfe \ciQ Rinse Solvent Rinse: Acetone fiexane SetViy Other (Specify): Sample Source Type (Circle) Undfill Leachate Drum Test Well Depth: Other: Storage Tank Top Middle Bottom Truck Drum Tank Other. Wells Monitoring Production Drinking Private Industrial Effluent Process Stream Holding Pond Drum Waste Pile Municipal Treatment Influent Effluent-CI Effluent-Non Cl Sludge Ambient Lake Stream Pond Ocean Estuary Sample Location Description: ^ - • V l - • O A ^ I ? Ir ^ C m )cJo d ro. inOQC C 'fZi Remarks: T o ft - ^ c.^^'.'- ^''^'z Form; FTB RPO-1ia2-2 Samples to: Bact J «io Ctvetn^ Other SUtionlto. S ^ i ^ t O (r < ( ^ = 1 •: - Sample Depth (Ft.)/Fac. Loc. Code -2. mmtT ^ O, £r Lab Number 087006 Type of Sample Grab Composite Time Space Ooltection (Ending) Date < ^ Mo Day 0|<> Ending Time (24 Hr) / ^ 3 O Beginning Date Yr Mo Day S\S\Ofi | Q | 9 Beginning Time (24 Hr) / JL.O ^ pH Sample Temp. (*C) DO (mg/i; Cond. (uMHOS/CM) Salinlty(%.) Sample Bplit O Yes O No If Yes With Whom? Receipt D Yes O No 100051 ATTACHMENT IV Waste Manifests Berlex Laboratories St. Croix. VI September 9, 1985 100052 PAWT A : w • ( • M i a i a u M IBISTHJ Chemical I C o . , I n c . z nocuvir;r tm F II IC OB riiUM (Uit'O 77U-22t)n n Aown ' <|i . r I' -s I r « t « t e 1 3 0 ' ; Eathte Bethlehem, S t . Croix, U.S.Virgin IslanJ:; T r a i l e r Marine t r a n a p o r t Corporation 721-1313 Isle Grande, Puerto Rico IMNSrOKIl* HO 2 Transporte Diaz tmtooia ' ' I Zona Portuaria, (ItU'l) V I'n-iTt'.t Puerto Nuevo, San Juan, Puerln Kim BBfoyumiunmInland'Chemical of P . R . , I n c . sra u o a u < -: ' Km. 5 1 , Highway fllllM 'Iwrn HM-i09n # 2 , Manati,' Puerto Rico !»'* W MO | v , l , l ) , 9 , H , D , r . , 5 . 1 0,9,&1 | H , n , D , v . » , n , 6,0.6, s.7.9! I'I Iti DiVl til Ol 3, 2, 61 6,3.^1 ll'lHit) (1, 9, 0,3, 9, 9 , 7 , 1 , 8 | U , u . . i | V | U i ; > i y , > , / , i . f MfM nua n c Twu^sramtfi ut. TO • uTum ru ivr TK rou.o«w( u tfMii:-i.Mi IMS I I- II M iC | D j O J L faorausDOT I' . I Xylene RQ \A il "• ^ I I I euntvjca riam. Liquid MlMIR 1307 fMIM •ri .klMIIlT 1 I3l6l2lfil LL.I_I_LJ 1 1 1 1 1 1 1 1 1 1 1 1 1 , i.L.L.I 1 1 t 1 1 1 n.ii .... (iWI/. 1 M j i-iaJ I M I LijJ IxJ 1 w l i f i i ITIKI M 1 ,1 L 1 1 1 1 1 1 1 1 ,J iAe i n tu/ liJ u u u Ll u iai/ir« MASii ir*-i IrinmlV L l l 1 1 1 1 1 1 1 ^ i i i i i I M H 1 , . .1 :.ittJU Htit3i<i.:MSTr.cnouatauOiiC CWT*tiilll|UMrTIOii ^t BlKimctiH^ni api.i-.M;.v ;-,-;.:.iinr.t:ir'. iiiei .ini'V'.'.i •'.( tuiii.ii.'.//.h::ci.'r>bAtjii[ VKuCn 00 hOI MM TO • MUtftSni^ I: | I i l l ; k « • i|i»tc»*ii n(i.i«aB ¥ • • twaUMn •< Iiim^inM B.t IM M« »• Immmmti*. •• I' N Ifcc ««ut *[ta*t< .IH». •«•• tiratimt M ik. Irm^mti wnrt Ikt 4K«t»im I ; ' I I • ' ' I : CtiaiUTOItf a t u T i M '"Liu o r e H. J e r o r e H. Ludwiq Tint President TCiUSrOMIf> ao 1 S C M T M I *% *• kni X «r Uamlttti *» mumu t» |I» %-t»ntt: I k»t azttrt* ta > — » t CMflima M«|I UW iaaftmn m t n IIMIIIM " MK Mmi'in J:MJir!^.Ll?s!^ TUttSfORUHVI! n ^ ' SECS i 9 | 2 | B | 2 | 2 | 3 | , tiiiciiuAM««io*n UIZI 1 Ml IB 131 f^r" r/v tn II* (' Hiljl-AO VII tIA T^hH ' • • ! l : IIAHA^ y-iS ••••i-v PART a .;.. „.A o,. [ V | 1 | D | 9 | 0 | 0 | 6 , 5 | 1 | D , 9 | 5 | 100053 inMtruetions s»Arrr r.-.; tiaiuna'MM , leland Chemical Xo m m u r a w t A L i n Ol- PUfcHTO RICO NVmONMENTAL QUALITY BOA US WASTE MANI ^#r" (BD9) 77B-22D0 Estate 13Q . Cetete Bethlehem, St. Croix, U.S.Virgin Islands Trailer Marine Tranaport Corporation Tc 009) 721-1313 v n u M u Isla Grande, Puerto Rico 1MKtfO«n« M ] Transporte Diaz PIIIIM (009) 792-7999 tlTlAOOKU . , 1 . . , , Zona P o r t u a r i a , Puerto Nuevo; San Juan, Puerto Rico numiKV powGt OR | Q(snu*i (ttoi n a m Inland Chemical 6f P.R., I n c . 'To09) B54-1090 tm tioows , 1 Km. 5 1 , Highway t - l , Manati, Puerto Rico 1^4 c «c | v , I i D , 9 , B , 0 , 6 , 5,1.0.9 P , R , D , 9 , B . 0 i 6 , < i , 4 . 5 | 7 | P | R , D l 9 | B | D , 5 , 2 | 6 | 6 i ? IPIR. PI 0,9, 0,3, 9, 9, 7,1 ( MOV IMU THO TMnrORTUB MB TO • VTUBl HX a / r i l t rOUOHMK; t t VfAOnATI MSiowtsn- . V k TOTil V • • <ttWT MMKiiT aocuMim n s PR i l t C ' 0 ' 7 ' • < n W H us DOT • iJ S w r a C M N t I '.. 1 Xylene RQ ifiwr auuocus riam. Liquid 1307 roMM aiT tut 3l 3| 2, Dl X J - J__L J_J- ..1 1 UMIS gal COMIAINIRS HO JJL im Lt Ld LJ Tor ir* MA; Ll U U U U U imm WASH • lia. L^ LLJ. J _ L t . l :ii icui icufKiNC iHStouCDOitswcuiowc CDiiiAaiiiituiiirTml ^ otHTiriuiKM u AimiiKUiAi WASUSMUUIUO« siamuiiir w AiiObiazAioouSNiiiiu WHIOI 00 Ml MAW TO • MAN*EsnOl | — \ aumOKSmiWCATlOi; TlM»»t»v»i>Mm»iB»»tM»»««««ntii»t|ie»r%a«i*«t««ui*t<.«i»it<»w«l«iillU»'«»t«fiWi«it«niiiaBt».u»a»aii«uiiB«tt»<*{ K i)w «ybciMi wfutawa tt mt DavaiMX •< Iivayinjan III IM mt 0* C u i m i ^ i h *i f K Tlw arnit t n o ^ t i Aew M K cimi(M>< u (kc TitnkHnn MHH TM bB«(r*i|>afB4FaciWta«>ai<w'Kn|iiaaiti«aaMiltai»«MMm. •i«k«>a<liiH<*M«tiW lnilil|*i(lk>ta>rtMigDkiitaMunitinMI(«a**i I i ClUUTOirS SiCMTUM I I Jerome H. Ludtrig Tint President WMonmum iS«MTWI ntIW>WIi<tto—it»i»§Biiiiiii»i•» BATl SMTKiU I M l |1 |31 lBl3l TMRSnWK*) MU I J " ; ^ SECS I 9 l 2 l 8 l 2 n i 9 i 0 . UHCItO M f W l OATl OATl H i u m c 1_U |_L_l LJ Mil DAT ^ f TlAtl Al IHIS 1M0llAIII,-h PART B UN IPA t f |V|IlD|9|B|D|6|5|1|Dt9| I lluvtfOKTIAliO t SUAT|W1ani%thaikm •MrH M omffili t* KB a v M R * ad aaHrW • • • iMr.*tti hKi.>iVOIIUA W > lEllAtUM I f a s k m tl a^ InwM^iiita M M S « mt M..(t9i«rfl» lnii^igttwi<WiaOftwfp«—ipi! Iiu*srwin>ac 7BMATlK1IB«ftiall«nwi nunyonithko > r;^' M 11 1 1 1 1 hniAiMtuT mmu. o* oorut netm muTm « m I KTIMtl MtaVISl ANC SwfMIIITOIIunK 01 MASOkS DA 11011 IVl n n lUIl (UCIIVIO rfiH hAr^ ^-g- mr' mr* "^ NAiouiC •itytgt iMTMcmrvMHoiPvoeAibfimfMATui^n^ri''^ I Bflti • # M (tNOM t l M M^tM (•Ham t r * At taBf^ *>M tN^tB «nt» l»Mt ««cTtt»g>i «•>« XI HI'ton* ' i . ll' • . • tl ( t w f! tmtiftKt « Wi; t n * M ^ . « | l|il IM iMr<Mmmg X « * i I t k o |t'J> T . ^ I M ; J: I PAU MCtnffO L r ^ ^ ^ - ' '-.i-J •wvjt:\ti'. Nu 100054 1D/«fi >ART A: C O M M O N W E A L T H OF r^UERTO RICO E N V I R O N M E N T A L QUALITY BOARD H A Z A R D O U S WASTE MANIFEST DOCIIMIM MU « l « I U T 0 « W " « . , - , Island Chemica] Co,, Inc. I MlllM |(niV)) 77(1-221)0 •• " IL U6 " e s t a t e 13Q, Eetate Bethlehem, S t . Croix, U.S. Virpin Islands TMNS'Oinill NO I T r a i l e r Marine Transport Corporation (009) 721-1313 ST( U D K i i I s l a Grande, Puerto Rico UtAHSPORUH NC 2 Transporte Diaz snt AiiDittss Zona P o r t u a r i a , Puerto Nuevo, San Juan, Puerto Rico riM.M lEIW.) 792-7';99 . oisfoui trsoi lACun Inl^pd Chemical of P.R., Inc. ffftf^) B54-1090 sn*oo«ss Km. 5 1 , Highway # 2, Manati, Puerto Rico I •'.• i;; kCi |V|l|U,V|U|ll,(,,i,1 11 |V,' L ii^ip'oiii^ir. iziiLisni' I'l"'.^l9|l • j i 7 l C ^ U y } i ' hR|D|0|9,0.3,9,9,7,1,f I MOM THAN TWO TMNSrORTIia U l TO • i n i l l U . Ftl W r TM rOUOMMK AS t f r t O M t l 1 1 T t U f O W S N O - . » t TOTAt or • TM FIST I I A a F t r DOCtMNT NO B P R [I. e.o.6 I I 1 I. J . I f M f t l J I S OOI BOT)NCNAMI 1 Toluene RO MOOT MAZAJeOAS riam. Liquid 1294 IBRM M l OUANTin L i l j T j L 1 1 1 l l l l t l L I I I I 1 1 1 ! 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V I 00 «0> NAM 10 Bf NUBTiSTU) :.'iA«i.!i.. i . . u i t w v . iii:^' CikKUIORSUKIUICAIIQIi \Ol^a\^t^t^•^^Ol»tt^^t\an»0^r^l^mmflxm^^ttflvi|rltUilll*^.^c-.*.*m-llmxM^ril^.4Kdr^tr^^la^.m,^'>|•.lm»l•.m.^.^^r^..t^^..^^ m Mw AHitMtW. iriultiant tf DM Oi^jnmM t) titmpantiitn US iPA tn<lkt Uamnattiilieil'K 1^r mtut Onaikr^ ^lumr » . . . .. •vgm^iu'iir U.m.M,-:f m^rti t.'t ItmnicmS«ti»;tttPa»o«tiftc*nan 1 1 i l l t c c t p ' t t t t l i ^ i K W t l t i a a t o M M « I H m4ti»nnt'*r•«•»'uai.wi ltm*,t/ii.iitmr- ...MnHaitmrtn.:..mTtttr-.uvt.y -.^ IIAII UMI'liI t ^ m^ ^ I2l3l1l0i3i0i3i tiriLini/.McvAi luri RATI MMr.in ILLL* mzi £ii m PART B U N irA u « jff^:S/j^9 V,I,D|9,n,0,6,5|1|0|9,; 1MMJ*0in(»H0 il'fiH itt cwitt.fU 1 SBNATun -1ctnil|lluK9nMi I tlu^sfOlnill NO > SCWTIK i t I * ttn ti t^ ttaafftm I l * n tttiviat la f t w t u t t n t ai*. Ma I M S I TAANSrOAIIR Ml.' ? l U i i i r o n i t M l ISCNAIUC 1 n n i i r t > « l k t r t t B U > * n t * * « * a a t n « r Mt>rf Mt a m n n t< Ma t l ^ n a v " ..,.. fhAIMINT tlOMCI OR OISIVSAI FAttrTT MSCATVa V M n r | | F F I I U a S UTWIU MAM) I <iT AMII SIIPMi III M l S I M t 01 MASm: tORMCOOPOSIIBIiOillLICniC MATUtklS 'illiii' | • • sr I J .: I 1 IWHAIM ST1WA61 M 0l5»0NUi lAOini WIUIM "U«« Mi« l M » t a i ' I U.I4,»«,», » « , « , .1««,!„.,»« artt.4 . « « « fctofi* • MM *«ui„i titu' i c , «.>tm»Titi Mi.a Ml «... le,,, * • • • ll •->.'(>>», r W.J -nBtt.Mrt iKi Ik. U..atmin:< (...i.i, fcj»r .1:3 \t\ mn UAii Duivinfn m^j g,?^ ^ Oiiii tuiiwr. "A' H T H 'TfT" ' • T ' MANn ISI. r>' lull Mrmiii fil!r:!VlM '.'i: I JJ ^^ ^^ e£ 100055 RT A: OOCUMEM NO PR IC 05 UMKATOHNua Island Chemical Co., Inc. PMOdl (809) 778-2200 sm AOo«u "Estate 13Q, Estate Bethlehem, St. Croix, U.S. Virgin Islands TIUIISK»m« NO I Trailer Marine Transport Corporation 7'i''69) 721-1313 SIIAOOUU Isla Grande, Puerto Rico |P|RiDi9,0,f)|6,6,6,5,7,'. IIUIlSn)Rll« NO } Transporte Diaz piiim (0D9) 792-7999 S m AOOKSS Zona Portuaria, Puerto Nuevo, San Juan, Puerto Rico TttATMNT. SIOMU t » osPOSAi (TsoiFAaiTT Inland Chemical oT P.R., Inc. rtiuNi (nov) IIW-1D90 SITl AOOIUSS Km. 51, Highway # 2 , Manati, Puerto Rico (PA O NO V|I ,0,9,6 ,0,6,5,1 0,9,; P|R|D|9|R,0,5|2|6|B|3,' |p,R,0,0.9,0.3,9.9,7.1,1 f MDK M M TWO TUNSfORTtlB M l n K UTUZID. FU OVTTK lOUiMMS AS WfMOPUK THSFOWStlO- ' i TOTAt OF - 2 — raoft* us OOT (MfiyiCNAME • Toluene RO WFMST MAWEST 00CUMEN1 NO B P.R " i C l O . 5 . . I MOOT MAttWOASS Flam. Liquid 129ii FOAM KT OUANTITT Liiiiiiiii I M I I I I I I M I 1 M t I I I ' UN:IS r.al coniAiWKS NO LLJ:J j - j . 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I«« l>»> j nl.t (iwi«m |« t t t t litnt«|ilMiU.' lwnpai^Bkt«a..'iw<niioii»linitlai, HMRAIORS SISNA Jerome HT^Lu&wig TITU President IRANSPORTO N M SCaATUK I t lla Wu t l ai, tanrtttgi ttt iA^maa I t a t «rtt»t< la Naattn ctnfcnm anHi Wa tttoaiita • Nw t l l k i OAT[ Sin>TIII t 111 |1|D| |B|3| TRARSPORTtRNn I S**;^' s e x U|2|3|1|0|3|1i9, U P l C l i O ARnvAl OAK ^ ^ ^ U l l Wiir.10 ^fi\l I toiTi ^J>i< t/ll HAY «> Iv, IlD|9|B|0|6,5,1|0i9|5 PART a B N IPA ON TMMSPORTIRNO I tICNATURI l a n i | > M H < M t M t t t l l a a » v t < a * « B M n # | lAAWSPORUIl NO ) MkATUK I t M kni t l i n baaMi«r tarn aaitfiu t l ik. (kaiHactii I ka>i nnvi.<iv«as*aturhnaa.n.nBM»^tiaiiaOaiaan.(c>i" riUNtPORIIR NU 7 STo' M M 1 I I I IHAkSPORIIINO T S g « i A T u W - | c t ( i # , a a l k t w a B i l t | i i | < a « k » M a i ^ i h a t f iia laiimii t l IIM i TRIATWI m SlOUCt OR OlSPOSAl FACtlTT MIDtnON OF ANT OTFIKNCtS U TM EN MANU [ SI ANO SHIPUI NI OR IISIWI, 01 W AS(III<: rORANODlSPOS.'ICIiOIR[JiniO MAIIIIUUS lAAIMIAT SIORACl OR 0l!P9N&At lADint ilM:.IUlI Viw'tituN mprciu,n. I iin«r ik« • * ctattmi t l Mkt ih^rirrj union* aOi Tta t n a i p i a tn Itai •ij...lf n ticf»i ti.«n t i c u r a i f n i aairl t " ffrn I f " ' k ( * i al t « . . | . v , a i f . i .->»».in.«l, 1(11 ih. I...uaai«ni» fait .1, S. ...i ,K,' 77!i IS97 AH OIllVtRU - , _ OAII RICIIVID H r ^ ^ ^ ^ ri H.\kOUN[i ^•1 tMfin o 'A' / / l.-\i I f VII. u^ ^ f^ )':ij:rtu::.-Ji^-CS- - 40/80 100056 M -i.'.r>.DOUS W A S T E M A N I F E S T n:ii .:M,'.'i NLi PR K Oi (nrn) 77ii-22ijn ot klk'l island Chemical I n . , I m : . . ACDWSS Cstet.e 13Q C s t u t f Rrtlilphem, S t . r m i v . U.S. ^ r ' j j j i ^ : " i i i " l i l T r a i l e r Marine Triinnport Corporatinn I (ni)9) 721 131J ii-i IT. «r. V i i i D i 9 | n , n t 6 | 5 , i (1,•' sin A::-^.";'. Jsl.T Cramlr-, Puirrto Rico vT-i .1 i:; . •. ' 1 r;inr.porl '• Di.T.' — I }P.R.D.9.D.0,6.^.4.5.- (IllVO 7'>2-7'>9V S!, i.-r.«|-.;, / a y j f o r t u a n a , Puertii Nuevo, Sun Juan, Puerto Rico T ' l i : 7 ^ ' •••:i . ^ W C ' l . i i n - . - .,,.-1 ••• •i.rnn Inland rhemjcal o f P.R.. I n c . (009) 056-1090 Kn.. ' ' 1 . Hiqhwny f 2 , H i i n u t i , Puerto Ricn ••vii:! ••.•••. ...>Tit.-.;.v.« ijs •• ; ;i tl i;!:'.cin. I i i Our iw loii'n'.'.:. A'jA'.;.r».i' 1 1 fi.j. ».!-.• If. vi •- • •- r> t TTAi 01 Tw i«n t»kv*»M r.ici«nvi Nn ;s P | R | D | 9 . 0 | 0 | 5 | 2 | 6 | H , 5 | P | R , D i O , 9 | D | 3 , 9 , 9 , 7 | l R l l il^ .0 1^ • • t ' •••••>ti<i.%i'iii i n l u ' i H - V'i ICOOT MA:£r.l UASS Irt riaiii. 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U . - I . . nuaspoaiit NO 1 r. J. I- ' • j r l n n Trimrrio pri Aonm SS J I • : .• ft ' c , PULTLO r.i U U . i.^ - . , . 1 - . . t . 1 l i . . i W . J r t C^vvr:-- y . - ^ C O TWHSPORItR NO } 1. l o '.;iaz • TO. & J . . I A ; J A U J I . I . i '"ao:.') 721-1313 PHONE (007) 7P2-7999 SHE ADORIS! /. ; . / l u t r l . - i , Puerto Nusvo, 5.»r, J u n , TuDrln T l c o TREAIMEKl STORAGE OR oisPOSAi (TsollAcniTT Inlnrnl O i c . i l c a l o f P . H . , I n c . PWONE (';j?) ns-viHTn sni AOORiss . . . ! , '.l Mi/.iy 9 ? , f ! o n : i t l , Puerto Rico V MORE THAN TWO TRANSPORTERS A K TO U U T U n C . F l i OUT TNF FOUOWING AS APPROPlATI THIS FOHA- S NO «F A TOTA! V - 1 - T W FIRST UAWFEST OOCUMfBT NO IS P. R. « t « » i US OOT SHIPPING NAME , T o ? . n - . . : I 3 4 s e us DOT lUZAROCUSS Flan, Llr^ild aUMUR 12M FORM L an OUAMTTTT 1 |6|7|fi|3 t , . . 1 l . l l l l . . , . 1 1.. . .1 IMTS Cal, |P,n,0,9,D,l),o,6,<.,5,/, P,fi,0,9,U,0,5,?.,.-.,^,S |p,r,l),0,9,0,3,9,y,7,l, | l , C , 0 , 3 , , , 1 CONTAIWRS ao l i n l 1 1 1 I I I I M I IM TYPE ITP M ICE" EPA HA? y Ll 108/E'« WASH Ki h-l . I 1 1 I 1 1 l l . J ^ SPEOAI NANOliNC MSTRUCTWNS'wauOWG COMIAai£R UEMPTUN h i DCNTIFCATION Of AOOaiONAl WASTIS WClUOEO « SMPMINT OF A NONNA2ARO0US NAIilM WHICH DO NOT H A M TO H MANIFESTtOl SENERATORSCERII'tCATIOrj Tki>aiactnil|tlitil«tbwtaanitaatnaliaf piitntbasilitd.ttMntit.tu>tttan4lib(Ut«in«aimtrtt*fiaa«iutala'*vsponaiio<iticaiging m Ha latiictMi itftlaani t l Ma Ottaiaaffl t l Timttruiitn US (PA ai^ Ha CtMBcnatiRIi t l r.K Tkt wmn tmsiktt tbotiatra t t a i i r i * • • » Traawtna aaaw4 Tkt litaawai $•«!«• a Oopestl Ftcilar can aid ««tcttpi Ha it^aaai t l IWBttui atat. •>« Iw t «iM HHiBi It i t at I ttnrtr Nia te k i t f t i ^ AaawlrdtK SINIRAIURSSICMAIURl '. . .-. . / • t y r : / Jenjuia 11. lod'.fli] ^; ' I . TITU PrcJltJont nuNSPORTIR NO I SCNATURt I t Ma ktsi tf • ( laaal«<9i Ua ^laaiai I kan ticttitil la kanstwi ctaiaaa auk Mt tea^Dta •• tlHa OATttHIPPtO fl ff I I (71 n c j TRANSPORTIRn I «Httu SOCJ P 13 t l t n IS C 13 I (XPECTtO ARRIVAl OATl OATl RtCEIVlD LlLJ L J ^ LJ_ wn flAT III / • / HAR AT TWS KRFORATMM =^::£ = r - ~ r r - ^ •=, * »»ART B flZf^^ « N (PA m 0^-fi}y__ , Iv il 0 19 ^n C F^ ,5 tl 0 F.' f . u • . ; » : ; B i : - « . ? • s : < i ' u " i • 1 t » ^ . l ^ • l « l l < l ^ r s « ^ ^ t m s r « t 4 C ? ! ^ t l » l r r ' l ^ ! : , y - \rr* i*a tmsmx »• •», maiimii ' t^ K^ ^r- / . . . . ' • ' . ^ / ^ L r . - . n r. .. • • ' — r ^ -^y^A, > ^ ^ j /(A^i/^C^rfli r / TNAKSPORUR NO » S«NA1UNE I t « • t i t i tf - , l a t - l t t * t Ha ( t m m i t l l ( i u.,«M<a I k M mtvirf. "a naniaai tsr<aaa aMti Ha tnoatan ta Hn aiaHlni TMNSPORn^Xo : «HIClE v - / 10 NO I I I I I M I 1«-.:»:aTia»- J J - . . U - . * ! ' t . - ' , « r i , « , , * , a „ . , M . « h a a a . . . . i . , »(r.a **.. M.M.*.-. »• ii..t t»aaawi I l a a i H i M t i o M U oa r I'OiA; l a t a n t anicAno* o< amt o a r i M a c i i W I M I H MamrttT AND SHIPMIMI ORUSTWC Of IVASONS i < i . a f . • . . . • .. 1. . i r ' i : Vi-.••»•« ?l T R A ' M I S : : : o r . A O ! O R O I S P O N S A I I A C H I T T SIlWA'URi " U t - w < » l a w « n ^ j I ct<i>«t fktt Ikt ramtfit t< nui i h « m r m e a i l t n . a a t • « i t » o , i a „ « , ^ ^ mtrrHnl t . t f f Ihei. a.%...;ia«i.f, Boitfl c' triri *tt*a" -1. tS-.t .1 trntti ".• > f M• mj....i-...:, m i lat Eananamial auti.t, fio>.« iSDOi DATE : ! ; i v f t ; r u g i ' i ^ ^!- OATE RECEIVED I L I L-1_J l - I - ' T M W'^' »-'• :r i^L NAMI:IIJC AM.iilD OATl MCEIWD ^ , OOCIWENT HOsf-**? P B J4S.»,..^. • « 100058 y / " cou'sr.iuiJv.'^Af.'i;. L. . .... . w., -y' E'»*VIKONr.':EriVAL Q U A L I T ' . ' D O \ n D L J ^ Z A R D O U G IVAGTC XZiWiW J A CS^^IC&L / * . . * M i Z a • ^ '••"-•'•"''t i ' t u v J i - . » t L j % . . . I . R t i l - • ^ • •-• • " • • • - ; , < V - . . . - . . - - • • -V - - r Z - . - • • MiiiniA • ^ . . . 1 - - . - . •1 iiii-.i ^ J r fiuiMi.';.' DOCUMENT NO. PHONE r - • " > • • ' ' • • " 2 i . i M - I ' M . f l l i M r . l OR * i - r - i i - . l OC I l*Cnn» i . . » . . , ^ r!i.> - i r - l r-" '• V I - - -.. Aiiiims: • , ••• • . ; • ' , 1 - - T t , - i ! - — « ' ? - , , .;....« PH.".;;; " • • - - . PHUNE r - ' .--.•._1^.•^l • r K (PA Al liil 1VIT1^-1-.M 111' |- 111 I I ' 1 Lje.iii3Xj._L_' .'.-;:_'..x-! LlvMrJ.J..l;.J J. 1. !. I ! 1 j 1. '-•.'iJiil .1 •!• 1 1 ' : ' l l -.TTirii 1HA> n-.U lUANSHORIlRS A K 10 BE U T i m O . t U OUT T K FOUOMIINO AS APPROItAll ' i r . ; I iJIBA 15 '10 1 '-.— OF A TOTAL OF — I — THI FIRST MANlflST OUCOMrW! NO K PR L'-liL » ' ! r>.>.T.R m wn eitrrwu UU1E as OOI RAZARSCUSS riL-j. T.;-;alJ. •WISER -!.:•_ fORM MT OUANTTTY UL-J 11 1 1 I_J_J 1 I I I I ' I I ' l l l i l t UNIIS Z'-la .1 L CONl/JNTn.<: UO LL..J I I L L J LuJ -L_L L^l TTPl I irii iJ i.] LJjiJ !..J l i l t 11.-. VV.'.l. 1,1 I'rr; LLI a.*i-i.!r=:- 1_!..L LLiii-Jii'-- LLJILHU.. '••.IH.- •li:H.i:.'r.1ll(CTinNSaBlUOWCC0NTAMtR(nMProNM DENTirCATIQNorAOOITMMAlWASTISMaUOtOWSMPMEHtOFANOMHAUNIWIi.-^'iAli;.! ;.-:nt't ::ni MAV TO H MAMI($T(0| • . ^ ' i ~ i C H ' I I H . A I I O H ll»»BltttniltMtallitatn>taaattaatiiat»ataai«it,tl«.^Hit*tr*iiiialaMltila«dl»cll««aitacaai»TiCT«*iitiitivii.-..<-"'.-w^H ...«•>../ .... a,«f'• Jt wailainm t l Hn Ol»««atM d Traatttlaatii US IPA ani \kt Ca * t i al I' M Ike a a i i «t»a*a< M a n attt oaaafa* tt Hn ' i a r i - - , u-.^ • , / MM..,! SI. t r ^ w H a p w ^ F t n t p ^ i t a a t c t t l M N a t N a i i n i»l>»>ail»p>awt.«aJlMct.»W|aiaallttt«t l i i i l r * n H a h r a < i a i n a * » a W t a . i n i - « • . »•••••'.•.. '-.. A-^Sr .ciraiur .siutuiuitf ITITU •AFI BIIPriD l_!_l L L J U_I -'•Vill^Wl I S m A T u n I t Na tat atMvtatalttgt tte HMrnn t l l l a vt« I k>-• a n t ^ t t In aantai t a t l v a i a M Ha i m i t u t * a> tta ntailtti" TMNmiRTlRWl I WWDE V NO ;• . • ; M I ,t I ^ . M L.l..! l . ' . i L-' OAn iaa!i?:i L J j J l.'...t t : ' Mf. I ' I ' .-> TIAtl AT TNC nRFON-MXIN •/F,-V< ' . i r r:T I 6(N IPA l ) » Lj__u-L-i_'.i • I "POill'HUO I ST.NAIim - T t r ^ m a l l m t a M i a a t a t ^ a H k a a u i a i a a r J HI I mn^fn t t Hn tlivaitat' ' I.. Tfili R NO 2 tnMMUW I t ( a t « i t l a^ tt<vtniai>anatiiaatat<aHk«auiaiaar \ Ha aaitMs a. H I . ! - i - . i . 11 M*. artattrtf la Ifl • art. N a t t i U f i a i t a l t a i a a . i l i f TAAnr^MIIIRN^ 2 VllllUt m NO I I I I I M I <K<470RI.R«) 2 t B N A T V K l a i t t | t t a l l i M t a i a a 9 a t t a t k a a a i a u « T I Jl • H tta .vntaH tt « • tttt"ttC ; m \ M B N SllWAHOR0Un»Al.fAaiTTMCA110Na(A«YMrF(RINClSKTW<lNUMir[S1ANDBIPMtNTaRUnK;0IKAaM$ ii«AaiaisposittadFKj(CTB M A T I M U 1 0 0 0 5 9 IKalAHin SIUn.\tt OM OUPOKAl F AOIITT ISNAIUft -Vpw ^ m * tafwwai li«l<h». tt<aMtMiti«tttt^BR««ttnlaaaattttt«tiavMatBttnawalw • t » i tte t t r M n m t s r i smH m Km hrw" DAll D I V - ' •' • U1.J I. : "I U M I l:'>i>. • L.l-1 I - ' . J '- J_i 1..U U IN iic.n. A': TWO. k • . « , •) awnrwi a laJ ttaattttiMi u « Na liiiiaaiiaiN tattr i t a t H O I ri^^*". ••'4-' 4 - ' BAT) RiaiVIO , DOCUMENT NO -*4 1 A, L r S c n i v i r f U N M k N T A L Q U A L I T Y B O A R D HAZARDOUS WASTE MANIFEST DOCUMENT NO P.R. Chemical Conroanv. Incorooratftf PMME (809) 778-iiQO f^•.^« T'^n Tmfata Ra»>iT»hgm^ Kt. Crnj., r\.K V i r g i n TaTawM. INSPORTIR NO ) Trailer Karine Tranoport Corporation PNONE (809) 721-1^13 t m ADDRESS lala Grande, Puerto Rico TWIISPORTIR HC 2 Transporte Diaz IMOH (809) 792-7999 STE AOORtSS Zona Portuaria, Puerto Huevo, San Juan, Puerto Rico I W A T M f r STORAGE OR BgpQSAt (TSOifAaiiTT I n l a n d Chemical of P . & . , I n c . PHONE (809) 8M-1090 VTE AOORISS KB. S I , Highway #2, Hanati, Puerto l i c o {PA .IQCI. B NC |v.I.r>.9.6,0.6.5,1.0.9.51 |P|RiDi9 .8,0,6,4,4,5.7 .9 I k i R l D l 9 i e i 0 i S i 2 i 6 i B i 3 i 4 k | R H ) I 0 | 9 | 0 | 3 | 9 | 9 | 7 i1 i8 » MOW THAN TWO TMNSPORHRS ARE TD t< UTUZEO. F U OUT TM FOUOWWC AS APPROPlATI 1 1 THIS FORM IS m OF A TOTAl OF TW F K T ttAWFlST DOCUMFNT HO B PR. l ^ . ' ^ . P .^ • • • 1 mOPCR u s DOT tMPPWCNAMl TOLTJENZ RQ US OOT HAZARD OASS Flam. Liquid UN NUMKR 1294 FORM an auAKmr JLZJLSL : a i . u « ' ' l i l t M i l M M ' I ' I UMTS CONTAiWRS •0 X J L I I J_L J_L TTPl kJ LJ LJ Ld Ld TBT (PA HA: u U U U u u (OB/IPA • A S n T Y P l 10 to 15 I I I J_l_L I I I J_l_L JL_L. SPEUAl HANOIHUG N5TRU:TI0NS INCIUOWC COKTAUIER EXEMPTION ILI OfNTIFCATION OF AOOITUMAl WASTIS MCUSEO M SWPMtMT 01 A NONHAMROOUS NATURE WHICH 00 NOT HAVt TO H NUNIFlSTlDl SINE RATOR S CtRTIFICATIorj Tka a M ctni«r ifet ikc ator aaatt ntiaiib « i puprli dauilwA tttoAtfl. aianid tnt lattttt m t r t f i • Ha •plitaWi n«ulti0ra t l tia Ot^nawai t l Tiaatannan US (PA m t mt CtuwanatiWi t l P.R Tia a m i <t>cntt« tbsM a m TitanntM Suit«t aOoptitlFaaliiTunantaillaitapiHa tlaanxM t l l i t r B t a a a i i u . a i t k i > t n M t t n M t t Aon I ttttHr tta tt* ttiaaHtttt lUan l a tanttanttan accating It ttt Tiaottna ataitt Tkt a n a ait o n t n n ttt tan tl nr - ' - y ~ z . ' Z ~ ' ^ % yfcANsi KIIFRATORS KHATURl TITU President NSPORTtR NO t SIGNATURE I t ttt t t t i 4 * ^ tat«lit|i ttt ctanmi t l ttt tt»«am I k m t m t t t ^ B i " t t t p y anltnm atk ttt tnoaian tn tta aaalitt" f It It l?IQl I HI •>! ^T«tr "nn" " r r ' TRANSPORTIR NO I j " ; ^ " scxu I ?! H II ni V II 91 (IKCTEO ARMVAi OATl U L i LdJl LftUI •"-mr *wr r'Tff*' OATl RtCEIVlO 1/ 1/ I l ^ r - l l ? l J l MO DAY FP TtAR AT THIS Pf RFORATIOM PART B GFN tPA BN lYiiini9ifiinifii'inin'9'^ TRAHSPORTtP NO \ BGNATURE'TaniHtkalkanar a i a i t na caMinii *• ikn tkiaaaw •aiakf TAANSPOtTia NO 2 IIGWAIuM I t Ha t n i t l ai, B M M t « i Iki a a^tM««it I ka.f aucpiatf la Uin»ten caalaran ««k Ha t t u i a * ^ * aa (I Mtmt 01 ih« l a u n H n t ' TRANSPORTIR NO 2 '*"'"' 1 I I I I I t I P ND ' ' ' ' I ' I ' THMtfORTTANO 2SICHATUNI 1 n n A , tta I kaM aa a i n o fkc canirnt, oi ih.i sfupnani taattitt aak a ataaiaihr TREATMENT STORAGE OR OlSPOSAt FACKITT WOlUnON 0'ANT OirF{«NC('S BFTWIEN MANIFEST ANO SHIPMENT OR IISTNC OF RtASONS FOR ANO DISPOSITION or REJICTIO MATiRUUS TAAIMEkl STORAGE OP OiSPOKSAi lACIinr SIGNATURE "Utoa muti aatician t canitv thai tta cDmtnis et This skaaitai conlaa* atfh ttm ttsoaian en ihu aianiltsi ttctei ike»g t t i t t a i t i e i netetf en itin loni.' tl U i , al enwi|tnct a <»ij aaautttitl, call t t t Eaaraaaanal QatWy lead ||09i J2m8j OATl OCllVfRlO ^ M WrJ M-^ DATE RECEIVEC ^-ATA hth-' S H I I I I I ' I I I MANOlWC METHOD OAn RECIIVEO H ^ ^ H ^ OOCUMENt NO P R ! 1 0 / 100060 0/8»» KA^%;.i^^ - . . . - w w w « t t > - » w » » w » r ^ r« • r ^ o I A R T A : DOCUMENT % 0 ' ^ C O f > « HIERATOA HANI Ia1att4 Otattical PMOHE Sm ADDRESS Cacata t$4 K f t o t a t e t \ l « ^ « i . 9 t . C m U W.t. V i r f l " XaUtt^a TWUCPOFITIR HO I T r a t l t ««cTtaa Tratta^art « n AOORCSS X»t* CT«»Ja. Pttarta %iaa ASll PHONE TRAHSPDRnR HO 2 TraaayttTt* Plaa PHOIf B H AOORE&S Ztttt* f T t - x r i a . Pttirrti Jfaetta. •as 3ttas. tie* reuTMENI. STORAGE OR oiSPOSAi cTSOi FACiim X » 1 a a 4 C % a » i c a l • £ P . I . , I A C . T^^ n ^ w f i S m ADDRESS Xtt. 5 1 . r t l c W a ; # 3 . 7 a a « t { . Ptaert* » i « 9 IPA B no k . i •»•<.» ,e ,t.s.iit.<i*- j^f*''"'*'".^.* •*•*.v^*' ^,^,»,f ,8,0,>,?,*,?,ii*l | » . ^ » « . < i O . ! i < i < . 7 . 1 , ' - l V MORE THAN TWO niANSPORTfRS ARE TC K UTUZEO. F U OUT TW FOUOWMC AS APfROPUn THS FORM IS HO OF A l O T R i a F I M l n S T MAMFIST OOOMEKT HO B P R ' • * . * » ^ • • nOPERUSOOT aapptnGHAME TfrlwT'.c T3 UOOT MAZARDOASS r i i Ue«l^ t3*A an OUAHTmr I l>l'l'l> J_L -L_L _L_L _L_L ^5-Li_llJ ' I ' UMTS C8HTAR«R$ L Uii TTPl hi LJ LJ LJ LJ TBT (PA HA7 JUSL Ll U u u u u Ifli/IF> WASTITT?! J_L-L I L (KClAl HANOUNG MSTRUCTUNS INaUDWC COHIAMER UEMPIXM tit DEHTIFCATION OF AOOITUMAl WASTIS NCUBEO M SMPMEKT OF A NONHAZARDOUS NATURE MMCH 00 aiTT I U « TD • MANrttmil catdaan lor taatataan aualmt noon a m aati(n*4 tt ttt Tttntena aaittd Tkt tta ttt latfBHi io NM ait o n t o a ttt htn tl ^r amitt amtnitx a t preptr Omtt»t tttcntid. • a t t t ait ltt««i< I ' i n r t o w i f i i i i i i i n H i i i . US EPA aK ttt CaaaanatHth t l P.R TW a t n t «itcriAt< • t Attf • * t f t « r « • MttMH t l hBa*u> aittt. l i t ktt t t M f t n t t M * • I o n t t ^ ^ ^ M W Tnu Y n s U M t iURK ^ " ^ 9 ^ : ^ TRANSPORHR HO 1 «Hiaf . _ _ . iVi»i°i>i^'i UPEITUIARItMiDAn , i V i QIJ llLl OATl RECEIVED LLJ U - l L-L MD OAT FR yy TEAR AT TMS PERFORATION z?//s^ TaAm^omr. NO ^ TMNjpomri a t " »r«-v t K H A T V K T ^ I H # | ^ ^ M a K 4 A v a i e a a t t a u m / . , . - j / ' 1 I 2 JIJNATURE Tt ttt kt«i t l ai, kaaaaatgf Na Bauau at tM "TRANSPORTIR NO 2 aa*ittlatra>ita<canMn«iaa»H»tna«iv<aaHiaaaiirtni' ' ^ " ^ Z t i l l «. ^, .. hV,^«,V,»,'r.^ ' ' ' « ' I ' • RHD 2*ICNATUR[-Ictnit«tt«<lkm IBPRtnii t" Ika ittpaiaM ' ati ttaniiet mt^ m aaauAt THATMEVI nWAGE OR DISPOSAL FAUITT MOICATION OF ANT DtFFERENCES HTWEEN NUMItlST AHO SWPIAENT ORUSTMC 01 REASONS KXAMJOUPOSniONOFKJECTIO MATERUUS TMEJT PDRACE OR DISPONSAI FACAITT SIGNATURE "U»tn nuU aoptcion I t t t ^ tttt tti c m t m tl Itia akatnan onl vtn atti tkt ttttraian tn Ika auialtsi f t p i ttait Aaattaieiti nam en Ww latin ° ^ g > " ^ jg OATl RICIIVID tun SJAT-* \ r ' i H hlf!- '-TT tt t a t l l aaaftnt, a i^.l aaiatiam, tir'. ikt Eamnaionta Qutia, teat |U9) T2Vni2 < ^ ^ ^ . V r / :2 HANOUNG METHOD DATE RICEIVEO zz^ CA<i ,r. M^ ^ DOCUMENT NO- •/ P R 4 0 / « 0 ^^•^^% .T^ M \ U.'^~-' , ^ : 100061 PHOTCXSRAPHS Berlex Laboratories St. Croix. VI September 9, 1985 100062 PHOTOGRAPHS photo #1 - Aboveground raw material storage tanks. Berlex, VI Photo 12 - Outside material storage area. Berlex, VI 100063 PHOTOGRAPHS Photo #3 - Outside material storage area. Berlex, VI photo #4 - Location of toluene drying oven. Berlex, VI 100064 PHOTOGRAPHS Photo #5 - Entrance to toluene drying oven. Berlex, VI pyridine contaminated Area. Synthetic liner used Photo #6 - Py^^J^Sent saturation of soil. Berlex, VI 100065 PHOTOGRAPHS Photo f7 ( #8 - Pyridine contaminated area. Lab waste drainage area, surface sampling using trowels. Berlex, VI 100066 PHOTOGRAPHS Photo #9 - Pyridine contaminated area. Lab waste drainage area, surface stunpling using trowels. Berlex, VI Photo #10 - Pyridine contaminated area. Lab waste drainage area, subsurface sampling using bucket augers. Berlex, VI 100067 PHOTOGRAPHS Photo 111 - Pyridine contaminated area. Lab waste drainage area, subsurface sampling using bucket augers. Berlex, VI ,.«c , U - «-,.Uon aru^s^cf toluene cont..in.». .oU in 100068 PHOTOGRAPHS photo 413 - Close-up view of toluene contaminated soil stored in warehouse. Berlex, VI Photo #14 - 55-gallon drums of raw materials stored in warehouse. Berlex, VI 100069 Attachment 2; Hazardous waste manifests Berlex Laboratories (ICC) VID980651095 March 13, 1986 100070 (As Required By The Alabama Department ot Environmental Management) F-l«aM prim or type (form atsifisoa iar use en uMt fT2-piteh) ijpewriier.l form Apprpitea QMB No 3000-0*04 [.pires 7-31-86 I * UNIFORM HAZARDOUS WASTE MANIFEST TJenera'ior A Name «n<j T3!STIin[~ft3oreis jeneraior A Name and Mtilinc Aooress S s t r S ^ ^ Ct»^£^'C6tr i o ^ ^ 4 A / 4. Gan«r»ior» Ftwr^e ( ^ O / ) ^ ^ t f - t f > S P g a. Iransponer i bompany Name 1. Ganaraior A US EPAIO No. Ailaniteti T r a i l e r Nusiber TMTZ 680365 TXf)4/j i^e/er-^ ar<c/g-. /. iranaponar il Company Name US EPA 10 Number e. us EPA ID Numtwr 2 Page 1 of a£^ Inlormatton ir the thaoec areas i t not r a q u i r a d by F a d t r a i law A.Stau Manifact Oocumani Numttar CWMA 24.^0.'^? •.StAtt Ottnaratora l o ~ : r- l - r ' . CStaM Tranflpertafs i o * 0. Tranaponar'a f h e n T E. Stata TmnNponw'A 10 f.'Tranaponar'a Ptiona' & Stata FtteUoy:* 10 5^E5aZM[ 8. DatisnaiaO Pacility Nama and Site Addiess C H E M I C A L WASTE M A N A G E M E N T . INC. Emelle Facility Alabama H i ^ M a y 17 at Mila Markar 1S3 Emelle. Alatiama 35459 107 US EPA ID NumtMr : - . • •. - • - ; . i . r ' - . . : ' - . zz^ .-. * ' RFaeiliiy's nnoa , A | L , C ^ 0 | 0 | 0 | 6 , 2 , 2 [ 4 | 6 , 4 ^205/652-972T-Si^^fe^>•' ^ • T ^ 11. US DOT Dtaetiplientlneb/ding ^rtfitr Shipping Namm. Natard O n * . »nd ID Mumb»r) //ff^/0ji4»uf i*^^7Z Xr^Ao ^^S(r0Uf0fc f ^ s : * * ^ * ^ 1XC«nuinara No. Type 13. Teul Quantity 14. \inn Wi/Vo ^•..•WBB•»te.^. T«rr 9/e/ff^c / f / ^ ? / ^ CWM Profila Number y ^ ^ ^ ^ f f f S o 2 , ffK/lf&^ ^ / ^ ^ ^ y - CWM Profile U u m b t r / C C / ^ 4 f f 4 C S UL m •-AZ*^*'Zh'^^''^- ••'r-.y' - *z-i<i-»t.x:":i ^'^;'Z;^.Zif:: mm I ,yyA.yzj^y.Z:- \ . ...•n,;s--«..«--5**-, /^ByQKf^aar cosj/^ Jc^.a ^^nf Cy^e»c */ue»fJJ C^Af'C A ^ ^/'t^ CVWI Pfofile Number / Q U P ^ ^ f f 4 > 4 - LdM: m CWM Profile Number I B'-Adflltianal Paacriptiofn. tor M f r i a t i Uaiad A b c ^ L '*•• y-;ir.y^-'-_^--Z "/Z-AA^A'tZeZ''- iT ••Z'^--7;.yy!'//r 16. Spacial HarvJimg Inalructions artd AOOiiional IrHormanon . ' . K. Handling Ceda* iai Waatm UHad Abcva ZA'Zr-. :>3i >.Dei '• - ' f • cDB/z,Z^// I ' ' ^ • * ' . •' Ifi. Sp«ci«l MndiioQ Instructions Bt>C Addiiionai Inormation , :»w< Tf^^C ^ Ca/yff/9 i e . OENERATok'S CERTIFICATION: I Ftaraby declare that the comamt d this eonaignmant are Fully and accurately dascribad abova t>y prepar ahipping nama and are classified, packed, marked, and labeled, and ara in all respects in proper condition for transport by FiigFnvsy according lo applicable imantational and national government ragulations. Unlasa I am a amalt quantity Qonarator wtio has boon axempted by statute or ragulatien from ttte duty to tnake a waste minimisation eartificstion Widar Section 3002(b) of RCflA. I also certify tttat I Itave a program in place to reduce ttta veluine and toiieity ef waste generated to tha degree I have determined to be economicallv practicable and I have aaiectad tha mattied of treatment, storage, er disposal currently available to me which minimiies the present and future ttweat to human ><ealth and the environment Printed/Typed Nerne Sigrtatur ^ ' ^ ^ ^ c f ^ ; ^ ^ Month 0»t toar 17.Treftaoortar 1 AekrMwIedgement of Receipt of Materials Sigrtsiure t / ~ Printed/Typed Name Z Oneale^s Transport Inc Norton C. M. Burt Month 0$r y»»' hinlilTlfil'i 1 B.Trertsponer 2 Aeknowtedgemein ef Receipt of Materials Pripiqd^vped Name " / / /y7(^y<^/l/tL<7./z Signatur'a' / / / ^ . . Month Om taBr £ ^ IB.Diacrapency Indication Space ^ ' ^ 20.Faciliy Owner or Operetor: CenHtcation ol receipt of FMterdous matenalt I except et noted in item 19. Prinyd/Tvped N a m e ^ Month Dor >'••' i/i^^^^iri3 ^ * - * ' * f^*" aTOO-M (Rev. 44S) Previoue adhMm is obaoietr « ; T A T P OP A ' I A R A I U ^ A / K A , n ^ ^ A r r n m n n r r ^ S h i n m e n t ) I - T T T T T 1 0 0 0 7 1 tPorm tjtitgnetS for m f o " e'i'r M2pitch) typtwriier I UNIFORM HAZARDOUS WASTE MANIFEST (Continuation Sheet) __ 21.Generator t US EPA ID No .vts%.utttvti n o t^ / ^ ^ / 4 f ^ s-y c 9 . y \ x C OQJ ManTTesT Oocumeni No f6t*n Appro%a OMB No 7000 0404 E.p.tet 7 31 86 J.Generator's Name Ist-P^ tZ^f^'Cffc c**m>v^ Trailer Number TKTZ 680365 24.Trenaooner ^ Q t o m p t n i i Hnma 26."f>anapawai '\ Cewtpany Metnn 22.Tagc Infoimaiion in the sriadeS areas It n o l r e q u i r e d by Federal law L. State Manifest O o c u m ^ Number CWMA - i f ^ ^ s ^ M.Steto C«Fi«rator'( ID N.SMia Trenaponer't l o 0. TrattsponeF't Pftoni ~7h. US EPA ID dumber Rwrn RANncR. 2 T US EPA 10 Number p. State Trensponer's ID 28. US OOT Description Oncluding P t o p v Shipping N a m * . Hptpra Class, a n d ID Number}. 29. Containers No Type O T r a n a p o n a r s ' ' ^ o ^ ^ ' l S - . ^ ^ q - f i 7 Z j q inert | 3 0 . I 31 Total Quentitv Unit IWIAWI R. Waste No. CWM Profile Number , M CWM FlUlllt \ W T \ \ \ K \ / f u f i ' \ //pe9APa*^ ^ 6 J / t ^ tficifiyUar(y*t€^a^. Zi«d*t>e4) CWM Profile Number /£H ' • " • ' ' • • ' ' y -. . ' - •••: - i . ' - J . r > - . ' y - ' • Z ' - y y z . ' ^ - ' CWM Profile Number ¥". H . I . I -^/ZyyAE ' CWM Profile Number ./z:yEAi:^ CWM Profile Number CWM Profile Numtier CWM Profile Number •8. Additiertal O ^ e r i p t i o n ^ o r Materielt fistedJ^beve IEJ?, aterielt Listed Above ' ^ T. Handling Codes for Wattst Lilted AbOM a. d . g. a^^**U</^t^Ui^^Si^^^'C^k/Af. 33. Trartaponer Acknowledgement of Receipt ef Materials Date Signature ~ ~ / Month Day Yaar ^CyUry. a. 7M. A ^ t / l . - I .1 t r i p . y \ i \ ^ I ^ • ' * ^ ' T g ^ ' n . ^ ^ r j u i . p u i L l U L — ftiorcon- ^ Burt 34Treftspon"ar 'ZAdtnowladQemant or Wacaiot of Materials Priptad/Typod Nama j ^ ~ \ / - . Sfieniture I DiacrapaFKy ittdication space / t l TimZK' ,EPA Form 8700-22A ( 3 ^ ) STATE OF ALABAMA (Must Accomoonv Shioment) 100072 ' (As Required By The Alabama Department of Environmental Management) L-tse prim or type. (fortr!tiosiffntd for vte :n ^lita n2-pi:ehj typewriier) fo"" Appievoil OMB No 2OO0-04O4 [spires 7-31-86 UNIFORM HAZARDOUS WASTE MANIFEST 1. Ceneraior t US EPA 10 No Manilesi lino m^cPAAC ^MC^KSt, C»*n^o4/y 9 o o ^A^^efy^tLO /^t3Sy> ^<«f<i(«^ ^ e c J sX'i/ejey «i^F¥*' o y ^ ^ o 4. Generetors Phone ( J l C / ) ^ V ^ f - - ^ y C & t^i / /> 19^Bo ,6 li-i / |g if f^Lg^?^i^'"^N> T r a i l e r Number RTMZ;274676 ireruponer 1 Compan) Name rKame £. us EPA ID Number 2 Page 1 of X . A.Sute ManTtesi Oocumeni Numtw Inlormaiion in ihe thaoeO t f t t s l l noi required !>» Fedeiai law. CWMA 243033 B. State Ceneraior'a 10 C. State Traiiaponar's 10 0. Transporter's Phone £. State Trtnsporter's 10 Traruponer 2 Company ~(tame B. US Ef A10 Number L I L —ll.... H I e . . . JLJJ ' . A ' ' ' ..e- r o . .rl ^.. —..L. ' F. Trsnaporter's Phone" uosigrtatea t-acilny Name acv] Sue Address' CHEMICAL WASTE M A N A G E M E N T . INC. Emelle Facility AlatMrrta M i d w a y 17 at Mile Marker 163 Enrtelle. Alabama 35^59 i T US EPA ID Number G.SUU Faeiliiv's 10 , A | L| 1^ 0 | 0 | 0 , 6 | 2 | 2 i 4 | 6 | 4 KFeelity's Phone 205/652-9721 11. \)&OOXX)aaaipUonlliteludingPrapmrShippirtg Nama. MatardClatt. and IDHumbarl ^ / e ^ ^ - ^ A / ^ 9 / f 9 CWM Profile N u m b e r / i f c y ^ ^ V ^ ^ a J 12. ComaifMrt No Type 13 Teul Ouaniiiy 14. Unrt WlA^o I. Waste No. L£.6l£l F" //^cz/i/t^ous *o9Jrt >rt^/^ yt/^(r0Wi^^ €OV6o/ec^a£/*tj CWM Profile Number / ^ C ^ l > ^ f £ , 0 4 ' ^/C/c'-tf- yi//i9/<f9 ill^^M I I I I ffAj«f^r A//} '?/ff CWM Profile Number / f O ^ / > ^ ^ 0 2 ^ :££. ^m: CWM Profile Number OaecrVtiona for Materials Listad Above • //4u. /€Si Ma» /.c'A Tbi^u^^^m^^aCXro AddiiMnel / / ^ . M i * f9(a^ A o y . Tiutmc i M ^ C^t^meoAytt //Ca / c u / ^ / ^ y ( TiiMmt. O4t^S»0M4^ i _ l fv^ K. Hendling Cedes for Wastes Listed Above toPSJ • • d. 16. Special Handlirtg Insituctions artd Addiliorul Irtormstion naraiirtg insituctions arto Aooiiiorui Irtormstion 16. GENERATOR'S CERTIFICATION; I Ftereby declare that the conientt of this contignmem ere fully and accuraiely described sbove tiy proper shipping iMme and are classified, packed, marked, artd labeled, and are in all respects in proper eortdition for transport by highway according to applicable imarnatioftal artd natiortat govarnmem regulations. Uftiess I em a small quamity gerterator who ttat been exempted by statute or regulation from ttte duty to utake a waste minimization eartificstion under Section 3002(b) of RCRA. I else certify ttiai I have a program in place to reduce ttte volume and loiicity ef waste generated to the degree I have determirted to be economically practicable artd I have selected the ntethod ef treatment, storage, or ditpoial currently evsilable to me which minimites ttte presem end future threat to human ttaalth artd the environmeni Printed/Typed Name I ^ ^ L i ^ / ^ Month Doy Voor 17.Trartsponer 1 Acknowledgement of Receipt of Maierialt . i^t A- Primad/Ttped Name O'Neale's Transport Inc Norton C~M. Burt Sig nature 1i^ier\ £.. m Month Dty Vaor n'Qm7i8i5 IS.Transponer 2 Ackrtowledgement of Receipt of Materials SignaiuJE"^ "^ / / ', Mofiih~Dir >'••' Prinjs^/ayped Name . > IBOiacrapancy Indication Space F A C r lO.Facility Owner or Opareior: Certification of receipt of ttaxardous maierials coveted I>Y this maMleti ^ ^ ^ /^xr*A:^ Signature Month Dtr y»»' i / i ' ^ F ^ 3 i r i S " tPAForm•700-22JRe*.4.i6)Previousedrtionisobsotete S T A T E O F A L A B A M A ( M u S t bny Shipment) / / / / / ,///) 1 0 0 0 7 3 2'i";Go leraior t US EPA ID Nc ni er m>e (Form dengned i n ' ..-tr on elut (1?G;tch) typewriter I UNIFORM HAZARDOUS "'"" ' WASTE MANIFEST (Continuation Sheet) Maniiesi Document No 6 c TsejSAM ^/v/vir^jff*, C*^*fyS4^ Trailer Number 3d>e> ^^/£/:v(cO JStiOJ) o^oTo RTMZ; 274676 24.Trertsponer,5»Compeny Name ^ / » 4 ^ y j L A / ^ r - j m H i / e p g " 26. Trertaponet-i^ Company N a m e " T# 257 US EPA (0 Number f ^ C . f i 9 e O e « 9 9 7 7 ^.Tranaponer's ^horte -U s ^ T T . U S EPA 10 Number 28. US OOT Description (Inclvding ^ n p a r Shipping Nama. Hazard Class, a n d ID Numbert , je£j^'/^ ,^/,^^//f eriMF.uii.nu iuii,<t;f(rii/?yr7^ / . H A » ^ ^ y y - g ' ^ A ^ / P 9 <.WM PIbl.l* Number A f ^ / 9 J > 9 / g & ^ - J L ^ ] J > / ^ wua^^ f^U^iA/^.^ - ^ / e ^ - ^ r**^^ ^ i / y UWM Profile Number z ^ ^ ^ & ' ^ ^ X ^ " %otrr. App'0»ea OMB No ^000 0404 tip.'et 7 31 86 niormaiion in the shaaed areas ?2T age It n o l required by Federal law L. Stata Manifest Document Numbe CWMA Z'^SQS3 M.Swte eartarator's I S N. Slats Transponer's ID P. State Transportor'a ID O T r a n a p o n a r s Pt)ona 29. Containers ^/!^ — 5 a — Total Quantity Unit 'jj.S-Ij39-62^!9 R. Waste No. CWM Profile Number aot/jj:^ 'S •:»/'^'> :•^SIJ^v c w M Profile Number CWM Profile Number CWM Profile Number CWM Profile Number CWM Profile Number S. Additiortai Dateriptions for Materials Listed Above TTzasun^^rz/*^^ ^ $ ^ ^ M t < ^ 32. SuaCIarilaiiUliiiu Instructipns end Additional Information T. Handling Codes for Wattes Listed Above a. d . g. b. e. h. c. f. i. 33. Trartaponer Acknowladgemani of Receipt of Materials I^MJ:^ t.TQ. J M J ' A : Date ^|SiSd2elJa!35is4«iriLjj)c >iViMr,.., r M t ^ . t r r ^ Month Day Year v ni 1 7IR S y t v 0 t C Name i l l BiacrapatKy Indication Space tsponer.? Acknowledgement or Receipt of Meterials ^^_^ - . ^ . ^ I Dsie ^ 5 7 f v S 6 ~ N a m e ~ ^ I ' / / TsignSturS % " " / " ! 7 / — ilMonr/i Z>«r Year ^Jry^Zr,ncAA- I U>,..,.//f./rr.yir 1/M.^l^ - r ^ n T t n I &ahj4u»Ma^dKak C K & A . ^ ' 100074 i P A F o r m 8 7 0 0 - 2 2 A (3-84) ^ T A T F O F A l A R A M A ^ M n e t A r r - n m n n m r Ck!m.*.».«»> • ^ Hlease "prim or type (ftfm designed tor ute on elite I1}-pitch) typetniier.) bNil^6tlM HAZARDOUS (As Required By The Alabama Department of Environmental Management) forii. Approited OMB No 2OO0-O404 [spires 7-31-BC WASTE MANIFEST Mailing AdOri 1. Certeraior t US EPA 10 No Manileti Kl / ug> I f i g I <>i^ 1^1/1 g i ^ i n j?^yr<» I t 2. Page 1 of X Inlormaiion in Ihe triaoea areas is not required by Feaeral law 'i deneraior t Name ert7 Mailing ~ . . . . A t M t e Oocumem Number I Generator's Phone { Z « / ) ( a 9 ^ ' - < ^ 0 0 Trailer Number RTMZ 251880 L^^wais aaansaei uocumam mumoer ^-CWMA •••--243031 |.>. l i e Oaiwissui 'a P Iransponer 1 company Name _ T^i84ifAo^r-^2We^ 6. US EPA ID Number \f\/t \&\9\&-,t>\cyf \^\r\7 \9 f% 10 0. Tianaporterls Atone /. Irartsponer 2 Company Nante 8. US EPAIO Number \P\^\b 19i^|0|* \*\9\S'\7 ^ E S a t e Tl s e F. Trenapener's ntone" «. uetignaied Facility Name a i ^ &ite Addrass~ CHEMICAL WASTE MANAGEMENT. INC. Emelle Fscility Alabama Hif^way 17 at Mile Marker 163 Emelle. Alabama 35459 lOT US EPA 10 HuiJitiet G.S«aw Fecanys O , A | L | D| 0 t 0 | 0 | 6 | 2 | 2 | 4 | 6 , 4 11. USDOT0aeenplionA'K*4abvP»'aparS/i^w<nVMama. MararidCtesi.wid0Mm6er; ^/6<»js-^ yf/>i^9yf9 C1NM Profile Number y^C/).Z> ^ B 6 C 2 . . RFaciUtys niene 205/652-9721 12. Conuiners No iMi Type J ^ 13. Teul Ouamity 14. Unit WlA^o I «V«siaNo. <7yey9ftr€' y y ^ 9 4 ^ C W M Profile Number X t f T ^ ^ 9 6 ^ 3 S$d/}f 0 ^ ^ " ^ A4A y / / f CWM Profile N u m b e r / f e ^ ^ 4 ^ £ C 4 ^ LM. d CWM Profile Number Additional Oeeer<»oorts tor MaterialsListad Above T . //49, ^*«f/**r^ /'^V( / • t ^ ^ c *9^* »»\fmc / / ^ . yf/>^'MaM9t4VC/ su>-A»M*9M£^fOi^AtaA^y ^i4r/cy9ciMrt^ / / C . Z s s r l^6«C^ ^ ' * ' ^ 7Scct0»*€m ^ 9 * 0 J&*% m t . C A J b j U / ^ t m / T. K. Hendling Codes for Wastes Listed Above lb. Special Hartdlirtg instructions artd Additional Irformation .c^i 10. bpociai nartoiirtg instructions arte Aoqiiionai irtormation ^ ^ __^ _r v .*.. ^ . - _ . 16. OENERATOR'S CERTIFICATION: I tterstiy declare tttat the contents of thit consignment ere fully and accurately deteribed above by preper ahipping name ertd era ciassHied. pecked, marked, and labeled, and are in all respeeu in proper condition for transport by itighway accordiitg to applicabia intematiortel end itational govemment regulatiorts. Unless I am a small ouamity genereter who has been exempted by statute er regulation from ttte duty to ntake a waste mtnimization certification under Section 3002(b) of RCRA. I else certify tttat I have e program in place to reduce the volume end toxicity ef «»aste ganersted to the degree I tteve determirted to be economicslly prscticable and I heve eelected the method ef treatment, storage, er disposal currently eveilable to me which wiirnimaes the presem ertd future threat te human ttaalth artd the environment PTinted/Tyoed Name /[amy-AZY/^- ^M^^y^ Month Dey Year 17.TrBitsporter 1 Acknowtedgemem of Receipt ol Materials Sigitature . . I me ransport Inc Month Day Year ninni7 ft ri IS.Transportsr 2 Ackrtowledgement of Receipt of Materials t«l/Tvped Name y y rxjn/^ /^?^/^/./ Sigri^urs Month Dty Year ^ 19.0iscrepancv Indication Space .uJMSP-Facility Owrter or Operator: Cenilicstion of receipt of Itazardout materials cover fi ceot as (toted in hem 19. Typed Nerne (a>y7/!^-ti Sigitature (Mu^Accompany Shipr Month Day Year . EPA Fetm STOO-ZX (Rav. 4.«S) Previous edition is obsolate. S T A T E O F A L A B A M A Shipment) Ji^l(,Zl'jO 100075 ...•*! f.\ i prini ertypa '21.Gerterator $ USEPA ID \ ' UNIFORM HAZAHWJUS "^ WASTE MANlF£«y. (Continuatini;^neeT) 23.Generator's Name Manifest d Document No. e^y^yo z^ 'bt. Transooner Company Name "?fe Transpoftarji T o w y h y Name R Y P F P P ^ M ^ - g P Trailer Kunber RTMZ 251880 ^ 0 / / £ 9 d C r ^ / t O US tif*^ l b k u m b e i 25. USTPA fO Number \rc^^0oSOS 90 7 27. 1 ^sss. u s EPA 10 Number form AoproveO OMB No POOfe 040^ tip.ret 7 3 22 .'Page Zff/Zr Inlormaiion m the snadea areas IS not required by Federal law. 1 Be L. State Menifest bocument Numtser CWMA J/43<^3/ M . S u t a Canarator's ID N. State Tranaponar's ID O.Tranaponar's Pftone '. Stata Transponer's ID a.Trartaponar's Ptiorte ,^3P.-^^9S2/J9 •31 Unit m/VtaH 26. US DOT Description (Including Proper Shipping Name. Hazard Class, artd ID Numberi - Profile Number / K ^ S f 9 / 1 ^ 0 Z ± - ^ H ^ ~y^z9/e^cea a^»f/t. A^^tyyo >»^^^7w^«'e6<^^fl^««»/rw^ CWM Profile Number / f c / l ^ 9 t C e 3 yi^atj/ttZr^<yayZl o64a^ A4a/^c^^t^ fd^u/atf^ttm/ ^ ^ ^ a '7uA)Mi'_^.Ji i r N u m b e r / f e / ^ ^ ^ O f L r CWM Profile Number CWM Profile Number CWM Profile Number 29. Containers No. I Type ^ 3 S ^ E l l 3a Total Quantity R. Waste No V -r»'=^..'^'-"i..-i rL'y--^y''--':fr^. CWM Profile Number ZyyiZ*yzt^y-r.i^. ]zzz:^yzy:yt: ZA-'^-Z:^x-^ i..-s,^:sA^y^. CWM Profile Number * r » - ..rimjr.i-^. CWM Profile Number S. Additional Descriptions for Meterials Lined Above j ^ / f , y»af < / • • . z v : TT. S.. . ^ > : V - :z^ 32. StyteHHsndlinoJnstructtons and Additiona ^/Ca\4^ -.^^^"^ T, Handling Codes for Wattet Listed Above . .. • • - ' - •.:-'• • ^ z y " « • • ' ' b. e. It- c. f . i <JP( d d ^ ,JidmZt't^'<c4/^&^, 33. Transponar Ackr>owied0erTtent of Receipt of Materials i Date Printed/Tvpcd Name jVnBalo^u T i a i i L p m i In'c" T i / ^ ^ n n I . M k r . V - f — Siohstura 'Ttfivfai-g^-^n. &Xf.hMA. M o n t h Day Year 1 nh 7lf! ' Transponar " ^ Acfcrtowladgemant or Receipt of Msterials ' ' I Date T^S^AT ^ /loAo^ i4l.3\lW^^Co,. W)-^.^^^^rrZifTZi Oiacrapartcy totdication Space LZ^ZJ'^ - 35 100076 EPA Form 8700-22A (3-«4) « ; T A T F n p A I A R A K A A fMii«t A r m m r v t m / Cki«t»««*1 Attachment 3; Copies of chain of custody and sampling paper%«ork Berlex Laboratories (ICC) VID980651095 March 13, 1966 100077 CHAIN or CUSTODY RECORD ^ cet [^ >r- fc«i«'irr>l •NVtIONMtNTAL PtOTiCDON AOENCY > »OION 1! SUtVEILlANCE A ANAITDS OIVISON tPISON. NEW JEISEY OStlT iTZC'O^toi^S'lo^S' Nea* ef tMH mttd A44i*u: "1 ( • • p i * Nvabar N«Bb«r • I PetcHrtie* ei toBpl*> - T ^ n . I Af> t4^4tsf«:. O "^ O^TYNpOl v P ^ ^ b6S3S-v, «;? H o m l 1 / I A U -/t,.- "PO/) a^pcMffaiS . 2 / « - k r ^ ^ s * r^r^ "^"^ AJV/O/i s e r i a l f s i i / ^ £ t J l ^ ^ CLJKfs'i-CLi'^r- " f o r fr^c4e>i\s ^caynour)a.U^&\^ "jtt 3 "Ther c^AtPoyfCr S^t^^n-plt «*JOs - f » ^ e ^ -^^w>»-» 4 ^ c on-« .4 uzserl Feraen Attwaine I«ip«nj Tia* Pel* SaasI* Nvaker •elieaitltked By: •eceive^ By: Tia* Date Keseeii lar Cheese ef Cettady Saapl* Neak*r lelieevi'lt*' By: tecelved By: Tia* Del* teeteii ler CItans* • ' CeMedy t e a e U N«ah*r ••linqiiitKed By: l*«*i**4 By: Tia* Date lee«e» ler Chaa(e ef Cettedy t e a a l * Nvabar •*ceiv*4 By: Tia* Dal* leaeea ler Cheaf e sf Cvitedy Pof e Ne. 100078 •NtniOMMENfAL PkOnCnON AOtNCY - BfOION II SUIVEILLANCE A ANAITBS OIVtSON iOISON. NEW JEtSEY OSSIT Moa* • ! Itoit am4 Addiau: /^. , • ; • O f ' \< t L r* t^c » r-*c; I 1 r • :_ £1- r>f-^ ,^^ ^'*i:>'tcir.zir^'r Saapl* Nuab*r ' M -il .'* '. - " / •• •_ - -1 •« l . ' . ^ N>ab*r •1 Ceataie*ri - J i 1 . J> Zi 1 1 OetciipttM ef S«apl*> < - : .-V. / ^ / . ^ ' - ( , . 1 c ^) ' • • ' ' ' - , . ' : C i t r r ' . i < ' r ' :' y r . r -fr-r F t *; ^ ' <r- ' / • ' -5 i^y..-' . « r , ' ' ' - ' V . r ' ^ - ' " ^ « * ' • ' " «•• - • • - • ' : ' .' # f l i c . . J " ' r b . H f r / v r /wWt./? « . m . : r , , . . /, J j ^ r'V -,.. i^c-i ^ V - / i ' - i• f f/ r* '^r^ f-f '-•''- ^r. I U-y- < t r L . i ^ f Cf f w n - C >^ ': - r t>-^l .1 Farawi Aaaaaies l*>»*a>iWtity let teapl*: f ^ ' a J <• C f'^^- c_fc— %mwp\% N«aik«r />.l • U > ' Saapl* Neaber ; 1 Saapl* Neaber Seapl* N«ab*r l*lHi4»i«li*d B r ( ^ ( x \ y ^ ..••' ' - = _ ZZE' \}i-z Balieae«>li*4 By: Beliaa«i*k*d By: •*c*i«*d By: •eceived By: « " /•\v<cyjE •eceived By: l*c*ived By: Tia* Tia* Tta* Tia* Del* Dot* AE Del* Dat* Tia* 5o^ Dal* -1. Beaiea let Chaas* ef Ceitedy '-'..r. i . i , - Z- Beeie* let Cbeasa ef Cattady . . / . z , ci.^ o:.^hf< BeaM* let Cbaes* * i Cettady Pesa Na. 100079 FIELD DATA SHEET ENVIRONMENTAL PROTECTION AGENCY • Roglon II, Edison, New Jwsey ENVIRONMENTAL SERVICES DIVISION Collector<s) Affiliation SAMPLING METHOD (Circle) ^ ^ Kemtnerer Dredge Ponar Xtdanudi^ Niskin Net Seine Trawl Bucket Trowel Cream Dipper Autontatic Other : LDMSCODE fr\ DATA BASE CODE. STA. TYPE CODE _ SUBSTRATE TYPE (Circle) Aqueous ^o^esUlDB^^ Sludge OH Biological Soltrent Extract Other ( ) BOD — Seed Supplied D Yes D No Source: Sample Preparation (Circle) X'^'^iftO P"^'^uTe Si)fl|<ir9nntjftffi Plastic Jar Jweter—^'^ T*Oft Vlal-^ Cubitalner Acetate Core Poll Cap Other Preservation A d d Solvent. Chemical- duBLioeA Dry Ice Ambient Other ^ Acid Rinse Solvent Rinse: waa Blhylens Chlarltf Other (Specify): lerMtf^ Sample Source Type (Orcle) Undfill Leachate Drum Test Well Depth: Other Storage Tank Top Middle Bottom Truck Drum Tank Other. Wells Monitoring Production Drinking Private Industrial Effluent Process Stream Holding Pond Drum Waste Pile Municipal Treatrttent Influent Effluent-CI Effluent-Non Cl Sludge Ambient" Like Stream Pond Ocean Estuary Sample Location Description: s4f Cexr^*! L c ^ ^ Rerttarks: , \ \ - - C^yyor-i ^ l < r . s s \ « r - ^ r l - ' C S da^nno.1 i ^ s t ^ )^^,- J, , r i , e ••_ tz. /• f ^ - r v f ^ t - - - ^ '^ erA ' r n ^ r ^ ( . y form: FTB ftPP-1142.3 Samples to: fiact Bio CHJP^ ' other Station No. Vl23*f T ^ l^si d9 c Sample Depth (Ft.)/Fac. Loc. Code ol_o| Lab Number 085251 Type of Sample Grab Composite K ^ Time Space Collection (Ending) Date t'lu ^ > ft'z Ending Time (24 Hr) 1 3 1 8- Beginning Date Yr 1 Mo 1 Day 1 Beginning Time (24 Hr) pH Sample Temp. PC) DO (mg/l) a Cond. (uMHOS/CM) Salinlty(%.) Sample Split fivas D No If Yes With Whom? ' c«rv%tTrccHc. Receipt D Yes D No 100080 FIELD DATA SHEET ENVIRONMENTAL PROTECTION AGENCY • Region II, Edison. New Jersey ENVIRONMENTAL SERVICES DIVISION ^ ^ A Project Name fc^e r i c ^ L ^ i p o ,,xA-T,r . c ^ ^<,if. C r o N Y V J T llector(s) T?^ ' f ' Affiliation L ) ^ fc,Vn AMPLING METHOD (Circle) Kemmerer Dredge Ponar / ^ a n u a p Niskin Net Seine Trawl ^"BCcicet Trowel Cream Dipper Automatic Other : LDMS CODE KYI DATA BASE CODE. STA. TYPE CODE _ SUBSTRATE TYPE (Circle) AqueotK Solvent ' f S e d i m e n O Sludge Extract Other ( Oil Biological ) BOD — Seed Supplied D Yes D No Source: Sample Preparation (Circle) Container Cubitalner Acetate Core Paper i gflon'Cap Foil Cap Other. Ac eservation Acid Solvent Chemical. Dry Ice Ambient Other Cleaniftg Procedure detergent Wash" jfffaterRinse 3 Acid Rinse Solvent Rinse: Acetone ^ethylene C h l o r i 3 ^ Other (bpectty): ' Sample Source Type (Circle) Landfill Leachate Drum Test Well Depth: Other; Storage Tank Top Middle Bottom Truck Drum Tank Other. Wells Monitoring Production Drinking Private Industrial Effluent Process Stream Holding Pond Drum Waste Pile Municipal Treatment Influent Effluent-CI Effluent-Non Cl Sludge Ambient U k e Stream Pond Ocean Estuary Sample Location Description: c m Samples to: Bact Bio Cheft^ Other Station No. v^4^YloUslibM>5F Sample Depth (Ft.)'Fac. Loc. Code 3 \ o \ U b Number 085252 Type of Sample Grab Composite ^ ^ ^ -Time Space Collection (Ending) Date fii Mo 0\ 31 51 Ending Time (24 Hr) /MNS" Beginning Date Yr 1 Mo 1 Day 1 Beginning Time (24 Hr) pH Sample Temp. (^J) (Iciia uJct<Ae P'T S ^ cpe> c^e. ^ » ^ C A - ) ' S o t f r > r c 4 o IO'* Remarks: a.- H o »^f V I A U ^ r [/o7) ^ u n a t u ^ k s I - auar-i Ciiocs^ \yir {k>r fO^O/) ^cxyna>UfJ<, 1 - q u o r i %lcr<ar \£>* -f^*- (-"^^ a^CcM^^sis ^ 1 Er^r^ ^^ /ill 1^1 - f o r l^CZtZ, O A ^ C L Z U ^ ^ I S A o r -for ^rr^cleth Oyi^CiJ^CZ ft f e'^»"^r>«-^' r e t , - ( 1,1 C r ' l t ^G^^r^ ?>(cr> • f r J Fetm: FTB lin>-t142-2 DO (mg/l) s Cond. (uMHOS/CM) Sallnlty(Ve,) Sample Split I K f e s O No If Yes With Whom? f h c ' i j i - h ^ Receipt ^ Yes D No 100081 m ENVIRONMENTAL PROTECTION AGENCY - Region II, Edison. New Jersey ENVIRONMENTAL SERVICES DIVISION Project Name Collector(s). r ' R r _ r i r ^ L.^t\rjOx A 4x>T Ig- S , 5 < C f C » r XJT r e . Affiliation > ^ ^ ^ " P A m AMPLING METHOD (Circle) ' Kemmerer Dredge Porter ^ l a n u g ^ Niskin Net Seine Trawl Bucket Trowel Cream Dipper Automatic Other : LDMS CODE r>r\ DATA BASE CODE. STA. TYPE CODE _ SUBSTRATE TYPE (Circle) Aqueous rSedimeni^ Sludge Solvent Extract Other ( Oil Biological ) BOD — Seed Supplied D Yes D No Source: Sample Preparation (Circle) Container Sample Source Type (Circle) Industrial Effluent Process Stream Holding Pond Drum Waste Pile Municipal Treatment Influent Effluent-CI Effluent-Non Cl Sludge Ambient Uke Stream Pond Ocean Estuary Sample Location Description ^ £ i . t r ^ p \ t r \ c T - ^ ATX>r&x. I D I•^cine 5 p^r Remarks: 2 ' ^c^ I " \ /. v/.ctU w^v- To/s cii.rr\a. < W C ' 5 - - J U G r-i ^/^'--S Y ' ' " F ^ 6 cx*^cJ«^S.i - Juc^*--* cAos.'s, v « * - -for m<r/^^s ^SL^-ioii/sr^ P Fotm: FTB PtFO-tta2-2 Samples to: Bact Bio Chem Other Station No. M3tcf<^ hS^ ^ Sample Depth (Ft.)/Fac. Loc. Code 3U | 0 e3. U b Number 085253 Type of Sample Grab Composite ^ ^ Time Space Collection (Ending) Date Yr Mo Day ? l 6 > b l 3 i \ 3 Ending Time (24 Hr) I ^ P o Beginning Date Yr 1 Mo 1 Day 1 Beginning Time (24 Hr) pH Sample Temp. (^) DO (mg/l) Cond. (uMHOS/CM) Salinlty(V.,) Sample Split 0 ^ a » D No If Yes With Whom? f i , r . (. *- j CryiiraA Receipt CHfSs D No 100082 FIELD DATA SHEET ENVIRONMENTAL PROTECTION AGENCY - Region II, Edison, New Jersey ENVIRONMENTAL SERVICES DIVISION Pt^jat-. M.tn^ ( - r . f \ r t : U ^ b / . r <^-^Or . c •> , S * Collector(s). ^cfc.c y f l . ^ * ^ r t r .Affiliation. r;^t-?^ SAMPLING METHOD (Drcle) Kemmerer Dredge Ponar Niskin Net Seine Trawl Trowel Cream Dipper Automatic Other LDMSCODE m. DATA BASE CODE. STA. TYPE CODE _ SUBSTRATE TYPE (Circle) Aqueous ^ ^ d i m e n t ^ Sludge Oil Biological Solvent Extract Other ( ) BOD — Seed Supplied D Yes D No Source: Sample Preparation (Circle) Container SlasS J%t Plastic Jar Metal <^OA^iap Cut>ltainer Acetate Core Paper Cap feflon CaE -oil Ca'p' Other Preservation Acid Sohwnt Chemical. ^ e t l c e ) Dry Ice Ambient Other Cleaning Procedure itergtrtTWash]] fater hinse^ Acid Rinse Solvent Rinse: Acetone lethylene Chloride., Otherlspecify): Sample Source Type (Circle) Undfill Uachate Drum Test Well Depth: Other: Storage Tank Top Middle Bottom Truck Drum Tank Other. Wells Monitoring Production Drinking Private Industrial Effluent Process Stream Holding Pond Drum Waste Pile Municipal Treatment Influent Effluent-CI Effluent-Non Cl Sludge Ambient Uke Stream Pond Ocean Estuary Sample Location Description: 4o 3 -Pre-t- Remarks: I - ^ o r A Pl^^s^ > r -<^- p e e a^cJ^^':> \ ^ . d i ^ ^ X ^ ^ t n c h i ^^ s>ycL^ •f I ' I I f f ^ • ^ t.^-5f C J l t Vi--»--) t i \ ^ C t f • ( / \ « ^ S^c/vr^p'c:^ ^ r r d . Fenn: FTB KP0-tta2.a Samples to: Bact Bio Chem ^ t h e r Station No. l / a i ^ T 0 t,5l O^ 5 Sample Depth (Pt.)/Fac. Loc. Code 5 U b Number 085254 Type of Sample Grab Composite time Space Collection (Ending) Date Yr Mo 0 z Day l|5 Ending Time (24 Hr) LH3^' Beginning Date Yr 1 Mo 1 Day 1 Beginning Time (24 Hr) pH Sample Temp. rO) I DO (mg/l) Cond. (uMHOS/CM) Sallnity(%,) Sample Split O No If Yes With Whom? R v c i l j - ^ i Receipt Ot'VSs' O No 100083 FIELD DATA SHEET ENVIRONMENTAL PROTECTION AGENCY - Region 11, Edison, New Jersey ENVIRONMENTAL SERVICES DIVISION Ptr^j^M l u , . ^ \ A ^ r [ c t i L < t f c g r r . t 4 2 > r . g - s , - 6 ' * • ^ r Collector(s) — t j L U L C Affiliation U $ ^* vx U ^ g . PA SAMPLING METHOD (Circle) Kemmerer Dredge Ponar ^iManual Niskin Net Seine Trawl Bucket Trowel Cream Dipper Automatic Other LDMSCODE J O L L DATA BASE CODE. STA. TYPE CODE- F SUBSTRATE TYPE (Circle) Aqueous ^ediment^ Sludge Solvent Extract Other ( on Biological ) BOD — Seed Supplied D Yes D No Source: Sample Preparation (Circle) ner Glass Jaj, Plastic Jar Mei ^POA: Cubitalner Acetate Core Paperj riilonj Foil Cap Other Preservation Acid Sohrent Chemical. tW^t~ice> Dry Ice Ambient Other Procedure Acid Rinse Solvent Rinse: Other (Specify): Sample Source Type (Circle) Undfill Leachate Drum Test Well Depth: Other Storage Tank Top Middle Bottom Truck Drum Tank Other. Wells Monitoring Production Drinking Private Industrial Effluent Process Stream Holding Pond Drum Waste Pile Municipal Treatntent Influent Effluent-CI EHIuent-Non Cl Sludge Ambient Uke Stream Pond Ocean Estuary Sample Location Description: L ^ ^ CA->csV^ 'P»T O f l oce 4x> ? Aref- Remarks: i — A x y o ^ - i eAr<l£. t a r - f o r l ^ \ J O A cunnauUiz,*s^ i - C t u a ^ i ^fTr. s-> y**- - f i - ^ " P e c c c ^ a ^ S ' S ; _^t)-"e 'Ctaot t"^ c J o ^ ^ itar •fiz>' ty^chilz. QJVUMZ'J \ / - M r . f e J r ' f ->J. K tt -•"^'- c ^ •-] r t - f - t . t V , ' r - t Ferm: FTB ftP0-tta2.2 Samples to: Bact Bio Chem , other Station No. \/xP<?? O CS f c ^ s Sample Depth (Ft.)/Fac. Loc. Code 3i» G 1 U b Number 085255 Type of Sample Grab Composite t - - ^ Time Space Collection (Ending) Date Yr Mo 0 | 3 Day ' 1 ^ Ending Time (24 Hr) I s ¥ \ o Beginning Date Yr Mo Day Beginning Time (24 Hr) pH Sample Temp. (^) DO(mofl) Cond. (uMHOS/CM) &allnlty(V.,) Sample 8pin er^M o No If Yes With Whom? ^ 0 ' • ' ' "^^l , f c e n t r e f h c Receipt S^Yes O No 100084 •-•r-y.iy^''r?^;-^v FJELD DATA SHEET ENVIRONMENTAL PROTECTION AGENCY - Region II, Edison, New Jersey ifrgVIRONMENTAL SERVICES DIVISION ^ i T . \ r j L y i lootr e ^ h t n ^ i t ' . , * ^ ^ (. # ' Project Name. 'iollector(s) r«,.K «/X \ ' ' • f r . AHiliation. U-^ £.?-4 SAMPLING METHOD (Circle) Kemmerer Dredge Porter Manual Niskin Net Seine Trawl Bucket Trowel Cream Dipper Automatic { ' 6 i i ^ f-s^y I f ^ : LDMS CODE m. DATA BASE CODE. STA TYPE CODE _ SUBSTRATE TYPE (Circle) ^queous^ Sedintent Sludge Oil Biological Solvent Extract Other ( ) BOD — Seed Supplied D Yes • No Source: Sample Preparation (Circle) Container Preservation Solvent—. Chemical. ^ e t j c f t ^ Dry Ice Ambient Other Cleaning Procedure itergent' iter Rins Acid Rinse Solvent Rinse: Acetone pexan"e) (faethyleni lethylene Chloride^ Other Specify): Sample Source Type (Circle) Undfill Leachate Drum Test Well Depth: Other Storage Tank Top Middle Bottom Truck Drum Tank Other. Wells Monitoring Production Drinking Private Industrial Effluent Process Stream Holding Pond Drum Waste Pile Municipal Treatntent Influent Effluent-CI Effluent-Non Cl Sludge Ambient Uke Stream Pond Ocean Estuary Sample Location Description: Or .4c OL? elJ Remarks: fta h Z' m 4:: i r e ci farm: FTB RFO-1143-2 Samples to: Bact Bio Chem Other Station No. V t 1 q ^ 6 C e 5 / 6 f 3 Sample Depth (Ft.)/Fac. Loc. Code 3 0 0 0 U b Number 085256 Type of Sample Grab Composite Time Space Collection (Ending) Date Yr Mo ^13 Day t \ 3 Ending Time (24 Hr) I (s OXS" Beginning Date Yr 1 Mo 1 Day 1 Beginning Time (24 Hr) pH Sample Temp. (*C) DO (mg/l) Cond. (uMHOS/CM) Sallnity(%,) Sample Split O ^ e s O No If Yes With Whom? T ^ « . •• -^ 1, , c <'ry\r\et. <. T' » Receipt ^ ^ e s O No 100085