O'Henry Data

Collection: Federal Reference
Sub-shelf: EPA SEMS (Superfund, Region 2)
Kind: Government Report
Date: 1951
Pages: 20
Text: Native Text

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Original source: https://semspub.epa.gov/src/document/02/64530

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Software Version: 3.2 <16C20> Sample Name Sample Number Operator Instrument AutoSampler Rack/Vial BLANK SPIKE B2879 V3400A/SALLY NONE 0/0 Time Study Channel : A : 3/11/93 10:37 AM A/D mV Range : 1000 Interface Serial # : 0159572256 Data Acquisition Time: 3/11/93 12:50 AM Delay Time End Time Sampling Rate Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount 0.00 70.00 2.0000 min. min. pts/sec n:\v3400s\SC10013.raw n:\v3400s\SC10013.rst N: \V3400S\8000SUE.ins N:\V3400S\HALL.prc N:\V3400S\LINHSC10.smp n:\v3400s\scl0.seq 5 1, mL 0000 Area Reject Dilution Factor 100.00 1.00 ITAS-KNOXVILLE V3400B J+W DB-624 75m*0.53mm m,3.00um df ELECTROLYTIC CONDUCTIVITY DETECTOR: Percent differences, standard concentrations, and Cfs for BrClMe, o-Cl,F-Benzene, and B2ClIsopO are incorrect due to the compounds having a concentration different than the other compounds in the mix. The percent differences for these compounds and Cfs must be done manually. The computer could only calculate percent differences and Cfs from only one standard concentration. Standard check compared to / /92 linearity P««k * 0 2 3 4 5 6 7 9 10 11 12 H 15 16 17 18 19 21 22 23 R«t Tiw C«porant (bin] MM 1.845 7.030 8.334 9.089 11.924 12.488 14.014 17.038 19.098 20.234 21.831 24.175 24.828 25.492 26.619 27.757 28.377 31.111 31.851 32.802 Air DCIOFH* cue VCl •ma CIE« Tcimt 11DCIE CN2C12 T-12DCIE 27561 HOC I £• C-12DCIE CNC13 •rCIM* 111TCIE« ecu 12DCIE* TCIE 12DCIP* IrOCIN* H*i* MO 0 203668 322979 303983 143861 315478 435604 631010 758246 691180 554546 577128 721860 546152 584032 701588 437563 699218 470855 422425 t M. Cal. CONCENTRATION STANDARD CON. R*r«* IPPt] (PPt) .00 .05 .84 .00 .14 .66 .88 .81 .44 .75 .50 .81 .81 .38 .63 .63 .84 .63 .00 .59 W •V * W vt 8V W V8 Vt IV W VE 8V W W W W W W W W 0 35 28 25 23 26 23 25 24 22 20 21 20 108 19 20 18 22 20 18 .00 .70 .59 .76 .94 .00 .36 .42 .30 .66 .12 .55 .40 .51 .74 .72 .42 .12 .34 .81 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 .000 .000 .000 .000 .000 .000 .000 .000 .000 .000 .000 .000 .000 .000 .000 .000 .000 .000 .000 .000 Covenant NOT Air Afitp^M* Cfi5^5 vci •Cjgt QI&') TC"Tr1«i 110CIE CH2C12 T-12DCIE *tWW11DCl£« C-12DCIE CNC13 •rCIN* 111TCIE* ecu 12DCIEB TCIE 12DCIPB IrOCIN* PERCENT RECOVERY 0.000 178.485 142.967 128.810 119.717 130.009 116.806 127.112 121.487 113.286 100.604 V>mW 107.754 "rs*'M\b 102.007 542.571 98.678 103.598 92.119 110.587 101 .675 94.056 TUT OO4 *64530* 64530 24 K 27 28 29 30 31 32 34 35 36 38 39 40 34.091 35.103 37.473 38.283 40.130 41.255 45.744 47.748 53.523 54.992 57.694 62.375 62.986 64.911 •nsw ZClEttiyiVO C-13DCIP* T-13DCIP* 112TCIE* T*tClE 08rClNt ClIZ o-Cl,F-B«nz*n* CHBr3 1122T*tCl6t 123TMClProp*n* 13DCIBZ 140CIH 12DCIIZ KSS =_=— 53583.87 W 682727.63 VE 117900.32 W 384530.47 W 645653.31 W 209084.50 W 181622.75 W 269434.16 W 98843.70 8V 232747.58 W 183874.39 W 349182.22 IV 373659.91 W 341914.19 W 1.36*7 13.28 27.09 7.75 19.06 21.01 16.99 19.52 110.88 16.03 17.80 20.30 20.05 19.34 18.98 874.56 20.000 20.000 20.000 20.000 20.000 20.000 20.000 20.000 20.000 20.000 20.000 20.000 20.000 20.000 680.000 __«»»= 2ClEthylVO C-1SOCIP* T-130ClPe 112TCIE* TttClE DBrCIN* ClBz o-Cl,F-B*nz*ne CHBr3 1122T«tClEi 123TriClProp*n* 130CIBZ 140CIBZ 120CIBZ 66.396 135.457 38.764 95.313 105.070 84.955 97.584 554.391 80.169 89.018 101.510 100.242 96.708 94.881 4.372*3 ITAS-KNOXVILLE V-3400B J+ W DB-624 75m*0.53mm ID, 3.00um df ELECTROLYTIC CONDUCTIVITY DETECTOR-BrClMe AND O-C1FBZ ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. ALL OTHER ANALYTES ARE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLUME OF 5.O ML. PMk * 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 ft*t T«B» RT DIFF. it CoMporwnt Ar**/ [•In] X NMH Awwit 5.758 7.030 8.334 9.089 11.924 12.488 14.014 16.470 17.038 19.098 20.234 21.831 23.342 24.175 24.828 25.492 26.619 27.757 28.377 29.381 31.111 31.851 32.802 34.098 35.103 36.538 37.473 38.283 40.130 41.255 45.744 47.748 50.756 53.523 54.992 57.694 60.188 62.375 62.986 0.0 88 48587.0898 0.2 BV OClOFNt 1 .3236*5 0.1 W CLNE 2.2035*5 0.2 VI VCl 2.4098*5 0.0 BV BrM* 1.1025*5 0.1 W CtEi 2.2986*5 0.1 VB TCIFN* 3.4124*5 0.0 BV 4.6834*5 •0.0 VB 110CIE 3.1433*5 •0.0 BV CH2C12 3.2921*5 -0.0 W T-12DCIE 3.1618*5 -0.0 VE 27561 11DCI 3.2941*5 0.0 EB 7.9539*5 -0. BV C-12DCIE 2.9933*5 -0. W CHC13 4.2975*5 -0. W BrCIN* 62446.0664 -0. W tmcif* 4.5257*5 •0. V*CCt* 4.8175*5 •0. W1BMU* 2.9205*5 0.0 V¥.*^ 8.5749*5 •0. W TClf 3.6164*5 -0. W 12DCIP* 2.8700*5 •0. W BrOCIN* 2.8324*5 •0.1 W 2ClEthylVO 59*25.0977 -0.1 VE C-13DCIP* 2.8772*5 0.0 EV 5.0887*5 •0.0 W T-130CIP* 1.8868*5 -0.1 W 112TCIE* 2.6393*5 -0.0 W T*tClE 4.1667*5 •0.0 W OBrCIN* 2.0572*5 -0.0 W ClBz 1.5051*5 •0.0 W o-Cl,F-B*n 41363.9922 0.0 VB 2.2072*5 -0.0 BV CHBrS 1.0349*5 •0.0 W 1122TttClE 1.9189*5 3.0 W 123TriClPr 1.2595*5 0.0 VB 4.6485*5 -0.0 BV 13DCIBZ 1.9412*5 •0.0 W 140CIBZ 2.2881*5 Ar** Height INST. AK C«l. Component SAMPLE CON [UV*MC] [uV] (ISX) R*no* NMM (PPB) 32870.25 1951.38 4725182.50 203668.05 6300644.00 322979.84 6208365.50 303983.00 2639792.75 143861.14 5976887.50 315478.66 7971876.00 435604.88 4907508.50 260086.80 7991203.00 631010.81 7999146.50 758246.44 7163937.50 691180.75 6627984.00 554546.50 44269.50 1490.49 6450837.00 577128.81 8767528.00 721860.81 6776290.00 546152.38 8931882.00 584032.63 9981729.00 701588.63 5380778.50 437563.84 427154.81 11830.87 7998558.00 699218.63 5836166.00 470855.00 5328287.50 422425.59 791772.88 53583.87 7794816.50 682727.63 168408.50 4619.84 1462820.00 117900.32 5031290.50 384530.47 8755942.00 645653.31 3495502.50 209084.50 2937625.75 181622.75 4586367.00 269434.16 48309.19 1103.91 1659355.25 98843.70 3416382.25 232747.58 2557039.25 183874.39 75979.00 2846.74 3891884.75 349182.22 4425685.00 373659.91 0.68 35.70 28.59 25.76 23.94 26.00 23.36 10.48 25.42 24.30 22.66 20.12 0.06 21.55 20.40 108.51 19.74 20.72 18.42 0.50 22.12 20.34 18.81 13.28 27.09 0.33 7.75 19.06 21.01 16.99 19.52 110.88 0.22 16.03 17.80 20.30 0.16 20.05 19.34 * OCIDFN* cue VCl BrM* ClEa TCIFN* 11DCIE CH2C12 T-120CIE 27561 110CI C-120CIE CHC13 BrCIN* 111TCIEB CC14 12DCIE* TCIE 12DCIP* •rOCIN* ZCtEthylVO C-13DCtP* T-130CIP* 112TCIE* TttClE OBrCIN* ClBz o-Cl,F-B«n CHBr3 1122T*tClE 123THClPr 130CIBZ 14DCIBZ 0.68 35.70 28.59 25.76 23.94 26.00 23.36 10.48 25.42 24.30 22.66 20.12 0.06 21.55 20.40 108.51 19.74 20.72 18.42 0.50 22.12 20.34 18.81 13.28 27.09 0.33 7.75 19.06 21.01 16.99 19.52 110.88 0.22 16.03 17.80 20.30 0.16 20.05 19.34 TUT 004 1933 40 41 42 43 44 45 64.911 67.982 68.298 68.699 69.445 69.796 •0.0 W 12DCIIZ 2.0464*5 0.0 W 0.0 V8 0.0 18 0.0 8V 0.0 Vt 2.4202*5 1.9099*5 4.2415*5 1.2923*5 2.4040*5 3883342.00 341914.19 1S44.97 1388.67 21976.03 1328.81 1783.44 115.02 131.00 933.5S 185.27 133.67 18.98 12DCIBZ 18.98 0.01 0.01 0.05 0.01 0.01 0.01 0.01 0.05 0.01 0.01 2.8 1.2768*7 189479440.00 1.39*7 887.06 887.06 Missing Component Report Component Expected Retention (Sample File) Air 1.845 Y. NOT DETECTED ON PRIMARY RUN: Z. NOT DETECTED ON PID TUT OO4 1934 i 8 •S R i s •• 5* 35— 30- E 25- .. . ^ c • o — 3 oo (/) <Uo: 15- _c1 8) ««iiit 10- 5- l^|8.o • e*o j, if } -lls| r*s5 8 R8 °* °. ^. -."! *! ^ S?i 'fi ?n .-»* <0 Km <-«••-•- -»tM \ ir rl ^* ii • i \ i i n n i i l i t 1 1 1 1 1 1 H 2 3 a - w ni u " " -* *** 1 1 1 1 1 8 i i * £< i i i t 0 !-•- IT. I I I | I I I I | I I I I | I I I I | I I I I | I I I I | I I M | F I I I | I I I I | I M I | I I I I | I I I I | I M I 10 20 30 40 50 60 Retention Time [min] ) Software Version: 3.2 <16C20> Sample Nave Sample Number Operator Instrument AutoSampler Rack/Vial BLANK SPIKE B2879 V3400A/SALLY NONE 0/0 Time Study Channel : B : 3/11/93 10:39 AM A/D mV Range : 1000 Interface Serial Delay Time End Time Sampling Rate Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount # : 0159572256 0.00 min. 70.00 min. 2.0000 pts/sec Data Acquisition Time: 3/11/93 12:50 AM n:\v3400s\TC10013.raw n:\v3400s\TC10013.rst N:\V3400S\8000SUE.ins N:\V3400S\PID.prc N:\V3400S\LINPTC10.smp n:\v3400s\scl0.seq 5 ml 1.0000 Area Reject : 100.00 Dilution Factor : 1.00 ITAS-KNOXVILLE V3400A RTX 502.2 105m*0.53mm ID,3.00um df PID DETECTOR: Percent differences, standard concentrations, and Cfs for FBz, o- Cl,F-Benzene, and B2ClIsopO are incorrect due to the compounds having a concentration different than the other compounds in the mix. The percent differences for these compounds and Cfs must be done manually. The computer could only calculate percent differences and Cfs from only one standard concentration. PMk « 0 7 19 24 31 36 37 39 44 45 49 SO 53 57 58 59 60 61 74 75 81 Rtt t 5 8 16 20 24 28 29 31 34 35 36 37 40 45 46 46 47 50 62 62 64 TfM •in] .000 .989 .970 .174 .109 .415 .343 .047 .026 .041 .573 .404 .059 .669 .230 .900 .668 .774 .310 .923 .848 Ceaporunt Air VCl 11DCIE T-120CIE C-12DCIE Bz«z TCIE 2ClEtHylVO C-13DCIP* Teluww T-13DCIP* UtClE an EthylBz •-Xylm o-Cl,F-Mnz«n< o-Xyl«rw 13DCIBZ 140CIBZ 120CIBZ H«ight [UV] 0. 20106. 884S9. 288308. 106842. 221101. 214707. 134382. 24055. 70869. 203251. 15673. 80230. 137859. 118072. 129691. i 144627. 107516. 190242. 190255. 155623. 00 40 41 13 8* 59 56 20 60 31 75 60 75 47 98 93 94 95 05 52 63 •I C*l. Rw«i w VE VI W W W W VI W W Ww VI IV wwww •Vw 88 CONCENTIATiaH 1 l <PfB) 0.000 28.270 24.143 21.482 20.991 19.602 112.247 20.896 13.406 27.394 19.417 8.112 20.337 18.567 19.100 20.411 110.487 20.011 18.587 18.560 17.977 tT AWARD CON. (PPt) 20.000 20.000 20.000 20.000 20.000 20.000 20.000 20.000 20.000 20.000 20.000 20.000 20.000 20.000 20.000 20.000 20.000 20.000 20.000 20.000 20.000 Caapontnt HIM Air VCl 110CIE T-12DCIE C-12DCIE BZ FBz TCIE 2ClEthylVO C-13DC1P* Tolumt T-13DCIP* T«tClE ClBz EthylBz •-Xylm o-Cl,F-i«ru«n o-Xylww 13DCIBZ 14DCIBZ 12DCIBZ PERCENT RECOVERY 0.000 141.350 120.714 107.409 104.954 98.012 561.233 104.480 67.031 136.972 97.082 40.562 101.687 92.835 95.497 102.055 • 552.437 100.053 92.937 92.799 89.883 420.000 2.899*3 TUT OO4 1936 ITAS-KNOXVILLE V3400A RTX 502.2 105m*0.53mm ID,3.00um df PID DETECTOR-FBZ AND O-C1FBZ ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. ALL OTHER ANALYTES ARE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLUME OF 5.0 ML. Peak * 1 2 3 4 5 6 7 6 9 11 12 13 U 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 S3 54 55 56 57 58 59 Rtt Tint RT OIFF. Bl Component [•in] X NMW 5.680 6.625 7.082 7.732 8.317 8.626 8.909 9.377 10.163 11.813 12.460 13.799 14.007 15.053 15.642 15.912 16.559 16.970 18.160 18.857 19.040 19.759 20.174 21.024 21.446 21.818 22.470 23.058 23.419 24.109 24.826 25.467 26.616 27.763 28.415 29.343 30.541 31.047 31.276 31.843 32.801 33.254 34.026 35.041 35.545 35.829 36.078 36.573 37.404 38.274 39.329 40.059 41.213 44.413 44.865 45.665 46.230 46.900 0.0 BB 0.0 B8 0.0 BB 0.0 BB 0.0 BV 0.0 W -0.1 VE VCl 0.0 EV 0.0 VB 0.0 W 0.0 VI 0.0 BV 0.0 VB 0.0 BB 0.0 BV 0.0 W 0.0 W -0.0 VB 110CIE 0.0 BV 0.0 W 0.0 W 0.0 W -0.0 W T-12DCIE 0.0 W 0.0 W 0.0 W 0.0 W 0.0 W 0.0 W -0.1 W C-12DCIE 0.0 W 0.0 VB 0.0 BV 0.0 W -0.1 W Bz -0.1 w raz 0.0 W -o.i VE mi 0.0 EV . 0.0 W 0.0 W 0.0 W -0.1 W 2ClEthylVO -0.1 W C-13DCIP* 0.0 W 0.0 W 0.0 W -0.1 W Tolucn* •0.1 W T-13DCIM 0.0 W 0.0 W -0.1 VB TctClE 0.0 BV 0.0 W 0.0 VB -0.0 BV ClBz -0.0 W EthylBl -0.0 W M-Xyltn* Ar*«/ AMOWt 627.8618 10532.1953 6417.8721 10358.6338 9567.7539 10817.7744 9629.6406 10779.6924 11014.4248 11786.4463 38079.9336 73301.9453 34644.9727 36706.9063 37329.9219 38010.3750 29830.6250 33163.1211 90604.2031 1.0460*5 1.8906*5 76923.9844 1.2712*5 1.6404*5 2.3941*5 67076.1563 69046.5469 41002.1250 35670.2773 62055.1328 71297.4063 2.1258*5 1.7698*5 95286.3750 16702.6719 90926.9922 46334.1055 59853.5391 1.4557*5 23900.5313 18829.6406 12104.3789 17134.6523 24472.6836 92890.7813 1.4422*5 82959.9688 14297.9834 28816.1758 45273.0781 35941.9531 73474.6563 2.8661*5 1.2236*5 80775.6875 72772.6797 76765.7891 Ar*a Height IMST. AM C«l. Component SAMPLE CON (UV*MCj tuVJ (1SX) Rang* NMW (PPB) 20306.50 4022.20 1414.00 191 !o6 3385.00 228.61 1220.75 135.30 4318.56 296.54 5661.58 420.90 305817.69 20108.40 32156.50 2375.26 11738.91 774.59 22282.05 1438.95 5449.69 328.88 3558.18 342.36 8668.81 433.31 107060.00 11322.50 22230.76 2219.02 13034.13 1279.32 17898.33 1725.31 720196.31 88459.41 823.00 90.93 6011.22 890.43 25012.84 3209.24 4635.44 329.05 1652470.75 288308.13 1256.31 132.63 4095.38 335.05 11066.14 620.35 2384.93 180.98 1817.00 133.95 54541.86 6770.82 748745.75 106842.89 8318.72 682.33 9183.28 655.61 10513.97 559.61 10523.31 672.76 1867845.25 221801.59 1874817.38 234707.56 7225.80 511.06 968197.63 134382.20 14950.00 1606.31 14554.25 642.96 9234.27 525.38 9565.80 692.88 162273.06 24055.68 469393.50 70869.31 4050.61 428.19 16067.69 1810.69 7319.31 531.23 1610790.75 203251.75 115991.34 15673.60 7731.34 436.61 12366.02 1077.55 730963.25 80230.75 6028.22 323.67 5058.38 131.04 4287.45 260.15 1499756.75 137859.47 1389920.25 118072.98 1566871.75 129691.93 0.00 2.25 0.32 0.19 0.42 0.59 28.27 3.34 1.09 2.02 0.46 0.09 0.12 3.09 0.61 0.35 0.47 24.14 0.03 0.07 0.24 0.03 21.48 0.01 0.03 0.05 0.04 0.03 1.33 20.99 0.13 0.13 0.05 0.06 19.60 112.25 0.08 20.90 0.25 0.10 0.39 0.51 13.41 27.39 0.17 0.17 0.05 19.42 8.11 0.27 0.27 20.34 0.08 0.02 0.04 18.57 19.10 20.41 VCl 110CIE T-12DCIE C-12DCIE BZ FBI TCIE ZClEthylVO C-13DCIP* Totu*n* T-130CIP* T*tClE ClBz EthylBz •-Xylcn* 0.00 2.25 0.32 0.19 0.42 0.59 28.27 3.34 1.09 2.02 0.46 0.09 0.12 3.09 0.61 0.35 0.47 24.14 0.03 0.07 0.24 0.03 21.48 0.01 0.03 0.05 0.04 0.03 1.33 20.99 0.13 0.13 0.05 0.06 19.60 112.25 0.08 20.90 0.25 0.10 0.39 0.51 13.41 27.39 0.17 0.17 0.05 19.42 8.11 0.27 0.27 20.34 0.08 0.02 0.04 18.57 19.10 20.41 TUT 004 1937 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 47.6*i 50.774 52.824 53.445 53.770 54.983 56.62S 57.340 57.622 57.959 59.442 60.228 60.972 61.829 62.310 62.923 63.722 63.920 64.096 64.375 64.523 64.848 65.434 66.198 66.492 66.925 67.990 68.327 68.650 68.881 69.125 69.365 Missing •0.0 •0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 -0.0 -0.0 0.0 0.0 0.0 0.0 0.0 -0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 -0.7 www w ww VI •V VEa IVw VB 88 IV W W w w w VI M M IB •V VI IB IVw ww VI Component Component Air Y. NOT DETECTED o-Cl.F-Hn 15708.6357 o-Xyl*n* 63206.7773 1.4877*5 68557.8281 1.1499*5 1.1901*5 2.7818*5 86500.4063 84062.9063 1.2087*5 1.8691*5 94619.0391 2.3278*5 1.5488*5 130CIH 69156.3594 140CIBZ 64668.7383 79692.7031 62729.0313 1 .0100*5 62525.0586 61692.9531 12DCIBZ 53024.7383 76958.1406 49861.5859 47803.2695 51512.3008 1.2581*5 42392.8906 1.1351*5 76593.4141 50132.1602 1.2115*5 6.9277*6 Report 1735605. 1264805. 15001. 4598. 50 50 84 16 8763.13 5993. 3793. 6303. 1257951. 11493. 1712. 22042. 4009. 1637. 1285436. 1200232. 2792. 6790. 17240. 2413. 1976. 953205. 1254. 439. 84709. 461. 1447. 562. 2574. 3223. 2414. 2966. 24146912. 38 81 82 63 50 88 48 38 25 88 63 70 83 80 43 72 75 76 75 81 92 50 84 85 63 54 14 00 144627.94 107516.95 541.79 360.37 409.45 270.58 139.58 745.89 153160.72 973.20 93.79 2384.35 176.28 108.19 190242.05 190255.52 359.23 937.18 1477.75 334.16 277.38 155623.63 141.15 76.35 15340.64 77.63 99.60 114.94 196.37 364.35 416.95 211.94 2.89*6 Expected Retention 5.000 ON PRIMARY RUN: Z. 110 20 0 0 0 0 0 0 14 0 0 0 0 0 18 18 0 0 0 0 0 17 0 0 1 0 0 0 0 0 0 0 618 .49 o-Cl.F-Mn .01 o-Xyltn* .10 .07 .08 .05 .01 .07 .96 .10 .01 .23 .02 .01 .59 130CIIZ .56 140C1BZ .04 .11 .17 .04 .03 .98 120CLBZ .02 .01 .77 .01 .01 .01 .02 .04 .05 .02 .06 110 20 .49 .01 0.10 0 0 0 0 0 14 0 0 0 0 0 18 18 0 0 0 0 0 17 0 0 .07 .08 .05 .01 .07 .96 .10 .01 .23 .02 .01 .59 .56 .04 .11 .17 .04 .03 .98 .02 .01 1.77 0 0 0 0 0 0 0 618 .01 .01 .01 .02 .04 .05 .02 .06 (Sample File) NOT DETECTED ON HALL TUT OO4 1938 i g o ft * *• t £ ' IS s* 35 30— w- C O K ^K ** V vn ^ oo £ (D c a en a)a: 25— 15— 10 5— • 98 ! a. *£>.-• 1 — f • • » — • «< 0 M IL Z in w 8: *s **o 5 3 * 8 i i i MI i i i i i I I I I I I I I I 0 M as S I I I I I I I I I I M I I I I I I I I I I I I I I I I I I I M I I I I I I I I I I I I I I I I 10 20 30 40 50 Retention Time [min] •-'o h-D!- I I | I I I I | I I I 60 Software Version: 3.2 <16C20> Sample Name Sample Number Operator Instrument AutoSampler Rack/Vial W7329/MS V3400A/SALLY NONE 0/0 Time Study Channel : A : 3/11/93 10:48 AM : ITEK53554 A/D mV Range : 1000 Interface Serial # : 0159572256 Data Acquisition Time: 3/11/93 7:09 AM Delay Time End Time Sampling Rate Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount Noise Threshold Multiplier 0.00 70.00 2.0000 min. min. pts/sec n:\v3400s\SC10018.raw n:\v3400s\SC10018.rst N:\V3400S\8000SUE.ins N:\V3400S\HALL.prc N:\V3400S\LINHSC10.smp n:\v3400s\scl0.seq 5 mL 1.0000 15 1.0000 Area Reject : 100.00 Dilution Factor : 1.00 Area Threshold : 73 Bunch Factor: 2 Divisor : 1.0000 Adder : 0.0000 Instrument Conditions: Total Number of Peaks Detected: 33 ITAS-KNOXVILLE V-3400B J+W DB-624 75m*0.53mm ID, 3.00um df ELECTROLYTIC CONDUCTIVITY DETECTOR-BrClMe AND O-C1FBZ ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. ALL OTHER ANALYTES ARE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLUME OF 5.O ML. Pt.k 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 R*t TIB* 11 [•In] 5.887 7.137 7.681 9.136 14.198 17.087 19.151 20.299 24.229 24.882 25.990 26.679 27.817 28.433 29.440 31.182 32.893 36.601 40.188 41.310 45.897 47.817 r OIFF. BL Ce*pon*nt 0.0 BV 1.7 WMttfN* 0.0 W 0.7 VB VCl 1.4 88 TCIFM* 0.3 BV 110CIE 0.3 W CM2C12 0.3 W T-12DCIE 0.2 W C-12DCIE 0.2 W CHC13 0.2 W BrCIN* 0.2 W 111TCIE* 0.2 W CCU 0.1 W 12DClEt 0.0 W 0.2 W TCIE 0.1 W BrOCIN* 0.0 W 0.1 W T«tClE 0.1 VE OBrCIN* 0.3 EV CIBZ 0.1 W o-Cl,F-B*n Ar**/ AMWK 1.1094*9 1.0731*5 85934.8047 2.2953*5 2.4060*5 3.1416*5 4.2533*5 6.5407*5 2.9782*5 4.2862*5 63313.9805 4.5438*5 4.8623*5 2.9982*5 7.2541*9 4.1278*9 3.0967*9 1.5217*6 6.4851*5 2.4639*5 8.1973*5 41866.7978 Ar** Height 1 282412.88 7725.92 71098.38 1906.60 73069.09 2464.49 4780099.90 229120.34 2990.29 161.16 9789200.90 497072.09 428111.72 31410.87 196139.38 9147.99 6410973.00 576471.79 7889828.90 651304.75 6384041.00 507484.75 8154479.00 931086.88 8102841.00 964269.90 5023243.50 403284.28 377917.34 12372.93 11913041.00 912376.63 4739936.00 343689.69 119514.50 1093.03 21007940.00 995283.06 3894462.90 189746.50 182567.90 2072.59 4271907.50 247946.97 HST. AM I (ISX) I 2.55 0.66 0.85 20.83 0.01 18.42 1.01 0.30 21.53 18.41 100.83 17.95 16.66 16.98 0.52 28.86 15.31 0.08 32.39 15.64 0.22 102.04 Cal. Co*pen*nt *, k*no* N*M • OCIDFM* VCl • TCIFN* 11DCIE CH2C12 T-12DCIE C-12DCIE CMC 13 BrClH* 111TCIE* CCU 12DCIE* TCIE BrOCIN* TttClE DBrCIN* Clil o-Cl,F-B*n AMPLE CON <PPB> 2.55 0.66 0.85 20.83 0.01 18.42 1.01 0.30 21.53 18.41 100.83 17.95 16.66 16.98 0.52 28.86 15.31 0.08 32.39 15.64 0.22 102.04 TUT O04 1940 23 24 25 26 27 28 29 30 31 32 33 12.813 S3.S89 5*. 794 58.084 59.116 60.159 62.593 63.054 65.007 67.374 69.081 0.0 0.1 1.4 0.0 0.0 0.0 0.3 0.1 0.1 0.0 0.0 W VE EV W W VI H •V VE El U CHIr3 123Tr1ClPr 13DCIIZ 140CIH 12DCIIZ 2.7035*5 1.2054«5 6.5937*5 4.0695*5 3.4134*5 9.7797*5 2.8120*5 2.2205*5 5.2303*5 3.8345*5 6.6331*5 24112.84 1784724.13 58405.50 29333.41 15491.19 13596.56 2453.00 3952100.00 129646.41 1655.50 9913.00 449.02 89978.78 802.24 652.83 411.03 242.14 151.93 343841.41 4473.09 77.79 269.27 0.09 14.81 0.09 0.07 0.05 0.01 0.01 17.80 0.25 0.00 0.02 CHBr3 123TriClPr 13DCIBZ 140CIBZ 120CIBZ 0 U 0 0 0 0 0 17 0 0 0 .09 .81 .09 .07 .05 .01 .01 .80 .25 .00 .02 8.5 1.3770*7 106072616.00 7.11*6 465.22 465.22 Missing Component Report Component Expected Retention (Sample File) Air CLME BrMe ciEa 2756111DClEa 12DClPa 2ClEthylVO C-13DClPe T-13DClPe 112TClEa 1122TetClEa I.845 8.324 II.919 12.473 21.838 31.870 34.116 35.123 37.487 38.300 54.996 Y. NOT DETECTED ON PRIMARY RUN: Z. NOT DETECTED ON PID TUT 004 1941 g •*- o* O K» | I 8* • ."85 oo L. ui a. <o <U (/) Oa 35- 30— 25— 0_ 20- 15— 5— ? g «5 5 n I I si H 11 I 1 1 1 1 I 1 1 I 1 1 I 1 1 1 1 1 1 1 1 I 1 1 I 1 1 1 1 I I I I I 1 1 I I I 1 1 I 1 1 I 1 1 1 1 1 I I 0 10 20 30 40 50 Retention Time [min] I I I I | I I I I | I I I 60 Software Version: 3.2 <16C20> Sample Name Sample Number Operator Instrument AutoSampler Rack/Vial W7329/MS V3400A/SALLY NONE 0/0 Time Study Channel : B : 3/11/93 10:49 AM : ITEK53554 A/D mV Range : 1000 Interface Serial # : 0159572256 Data Acquisition Time: 3/11/93 7:09 AM Delay Time End Time Sampling Rate Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount Noise Threshold Multiplier 0.00 min. 70.00 min. 2.0000 pts/sec n:\v3400s\TC10018.raw n:\v3400s\TC10018.rst N:\V3400S\8000SUE.ins N:\V3400S\PID.prc N:\V3400S\LINPTC10.smp n:\v3400s\sclO.seq 5 ml 1.0000 Area Reject : 100.00 Dilution Factor : 1.00 10 1.0000 Area Threshold : 49 Bunch Factor: 2 Divisor : 1.0000 Adder : 0.0000 Instrument Conditions: Total Number of Peaks Detected: 79 ITAS-KNOXVILLE V3400A RTX 502.2 105m*0.53mm ID,3.00um df PID DETECTOR-FBZ AND O-ClFBz ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. ALL OTHER ANALYTES ARE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLUME OF 5.0 ML. Pert * 1 2 3 4 6 7 a 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 Rtt (• 5. 6. 7. 7. 9. 9. 10. 13. 15. 15. 15. 16. 17. 17. 18. 19. 19. 20. 20. 21. 22. 23. TU» R1 i(rv] 703 649 106 577 032 373 210 826 101 690 958 606 018 694 906 078 82* 219 619 499 263 095 r DIFF X 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 • .0 .0 .0 .0 .4 .0 .0 .0 .0 .0 .0 .0 .3 .0 .0 .0 .0 .2 .0 .0 .0 .0 •L Co»pon*nt tv V8N M VI VCl IV vt •V VI tv ww VI 11DCIE IV W W W W T-12DCIE W W W W ArM/ Aaoutt 779.6002 4190.9912 3443.2969 11721 .MM 10309.5430 10389.7959 84918. 1*84 35101.7227 369*9.3750 37878.7266 33331.3125 29663.7383 45940.31*4 1.2873*5 1.3298*5 1 •70^^99 82534.15*3 1.8130*5 2.3188*5 58177.9336 1.3416*5 ArM [|**MC] 342247. 497*. 50*. 444. 292985. 18128. 8162. 4824. 92323. 18723. 11654. 92S4. 605613. 168*. 4589. 279*. 14*818. 23094. 2912. 6092. 1411. 3631. 91 58 50 00 16 50 17 78 19 44 6* 63 25 31 09 33 00 23 80 50 64 92 Height I liM 39718.77 408.28 85.96 91.72 17779.04 1251.25 558.79 208.18 9636.91 1855.66 1127.35 1017.33 74804.02 134.49 478.02 282.20 12551.27 3755.39 215.62 352.62 123.51 137.79 NST. AK C* (I5X) *• 0.00 6.38 0.12 0.13 25.00 1.76 0.79 0.06 2.63 0.51 0.31 0.28 20.42 0.04 0.04 0.02 0.94 0.28 0.02 0.03 0.02 0.03 I. Co*Mn*nt SAMPLE CON ng* NMM (PPI) 0.00 6.38 0.12 0.13 VCl 25.00 1.76 0.79 0.06 2.63 0.51 0.31 0.28 110CIE 20.42 0.04 0.04 0.02 0.94 T-12DCIE 0.28 0.02 0.03 0.02 0.03 TUT OO4 1943 29 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 SO 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 23.488 24.1*4 24.878 25.529 26.678 27.840 28.472 29.399 30.608 31.100 32.851 34.229 35.878 36.621 37.105 39.381 40.116 41.263 44.471 45.727 46.296 46.972 47.736 50.868 51.161 52.894 53.509 56.303 56.706 57.407 57.801 59.347 60.219 60.851 61.036 62.132 62.376 62.990 64.164 64.420 64.913 65.268 65.498 65.729 65.892 66.255 66.546 66.957 67.769 68.041 68.658 68.936 69.174 69.420 69.753 0.0 0.2 0.0 0.0 0.0 0.0 0.2 0.1 0.0 0.1 0.0 0.5 0.0 0.1 -0.9 0.0 0.1 0.0 0.0 0.1 0.1 0.1 0.1 0.2 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.1 0.1 0.0 0.0 0.1 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 w VB IV w www VE EVw w ww w w w w w w w VB BV w w VB BV W W VB BV VB BV W W W W VB BB BV W VB BB BB BV VB BB BV VB BB BB BV W W VB BB C-12DCIE BZ FBI TCIE 2ClEthylVO Toluene T-13DCIP* TetClE CIBZ EthylBz m-Xyl*n* o-Cl,F-S*n o-Xyltn* 130CIBZ 140CIBZ 120CIBZ 56918.9727 35774.5742 62053.4570 72503.0000 1. 7613*5 1 .8023*5 95552.0703 16616.4629 1.1784*5 46258.0742 28900.4551 98710.4297 88637.5234 89955.9922 32924.6211 53992.1602 36984.1602 1.5797*5 89838.6953 83964.8203 75517.8047 81415.4141 15729.6943 74796.6953 70496.4844 1.2207*5 2.1835*5 1.0450*5 1.0108*5 1.3058*5 2.1147*5 1.9012*5 1.1551*5 1.2555*5 1.1342*5 1.7437*5 80831.0938 65504.8438 1.3098*5 1.2201*5 59570.7617 41721.1367 65965.2422 50475.8242 47084.5352 48698.3164 49920.1250 1 .4502*5 26435.7900 38024.3828 1.2491*5 67147.7813 44794.3281 73539.3790 37543.9297 3708 751836 7664 8649 8003 9309 1541763 1706589 2065 1840647 9060 13228 119729 23227 8384 5650 6146810 14405 22268 12980 9220 12895 1561134 7128 9807 8276 11791 3516 1236 7626 6250 2661 13377 2803 10928 1250 3383 1127706 13673 3779 14542 198 638 624 736 1129 16445 4510 308 847 5949 6752 560 1471 312 .81 .88 .84 .50 .47 .55 .13 .63 .50 .63 .19 .19 .34 .98 .44 .94 .00 .94 .50 .47 .25 .56 .75 .31 .11 .03 .63 .50 .39 .31 .69 .33 .56 .05 .47 .05 .02 .25 .23 .75 .52 .00 .50 .46 .79 .50 .25 .52 .27 .49 .75 .87 .77 .61 .00 331.66 106971.22 628.72 607.23 514.16 584.44 182571.14 214755.63 112.72 255894.89 425.54 181.10 14139.91 2702.99 414.28 412.89 655663.56 359.76 1840.45 1147.86 754.78 1006.42 129915.13 512.06 747.46 364.27 290.15 180.79 125.18 597.74 302.52 143.27 1185.26 228.50 986.13 73.37 428.37 176477.28 903.68 268.17 2113.36 41.08 83.79 107.10 135.47 200.79 2851.89 269.25 100.95 192.95 412.35 870.61 108.38 173.25 71.94 0.07 21.02 0.12 0.12 0.05 0.05 16.14 102.71 0.02 39.79 0.31 0.13 1.35 0.26 0.26 0.11 166.20 0.09 0.25 0.16 0.12 0.16 99.25 0.10 0.14 0.07 0.05 0.03 0.01 0.06 0.03 0.01 0.12 0.02 0.10 0.01 0.04 17.22 0.10 0.03 0.24 0.01 0.01 0.01 0.02 0.02 0.33 0.03 0.01 0.02 0.05 0.10 0.01 0.02 0.01 C-12DCIE Bz FBI TCtE - 2ClEthylVO Toluene T-130CIP* TetClE CIBZ EthylBz n-Xylene o-Cl,F-B*n o-Xyltne 130CIBZ 140CIBZ 12DCIBZ 0.07 21.02 0.12 0.12 0.05 0.05 16.14 102.71 0.02 39.79 0.31 0.13 1.35 0.26 0.26 0.11 166.20 0.09 0.25 0.16 0.12 0.16 99.25 0.10 0.14 0.07 0.05 0.03 0.01 0.06 0.03 0.01 0.12 0.02 0.10 0.01 0.04 17.22 0.10 0.03 0.24 0.01 0.01 0.01 0.02 0.02 0.33 0.03 0.01 0.02 0.05 0.10 0.01 0.02 0.01 2.2 6.3184*6 16732331.00 1.93*6 527.51 527.51 Missing Component Report Component Expected Retention (Sample File) Air C-l3DClPe 5.000 35.060 Y. NOT DETECTED ON PRIMARY RUN: Z. NOT DETECTED ON HALL TUT OO4 1944 oo - - i 35- - 8. "o M J £ •• 5£ 30— ?f i — i !? E 25— §I3s a) I «5£g.2 H? }5J*s ° 2°~ " " " ( / ) <U ^ 15— c1 j| 10- _ _ •{ _ I E5 b IU 0. • ——— to 8 ~ -|le 5 3 S "• 5 c'8o !, i| tf r- •« •- 1 8 o Sj« »j*^T~ VlT^M o m ~ K g O "^ • 1* Sp 6 J fiaH 8 * £ & ^w - ? X°-°^ » «AI^^ 5'VKft' I 8n 3 tS F&Q "** ^ "M im — r^Ymrrn rrTiTtTYT'TT i i i ; ^ *c s * 8 1 IB M • *'* 1 3 : R • ^^ i ? 7 i? * i ? I S 1 M -~TT~T IT — n -i —— r II 1 1 II 1 S IU Ul •4 iu _i a. a. w d d td Wd MI . ^ d f l f i u , d * 8 d 5 g g 7 7 aB d d7 87 £ < > «- >- o Bu. >- Ko "»- ~ TTTl —— ~ ———————————————————— t ~* 1 5 1 * — *• • • — • *• o 1 1 1 1 1 1 1 1 1 I I I I I III I I 1 1 1 1 10 20 ' 30 ' 40 Rf^tf^nt on T m (=> f m r1 5F ^•^ * Tffin « ,. ' %^ g^fi ^5; 1 ^i|i MM 1 HI Jd- i M 1 | 1 1 1 1 | 1 1 1 1 ; •* •> aff5 ft 1? HJL u in 0- o h- h- m » 9 • [ Jt MJgy^JBR *O?U6jf .^BTBBp IW rnTn 1 1 i li II 1 1 1 1 1 50 60 inl software Version: 3.2 <16C20> W7329MSD V3400A/SALLY NONE 0/0 Sample N Sample Number Operator Instrument AutoSampler Rack/Vial Tine Study Channel 3/11/93 10:50 AM ITEK53554 A/D mV Range : 1000 Interface Serial # : 0159572256 Data Acquisition Time: 3/11/93 8:25 AM Delay Time End Time Sampling Rate Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount Noise Threshold Multiplier 0.00 min. 70.00 min. 2.0000 pts/sec n:\v3400s\SCl0019.raw n:\v3400s\SC10019.rst N:\V3400S\8000SUE.ins N:\V3400S\HALL.prc N:\V3400S\LINHSC10.smp n:\v3400s\scl0.seq 5 mL 1.0000 15 1.0000 Area Reject : 100.00 Dilution Factor : 1.00 Area Threshold : 73 Bunch Factor: 2 Divisor : 1.0000 Adder : 0.0000 Instrument Conditions: Total Number of Peaks Detected: 37 ITAS-KNOXVILLE V-3400B J+W DB-4S24 75m*0.53mm ID, J.OOmn df ELECTROLYTIC CONDUCTIVITY DETECTOR-BrClMe AND O-C1FBZ ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. ALL OTHER ANALYTES ARE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLUME OF 5.O ML. Peakt 1 2 3 4 5 6 7 B 9 10 11 12 13 14 15 16 17 IB 19 20 21 22 ft«t Ti** *T OIFF. Bl Colorant (•in] X Maw 2.196 3.292 5.884 7.129 7.673 9.134 12.475 U.U9 17.090 19.154 20.300 21.965 23.433 24.23S 24.888 25.555 26.684 27.822 28.438 29.447 31.188 32.860 0.0 It 0.0 M 0.0 IV 1.6 W DCIDFN* 0.0 W 0.7 VE VCl 1.6 EV ClE* 1.0 VI TCIFM* 0.3 IV 110CIE 0.3 W CH2C12 0.3 VE T-12DCIE 0.6 EV 27561 110CI 0.0 W 0.2 W C-12DCIE 0.2 W CHC13 0.2 W BrCIN* 0.2 W IHTClEa 0.2 W CCU 0.2 VE 12DClEa 0.0 EV 0.2 W TCIE 0.1 VE IrOCtM* Ar**/ A*M1t 5*3.7947 413.8906 1.0655*5 1.1017*5 89343.2109 2. 4150*5 1.0031*6 5.9137*5 3.1947*5 4.3262*5 5.8148*5 1.3864*6 1.0699*6 3.0399*5 4.3607*5 63618.1836 4.5700*5 4.8359*5 3.0139*5 7.3649*5 4.1818*5 3.0508*5 ArM Height INST. AM C«l. Component SAMPLE CON (UV*MC) [UV7 (l«) R*n*« NMN (PPI) 4204.50 163.63 1354.50 83.50 305547.63 8777.06 82540.89 2165.33 87636.94 2853.39 5434721.50 253686.88 72110.50 872.13 43122.63 1003.93 6593257.00 512256.81 471910.44 34040.44 187372.69 9829.94 34158.00 679.00 9917.83 248.24 6501988.00 572786.50 7877903.00 639204.38 6463886.00 511374.84 7923248.50 513067.03 9008378.00 630761.19 5066645.00 399250.59 363156.50 11710.83 12061443.00 911823.69 5318466.00 391473.72 7.46 3.27 2.87 0.75 0.98 22.50 0.07 0.08 20.64 1.09 0.32 0.03 0.01 21.39 18.07 101.60 17.34 18.63 16.81 0.49 28.84 17.43 - OCtOFM* VCl CIE« - TCIFM* 11DCIE CN2C12 T-120CIE 27561 11DCI C-12DCIE CMC13 IrCIN* 111TCIE1 CCU 12DCIE* TCIE BrOCtN* 7.46 3.27 2.87 0.75 0.98 22.50 0.07 0.08 20.64 1.09 0.32 0.03 0.01 21.39 18.07 101.60 17.34 18.63 16.81 0.49 28.84 17.43 TUT OO4 1946 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 36.SO 38.050 38.575 40.188 41.317 45.885 47.815 53.583 60.374 60.958 61.588 62.516 63.036 64.987 68.099 0.0 EV 1.5 W T-13DCIP* 0.7 W 112TCIE* 0.1 W T*tCtE 0.1 VE DBrClN* 0.3 EV Clll 0.1 W o-Cl,F-l*n 0.1 VI CNir3 0.0 §V 0.0 W 0.0 VI 0.2 IV 130CIIZ 0.1 W 140CIIZ 0.1 VI 12DCIBZ 0.0 IB 2.2858*6 2.7817*5 1 .2024*6 6.5458*5 2.4101*5 7.4300*5 42880.6289 1.1909*5 3.4253*5 3.7704*5 2.7303*5 2.9115*5 2.2340*5 4.8838*5 4.5926*5 116053.50 1279.48 14489.52 724.68 42455.31 712.21 21213024.00 995703.31 4372982.50 226004.13 172668.50 2162.65 4532139.00 256831.55 2048127.75 107434.42 1942.13 98.75 3470.05 160.29 1445.81 92.23 6656.19 398.18 4087116.50 353437.34 129631.56 4782.52 2815.00 110.44 0.05 0.05 0.04 32.41 18.14 0.23 105.69 17.20 0.01 0.01 0.01 0.02 18.30 0.27 0.01 T-130CIP* 112TCIE1 TetClE OBrClMe Clll o-CL,F-B*n CHIr3 130CL8Z 140CIBZ 12DCI8Z 0.05 0.05 0.04 32.41 18.14 0.23 105.69 17.20 0.01 0.01 0.01 0.02 18.30 0.27 0.01 11.2 1.7460*7 110659992.00 7.35*6 493.09 493.09 Missing Component Report Component Expected Retention (Sample File) Air CLME BrMe 12DClPa 2ClEthylVO C-13DClPe 1122TetClEa !23TriClPropane I.845 8.324 II.919 31.870 34.116 35.123 54.996 56.030 Y. NOT DETECTED ON PRIMARY RUN: Z. NOT DETECTED ON PID TUT OO4 1947 i s 0 Kl 5 I a o sS ,§ oo I i is 8 i, j! • I,1-- allti 1 — *• • • V •»-•** u M u. i M M (D C 0) (D o: 00 (h '.-'o f- M | I II I | M M | M M | M M | II II | II M | M II | I M I | II II | II II | 20 30 40 50 60 Retention Time [ rn i n ] Software Version: 3.2 <16C20> Sample Name Sample Number Operator Instrument AutoSampler Rack/Vial W7329MSD V3400A/SALLY NONE 0/0 Time Study Channel B 3/11/93 10:51 AM ITEK53554 A/D mV Range : 1000 Interface Serial # : 0159572256 Data Acquisition Time: 3/11/93 8:25 AM Delay Time End Time Sampling Rate Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount Noise Threshold Multiplier 0.00 min. 70.00 min. 2.0000 pts/sec n:\v3400s\TC10019.raw n:\v3400s\TC10019.rst N:\V3400S\8000SUE.ins N:\V3400S\PID.prc N:\V3400S\LINPTC10.smp n:\v3400s\scl0.seq 5 ml 1.0000 Area Reject : 100.00 Dilution Factor : 1.00 10 1.0000 Area Threshold : 49 Bunch Factor: 2 Divisor : 1.0000 Adder : 0.0000 Instrument Conditions: Total Number of Peaks Detected: 69 ITAS-KNOXVILLE V3400A RTX 502.2 105m*0.53mm ID,3.00iim df PID DETECTOR-FBZ AND O-ClFBz ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. ALL OTHER ANALYTES ARE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLUME OF 5.0 ML. Peakf 1 2 3 5 6 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 R*t TIM RT Olff. tain] X 5 7 7 9 10 13 15 15 15 16 17 18 19 19 20 20 21 22 23 23 24 24 .700 .064 .563 .043 .203 .795 .099 .691 .958 .609 .020 .918 .091 .831 .224 .618 .502 .265 .104 .496 .169 .881 0.0 0.0 0.0 0.5 0.0 0.0 0.0 0.0 0.0 0.0 0.3 0.0 0.0 0.0 0.2 0.0 0.0 0.0 0.0 0.0 0.2 0.0 BL Component M 18 M W VCl VI IV VI •V W W VI 110CIE •V W W VE T-12DCIE EV W W W W W C-12DCIE W Ar*«/ AMMtt 5031.3462 4965.3618 12684.2588 11303.2529 90468.2266 34761.8516 36981.0332 37471.1484 33477.6797 30107.6016 2.4294*5 1.2662*5 1.5687*5 84327.3672 1.6293*5 2.3076*5 57353.1602 1.3856*5 55197.9180 36204.1445 61661.0781 Art* tuv*s*c) 362629 636 758 311987 9383 4679 92835 18863 11693 8854 605867 1864 2710 145501 24523 1553 6011 1485 3375 3424 750679 7380 .50 .00 .25 .81 .89 .66 .33 .21 .84 .98 .69 .19 .70 .50 .53 .00 .13 .63 .42 .80 .88 .59 Height INST. A*t Cal. CMporwnt SAMPLE CON [uVl (ISX) Rang* NMW (PPB) 43017 89 108 17495 590 189 9785 1868 1143 969 73732 102 287 12448 3903 127 349 131 123 315 105539 609 .04 .91 .62 .46 .52 .53 .11 .93 .45 .14 .19 .98 .30 .18 .01 .92 .60 .85 .99 .81 .32 .25 0.00 0.13 0.15 24.60 0.83 0.05 2.67 0.51 0.31 0.27 20.12 0.01 0.02 0.93 0.29 0.01 0.03 0.03 0.02 0.06 20.74 0.12 0.00 0.13 0.15 VCt 24.60 0.83 0.05 2.67 0.51 0.31 0.27 110CIE 20.12 0.01 0.02 0.93 T-12DCIE 0.29 0.01 0.03 0.03 0.02 0.06 C-120CIE 20.74 0.12 TUT 004 1949 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 25. 53i 26.673 27.820 28.477 29.405 30.603 31.105 32.859 34.235 34.760 35.902 36.121 36.628 37.113 39.389 40.124 41.273 45.731 46.292 46.971 47.737 50.854 52.891 53.508 56.691 57.390 57.778 59.498 60.211 60.834 62.095 62.360 62.971 64.140 64.893 65.517 65.871 66.240 66.532 66.971 68.024 68.701 68.968 69.165 69.421 Missing 0.0 0.0 0.0 0.2 0.2 0.0 0.1 0.0 0.6 •0.9 0.0 0.0 0.1 -0.8 0.0 0.1 0.0 0.1 0.1 0.1 0.1 0.2 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.1 0.1 0.0 0.1 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 1.6 VI •V ww VE EV W W W W W W W W W W W W w wwww w VB BV VB BV W W W VB BV W VB BB BB BB BV VB H BB BV W VB Component •x FBZ TCIE 2ClCthylVO C-130CIP* Tolkien* T-13DCIP* T«tCtE ClBl EthylBz m-Xyl*n* o-Cl,F-B«n o-Xylen* 130CIBZ 140CIBZ 12DCIBZ 70121.7344 1. 8222*5 1.7576*5 96308.6719 16741 .4531 94482.8594 46575.9336 54103.7656 27822.3731 87059.7422 1.3853*5 1.7004*5 92467.5078 28731.1094 66297.0859 36972.7734 1.1960*5 1.1810*5 78352.9609 81124.9219 15792.3682 90010.3125 1.2689*5 1.6298*5 1.8541*5 1.2367*5 1.3083*5 2.3603*5 1.2677*5 3.0778*5 2.2382*5 73227.9063 65513.0938 1.2674*5 58947.7344 75633.5000 42030.5117 50581.1289 49214.3125 1.3091*5 1.1555*5 73135.1328 65985.5469 35034.8828 80572.7031 6.2052*6 8397.25 7986.75 9600.30 1520664.50 1706491.3* 1369.00 1838176.25 21253.44 3686.52 5762.69 5735.77 8105.94 21030.11 7595.44 4370.47 6192049.00 12672.56 19405.31 11410.16 11630.03 1599709.50 8665.25 10542.59 11105.94 1853.19 5769.44 2233.09 2435.59 9079.22 4230.31 1892.69 3913.73 1180471.38 27634.31 15504.80 760.99 261.25 630.00 10260.53 2528.70 4016.50 676.00 4232.75 226.95 1077.31 16703807.00 609.54 495.93 618.04 178658.05 213140.00 93.18 253807.28 534.26 179.06 171.24 433.40 499.00 2380.76 430.17 260.06 660692.50 417.97 1219.99 900.25 910.91 132596.94 517.26 446.39 366.13 102.30 477.47 174.69 105.61 733.02 140.68 86.55 547.02 184711.34 1887.51 2277.02 87.10 53.81 107.83 1804.87 167.22 300.89 80.02 555.32 56.08 115.75 1.91*6 0.12 0.04 0.06 15.79 101.93 0.01 39.47 0.39 0.13 0.07 0.04 0.05 0.23 0.26 0.07 167.48 0.11 0.16 0.15 0.14 101.30 0.10 0.08 0.07 0.01 0.05 0.02 0.01 0.07 0.01 0.01 0.05 18.02 0.22 0.26 0.01 0.01 0.01 0.21 0.02 0.04 0.01 0.06 0.01 0.01 519.24 Bz FBZ TCIE 2ClEthylVO C-130CIP* Toluene T-130CIP* TctClE ClBz EthylBz m-Xylen* o-Cl,F-B«n o-Xyl*n* 0 0 0 15 101 0 39 0 0 0 0 0 0 0 0 167 0 0 0 0 101 0 0 0 0 0 0 0 0 0 .12 .04 .06 .79 .93 .01 .47 .39 .13 .07 .04 .05 .23 .26 .07 .48 .11 .16 .15 .14 .30 .10 .08 .07 .01 .05 .02 .01 .07 .01 0.01 130CIBZ 140CIBZ . 120CIBZ 0 18 0 0 0 0 0 0 0 0 0 0 0 0 519 .05 .02 .22 .26 .01 .01 .01 .21 .02 .04 .01 .06 .01 .01 .24 Report Component Air Y. NOT Expected Retention 5.000 DETECTED* gpr PRIMARY RUN: Z. (Sample NOT DETECTED File) ON HALL TUT O04 1950 V3400A PID Fil : n:\v3400a\TC10019.reM Start Ti«* t 0.00 arfn Seal* Factor: 0 End Ttae : 70.00 «in Plot OffMt: 4 •* Sa«pla •: Pag* 1 of 1 Oat* : 3/11/93 10:51 AM Tia» of Injection: 3/11/93 8:25 AM LOM Point : 4.00 fH High Point : 39.00 «V Plot Seal*: 35 «/ Response [mV] o- cn O en I I I I I I I i I I ro O 01 en o~ O _ 0) H S" 15 0 0~I 0~ 5' en CD AIR VCL -10.20 -11.52 -ca -13.80 110CLE T-12DaE - ±XV» C-1ZDCU - K FU .68 .82 -£-30.60 2OETHTLVO- C-13DO.PE - TETCLE .63 .39 -£-41.27 o-xruiK - 12DOK - -9.04 -15.10 -19.83 TUT OCA 1951