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VO o CO SDMS Document '--Mu:«^--'ia?;?.-"«r?:z?s:?.f*-3?c^ar.rF^.»Tr?»s:j!^.7^ 115563 PN VIRGIN ISLAND CHEMICAL SITE •Aj,: REMEDIAL INVESTIGATION ST. CROIX, U.S. VIRGIN ISLANDS DRAFT DATA SUMMARY REPORT VOLUME I OF II Prepared For Island Chemical Company, Inc By Harding Lawson Associates Philadelphia, Pennsylvania August 15, 1995 V , / Hardtaig Lawson Associates August 15, 1995 29872 12.3 Ms. Sherrel D. Taylor-Domville United States Environmental Protection Agency Region II Emergency and Remedial Response Division 290 Broadway New York, New York 10007-1866 Draft Data Summary Report Remedial Investigation Virgin Island Chemical Site St. Croix, U.S. Virgin Islands Dear Ms. Taylor-Domville: This Data Summary Report has been prepared to document HLA's activities associated with the Remedial Investigation of the Virgin Island Chemical Site located in St. Croix, U.S. Virgin Islands. This report is prepared in accordance with the requirements specified in Section VIII of the Administrative Order on Consent (Order) for this project effective October 6, 1994 (EPA Index No. II CERCLA-94-0401). If you have any questions, please contact Jason Schindler at (215) 627-4505 or Edward Nemecek at (609) 936-0700. Yours very truly, 1 HARDING LAWSON ASSOCIATES Iward A. Nemecek, R.G., CPG Principal Hydrogeologist JMS/EAN/skb'tgaDRM/BP \WORDPROC\29872\DSR01.REP cc: Mr. Cecil Williams, Virgin Islands Department of Planning and Natural Resoiu"ces Lori G. Singer, Esq., Sills, Cvmimis, Zuckerman, Radin, Tischman, Epstein & Gross Attachment: Draft Data Summary Report 302370 Engineering and 131 North Third Street, Philadelphia, PA 19106-1903 215/627-4505 Fax 215/627-4250 Environmental Services ^ Subsidiary o / Harding Auociom • Offices Nalionwidf Draft Data S u m m a i y Report Virgin island Chemical Site St. Croix, U.S. Virgin Islands USEPA Index No. II CERCLA-94-0401 Prepared for Island Chemical Company HLA Project No. 29872 1^3 Jason M. Schindler Associate Geologist Edward A. Nemecek, R.G., CPG Principal Hydrogeologist August 15, 1995 Harding Lawson Associates - - ^ - Engineering and Environmental Services 131 North Third Street Philadelphia, PA 19106 - (215) 627-4505 3 0 2 3 7 1 CONTENTS 1.0 BACKGROUND 1 1.1 Introduction 1 1.2 Objectives 1 1.3 Site Description 2 1.3.1 Site Location 2 1.3.2 Site Structures 2 1.3.3 Site Setting 3 1.4 Areas of Potential Environmental Concern 3 2.0 SCOPE OF WORK 4 2.1 Potable Water Sampling and Preliminary Reconnaissance 4 2.2 Site Clearing and Reconnaissance 4 2.3 Field Sampling Program 4 2.3.1 Soil Sampling Program 4 2.3.2 Groimdwater Monitoring WeU Installation 6 2.3.3 Rehabilitation of Existing Wells 6 2.3.4 Well Survey 7 2.3.5 Groundwater Monitoring and SampUng 7 2.3.5.1 Water Level Monitoring 7 2.3.5.2 First Rotmd of Groundwater Sampling 7 2.3.5.3 Quarterly Groimdwater SampUng . 8 2.4 Data Validation 8 2.5 Background Investigation 8 2.5.1 Identification of Surrounding Facihties and Database Review 8 2.5.2 Review of Historical Aerial Photographs 8 2.5.3 Review of WeU Records 9 3.0 QUALITY ASSURANCEyQUALITY CONTROL 10 3.1 Field Quality Assurance/Quality Control 10 3.2 Analytical Data Validation 10 3.2.1 November 1994 Potable Water Samples 10 3.2.2 Soil Samples 11 3.2.3 February 1995 Groundwater Samples 11 4.0 RESULTS 12 4.1 Geology 12 4:2 Soil Quality 12 4.2.1 Organic Vapor Readings 12 4.2.2 Soil Sample Analytical Results 12 4.2.2.1 Volatile Organic Compounds in Soil 12 4.2.2.2 Semivolatile Organic Compounds in Soil 13 4.2.2.3 Pesticides and PCBs in SoU 13 4.2.2.4 Inorganics in SoU 13 4.3 Groundwater Flow 14 4.4 Groundwater Quality 14 4.4.1 VolatUe Organic Compounds in Groundwater 15 4.4.2 SemivolatUe Organic Compounds in Groimdwater 15 4.4.3 Pesticides and PCBs in Groundwater 16 4.4.4 Metals in Groundwater 17 3 02372_ \WORDPROC\29872\DSRoi.REP August 14,1995 4:38pm Harding Lawson Associates ' ' i 4.5 Site History and Potential Areas of Concern 19 4.5.1 Site Reconnaissance 19 4.5.2 Surrounding FacUiUes 19 4.5.3 Results of Review of Historical Aerial Photograph 20 4.5.3.1 February 15, 1954 20 4.5.3.2 AprU 20, 1959 20 4.5.3.3 1962 20 4.5.3.4 February 20, 1964 20 4.5.3.5 February 17, 1971 21 4.5.3.6 November 20, 1971 21 4.5.3.7 January 17, 1974 21 4.5.3.8 November 14, 1977 21 4.5.3.9 November 11, 1988 22 4.5.3.10 October 9, 1989 22 4.5.3.11 January 24, 1990 22 4.5.3.12 January 20, 1991 22 4.5.3.13 Current Site Conditions 22 4.5.4 Results of Review of WeU Records 22 5.0 CONCLUSIONS ,. 24 5.1 General 24 5.2 Geology 24 5.2.1 Stratigraphy 24 5.2.2 SoU Quality 24 5.2.2.1 VolatUe Organic Compoimds in SoU 24 5.2.2.2 SemivolatUe Organic Compounds in SoU 25 5:2.2.3 Pesticides and PCBs in SoU 25 5.2.2.4 Metals in SoU 25 5.3 Groundwater 26 5.3.1 Groundwater Flow 26 5.3.2 Groimdwater Quality 26 5.3.2.1 VolatUe Organic Compounds in Groundwater 26 5.3.2.2 SemivolatUe Orgaruc Compounds in Groundwater 26 5.3.2.3 Pesticides and PCBs in Groundwater 27 5.3.2.4 Metals in Groundwater 27 6.0 RECOMMENDATIONS 29 7.0 ACRONYMS AND ABBREVIATIONS 30 8.0 REFERENCES 31 TABLES 1-1 Areas of Potential Environmental Concern 2-1 Samples Submitted for Laboratory Analysis 2-1 Well Construction and Development DetaUs 4-1 SoU Sample PID Readings 4-2 SoU Sample Analytical Results - VolatUe Organic Compounds 4-3 SoU Sample Anal3rtical Results - SemivolatUe Organic Compounds 4-4 SoU Sample Analytical Resuhs - Pesticides and PCBs 4-5 SoU Sample Analytical Results - Inorgarucs '3 n O ' ^ T ^ 4-6 Groundwater Elevations J V A . \WORDPROC\29872\DSRoi.REP August 14.1995 4:38pni Harding Lawson Associates ii 4-7 Groundwater Sampling Field Analytical Results 4-8 Groimdwater Sample Anal)rtical Results - VolatUe Orgaiuc Compoimds 4-9 Groundwater Sample Analytical Results - Semi-Volatile Organic Compounds 4-10 Groundwater Sample Analytical Results - Total Inorganics 4-11 Groundwater Sample Analytical Results - Dissolved Metals 4-12 Groundwater Sainple Analytical Results - Pesticides and PCBs 4-13 Production WeUs Witiun Three MUes of Site 5-1 Parameters Detected tnd AKARS/- SoU Samples 5-2 SoU Concentration Comparisons for Selected Metals 5-3 Parameters Detected and ARARs - Groundwater Samples FIGURES 1-1 Site Location Map 1-2 Site Map 1-3 Regional Geological Map 1-4 Areas of Potential Concern 2-1 SoU Boring Locations 2-2 WeU Locations 4-1 Generalized Geological Fence Diagram 4-2 Groundwater Contour Map - February 14, 1995 4-3 Groundwater Contour Map - May 8, 1995 4-4 Groundwater Contour Map - May 9, 1995 4-5 Groundwater Contour Map - May 10, 1995 4-6 Groundwater Contour Map - May 11, 1995 4-7 Surrounding FacUities Map APPENDIXES A Groundwater Sampling Forms B Field QuaUty Assurance Audit Reports C Data VaUdation Package - Potable Water Samples D Data VaUdation Package - SoU Samples E Data Validation Package - February Groundwater Sampling F Data Validation Package - May 1995 Groundwater Sampling G DrUling Logs H Well Completion Forms I Water Level Measurement Forms J Historical Aerial Photographs K WeU Records L Phase I Baseline Ecological Assessment DISTRIBUTION Last Page of Document 302374 \WORDPROC\29872\DSRoi.REP August 14,1995 4:38pm Harding Lawson Associates iii 1.0 BACKGROUND 1.1 Introduction This Data Summary Report (DSR) has been prepared by Harding Lawson Associates (HLA) to document activities associated vidth the investigation of the Virgin Island Chemical Site (site) located in St. Croix, U.S. Virgin Islands. This report has been prepared in accordance with the requirements specified in Section VIII of the Administrative Order on Consent (Order) for this project effective October 6, 1994 (EPA Index No. U CERCLA-94-0401). As required by the Order, this DSR includes the foUovring: Validated data in an electronic format Summary of quaUty assurance/quaUty control (QA/QC) issues Summary of the interpretation of the data Maps shovdng sampling locations Tabulated data This report also summarizes the results to date of implementation of the foUowing tasks of the approved Project Work Plan: / • Potable Water Sampling - /' Site Clearing and Reconnaissance SoU Sampling Program Groundwater Monitoring WeU InstaUation RehabUitation of Existing Wells Surveying Well Locations and Elevations Groundwater Morutoring and SampUng Data Validation Data Evaluation 1.2 Objectives The objectives of the Remedial Investigation (Rl) of this site are: • To evaluate whether onsite conditions pose a cause for environmental concem • To evaluate whether potential source areas not previously identified are present onsite • To identify potential contaminant pathways o n 9 "^ 7 R \WOROPROC\2g872\DSRoi.REP August 14,1995 2:23pm Harding Lawson Associates ' 1 • To assess the possible presence of a shaUow clay layer reported by others • To determine the horizontal direction of shallow groundwater flow • To generate data of sufficient quality: (1) to be compared to identified applicable or relevant and appropriate requirements (ARARs); (2) to be used to develop a baseline human health and/or ecological risk assessment, U necessary; and (3) to be used to develop a feasibihty study, if necessary. 1.3 Site Description 1.3.1 Site Location The site occupies approximately three acres in south central St. Croix, U.S. Virgin Islands (Figure 1-1). The site is located on Melvin Evans Highway (Route 66), approximately 1,500 feet north of the Alexander HamUton Airport. The property is located on Plot 13Q of Estate Bethlehem Middle Works at 17°42'35" north latitude, 64°47'26" west longitude. The site is bordered to the northeast and southeast by an intermittent stream identified as River Gut. It is bordered to the west by an undeveloped lot and to the southwest by Route 66. A concrete batch plant, an asphalt paving company, and two automobUe repair shops are located to the east of the Site, across River Gut. FacUities surrounding the site are discussed in Section 4.5.2. 1.3.2 Site Structures The facUity is abandoned. The current layout of the facUity is shown in Figure 1-2. Major onsite structures include the foUovnng: Laboratory and Warehouse BuUding "Maintenance BuUding Aboveground Storage Tank (AST) Farm Concrete Pads Adjacent to AST Farm (Former AST locations) Loading Dock Concrete Storage Pad Centrifuge and Dryer BuUding Reactor Process Area Former Process Pit (filled during previous work at this site) Generator BuUding Pump BuUding 250,000-Gallon FUe Water AST 302376 \WORDPROC\29872\DSR01.REP August 14.1995 2;23pm Harding Lawson Associates 1.3.3 Site Setting The site is located in a valley. Surface elevations at the site range from approximately 30 to 40 feet above mean sea level (MSL). Land to the southwest (approximately 200 feet) and to the east (approximately 1,000 feet) of the site slopes steeply upward to roughly 150 to 200 feet above MSL. The surface slopes gentiy across the site from southwest to northeast. Ground surface just beyond the northem and eastern fence lines slopes steeply downward approximately 12 to 15 feet into the gut. An earthen berm partiaUy separates the AST farm in the westem part of the facUity from the remainder of the site. On the western side of the berm, runoff drains from southwest to northeast. Surface drainage on the eastern portion of the site is controUed by the buUdings, concrete paved areas, and two storm drains that channel runoff to the gut along the southeastern site boundary which drains to the Caribbean Sea, approximately 4,500 feet to the south. Flow in River Gut is intermittent and generaUy only occurs during the rainy season, between September and December. SoUs beneath the site consist of alluvium. The geology and hydrogeology of St. Croix were discussed in the Project Work Plan. Results of the site-specific hydrogeological investigation are discussed in Section 4.1. Figure 1-3 presents a generalized geologic map of the island. 1.4 Areas of Potential Environmental Concern The followdng areas of potential environmental concem were identified through the work performed prior to and during this investigation. These areas are identified as: Area A - Laboratory and Warehouse BuUding Area B - Aboveground Storage Tank Farm Area C - Former Process Pit Area D - Loading Dock and Former Lab Pit Area Area E - SoU Beneath Concrete Pad Near ASTs Area F - Concrete Storage Pad Locations of the areas of potential concem are showm in Figure 1-4. Descriptions of these areas are summarized in Table 1-1. 302377 \WORDPROC\29872\DSRoi.REP August 14,1995 2:23pm Harding Lawson Associates 2.0 SCOPE OF WORK 2.1 Potable Water Sampling and Preliminary Reconnaissance On November 4, 1994, HLA collected potable water samples from the two cisterns planned to be used for equipment decontamination water during this project. Sample PT-1/110494 was coUected from the cistern at the Caribbean Hydro-Tech (CHT) faciUty, the drilUng company used during the project. Sample PT-2/110494 and a duplicate sample PT-102/110494 were taken from the onsUe cistern. The water and quality control samples were submitted to PACE Enviromnental Laboratories, Inc. (PACE) in St. Rose, Louisiana, for analysis of Target Compound List (TCL) volatUe orgaruc compounds (VOCs), TCL semivolatile organic compounds (SVOCs), TCL pesticides and polychlorinated biphenyls (PCBs), Target Analyte List (TAL) inorgarucs, and pyridine. Laboratory results indicated that, with the exception of estimated concentrations of bis(2-ethylhexyl) phthalate below the method detection limit (MDL), no TCL VOCs, SVOCs, pesticides, PCBs, or pyridine were detected in the samples. Several metals were detected in samples from both cisterns. In general, metals concentrations were higher in the dupUcate sample from the onsite cistern than in the sample from the CHT cistern. Based on these results, water obtained from the CHT cistern was used during this project. 2.2 Site Clearing and Reconnaissance HLA performed an initial site inspection on July 2, 1993, prior to development of the Project Work Plan. A second site inspection was performed in conjunction with the potable water sampUng on November 4 and 5, 1994. / After receipt of requested permits from the St. Croix Department of PubUc Works (DPW), site clearing activities were performed between January 9 and 12, 1995. Vegetation at the site was cut by Christian Heavy Equipment Rental, Inc. (CHERI). An HLA geologist supervised the cutting activities. Vegetation was cut to ground level and pushed into several pUes onsite using a bulldozer. Site clearing activities were observed by representatives of the DPW. On January 13, 1995, HLA conducted a third site inspection as specified in Section 5.4 of the Project Work Plan. HLA performed a fourth site inspection between AprU 10 through 12, 1995, during the ecological evaluation. 2.3 Field Sampling Program 2.3.1 Soil Sampling Program Eleven soU borings were completed at the site. SoU boring locations are shown in Figure 2-1. The borings were drUled and sampled following the procedures described in the Project Work Plan. The borings were advanced using hollow-stem auger driUing tectmiques by CHT. DrUling activities began on Wednesday, January 18, 1995. On this date, a decontamination area was estabUshed and soil boring SBEl was drUled and sampled. SoU samples were collected, described, and screened for organic vapors following the procedures described in the Project Work Plan. A representative, of CDM Federal Programs Corporation (CDM), observed field activities on behalf of the U.S. Environmental Agency (EPA). At the request of CDM, a split-sample was coUected from soU boring SBDl from the 22- to 24-foot depth interval and provided to the CDM representative. The spUt- sample was created follovidng the procedures described in the Project Work Plan. ? 0 2 3 7 8 WORDPROC\29872\DSRoi.REP August 14,1995 2:23pm Harding Lawson Associates 4 Durmg instaUation of boring SBCl, located adjacent to the Former Process Pit, a layer of relatively low permeabUity was encountered above the water table. The layer was at least 4 feet thick. WeU MW-2 was originaUy plarmed to be instaUed at this location. HLA raised concems to EPA that puncturing the low permeabUity layer for the purposes of weU instaUation might provide a conduit for contaminants, U present in this area, to reach the groundwater. With the approval of EPA, the decision was made to forgo installation of this weU. Because the weU was not installed at this location, a fourth soU sample was coUected from the boring to provide additional data on soU quaUty. SoU samples were obtained using a split-spoon sampUng device as described in the Project Work Plan. SoU borings SBBl, SBCl, SBC2, SBDl, SBD4, SBFl, SBF2, and SBF3 were sampled continuously to completion depth at the water table. SoU borings SBD2 and SBD3 were sampled continuously to 10 feet below grade and continuously from 15 feet below grade to the water table. SoU boring SBEl was sampled continuously to 10 feet below grade, at 15 feet below grade, and continuously from 20 feet below grade to the water table. The borings were terminated when groundwater was encountered; this; occurred at depths ranging from 20 to 27 feet below grade in the borings. A portion of material from each split-spoon sample was placed in a plastic bag and screened in the field for relative orgaruc vapor concentrations using a photo-ionization detector (PUD). Sample material collected for laboratory analysis of VOCs was not subjected to field screening. Field screening results are discussed in Section 4.2.1. Generally, samples coUected at the surface, at an intermediate depth interval, and above the water table were submitted for laboratory analysis. The intermediate depth interval was selected based on relative organic vapor concentrations and/or visible evidence of contamination. If none of the samples from a given boring exhibited detectable organic vapors or visible evidence of contamination, the intermediate depth sample was coUected immediately above the first layer of relatively low permeabUity encountered. Intermediate depth samples were not collected from borings SBD2, SBD3, and SBEl because no evidence of contamination or a layer of relatively low permeabiUty was encountered prior to deep sample coUection above the water table. Samples coUected for laboratory analysis are identified in Table 2-1. A layer of relatively low permeabUity was encountered at approximately 15 to 15.5 feet below grade in borings SBFl and SBF3. Intermediate depth samples were coUected for VOC analysis from the 14- to 15.5-foot interval in these borings. Because there was insufficient recovery for analysis of the remaining parameters, recovery from the 12- to 14-foot interval was composited wiih the remaining sample material and submitted for analysis. This change in scope was approved by EPA. As noted above, a layer of relatively low permeabUity was encountered at approximately 20 to 20.5 below grade in boring SBCl. Intermediate depth soU samples were coUected from the 16- to 18-foot and 18- to 20-foot depth interval to provide additional data on soU quality. The soU samples were shipped to PACE for the analyses specUied in the Project Work Plan. The soU samples were analyzed for the followdng parameters: • TCL VOCs • TCL SVOCs and pyridine • TCL Pesticides and PCBs • TAL Inorganics On Thursday, January 19, HLA attempted to ship samples collected from boring SBEl on Wednesday, January 18 and Thursday January 19. Although PACE had obtained an extension from the U.S. Department of Agriculture (USDA) in Maryland on its permit to import soUs, Federal Express refused to ship the samples off St. Croix untU the local office of the USDA authorized the company to do so. \WORDPROC\29872\DSR0l.REP August 14,1995 2:23pm Harding Lawson Associates o n i o n o 3 V z J / y The local USDA office did not provide authorization untU Friday, January 20, 1995, at which time samples coUected from SBEl on January 18 and 19 and samples coUected from SBD2 on January 19 were shipped to the laboratory via Federal Express. The samples were not deUvered to PACE untU Monday, January 23, due to a delay by Federal Express. Upon receipt, the laboratory found the temperature of tiie samples from SBD2 to be greater than 18 degrees Centigrade (°C). This issue was discussed wdth EPA on February 1. Although the appropriate permits were in place, samples coUected from SBFl and the surface sample collected from SBF2 on January 23, 1995, were held by U.S. Customs in Tennessee. The samples were not released to the laboratory untU Monday, January 30. Upon receipt, the laboratory measured the sample temperatures at greater than 19 degrees °C. Therefore, the decision was made to redriU and resample the affected borings and to coUect another surface sample. Replacement boring SBFlA was driUed on February 3, 1995, and samples were coUected, along with a replacement surface sample, SBF2A. The samples were sent to the laboratory via U.S. Postal Service Express MaU on the same day. Although the samples were sent for next day delivery, the laboratory did not receive the samples untU Monday, February 6. Again the samples arrived at the laboratory at elevated temperatures. Because no evidence of organic vapors had been detected in the soU samples and because the integrity of the organic fractions had been jeopardized, the samples were analyzed for inorganic parameters oiUy. These changes in scope were approved by the EPA. 2.3.2 Groundwater Monitoring Well Installation Monitoring well locations are shown on Figure 2-2. Four of the five wells described in the Project Work Plan were instaUed. As noted previously, boring SBCl was not completed as groundwater monitoring well MW-2. The remaining four weUs were instaUed, constructed, and developed in accordance with the procedures described in the Project Work Plan for single cased monitoring wells. Well construction detaUs and observations recorded during development are summarized in Table 2-2. Well MW-1 was instaUed near AST 9 on the westem portion of the site. The pUot boring for this weU was advanced on January 31, 1995. On February 3, 1995, the pUot boring was overdrUled and the well was constructed. The well screen was set from 23 to 33 feet below grade. The weU was developed using a submersible pump. Well MW-3 was installed near the eastern site boundary to the north of the central storm drain. The pUot boring for this weU was advanced on January 30, 1995. On February 2, 1995, the pUot boring was overdrUled and the well was constructed. The well was screened from approximately 18.5 to 28.5 feet below grade and developed using a submersible pump. Well MW-4 was installed to the north of the laboratory buUding in the area of the former Lab Pit. The pUot boring for this well was advanced on January 25, 1995. On January 26, 1995, the pUot boring was overdrUled and the well was constructed. It was screened from approximately 18 to 28 feet below grade and developed using a baUer and submersible pump. Well MW-5 was installed near the northeastem corner of the site. The pUot boring for the well was advanced on January 27, 1995. On February 1, 1995, the pUot boring was overdrUled and the well was constructed. It was screened from approximately 17.5 to 27.5 feet below grade and developed using a submersible pump. 2.3.3 Rehabilitation of Existing Wells The two existing production wells (P-1, and P-2) were modified in February 1995 to facUitate access and provide security. This included removal of the pump from P-1 and patch-welding the steel casing of P-2. A locking protective steel casing cap was installed at the top of each well. Water-tight plugs could not be placed at the tops of the wells because the wells do not contain irmer casings. The \WORDPROC\29872\DSRoi.REP August 14,1995 4:42pm Harding Lawson Associates 6 302380 production weUs were redeveloped on February 10, 1995 foUowing the procedures described in Project Work Plan. The bottoms of the wells were sounded using a weighted, decontaminated tape measure. The weUs were found to be 98 (P-1) and 96 (P-2) feet deep. Because the wells were found to be substantiaUy deeper than the morutoring weUs and information regarding the construction and integrity of the weUs is not avaUable, the two production wells were not used for groundwater sampUng. 2.3.4 Well Survey The latitude, longitude, and elevations of the two existing production wells and the four new morutoring weUs were surveyed by a licensed surveyor. Elevations surveyed include the inner, outer, and ground elevations with respect to MSL. The locations of the inner casing elevation measurements of the four new monitoring wells were marked for future water level measurements. 2.3.5 G r o u n d w a t e r Monitoring a n d Sampling 2.3.5.1 W a t e r Level Monitoring HLA performed the initial round of water level measurements on Tuesday, February 14, just prior to beginning the initial round of groundwater sampling. During this process, HLA opened the four monitoring weUs and two production weUs onsite. Relative organic vapor concentiations were monitored at each weU head using a PID. PID readings were taken upwdnd of each weU, at the top of each weU head, and just inside the top of each inner weU casing. Water levels were measured in each well using an oU/water interface probe. The probe was calibrated against a steel surveyor's tape in the field before use. No discrepancies between the probe and the steel tape were noted. Water levels were measured with respect to survey marks at the top of the inner casing in each weU. Water levels in the four monitoring wells were gatiged on February 10. Four rounds of depth-to-water measurements were taken during groundwater sampling activities between May 8 and May 11, 1995. Water levels were measured using a field-caUbrated electric water level indicator. A heavy rainstorm occurred on May 9. Data for M a y ^ a n d 9 xapiesent conditions - prior to the storm and data for May 10 and 11 represent conditions after the storm. The surveyed well elevations and the depth-to-water measurements were used to calculate groundwater elevations. 2.3.5.2 First Round of G r o u n d w a t e r Sampling HLA collected groundwater samples from the four new morutoring weUs on February 14, 15, and 16, 1995. Groundwater samples were collected foUowdng the procedures described in the Project Work Plan. The wells were purged using field-decontaminated PVC bailers and sampled using dedicated Teflon™ baUers. Approval to use the PVC baUers for purging was granted by the EPA Remedial Project Manager whUe onsite. DetaUs regarding the purging and sampling of each well were recorded on groundwater sampling forms, which are included in Appendix A. The groundwater samples were shipped to PACE for the analyses specified in the Project Work Plan. The samples were analyzed for the following parameters: TCL VOCs TCL SVOCs TCL Pesticides TCL PCBs TAL hiorganics 3 0 2 3 8 1 \WORDPROC\29872\DSR0i.REP August 14.1995 2:23pm Harding Lawson Associates 7 • Pyridine Both field-fUtered and unfUtered samples were analyzed for TAL metals. 2.3.5.3 Quarterly Groundwater Sampling HLA coUected the second set of groundwater samples from the site on May 9, 10, and 11, 1995. During this event, the wells were purged using dedicated PVC baUers. The groundwater samples were collected, handled, and analyzed following the same procedures as those used for the initial groundwater sampling event. The groundwater samples from the second round were received by the laboratory on May 12, 1995. Sample deUvery was delayed due to flooding in New Orleans. 2.4 Data Validation All laboratory data were validated as described in the Quality Assurance Project Plan (QAPP). 2.5 Background Investigation 2.5.1 Identification of Surrounding Facilities and Database Review HLA performed a records review and a reconnaissance of the area to identify other facUities wdthin one quarter mUe of the site. The records review included a database search through Environmental Data Resources, Inc. (EDR). The database search included the identification of facUities wdthin the same zip code as the site. The commercial database search companies contacted were unable to provide information on facihties within a given distance fi-om the site. The EDR report included searches of the foUowdng databases: National Priorities List (NPL)' Resource Conservation and Recovery Information System - Transfer, Storage, and Disposal (RCRIS-TSDJ. State Hazardous Waste Sites Comprehensive Environmental Response, Compensation, and LiabUity Information System (CERCUS) State LandfiUs Leaking Underground Storage Tank Sites (LUST) Underground Storage Tank Sites (UST) Resource Administrative Action Tracking System (RAATS) - Resource Conservation Recovery Act (RCRA) RCRIS Small Quantity Generators RCRIS Large Quantity Generators Hazardous Material Incident Report System (HMIRS) PCB Activity Data Base (PADS) Emergency Response NotUication System (ERNS) FacUities Index System (FINDS) Toxic Release Inventory System (TRIS) NPL Liens Toxic Substance Source Act (TSCA) 2.5.2 Re^ew of Historical Aerial Photographs To find avaUable historical aerial photographs, HLA contacted the United States Department of the Interior (USDI), National Ocean Services (NOS), Cine Photo Services, and Aerial Viewrpoint located in the United States and Puerto Rico. At the time the Project Work Plan was submitted to EPA, HLA had located 14 aerial photographs for the site from two sources, the USDI and In terra Photographic Services (now Aerial Viewpoint). 3 0 2 3 8 2 WORDPROC\29872\DSRoi.R£P August 14,1995 2:23pm Harding Lawson Associates 8 After the Project Work Plan was submitted, HLA located nine more aerial photographs from two additional sources: NOS and Cine Photo Services. No other sources of aerial photographs providing coverage of the site were identified. The foUowing list presents the aerial photographs obtained and reviewed by HLA. DATE SOURCE February 15, 1954 USDI AprU 20, 1959 NOS 1962' Aerial Viewpomt February 20, 1964 NOS February 17, 1971 Cine Photo November 20, 1971 NOS January 17, 1974 USDI December 11, 1976 NOS November 14, 1977 NOS December 1, 1984 NOS November 24, 1988 NOS October 9, 1989 Cine Photo January 24, 1990 USDI January 20, 1991 USDI WhUe 23 aerial photographs were purchased, orUy the 12 photographs listed above were used for the site evaluation. The remaining 9 aerial photographs were not used because the site was obscured by cloud cover. 2.5.3 Review of Well R e c o r d s There is no centralized source for information regarding weUs located on St. Croix. Information on surrounding wells was compUed from a variety of sources including the documents entitied Water WeUs on St., Croix, U.S. Virgin Islands (USGS, 1994), Report on Current Groundwater Conditions in the U.S. Virgin Islands, (Geraghty and MiUer, 1983), Potentiometric Surface ofthe Kingshill Aquifer and Hydrologic Conditions, St. Croix, U.S. Virgin Islands (Torres-Gonzalez, 1990), and discussions wdth the Virgin Islands Port Authority (VIPA) and Water and Power Authority (WAPA) as well as several inspections of the surrounding area performed by HLA. Little or no information is avaUable for most of the weUs identUied. 'Exact date not avaUable 3 0 2 3 8 3 \WORDPROC\29872\DSRoi.REP August 14,1995 2:23pm Harding Lawson Associates 9 3.0 QUALITY ASSURANCE/QUALITY CONTROL 3.1 Field Quality Assurance/Quality Control Two field QuaUty Assurance (QA) audits were performed in accordance wdth the requirements of the Order and the project QAPP. The purpose of the audits was to evaluate the groundwater sampling program, including: sample identification; sample contiol; chain-of-custody procedures; field documentation; and sampling operations, handling, and packaging procedures. Results of the field audits were reported to EPA. Copies of the field audit reports are included in Appendix B. The first field QA audit was performed on February 14 and 15, 1995. Results of the audit indicated a number of deficiencies in the manner in which the field crew recorded pertinent data. Although the data were recorded, they were not necessarily recorded on the forms selected for this project. Because all of the necessary information was recorded, the deficiencies did not affect the quaUty of the samples or the objectives of the project. The second audit was performed during groundwater sampling activities on May 10, 1995. Findings of the second audit indicated that the deficiencies noted during the first audit had been corrected. 3.2 Analytical Data Validation 3.2.1 November 1994 Potable Water Samples All of the data for the November 1994 potable water sampling event were foimd to be acceptable for use as qualified. Results of the data VaUdation for these samples are included in Appendix C. The , following principal qualifications were noted: •' " A • The relative 'standard deviations (%RSD) for some VOCs in the initial cahbration results did not meet the Unearity criterion. In addition, the relative response factors for some VOCs did not meet the minimum criterion. Therefore, the positive results for some VOCs were qualified as estimated, whUe the non-detected results for some VOCs were qualified as unusable. • The continuing caUbration results for some VOCs did not meet the acceptance criteria for percent difference and/or minimum relative response factor. Therefore, the positive results for some VOCs were qualified as estimated and the non-detected results for some VOCs were qualified as either estimated or unusable. • ' Because the method blank contained a compound also detected in the associated investigative samples, some SVOC positive results were qualified as non-detected. • Due to matrix spUce recoveries falling outside the acceptance criteria, serial dUution resvUts outside acceptance criteria or Graphite Furnace Atomic Absorption (GFAA) analytical spike recoveries outside the acceptance criteria some metals results were qualified as estimated. • The reported results for pyridine in the investigative samples were qualified as estimated because a visual comparison of the peak acquisition was not possible. 302384 \WORDPROC\29872\DSRoi.REP August 14,1995 2;23pm Harding Lawson Associates 10 3.2.2 Soil Samples All of the soUs data were found to be acceptable for use as qualified. Results of the data vaUdation for these samples are included in Appendix D. The followdng principal qualifications were noted: • Because of problems noted in initial caUbration, detected results for numerous compoimds were qualified as estimated and non-detected results in several samples were qualified as estimated or rejected. • Detections of acetone, chlorobenzene methylene chloride tolune and total exylenes in a niunber of blank samples were qualified as undetected in nimierous investigative samples because of laboratory blank contamination, or were qualified as estimated because of problems noted in initial and continuing caUbration. • For a number of blank samples, results for bis(2-ethylhexyl)phthalate in several investigative samples were qualified as undetected, and non-detected results were rejected and detected results estimated for acetone, 2-butanone, and 2-hexane because of problems noted in both the initial calibration and continuing caUbration. • Because of problems noted in the GFAA analysis, and with spike recoveries, the detections of antimony, selenium, cyanide, cadmium, lead, vanadium, thalUum, and arsenic in several of the investigative samples were quahfied as estimated. • Sample SBD3/0-2 was re-analyzed due to intemal standard problems. However, because the sample was re-analyzed 41 days past sampling date, or 27 days past holding time, the results of the re-analyses were all qualified as estimated. Therefore, the results pf the original analyses are reported. 3.2.3 February 1995 Groundwater Samples All of the data were'found to be acceptable for use as qualified. Results of the data vaUdation for these samples are included in Appendix E. The foUowdng principal qualifications were noted: • Because of problems noted in continuing caUbration, surrogate recoveries, and/or several compounds in a number of samples, were estimated or rejected. • The results for BHC and pyridine in the investigative samples were qualified as estimated. • Because of calibration problems and preparation blank contamination, arsenic, beryUium, and lead were qualified as undetected in several samples. • Because of problems noted in matrix spike recoveries antimony, selenium, sUver and a number of analytes in several samples were qualUied as estimated or rejected. • Because of problems noted in the post digestion and noted in the Inductively Coupled Plasma (ICP) serial dUutions, a number of analytes in several samples were qualified as estimated. 302385 \WORDPROC\29872\DSR0i.REP August 14,1995 2:23pm Harding Lawson Associates 11 4.0 RESULTS 4.1 Geology Drilling data generated during the soU boring and monitoring weU instaUation program were used to prepare a generaUzed geologic fence diagram for the site (Figure 4-1). The locations of soU borings and the lines of cross-section are shown on Figure 2-1. HLA drilling logs and weU completion forms are included in Appendix G and H, respectively. The stratigraphy beneath the site appears to be consistent wdth the aUuvial deposits described previously by the U.S. Geological Survey (USGS) and others. Boring logs indicate the site is underlain by at least 25 feet of sandy clay and sUty clay with lenses of graveUy sand and sUty sand. GeneraUy, the layers appear to be discontinuous. The lowermost layer encountered is a sUty sand that appears to be continuous across the site. The top of this layer was encountered at depths ranging from 24 to 33 feet below grade. 4.2 Soil Quality 4.2.1 Organic Vapor Readings During the soU boring program, a PID was used to screen soU samples in the field for relative organic vapor concentrations. Results pf the PUD screenings are summarized in Table 4-1. Orgaruc vapors were detected in the soU samples from 1 of the 11 borings. Organic vapors were not detected in any of the soU samples from the remaining 10 borings. 4.2.2 Soil Sample Analytical Results Thirty soU samples and one field duplicate were submitted for laboratory analysis during this investigation. Sample locations and depths were discussed in Section 2.3.1. Analytical results are summarized in the foUowdng tables: • Table 4-2 - SoU Sample Analytical ResiUts - VolatUe Organic Compounds • Table 4-3 - SoU Sample Analytical Results - Semivolatile Organic Compounds • Table 4-4 - SoU Sample Analytical Results - Pesticides and PCBs • Table 4-5 - SoU Sample Analytical Results - Inorganics Twenty six of the soU samples and the dupUcate sample were analyzed for TCL VOCs, SVOCs, pesticides, and PCBs. All of the soU samples were analyzed for TAL Inorgarucs. 4.2.2.1 Volatile Organic Compounds in Soil Six TCL VOCs were detected in soU samples from the site. These VOCs and the samples in which they were detected are summarized below: Acetone SBBl/6-8; SBDl/12-14 Carbon disulfide SBDl/0-1; SBD2 (both samples) Ethylbenzene SBBl/0-1 (and dupUcate); SBBl/6-8 Toluene SBBl/6-8; SBCl (aU four samples); SBD4 (aU tiiree samples) Trichloroetiiene SBEl/0-2 Xylenes SBBl (aU four samples and duplicate); SBC2 (aU three samples); SBD4/0-1; SBD4/14-16 3 0 2 3 8 6 \WORDPROC\29872\DSRoi.REP August 14,1995 2:23pm Harding L^wson Associates 12 With the exception of ethylbenzene, toluene, and xylene in Sample SBBl/6-8, the VOC concentrations were relatively low. Most of the results were near or below the analjdical MDL. 4.2.2.2 Semivolatile Organic Compounds in Soil Five TCL SVOCs were detected in the soU samples. These SVOCs and the samples in which they were detected are summarized below: • Bis(2-etiiylhexyl)phthalate SBBl/6-8; SBCl (aU four samples); SBC2 (aU tiiree samples); SBDl {aU three samples) SBD2/19-21; SBD4 (aU three samples); SBF2 (both samples); SBF3/0-1 (aU three samples) • Butylbenzyl phthalate SBC2/0-1; SBF3/0-1 • Di-n-butyl phtiialate SBC2/0-1; SBC2/20-22; SBC2/24-26; SBD2/19-21; SBD4/0-1; SBD4/20-22 • Di-n-octyl phthalate SBD3/0-2 • Pentachlorophenol SBF3/0-1 Generally the four phthalates were detected near or below the MDL in the soU samples. . Pentachlorophenol was detected in only one sample, at an estimated concentration below the MDL. 4.2.2.3 Pesticides and PCBs in Soii Six TCL Pesticides were detected in the soU samples; no PCBs were detected in the soU samples. The pesticides and the samples in which they were detected are summarized below: /-BHC SBD4/20-22 a-Chlordane SBDl/0-1; SBEl/0-2; SBEl/0-2; SBF3/0-1 K-Chlordane SBEl/0-1 Endrin SBF3/0-1 Endrin aldehyde SBC2/0-1; SBF3/0-1 Endosulfan n SBEl/0-2; SBF3/0-1 With the exception of j'-BHC in SBD4/20-22, aU of the pesticides detected were identified in surface soU samples. 4.2.2.4 Inorganics in Soii Thirty-one soU samples were analyzed for cyarude and TAL metals. Cyanide was not detected in any of the samples. Of the 23 TAL metals analyzed, 20 were detected in the soU samples. Selenium, sUver, and thalUum were not detected in any of the soU samples. The foUowdng 15 TAL metals were detected in aU of the soU samples analyzed: Aluminum Cobalt Nickel Barium Copper Potassium Cadmium Iron Sodium Calcium Magnesium Vanadium Chromium Manganese Zinc The frequency of detection for the remaining five inorganics is as follows: • Antimony was detected in 10 of the 31 soU samples. • Arsenic was detected in 4 of the 31 soU samples. • BerylUum was detected in 27 of the 31 soU samples and in the dupUcate sample. • Lead was detected in 24 of the 31 soU samples and in the duplicate sample. 302387 \WORDPROC\29872\DSR0i.REP August 14,1995 2:23pm Harding Lawson Associates 13 • Mercury was detected in 23 of the 31 soU samples. Although mercury was detected in Sample SBBl/0-1, it was not detected in the dupUcate sample coUected at this location. 4.3 Groundwater Flow As noted in Section 2.3.5.1, HLA measured depth to water in the monitoring weUs once during the irutial sampling event in February 1995 and four times during the groundwater sampling event in May 1995. During water level gauging activities no sheen or separate phase liquids were observed. Depth to water in the four morutoring wells ranged from 20.58 (MW-5, May 10) to 27.18 feet (MW-1, February 8). Copies of water level measurement forms are included in Appendix 1. These depths are near the top of the lower sUty sand layer identified in Section 4.1. Depth-to-water measurements, calculated groundwater elevations, and PID readings are summarized on Table 4-6. Data from the four groundwater monitoring wells were used to prepare groundwater contour maps (Figures 4-2 through 4-6). The two production wells, identified as P-1 and P-2, are much deeper than the four morutoring weUs and no information is avaUable regarding construction of these wells. Therefore, calculated groundwater elevations for the two production weUs were not used to constiuct the contour maps. The map prepared for February 1995 shows groundwater flow to the north and a hydrauUc gradient of approximately 0.005. WhUe minor precipitation occurred daUy, no significant precipitation events were noted during the week prior to the date for which this map was prepared. The maps prepared for May 8 and 9, 1995, are based on data coUected during a dry period. The total rainfall during the 24-houT period preceding these water level gaging rounds was 0.10 and 0.00 inches, respectively, measured at the Alexander HamUton Airport. Measurements of 0.84 and 0.00 inches were collected for the same two 24-hour periods at the Urdversity of the Virgin Islands in Bethlehem Upper Works. The maps prepared for May 8 and 9 show groimdwater flow to the east-northeast and a hydraulic gradient of 0.001 to 0.002. The maps prepared for May 10 and 11, 1995, are based on data coUected after a significant precipitation event during the afternoon of May 9. Standing water and flowdng water were observed onsite during the rain storm. The total rainfaU during the 24-hour period preceding the May 10 water level gaging round (including the rain storm of the afternoon of May 9) was measured at the airport as 1.85 inches and at the University as 1.84 inches. The maps prepared for May 10 and May 11 show groundwater flow to the w.est and.northwest, nearly opposite of the flow direction prior to the rain storm. The calculated hydraulic gradient for these two dates is approximately 0.02, approximately 10 times greater than the gradient prior to the rain storm. 4.4 G r o u n d w a t e r Quality The initial set of groundwater samples was coUected in February 1995. The second set of groundwater samples was collected in May 1995. Results of the field and laboratory analyses for both sets of groundwater samples are summarized on the foUowing tables: 302388 WORDPROC\29872\DSRoi.R£P August 14, 1995 2:23pm Harding L^wson Associates 14 Table 4-7 - Groundwater Sampling Field Analytical Results Table 4-8 - Groundwater Sample Analytical Results - VolatUe Organic Compounds Table 4-9 - Groundwater Sample Anal)dical Results - Semivolatile Organic Compounds Table 4-10 - Groundwater Sample Analytical Results - Total Inorganics Table 4-11 - Groundwater Sample Analytical Results - Dissolved Metals Table 4-12 - Groundwater Sample Analytical Results - Pesticides and PCBs 4.4.1 Volatile Organic C o m p o u n d s in G r o u n d w a t e r The following six TCL VOCs were detected in groundwater samples from the site: Acetone Chloromethane Ethylbenzene Methylene chloride Toluene Xylenes Acetone was detected in May in the sample from MW-3 at an estimated concentration of 42 micrograms per Uter (//g/L). Acetone was not detected in any of the samples coUected in February or in any of the other wells sampled in May. Chloromethane was detected in the sample and dupUcate sample coUected from MW-1 in May at a concentration of 2 //g/L. Chloromethane was not detected in any of the samples coUected in February or in any of the other wells sampled in May. Ethylbenzene was detected in the samples coUected from MW-1 in February and in May. The reported ethvlbenzene_concentiation in this weU declined from 750 //g/L in February.to 120 //g/L in May. Ethylbenzene was also detected in the sample from MW-5 coUected in February at 2 //g/L. It was not detected in the sample from MW-5 in May or in the samples from the other two monitoring wells during either 0vent. Methylene chloride was reported in samples coUected fiom two of the monitoring wells in May (MW-4 and MW-5). The results were qualUied to indicate that this substance was also present in QC samples. Toluene was detected in samples collected in February from MW-1 and MW-5 at 0.1 //g/L (estimated) and 5 //g/L (estimated), respectively. Toluene was not detected in samples from MW-2, MW-4, or in any of the samples collected in May. Xylenes were detected in the samples coUected from MW-1 in February and in May. The reported total xylenes concentration in this well declined from 2,100 //g/L in February to 3 //g/L in May. Xylenes were also detected in the sample from MW-5 collected in February (5 //g/L) and in the sample from MW-3 collected in May (0.9 //g/L, estimated). Xylenes were not detected in the sample from MW-5 in May, the sample from MW-3 tn February, or samples from MW-4 during either event. 4.4.2 Semivolatile O r g a n i c C o m p o u n d s in G r o u n d w a t e r The following six TCL SVOCs were detected in the groundwater samples: Bis(2-ethylhexyl)phthalate 4-ChloroanUine 2,4-Dimethylphenol Isophorone 4-Methylphenol 3 0 2 3 8 9 \WORDPROC\29872\DSR0l.REP August 14,1995 2:23pm Harding Lawson Associates 15 • Phenol Bis(2-ethylhexyl)phthalate was detected in samples collected in May from aU four of the monitoring wells. Reported concentrations ranged from 3 //g/L in the samples from MW-1 and MW-3 to 11 //g/L in the sample from MW-4; however, all of the bis(2-ethylhexyl)phthalate results were qualified by the laboratory to indicate the presence of this chemical in QC samples. Bis{2-ethylhexyl)phthalate was not detected in any of the samples collected in February. The SVOC 4-chloroanUine was only detected in the sample collected from MW-3 in May, at an estimated concentiation of 2 //g/L. The SVOCs 2,4-dimethylphenol, isophorone, and 4-methylphenol were only detected in the sample collected from MW-1 coUected in February at concenfrations of 30 //g/L, 0.7 //g/L (estimated), and 40 //g/L, respectively. Phenol was detected in the samples coUected from MW-3 in February and May at estimated concentrations of 1 //g/L and 0.8 //g/L, respectively. Phenol was not detected in any of the samples from the other three morutoring wells. 4.4.3 P e s t i c i d e s a n d PCBs in G r o u n d w a t e r The foUowdng 15 TCL Pesticides were detected in groundwater samples from the site; no PCBs were detected in the groundwater samples: Aldrin oc-BHC y9-BHC A-BHC I- K-BHC OC-Chlordane j'-Chlordane'' 4,4'-DDE 4,4'-DDT Endosulfan sulfate Endrin Endrin aldehyde Endrin ketone Heptachlor Heptachlor epoxide OrUy two of these pesticides were detected in the samples from the same well during both events, y Chlordane and 4,4'-DDE were detected in the samples from MW-1 during both events. y-Chlordane was also detected in the sample from MW-3 coUected in May. Ten of these pesticides were detected in only one sample from one round. Endosulfan sulfate and endrin ketone were detected oiUy in the sample from MW-1 collected in February. Endrin, }'-BHC, 4,4'-DDT, heptachlor and heptachlor epoxide were detected orUy in the sample from MW-1 coUected in May. Aldrin was detected only in the sample from MW-3 collected in February. «-chlordane and A-BHC were detected orUy in the sample from MW-3 in May. The remaining three pesticides were detected sporadically. «-BHC was detected in the samples from MW-1 and MW-3 collected in May. yff-BHC was detected in the sample from MW-1 collected in February and in the sample from MW-3 coUected in May. Endrin aldehyde was detected in the samples collected from MW-1, MW-3, and MW-5 in February. 302390 \WORDPROC\29872\DSRoi.REP August 14,1995 2:23pm Harding Lawson Associates 16 4.4.4 Metals in Groundwater The fUtered and unfiltered groundwater samples were analyzed for the 23 TAL metals. The imfUtered groimdwater samples were also analyzed for cyanide. Cyanide was not detected in any of the samples. Twenty of the TAL metals were detected in the fUtered groundwater samples; 21 were detected in the imfUtered samples. Thallium was not detected in any of the fUtered or unfiltered groundwater samples. The frequency of detection for the other 22 TAL metals is as foUows: The following six TAL metals were detected in all of the fUtered and unfUtered groundwater samples analyzed: Barium Manganese Calcium Potassium Magnesium Sodium FUtered results for these six metals were generaUy simUar to or shghtiy lower than the unfiltered results. Most of the barium and potassium data were qualified to indicate the presence of these metals in associated QC blanks. The frequency of detection of the remaining 14 metals is discussed below. Aluminum and antimony were detected in 5 of the 8 fUtered groundwater samples. These two metals were detected in the same samples. Aluminum results for all of these samples and antimony results for three of the samples were qualified to indicate the presence of these metals in the associated QC blanks. Aluminum was detected in aU of the unfiltered groundwater samples; antimony was detected in none of the unfiltered groundwater samples. Aluminum concentrations reported in the unfUtered samples were generally one to three orders of magnitude higher than the results for the fUtered samples. This suggests that the unfUtered data for aluminum reflect suspended soUds. The reason for the presence of antimony in the fUtered samples and absence of this metal from the unfUtered samples is unclear. Arsenic and beryUium were detected in fUtered groundwater samples from MW-1, MW-3, and MW-5. These two metals were detected in the same samples. Arseiuc was detected in aU but two of the unfUtered groundwater samples, and beryUium was detected in all of the unfUtered groundwater samples. The results for these two metals in all of the fUtered samples and in all but one of unfUtered samples were qualified to indicate the presence of these metals in the associated QC blanks. Arsenic and beryllium results for fUtered and unfUtered samples were generally simUar. With one exception, cadmium was not detected in any of the groundwater samples coUected. Cadmium was reported in the unfiltered sample from MW-5 coUected in February. However, this result was qualified to indicate the presence of this metal in the associated QC blanks. 302391 \WORDPROC\29872\DSR0l.REP August 14.1995 2:23pm Harding Lawson Associates 17 Chromium was detected in fUtered samples coUected from aU four of the monitoring weUs in February. Chromium was not detected in any of the filtered groundwater samples coUected in May. It was detected in unfUtered samples coUected from MW-1 and MW-3 in May and from MW-5 in February. Except for the February result for MW-5, all of the chrorruum detections were qualUied to indicate the presence of this metal in the associated QC blanks. Chromium concentrations were generaUy simUar in both the fUtered and unfiltered samples. Cobalt was not detected in any of the fUtered groundwater samples coUected during either event. Cobalt was reported in one unfiltered sample coUected in February (MW-5) and in two unfUtered samples coUected in May (MW-1 and MW-4). Both of the results for May were qualified to indicate the presence of this metal in the associated QC blanks. Copper was detected in four of the fUtered groundwater samples and in four of the unfUtered samples collected. The fUtered and unfUtered copper samples were coUected from weUs MW-3, MW-4, and MW-5 in February and from weU MW-1 in May. Reported copper concentiations were generally slightly higher in the fUtered samples than in the unfUtered samples. Iron was detected in four of the filtered groundwater samples. The fUtered iron samples were coUected from weU MW-3 in February and May, and from weUs MW-1 and MW-5 in May only. Iron was detected in aU of the unfiltered groundwater samples at concentiations ranging from just above to three orders of magrutude higher than the iron concentiations reported in the filtered samples. Lead was detected in the fUtered and unfiltered samples from aU four monitoring weUs coUected in May. Lead concentrations in the fUtered samples were generaUy sUghUy higher than in the unfUtered samples. It was detected in oiUy one of the unfiltered (MW-5) and in none of the filtered samples collected in February. Mercury was detected in the filtered samples from MW-3 collected in February and May and in the fUtered samples from MW-4 and MW-5 coUected in February. Mercury was detected in none of the unfUtered samples collected in February and in the unfUtered samples from MW-1, MW-3, and MW-4 collected in May. There was littie correlation between the mercury results reported for fUtered and unfUtered samples. Nickel was detected in both fUtered and unfiltered samples from weUs MW-3, MW-4, and MW-5 coUected in February. It was also detected in unfUtered samples from MW-1 and MW-4 coUected in May. Except for the May result for MW-5, aU of the nickel detections were qualified to indicate the presence of this metal in the associated QC blanks. Nickel concentrations reported in the fUtered and unfUtered samples were generally simUar. Seleruum and sUver were detected only one time and in one well. Both were reported in the fUtered sample and duplicate QC sample collected from MW-1 in February. Seleruum was also reported in the unfUtered sample and duplicate from MW-1 ki February. All of these results were qualified to indicate the presence of these metals in the associated QC blanks. Vanadium was detected in aU but one of the filtered groundwater samples and in all of the unfUtered groundwater samples from both sampling events. Vanadium was not detected in the fUtered groundwater sample from MW-3 collected in May. The results for all of the fUtered samples and for most of the unfUtered samples were qualUied to indicate the presence of this metal in the associated QC blanks. Vanadium concentiations reported for the fUtered samples were generally sUghtly lower than the unfUtered samples. Zinc was detected in all of the fUtered groundwater samples and in all but one of the unfUtered groundwater samples collected from both sampling events. Zinc was not detected in the sample or duplicate QC sample collected from MW-1 in February. Zinc concentrations were generaUy sligtilv.^ ^^ higher in the fUtered samples than in the unfUtered samples. 3 0 2 3 92 \WORDPROC\29872\DSRQi.REP August 14,1995 2:23pm Harding Lawson Associates 18 4.5 Site History and Potential Areas of Concern 4.5.1 Site Reconnaissance During the initial site inspection in July 1993, areas of potential concern were identUied as described in Section 1.4. During the second site inspection in November 1994, proposed boring locations were checked for accessibUity. During the third site inspection, conducted after site clearing in January 1995, HLA personnel observed evidence of contamination under a valve beneath AST No. 11. No additional areas of potential concem were identified onsite during the third site inspection. During the ecological evaluation site inspection in AprU 1995 (Appendix L), a valve beneath AST No. 5 was found to be leaking a black viscous fluid. Black stained soUs were noted beneath the valve. At that time HLA personnel tightened the valve and stopped the leak. 4.5.2 S u r r o u n d i n g Facilities HLA identified 12 facUities within one quarter mile (1,320 feet) of the site. Locations of these facihties are showm on Figure 4-7. Descriptions of each of these facihties are presented below: 1) An undeveloped lot, reportedly owmed by CHS Holding Company, borders the site to the west. This lot was recentiy subdivided and cleared. Debris from the property were apparentiy pushed into River Gut, upsfream from the Virgin Islands Chemical Site. 2) A wooded lot is located southeast of site and is overgrown wdth vegetation. One weU is located on the property. The weU was instaUed by the Virgin Islands Water and Power Authority (WAPA) and is currentiy not in use. No information is avaUable regarding the weU's construction, prior use, or reason for abandonment. 3) Charlie's Concrete Service (CharUe's) is located approximately 100 feet east of the site, across River Gut. CharUe's manufactures Redi-Mix concrete. 4) Virgin Islands Paving Company (VEPC) is located approximately 300 feet north of the site across River Gut. VIPC specializes in the instaUation of asphalt roads, driveways, and parking areas. 5) Fix-it-Right Transmission, an automobUe repair faciUty, is located approximately 400 feet northeast of the site across River Gut. The property appears to have been a former service station and may contain underground storage tanks. 6) King's Automotive (King's) is located approximately 400 feet east of the site across River Gut. Kings' currently operates as an automobUe repair and body shop. 7) Meridan Engineering is located approximately 600 feet northwest of the site. This site is Usted as a FacUity Index Site (FINDS) site, which indicates the site may appear on another regulatory list. 8) Virgin Islands Asphalt Products Company (VLAPCO) is located approximately 700 feet northwest of the site across River Gut. VIAPCO manufacturers asphalt products. 9) A concrete structure is located approximately 800 feet southwest of the site. According to Mr. Jeffery Lawlor, Engineer for the Port Authority of St. Croix, the structure is a concrete water catchment pad constructed by the U.S. MiUtary that formerly collected rainfall runoff into a 1/2 mUlion-gallon cistern. ^ 302393 \WOROPROC\29872\DSRoi.REP August 14,1995 2:23pm Harding Lawson Associates 19 10) Fairplains weU field is located approximately 1,000 feet southeast of the site. 11) The Golden Grove Adult Correctional FacUity is located approximately 1,100 feet northwest of the site. 12) The Old Golden Grove WeU field is located approximately 1,200 feet to the west of the site. 13) Zenon Construction Company (Zenon) is located approximately 1,300 feet southeast of the site. Zenon provides construction materials and equipment for buUding and repair projects. 4.5.3 Results of Review of Historical Aerial Photographs The results of the review of each aerial photograph used in the site evaluation are summarized below. A description of the site property is followed by a description of immediately adjacent and surrounding properties. Subsequent photographs are reviewed in the same manner as the previous photograph. After the site, immediately adjacent, and surrounding property descriptions are completed, the photographs are compared and contiasted to each other. Changes that have occurred on the site since the previous photograph was taken are indicated, foUowed by changes on adjacent and surrounding properties. The review was supplemented by observations made by HLA during the site investigation. Copies of the photographs are included in Appendix J. An arrow indicating geographic north and the date the photograph was taken are located in the upper right comer of each photograph. An arrow marked "SITE" indicates the location of the site. Because the photographs are presented in differing scales and were cropped for inclusion in this report, the site features described in the text may not be visible in aU of the photographs. 4.5.3.1 February 15, 1954 The site was undeveloped. Adjacent properties to the north and east appear to have been used for agriculture.. Adjacent properties to the south and west were undeveloped. Two housing developments are visible, approxiniately 1/2 mUe north (Upper Bethlehem) and approximately 3/4 mUe to the northwest (Golden Grove) of the site. The Alexander HamUton Airport and the Dr. Randall James Racetrack are located approximately 3/4 mUe south of the site. Airport facihties were much smaUer than at present, and the racetiack had no grandstand. The catchment basin appears as a large hexagonal structure on top of the ridge to the southwest of the site. 4.5.3.2 April 20, 1959 No changes on the site property and surrounding properties were noted since the 1954 photograph. The site and adjacent properties to the south and west remained undeveloped. As in 1954, adjacent properties to the north and east appear to have been used for agriculture. 4.5.3.3 1962 The adjacent property located northeast of the site, currentiy a cement manufacturing company, appears to have been developed for agriculture. This area appears as forestland in earlier photographs. This photograph shows what appears to be east-west trenching rows of an undetermined type. No other changes on the site and surrounding properties were noted since the 1959 photograph. 4.5.3.4 F e b r u a r y 20, 1964 The site and immediately surrounding properties appear as they did in the 1962 photograph. The area immediately to the west of the catchment pad has been developed further since the 1962 photograph. WORDPROC\29872\DSRoi.REP August 14,1995 2:23pm Harding Lawson Associates 20 302394 The airport and racetiack have been greatiy expanded. Water appears to have been present in the River Gut approximately 1/4 mUe upsfream from the ocean, approximately 1 mUe east of the site. Trenches have been excavated south of the airport. The frenches appear to empty into the ocean in the viciruty of Manning Bay, approximately 1.5 mUes southeast of the site. Constiuction of the facUity currently occupied by the YIALCO Bauxite plant approximately 1 mUe east of the site, had begun. 4.5.3.5 February 17,1971 Two btuldings, the laboratory and the maintenance buUding, were constmcted and 20 ASTs were installed on the site between 1964 and 1971. The cement plant located to the east and the asphalt plant located to the north of the site are also visible for the first time. Because this photograph was taken at high altitude and has poor resolution, ground stiuctures are small and difficult to distinguish. 4.5.3.6 N o v e m b e r 20, 1971 This photograph better shows the constiuction on and around the site since 1964. Visible additions to the site included the laboratory buUding, maintenance buUding, 20 ASTs, the tower, a driveway, and a paved surface that covers much of the area around the two buUdings. The concrete pad surrounding production weU P-2 appears to have been constructed in the northern comer of the site. An unknowm structure is visible in the northern portion of the site, southeast of P-2. No changes appear to have occurred onsite or on the surrounding properties since the earUer 1971 photograph had been taken. Water was visible in the River Gut upstream of the site at this time. A section of the channel of River Gut has been filled and moved approximately 400 feet to the southwest. In 1964, the gut ran along the road; in 1971, it was relocated to run along the northeastem site boundary. The property to the north, currently an asphalt plant, and the property to the east of the site, currently a concrete plant, have been developed. A small bridge has been constiucted over River Gut near the northem comer of the Site. The bridge cormects the neighboring property to the west of the site wdth the property across the gut to the north of the Site. The property to the northeast of the site, currentiy a paving company, has been partiaUy cleared of vegetation. A buUding located approximately 400 feet northwest of the site was constructed between 1964 and 1971. The buUding is currentiy occupied by Fix-it-Right Transmission, an automobUe tiansmission repair shop. In general, development of agricultural/undeveloped land is occurring in the immediate viciruty of the site. A large housing and traUer park development (Profit) has been constiucted approximately 1/2 mUe northeast of the site. A sewage treatment plant is under constiuction approximately 1 mUe southeast of the site. The facUity currently occupied by the VIALCO bauxite plant appears to have been greatly expanded. The Hess oU refiner}' and the St. Croix landfill, located approximately 1 mUe east and 3/4 mUe southeast of the site, respectively, are visible for the ffrst time. Krause lagoon, located approximately 11/4 mUe east of the site, has been dredged and is being used as a shipping channel by Hess and VIALCO. 4.5.3.7 January 17, 1974 Onsite, the warehouse addition to the laboratory was constructed between 1971 and 1974. The Golden Grove Correctional FacUity to the northwest was constructed since the 1971 photograph. Construction of the Melvin Evans Highway east of the site is visible. The St. Croix landfiU and the VIALCO Bauxite plant have greatly expanded since the 1971 photograph. 4.5.3.8 November 14,1977 Vegetation in and along the edge of the gut appears to have been cut since 1974. Construction of the Melvin Evans highway south and west of the site has been completed. WORDPROa29872\DSRoi.REP August 14,1995 2:23pm Harding Lawson Associates 21 302395 4.5.3.9 November 11,1988 OrUy 14 ASTs are visible in this photograph, indicating that sbc ASTs have been removed. The large water tank and several small buUdings were constiucted on the southeastern portion of the site. The structure noted in the northwest portion of the site visible in the November 1971 aerial photograph is no longer visible, and the photograph indicates the area is overgrown wdth vegetation. The River Gut appears to contain water adjacent to and upstream of the site. Additional development of the property to the east of the site is visible. 4.5.3.10 October 9,1989 Damage from Hurricane Hugo, which occurred on September 17 and 18, 1989, is evident over most areas on the aerial photograph. Onsite, a roofing panel appears to have been blowm off of a portion of the maintenance buUding. Debris is scattered over most of the airport and racetrack grounds. Several small afrplanes appear to have broken wings and damaged fuselages. One airplane is located across the sfreet from the airport in a vegetated area. The roof of one of the afrport terminals appears to have been blown off. 4.5.3.11 January 24, 1990 At the time this photograph was taken, the site is partiaUy obscured by cloud cover. However, the airport terminal roof has been repaired and damage from Hurricane Hugo is less apparent than in the photograph taken 3 months earUer. 4.5.3.12 January 20, 1991 Vegetation appears to be encroaching on the northeastem and southeastern borders of the site. Four stiuctures, which may be fraUers, are visible northwest of the laboratory, northwest and southwest of the mainteriance buUding, and south of the tank farm. Surrounding properties have changed httie since the previous photograph. 4.5.3.13 Current Site Conditions Information for current site conditions is based on observations by HLA during field work. 1995 observations are based on site visits, since a current aerial photograph is not avaUable for review. The site is currently abandoned. AU buUdings onsite have been vandalized and are in a state of disrepair. Prior to site clearing abandoned automobUes and pUes of trash were strewn over most areas of the site. Vegetation had overgrowm most unpaved areas of the site untU its removal in January 1995. Ten ASTs are present. One AST has been moved approximately 20 feet out of position compared with its original position based on previous site plans. The undeveloped property located northwest of the site was cleared of vegetation in January 1995. No other apparent changes in the surrounding properties were observed. 4.5.4 Results of Review of Well Records HLA identUied 231 production weUs within 3 mUes of the site. Of the 231 production wells identUied, 94 are reported as not used. Of the 137 production wells reported as active, 57 are identified as pubUc supply, 55 are identified as domestic or agriciUtural, and 25 are identUied as commercial or industrial. The closest active domestic or agricultural weU identUied is Golden Grove Correctional No. 1, located approximately 1,300 feet northwest of the site. The closest active commercial or industrial well appears to be located at the concrete facUity adjacent to the site. A structure that appears to be a well house is located approximately 150 feet northeast of the site, across River Gut. This well was not identified in any of the published sources or during discussions with VIPA or W/\PA. The closest \WORDPROC\29872\DSRoi.REP August 14,1995 2:23pm Harding Lawson Associates 22 302396 active pubUc supply well is located in the Fairplains weU field, approximately 1,000 feet southeast of the site. AvaUable information regarding the weUs identified is summarized on Table 4-13. Well numbers showni on Table 4-13 refer to the location maps presented in Appendix K. \WORDPROC\29872\DSRoi.REP August 14,1995 2:23pm Harding L^wson Associates 23 3 023 97 ~ 5.0 CONCLUSIONS 5.1 General Findings of work performed to date indicate the foUowdng: • The two constituents identified in previous investigations, pyridine and chloroform, were not detected in any of the soU or groundwater samples collected during this investigation. • No additional potential source areas were identUied onsite. • The stained soUs and release observed beneath the ASTs indicate contamination detected in this area is due in part, to recent storage of petroleum products in the AST area. • Conclusions regarding the ecological findings are discussed in Appendix L. 5.2 Geology 5.2.1 Stratigraphy • The shallow clay layer previously reported (ESI, 1987) does not appear to be continuous across the site. It was not encountered in all drilling locations. • Stiatigraphy is consistent with the aUuvial envfronment reported. No evidence of significant fUling was observed in the bdrings. 5.2.2 Soil Quality To evaluate soU quaUty, HLA compared the results for soU samples coUected during this project to the ARARs identified during preparation of the project work plan and updated during this investigation. The only ARAR identified for soUs on this project was the proposed Examples of Concentiations Meeting Criteria for Action Levels (Federal Register, Vol. 55, No. 145, July 27, 1990) (Proposed RCRA ALs). Maximum concentiations of substances detected in the soU samples are compared wdth the Proposed RCRA ALs on Table 5-1. Because Proposed RCRA ALs are not avaUable for many of the metals detected, HLA also compared the metals concentrations detected (Table 5-2) to results of soU samples coUected from St. Croix by the USGS (1989). Thfrty seven TCL and TAL substances were detected in soU samples collected during the sampling event. 5.2.2.1 Volatile Organic Compounds in Soil Six VOCs were detected in the soU samples coUected by HLA. All of the VOC concenfrations reported were at least two orders of magrutude below the proposed RCRA ALs. Therefore, VOCs are not considered a concern in soU at this site. \WORDPROC\29872\DSRoi.REP August 14,1995 2:23pm Harding Lawson Associates 24 302398 5.2.2.2 Semivolatile Organic Compounds in Soil Five SVOCs were detected in the soU samples coUected by HLA. Results for bis(2- ethylhexyl)phthatate, butylbenzyl phthalate, and pentachlorophenol were approximately two orders of magnitude or more below the Proposed RCRA ALs. No SVOCs were detected at concentiations above the potential ARARs. No ARARs were identified for di-n-butylphthalate and di-n-octylphthalate. However, these two compounds were reported only at estimated concenfrations below the MDL. Therefore, SVOCs are not considered a concem in soU at this site. 5.2.2.3 P e s t i c i d e s a n d PCBs in Soil Six pesticides and no PCBs were detected in the soU samples coUected by HLA. The highest concentiations of y'-BHC and eldrin were at least three orders of magrutude below the proposed RCRA Als. No ARARs were identUied for the foUo\ving four pesticides: oc-Chlorodane, K-Chlorodane, endosulfan II, and endrin aldehyde. Various pesticides, including those detected, have been used on a widespread basis across the island. The pesticides were detected sporadicaUy and at tiace concentrations. Based on the widespread use of pesticides and the relatively low concentiations detected onsite, pesticides are not considered a concem in soU at this site. 5.2.2.4 M e t a l s in Soil Twenty TAL metals were detected in the soU samples coUected by HLA in January 1995. No ARARs were identified for 13 of the metals detected. However, from 1983 to 1988, the USGS coUected 127 soU samples from various locations on St. Croix. These samples were analyzed for a variety of metals (USGS, 1989). HLA considers results of the work performed by USGS to represent background metals concentiations for the island. i Seven of the metals were compared to the Proposed RCRA ALs. One metal, beryUium, was detected at concentrations above the Proposed RCRA AL of 0.2 mg/kg. BeryUium was detected in 27 samples at concentiations ranging from 0.15 mg/kg to 0.58 mg/kg. These results are aU within one order of magrutude of the Proposed RCRA AL and are also wdthin the range of concenfrations reported by USGS. This metal was not reported as having been used or detected previously at the site. BeryUium is not considered a concem at this site. Metals were also compared to USGS reported concentiations. Table 5-2 presents a comparison of ranges of concentrations of metals in samples coUected by HLA and USGS. Results for 13 of the metals detected by HLA were wdthin or almost identical to the ranges of concentiations reported by USGS. These metals included barium, beryUium, calcium, chromium, cobalt, copper, fron, lead, magnesium, manganese, ruckel, sodium, and vanadium. Three of the metals detected by HLA were not detected by USGS. These metals are antimony, arsenic, and cadmium. However, the concentrations of these metals detected by HLA were below the MDLs used by USGS. Three of the metals detected by HLA were not analyzed by USGS. These metals are aluminum, mercury, and potassium. Of the 20 metals detected by HLA, zinc, was reported at concentrations higher than those reported by USGS. Zinc was detected in all of the samples collected by HLA, at concentrations ranging from 35.1 mg/kg to 5,790 mg/kg. USGS results were all below the zinc MDL of 200 mg/kg. The soUs on St. Croix are derived from volcaniclastics, which often contain heavy metals. Based on the comparison wdth USGS data, the metals detected, wdth the possible exception of zinc, appear to represent background concentiations. Elemental zinc was not reported on the avaUable inventories of materials handled at the facUity. \WORDPROC\2g872\DSRoi.REP August 14,1995 2:23pm Harding Lawson Associates 25 302399 5.3 Groundwater 5.3.1 Groundwater Flow • Groundwater occurs in the lower sUty sand discussed in Section 4.1 • ShaUow groundwater flow is partiaUy contiolled by precipitation. Groundwater generally flows to the east and northeast. However, foUowdng a rainfall event, groundwater flow reversed across a portion of the site. 5.3.2 Groundwater Quality To evaluate groundwater quaUty, HLA compared the results from the two sampUng events to potential ARARs identified for the project. Potential groundwater ARARs identUied for this project include the following: National Primary Drinking Water Maximum Contaminant Levels (40 CFR 141.61 and 141.62) (Primary MCLs) National Secondary Drinking Water Maximum Contaminant Levels (40 CFR 143.3) (Secondary MCLs) National Drinking Water Maximum Contaminant Level Goals (40 CFR 141.50 and 141.51) (MCLGs) Maximum Concentiations of Constituents for Groundwater Protection under the Resource Conservation and Recovery Act (40 CFR 264.94) (RCRA MCC) Proposed Examples of Concentiations Meeting Criteria for Action Levels (Federal Register Vol. 55, No. 145, July 27, 1990. (Proposed RCRA Als) *. / The RCRA MCCs establish limits for constituents in groundwater beneath imits regulated under RCRA such as lan_dfiUs and^.tieatment faciUties. Because the site is not regulated under RCRA, this may not be an ARAR. Maximum concentrations for each of the substances detected in the groundwater samples are presented wdth the ARARs on Table 5-3. Forty seven TCL and TAL substances were detected in groundwater samples collected during the two sampling events. These substances are discussed in the foUowdng sections. 5.3.2.1 Volatile Organic Compounds in Groundwater Six VOCs were detected in the groundwater samples collected by HLA. The orUy VOC detected at concentrations above the potential ARARs was ethylbenzene. Reported concentiations of this compound slightly exceeded the Primary MCL and MCLG of 700 //g/L in samples coUected from one well during the ffrst of the two sampling events, in February ethylbenzene was detected in the groundwater sample and duplicate collected from MW-1 at 750 //g/L and 720 //g/L, respectively. However, the concentration of ethylbenzene decUned to 100 //g/L and 120 //g/L in the two samples collected from this well in May. The source of ethylbenzene at this location is likely due to leakage of petroleum from the AST observed in this area. 5.3.2.2 Semivolatile Organic Compounds in Groundwater Six SVOCs were detected in the groundwater samples collected by HLA. The Proposed RCRA Als are the orUy ARARs identUied for four of these SVOCs, bis(2-ethylhexyl)phthalate, 4-methylphenol, isophorone and phenol. No ARARs were identified for 4-chloroaniline and 2,4-dimethylphenol. The orUy SVOC detected at concentrations above the Proposed RCRA Als was bis(2-ethylhexyl)phthalate. The Proposed RCRA AL for this compound is 3 //g/L. This compound was detected in all of the \WORDPROC\29872\DSRoi.R£P August 14,1995 2:23pm Harding Lawson Associates 26 3 0240r0 samples coUected in May at concenfrations ranging from 3 //g/L (estimated) in one of the dupUcate samples from MW-1 to 42 //g/L in the sample from MW-3. However, aU of the results were qualified by the laboratory to indicate that bis(2-ethylhexyl)phthalate was detected in the associated QC blanks. This compound is a common laboratory- or field-induced contaminant. Furthermore, this compound was not detected in any of the samples coUected in February. Therefore, it appears that bis(2- ethylhexyl)phthalate was the result of laboratory- or field-induced sample contamination. Therefore, SVOCs are not considered a concem in groundwater at this site. 5.3.2.3 Pesticides and PCBs in Groundwater FUteen pesticides and no PCBs were detected in the groundwater samples coUected by HLA. The foUowdng four pesticides were detected in groundwater samples at concentiations exceeding avaUable ARARs: aldrin, oc-BHC, heptachlor, and heptachlor epoxide. • Aldrin - Once very common, the manufacture and use of this insecticide was discontinued in the USA ui the 1980s (Merck, 1989). • a-BHC (Hexachlorocyclohexane), sold under the name Lindane, is used primarUy as an insecticide. • Heptachlor and Heptachlor epoxide - Heptachlor epoxide is a degradation product of heptachlor (Verschueren, 1983). Heptachlor is used as an insecticide. The use of this compound was discontinued for surface apphcation in 1975 (Federal Register, Volume 40, Page 28850, July 9, 1975). The remaining approved use of this product is subsurface ground injection for termite contiol (Merck, 1989). Termites were observed by HLA personnel to be very common on the site. . , No other ARARs were identified for aldrin or oc-BHC. Concentiations of heptachlor and heptachlor epoxide were more than an order of magrutude lower than the Primary MCLs for these substances. For the most part the pesticides were detected sporadicaUy and at tiace concenfrations; only one of the results exceeded 0.1 //g/L. Based on the widespread use of pesticides across the island and the relatively low concentiations detected onsite, the site is not considered to be a source for pesticides in the groundwater. 5.3.2.4 M e t a l s in G r o u n d w a t e r Seventeen TAL metals were detected in the filtered groundwater samples coUected by HLA. Five of these metals were detected at concentiations that exceeded one or more of the ARARs identUied. These metals were antimony, beryllium, fron, manganese, and selenium. Because metals data for the unfUtered samples appear to reflect suspended material, results for unfUtered samples are not considered to reflect groundwater conditions at the site and are, therefore, not considered in this discussion. Antimony was the only metal detected in groundwater at concentrations above the Primary MCLs. Reported antimony concentrations exceeded the Primary MCL of 6 //g/L in two samples. Antimony was detected in one of the samples collected from MW-1 in May at 6.8 //g/L; it was not detected in the duplicate sample from this well. Antimony was detected at 95.6 //g/L in the sample from MW-4 collected in February. It was not detected in the sample collected from this well in May. Beryllium was detected in two samples. It was detected at 0.34 //g/L in the sample coUected from MW-5 in May and in one of the two duplicate samples collected from MW-1 in May at 0.1 //g/L; it was not detected in the duplicate sample from this well. Both of these results exceeded the Proposed RCRA AL of 0.008 //g/L. These results were qualUied to indicate that this metal was also detected in associated QC samples. None of the beryUium results exceeded the Primary MCL of 4 //g/L for this \WORDPROC\29872\DSR0i.REP August 14,1995 2:23pm Harding Lawson Associates 27 3 02401" metal. This metal was not reported as having been used or detected previously at the site. Based on its inconsistent detections and laboratory qualifications, it appears that the beryUium results may reflect laboratory- contamination and do not represent actual groundwater conditions. Therefore, berylUum is not considered a concem at this site. fron and manganese were detected in several samples at concenfrations above the Secondary MCLs for these two metals, fron concentiations exceeded the Secondary MCL of 300 //g/L in the samples collected from MW-3 in February and May. fron concenfrations detected in other samples were below the Secondary MCL for this metal. Manganese concentrations exceeded the Secondary MCL of 50 //g/L in all of the groundwater samples coUected in May and February. Reported manganese concentiations ranged from 535 //g/L in the sample coUected from MW-4 in February to 5,130 //g/L in the sample collected from MW-3 in May. Secondary MCLs relate to aesthetic qualities. No other ARARs were identUied for these two metals. Because groundwater is not used for potable purposes onsite, the fron and manganese concentiations detected are not considered a concem at this site. Selenium was detected in samples from two weUs. It was detected in the sample and dupUcate collected from MW-1 in February at 15 //g/L and 17.6 //g/L, respectively, and in the sample coUected from MW-4 in May at 1.6 //g/L. The results for MW-1 exceeded the RCRA MCC of 10 //g/L but were below the Primary MCL and MCLG of 50 //g/L. As noted previously, the RCRA MCCs establish linuts for constituents in groundwater beneath units regulated under RCRA such as landfiUs and tieatment facUities. Because the site is not regulated under RCRA and the reported seleruum concentiations are below the MCL, this metal is not considered a concem at this site. 302402 \WORDPROC\29872\DSRoi.REP August 14,1995 4:44pm Harding Lawson Associates 28 6.0 RECOMMENDATIONS Based on results of work performed to date, HLA recommends the foUowdng additional activities: • Properly close the 14 ASTs that remain onsite. This should include cleaning the ASTs of residual material to remove the potential for future releases. • Because ethylbenzene and several metals were detected at concentiations above ARARs, HLA recommends collection of two additional rounds of groundwater samples for analysis of TCL VOCs and dissolved metals. • U results of the additional sampling indicate that groundwater at the site is not a concern, the four morutoring wells and two production wells should be properly abandoned. • Because the site has been subject to tiespassing, HLA recommends that security be implemented at the site, for example, the fence should be repafred. 302403 \WORDPROC\29872\DSR0l.REP August 14,1995 2:23pm Harding Lawson Associates 29 7.0 ACRONYMS AND ABBREVIATIONS AL Action Level /\RARs AppUcable or Relevant and Appropriate Requfrements AST Aboveground Storage Tank CDM CDM Federal Programs Corporation CHT Caribbean Hydro-Tech, Inc. CERCLIS Comprehensive Envfronmental Response, Compensation and LiabUity Informative System CFR Code of Federal Regulations CHERI Christian Heavy Equipment Rental, Inc. DPNR St. Croix Department of Planning and Natural Resources DPW St. Crobc Department of PubUc Works DSR Data Summary Report EDR Envfronmental Data Resources, Inc. EPA U.S. Envfronmental Protection Agency FINDS FaciUty Index System GFAA Graphite Furnace Atomic Absorption HLA Harding Lawson Associates ICP Inductively Coupled Plasma MCL Maximum Contaminant Levels MCLG Maximum Containment Level Goods MDL Method detection limit ' mg/L MUUgrams per Uter MSL Mean Sea Level /• NOS National Ocearuc Services NPL National Priorities List ORDER ' Administiative Order On Consent, EPA Index No. U CERCLA-94-0401 PACE Pace Envfronmental Laboratories, Inc. PCBs Polychlorinated biphenyls PID Photo-ionization detector POTW PubUcly owmed freatment works ppm Parts per mUUon QA Quality Assurance QAPP Quality Assurance Project Plan QC Quality Contiol RCRA Resource Conservation and Recovery Act DSR Data Summary Report SVOC SemivolatUe organic compound TAL Target Analyte List TCL Target Compound List USDA Uruted States Department of Agriculture USDI United States Department of Interior USGS Uruted States Geological Survey VIAPCO Vfrgin Islands /\sphalt Products Company VICHEM Vfrgin Islands Chemical Company VIPA Vfrgin Islands Port Authority VIPC Vfrgin Islands Paving Company VOC VolatUe organic compound WAPA Vfrgin Islands Water and Power Authority //g/L Microgram per liter //g/kg Micrograms per kUogram %RSD Relative standard deviation 302404 \WORDPROC\29872\DSR01.REP August 14. 1995 2:23pm Harding Lawson Associates 30 8.0 REFERENCES Budavari, Susan, ed. 1989. The Merck Index - An Encyclopedia of Chemicals, Drugs, and Biologicals. Eleventh Edition. Rahway, New Jersey. Merck Company, Inc. Comprehensive Envfronmental Response, Compensation, and LiabUity Act of 1980 (CERCLA): PubUc Law 96-510, 42 USC 9601 et seq. Envfro-Science, Inc., 1987. Remedial Investigation Work Plan for Island Chemical Company, St. Croix, USVI, AprU 16. Geraghty & MUler, Inc. 1983. Report on Current Groundwater Conditions in the U.S. Virgin Islands, AprU 29. Green, Boko, and G. Cherry, 1994. Water wells on St. Croix, U.S. Virgin Islands. U.S. Geological Survey Open-FUe Report 91-503. Harding Lawson Associates, 1994. Island Chemical Company, Inc., Remedial Investigation Work Plan, St. Croix, U.S. Virgin Islands, March 17. McHugh, J.B., Tucker, R.E., Hopkins, R.T., Roemer, T.A., and Alminas, H.V. 1989. Gold, silver, tellurium, and spectrographic analyses for rock and soil samples from the U.S. Virgin Islands. U.S. Geological Survey Open-FUe Report 89-355. Robinson, T.M., 1972. Ground-water!in central SL Croix, U.S. Virgin Islands. U.S. Geological Survey Open-FUe Report, Caribbean District. Superfund Amendnients and Reauthorization Act of 1986: Pubhc Law 99-499. Torris-Gonzalez, S. and F. Rodriguez del Rio, 1^90. Potentiometric surface ofthe KinshUl aquifer and hydrologic conditions, St. Croix, U.S. Virgin Islands. U.S. Geological Survey Water-resources Investigations Report 89-4085. July. U.S. Envfronmental Protection Agency, 1990. 40 CFR Parts 264, 265, 270, 271, Federal Register, Volume 55, No. 145/Friday, July 27, 1990/Proposal Rules, (30865-30867). 302405 \WORDPROC\29872\DSRoi.REP August 14,1995 2:23pm Harding Lawson Associates 31 DRAFT Table 1-1. Areas of Potential Environmental Concern Virgin Island Chemical Site St. Croix, U.S. Vfrgin Islands Area Identification Location Description A B D Laboratory and Warehouse Building Aboveground Storage Tank Farm Former Procnss Pit Lf)a(ling Dock nnd Former Lab Pit Area Soil Boncalh Concrete Pad (Former AST Pads) Center of site Northwest side of Site Location of drum storage during USEPA removal action. Former location of 20 ASTs, 10 tanks remain onsite. ESI identified and excavated area of soil between ASTs 8 and 9. East of Maintenance Former location of underground concrete storage lank used to collect process Building waste water, Norlh of Laboratory Cobblc-fillnd pit located bcnoalh loading dock Uinl formerly received waste liquids from laboratory drains. Pit was connected to a second pit located near the properly boundary by a 4-inch PVC pipe. Northwest of ASTs ESI identified and excavated one area of affcclod soiL Concrete Sloragc Pad Norlh of Laboratory Used for storage of various materials. CO o IO o wordproc\29872\tlsrQl.lb] Harding Lawson Associates Table 2-1 Samples Submitted for Laboratory Analysis Vfrgin Island Chemical Site St. Croix, U.S. Vfrgin Islands SoU Boring Depth Intervals Submitted for Laboratory Analysis (feet below grade) Date Sampled o z' SBBl/MW-1 SBCl SBC2/MW-3 SBDl/MW-4 SBD2 SBD2A SBD3 SBD4/MW-5 SBEl SBFlA SBF2 SBF3 0-1, 0-1, 0-1, 0-1, 0-2, 0-1 0-2, 0-1, 0-2, 0-1, 6-8. 24-26 16-18, 20-22 20-22, 24-26 12-14, 22-24 19-21 17-19 14-16, 20-22 20-22 13-15, 20-22 12-15, 18-20 0-1, 12-15, 18-20 01/31/95 01/27/95 01/30/95 01/25/95 01/19/95 02/03/95 01/20/95 01/27/95 01/19/95 01/23/95 01/24/95 01/24/95 wordproc\2987 2\dsrO 1 .tbl Harding Lawson Associates 302407 CO o IO o 00 Well H y^Ld^ T a b l e 2-2. W e l l C o n s t r u c t i o n a n d D e v e l o p m e n t D e t a i l s V i r g i n I s l a n d C h e m i c a l S i t e S t . Croix, U.S. V i r g i n I s l a n d s Dale Completed Deplh lo Watcr^ Depth Interval Screened^ Surveyed Elevation Data' Ground Surface Top of Outer Casing Top of Inner Casing Well Development Informalion Development Method Volume Removed (gallons) Duration (hr:min)'' Turbidity (NTUs)' MW-1 MW-3 MW-4 MW-5 P-1 P-2 2/3/95 2/2/95 1/2G/95 2/1/95 NA NA 28 23 - 33 29.41 31.45 23.5 18.5 - 28.5 28.45 31.33 23 1 8 - 2 8 20.84 20.77 22.5 17.5 - 27.5 26.40 29.62 35.1 25.7 98^ 96' 38.00 39.80 29.55 30.38 31.36 Submersible 35 1:30 pump 30.80 Submersible 35 1:47 pump 20.63 Submersible 53 2:02 pump & bailer 20.83 Submersible 10 1:55 pump NA Submersible 330 0:55 pump NA Submersible 330 0:50 pump 8.64 91.6 06.1 >200 24.2 2.09 Notes: NA Not Available/Not Applicable ' Measured in feet below ground surface during well installation activities ' Well P-1 and P-2 total depths measured on May 8, 1995, from top of outer casing. Screened intervals for these wells are not available. ^ Measured in feet above mean sea level (National Geodetic Vertical Datum of 1983). •• Well development took place between February 6 and 10, 1995. Development at all well locations MW-4 and MW-5 was discontinuous. ' Nephelometric turbidity units; last measurement following completion of well development. Source: Harding Lawson Associates (HLA Project No. 29872) wordproc\29872\dsr01.tbl Harding Lawson Associates Table 4 - 1 . Soil Sample PID Readings Virgin Island Chemical Site St. Croix, U.S. Virgin Islands SoU Boring SBBl/MW-1 SBBl/MW-1 SBBl/MW-1 SBBl/MW-1 SBBl/MW-1 SBBl/MW-1 SBBl/MW-1 SBBl/MW-1 SBBl/MW-1 SBBl/MW-1 SBBl/MW-1 SBBl/MW-1 SBBl/MW-1 SBBl/MW-1 SBCl SBCl SBC2/MW-3 SBDl/MW-4 SBD2 SBD2 SBD3 SBD3 SBD4/MW-5 SBEl SBEl SBEl SBFl SBF2 SBF3 Date Sampled 01/31/95 01/31/95 01/31/95 01/31/95 01/31/95 01/31/95 01/31/95 01/31/95 01/31/95 01/31/95 01/31/95 01/31/95 01/31/95 01/31/95 01/27/95 01/27/95 01/31/95 01/25/95 01/19/95 01/19/95 01/20/95 01/20/95 02/01/95 01/19/95 01/19/95 01/19/95 01/23/95 01/24/95 01/24/95 Depth Interval (feet) 0-2 2-4 4-6 6-8 8-10 10-12 12-14 14-16 16-18 18-20 20-22 22-23 23-24 24-26 0-22' 23.5-24.5 0-26' 0-24' 0-10' 15-25' 0-10' 15-21' 0-24' 0-10 15-17 20-24' 0-24' 0-22' 0-22' ' Samples collected continuously across interval identified. All results were PID Reading (ppm) 6.4 1.7 1,129 1,542 318 492 454 21.6 9.7 138.5 255 611 14.1 1.2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 D. wordprocV29872\dsr01.lbl Harding Lawson Associates 302409 00 o to l - » o ^t^i W^ .ti. Table 4-2 Soil Sample Analytical Results -Volatile Organic Compounds Virgin Island Chemical Company Sample Location: Sample Date; Lab Sample TD: Results reported in micrograms per kilogram. 1,1,1-Tridi1(Trix-(h:nic 1,1,2,2-Tc(r.ndil<)r(K:(li:uic 1,1,2-TridilrirrH.-(li;uie l,1-nidil(iriK'tli!uic l,l-T)idi1oroc»lu-Jic 1,2-Didiloroclliam; I .•I-nidilmxtliaic (l<il:il) 1,2-l)idiliir(iir(ii)iiiie 2-nulanonc 2-Hcxancnc 4-MctliyI-2-pailniinic AcrfcTic Benzene nromodidiloroindhaiic Dromofonn nroraomcUiaiic CarbcTi Disiiindc Caibfm Tctxadiloridc QiIorn1)ar/aic Cliloroctliniic I Qilorofonii i ,Clilor<flnc(1i!uic 'cis-1 ,.1-nidil(ir(vr< 1"^"^ Oiliromodiloroinclli.Tne ! I;lhyllini/aic snfz/is-io t/24/95 v.sRonj SnF3/0-l 1/24/95 V.SR004 SBr3/12-I5 1/24/95 vsRons SnF3/18-20 1/24/95 VSR009 12.U 12. IJ 12.IJ 12.1) 12.1) 12. U 12.1) 12. IJ 12.U 12. U 12.U 29. UJ 12.U 12.U 12. U 12. UJ 12. U 12.U 12.U 12. U 12.U 12.11 12. U 12. U 12. IJ II.U II.UJ l l . U 11.U ll.U ll.U ll.U ll.U l l . U 11. UJ II.UJ II.UJ ll.U l l . U l l . U II.UJ l . J l l . U II.UJ ll.U l l . U ll.U ll.U ll.U II.UJ l l . U l l . U l l . U ll.U ll.U l l . U ll.U ll.U l l . U l l . U l l . U 96. lU l l . U l l . U l l . U II.UJ 2. J l l . U 11. 11. 11. 11. II. 11. II. 38. 11. U U U u u u u u u u u UJ u u u UJ u u u u u u u u u See last page of (aide for notes. Harding Lawson Associates ,-:» Table 4-2 Soil Sample Analytical Results - Volatile Organic Compounds Virgin Island Chemical Company Sample Location: Sample Date: Lab Sample ID: Results reported in micrograms per kilogram. Mctliyloic diloride SljTCIlC Tctraddoroclliciie Toluene Ir-in-s-l ,3-Diddi)r(Vf'V>^"! Tridilorocthaic Vinyl Chloride Xylaie(l<)(id) SHK/IS^O 1/24/95 V.SRn03 SBF3/0-1 1/24/95 VSROW SBF3/12-15 1/24/95 vsRons SBF3/I8-20 1/24/95 VSU009 12. UJ 12.U 12. U 12.1) 12. U 12. U 12.11 12. U 17. UJ 11. UJ II.UJ II.UJ ll.U ll.U ll.U II.UJ 14.1 n - Detected in sample and associaled bl.ink 1) - Compoimd qnmilitalcil m a dihilcd s.implc E - nxccetlcd llic cilibralini r.iiigc ofinstnuncnl J -Hslim.Mwl Value R - Rcsidt was rejected during data validalicm U - AnalyziJd but not detected X - M.Tiuial addiliiii ofci.s .ind tr.nns isomers OJ O IO H H Harding Lawson Associates h OJ o IO l-» to Table 4-3 Soil Sample Analytical Results - Semivolatile Organic Compounds Virgin Island Chemical Company Sample Location: Sample Dale: Lab SaniplcTD: Results reported in micrograms per kilogram. 1,2,4-Triddor<»bi3i/ciic 1,2-Didilor(il)uixnie 1,3-niddonilicn/ciic 1,4-l)idil(irobciv/uic 2,2'.<ixybis(l-Cliliir(5irmi;uie) 2,4,5-rridili>niilinml 2,4,6-Tridiloni|iIu-niil 2,4-l)iddi)r<n)licm)l 2,4-Dimetliylplicnol 2,4-Dinilrophaiol 2,4-Dinitro(o1uaic 2,6-Dinilrotoluaie 2-Clilorr»iapliUialcnc 2-ClilorophciioI 2-Mctliyln.Tplilhalmc 2-Mclliylplia)ol 2-Nitro.Tniline 2-Nilrophcnol 3,3'-Diddorobcnzidinc S-Nilro.Tiiilinc 4,6-Dinilr<>-2-nic(liylpli«u)l 4-Hronin|)liciiyl-i)liuiykllier 4-Cblnro-3-mctliylplicjiol 4-Chloro;niiline 4.ChlorqiIiaiylii!iuiyldlicr See last page of table Tor notes. SBBl/0-1 1/31/95 WCOOI 410. U 410. U 410. I) 410.1) 410.U 990. 11 410. U 410. U 410. U 990. UJ 410. U 410. U 410. U 410.U 410. U 410.U 990. U 410. U 410.UJ 990. UJ 990.1 )J 410. U 410. U 410. UJ 410. U SBBl/0-1 1/31/95 WCOOI 390. U .390. U 390. U 390.U 390. U 9.'50.U 390. U 390. U 390. U 950. UJ 390. U 390. U 390. U 390. U 390. U 390. U 950. U 390. U 390. UJ 950. UJ 950. UJ 390. U 390. U 390. UJ 390. U Hardini SBBI/6-8 1/31/95 V\'G0n3 460.1) 460. U 460. U 460. U 460. U 1100. U 460. \ I 460. U 460. U IIOO.UJ 460. U 460. U 460. U 460. U 460. U 460. U 1100. U 460. U 460. UJ IIOO.UJ IIOO.UJ 460. U 460. U 460. UJ 460. U q Lawson SBBl/24-26 1/31/95 wonos 410. U 410. U 410.U 410. U 410.U 990. U 410. U 410. U 410. U 990. UJ 410. U 410. U 410. U 410. U 410. U 410. U 990. U 410. U 4I0.UJ 990. UJ 990. U.f 411). U 410.U 410.UJ 410. U Associates SBCI/O-l 1/27/95 VTUKPI 400. U 400. 11 400. n 400. I) 400. I) 'Ml. 11 400.11 400. U 400. U 980. U 400. U 400. U 400. U 400. U 400.1) 400. U 980. U 400. U 400. U 980. U 980. 1) 400.1) 400. U 400. U 400. U SBCl/16-18 1/27/95 VTF003 370. U 370. U 370.11 370. U .370. U 9)0.11 370.11 .370.1) 370. U 910. U 370. U 370. U 370. U 370. U 370. U 370. U 910. U 370. \} 370. U 910.U 910.11 370. U 370. U 370.1) 370. U SBCI/18-20 1/27/95 VTHKM 400. U 400. 11 400. 11 400. 11 400.1) 980. 11 400. U 400. U 400. U 980. U 400.1) 400. U 400. U 400. U 400. U 400. U 980. U 400. U 400. U 980. U 980. 1) 400. U 400. U 400. U 400.1) SBCl/20-22 1/27/95 vrroos 390. U 390. U 390. U 390. U 390, U 940. U 390. U 390. U 390. U 940; UJ 390. U 390. U 390. U 390. U 390. U 390. U 940, U 390. U 390. U 940. UJ 940. UJ ' 390, U .390. U 390.1 IJ 390.1) OJ o to M OJ g.N Table 4-3 Soil Sample Analytical Results - Semivolatile Organic Compounds Virgin Island Chemical Company Sample Location: Sample Date: Lab Sample ID: Results reported in micrograms per kilogram. 4-Mc(liy1phai<il 4-Nilro:milinc 4-Nilr(nilim(il Acaiaplilliaie Acaiapblliylmc Anlbraccnc llorA^aVinllirarnio Ua\-/i-^a)iy^-raii: ncn7xi(T)nuor.TiitJiciic nQn7fi(gJi,i)pcr>lciic nai7o(k)nuoranlliciic bis(2-Chlor oc(boxy)nK-lli:uic bis(2-ChloroctliyI)cOicr bis(2-I2UiyIlicxyl)plil]ial.nlc Dulylbcnzylphtlial.nle Carba7oIc Cliry.>;ciic Di-fi-lnitylphlh.nl:ilc Di-n-octylphtlinl:ilc DilH'n7(aJ0-Tiillir;icnic Dihcn/iil'iiriDi Dictliylplillialale DinK-tliylphlliabile FIuor;inlhc3ic I'hiiireiie Sec last page of table for no es. SBBI/0-1 1/31/95 wconz 410. U 990. I).) 990. I ),l 410. U 410. U 410. U 410.11 410. U 410. U 410. U 410. U 410. U 410. U 410. U 410. U 410.1) 410. U 410. U 410. UJ 410. 11 410. U 410.1) 410. U 410. U 410. U SBBl/0-1 1/31/95 wcow 390. U 950. UJ 950. UJ 390. U 390. U .190. U 390. 11 390. U 390. U 390. U 390. U 390. U 390. U 390. U 390. U 390. U 390. U 390. U 390. UJ 390.1) 390. 1) .390. U 390. U 390. U 390. U Harding SBBl/6-8 1/31/95 Wr.(K)3 460. U 1100.1 )J 1100.1 l.l 460. U 460. U 460. U 460,1) 460,1) 460, U 460, U 460, U 460, U 460. U 550. B 460. U 460. U 460. U 460. U 460, UJ 460. 11 460.1) 460. U 460. U 460. U 460. U Lawson SBBl/24-26 1/31/95 wcons 410.11 990. UJ 990. UJ 410.U 410. U 410.U 410. U 410.11 410. U 410. U 410. U 410. U 4 I 0 . U 4 I 0 . U 410. U 410. U 410. U 410. U 410. UJ 410. U 410. U 410.1) 410. U 4 I 0 . U 410. U Associates SBCI/O-l 1/27/95 v m m 400.11 980. 11 980. 11 400. 11 400. I) 400. 11 400. 11 400. 1) 400. U 400.1) 400.1) 400.1) 400. U 440. 400. U 400. U 400. U 400. U 400. U 400, 11 400. 1) 4(K), U 400, I) 400, 11 400, 11 SBC1/J6-I8 1/27/95 VTttl03 370, U 910.1) 910. U .370. U 370. U 370.1) 370. U 370. U 370. U 370. U .370.1) 370. U 370. U 54. J 370. U 370. U 370. U 370. U 370. U 370. U 370. 11 370.1) 370. U 370.1) 370. U SBCI/18-20 1/27/95 VIHKII 400. U 980. 11 980, 11 400, U 400,1) 400,11 400 11 400, 11 400. U 400. U 400. U 400. U 400.1) 97..I 400. U 400. U 400, U 400, U 400, 11 400,11 400 II 400, U 400, U 400.1) 400.1) SnCI/20-22 1/27/95 VTHIOS 390. U 940. UJ 940. UJ 390. U 390. U 390. U 390. U 390. U 390. U 390. U 390. U 390. U 390. U 55. J 390. U 390. UJ 390. U 390. U 390. U 390,1) 390, U 390: 11 .390. U 390 1) 390, U '.%l ,:'% Table 4-3 Soil Sample Analytical Results - Semivolatile Organic Compounds Virgin Island Chemical Company OJ o to H Results reported in microgi IIcxadilorobai7aie Ilexadilnroliiiladinic IIexaddor(>c7cl(nicii(:idiinc Ilc.xadilorocthinic Indmo(1,2,3-cd)p)TCIlc Is<^J^ho^fIlC N-Nitrtwo-<Ii-ii-pr*^i\'l:inilnr N-Nilro»Klipliuiylaininc N.npbllialaic Nilrolicnzaic Pcniaddorrphaiol Hienanlbrciie riicnol Pyrene Pyridine Sample Location: Sainple Date: Lab Sample ID: rams per kilogram. SBBI/0-1 1/31/95 V\'0(K)2 410.U 410,1) 410, I U 410,1) 410, U 410,1) 410. U 410,1) 410, U 410, U 990, UJ 410, U 410, U 410, U 410, U SBBI/0-1 1/31/95 WGOW 390. U 390. 11 390. UJ 390. U 390. U 390. U 390. 11 390. U 390. U 390. U 950. UJ 390. U 390. U 390. U 390. U SBBl/6-8 1/31/95 WG003 460. U 460.1) 460. 1 U 460. U 460. U 460. U 460. 11 460. U 460. U 460. U IIOO.UJ 460. U 460. U 460. U 460. U SBBl/24-26 1/31/95 WGOOS 410. U 410. U 410. UJ 410. U 410. U 410.U 410. U 410. U 410. U 410. U 990. UJ 4 I 0 . U 410.U 410.U 410. U SBCI/O-I 1/27/95 V1I1KI2 400. 400. 400. 400. 400. 400. 400. 400. 400. 400. 980. U 400. 400. 400. U U U 400. U SBCI/16-18 1/27/95 VTH003 370.1) 370, 11 370,1) .370.11 370. U 370. U 370. 11 370. U 370. U 370. U 910. U 370. U 370. U 370. U 370. U SBCI/18-20 1/27/95 VTIIKVI 400.11 400, U 400,1) 400, U 400, 11 400. U 400 11 400, U 400. U 400. U 980. U 400. U 400. U 400.1) 400. U SBCl/20-22 1/27/95 VTPOOS 390. U 390. U. 390. UJ 390. U 390. U 390. U 390. U 390. U 390. U 390. U 940. U 390. U 390. U 390. U 390. U Sec last page of taltic for nntcs. Harding Lawson Associafes OJ o on ^^,1 t^Jti Table 4-3 Soil Sample Analytical Results - Semivolatile Organic Compounds Virgin Island Chemical Company Sample Location: Sample Dale: Lab Sample ID: Results reported in micrograms per kilogram. 1,2,4-Triddor(ihar/uic 1,2-Didilor()hai7nic 1,3-l)idiloroIicn7aic 1,4-I5idi!()r(ihcii7ciie 2,2'-o\->'hls(l-Chl<ir(vm'™"^) 2,4,5-"rridihut>^iIuin4 2.4.6-riidd«riniliii\iil 2,4-Diddor<ii)liaiiil 2,4-Dimc(]iylphcnnl 2,4-Dinilrrphcnol 2,4-Dinilr(ilohiaic 2,6-Dinilr(i(ohicnc 2-CliIoron.Tphllialciic 2-Cliloro|ilienoI 2-McthylnaphlIi.nlaie 2-Mclliylphaiol 2-Nilr 0,111111110 2-Nilroplimol 3,3'-Didilorohcn7idinc 3-Nilro.iiiilinc 4,6-Dinilro-2-incthylpli«i(>l 4-llronirnilieiiyl-|)liaiyldlicr 4-C1iloro-3-niL-(liylpIiai(>l 4-Chloro:iniliiic 4-Clilor<i]iliaiyli'haiyUlln.T SBC2/0-I 1/30/95 VTxnoi .370. U 370. U 370. U 370.1) 370. U 900. 11 370. 11 370. U 370. U 900. U 370. U 370, IJ 370. U 370. U 370. U 370. U 900. U 370. U 370. U 900. 1) 900. U 370. U 370, U 370,11 370. U SBC2/20-22 1/30/95 VTxno2 390. U 390. U .390. U .390. U 390. U 950. U 390. 11 390. U 390. U 950. U 390. U 390. U 390. U 390. U 390. U 390. U 950. U 390. U 390. U 950. U 950. U 390. U 390. U 390. U 390. U SBC2/24-26 1/30/95 VTXn03 380. U 380. U 380.11 380. U 380. U 930. U 380.1) 380. U 380. U 930. U 380. U 380. U 380. U 380. U 380. U 380. U 930. U 380. U 380. U 930. I) 930,1) 380, U 380, U 380, U 380.1) SBDl/0-1 1/25/95 vsino2 360. U 360. U 360. U 360. U 360. U 880. U 360. 1) 360. U 360. U 880. U 360. U 360. U 360. U 360. U 360. U 360. U 880. U 360. U 360. U 880. U 880. U 360. U 360. U 360. U 360. U SBDI/I2-I4 1/25/95 V.>iI(KI3 400. U 400. U 400. 1) 400. I) 400.1) 960. U 400.1) 400. U 400. U 960. U 400.1) 400. U 400. U 400. U 400. U 400. U 960. U 400. U 400. U 960. 1) 960, 1) 400 U 400. 1) 400. 11 400, U SBDl/22-24 1/25/95 V.SIO(M 380,1) 380. U 380. U 380. U 380. U 920.1) 380. 11 380. U 380. U 920. U 380.1) 380. U 380. U 380. U 380. U 380. U 920. U 380. U 380. U 920.1) 920.1) 380.1) 380.1) 380,11 380, 1) SBD2/0-2 1/19/95 V0I1(HI3 410,1) 410,11 410,1) 410,1) 410,1) 1000, U 410 U 410,1) 410, U 1000, UJ 410. U 410. U 410. U 410. U 410. U 410. U 1000. U 410. U 410.U 1000, UJ IOOO. U 410,1) 410. I) 410 1) 410.1) SBD2/19-21 1/19/95 VQB004 370, U 370. U 370. U 370. U 370. U 910. U 370. U 370. U 370. U 910. UJ 370. U 370. U 370. U 370. U 370. U 370. U 910. U 370. U 370. U 910. UJ 910. U • 370. U 370. U 370. U 370.1) See last page of l^ble for notes. Harding Lawson Associates OJ o to <;y Table 4-3 Soil Sample Analytical Results - Semivolatile Organic Compounds Virgin Island Chemical Company Results reported in microgra 4-Mc(liyIpliuiol 4-Nilro.ini!i'iie 4-Nilr<nihi-iiol Acaiaplilliuie Acai.Tphlliylaie Antbraciaic Iliii7o(n);inlhr;icoic I)ui7ii(a)pyraic ncn7o(b)nuoranlliaic nai7o(gJi,i)pcr>Iaie nai7o(k)nuoraiitliaie bis(2-Chloroc(lii>\y)iiii1h:uie bis(2-ailoroc(liyl)i.ihcr bis(2-r;UiyIlicxyl)phlh3lalc nutyllicnzylphllialale CarhaTolc Qirysaic Di-n-hiitylphl)ia1ntc Di-n-odylplithalalc /lJ)iliai7(aJ0anlhracme "Bil)ai7iiriir:ui JJicUiylphtlialale y>nic(liylplillial.ile Viiior.Tiithciic Fluorene Sample Location: Sample Date: Lab Sample ID: ims per kilogram. Sec last page of table for notes. SBC2/0-I 1/30/95 n x n o i 370.1) 900. 11 900. 11 370. U 370. U 370.1! 370. 11 370. U 370. U 370. U 370. U 370. U 370. U 200. J 120. J 370. U 370. U 57. J 370. U 370,1) 370, 11 370,1) 370,1) 370,1) 370, U SBC2/20-22 1/30/95 VTX002 .390. U 950. U 950. U 390. U 390. U 390. U 390.1J 390. U 390. U 390. U 390. U 390. U 390. U 48. J 390. U 390. U 390:U 47. J 390. U 390. U 390. U 390. U 390. U 390. U 390. U Hardir SBC2/24-26 1/30/95 VTxnoj 380.1) 930.1) 930.1) 380. U 380. U 380. U 380. U 380. U 380. U 380. U 380. U 380. U 380. U 54. J 380. U 380. U 380. U 36. J 380. U 380. U 380. 1) 380.1) 380. U 380. U 380. U SBDI/O-l 1/25/95 v.sino2 360. U 880.1) 880. U 360. U 360. U 360. U 360. U 360. U 360. U 360. U 360. U 360. U 360. U 170. J 360. U 360. U 360. U 360. U 360. U 360.1) 360.1) 360. U 360. U 360. U 360. U iq Lawson Associates SBDl/12-14 1/25/95 vsi(m3 400. 1) 960. 1) 960. 11 400. U 400. 1) 400.1) 400.1) 400. U 400. U 400. U 400. U 400. U 400. U 52. J 400. U 400. U 400. U 400. U 400. U 400. 11 400. U 400.1) 400. 1) 400, 1) 400, 1) SBDl/22-24 1/25/95 vsinn-i 380, U 920,1) 920,1) 380, U 380,1) 380. U 380.1) 380. U 380. U 380. U 380.1) 380. U 380. U 36..I 380. U 380. U 380. U 380. U 380. U 380,1) 380, 1) 380,1) 380,1) 380,1) 380, U SBD2/0-2 1/19/95 V0I1(KI3 410,U 1000, 1) IOOO, UJ 410, U 410.11 410,1) 410. 1) 410, U 410, U 410, U 410, U 410, U 410, U 410, U 410, U 410, IJ 410. U 410, U 410, U 410,1) 410,1) 410, UJ 410. U 410. U 410. U SBD2/19-21 1/19/95 VQIMXM 370.11 910. UJ 910. UJ 370. U 370. U 370. U .370.11 370. U 370.'U 370. U 370. U 370. U 370. U 64. J 370. U 370. UJ 370. U 33. J 370. U 370. U 370. U ' 370. U 370. U 370. U 370 U Table 4-3 Soil Sample Analytical Results - Semivolatile Organic Compounds Virgin Island Chemical Company Sample Location: Sample Date: Lab Sample ID: Results reported in micrograms per kilogram. lIe.\adil()roliar/ciic IlexadilcTohiilailiaic llexadilorixrycli^iniladiciic IIexadil(ir(x.1liaiic Indaio(1.2,3-cd)]i\Tiiic Isojihiirciic N-Ni(rtwt»-<Ii-n-pMvvIaniitic N-Nilr<)s(HlipI]uiylaiiiinc Naplitlialcnc Nilrohai7ciie l'eiil.ndiloro(iliuiol lliai.-mllirciic lliciiol Pyraic Pyridine SBC2/0-1 1/30/95 VTXOOI 370. U 370. U 370. U 370. 1) 370. I) 370.1) 370. 11 370. U 370. U 370. U 900. U 370. U 370. U 370. U 370. U SBC2/20-22 1/30/95 VTX002 390. U 390. U 390. U .390. U 390. U .390.1) 390.11 390. U 390. U 390. U 950. U 390. U 390. U 390. U 390. U SBC2/24-26 1/30/95 VTXn03 380.1) 380.11 380.1) 380.1) 380.1) 380. U 380. U 380. U 380. U 380. U 930. U 380. U 380. U 380. U 380. U SBDl/0-1 1/25/95 V.SI002 360. U 360. U 360. U 360. U 360. U 360. U 360.11 360. U 360. U 360. U 880. U 360. U 360. U 360. U 360. U SBDl/12-14 1/15/95 VSII)()3 400. 1) 400. 11 400. I) 400. 1) 400. 11 400.1) 400. 11 400.1) 400. U 400. U 960. 1) 400. U 400.1) 400. U 400. U SBDl/22-24 1/25/95 VSIOW 380.1) 380. \ I 380.1) 380.1) 380. U 380. U 380. 11 380. U 380. U 380. U 920. U 380. U 380. U 380. U 380. U SBD2/0-2 1/19/95 VQIKKIJ 410.1) 410. U 410. UJ 410,1) 410, 11 410,1) 410 11 410,1) 410, U 410,1) 1000, U 410, 1) 410,1) 410,11 410, U SBD2/19-21 1/19/95 VQBIXM 370. U 370. U 370. U 370. U 370. U 370. U 370. U 370. U 370. U 370. U 9 I 0 . U 370. U 370. U 370. U 370. U OJ o to H Sec last page of table for notes. Harding Lawson Associates OJ o to H 00 B\ Table 4-3 Soil Sample Analytical Results - Semivolatile Organic Compounds Virgin Island Chemical Company Page? Sample Location: Sample Dale: Lab Sample ID: Results reported In micrograms per kilogram. 1,2,4-Tridilori>lK-n7nic 1,2-nidiloro)icn7oic 1,3-I5idilorolicir/ciic 1,4-DidilorohcirAiie 2,2'-o.\-ylii.s( 1-Chhir<Vr( V'""-') 2,4,5-rridilor<i)liaiiil 2,4,6-lridil(iniilini<>l 2,4-Didiloroi)hmol 2,4-Dimctliylphmol 2,4-Dinitropliaiol 2,4-Dinilrololiiuic 2,6-Diiiilrotohiuie 2-CUlorcnaplitlialaic 2-Clilorophciiol 2-MctliyIunphllialaic 2-MctliyIphaiol 2-Nitroaiiiliiic 2-Nilioplimol 3,3'-Didilorol)cii7idiiic 3-Nilroaiiilinc 4,6-ninilr(>-2-mdIiylpliciiol 4-Urom()pliciiyl-])hniylcllicr 4-Chloro-3-nirtliyIpliai(il 4-Chl(n'o:iniIiiic 4-Chlor(vhaiyl-i)lic3iyli.-tha- Sec last page of table for notes. SBD3/0-2 1/20/95 VQAimi 370.1) 370.1) 370.1) 370. U 370. U 900. 1) 370.11 370. 1) 370. U 900. UJ 370. U 370. U 370. U 370. U 370. U 370. U 900. U 370. U 370. U 900. U 900. U 370. U 370.1) 370.11 370.1) SBD3/17-19 1/20/95 VQA003 370. U 370.1) 370. U .370. U 370. U 910. U 370.11 370. U 370. U 910. UJ 370. U 370. U 370. U 370. U 370. U 370. U 910. UJ 370. U 370. U 910. UJ 910.U 370. U 370. U 370. U 370. U Harding SBD4/0-I 1/27/95 vrviMC 460. U 460. U 460. U 460. U 460. U 1100. U 460. U 460. U 460. U IIOO.UJ 460. U 460. U 460. U 460. U 460. U 460. U IIOO.U 460. U 460. U IIOO.UJ IIOO.UJ 460. U 460. U 460. UJ 460. U SBD4/14-16 1/27/95 VTKOm 380. U 380. U 380. U 380. U 380. U 930. U 380. U 380. U 380. U 930. UJ 380. U 380. U 380. U 380. U 380. U 380. U 930. U 380. U 380. U 930. UJ 930. UJ 380. U 380. U 380. UJ 380. U Lawson Associates SBD4/20-22 1/27/95 VrMXlH 390.11 390. 1) 390.1) 390.1) .390.1) 940. 1) 390. 11 .390. U 390. U 940. UJ .390. U 390. U 390. U 390. U 390. U 390. U 940. U 390. U 390. U 940. UJ 940. UJ .390.1) 390. U 390. 1 IJ 390. U SBEl/0-2 1/18/95 VOC003 350. U 350. 11 3.50. U 350. U 350. U 860. U 350.1) 350. U 350. U 860. UJ 350. U 350. U 350. U 350. U 350. U 350. U 860. UJ 350. U 350. U 860. UJ 860. 1) 3-W 1) 350.1) 350.1) 350.1) SBEl/20-22 1/19/95 V(JI1IK)2 380. 1) 380. 11 380. U 380. U 380. U 930. 11 380. U 380. U 380. U 930. UJ 380.1) 380. U 380. U 380. U 380. U 380. U 930. UJ 380. U 380. U 930. 1 )J 930. U 380. 1) 380. U 380. 1) 380.1) SBF2/12-1S 1/24/95 VSR002 350. U 350. U 350. U 350. U 350. U 860. U 350. U 350. U 350. U 860. UJ 350. U 350. U 350. U 350. U 350. U 350. U 860. U 350. U 350. U 860. UJ 860. UJ 35d U 350. U 350. UJ 350. U . - ^ W" ty S Table 4-3 Soil Sample Analytical Results - Semivolatile Organic Compounds Virgin Island Chemical Company OJ c to Sample Location: Sample Dale: Lab Sample IT): ResuUs reported in micrograms per kilogram. 4-MLlIiylpliciiol 4-Nilro;iniliiic 4-NilropIiuiol Acaiaphlliaic Accji.T]ililhylaie Anlliracaic nm7n(a):iiilbrin.«ie Hai/n(a)p)Taie ncnzn(b)nuoranlIiaic ncnzn(gji,i)pcrylcne ncn7n(k)n«or;ai(haic bis(2-Chlorodlioxy)mc<h;iiic bis(2-aiIoroc(liyI)dhcr bis(2-F.UiyllicK>'l)phUialate niilyUiaizylphtlial.ite CnrbaTolc Chrysene Di^l-lnltylphlllal:llc Di-n-octylphllial.nic Dihcii7(aJ>)aiilhrncoic niliai7nrnr:ui Dietliylphlhalalc nimcO\ylphlh;il:ilc I'luor.TiUhcjic Fliiorme See last pare of table for notes. SBD3/0-2 1/20/95 VOAn02 370. U 900.1) 900. UJ 370. U 370.1! 370. 1) 370. 11 370. U 370. U 370. U 370. U 370. U 370. U 370. U 370. U 370. UJ 370. U 370. U 120. J 370. t) 370.1) 370.1) 370. U 370,1) 370.1) SBD3/17-19 1/20/95 VQA003 370. U 910.U 910.UJ 370. U 370. U 370. U 370. 1) 370. U 370. U 370. U 370. U 370. U 370. U 370. U 370. U 370. U 370. U 370. U 370. U 370.1) 370. U 370. UJ 370. U 370. 1) 370. U Hardinc SBD4/0-1 1/27/95 VTFtKW 460. U IIOO.UJ IIOO.UJ 460. U 460. U 460. 1) 460. 11 460. U 460. U 460. U 460. U 460. U 460. U 75. J 460. U 460. UJ 460, U 32. J 460. U 460.1) 460. 1) 460. 1) 460, U 460,1) 460, U SBD4/14-16 1/27/95 VTfW)7 380, U 930, UJ 930, \IJ 380, U 380. U 380. U 380. U 380. U 380. U 380. U 380. U 380. U 380. U 47. J 380. U 380. UJ 380. U 380. U 380. U 380. U 380. U 380.1) 380. U 380. U 380. U 1 Lawson Associates SBD4/20-22 1/27/95 VTHMIH 390.1) 940.1U 940. 1 )J 390. U 390.1) 390 11 390. 11 390. U 390. U 390. U 390. 1) 390. U 390. U 120. J 390. U 390. UJ 390. U 34. J 390.11 390. 1) 390. 11 390. 1) 390. U 390. 11 390. 1) SBEl/0-2 1/18/95 VQa)03 350. U 860. U 860. UJ 350.1) 350. U 350. U 350.1) 350. U 350. U 350. U 350. U 350. U 350. U 94. J 350. U 350. U 350. U 350. U 350.11 350.1) 350 11 350. DJ 350. U 350. 1) 350.1) SBEl/20-22 1/19/95 VQni)02 380. U 930. U 930. 1) J 380.1) 380.11 380.1) 380. 1) 380. U 380. U 380. U 380.11 380. U 380. U 380. U 380. U 380. 1J 380. U 380. U 380. U 380.1) 380 1) 380. UJ 380.1) 380. I) 380, U SBF2/12-15 1/24/95 VSR002 350, U 860. UJ 860. UJ 350. U 350. U 350. U 350.1) 350. U 350. U 350. U 350. U 350. U 350. U 58. J 350. U 350. UJ 350. U 350. U 350. U 350. U 350.1) • 350 1) 350,1) 350,1) 3.50,11 Table 4-3 Soil Sample Analytical Results - Semivolatile Organic Compounds Virgin Island Chemical Company Ui o to i > to o Results reported in microgi Ilexadilonihai7«ie ncxadilor(^ljiit:idiciic Ilexadilorocychipailadiwie Ilcxadilormlliaiie hulciio(l ,2,3-cd)ii>T«ie Isi^llKUfllC N-Nili'»vsii-tii-ii-)*rtin'I;nuiiic N-NilrosiKlipliuiyliunine N.TphlhaIcnc NitrohmTaic Pail.ndihirophcnol llicnantlmiic Iliaiol P>Tcnc P)ridiiic Sample Location: Sample Date: Lab Sample ID: rams per kilogram. SBD3/0-2 1/20/95 VQAOnz 370. U 370. I) 370. 1) 370. 1) 370. 11 370. U 370. 11 370. U 370. U 370. U 900.1) 370. U 370. U 370. U 370. U SBD3/17-19 1/20/95 VQA003 370. U 370.11 370. IV 370. U 370. U 370.1) 370.11 370. U 370. U 370. U 910. U 370. U 370. U 370. U 370. U SBD4/0-1 1/27/95 vrnxw 460. U 460. U 460.1 )J 460. U 460. U 460. U 460.1) 460. U 460. U 460. U IIOO.U 460. U 460. U 460. U 460. U SBD4/14-16 1/27/95 vrroo? 380. U 380.1) 380. UJ 380. U 380. U 380. U 380.11 380. U 380. U 380. U 930. U 380. U 380. U 380. U 380. U SBD4/20-22 1/27/95 VlfWlS 390. U 390. 11 390. UJ 390. 1) 390.1) 390.11 390. 1) 390. U 390. U 390. U 940. I / 390. U 390. U 390. U 390. U SBEl/0-2 1/18/95 VQcnoj 350.1) 350.11 350. UJ 350. U 350. U 350.11 350. 1) 350. U 350. U 350. U 860. U 350. U 350. U 350. U 350. U SBEI/20-22 1/19/95 VQn()02 380.1) 380.1) 380. UJ 380. U 380.1) 3K0.1) 380. 11 380. U 380. U 380. U 9.30.1) 380. U 380. U 380. U 380. U SBF2/12-15 1/24/95 VSR002 350. U 350. U 350. UJ 350. U 350. U 350. U 350. U 350. U 350.U 350. U 860. U 350. U 350. U 350. U 350. U See last page of table for notes. Harding Lawson Associates . €\ Table 4-3 Soil Sample Analytical Results - Semivolatile Organic Compounds Virgin Island Chemical Company OJ o to i > to H Sample Location: Sample Date: Lab Sample ID: Results reported in micrograms per kilogram. 1,2,4-Tridilorol)cji7cnc 1,2-nidilorol>cii7uic 1,3-Didilnrolicn7uic 1,4-nidilorobav/oic 2,2'-oxyI)i.s(l-CIiloroiir(ni.nic) 2,4,5-'rridiloni(ihaiol 2,4,6-'rridil<>iiiiluinil 2,4-Didiloriiphciiol 2,4-DimctliyIphaiol 2,4-ninitrophcnol 2,4-Dinitrotohiciic 2,6-Dinilnilohiaic 2-CliIoronaphlhalaic 2-Qilorophaiol 2-MctliyIn.Tphllialcnc 2-MclliyIphaiol 2-Nitro.Tniline 2-Nitroplicnol 3,3'-Didilorobai7idinc 3-Nilro.'uiiIine 4,6-Dinilro-2-mclliylpliiiui! .4-nrnmnpliaiyl-phuiyli.-llicr k4-Clilor(v3-mctliyIphcii<i! N-CliIoro.inilinc I •4-CliIor(ii>liaiyl-iihciiylctlicr SBF2/I8-20 1/24/95 v.snnn3 SBF3/0-1 1/24/95 VSROOI SBF3/12-14 1/24/95 VSRCKlT SBF3/18-20 1/24/95 VSRIXW 380. U 380. U 380. U 380. U 380. U 930. U 380. 11 380. U 380. U 930. UJ 380. U 380. U 380. U 380. U 380. U 380. U 930. U 380. U 380. U 930. UJ 930.1 IJ 380. U 380. U 380. UJ 380. U 380. U 380.1) 380.1) 380. \} 380. U 920.1) 380. U 380. U 380. U 920. UJ 380. U 380. U 380. U 380. U 380. U 380. U 920. U 380. U 380. U 920. UJ 920. UJ 380. U 380. U 380. UJ 380. U 370. U 370. U 370. U 370. U 370. U 900. U 370.1) 370. U 370. U 900. UJ 370. U 370. U 370. U 370. U 370. U 370. U 900. U 370. U 370. U 900. tJJ 900. UJ 370. U 370. U ,370, UJ 370. U 370. U 370.1) 370. U 370. U 370. U 900. U 370.1) 370. U 370. U 900. UJ 370. U 370. U 370. U 370. U 370. U 370. U 900. U 370. U 370. UJ 900. UJ 900. UJ 370. U 370. U 370. UJ 370. U See last page of table for notes. Harding Lawson Associates ...tai... \ , Table 4-3 Soil Sample Analytical Results - Semivolatile Organic Compounds Virgin Island Chemical Company Sample Location: Sample Date: Lab Sample ID: Results reported in micrograms per kilogram. SBF2/18-20 1/24/95 V.SRn03 BF3/0-1 1/24/95 VSR004 SBF3/12-I4 1/24/95 V.SROO? SBF3/18-20 1/24/95 VSRIHW OJ o to it^ to to 4-Mc(liylplicnol 4-Nilro.iniline 4-Nilr(Tihciiol Acai.Tphlliaie Accn.Tphlhylaic Anlhnicoic 1 Uiv/ii(a)aiidir:n."i'iic I)cirAi(a)j))Taie nai7jo(b)nuoranUiciic nai7n(gji ,i)pcrylcnc ncn7o(k)nuoranlluiic bis(2-Clilorot(boxy)me<h:u>c bis(2-ailoroctIiyl)ithcr bis(2 -EUiylli cxyl )phllial al c nutylbaizj'lphllial al e Carba7olc Cliryscnc Di-n-biilylphtlialnic Di-n-octylphllialale nibai7(aJi);mllir.Tciiic r)iban7oriir:ui nictliylphlliahile nimcdiylphlhahilc Fluor;mthi.nc Miioraic 380. U 930. 1U 930. UJ 380. U 380. U 380. U 380. 11 380. 1) 380. U 380. U 380. U 380. U 380. U 98. J 380. U 380. UJ 380. U 380. U 380. U 380. U 380. U 380.1) 380. U 3S0.1) 380. U 380. U 920. UJ 920. UJ 380. U 380. U 380. U 380.11 380. U 380. U 380. U 380. U 380. U 380. U 720. 490. 380. UJ 380. U 380. U 380. U 380. U 380. U 380. U 380. U 380.1) 380. U 370. U 900. UJ 900. UJ 370. U 370. U 370. U 370.1) 370. U 370. U 370. U 370. U 370. U 370. U 65. J 370. U 370. UJ 370. U 370. U 370. U 370.1) 370. U 370. U .370. U 370. U 370. U 370. U 900. UJ 900.1) J 370. U 370. U 370. U 370. 1) 370. U 370. U 370. U 370. U 370. U 370. U 32. J 370. U 370. U 370. U 370. U 370. UJ 370.1) 370. U 370. U 370. U 370. U 370. U Sec last page of table for notes. Harding Lawson Associates f : ;• .\,- ,r y i • •-') f ^- '(. • \ * Table 4-3 Soil Sample Analytical Results - Semivolatile Organic Compounds Virgin Island Chemical Company Sample Location: Sample Dale: Lab Sample ID: Results reported in micrograms per kilogram. ncxadilnroheii7ciie Ilcxadilorobuladiaie IIcxadi!iirix.'5cl(iinil:i(!lnic Ilcxadilnrocdi.inc Indaiii(l ,2,3-cd)|nTciic Is(iilioroiic N-Nil^o^;ll-^li^l-pn^lylalllilU• N-NitrosiKlipboiyl.Miiinc Naphllialcnc Nilrobai7aic Pcjiladiloropbcnol lliaiaiillirnie Iliaiol I'yraic Pyridine SBF2/I8-20 1/24/95 VSR0II3 380. U 380. 1) 380. UJ 380. U 380.1) 380. U 380. U 380. U 380. U 380. U 930. U 380. U 380. U 380. U 380. U SBF3/0-1 1/24/95 VSR004 380. U 380. U 380. UJ 380. U 380.1) 380. U 380.11 380. U 380. U 380. U 1900..I 380. U 380. U 380. U 380. U SBF3/12-14 1/24/95 VSR007 370. U 370. U 370. UJ 370. U 370. U .370.1) 370. 11 370. U 370. U 370. U 900. U 370. U 370. U 370. U 370. U SBF3/I8-20 1/24/95 vsnnm 370. U 370. U 370. UJ 370. U 370. U 370. IJ 370.11 370. U 370. U 370. U 900. UJ 370. U 370. U 370. U 370. U OJ o to to n - Detected in s;iiiiplc .ind as.sixH.nlcd bhuik O - Compound qu.intilalcd ui a dihilcd sample F. - Exceeded the calibralim range ofinstnimail J-E.'itiin.nlcd Value R - Result was rejected during d:il:i validalicii U - Aiialy7ed Iml mil dclcttcil X - M.inual addition of cis :iml Iriuis is<iiiicrs Harding Lawson Associates .^.. OJ o to to Table 4-4 '^' Soil Sample Analytical Results - Pesticides and PCBs Virgin Island Chemical Company Sample Location: Sample Dale: Lab Sample ID: Results reported in micrograms per kilogram. 4,4'-Dnn 4.4'-DI)i; 4.4'-DDr Alibin alpha-nilC alpba-ChIord:uic A i i K h i i - 1 0 1 6 Aroclor-1221 Aroclor-1232 Aroclor-1242 Aroclor-1248 Aroclor-1254 Aroclor-1260 bda-nHC dcita-nnc Dieldrin rjulosiilfiui I nndosiilfan II riidosnlfini Sulfate Fjiilrin I jub-in alddiydc rjiilrin kctoie ganima-llllC (Lindane) g;>iiiiiia-Chli>ril:ino Ilcptadilor SBBI/0-1 1/31/95 WC0(I2 4.1 U 4.1 U 4.1 U 2.11) 2.1 U 2.1 1) 41.U 82.1) 41.U 41.U 41.U 41.U 41.U 2.1 U 2.1 U 4.1 U 2.1 U 4.1 U 4.1 U 4.1 K 4.1 1) 4.1 1) 2.1 11 2.1 U 2.1 U SBBI/0-1 1/31/95 WCIKH 3.9 11 3.911 3.9 U 2. U 2. U 2.1) 39. U 79. U 39. U 39. U 39. U 39. U 39. U 2. U 2.U 3.9 U 2.U 3.9 U 3.9 U 3.9 R 3.91) 3.9 U 2.11 2. U 2. U SBBl/6-8 1/31/95 wnno3 4.6 UJ 4.6 UJ 4.6 UJ 2.4 UJ 2.4 UJ 2.4 UJ 46. DJ 92. UJ 46. UJ 46. UJ 46. UJ 46. UJ 46. UJ 2.4 UJ 2.4 UJ 4.6 UJ 2.4 UJ 4.6 UJ 4.6 U j ' 4.6 R 4.6 UJ 4.6 UJ 2.4 UJ 2.4 UJ 2.4 UJ SBBl/24-26 1/31/95 WGOOS 4.1 U 4.1 U 4.1 U 2.1 U 2.1 U 2.1 U 41.1) 82. U 41.U 41.U 41.U 41.U 41. U 2.1 U 2.1 U 4.IU 2.1 U 4.1 U 4.1 U 4.1 \X 4.1 U 4.1 U 2.1 1) 2.1 1) 2.1 U SBCl/0-1 1/27/95 V1HKI2 4. DJ 4. 11J 4.I)J 2.1 1 IJ 2.1 UJ 2.1 UJ 40. 1 IJ 81. UJ 40. UJ 40. UJ 40. UJ 40. UJ 40. UJ 2.1 UJ 2.1 DJ 4. UJ 2.1 DJ 4. DJ 4. DJ 4. 1( 4. DJ 4. 1 U 2,1 UJ 2.1 1 IJ 2,1 UJ SBCl/16-18 1/27/95 VTtT)03 3,7 1) 3,7 U 3,711 1,91) 1,9 UJ 1,9 U 37,11 75. U 37. U 37. U 37. U 37. U 37. U 1.9 1) 1.9 U 3.7 U 1.9 U 3.7 U 3.7 U 3.7 R 3.7 11 3.7 D 1.9 1) 1.9 11 1.9 U SBCI/18-20 1/27/95 VTfXKM 4.1) 4. D 4.1) 2.1 D 2.1 DJ 2.1 U 40. D 81.D 40. U 40. U 40. D 40. U 40. U 2.1 1) 2.1 U 4. D 2.1 D 4. D 4. U 4.R 4.1) 4.1) 2.) U 2.1 U 2.1 D SBCl/20-22 1/27/95 VTF005 3.9 U 3.9 U 3.9 U 2.U 2.UJ 2.U .39. U 78. U 39. U 39. U 39. U 39. U 39. U 2.1) 2.U 3.9 U 2. U 3.9 U .3.9 U 3.9 R 3.91) 3,9 U 2,1) 2, U 2,U See last page of table for notes. Harding Lawson Associates f"' Table 4-4 Soil Sample Analytical Results - Pesticides and PCBs Virgin Island Chemical Company Sample Location: Sample Date: Lab Sample ID: Results reported In micrograms per kilogram. Ilqitadilor qioxidc Mdhoxydilor 'I'ox.Tiihaic SBBl/O-l 1/31/95 \'V(;o(i2 2.1 UJ 21.11 210.1) SBBI/0-1 1/31/95 WCOOI 2.UJ 20.1) 200. U SBBl/6-8 1/31/95 wr.ofl3 2.4 UJ 24. UJ 240. UJ SBBI/24-26 1/31/95 WCIKIS 2.1 UJ 21.U 210.U SBCl/0-1 1/27/95 VTOKI2 2.1 DJ 21. DJ 210. 1IJ SBCl/16-18 1/27/95 VTHI03 1.9 DJ 19. D 190. D SBCI/18-20 1/27/95 VTMKII 2.1 DJ 21.1) 2I0.D SBCl/20-22 1/27/95 VTFOOS 2.UJ 20. U 200. U OJ o to to cn See last page of Iable for notes. Harding Lawson Associates Table 4-4 Soil Sample Analytical Results - Pesticides and PCBs Virgin Island Chemical Company OJ o to to a> Sample Location: Sample Date; Lab Sample ID: Results reporteil in micrograms per kilogram. 4.4'-DDD 4,4'-DDn 4,4'-DDr Aldrin nlpha-nilC nlpha-Cblord:inc Arix;lix--10l6 Aroclor-1221 Aroclor-1232 Aroclor-1242 Aroclor-1248 Aroclor-1254 Aroclor-1260 bela-nilC dclta-nilC Dieldrin nndosuiran I nndosiilfan II nndosnlfan Siiiral c Fn drill I'jidrin alddiydc r.ndrin kdme gainma-llIlC (I.iiul.-uic) g.Tmina-CliIord.tiio llqiladilor SBC2/0-1 1/30/95 VIXOfll 3.7 U 3.7 1) 3.7 U 1.9 U 1.9 1IJ 1.9 D 37. 11 74. D 37. U 37. U 37. 1) 37. U 37. U 1.9 U 1.9 U 3.7 U 1.9 U 3.7 U 3.7 U 3.7U 4.2.1 3.7 U 1.9 U 1.9 U 1.9 U SBC2/20-22 1/30/95 VTXD02 3.9 U 3.9 U 3.9 U 2. U 2. UJ 2. U .39.11 79. U 39. U 39. U 39. U 39. U 39. U 2.U 2.U 3.9 U 2. U 3.9 U 3.9 U 3.9 U 3.9 U 3.9 U 2. U 2.U 2. U SBC2/24-26 1/30/95 VTX003 3.8 U 3.8U 3.8 U '2.U 2.UJ 2. U 38.1) 77. U 38. U 38. U 38. U 38. U 38. U 2.U 2.U 3.8U 2.U 3.8U 3.8U 3.81) 3.81) .3.8 U 2.U 2. U 2.U SBDl/0-1 1/25/95 VSI002 3.6 U 3.6 U 3.6 U 1.9 U 1.9 UJ 7.2 J 36. U 73. U 36. U 36. U 36. U 36. U 36. U 1.9 U 1.9 U 3.6 U I.9U 3.6 U 3.6 U 3.6 D 3.6 U 3.6 U 1.9 U 7.7 I.9U SBDl/12-14 1/25/95 vsions 4.1) 4.1) 4.1) 2. D 2.1)J 2.1) 40. D 80. D 40. U 40. U 40. U 40. U 40. U 2. U 2. U 4.U 2.U 4. U 4. U 4.1) 4.D 4.11 2.1) 2.1) 2.1) SBDl/22-24 1/25/95 V.SI004 3.8 U 3.8U 3.8 U 2.U 2.UJ 2. U 38. U 76. U 38. U 38. U 38. U 38. U 38. U 2.U 2.U 3.8 U 2.U 3.8 U 3.8 U 3.811 3.8 U 3.8 U 2.1) 2. U 2. U SBD2/0-2 1/19/95 VQB003 4.1 U 4.1 U 4.1 1) 2.1 1) 2.1 D 2.1 D 41.11 82. D 41.U 41.U 41.U 41. U 41.U 2.1 U 2.1 U 4.1 U 2.1 U 4.1 U 4.1 U 4.1 U 4.1 1) 4.1 U 2.1 1) 2.1 U 2.1 U SBD2/19-21 1/19/95 VQIWKM 3.7 U 3.7 U 3.7 U 1.9 U 1.9 U 1.9 U 37. U 75. U 37. u ' 37. U 37. U 37. U 37. U I.9U 1.9 U 3.7 U 1.9 U 3.7 U 3.7 U 3.7 U 3.7 U 3 7<; 1.91) 1.9U 1.9 U See last page of table for notes. Harding Lawson Associates Table 4-4 Soil Sample Analytical Results - Pesticides and PCBs Virgin Island Chemical Company !.<>SW^ Sample Location: Sample Dale: Lab Sample ID: Results reported in micrograms per kilogram. Ilcptadilor epoxide Mclhoxydilnr Toxaphene SBC2/0-1 1/30/95 \TX00l 1,91) 19. U I90.U SBC2/20-22 1/30/95 VTX002 2.U 20. U 200. U SBC2/24-26 1/30/95 VTXnfl3 2.U 20. U 200. U SBDl/0-1 1/25/95 V.SI002 1.9 U 19. U 190. U SBDl/12-14 1/25/95 VSirK)3 2.1) 20.1) 200. U SBDl/22-24 1/25/95 vsion4 2. U 20. U 200. U SBD2/0-2 1/19/95 VQn0()3 2.1 U 21.U 210. U SBD2/I9-21 1/19/95 VQB004 1.9 U 19. U 190. U OJ o to See last page of table for notes. Harding Lawson Associates . . - < * Table 4-4 Soil Sample Analytical Results - Pesticides and PCBs Virgin Island Chemical Company OJ s> to '. 00 , Pages ' Sample Location: Sample Date: Lab Sample ID: Results reported in micrograms per kilogram. 4.4'-nDD 4,4'-DDi; 4.4'-DDT Aldrin .nlpha-nilC aIpIia-CIilord;ine Ar(vlnr-1016 Aroclor-1221 Aroclor-1232 Aroclor-1242 Aroclnr-1248 Aroctor-1254 Aroclor-1260 bda-nilC dclla-nnC Dieldrin nndosnlfan I Hndosulfan II nndosnlfan Sulfate Fiidrin llnilrin alddiydc Fjubin ketone g.Tmma-llllC (1 .iiid;nic) g.iinma-CliIord:mc Ilqitadilor ^ SnD3/0-2 1/20/95 VQAn02 3.7 U 3.7 U 3.7 U 1.91) 1.9U 1.9 U 37.11 74. U 37. U 37. U 37. U 37. U 37. U 1.9 U 1.9 U 3.7 U 1.9 U 3.7 U 3.7 U 3.7 U 3.7 II 3.7 1) 1.9 U 1.9 U 1.9 U SBD3/17-I9 1/20/95 VQA003 3.7 U 3.7 U 3.7 U 1.9 U 1.9U 1.9U 37.1) 75. U 37. U 37. U 37. U 37. U 37. U 1.9U 1.9U 3.7 U 1.9U 3.7 U 3.7 U 3.7 U 3.7 U 3.7 U 1.9 U 1.91) 1.9 U SBD4/0-1 1/27/95 VTPOOS 4.6 U 4.6 U 4.6 U 2:4 U 2.4 UJ 2.4 U 46.11 93. U 46. U 46. U 46. U 46. U 46. U 2.4 U 2.4 U 4.6 U 2.4 U 4.6 U ' 4.6 U 4.6 R 4.61) 4.61) 2.4 U 2.4 1) 2.4 U SBD4/14-16 1/27/95 VTF007 3.8 U 3.8 U 3.8 U 2.U 2.UJ 2.U 38.11 77. U 38. U 38. U 38. U 38. U 38. U 2.U 2.U 3.8 U 2.U 3.8 U 3.8 U 3.8 R 3.8 U 3.81) 2.U 2.1) 2.U SBD4/20-22 1/27/95 VTHHI8 3.9 U 3.91) 3.9 1) 2. U 2. W 2.1) 39.1) 78. U 39. U 39. U .39.1) 39. U 39. U 2. U 2. U 3.9 U 2.U 3.9 U 3.9 U 3.9 R 3.9 I) 3.9 1) 4.8 2. D 2. U SBEl/0-2 1/18/95 VQCD03 .3.5 U 3.5 U 3.5 U 1.8U 1.8U 4.6 J 35.1) 71.U 35. U 35. U 35. U 35. U 35. U I.8U 1.8 U 3.5 U I.8U 16. J 3.5 U 3.5 U 3.5 U 3.5 1) 1.81) 4.8.1 1.81) SBEl/20-22 1/19/95 VQIKIOI 3.8 DJ 3.8 DJ 3.8 UJ 2. DJ 2. DJ 2.DJ 38.1 IJ 77. UJ 38. UJ 38. DJ 38. DJ 38. DJ 38. UJ 2.UJ 2. UJ 3.8 UJ 2. UJ 3.8 UJ 3.8 UJ 3.8 UJ 3.8 UJ 3.8 lU 2. DJ 2. DJ 2. UJ SBF2/I2-15 1/24/95 VSR002 3.5 UJ 3.5 UJ 3.5 UJ 1.8 UJ 1.8 UJ 1.8 UJ 35. UJ 71. UJ 35. UJ 35. UJ 35. UJ 35. UJ 35. UJ 1.8 UJ 1.8 UJ 3.5 UJ 1.8 UJ 3.5 UJ 3.5 UJ 3.5 R 3.5 UJ 3.5 <)J 1.8 UJ 1.8 UJ 1.8 UJ See last page of table for notes. Harding Lawson Associates . . < Table 4-4 Soil Sample Analytical Results - Pesticides and PCBs Virgin Island Chemical Company Sample Location: Sample Date: Lab Sample ID: Results reporle<l in micrograms per kilogram. Ilcptadilor epoxide Metlioxydilor Tox.nplicnc SBD3/0-2 1/20/95 VQA0(12 1.91) 19. U 190. U SBD3/17-19 1/20/95 VQA003 I.9U 19. U 190. U SBD4/0-1 1/27/95 \JfW6 2.4 UJ 24. U 240. U SBD4/14-16 1/27/95 VTP007 2.UJ 20. U 200. U SBD4/20-22 1/27/95 VTHMIS 2. UJ 20. U 200. U SBEI/0-2 1/18/95 VQC0O3 1.8 U I8.U I80.U SBKl/20-22 1/19/95 VOI1()02 2. UJ 20. UJ 200. UJ SBF2/12-15 1/24/95 VSROOl 1.8 UJ 18.UJ 180.UJ OJ o to lli to VD Sec last page of table for nolcsi Harding Lawson Associates Table 4-4 Soil Sample Analytical Results - Pesticides and PCBs Virgin Island Chemical Company Sample Location: Sample Date: Lab Sample ID: Results reportcil in micrograms per kilogram. SBF2/18-20 1/24/95 VSR003 SBF3/0-1 1/24/95 VSRO(M SBF3/12-15 1/24/95 VSR007 SBF3/18-20 1/24/95 VSR009 4,4'-DDD 4.4'-DDl', 4,4'-DDT Aldrin alpha-nilC alpIia-Clilord:ine Arivlor-1016 Arocior-1221 Aroclor-1232 Aroclor-1242 Aroclor-1248 Aroclor-1254 Aroclor-1260 beta-nilC dclta-nilC Dieldrin Undosulfim I Endosulfan II Endosulfan Sulfate Endrin OJ Endrin alddiydc O IO Endrin kcloic OJ O g.Tmma-niIC (l.ind:uie) g.Tiimia-CliIord;uie Ilcptadilor 3.8 U 3.8 U 3.81) 2. U 2. UJ 2.1) 38.11 77.1) 38. U 38. U 38. U 38. U 38. U 2. U 2. U 3.8 U 2. U 3.8 U 3.8 U 3.8 R 3.8 U 3.8 U 2. U 2. U 2. U 3.8 UJ 3.8 UJ 3.8 UJ 2. UJ 2. UJ 3.9 PJ 38. UJ 76. UJ 38. UJ 38. UJ 38. UJ 38. UJ 38. UJ 2.UJ 2.UJ 3.8 UJ 2.UJ 3.8 UJ 3.8 UJ 5. PJ 4. PJ 3.8 UJ 2. UJ 4.1 PJ 2. UJ 3.7 U 3.7 U 3.7 U 1.9 U 1.91) I.9U .37. U 74. U 37. U 37. U 37. U 37. U 37. U 1.9 U 1.9 U 3.7 U 1.9U 3.7 U 3.7 U 3.7 R 3.7 U 3.7 U 1.9U , 1.9 U I.9U 3.7 U 3.7 U 3.7 U 1.9U 1.9U 1.9 U 37. U 74. U 37. U 37. U 37. U 37. U 37. U 1.9 U I.9U 3.7 U 1.9 U 3.7 U 3.7 U 3.7 K 3.7 U 3.7 U 1.9 U 1.9 U 1.9 U See last page of table for noles. Harding Lawson Associates Table 4-4 Soil Sample Analytical Results - Pesticides and PCBs Virgin Island Chemical Company Sample Location: Sample Dale: Lab Sample ID: Results reported in micrograms per kilogram. SBF2/I8-20 1/24/95 VSR003 SBF3/0-1 1/24/95 vsRoai SBF3/I2-15 1/24/95 VSR007 SBF3/18-20 1/24/95 V.SROO? Ilcptadilor epoxide Mdlioxydilor Tox.TpIione 2. UJ 20. U 200. U 2. UJ 20. UJ 200. UJ 1.9 UJ 19. U 190. U 1.9 UJ 19. U I90.U n - Detectetl in s-Tniplc .ind ass(x.-i:iled hhnik D - Compoiuid (]iianlit:iled <«i a diluted siuiiplc V, - I;xccc<lc«l tlie calihraliiiii i:uige orinslnimnit J - E^imnte<l Value P - >25% dilfercncc between 2 GC columns U - Analyzed but not detected X - M.inual addition of cis .-md trans isomers OJ O to OJ Harding Lawson Associates y % Table 4-5 Soil Sample Analytical Results - Inorganics Virgin Island Chemical Company Pagel Sample Location: Sample Dale: lyab Sample ID: Results reportcil in milligrams per kilogram. SBBl/0-1 1/31/95 WCflfl2 SBBl/0-1 1/31/95 W « X M SBBl/6-8 1/31/95 W G 0 0 3 SBBl/24-26 1/31/95 WGOOS SBCl/0-1 1/27/95 inmm SBCl/16-18 1/27/95 VrF003 SBCI/18-20 1/27/95 VTH)fl4 SBCl/20-22 1/27/95 VTPOOS OJ O to iAi to Aliuiiiniun • Anlimmy Arsmic Dariimi ncryllium Catbiiium Cnlciuiii Cliromiuin Cobalt Copper Cyanide Iron Lead Magncsiimi Manganese Mcrau-y Nickel Potassiiun Selenium Silver Sodium Tliallium V.Tnadium 7.mc 23300. *J 0.34 NU 0.27 NK 197. 0.32 2.8 N*J 17800. 19.9 *J 29.6 54.5 N*J 1.2 NR 32100. "J 3.4 NS*J 7260. 1860. 0.29 19.2 *J 4180. 0.34 NWR 1.3 U 575. B 0.66 U 109. NJ 72.7 EM 28200. *J 0.33 NR 1.5 NR 268. 0.58 3.1 N*J 12200. 21.9 *J 31.7 58.4 N* J 1.2 NR 37000. * J 7.1 N*J 7760. 2100. 0.12 U 24.7 * J 4330. 3.3 NR 1.2 U 702. n 0.64 U 110. NJ 3620. E* J 26400. *J 0.39 NU 0.3 NU ill. 0.35 3.8 N*J 35400. 27.2 *J 18.7 60.2 N*J 1.4 NR 39500. -J I.8NW*UJ 10800. 739. 0.16 18.9 "J 2520. 0.39 NWR I.4U 2140. 0.75 U 165. NJ 76.3 E*J 17600. * J 0.35 NR 0.27 NR 87.4 0.36 3. N*J 6550. 28.2 * J 16.4 47.3 N« J 1.2 NR 33100. *J 2.8 N* J 7070. 545. 0.12 U 18.1 «J 1130. B 0.35 NWR 1.3 U 1220. B 0.67 U 162. NJ 53.6 EM 22200. M 0.42 BIN 0.27 NU 119. 0.03 1) 3;5 NM 37500. 22.6 M 18.9 54.8 NM 1.2 NR 31400. M 0.23 NW*UJ 9000. 812. 0.15 16.2 M 2720. 0.34 NWR 1.211 2430. 0.66 U 112. NJ 5790. EM 12900. M 0.32 NU 0.25 NR 98.3 0.02 U 1.5 NM 7490. 8.8 M l l . B 27.9 N* J I.I NR 19700. M 0.12 N*UJ 4730. 672. 0.14 10.4 *J 729. B 0.32 NWR 1.2U 1210. 0.62 U 78.9 N.I 35.1 EM 12400. M 0.34 NU 0.27 NWU 128. 0.15 B 1.6 NM 66KI>. 11.1 M 12.1 B 35.1 NM 1.2 NR 21800. M 0.66 MN*UJ 4790. 902. 0.14 I2.9M 597. B 0.34 NWR 1.2 U 1050. B 0.66 U 93.1 NJ 37.1 E»J 20600. "J 0.33 NR 1.3 NR 101. 0.5 2.1 NM 133000. 30.1 *J 12.5' 38.4 NM 1.2 NR 22400. * J 4.5 NSM 9290. 604. 0.28 21.8 M 3370. 3.3 NR 1.2 U 510. B 0.63 U 73.8 NJ 61.6 EM Sec last page of table for notes. Harding Lawson Associates OJ o to OJ OJ Table 4-5 Soil Sample Analytical Results - Inorganics Virgin Island Chemical Company Results reportcil in milli Almniiuini Anlimmy Arsenic D.arium Beryllium Cadmiiun Cnldiiin Cliroiniiun Cobalt Copper Cy.inide Iron Lead Magncsiimi Mang.Tncsc Mercury Nidcel Potassium Selenium Silver Sodiiun lliallium Vnnadiimi Zinc Sample Location: Sample Date: Lab Sample ID: i grams per kilogram. SBC2/0-1 1/30/95 VTXOOI 14700. • 1.3 WJ 1.5 U 112. 0.34 3." 7i«on. * 18.9* 12.4 50.9 l.l UJ 26300. « 31.2 7650. * 689. 0.27 15.6 2460. 3.1 NR 1.1 U 416. B 0.61 UWJ 65.6* 182. SBC2/20-22 1/30/95 VTXOOI 11700.* 0.33 UWJ 0.34 U 106. 0.33 1.9* 12100.* 18.8* 15.2 47.8 1.2 UJ 20800. * 3.9 6290. * 291. 0.14 12.5 1250. 3.3 NR 1.2U 965. B 0.64 U 90.* 45.8 SBC2/24-26 1/30/95 VTX003 9980. • 0.33 UWJ 0.91 U 67.8 0.36 2.* 5680. * 18.6* 12.6 47.1 1.1 UJ 24500. * 3.2 5110.* 354. 0.12U 14.1 1040. B 0.33 NWR 1.2 U 586. B 0.63 UWJ 131.* 50.9 SBDl/0-1 1/25/95 VSIOfll 16100.* 0.31 UWJ I.2U 132. 0.35 2.8* 84500. * 19.8* 16.1 45.1 1.1 UJ 25400. * 6.8 8540. * 976. 0.26 15.6 1940. 3.1 NR 1.1 U 557. B 0.59 UWJ 99.4* 89.5 SBDl/12-14 1/25/95 VS1003 13400.* 0.46 BW 0.8U 187. 0.34 3.5* 14700.* 25.4* 23. 50.4 1.2 UJ 32700. * 4.7 7320. * 2070. 0.14 20.9 1250. 0.34 NWU 1,21) 1200. B 0.65 1) 194.* 50.3 SBDl/22-24 1/25/95 VSI004 16300. * 0.45 BJW 0.33 U 12L 0.24 3.4* 5820. * 19.9* 15.2 50.4 l.l UJ 33200.• 2.9 6700. * 940. O.IIU 22.6 1000. n 0.32 NWR 1.21) 1120. B 0.62 1) 157.* 59.3 SBD2/0-2 1/19/95 VQn003 18400. * 0.35 UWJ I.5U 98.3 0.37 1.9* 60600. • 22.1 * 18.9 51.7 1.2 UJ 26700. * 5.9 7530. * 842. 0.15 18.2 2090. 3.5 NR 1.3D 558. B 0 67 I )WJ 116.* 66.3 SBD2/19-21 1/19/95 VQI1004 10700.* 0.48 BJW 0.66 U 131. 0.26 2.6* 5700. * 19.9* 16.' 47.7 I.IUJ 27400. * 4. 5480. * 755. 0.13 16.7 985. B 0.32 NWR I.2U 780. B 0.61 tj 141.* 50.5 See last page of tabic for notes. Harding Lawson Associates Table 4-5 Soil Sample Analytical Results - Inorganics Virgin Island Chemical Company V OJ to OJ ' Results reportcil Aluminum Antimony Arsaiic Bariimi ncryllium Caibiiiiun Ciilciiim Qiromiiun Cobalt Copper Cy.-mide Iron Lead Magnesiiun Manganese Merciu7 Nickel Potassium Selenium Silver Sodiimi llialliimi V.inadium Zinc Sample Location: Sample Date: Lab Sample ID: In milligrams per kilogram. SBD3/0-2 1/20/95 VQA0fl2 12800.* 0.32 MWJ 0.67 U 99.7 0.38 1.7* 21900. * 20.4* 15.4 62.2 1.1 UJ 23600. * 5.4 6250. * 589. 0.13 20.5 1280. 3.2 NR 1.1 U 497. B 0.61 UWJ 98.1 * 56.7 SBD3/17-19 1/20/95 VOA003 9350. * 0.32 UWJ 0.4 U 140. 0.3 1.6* 4640. * 18.* 12.2 39.7 I.I UJ 25000. * 3.9 4340. * 1020. 0.14 14.7 602. B 0.32 NWR 1.2U 610. B 0.62 U 137.* 56.7 SBD4/0-1 1/27/95 vrroofi 25000. *J 0.4 NU I.I NU 274. 0.44 3.4 N*J 65200. 28.1 *J 20.5 57.1 N*J 1.4 NR 37300. *J 3.5 N* J 13900. 1040. 0.33 17.6 *J 1640. 4.NR 1.4 U 1510. 0.76 U 155. NJ 59. E* J SBD4/14-16 1/27/95 vrrom 18000. *J 0.33 NU 1.6 NR 44.1 B 0.37 3.1 N*J 6450. 24.1 *J 8.1 B 39.9 N* J 1.1 NR 31300. *J 2.UN*J 7700. 216. 0.14 11.6 *J 1190. 3.3 NR 1.2U 1660. 0.63 U 131. NJ 51.2 E*J SBD4/20-22 1/27/95 VTHKI8 13000. * J 0.33 NU 0.26 NWU 105. 0.24 2.2 N*J 6350. 18.9 *J 15.9 34.6 N*J 1.2 NU 26800. *J 1.9 N* J 5140. 1100. 0.28 17.1 *J 919. B 0.33 NWR I.2U 775. B 0.63 11 126. NJ 43.5 E*J SBEl/0-2 1/18/95 voa)03 16900.* 0.54 lUW 1.7 U 60.1 0.3 4.* 35200. * 17.5* 16.8 43.4 L I U 32200. * 89.9 7920. * 791. O.IIU 16.8 1470. 3.NR 1.1 UJ 358. B 0.58 U 88.* 555. SBEl/20-22 1/19/95 VQniK12 12700. * 0.88 B 0.29 U 99.5 0.34 1.7* 4970. * 12.9* 13.6 51.7 1.2 UJ 24800. * 3.4 5360.* 858. 0.14 16. 936. B 3.3 NR I.2U 908. B 0.63 U 108.* 45.4 SBFlAyO-1 2/3/95 WfXWl 14200. 0.46 BJNW 0.96 BJ 63.2 0.21 U 1.1 119000.* 14.8 *J 10.4 B 28.7 I.IUJ 18100. 5.3 S 6830. 489. O.IIU 11.4 1240. 3.1 NWR I.I U 556. B 0.59.^ J 48.7 87.9 FJ See last page of table for notes. Harding Lawson Associates OJ o to OJ on Results reported in Aluminmn Anlimmy Arsaiic Dariiim ncryllium Cadmiiun Ciilciiim Clirominm Cobalt Copper Cyanide Iron Ixad Magnesiiun Mang.incsc Mcrauy Nickel Potassium .Selenium Silver Sodium Thalliiun VrainiUiim Zinc Sample Location: Sample Dale: Lab Sample ID: milligrams perkil ogram. SBFl A/13-15 2/3/95 WO0fl3 19200. 0.31 NU 1.5 RI 110. 0.31 1.4 9900. * 15.9 *J 11.1 39.9 1.1 UJ 24600. 2.7 5780. 542. O . I I U , 15.8 1230. 0.31 NWR 1.1 U 1360. 0.59 U 105. 42.1 lU Soil Sample Virgin SBFl A/20-22 2/3/95 WO004 21700. 0.34 NR 1.2 BJ 122. 0.46 2. 7950. * 31.4 *J 21.4 61.7 1.2 UJ 38500. 5. 10300. 1120. 0.25 21.3 1120. B 3.4 NR 1.2 U 1790. 0.65 U 138. 70.7 EJ Table 4-5 1 Analytical Results - Inorgai Island Chemical Company SBF2/12-15 1/24/95 VSR002 15500. * J 0.3 NR 1.7 NR 153. 0.36 2.6 N*J 9H70. 18.7* J 16. 52.2 N* J 1.1 NR 29500. * J 3.3 N* J 6200. 915. 0.13 15.4 *J 1090. 3. NR 1.1 U 1140. 0.58 U 144. NJ 48.5 E*J SBF2/18-20 1/24/95 VSR003 18600. *J 0.33 NR 0.26 NR 95.9 0.36 3.5 N*J 6480. 28.3 *J 17.5 57.3 N*J 1.2 NR 39500. *J 1.2NW*UJ 7570. 646. 0.14 19.2 *J 1050. B 0.33 NWR 1.2U 1290. 0.63 U 171. NJ 58.5 E*J nics SBF2A/0-1 2/3/95 wooos 16300. 0.39 B.IN 0.95 B J W 9.5.2 0.31 1.3 101000.* 21.4 *J 13.3 40. 1.1 UJ 23500. 4.8 S 6730. 601. 0.24 13.2 1970. 3.1 NR I . I D 491.11 0.61 I) 89.1 178. lU XA • \ : ' ' SBF3/0-1 1/24/95 VSRa04 17300. *J 0.32 NR 0.25 NR 112. 0.21 B 6.4 N*J 60000. 30.4 *J 17.6 141. N * J I.I NR 63400. *J 3. NS*J 7480. 888. 0.27 26.9 *J 2530. 0.32 NR 1.2D 385. B 0.62 D 99.2 NJ 479. E*J \ ^ SBF3/12-15 1/24/95 VSRWIT 18800. *J 0.31 NR 1.2 NR 177. 0.36 3. N*J 25000. 19.6 *J 17.8 56.1 N*J 1.1 NR 33900. *J 3.2 N*J 7870. 1240. O.Il D 17.3* J 1380. 0.31 NWR 1.1 1) 1450. 0.61 D 172. NJ 60.5 E*J SBF3/18-20 1/24/95 VSR009 14700.* J 0.31 NR 0.25 NR 56.3 0.05 U 2.9 N*J 9520. 25.3 *J 12.3' 42. N*J I.I NR 31900. *J 0.29 N W n j J 6520. 385. O.IIU 13.6 *J 855. B 0.31 NWR 1.1 U 731. B O.riU 151. NJ 54.6 E*J See last page of table for notes. Harding Lawson Associates OJ o to OJ Table 4-5 Soil Sample Analytical Results - Inorganics Virgin Island Chemical Company •TV, 0 r % Pages Sample Location: Sample Date: Lab Sample ID: Results reported in milligrams per kilogram. SBFlA/13-15 2/3/95 WOO03 SBFl A/20-22 2/3/95 WOflO^ SBF2/I2-15 1/24/95 VSR002 SBF2/18-20 1/24/95 VSR003 SBF2A/0-1 2/3/95 wooos SBF3/0-1 1/24/95 VSR004 SBF3/12-15 1/24/95 VSR007 SBF3/I8-20 1/24/95 VSR009 * - Duplicate analysis not williin control limils + - Corrclatim coclFiciail for MSA < .995 n-<CR15Lbul>=IDL E - Estinwlcd due to tlic presence of interference J - Estimated Value M - Duplicate inject im precision noi md N - Spike recovery not within cmlrol limils S - Ddcnninctl by Mdhcxl of Stiuiilard Additims U - /\naly/i-il but not ddected W - GFAA post-digest spike out of cmtrol limils Harding Lawson Associates ^ ;^ T a b l e 4-6. G r o u n d w a t e r Elevations a n d PID R e a d i n g s Virgin Island C h e m i c a l Site St. Croix, U.S. Virgin I s l a n d s WeU Name MW-1 MW-3 MW-4 MW-5 P-1 P-2 MW-1 MW-3 MW-4 MW-5 P-1 P-2 MW-1 MW-3 MW-4 MW-5 P-1 P-2 MW-1 MW-3 MW-4 MW-5 P-1 P-2 MW-1 MW-3 MW-4 MW-5 P-1 P-2 Date 2/14/95 2/14/95 2/14/95 2/14/95 2/10/95 2/10/95 5/8/95 5/8/95 5/8/95 5/8/95 5/8/95 5/8/95 5/9/95 5/9/95 5/9/95 5/9/95 5/9/95 5/9/95 5/10/95 5/10/95 5/10/95 5/10/95 5/10/95 5/10/95 5/11/95 5/11/95 5/11/95 5/11/95 5/11/95 5/11/95 Top of Inner Casing Elev. (feet) 31.36 30.80 28.63 28.83 38.00^ 29.55' 31.36 30.80 28.63 ^ 28.83 39.80' 30.38' 31.36 30.80 28.63 28.83 39.80' 30.38' 31.36 30.80 28.63 28.83 39.80' 30.38' 31.36 30.80 28.63 28.83 39.80' 30.38' Depth to Water (feet) 27.18 25.71 24.35 24.63 35.20' 22.65' 27.10 26.52 24.43 24.74 36.83 26.58 27.09 26.54 24.44 24.76 36.81 26.53 26.68 24.47 23.85 20.58 36.75 26.35 26.23 21.97 23.12 20.89 36.71 26.38 Groimdwater Elevation (feet) 4.18 5.09 4.28 4.20 2.8 6.9 4.26 4.28 4.20 4.09 2.97 3.80 4.27 4.26 4.19 4.07 2.99 3.85 4.68 6.33 4.78 8.25 3.05 4.03 5.13 8.83 5.51 7.94 3.09 4.00 Notes: ' Ground surface elevations. ^ Approximate measurements from around surface. ^ Elevation given for production wells P-1 and P-2 is for top of outer casing wells do not have inner casings. "* Photoionization detector readings of relative organic vapor concentrations in relative parts per million, measured inside casing. PID Readings'* 3.3 0 0 0 0 0 16 0 0 0 0 0 15 0 0 0 0 0 1.7 0 0 0 0 0 1.8 0 0 0 0 0 ;. These presented wordproc\29872\dsr01 .tbl Harding Lawson Associates 302437 Ui o IO Ui 00 Table 4-7. Groundwater Sampling Field Analytical Results February and May 1995 Sampling Events Virgin Island Chemical Site ^St. Croix, U.S. V rgin Islands Well MW-1 MW-3 MW-4 MW-5 MW-1 MW-3 MW-4 MW-5 Date Sampled 2/10/95 2/15/95 2/14/95 2/15/95 5/9/95 .5/11/95 .Vl 0/95 5/10/95 Volume of Water Purged (f5nl) 19 12 10 6' 16 20 10 20 Time lo Purge (min) 55 42 53 20 23 24 20 59 pll 0.09 7.17 0.92 8.83 6.99 6.85 7.10 6.77 Conductivity (umhos/cm) 2,460 2,950 1,500 2,170 2,290 3,220 2,200 2,110 Temperature CC) 26.0 31.7 28.5 25.7 28.4 29.5 28.1 28.4 Dissolved Oxygen (mg/1) 3.37 2.28 1.5« 5.01 2.12 1.04 1.02 2.62 Redox Polential (mV) 125.5 -24.1 134 1G3.3 -26.5 -88.8 108.5 197.8 Turbidity (NTUs) >200 1,033 >200 10.1 147 160 >99!) 30 Salinity (%) 0.11 0.15 0.10 0.10 0.11 0.16 0.10 0.10 Note: Measurements recorded prior to sampling. ' The calculated purge volume for this well was approx. 11 gallons in February 1995. However, purging was considered complete after removal of approximately 0 gallons due to exceptionally poor recharge at that time. Source: Harding I-.awson Associates »vonlproc\20872\ilsrOi;ibl Harding Lawson Associates \ r Table 4-9 Groundwater Sample Analytical Results - Semivolatile Organic Compounds Virgin Island Chemical Company OJ o to Ui VD Sample Location: Sample Date: Lab Sample ID: Results reported in micrograms per liter. 1,2,4-TridiIoroliai/oic 2,2'ox>Iiis( I-Clil<ff<vr<l':iiic) 2,4,5-TricIiloroiiliaiol 2,4,6-Tridiloroiiliciiol 2,4-Didiloroplicnol 2,'l-niiiiclliyIplioi()l 2,-1-nini(niiluiiiil 2,4-Diiiilrotoliiaic 2,6-DinilTOloUiaic 2.CliIoronaplilIiaIaic 2-CliloropIicnoI 2-MdhyInaplilIialaic 2-MclliylphmoI 2-Nilro.iniIiiic 2-Nitropliaiol 3,3'-DidiIorol)aixi(liiic 3-Nilro.Tnilinc 4,6-Dinitro-2-nicthylpIiciiol 4-nromophcnyl-plicnylctlicr 401iloro-,1-nulliylpliciiol 401iloro.-iiiilinc 4-ailoroiiliaiyl-pIiuiylcllier 4-MctIiytpliaiol 4-Nilro,iiiiliiic 4-NilropIiaiol MW-1 2/16/95 WA\vno4 5. UJ, 5. U 20. U 5. U 5.11 30. 20. 1 U 5.U 5.U 5. U 5.U 5.U 5.U 20. UJ 5. U 5.UJ 20. U 20. U 5.U 5.U 5. U 5. U 40. 20. U 20. U MW-1 2/16/95 WAWOOS 5 . U J 5. U 20. U 5.U 5.U 22. 20.1 IJ 5.U 5.U 5.U 5.U 5.U 5.U 20. UJ 5.U 5.UJ 20. U 20. U 5.U 5.U 5. U 5.U 48. 20. U 20. U MW-1 5/9/95 .XfiUOOl 5.U 5. U 20. U • 5. U 5.U 5. U 20.1) 5. U 5.U 5.U 5.U 5.U 5.U 20. U 5.U 5.U 20. U 20. U" 5.U 5.U 5.U 5.U 5. U 20. U 20. U MW-1 5/9/95 XCUOOIRE 12.U 12. U 50. U 12.U I 2 . U 12. U 50.11 12. U 12. U 12. U 12. TJ 12. U 12. U 50. U 12. U 12.U 50. U 50. U 12. U 12. U 12. U 12. U 12. U 50. U 50. U MW-1 5/9/95 XCtllKll 5.11 .5.11 20.11 5.U 5.U 5.11 20.11 5.11 5.U 5. U 5. U 5.U 5.U 20. U 5.U 5. U 20. U 20. U 5. U 5.11 5. II 5.1) 5. II 20.11 20. U MW-1 5/9/95 XCIXMUtE 5. U 5.U 20.11 5.U 5. U 5.U 20. 11 5.U 5.U 5.U 5. U 5.U 5.U 20. U 5.U 5.U 20. U 20. U 5.U 5.1) 5.11 5.U 5. U 20.11 20. U M W - 3 2/15/95 WAWOOJ 5. UJ 5 . 1 ) 2 0 IJ 5. U 5.11 5.11 20. DJ 5. U 5. U 5. U 5. U 5. U 5.U 20. UJ 5. U 5.UJ 20. U 20. U 5. U 5. U 5. 11 5. U 5.1) 20.11 20. IJ MW-3 5/11/95 XiniKM 5.U 5.U 20. U 5.U 5.U 5.U 20. U 5.1J 5.b 5.U 5.U 3.U 5.U 20. U 5.U 5.U 20. U 20. U 5.U 5. U 2. J ' iu 5. U 20. U 20,1) See last page of table for notes. Harding Lawson Associates CO o to o Results rcportwl in microgra Accnaplillialc Acen.iplilliylaic Aniliracaic nonzn(.n);inlIir:icaic ncn7o(a)ii>Taic riai/iXb)'!""''™"''""-' I)or/ii(n.li.i)iinyloic Baizo(lc)niioranlliaic bis(2-CIiloroct]ioxy)nictli.Tiic bis(2-ailoroctIiyl)ctIicr bis(2-niliyllic.'<yl)|ililli.il:ilc riulylbaizylplillialal i; Qiryscnc Di-n-bulylplillialatc Di-n-octylpliUialalc Dibmz(aji).'mtliracaie Dibciizoriir.in Dictliylplilhalalc Dimctliylplilhalatc Miior.Tiilliaic Fliioraic llcxadilorolicn/xaic llcxadilorolniladiciic Ilcxadiloroc>vlo)iaila(liaic Itcxadiloroctlu-me Sample Loc; Sample Lab Sampl ms per liter. Table 4-9 Groundwater Sample Analytical Results - ition: Date: leTD: MW-1 2/16/95 WA\\'nn4 5. U 5. U 5. U 5. U 5. U 5.1) 5.1) 5. U 5. U 5.UJ 5. UJ 5. U 5. U 5.U 5. UJ 5.U 5. U 5.U 5.U 5. U 5. U 5. U 5. UJ 5. UJ 5.U Virgin MW-1 2/16/95 WAWnos 5.U 5.U 5.U 5.U 5.U 5.U 5.11 5.U 5.U 5.UJ 5.U 5.U 5.U 5.U 5.UJ 5.U 5.U 5.U 5.U 5. U 5.U. 5.U 5.UJ 5.UJ 5.U < Semivolatile Organic Compounds Island Chemical Company MW-1 5/9/95 xounoi 5.U 5. U 5.U 5.U 5.U 5.U 5. U 5.U 5.U 5.U 11.n 5.U 5.U 5.U 5.U 5.U 5.U 5. U 5.U 5. U 5. U 5. U 5.U 5. U 5.U MW-1 5/9/95 XGimoiHF, 12.U 12.1) 12. U 12. U 12.U 12.U 12.U 12. U 12. U I2.U 3. n j 12. U 12. U I2.U 12. U 12.U 12.U 12. U 12. U 12.11 12. U 12. U 12. U 12. U 12. U MW-1 5/9/95 xc.cmn 5. U 5. U 5. U 5.11 5.11 5.1) 5.1) 5. U 5.U 5.U 3. IU 5. U 5.U 5. U 5.U 5.U 5. U 5.U 5. U 5.1) 5. U 5. U 5.1) 5.1) 5.U MW-1 5/9/95 XCinOZHE 5.U 5. II 5. U 5.U 5.U 5. U 5. U 5. U 5.U 5.U 6. n 5. U 5. U 5.U 5.U 5.U 5. U 5.U 5.U 5. U 5. U 5. U 5. U 5.1) 5.U MW-3 2/15/95 WAWIKlJ 5. U 5.11 5. U 5. U 5. U 5. U 5.1) 5. IJ 5.U 5. UJ 5. U 5. U 5. U 5. U 5. UJ 5.U 5. U 5. U 5. U 5.1) 5.1) 5.1) 5. UJ 5. UJ 5.1) MW-3 5/11/95 XiniH)9 5.U 5.U 5.U 5.U 5.U 5,U 5.U 5,U 5. (J 5.U 3.nj 5.U 5.U 5.U 5.U 5.U 5.U 5.U 5.U 5,U 5.U • 5.U 5.U 5.U 5. U See last page of table for notes. Harding Lawson Associates . - - < Table 4-9 ^^ Groundwater Sample Analytical Results - Semivolatile Organic Compounds Virgin Island Chemical Company to o to Sample Loca Sample 1 Lab Sampl Results reportol in micrograms per liter. Iii(lmo(1,2,3-c<l)pjTaic Isoplior(Tic N-Nilroso-(liHi-proiiyl.nniinc N-Nilrosodipliaiylaniiiic N.tplillinlmc Nilroliai7aic ruitndilortifiluitol I1icn.inllircnc riimol PjTcne Pyridine ilion: Date: elD: MW-1 2/16/95 WAWKM 5. U 0.6 J 5.U 5. U 5. R 5.U 20. 11 5. U 5.U 5.U 10. UJ MW-1 2/16/95 WANVDOS 5.U 0.7.1 5.U 5.U 5. U 5. U 20.1) 5.U 5.U 5.U 10. UJ MW-1 5/9/95 xcunoi 5.U 5.U 5.U 5.U 5.U 5.U 20. U 5.U 5.U 5.U 10. U MW-1 5/9/95 XOUOOIRE 12. U 12. U 12. U 12. U 12. U 12. U 50.11 12. U 12. U 12. U 10. U MW-1 5/9/95 XCIKIOI 5. U 5. U 5. U 5. U 5.11 5. U 20. 1) 5. U 5.U 5. U 10. U MW-1 5/9/95 Xf;iJ002RE 5.U 5.U 5. U 5.U 5. U 5.U 20.11 5.U 5.U 5.U 10. U MW-3 2/15/95 WAWOOJ 5. U S.K 5. U 5. U 5. U 5.1.1 20. 11 5.U l . J 5. U 10. UJ MW-3 5/11/95 xinim 5.U 5.U 5.U 5.U 5.U 5.U 20. U 5.U 0.8 i 5.U 10. U See last page of t:ible for notes. Harding Lawson Associates f J : • ; • ' • to o to to Table 4-9 Groundwater Sample Analytical Results - Semivolatile Organic Compounds Virgin Island Chemical Company Sample LocaUon: Sample Date: Lab Sample FD: Results reported in micrograms per liter. MW-3 5/11/95 Xin»X)9UE MW-4 2/14/95 WAAOOI MW-4 5/10/95 xinnoj MW-4 5/10/95 xininojRE MW-5 2/15/95 WAWOOt MW-5 5/10/95 Xini)02 1,2,4-Tridilorobai7aic 2,2'-oxybis( 1 -CliUiroiiro(i;me) 2,4,5-Tridiloropliciinl 2,4,6-TridiIoropItaiol 2,4-Didiloropliaiol 2,4-DiniclliyIpIiciiiiI 2,4-l')inili<vl<>iiol 2,4-OinitrotoIiimc 2,6-Dinilrotolucnc 2-Cliloroii.TpIillialaic 2-CliloropIicnoI 2-MctliyInapIilhalaie 2-McOiylplimol 2-Nilroaniline 2-Nitrophaiol 3,3'-Didilorobcn7idinc 3-Nitroaniline 4,6-Dmitro-2-mc(hylphcnol 4-Dromophcnyl-pliaiyIcthcr 4-CliIoro-3-mc<liy1pliaioI 4-Cliloro.Tnilinc 4-CliIoropliaiyl-])lKiiyIdlicr 4-Mi-Oiylplicnol 4-Nitro.TniIinc 4-NitrcpliciioI 11 11 44 II II II •I'l II l l . U l l . U ll.U l l . U l l . U 44. U ll.U l l . U 44. U 44. U l l . U ll.U l.J ll.U l l . U 44. U 44. U 5. UJ 5.U 20. U 5.U 5. U 5. U 20. 1 IJ 5.U 5.U 5.U 5.U 5.U 5.U 20. UJ 5.U 5.UJ 20. U 20. U 5.U 5.U 5.U 5,U 5.U 20. U 20. U 5.U 5.U 20. U " 5. U 5.U 5. U 20. 11 5.U 5.U 5.U 5.U 5.U 5.U 20. U 5.U 5.U 20. U 20. U' 5.U 5. U 5.U 5.11 5. U 20. U 20. U 5.U 5.U 20. U 5.U 5.U 5.U 20.11 5.U 5.U 5.U 5.U 5.U 5.U 20. U 5.U 5.U 20. U 20. U 5.U 5.U 5.U 5.U 5.U 20. U 20. U 7. UJ 7. U 29. U 7. U 7.11 7. U 7<). I ).l 7. U 7.U 7. U 7. U 7.U 7. U 29. UJ 7.U 7. UJ 29. U 29. U 7. U 7. U 7.11 7.11 7.11 29. U 29. U 5. U 5.U 20. U 5. U 5.U 5. U 20. 11 5. U 5.U 5. U 5. U 5.U 5.U 20. U 5. U 5.U 20. U 20. U 5.U 5.U 5. U 5.11 5.11 20. U 20. U MW-5 5/10/95 X]n(l02l(E 5. U 5. U 20. U 5. U 5.11 5. U 20. U 5. U 5.U 5, U 5. U 5. U 5.U 20. U 5. U 5.U 20. U 20. U 5. U 5. IJ 5. U 5.11 5. U 20.11 20.1) See last page of table for notes. Harding Lawson Associates A\ A' .'\ 00 o tJ 1 ^ 00 Table 4-9 Groundwater Sample Analytical Results - Semivolatile Organic Compounds Virgin Island Chemical Company Pages Sample Locotion: Sample Date: Lab Sample ID: Results reported In micrograms per liter. MW-3 5/11/95 XlltllKWHE MW-4 2/14/95 WAAOni MW-4 5/10/95 xinroj MW-4 5/10/95 XiniOOJRE MW-5 2/15/95 WAWOfll MW-5 5/10/95 xinnoi AcdiapIiUicnc Acainplilliylaic Aiilliracaic nai7D(a)anUuacaic nai7t)(n)P)''''"c nai7o(l')1norimlliaie llorA>(g.li ,i)l)aTl"ic 13cn7JO(k)nuoraiilIiaie bis(2-Cliloroctlioxy )in<:th an c bis(2-ailorocthyl)c0ier bi.<<2-niliynic.\yl)plitlial.ntc nutylbar/ytplillialalc airyscne Di-n-butylplillial.nlc Di-n-octylplilh.nlatc Dibcn7(aji)anlhraccnc DibenTofiiran Dietliylphllialatc Dimcthylplillialalc Fluor milliaic nuoraic ncxadilorol)ai7aic lltxadilorolmtailiaic IIc.\adilorix:5cliiiail.nilieiic IIc.vadiloroctli.Tnc ll.U ll.U ll.U n.u ll.U ll.U ll.U ll.U l l . U n.u 42. U n.u n.u n.u n.u n.u n.u n.u n.u n.u n.u n.u n.u w.v n.u 5. u 5. u 5. u 5.U 5. U 5. U 5.11 5.U 5.U 5.UJ 5. U 5. U 5:U 5.U 5.UJ 5.U 5. U 5.U 5. U 5.U 5. U 5.U 5.UJ 5.UJ 5. U 5.U 5.1J 5.U • 5.U 5.U 5. U 5. U 5. U 5.U 5.U 11.n 5.U 5.U 5.U 5. U 5.U 5. U 5.U"' 5.U 5. U 5.U 5. U 5.U 5. U 5.U 5.U 5.U 5.U 5.U 5.U 5.U 5.U 5.U 5.U 5.U 14. n 5.U 5.U 5.U 5.U 5.U 5.U 5.U 5.U 5. U 5.U 5. U 5.U 5.U 5.U 7. U 7.1) 7.1) 7. U 7. U 7. U 7. U 7. U 7.U 7. UJ 7. U 7. U 7.U 7. U 7. UJ 7. U 7.U 7. U 7. U 7.1) 7.11 7. U 7. UJ 7.1 JJ 7. U 5. U 5. IJ 3. U 5.U 5. U 5.11 5.11 5.U 5.U 5.U 7. n 5.U 5.U 5. U 5.U 5. U 5. U 5.U 5.U 5. U 5..U 5. U 5. U 5.11 5. U MW-5 5/10/95 XIIKMIIKK 5. U 5. U 5. IJ 5.U 5. U 5. U 5.11 5.U 5.U 5. U 7. II 5. U 5. U 5. U 5.U 5. U 5. U 5.U 5.U 5.11 5. U 5. U 5.U 5, II 5. U See last page of table for notes. Harding Lawson Associates Table 4-9 C j " ^ '^ Groundwater Sample Analytical Results - Semivolatile Organic CompoOhds Virgin Island Chemical Company ct A Sample Location: Sample Dale: Lab Sample TD: Results reported in micrograms per liter. Indaio(l ,2,3-c<l)i))Teiic I.sopliordic N-Nitros<wliHi-jiro|iyl!iiiiiin; N-Nitros<xlipliciiyl!iiiiim; NapliOialaic Nilrobai7aic I'aitndilorniiliaiol riicnantlirmc Himol Pyrene Pyridine MW-3 5/11/95 XIIIIXWRE n.u n.u ll.U ll.U l l . U n.u 44. u l l . U 0.4 J l l . U 10. U MW-4 2/14/95 WAAOOl 5.U 5. K .5.1 J 5.U 5.U 5.U 20. U 5.U 5.U 5.U 10. UJ MW-4 5/10/95 .XIIIIMIJ 5.U 5. U 5.U • 5.U 5.U 5.U 20.11 5.U 5.U 5.U 10. U MW-4 5/10/95 xinrojRE 5.U 5. IJ 5. U 5.U 5.U 5.U 20. U 5.U 5.U 5.U 10. U MW-5 2/15/95 WAWIIOt 7. U 7. I( 7.1) 7. U I.K 7. U 29. U 7. U 7.U 7.tJ 15.1 UJ MW-5 5/10/95 XIII 1)02 5. U 5.U 5. U 5. U 5.U 5. U 20. U 5.U 5.U 5.U 10. U MW-5 5/10/95 X!niKI2KE 5. U .5. U 5.11 5. U 5. U 5. U 20.11 5. U 5.U 5.U 10. U to o to B - Detected in s.Tniplc and associaled blank D - Compound qu.intit.itcd cn a diluted sample n - Rxcccded llic calibralim range of instrument J-nstimalcd Value R - Result was rejected during d.ila validatini U - Analyzed but not detected X - Manual addiliai ofcHs and Ir.ins isomers Harding Lawson Associates Table 4-10 Groundwater Sample Analytical Results -Total Inorganics Virgin Island Chemical Company Sample Location: Sample Date: Lab Sample ID: Results reportc<I In micrograms per liter. MW-1 2/16/95 WAwnoi MW-1 2/16/95 WAWIXM MW-1 5/9/95 XGUOOl MW-1 5/9/95 xciJno2 MW-3 2/15/95 WA\VD03 MW-3 5/11/95 XIUD09 MW.4 2/14/95 WAAOOI MW-4 5/10/95 xinDO] 00 o to Ul Aluminum Antiniaiy Arsenic narium nerylliiun Cadmiiun Ciilciiim Chroniiimi Cobalt Copper Cyanide Iron Lead Magnesium Manganese Mercury Nid<el Potassium Selcniiun Silver Sodiimi Tlialliimi V.Tnadiiun Zinc 656. EN*J 1.4 UN 4.4 Ii 145.11 0.2 NMJ 3.1 U 49H00. IU 4.4 U 9.5 U 16.7 U 10. U 640. N*J I.9U 34400. ENJ 1450. EJ 0.2 U I3.I U 2350. B 24.2 BJmV 5.1 U 432000. IU 2.7 U 33.3 n 31.4 U 693. EN*J 1.4 IW 7.7 n 138. n 0.2 KW*UJ .3.1 U 47900. K.1 5.2 U 9.5 U 16.7 U 10. U 678. N*J 2.7 U 32900. EJ 1380. ENJ 0.2 U 13.1 U 2310. B 19.6 BJNW 5.1 U 406000. EJ 2.7 U 34.1 B 17.8 U 1330. N« 1.4 UW 3.9 UN 181. B 1.4 N 2.4 U 44900. 2.2 U 3.8 U 13.4 U 10. UN 1590. N* 3.8 W 31200. 1560. 0.44 10.3 U 1260. B 1.6 UW 3.6 U 397000. 2.6 IM' 42.4 B 21.6 7890. N* I.4UW 3.4 BN 177.B 1.6 N 2.4 U 39800. 7.B 5.5 B 18.7B 10. UN 9980. N* 2.8 BW 28900. 1450. 0.2 U 14.1 B 1700. B 1.6 UW 3.6 U 349000. 2.6 UW 55. 77.9 3340. ENM 1.4 UN 5.4 II 189. U 0.3 NMI 3.1 U 148000. IM 8.2 U 9.5 U 35. 10. U 5140. N"J 1.7 U 81900. ENJ 4180. FJ 0.2 U 21. B 17100. 20.5 BJN 5.1 U 396000. ICI 2.711 57.1 78.6 1270. N* 1.4 UW 5.4 BN 125. B 0.18 BN 2.4 U 211000. 2.8 B 3.8 U 13.4 U 10. UN 11700. N* 1.6 BW 90500. 5270. 1.4 10.3 U 26400. 16. U 3.6 U 348000. 2.6 UW 15.3 B 22.9 1560. EN* J I.4UN 1.8 B 131. B 0.6NWMIJ 3.1 U 54200. IU 5.9 U 9.5 U 23.1 B 10. U 1380. N*J 3. U 37900. EJ 1000. ENJ 0.2 U 21.9 B 1920. B 1.4UNWJ 5.1 U 388000. K.I 2.7 U 46.6 B 65.3 2670. N* 1.4 UW 1.5 UN 145. B 0.24 BN 2.4 U 53500. 2.2 U 8.3^ 13.4 U 10. UN 2560. N* 2.1 BW 36000. 1170. 0.31 12. B 1610. B 1.6 UW 3.6 U , 394000. 2.6 UW 44.2 B 25.9 See lost page of table for noles. Harding Lawson Associates ... i>\ ^ • A - i . A » Table 4-10 Groundwater Sample Analytical Results -Total Inorganics Virgin Island Chemical Company Sample Location: Sample Dale: Lab Sample ID: Results reported In micrograms per liter. MW-5 2/15/95 WAWnoi M W - 5 5/10/95 xiniw2 Ahmiinimi Anlimmy Arsenic D-Trium nerylliimi Cadinium Colciiun Chromiiun Cobalt Copper Cyanide Iron Lead Magnesium Manganese Merairy Nickel Potassium , . Selenium 0 0 O SUver to it^ Sodiimi fj^ Thallium Vanadium Zinc 18500. EN" J 1.4 UN 2.1 B 270. 1.3 N*U 3.8 B 148000. EJ 23.8 82.5 367. 10. U 28400. N* J 17. 81500. E J 14100. E N J 0.2 U 79.8 4110. B I4.UNJ 5.1 U 349000. E.I 2.7 U 456. 227. 306. N* 1.4 UW 1.5 UN 162. B 0.15 BN 2.4 U 66000. 2.2 U 3.8 U 13.4 U 10. UN 339. N* 20.3 S 52000. 108. 0.2 U 10.3 U 1320. B I . 6 U W 3.6 U 314000. 2.6 UW 30.3 B 20.3 See last page of table for noles. Harding Lawson Associates Table 4-10 Groundwater Sample Analytical Results - Total Inorganics Virgin Island Chemical Company Sample Locotion: Sample Date: Lob Sample ID: Results reported In microgmms per liter. MW-5 2/15/95 WAwnoi MW-5 5/10/95 xini)02 • - Dupliciile mialysis not within cmlrol limils -I- - Correliitim cociriduil lor M.SA < .995 n - < CRDL but >=1DL E - Hstimaled due to tlic presence of iiilcrfcriTicc J - nstimaltti V.nlue M - Duplicate injcclim precisim not met N - Spike recovery not within atilrol limils S - Dctcrmiuctl by M>ili<yl or.Stiuuliud Additims U-Anoly/cd but nc< detected W - GF/VA post-digest spike out of control limits 00 o to Harding Lawson Associates Table 4-11 Groundwater Sample Analytical Results - Dissolved Metals Virgin Island Chemical Company V^' Sample Location: Sample Dale: Lab Sample ID: Results reported in micrograms per liter. MW-1 2/16/95 WBIWM MW-1 2/16/95 \VBIJ)OS MW-1 5/9/95 XGOOflS MW-1 5/9/95 XCtI0O« MW-3 2/15/95 wmmoj MW-3 5/11/95 xinnio MW-4 2/14/95 wnJooi MW-4 5/10/95 XIDDOT AUiminiun Antimony Arsaiic D.iriuni ncryllium Cndmium Ciilciiim Cliromiimi I Cobalt Copper Iron Lead Magnesium Manganese Mercury Nickel Potassium Sclcniimi Silver t o Sodium O [O I Tlialliura 00 Vanadium Zinc 51.8 B 1.8 IUN* 7.1 U 124.11 0.67 U 3.1 U 42500. 4.9 B 9.5 U 29.9 ' J 32.1 U 1.1 U 30500. . 1190. 0.2 U 13.1 U 2250. n 15. BJNW 6.9 BJN 389000. 2.7 U 28.5 n 59.1 40.3 B 1.4 aiN* 4.KU 126. B 0.28 U 3.1 U 46000. 5.1 B 9.5 U 16.7U*J 32.1 U I.2U 33100. 1020. 0.2 U 13.1 U 2050. B 17.6 BJNW 5.3 BJN 411000. 2.7 UW 31.1 B 61.4 19.8 U I.4UW 2.4 UN lisi. B O.I UN 2.4 U 43000. 2.2 U 3.8U 72.8 N* 17.9 B 14.3 NS* 29500. 1530. N 0.2 UN 10.3 U 1220. B 1.6 UW 3.6 U 384000. 2.6 UW 31.1 B 89.5 31.B 6.8 W 1.6 BN 161.B 0.1 BNW 2.4 U 42400. 2.2 U 3.8 U 34.7 N* 26.3 B 13.1 N*+ 29200. 1520. N 0.2 UN 10.3 U 1290. B 1.6 UW 3.6 U 381000. 2.6 UW 32.5 B 77.2 64. B 4.9 RJN- K.6 11 286. 0.31 U 3.1 U 125000. 8. B 9.5 U 31.5 *J 454. 0.87 U 70700. 3100. 0.31 38.2 B 15500. I4.UNJ 5.1 UN 351000. 2.7 UW II. II 160. 19.8 U 1.4 UW 8.2 BN 236. 0.2 BN 2.4 U 211000. 2.2 U 3.8 U 13.4 UN* 9770. 24.4 NS* 89800. 5130. N 0.42 N 10.3 U 26500. I.6UW 3.6 U 348000. 2.6 UW 3.611 52.4 42.3 B 95.6 N* J 1.9 IJ 70.6 II 0.61 U 3.1 U 490011. 4.1 B 9.5 U 30.8 * J 32.1 U 1.7U 35200. 535. 0.2 U 25.3 B 2000. B I.4UNWJ 5.1 UN 374000. 2.7 IJ 26.2 B 93. 19.8 U 1.4UW 1.5 UN 75.1 B O.IUNW 2.4 U 48200. 2.2 U 3.8 U' 13.4 UN* I2.IU 1.9 BNW* 33800. 705. N 0.45 N 10.3 U 1530. B 1.6 M 3.6 U 392000. 2.6 UW 22.1 B 49.7 See last page of table for noles. Harding Lavvson Associates . . ' . y r^ y^ 00 o to > ; ^ VD Table 4-11 (Groundwater Sample Analytical Results - Dissolved Metals Virgin Island Chemical Company Sample LocaUon: Sample Date: Lab Sample ID: Results reported in micrograms per liter. MW-5 2/15/95 wnimoi MW-5 5/10/95 xinixx Aluminiun Antimony Arsenic Darium Dcrylliimi Caibnium Ciilciiim Chromiimi Cobalt Copper Iron Lead Mapiesiiun Manganese Mercury Nickel Potassiimi Selenium Silver .So<liiun 'ni.illium V.inadium Zinc 45.7 B 1.5 IUN* 3.'IU 277. 2.1 U 3.1 U 60300. 5.9 B 9.5 U 48.3 *J 32.1 U 3. U 52700. 2160. 0.2 U 33.1 n 3300. B 14.UNJ 5.1 UN 334000. 2.7 UW 26. B 103. I9.8U 1.4 UW 1.8 BN 164. B 0.34 BNW 2.4 U 64300. 2.2 U 3.8 U 22.5 BN* 105. 44.4 NS* 51500. 81.4 N 0.21 N 10.3 U 1210. B 1.6 UW 3.6 U 316000. 2.6 UW 27.7 B 76.5 See last page of table for notes. Harding Lawson Associates Table 4-11 Groundwater Sample Analytical Results - Dissolved Metals Virgin Island Chemical Company XX Sample Location: Sample Dale: Lab Sample ID: Results reported in micrograms per liter. MW-5 2/15/95 WIIIKKII MW-5 5/10/95 XTnK)0« * - Duplioitc an.nlysts not williin cmlrol limits + - Correlnlim codliciail lor M.SA < .995 n - < CROL hut >=II)L E - Iistim.itcd due to tlie presence of iiilerfcraice J - nstimalcd Value M - Duplicate injection prccisirii not met N-Spike recovery not within ctmlrol limits .S - Octciiiiiiietl by Milliod iirsiiiiiiliinl Additims U - Analyzed but not detected W - GFAA post-digest .-^ike out of cmlrol limits 00 o to tn o Harding Lawson Associates sf \ J .'^ -r Table 4-12 X Groundwater Sample Analytical Results - Pesticides and PCBs Virgin Island Chemical Company Sample Location: Sample Dale: Lab Sample ID: Results reported In micrograms per liter. Ilcptadilor epoxide Mclhoxydilor Toxnpliaic MW-4 5/10/95 xinmoa 0.01 U 0.1 U 1,11 MW-5 2/15/95 WA\\TX)l 0.014 U 0.14 U 1.4 U MW-5 5/10/95 xinii)02 O.OI U 0.1 U l.U MW-5 5/10/95 Xinil02RE 0.01 U O.I IJ l.U n - Detect etl in sniinilc nnd n.'isixniilcd liliuik D - Compoiuid (|U.iiilit:i(c-<l m a diluted 5.1011)10 I; -Ilvcectlcd the aililniitioii riuigc orinstninioit J - llstiinatcJ Value P - >25% difTcrcncc bctwcai 2 GC oilumns U - Analyzed but not detected X-Manual addition of cis and trans isomers to O to tn Harding Lawson Associates .^i r4:ty Table 4-12 Groundwater Sample Analytical Results - Pesticides and PCBs Virgin Island Chemical Company to o to tn to Sample Location: Sample Date: Lab Sample ID: Results reported In micrograms per liter. 4,4'-DDD 4.4'-nnr; 4,4'-niyr Akb-in alpha-nilC oIplia-CIiIord;Dic Ar.H;l<w-I016 Aroclor-1221 ArocIar-1232 Aroclor-1242 Aroclor-1248 Aroclor-1254 Aroclor-1260 bcta-nilC della-nilC Dieldrin Endosulfan I Endosulfan IT Endosulfan Sulfate Endrin Endrin alddiydc Eiitbin kctme gamma-nilC (I.ind:mc) g.imma-QiIord.iiic Ilcptadilor MW-1 2/16/95 WAWIKMHE 0.02 UJ 0.02 I IJ 0.02 UJ 0.01 UJ 0.01 UJ 0.01 UJ 0.2 UJ 0.4 UJ 0.2 UJ 0.2 UJ 0.2 UJ 0.2 UJ 0.2 UJ 0.17 PJ 0.01 UJ 0.02 UJ O.OI UJ 0.02 UJ 0.02 UJ 0.02 UJ 0.037 IM 0,02 UJ 0.01 UJ 0.025 PJ 0.01 UJ MW-1 2/16/95 WAWOOSHE 0.02 UJ 0.03 PJ 0.02 1 IJ 0.01 UJ O.OI UJ 0.01 UJ 0.2 UJ 0.4 UJ 0.2 UJ 0.2 UJ 0.2 UJ 0.2 UJ 0.2 UJ 0.18 PJ 0.01 UJ 0.02 UJ 0.01 UJ 0.02 UJ 0.035 PJ 0.02 UJ 0.041 PJ 0.025 J 0.01 UJ 0.03 PJ O.OI UJ MW-1 5/9/95 XGIIOOI 0.02 U 0.043 P 0.02 O.OI U 0.039 P O.OI u 0.2 U 0.4 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U O.OI U 0.057 P 0.02 U 0.01 U 0.02 U 0.02 U 0.02 U 0.02 U 0.02 11 O.OIU 0.017 P 0.025 P MW-1 5/9/95 XOllOfll 0.02 U 0.025 P 0.02 U O.OI U 0.032 P 0.01 u 0.2 U 0.4 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U O.OI U 0.017 P 0.02 U O.OI U 0.02 U 0.02 U 0.044 P 0.0211 0.02 U O.OI U 0.015 P 0.022 MW-3 2/15/95 WAW003UE 0.02 UJ 0.02 UJ 0.02 1 IJ 0.013 J 0.01 UJ O.OI UJ 0.2 1IJ 0.4 UJ 0.2 UJ 0.2 UJ 0.2 UJ 0.2 UJ 0.2 UJ 0.01 UJ 0.01 UJ 0.02 UJ O.OI UJ 0.02 UJ 0.02 UJ 0.02 UJ 0.025 J 0.02 1 IJ O.OI UJ O.OI UJ O.OI UJ MW-3 5/11/95 XIU 1109 0.02 U 0.02 U 0.02 11 0.01 U O.OI U O.OI u ' 0.2 U 0.4 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.017 P O.OI U 0.02 U O.OIU 0.02 U 0.02 U 0.02 U 0.02 U 0.02 11 O.OI U . 0.013 P O.OI u MW-3 5/11/95 XllIIMWUE 0.02 U 0.02 11 0.02 1) 0.01 u 0.083 O.OIl P 0.2 11 0.4 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U O.OI U O.OI u 0.02 U O.OI U 0.02 U 0.02 U 0.02 U 0.02 II 0.02 U 0.014 P O.OI II 0.01 u MW-4 2/14/95 WAAOOI 0.02 U 0.02 U 0.02 U O.OIU 0.01 UJ O.OIU 0.2 U 0.4 U 0.2 li 0.2 U 0.2 U 0.2 U 0.2 U O.OIU O.OIU 0.02 U O.OIU 0.02 U 0.02 U 0.02 U 0.02 U 0.02 U 0.01 U 0,01 U 0,01 U Sec last page of table for notes. Harding Lawson Associates Table 4-12 Groundwater Sample Analytical Results - Pesticides and PCBs Virgin Island Chemical Company Sample Location: Sample Dale: Lab Sample ID: Results reported In micrograms per liter. Ilcptadilor epoxide Metlioxydilor Toxaphene MW-1 2/16/95 WAWOMIIE 0.01 UJ 0.1 UJ l.UJ MW-1 2/16/95 WAWDOSRE 0.01 UJ 0.1 UJ l.UJ MW-1 5/9/95 xoimoi 0.014 P 0.1 u l.U MW-1 5/9/95 XGU0fl2 O.OI U O.I 11 l.U MW-3 2/15/95 WAWnfl3HE O.OI UJ O.I UJ l.UJ MW-3 5/11/95 xintm 0.01 u 0.1 u l.U MW-3 5/11/95 XtniKWRE O.OI U O.I U l.U MW-4 2/14/95 WAAOOI O.OIU 0.1 U l.U 00 o to >^ t n 00 See last page of table for notes. Harding Lawson Associates c^- Table 4-12 V ' Groundwater Sample Analytical Results - Pesticides and PCBs Virgin Island Chemical Company Sample Location: Sample Date: Lab Sample ID: Results reportcti In micrograms per liter. MW-4 5/10/95 xinno3 MW-5 2/15/95 WA\VDOI s MW-5 5/10/95 xinr)02 MW-5 5/10/95 XTnW)2RE to o' IO' 4,4'-DDD 4,4'-DDn 4,4'-DDT Aldrin alpha-nilC .ilpha-CIilord.mc Ar.H:b<r-I016 Aroclor-1221 Aroclor-1232 Aroclor-1242 Aroclor-1248 Aroclor-1254 Aroclor-1260 bcta-DIIC delta-DIIC Dieldrin Endosulfan I Endosulfan IT Endosulfan Sulfate Eiiibin Endrin alddiydc Endrin ketone g.imma-DIIC (Liiid.Tiic) g.imma-OiIord.iuc Ilqitadilor See last page of table for noles. 0.02 U 0.02 U 0.02 U O.OI U O.OI U O.OI U 0.2 U 0.4 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U O.OI U O.OIU 0.02 U O.OIU 0.02 U 0.02 U 0.02 U 0.02 U 0.02 11 0.01 U O.OI U O.OI U 0.029 U 0.029 U 0.029 U 0.014 U 0.014 UJ 0.014 U 0.29 U 0.57 U 0.29 U 0.29 U 0.2? U 0.29 U 0.29 U 0.014 U 0.014 U 0.029 U 0.014 U 0.029 U 0.029 U 0.029 U 0.037 J 0.029 U 0.0I4U O.OI 4 U 0.014 U Harding 0.02 U 0.02 U 0.02 U 6.0i U 0.01 U O.OIU 0.2 1) 0.4 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U O.OIU O.OIU 0.02 U O.OIU 0.02 U 0.02 U 0.02 U 0.02 U 0.02 U O.OIU 0.01 U 0.01 U Lawson 0.02 U 0.02 U 0.02 U O.OI U O.OI U O.OIU 0.2 U 0.4 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U O.OIU O.OIU 0.02 U O.OIU 0.02 U 0.02 U 0.02 U 0.02 U 0.02 U O.OI U 0.01 U O.OIU Associates Table 4-13. Prod S^^ro Well No.' Well Idonlificalion Use' Year Const. Deptli (feel) Diam (in) n V i Within Three Miles of Site lslai.„ Oliemical Site bix, U.S. Virgin Islands age ra Interval (feel) Altitude {fl above MSI.) Deplh lo Water (fl below grade) Yield (8P"') Direction to o to tJI t tJl ^ 19-54 19-55 19-22^ 19-21 19-25a 19-2.''.b 19-250 19-25d 19-27 19-20 19-2;)^ 19-2411 19-241) 19-24(; 19-24(1 19-;i0 19-2!) 19-20 19-30 19-37 19.30 19-53 1 19-29 19-52 19-49 1 19-51C 19-51.1 19-5lb Former VJAPJ V well Possible well house at concrcle facilily Meridian 1 Meridian 2 AR-2-1 AR-2-2 AR-2-3 AR-2-4 Fairplains 0 Fairplains 9 Golden d r o v e AR-2-5 AR-2-(i AR-2-7 AR-2-8 I'airiilaiiis 2 Fairplains 7 Golden Grove Faiqilains 1 Fairplains G Fairplains 4 WAI'A-14 Golden Grove V T 1 2 W A I ' A - n WAl'A-15 Doling Near A Golden Grove VVAl'A-21 WAPA-21A Gorr. 2 Corr. 1 FW-O ngiiila 6 (PW G) NU C c NU NU NU •NU PS PS NU NU NU NU NU PS PS A PS PS PS NU PS NU PS PS NU NU PS NU - - -- -- 1990 1990 1990 1990 - - 1990 1990 1990 1990 -- - -- - -- -- 1909 1972/1973 -- 19(19 19(19 -- - 19H9 1989 - - - -- 57 56 57 59 55 05 47 50 57 50 59 «2 G5 80 70 00 G8 100 - - 120 100 - - 100 70 -- 8 8 4 4 4 4 0 0 G 4 4 4 4 0 I) 0 6 C a 4 - G G G -- 0 0 4 - - -- - screened 8-58 screened 18-58 screened 19-59 screened 19-59 -- -- - scieeiicd 18-50 sci-eeiiod 17-57 screened 18-50 screened 19-59 - - -- - - screened 20-40 -• - scKieiied 30-115 scKMMied 31-92 -- -- scix-.oiied :in-90 screened 15-70 -- - 19 23 22 21 21 21 18 25 37 18 19 21 28 20 10 38 20 20 20 25 ~ 44 30 :i5 - 40 40 40 27 23 22 22 19 19 19 27 20 IG 19 2(1 25 51 27 :)7 32 - -- - - - - - - 15-20 - - - -- - - 20 10-15 - < 5 < 2 :i() 20 80 60 SE NR NW NW SE SE SE SE SE SE W E P: E SE SE NW SE SE SE W W W W W W W Distance (feel) 60 150 600 700 1,000 1,000 1,000 1,000 1,000 1,000 1,000 1,100 1,100 1,100 1,100 1.100 1,100 1,300 1,300 1,300 1.400 2,100 2,500 2,600 2,(100 2,(100 2,900 2,000 2,900 2,900 .Sec last [Jiige for notes. Harding Lawson Associates 00 o to tn Table 4-13. Production « Virgin Isla. . Chemical Site Sl. Croix, U.S. Virgin Islands s Within Three Miles of Site Page T 8 Well No.' 19-30 1 19-45 19-50 19-48a 19-40b 19-48C 19-40d 19-47a 19-47b 19-47C 19-47(1 19-31 19-43 1 1 19-42a 19-42b 1 19-41 18-G2 10-63 19-40 10-61 19-7 1 1 19-32 19-G 18-70 1 Well Identification VT 0 Riggers and Erectors Port Aulhorily 4 WAPA-16 AR-1-1 AR-1-2 AR-1-3 AR-1-4 AR-1-5 AR-1-G AR-1-7 AR-1-0 VT 7 Negro Pay 9 Golden Grove PW-9 Negro Day 5 Negro nay 0 Negro Hay 8A Golden Grove PW-7 Negro Pay 7 Golden Grove 1, DPW-1 Negro Ray 1 Negro Day 6 Golden Grove 3 VT 1 Golden Grove PW-4 Negio Hay 4 VT 2 UV-1 VI pajrer Negro Bay 3 U s e ' NU C NU PS NU NU NU NU NU NU NU NU NU PS PS PS PS NU PS PS PS PS PS PS NU PS PS NU NU NU PS Year Const. - - -- 1909 1990 1990 1990 1990 1990 1990 1990 1990 - 1972/1973 1973 - -- 1972/1973 - -- -- -- -- 1972/1973 1973 - -- -- 1973 Depth (feel) ~ - 60 100 53 55 60 59 59 59 59 59 -- 102 - 95 35 -- - 102 60 96 113 66 - no 95 -- 90 90 95 Diam (in) 6 -- - 6 4 4 4 4 4 4 4 4 0 8 -- -- 8 8 -- 8 6 8 8 8 6 - - 6 6 8 - Inlerval (feel) - - -- screened 30-100 screened 13-53 screened 17-57 screened 20-60 screened 19-59 screened 19-59 screened 19-59 screened 19-59 screened 10-50 -- - -- - -- - - -- perforate! 64-104 -- - -- -- - -- -- - " -- Allilude (fl alxjve MSL) 24 -- 18 35 40 40 40 40 40 40 40 40 23 48 -- - 45 45 - 40 40 80 40 50 00 -- -- 21 90 40 - De ilh lo Water (fl below grade) 24 -- -- 44 34 35 37 37 32 32 33 33 24 - -- - - -- - -- 29 65 -- 25 00 -- - - 54 -- - Yield (81'n>) - - - 25 -- - - -- -- - - - -- < 2 -- -- - < 2 - - - - -- - - -- -- -- 2 Direction E SW W W W W W W W W W W E SW W SW SW SW W SW W W SW W NE W WSW E NW SW WSW Distance (feel) 3,000 3,000 3,000 3,000 * 3,100 3,100 3,100 3,100 3,200 3,200 3,200 3,200 3.300 3,300 3.300 3,400 3,400 3,400 3,400 3,500 3,.5O0 3.500 3,600 3,600 3,700 3,700 3,700 3,000 3,000 3,900 4,000 O .S(!e last page for notes. Harding Lawson Associates Table 4-13. Production V, Within Three Miles of Site Virgin Islai.. .chemical Site Sl. Croix, U.S. Virgin Islands Page to o to Ul <1 Well No.' 19-41 1 18-60 10-59 1 19-44 19-4 1 18-58 1 19-5 1 19-46 19-10 19-9 18-43 19-111) 19-10 19-11a 18-44a 18-441) 19-12 10-42 18-37 18-30 19-13 18-39 18-40 18-41 27-4 19-8 Well Idonlificalion Negro Bay 6 Golden Grove PW-2 Golden Gr. Trailer Pk 3 Golden Gr. Trailer Pk 2 Golden Grove PW-3 Port Aulhorily 5 USDA College of V.l. Golden Gr. Trailer Pk 1 Near Profil Ansiiliiio CoriKiliiis Airport V T 10 V 11 V 9 WAPA 19 V 7 V 1 V T 9 WAPA 2 WAPA 2A V 12 WAPA 20 WAPA 5 WAPA 6 V 8 WAPA 17 WAPA 18 WAPA 7 ( ^ i i z a i i Riiiii 1 V 10 U s e ' PS NU C c PS PS A D C NU A NU NU NU NU PS NU NU NU NU PS NU PS PS NU NU NU PS PS 1 NU Year Const. - 1972/1973 - 1972/1973 - 1909 - - - 1990 - - 1990 1990 1909 1990 1909 -- 1989 1989 1990 1989 1989 1989 1990 1909 1909 1909 1962 1990 Deplh (feel) 120 - 00 - 60 90 95? 110 - 100 -- - 140 170 100 170 100 -- 60 60 130 100 100 100 150 95 90 100 110 150 Diam (in) - - G 6 - - 4 - G - 6 - 6 (i 6 6 6 G G G 4 G G 6 6 6 4 G 6 0 6 Inlerval (feel) - - - - -- - -- -- -- - -- - -- screened 20-00 -- -- -- scr(!cned 20-60 screened 20-40 -- screened 20-95 open hole 20-00 sci-eencMl 20-80 - screened 10-40 screened 20-80 screened 20-80 screened 58-110 - Allilude (fl above MSL) - -- G5 70 - 20 04 - 70 - 63 - 11 98 105 56 104 62 104 50 50 81 58 GO 02 95 75 62 70 35 100 Depth to Water (ft below grade) - • -- -- - - 40 - - - 10 -- 0 83 107 17 100 -- 104 14 14 03 14 21 26 94 13 13 12 - • 98 Yield ( R P " ' ) 54-62 - -- -- -- 3 -- - - - -- - - - 30 -- - 25 30 60 30 25 - < 5 25 30 - — Direction W S W 00 NW NW 2 SW N NNE NW NE N SW W NE NE NW Nt: NE NE NW NW NE NW NW NW NE NW NW NW SW NE Distance (feel) ^ 4,000 4,100 4,200 4,300 < 4,400 4,500 4,600 4,600 4,600 4,900 5,000 5.000 5,100 5,300 5,400 5,400 5,500 5,500 5..500 5,500 5,500 5,600 5,600 5,G00 5,900 6,000 6,000 6,000 6,000 6,000 6,100 ^ ^ " , ^ S / i St« lasl page for notes. Harding Lawson Associates 00 o to tn 00 Well No.' Table 4-13. P r o d u c t i o n ^ ^ ^ s Within Three Miles of Site Virgin Islii. . Chemical Site Sl. Croix, U.S. Virgin Islands P a g t ^ t 8 Well Identification Use' Year Const. Deplh (feel) Diam (in) Inlerval (feel) Allilude (fl above MSL) Deplh lo Water (fl below grade) Yield (BP'") fJircction Distance (feel) 19-14 V 5 10-15 V 4 19-33 V T l l 19-17 V 2 19-16 V 3 10-73 WAPA 3 18-46 Adventure 10 18-45a WAPA 14, Adventure 10-451) WAPA 4 19-1 Diaz Housing Proj. 1-12 18-34 WAPA 12 19-34 VT 4 19-35 VT 5 19-19 V T 3 18-47 Advciilurc 28 18-48 Adventure A 10-33 WAPA 11 10-49 Adventure I) 18-32 Windmill 1 18-50 Adventure C 10-31 Windmill 2 18-30 Winduiill 3 18-51 Adventure 15 18-72 WAPA 1 18-52 Adveiiliire D 10-53 Advi-illlllt; 10 20-41 Hess 1274C 20-43 Hess 1274A 20-42 Hess 127411 20-44 I less 1274D 10-14 Elizabclh Benjamin See last |)iigo for noles. NU NU NU NU NU NU A PS NU PS NU NU NU NU NU PS NU PS A , PS A A PS NU PS PS I 1 1 . 1 D 1990 1990 -- 1989 1990 1989 1962 1962 1909 1989 -- - 1966 1985 1009 1985 - 1985 - - 1962 1989 1985 1962 1967 1967 1967 1967 1956 175 150 - 120 145 no 66 85 100 100 100 - - - 54 110 100 no 30 106 30 30 106 127 110 127 - - - -- 150 6 6 6 6 6 4 0 6 4 -- 4 6 6 6 4 0 4 0 6 0 0 G 6 4 8 8 8 8 8 8 6 - -- - - screened 50-90 screened 37-103 screened 36-107 screened 40-00 -- screened 20-00 - - screened 30-50 - screened 20-00 - - - - - scr(;ened 34-106 screened 60-00 - scixuuied 38-127 - - - - .. 100 85 35 80 83 60 70 80 80 120 00 26 11 02 00 70 80 75 95 80 95 95 80 00 00 80 00 70 92 39 110 101 01 36 01 34 14 64P - -- 20 26 12 02 30 - 12 - 17 29 -- -- 29 35 - 35 -- -- -- - 0 - -- - < 5 - 40 < 5 - 55 - - -- - 10-12 4 - 1 - -1 - - 5 10-12 65 - - - - - NE NE E NE NE NW NW NW NW N NW _E F. NE NW NW NW NW NW NW NW NW W W W W E !•: E v. NW 6,200 6,300 6,400 6,500 6,500 6,800 7,000 7,000 7,000 7,100 7,200 7,300 7,600 7,600 7.000 7,800 7,800 8,000 8,000 8,100 8,100 8,200 8,200 8.200 8.300 8,400 0,700 0,800 0,800 8,90(1 9,000 ^ *'«<7 : Harding Lawson Associates 00 o to l{^ tn yo Table 4-13. Production i : Within Three Miles of Site Virgin Islai... Cliemical Sile Sl. Croix, U.S. Virgin Islands Page f 8 Well No.' 18-71 20-45 19-3 9-40 20-21 18-22 18-24 18-69 10-54 20-27 10-17 10-23 18-25 18-21 18-18 10-20 10-19 20-20 20-50 10-13 10-15 20-26 20-23a 20-23b 10-10 20-22 20-20 Well Idenlificalion Monserrale Garcia VT6 UV2/Exp. Slalion Rcxlriquez Guadehipe 1 lousing Projecl Ilarren Spot 4 Miguel Garcia Peter Cliffy Brown Hous. Proj. 1-18 Ml. Pleasaiil Hous. Proj Barren .Spot 0 Geoigi! Dubois jaines Lawrence Pliilli]) Sleadiuaii Randolf Wilson Joseph Francof Mai'cia Valiiiont Santiago Barren Spot 31 WAPA 22 Bishop Grafton Farall Barron S|)ol 3A WAPA 23 WAPA 23A Frederick Raymond WAPA 25 Barren S|)ol 7 Use' NU NU D PS PS D D PS PS PS D D D D D 1) A PS PS D.A C PS PS NU D PS PS Year Const. - 1982 -- 1961 1980 - 1061 1990 - - - 1076 - 1962 1989 •-- 1964 1089 1909 1907 1909 1961 Deplh (feel) - - 95 125 106 50 - 150 125 55 -- 50 65 50 60 - 131 no 75 -- -- no 110 - 120 140 Diam (in) 6 6 6 - 8 6 6 - - 8 G 8 6 6 6 0 10 0 G 6 G 0 G 4 6 6 0 Inlerval (feel) - -- - -- perforated 57-88 open hole 88-115 - -- -- -- screened 59-120 open hole 120-130 - -- -- -- -- - -- screened 49-108 open hole 108-131 screened 70-110 - -- -- sciiu;ned 70-110 screened 70-110 - screened 78-118 screened 55-115 oixiii hole 115-140 Allilude (fl above MSL) 120 -- 100 135 68 120 110 100 120 GO 120 117 120 120 120 120 120 55 65 115 130 65 65 65 1.30 65 55 Deplh lo Water (fl lelow ^lade) - 9 -- - 59 - -- -- - (by -- - -- - - -- - 51 53 -- -- - 57 59 -- 50 52 Yield (R\>"') - 9 4 -- 20 - • . -- -- - - -- -- -- -- - -- 10 15 -- 80 80 - 70 15 DirccUon NW E N N NE NW NW W W NE NW NW NW NW NW NW NW NE NE NW NW NE NE NE NW NE NE Distance (ted) 9,100 9,600 9,700 9,900 9,900 9,900 9,900 9,900 9,900 10,000 10,000 10.000 10,000 10,200 10,300 10,300 10,300 10,400 10,500 10,500 10,500 10.600 10,600 10,600 10,600 10,700 10,800 5r Q 18-12 Albert Slephens 38 130 19 NW 10,000 Sec lasl (Kigo for noles. Harding Lawson Associates Table 4-13. P r o d u c t i o n ^ s Within Three Miles of Site Virgin Islu..- Chemical Sile SL Crobc, U.S. Virgin Islands Page f 8 Well No.' Well Identification Use' Year Const. Depth (feel) Diam (in) Inlerval (feel) Allilude (fl above MSL) Deplh lo Water (ft below grade) Yield (RP'"1 Direclion 0 0 o to o 20-4 19-2 18-11 18-3 8-25 8-22 8-23 9-47 8-21 20-24 9-40 8-20 20-20 20-25 18-28 8-19 10-10 9-39 8-13 18-65 18-64 8-15 8-10 8-16 8-17 8-12 10-66 27-3 10-27 Barren Spol 5 William Cecil 1 Rene Comelly Bally Annaly Farms 1 J. Kidd (J. Sanliago) M. .Santiago RichartI Schrader Crnzan Gaixlcns 1 Biirreii S|)f)l 6 William Cecil 2 Antonio l''igeroa Barren Sjiot 1 WAPA 24 Micha Williams Cnizan Gardens 2 Anipiilla I.oii|)e Eulogio Bermudez Reuben Gomez Crnzan Rum 4 Cruzan Rum 5 Cai-anibola 10 Caraiiibola 13 Caranibola 11 Caiiiiubola 12 Henry Gore Cruzan Rum 6 Cruzan Rum 2 .ST.X Mutual Home 2 PS D D A A NU D D NU PS NU 1) PS NU NU NU NU NU D I 1 A A A A D NU I C 1961 1968 - " - 1960 1966 - 1064 - 1067 1989 -- - -- 1972 - 1900 - 1986 1986 1964 1064 1024 1062 — 128 90 -- -- - 85 125 55 00 94 125 80 08 120 24 -- - 60 - 120 - 40 60 135 75 106 109 85 6 6 8 6 -- 6 6 6 6 G -- a 8 G 48 6 6 6 6 6 6 0 6 6 G 0 8 6 screened 55-75 perforated 71-130 -- - -- -- - -- -- -- screened 50-121 - - - screened 80-120 -- - -- - -- screened 86-120 -- -- - - - screened 44-109 .. 75 131 150 135 140 175 175 160 170 80 100 170 90 93 160 180 160 175 200 60 60 260 275 265 270 180 60 40 195 67 10-20 NE Distance (feel) 10,900 - -- 7 - - - - - - - - 00 79 3 -- - . - - - - - - - - - 43 - .. . - - - 2 15 -- -- 20-:i5 -- 25 10-20 35 -- - -- -- " 4 -- 40 8 0 25 -- 12 -- - NE NW NW NW N N N N NE NE N NE NE NW N NW N N W W NW NW NW NW NW W SW NW 11,100 11,100 11,300 11.400 11.500 11,500 11,500 11,700 11,700 11,000 11.900 11,900 11,900 12,000 12,200 12,500 12,800 12,000 13.000 13,000 13,100 13,100 13,200 13,200 13,200 13,200 13,400 13,500 See lasl page for noles. Harding Lawson Associates Table 4-13. Production Is Within Three Miles of Site Virgin Island Cliemical Sile Sl. Croix, U.S. Virgin Islands Pagi >f 8 Well No.' Well Idenlificalion Use' Year Coiisl. Depth (feet) Diam (in) Interval (feel) Allilude (fl above MSL) Deplh lo Water (fl Ijclow grade) Yield (gP'n) Direclion to o to 10-67 9-40 9-36 8-9 9-38 18-29 18-26 20-30 0-37 10-56 9-34 9-35 9-33 9-46 20-31 0-0 9-41 10-7 10-60 9-45 0-24 18-G 20-32 18-5 20-33 9-44 0-7 20-7 10-2 10-9 Cruzan Rum 3 Alfred Grcenway Francisco Navarro 1 Governmenl Windmill l.ouise Williams STX Mulu.nl Home 1 STX Mulual Home 3 Hess 14 Nobert Coviello Bolnnical Gardens 2 Ariiioiiio Carrascpiillo P'raiicisco Navarro 2 Ramon Cruz II. Moolenar Hess 13 Beniano Rodriguez OliviM- Skov 1 laymen Arnold 4 Brown Hous. Proj. 1-23 Preiiia Khan Ethel Brathwaile llayiiien Arnold 3 Hess 12 Hayment Arnold 2 Hess 11 Daniel Andino Henry Samuel lohansen 2 Carlis ll(dl Ral|)li George NU NU D NU D C C 1 NU NU NU D D A 1 D NU NU PS C D NU 1 NU 1 NU D D.A NU D,A 1904 1974 1947 1967 -- - 10G7 1967 - - - -- 1967 -- 1967 1990 -- ... -- 1990 1967 1990 1967 1038 1058 - 122 12 65 45 52 75 -- -- 70 102 - 65 00 175 -- 50 170 - 150 90 75 - -- - - 218 67 100 8 36 6 G 6 6 6 0 G G - 6 6 0 8 6 6 6 - G 6 4 8 6 0 6 G 6 6 6 screened 42-91 open hole 01-122 -- - - - - - - open hole 21-70 -- - -- -- - " - -- -- - - - -- - - - scrcenof scrceiiei - 55-75 5G-7G 60 180 210 210 210 195 200 45 220 145 230 220 230 260 40 230 1(10 220 95 100 205 230 49 230 51 180 280 130 220 200 50 W Distance (feel) 13,500 - 13 - - - - 43 - -- - -- 110 - -- 92 - -- -- -- - -- -- - 126 30 — -- • - - B 8 - -- -- 8 -- - -- -- - -- -- 2 -- - - - - -- :; • - - 10 7 - N N N N NW NW E N W N N N NE E N N NW W N NW NW E NW 1' N N NE NW NW 13,600 13,600 13,600 13,600 13,600 13,600 13.700 13,700 13,700 13.000 13,000 13,000 13,800 13,900 13,900 13,900 13,900 13,900 14,000 14,000 14,000 14,100 14.100 14,400 14,400 14,400 14,400 14,400 14.400 ^ See lasl page for noles. Harding Lawson Associates 00 o to a\ to Well No.' Well Idenlificalion Use' Table 4-13. Production \ s Within Three Miles of Site Virgin Islanu Chemical Sile Sl. Croix, U.S. Virgin Islands Page f 8 Year Const. Depth (feel) Diam (in) Interval (feel) Allilude (fl above MSL) Deplh to Water (fl l)elow grade) Yield (BPm) Direclion 10-57 Botanical Gardens 1 20-34 Hess 10 8-11 Carambola 8 18-8 Maymen Arnold 5 10-10 Hellhrop 8-10 Carambola 9 18-1 U.S. Government 10-11 Emmanuel 20-8 Johaiiscii 1 10-4 Hay men Arnold 1 10-55 Felix Peleison 12 27-1 Daniel Lloyd 10-36 (^iiiiiiiiings 10-35 Ruby Fleming 17-21 Felix Peterson 2 17-24 Felix Peterson 1 9-32 Adam Kalloo 0-14 Mari(;d Decembre 27-2 Brcnda Hall 9-43 Henry Carter 1 9-42 Henry Carter 2 /\ I A NU D A NU D D NU NU D NU D NU NU NU D D NU NUl "" 1967 1986 1990 - 1900 -- 1969 1000 - - 1060 - - - - 1054 1054 56 60 60 175 05 65 6 0 8 6 6 6 G 6 0 6 6 6 6 6 6 6 G 6 6 6 6 perforated 71-130 0|ieii hole 21-110 open hole 30-65 160 53 180 240 150 170 230 155 150 230 175 53 210 240 180 180 05 275 35 220 265 20 20 15 Distance (feel) W E NW NW NE NW NW NE NE NW W SW NW NW E E N NW SW N N 14.400 £ j 14,500 < P ^ 14,500 ^ ^ 14,500 Z " * * ^ 14,600 ^ ^ 14,600 14,600 14,600 14,800 14,000 14,000 14,000 15.100 15,100 15,400 i 15..500 15,600 15,600 15,600 15.700 15,700 ': Well Niiiiiber refers lo maps included in A|i])ondix K. Where no well number is provided, insufficient informalion is available lo locate ihe well. ': Well Use: A: Agriculture or Slock C; Commercial D: Domeslic I: Induslrial NU: Well noi in use PS: Public Supply 3. Wells VIPA 1 and VIPA 2 were identified by NUS corporalion. These wells apixiar lo corresjxjud lo the wells idenlificd above as Meridian 1 (10-22) and Golden Gr. Correctional 2. -: Informalion not available Souree: Adapted from USGS, 1004; Geraghty & Miller. 1903; Torres-Gonzalez. 1990 and HLA Site liis[)cction, 1995. Harding Lawson Associates Table 5-1 Parameter Detected Acetone Carbon Disulfide Ethylbenzene Trichloroethene Toluene Xylenes (Total) bis(2-Ethylhexyl}phthalate Butylbenzylphthalate Di-n-butylphthalate Di-n-octylphthalate Pentachlorophenol 7-BHC a-Chlordane 7-Chlordane Endosulfan II Endrin Endrin Aldehyde Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromiimi Cobalt . Parameters Detected and ARARs SoU Samples Virgin Island Chemical Site St. CroLx, U.S. Virgin Islands Proposed RCRA Action Level' 8,000 8,000 8,000 60 20,000 200,000 50 50 - - 200 0.5 " - - 20 - - 30 80 4,000 0.2 40 - " — Maximum Concentration Detected' 19' 0.003' 57 0.001' 1' 310^^ 0.72 0.49 0.057' 0.12' 1.9' 0.0048 0.0072' 0.0077 0.016' 0.005""' 0.0042' 28,200' 1.3^' 1.5«' 274 0.58 6.4 133,000 31.4'' 31.7 "V See last page of table for notes wordproc\2g872\dsr02.tbl Harding Lawson Associates 302463 Copper Iron Lead Magnesium Manganese Mercury Nickel Potassium Sodium Vanadium Zinc Table 5-1. Parameters Detected and ARARs Soil Samples Virgin Island Chemical Site St. Croix, U.S. Virgin Islands "^ 20 2,000 141^-' 63,400*' 89.9 13,900 2,100 0.33 26.9*' 4,330 2,430 194* 5,790^*' # ^ Notes: All concentrations presented in milligrams per kilogram. ' Examples of Concentrations Meeting Criteria for Action Levels (Fed. Reg. 55 No. 145) ^ Soil samples collected by HLA in January 1995 Not available ^ Detected in sample and associated blank ' Estimated concentration •'^ Spike recovery not within control limits ^ Exceeded the calibration range of the instrument '' Greater than 25 percent difference between 26C columns Duplicate analysis not within control limits wordproc^29872\dsr02.tbl Harding Lawson Associates 302464 =^ Table 5*2. Soil Concentration Comparisons Metals Detected in Samples Analyzed by HLA Virgin Islands Chemical Site St. Croix, U.S. Virgin Islands >"^ '^• Metal Detected Ranges in Concentrations of Metals Reported in Soil Samples HLA Minimum Maximum USGS' Minimum Maximum Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Nickel Potassium Sodium Vanadium Zinc 9,350 0.32 0.95 44.1 0.15 1.1 4,460 8.8 8.1 27.9 18,100 1.9 4,340 216 0.13 10.4 597 358 48.7 35.1 28,200 1.3 1.5 274 0.58 6.4 133,000 31.4 31.7 141 63,400 89.9 13,900 2,100 0.33 26.9 4,330 2,430 194 5,790 NA ND (100) ND (200) 50 ND (20) ND (20) 1,500 10 ND (10) 30 30,000 10 7,000 700 NA < 5 NA 3,000 70 ND (200) NA ND (100) ND (200) 1,500 1.5 ND (20) 70,000 300 100 100 50,000 300 15,000 10,000 NA 200 NA 10,000 200 <200 All concentrations presented in milligrams per kilogram ND Not Detected (Detection limit presented in parentheses) NA Not Analyzed ' Source: Adapted from Gold, Silver, Tcl'urium, and Spectrographic Analyses for Rock and Soil Samples flxjm the U.S. Virgin Islands, Open-File Report 89-355, 2USGS, J 989 wordproc\29872\dsr02.tbl Harding Lawson Associates 302465 <s ! ^ :a t:^;* Table 5-3. Parameters Detected and ARARs Groundwater Samples Virgin Island Chemical Site St. Croix, U.S. Virgin Islands ' ^ Parameter Detected Potential ARARs' Primary Secondary MCLG RCRA 7/27/90 Maximum Concentration Detected^ Volatile OrBanic Compounds Acetone Chloromethane Ethylbenzene Methylene chloride Toluene Xylenes (Total) Semivolatile Organic - - 700 - 1,000 10,000 Compounds bis(2-Ethylhexyl)phthalate 4-Chloroaniline 2,4-Dimethyl phenol 4-Methylphenol Isophorone Phenol Pesticides Aldrin a-BHC /9-BHC A-BHC 7-BHC cx-Chlordane 7-Ghlordane 4,4'-DDE 4,4'-DDT Endosulfan Sulfate Endrin Endrin Aldehyde Endrin Ketone Heptachlor Heptachlor Epoxide See lasl page for notes. - " " - " - - - - - 2 2 2 - - - 2 - - 0.4 0.2 .. -- 700 - 1,000 10,000 .. .. " .. - — - - - .. 2 0 0 - - - 2 - - 0 0 - - - - - - - - - - - — - - - - 4 - - " - - 0.2 - - - — 4,000 - 4.000 5 10,000 70,000 3 - " 2,000 90 20,000 0.002 0.006 0.2^ - - 0.03 0.03 0.1 0.1 " - " - 0.008 0.004 S' 2 750 0.6^' 5' 2,100' 42^ 2' 30 48 0.7' 0.8' 0.013' 0.083' CIS""' 0.057'' 0.014'" O.Oll'' 0.03'"' 0.043'' 0.02 0.035'' 0.044'' 0.041''' 0.025' 0.025'' 0.014'' wordproc\29872\dsr02.tbl Harding Lawson Associates 302466 . • ^ V An- T a b l e 5-3. P a r a m e t e r s D e t e c t e d a n d A R A R s Groundwater Samples Virgin Island Chemical Site St. Croix, U.S. Virgin Islands ^xf'age 2 of 2 Parameter Detected Potential ARARs' Primary Secondary MCLG RCRA 7 m m Maximum Concentration Detected^ Dissolved Metals Aluminum Antimony Arsenic Barium Beryllium Calcium Chromium Copper Iron Lead Magnesium Manganese Mercury Nickel Potassium Selenium Silver Sodium Vanadium Zinc 200 64" 2,000 4 100 — " " — 1,000 300 — 2,000 4 100 1,300 _. 50 1,000 " 50 - 10 0.008 95.6 IN- 8.2 BN 286 0.34 BMW 211,000 8« 50 2 100 50 100 5,000 300 - 0 " - 2 100 - 50 - - - _, - - 50 - - 2 - - 10 50 - - __ ", - - - - - 700 - - - " - 72.8^" 9,770 44.4NS- 89,800 5,130"^ 0.45^ 38.2^ 26,500 ^7gB)NW 6.9^'^ 411,000 32.5" 160 Notes: All concentrations presented in micrograms per liter. ' Potential applicable or relevant and appropriate requirements (ARARs): Primary: National Primary Drinking Water Ma.ximum Contaminant Levels (40 CFR 141.61 and 141.62) Sefxmdary: National Secondary Drinking Water Maximum Contaminant Levels (40 CFR 143.3) RCRA: Maximum Concentraiions of Constituents for Groundwater Protection under RCRA (40 CFR 264.94) MCLG: MCL Goals (40 CFR 141.50 and 141.51) 7/27/90: Example Concentrations Meeting Criteria for Action Levels (Fed. Reg. 55. No. 145) ^ Groundwater samples collected by HLA in February and May 1995 Not available Detected in sample and associaled blank Estimated concentration Spike recovery not within control limits Determined by Methcxl of Standard Additions GFAA post-digestion spike out of control limits Duplicate analysis not within control limits wordprc>c\29872\dsr02.lbl Harding Lawson Associates 302467 ^olr^roSS- ..---r- . • - - = > i . : '•.rcrXX) PTofit.i-'RmnsJ-:d-'' 'Go\iie-r\^'-^^^X<X y N-Vl \ ^~^\/ ^ _ ^ ^ . , . J V I A^\ —. '^Grcrve*- -.\jx-^ ^ ^ \ r . \ ''^, Uooer Bethle<ieih( V : ? ? ^ ' ' ^ ' j Harding Lawson Aasocfotes SUE LOCATION MAP ' Engineering ond Environmental Services . ^ 1 3 1 North Third Street " " Philodelphia. PA 19106 5 S J 215-627-4505 VIRGIN ISLAND CHEMICAL SITE ST. CROIX. U.S. VIRGIN ISLANDS ncuRE 1-1 ; DRAWN ; JSW JOe NUMBER 29872.13.2 APPROVED f i l l S-BASE DATE 6/6/95 REVISED NO. 302468 302469 U i o to o S4' -48' 4 6 ' • 17*44' 42' 52- 64-50' 4 r 4«' —r— 4 4 ' — I 42' 6 4 ' C J R I B B /•: J X SALT m v t « tSTUART m CRANDC PRINCtSSC COLDCN ROCK «. t BD BEACH DEPOSITS AL AUUVIUM KL KINGSHia UMESTONE JF JEALOUSY FORMATION GDI CABBROIC It DIORITIC INTRUSIVES U t O MT. EAGLE GROUP Harding Lawson Associates REGIONAL GEOLOGICAL MAP Engineering ond Environrnental Services < ~ 131 North Third Street ^ ^ Philodelphia, PA 19106 215-627-4505 VIRGIN ISLAND CHEMICAL SITE ST. CROIX. U.S. VIRGIN ISLANDS HGURE 1-3 DRAWN JSW JOB NUMBER 29872.13.2 APPROVED FILE S-BASE DATE 6/7/95 REVISED DATE 302471 T' 'V" LJ LJ t n f - ^ 1— m 1— to t - r-- h- oo \- O) 1 - o T - 1 1-- UNPAVED MW-1 ^ EARTHEN BERM DRIVEWAY WALL SUMP CO (O O a: >- < o < > UJ 2 _ J UJ 2 UNPAVED GENERATOR BUIIJ}|NG a PADS CD p-1 Hi MAINTENANCE BUILDING CONCRETE OPEN REACTOR AREA °lo PROCESS [ x y x y i AREA LEGEND MONITORING WELL PRODUCTION WE:LL INLET EXISTING ABOVEGROUND STORAGE TANK TANK PAD-FORMER ABOVEGROUND STORAGE TANK LOCATION FOR ILLUSTRATION PURPOSES ONLY SQUBCL PROPOSED ICC SOIL SAMPLING LOCATIONS BY ENVIRO-SUENCES. INC. DATED: 6 / 1 9 / 8 6 AND SHE MAP. VI ClltMlCAL. ST. CROIX. U.S.V.I. BY NUS CORPORATION DOCUMENT 0 2 - 9 1 0 1 - 0 4 - 5 1 . UNDATED Harding Lawson Associates Cngineerfng and ISHSZ Environmental Sen/Ices F i ^ 131 North Third Street ' J l , ^ Phrlodttlphio. PA 19106 215-627-4505 WELL LOCATIONS VIRGIN ISLAND CHEMICAL SITE ST. CROIX, U.S. VIRGIN ISLANDS FIGURE 2-2 DRAWN JSW JOB NUMBER 29872.13.2 APPROVED FILE 29872601 DATE 5/6/95 RE?v1SED DATE 302472 Ui o to Harding Lawson Associates — ^ Engineering ond ZZZZ Environmental Services ? ^ ^ 131 North Third Street ' 2 m ^ Philodelphio, PA 19106 = S S 215-627-45C5 GENERAUZED GEOLOGICAL FENCE DIAGRAM VIRGIN ISLAND CHEMICAL SITE ST. CROIX, U.S. VIRGIN ISLANDS RGURE 4-1 DRAWN JSW JOB NUMBER 29872.13.2 APPROVED RLE S-BASE DATE 6/9/95 REVISED DAT: REVISED DATE 302474 REVISED OAU; 302475 REVISED UO. 302476 APPENDIX A Groundwater Sampling Forms 302477 GROUNDWATER SAMPLING FORM Page 1 of '_ lob Name; Island£fteitAiit&C(tn<pSB»r*'^ jb Number:29a72 Recorded By: A-lfjmiA \ J (Sigmuure) y W e U W : - . , . . ^ - ^ ' / Well Type! • ^J^onilor Well Material: , f ^ ' f VC* Date: ^jjllj^tr' Sampled By: Sleohen Brueckner, lame D Extiaction D Sl. Steel Time: s Collins n Other D Other (Sampling Team Members) INSTRUMENT IDENTIFICATION RECORD Instrux$)iO- PID CondtJFtvity Temp. yt>'9. TfM mi Dissolvi olv|dJ3J. .Turbidity ORP Depth to W a t e r y , JWTfaA^i ' • ' . m a^M. Tv''.C \ i For Calibration Inrormation, see Instrument Calibration Record dated Iiiiiiiiiii Casing Diameter (D in inches): T Total Depth of Casing (TD in feet BTOCl: 3 5 " . M 6 Water Level Depth (WL in feet BTOC): % 1 . 0 ^ i • . , , Screened Intenfata'WA^QCUromg'f.^ Xa^JfA iiiiiiiiiiiiiiiiiiiiiiii TD (feet) WL (feet) D (inches) - : : ^ . ^ r o .,. WELL PURGING ^ '^r.ifXd'^f - PURGE J^ETHQpo-;.-,^ ^.,.;. ^^-C 3-3 j a i l e r - Type: ^ ? ^ C D Submersible D Centrifugal D Bladder; Pump No.: _ n Other - Type: \ PUMP INTAKE SETTIMG n Near Bottom D Near Top t^y.oo n Other: Depth in feet (BTOC). 3. No. Volumes X 0.0408 = iipii Gallons Calculated Purge Volume • <fl:^ S0V5 c(r2« \(i\<\ l«MJ J . Minutes Elapsed 0 as \s HA « ^ T-r r TTTTT \ . • iHfe (gpm) ^i -r oallons Purged" ^ ' • ^ yk.%r ^ U . S /5 • J Turbid. ^(NTUs) X«t>o, S;2^ ^3on > 3 . ^ y/^ iilii|iililllEii|i^ Rtedox'- Pot.(mV) m.5 •/2.5,9 121."^ 151.1 /wwv Diss. 0 , 2T>,/ 30.-^ w.w x\.^ NIA pH • 7 . ^ 7^7 ^.<5 i.i^ A/^ Cond. (^mhos/cm) 24.-70 236.(5 i i - J O o.\^.t hJ/A. Temn 54 7«''7 7^.2- ^8.? ? « , « A)M >?»;>.3 Depth to Water WAA >VA/\ NH\ H l ^ W.<2' b 11. - wv ll^\Z^}^Z l /^b.-'iLfilPfl 5- 10 IM- IS *» r^Pij. f - L l *'*.0 kM^ l:^ ':^*i}l N.M - Noi .V(e«5ured GBSERM^P^^:i;DtllRING;|/ELiPURGlK!G tuibidilv'lQuaiilatative): VNt«^H Purge Water Disp.: D San. Sewer D Storm Sewer B Drum: Type Well Condition: Odor: »Wr>J _ J ^ _Color; Other: /«l(w\) fCWVs . Size 55 gal D Other: 302478 \WORK\27654\FORMS\GWSAMPLE.FRM Form Printea: T e * u ^ ^ t f i l 9 9 5 MV/"1 GROUNDWATER SAMPUNG FORM Page 2 of _ Well No.:. Job Nam*: Island Chemical Company Job No.: 29872 Task No: 07.1 Date: 3711/Cty Time: Recorded by: ijXAkt^i HfV«Ai»Ar fmsy Af^ALYSES PRIOR TO SAMPUNG WELL SAMPLING »/ Time Depth to Water (feet) Turbidity (NTUs) Redox Pot. (mV) DUs O, •(;ng^)»^) itt pH Cond. itJmhoplcm) Temp\. f|;£ Comments ^\:.;^ I ^^ 1(10 Itil >aAC il^.S" !iU^ 1.01 34^) 3AiL •^v.<>ytl^Ul^^ laSi aLir <VAv ^^^ /VM /^/A^• /WAV W/A } t U ^ ^ tf^ sote Ui ~ oreaier IbtD SAMPLUKMETHOD , , _ f, • qiBailer - Tj-pe: UrtitffcSU. I C H P » > n Submersible D Centifugal Q Bladder; Pump No.:, D Same as Above n Grab - Type: D Other - Type:, SAMPLir^ DISTRI Label Nos. 2^O2\0\\ anf^lOQ . p^i^zioi-s , .V..; - BUTICfl Sample Name: _ Containers No., Size and Type 5 X 40-mL glass VOAs 2 X l-L .Amber GUgi 2 X l-L AJnbeV Glass 2 X l-L Amber Glass 1 X l-L Plastic i J t . l A Plastic 1 X'1-L AmbeJ-.Glass " * • ; . >-'. i -ft.^J. 'viysH\io^\^'\^ Analysis Requested TCL VOCs -1- 15 . TCL SVOts -1- 15 Pyridine H, ^"^ ^ Pesticides/PCBs TAL Inorganics (Total) TAL Inorganics (Dissolved) '. "Gyajiide " ' * . - , .' . f- . . \ . . .. -j'- ^z .n:- ' .' .' ^,. Laboratory: Preservatives HCl pH = 1.0 None None None HNO3 pH = l i ^ HNO3 pH = 1^5" NaQHpH^|2,.S f , '.?•.•• V . - ' f V . ' V > 'ACE Inconxjrated Laboratory • •• ; Conunents No'keadspace 1 • ' '^ . - • , f . • iM^iv,\ Field FUtered / - W l ,/t^^ Preservatiy*%dded after filtering lM.«r«V * * • . . • • . } ' • ' " *••. <'r • ' r -.» " ' t . y > - " QUAUTY CO^fTROL SAMPLE? Duplicate Samples Blank Samples Other Samples Orig. Sample ID AW>t/oai4A5" Dup, Sample ID >MiA/-l^ty02U^S Type Trip Blank Rinse Blank Sample ID Type MS/MSD Sample ID s ' - * ; I . ' «««» * ^T.''* VVORK\27654\FORMS\GVVSAMPLE.FRM 3 0247 9 Form Printed: February 10, 1995 GROUNDWATER SAMPUNG FORM Page 1 of WeU No.: AlW' 3 Job Name: Island C^^tndA-QbmtA&yT'^ Job Numberlj9"a72 , X Task: 07.1 Recorded By: i t n a u r t ) ^ n Well Type: ' ^Monitor WeU Material: , ' 'tfpVC Date: U ^ Sampled By: Stephen Brueckner, lame • Extraction n St. Steel Time: . Collins D Other D Other (Sampiing Team Members) INSTRUMENT IDENTIFICATION RECORD Instrument PID pH Conductivity Temp. Dissolved O; yum Turbidity ORP Depth to Water Ofi(>d. IS Serial No. aia5 -j^o-'ii f'^i •S2S4 1\D<3H<M4 llO^S «l»WOOX; :iV For CaUbration Information, see Instrument Calibration Record dated ^ 1 ' ^ 1 ' 5 mimmMmm WELL PURGING PURGE METHOD Casing Diameter (D in inches): Total Depth of Casing (TD in feet BTOC): ^ / . " T f l Water Level Depth (WL in feet BTOC): 2 S ' . ' 7 t » Number of WeU .Volumes to be Purged: 3 Screened IntervaliibS*ht0'SOCHrom XU^ to 3 1 . ^ PURGE VOLUME CALCULATIONS f 3 / . 7 ? - ^j.74, )x ^• ^x ^ J^ailer-Tyi>e: 3 f. V . ^ OC): ^ / . " T B D Submersible D Centrifugal D Bladder; Pu D Submersible D Centrifugal D Bladder; Pump No.: _ D Other - Type: PUMP INTAKE SETTif^G D Near Bottom D Near Top «^. » . • • . - : ! > ; D Other: Depth in feet (BTOC) J * / / / ^ ^ < ^ J \ j / j 3 X 0.0408 = i ^ t / / TD (feel) WL (feet) D (inches) No. Volumes Calculated Purge Volume 1ETER MEASUREMENT (ic:t;Lj Tvju« ^iccij u ^uiuuesj ixu. volumes nt^^vp^^yf:^^.::^.f MLDPA^E ^ / z : ^ MiniMes ' Elapsed (gpm) Cjallbns Purged ^"sr; Turbid. (NTUs) "7W 'fedox Pot.(mV) ^^irr Diss. O •n pH Cond.' (^mhos/cm) Temp y^u Depth to Water Comments as?!*;:'^*; (2S"S 0 i l l ^^'VO 10,3 J ^ 1101 • o ^ />/• 4 ' - l ^ . d) 6.^1 AfLA^ ncl-7 A/><1 : ^ '/.f w vv 1 ^n - 2 "5.2: fit qqa-O iia. J/M J:!:!. iiil ±^ ^la / 0 ^ 3 -2^< 2 H T 0 n.O >/^ ^ ( . h" IW) a^.sy 2^ VcJg.---"\>AU /Vki£ ^^\-\ U> \>JiV^OA' I'^CTd; f t>f^>»»;^i<:rA o ^ O i - Ure«ter iDan NM ^ Not Meisured ERVAT10^4S DURING Turbidity (Quahlatative):___i^ er U •ELL PyRGfNG Purge Water Disp.: D San. ^ewer D Storm Sewer B Drum: Type WeU Condition: Odor: WWJL :l/cw-L _Color: y<l/o./-'b'ttWy\ Other: ' Size 55 gal D Other: . . / • . , * > / * • \WORK\27654\FORMS\GWSAMPLE.FRM 3 0 2 4 8 0 amer Isli WELL SAMPLING GROUNDWATER SAMPUNG FORM Page 2 of WeU Job Namer Island Chemical Company Job No.: 29872 ^ Date: a y i ^ / q y Time: Recorded by: ^ffmMklf.. (jfyflcWlr Task No: 07.1 FIELD AMALYSES PRIOR TO SAMSUNG »»T»55- TTT?' Depth to Water (feet) -hr Turbidity (NTUs) Redox Pot. (mV) DissOj (mg/L) pH Cond. (fjxnhps/cm) Temp "C - i - i . H.OITUII9II ^ i - i - ^ Zi> rit.. £. . ..>* i t iiji =;**i= jidls » « B : < J I — OteittPllun n Bailer - Type: P Same as Above D Grab - Type: Q Submersible D Centrifugal D Bladder; SAMPLING DISTRIBUTION Sample Name: _ Label Nos. 2*VP2\01V<5 yir^2\oa.U2 a^^j-awa^an apir^auias ^cto.mi 3M:^2\o:n • Containers No., Size and Type 5 X 40-mL glass VOAs 2 X l-L Amber Glaspv 2 X l-L Amber Glass 2 X l-L Amber Glass 1 X l-L Plastic 1 X l-L PlasUc || IX l-L Amb«» Glass : •' */ » <?.rs Pump No.: Analysis Requested TCL VOCs -1- 15 • TCL SVOCs •(• 15 Pjrridine" Pesticides/PCBs TAL Inorganics (Total) TAL Inorganics (Dissolved) . Cyanide ' ' • • • ' . • " . • ^ ^ . Laboratory: Presen-atives HCl pH = _ L f . . . None None . None HNO3 pH = 1:5 H1VO3 pH = t S " NaOH pH =' l^- • n Other - Type: 'ACE Incorporated Laboratorv Ccnnnients No hbadspace • * % ^ . ^ \ U \ ^ ^ \ H/UOT Field Filtered I M ,K«\ H * ^ , Preservative added after filtering I U U A AT-OH • . • » > • '« * • • , ^ , • : J . ' )UALITY CONTROL SAMPLES Duplicate Samples Blank Samples Other Samples Orig. Sample ID Dup. Sample ID Type Trip Blank Rinse Blank Sample ID l^\iuw|h.<\^«--^S'' Type MS/MSD Sample ID V n < i , l , r . ' A " - A •>• .1 '•''' lA'^'-X.^- i - ' ' ' ^ V ; . * - ( • CA- r r c ik'-tu: ,vu /i^^^ .^^^..'.-.^ y^yx- ^ y 302481 \WORK\27654\FORMS\GVVSAMPLE.FRM Form Printed: February 10, 1995 WeU No.: _ WeU Type: WMonitor GROUNDWATER SAMPLING FORM Page 1 of _ D Extraction • Other . Mii Nam A • li&nd Chemical £bmd»nv " Job Number:29^2^ / ^^ /ask: 07/ Recorded By: (Signarure) WeU Material: . ' ' ".^ifPYC S . tff(-C^ Sampled Bv: Stephen Brueckner, Fames Collins n St. Steel n Other Time: | * r ' A / ^ > - / g t ^ r " (Samptutg Team Members) INSTRUMENT IDENTIFICATION RECORD 1^ Instrument Serial No. PID niMJOoih. pH .32£2l5. Conductivity ^ ^ £ , Temp. s^ 'm= Dissolved 0 ; '^SPockM^ Turbidity Depth to Water ^ < ^fl^l^^^ For Calibration Information, see Instrument CaUbration Record dated ^ 1 1 ^ 1 ^ S" I M / I PiiGEiiOli^Mi Casing Diameter (D in inches): ^ '.•diiC I A Total Depth of Casing (TD in feel BTOC): • 6 a U # j > l ^ ' Number of WeU Volumes to be Purged: ^ WELL PURGING PURGE METHOD^.. J ;•• •ptJaUer - Type: J r • V C cm) ±:c. M- Water Level Depth (WL in feet BTOC)! 1 < D Submersible D Centrifugal D Bladder; Pump No.:. D Other - Type:. Screened Interval^FJ^t (BXOG) from "y?-^ to T*?-' 2.t^..^C....-M.^•55 3:%'% l^.-J iiiipiiiiiiiiiiiiil^ 6rt PUMP INTAKE SETTING n Near Bottom D Near Top D Other:, ~r=7.' r^^:^^^^5^-^arF0-)x ^ ^x TD (feet) WL (feet) D (inches) No. Volumes Depth in feet (BTOC) _ O X.0.0408 = Ji. • f \ y . , ' 2 . ^ > ' ZA Calculated Purge Volume iELiiiMifiiiiiiiiSiRiiiii Gallons m "Tun gg 5 •* • Minutes Elapsed Rate (gpm) Gallons Purged Turbid. (NTUs) Redox Pot.(mV) Diss. O2 (mg/L) pH IML Cond. (/J mhos/cm) Temp Depth to Water -VvUllULlLirtS ^'7^77^ 0 •• iSMa •z2^2a r ' ? 22^22 /32. ^.yr^ CT. ^5.-^ 2 ^ 6 ^ 13X2JX ML ^ L jm_ ! S ^ \/^FP7 fS'Sd as ^ 2 /C:or Ig -^ Q. ^san /35" •;^r2f?g Z3A. n-'? . 2 ^ ^ U £ /fra/r? >^M ^ 7 4 ^ ^ ^ / ^ ^ A VM /i£^2£r M^ /^/yr ^H - ' L ^ 2 5 ^ / 3 ^ ^ ^ • O LUS. issn. gy-3 AM <t^3 H^4^^£ s-3 1.5 7200. 2jn-Q ^ / ^ ^ o r3'3 • f \ ^ ^ Iti^D. :i±T^ \l(>fpr m NM Tireaier Inan ' Not Measured G5§||VilONS::OURING: Turbidity (Qualitatative Purge Water Disp.: D San.Sewi WeU Condition: O OO Odor: A/eA/<^ Geo d- \WORK\27654\FORMS\GWSAMPLE.FRM "n ilorm Sewer & Drum: Type V ^ Size 55 gal _Color Other: : A^H^r- l^prfTwStBfe' D Other: r .'.V 302482 ; M^-H GROUNDWATER SAMPUNG FORM Page 2 of _ WeU No.: Job Name;'Island Chemical Company Job No.: ^9872^ Date: a./<v/^r Time: Recorded 1 Task No: P~.i I < -'. WELiiiiMPIIING bv: ^f^tuux nrvfcUorj CTii^^^ilTitt^Jfc FIELD ANALYSES PRIOR TO SAMPUNG ftirtie r\ xy Depth to Water (feet) - •r•^•^ Turbidity Redox Pot. (mV) ^?rrr > i ' Diss Oj (mg/L) y,fs>. tV'T^rr- pH Cond. (^r^jg/cm)^ * — ^ '•*;*•> v . v ; Temp °C -Commei^ »>4aj—,.nfsV: I / t •7-rr rrrr Holt: or— Itretrer 1 tin iiil Bailer > type:. X^iOolU. KrV»\ O Submersible- C^Gedkrifugal n13ladder; Pump No.: _ • Same as Above D Grab - Type: D Other - Type: SAMPLING DISTRI Label Nos. l^n-^iOii^lH ^r^2\0l%ZL Jf^U2^01^=i^^i :x\<Pl\ai^ ^imiOHO , aPifl^nCJ«+l • 1 • • • - 1 • ' BUTJON Sample Name: _ Containers No., Size and Type \ X 40-mL glass VOAs 2 X l-L Amber Glass ^ i. 2 X l-L Amber Glass 2 X l-L Amber Glass 1 X l-L PlasUc .l.X.l-LPlastj[: 1 X l-L Ambei,Glass ' • • • ' . •':•'' X - - . • : • t . • * .... -.• • •. V A - J • s VIv^-H ^ ^ 3 1 4 1 5 Analysis Requested TCL VOCs -1- 15 •TCL SVOCs -f 15 Pyridine PesUcides/PCBs TAL Inorganics (Total) TAL Inorganics (Dissolved) •Cyanide , ^.^ '.,. . . ' • - ' • • ; T , . , V . ^ . , . = • > • ' • . * • • - . 1 ' V ; - ' •' ^ ^ ' • ; • ' • • _ . •. ' * •.'':'. !"• .t Laboratory: Preservatives HClpH = I S None None«| None HNO3 pH = 2_ HNO3 pH = _Zr NaCfH pH =.12.\ ' ' ' * • . ' I . s • *^! 'ACE Incorporated Laboratorv .••p^liiaents • NO headspace . '•.:^L ' I 1 pvLL UiAt «^N^ ^ ' ^ FieldFUtered » ^^^'' " " • ' ''^J^*^ Preservative added after filtering 4jlM.i-5,fcl /V»OH • • ' • ? : . : "- ^ ^•... •;^>'*!^' ^ " Ai (* " ..* • ' .••*. '"^ )• y " - ' • • • ' * * • ' rt—)•• N % K-\^. . .r. • v;. ^ . t' . QUALITY CONTROL SAMPLES Duphcate Samples Blank Samples Other Samples Orig. Sample ID Dup. Sample ID Type Trip Blank Rinse Blank Sample ID T^/02IHHg Type MS/MSD Sample ID \WORK\27654\FORMS\GVVSAMPLE.FRM 302483 Form Printed: Febn-arv 10. 1995 GROUNDWATER SAMPLING FORM Page 1 of lob Name: Island Chemical Company Job Number:29872 Task: 07.1_ Recorded By: QdrfHtjfi. WeU No.: M M/—^ WeU Type: J J Monitor D Extraction WeU Material: , ^ P V C D St. Steel Date: -"2./.•>'' -> 'A Time: Sampled By: Stephen Brueckner, lames Collins D Other n Other (SampUng Team Members) IDBiliiiCAiiON RECORII Instrument PID '•^AA Conductivity Temp. Dissolved O2 Turbidity ORP Depth to Water c^.*-< Serial No. uA^JTAi A : s ' A ^ ^ ^ ^ iX • ^ / arK For Calibration Information, see Instrument CaUbration Record dated »C| Iiiiiiiiiii Casing Diameter (D in inches): / Total Depth of Casing (TD in feet BTOC): S 0 » ? / Water Level Depth (WL in feet BTOC): 2 . ^ , ( . T Number of WeU Volumes to be Purged: Zf Screened Interval in Feet (BTOC) from 2.^4^1 to l ^ . ^ t PURGE VOLUME CALCULATIONS WELL PURGING PURGE METHOD i" ^y.^' c ^IjBailer - Type: , n Submersible • Centrifugal D Bladder; Pump No.: n Other - Type:. PUMP INTAKE SETTING n Near Bottom D Near Top n Other: Depth in feet (BTOC). • ^ • ^ T ^ S J ^ M k L -bo.ll - X4,$'ix ^ TD (feet) WL (feet) D (inches) No. Volumes X 0.0408 //»08 GaUons Calculated Purge Volume f^€f\^\}UA ^ ^ ^ T^f oF C^lH^ pigLD PARAMETER MEASUREMENT Time ft K ,2:y) 121 s- Minutes Elapsed 0 15" ao Rate (gpm) GaUons Purged 0 -'"S.T 6 Turbid. (NTUs) U)^ -^li \M « Redox Pot.(mV) /'5-' -,' • ? 2 . h . 1 - nu^ Diss. O2 (mg/L) 3 7 0 ^-i-.O tltf^ pH lOT 1.')L A/M Cond. (^mhos/cm) •m^o Zl>Go NH\ Temp '11.-^ ^S' 2. * f l ^ Depth to Water C^JU.'^j !"^i>^' ftn.L*'^ -q" & < L r ^ ^ A/AA .S'M = Not Measured OBSERVATIONS DURING WELL PURGING Well Condition: Turbidity (QuaUtalaUve): Uw ^ - ^ <<4-'.W^CAA***Q Odor: _ *«»0. Purge Water Disp.: D San. Sewer D Storm Sewer A Drum: Type ^ ^ Color: Other; IILA i^«LA- Size 55 gal D Other: \WORK\27654\FORMS\GWSAMPLE.FRM v^Wl ^19^ ^^rttkcsW \ Form Printed: 1 3 0 2 4 8 4 Form Printed: February 10, 1995 GROUNDWATER SAMPLING FORN Page 2 of _ WeU No. JobN Date A ^ - S Name: Isiand Chemical Company :: 9J\^fn^ Time: iY, Job No.; 2.9872 ^ Task Recorded by: S»i*ph£>i ^ A r f c j u ^ Tqsk No: 07.1 IRffiiiiSAMJiiiiiG FiaJ3 >WALYSES PRIOR TO Si^PUNG Time ms ^ole; U i = t Depth to Water (feet) .reater I h a n Turbidity (NTUs) / < ^ . l Redox Pot. (mV) la.i Diss O2 4ii% pH U l Cond. (/jmhos/cm) aifo T e m p ^ ^?.Vh Comments i.l>:^7 1 1-0^1 1 Bladder; Pump No.: D Same as Above n Grab - Type: U submersible u Ceiyrirugai • Bladder; . rump Nc l l i p i l l l i l j l l l i l i l l Sample Name: A \ V - ^ / o a i S « t 5 n Other - Type:. Laboratory: PACE Incorporated Laboratory Label Nos. Containers No., Size and Type Analysis Requested Preservatives Comments vol V/VKS . \ _ X 40-mL glass VOAs TCL VOCs -I- 15 HCl pH = J _ No headspace t^f<<»*** liC^L yvia\6*^\ ^ta ( \ X l-L Amber Glass TCL SVOCs -I- 15 None -I - I i.*Hrto>o^ ^^ l ^ l-L Amber Glass Pjfridine None ^t(X) 3^fn\o^2. ^^ HI l-L Amber Glass Pesticides/PCBs None m ji^^aios3 1 X l-L PlasUc TAL Inorganics (Total) HNO3 pH = ^ % M»^ ^^lOOj FieldFUtered " T P C T ™^ Preservative added after filtering ,^":?210154 1 X l-L Plastic TAL Inorganics (Dissolved) HNO3 pH = l;5 [(too i J^i72 IOS«> 1 X l-L Amber Glass Cyanide NaOH pH = {5 \v(*l A/.OH •"SOd K ) < ? ^ - ^^^(J*«lt>v»H\ CM\.V m o\\ U \<i70 ('>-^^Xg»^i<k c^^l.v^ hi^milfU'^iJ a L f . :fc»** S «i< *^a QUALITY CONTROL SAMPLES Duplicate Samples Blank Samples Other Samples Orig. Sample ID Dup. Sample ID Type Trip Blank Rinse Blank Sample ID Type MS/MSD Sample ID 3 0 2 4 8 5 \VVORK\27654\FORMS\GWSAMPLE.FRM Form Printed: February 10, 1995 K Is. Well No.: /^M/-/ Page 1 of_X Job .Name: Island Chemical Company 'ob Number:2987Z^ Task; 09.1 -orded By: XJXl.mcl V Well Tj^pe: ^K^onilor Well Material: , >fl PVC Date: Or/OW ^i" Sampled Bv: Strohen Brueckner. D Extraction n St. Steel Time: 10 ^ ^ lames Collins a Other D Other (Sampling Team Members) 1-RUMENl^ IDENTIFICATION RECORD Of^ , /CfaV Instrument Conductivity AcXlhikAiA. Temp. Dissolved O2 Turbidity ORP Depth to Water Serial No. | 2 ^ ^ M L - Z ^ ^ l CLSl-M i:z^?M 24H\ (1>31- l i ^ ' ^ - H u For Calibration Information, see Instrument Calibration Record dated ^ IS" PURGEJVOLUlviE Casing Diameter (D in inches); WELL PURGING PURGE METHOD Total Depth of Casing (TD in feet BTOC): SS^. y Water Level Depth (WL in feet BTOC): S'?^- 0 ^ Number of WeU Volumes to be Purged: 3 Screened Interval in Feet (BTOC) from 3 * 1 , ^ to3KI»° Jl^ailer - Type: O °VC D Submersible D Centrifugal D Bladder; Pump .\o.: l[/f^ D Other - Type: \ A / f i PiMlit|iliKE: S | i i | i D .Near Bottom D Near Top n Other: M. iiiGiiiiiiiiiiiiiiiiiii Depth in feet (BTOC) 3 m. X 0.0408 = TD (feet) WL (feet) D (inches) .\o. Volumes i^ GaUons Calculated Purge Volume FIELD PARAMETER MEASUREMENT k • fOMt 10^^ \\C^\ i t i O i | a i m - Minutes Elapsed 0 L [H 21 2.T ^^\',l'}>^ Rate (gpm) WA ^/4 UPt h\A A/A AfA Gallons Purged 0 U.S" q 14-u ^1 Turbid. (NTUs) ^ 3 *{-U 4-^5 s-a /VAA T 3 ^ Redox Pot.(mV) - ^ 2 . ? -?S.<1 -T"?."^ - W . f M/^ 1 1 . ^ Diss. O2 (mg/L) 3.13 O.^T 1. 2 2 O.t?- A/M 2 , ^ t pH r « i r.sT ^.so d.-i^ A/M uy Cond. J|£^ 2.as Zi.'S.J 2,aH- 2 . 2 6 m :Z.2( Temp °C 2^.*i ;i^.s 2 i s 9 2 t S NM Z1..-A Depth to Water MM AIAK AIM A/M 1U4'\ A)M 1 1 S.«Wt-f i.To\ 0.10 0.10. O.JO O.IO C ^ i ^ ' - . ^ i ' ^ ^/A^ - ^ v « 4 c <liJwy , ( 7 , 1 1 -=» • '^Ijt.VHylX. VV.JM i o i * * ! 6*'-^Wi': rii^vV- A«!vi«i 1 1 1 1 L, i -• urcalcr i nar. .NM = So! .Measured czRVATlONS DURING O--^^ I I 0''*'"i I ^!NG WELL PURGING Well Condition; ' ^ ' ^ ^ - ^ ' " ' ' ^ "^"^ '^°'°'' ^ ^ ' ' T « . > . l W ( W fVOA/l WA.J Odor; UMJ^U. rnrfcU-l^ 'T(/JI.>\ .)w.-.dj:^Vf "Othcr; Turbidity (Qiialitalalivc): T«i^N.lW ( ..- . .-• . , . . , ...., . Purge Water Disp.; D San. Suwcrl D Storm Sewer ^ i * Drum: Type X " Size 55 cal '• D Other \VVORlCi29872\01\GWSAMPI.E.FRM 4P^ ^H-X_yx I'orm Printed; May 1, 1995 302486 Page 2 oi 2. WeU No.: AIM/--/ lob Name: Island Chemical Company job No.; 29872 Task No; 09.1 Date: OS\0<t jQ<Time: t&UV R^orded by: ^U^tSUy. O u i i i S y y , ^ ^ ^ C A ^ I A ^ « WELl^ SAMPLING PMjiAMii^ Time 1/3^ \ole: CT . I Depth to Water (feel) 2«1.^6 .reater loan Turbidity (NTUs) (4T Redox Pol. (mV) - 2 ^ . ^ Diss O2 (mgO.) 2.\1 pH ix^'x Cond.'^f'-'" 1 i , , i , 1 1 l.Z'\ Temp °C 2.%A Comments UO^ It^l slwl-j ^ , S . ^ i;u.^(?j (7.M S A M M M H ^ ^ ^ ^ ^ ^ U ^ )eiU v . V J^BaUer - Type n Submersible D Centrifugal O Bladder: » rump S A M | i l l 3 | | ! S T R ! B i T l © N Sample Name; M W - f / d S / O ' f ^ n Same as Above O Grab - Type: Pi;mp •No.:_. A / A D Other - Type: J& Laboratory: PACE Incorporated Laboratory' Label Nos. Containers Jo.. Size and Type Analysis Requested Preservatives Comments I I M F ' . i »"50 2 ^ 7 2 3 0 0 2 * -rru^ EIJ 40-niL glass VOAs TCL VOCs + 15 HCl pH = 1-5" No headspace t drops HCl 2!tTri-y>o^fn 2 X l-L Amber Glass TCL SVOCs -I- 15 None awzsdog Of 2 X l-L Amber Glass Pyridine None ~ixri8r5SWjTr f'iJj'J'A^. 2 X l-L Amber Glass Pesticides/PCBs None » * K . i " 7 g 3 0 / J 1 X l-L Plastic ' ^ ^ ^ ^ - 1 ^ * / e ^ TAL IwnfQnnics (T( ""'eTfiJUS 3 L C .eft/if TAL ItiuijidiULj (Dissolved)^ HNO3 pH = J _ wai HAiO, 1 X l-L PlasUc HNO3 pH = J_ Field Filtered ( v.~u^ HA/O-t, Preservative added after filterinE l-rtn-lQlf 1 X l-L Amber Glass Cyanide NaOH pH = i l I v/c*l t4^0H \ldCs cJ- " ^ Jr SsiOG^ /Y^-VM a.AAst/Ac5 ktiw^ fA.w cjot^ ^1- W.bQ (JUL: ^ V ^ U Lri.v (^/WK^-. I J S^'-^lii ^ 7^w%^^/v^.^ •^VQC< ^tJWv C w . J g . ^ \ , U / V L J s ^ a J Q^lfiuUi yVU.Js Ci ^ r pp<i'^ IJJIOi. h*J- BcAM^ il\sli^S\) S i r S^'-yU <^>^ i fOTV-vJA ,/>Ax QUALITY^ CONTROL: SAMPLES Duplicate Samples Blank Samples Other Samples Orig. Sample ID Mw-tfoslo^l^ TiMt •• 1330 Dup. Sample ID MW-''/0//as/Of/fS' Type Rinse Blank Sample ID Trip Blank , ^ ^ , , ^ ; ^ ^ J J l i n \i'G( B 1-^ type MS/MSD TTME: ttOO Sample ID ' -..•l.^-.-.A^'^/yA --1V- :. Cft\\j A:-:. ^..-.. ' - • : . - : > •;/>-<!:• X . • : ' ' i * \ I \\VOR!O>29872',01\CWSAMPLE.FRM f H L-MU:i JA Form Printed: May 1, 1995 3 0 2 4 8 7 I B S Well No.: _ Well T>'pe: /IH^ Page 1 ot_f^ j ^ ' onitor )ob Name: Island Chemical Company '-.b Number:29872. . Task: 09.1 corded Bv: •XjArhyd -^ ,.- /V<.^-y^ WeU Material: K P V C Date: O A f l ' I ' y f Sampled Bv: Stephen Brueckner. lames Collins n Ejctraction n St. Steel Time: ( H ^ ^ a Other, n Other ISampUng Team Memben) INSTRUMENT IDENTIFICATION RECORD ().^s '^fcy Instrument Serial No. PID • '^yi\ pH I257M Conductivity •r<Cnil.A L-lv 12^7^ Temp. iJ-Ajb-'.'-'<- i2q?w Dissolved Oj 125?H Turbidity : - < : - ' : / L ' . i i , v t las^^ ORP t"iC IC. ,U ^LM Depth to Water P721- 5 Ai_- ^ /> (3^5^ For Calibration Information, see Instrument Cahbration Record dated -^ I ' I ' j A> i Casing Diameter (D in inches): Total Depth of Casing (TD in feet BTOC): 2 ) \ , L - ? ' : Water Level Depth (WL in feet BTOC): ^ l . ^ t , Number of WeU Volumes to be Purged: f^ Screened Interval in Feet (BTOC) from ^i.S" to o j / . j ' PURGE VOLUME CALGULAT30NS WELL PURGING PURGE METHOD - i - P i A . , r t , J 'roc — IX c- _ _ y ?yc •p^ailer - T>-pe: n Submersible D Centrifugal D Bladder; Pump No. a Other - Tj-pe: A^'A A ' / ^ H PUMP INTAKE SETTING D .Near Bottom D .Near Top Depth in feet (BTOC) • Other: . /i//? .A'T^ X 0.0408 = TD (feet) WL (feet) D (inches) .No. Volumes 15^ GaUons Calculated Purge Volume FIELD PAfWMETER MEASUREMENT ll 1 on^t Aim ^ \ < % O^-^T ICOO i(;02 Minutes Elapsed Ci L l a 1 ^ 9M O.L l-J 1 = ortiatcr i Rate (gprn) yh t^A- Mfir M/V NA l\}A- GaUons Purged d s 10 IS: art 20 Turbid. (NTUs) Gr«^'\M GT'\^'^ 820 '=l«0 l.'yd MN\ Redox Pot.(mV) -•W.s -tT.M- -T3. t - l i . Z -«1^.M- >;M Diss. O2 (mg/L) 0 , 5 2 O.^T 1.01 I.OO L I S AIM PH (v?5" fi,$l ^ ? , ^ ^ . ^ ^ r'^l /VM (p«tfe©s/cm) X 3 0 1.31 1.2.0 1.2H 3 . 21+ A/AA Temp °C a*^.'^ 2*^.M- S-^.i^ J.<^.4- a<i. (4 A;AA Depth to Water Nf^ MAA M^A MAA A/M i3.m« Cnmmcnts'^" n.u rt. (4 n.(s 0. u n. ifc ««^ r\"{,^-v - ^ -^ - Cf 'v**f . r ^ j i 1 1 .\.\I = Not .Sieasurcd Turbidity (Qualitatative): ^ JGWELLiPl LuERVAT!ONS:DURlNGWELt^:f?URGlNG ):i^H __ Purge Water Disp.; D San. SAvej- D Storm Sewer 0^ Drum; Type Well Condition: _ Odor: y^c*^ -^ p a d _Color; Other; ^ ^ Size 55 gal D Other; \WORK\29872\0l\GWSAMPLE.FRM I'orrii Printed; May 1, 1995 302488 Well No.: Afiyi/'-3 Page 2 oi _ ^ Job Name: Island Chemical Company Job No.: 29872 Task .No: 09.1 Date: ^ S X 1'1'f Time. C ^ l j i J Recorded by; iy^>-nc>-t C.-(XO^ 'S'-yy^.^T^ / ^ X « WELi^ SAMPLING fc.^:;:ANAiYSES:§:RRlGR:iB;SAMP Time 1014- Depth to Water (feel) a^.si Turbidity (NTUs) UO Redox Pot. (mV) - % ^ . % Diss O2 (mg/L) \ . % ' ^ pH i.%^ CouA. '"'y/c. l.:2a Temp °C a-^. s-. Comments 5Ai_, ^.-r/yrX) o.u Noie: ij"i - Greiter Than Sp^P|i«G;;jfEiHCS? Jailer -Type: 'C'-^fO'? f^h^f' f p f U ' ^ n^ubmersible D Centrifugal D Bladder; fump ;\ S A M i i i p i l i f i i B i i p l Sample Name: f < ^ ^ - X > / O i ? / / y i S .No.: n Same as Above D Grab - Type: Aly/i — D Other - Type: AU^ Laboratory: PACE Incorporated Laboratorv Label .Nos. Hii? hnm'^'i'fi.to Wm?X'M:^7. mrA:jO:hxh^ [iTirm^'y \'rm73ci(. P y-'X^ooxj Containers .No., Size and Type ^ 4'0-mL glass VOAs 2 X l-L Amber Glass 2 X l-L Amber Glass 2 X l-L Amber Glass 1 X l-L Plastic 1 X l-L Plastic 1 X l-L Amber Glass tl'W^ \ ^«<^J\K 1 -> Analysis Requested TCL VOCs -H 15 TCL SVOCs + 15 Pyridine PesUcides/PCBs ••>n e 1-AJ-s 3-Lr TAL loorganioc fTotal) /-^r TTv O^'-i -Tc-^ Cyanide i d ^ - Preservatives HCl pH = III? None None None HNO3 pH = ( ^ HNO3 pH = I i 5 NaOH pH = \ ^ Comments No headspace 6 drops HCl \vcui MA/0^ Field Filtered I ^ "M^Ol^ Preservative added after fUtering I v>v^ AjcOt^ QUALIPt^iOONTROLSAMPLES Duplicate Samples Orig. Sample ID NA- AA- Dup. Sample ID uh M/V Blank Samples Type Trip Blank Rinse Blank Sample ID — / I I ' A , ' — ^ IPF Other Samples Type MS/MSD A/A Sample ID A/A (\/'4 \VVORK\29872\01\G\VSAMPLE.FRM Form Printed: May 1, 1995 3 02489 Well No.: _ Well T\T3e: X^!MC MiV'f Page 1 of_2^ Job Name: Island Chemical Company 'ob Number:29a72 Task^ 09.1 .ecorded Bv: C^UiN,' j CbAJA^ Well Material: J^PVC Dale: O S / / d M r D Extraction n St. Steel Time: ^ ^ ^ 0 n Other n Other Sampled Bv: Stephen Brueckner, lames Collins (Sampling Tecjn Members) Instrument Serial No. PID 0"i.A1 •'>yc'/3 :^Zi\ INSTRUMENT IDENTIFICATION RECORD pH . /Ao^iC^i^fO ( 2 S ^ 4 Conductivity t25^M Temp. i25-?H Dissolved 0^ i2b7-M Turbidity tAoniPAU'O 125^^ ORP 2^41 iy-5 /OCAS Depth to Water \m-Tr .i:,Ai„.i.:7y A'c-^'A>^ 13S^H For Calibration Information, see Instrument CaUbration Record dated ^A^/^^ PURGE^^iOLUME Casing Diameter (D in inches): Total Depth of Casing (TD in feet BTOC): __ J£ WELLPURGING g||i|;j|E|H(3i^^'^^'^'''' D Bailer - T\-pe: Si ' ^ Pu'c Water Level Depth (WL in feet BTOC): ^ , 1 0 Number of WeU Volumes to be Purged: .^ D Submersible Q Centrifugal D Bladder; Pump No.: /•//* n Other - Tj-pe: A'A Screened Inlerval in Feet (BTOC) from -"S•'A to iS ^ PiRGE^i:iliiiiiiAioiiiiiiis Tk.U - 23.70 )x ^ lUMilN JAKE .Silili! n Near Bottom D .Near Top Depth in feet (BTOC) _ ^ X 0.0408 = • Other; . ^."1 TD (feet) WL (feet) D (inches) .No. Volumes Gallons Calculated Purge Volume FIELD PAR.AMETER MEASUREMENT 1 — \ "^ fiio IZlt i 2 M l K'A'^ Minutes Elapsed 0 L la oX> Rate (gpm) A/A A/A ^h v^ GaUons Purged 0 ^ t 10 Turbid. (NTUs) GT*^'\*\ Q>T'\'^^ 6 r <i«\<\ Grq'A*^ Redox Pot.(mV) IA ^ . ^ m i^-i^ ^ ' L , Diss. OJ (mg'I) fl.^T Qac 0. 'i\ L JO .V (Of.^)^ pH ^ . O f ?.ot =!.()? =^.lo A ^ \ Ccfad.j^ 2.(1 2 , 2 0 D . [<\ 2.17- l.Wv '\li<^lJ<i A Temp °C 2%.^ 2«i.2 a-«.-5 2S.2 L ^ 1 ^ Depth to Water AiM V A ^ WM is.O'i f i ' r ro-x- Comments waU- li»*\ OMV. e->.t. • OAQ 0.10 Q . l U O.tO 1 1 1 1 NM = Sot .Measured ^ ^ . o E R V A T t O N S DURING WELL P U R G I N G Wdl Condition: ' ^ f c A _ J^»-|i ^K y.«^< a>\>Color; il ^ ^ r b i d i l v fOiialilatativcl; A . J l - /».J1A^ Odor; Agyx^ -> Other: r o w A Purge Water Disp.: • San. Sewer D SlormlSnucr •gJ Drum; Type V^ Size 55 gni D Othc \VVORK\,29872\01\GWS.-\.MPLE.FR.M Form Printed: May 1. 1995 302490 Page 2 of 2, >^M/-V Well No.: Job .Name: Island Chemical Company Job .No.: 29872 Task .\o; 09.1 Date: O^JOff^-Xime t2'2.0 Recorded by: 'A'J'fi^..' '/^U..UI^X'C~J~ X } ^ ^ ' y ^ ^ - : stand i.n WELliSAMPIIING Fi£LD;ANAi>^ES iPRlOR TG>SAMPLING Time \1\'k Depth lo Water (feet) axi^\,<\ Turbidity (NTUs) GTH9S Redox Pot. (mV) 1(15.5 Diss O2 (mgrt.) /.02 pH ^.10 2!L^*, 2.. 2d Temp °C :i%.\ Comments • (3.10 1 =r= ^ y ^ ^ r , R j > A i f SA'./^jt ^IJBailer - Type: ; G Submersible D Centrifugal D Bladder; S A M i i l p : p j p = ^ i B U i i © i Sample Name: oic Mj^Y/af^/ W n Same as Above M .^ .^ rab - Type: A ^ A a Other - Type: / i ^ > ? Laboratory: PACE Incorporated Laboratory- Label Nos. Containers No., Size and Type Analysis Requested Preservatives Comments £ X 40-mL glass VOAs TCL VOCs + 15 HCl pH = 2 No headspace i drops HCl 9^?7:i-U>3A,A> 2 X l-L Amber Glass TCL SVOCs -I- 15 .None ?^>'iyZAMAY 5 3 " 2 X l-L Amber Glass Pyridine None ':'}'i'7}.3C-:fL.3A 2 X l-L Amber Glass Pesticides/PCBs None I W ^ ^ r y 7A^l.A>^ 1 X l-L Plastic •^^'^•'-ro4it ^ ' ' ' ' TAL Innffnnics ~^Z^^^^yS^> HNO3 pH = 2 ^ v/i-ai '.9<l7^-'^t.H 1 X l-L Plastic H.NO3 pH = ^ 5 Field Filtered ( VV^^ ^ M ( j . Preservative added after fUterine ,A}7l--^cHC 1 X l-L Amber Glass Cyanide NaOH pH = [ 2 . 9 ' ^'"^ f/^CH r*, try il> tVJut Sv. v ^ : ^ ^ \ \ ^ QUALITY CONTROL: SAMPLES Duplicate Samples Orig. Sample ID (\1/L N/V Dup. Sample ID ii/i A//V Blank Samples Type Trip Blank Rinse Blank Sample ID Other Sami^lei Type MS/MSD <^t.^ Sample ID w NW 302491 \VVOR10.29872\01-,CAVSA.MFLE.FRM Form Printed: May l."l99n Page 1 o f ^ WeU No.: _ Well Type: j B M o n i t o r Job .Name: Island Chemical Company '--b Number:29872^ Taak: 09.1 -orded By: Cl^^m-tw . ^ . r p £ L ~ >—^ Well Material: V Date: OnjlO\Q5^ PVC Sampled Bv: Stephen Brueckner. lames Collins D Extraction D Sl. Time: Steel n n Other Other jS. ^nature) iSampUng Team Members) INSTRUMENTIIDENTIFICATIONIRECQRD i^cs ICAeS Instrument Serial No. PID >3^( pH /l^7M Conductivity Mcl'ifi/i O'lC lisT-M Temp. liS7M Dissolved Oj |2S^M Turbidity »357M ORP 2 i ^ | Depth to Water r2T2T- 5AiL^<^;Ty /:!9^M For Calibration Information, see Instrument CaUbration Record dated 5 / ' • ^ I \ ^ w PURGE VOLUME WELL PURGING PURGE METHOD Casing Diameter (D in inches): Total Depth of Casing (TD.in feet BTOC) Water Level Depth (WL in feel BTOC): J ^ Number of WeU Volumes to be Purged: Screened Interval in Feet (BTOC) from I 52-' C. J i c D BaUer - T\'pe: D Submersible D Centrifugal D Bladder; Pum D Other - Type: 0 /to? ^ I^g PURGE VOLUME CALCULATIONS PUMP INTAKE SETTING n .Near Bottom D .Near Top D Other: _ Depth in feet (BTOC) / ^ / 4 ATi^ ^O. h i TD (feet) lO."^' WL (feel) D (inches) -No. Volumes X 0.0408 = /^W GaUons Calculated Purge Volume FIELD PARAMETER MEASUREMENT i . • m<^ \t^-<% ai^H \\<i^(, i(532. u-o- 10^42 Minutes Elapsed 0 T l\ H3 4"^ <.'k ^ Rate (gpm) m M A//V Al/A- AjA Ai(V fV/i Gallons Purged (S I A *T la u ?c Turbid. (NTUs) % 515- 5^0 fe70 sst) H^5- fOS T^edox Pot.{mV) /*i.4 u^.s IK). 5- ISILM- K-^.5- iS^^.S H3.-+ Diss. OJ (mg/L) i.to LCI 2.24- a.'^o 2.4^9 2.3C 2.2<2 pH ^ . ^ ' < /^."il rj.n (.^H fi.f?- i^n i.%\ •^Cond. J u . (llilillMWl'l III) 0..1>\ 2.2q 2 . 2 4 =2.24- 2 . 2 \ 2.21 2 . y<\ Temp °C 2?.7- i?.7- 3lrT Zi.C :>?,o 3^,0 .i?.li Depth to Water A|A\ .M/uv A/M AJAA WA^ A)A\ 22. «S" V*t/>.T/^7^ n.u o.n n.iO O.lO n, 10 O.ID ."'.'•.•'.V-rs j 0.10 ,!--4^-W\ • Lirealcr i nan .\\[ = N'of -Measured F. ^.£RVATI(E>NS:DUR1NC1 WELL PURGING Turbidity (Q\iaiitatative); .•v\iV,iiHy .-liW^. -iL iv^ j^^DM Purge Water Disp.: D San. Sewer D Storm Sewer J r I Well Condition; Odor; Drum; T' lor; »VAV<^ rvpe P^ ^ .CM^ _Color: Other: .I^CLT ^ W^ Size 53 cal a Other: 302492 \\VORlO,29872\01\G\VSAMPLE.FRM Form Printed: May 1, 1995 y^w.^6' Page 2 ot ^ Well No.: Job Name* Isbnd Chemical Comp.-inv Job No.: 29872 Date: t S l l h r t S Time: Z \ 1 £ Recorded b .'ame* Island C T.isk No; 09.1 f. y: cu^ra^g?.^ S ^ . f^u^U^^ WELI^SAMPiliNG ELDsAtpLSSESlRRIORiiOiSAMPillNCS Time 1107 \ote: (j i - L Depth to Water (feel) as^^ll- ireater ihan Turbidity (NTUs) z% Redox Pot. (mV) m . % DissOj (mgO.) 1 A 2 pH ixn Cond.-yOfCv, 2.\\ Temp °C 2 S , ^ Comments yx^i^ {%) 0.[Q> SAMELlNG;:«l?rH0D . , D Same as Above Jig^aiier - fype;" V A f ^ S A l ^ iJffCfiO D Grab - Type: • Submersible D Centrifugal D Bladder; Pump .No.: A / A O Other - Type: S A M I ^ I t i G i i l S i i i B r o O l s i SampleName; f^''S/0S//ey9^ Uboratory: PACE Incorporated Laboratorv 'TSX Label .Nos. Containers No., Size and Type ^ X 40-mL glass VOAs Analysis Requested TCL VOCs -I- 15 Preservatives HCl pH = ^ Comments No headspace ^ drops HCl tn7t90f^,<fh 2 X l-L Amber Glass TCL SVOCs -f 15 None ^ ^ 2 3 0 ^ ^ 2 X l-L Amber Glass P3Tidine None 29mym,fo 2 X l-L Amber Glass PesUcides/PCBs baoa^sucs (Total) None I /,-^l MA/Ot. Z9rrz3osi 1 X l-L Plastic TAL ««caaBM6n3 is s ol v ed H.N'Oj pH = (_S' imz^osz 1 X l-L PlasUc TAL I««cgaBta6 HNO3 pH = [^5" Field Filtered \ y J ^ HI^Oj^ Preservative added after filtering tfSTZ^fJ 1 X l-L Amber Glass Cyanide NaOH pH = •£.-' /v/>J l\}o.0\'\ VcMJL <c.^\^^ I 4 ^ QUALITY^OONTROL SAMPLES Duplicate Samples Orig. Sample ID A/'A ^'/v Dup. Sample ID AjA A/A- Blank Samples Other Samples Type Trip Blank Rinse Blank Sample ID SU? - ^ M ^ MA_ Awri"^^ Type MS/MSD h)h Sample ID A/A- /^A- \WORK',29872\01\GVVSAMPLE.FR.M Form Printed; May.l. 1995 302493 APPENDIX B Field QA Audit Reports 302494 ly OFFICE MEMORANDUM To: Mr. Santo Guillermain, Lori G. Singer, Esq. From: Jason Schindler Date: June 7,1995 Subject: Island Chemical Company QA Audit Project Number: 29872 17.1 Attached is a copy of the report of results of the second Quahty Assurance (QA) field audit performed during sampling activities at the Island Chemical Company site. No deficiencies were identified during this audit, indicating that the deficiencies identified during the initial February 1995 QA Audit have been corrected. HLA performed the second field QA audit at no charge. Harding Lawson Associates Engineering and Environmental Services 131 North Third Street Philadelphia, PA 19106 - (215) 627-4505 302495 Harding Lawson Associates June 7, 1995 29872 17.1 Ms. Sherrel D. Taylor-Domville United States Environmental Protection Agency Region U Emergency and Remedial Response Division 290 Broadv^ray New York, New York 10007-1866 Results of Second Quality Assurance Field Audit Island Chemical Company Site Reniedial Investigation St. Croix, U.S. Virgin Islands Dear Ms. Taylor-Domville: This report has been prepared to document results of the second Quality Assurance [QA) field audit performed during the Remedial Investigation at the Island Chemical Company site in St. Croix, U.S. Virgin Islands, on May 10, 1995. This report has been prepared in accordance with the requirements specified in Section VII Part Ai(3)(g) of the Administrative Order on Consent (Consent Order) for this project dated September 29, 1994 (EPA Index No. II-CERCLA-94-0401) and described in Harding Lawson Associates' (HLA) conditionally approved Quality Assurance Project Plan (QAPP) revised August 3, 1994, Section C8.1. On Wednesday, May 10, 1995, Mr. Bharat Patel of HLA performed a QA field audit as a followup to the initial audit performed on February 14 and 15 (HIA, March 1, 1995). The purpose of the audit was to evaluate whether the deficiencies noted during the initial audit have been corrected. The audit was performed at the time of field activities during the second groundwater sampling program. The sampling activities and associated documents, including: sample identification; sample control; chain- of-custody procedures; field documentation; and sampling operations, handling, and packaging procedures, were observed. The audit was not announced to the field team before its occurrence. 1.0 FINDINGS OF AUDIT 1.1 Sample Labels The auditor examined sample labels for completeness and accuracy. The following sample labels were reviewed: All bottles for sample MW-1/050995 All bottles for sample MW-101/050995 All bottles for sample MS/MSD/GW/MW-1/050995 All bottles for sample TB/050995 All bottles for sample NrW-5/051095 Engineering and 131 North Third Street. Philadelphia, PA 19106-1903 215/627-4505 Fax 215/627-4250 Environmental Services A S..bsidiar, of H a r d i i j Associates . Offices Sani>n..idt 3 02496 Harding Lawson Associates June 7, 1995 29872 17.1 Ms. Sherrel D. Taylor-Domville U.S. Enviromnental Protection Agency The sample labels were foimd to be in comphance with the requirements specified in Section 6.1.2.1 of the QAPP. 1.2 Chain>of-Custody Records The auditor examined three chain-of-custody (COC) records for the samples (i.e., MW-1/050995, MW- 101/050995 and MS/MSD/GW/MW-1/050995) collected on May 9 and one COC record for a sample collected on May 10 (sample MW-5/051095). The records were reviewed to determine whether (1) the station number, station description, date, and time corresponded to the sample label, (2) the parameters to be analyzed were properly identified, and (3) custody transfers had been documented and the date and time of transfer had been recorded. The auditor also reviewed whether the samples were kept in custody at all times and were properly and securely stored. Findings were as follows: HLA's COC record, included in the QAPP, were used. COC records were prepared concurrent with the sampling on May 10. Sample date and times corresponded to sample labels. Parameters to be analyzed were identified correctly. Samples were kept in custody at all times and securely stored. Upon completion of the field sampling program, the COC records were again reviewed for completeness. The following deficiency was noted: • Custody seal numbers were not noted on three of the COC records for samples shipped on May 10, 1995. 1.3 Field Logbooks and Other Forms The field logbooks, Groundwater Sampling Forms, and Water Level Measurement Forms were reviewed during the field audit to confirm that each was signed and that all entries were dated. No deficiencies were noted. 1.4 Sampling Operations The auditor reviewed sampling operations to determine if they were performed as stated in the Field Sampling Plan (FSP) and as directed by the Project Manager. The auditor determined that the proper number of samples were collected at the assigned locations and that the samples were in proper containers and properly preserved. The auditor also confirmed that the required field measurements and QA checks were performed and documented. 302497 Harding Lawson Associates June 7, 1995 29872 17.1 Ms. Sherrel D. Taylor-Domville . . U.S. Emironmental Protection Agency 2.0 CORRECTIVE ACTIONS 2.1 Sample Labels No corrective actions were deemed necessary for the sample labels. 2.2 Chain*of-Custody Records No corrective actions were deemed necessary for the COC records, with the exception that custody seal numbers shall be noted diu'ing the future sampling events. 2.3 Field Logbooks and Other Forms No corrective actions were deemed necessary for the sample labels. 2.4 Sampling Operations No corrective actions for sampling operations were deemed necessary based on the results of the field audit. 3.0 CONCLUSIONS Results of this audit indicated no deficiencies that suggest problems with the quality of the samples. If you have any questions regarding this or any other project matter, please do not hesitate to contact either of the undersigned. - * Yours very truly, PIARDING LAWSON ASSOCL\TES 4^r Bharat Patel, CPG Managing Associate Hydrogeologist ^ - " • " f ^ y S n ^ . Sl ( Associate Geologist N^^^: Mr. Cecil A. Williams, GOVI, Department of Planning and Natural Resources Lori G. Singer, Esq., Sills, Cummis, Zuckerman, Radin, Tischman, Epstein & Gross BP/]MS/mls/EAW \VVORDPROC\29872\QA2R£P.RPT 3 0 2 4 9 8 APPENDIX C Data Validation - Potable Water Samples 302499 a OFFICE MEMORANDUM To; Project FUe From: Jason Schindler D a t a ; February 2, 1995 S u b j e c t : Data VaUdation - Island Chemical Co. Potable Water Samples Project Number: 29872 01.5 Following is data vahdation for potable water samples collected at Island Chemical Co. Site in November 1994. Cover memo was lost by secretary during reproduction. \WORK\2g872\01\HLA-016.MEM February 28, 1995 Harding Lawson Associates Engineering and Environmental Services 131 North Third Street Philadelphia, PA 19106 - (215)627-4505 302500 HLA DATA QUALITY ASSURANCE REVIEW SUMMARY Volatile Organic Compounds Analysis Case Number : c^ y / ^ ^ Project Number. 2 f S ^ 7 X / O . / Site: XJ^^U^i ^ k e ^ \ e ^ l ^^ Contractor Laboratory: ^ ^ ^ I a ^o^^-fi^r-v . XP^c. A^^UJ O J ^ f ^ Validator p / f ^ / ^ QC Reviewer H. Fk.'f l')>.r Validation Date: / ^ / ^ / / ^ ^ Review Date: / / J A r" Sample Matrix: Woi4ey Analytical Method: S A n L C V \ / o A / ' ' A ^ Sample Designations: - P T / / / 0 ?r:i/io ?r/ox/ -r/? 110^ l/A/SOO 1 IAAVS.oa 2- U/VS'0(P.3 lA/l/J 0 0 7 Data for the above samples are: Acceptable for use >C Acceptable for use as qualified Unacceptable for use Is action required by the project Manager? Yes le hroiect I (5) Comments: T / i < cLi^^o.. ^^cvc vw/r'^^cx-f-^ pf u j / i ^ t y-Ac A / a - f ' O H « ( ^ U . ^ > c t , * ^ « / G u / e / t / Z i n e ^ -/^ kv O ^ - ' " - ' - ^ - * - ' - y ? ' . . ' - . ' ' \hh^ f^h. n i ^ usEP/f cur voi^l.doc 10141994 1032 Fonn VOA 1.0 302501 DATA COMPLETENESS CHECKLIST Included, no problems Included, problems O Not included NA Not applicable Quality Control Summary "X Case Narrative pX Surrogate Recovery Surmnary X MS/MSD Summary -Tjff Reagent Blank Summary X GC/MS Instrument Performance Summary Sample Data X Chain of Custody Forms yX Holding Times X Organic Analysis Data Sheets X Quantitation Reports X Reconstructed Ion Chromatograms X Mass Spectra Printouts /rA TIC Mass Spectra Library Searches Initial Calibration Data -^ Calibration Summary X^ Standards Quantitation Reports X Standards Reconstructed Ion Chromatograms Continuing Calibration Data 7^ Calibration Summary \ y Standards Quantitation Reports X Standards Reconstructed Ion Chromatograms X Intemal Standards Summary Instrument Performance Data X BFB Mass Spectra X Reconstructed Ion Chromatogram X BFB Mass Listings voa_l.doc Po™ VOA If) I0U1994 1032 2 302502 Reagent Blank Data • ^ Organic Analysis Data Sheets X Quantitation Reports ^ Reconstructed Ion Chromatograms yy Mass Spectra Printouts AYA TIC Mass Spectra Library Searches Matrix Spike and Matrix Spike Duplicate Data X Organic Analysis Data Sheets X Quantitation Reports X Reconstmcted Ion Chromatograms Laboratory Control Sample X Organic Analysis Data Sheets X Quantitation Reports ' X Reconstructed Ion Chromatograms Xy^ Mass Spectra Printouts TIC Mass Spectra Library Searches J ^ Comments: voa_l.(k>c Fonn VOA 1.0 10141994 1032 "? 3 02503 SPECinC COMMENTS REGARDING ANALYSES Chain Of Custody Were samples properiy pre§eryed and received in good condiuon? C Yes^ No Were custody transfers correctly and completely documented? Tes^ No Comments: Holding Times Were sample analyses perfogm^ within holding times? "Yesj No Comments: Instrument Tuning Did the insuument performance checks meet acceptance criteria? Were samples analyzed within the 12-hour period following an acceptable performance check? ( X ^ ^ ^ No Comments: voa 1 .doc Fonn VOA ! .0 10141994 1032 4 302504 Initial Calibration Did the laboratory meet the method requirements regarding the minimum number of calibration standards for an acceptable initial cahbration!' C YesJ No Did the initial calibration curves meet the linearity criteria for maximum percent relative standard deviation (%RSD)? ^ Yes yi<oX) Did the initial calibration meet the minimum relative response factor (RRF) criteria? Yes y ^ ^ Comments: Se*- /»*>« 13 •^•' t^-f^-ctA^J a^ufy/cj- C^K/ ^i>. le^/cfcj. i h h f Continuing Calibration Did the continuing calibration curws^eet the Unearity criteria for maximum percent difference (%D)? Yes t ^ y X Did the continuing calibration meeuli^-tninimum RRF criteria? Yes ( N O _ ^ Comments : Xe=- pa>c / y /""^ o-'H~ecf'cU a. t.yu. Iy-fcs oiinJ. ff^i^/^^CJ. 1*1 rr l l l h ^ vcM l.doc Fonn VOA 1.0 10141994 1032 S 302505 Surrogate Recoveries Were the surrogate spike recoveries within acceptance limits? X ^ No If the spike recoveries were unacceptable, wergthe samples reanalyzed? Yes No / N A } Comments: Matrix Spikes Were mauix spike analyses performed at the correct frequency and on a sample matrix representative of the samples in the sample delivery group (SDG)? i^f^ No Were the matrix spike recoveries and relative percent differences (RPDs) within acceptance criteria? (YS> No 7 ) ^ Comments:^ ^ ^ ^ ^ ^ ^ _ _ ^ ^ . ^ ^ . J ^ A ^ - / d i ^ ? T J ^ V, f<! — ^ . . y ^ : Z £ ^ X ^ r.'.«.^ LCS //u-.'-fj). N o ' R P t ? /.'--I'-t-J e^-/cfe//j-/,eX T<^*- ^ 0 ^ ^.ciff'x i p i k c d u j i l i (i.e.i-^S Cwc Ao+ Irrc^^U, Ireof il>^^ ( o i ^ Internal Standards Were the intemal standard areas and retention times within the required limits? ( T ^ ^ No If the intemal standard requirements were not met, were the samples reanalyzed? Yes No r " ' ^ ^ Comments: voa.l.doc Fonn VOA 1.0 10141994 1032 6 302506 Blank Analyses Were the appropriate numb^of blank analyses performed? ' Y S ^ NO Were analytes detected in the blanks? / - I ^ No If analytes were detected in the blanks, were the same analytes detected in the associated investigative samples? Yes ( ^ NA Did the sample results require qualification due to the presence of analytes in the associated blank samples? Yes l^oX> Comments: Laboratory Control Samples Were laboratory control sample (LCS) analyses performed at the correct frequency? ("f^ No NA Were the LCS recoveries within acceptable limits? (X^^Qs) No NA Comments: vo« l.doc Form VOA 1.0 10141994 1032 7 302507 Sample Results Were target analytes reported in the investigative samples? Yes X N ^ . ^ i^^in Were mass spectra providedjor the target analytes detected in the investigative^samples? (jfeQ No Were the mass spectra of acceptable quality and analytes correctiy identified? (23X^ No Were the quantitated results for target analytes calculated using the appropriate intemal standards and were the relative retention times (RRTs) acceptable? Yes No ^ Comments: OMcfCyo.^ 9 T X ^ ~ X ^ ; ^ > J 1 « W L Tentatively Identified Compounds Were tentatively identified compound (TIC) s^ches conducted for all sample analyses? Yes No X ^ ^ P * Were non-target peaks evaluated as required? Yes No Were the TIC mass spectra, searches, identifications, and quantitated results acceptable? Yes No Comments: /i _ / / ^ - ^ //^ T / d - ' ^ ....-— J-rf^^-J! : ^ /A^.a>-^^^-€jz-<^ , voa_l.doc Fonn VOA 1.0 10141994 1032 8 302508 Log Books Were sample preparations properly documented and performed in accordance with method protocols? res) No NA Were sample analyses properiy documented and performed in accordance with method protocols? ( X f ^ No Comments: vot_1.doc Fonn VOA 1.0 10141994 1032 Q 3 0 2 5 0 9 Calculation Checks Insiniment Tuning u/lHlt V // •' / 6 Relative Abundance: "'"'' "'^^*^ ^^^^^Mr^'^'-^'^-^^ ' v / ^ ± i ^ ^ ' ^ n /io.rs sz:^ %RSD: Contmuing Calibration 7 7 ^ 7 ^ / t^ c^ ^ ^-^c^ ^ RRF: ' xyyjTo'^ ^ - A;?7 7 Surrogate Recovery 10 Fonn VOA 1.0 302510 voj_l.doc 10141994 1032 Matrix Spike Recovery -(^yM.^-rj^^ii.uyy.^ ^^yyy^yci(^ -^ w^'^ yo > < ' inX i ^ ^\,^~^'--^^'-V'^'T^^Jl^X^xyxI^^ ^f.j^;^ ?^% RPD: y 9 . 6 - r ' ^ J C(^Q,iMjn^9'^''-^-^J^.^U^ \ / 0 f - A A ^ O ^ I ^ * ^ iJtnsA.' I l6 t f i f > Sample Results '"^^'^ -yx^AT^^ '^"'''''' ^ CRQL:, /3/v/ A-^ju^iJ CAQZ. - O t Q L >r I t^iP Detected Result: ::. f. ^ S f ^ / , l^j>^^.^-^yt:^ H-^^-n, W^ TIC Result /yoA^e- vo«_ l.doc 10141994 1032 11 Fonn VOA 1.0 302511 HOLDING TIME QUALIFICATION SUMMARY FORM Sample Identification P T i n o p-r ^ i i o -FT ~/ozf TX^ lioV Date Sampled jl^cA-99' j 1 I Date Analyzed //-AY-^y \ I /I- / ^ ' 9 V Analysis Holding Time JO I h 10 / / Qualifier / V d / i / ^ \ \ \y u> o to (Jl I-* to Comments voa_l.doc I0I4I994 1032 Form VOA 1.0 12 INITIAL CALIBRATION QUALIFICATION SUMMARY FORM Date/Time Instrument Analyte RF RSD Samples Affected Qualifier //////? f XA^..^.^:eyL...^ 7 ^ . ^ JVfeXr^ V-rnia. TTn-iio, ?T/^i_) y \ / O j M ,o/(? Ji^'f ^-/L~f. ^rV^-^'T'-C'^ ML 'TY.'T^ IAII Ji-TCa.t^^'ir^^.e.-^ oyy jji/e J/ u> o to cn M Ui Comments: v o l _1 .doc 10141994 1032 Form VOA 1.0 13 CONTINUING CALIBRATION QUALIFICATION SUMMARY FORM Date/Time A// <;-2.-) ( I I .' , ' Instrument t A yi.\ Analyte ^/jA/iTi.n-y^.^^^^K^'.^^^ ^ . i ^ ^ . / A £ ^ ^ i ^ / / t^AT^^-r^A- / -/Tyj/on^-ekt^— Ayo~l, ? -Ac*X^-v?>t<rw«n fiam.^ ~L 7^>-*^^*»>./lirp^ ^~//AMJ~2-y.^-h.>...r^ ^ ''l4-'^ct,^t.s..^f-rve^ RF - .oosr ,00/e e. , 0 ^ 9 ^0(3 %D 4^^.r -v/. "/ :x^.o ^ ^ 6 f^-y . 2 ^ , ^ ^7.7 <^^ ? ^^ 7 .r Samples Affected T ^ //^'5^ / / / / / / xV Qualifier T / U ^ / 0^ r//^ T/Jt :yl^ir t V T/Zr r//e Comments: o to tn H voa_l .doc 10141994 1033 14 Form VOA 1.0 BLANK SUMMARY FORM Blank ID VeLKO I TB lloi Analyte /Ku.-i'Lyl^..^ yLlnyi^-^ n c1-Uy lri\r. oUloi-Ai^^ Blank Result (units) /^-A ' • IcJ* •* / A.e.U yT Jf Action Level / O )uJL ,'-/' /o u^/l Associated Samples p T / / / 0 , P T l / l O ^ P T M 2 - ] PT tlic,. PT 7Uo P T l^?.l • 7t^ Comments: w o to tn l - » tn voi_ I .doc 10141994 1032 Form VOA 1.0 15 Summary and Conclusions T k e , yylu-f, I e. C>t^»a»>i'e. C o *~yfo i.^>i. of J" l^CrTM/<r -A^t.- XOLi^„ f c "/"Ac- V--c\u-i'^\fc S'^CKinUoieJ d ^ ' ^ l c t f / o i / i J C 7 » ^ S ( : P ) -f-ut> Qc^-totr\r C..%-.iy 2.- ^''-•faKoMC t n f ^ c it^fj-Ac^l Cfc/,'4 »-«• f/'o n t ^ e j ~ u / : ^ C/TC/ V-e.t<Liiiye ycj-r, o^iS c -f'te f o t^ r Tb ir gfe-fo^^c^ .^ ~ ^ U "f a «n o t^ e . Ci-^ oA ,C/>t/rl .-/f g-l>-. 0»1 . gLi^c/ .2 - A c^gc »» o »i r- k(j.\yc fee-Cfci q,iA.e^ l / ' r i ' e ^ < ^ ^J'ft'^u.-h^ei^ ^ ^ O - ^ Ujk.U fUi Ju^n - d^+rct^cf ^^CiJ-'^l-f-r k tA t«e- e g * i g ac J/A'dc/ £ . J t A t r X U A - g L I c C / Z ) I 1^ a. I I SCIrr^rr, / g - T . »owc<.nc cirxioyo i ^ ^ + l \ u i ^ c : ^^f^Ay/cMC: c k l o ^ . ' d c . gce-yo^e. • # ^ =7^ ^ - ^ U f c v <^o>, e- C/f->^ f ^ ' a t r x " 1, 7 ~ c/1 & A /& t'-o/0>'op < *i e ' j — i^c-^/i'7l~ ^ ~ C t ^ r T C t ^ i_3_ -fc> >^ ge>^c<n.'f' eiI'hr-c.k'^ i^cc _fi_il </ /&> t/" /•^^ / eey I j r v i ^ >.u-> lrel(^4,'yyc V-^SUo^vr 'f'<C-f-Ci^^. fill's CCcUJ-^cA i h e P^tiAZ-j-,'lyC IrcJu. I t / •for -f-L ^ J C CO ~ t^ U !.<. .«^t/j' T/J y/o V fo ^ / / • f W <t7 Aj g/'-f^Ci'' ^ss-^i^xj-ec/ C ( A T ) OV^ ^ t ^ t ^ J o k I c ( ^ ) X s r : c j>o.c,tL 11 ^ f cjciu. ' ) s j nfp lUl"^ Validator's Signature: - / p ^ , , < A ^ X d c ^ ^ / Validator's Initials: p A j<X Validation Date: /p/p^/?s^ QC Reviewer's Signamre: ' ? ^ ^ < A ^ 7 ^ ^=^^C^4»-' QC Reviewer's Initials t l f f Review Date: //^/^r voi_l.doc 10141994 1032 Fonn VOA 1.0 16 302516 ILCA LOW CONC. 'vJ^^TER VOLATILE ORGANICS ANALYSIS )JATA SHEET EPA SAMPLE W0„ :, Nafoe: i:iTC/GI,i!^F SOUIH. i...£ii;> L-CjcU;^;; 0;ULF_ Cc'.i:>&/ N o . Lab Sample ]:DS UNS003_._ L..ai:,. F":i.].e ID;i \ - f M M Q F-i.i.i'cie Vol.Luner, 2'5,..00 iiii.!.) Con tractn PT102] HI... A ; ._ SDG No - ;: 9£l.lj95.. Date Received: i.ikZS^12.^. Date Analyzed; l.j^X.A3AXiX. D ;i. i u l: 1 o n F' a c t o i" " i ,. 0 CA!:? NC.. "V •' .. . r;; rf 9 - O i -a ; 10061 -O 2- ; :;. O B • • • • i ( ' > •••:;. • •••L.lL.N I.' •1 ,,2-D:i, br'onioetharie • T o 1 i..i e i'l e •Ci'iJ.oi'oben /:ene CONCENTRATIOKi (uo/i...) • ; : > • ! : . > ' ! ' • & I"! VA' • X ' / l e i " ! ••/: \ '>:.'::i x--:-.-. ) -'.\. ,..:.'.- }.)'.'.. Ij'.-Ci.'.'iC.l—--.'..'-- ' ••i..Ai"ii. o v'Oii'iir- '•:.: "!ai"!e •• ::'•'.-" c:i t I'i o lYi e 'V. i"i a i"i e • vyii-. ••/1 C ! "i I >:> I • ;i. r! e ••''• 11^' ':::ifoe'i:!'ia!"ie "ile'i;.l"iy'lei"ie l..:i'i.i.o] .!. '"> !•"' •""':';' r' CJ o a !"i e -.;. .. .i.--.1.''!:. c!"i.1 oI"ee'i;.i'le'.">.e • 1 .: .-.. •" .U ^t. >z -."i .1. o \"0'.'.•.''[. (•"lar"! e •'..'. '.I -:::•--1 .i /;'•••.!,•' ii. c! h.; o ' c : vX- 't'. ."leri e C M ] Qrol'r-rn-i • :. -^ i:;! 'I..'':i. c:i"i.:.c?! "'ije 1;.'••(a:•!e •2^-Birtani::;ir^;e> • oHioci"!.1.C'V I.'.'.'il!e'L!•!-f^i.I'le -'.i ., 1 „ 1 - ! '••'".-, <:.''. .\.Ci\'0<:-.'\.)\c:y\<::: •'. J a ;•'" ijOi^'i i e "".•. I " a C I'l .l, i"> ;-•• ;i r; r.;^ •BrcKiuin:!!!. •:::I'l.i. •:<v'Oi\)i-:.'<:.I'larie • 1 ,| /;!^^.i..' 1 C i'l .!. >.'.'.' i"C' iJ I'C'i ':'! a I": i^:' • r^ * ] ^ ; * . ••• : ,, . . ^ I ' ^ . ' ^ i . C! I t .1. (!) 1 L!<'•j i''"i"!! ;^!ie i 1 e •\ f:!. c!"i .1. o r ' o e c i'^ier'! t-' D i t>\-~o\uc^ci"i.!.C'I'^Miie'!;.barie .:. M .1. ., ; •tiei'^i V ' e i ' i e ••'I :••• a n •:;;••••• 1 ,, 3 - 1 ) 1 i;:iilo!-opi'^o!jer'ie • . I ' r ' f j f i ' C v V i " ? I'^iii ••r:.[. ••••jv,/.v, •;• I ••,-•./ i . - y --.••'i//.\-f •l;..;Vi, i'l r > | - | . - : . . ".::'."' i^iSXaruj!"!e • i <..-:'[. .'<••. C •"<.!. O : " C > e K. '"{i-::y'\ e •• 1 ,, -.!:•"•••/..'1 c^'i .i.<:J'•"oi!>eri!'! 'X'r^ie •• 1 ,, •'•;•••• D1 c. Y) 1 o \- ij bArI:;: e:"' e •• :. ., .^]'. —>.)'.; '...'.'t .i.\.} I' i..i.)'''.'.'\"\ Z e i ' i v ! ' '•••Ci-vi'i A \...C'A OIO 01 I.:.; R P : !.; B^ r i R I I 302517 ILCE LOW CONC. WATER VOLATILE ORGANICS ANALYSIS DATA SHEET TEHTAT T VELY IDENTIFIED COMPOUNDS .:> NameK ETC/GOLF SOUTl^l !..ab Code: G].)i.jF Case No.;; NLifi l...ab Sample ID: yN^<)3_ • a b F i l e I D : y o y N S 0 3 ;••• i.u •• (1 e V o 1 l.l. m e n 2 a „ O 0 (HI 1) C o n t r a c t : : SAS N o „ ;; EPA SAr'iPL..E i-jO» P T 1 0 2 1 D a t e R e c e i v e d : ? J : . / 0 a / . 9 £ Date Anal'/zed :; l.l.clA:X5i.!:i D i 1 n t n. o i "i I'" a i:: 1;. c> r • 1 . 0 i^l u m b e r T I C s •v'oi..u"id :; L..ri';> NUr'livlE.I''-! IF-'OLIND NAl'iE RT EST.. cor^c.. ; (uq/l...) ; [-). \ f r ^ t » r*s '^ Date — ™„ i ^ ^ £ ^ ^ 010015 302518 ILCA ..QW CONC. WATER VOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAI'IPLE NO. P T l l l O .:.' N a m e : i;;:TC/GUi...F 5Ql...iTi-i L.atj C o d e n Gl>LF C a s e l...ab S a m p l e I D : UllSCK)! (••ii...H C o n t r a c t : SAS No.. : L.ab F i l e I D : VOLJNSOl P u r q e V o l u m e : 2 3 . 0 0 ( m l ) N O „ Cl.li'ir'OC^i'^^D ; SDG No. : 9^195. Date Received: ilZ0.5/9£ Date Analyzed: i.;L;;ll.:^/94 1'} i 1 u t i Ol"! i'"a c t o r i: 1 . 0 CONCENTRATION ( u q / L ) \A •j Q/,....93..../^ l 0 8 - 9 3 ~ 3 --- 1 O S - 9 0 •••7 •: :"-ii"<-'^i-'l —-.'1. - " 1 . , -i—D:i. b!'"Ofi'ioe"v.l''ar'ie • T' 1;' !L u. e ri e _ • C!' I J. o r o b e ri z e n e .1. , /'.. . I... • - " { - - , / ...j - S t y ! • • • eI-,e Xylene (total> 1 .1 J.-.'.--'.'.>"\. iij!'oniC!r^^•.:>•••• < : : . \ - \ A . O r o o r o p a n e I.,; l"i .1. o !'"oiiie t I'iarie — B i ' i j f h o m e t r:ai'-i e '.J-}.\-\--/A. I...: n.!. o !•• :i. G e _ I..', r I.(. O j ' '•'.':• Z: ':. \">, a I'r O — Ne-i;.;-iy 1 e n e C h 1 c<y:;.ci.;o _ ••" i"'\ f;:e 'Lcir: e 1 .. :..•••.•..>::. c: b.!. o r ' o e ' 1 ; . ber^i e •••• 1 ., 1 • D 1 •;:; i'l.;.c: r o e 'i;, \'uxrie c: :•. •;:; • 1 ,, 2^^ D:i. c: r i l i:;!"(::ie t i lei'^ie •i.o I" Of :> ! " 0 ' i ' o rTi'i • >!••• l-H.rLaiioi'ie ••• i.v' v'o.^c- -•'.'. :"i .1. o r'Ofi^ie v. i "ia!"te - X ,, 1 ,. 1 ••• t 1" 1 c ;'i .1. o r o e t Viar'ie - . . • ( . • , . 1 . . • ; ' . . . . " . „ ) . ^ . . . i . • • • I . . . I 12''- 7 9 - 7 1 - 1 0 0 •71-^... lOS 1 : : . • • • • • • ••••4B^^-1 OO^^b -•••• 4 3 - 2 6:1. ••••02/^^6 • • • . ' • 1 " . . . . • " . • ' • • • • l O ^ ^ ^ ^ l I'liCJL! !i. L : !"t.I. o i••'!!>:•:•!(;•;••(;. I ' l a r I (•;; - 'Z'l \::—-'.[. ,, •.!>•"•;..-';;. c; i!.-. o i"i"> i;> roj pel"! iv' -"> v '.. c.h 1 o I'^oe i.. r^ier^i e •• .;..•' :i. I j i•• on'lo c. n... o r oivie 'l. i "1 a r i e '• 1M 1 ..A.— I r'!!.Ci'i.1.0;'oe•i'.i'ia.;'!e •Bei'i ij'erio '• •'•. !•" a }• t '::;• •• ' .1. .; :-'.• " ' .'..-^ .\. >'.'.'. I I .!. •.'.'.' i " i'.'} ''.'}}-" '.'.'.. Kj 'X! ".V;; ' • • ' : : : M ! ' i O ' r o • r ; ' i ••'•^••'>':e ';. 1 •!y.!.--.•:-.'. 'ci"! ••; a i ' i o n e •• i e•!;.r"a'::;r^'i.!.or'tje•'•.;'iei'-|e • .;. •• 1 ., !-.'b-••••'"•• i e••;. i"ac: I'l.i. oi'"o--;.'••;.. ••:•; -i. ., 3 - - D j . '::;i'. :.':;.' -'.jli^en z e r ' i e •-'.'.. . ''-••-1':i. c: ;••;.!. or-oi:;!(.:•;.|-| zei'-ii-:-' •• 1 ., 1: ••.'..•' x <:.'. \"i... 'J':"..'.'.' I j o n :•;•: ei"i e I; l.l ;U R h y f t : 6i 0 1 0 3 02 519 ILCE LOW CONC. WATER VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COl^lPGUNDS b Name: ETC/GUI..!" SOUTH i...al;:> fi:ode: GULF'- Cas-e^- Ha.. Lab Sample ID: UNS()0.; i...a I;) F :i ]. e I D : V O J N S O 1 . r' u!" q e Volume: 2 b . 0 0 PTlllO Con tract: SAS Ho „ :: SDG No „ : 941.93. Da^i:e R e c e i v e d : LXZ.£\^/.2.!:::. D a t e AnaI-y-;;-ed : l.L:-r^.lS3l?4 D :i. .i. Ll "L i on i"a c t o r ;; 1 ,. 0 •iumner' i.i.L.;-;;'- lourid ;: A':> AVl'lBA.A COi'ii-''OJND I ,, I i.. u a / L.. .J ^ . ^ 5 ^ r-A ^,-T-rrf Daie ........-^riii/ f V " * ' " y ' ' " " 010019 302520 ILCA LOW CONC. WATER VOLATILE ORGANICS ANALYSIS DATA SHEET D i-lame: ETC/Gl.Ji...F SQUTi^' ; bab Code: GULF _ Case No..: H.LA Lab Sample ID: 0115002 i...ab File ID: ygUNS.C;2 F'u I"g e V o 1 u m e ;; 2.5 ,,.()0..._ (fn 1 ) C o n trai:;:t: Eh'A ;;:;Ar'ii--i..E N O . PT2110 i:;A.::: !--KJ „ C0i''ii"'i.iui--:u ; SDG No. : 94193.. Date Received: '^.1Z.!>1X[/.2A-:. Date Analyv^ed;: 'Lkc.'-':3./.A.!^. D :i. 1 Li t i o n !"' a c 't o i •": 1..^.0 _ CONCEN";'RATION (LU:I/1... ) Q ; 106--V3--4- ; ;i.0o-90-^7- 1 0 0 "41 ••••4- ; 1 0 0 - 4 2 ^ - 3 - 1 i--, .- .1 .—I . - , ' ••.••'.<i. • • • • ; • - ; • / ' • • • • " • ' ' " / ' ' " i — • (• n f > - •'•-' .••• . 1 • • • • • . . ' ^ . l • • • • • : : j ; / ' - / - • ' • . M - - c : . : 124-48:"1 ; 7 9 "-O 0 - 3 ; 7 1 'I3--2 ; 1 0 0 6 1 - 0 2 - 6 - ' •; ( i p , - - •' ('• .1. • ; 0 . i . L i . e n e _ _ • 1.:^ i'l.!. o I" o i') e I'l z e !^i e •!::. •'.•. " •;.•••• .1. '.'..1 e r i z e r i e • S ' l . y r e n e ••.•••'•/'.i.erie ( LO'i.'.a.i. j '• 1 ,, 2--D i b !'• v;:'Vi'io- 3-- o. h 1 o r o p v o pai': e - C h l o r o m e t h a n e •• B r o m o m e •L ;• i a ri e • V i n y 1 C l"! I o \- :i. d e • • C h l o r o e t - . a n e -i'1etl"iylei"ie '..''r,Lov.;.•:::e - Aicocono ••i...;a!•"• i!>(;>n L'*'i.•;;:L'..:.'T ! . ' . ! * e •• 1 „ 1 ••;.•'j c i " I . i . o i " o e ' L • " l e i ' i o -'.'.. ,| !i. ••••D1 c"';.:. o ; ' " o e ' L !'i a T i e •''.'.'.i';:.•••* 1 .• A--).)?.. cY't,'....-.-)I'fje'y.\"'0'":e •'i;.rar'i•:•:•••• 1 .: .::.•?-''i. c i ' i i . o ; ' " o e ^ v . i " i e i ' ) e - A : 1 oi'^crf c:'i"fii • 1 :, >•••;.':•. •:; I'i ,k o I ' c j e ^L i ' i a n e ••2—B'Vi.'i:.ai"iOi"ie • B i ' ' f j i ' i i o c : "i i.Cli"i::>!iie"<. i'l-i-xvie --.'.. ,: .1. .| !i. •• • ! !" :i. c: il .!.•":• i^'C'O'U'l a !"i e • i '.•:•...'.-' rJoi"i ! ••::''.. i " a c . i'\ .1.oi'" ii;i e ".••;; !^'i!!>i!'iod ;i c i "i .• o 1 "(''ri'ie 'L i'lai i e •• . ., .:/"•• J..'.... c i 11 o ]-" o \'.'.'!'" o p a i l e •• c: :i. ^^••••^ J, „•.::'• J.-''I c l ; : o I "o p'"(Vi ijer'io •''i. cri.!.o!•"iJe'ti'iei"ie -i.'.i 11. b rofiiCiL: !i .1. o! •'•jfiie x'r\.\i'io • 1 ., 1 :, 2 •••• T I'" i i;:: i"i 1 o i • o e t A ••' i-i o -Bei'i z o n e ••'i;. |-'a I'l •;;:••••• 1 ., •.:^'^^'Di.L;h.loi'^f::i ; I ' o p e r i o -A\''oi\'iO"<'o \-"ii.''. •••'•^•••i-le•!;.hy 1 • ' • ' 2 ' - P e n La,".o;',,:.;:. ...'1.^^....'.^ ••2--!-iex ai''Ci:'ie •• "i" e 'L !••• •-::'. on^. o r o e t A o • • e •• 1 .1 1 .1 A .. ••••'.'•"" I e'L r a L : I'l.;.o:"(:i.:./:•••;.;••)ar;e - 1 ,, 3 ^ - D i c b l o •••'•::;bL:'i"i <;ei"ie '--... ----:..-.'>. L! I I ,;, O I'- O !'!' e I I '.''..::'. i": i.'.-' -'i. .. 1 ! " • L' 1 o 1 "I... o ] - ' • • . " ' I J O I " ! 7.e!"i<.:•• •...M'.:i'i I L.C; 11 I...I /? ' I i .•:.-• R H; V ^ < H' \5 C ^ ^ H < ^ 11 R '-. I ni0022>^<'252i I L C E EPA SAi'lPLE NO. LOW CONC. WATER V O L A T I L E ORGANICS A N A ' L . Y S I S DATA SHEET T E N T A T I V E L Y I D E N T I F I E D COl'iPOUNDS 1 : P T 2 1 1 0 .!:) N a m e : ETC/GU!..F SOUTi^i C o n - L i - a c i t : I _ L a b C o d e : GUIJ;; C a s e N o „ : K^.^A_ SAS H o „ \ \ __... SDG H o . : 941J93 l...ab S a m p l e I D : U N S 0 0 2 , D a t e R e c e i v e d : 1.1ZX>X./.2.A. Lab File ID; yjGyiJli£2 D a t e A n a l y ; - e d : A.A.cl3.A5'.f:{ P u r g e V o ] . u m e : S.5.j:iiQ.... ( m l ) D i 1 u t i o n 'factor';: I...7.0;._ ! -I Li m b e I- "'IC^i ' f o u n d : 0 ; ; : EST., CG! :;AS ;-H.!>-'lBER ; Cn;-lF'n:.IND .-AAAA \ RT ; (Lu:i./I...) <", 'J 302522 ILCA JJW CONC. WATER VOLATILE ORGANICS ANALYSIS DATA SHEET a Name: ETC/GULF SOUTH Contract: EPA SAMPLE NO, TBI104 al::. Code: m L F Case No.: HL.A. ..ai:j Sample ID: yHS^lyZ..... ab File ID: yoyNS07R •'LU'"qe Volume: i^.a..;f.00 (ml) SAS i-io. : SDG No. : 94j;£3. Date Received: ^Jv;03/94 D a t e A n a l y : / e d : l..:!:.c :]:^•'''.2f^ D i ]. u t :i.ori F a c: t o r ;; 1 „ 0 CAS WO, e;OMF'OUND CONCENTRATION ( L - . q / ; . . . ) i ( ! ' l • • . " • • ' ' " - • ' ( ' • " • • .-'' — •") V > v ' > - — / . l . ^ - ' — ' - I ; 7 3 - 0 1 - 4 I 7 3 ••••00 ••••3 : 7 5....()9....2 — .... f.. .....,.. ... . . I — - . . . ; . ...I !-• ! - ' • ' • , ; ,'- '-."-..J ,:'::•.!. - '•..' .t. - - - j : 7 9 - 0 1 - 6 ; 1 2 4 - 4 0 - 1 ; 7 1 - 4 3 - ; 2 ; 1 0 0 6 1 - 0 2 - 6 I -."••- o r : •-;, I .•• : . < A . . -..I / . . ; : i . 0 8 - i o - 1 i'l.i. L:ii"ODi''Lii::iane 1 „ 2"•D :i. b I'^omoe t h. •y ,-•;, ] II i^:, |-| i::, — I..: h.i. o i ' o b e n X e n e —F. r.h-/l ::.e['i :;^ene - S ' t y i ' ^ e r i e —•.:••:."v/.:.e:"ie ( L O L<;...i. .i - - - l ,, 2—D:i. b!'"'omL:i'^^'3-• - f..: ii.!. LJ ;••• o m e ' U l a. I'l e B r o mo m e 't h a n e V i. o y C i"i 1 o I" :i. d e _ —C i'i I o i"L:ie 'L i'lar'! e —-''o Li'V';.-' .1.ei'ie "...i"t .1.L:'V:I.Oe A c e ' L i : : : i n e r;: a I" b o n D :i. •;;;. v. .. f x '.:• e 1 ,, 1 -•T.j:i. I-':--; 1 rt'•••r'le'tTiene 1 ,, A. — D A. c I'l .i. o I" o e 't \"i a !"i e 'i.'.'••'an ::••••• :i. „ A.--A'\. L:!"!.:.':::.; "oe''3"!ei"ii (.:!'i.;. L:Ii"i:::i "''L.lI "i'ii :i. . , 2 •••• D :i. L: i"; ]. o i " o e ''3'i •::-,n e _ 2^^-Bu Lai'!L'li'ie H ['•ornoc: b .i. L:I I'f::.!":!^ "•:. i ' l a n e 1 ,, A. ., J. 1 I" :i L: n .1. c:M"L:ie "L !iai"i e i...:ar"bL>r"i ] e"':.r'a ::n .i.L:.i"":;. c!e .1";!""c:.in L>Li :i. cb.i.•.j\-"oi\'ii:.-;'tiiai"!o 1 ., 2""""D::. L:!""il L:!:""L:,p!"'"Oi::iai"ie ::::i V^-'A. „ ..::,-• .i.>:i. L:n.i.L:ii"-i::ip!''"L:i':.^ene T I " :i. <:.-. i"i 1 o)•"• a •;:: L b e I'l e ].):, \.< i"'c:i(riLi c. ii.!. o ;•" L:i(r'e L riari e :i. ., 1 ,AA. - . '•":i. L:i'i i.L:II "oe'i;.iiai'ie .1".', e I'l:?: e i"i e i;. I'aii":::" • L;. „ ^:> 'i.):!. L: i"!.!. o r r i i:>i "Cj I::L:' Bi"Ofi';:::L'roi""fii • - " " " o e 'i.. i"i"y".i. ""•• :•:;:••• !••'e!"i " L a n L I \ " \ e ;i..i I. M I., 11 I >::• " a L: 1'I .1. o i-"" o i i e :i'iarie """-I-':i. L: i"i !.i.:i\-"o i : i e i ' i . ; : e n e """D :i. L: !; ] o v- i . o n ;: e n e """L':t. L: i"i.!. o i"""Li !::iet""i 7.o:''\o . ^ \ i ^ ^ r V : A < ^ ^ 1 1U 1 \A^ ur 1 ; L! 3 3..] R 3 3..^ R 010026 3 02 523 iLCE LOW CONC. WATER VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COl'iPOUNDS i:i Name: ETC/GULF SOUTH __ La;:i Code: GULF _ Case No.: H.LA_ !...ai:> Sample ID: UNSOOZ L.ab File ID: V0yN907R i"-'urq e Vo 1 ume: ^.a.f^.OO ( m 1) Contract: EPA SANPLE NO. TBI104 ^S No.: . _ SDG No.: 9':1193.. D a't e i •; e L: e :i. V e d ;; 1.1./O a / 9 4 Da'te Ai"ialyved: D :i. 1 u t i o !"• !~ a c t o i": :l..' • ; . ' • ' '••, . • • ' < : > , - • ' . i""-!uni!:jer" T!rC3:; "i^ound : ::3r'i:""'0L.lND N A M E !:;.:;:> I , i" I i !" '...-'...': -1,. \ I Fi Daie , II r^ A, "T C pj _/yM. x^ 302524 010027 HLA DATA QUALITY ASSURANCE REVIEW SUMMARY Semivolatile Organic Compounds Analysis Case Number: f ' ^ / f j ^ Project Number ^ c^p. -p^ -^^ \ Site: -T^Ja,^<L CL<^,^\n.f C. Contractor Laboratory: P. ^ ( ^ ^ XX t^ C" 7 ^ / 1 / Q . U J ^>^/eLt?.K,.«? Validator ^ J j / j , ^ QC Reviewer /7. ^ L . ' / h ' t ^ Validation Date: yjL<///ff ^ Review Date: i/jd " r r Sample Matrix: y/i/c^"tor Analytical Method; S A H L C W O 4 1° h ^ Sample Designations: ? r i i \ o P T 2 1 1 n ?T 10:2-1 / UhScAc? 1 I j A ^ ' ^ i i C P Z - ^ A A S O O ^ Data for the above samples are: Acceptable for use y ^ Acceptable for use as qualified Unacceptable for use Is action required by the Prgject Manager? Yes CNfl) Comments: T A . ^ . i o i u . . . c s . . l / du-^ec^ ^ ^ >\j, "-^^ ' ' l A S f . P ^ C L P l l i l i r n ev^i e v^ '/ F<r4- n ' l i . bDa_l.doc 10141994 1034 Foim BNA 1.0 302525 f DATA COMPLETENESS CHECKLIST JC Included, no problems j ; Included, problems O Not included NA Not applicable Quality Control Summary 7Tj- X ^ ^ Case Narrative "X Surrogate Recovery Summary X MS/MSD Summary •^ Reagent Blank Simunary X" GC/MS Instrument Performance Summary Sample Data tmpi X Chain of Custody Forms X Holding Times X Organic Analysis Data Sheets X Quantitation Reports X Reconstructed Ion Chromatograms X Mass Spectra Printouts X TIC Mass Spectra Library Searches Initial Calibration Data X Calibration Summary V Standards Quantitation Reports X Standards Reconstructed Ion Chromatograms Continuing Calibration Data /lAA^ Calibration Summary Al^A Standards Quantitation Reports /I^A^ Standards Reconstructed Ion Chromatograms AVA Internal Standards Summary Instrument Performance Data X DFTPP Mass Spectra X Reconstructed Ion Chromatogram X DFTPP Mass Listings bDJ_l.doc ""'"W1034 2 FomiBNAIi) 302526 Reagent Blank Data Organic Analysis Data Sheets igen Quantitation Reports X^ Reconstructed Ion Chromatograms . Mass Spectra Printouts . TIC Mass Spectra Library Searches Matrix Spike Data and Matrix Spike Duplicate Data X Organic Analysis Data Sheets ' X Quantitation Reports X^ Reconstmcted Ion Chromatograms Laboratory Control Sample X Organic Analysis Data Sheets "X Quantitation Reports X^ Reconstmcted Ion Chromatograms ^ Mass Spectra Printouts /X/4 TIC Mass Spectra Library Searches Comments: ^ ^ A ^ArtZ- '-^r biu_l.doc 10141994 1034 Fonn BNA 1.0 3 02 51:7 SPECFIC COMMENTS REGARDING ANALYSES Chain Of Custody Were samples properly preserved and received in good condition? / ^ Y J ) NO Were custody transfers corrg;^ and completely documented? Q ^ ^ No Conmients: Holding Times Were sample extractions performed within holding times? "YisX No Were sample analyses perfom^ within holding times? ( X ^ ^ No Comments: C11U>. . _ _ J . ... r^i'F 1/^/93- Instrument Tuning Did the instrument performance checks meet acceptance criteria? / f e T ) No Were samples analyzed within the 12-hour period following an acceptable performance check? x-^^p No Comments: biu_l.(k>c 10141994 1034 4 Fom.BNAl.0 302528 Initial Calibration Did the laboratory meet the method requirements regarding the minimum number of calibration standards for an acceptable initial calibration? X^Yes) No Did the iiutial calibration curves meet the Unearity criteria for maximum percent relative standard deviation (%RSD)? , . ^ ,.'Xes} No Did the initial calibration me^t the minimum relative response factor (RRF) criteria? ,. "Yes) No Comments: Continuing Calibration Did the continuing calibration curves meet the hnearity criteria for maximum percent difference (%D)? Yes No Did the continuing calibration meet the minimum RRF criteria? Yes No Comments: /V/ boi_1.doc 10141994 1034 Fonn BNA IJ) 302529 Surrogate Recoveries Were the surrogate spike tecoxeries within acceptance limits? ( Y ^ No If the spike recoveries were unacceptable, we^the samples reanalyzed? Yes No y ^ ^ ^ ^ Comments: Matrix Spikes Were matrix spike analyses performed at the correct frequency and on a sample matrix representative of the samples in the sample delivery group (SDG)? ( X ^ ^ No Were the matrix spike recoveries and relative percent differences (RPDs) within acceptance criteria? Yes No A ^ Comments: . / /' '* Internal Standards Were the internal standard areas and retention times within the required limits? C ^ ^ No If the intemal standard requirements were not met, were the samples reanalyzed? Yes No A " " ^ Comments: boa^l.doc 10141994 10J4 6 Fonn BNA 1.0 302530 Blank Analyses Were the ^propriate number^ blank analyses performed? / - t w ^ No Were analytes detected in thgblanks? ^Xfep No If analytes were detected in the blanks, were the same analytes also detected in the associated investigative samples? ^.^ /Yes) No NA Did the sample results require qualification due to the presence of analytes in the associated blank samples? ( X ^ ^ No Comments: ^^i-TTtt) . . sie^ \^y^. \ s v ^ (-fer^i ^ sBu<i 7^riX5</V3^^^/^TM^^^Pr/.? I t I " (( .1 I pTfifio Ifi^A 5-^ „ / /, ,. pTiC)X./ p ^ / ^ S-iA. Laboratory Control Samples Were laboratory control s^mpje (LCS) analyses performed at the correct frequency? (Xfes) No NA Were the LCS recoveries ^^hin acceptable limits? XYCT) NO NA Comments: boa.l.doc " " " " ^ " n * 7 Fonn BNA 1.0 302531 Sample Results Were target analytes reponed in the investigative samples? X^^^yx No []) Were mass spectra providedjoi, the target analytes reported in the investigative samples? fesX No Were the mass spectra of acceptable quatity and analytes correctiy identified? ( ^ e s j No Were the quantitated results for target analytes calculated using the appropriate intemal standards and were the relative retention times (R^s)^acceptable? cyxxs§-y No Comments: ^^ 0 ^ - ^ JL^,,^ c^J^:.^..,..^.^ J ^ f ^ - ^ ^ ^ J ^ ) } ^ ^ Tentatively Identified Compounds Were tentatively identified compound (TIC) searches conducted for all sample analyses? /-^€S^ No NA i j ^ Were all non-target peaks evaluated as required? /Yes^ No Were the TIC mass spectra^ seiches, identifications, and quantitated results acceptable? Xrep No Comments: bDa_l.doc "»*"»*"»* 8 FomiBNALO 302532 Log Books Were sample preparationspsepaly documented and performed in accordance witii method protocols? (_X^ty^ No Were sample analyses prowrifcdpcumented and performed in accordance with method protocols? ' ^ s ^ No Comments: bui_t.doc 10141994 1034 Fonn BNA 1.0 302533 Calculation Checks , } i h ^ Instrument Tuning u U / l i ^ o n T^ Relative Abundance: (f ^ ^ ^ ^ 3 ^ Initial Calibration '^'"^---fAr'"'"^^^-'^ RRF: Z'/^/:: ^ >-^^^^2X.->C ; ^ %RSD: Continuing CaDbrarion RRF: %D: Surrogate Recovery _ ^ j / / ^ j . ^ ^ ^ c^ ^ - ^j bn»_).(k3c 10141994 1034 10 Fonn BNA 1.0 302534 Matrix Spike Recovery ( f P-OOd ^ j c^^/Vi RPD: /^ ^ ^ ^ ^ < / y pi 0 ii:^^_zyiiil^'xi'^ :^ ? . ^ ^ % ^ ^ ^ ^ TxyT^y^^'^W^ Sample Results /i *< j w+ft/ J-- . _ c > ^ Q L i^Ff CRQL: c/?<2J. X /?;?VA-f.'o^ '---+0^.-^ , / v / ^ r Detected Result: (^/^ • ^ - ^ / ^ P T 2 J / 0_ . A o r^ ' ^ • > ^ J ^ ^ j u A U . . y j A t . ^ :/rjl , . A TIC Result PT^^'lO ^-'^^'^^y^^ XLO^/I_ fp.fi-^o^i) boa^l.doc 10141994 1034 1 1 Fonn BNA 1.0 302535 HOLDING TIME QUALIFICATION SUMMARY FORM Sample Identification Date Sampled Date Prepared Date Analyzed Prep. Holding Time Analysis Holding Time Qualifier P T I / J J 0 ^ 9 ' / i i ~ ^ - ^ y . / / • _ f - f V 1^-2^-9 9 s-1 ^ A.IA "yg MMl /n$_J_/ioV9'/ Pl'i^/^ /o{A9Y AF P T I o ^ y 'f'^'f'^Y w o to (Jl U) o\ Comments bni_l.doc I0UI994 10J4 12 Fotm BNA 1.0 INITIAL CALIBRATION QUALIRCATION SUMMARY FORM Date/Time Instrument Analyte RF / / uy X RSD / XK.- U ' L^ ^ Samples Affected y^ Qualifier Comments: u> o lo tji bn»_l-doc 10141994 1034 13 FamBNA 1.0 CONTINUING CALIBRATION QUALIFICATION SUMMARY FORM Date/Time Instrument Analyte RF / ^ AM \ > %D ^ , Samples Affected - • " Qualifier Comments: u> o to Ul UJ CO bn«_1 .doc 10141994 1034 14 Fonn BNA 1.0 BLANK SUMMARY FORM Blank ID "^RL-^I Analyte uz.f^^e:zUyLJ\fjALL^ s / / Blank Resuh (units) 'J/ 1 A^i / /^ / ^ Action Level W^o, / L . / / Associated Samples p T i i o , P T ; > / / O , PTI02.1 yh ,S-/^ s p to o IO Ul Ui VO bfia_I.doc 10141994 1034 15 Fonn BNA 1.0 Summary and Conclusions J A L e OJ c i u a . 1 ' T-ie 7. £CKI'y.^f>Uj C ^ » » f A . / ^ c < / ^ ' > C ^ - € . ^ L , y l k c ^ y l ) p U + ^ c l * ^ - l - r . (LJ- A € > C y / ) p / ^ + ^ « - / o - t c /M f ^ g t W y ^ C J - i 7 ^ C c i ' l ^ C S u l - ^ j e ' l c J ' }<^A'A f 1^ Ce. i^ ° ^-,^11 i^C f c 4 uo-irPXc-^ qj^ JMrsc^e-t-cctr/ C ( A ) . ^^^ /AAi- Validator's Signature: ^ X y F y d A i ^ / " X x ^ y . A ^ Validator's Initials: 9AK Validation Date: / 2^/2 Y/ T 9^ QC Reviewer's Signature: ^ > ^ ^ U / < ^ ^ ?"^-'^^-^^<!<,.^ QC Reviewer's Initials r i P P Review Date: / / V / ^ i~ bQa_l.doc 10141994 1034 16 Fonn BNA 1.0 302540 iLul; LOW CDHC- WATER SEMIVOLATILE ORGAMICE A A A I U O ;; I;:;IC/GIJLF._.J3GI.JT1J_._ _.._._ _ '.i;> C o d e ^ S U L Z - C A B & No..;: riLA ;...a:::i S a m p l e ID:; yU.SC>03 L a b F i l e ID;; 3VUWS03L S a m p l e v o l u m e ; ; 'z.A'\:Xl ( m l ) I;;:F' •ID. i i •-! 1-11... 1 .::< • f-^ V , -'•• T " .'-• . . : i J.•'I-l I I-i '.on t r a : : : ; H O r^lO , • 1 0 2 1 l..-oi""p i;;:en "';. r-a" '. v a. c "t- '-.' c j .i. '..i i"t"i oO(.;' SDG N o , )..'<:.. I..IV.' n.'.v.'1... • . • . • . L v ' t : - ' ! I " D a t e Ex t i ' - a c t e c i ;: Da t o M !'"i a. "y"/! e ci;; D:i. lut:!.or"i !"~ac:xc:M'- I •: / r - . i ~ . / • : ; > / 11./ 0 A A. '.'../ V ' y / ' - .1. !"">.:) e . 1 ! . ' . . . I ! 1'.-.•:• 1; u q / i.. ...;rj.f:/...."7 • '. . . : : . • • • " ' . - • 1 t . 1 . '. .' 1" : ' . . . * r ••"ie"U-"i^- uji ier"ic::i ,. • H " " " " ! ' ! e "0 i""'";/.^ O I "rXM"": i.'.i ••i'-l:!. "v. ""c:! '":ie!""i 7. et'"i E ' • .1. •;;;• i::> !::i :"ii:":' i " L : I : "i •: ":::!•"•!'•' :i. "v. ' - " o '•'.'i";!':•:'!""!i:::i i. • • i " 0 O I ' O ^ . < - . - / - - •••" ' • • • • " ""••" - 1 . . . . - I • >-' .'i ')A-f—-AA- ' A. •;:;- ( ::;:••••-.-.• ;""! .1 O ) " 0 < : : ' "-'.. Y \ . 7 . V ' I . ".ll..! '-•""• ''•:'-1" 1.! •::'i"""o"""• ..:>•••• •"',(::,•:;. \ \ y . ; . |:;ir,er"ii: — " ' • ; : ! • • • • i ' ' ' i e " I : . ! " " ! " ; / . : . !""i ;••. - . • . - . • . • . -[.-.A. '• O i " " : .V •""":•:• X a • . . r-,.-..-'.7'" :;,•:::";••"(::.,.L:Ipei""i"'"-:""ici; ••"•-;;;"••• I...: l""i,!. !:::• i"""i:::ii""i a. \ > r; "•: • " a ,i. ei"": o ;;'::"-i"^::: "" :^""f::iai""i:: '.', ;>.!""ie :"•"! o o Y ) -'il -7..'["'., •">•>•".'-. ei""i e 2 ., .;">"-D:i. i'"i:. ••:i-""rvr r;i;;. i..ie!"iC' 3 •""• !"••! :J. "I;. r O ' A r i ";. ;:. .;.;"";!/.". i--i i " : : e ; " " i •:.>, 7 ; '."\ '•:.', \ < " . 7 \ ;:•::• 0200J 302541 ILCU EPA SAMrl. . .-I 1.. • •!• r-^ r.-. !'•! a rn e : ^i^F (" / G U I... I • '•> 0 U T !•: :..-ocie;; G]ll...r L.:ai:>c: S a m p l e ID:; yi;iS^^y!3 FLLl.e I D s SVUr^lSOSL ">a.'y. '\7.1. e Vo.!.ufne 9 •! O _ o ..) „'..) y fl"! .i. .' •|; !•• .:V^'r e d E:! X X I " a C: t V/Olci.fl'it Con trac"t s •;;M-|.;:.i \--\-...>, 1 PT102i SDG No „ ;: "^AlvA, Date Received:- .Ll./.O-aL Da'i:.e b.x"l:.i"actecl;; !!.!•/()'?/ A-iXX-O t"-*ir> a .t.'•/'z ecf;: .....'...-' AA,-.7.--' D X 1 '.X t :i. c:i!"i r" a c: x.'.':>'.-- v. '.:. ... 0 M 1 V -..i A...A.\',V::. \ -!::•/.-"•;• n r •^:A -• .: i..iN ;.. . . X Q / ;... I I 1 ' 1 I';;.'! 1 I...'.,. I •. . " . . ' • • • ' .' t i : •••;• . • ! 1 " •' .7--3A--0 I • - • . , ' - ; i : ....OA--VV~-.:.- 207--0(;i--9^ ^•'0--32 "S •| 93....39....5.. ^.•i3--70--3 .:.>.;. i:.ic-?n :;:c:i'V"u i^'ai"! •.•-.;! •! '•?••"'.'..-':i.i"i :i.'.".••"•::,'*"..c:'.1.coi'ic-:* •' .i • :J. O: t y'. V" .1. i:> I'l x i"i a .\. a t . e •'•?•••• 1...- '"i.:. o 7-.-.-) 7) i"iei"j V .•. •••• |"> i'lei"! •" •r Ici-OI^'Wl'ie •'•[••••i'-i::. '•:. i'"c:iari :i. .L :i. ci e -y--r-i--\ :\. •'•. r'C>-;::.r:ir; -I. n |-.ei"i' • • 7 X . - ' A v - o < y \ < - i ;•• .•,,•:.,!••.••...•• ' 1 !'..•.'! I -.• .'. i..-.' i.. I • •j-'(.•.;, !••, •!•,•.•. .;;; .••, • ; ; j |.-,---| |--, n,v.;,r^, f j | ••)••• :-i!;-:,!^^i .:Vi.i'l •::. r i ; - " " f - ; : ' " ' i c v ••'•'•M"i ••;. ' 7 . 7 ' Y \ r.-; r - i y . - ' D - x - - r 7 - X y 7 •;•.•/•;.:::-:••,•i;.:-,ala '.-.•.' I J 1 . . . -'::.'..<.'\.'';'A. 7>07i :cy.i i::ii'V':.i'la .1.a'V.c:' • •> ,i -.7 -".'..' :•. c: "1.:. o i'"c:i i::'C:'ri:;: A. C! '.'.. \"i o l^eii /: c:i ( a > An x.'xir" ixcofio .i;;!eii:;: C'l C l::i) i^'lcii::'ra'• 'Lhc:'rie B -'-7 :'"i 7. o ( i':.) i'-' 11,.!. 0 ;••• a r'l A A o y-i o B e r I z o ( a ) !"'y;'c-'iie .1 I'lC'ei'iCj V 1 .| :•:;:,. ^:>•••c:c: !• r'--7•"'•-•' 71.7? 'A'A L'en;? ( a .^ •:. A r v c l i i •ac:eric:' HC''I"| ,-:C:i I' C! -I ;"l ,, :i. .) 'i''7';7--.7, (::.,-,(::, Reviiv. 1:: 1 1 0200JC 302542 ILCF LOW CGHC, WATER SEnlVOLATILE ORGANICS ANALYSIS DATA SliEET TENT AT I VELY I DEIMI ;I: F I ED (:;nnpnuNDS > Hame: ^JX^/G[^\Ji,JAQl\T]:• •...ai::i Ciode:: GLJL.F ;...ai:) S a m p l e IDs y j i ^ 0 0 3 '..ab F i l e IDs SVLNS03L,.. liamp'i.e v o l u m e : ?i:.Q..-.Vl (iiiX) l..:cM'i c:c:i-i T i-a'^eci .:.i'i 'i ,::•/c:'c ;.cii'i v-.7 I.ufiit: . ufiiov;' A.'.7\x...i i::.i" i-'i ;;>i^'ir'!r'i...!::. l-iC) , i" i .i.y;;:::;. Con tract: SAS No., :; SDG No, : 9.'ii£5.. Date Received:' 1 l./OI3/9^:'i D .f;-1 e E:«: 11 - a c t e ci - 1:). / 0 9./ 9 •'•' Ua'':.e Mi"!a.i.y2eci;; 12/02/V'''' D::. ]. !..i'V.::. oi'i Fac:'i;.cjr":: :;.,:() •fC:'Ui":Ci c>c.v;i2'vved ^ y - ' — ~A~ Date 020013 302543 I...OW COHC„ WATER ILCB SEnIVn;...ATILE ORGANICS ANALYS: > h-lanie: 'ET,CAGU\Ji_SO\n:}A ..ai:i C o d e : GULF. C a s e No ..ab S a m p l e I D : yN.SOO.:L _.._ ..ab f ' i l e I D : SVUNSOIL.... :5 a i'.'i u 1 e V c:) ]. u lu e : 2 3 Q „ ()^ (, n 1) '• (.in c:eri't r;x'tod Ei!x tr"ac: t Vo!l cifiie Con t r a c t DATA ShE:ET EPA SAr'il'-'L.E NO, T l l l O >00 t. u .i, ,1 SDG N o . : 9^.19.5 D a t e R e c e i v e d : - 1 1 . / 0 5 / 9 4 D a t G E x t r a c x e ci;: 1.;!:./09 /9:;:> D a t e A n a l y z e d : i 2 / 0 2 . / 9 4 D :i. !l. u t :i. o rt F" a c: t o i" :; 1 ., 0 .i'l '1 ec:X:).c)!"i vo.i.unie i -iO, C011i'-'0i...i!MJ C O H C E N ' R A T l O h { u Cl /1....;, i O S - 6 0 - :• • 321--64--7- ....'. : 1 3 1 - 1 1 •• 3- ; 2 0 8 - 9 6--B- ; 6 0 6 ••••20 ••••2- ; y9....09--2 !••'i>eru::i.!. b::.:;; (2^-C h 1 o r'oe t i"iy 1) E 'ci u-:- y- 2--:'':C:'Xi"i'yl :::i:':C:'fiC2;. ..-'. „ '.-A. --07.'-/7)'j.7[. { ^ ••••P'":.!. ui^oDi"ci;:>a;"ie ) —4—l'''letI'lVJ. i:;i'lonc;.:. hi •••• M i x r o c; c:' -• D :i, -• n -• ;••'; - o p y ii. a r i •:;. vi o - -r'lc:' X a c: n .1. c:* i^"c:>e 'c *"ia!*'i..- .i. •;:-.0 p i"iC> '•• C;!"! .7: VA. ' Z y \ A . O r 0 7iO 7:>--r. .7.--('i77 V. rv'v'.i, !"i -a I':' i"! 'u. i"i •:Vi..:, ci'Tt ':•:•: !':e :••: -a c: i';.:. c:' r c:' 7^ -/ o.;. o o c i t x aci :t. cvi t e I r c ? :) 1 •;•::• ! " i c : . : . r " C ? ; : ) 1 •;•::• !"i I.':. o !'"(::>I'l a 7..'.') "-z ,"'a .i.er'! c:' !.:• :J. ri>e "z ry-y A. :''' yZ'. i. a t e - Ac:c • • a;:>|-i l;.••;y!•.erie \.-\ c:e!'i a':' :• x i'lOi i e i:: I t l i:; I , I 'A \ 1.1 t:: l i t OPonoo 302544 ::.:...CC .GW CONC., WATER SEMIVOLATILE ORGi: b Hame: ETC/GIJ:...F SQliTi-i .<:!. l.J K..K.fO,f:.-t " :X:\}:rl^-SX. '...•-;:!. ::.•'.•.•.• .ab Samp].e I D : yNSO.0.1 .aD F i l e I D : iPA SAl-iF'LE ANALYSIS DATA SLEET P T l l l O C o n x r a c t : HI i'^ SDG No., : 9419:i^ Syy NSO:;,L_ jampil.e v o l u m e ; ; 930.^0. (r;L'. ) i:c'!i c:en t !'"axeci E x t r a c : t yc:ii!. cuiie :; ii'l i ec:X:'.ori v o ii.ui:ie : 1 .. 0 ( COiMCii iii: 0 I'll" '• ii:':i. b e n z o f z y r :\7: r>ib--A.- i : ; * • - ; ••, ;.' :i. e T. i' I •';.-•'•.:.::.' r. "z i": a .i. a ':*"":..: i "1.1. o i'"c:! i::i i "ic:'i"! ---z .\. : i •.-..' i ' ^ i ' ^ r ! : ! . • "!exa I ,• ! I ' l ; :"i - H C ! .' 1 I'. •;L'. t y.i, ;::''\-.'i"! z y.!. i::i i'i '<:. I"ia.;, a ;, ,i -.:ii il. c:i"i.!.('•'c'c:'i:'i!''-''''i -.z 'A. ':::• I- • 1 . ',•::..... O O . . ; AOA- ; 207""0S-"9' ; b0'-32-"8 ,' 111..-,' .1.r'icie!"io V ii. . i-;;:,, •.'.- • z.-.:. \ i-"/v"3i'"i( D a t e l ^ e c e i v e d : 1..1./0.'T:2.';:' D a t e Fix ti"ac:'ted :: l.i;../09/.!'>' Da'i:© At'iaiL'/zecL: ii-^:i<i'0i::-;:i'.9 .,.:•::. .1. u A:i.CJH ?• a c:'coi": :.. ,. 0 X .><X^5^ : v.: ! •^n .£Al^ Dale lzJjXLp.1- n 9 n 0 o '^ 302545 ILCF .OW CONC. WATER SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED CONFOUNDS I — I " , A .•". A l v ' ' • • i - !,••• i;:.i- M ;:M-irii- t...'.:. i-lL, b i'^laine: !;;;iC/.GyLF__SOUTH aiij C o d e : GLJLF C a s e No ai:> Saiiiple I D : yNSOO;!, a b F i l e I D : CVyNS01L_ ail'"•'.') ii.e vc'i Ii..i.i'rie: ::)ri c:en'L :''.,,' e c: •': :i. o;'i AZ) i. Cifiie Con t r a c t ; : SAS N o - : (. U .1. ) T l i l O SDG No . : 94.19J:. D a t e i v e c e i v e d : - 1 . 1 / 0 b / 9 4 D a't e liii X 'l. I" a c: •»:. e d : 11 / (i:^9./ 9 4 iJA'l:.e Anal'y'zeci;: 'LA./O'y./'/''••: 'vcn.u'ici iCi'^IC,, KcV'iS-Vvi^ii ^ i / Date 1 l...'AA i £jyy- yyi .llY/'^Y.. 020024 302546 I L C B E P A SArci"l..E N 0 „ LOW C O N C - W A T E R S E r i l V O L A T I L E O R G A N I C S A i - i A L Y S I S D A T A S H E E T J . I M a m e : !n;TC/GlJLF;....SOLm i...ab C o d e : G I J L £ L a b S a m p l e I D : y N S 0 0 2 L a b F i l e I D : S V ! J . N S 0 2 L ?iJ a m p ii. e v c:i il. u m e :: 9 2 5 ^ .0. (fi'i i l ) Con 'i. i^act:; • 1...1' 11...'...'I I .I.n..I o<... i::. X ' c r a c x vc:i.i ci.ii'ie !! Volume: , 0 ( Ci 1 1 (.i:Gi'1F-'0UND S D G N o - D a ' c e i \ e c e i v e d : Da'i;.e E i x t r a c t c ? d r Da'l:e Ai-iaii.yzeci •; D :i. il. u 'v :i. c:i •-•. F" a c: "t o i" ni-i;; ...3.A^.:A. Ciiin'-iCEi''i TTsA r I D ( V.QA'... ) O / l •! « • : : , « / ^ t -l-...^..:;;} l ^ l / ( i ) b / 9 ; l l . / 0 9 . - " 9 ' ; ; i • ; • , : • ) • • / ' ; ' > ; : ' • ; — • , - - - , o — • A . \ ) r . ^ f::;f::;....'7 ,<.!......vii.... 2 0 9 - 9 6 - 9 6 0 A — 2 0 — 2 - i-'i'iorio.i. ; '::i :i. ^;;. f >:•••• Ci i'l .i.o;" c:ie'V. :"!'•;••••.'. ;:::.'^i'lei" _ _: 2 - C i ' i i i , o r o p h e n c j i _ ; /::'-i^ie c i i y .i. ::>i"ienc' . _ _ ! i;:!,, 2 " c:ixyD:!. •::: i. '.i — I..:i"i.1.c:ii"oprc:i;::ia:"ie ) \ 4 -• I •'! e 'l i"! y ii. J:) i'i e n o ii. ; - !'••!••••!'>!:!. V.i''c:i;::c:i--I):i.-•;"!--'•-'z'zzrv/ii.afnii"ie , i"! e X a c: :"i .i. -zz v o e x. i'i a i "i e ', :" :v t.i"c:i::.'e!"i X o i ' i e _ _ : :•::!,,'-2••-c^:i.ii'le'ti'V;/.1. L)I'lei'to.:. i - i:i :i •;::. 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' " c ) •::''. i ! : : .,.::. i ' l C * ' !'..| c;ei"i.;:'.::)i'i •: 7<eii zz Rev--..:J Z, ^.UX.Z<:X>^ Date _ _ _ Z i ^ - ^ K / ^ / r:: i 02002? 302547 ILCC .GW CONC- WATER SE11IVOLATILE ORGANICS AHAI...YSIS DATA SHEET J i-iame : ETC/GyLP....J>.gUT>! _ ..ai::i :iii:ode: GLK^F C a ^ i e i'-ic:'-: HL..A. ..alj S a m p l e I D : yiiiS0.02 .ai:> F i l e I D : i.VyNS02,L i:am!::ile v o l u m e : 9.2^L,.(). (mii. ) i:o!'i c:er'!'Cra'teci E x t r a c : t V o l u m e ; : ii. 0 0 0 C o n t r a c t •-.::.<-It) I'vCJ, l;:.F''A SAI'iF-'Lliii I'-iC • • T 2 1 1 0 SDG I'^lc:. „ : PAJJAJA D a t e R e c e i v e d : - L:Lc!v-:.!ii:2.9•;•; D a t e iiii X 'c i" a c: 'i:ed ;; l..ii./^09/94 D a t e A !"• a ii. y z e cl ;; 1 2 / 0 2 / 9 4 D i ii u 't:;. o n i"" a c "co i" ;: ii.., O , o;"i Vcxi.ufiie , ' ) I I I ! i o F : (.i:l.ii|i•'ii••'l..i^.ir•! i. :OlNC!::.!'^iTKA' ( u c i / L ) I. . " • . . ' • — ' . . . . i ! . . . Q a . i : 0 7 - ' 0 8 " ; i 0 - 3 2 - i 'J...':i.ex ! ''.x.;.:::':'i c i!a.1. a c e -<• ••••I..: i'l.!. cji"o i:>i"ic:i'i y.i. •••• pi'u on '••/}. zz x. i"ie!" ••;•• il u c:i!''e!'t c: ••':•; ,. cv.::':;.!'; ;•. c: "c:'- i-::! —i''ie'ci"iy.i. i::i|"i!:::'i'!c:i.!. •I''i'"i''^i:i. d'Cn;:C;C! :i. :::•:"iO!"!';/...afi'i:i I'le ( i:. ) ..,;.}.•.•. H i-i;-;,f|-M:;) •-; I'lei'l Y .1. -- 7.' i'lO:": '•/.;. o c l i e i " :• z'zj i:iei": z ei"i e , i";,!' c:i'": i'lo'"I c:i .i. ;•• .!. ci.c:ii''ai"i • :i'\,/ i T M - i e - o ,, ZA! • "iJ :i. C: ! i.;. C: i"::) i:jei"i X :i. C: :i. •.ye I'l 7. zx (.::"!. '1 I-l i'l "..i'i i "a c:ei"ie .. t i ".... X 'iii. I. A.-\-:. c i"i'\.C;. i'lCi' X V.l. .J r ' '"i 'C !"ia .i. a CCv "lii' ii. ""I"! ""0 c: 'iy:..' ii. !'•' A •!:. cia ii. a 'Ce "Bei'i x,:;:i ( i::i) I'-il.'. i.c:'i''ai'; ' C i ' i e n e "Be:"! X o (. !••'.) '•" i'. ..xzx !'".a!"i 'C["lerio " .1. i"i ci Cv! lO •. ii. ,i!.::!.,..: :::c; .i' i"' V! "ei'ic:- "l>:i i::ic:'i'i::' \ a.., i'i ; i.'n"i X.rii".;;.,;; ^.,i"|iv:. 1 l..: *. / n Date Ev _ . _ J ^ . A ; _ 02003C 302548 ILCF LOW CONC. WATER SEillVOLATILE ORGANICS ANALYSIS TENTATIVELY IDENTIFIED COMPOUNDS ' '•:' Name: ETC/GULF SOUTH _ Contract: ab Code: GULF Case No-: H.LA._.. SAS No „ s Lab Sample ID: UNS002._ Lai:; F i l e I D : S y y N S 0 2 k ;iiami:>ii.e v o l u m e : 925.-..0. (i'nl) Coi'i c e n ' t ra'teci Ex'^rac:'!: V(::iii. i.i.me: ii.OOO (cc] ) iiin.:iect:i.cj!"i Vc:cl.ume: 'LA\SI ( u l ) EPA SAr'!PL..E NO, DATA SI-iEET P T 2 1 1 0 SDG No . : 94_19 b D a t e l ^ i e c e i v e d : . 1 l / p b . / 9 4 Da'te Ei X 'b"a c t e d : l..ii;./i09;/25. D a t e AI "I a ii. y z e d : IZZ.QX/S.3. D :i. ii. u 't :i. an Fa c:'(:.o i": :i.., () DJ-i: i:sT „ ciONc,. ; \ ' " ] Date ^r-^ Pcv:,:.vP':; Xj ^ £ l < zv/?/. 020031 302549 HLA DATA QUALITY ASSURANCE REVIEW SUMMARY Metals Analysis Case Number: ^ ^ ^ 1 9 ^ Project Number ^ <^,^^^X- / ^ ^ / ^ nxJ.^i c^L •g-*^ •* g o L_d^ Contractor Laboratory: p ^ ^ ^ . X . . / / ^ , . ^ ^ A a.•^ .s Validator f^ /^Kv, \{p.. Validation Date: \ } ^ ^ : i , l 9 ? r ^ 7 QC Reviewer, /v). p L i J I j ^ j Review Date: / - r - 9r Sample Matrix: W«i-f • c r Analytical Methods: X L t ^ o S . O ci^^ T i P l 02. o*^ Sample Designations: p r /III) pTc^iio p r i o r i /^^,C^»/^ 'CD I/ZIZSAJ0) /y/4/J't:?^2^ )A/l/S/Xrv3 Data for the above samples are: Acceptable for use >^ Acceptable for use as qualified Unacceptable for use Is action required by the Project Manager? Yes (No!) nol.o Cnt.y Iff?) w<«i •(^fli.^c^ f^r cti( i^^ioh ^ " ^ c^«i^,Vc^ •.eJ <^' IA.V ^ C C C Comments: 4 CLF Jovv JZ.' WrVi, t i e eKccyt7- w A / c ^ i W C ir(; Q.yi«.ly2.etA U J . i r i p ti,c C i . / ' r o w X Z . / 1 ^ 2 . C ? , Poi^-t- 6 J F''^<^ - - T i ^ e ^ct-/-d^ lA^ckt \rc,llAc^tecy u s i ' ^ ^ fA(^ 6Xj~EP/f C L/^^ fxl'^f-o^^j IDClJ.<l0C 10MI9»«lin3 Fotm MET IJO 302550 DATA COMPLETENESS CHECKLIST X Included, no problems * Included, problems 0 Not included NA Not applicable Quality Control Summary "yC Case Narrative r—Z X Chain of Custody Forms X Cover Page X Holding Times X Inorganic Analysis Data Sheets •y Initial and Continuing Calibration Summary X ICP and AA CRDL Check Standard Summary N A Linear Range Verification Standard Summary •?K Calibration and Preparation Blank Summary X ICP Interference Check Sample Sunraiary •^ Matrix Spike Sunraiary O Post Digestion Spike Sample Summary X IXiplicate Sample Summary X Laboratory Control Sample Summary A//4 Method of Standard Additions Summary •^ ICP Serial Dilution Summary X Quarterly Instnmient Detection Limits Summary X Annual Interelement Coirection Factors Summary X Quaiteily ICP Linear Range Summary ?< Sample Preparation Log Summary X Sample Analysis Run Log Summary Sample Raw Data X ICP Raw Data X GFAA Raw Data X Mercury Raw Data X Cyanide Raw Data Comments: iDet_l jioc 10U19»«lin5 2 FoemMETl.0 302551 SPECFIC COMMENTS REGARDING ANALYSES Chain Of Custody Were samples properly preserved and received in good condition? ( X ^ ^ ^ No Were custody transfers correctly and completely documented? (X^^y> No Comments: Holding Times Were sample preparationsand^ analyses performed within holding times? ( ^ ^ No Conunents: met_l JDC 10U19W1O35 3 FomMETlJ) 302552 Instrument Calibration Were instruments calibrated daily and each time that sample analyses were performed? ( Y M ) No Were the instruments cali^cat^ using the minimum required numbers of blanks and standards? (Yes) No For the GFAA methods was one standard analyzed at the Contract Required Detection Limit (CRDL)? Yes C ^ ^ ^ For the applicable methods did the correlation coefficients meet the minimum requirement of 0.995? ( Y ^ No NA For the cyanide analyses wa&a midrange standard distilled and analyzed? (yes^ No Comments: . * T^ic/U^ c;?i7L o^ TuKw. X s^ou.s IO ujr/l v^A/^i, ^ ^ s C^OSScct 0'-c+ £Xv,y J tA^/L U^ttJ ^ei^t/ V.^i'/'y-f C-i^ » H . T A e XC/M J-to.ie,JeKva(s a v c O^ Io^ ^T^ To^ cn^t^ / o o C F o u i ^ X'/l/'^ Initial and Continuing Calibration Verification Were the calibration standa£sjs and blanks analyzed at the required frequencies? ( Y « > No Were the standard recoveries within QC limits? Yes ( N ^ Comments: T U 7o k-ecc^^ey i ^ y C X K W ^ . * , ^ .'^ tAc / ^ / f / . . / cW/4-c.f/o ^ \MOii 1 ^ 1 . ^ ^ . . ~fk^t.cPo^Cj a l l t^<^J^\+s ^ " ^ - T ^ c ^ yA*.- VAc XK)L cure £^^^l,--(-,'e<y ^J U>^u.rci>lc C K ) cx^J. ce-l( ir^JultJ- [pe(_tuk>c 10U19W1035 4 FormMETl^ 3 0 2 5 5 3 CRDL Standards Were CRDL standards (CRLajid CRA) analyzed at the required frequency? (^eT) No Were the ICP standards ( ^ D analyzed at the required levels? (Yes) No For the low concentration.jne^od, were the CRDL results acceptable? Q f t s ) No NA Comments: Matrix Spike Were matrix spike analyses performed at the correct frequency and on a sample matrix representative of the samples in this SDG? ( ^ s ) No Were field or rinse blanks used for the spike analysis sample? Yes ( ^ Were the matrix spike recoveries within acceptance criteria? Yes (No) Were post-digestion spikes performgd when required? Yes (^No) NA Comments: feciewi <^u<t//-f.'ec/ «j" €^-lIt^cii-.ec/ C T / ( ^ T ) ' met_l JAOC 1014199*1035 5 Fonn MET 1.0 302554 Laboratory Control Sample Were laboratory control acQEje analyses performed at the required frequency? ( J M ) NO Were laboratory control samgie recovery results acceptable? (Yes^ NO Comments: ICP Interference Check Sample Were ICP interference chai^amples (ICS) analysed at the required frequency? (Yes) No Were the ICS recovery crijsrm met? (Ye^) No Were results greater than thfiTOL reported for elements not present in the ICS solution? (YeT) No Were negative results with absolute values greater than the IDL reported for elements not present in the ICS solution? ^ ~ . ( W ) No Were the concentrations of metals in the investigative samples similar to the concentrations of the ICS solution? Yes (No^ Did the sample results require qualification due to interference problems? Yes XNO^ Comments: met_l uloc 10141W4 1035 6 Fonn MET 1.0 302555 Duplicate Sample Results Were duplicate sample an^lj;ses performed at the required frequency? (Yes) No Did the duplicate sample^£s^^te meet acceptance criteria? (^^YM^ NO Comments:. Blank Analyses Were preparation and calijjiation blank analyses performed at the required frequency? ( j e ? ) NO Were elements reported in the blanks at levels above the CRDL? Yes (No^ Were elements reported injlse blanks at levels between the IDL and the CRDL? (Yes) No Were negative results withahgolute values greater than the IDL reported in the blanks? (YeT) No If analytes were reported in the blanks, were the same analytes also reported for the associated investigative samples? (jTeT) No Did the sample results requiiequalificaiion due to the presence of analytes in the associated blank samples? ( ^ y No Comments: yAe. /Vaw c^t/f ^ ; V c vesy^l-^-^ f'^ ^ F l U / O o.^U fAe. i>cyy /I, U i ^ V-cjiAl-p -fov p f ^ l / o kc*.iyc lo Cc ^ ciuu. Ii'-h, ec/ a s x^^-P r i ; ^ c s i-U asjoci\-^ec^ W-^/< C^^ce^rir^pXo'.s. 10U1994 1035 7 Fonn MET IU 302556 ICP Serial Dilution Were serial dilution analysesperformed at the required &«}uency? ( J ^ No For analytes with concentrations greater than 50 times the IDL, were the percent differences within acceptance criteria? ^.,=^ Yes ( N O ) Comments: r / • ' / T U C - S c i r l a l d,'li^fi'o^ KC/wZ-fcr -ioy 0 ^ / c , t ^ i ^ ^ hr^£<y t^ cSi i^)^^ A W ^v>.aKft«H<rj-c Wcirc- o"'+J.'«^e, ilxc c>.cC-e.o-i-i\i^cc li't^.'Ps. Tl^^^-e. P<^*^c. a l l C"c«/c ("LA>^ , M « ^ M e j /1<>~^ A*^c// >^<«»^^A *i e / e i^csuf-fj o.t/-c. (^uc^tf'p.'cef 0.4 e s i i i ^ a - t e J C T ) . GFAAQC Were duplicate injections neiformed for exh GFAA sample analysis? (Ye?) No For results greater than thgJCRDL were the percent RSD results calculated correcdy and within control limits? (YeT) No NA Were the GFAA analytical spike fposj-digestion spike) recoveries within acceptance criteria? Yes ( N O ) If the GFAA analytical spike recoveries were not acceptable, were samples diluted and reanalyzed when required? ^~-..,,^ ( Y C S ) No Was the method of standard additions (MSAi_U5ed for GFAA analysis when required? Yes No (T/zT) When MSA analyses were performed, wereofae^rrelation coefficients and spiking levels acceptable? Yes No \ y i \ ) Comments: )A} o^c +o G F A A c«wtv«./v^/',"cft ^ XPi'Ac i^c co\yev,'cs cfi^ifAc^c fl^c cccc-9P/-cc Her Ck-i'f cir/a. . i k e T«//«'>~',V» ^ c s u l i j kiA.\yc 4> <c n <^UH. Ii'p,'c.ci( a.s f T / ^ X \ A'^iK^Oir.y . Ic&tt SeUi-M t^l^y a.hip{ fUu/ I >oti^. Pis //oV /fu\te l^tfhy y ^I^Sci^'C . ICCM/. s e lein,Xii^ aine/ f Ae<///t-<^v,. P T ^ l l o /'^^f.•'-^*.^^/efl^y a - ^ i-Uuli;(A^. lxl.Xicx. 101419*4 1CB5 8 Fonn MET 1.0 302557 ICP Interelement Correction Factors Were aimual interelement correction factors provided for each inscmment used for sample analysis and were they current? y : ^ / Y M / NO Comments: ICP Linear Ranges Were linear ranges provided for each instrument used for sample analysis and were they current? PYtyy No Was a quarterly linear rangewrification analysis performed and if so, were the results acceptable? ( ^ No For the low concentration method was a linear range standard analysis performed as required, and if so. were the results acceptable? ^,_- ( Y ^ No NA Comments: Log Books ation5-prc r^es) Were all sample preparation^-p^operly documented and performed in accordance with method protocols? No Were all sample analyses properly documented and performed in accordance with method protocols? y^is) No Comments: incl_l.ik>c 10141994 1033 9 Fonn MET l a 302558 Sample Results Were target analytes reported4n the investigative samples? (^efy No Were the quantitated results for target analytes calculated and reported correctly? (Yes) No NA For the applicable methods, were peak integorions performed correctly? Yes No ( ^ ^ Were detection limits provided for the reported target analytes, and if so, were they current and acceptable? /^^fep No Comments: UKtJjjOC 10141994 1035 1 0 ' Fonn MET 1 J) 302559 HOLDING TIME QUALIRCATION SUMMARY FORM Sample Identification Analyte Date Sampled Date Prepared Date Analyzed Analysis Holding Time Qualifier rr/no T.CP^P£SM n-^-'?^ i i - n - f y n - / y ^ 9 ^ ^d//^2.-' P T I O X / MS noy ?Tyi I/O u^ vy JX ? T / 1 1 0 ( y>».H I a • //^y^9 y U-ia^'^y n-ir-"^? PTIO^f /^S//o f t t p 'PTiLilO li/ d/ ScyA<^^Ph 1 4 H ? - ^ l i - f P ^ ^ V t/J^ f\ l l - ^ c f ^ ^ f X M ^ ii-^/o-^Y % i i - ^ - n im- fy /2--02-9y Ui o to Ul O Comments: lncl_l.doc I0I4I994 I03S 11 Pomi MET 1.0 BLANK SUMMARY FORM Ui o to Ul Blank ID T C 0 C C G ^ c r n 2 TCB Pi^to Plu^lc Analyte Beryl hu UlA /4uTt; Uv^Oi^ J - i^oto 7- Mac,i^c.C, IXu^ jzjy 5^ Blank Result (units) 0 . \ u g , / / . 7-3 W z V l . r Uy/Z. / 7 . 0 ty<ylL i.or uy ^ Action Level o- ^ ^ylL Ic. 0 ujL 2 1 1 . y 1^1 L ? r UjcA lS'.:is-^ylL Associated Samples A l l Sc^l^/ffe^ All S o i ^ ^ l c s All Sc< i^^^/cs A l l SCM^r,lcS A l l SCKUy,/cS Qualifier u CPT t\/Ci M C tf CPTU l^^hr u C F T 2\io) l l i o j / Comments: Summary and Conclusions T T k e . iie-uy^ ^ *Ag/ 'Z/'nc. V-e.stAlir ' ^ k ' / ^ T I 11 '^ 0. mcA j - k c O c y y f I /CA i-x^ V-cr^lP foi^ P T ^ l l o kc^^c 4ge», ojoiul/fXec/ ^J" IA i^c/<-•!'<: cPr py -/-^e CKSfoc~i'c-Pe.y( Izilcihh C o^^Cg>^^^*^'<^'/•/'o^/1 J. ^u*.lA-fi'cy a.j e.f f 1't~^ «t f e g/ ^ J ~ / j.ecgi<K.ft» T^^C Se*'i'<il oli/(^t,'oto heAn lis Pi,y i-kc/e c/g^t^en-fcT »^f «^c oi^Ps/cfc a.cc-e./ij-Ci t^cc Cl^.'j-e. ie;'a. lOue. -jo ^ f^ A A c{VKulyi,'c<K\ i o ' k ^ \rc.ci9\/e.\r,'cs o^-^Si'dr i U c ^ccgB fAKff c l^.'^^r• t^i (^ . jkc To//tf 1.^,'lAi^ »^e.rt</fj Acting L^ct^ CfuuHh'^c/ ^ / ^ €:.rPii^c^fcc^ C T / C A I I P T I ^ 2 1 /4kvf. l^c/hy , I c c ^ p j , T C l c U\, u(i^ Ane/ ikc.llAo>.t/^ -f-t P T l( l o L c * . ^ eKi^y fk<* I li'iAl^r.-^ , P T ^ l l o An^^/^»^o^^y , /Ct<^?/ <^^M^ t U u I I j t ^ t ^ . 75 TX ^ 71 Validator's Signature: Validator's Initials: i!?^l< Validation Date: p ^ ^ ^ / f ^ j ^ QC Reviewer's Signature . /?vyu<^ ^- T^y^yc^^ QC Reviewer's Initials H PP Review Date : ly^/^r iDel_l,doc 10U19W 1035 13 Fonn MET IJ) 302562 U.S. EPA - CLP , EPA SAMPLE NO. 1 INORGANIC ANALYSIS DATA SHEET ab Name: PACE Contract: Lab Code: GULF Case No.: HLA SAS No.: Matrix (soil/water): WATER Level (low/med): LOW % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L I PT1021 I I I SDG No.: 094195 Lab Sample ID: UNS003 Date Received: 11/05/94 1 1 ICAS No. 1 1 17429-90-5 1 17440-36-0 17440-38-2 17440-39-3 17440-41-7 17440-43-9 17440-70-2 17440-47-3 17440-48-4 17440-50-8 17439-89-6 17439-92-1 17439-95-4 17439-96-5 17439-97-6 17440-02-0 17440-09-7 17782-49-2 17440-22-4 17440-23-5 17440-28-0 17440-62-2 17440-66-6 157-12-5 1 Analyte Aluminum Antimony Arsenic Barivim Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc 1 Cyanide Concentration 145 1.4 8.6 10.6 0.10 3.3 50700 4.5 9.5 11.9 516 0.92 23300 315 0.20 25.8 1 30800 2.0 1 4.1 513000 1.5 1 5.9 1 278 1 10.0 1 C| 1 1 Q 1 1 Bl UINW T Bl Bl Ul Ul IE T Ul Ul Ul 1 B|W |E IE T 7 T Ul Ul 1 UINW 7 Ul 1 1 lUINWT lui 1 lui 1 1 M 1 P 1 F 1 F 1 P 1 F 1 P 1 P 1 P 1 P 1 P 1 |P 1 F 1 P 1 P 1 |CV| |P 1 |P 1 |F 1 |P i |P 1 |F 1 |P 1 P 1 |AS| l_l Color Before: COLORLESS Color After: COLORLESS Comments: Clarity Before: CLEAR Texture: Clarity After: CLEAR Artifacts: NO VALIDATED Reviewed By ^ . X ^ ^ ^ Z ^ ^ ^ : : ^ ^^'< Date.., /" ^~^-^ FORM I - IN ,02563 ILM02.0 080004. .jah Name: PACE Lab Code: GULF Matrix (soil/water): WATER Level (low/med): LOW % Solids: 0.0 U.S. EPA - CLP 1 INORGANIC ANALYSIS DATA SHEET Contract: Case No.: HLA SAS No.: EPA SAMPLE NO. I I I MS1104 I SDG No.: 094195 Lab Sample ID: UNS004 Date Received: 11/05/94 Concentration Units (ug/L or mg/kg dry weight): UG/L 1 1 1 I I I I ICAS No. 1 Analyte |Concentration|C| Q |M | 1 1 1 M i l 17429-90-5 1 Aluminum | 91.2 |B| |P | 17440-36-0 1 Antimony 1 1.4 |U|W T IF | 17440-38-2 1 Arsenic | 8.5|B|WT |F| 17440-39-3 1 Barium | 12.5 |B| |P 1 17440-41-7 IBerylliumI 0.10 |U| |F | 17440-43-9 1 Cadmium I 3.3 IU| IP 1 17440-70-2 1 Calcium 1 18500 | |E T |P i 17440-47-3 1 Chromium I 4.5 |UI IP 1 17440-48-4 1 Cobalt | 9.5 |U| |P I 17440-50-8 1 Copper | 11.9 |U| |P | 17439-89-6 I Iron j 339 | I |P I 17439-92-1 ILead | 0.80 |U|W T |F | 17439-95-4 |Magnesium| 20700 | |E J |P | 17439-96-5 |Manganese| 720 | [^ T IP 1 17439-97-6 |Mercury 1 I I I I 17440-02-0 INickel 1 25.8 |U| |P | 17440-09-7 IPotassiumI 28500 | | |P | 17782-49-2 |Selenium | 2.0 |U[W o" |F | 17440-22-4 iSilver | 4.1 |U P | 17440-23-5 1 Sodium j 464000 j | |P j 17440-28-0 IThallium 1 1.5 |U|W T |F j 17440-62-2 (Vanadium | 5.9 |U| |P | 17440-66-6 IZinc j 386 j | |P | 157-12-5 1 Cyanide j 1 L 1 1 1 1 1 I I I I Color Before: COLORLESS Color After: COLORLESS Comments: Clarity Before: CLEAR Texture: Clarity After: CLEAR Artifacts: NO V.ALJP.ATED Reyi27/ed Sy ^^^^-^X/^- ^'^^^^-^^^ /PAK Date„ /- r - t r FORM I - IN 302564 ILM02.0 A ^ ^ ry f. t - f O U.S. EPA - CLP EPA SAMPLE NO. I PTlllO INORGANIC ANALYSIS DATA SHEET Ab Name: PACE Contract: | | Lab Code: GULF Case No.: HLA SAS No.: SDG No.: 094195 Matrix (soil/water): WATER Lab Sample ID: UNSOOl Level (low/med): LOW Date Received: 11/05/94 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L ICAS No. 1 17429-90-5 17440-36-0 17440-38-2 17440-39-3 17440-41-7 17440-43-9 17440-70-2 17440-47-3 17440-48-4 17440-50-8 17439-89-6 17439-92-1 17439-95-4 17439-96-5 17439-97-6 17440-02-0 17440-09-7 17782-49-2 17440-22-4 17440-23-5 17440-28-0 17440-62-2 17440-66-6 157-12-5 Analyte Alviminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Cyanide Concentration 252 1.4 3.8 10.6 0.10 3.3 6040 4.5 9.5 11.9 56.0 0.80 295 5.5 0.20 25.8 1 1410 2.0 1 4.1 1 5680 1 1.5 5.9 1 17.7 10.0 C Q U N T u u u u E T u u u UB1 U u w B E T 7 B E T u U B U N r U IU NW T U .31 Of U 1 M 1 p 1 F 1 F 1 P 1 F 1 P 1 P 1 P 1 P 1 P I P 1 F 1 P 1 P 1 CV| P 1 P 1 F 1 |P I |P 1 |F 1 P 1 P 1 ASl Color Before: COLORLESS Color After: COLORLESS Comments: Clarity Before: CLEAR Texture: Clarity After: CLEAR Artifacts: NO VALIDATED Reviewed 3y ^^^--^^V^ ^X^^/^Az/fM Date ^—lz£iXl£ FORM I - IN 302565 ILM02.0 0S0005 U.S. EPA - CLP EPA SAMPLE NO. PT2110 INORGANIC ANALYSIS DATA SHEET ab Name: PACE Contract: 1_ j Lab Code: GULF Case No.: HLA SAS No.: SDG No.: 094195 Matrix (soil/water): WATER Lab Sample ID: UNS002 Level (low/med): LOW Date Received: 11/05/94 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L 1 i 1 1 ICAS No. 1 Analyte |Concentration|C 17429-90-5 1 Aluminum | 641 |_J 17440-36-0 1 Antimony I 1.4 |U 17440-38-2 1 Arsenic I 21.6 \_\ 17440-39-3 IBaritim 1 19.2 IB 17440-41-7 IBerylliumI 0.10 IJBT 17440-43-9 1 Cadmium | 5.1 | 17440-70-2 1 calcium 1 245000 | _1 17440-47-3 1 Chromium 1 17.3 I 17440-48-4 ICobalt 1 9.5 |UJ 17440-50-8 1 Copper 1 15.9 |BJ 17439-89-6 1 Iron 1 3230 1 17439-92-1 ILead 1 9.7 | 17439-95-4 IMaqnesiuml 29100 1_| 17439-96-5 1 Manganese 1 1090 |_J 17439-97-6 IMercury 1 0.20 IU 17440-02-0 INickel 1 34.1 IB 17440-09-7 IPotassiumI 30300 | 17782-49-2 1 Selenium 1 20.0 |U 1 1 Q IM 1 1 1 IP 1 NW J- IF 1 IF 1 IP 1 0( IF 1 IP 1 E 7 IP 1 IP 1 IP 1 IP 1 IP 1 W J IF 1 E T IP 1 E T IP 1 icvi IP 1 IP 1 N J IF 1 17440-22-4 ISilver 1 4.1 |U| |P I 17440-23-5 1 Sodium | 501000 | | |P | 17440-28-0 IThallium 1 1.5 lUINWO" IF | 17440-62-2 1 Vanadium | 12.7 |B| IP 1 17440-66-6 IZinc | 1460 1 j |P 1 157-12-5 1 Cyanide I 10.0 |U| |AS| 1 1 1 I I I I Color Before: COLORLESS Color After: COLORLESS Comments: Clarity Before: CLEAR Clarity After: CLEAR Texture: Artifacts: NO VALIDATED Reviewed 3y ^^'^^--^^W^"^ ^'^^i/^^yk A/?AC Date L£zZ£ FORM I - IN 302566 IIM02.0 080006 HLA DATA QUALITY ASSURANCE REVIEW SUMMARY Semivolatile Organic Compound Analysis Case Number: Site: Contractor Lab: Validator: QC Reviewer: Sample Matrix: Analytical Method: 94195 Project Number: Island Chemical Company Pace Incorporated, New Orleans Kirsten Meier h.n.'/Cj^ Validation Date: Review Date: Water SW 846, Method 8270, Pyridine only 29872 10.1 Januaiy 6, 1995 i/f/<tr Sample Designations: Client ID (Lab Sample ID) PT-1/110494 (UNS-001) Pl'-2/110494 (UNS-002) Fr-102/110494 (UNS-003) Data for the above samples are: [ ] Acceptable for use [x] Acceptable for use as qualified [ ] Unacceptable for use Is action required by the Project Manager? Yes No[x] Comments: The investigative samples were validated in accordance with the "USEPA CLP National Functional Guidelines for Organic Data Review", February 1994. 302567 boi.elec.ll 1ZNI994 I 3 » Fonn BNA l.l CueNvnber M H PnjeolNii^ier 'JUtri 10.1 Sle ID: bkmd CfamicBl Coo^Biiy DATA COMPLETENESS CHECKLIST [x] Included, no problems [""j Included, problems [O] Not included [NA] Not applicable Quality Control Sununary X Case Narrative * Surrogate Recovery Summary * MS/MSD Sunmiary _x Reagent Blank Summaiy X GC/MS Instrument Performance Summary Sample Data X Chain of Custody Forms * Holding Times * Organic Analysis Data Sheets X Quantitation Reports * Reconstructed Ion Chromatograms X Mass Spectra Printouts NA TIC Mass Spectra Library Searches Initial Calibration Data X Calibration Summary X Standards Quantitation Reports * Standards Reconstructed Ion Chromatograms Continuing Calibration Data X Calibration Summary X Standards Quantitation Reports * Standards Reconstructed Ion Chromatograms * Intemal Standards Summary Instrument Performance Data * DFTPP Mass Spectra X Reconstructed Ion Chromatogram X DFTPP Mass Listings bm ekc.ll ' 2 » " « 15» 2 Fom. BNA l.l 302568 CueNiBtef: MI95 PnieclNuiter: 2W72 10.1 Sic ID; bkiid Oirtmflil Compny Reagent Blank Data X Organic Analysis Data Sheets X Quantitation Reports * Reconstructed Ion Chromatograms X Mass Spectra Printouts NA TIC Mass Spectra Library Searches Matrix Spike and Matrix Spike Duplicate Data * Organic Analysis Data Sheets X Quantitation Reports * Reconstructed Ion Chromatograms Laboratory Control Sample NA Organic Analysis Data Sheets NA Quantitation Reports NA Reconstructed Ion Chromatograms NA Mass Spectra Printouts NA TIC Mass Spectra Library Searches Comments: The Reconstructed Ion Chromatograms showed peak areas from the scan 350 and higher, while the compound of interest. Pyridine, appears at aproximately scan 210. A visual comparison of data for Pyridine was not possible. bni_elcc.ll "2N'9»« "SM 3 Fonn BNA l.l 302569 Cue Hitrher. 94195 PrajeetNiaker 29(72 10.1 Sle ID: bhnd CteinKml Can^may SPECinC COMMENTS REGARDING ANALYSES Chain Of Custody Were samples properly preserved and received in good condition? Yes[x] No Were custody transfers correctly and completely documented? Yes[x] No Comments: None Holding Times Were sample extractions performed within holding times? Yes[x] No Were sample analyses performed within holding times? Yes[x] No Comments: The associated matrix spike samples were extracted on 11-23-94, exceeding hold time by 12 days. No qualification of data. Instrument Tuning Did the instrument performance checks meet acceptance criteria? Yes[x] No Were samples analyzed within the 12-hour period following an acceptable performance check? Yes[x] No Conmients: Tune on 11/9/94, 9:26:00: For obtaining the mass spectrum, the background subtraction included a small peak. The analyst should insure, that only baseline scans are used for background substractions. No qualification of data. Tune on 11/29/94, 13:42:00 : The baseline is not visible on the Ion Chromatogram. It is assumed, that it is identical to the x- coordinate of the chromatogram. No qualification of data. b n elec.ll ' ^ ' ^ '530 4 Fom. BNA 1.1 302570 CaKNiMiter: 94195 PisjeoNunhen 29872 10.1 S K ID: bhod OmiKsl Compny Initial Calibration Did the laboratory meet the method requirements regarding the minimum number of calibration standards for an acceptable initial calibration? Yes[x] No Did the initial calibration curves meet the linearity criteria for maximum percent relative standard deviation (%RSD)? Yeslx] No Did the initial calibration meet the minimum relative response factor (RRF) criteria? Yes[x] No Comments: This review is onJy based on the evaluation of Pyridine. The iiutial calibration QC criteria were met for Pyridine. As stated previously, the chromatograms do not show the scans for Pyridine and N-Nitrosodimethylamine, a visual evaluation was not possible. The possibility that the injection peak or other factors might have interfered or affected the quantitation of the target analyte,Pyridine, caimot be evaluated. The concentrations of the initial and continuing standards are listed in the header as twice as high as the concentrations used in the quantitation section of the data. The injection volume is not clearly defined, but appears, that the same amoimt of 1.0 ul was used for standards and samples. Since no detections of Pyridine were reported, no qualification of data is necessary. Continuing Calibration Did the continuing calibration curves meet the linearity criteria for maximum percent difference (%D)? Yes[x] No Did the continuing calibration meet the minimum RRF criteria? Yes[x] No Comments: This review is only based on the evaluation of Pyridine. The continuing calibration QC criteria were met for Pyridine. As stated previously, the chromatograms do not show the scans for F'yridine and N-Nitrosodimethylamine, a visual evaluation was not possible. The possibility that the injection peak or other factors might have interfered or affected the quantitation of the target analyte^Pyridine, cannot be evaluated. bnaelec.n IZ^l**" '530 5 Form BNA l.l 302571 Caae Number 94195 PnigeelNimben 29872 lO.I Sle ID: bbnd Cbemioel Caapnir Surrogate Recoveries Were the surrogate spike recoveries within acceptance limits? Yes[x] No If the spike recoveries were imacceptable, were the samples reanalyzed? Yes No NA[x] Comments: The lab provided a summary of the surrogate recoveries and the recoveries were Within the lab specific windows. The concentrations of the surrogates used were not provided and recalculation of data was not possible. No qualification of data. Matrix Spikes Were matrix spike analyses performed at the correct frequency and on a sample matrix representative of the samples in the sample delivery group (SDG)? Yes[x] No Were the matrix spike recoveries and relative percent differences (RPDs) within acceptance criteria? Yes[x] No Comments: The matrix spikes were performed with a 8270 mixture, which does not include Pyridine. The lab provided a summary of matrix spike recoveries, recoveries were within 8270 QC limits. The concentration of the added matrix spike solution was not provided and recalculation of the recoveries was not possible. No qualification of data. Internal Standards Were the intemal standard areas and retention times within the required limits? Yes[x] No If the internal standard requirements were not met, were the samples reanalyzed? Yesx[x] No NA Comments: No intemal standard area and retention time summaries were provided. The associated peak responses were compared and the QC criteria were met. No qualification of data. bm.ebc.ll 12291994 1330 6 Fom. BNA l.l 302572 OneNinber 94195 PntjectNunlier 29872 10.1 Sle ID: blud fhcmiwl Con^Kqr Blank Analyses Were the appropriate number of blank analyses performed? Yes[x] No Were analytes detected in the blanks? Yes No[x] If analytes were detected in the blanks, were the same analytes detected in the associated investigative samples? Yes No NA[x] Did the sample results require qualification due to the presence of analytes in the associated blank samples? Yes No[x] Comments: This review is only based on the evaluation of Pyridine. The target analyte was not detected in the associated prep blanks and qualification of data was not necessary. Laboratory Control Samples Were laboratory control sample (LCS) analyses performed at the correct frequency? Yes No NA[x] Were the LCS recoveries within acceptable limits? Yes No NA[x] Comments: Not applicable. bra elec.ll '22«"»< '530 7 Fonn BNA l.l 302573 Cue NtBten 94195 PiojeclNunAer 29872 10.1 Stt ID: bbmd OwnW^l Ccevfmny Sample Results Were target analytes reported in the investigative samples? Yes No[x] Were mass spectra provided for the target analytes detected in the investigative samples? Yes No NA[x] Were the mass spectra of acceptable quality and analytes correctly identified? Yes No NA[x] Were the quantitated results for target analytes calculated using the appropriate intemal standards and were the relative retention times (RRTs) acceptable? Yes[x] No Comments: As stated previously, the chromatograms do not show the scans for Pyridine and N-Nitrosodimethylamine, a visual evaluation was not possible. The possibility that the injection peak or other factors might have interfered with or affected the quantitation of the target analyte, Pyridine, cannot be evaluated. Therefore, the reported results for Pyridine in the investigative samples were qualified as estimated (J). Tentatively Identiiled Compounds Were tentatively identified compound (TIC) searches conducted for all sample analyses? Yes No NA[x] Were non-target peaks evaluated as required? Yes No Were the TIC mass spectra, searches, identifications, and quantitated results acceptable? Yes No Comments: Not applicable. bm_elec.ll 12291994 1330 g /.»F*Bn*Nii-n 302574 Cue Nunber 94195 PiDJeaNinber 29872 10.1 She ID: bhud OnnicMl Cnwqiiy Log Books Were sample preparations properly documented and performed in accordance with method protocols? Yes[x] No NA Were sample analyses properly documented and performed in accordance with method protocols? Yes[x] No Comments: None bra_elec.il 12291994 1330 Fonn BNA 1.1 3 02 57 5 • C u e N i B t e r 94195 PrcjectNunber. 29«72 lO.l Sle ID: bbnd Chrmiml Coopngr Calculation Checks Instmment Tuning m/z of 127, 11/16/94, 11:20:00, BPl 11694D Relative Abundance: 864/1758x100%=49.147 Initial Calibration Std 50, 11/9/94, D5-Phenol RRF: 16823*20/10117/25=1.330 %RSD: 0.071/1.309*100% =5.422 Continuing Calibration Std 50, 11/16/94, Pyridine RRF: 10826*20/9825/25=0.882 %D: (0.918-O.882)/0.918*100% =3.922 Surrogate Recovery Concentration used unknown bm_elec.ll 122^1994 1330 1 0 Fom. BNA l.l 302576 CueNister 94195 PisjeolNimber 29872 10.1 Sle ID: bbnd CbonicKl f.i»i^»ny Matrix Spike Recovery Concentration used unknown RPD: Sample Results CRQL: Water sample Detected Result: No detection TIC Result Not required bra_elec.ll ' ^ ' » « ' 5 3 0 11 Fonn BNA 1.1 302577 Cue Number: 94195 ProjcaNumher: 29»72 10.1 Sile ID: liluid Chemical Ccxnpany HOLDING TIME QUALIFICATION SUMMARY FORM Ui o to (Sl 00 Sample Identification Date Sampled Date Prepared Date Analyzed Prep. Holding Time Analysis Holding Time Qualirier Comments: None t«w_eWro.ll i:?9l9*) I3.V) 12 Fonn BNA l.l C u e Nimber: 94195 ProjeclNumher; 29872 10.1 .Site ID: bland Chemical Comfttny INITIAL CALIBRATION QUALIFICATION SUMMARY FORM Date/Time Instrument Analyte RF RSD Samples Affected Qualifier Comments: None LO O to cn •J VD lra_eleo.ll I229IW4 1330 13 Cue Number: 94195 ProjcclNumber: 29g72 10.1 Sile ID: Island Chemical Company CONTINUING CALIBRATION QUALIFICATION SUMMARY FORM Date/Time Instrument Analyte RF %D Samples Affected Qualifier Ui o to Ul 00 o Comments: None hra_eWc.ll 12291994 1530 14 Forni BNA I. Caae Number: 94195 ProjeclNumber: 29»72 I O.l Site ID: bbuid Chemical Company BLANK SUMMARY FORM Blank ID Analyte Blank Result (units) Action Level Associated Samples Comments: None CJ o to cn 00 H bra_elec.ll ll;919+l I5X) 15 Form BNA 1.1 Cue Ninber 94195 PraJDctNufaer 29872 10.1 Sle ID: b i n d CVmkal Caapenf Summary and Conclusions The analytical results for Pyridine are acceptable for use as qualified. The reported results for Pyridine in the investigative samples were qualified as estimated (J) since a visual comparison of the peak acquisition was not possible. Validator's Signature: lXrjl<AuL. Hju'^y Validator's Initials: -JI P \ Validation Date: l ~ ( , ~ ^ 5 QC Reviewer's Signature: ^ T u ^ c ^ C ^ >> ^ ' ^ ' C l ^ ^ ^ QC Reviewer's Initials: P I P P Review Date: I - J - f f bra_elec.ll 12291994 1330 16 Fora. BNA l.l 302582 L ENVIRONWENTAL LABORATORIES REPORT OF LABORATORY ANALYl Analytical Results - Semivolatile Organics by Hethod 8270 Harding Lawson Associates Client ID: PT-1/110494 Description: NA Sample ID: UNS-001 Matrix: Water Wet/Dry Basis: NA Collected: 11/04/94 Received: 11/05/94 Prepared: 11/11/94 Analyzed: 11/16/94 Percent Moisttire: NA CAS No. 110-86-1 P a r a m e t e r Pyridine Concentration, ug/l (pvh) Sample ND 3 Blank ND Detectio Limit 10.0 ND-Not Detected at or above the detection limit stated. VALIDATED Reviewed By l^OJ^Uiy, HAUX Date • ' - 6 - 9 ^ 302583 161 James Drive West. Suite 100 St. Rose. LA 70087 TEL' S04-469-0333 FAX. 504-469-0555 An Equ3l Opportunity Employer 201 i.TL^' i H C O R P o n a T c o ENVIRONMENTAL LABORATORIES REPORT OF LABORATORY ANALYSIS Analytical Results - Semivolatile Organics by Method 8270 Harding Lawson Associates Client ID: PT-2/110494 Description: NA Sample ID: UNS-002 Matrix: Uater Wet/Dry Basis: NA Collected: 11/04/94 Received: 11/05/94 Prepared: 11/11/94 Analyzed: 11/16/94 Percent Moisture: NA CAS No. 110-86-1 P a r a m e t e r Pyridine Concentration, ufn/l (ppb) Sample N D 3 Blank ND Detection Limit 10.0 ND-Not Detected at or above the detection limit stated. VALIDATED Reviewed By Date /- C - f € 302584 161 James Drive West. Suite 100 St Rose. (.A 70087 TEL: 504-469-0333 FAX: 504-463-0555 An Equal Opportunity Employer 202 APPENDIX D Data Validation • Soil Samples 302585 ~ r HLA DATA QUALITY ASSURANCE REVIEW SUMMARY VolaliJe Organic Compounds Analysis Case Number: ^ ^ 0 \ 0 Site: ^ ^ j U r J i t j U ^ y ^ u U Project Number 2 ^ ? 1 Z , ) 0- Z t.^/Cyir\AsinJl Contractor Laboratory:^ p ^ ^ g ^SU/A VaUdaor Tf. l A t f J ^ j l ^ r=f Validation Date: 3 \ z i ^ \ m <:ifZ Reviewer ^?>uXc/(^>.^ 'P'. ^y^^-P^yX Review Date: ? / ^ ? y ? T ~ Sample Matrix: :>So-UL^ ( I Z ) Analytical Method: E:PA C L P nAa^yv<xPj^.^DvJ Sample Designations: dZooOi r.^^07,7. C^ZZ^ZL \ ) \ 0 0 0 \ Pll2l4- 012,124- DZOOZD PZl^ZI D^oon^ D:2>I7I<? ei^^io E:IZOZ-2. Data for the above samples are: Acceptable for use y Acceptable for use as qualified Unacceptable for use Is action required by the ^pjer.t Manager? Yes (JioJ Comments: P oJCouJUO-e-T_e J L A ^ t l l t J L i C t c - ^ l - a ^ ^ ^ M ^ J b M ^ [ i ^ ^ P f ^ ( V K ^ A C I ^ VCM_t.doc 1014199*1032 Forei VOA 1.0 3 0 2 5 8 6 DATA COMPLETENESS CHECKLIST Included, no problems Included, problems Not included NA Not applicable Quality Control Summary X Case Narrative X Surrogate Recovery Summary X MS/MSD Sunmiary TJf- Reagent Blank Summary • ^ GC/MS Instrument Performance Summary Sample Data • ^ Chain of Custody Forms jl6- Holding Times X Organic Analysis Data Sheets yC Quantitation Reports yC Reconstructed Ion Chromatograms X Mass Spectra Printouts X TIC Mass Spectra Library Searches Initial Calibration Data - ^ Calibration Summary X Standards Quantitation Reports ')C Standards Reconstructed Ion Chromatograms Continuing Calibration Data • ^ Calibration Summary X Standards Quantitation Reports X Standards Reconstructed Ion Chromatograms - ^ Intemal Standards Summary Instrument Performance Data X BFB Mass Spectra X Reconstructed Ion Chromatogram X BFB Mass Listings voa_l.doc 10U1W4 1032 Form VOA Ml 302587 Reagent Blank Data ^ Organic Analysis Data Sheets X Quantitation Reports X Reconstructed Ion Chromatograms X Mass Spectra Printouts X TIC Mass Spectra Library Searches Matrix Spike and Matrix Spike Duplicate Data X Organic Analysis Data Sheets X Quantitation Reports A Reconstmcted Ion Chromatograms Laboratory Control Sample ]syV Organic Analysis Data Sheets f4|^ Quantitation Reports fslAr Reconstruaed Ion Chromatograms f\lA Mass Spectra Printouts f4/\ TIC Mass Spectra Library Searches Conmients: vo._l.<Joc Fonn VOA 1.0 10U19M1032 T, 302588 Harding Lawson Associates CUCCT r\c . . , ^ ^ Engineering and ^ " ^ ^ ' ^ ^ ; = ; = . : • Environmental Services JQQ ^ Q PROJECT . U ^ ^ U t V U ^ C J U y n u L ^ A J ^ C j y t ^ ^ ^ ^ d / h ^ ^ COMPUTED BY ^ . u f c f c t ^ SUBJECT Pfljbcu U/iiiiJta'tCo-'K- CHECKED BY Z^So/oizo^S' S0O\Z0 \JQA"00\ 5BV>3/0-zl0iU>'i^ Vl>oooZ. S/diA'OOZ- sd^i/zD-zt'/oii'j^f eri2.oz2- sia^-oDz- SBVZlo.D-Zoloim^ VZoozo \Jq^''003 S?>B\', 0.^-2.01,01 m6^ e \ 0 5 W VSC-0D2- ?.2>9t>lo\z^')6 SOV\Zf \I6%-00\ 53P)/o-i/oizf^^ P\oooi \]SX-ooz 5?>V\j]Z-\^lo\Z^^b V\\Z\^ V5X-003 5^Pl/z2.'24/o|2f^5' Pl222'4- \ISX-00i+ S??Cz/o-lloi3 0^f CZODv\ VTX-^Ol 53c,-zlto'2iloi3ooff c^^o^•^- VTX-oot. SBCZJld^-TLJOi^C^e' C2Zi\-ZG VTX-OO^ Rd5oloi30'^5' R&sool VTX-rotf HA] 302589 SPECinC COMMENTS REGARDING ANALYSES Chain Of Custody Were samples properiy pr^wved and received in good condidon? / T e ^ No Were custody transfos coneedy and completely documented? /Yes) No Comments: fjiA^Tr Ce-frfiz^^ JU^t^«-e j ^ i i / k i ^ i ^ ^ 0 / V ^ f t ^ AJI^ttUA-tA C w M ^ Y ^ y\^\l(nMx/^u^ Holding Times Were sample analyses peilgiined within holding times? ^ y ^ No Comments: OSSL j/^rQrr^rwC&lA ( X ^ A J ^ ^ - V ^ ' ^ ^ J-^'^"'^^'^-^ Instrument Tuning Did the instrument perforpjance checks meet acceptance criteria? CYBS^ NO jLj.AA;t^:rfx J^X^WWL iih Were samples analyzed wkhio the 12-hour period following an acceptable performance check? (Jfes} No Comments: (X C oJUM.^^<dC^^^p^ J t ^ ^ l * - x JuOtlA^ ' W X C L J J ^ J A ^ Z M ^ Y Y U ^ ^ j l ' ^ / l 7 ^ voi_l.doc 10U19M 1032 Fonn VOA li) 3 0 2 5 9 0 Initial Calibration Did the laboratory meet the method requirements regarding the minimum number of calibration standards for an acceptable inidal caIibratiQA?>. /Yes) No Did the initial calibration curves meet the linearity criteria for maximum ()ercent relative standard deviation (%RSD)? ^ - x Yes ( N O ) Did the initial calibration ^ipeet the minimum relative response factor (RRF) criteria? Yes) No Comments: j ^ e A > - l ^ ^ (l^eryy^Sr^t-^AyJlj^ ^ d ^ ^ S V . A M J ^ ^ - ^ ^ ^^^Ut^^ch^ : 0 - A Y \ . Continuing Calibration Did the continuing caUbration cur^e»>meet the linearity criteria for maximum percent difference (%D)? Yes /^No) Did the continuing calibration^meet the minimum RRF criteria? ( 3 ; No Comments: ^^^^^^e/uX Qj^yr^^^fM^/JU- :M--^^^^><Ji % 0yVtd^^^^^ ^ k M ^ J ^ - M j ^ i ^ \)oJjjS^ - ^ I0P >^^^ MJU^^ 1Z^%J^ (JJU-v^-CtL^tu^. vo«_l.doc Fonn VOA ijO 1014199*1032 5 3 0 2 5 9 1 Surrogate Recoveries Were ti>e surrogate spike recoveries within acceptance linuts? /Yes) No If the spike recoveries were unacceptable, waf&>the samples reanalyzed? Yes No ( N A ) Comments: yW^ Matrix Spikes Were matrix spike analyses performed at the correct frequency and on a sample matrix representative of the samples in the sample deUvcfv group (SDG)? (YeO No Were the matrix spike recoyenes and relative percent differences (RPDs) within acceptance criteria? (Yes) No Conunents: VVl6/h^5P OAvuJ-^-f^Jy^rtJu^ jQV\SU\yr^Mi ©rtjAM)up^ C2000 Internal Standards Were the intemal standard areas apdjEtention times within the required limits? Yes r N o ) If the intemal standard reqiuF^ents were not met, were the samples reanalyzed? (Yes) . No NA Comments TI-HL 0<AJUK. C^^xA^A.^ clfcEruA€/mfi4^-€_- d ^ J<ATI^.Mcb^^rxB^ P2>0 00'Z-. T J U - J^OAV^V^^ JUO^!U^ y\XAA^jJ->j^pfJ<- 6•^ife^^ J W ^ A A V ^ voa.Ldoc .. *> A o r- rt *^ 10141994 1032 ' 5 3 0 2 5 9 2 Blank Analyses Were the appropriate numteLQf blank analyses perfoimed? /Yes} No Were analytes detected in the-blanks? (Yesj No If analytes were detected iijjhfi blanks, were the same analytes detected in the associated investigative samples? /Yesj No NA Did the sample results lemjiie qualification due to the presence of analytes in the associated blank samples? •Yes) No Comments: j M A > t u J i (SjM^^Xoryy^ jLfi^AX. Y^UKHJL JtAV^ M J L y ^ f j ^ | 4 ^ £ t i ^ - « ^ \ Laboratory Control Samples Were laboratory control sample (LCS) anaiyse&jjerformed at the correct frequency? Yes No (NA Were the LCS recoveries within acceptable^kmiis? Yes No ( N A ) Comments: /IrKtC v „ j . d o c Fonn VOA IJO 10141994 1032 7 302593 • Sample Results Were target analytes repondd-iii the investigative samples? ( Y M ^ No Were mass spectra providaHor the target analytes detected in the investigative samples? ^ e s ) No Were the mass spectra ofaeeeotable quality and analytes correctiy identified? (Yes) No Were the quantitated results for target analytes calculated using the appropriate intemal standards and were the relative retention times (RI^Ts) acceptable? C Y ^ NO Conmients: "flp^ Tentatively Identified Compounds Were tentatively identifi»^rDinpound (TIC) searches conducted for all sample analyses? (YCS) NO NA Were non-target peaks evaknted as required? Yes) No Were the TIC mass specmir-SMrches, identifications, and quantitated results acceptable? (yesj No Comments: yitrn^ Fonn VOA 1.0 voa_ l.doc 10141994 1032 8 302594 Log Books Were sample preparations Brtjperiy documented and performed in accordance with method protocols? 'Yes) No NA Were sample analyses propeiW documented and performed in accordance with method protocols? nfesV No Comments: Ylew^ vo.J.doc Fom. VOA IJ) 10141994 1032 9 3 0 2 5 9 5 Calculation Checks Instmment Tuning ifZlf^S', / ? | ^ Relative Abundano;: Initial Calibration [ ^ T z T ^ p ^ %RSD: Continuing C a l i b t a t i o r ^ Y T l h l j l ^ ^ 0.661 - 0. GM-7 I j;6d/Vvv/piZje. 62.^01 - j ^ ^-A^UiiiWum-cr^^^ voa_l.doc 10141994 1032 FOOD VOA I jO 302596 Matrix Spike Recovery j&iX/r^^^ tZOOO\\ W^;::^ZXT4. Ukt aiM XIOO = %R RPD: C?o - ^ 0 -^ p]o.^x I OC' = -^.^sy. ^ 1^ I -A:clU.^^dU^ Sample Results j^giAvv\^ VZ00ZO_ CRQL; aSo "^^ \ Z . 9 - \ Z j ^ l ^ - j r \ - ( M t r v ^ ^ Detected Result: U _ _ • _ LeYW|0«-U/VU3L 34^7 X 5*0 , ^ _^ . u TIC Result voa 1 .doc _ Fonn VOA IJ) 10141994 1032 , . 302597 HOLDING TIME QUALIHCATION SUMMARY FORM Sample Idcniificatioii D3000ZR^ Date Siimplcd )/2oMr Date Analyzed j/2/^5- Analysis Holding Time ] ^ A0UA.6 0 / Qualifier TIUT I \ Ui o to Ul \D CO Commcnis: vo»_l.doc 10141994 I0J2 12 Fonn VOA 1.0 INITIAL CALIBRATION QUALIFICATION SUMMARY FORM ^ ^ Date/Time l/27/qg' \l^oh^ zMhf zk\^^ Instrument £. £. £ Analyte 0>1/m^^e7V^x(iv4^vv^ ^ih'^J(rdlt,^ (lo/fa^-<Sr- l.l-p]uv&Wd:^dtic Pyt;&Tti/inrut:fcf^<t/KX Clg^.v^ . ^ 3 4 ] ^ ^ >^L.X. - aq^X Py1>fHva»-YVvcfcF><aytvg 0/l^lryXye-^VXS!MAA^J dh-^^rrtd A t s h : md^cUr^, - fl^uli g-K.g. RF RSD XkxL :^.o 3 ^ 4/.. 7 37.3 it^l itlA 17-7 <7 itLs: 3*4^4- 3Z.^ M^ 2AA. MR. Samples Affected ^\0^20^ J=\2DZ^^ DZOO'ZD^ VZ\c\Z\ ^ 92oon2.^ P 3 m q D3000ZZ^ O\ZZZ^V\0no\ ^D\\Z\Or. Clnnr, i ^ ClXloO^. dZlA-iXo Qualifier Xxk. rjur ly- ^(rlijcr) to o to tn «^ V,Vv^,^^>^K^^ Z/Zlq^ ' j^j^Aj^ MtJLiU^ CW. ,>l^^Uiuw ( W : ^ ^ Ji;n>S^ . ^ Forai VOA 1.0 vot_l.doc 10141994 1032 13 CONTINUING CALIBRATION QUALIFICATION SUMMARY FORM Date/Time \%lzJ^^\20^ -'fM ' V \z/sh^}zs( W^^/^r^ Instrument r E . F F Analyie Ifhjp't^je.. 2 - & L^yiA^ey^JL. 4'Ynj^A2'ppMk^ \A.'L.Z'rcfi, (Xcjpkh-v^ji^ 2 - , n iuTfl/M>e-Mj? 2 - Hjt//>A^jenjL OjtJckje-y\jL. 2'Bjud&4v©v«JL Z-Hj^£L<v\je-vNJ2- RF . rK€. — — — . — — %D -42.1 -;^?.((p 3.^.1 26.^ -15-1-7 - 2 ^ . 5 -113.4- -3I.C? -74^ 'I0Z.6 Samples Affected D^ooo^R^E 1 DlOOoi . D/IZI4- ^ A t C20OOI, C ^ ^ O Z T . . C2Zt^^ I ^ Qualifier T/UJ-| • / - \^ 1 r Comments: u> o to a\ o o vol.l.doc 10141994 1013 FonD VOA I.O 14 BLANK SUMMARY FORM Ui o to <ri o nrr Blank ID yygLKL \/0L)<LZ VgL.KL3 v/guKuq- \/e»Lk!L6- \/3LKU^ Analyte rn o^^.j^/w ^jig^i/^^. Q/Lphmi2. Y^ dd.J^oyvudJltiyJU (l/^jdjey, TIC ("^QVR-T^ yy] piA..g.^/ rl4v/<> (h ^vO cMfrXkdlp ttyi^ fW<Lr/ M v ^ (Xt/ikm^j^. rlS^Jk Blank Result (units) ' ^ - ^ ^ P ^ / ^ . ^^ .4/^- ^ .^/V gf-J ^/i^//:^g 3Z M^'l^ ± 3 1 ^ t-J- ./^y, ?-T IXA^/ .2il 3-T 4/ iii. ^ ^ ^ 4-T ..M^% 2.-T .A^/Kg Action Level Ition Level no z^o no ^ 0 0}0 ^ 0 lo_ so So 2>o m_ 40 10 Associated Samples VZOOZOj V^\c\Z\.B\0S2O. ^XtOZZ D3wnZ^V%n\^ k- \>\ZVh\' DI0OC71; Dl\2l4- ^y CZDoo\j CZZ.02Z.J azz^Co D3000ZRg Comments: ^ | ; l ^ ^ . - j t ^ M i l i ^ ' - l ^ - - 1^ 2^ 2 - : : t h ^ A A ^ a * - d ; ^ ( t r ^ 10141994 1032 l,l,^-i-U"''^Uotrc- l,2,2-i\.:fl^'>irr>- Sqi^/cl'^ CoMce.t,-^»-«//»My 0 / I ' l CAr '/ cf'^'*.'Pr'ee/ a S e - ^ U a U c ) W e k - t ^ . i ^ i l A C e c / '^S ^ c y ' ^ c f - e . / <r"/? ; "^ ^v« h lo<r/e>v^ fA t <?vc+,'ot, /ei^«./ h.>te.c>/ a / o u e n f ¥ Summary and Conclusions n o p (^(d^n. vt /^/^>L^>..i Jfn. O I A Q P A ^ y O ^ & ^ i ^ - l j j . A>-rMyJl^ £i jY\A>-f. • j ^ ^ ^ / \ f D ^ ^ ^ /^^VtVMp f i ^ jAhe^.i^ KK^X^./pi;-^iU^^^iJ) ^KpuJr<i J(,.f^J/yy^ Xi/wv^ <^^^Al>/U/l. Jl^fii^Jjlyy^^ Xi/WV^ /^MAJJ^/U.TL Q A A ^ VjAHU^r ^ ^y\AAA^fr-T.^ Oh>->A-i>^ >tAM:hL^ -HL<- bv\,piX\i.tjiMeA.iC^ r l C A L ^ _ ^ ^ 1 A > ^ 1 ^ lLSr^rPf^^Kzxsnr.— kKY^^SL n i A o l l u J i r i A . iJi^^Opt/jtcJ^fli) iyv^aJj?.U.-±£jL AAMH>^U^n[iW€ y^rX^yy^JljbAA. VCX.^'pLx J3ij4) X C j & u d cryx. Validator's Signature y Validator's Initials: 'i.wtciA/ Validation Date: QC Reviewer's Signature: ' 0 ^ 1 ^ ^ ^ ^ . y^-^^XX./*^ sIz^j^S'- QC Reviewer's Initials / ^ P P Review Date: ?/-? f / 9. S a ^ ^ l c Co He c>iV-f «.+)"«> lAj- " p T l C r I ^icH-tf'p.'ee/ <^S l ^ ' ^ h k O o f - i i ' ^ ' ^ i ' ^ - f r o u , Ce.cj. 1^1,7 ~ ii^l oHo.ri^ - l^2)?~ -f k,'f/i^ok-o ef Acmc.^ lA^ei^c e^i^c h'Pr'ecP '^•^ Fora OCT 1J 16 ocp.l.doc 10141994 1032 302602 VOLATILE ORGANICS ANALYSIS DATA SHEET ..o liame: ETC/GULF SOUTH Uon tract: :PA SAI'IPLE MO, C20001 Lab Code: GULF Ca=>e Ho. : HLA SDG No.: 95010 llAti^ix: (soil/water) SOIL Samp:ie wt/vol: 5^0 (g/mL) G Level: (low/med) I... QUI '.-:. fl o i. s 1;. n r e: n o t dec:. 1^1 GC Column: P]LX;:::.502.^_. ID: ..Jir!_5:30 (mm) S o i 1 L:' X l. r a o. t V •::> 1 u m e : ___ (1.1 L ) Lab Sample ID: VTXOOI Lab F:i.le ID: VCi.VTX01_R_ Da te Re ce .1 ved : 02/01/9 5 Date Analyzed: 02/0S/95 D i 1 u t i o n F a <.:. t o r : 1.;jC^ Soi 1 A.11 C| 1.1.ot V o 1 uIne : (uL.) CAS NO. COriF'OUND CONCEHTRATION UNITS: (ug/L or uci/Kci) UG/KG Q 74-S7-3 —Chloromethane 74--Bo-? Bromomethane 7 !3-01 -4 V i n y 1 C h 1 o r i d e _ 7 5--00-3 ( " h l o r o e t h a r i e 75-09-2 Methy 1 ene Ch 1 oride 67-64-i - Acetone I Z Z Z l ] ! 75-l.!3-0 Carbon Disulfide'^'J'ZL I 7!:V-35--4 •• -1,1-D:!. c h l oroethene.." 7 5 - 3 4 - 3 1 , 1 -D n. c h 1 o r o e t i"ian e ._ 5 4 0 " 5 9 - 0 :l. ,2™D:i.chloroethene( t o t a l )_ 6 7—6 6—3 C l"i 1 (j I" o "f c::i r m _ _ 107-06-2-— 1,2-D:i. ch 1 o r o e t h a n e 7;i -55-6 1 ,1, l-Tr:L chloroethane,.. _ 56-23-5 Carbon Tetrachloride 75--27- 4 Bromod i ch 1 orome thane 78-87-5 1,2-Dichloropropane 1006 :l. - 0 1 - 5 c i r>-1 , 3 - D i c fil o r o p r o pen e_ 7 9 - 0 1 - 6 T r i c h l o r o e t h e n e 12 4 - 4 9 -1 - —D i t" r o m o t: hi 1 o r o (ii e t hi a n e _ 7 9 - 0 0 - 5 1 , 1 , 2 - T r i c l-i 1 o r o e t h a ri e 7 1 - 4 3 - 2 B e n z e n e 10061 - 0 2 - 6 1 r an ir,- \ , 3-D i ch 1 o r o p r o pen e ll 10 8 - 1 0 - 1 4 - It e t h y 1 - 2 - !=• e n i.-. a ri one _ 5 9 1 - 7 8 - 6 2-Hexarione . 127-13-4 Tetrachloroethene 7 9 - 3 4 - 5 1 , 1 , 2 , 2 - T e t r a c l i l o r o e t f i a n e 1 0 8 - 8 3 - 3 T o l u e n e 1 0 8 - 9 0 - 7 C h l o r o b e n z e n e 1 0 0 - 4 1 - 4 E t h y l b ( ? n z e n e 1 0 0 - 4 2 - 5 S t y r e n e I ^ - I . . _ ^ . _ _ 1 3 3 0 - 2 0 - 7 X y l e n e ( t o t a l ) ylJ=\JL.\-U^rSA t . 11 11 11 1.1 ^ ^ 11 "' 1 11 .1. .!. 11 .1. .1. 1 1 11 11 11 11 1 :i. 11 1 1 11 11 .I'l 11 11 11 11 11 11 11 11 11 :u :u ;u :u li^U :ur ; j : J ; Ll 1 1 I 1 '-' : u : 1...! ;u ;u :u IU :u !'...' 1 u 1 Ll :u ;u ;u :u :u:r :u ;u :u :u :u ;u Reviewed r-;^ATED ^ 'x^ 30. ^ n ^311^1 <^V 3/90 302603 IE VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS EPA SAMPLE NO. Name: ETC/GULF SOUTH Lab Code: GULF Case No.: HLA Matrix: (isoil/water) SOIL Sample wt/vol: 5.0 (g/mL) G Level: (low/med) LQIO '; Moisture: not dec. 11 GC Column: RTX-502.2 ID: Q.530 (mm) Soil Extract Volume: (uL) Contract: SAS No.: SDG No.: 95010 Lab Sample ID: VTXOOI Lab File ID: Date Received: Date Analyzed: Dilution Factor: VOVTXOIR 02/01/95 02/08/95 1.0 Number TICs -found Soil Aliquot Volume: CONCENTRATION UNITS: (uq/L or ug/Kg) UG/KG .(uL) CAS NUMBER = • . = = = : • . ; : : = : : : = = : = = ; • . = = : = = : 1. 76-13-1 2. 1634-04-4 COMPOUND NAME =:•.= ===:=: ===.•=:=:=:=:==== = = = ====:=:=:=: = 1,1,2-TRICHLORO-l,2,2-TRIFLU 2-METH0XY-2-METHYPR0PANE RT 4.53 5.65 EST. CONC. ==:= = ==== = =:===: 8 10 Q ===== JN JN VAUD/^T5D Revif:'.*-d Ey Date ^IH^^ FORM I VOA-TIC 302604 3 / 9 0 J. ft EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET Name: ETC/GULF SOUTH Lab Code: G U L F Case No.: HLA Contract: SAS No.: SDG No.: 95010 Matrix: (soil/water) SOIL S a m pie w t. /vol: 5 ^^ ( g / m L ) G Level: (low/med) \~SJM T; Moisture: not dec. 1_6 GC Column: RTX-5Q2.2 ID: 0.530 (mm) Soil Extract Volume: (uL) Lab Sample ID: VTX002 Lab File ID: VOVTXO: Date Received: 02/01/95 Date Analyzed: 02/08/95 Dilution Factor: 1.0 S o i l Aliciuot Volume: .(uL ) CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG Q 74-87-3 74-83-9 75-01-4 75-00-3 75-09-2 67-64-1 — - 75-15-0 75-34-3 540-59-0 c ) / "" i'.y •':> X . i " " — — " 107-06-2 / ^.|— .:;./ -J 78-87-5 10061-01-5- 79-01-6 ~ 124-48-1-— —.»f-. i'^, ,'--|,__ r: ,.„ „_,_ „ 71-43-2 10061-02-6- -^ n: *-. i;: .-•, / ^< — X-. ..I — .il. 108-10-1 .91-78-6 .27-18-4 79-34-5 103-38-3—- 108-90-7 100-41-4 100-42-5 1330-20-7— Chloromethane •E<romome t h a n e •Vinyl C h l o r i d e •Chloroethane Me thy1en e C h l o r i d e • A c e t o n e •Carbon D i s u l f i d e •1,1-Di chl o r o e t h e n e • 1 , l~Di c h l o r o e t h a n e •1,2~Dichlorcjethene( -total) •Chloro-form -1 , 2-Di ch 1 oroethane^ -2^—Butanone -1,1 , 1-Tricliloroethane? -Ca r bon Te t ra ch 1 o r i d e -Bromod i cliloromethane -1,2-Dichloropropane - c i Si-1,3-D i c h 1 o r o p r o per^ e • T r i c h l o r o e t h e n e •Dibromochloromethane -1M1,2-Tr i ch1oroe t hane -Eienzene _ -1 r an s - 1 , Z> -D i c h l o r o p r o p e n e -Bromoform -4-Methyl"2-Pen-tanone -2-Hexanone_ Tetrachloroethene —1,1,2,2-Tetrachloroethane —Toluene -Chlorobenzene -Ethylben zene -Styrene -Xylene (tot a 1')...'" Z » • — ^ ^ •— ^ — ••— ••• ~>- B w a , .... ... ^ . ..-. ^_ __. ^_ __ ^ ^ * - - . — jJ t* . 1 KKViCTTCtr^y^ FORM iDaJ^iftr IE VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS EPA SAMPLE NO. Name: ETC/GULF SOUTH Lab Code: GULF Case No.: HLA Matrix: (soil/water) SOIL Sample wt/vol: 5.0 (g/mL) G_ Level: (low/med) LOUl '•: Moisture: not dec. 16 Contract: SAS No.: SDG No.: 95010 GC Column: RTX-502.2 ID: 0.530 (mm) Soil Extract Volume: (uL) Number TICs found: 3 Lab Sample ID: VTX002 Lab File ID: VQVTX02 Date Received: 02/01/95 Date Analyzed: 02/08/95 Dilution Factor: 1^._0 Soil Aliquot Volume: .(uL ) CGNCENTRATION UNITS: (ug/L or ug/Kg) UG/KG CAS NUMBER = = : = = = ::i L - : = = = :.•=•.= = : = = 1. 76-13-1 2. 1634-04-4 '> - COMPOUND NAME 1,1,2-TRICHLORO-l,2,2~TRIFLU 2-METH0XY-2-nETHYLPR0PANE \..MKNOi;JN HYDROCARBON RT -.•= = -.:==: = = :•.: 4.55 5.63 17.93 EST. CONC. r = : = — = = •-= = = = = — = = 10 6 5 Q ===== JV-1 JN Jt^ Reviev/cd By Date VALIDATE 302606 FORM I VOA-TIC 5/90 IA VOLATILE ORGANICS ANALYSIS DATA SHEE1 EPA SAMPLE NO. K«u Name: ETC/GULF SOUTH Lab Code: GULF Case Wo.: HLA Matrix: (soil/water) SOIL Sample wt/vol: 5.0 (g/mL) G Level: (low/med ) LOUJ r-.' Moisjture: riot dec. 14 GC Column: RTX-502.2 ID: O.530 (mm) S o i l E x t r a c t Volvune: ( u L ) C o n t r a c t : SAS N o . : SDG No.: 95010 Lab Sample ID: VTX003 Lab File ID: V0VTX03 Date Received: 02/01/95 Date Analyzed: 02/08/95 Dilution Factor; 1 .0 Soil Aliquot Volume: .(uL) CAS HO. COMPOUND CONCENTRATION UNITS; (ug/L or ug/Kg) UG/KG Q 7 4 - 8 7 - 3 7 4 - 8 3 - 9 7 5 - 0 1 - 4 7 5 - 0 0 - 3 7 5 - 0 9 - 2 6 7 - 6 4 - 1 75-15-0-: 7 5 - 3 5 - 4 7 5 - 3 4 - 3 5 4 0 - 5 9 - 0 — 67—66—3 1 0 7 - 0 6 - 2 — C'.fj-i-.Zj—0 7 5-27-4 7 8 - 8 7 - 5 1 0 0 6 1 - 0 1 - 5 7 9 - 0 1 - 6 1 2 4 - 4 8 - 1 7 9 - 0 0 - 5 7 1 - 4 3 - 2 1 0 0 6 1 - 0 2 - 6 - —ri-A ^ y i r . _ r ^ / ,.' /:.-.1 '.L. 1 0 8 - 1 0 - 1 5 9 1 - 7 8 - 6 1 2 7 - 1 3 - 4 7 9 - 3 4 - 5 1 0 3 - 8 3 - 3 1 0 8 - 9 0 - 7 1 0 0 - 4 1 - 4 1 0 0 - 4 2 - 5 1 3 3 0 - 2 0 - 7 — C h l o r o m e ' t h a n e B romome^ t h a n e^ Vinyl Chloride Chloroethane Me thy1ene C h1o r i d e Acetone Carbon Disul-fide 1,1-D:i chloroethene 1, l - D i c h l o r o e ' t h a n e _ 1,2-D i c h 1 o r o e t he;n e ( t o t a l )._. C h1o r o f o rm 1 , 2 - D i c h l o r o e t h a n e 2 •- B u t a ri o n e 1 , 1 , l - T r i c h l o r o e t h a n e ^ C a r bon T e t r a c h l o r i d e Bromodi chloromethane -1,2-DichlQropropane cis-1,3—Dichloropropene Trichloroethene Di bromoclilorome tbane 1,1,2~Tri chloroethane Benzene trans-1,3-D ichloropropene., Bromoform 4-Methyl~2~Pent<i^none 2-Hexanone Te t ra c h1o roe t hene 1 , 1 , 2 , 2 - T e t r a c h l o r o e t h < T i n e _ T o l u e n e C h 1 o r o ben z e^n e Eth-/1 ben zene S t y r e n e , - X y l e n e ( - t o t a l ) H Z l l V nReviewed"By 1-2. ^4r\f&^-- 12 ; 12 : 12 ; 12 ; 50 ; 12 : 12 : 12 ! 12 • 12 ; 12 12 ; 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 o dr. u u : u u .js^ax; Ll : u ; u u u ; u ; u X • u u u u u u u u ;u • u ;u :u ',\^'J' ;u :u ;u :u :u ;u ; j 1 302607 £^Z. ;/9o IE VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS 5.0 (g/mL) G_ ) Name: ETC/GULF SOUTH Lab Code: GULF Case No.: HLA_ Matrix: (soil/water) SOIL__ Sample wt/vol: Level: (low./'med) L.OW '-:. Moisture: not <:}.cs:<:.. 14 GC Column: RTX-5C)2.2 ID: 0 • 530 (mm) Soil Extract Vc-lume: (uL) Contract: EPA SAMPLE NO. :426 No. : SDG No. : 95010 Lab Sample ID: VTXQ03 Lab File ID: V0VTX03 Date Received: Date Analyzed: Dilution Factor: 02/01/95 02/08/95 1 .. 0 Soil Aliquot Volume: . ( u L ) Number TIC-s -T CAS NUMBER === ========-.:==: 1. 2. 76-13-1 . 3. 1634-04- \ , . CONCENTRATION UNITS: ound: 4 (ug/L or uq/Kq) UG/KG ; COMPOUND NAME = = r.- J : ; - . - . = = = = = = = = = = = = = = = = = = = = = = = = = = 7.= ; UNKNOWN ;1,1,2-TRICHLORO-1,2,2,-TRIFL 4 i 2-METH0XY-2-METHYLPRGPANE :UNKNOWN HYDROCARBON RT 3.02 4-53 5.60 17.88 EST. = • = = = = = CONC. 5 8 4 C ==-.; J N JN JN JKJ Q Revinv.'cH n Date; VALIDATE. 302608 FORM I VOA-TIC ; / 9 0 IA VOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. ,L, Name: ETC/GULF SOUTH Lab Code: GULF Case No.: HLA Matrix: (soil/water) SOIL Sample wt/vol: 5.0 (g/mL) G Level: (low/med) LOUJ "; Moisture: not dec. 9 GC Column: RTX-502.2 ID: 0.530 (mm) Soil Extract Volume: (uL) Contract: SAS No.: SDG No.: 95010 Lab Sample ID: VSI002 Lab File ID: V0VSI02R.. Date Received: 01/27/95 Date Analyzed: 02/03/95 Dilution Factor: 1_--Q. Soil Aliquot Volume: (uL) CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG 74-87-3 74-83-9 7 5 - 0 1 - 4 7 5 - 0 0 - 3 7 5 - 0 9 - 2 6 7 - 6 4 - 1 7 5 - 1 5 - 0 7 5 - 3 5 - 4 7 5 - 3 4 - 3 5 4 0 - 5 9 - 0 6 7 - 6 6 - 3 1 0 7 - 0 6 - 2 —} o r p - y -.•' „_ _ .* 7 1 - 5 5 - 6 r r / '~»T'_n: •..' i-j x... -.J ^' 7 5 - 2 7 - 4 7 3 - 3 7 - 5 1 0 0 6 1 - 0 1 - 5 7 9 - 0 1 - 6 1 2 4 - 4 8 - 1 79-00-5 7 1 - 4 3 - 2 1 0 0 6 1 - 0 2 - 6 — • —; rz *\t c; „ f _ _ - _ 1 0 3 - 1 0 - 1 5 9 1 - 7 3 - 6 1 2 7 - 1 3 - 4 7 9 - 3 4 - 5 1 0 8 - 8 8 - 3 1 0 8 - 9 0 - 7 1 0 0 - 4 1 - 4 1 0 0 - 4 2 - 5 1 3 3 0 - 2 0 - 7 C h l o r o m e ' t h a n e B r o m o m e t l i a n e V i n y 1 C h 1 o r i d e C h 1 o r o e t \\A\\ e M e t h - / l e n e C h l o r i d e A c e t o n e Carbon Disulfide 1 , 1 - D i c h i orcjiet hene 1 , 1 - D i c h l o r o e t h a n e 1,2-D i c h1o r o e t hen e ( t o t a 1 ) C h l o r o f o r m J., 2—D i c l"i 1 •::• r o e t h a n e 2 - B u t a n o n e 1 , 1 , 1 - T r i c h l o r o e t h i a n e C a r b o n T e t r a c h l o r i d e Bromod i c h l o r o m e t h ^ m e 1 , 2 - D i c h l o r o p r o p a n e • c i s - 1 , 3 - D i c h l o r o p r o p e n e T r i c h l o r o e t h e n e •Di b r o m o c h i o r o m e t h a n e ^ • 1 , 1 , 2 - T r i c h l o r o e t h a n e • B e n z e n e • t r a n s - 1 , 3 - D i c h l o r o p r o p e n e • B r o m o f o r m - 4 ~ M e t h - / l - 2 - P e n t a n o n e -2—l-1ex.:!\none •Te t r a c h 1 o r o e t h e n e -1 ,1,2,2-Tetrachloroethane Toluene — C hio ro ben z ene —Ethylbenzene —Styrene —Xylene ' ( t o t a l ) '"_ ¥AkHDA" •-Reviewed-fr/-^—iiHXtkM 11 11 11 11 (1 ^ II 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 I I 11 11 11 11 11 11 11 11 11 11 D Q U U U tJ i^\JXTi J tJ u u u u u J~ u u u u u u u u u u u u UO" u u u u u u u FORM Ppte.,;et%- 302609 " 3 / 9 0 IE VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS EPA SAMPLE NO. t..-' Name: ETC/GULF SOUTH Lab Code: GULF Case No.: HLjA. Contract: SAS No.: Matrix: (soil/water) SOIL Sample wt/vol: 5.0 (g/mL) G Level: (low/med) LOW ": Moisture: not dec. 9 GC Column: RTX-502.2,,. ID: 0.530 (mm) Soil Extract Volume: (uL) Number TICs found: 1 CAS NUMBER 1. 1634-04-4 SDG No.: 95010 Lab Sample ID: VSI002 Lab File ID: V0VSI02R Date Received: 01/27/95 Date Analyzed: 02/03/95 Dilution Factor: 1 .0 Soil A1 i C| uo t Vol ume : .(uL ) CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG COMPOUND NAME PROPANE, -METH0XY-2~METHYL RT ,65 EST. CONC 1 3 Q JN VA Reviev/cJ Cy . b Date u/^k. FORM I VOA-TIC 302610 3/90 IA VOLATILE ORGANICS ANALYSIS DATA SHEET m AD Name: ETC/GULF SOUTH Lab Code: GULF Case No.: HLA Contract: SAS No.: EPA SAMPLE NO. D11214 SDG No.: 95010 Matrix: (soil/water) SOIL Sample wt/vol: 5.0 (g/mL) G Level: (low/med) LQI^J ••: Moisture: not dec. 17 GC Column: RTX-502.2 . ID: 0.530 (mm) Soil Extract Volume: (uL) Lab Sample ID: VSI003 Lab File ID: V0VSI03R Date Received: 01/27/95 Date Analyzed: 02/03/95 Dilution Factor: l..zX}. Soil Aliquot Volume: (uL) CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kq) UG/KG Q 74-87-3 74-83-9 75-01-4 75-00-3 75-09-2 67-64-1 75-15-0 :.-4 / :.-.i- xa-: 540-59-0 67-66-3 107-06-2— 78-93-3 71-55-6 ir. / '^"T n: %.' K O " " x _ •.-> " " v.l 78-87-5 10061-01-5— 79-01-6 124-48-1 79-00-5 71-43-2- 10061-02-6-— 75-25-2 103-10-1 591-78-6 127-18-4 79-34-5 103-88-3 103-90-7 100-41-4 100-42-5 1330-20-7 Chloromethane B romome than e Vinyl Chloride Chloroethane |*1ethy 1 ene Cli 1 aride - Ace tone Carbon Disulfide 1,1-Di chloroethene 1,1-Dichloroethane 1,2-Dichloroethene(total) Chloroform 1,2-Di chloroethane 2-E<utanone 1,1,1-Tri chloroethane CarJDon Tetrach 1 oride Bromod i chloromethane 1,2-Dichloropropane cis-1,3-Di ch1oropropene Trichloroethene Dibromochloromethiane_ 1,1,2-Tri chloroethane E'en zene t ran s-1,3-D i c h1o ro p ro pen e Bromoform 4-Methyl-2-Pentanone 2-Hexanone Tetrachloroethene 1 ,1,2,2-Tetrachloroethane Toluene C hi loro ben z ene ^ Ethyl ben zene S t y r e n e _4..—^i- >.—> Xylene ('total")' V A L l D A T Reviewed 5y FORhbtJ VOA 1^ n ^ ^.4Amf-'- 12 ; 12 ; 12 ; 12 ; - ^ : 36 B; 12 ; 12 ; 12 : 12 12 ' •1 o . \ . j i . 12 ' 12 12 12 12 12 12 12 12 12 f2 12 12 12 12 12 12 12 12 12 12 wa u ; u ; u tJ ; j&^U i j f ^ ^ ^ : u ; u u : u ; u ! 1 • ucr : u u ; u u : u : u ; u ; u u : u ;u .u : : u j - : ;u ; !U ; ;u :u :u : ;u :u 1 • 302611 3/90 IE VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS EPA SAMPLE NO. r^D Name: ETC/GULF SOUTI-I Lab Code: GUL,F, Case No.: HLA Matrix: (soil/water) SOIL Sample wt/vol: 5.0 (q/mL) G_ Level: (low./med) LOW ': Moisture: not dec. 17 GC Column: RTX;-502_^_. ID: 0.530 (mm) Soil Extract Volume: (uL) Contract: SAS No.: SDG No.: 95010 La b Sam p1e ID: VSI003 Lab File ID: V0VSI03R Date Received: 01/27/95 Date Analyzed: 02/03/95 Dilution Factor: 1 .0 Soil Aliquot Volume: .(uL) Number TICs found 1 CONCENTRAT I ON t.lN I T S : ( u g / L o r u g / l ? g ) UG/KG CAS NUi^iBER 1. 1634-04-04 COMPOUND NAME PROF'ANE, O — WIT METH0XY-2-METHYI. Revie-.'.'"' n- VAl! DATED lu/fotLf Date; mifi^ FORM I VOA-TIC 302612 3/90 IA VOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. •Lata Name: ETC/GULF SOUTH Lab Code: GULF Case No.: HLA Matrix: (soil/water) SOIL Sample wt/vol: ,5. 0, (g/mL) G Level: (low/med) LOW "; fl o i 6 t u r e :; not cl t^ c. 13 GC Column: RTX-502.2 ID: O.530 (mm) Soil ir.xtract Volume: (uL) Contract; SDG No.: 95010 Lata Sample ID: VSI004 Lab File ID: V0VSI04 Date Received: 01/27/95 Date Analyzed: 02/02/95 Dilution Factor: 1 .O Soil Aliquot Volume: (uL) CAS NO. 74-87-3 74-83-9 75-01-4 75-00-3 67-64-1 75-15-0 7 5-35-4 75-34-3 540-59-0 67-66-3 107-06-2 71-55-6 56-23-5 75-27-4 COMPOUND CONCEi-iTRAT I ON Ul-I I TS: (ug/L or ug/Kg) UG/KG Q 7 8 - 8 7 - 5 1 0 0 6 1 - 0 1 - 5 - 7 9 - 0 1 - 6 1 2 4 - 4 8 - 1 7 9 - 0 0 - 5 7 1 - 4 3 - 2 1 0 0 6 1 - 0 2 - 6 - 7 5 - 2 5 - 2 1 0 3 - 1 0 - 1 5 V1—73-6 1 2 7 - 1 8 - 4 7 9 - 3 4 - 5 1 0 3 - 8 3 - 3 1 0 3 - 9 0 - 7 1 0 0 - 4 1 - 4 1 0 0 - 4 2 - 5 — - 1 3 3 0 - 2 0 - 7 — - C h l o r o i n e t h a n e -B romome t han e - V i n y l C h l o r i d e -Cil 1 oroo? tliane - hie t l-iy 1 e n e C i i ]. o r" i d e _ —Ace tone -Ca rbon D i s u 1 f id e — 1,1—Di c h i l o r o e t h e n e - 1 , 1 - D i c h l o r o e t h a n e - 1 , 2 - D i c h l o r o e t h e n e ( t o t a l ) —Ci"iloro-f orm - 1 , 2 - D i c h l o r o e t h a n e - 2 - B u t a n o n e ~1 , 1, l - T r i c l ' i l o r o e t h a n e - C -a I •• 1.-J o n T i? t r a c i-i 1 o r i. d e -Brodiod i chloromethane -1,2-Dichloropropane — c i s-1,3-D i c h1o ro p ro pen e -Tr i ch1oroet hene -Dibromochloromethane -1,1^2-Trichloroethane —Benzene -trans-1,3-Di chloropropene —Bromoform -4-Methyl-2-Pen"tanonel..lZ -2.-Hexanone -Tetrachloroethene -1,1,2,2-Tetrachloroethane —Toluene —Chlorobenzene -Ethyl ben zene — S t y r e n e _ , - X y l e n e (to't'al')' VSvID ATEJ Revfewed~By Fni^PThtJ wriA 11 : 11 ; 11 ; 11 15 ; 24 ' 11 11 11 ; 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 u ur u Ll ^ u : r j> ucr u l.J !.J u 1.J 1...I u L.l u tJ U 1..! u tJ u u u u u .u u .u u !U u • !U .u 3 0 2 6 1 3 3 / 9 0 9L IE VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS EPA SAMPLE NO. ab Name: ETC/GULF SOUTH Lab Code: GULF Case No.: HLA Matrix: (soil/water) SOIL Sample wt/vol: 5.0 (g/mL) G Level: (low/med) LOW r: Moisture: not dec. 13 GC Column: RTXr.502.;2._ ID: 0.530 (mm) Soil Extract Volume: (uL) Contract: SAS No.: SDG No.: 95010 Lata Sample ID: VSIG04 Lab File ID: V0VSI04 Date Received: 01/27/95 Date Analyzed: 02/02/95 Dilution Factor: 1.0 Soil Aliquot Volume: .(uL) Number TlC^Pi found; .1 CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG CAS NUMBER 1 . 1 6 3 4 - 0 4 - 4 COMPOUND NAME ?-METHDXY-2-METHYLPR0PANE RT 5.6" EST. CONC. 11 n JN Reviev/ed Dy Date _ ^^^l^ 302614 FORM I VOA-TIC 5/90 EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET # . 'cto Name: ETC/GULF SOUTH Lab Code: GULF C a s e N o . : ^•1LA C o n t r a c t : SAS N o . : SDG No.: 95010 Matrix: (soil/water) SOIL Sample wt/vol: 5.0 (q/mL) G Level: (low./med) LQJAI r: Moisture: not dec. 20 GC Column: RXX;-502.2._. ID: 0.530 (mm) Soil Extract Volume: (uL) Lab Sample ID: VQB003 Lab File ID: V0VQB03 Date Received: 01/23/95 Date Analyzed: 01/27/95 Dilution Factor: 1^.0 Soil Aliquot Volume: .(uL) Z^y-\'i:> I'ICj 74-G7-3-— 7 4 - 8 3 - 9 -- 7 5 - 0 1 - 4 7 5 - 0 0 - 3 7 5 - 0 9 - 2 6 7 - 6 4 - 1 7 5 - 1 5 - 0 - 7 5 - 3 5 - 4 - —. tr. ~y / . -y / . . I O ' 4 ••••..;• 5 4 0 - 5 9 - 0 /.^..../j^,....3 1 0 7 - 0 6 - 2 — / ..r~-,::./—H—- / Cu CD / ^' COMPOUND CONCENTRATION UNITS: (ug/L or ug/Ka) UG/KG Q 10061-01-5 124-48-1 79-00-5 - 71.-43-2 10061-02-6 103-10-1 591-78--6 127-18-4 79-34-5 108-88-3 108-90-7 100-41-4 100-42-5 1330-20-7 Chloromethane Bromomethane Vinyl Chloride Chl o roe t i-i£in e I'le t I T / 1 e n e C I'l l o r i d e Ace t o n e C a r b o n D i s u l f i d e _ _ 1 , 1 - D i c h l o r o e t h e n e 1 , 1 - D i c h l o r o e t h a n e • 1 , 2 ~ D i c h 1 o r o e t h e n e ( t o t a 1 ) C I'l 1 o r o -f o r m 1 , 2 - D i cl"i 1 o r o e - t h a n e 2 - E < u t a n o n e • 1 , 1 , 1 - T r i c h 1 o r o e t h a n e • C a r I;) o n T e t r a c hi 1 o r i d e •Bromod i chloromethane •1,2--Di chloropropane cis-1,3-Dichloropropene - T r i c |-i 1 o r o e t I'i e n e - D i tir omo c h l o r ome t h a n e - 1 , 1 , 2 ~ T r i c h l o r o e t h a n e - E < e n z e n e ~ t r a n s - l , 3 - D i c h l o r o p r o p e n e —E<romof o r m - 4 - M e t h y l - 2 - P e n t a n o n e -2-Hc^ X ar I one -Tetrachloroethene -1,1,2,2-Tetrachloroethane —Toluene —Chl loro t)en zene ^ —Ethyl ben zene —S tyrene -Xylene (total) 3 Z ^ r-fcJ- Reviewed By FORt^afe )^S^ 12 ; 12 ! 12 ; 12 ; l-Z, J ^ : 12 : 12 ; 12 ; 12 12 ; 12 12 ; 12 12 ; 12 12 12 12 12 12 12 ^.2 12 12 12 12 12 12 12 12 - . - ^ ^^ - n 12 " ^ W i f r i f i / n ^ u ; u T : u : u u- ; J&<rUT; uT ; J ; 1.1 J- • u tJ u u u u u u u u u u u u u :u u :u • u :u ;u ;u lU ; u :u 302615 3 / 9 0 IE VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS :PA SAMPLE NO, HLA . l-ame: ETC/GULF SOLITH Lab Code: GULF Case No. Matrix: (soil/water) SOIL Sample wt/vol: 5.0 (q/mL) G. Level: (low/med) LOW r: Moisiture: not dec. 20 GC Column: RTX-502.2 ID: O„530 (mm) S oil Extract V o 1 u me: (u L ) Contract: SAS No.: SDG No.: 95010 Lata Sample ID: VQB003 Lab File ID: V0VQB03 Date Received: 01/23/95 Date Analyzed: 01/27/95 Dilution Factor: 1 .0 Soil Aliquot Volume: .(uL) Number TICs found 1 CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG CAS NUMBER 1 . 1.634-04-4 COMF'OUND hIAME 2-METH0XY-2-METHYLPR0PANE RT 5 . 1 3 EST. CONC. 11 Q JN Reviev/cd E'; Date FORM I VOA-TIC IDATED 302616 3/90 IA VOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. Lab Name: ETC/GULF SOUTH Lab Code: GULF Case No.: HLA Contr^ict: SAS No.: SDG No.: 95010 Matrix: (soil/water) SOIL Sample wt/vol: 5.0 (g/mL) G Level: (low/med) I...OW *; Moisture: not dec. 12 GC Column: RTX-502.2 „, ID: _0_:.5_3p_ (mm) Soil Extract Volume: (uL) Lab Sample ID: VQB004 Lab File ID: V0VQB04 Date Received: 01/23/95 Date Analyzed: 01/27/95 Dilution Factor: 1.0 Soil Aliquot Volume: .(uL) CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG Q 7 4 - 8 7 - 3 7 4 - 8 3 - 9 7 5 - 0 1 - 4 7 5 - 0 0 - 3 6 7 - 6 4 - 1 7 5 - 1 5 - 0 5 4 0 - 5 9 - 0 ,7-66 .'r.XTt—Z.^ 1 0 7 - 0 6 - 2 / o " " / j / x.'j 7 1 - 5 5 - 6 t= /, o "-* n: „., 7 5 - 2 7 - 4 7 3 - 8 7 - 5 1 0 0 6 1 - 0 1 - 5 - 7 9 - 0 1 - 6 1 2 4 - 4 8 - 1 7 9 - 0 0 - 5 7 1 - 4 3 - 2 1 0 0 6 1 - 0 2 - 6 - —ttr. '•;# c O ™ «_ _„ _ 1 0 8 - 1 0 - 1 5 9 1 - 7 8 - 6 1 2 7 - 1 8 - 4 7 9 - 3 4 - 5 1 0 8 - 8 8 - 3 1 0 8 - 9 0 - 7 1 0 0 - 4 1 - 4 1 0 0 - 4 2 - 5 1 3 3 0 - 2 0 - 7 — C h1o rome t han e E*romome-thane Vin-/1 Chloride C h1o r o e t h a n e Methylene Chloride Ace ton e Carbon Disulfide 1,1-Dichioroethene 1,1-Dichloroethane 1,2-Di chloroethene(total) Chloroform 1,2-Di chi 1 oroe thane 2-Eiutanone _ 1,1,1-Trichiloroethane Carbon Tetrachloride E<romod i ch 1 oromethane 1,2-Dichloropropane cis—1,3—Dichloropropene Trichloroethene D i b romo c h1o rome t hane 1,1,2-Trichloroethane Benzene t r a n s - 1 , 3 - r ) i c h l o r o p r o p e n e •Bromoform _ _ 4 - M e t h - / l - 2 - P e n t a n o n e 2!-Hexanone-> _ Tetrachloroethene •1,1,2,2-Tetrachloroethane Toluene •Chlorobenze^ne E t hy 1 ben z en e • S t y r e n e »_t_jt_i . i-. Xylene ('total) ZliVAjojEA 'Revrewe^T3y' FOipgteT \/nft 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 uj- u ucr J U J " u u u u u u u u u u tJ u u u u u u u u u u u u u 302617 5/90 IE VOLATILE ORGANICS ANALYSIS DATA SHEET TEi-ITATIVELY IDENTIFIED COMPOUNDS EPA SAMPLE NO, ..J Name: ETC/GUi...F SOUTH Lab Code: GULF Case No.: HLA Contract: SAS Ho.: SDG No.: 95010 Matrix: (soil/water) SOIL Sample wt/vol: 5..0 (g/mL) G Level: (low/med) LOUJ ": Moisture: not dec. 12 GC Column: RIX;:;.502jj;;_. IDs 0.530 (mm) Soil Extract Volume: (uL> Lata Sample ID: VQB004 Lab File ID: V0VQB04 Date Received: 01/23/95 Date Analyzed: 01/27/95 Dilution Factor: 1^..._0 So i 1 A1 i c|UO t Vol ume: (uL ) Number ^•s f oui'-id : 0 CONCENTRATION UNITS: (ug/L or ug/Kg) UG/Kji CAS NUMBER COMF-OUhID NAME RT EST. CONC Reviev/cd By Date FORM I VOA-TIC 302618 3 / 9 0 I A •'OLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. J Name: ETC/GULF SOUTH Lab Code: GULF Case No.: HLA Contract: SAS No.: SDG No.: 95010 Matrix: (soil/water) SOIL Sample wt/vol: 5.0 (g/mL) G. Level: (low./med) UQW '.', Moisture: not dec- ' 11 GC Column: RT.X-502..2... ID: 0.530 (mm) Soil Extract V i;::-1 u. ii e; (u L ) Lab Sample ID: VQA002 Lab File ID: V0V0A02R Date Received: 01/23/95 Date Analyzed: 01/30/95 Dilution Factor: 1.0 Soil Aliquot Volume: .(uL) CAS NO. COMl-'OUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG Q 74-87-3- — 74-83-9— 75-01-4- — 75-00-3 - 75-09-2 - 67-64-1- 75-15-0 - 75-35-4 — 7 •."' %'.;• '-T—•.:> 540-59-0 — 67-66-3- — 107-06--2 •- 78-93-3 71-55-6 56-23-5 — 75-27-4 — 78-87-5 10061-01-5 79-01-6- 124-48-1 - 79-00-5 - - 71-43-2 - — 10061-02-6 7 i;: '-^ ir *-. %.' ~^. *.' *:. '"" — — 108-10-1 591-78-6 127-18-4 79-34-5 108-83-3 108-90-7 100-41-4 100-42-5 1330-20-7 -C h1o rome t han e ~B romome t hane _ -V i n y1 C hlori d e ; -•'C.'ii 1 oroe thane -liet !-iy 1 e n e C i"i 1 o r i d e -Acetone _ -Ca r bon D i su1f i d e -1,1-Di ch1oroethene -1,1-Dichloroethane -1 ,2-D i c hi 1 o roe t hen e (to ta 1) -Chloroform -1,2-Di chloroethane -2~Eu.rtanone — 1., 1,1-Tri chloroethane -Ca r bon Te trachlor i d e -E< romod i c h 1 o rome t han e . -1,2-Dichloropropane -cis-1,3-Di chloropropene —Trich1oroe thene —Dibromochloromethane — 1 , 1 , 2 - T r i c h l o r o e t h a n e —E<en z en e —trans-1,3-Dichloropropene —E<romof orm -4-Methyl~2-Pen tanone'_]^ —2-Hexanone —Te t ra c h1o roe t hene — 1,1,2 ,2-Tetrachloroethane> —Toluene —Chlorobenzene —Ethylbenzene —Styrene _ —Xylene (total) VSLtD 11 ; 11 ; .U .L 1 11 ; 97 ; 25 ; 11 ! 11 : 11 ; 11 ; 11 ; 11 11 ; 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 u : UT : u u T ; .JE^UX >^ XXTi u : t.' : u : u ; u u ; u u u u u u u Ll 1.J u U ;u U T : u T ;u J" ; u T : u T :uT ;u T :uT Reviewed By FORm.tJ VOA 302619 3/90 IE VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS EPA SAMPLE HO. W...^o Name: ETC/GULF SOUTH Lab Code: G.ULJF; Case No.: HLA ilatrix: (soil/water) S.OJ;L Sample wt/vol: 5.0 (q./mL) G Level: (1ow/med) LOW "•; Mois'ture: not dec. 11 GC Column: RTX;-502..2„ ID: 0.530 (mm) Soil Extract Volume: (uL) Number TICs found: 2 Contract: SAS No.: SDG No.: 95010 Lab Sample ID: VQA002 Lab File ID: V0VQA02R Date Received: 01/23/95 Date Analyzed: 01/30/95 Dilution Factor: 1_=.Sl Soil Aliquot Volume: (uL) CONCENTRAT 101^^ UN ITS: (ug/L or ug/Kg) UG/KG CAS NUMBER 1. 76-13-1 2. 1634-04-4 COMPOUND NAME ETHANE, 1,1,2-TRICHLORO-1,: F'ROPANE, 2-METH0XY-2-METl^lYL- i ; RT 1 = = = = = = = = ; 4 . 1 0 1 tr. ':* o 1 O m ^ . 4 . . 1 . ,. . .„ E S T . CONC == 1 1 0 4 „ . _„. .„. _.. _ „.. _., „ . Q ;j&a^R JN VALIDATE FORM I VOA-TiC 302620 3 / 9 0 IA VOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. Name: ETC/GULF SOUTH Lab Code: GULF Case No.: FjLA Matrix: (soil/water) SOIL Sample wt/vol: 5.0 (g/mL) G_ Level: (low/med) LOW r: Moisture: not dec. Contract: SAS No.1 SDG No.: 95010 Lab Sample ID: VQA002RE Lab Filvf ID: V0VQA02 11 GC Column: RTX-502.2 ID: 0.530 (mm) Soil Extract Volume: (uL) Date Received: 01/23/95 Date Analyzed: 03/02/95 Dilution Factor: 1.0 Soil Aliquot Volume: .(uL) CAS NO, COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG Q /• •-* O^J •/ 75-01-4 75-00-3 75-09-2 - 67-64-1 75-15-0 75-35-4 540-59-0 6/-6.6-3 .1.'.} .' - - (..' O — i.. —-V7^ . . . I A ) " ' ....-•* ._._____ » _ _ 71-55-6 56-23-5 75-27-4 78-87-5 10061-01-5 79-01-6 124-48-1 79-00-5 71-43-2 10061-02-6 108-10-1 591-78-6 127-18-4 79-34-5 108-88-3 108-90-7 100-41-4 100-42-5 1330-20-7 -C h 1 o r ome t han e -Bromomethane -V i n y1 C hlo r i d e -C hi 1 o roe t han e -Me thy 1 ene Chlor i de -Acetone -Carbon Disul-f ide -1,1-Di chloroethene -1,l~Dichloroethane -1,2-Di chloroethene(total) -Chloroform -1,2-D i c hioroe t han e - 2 - E« u t a none -1,1, l~Trichiloroethane -Carbon Tetrachloride -Bromod i chloromethane. _.__ -1,2-Dichloropropane -cis-1,3-Dichloropropene -Trichloroethene - D :L b I'- o m o c hi 1 o r o m e t h a n e -1,1,2-Trichloroethane -Benzene -1rans -1,3 -Di chi 1 oroprop(-?ne_ -Bromoform _ -4-Methyl-2~Pen-tanone -2-He X an one -Te tra c h 1 o roe t hen e __. -1 ,1,2,2-Tetrachiloroe thanes -Toluene -Chloro l::'e^n z en e -Ethyl taen zene. —Styrene —Xylene ( t o t a l ) Reviewed Gy :::::VA"DXi VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS ^.o Name: ETC/GULF SOUTH Lab Code: GULF Case No.: HLA Contract: SAS No.: EPA SAMPLE NO. D30002RE SDG No.: 95010 Matrix: (soil/water) SOIL S/ample w-t/vol: 5.0 (g/mL) G Level: (low/med) LOW '-: Moisture: not dec. ;l,J. GC Column: fXX^l^>Z.:.Z.... -tD: ._.0..,..53:P. (mm) Soil E-ixtract Volume: (uL) Lab Sample ID: VQA002RE Lab File ID: V0V0A02 Date Received: 01/23/95 Date Analyzed: 03/02/95 Dilution Factor: L:.£> Soil Aliquot Volume: (uL) Numiber TICs found: 1 CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG CAS NUMBER 1634-04-4 COMPOUND NAME PROPANE. •METV-IOXY- -METHYL- RT r: M *"i EST. CONC. 47 Q IN VALIDATED jomsix. 302622 FORM I VOA-TIC 5/90 EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET .xj Name: ETC/GULF SOUTH Lab Code: GULF Case No.: HLA Matrix: (soil/water) SOIL Sample wt/vol: 5.0 (g/mL) G Level: (low/med) LOW "•: Moisture: not dec. 12 GC Column: RTX-502.2_ ID: ,0.530 (mm) Sjoil E x t r a c t Volume: _ (uL) Contract: SAS Ho.: SDG No.: 95010 Lab Sample ID: VQA003 Lab File ID: V0VQA03R Date Received: 01/23/95 Date Analyzed: 01/30/95 Dilution Factor: 1-0 Soil Aliquot Volume: (uL) CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L o r ug/Kg) UG/KG Q 74-. 7.0,. 75- 75 75 67 75 75 "7 1= -83- -01- -00- -09- -64^ -15- -35- -34 540-5' 67 10 78 71 56 -66- 7-0 -93- -55 -23 -9 -4 -3 - 1 — -0 -4 — _-:T 7-0— -3 ^>-2- -3 _^r, - • T \ —I It; r~,—t /I „. / >.' - i : . / " M 78-37-5 10061-01-5 124-48-1 79-00-5 71-43-2 10061-02-6 75-25-2 108-10-1 591-78-6 127-18-4 79-34-5 108-88-3 103-90-7 100-41-4 100-42-5 1330-20-7 Chloromethane Bromomethane Vinyl Chloride -__ Chloroethane Methylene Chlor i d e Acetone Carbon Disu1fide 1, l-r;i chl oroet hene 1,1-Dichloroethane 1,2-D i c h1oroe t hen e(to tal) C h l o r o f o r m 1,2'-Di c t-'i 1 o 1'-oe t liarie ._ 2-Bu tan o n e 1 , 1 , 1 - T r i chloroethanox-_ C a r bon T e t r a c hi 1 o r i d e —Ei romoci J. c h 1 o rome tfian e -1,2-Dichloropropane -cis-1,3-Dichloropropen e -Trichloroethene -Di bromoch1orome thane -1,1,2~Trichloroethane -Benzerie - t r a n s - l , 3 - D i c h l o r o p r o p e n e —B romofo rm - 4 - M e t h y l - 2 - F ' e n t a n o n e - 2 - H e x a n o n e - T e t r a c l n l o r o e t h e n e - 1 , 1 , 2 , 2 - T e t r a c h l o r o e t h a n e - T o l u e n e ^ -Chlorobenzene —Ethylbenzene -Styrene -§-r> -Xylene (total) 5/./5l,lD RevieV/ccTcTy FOrmtJ VGA |[' PD 11 11 11 11 18 19 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 il 11 11 11 11 11 11 11 11 11 11 :u ;u J" :u ;u J" •^UO' l-E^UJ" :u :u ;u ;u ; Ll : tl ; Ll :u ; 1.1 ;u ;u :u :u ;u :u ;u !U !U ;u ;u ;u ;u ;u :u :u :u ;u 302623 )/90 IE VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS :PA SAMPLE NO. Name: ETC/GULF SOUTH Lab Code: GULF Case No.: HLA Matrixn (soil/water) SOIL Sample wt/vol: 5.0 (g./mL) G_ Level: (low/med) LOW ': Moisture?: not d e c . 12 Contract: SAS No.: SDG No.: 95010 Lab Sample.ID: VQA003 Lab File ID: V0VQA03R GC Column: RTX-502.2 ID: 0.530 (mm) Soi 1 Extract Vol ume : (uL) Number TICs found: 2 Date Received: 01/23/95 Date Analyzed: 01/30/95 Dilution Factor: 1-0 Soil Aliquot Volume: .(uL) CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG CAS NUMBER ===•=•============ 1. 76-13-1 2. 1634-04-4 k COMPOUND NAME ETHANE, 1,1,2-TRICHL0R0~l,2, PROPANE, 2-METH0XY-2-METHYL- RT 4.07 5.13 EST. CONC. 45 14 Q ===== ^iWirR JN IDATED. 302624 FORM I VOA-TIC 3 / 9 0 IA VOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO, , Name: ETC/GULF SOUTH Lab Code: GULF Case No.: HLA Matrix: (soil/water) SOIL Sample wt/vol: 5.0 (g/mL) G Level: (low/med) LOW r: Moisture: not dec. 1^5 GC Column: RTX-502.2 ID: 0„530 (mm) Soil E"X tract Vo 1 ume: (uL) Contract: SAS No.: SDG No.: 95010 Lab Sample ID: VQC002 Lab File ID: VOVOCOl Date Received: 01/23/95 Date Analyzed: 01/27/95 Dilution Factor: 1. • O Soil Aliquot Volume: CAS NO. COMPOUND CONCENTRATION UNITS: (uq/L or ug/Kg) UG/KG 0 (uL) 74-87-3 74-83-9 75-01-4 75-00-3 75-09-2 67-64-1 75-15-0 540-59-0 67-66-3 107-06-2 71-55-6 XT. A '—. -r r: s.' : j i... ' . . ' j " >.' ~"" •-» r.-. _ *-;, —»_,. ^ , ^_ _^ _ 78-37-5 10061-01-5- 79-01-6 124-43-1 79-00-5 71-43-2 10061-02-6- 103-10-1— 591-73-6— 127-18-4— 79-34-5 103-88-3— 108-90-7— 100-41-4— 100-42-5— 1330-20-7- • X d e -C |-i 1 o rome than e -E< romome t han e -Vinyl Chloride_ - C h 1 o r o e t hi e. n e - M e t hi y 1 e ri e C hi 1 o i • A c e t o n e -Carbon Disu 1 f ide -1,1-Di chloroethene, -1 , 1 - D i c i - i l o r o e - t h a n e -1 , 2-D i c hi 1 o r oe t hien e ( t o t a l ) - C ! - i l o r o f orm -1 , 2 - D :i. c: t-i 1 o r o e t hi a n e - 2 - B V. t a n o n e -:!., 1,1 - T r i c h .1. o r o e' t hi a rt e _ -Ca!'• bon Tetr.?.ch 1 o r i d e -B romod i chl orome t han e -1,2-Dichloropropane -cis-1,3-Dichloropropene -Trichloroethene -D i t) romo c hi 1 o rome t hian e - 1 , 1 , 2 - T1'- i c h 1 o r o e t hi a n e - B e n z e n e - t r a n s - 1 , 3 ~ D i c l ' i l o r o p r o p e n e -Bromoform - 4 - M e t h y l - 2 - r e n t a n o n e -2-i-iexanone -Tetrachloroethene._ _ -1,1,2,2-Tetrachloroethane -Toluene _ _ -Chloro ben z ene -Ethylbenzene -Styrene_ -Xylene (total) •-¥MJ^AJE Reviewed By S=£: FORM I VOA/yi Date 12 ' 12 12 ; 12 1 2 • 12 : 12 12 ; 12 12 • 1 ' - . .1. i:. 12 12 12 12 12 1 12 12 12 12 12 12 12 12 12 12 12 12 12 12 , U u3- : u uT : J!>-U3": u u T : u t.i u t.l (J t.l u u u u J u tJ .u u .u u ;u u :u • U ;u :u ;u :u 1 ^ 102625 5/90 IE VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS .o Name: ETC/GULF SOUTH Lab Code: GULF Case No.: HLA Matrix: (soil/water) SO.I.L Sample wt/vol: 5.0 (g/mL) G Level: (low/med) LJDU) r: Moisture: not dec. 15 GC Column: RTX-502..,2„. ID:: Q. 530 (mm) Soil EIxtract Volume: (uL) Con tra ct: SAS No.: EPA SAMPLE NO. El0520 SDG No.: 95010 Lata Sample ID: VQC002 Lab File ID: VOVQCOl Date Received: 01/23/95 Date Analyzed: 01/27/95 Dilution Factor: 1_..0 Soil Aliquot Volume: .(uL) Nuni be r TICs found: 1 CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG CAS NtJI-'IBER 1. 1634-04-4 COMPOUND NAME 2-METH0XY-2-METHYLPR0PANE RT 5 . 1 5 Rev; Date 'ALIDAJED 302626 FORM I VOA-TIC '>/90 EPA SAMPLE NO, VOLATILE ORGANICS ANALYSIS DATA SHEET .^ Name: ETC/GULF SOUTH Contract: Lab Code: GULF Case No.: HLA No. SDG No, 95010 Matrix: (soil/water) SOIL Sample wt/vol: Level: (low/med) LOW 3.0 (q/mL) G Lab Sample ID: Lab File ID: VOBOO: VOVQBO: '•: Moisture: not dec. 14 Date Received: 01/23/95 Date Analyzed: 01/27/95 GC Column: RTX~502.2 Soil Extract Volume: CAS MO. II>s 0 - 530 (mm) (uL) D i l u t i o n F a c t o r : 1.0 COMPOUND Soil Aliquot Volume: CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG .(uL) Q 74-83-9 75-01-4 75-00-3 75-09-2 67-64-1 75-15-0 -;.' It: „„-r rn ^i „ 75-34-3 540-59-0- -66-3- lo: •06-: '3-3- 56-23 75-27-4 78-87-5 10061-01-5- 79-01-6 124-48-1 79-00-5 71-43-2 10061-02-6- 108-10-1 591-78-6 127-18-4 79-34-5 103-88-3 103-90-7 100-41-4 100-42-5 1330-20-7— Chloromethane £•: romome t hane V i n y 1 C h 1 o r i d e Chloroethane Methylene (•:hloride Ace-tori e Ca r bon D i s u l f i d e •1,1-Di c h l o r o e t h e n e 1 , l - D i c h l o r o e t h a n e 1 , 2 - D i c h i o r o e t h e n e ( t o t a l ) C h1o r e f o r m • 1,2—D i c h 1 o r o e than e •2—Bu tan o n e • 1 , 1 , l - T r i c h l o r o e t h a n e Carbon Tetrachloride -E<romod i chloromethane -1,2-Dichloropropane -cis-1,3-Dichloropropene -Tri chloroethene - D i bromochiorometl-iane - 1 , 1 , 2 - T r i c h l o r o e t h a n e —E<enzene - t r a n s - 1 , 3 ~ D i c h l o r o p r o p e n e - h r o m o f o rm —4-Me t h y 1-2-F'en t a n o n e - 2 - F l e x a n o n e -Tetrachloroethene -1,1,2,2-Tetrachloroethane? -Toluene -Chilorobenzene -Ethylbenzene —S t y r e n e X y l e n e ( t o t a l ) _ ! ' V A C T I - D A T E Reviev/cd By ^—-fyMV^—^ 1 FORM I VOA l-Z. Date __ ^^5E 12 12 12 12 . ^ 14 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 !U ; :u3" ; ; tj ; :u T ; :js<ruT; •jirlA^. !u ; ; tj 0" ; ;u ; ! t.l ; t) ;u : ;u ;u ; ;u ;u ;u :u ;u ;u ;u ;u ;u ; t.i ;u ;u :u :u :u ;u :u ;u :u 3 0 2 6 2 7 5/90 IE VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS EPA SAMPLE NG, F_«o Name: ETC/GULF SOUTH Lab Code: GULF Case No.: HLA Contract: SAS No.: SDG No.: 95010 Matrix: (soil/water) SOIL Sample wt/vol: 5.0 (q/mL) G Level: (low/med ) I...OW '•-: Moisture: not dec. 14 GC Column: RTX-502.2 ID: O.530 (mm) £> o 3.1 E X t r a c t V o 1 u m e : ( u L ) Lab Sample ID: VQB002 Lab File ID: V0VQB02 Date Received: Date Analyzed: Dilution Factor: 01/23/95 01/27/95 1.0 NuIII ber TICs -f ound : O Soil Aliquot Volume: CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG :uL) COMPOUND NAME RT EST. CONC. Q ' P H ^ ^ - — 302628 FORM I VOA-TIC 5/90 HLA DATA QUALITY ASSURANCE REVIEW SUMMARY Volatile Oreaiiic Compounds Analysis (LOIJ C,0NCg:NTT5Ar(0M) Case Number : C^ ^ Q | Q Project Number 2 ^ y 7 2 . , l 0 - 2 - Site: UU^JJ rJL.:..Jl C JCrYYU/lAyy^^Uy Contractor Laboratory: ?/\Cf: A ^ ^ jf^ ^ g ^ j A . Validator j : | , | i ; ^ , ^ Valid: Validation Date: 2l23m QC Reviewer ^PTuX^/<K*/ 7*! T'^A^M^^y^ Review Date: ? / ^ 9 / ? S ~ ' Sample Matrix: \ ^ J e d O ^ C J ^ EFA (LLP / r u r ^jvvLrj2^:tAX(I^r>- Q/t^^^/yy;^^^ 5ou; Analytical Method: Sample Designations: CB500I S n O l l ^ S o o i i q So 01^0 S00IZ5- Data for the above samples are: Acceptable for use X Acceptable for use as qualified Unacceptable for use Is action required by the Pfoject Manager? Yes ^ ) VlA±L&vtaX FjM\c:^^J-eryyoSl Qx^UMUu^^ji^ v(M_l.doc 10M19M 1032 Fotm VOA \ja 3 0 2 6 2 9 DATA COMPLETENESS CHECKLIST Included, no problems Included, problems Not included NA Not applicable Quality Control Summary X Case Narrative X Surrogate Recovery Summary KlA MS/MSD Summary X Reagent Blank Sunmiary X GC/MS Instiument Performance Summary X Labora.^'rr^ On+rol Sam pie-Summitry Sample Data 4 r Chain of Custody Forms Holding Times X Organic Analysis Data Sheets X Quantitation Reports X Reconstructed Ion Chromatograms X Mass Spectra Printouts X TIC Mass Spectra Library Searches Initial Calibration Data -Jr Calibration Summary X Standards Quantitation Reports X Standards Reconstructed Ion Chromatograms Continuing Calibration Data •y" Calibration Summary X Standards Quantitation Reports X Standaids Reconstmcted Ion Chromatograms X Intemal Standards Summary Instrument Performance Data X BFB Mass Spectra X Reconstructed Ion Chromatogram X BFB Mass Listings voa_l.doc 10141994 1032 Fonn VOA 1 J) 302630 Reagent Blank Data • ^ Organic Analysis Data Sheets X Quantitation Reports X Reconstiucted Ion Chromatograms X Mass Spectra Printouts X TIC Mass Spectra Library Searches Matrix Spike and MatruE Spike Duplicate Data NiA Organic Analysis Data Sheets N^A Quantitation Reports \^f\ Reconstiucted Ion Chromatograms Laboratory Control Sample X Organic Analysis Data Sheets X Quantitation Reports X Reconstructed Ion Chromatograms X Mass Spectra Printouts X TIC Mass Spectra Library Searches Comments: Fonn VOA IJ) vw_l.dDC 10141994 1032 3 302631 Harding Lawson Associates SHEET OF r==:^^p^ Engineering and ; s j ==.:1 Envronmental Services jOB NO. DATE 3l^•^~{^^^ PROJECT J J 4 W K U ^ CJUvituueL,gJ! (^.<rv»>^p<<>KM^ COMPUTED BY C ^ . \ j l L i i ^ S - L SUBJECT Dojfcfl^ {jAl'iJJA-buQ'y^ CHECKED BY y ^ f i ( / Y v \ ^ ^ 0 ^ ^ 0 >SuA^»<-^VV«-«<^V^ Z^So/oizoHf S o o z o SjlS^A-OO] S2>v3lO-zloi^oHF Vhooo-Z \l(il/[-OOZ. Z?so/on^^^ soom Mq^-ooi 53^l/zo-Z'2-/on'}'^5' ^IZtzz- -^a^'OOZ- s^vzlo-o-zojoim^ VZoozo s/q^-oo^ 5E>p^/H'^l/o(l19$' p^nzi V(?B-^^4- S?>BV,0^6'-'Zol,0imf B\05ZO VSC-ODZ- S3B\lo.o-0.?p\m^ £\ooof \JQC-003 K^o/o\z^^6' SODizf Met-00 \ SBPi/o-i/oi^f-^^ Piocoi \I^X'Ooz 5dV\j]z-\^lo\z^^S' Dilzi^V VSx-003 SgPl/z2.-24/o|2f'^r PIZ22M- \/6X~^otf SbCz/O'ljOlSO^f CZDCv\ VTX-^Ol 53CZ.IZc-Zzl0\300)f CZ.Z0Z2. VTX-oot, SBCzlz^-2I.lo(30'\5' CZZiA-ZC MTX-OD^ Rd5oloi30')5' Re>Sooi VTX-cfiif ng 302632 SPECmC COMMENTS REGARDING ANALYSES Chain Of Custody Were samples properiy preserved and received in good condition? Z'YM) NO Were custody transfers cop«e{iy and completely documented? (Yes) No Comments: "TjU^^ C^ir2eAuii^ J^p-^^-^JL j ^ ^ l l ^ O y ^ O^ZV^jtP- / I X L e c O ^ ^t-^T^K- Holding Times Were sample analyses per^pnoed within holding times? /Yes) No Comments: ]V;t Instrument Tuning Did the instrument performance checks meet acceptance criteria? /YeT) No Were samples analyzed within the 12-hour period followine an xceptable performance check? Xves) No Comments: )4.e>viL VOi_l.dDC 10141994 1032 Foim VOA \D 3 0 2 6 3 3 Initial Calibration Did the laboratory meet the method requirements regarding the minimum number of calibration standards for an acceptable initial calibratiop!' /Yes) No Did the inidal calibration curves meet the linearity criteria for maximum percent relative standard deviation (%RSD)? Yes fNol Did the inidal calibration meet the mmimum relative response factor (RRF) criteria? Yes mo) Comments: ^>4CU-tA^J^ QjtrYr\Ay^^A^^:)^. Continuing Calibration Did the continuing calibration cu^es^neet the linearity criteria for maximum percent difference (%D)? Yes CNO ) Did the continuing calibration meet the minimum RRF criteria? Yes neet the Comments: ^ W c - L « ^ t ^ y r O ^ ^ M ^ A u i % V O w i R P y V H l i > ^ 4 ^ J U K ' ^ X ff-O^a^ CXey<):^^ Jx'Y^^J:^. KxJ(;f^:)^yg-4j>^\^ J ^ C^XAxM^Ji^U^ O U ^ D / Vi_0 voa_l.doc 10141994 1032 Form VOA IjD 302634 Surrogate Recoveries Were the surrogate spike recoveries within acceptance limits? / Y ^ No If the spike recoveries were unacceptable, WSRL the samples reanalyzed? Yes No / N A ) Comments: yUu. Matrix Spikes Were matrix spike analyses performed at the correct ftequency and on a sample matrix representative of the samples in the sample delivery group (SIX})? Yes No Were the matrix spike recoveries and relative percent differences (RPDs) within acceptance criteria? Yes No Comments: YH^J^fc^j^ A ^ ^ ^ A J - O^MjdjjijpJLA^ J^>^'\£- K ^ d^V^J- O ^ M J L J C f r i ^ Internal Standards Were the intemal standard-arw^ and retention times within the required limits? nfes) No If the intemal standard requirements were npwnet. were the samples reanalyzed? Yes No ( ^ N A ) Comments: voa_l.doc 10141994 1032 Fonn VOA ID 3 0 2 6 3 5 Blank Analyses Were the appropriate nuin^)er-«f blank analyses performed? (Ves) No Were analytes detected in tti&blanks? /Yes) No If analytes were detected ujjlje blanks, were the same analytes detected in the associated investigative samples? ( Y M ) No NA Did the sample results reqjjiwJiualificaiion due to the presence of analytes in the associated blank samples? rYes) No Comments: j^iU>-tAuiJi o/jM.^dO^Jd'>^>^ M^^AA^ Y/\,xdji. ji.yr>^ J u h ^ ..J^AMy^y^ Laboratory Control Samples Were laboratory control sample (LCS) analyses performed at the correct frequency? ^es) No NA Were the LCS recoveries within acceptable limits? (Yes) No NA Comments: yi&Tut va«_luioc 10141994 1032 Fonn VOA IjO 3 0 2 6 3 6 Sample Results Were target analytes repon^d4n the investigative samples? ^ e s ) No Were mass spectra providoMor the target analytes detected in the investigative samples? ^ e s ) No Were the mass spectra of aee«ptable quality and analytes correctiy identified? (Ves) No Were the quantitated results for target analytes calculated using the appropriate intemal standards and were the relative retention times (R^I^) acceptable? (Y&S) No Comments: "- yl^Hje.- Tentatively Identified Compounds Were tentatively identified^coinpound (TIC) searches conducted for all sample analyses? Q M _ ) NO NA Were non-target peaks evaluated as required? /Yes) No Were the TIC mass specnju-searches, identifications, and quantitated results acceptable? / Y C S ) No Comments: yi^y^^ , . Fonn VOA IJ) VO»_1.0DC 10141994 1032 8 302637 Log Books Were sample preparations,^ft}perly documented and performed in accordance with method protocols? (Yes/ No NA Were sample analyses props^y documented and performed in accordance with method protocols? (Ves) No Comments: yiewiL »o.J.doc '"o™ ^ O * 1-0 10141994 1032 Q 302638 Calculation Checks Instnmient Tuning j Z / l / < ^ ^ . \ Z ^ 0 Relative Abundance: Initial Calibration RRF: l^\\^S-,\^3% f^gr^f> FL50I3H^A %RSD: , ^ r" - ^ X \ 0 0 - %tSD Continuing Calibration Z \ z \ o \ ^ 1715^f RRF: (^x^O^yrU CUl. jL/K^JtuiJ. CU^^^^^-^^cfce-)^) -0A3^^.^^JAi±-^ „ , -_ 2^.3 % .ft >.Tv.ew£U^ Surrogate Recovery SooiM t l Z ^ ^ l o o : : S7. ^ f'o--^ Jm^n^^^u.^^^ »o«.l.<ioc Fonn VOA Ii> 10141994 1032 J Q 3 0 2 6 3 9 Matrix Spike Recovery (^yn^/ntfp yu^ o z ^ p L ^ RPD: Sample Results ^XcUvu^(j2je, S O O I I ^ CRQL: Detected Result: TIC ResuU Js^m/nh, Soo\z^ T-ICL O M I ^ CiMA^vd^ i ^ i . i<i> Qmi:- . voi.l.doc Fonn VOA 1.0 10141994 1032 11 302640 HOLDING TIME QUALIRCATION SUMMARY FORM Sample Identification (au M£u^.-t Date Sampled i^AJr lAyM^yvK • Date Analyzed cP) -" Analysis Holding Time Qualifier to o to Comments: vot.l.Joc 10141994 1013 Fonn VOA I.D 12 INITIAL CALIBRATION QUALIFICATION SUMMARY FORM Date/Time |l/5)/^5- \ / Instrument ^ - \ ( Analyie T(\f±4o^ c Oi^^ 2-^AXXAi/v&-Ki7 . 2-\^ji^(jaA^.e'njp RF 1 >0.05" fi — 0 . 0 X 0 o.oz-} 0.0^ RSD 1 <30fo QC-2 49.^ 33.2- 37.3 Samples Affected nOL .4a^wt)ai^ u Y Qualifier ^z- 3-/P .T/R 1 T/?^ / w o Isi Ch 1 ^ IO voi_).doc I0I4I994 1032 Fonn VOA 1.0 13 CONTINUING CALIBRATION QUALIFICATION SUMMARY FORM Ui o to cn Ui Dale/Time Instrument 2/1/^5; )2fg ^ 'zl'^^^n\5- 2l?\% 1^00 2j\ol% \l\lc £1 £ . ^ £L Analyte Q/:je;t«vuz, Z-Birtii/K^wit 2 - Hjyn/yvjarvUZ riiUt^e 2'6ixfciuHog- 2-t40/yQ/Kenrvg, ffUi^ r l W ^ (WU lfrY\J ^-B.iAJbLM^tlg. ^--H.x^^A'vevu? CiJirumsXt>^M--<^ RF >0.05' 0.022. <9.(92-l /9.03^ aoi£. (2.1222. (?c?H-l o.o\^ CLm± (LMl o.o\^ %D ^30% 4M. M ^ 2^.0 3!id^ ^pz^ Comments: MQA J^^^dbLU>- c s r y ^ h ' ^ Jy^yjckb.. Samples Affected 5 0 o l ( 8 , S 0 0 \ \<\ S 0 0 I 2 Q sof?i7.er R^Soo J^^ Qualifier l/lL j ^ T/R. T/UT T/R T/ie jr/R> T/MJ: J/R ZZK. 3-fe T/UT x/t/ir x/{^ Fonn VOA 1.0 1141994 1012 z/io/^^niG, F • J / R BLANK SUMMARY FORM Blank ID Analyte Blai* Result (units) Action Level Associated Samples weut^ni A/mxiiz. f/[Al,^Pi>^^rllSUfQ. IT JO nt d ^ % i cUlfriKJi, I T JO SOOflS^ S00{\c\ Soo 12.0 ClltASrt^AAx^^jM 0^2 :r 1 MW^sn. ^oilu^^a^ oU^^xJh? 1 T \0 SOO\Z^ \/g>LKQ4- g g T ^ RgSnoi Comments OJ o to it* A>^OAyvvolU, (ley\f<i£ypiKSti^G-A^ J j i ^ ^ ckSU^y^ :k)l^ (Xy(iAA&y^JlsiA>-t^ j L ^ j j ^ ^ (>WWn< Summary and Conclusions f)KzLhu lAjer^.A4^H M ^ ^ AiM.jMi^iAAr^^^n±. Art^oMj Pi, i ) - n . . - ^ . 0 _ - .1 . li • ^ ^ n . n J ^ ^ . . . XL :. ^^...^ Ax Hi \AK^ /Af^KT a / ^ .XP\n,tPyii^JA^^n/lP^xJlA^X^ryu>^^ tn^ k/^^ C&y^^v^uyrd- /"md7/v^A^A^. Oi?0 j|^^7ftLe-K^ . ^XJ2^ (Qjctui^ j £ v Q / ^ i ^ ^ S o n i 7 ^ . S7)OI2^j /i/i^/::^ M S O n \ A9,iO.:h nfrydjuy\iAAy^ 4ULl/Kt-4 CLoJAJU-^dli^.^^ T X e , (^AJT^ A^jg, AXVX^X^pg^Tl A ^ A r t AiU^X^ A ^ P.AAr.il L L ' J L ^ f T Y j A j L Validator's Signamre: L X V f W - ^ , . JA^i^r^H-l^ Validator's Initials: Validation Date: 2>\22>\^S~ QC Reviewer's Signature: ^Zh^JJ/^Ay^ ^A^. -^^A^M^^y.^ QC Reviewer's Initials Pi P P Review Date: P / ^ 9 / ^ S - v«%«_l.doc 10141994 1032 16 Fonn VOA 1.0 3 0 2 6 4 5 ILCA LOW CONC. WATER VOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE ND. I ^b NAtne: ETC/GULF SOUTH r.ab Code: GULF C A Z B N O . : HLA Lab Sample ID: VTXOO'q Lab File ID: V0VTX04 Purge Volume: 25.00 (ml) Contract: SAS Ho.: SDG No.: 95010 Date Received: Date An a1yz ed: Dilution Factor: 02 or :/01./95 V10./9f;. 5 CAS NO. COhPOUND CONCENTRATION (ug/L) Q 7'^-87--3 74-83-9 75-01-'^ 75-00-3 75-09-2 A7-64~l 75-15-0 - 75-35-4 •~7 n: ".*' /I -."' _ / * . » " v . > * - ; • • • * . > 156-59-2 156-60-5 67-66-3 107-06-2 " 7 0 IS".-. -..- /o-'/o—o 74-97- 5 71-55-6 c: / r^,-:- t: "V IT r - , —. jr. 78-87-5- - 100A1-01-5-- 79-01-6 — 124-48-1 79-00- 5-- - 71-43-2 - 1006:1-02-6- ./ • _ ' - < : . ^1 —.il. - 108 10-1: - 591-78-6 - 127-18-^ 106-93-4- 79-34-5 109-88-3 108--90-7 - 100-41-4 100-42-5 1330-20-7— 541-73-1 — 106-46-7 - 9 5-50-1 -• 96-12-8 -Chloromethane -B romome t han e -Vinyl Chloride -C h 1 o roe t han e -He t t"iy 1 G-^n e C h lori ci e -Acetone --Ca r bon D i i>u 1 f 1 cl e - 1 , 1 - D i c h l o r o e t h e n e - 1 , 1 -I) 1 c i'l 1 c) i-c>e t hane -cis-1 .,2-Di chloroethene - t r a n s i - l , 2 - D i c h l o r c i e t h e n e - C h l o r o f o r m -1 J 2—D i d llo roe thane -2-Butanone -B romo c; h 1 o rofne t I'lari e - 1 , 1 ,1—Tri chloroe-c.hane - C a r t) o n T e> t r a c: h 1 a r i cl e _. -Bromodichloromethane - 1 , 2 - I > i c|-i] o r o p r o p a n B - c i s - 1 ^ 3 - D i c 111 o r o p i - o p e n e - T r i c|-i 1 o r o e t l i e n e - D i Irj r o m o c h 1 o r o m e t I'i a n e - 1 , 1 . , 2 - T r i f.-.ti.l.oi-cje-tl-iarie - B e r I:;: e ;• I e __ _ - t r a n s - 1 . 3 — D i c f i l c j i ' C J t ' r o p e n e - B r o m o f o i-- rn - 4 - M e t h y ]. - 2 • - F-' e r v t a n o r^ e ^___ _ - 2 - H e x a n o n e - T e ' l . r a c h l c j i ^ o e t h e n e - J. ^ 2 - D i ta r o m o c-1 h -rx n o - 1 , 1 , 2 , 2 - T e t r a c h l o r o e t l i a n e . _ - T' o 1 u e i-i e —C 111 o I'c.:' t;"e>ri 7 ei'i e —Ethyl ben zei le _ —S l yrcz^ |-1 e _ _ - y. A1 e n e ( t o t a 1) _ - :l , 3 - D i c h ]. o r o ben:;: eri e - 1 ., 4 - D i c: I-i 1 o I - o 1 j e i-i 7 e I'l e ; - 1 ,2—D i c: I'-l :i. o rCj beri 7. ene_,, - 1 n 2 - D i b romo—3— c li 1 o |-o p r o p a n c- I'Cii-.;!^" i Lev 12 12 L I T u u •^ R J L.! IJ 11 II u L.I IJ IJ I I '...• U !..l L.1 > I KJ L.l l..i U !J Ij U l.l IJ IOATE 111 0 / 9 ; n Hato '23 h ^ 302646: ILCE LOW CONC. WATER VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS EPA SAMPLE NO. b Name: ETC/GULF SOUTH Lab Code: GULF Case No.: HL.A Lab Sample ID: VTX00-<i Lab File ID: V0VTX04 Purge Volume: 25.00 (ml) Contract: SAS No.: SDG No.: 95010 Date Received: 02/01/95 Date Analyzed: 02./10/,?,5 Dilution Factor: 2.5 Number TICs found: 0 CAS NUMBER COMF-OUND NAME RT EST. CONC ( u g / L ) Q FORjvi I L C V - T I C 3 02 647 1 0 / 9 2 ILCA LOW CONC. WATER VOLATILE ORGANICS ANALYSIS DATA iSHEET EPA SAMPLE NO. ^ 1 -b Name: ETC/GULF SOUTH *.ab Code: GULF Case No.: HLA Lab Sample ID: VOCOOl Lab File ID: VOVQCOlRl Purge Volume: 25.00 (ml) Contract: SAS No.: SDG No.: 95010 Date Received: 01/23/95 Date Analyzed: 02/01/95 Dilution Factor: 1.0 CAS NO. COMPOUND CONCENTRATION (ug/L) Q 74-87-3 74-83-9 75-01-4 75-00-3 75-09-2 67-64-1 75-15-0 75-35-4 75-34-3 1 5 6 - 5 9 - 2 — 156-60-5 67-66-3 — 1 0 7 - 0 6 - 2 — 74-97-5 7 1 - 5 5 - 6 — — 56-23-5— • 75-27-4 78-87-5- - 10061-01-5- 79-01-6 124-48-1 79-00-5 71-43-2- - 10061-02-6" / -.V"'" JL.. C' JL\. ~* ~ 108-10-1 591-78-6 1 2 7 - 1 8 - 4 — 106-93-4 79-34-5 108-88-3 1 0 8 - 9 0 - 7 — 100-41-4 - 1 0 0 - 4 2 - 5 — 1330-20-7— 541-73-1 — 1 0 6 - 4 6 - 7 — r \ v.: r: /*•, -i •7 ...i~ ^ y j — .1. - — - Q /, •• '•> O -Chloromethane —B romome than e -Vinyl Chloride -Chloroet hane -Metliy 1 e n e C111 o r i d e - A c e t o n e —Ca r bon D i s u 1 f i ci e? - 1 , 1 - D i c h l o r o e t h e n e I - 1 , l-I>ic:hloroet!"ianC' — c i s - 1 p 2-D i ch 1 o r o e t h e n e - t r a n s — 1 ^ 2~Di chlciroethenc^ - C h l o r o f cjrm - 1 , 2 - D :i. c h i c I'OO t hiari e ^ -2-Butc^none -B r ome- c h 1 CJ r ome-r t lian e - 1 , 1 , l - T r i c h l o r o e t h a n e -Carbori Te^trac:h 1 c r i d e -Bromod i c h l o r c j m e t h a n e - 1 , 2 - D i c h l o r o p r o p a n e - c i - s - 1 . , 3 - D i cj-i 1 o r o p i - o p e n e •-T r i c 1^ 1 o r o e t herie-> — D i b r o m o c h l o r o m e t h a n e •-1 , 1 , , 2 - T r i ct-11 oi-oethiane —Benzene — t r a n s - 1 ^3-Di clilorc^propene •—Bromoform —4~MG^ t hy 1 - 2 - F-'e?n t a n o n e •-2~Hexanone —Te t r a c h 1 o ron.": t hen e — 1., 2 - D i brornoe t h a n e — 1 , 1 , 2 , 2 - T e t r a c h l o r o e t h a n e _ — T o l u e n e —Chloroben z ene —Ethyl benzene —Styrene —Xylene (total) '_ ~iS..~. — J. , 3-1>:i. cfl 1 CJrot)e->ri z e n e - - 1 , 4 - D i c h l c j r o b e n z e n e ••-1 , 2 - D i cl-riorobc^n z e n e - - 1 , 2 - D i b r o i T i o - 3 - c h l o r o p r o p a n e FORM I LCV V 1 ; 1 ; 1 : 1 ; ' - I 1 A.. 1 5 1 0 . 3 ; 1 ; 1 ; 1 ; 1 1 ! 1 ! 5 ; 1 ; 1 : 1 •i 1 1 1 : 1 1 •1 .1. 1 1 1 5 5 1 •1 1 0 . 2 1 1 1 •1 1 1 1 L.I U U U J I...I L.l U L.l L.I L.l L.l (.1 U ; 1 L.l l.l LJ L.1 1 ] L.1 IJ U Ll L.l ! L.l M ; L.l ;u ;u ;u : L.l ! L.l ; L.l Reviewed By Dfltp >/92 ILCE LOW CONC. WATER VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS EPA SAMPLE NO. b Name: ETC/GULF SOUTH Lab Code: GULF Case No.: HLA Lab Sample ID: VQCOOl Lab File ID: VOVOCOlRl Purge Volume: 25.00 (ml) Contract: SAS No.: SDG No.: 95010 Date Received: 01/23/95 Date Analyzed: 02/01/95 Dilution Factor: 1.0 Number TICs found 0 CAS NUMBER COMPOUND NAME RT EST. CONC. ( u g / L ) Q Reviev/c! F. Date VM! DATED ^3/zjh^ ^ FORi-'l I LCV-TIC 302649 lOZ'': ILCA LOW CONC. WATER VOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. b Name: ETC/GULF SOUTH Lab Code: GULF Case No.: HLA Contract: SAS No.: Lab Sample ID: VQBOOl Lab File ID: VOVQBOl Purge Volume: 25.00, (ml) SDG No.: 95010 Date Received: 01/23/95 Date Analyzed: 02/02/95 Dilution Factor: 1.0 CAS NO. COMPOUND CONCENTRATION (ug/L) Q 7 4 - 8 7 - 3 7 4 - 8 3 - 9 7 5 - 0 1 - 4 7 5 - 0 0 - 3 7 5 - 0 9 - 2 6 7 - 6 4 - 1 7 5 - 1 5 - 0 —> 12 -y K /I 7 5 - 3 4 - 3 1 5 6 - 5 9 - 2 — 1 5 6 - 6 0 - 5 — 6 7 - 6 6 - 3 1 0 7 - 0 6 - 2 - 78"-93-3 7 / 1 . . . 9 7 - S Z7-4 1 0 0 6 1 - 0 1 - 5 — 7 9 - 0 1 - 6 1 2 4 - 4 8 - 1 - " y o . . . . ' ' i , ' ' - , . . . . •-•• 1 0 0 6 1 - 0 2 - 6 — -7 n tr r: ^ 1 0 8 - 1 0 - 1 5 9 1 - 7 8 - 6 1 2 7 - 1 8 - 4 1 0 6 - 9 3 - 4 7 9 - 3 4 - 5 1 0 8 — S o - 3 1 0 8 - 9 0 - 7 1 0 0 - 4 1 - 4 1 0 0 - 4 2 - 5 1 3 3 0 - 2 0 - 7 — 5 4 1 - 7 3 - 1 1 0 6 - 4 6 - 7 ,"•. ;• -| 'T.....r;. —Chlorc^metl"ian€? —Bromomethane -Vinyl Chloride -Chloroethane -Me t hy 1 ene C h 1 or i de^ -Acetone , -V,Arbon D i su 1 f i d e -1,1-D i ch1o roe then e -1,1-Di chloroethane - c i s - 1 , 2 - D i c h l o r o e t l ' i e n e -trans-1,2-DJ chloroethene -Chloroform — .1,2 - D :i. c: h 1 o r o e t r 1 a n e — 2 - B u t a n o r i e - B r ofncj c Li 1 o r o m e t tian e - 1 , 1 ; , 1 - T r i c h l o r o e t l - i a n e - C a r b o n T e t r a c h 1 o r i d c ^ • - B r o f 11 o d i c hi 1 o r o m e t hi a n e •-1,2-D:i. c h i o r C j p r o p a n e • - c i s — 1 , 3 - D i c l"i l o r o p r o p e n e —T I" i c: Ll 1 o r o e t Liene —I) i IJ r o m o c li 1 o r o m e Li-ian e — 1., 1 , 2 - l i - i C M l o r o e t h a r i e —Ben z e n e -— t r a n s—1,3—D i c 111 o r o p r o p e n e___ —E r o m o f o r m — 4 - M e t h y l - 2 - P e n t a n o n e — 2 - H e x a n o n e -Te^ tra c hi o r 0 0 1 hevie — 1,2-Di bromoethane "—;i ., 1,2,2—Tetrac:t'ilc:iroetl'iaric-;'_ _ —Toluene —Chloroben zene _ _ _ —Ethylbenzene_ —"Btyrc^ne _ , _ — X y l e n e ( t o t a l ) . . . " I I _ I I I I _ I " I ' 1., 3 - D i c h l o r o b e n z e n e - - 1 ,, 4 - D i c h l o r o b e n z e n e — 1 , 2 - D i c h l c j r o b e i i /-ene • — 1 , 2 - D i b r o m o - 3 - c h l o r o p r o p a r i i - FORh I 1 0 . 1 1 1 1 1 1 1 :i. 1 1 1 1 i . . 42 •4 J. J. 1 1 1 1 J. 5 1 .4 .1. 1 •1 J. 1 .1 1 4 .1. 1 ;u ;u :u ;u : T ;u ; L.l 1 1 1 1 ^ • ' ; L.l 1 1 1 1 <-•• ; L.1 ; L l . :u ;u :u :u :u ;u :u ' ; 1 ; 1.1 ;Li !U Ll> R 1 0 / 9 2 ILCE LOW CONC. WATER VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS b Name: ETC/GULF SOUTH Contract: 'Lab Code: GULF Case No.: HLA SAS No.: EPA SAMPLE NO. S00119 SDG No.: 95010 Lab Sample ID: VQBOOl Lab File ID: VOVQBOl Purge Volume: 25,..00 (ml) Date Received: 01/23/95 Date Analyzed: 02/02/95 Dilution Factor: 1.0 Number TICs found: CAS NUMBER COMPOUND NAME RT EST. CONC. ( u q / L ) Q Reviewed By Date VAilDAT^D FQR'A, I LCV-TIC 302651 / / 9 2 ILCA ' L(5W CONC. WATER VOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. t Name: ETC/GULF SOUTH ab Code: GULF Case No.: HLA Lab Sample ID: VQAOOl Lab File ID: VOVQAOIR Purge Volume: 25.00 (ml) Contract: SAS No.: SDG No.: 95010 Date Received: 01/23/95 Date Analyzed: 02/03/95 Dilution Factor: 1.0 CAS NO- COMPOUND CONCENTRATION (ug/L) Q 74-87-3 74-83-9 75-01-4 75-00-3 75-09-2 67-64-1 75-15-0 75-35-4 75-34-3 156-59-2 156-60-5 67-66-3 107-06-2 74-97-5 56-23-5 75-27-4 "•'^•'-..r?""'_.. "^ ...„ 10061-01-5 79-01-6 124-48-1 10061-02-6 108-10-1 591-78-6 1 2 7 - 1 8 - 4 — — 106-93-4 79-34-5 103-88-3 108-90-7 100-41-4— 100-42-5 1330-20-7 541-73-1 106-46-7 - r\ c: _„ c: f...... -i „_ 96- -Chloromethane -B romome tiiane -Vinyl Chloride -Chloroethane -Methylene Chloride -Acetone -Carbon Disu 1 fide^ -1,1—Dichloroethene -1,1-Di c Lll oroet hane — c i s— 1;, 2~D i c h 1 o roe t hen e - t r a n s v - 1 , 2 - D i c h l o r o e t h e n e - C h l o r o f o r m - 1 , 2 - D i c h 1 oroc? t Lian £• ~2~Butanon(? -B romo c h 1 o rome t Lian e - 1 , 1 . , l - T r i c h l o r o e t h a n e -CarLjori T e t r a c h 1 o r i c i e -Bromodi ci^l oromet hane — 1,2—D i c h 1 oro f:> rCj pane - c i s - 1 , 3 - D i c l ' i l o r o p r o p e n e - T r i c h i o r o e t he;ne -D i b romo c i"i 1 o rome 11 "ian e - 1 , 1 , 2 - T r i c h l c j r o e t h a n e —Ben z en e — t r a n si - 1 , 3 - D i c: h 1 o r a p r o p e n e -Bromo-form -4-r'iethyl-2-Pc-?ntanono>? —2—Hexanone —Te t r a c I'll o r cje t Lieri e - 1 , 2 - D i bromoe^thane: — 1 , 1 , 2 , 2 - T e t r a c Li 1 o r o e L hi a n e - T o l u e n e -Cl-ilorobe-jrizenc:' — E t h y l b e n z e n e - S t y r e n e —'Xy 1 en e ( t o t a l ) — 1 , 3 - D i ciilc-)r-ol:)enzei'ie - 1 , 4 - D i c: 11 ]. o r o b e n z e ri e 1 , 2 - D i cLilorot>enzene - 1 , 2 - D i l3 r o m o - 3 - c h 1 o !'• CT p r o p a n e 1 1 1 1 4 6 1 .1 1 1 1 1 1 5 1 1 1 1 •I J. .1 1 .i. 1 1 1 1 3. 1 1 1 1 1 1 1 U U L.1 T L.l IJ U Ll U U U u u L.l L.l L.1 U U U I.J U L.l U Ll LUK R U U Ll U L.l U U Ll U FORM I LCV Reviewed By Date in vo CM o n ^EM^ ILCE •LOW CONC. WATER VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS EPA SAMPLE NO. Lab Name; ETC/GULF SOUTH L-.D Code: GULF Case No.: 1;1L^A_ Lab Sample ID: VQAOOl Lab File ID: VOVQAOIR Purge Volume: 25.00 (ml) Contract: SAS No.: SDG No.: 95010 Date Received: 01/23/95 Date Analyzed: 02/03/95 Dilution Factor: 1.0 Number TTCs found: CAS NUMBER COMPOUND NAME RT EST. CONC. ( u g / L ) 0 V Reviewed By Date F0RI1 I LCV-TIC 302653 10/92 ILCA L^W CONC. WATER VOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. I ab Name: ETC/GULF SOUTH "„ab Code: GULF Case No. Lab Sample ID: VSIOOl Lab File ID: VOVSTOIR Purge Volume: 25.00 (ml) HLA Contract: SAS No.: SDG No.: 95010 CAS NO. COMPOUND Date Received: 01/27/95 Date Analyzed: 02/08/95 Dilution Factor: 1-0 CONCENTRATION (ug/L) 74-87-3 75-01-4 75-00-3 75-09-2 67-64-1 75-15-0 75-35-4 • " t It; " T /i •*:' ••Z'CJ- 156-60-5 67—66—3 107-06-2 ~y 1"' „_ o "^ "• •_ — „ . - 7 •'. t^ >^ . _ / ! _ _ _ „ „, 75-27-4 10061-01-5 124-48-1 10061-02-6 - 108-10-1 591-78-6 127-18-4 106-93-4 79-34-5 108-88-3 108-90-7 100-41-4 100-42-5 1330-20-7 106-46-7 95-50-1 Chlorome? thane- Bromomethane Vinyl Chloride Chloroethane Methylene C h1o r i d e Acetone Carbon Disulfide 1,1~D i c h1o roe t hen e 1 , 1 - D i c l i l o r o e t h a n e c i s - 1 ^ 2-D i c IT 1 o r o e t h e n e -1 r a n s - 1 , 2 - D i c h1o r o e t hen e •CiTlorof orm - 1 , 2 - D i c h 1 o r o e t ban e -2.-E*utanone -B romo c lil o rome t l^ian e 1,1,1—TriciTloroetl-iane -Carbon T e t r a c l - i l o r i c l e -Bromod i c IT l o rome tiian e - 1 , 2 - D i c h l o r o p r o p a n e - c i s - l , 3 - D i cIT 1 o r o p r o p e n e _ -T r i c h 1 o r o e t hen e -Dibromochloromethane " J.., 1,2-T r i. c Ll 1 o r o e t Liein e -Benzene " t r a n s - 1 , , 3-Di chloropropene-? -Bromoform " 4 - r ' i e t h y l - 2 - P e n t a n o n e ;.._. -2-He X an on e -Te t r a c h l o r o e t Lien e -1 •,2~Di bromoethane? • 1 , 1 , 2 , 2 - T G - ? t r a c h l o r o e t hane - T o l u e n e "C ll 1 o r c:< ben z en e -iEthyl bt?iT z e n e - S t y r e n e -Xy 1 en e ( t o t A 1 )~I." I'J U ' ZZ.. -1,3—D i c hi o r o brT?n z en e - 1 , 4 - D i c h1o r o ben z en e -1,2—Di chlorot)e?n zene_ - 1 , 2 - D i b r o m o - 3 - c i T l o r o p r o p a n e FORM I LCV V Reviewed By 1 1 1 4 1 1 1 1 1 J. 5 d. 1 1 1 1 .1 J. 1 J. 1 1 1 J. 1 1 0 . 2 1 1 1 1 1 1 1 1 'uU^R • ^ R Ll IJ L.i 1., 1.1 U U L.1 i..i U LJ U 11 •wi^R L.l U LJ .1 LJ LJ LJ l.J 1.1 l.J Li IJ in CM o n 1 0 / 9 2 , - ILCE LOW CONC. WATER VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS EPA SAMPLE NO, J Name: ETC/GULF SOUTH Lab Code: GULF Case No.: HLA Lab Sample ID: VSIOOl Lab File ID: VOVSIOIR Purge Volume: 25.00 (ml) Contract! SAS No.: SDG No.: 95010 Date Received: 01/27/95 Date Analyzed: 02/08/95 Dilution Factor: 1.0 Number TICs found: CAS NUriBER COMPOUND NAME RT EST. CONC, (ug/L) Q 1. 75-69-4 TRICHLOROFLUOROMETHANE av>i Reviewed Cy Date 302655 FORM I LCV-TIC 1 0 / 9 2 HLA DATA QUAUTY ASSURANCE REVIEW SUMMARY Low Concentration Volatile Organic Compound Analysis C:ase Number: 95020 Project Number: 29872 10.2 Site: Island Chemical Company Contractor Lab: Pace Enviromnental Labs, St. Rosa, LA Validator: Kirsten Meier QC Reviewer: '^'^i^i^Aja^ ^ P ^ ^ ^ ^ M ^ VaUdation Date: 6 April 1995 Review Date: V-^'d - ^ J ~ Sample Matrix: water Analytical Method: CLP low concentration method Sample Designations: RBSO/012495 (SO00I2) RBSO/012795 (SO0127) RBSO/013195(BSO013) Data for the above samples are: [ ] Acceptable for use [x] Acceptable for use as qualified [ ] Unacceptable for use Is action required by the Project Manager? Yes No[x] Comments: Tha data was reviewed in accordance with the EPA Functional Guidelines, February 1994. 302656 w«_elcc.Il 12291994 1330 Fonn VOA l.l CneNuofcen 9SCB0 Froject NuBfeer 29g72 10.2 SMD ID: ktaid Ormir»l Coopaqr DATA COMPLETENESS CHECKUST [x] Included, no problems [*] Included, problems [O] Not included [NA] Not applicable Quality Control Summary X Case Narrative X Surrogate Recovery Summaiy ^NA MS/MSD Summaiy * Reagent Blank Summaiy X GC/MS Instrument Performance Summaiy Sample Data ._* Chain of Custody Forms X Holding limes * Organic Analysis Data Sheets X (Quantitation Reports X Reconstructed Ion Chromatograms X Mass Spectra Printouts X TIC Mass Spectra Library Searches Initial Calibration Data * C!alibration Summaiy X Standards (Quantitation Reports X Standards Reconstructed Ion Chromatograms Continuing Calibration Data * (Calibration Summary X Standards (Quantitation Reports X Standards Reconstructed Ion Chromatograms X Intemal Standards Sununaiy Instrument Performance Data X BFB Mass Spectra X Reconstructed Ion Chromatogram X BFB Mass listings voa elec.ll ' 2 » " » < ' 5 » 2 Fonn VOA 1.: 302657 CMcNmken 93020 PitjoO Nmfccr 29872 10.2 She ID: bkmd ChmiCTl Coa|Bq)r Reagoit Blank Data X Organic Analysis Data Sheets X Quantitation Reports X Reconstructed Ion Chromatograms X Mass Spectra Printouts X TIC Mass Spectra library Searches Matrix Spike and Matrix Spike Duplicate Data NA Organic Analysis Data Sheets NA (Quantitation Reports NA Reconstructed Ion Chromatograms Laboratory Conti-ol Sample X Organic Analysis Data Sheets X (Quantitation Reports X Reconstructed Ion Chromatograms X Mass Spectra Printouts NA TIC Mass Spectra library Searches Clomments: None vn elec.ll 12:^1994 1S30 3 Fom. VOA l.l 302658 C H B Nunber: 9SBD PrajsM Nmben 29S72 10.2 She ID: bhnd CtEaiical C C B ^ B ^ SPECtFIC COMMENTS REGARDING ANALYSES Chain Of Custody Were samples properly preserved and received in good condition? Yes[x] No Were custody transfers correctly and con^letely documented? Yes[x] No Comments: The Chain of Custody forms submitted with the data were not signed and dated by the lab upon sample receipt. No qualification of data. Holding Times Were sample analyses performed within holding times? Yes[x] No Conunents: None Instrument Tuning Did the instrument performance checks meet acceptance criteria? Yes[x] No Were samples analyzed witiun the 12-hour period following an acceptable performance check? Yes[x] No Comments: None «aa_ekc.l 1 I2»1994 13M Fonn VOA l.l 302659 Caae Nunber 93020 Projeo Nunber: 29S72 10.2 Site ID: Islaad Oirniiffal Cewi^mny Initial Calibration Did the laboratory meet the method requirements regarding the minimum number of calibration standards for an acceptable initial calibration? Yes[x] No Did the initial calibration curves meet the linearity criteria for maximum percent relative standard deviation (%RSD)? Yes No[x] Did the initial calibration meet the minimum relative response factor (RRF) criteria? Yes No[x] Comments: See table "Initial Calibration Summary". Detections for the listed analytes in the investigative samples were qualified as estiinated (J). For the analytes where the relative response factors did not meet the QC criteria of 0.05, reported detections were qualified as estimated (J), while non-detections were rejected (R). Continuing Calibration Did the continuing calibration curves meet the linearity criteria for maximum percent difference (96D)? Yes No[x] Did the continuing calibration meet the minimum RRF criteria? Yes No[x] Comments: See table "Continuing (Calibration Summary". For the analytes with an RRF below 0.05, detected results in the investigative samples were qualified as estimated (J), while non-detections were rejected (R). voi.elec.ll 12291994 15» 5 Fom. VOA 1.1 302660 Cue Nunber 99020 Pnjecl Nunber 29S72 lOJ Site ID: bland OnnkBl Cewr^mny Surrogate Recoveries Were the surrogate spike recoveries within acceptance limits? Yes[x] No If the spike recoveries were unacceptable, were the samples reanalyzed? Yes No NA[x] Comments: None Matrix Spikes Were matrix spike analyses performed at the correct frequency and on a sample matrix representative of the samples in the sample delivery group (SDG)? Yes No NA[x] Were the matrix spike recoveries and relative percent differences (RPDs) within acceptance criteria? Yes No (Comments: Not applicable Internal Standards Were the intemal standard areas and retention times within the required limits? Yes[x] No If the intemal standard requirements were not met, were the samples reanalyzed? Yes No NA[x] Comments: None >pai_ekc.ll 12291994 1530 6 Fonn VOA l.l 302661 CaacNui^Kr 9J020 Piqea Nunber 29g72 10.2 Sik ID: bland Chmw^l Coa^nqr Blank Analyses Were the appropriate number of blank analyses performed? Yes[x] No Were analytes detected in the blanks? Yes[x] No If analytes were detected in the blanks, were the same analytes detected in the associated investigative samples? Yes[x] No NA Did the sample results require qualification due to the presence of analytes in the associated blank samples? Yes[x] No Comments: See table "Blank Summaiy" for blank contaminants and associated samples and qualifiers. Detections of the listed analytes in the investigative samples below the action level were qualified as undetected (U). Results which were less than the Contract Required Quantitation Limit (CRQL) were raised to the CRQL. The storage blank VIBLKOl also had detections and the samples were qualified accordingly. Laboratory Control Samples Were laboratory control sample (LCS) analyses performed at the correct frequency? Yes[x] No NA Were the LCS recoveries within acceptable limits? Yes[x] No NA Comments: No raw data was submitted for the LCS. QC criteria were evaluated from the submitted summary. voa_elec.Il 12291994 13M 7 Fonn VOA l.l 302662 Caae Nunber 9»20 Pmjea Nunber 29872 10.2 Sile ID: bland Cbemial CoofKny Sample Results Were target analytes reported in the investigative samples? Yes[x] No Were mass spectra provided for the target analytes detected in the investigative samples? Yes[x] No Were the mass spectra of acceptable quality and analytes correctly identified? Yes[x] No Were the quantitated results for target analytes calculated using the appropriate intemal standards and were the relative retention times (RRTs) acceptable? Yes[x] No Comments: Due to the veiy low response factor for Acetone, the detection of this analyte in the samples SOOO 12 and S00127 were so large, that the samples had to be diluted. For sample S00012DL the result of 640 ug/l of acetone still exceeded the maximum analytical range of 625ug/l. Therefore the result of Acetone in sample S00012DL was qualified as estimated (J). Tentatively Identified Compounds Were tentatively identified compound (TIC) searches conducted for all sample analyses? Yes[x] No NA Were non-target peaks evaluated as required? Yes[x] No Were the TIC mass spectra, searches, identifications, and quantitated results acceptable? Yes[x] No Comments: No TICs were reported. voa_elec.ll 122»'99« IS» 8 Fonn VOA l.l 302663 CaaeN.mfaen 9S120 Prajecl Nuaber 29S72 10.2 Sile ID: bbnd Oirgbiml Cat^mf Log Books Were sample preparations properly documented and performed in accordance with method protocols? • Yes[x] No NA Were sample analyses properly documented and performed in accordance with method protocols? Yes[x] No Comments: None voa elec.ll 122^1994 1330 9 Fonn VOA 1.1 302664 CaaeNvmber 99020 Piejea NuiAer 29K72 10.2 Siks ID: bhnd Chrm«ml Ceoiw Calculation Checks Instrument Tuning, 1-31-95, 15:24, 177 m/z, based on mass 176 Relative Abundance: 518 •~~ X 100% = 6.3919 8104 Initial Calibration, 1-31-95, VStd025, Acetone RRF: ( 23645 ) X ( 5 ) ( 75880 ) X ( 125 ) %RSD: 0.0098 X 100% = 48.4289 0.0202 Contmuing Calibration, 2-8-95, 13:00, Acetone RRF: ( 5578 ) X ( 5 ) ( 86643 ) X ( 25 ) %D: 0.020 - 0.013 X 100% = 35.0 0.020 Surrogate Recovery, S00127, BFB % Recovery: 4.826 X 100% = 96.52 0.0125 0.0129 vol elec.ll 1229)994 13M 10 Fom VOA l.l 302665 Caae Nunber 93020 Pn^eel Nunber 29S72 lOJ Sile ID: bbnd Cbecikal Company LCS Recovery, VLCS, 2-3-95, Benzene % Recovery: 149 125 Sample Results CRQL: X 100% = 119.2 Detected Result, S00012, Acetone 87834 X 5 = 482.22 75894 X 0.012 , TIC Result, none detected vo«_elec.ll 12N1994 1530 \ \ Fonn VOA l.l 302666 Caae Number: 95O20 Projert Number: 29J72 10.2 Site ID: btand Chemical Cooq^any HOLDING TIME QUALIFICATION SUMMARY FORM Sample Identification Date Sampled Date Analyzed Analysis Holding Time Qualifier Comments: None Ui o NJ - J vo«_eleo.ll 12291994 1330 12 Fom. VOA l.l Cue Nimber: 950X Projoa Number: 29r72 10.2 Sile ID: Ulaixl Chanical Company INITIAL CALIBRATION QUAUHCATION SUMMARY FORM Date/Time 1-31-95 Instrument F Analyte Acetone Methylene Chloride 2-Butanone 2-Hexanone RF 0.012 0.017 0.032 RSD 48.9 60.8 33.2 37.3 Samples Affected all investigative samples all investigative samples all investigative samples all investigative samples Qualifier J/R J/- J/R J/R Comments: None LO o to a\ o\ 00 va_eleo.ll 12291994 1330 13 Form VOA l.l w o to a\ a\ C e Number: 95020 Projcrt Number: 29^72 10.2 Sile ID: blaivl Chemical Company CONTINUING CALIBRATION QUAUHCATION SUMMARY FORM Date/Time 2-3-95, 17:21 2-6-95, 16:00 1 2-8-95, 13:00 Instrument F F F Analyte Methylene Chloride Acetone 2-Butanone 2-Hexanone Methylene Chloride Acetone 2-Butanone 2-Hexanone Methylene Chloride Acetone 2-Butanone 2-Hexanone RF 0.012 0.016 0.032 0.012 0.015 0.033 0.013 0.019 0.041 %D 44.0 40.0 30.4 34.7 38.9 40 34.8 32.6 45.5 35.0 „ . ~ Samples Affected S00012,S00012DL S00012,S00012DL S00012,S00012DL S00012,S00012DL S00127 S00127 S00127 S00127 S00127DL, BS0013 S00127DL, BS0013 S00127DL, BS0013 S00127DL, BS0013 Qualifier J/UJ J/R J/R J/R J/UJ J/R J/R J/R J/UJ J/R J/R J/R Comments: None voa.elcc.ll 122919*1 1330 14 Form VGA l.l OJ o to o Caae Nunber: 93020 Projecl Nunber: 29772 10.2 Sile ID: bbnd Chemical Ccmpaiiy Comments: None BLANK SUMMARY FORM Blank ID VBLKOl VBLK02 VBLK03 VIBLKOl Analyte Methylene Chloride Methylene Chloride Methylene Chloride Methylene Chloride Toluene Blank Result (units) 1 2 1 1 0.1 Action Level 10 20 10 10 0.5 Associated Samples S00012, S00012DL S00127 BS0013, S00127DL all investigative samples all investigative samples voa_eleo. 11 12291994 1330 15 Fom. VOA l.l CaaeNui^Br 93020 Pn>)ee> Nunber 29872 10.2 Sile ID: bbnd Cbenaial Ceo^sEy Summary and Conclusions The analytical results for the low concentration volatile analyses are acceptable for use as qualified. Non-detections for Acetone, 2-Butanone and 2-Hexanone were rejected (R) and detections were qualified as estimated due to low response factors in the initial and continuing calibration. The results for Methylene Chloride were qualified as estimated (J) because the QC criteria in the initial and continuing calibrations were exceeded. Detections of Methylene Chloride and Toluene in the investigative samples below the action level were qualified as imdetected (U) due to blank contamination. When the detection of Acetone exceeded the calibration range, the lab marked that result with (E). The reviewer qualified these results as estimated (J). Validator's Signature: Validator's Initials: QC Reviewer's Signature QC Reviewer's Initials: liL^Un hUt/^ kh . f ^ - U . ^ ^ ^ ^ . ^yC^^^y^ Mr/' Validation Date: ^ - ^ - f S Review Date: V~ /o - f j ~ vaa_elec.il 12291994 1330 16 Fom. VOA 1.1 302671 ILCA LOW CONC. WATER VOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. Lab Hame: ETC/GULF SOUTH •:. Code: GULF Case N c : HI,...A Lab Sample ID: W G O O l Lab File ID: V O W G O l Purge Volume: 25.00 (ml) Contract: SAS No.: SDG No.: 95020 CAS HO, COinPOUHD Date Received: 02./03/95 Date Analyzed: 02/08/95 D i l u t i o n Fcuctor: 1.0 CONCENTRATION (ua/L) Q 74-83-9 75~0:l.-4 75-00-3 75-09-2 67-64-1 75-15-0 75-35-4 "•J XT. - y / - - : ' _ / -••-o-. —..> 156-59-2 156-60-5 67-66-3 — • :i. 07-06- 2 /" B — 9 3 • - 3 74-97-5 71-55-6 56-23-5- — 78-S7-5- -- 10061-01-5- 7 9 - 0 1 - 6 — .1. .-..•i- '•><:J I. 79-00-5-- 71-43-2 10061-02-6- 7 !.".i—2 5 ••/:'. i08-io-:i — 591-78-6 1 2 7 - 1 8 - 4 — 106-93-4 79-34-5 108-88-3-— 1 0 8 - 9 0 - 7 — 100-41-4 1 0 0 - 4 2 - 5 — 1330-20-7— 541-73-1 — 1 0 6 - 4 6 - 7 — 95-50-1 96- -C I'll oromet hane -B romome t lian e -Vi nyl Chloride -C h1o roe than e — Me t hy 1 e?n e C h 1 o r i d e -Acetone -Carbon Disul-f ide — 1,1-Di chloroethene — 1 , 1 - D i c i i l o r o e t h a n e — c i s - 1 ^ 2-D i >r. h 1 o r o e 11 van e — t r a n ? ; - 1 ,2~Di c h i o r o e t h e n e -C!-iloroform — 1 , 2 - D i c h 1 oi-oe t i-iane -2-B'..t. t a n o n e -B romo c. h 1 o rome t han e - 1 , 1 , 1 - T r i ci'il o r o e t Inane —Carbon T e t r a c 1": 1 o r i d e - B r oiTiod i c h 1 o r ome 11-ian e 1,, 2 - D i ctiloroprop.Ane — c i s - 1 ., 3 - D i cl^iloropropene T r i c h l o r o e t h e n e — D i i:> r o m o c 111 o i • o m e t i-1 Si n e - 1 , 1 , 2 - T r i c h l o r o e t h a n e _. _ •—B e n 7. e n e, — trarI•=•.-1,3••• Di cb 1 o r o p r o p e r i e —Bromoform —4-l'lethyl-2-F-'en t a n o n e __; •-2-Hexanone - Tetr&.ct-l 1 o r o e t l i e n e — 1,2~Di b r o m o e t l i a n e •—1, i , 2 , 2 - T e t r a c h l o r o e t h a n e ••-Toluenx"? —Chloroben zene_ — E t h y l iDen zente —S> tyrene —Xylene (total) 'X..1. Z^ •— 1,3-I>i c!•! 1 orotje^ri / ene_ 1,4-D i c h 1 o r o ben 7.en e • - 1 , 2 - D i c h i o r o b e n 7. e n e — 1,2 - D i 1:> I •" o n I o - 3 - c: b 1 o r o p r o |:> a n e. FORR'T'LCV 1 1 1 •4 X A-> 5 0 , 4 1 1 1 1 1 1 5 1 1 1 1 1 1 1 1 1 1 1 5 5 •-.• 1 ,1 j3<t:> 1 .1 1 1 1 1 1 1 Ll U Ll 1 1 L' y U P U l AAT R :i u Ll U L" U U i ^ i K Ll Ll .Ll 1 ( 1 < • . ' • . ' : Ll : Ll ;LI ;u ;u :u ; Ll 'KWR: 1 ;u :u >^C/ ;u !U :LI ;LI ;u :i.j ;LI ; i j 1 0 / 9 : 302672 ILCE LOW CONC. UATER VOLATILE ORGANICS ANALYSIS DATA SHEET TEN^tATIVELY IDENTIFIED COMPOUNDS EPA SAMPLE NO. •\b Name: ETC/GULF SOUTH 't-ab Code: GULF Case No.: HLA Lata Sample ID: WGOOl Lab File ID: VOVVGOl Purge Volume: 25.00 (ml) Contract: SAS No.: SDG No.: 95020 Date Received: 02/03/95 Date Analyzed: 02/08/95 Dilution Factor: 1.0 Hum be i- . I ICs found : CAS NUMBER COMPOUND NAME RT EST. COi>lC. ( u a / L ) Q V I V t CD tt. I'ORivi X L C V - T I C 302673 ILCA LOW CONC. WATER VOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. Lab Name: ETC/GULF SOUTH b Code: GULF Case No.: HLA. Lab Sample ID: VSROOl Contract: SAS No.: SDG No.: 95020 Lab File ID: F'urge Volume i CAS NO. VOVSROl >00 (ml) Date Received: 01/25/95 Date Analyzed: 02/03/95 Dilution Factor: 1.0 COMPOUND CONCENTR-^TION (ug/L) Q 7 4 - 8 3 - 9 7 5 - 0 1 - 4 - — 7 5 - 0 0 - 3 7 5 - 0 9 - 2 6 7 - 6 4 - 1 7 5 - 1 5 - 0 7 5 - 3 5 - 4 • 7 5 - 3 4 - 3 — 1 5 6 - 5 9 - 2 1 5 6 - 6 0 - 5 6 7 - 6 6 - 3 1 0 7 - 0 6 - 2 7 8 - 9 3 - 3 7 4 - 9 7 - 5 7 1 - 5 5 - 6 r: / '-.-.-' r: x.*C>"'\tLO- ^* 7 5 - 2 7 - 4 7 B - - 8 7 - 5 1 0 0 6 1 - 0 1 - 5 7 9 - 0 1 - 6 1 2 4 - 4 8 - 1 — 7 9 - 0 0 - 5 1 0 0 6 1 - 0 2 - 6 - - 7 5 - 2 5 - 2 1 0 8 - 1 0 - 1 5 9 1 - 7 8 - 6 1 2 7 - 1 8 - 4 1 0 6 - 9 3 - 4 7 9 - 3 4 - 5 — l O a - 8 3 - 3 1 0 8 - 9 0 - 7 1 0 0 - 4 1 - 4 1 0 0 - 4 2 - 5 1 3 3 0 - 2 0 - 7 — - 5 4 1 - 7 3 - 1 1 0 6 - 4 6 - 7 9 5 - 5 0 - 1 9 6 - 1 2 - 8 -CI l l o rome t h a n e t -Bromome t h a n e ! - V i n y l C h l o r i d e 1 - C h l o r o e t h a n e ', - M e t h y l e r ^ e Chl o r i d e ', - A c e t o n e ', -Carbon Disulfide 1 -1,1-Dichloroethene 1 - 1 , 1 - D i c h i l o r o e ? t h a n e I - c i s - 1 , 2 - D i c h 1 o r o e t h e n e ! - 1 r a n s ~ 1 , 2 - D i c l"i 1 o r o e t h e n e 1 ~C h 1 o ro-f o r m I - 1 , 2-D:! c b 1 o r o e t l"iane I - 2 - B u t a n o n e . I -•B r o m o c i il o r o m e t liane 1 - 1 , 1 , 1 - T r i c i i l o r o e t h a n e \ - Ca I' b o n T e t r a c h i o r i d e ', - B r o m o d i cl-iiorom.e-tl-iane ', - 1 , 2 - D i c l i l o r o p r o p a n e o ', - c i s - 1 . , 3 "Di c l ' i l o r o p r o p e n e ..__', - T r i chil o r o e t h e n e \ - D i b j- o m o r: b 1 o r o ni e t i i a n e I -i , 1,2-Tri chloroethane 1 -Ben zene I - 1 r a n n;- - 1 , 3 - D i c !• 11 o i'- o p r- o p e r i e ! -Bromoform \ -4~Methyl~2-Pen tanone ! -2-H«exanone ', - T e t r a c h l o r o e t h e n e _.. ', — 1 , 2 - D i l:>romoet h a n e ', - 1 , 1 , 2 , 2 - T e t r a c h l o r o e - l . h a n e ', - T o l u e n e __.! - C l i l o r o b e ^ n z e n e ', -Ethyl benzene ! -Styrene, 1 -Xylene (total) ! -1,3-Di chlorobenzene ', — 1 , 4 - I ) i c h I o r o l D e n z e n e ', -;1 ,2-Dichlorobenzene_ ', — 1 , 2 - D i b r o m o - 3 - c l - i l o r o p r o p a n e ', FORM I LCV 1 1 1 1 ? ^ 490 «:> - 1 1 1 1 1 1 5 1 1 1 1 1 1 1 1 1 1 1 1 5 1 1 , 1 ;u ; :u ; ;u ; u : ; * a U l ; ; E 3 ( 1 ;u : : Ll ; ;u ; ;u ; :u : '.u : i-tTR : ;u : ;u ; ; u ; u ; Ll ;u ;u :LI :u ; u ;u ;u 1 1 t 'i-HR ;u ;u / 0-<r^.\xr(Z J. ; Ll 1 ! u !i. 1 1 1 1 1 ;u :u : u ;u ;u ;uX " n f p t 1< \ V Qj •UJ i K . . < - •D: ; < ; ^ f-i„-^r •JA97. 302674 ILCE LOW CONC. WATER VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS EPA SAMPLE NO. Lab Name: ETC/GULF SOUTH j Code: GULF Case No.: HLA Lab Sample ID: VSROOl Lab File ID: VOVSROl Purge Volume: 25.00 (ml) Contract: SAS No.: SDG No.: 95020 Date Received: 01/25/95 Date Analyzed: 02/03/95 Dilution Factor: 1.0 Hum be? r TICs found: CAS NUMBER COMPOUND NAME RT EST. CONC, ( u g / L ) Q ^ FORM I LCV-TIC 10/92 302675 ILCA LOW CONC. WATER VOLATILE ORGANICS ANALYSIS DATA SI-HEET EPA SAMPLE NO. Lab Hame: ETC/GULF SOUTH ) Code: GULF Case No. Lab Sample ID: V3R001DL Lab File ID: VOVSROID F'urge Volume: 25.00 (ml) HLA Contract: E;AS No.: SDG No.: 95020 CAS HO. COMPOUND Date Received: 01/25/95 Date Analyzed: 02/04/95 Dilution Factor: 5.;,0 CONCENTRATION (ug/L) Q 74-87-3 74-83-9 75-01-4 75-00-3 75-09-2 67-64-1- 75-15-0 75-35-4 75-34-3 * tr / .„*^0,.,.0 ^ _^ 156-60-5 67—66—3 107-06-2 78-93-3 yC~<p-7-.^, 71-55-6 56-23-5 75-27-4 78-87-5 10061-01-5 79-01-6 124-48-1 79-00-5 71-43-2 10061-02-6 75-25-2 108-10-1 591-78-6 127-18-4 106-93-4 79-34-5 108-88-3 108-90-7 100-41-4 100-42-5 1330-20-7 541-73-1 106-46-7 95-50-1 96-12-8 —C h1o rome than e -Bromomethane -Vinyl Chloride —Ciil oroet inane -Me t hylen e Chlor ide -Acetone —Ca r bon D i su1f i d e -1,1-Dichloroethene -1,1-Dichloroethane -cis-1,2-D i c l-i 1 oroet hene -trans-1,2-Dichloroethene -ClTlorof orm — 1 , 2 - D i c h l o r o e t h a n e — 2 - B u t a n o n e -E<romochloromett"iane - 1 , 1 , 1 — T r i c h l o r o e t h a n e —Carbon T e t r a c h i o r i d e —Bromod i chlorome ti'iane — 1,2-Di ch'J oropropane ~ c i s -1,3-D i c i-i 1 o ro p ro pen e — T r i c h 1 or oe t hen e_ — D i b romo c h1o rome t nan e — 1,1,2-Tri chloroethane —Bo-;n7.ene — trans~l ,,3-Di chloropropene —Brom.of orm —4-Me t hyl -2-F-'en tan on e —2'.-Hexanone — T e t rach 1 o r oe t hier i e — 1,2~Di bromoethc^ne — 1,1,2,2-Tetrachloroethane —Toluene —Chlorobenzene —Ethylbenzene —Styi'ene —Xylene (total)_~ZL-I IIZI — 1,3—D i c hio ro ben z ene — 1 , 4 - D i c h l o r o b e n z e n e — 1,2~I>i c h l o r o b e n z e n e — 1,2-D i b r o m o - 3 - c ii 1 o r o p r o p'3.n e 5 ; U 5 :u 5 :u 5 ;u 10 J^ \JiJ^ C/J, 640 ;DE 3 2 ; D.T - 5 ; l.l 5 ; u 5 ;u 5 ;u 5 ;u 5 ; u 25 UW-R 5 5 5 /^^ ;u ;u ;u ;u 1 1 1 . o IU ; Ll :LI ; u :u ;u ;u ;u ;LI '.Ll ;u :u lU :u ;u ;u ; Ll ;u wr'' CO T3 0) 5 V '> IU cc . » . . »4 l~ORIS I LCV 10/^ 302676 ILCE LOW CONC. WATER VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS EPA SAMPLE NO, Lab Name: ETC/GULF SOUTH , Code: GULF Case No.: FILA, Lab Sample ID: VSROOIDL Lab File ID: VOVSROID Purge Volume: 25.00 (m1) Contract: SAS No.: SDG No.: 95020 Date Received: 01/25/95 Date Analyzed: 02/04/95 Dilution Factor: 5.0 Number TICs found; O CAS NUMBER COMPOUND NAME RT EST. CONC, ( u q / L ) Q o LlJ fell I I < S 0) > QC ( FORM I LCV-TIC 10/92 302677 ILCA LOW CONC. WATER VOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO, Lab Name: ETC/GULF SOUTH ' Code: GULF Case No.: HLA T-ab Sample ID: VTFOOl Lab File ID: VOVTFOl Purge Volume: 25.00 (ml) Contract: SAS No.: SDG No.: 95020 Date Received: 01/30/95 Date Analyzed: 02/07/95 Dilution Factor: l^^^^O CAS NO. COMPOUND CONCENTRATION (ug/L) 0 74-87-3 74-83-9 75-01-4 75-00-3 75-09-2 67-64-1 75-15-0 75-35-4 75-34-3- - •« r: /• r t o '"> - .1. •„»0-"^." 7"-<c:. 156-60-5 67—66—3 107-06-2 73-93-3 74-97-5 71-55-6 n: / '-,-:• c: ».'0—x:.o— ^.i; 75-27-4 78-87-5 10061-01-5- 79-01-6- 124-48-1 — 79-00-5- — 71-43-2 10061-02-6- 108-10-1 5 9 1 - 7 8 - 6 — 1 2 7 - 1 8 - 4 — 106-93-4 79-34-5- 1 0 8 - 8 8 - 3 — 1 0 8 - 9 0 - 7 — 100-41-4 1 0 0 - 4 2 - 5 — 1330-20-7— 541-73-1 106-46-7 — 95-50-1 96-12-8- —Chloromethane -Bromomethane -Vinyl Chloride -Chloroethane -Methylene Chloride -Acetone —Ca r bon D :i su. 1 -f i d e -1,1-Dichloroethene -1 .1 -Die h 1 o roe t lian e - c i s-1,2-D i c h 1 o I'-oe t hen e -1rans-1,2-Di ch1oroe t hene -C |-i 1 o r of o r m - 1 , 2-Di chloroe-thane? -2-Butanone —B r Oiiio c b'.]. o rome t lian e - 1 , 1 , 1 - T r i cl'iloroeti'iane -Carbo;i T e t r a c b 1 o r i d e -Bromod i c h l o r o m e t h a n e — 1 , 2 - D i c h l o r o p r o p a n e — c i s - 1 , 3 - D i cl-iloropropene —"(' r i c h 1 o r o e t l i e n e -D i bromochlorome'thane — 1 , 1 , 2 . - T r i c h l o r o e t h a r i e - B e n z e n e • - 11 - a n s - .1., 3 - P a. c b 1 o r o p r o p e ri e —Bromo-fcjrm -4-Me t liy 1 -2-F'eri t a n ori e —2—IHex a n o n e — T e t r a c |-il o r o e -t l i e n e — 1 ., 2--I) i b r omoe 'l. |-iane — 1 ,1 , 2 , 2 - T e t r a c h l o r o e t h a n e _ . _ . —Toluene —Chloroben zene. —E t h-/l b e n z e n e — S t y r e r i e —Xylene ( t o t a i y Z Z . _ Z I I Z ] —• 1,3 - D i c f 11 o I • o i;:i e n z e r i e — 1 , 4 - D i c i"! ]. o r o IT e n z e n e 1 , 2 - D i c ll 1 o r o b)en z en e _. — 1 , 2 - D i b r o m o - 3 - c h l oroprop^vne FGivM I LCV 1 1 1 1 *2 i X S 2 2 0 0 0 . 2 1 1 j . 1 J. 5 .i. 1 1 1 1 1 1 .1. 1 1 1 1 5 5 •4 1 / o . ^ 1 :i. j . .1. 1 1 1 1 u u u u ,JE^ i Z l E l J U Ll Ll U ! u ; I-' ^ ' Ll U Ll U ; u U : Ll , u ;u • u ;u .u ;u :u ! U :u L^f c/ :u ! u :u ;u ! U ;u 1( . \ ^ OS Si Q^ • 1 1 ) •^b- , ^ * » CD : > ' 5 .3? « • > 4S I 0) (0 (£ Q 1 ^ - / o - < f r ) / 9 2 302678 ILCE LO'W COI^C. WATER VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS EPA SAMPLE NO. Lab Name: ETC/GULF SOUTH Code: GULF Case No.: HLA Lab Sample ID: VTFOOl Lab File ID: VOVTFOl Purge Volume: 25.^00_ (ml) Contract! SAS No.l SDG No.: 95020 Date Received: 01/30/95 Date Analyzed: 02/07/95 Dilution Factor: 1_;^0 Number TICs found: O CAS NUMBER COMPOUND NAME RT EST. CONC. ( u g / L ) Q U^ FORM I LCV-TIC 1 0 / 9 2 302679 ILCA LOW CONC. WATER VOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO Lab Name: ETC/GULF SOUTH b Code: GULF Case No.: HJ,^A Lab Sample ID: VTFOOIDL Lab File ID: VOVTFOID Purge Volume: 25.00 (ml) Con tr^ict: SAS No.: SDG No.: 95020 Date Received: 01/30/95 Date Analyzed: 02/08/95 Dilution Factor: 25 CAS NO. COMPOUND CONCENTRATION (ug/L) Q 74-87-3— 74-83-9 75-01-4 75-00-3 75-09-2 67-64-1 75-15-0 75-35-4 -7.;: -y n -y 156-59-2 15v'f>-60-5 67-66-3 1 0 7 - 0 6 - 2 — 78-93-3 — 74-97-5— 71-55-6 .:>d>—Az.i—5 75-27-4 78-87-5 10061-01-5- 79-01-6 124-48-1 79-00-5 71-43-2 10061-02-6- "7'".... o <=, ™. '":• 108-10-1 591-78-6 127-18-4 - 106-93-4 79-34-5 - 108-88-3 108-90-7 100-41-4 1 0 0 - 4 2 - 5 — 1330-20-7— 541-73-1 — 106-46-7 9 5-50-^1 96-12-8 Chloromethane Bromome th.:7-.ne V i r^ y 1 C h 1 o r i d e Chloroethane M e t l i y 1 erie C|-11 o r i d e : A c e t o n e C a r b o n D i s u l f i d e 1 , 1 - D i c h l ' D r . - . e t h e n e 1,1-D:i c h l o r o e t l i a r i e c i s - 1 , 2 - ~ D i c h l o r o e t h e n e t r a n s — 1 ,2—Di cl i l o r o e t t i e n e _ C h l o r o f o r m 1 , 2 - D i cll] o i - o e t | - i a n e 2-Butanoni:-' _ B romo c I'i 1 o r orne t lian e 1 , 1 , 1 - T r i c l-i 1 o r . o e t h a n e Car bon T>:; t r a c i i l o i'- x do? E'romodi c h l o r o m e t h a n e 1 , 2 - D i c h l o r o p r o p a n e c i s - 1 , 3 - ) ) i c h l o r o p r o p e n e — T r i c h l o r o e t h e n e D i i'j I" o m .:"•.::: Til o r o in e t i'i a n e 1,1,2-Tri chloroethane Benzene - t r a n s - l ., 3 - D i c h l o r o p r o p e n e B r o m o f o r m 4 - M e - t h y 1 - 2 - F ' e n t a n o n e 2—Hexanone _ _ _ T e - t r a c h l o r o e t h e r i e 1 , 2 - D i b roirizxzz t h a n e 1,1,2,2-Tet r.^.c b 1 o root hane Toluene Chloroben zene Ethyl bei'i zene Styrene^ _ X y l e n e ( t i j t a l ) . _ ._ 1,3-Dichlorobenzene. 1 , 4 - D i c h 1 or ol;)enzeiie 1 , 2 - D i c h 1 o r o h e n z e n e 1 , 2 - D i b 1-oIIIo- 3 -cI'l 1 o I " o p r o p a n e 1 8 0 0 - • : : V . ' 25 2 5 1 2 0 2 5 '-I m ' - » r r 2 5 ^\ rr. 1 2 0 1 2 0 2 5 •-•» rr: \\ U L.l U DC7 L.1 U U U Ll U Li Ll L.1 L.1 U LJ U LJ U Ll LJ LJ U L.1 U LJ LJ U LJ U LJ U LJ U U U •ORM 1 l_CV 1 0 / 9 2 302680 ILCE LOW CONC. WATER VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS EPA SAMPLE NO. Lab Hame: ETC/GULF SOUTH Code: GULF Case No. Lab Sample ID: VTFOOIDL Lab File ID: VQVTFOID Pu rge Volume: 25.00 (m1) HLA Contract: SAS No.l : SDG No.: 95020 Date Received: 01/50/95 Date Analyzed: 02/08/95 Dilution Factor: 25 Number TICs found: CAS NUMBER 0 COi'lF'DUND NAME F;T CONC, ( u g / L ) Q iy • ^ C3 • • « ^ to K a •ORM I LCV-TIC 1 0 / 9 : 302681 HLA DATA QUALITY ASSURANCE REVIEW SUMMARY Volatile Organic Compound Analysis Case Number: Site: Contractor Lab: Validator: QC Reviewer: Sample Matrix: 95020 Project Number: 29872 10.2 Island Chemical Con:^>any Pace Environmental Labs, St. Rosa, LA Kirsten Meier ^^TXicJUcf^, 7^,Xa^yX^ Validation Date: 5 April 1995 Review Date: ^-f/- ? S ~ Soil Analytical Method: CLP OLM03.0, Multi-Media, Multi-Concentration Sample Designations: SBB101/0-1/0I3195 (BlOlOl) SBBl/0-1/013195 (BlOOOl) SBCl/0-1/012795 (ClOOOl) SBD4/0-1/012795 (D40001) SBF2/I2-15/012495 (K21215) SBF3/18-20/012495 (F31820) SBCl/16-18/012795 (C11618) SBD4/14-16/012795 (D41416) SBF2/18-20/012495 (F21820) SBBl/24-26/013195 (B12426) SBCl/18-20/012795 (C11820) SBBl/6-8/013195 (B16008) SBF3/0-1/012495 (F30001) SBD4/20-22/012795 (D42022) SBCl/20-22/012795 (C12022) SBF3/14-15/012495 (F31415) ( ) = Lab Sample ID Data for the above samples are: [ ] Acceptable for use [x] Acceptable for use as qualified [ ] Unacceptable for use Is action required by the Project Manager? Yes No[x] Conunents: The daU was reviewed in accordance with the EPA Functional Guidelines, February 1994. voB_ekc.ll I2»I9M 1330 Fonn VOA I. 302682 CMsNuBfeen 9X00 Piojca Niagher: 29C72 10.2 SHe ID: kimd Oimrinil Caamaj DATA COMPLETENESS CHECKLIST [x] Included, no problems [""J Included, problems [O] Not included [NA] Not applicable Quality Control Summary X Case Narrative X Surrogate Recovery Summary X MS/MSD Summary * Reagent Blank Summaiy * GC/MS Instmment Performance Summaiy Sample Data * Chain of Custody Forms X Holding Times X Organic Analysis Data Sheets X Quantitation Reports X Reconstructed Ion Chromatograms X Mass Spectra Printouts X TIC Mass Spectra Library Searches Initial Calibration Data * Calibration Summaiy X Standards Quantitation Reports X Standards Reconstructed Ion Chromatograms Continuing Calibration Data * Calibration Summary X Standards Quantitation Reports X Standards Reconstructed Ion Chromatograms * Intemal Standards Summaiy Instrument Performance Data X BFB Mass Spectra X Reconstmcted Ion Chromatogram X BFB Mass Listings vaa_elcc.il 122919M IJ30 Fom. VOA 1.1 302683 CueNuBben M020 Prajoet Nurben 29*72 lOJ She ID: bhrnd Onii»»l Craaqr Reagent Blank Data X Organic Analysis Data Sheets X Quantitation Reports X Reconstmcted Ion Chromatograms X Mass Spectra Printouts X TIC Mass Spectra library Searches Matrix Spike and Matrix Spike DupUcate Data X Organic Analysis Data Sheets X Quantitation Reports X Reconstmcted Ion Chromatograms Laboratory Control Sample NA NA NA NA NA Comments: Organic Analysis Data Sheets Quantitation Reports Reconstmcted Ion Chromatograms Mass Spectra Printouts TIC Mass Spectra library Searches None v « elec.ll ' 2 » 1 » « '330 3 Fom. VOA l.l 302684 CMcNundn: 93020 PKieot NuEfcer: 29872 10.2 Site ID: bkad Ctrrmml Cooanjt SPECinC COMMENTS REGARDING ANALYSES Chain Of Custody Were sanples properly preserved and received in good condition? Yes[x] No Were custody transfers correctly and conq)letely documented? Yes[x] No Comments: The submitted Chain of Custody forms were not signed and dated by the lab upon receipt of the samples. No qualification of data. Holding Times Were sample analyses performed within holding times? Yes[x] No Comments: None Instnunent Tuning Did the instmment performance checks meet acceptance criteria? Yes[x] No Were samples analyzed within the 12-hour period following an acceptable performance check? Yes[x] No Comments: For the tune on 2-8-95, 15:44, Instmment F, the submitted Form V does not match the raw data. For mass 177 the calculations were incorrect, the correct relative abundance for 177, based OQ 95, is 5.4% and based on 176, it is 6.2%, which is within the QC criteria. The chromatogram for the BFB peak shows a spike during the integration, however it does not appear to interfere with the tuning. No qualification of data. vo._ekc.ll I2»I9»4 15M Fom VOA l.l ,02685 Caae Nuoter: 9SQ30 PR9>X Ninfcer 29872 10.2 Sile ID: bksd rhmOTl Conaqr Initial Calibration Did the laboratory meet the method requirements regarding the minimum number of calibration standards for an acceptable initial calibration? Yes[x] No Did the initial calibration curves meet the linearity criteria for maximum percent relative standard deviation (%RSD)? Yes No[x] Did the initial calibration meet the minimum relative response factor (RRF) criteria? Yes[x] No Comments: See table 'Initial Calibration Summaiy' for the analytes exceeding the QC criteria and the associated investigative sample. Detections for the listed analytes in the investigative samples were qualified as estimated (J). For the investigative sanples F21215, F21820, F30001, F31415 and F31820 the initial calibration from 2-2-95 is also used as continuing calibration. Therefore, the detections and non-detections for Bromomethane, Methylene Chloride and Acetone in these samples were qualified as estimated (J). Continuing Calibration Did the continuing calibration curves meet the linearity criteria for maximum percent difference (%D)? Yes No[x] Did the continuing calibration meet the minimum RRF criteria? Yes[x] No Comments: See table "Continuing Calibration Summary" for the analytes exceeding the QC criteria. The results for the listed analytes in the associated investigative samples were qualified as estimated (J). voaekc.ll 122^1994 15M 5 Fom. VOA l.l 302686 Caae Nunber: 99030 Pniacl Nunber: 29872 10.2 Sbe ID: Itkad rhrmiral Coongr Surrogate Recoveries Were the surrogate spike recoveries within acceptance limits? Yes[x] No If the spike recoveries were imacceptable, were the samples reanalyzed? Yes No NA[x] Comments: None Matrix Spikes Were matrix spike analyses performed at the correct frequency and on a sample matrix representative of the samples in the sample delivery group (SDG)? Yes[x] No Were the matrix spike recoveries and relative percent differences (RPDs) within acceptance criteria? Yes[x] No Conunents: Matrix spikes were performed on the low soil sample F30001 on instmment F, no matrix spike was performed with the medium soil on instmment D. The lab submitted additional information for instmment D, matrix spikes from different samples and blank spike. No qualification of data. Internal Standards Were the internal standard areas and retention times within the required limits? Yes No[x] If the intemal standard requirements were not met, were the samples reanalyzed? Yes No[x] Comments: In the investigative sample F30001 the IS area for Clilorobenzene-d5 was 45.7% of the expected value, in the MS and MSD the areas were 35.4 % and 46.3% of the expected value. Therefore, the results for the analytes in the associated fraction were qualified as estimated (J). This applies to 2-Hexanone, 4-Methyl-2-pentanone, Tetrachloroethene, 1,1,2,2-Tetrachloroethane, Toluene, Chlorobenzene, Ethylbenzene, Styrene and total Xylenes. vca_elec.il 12291994 1330 6 Fom. VOA 1.1 302686A OaeNunben 9S030 Pnjaa Niinhir 29(72 lOJ SilB ID: bhnd Ormieal Conamr Blank Analyses Were the ^propriate number of blank analyses performed? Yes[x] No Were analytes detected in the blanks? Yes[x] No If analytes were detected in the blanks, were the same analytes detected in the associated investigative samples? Yes[x] No NA Did the sample results require qualification due to the presence of analytes in the associated blank samples? Yes[x] No Comments: See table 'Blank Summary'. Detections in the investigative samples below the action level were qualified as imdetected (U). Results below the CRQL were raised to the CRQL. Laboratory Control Samples Were laboratoiy control sample (LCS) analyses performed at the correct frequency? Yes No NA[x] Were the LCS recoveries within acceptable limits? Yes No NA[x] Comments: Not applicable vca_elec.ll )a919»«15» 7 Fom. VOA 1.1 302686B CaaeNwrin: 93(00 Piajeol Number: 29872 lOJ Ste ID: lakod OmiWwl Conaiqr Sample Results Were target analytes reported in the investigative samples? Yes[x] No Were mass spectra provided for the target analytes detected in the investigative samples? Yes[x] No Were the mass spectra of acceptable quality and analytes correctly identified? Yes[x] No Were the quantitated results for target analytes calculated using the appropriate internal standards and were the relative retention times (RRTs) acceptable? Yes[x] • No Comments: None Tentatively Identified Compounds Were tentatively identified compound (TIC) searches conducted for all sample analyses? Yes[x] No '' NA Were non-target peaks evaluated as required? Yes[x] No Were the TIC mass spectra, searches, identifications, and quantitated results acceptable? Yes[x] No Comments: TTCs were qualified as tentatively identified (NJ). vca_elec.il 12291994 UM 8 Fom. VOA l.l 302686C CaaeNuiter. 93030 t t t r a Nuiter 29872 10.2 Siu ID: bkad Cheraiaal Coonv Log Books Were sample preparations properly documented and performed in accordance with method protocols? Yes[x] No NA Were sanqile analyses properly documented and performed in accordance with method protocols? Yes[x] Nc, Comments: None voa elec.ll ' 2 » ' » ^ ' 5 » 9 Fom. VOA l.l 302686D CaKNuBben 93030 PiDjea Nunber 29872 10.2 Sile ID: bbnd CtrmOTl Comai^ Calculation Checks Instmment Tuning, 1-24-95, 9:24, 177 m/z, based on mass 176 Relative Abundance: 1004 X 100% = 6.82 14720 Initial Calibration, 2-2-95, VSTD020, 2-Hexanone RRF: (8650 ) x ( 5 0 ) ( 121379 ) X ( 20 ) %RSD: 0.0278 0.1940 Continuing Cjilibration RRF: ( 58494 ) X ( 141335 ) X %D: 0.194-0.414 xl00% 1, 2-3-95, ( 5 0 ) ( 5 0 ) 12:50, 14.3267 2-Hexanone ^ X 100% = -113.4021 0.194 Surrogate Recovery, F31820, D8-Toluene % Recovery: 55.948 X 0.89 X 100% = 99.5874 50 0.1782 0.4139 vca_elec.ll '2»'»»< 1J» 10 Fom. VOA l.l 302686E CaaeNutten 93020 Pn^eet N U ^ K T . 29872 10.2 Sile ID: bbnd Owniml Conaiqr Matrix Spike Recovery, FBOOOl, Toluene % Recovery: 69.79 - 0 57.50 xl00% = 121.3739 RPD: 2 I 121 - 122 121 -I- 122 X 100% = 0.8230 Sample Results, B16008 CRQL: Detected Result for Acetone (3931 ) x (43440) ( 47910) X (0.187) 19060.0960 TTC Result, B16008, Unknovm RT=2.58 ( 88550 ) X ( 43440 ) 394469 9751.3670 vca_elec.ll 12291994 1330 11 Fom. VOA l.l 302686P C*ee Nunber: 93020 Prajed Number: 29872 10.2 Sile ID: bbnd Cbemloal Conawy HOLDING TIME QUALIFICATION SUMMARY FORM Sample Identification Date Sampled Date Analyzed Analysis Holding Time Qualifier Ui o to cr\ 00 o\ Q Comments: None voa_elco.ll 12291994 1530 12 Form VGA l.l Ui o to 00 a\ Caie Nunber: 93020 Projecl Nunber: 29r72 10.2 Sile ID: bland Cbcraioal Ccmany INITIAL CALIBRATION QUALIHCATION SUMMARY FORM Date/Time 1-24-95 2-2-95 Instmment D F Analyte Acetone Bromomethane Methylene Chloride Acetone Bromomethane Methylene Chloride Acetone RF RSD 30.7% 32.4 34.1 39.9 32.4 34.1 39.9 Samples Affected B16008 BlOlOl, BlOOOl, B12426, D42022, ClOOOl. C11618, C11820, C12022, D40001, D41416 BlOlOl, BlOOOl, B12426, D42022, ClOOOl, C11618, C11820, C12022, D40001, D41416 BlOlOl, BlOOOl, B12426, D42022, ClOOOl, C11618, C11820, C12022, D40001, D41416 F21215, F21820, F30001, F31415, F31820 F21215, F21820, F30001, F31415, F31820 F21215, F21820, F30001, F31415, F31820 Qualifier J/- J/- J/- J/- J/UJ J/UJ JAJJ Comments: None vaa_clec. 11 12291994 1330 13 Fomi VOA 1. CaK Nunber: 93020 Project Nurker; 29871 10.2 Sile ID: bbnd Cbcmical Comuj' CONTINUING CALIBRATION QUALIHCATION SUMMARY FORM Ui o to <J\ CO CTi H Date/Time 2-10-95, 9:55 2-3-95, 12:50 2-8-95, 15:59 2-9-95, 13:13 Instmment D F F F . Analyte Chloromethane Acetone Acetone 2-Butanone 2-Hexanone Acetone 2-Butanone 2-Hexanone Acetone 2-Butanone 2-Hexanone RF %D 36.7 42.1 -151.7 -248.5 -113.4 -31.0 -74.9 -102.6 -31.8 -40.1 -61.3 Samples Affected B16008 B16008 ClOOOl, C11618, C11820, C12022, D40001,D41416,D42022 ClOOOl, C11618, C11820, C12022, D40001, D41416, D42022 ClOOOl, C11618, C11820, C12022, D40001, D41416,D42022 BlOOOl BlOOOl BlOOOl BlOlOl, B12426 BlOlOl, B12426 BlOlOl, B12426 Qualifier J/UJ J/UJ J/UJ JAJJ J/UJ J/UJ J/UJ J/UJ J/UJ J/UJ J/UJ Comments: None voa_eleo.l I 12291994 1330 14 Form VGA 1.1 Ca<e Nunber: 93020 ProjcaNunber: 29872 10.2 Site ID: bbnd Chemioal Company BLANK SUMMARY FORM t j j o to 00 a\ Blank ID VBLKLl 1 VBLKL2 VBLKL3 1 VBLKL4 VBLKMl Analyte Methylene Chloride Acetone Methylene Chloride Acetone Methylene Chloride Acetone Methylene Chloride Acetone total Xylene Methylene Chloride Chloroform total Xylene Unknown TIC, RT=2.53 min l,l,2-TrichIoro-l,2,2- trifluoroelhane, RT=3.93 min Blank Result [ug/kg] 9 7 8 3 3 8 4 4 4 600 150 190 3400 1700 Action Level [ug/kg] 90 70 80 30 30 80 40 40 20 6000 750 950 17000 8500 Associated Samples F21215, F21820, F30001, F31415, F31820 F21215, F21820, F30001, F31415, F31820 ClOOOl, C11618, C11820, C12022, D40001, D41416, ClOOOl, C11618, C11820, C12022, D40001, D41416, D42022 D42022 BlOOOl BlOOOl BlOlOl, B12426 BlOlOl, B12426 BlOlOl, B12426 B16008 B16008 B16008 B16008 B16008 Comments: Detections of the listed target analytes in the investigative samples below the action levels were qualified as undetected (U). Results which were less than the Contract Required Quantitaion Limits (CRQL) were raised to the CRQLs. Sample concentrations of TICs identified as blank contamination or artifacts were qualified as rejected (R) when below the action level noted above. vcujeie«. 11 12291994 1330 15 Form VGA l.l Caae Nunber 93020 PiOjeetNunber 29872 10.2 Sile ID: bbnd nniii»»l Conrasy Summary and Conclusions The analytical results for the volatile analyses are acceptable for use as qualified. Several analytes exceeded the initial calibration criteria. Therefore, detections of the listed analytes in the investigative samples were qualified as estimated (J). For the investigative samples F212i5, F21820, F30001, F31415, and F31820 the initial calibration from 2-2-95 is also used as continuing calibration. Therefore, the detections and non-detections for Bromomethane, Methylene Chloride, and Acetone in these samples were qualified as estimated (J). Several analytes exceeded the continuing calibration criteria. The results for theses listed analytes were qualified as estimated (J). See report for detailed listing. In the investigative sample F30001 the IS area for Chlorobenzene-d5 exceeded QC criteria. Therefore, the results for the analytes in the associated fration were qualified as estimated (J). This applies to 2- Hexanone, 4-Methyl-2-pentanone, Tetrachloroethene, 1,1,2,2-Tetrachloroethane, Toluene, Chlorobenzene, Ethylbenzene, Styrene and total Xylenes. Blank contamination was observed for Methylene Chloride, Acetone, Chloroform, and total Xylenes. Detections in the investigative samples below the action level were qualified as undetected (U). See report for details. Sample concentrations of TTCs identified as blank contamination or artifacts were qualified as rejected (R) when below the action level. TTCs were qualified as tentatively identified (NJ). Validator's Signature: Validator's Initials: QC Reviewer's Signature: QC Reviewer's Initials: ll^'Uvi^ rUAt-z ) / p \ Validation Date: ^ - 5" - fsS ZZTty^Au/ 7^ V^XcM^^ PIPP Review Date: y - //- f T voa_elec.ll 12291994 1530 . 1 6 Form VOA l.l 302686K VOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: ETC/GULF SOUTH .c-ib Code: GULF Case No.: HLA Matrix: (soil/water) SOIL Sample wt/vol: '^.0 (g/mL) G Level: (low/med) HEP ':. Moisture: not dec. 28 GC Column: RTX-502.2 ID: Q.530 (mm) Soil Extract Volume: 10000 (uL) Contracts SAS No.: EPA SAMPLE NO. B16008 SDG No.: 95020 Lab Sample ID: VVG003 Lab File ID: V0WG03M Date Received: 02/03/95 Date Analyzed: 02/10/95 Dilution Factor: 5.S.0 Soil Aliquot Volumes 100 (uL) CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG Q 7^-37-3 7'^~S3-9 75-01-'^ 75-00-3 75-09-2 67-6A-1 75-15-0 75-35-4 34- 540-59-0 67-66-3 — 107-06-2 73-93-3 71-55-6 *.' •.-/ ™ ^;^ ^ — J> — -- — — — -^ — 75-27-4 73-87-5 10061-01-5 79-01-6 124-48-1 79-00-5 71-43-2 10061-02-6 75-25-2 103-10-1 591-78-6 127-18-4 79-34-5 108-83-3 108-90-7 100-41-4 100-42-5 1330-20-7 -Chloromethane —Bromomethane -Vinyl Chloride -Chloroethane -Methylene Chloride -Acetone -Carbon Disu1fide -1,1-Dichloroethene -1., l~Dichloroethane —1,2-Dichloroethene(total) -Chloroform —1,2-Dichloroethane —2-Butanone — 1,1,l-Trichloroethane •-Carbon Tetrachloride —Bromod i c h1o rome t hane —1,2-Dichloropropane ~ c i € i - l , 3 - D i c h l o r o p r o p e n e —Trichloro(-3thene —Dibromochloromethane ~ 1 , 1 , 2 - T r i c h l o r o e t h a n e —Benzene —trans-1,3-Dichloropropene —Bromoform —4-Methyl-2-Pentanone —2-Hexanone —Tetrachloroethene —1,1,2,2-Tetrachloroethane —Toluene —Chlorobenzene —Ethylbenzene —Styrene —Xylene (total) 8300 B300 8300 8300 2300 ZQ^!^ 19000 8300 8300 8300 8300 ^^300 1£>00 8300 8300 8300 8300 8300 8300 8300 8300 8300 8300 8300 8300 8300 8300 8300 8300 8300 1000 8300 57000 8300 310000 UJ u u u CJ U LJ U U '>..) U u u U u u u u u u u u u u u J u u BE > OJ a: FORM I VOA __3/_9_Q. 302686L IE VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS Lab Name: ETC/GULF SOUTH ab Code: GULF Case No.: HLA Matrix: (soil/water) SOIL Sample wt/vol: 4.0 (g/mL) G Level: (low/med) MED ••: Moisture: not dec. 28 GC Column: RTX-502.2 ID: 0.530 (mm) Soil Extract Volume: 10000 (uL) Number TICs found: 2 Contract: SAS No.: EPA SAMPLE NO B16008 SDG No. 95020 Lab Sample.ID: VVG003 Lab File ID: V0VVG03M Date Received: 02/03/95 Date Analyzed: 02/10/95 Dilution Factor: '^.S). Soil Aliquot Volume: 100 (uL) CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG CAS NUMBER 1. 2. 76-13-1 COMPOUND NAME UNKNOWN ETHANE, 1,1,2~TRICHLORO-1,2, RT 2.58 4.02 EST; CONC. 9700 5200 1 1 ; Q : — 1 -, 1 1 ^ > ^ ; 1 1 _'—————' - < ? J a: FORM I VOA-TIC 302686M 3/90 Lfi VOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: ETC/GULF SOUTH _ab Code: GULF Case No.: HLA Matrix: (soil/water) SOIL Sample wt/vol: 5.0 (cj/mL) G_ Level: (low/med) LOUl ?: Moisture: not dec. 19 GC Column: RTX-502.2 ID: 0.530 (mm) Soil Extract Volume: (uL) Contract: SAS No.: EPA SAMPLE NO. BlOOOl SDG No.: 95020 Lab Sample ID: VVG002 Lab File ID: V0VVG02 Date Received: 02/03/95 Date Analyzed: 02/09/95 Dilution Factor: 1_...O Soil Aliquot Volume: (uL) CAS NO, COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG Q 74-87-3 74-83-9 75-01-4 75-00-3 75-09-2 Chloromethane Bromomethane^ Vinyl Chloride Chloroethane Methylene Chloride 67-64-1 Acetone 75-15-0 Carbon Disulfide I_I 75-35-4 1 , l~Di chloroethene 75-34-3 1,1-Dichloroethane 540-59-0 1, 2-Di chl oroet hene (to tal) 67-66-3 Chloroform 107-06-2 l,2~Di chloroethane 78-93-3 2-Bu t an on e 71-55-6 1,1,1-Tri chloroethane 75-27-4- Bromod i cl-iloromethane 73-87-5 1,2-Dichloropropane 10061-01-5 cis-1,3-Dichloropropene 79-01-6 Trichloroethene 124-48-1 Di bromoc h 1 oromet hane> 79-00-5- 1,1,2-Tri chloroethane_]_] ~ i - 71-43-2 Benzene 10061-02-6 trans-1,3-Dichloropropene_._ 75-25-2 Bromoform 108-10-1 4-Methyl-2-Pentanone~~ " 591 -78-6 2-He x an on e 127-18-4 Tetrachloroethene 79-34-5 1,1,2,2~Tetrachloroethane 108-88-3 Toluene 108-90-7 Chlorobenzene 100-41 - 4 — ^ E t hy 1 ben z en e 100-42-5 Styrene 1330-20-7 Xylene ( total) ^ II FORM I 'VGA 3/90 302686N IE VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS Lata Name: ETC/GULF SOUTH .ab Code: GULF Case No.: HLA Matrix: (soil/water) SOIL Sample wt/vols 5.0 (g/mL) G Level: (low/med) LOUl T-: Moisture: not dec. 19 GC Column: RTX-502.2 ID: O.530 (mm) Soil Extract Volume: (uL) Number TICs found: 5 Contract: SAS No.: EPA SAMPLE NO. BlOOOl SDG No.: 95020 Lab Sample ID: VVG002 Lab File ID: V0VVG02 Date Received: 02/03/95 Date Analyzed: 02/08/95 Dilution Factor: 1;_.^ Soil Aliquot Volume: .(uL) CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG CAS NUMBER 1. 76—13—1 2. 1634-04-4 3. 4.. COMPOUND NAME 1,1,2-TRICHLORO-l,2,2-TRIFLU 2-METH0XY-2-METHYLPR0PANE UNKNOWN HYDROCARBON UNKNOWN HYDROCARBON UNKNOWN HYDROCARBON RT 4.52 5.62 17.90 18.75 19.10 EST-. CONC. 11 8 6 4 JN JN JA; J Ay to 3026860 FORM I VOA-TIC 3/90 IA VOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: ETC/GULF SOUTH _ab Code: GULF Case No.: HLA Matrix: (soil/water) SOIL Sample wt/vol: 5.0 (g/mL) G Level: (low/med) LOW ": Moisture: not dec. 16 GC Column: RTX-502.2 ID: 0.530 (mm) Soil Extract Volume: (uL) Contract: SAS No.: EPA SAMPLE NO BlOlOl SDG No.: 95020 CAS NO. COMPOUND Lab Sample ID: VVG004 Lab File ID: V0VVG04 Date Received: 02/03/95 Date Analyzed: 02/09/95 Dilution Factor: 1.0 Soil Aliquot Volume: CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG (uL) Q 74-87-3 74-83-9 75-01-4 75-00-3 75-09-2 67-64-1 75-15-0 75-35-4 75-34-3 540-59-0 67-66-3 107-06-2 78-93-3 71-55-6 56-23-5 75-27-4 78-87-5 10061-01-5- 79-01-6 124-48-1 79-00-5 71-43-2 10061-02-6- 75-25-2 103-10-1 591-78-6 127-18-4 79-34-5 108-83-3 108-90-7 100-41-4 100-42-5 1330-20-7— -Chloromethane -Bromomethane -Vinyl C h1o r i d e -Chloroethane -Me -t hyl en e C h 1 o r i d e —A ce t on e -Ca r bon D i su1f i d e -1,1-Dichloroethene -1,1-Dichloroethane -1,2-Dichloroethene( total).. -Chloro-form -1,2-Dichloroethane —2-Butanone -1,1,l-Trichloroethane —Carbon TetraclTloride -Bromodichloromethane J —1,2-Dichloropropane —cis-1,3-Dichloropropene — T r i c h 1 o roe t lien e — D i bromoch1orome t hane --1,1,2-Tri chloroethane; —Benzene — t r an':5-1,3-D i chl oro p ro pen e_ —Bromoform —4~Methyl-2~Pentanone —2-He xar^ one —Tetrachloroethene — 1 , 1,2,2-TG;trachloroethane_ —Toluene —Chlorobenzene —Ethylben zene —Styrene —Xylene (total) - 12 12 12 12 13 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 'l2 12 12 12 12 12 4 12 24 U U U U U U U u U i..jcr L.l U U U LJ U U U LJ U LJ U Uj U U u LJ J LJ B < & •n > Ol tc FORM I VOA 302686P J/90 IE VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS Lab Name: ETC/GULF SOUTH -ab Code: GULF Case No.: HLA Matrix: (soil/water) SOIL Sample wt/vol: 5.0 (g/mL) G Level: (low/med) LOW ': Moisture: not dec. 16 GC Column: RTX-502.2 ID: 0.530 (mm) Soil Extract Volume: (uL) Number TICs found: 2 Contract; SAS No.: EPA SAMPLE NO, BlOlOl SDG No.: 95020 Lab Sample ID: VVG004 Lab File ID: V0VVG04 Date Received: 02/03/95 Date Analyzed: 02/09/95 Dilution Factor: 1.0 Soil Aliquot Volume: .(uL) CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG CAS NUMBER =:::==r:::r==:==:==:==:==: 1. 76-13-1 2. 1634-04-4 COMPOUND NAME 1,1,2-TRICHLORO-l,2,2-TRIFLU 2-METH0XY-2-METHYLPR0PANE RT =:======— 4.53 5.62 EST, CONC. S 8 Q JN JN FORM I VOA-TIC 302686Q 3/90 IA VOLATILE ORGANICS ANALYSIS DATA SHEET l.ab Name: ETC/GULF SOUTH .ab Code: GULF Case No. HLA Contract: SAS No.: EPA SAMPLE NO. B12426 SDG No.: 95020 Matrix: (soil/water) SOIL Sample wt/vol: 5.0 (g/mL) G_ Level: (low/med) LOW Lab Sample ID: VVG005 Lab File ID: V0VVG05 ": Moisture: not dec. GC Column: RTX-502.: 19 Date Received: 02/03/95 Date Analyzed: 02/09/95 Soil E"xtract Volume: CAS NO. II>5 0 . 530 (mm) (uL) D i l u t i o n F a c t o r 1 .0 COMPOUND Soil Aliquot Volume: CONCENTRATION UNITS: (ug/L or ug/Kg) LjCLdJlQ. Q (tiL) 74-87-3 74-83-9 75-01-4 75-00-3 75-09-2 67-64-1 75-15-0 75-35-4 75-34-3 540-59-0 67-66-3 107-06-2 78-93-3 71-55-6 56-23-5 75-27-4 78-87-5 10061-01-5- 79-01-6 124-48-1 79-00-5 71-43-2 10061-02-6- 75-25-2 108-10-1 591-78-6 127-18-4 79-34-5 103-88-3 108-90-7 100-41-4 100-42-5 1330-20-7— -Chloromethane -Bromomethane -Vinyl Chloride -Chloroethane -Methylene Chloride ~ A ce t on e —Carliion Disul fide -1,1-Dichloroethene -1,1-r-Di chloroethane ~1,2-Dichloroethene(total) -Chloroform — 1,2-Di c h 1 o r o€^ t hane —2-Butanone — 1,1,l-Trichloroethane —Carbon Tetrachloride —Bromodichloromethane — 1,2-Dichloropropane ~cis-l,3-Dichloropropene "-Trichloroethene — D i b romo c h 1 o rome -t han e — 1 , 1 , 2 - T r i c h l o r o e t h a n e —Benzerie —Li'ans-l ,3~Di chloropropene —Bromoform —4-Methy1-2-Pentanone —2-Hexanone —Tetrachloroethene — 1,1,2,2-Tetrachloroeth^ine —Toluene —Chlorobenzene —Ethylbenzene — S t y r e n e —Xylene "(total )._J 1_ 12 ; 12 ; 12 12 ; .X : 13 ; 12 ! 12 ; 12 ; 12 12 ; 12 12 12 1 *~^ J. x;. 12 12 12 12 12 12 12 12 J. 2 12 12 12 12 12 12 10 12 46 U U U Ll ^ u Ai^VZi u U u u u LJ UJ LJ u :u u • u u .u Ll ;u ij ;u ;u ;u3 ;u ;u ;u :u ', J ;u ;B a; QC FORM I VOA 3 0 2 6 8 6 R 3 / 9 0 IE VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS Lab Name: ETC/GULF SOUTH Ab Code: GULF Case No.: HLA Matrix: (soil/water) SOIL Sample wt/vol: 5.0 (g/mL) G Level: . (low/med) LOW ": Moisture: not dec. 19 GC Column: RTX-502.2 ID: 0.530 (mm) Soil Ex-tract Volume: (uL) Number TICs found: 3 Contract: SAS No.: EPA SAMPLE NO, B12426 SDG No.: 95020 Lab Sample ID: VVG0Q5 Lab File ID: V0VVG05 Date Received: 02/03/95 Date Analyzed: 02/09/95 Dilution Factor: 1.0 Soil Aliquot Volume: CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG (uL) CAS NUMBER == — =:=:=:=:=:=:===:=::=:=:==: 1. 76-13-1 3. 1634-04-4 COMPOUND NAME 1,1,2-TRICHLORO-l,2,2-TRIFLU UNKNOWN 2-METH0XY-2-METHYLPR0PANE RT = =:=:=::==:=:=: 4.52 4.. 87 5-62 EST^ CONC. z:.-=:==:=:; r:.-—=:=:====: 24 68 13 Q .— =:==:=: JN .JhJ JN QC FORM I VOA-TIC 302686S 3 / 9 0 IA VOLATILE ORGANICS ANALYSIS DATA SHEET ab Name: ETC/GULF SOUTH Contract: EPA SAMPLE NO. ClOOOl Lab Code: GULF Case No. HLA SAS No.: SDG No. 95020 Matrix: (soil/water) SOIL Lab Sample ID: VTF002 Sample wt/vol: 5.0 (g/mL) G Level: (low/med) LOW "; Moisture: not dec. 18 GC Column: RTX-502,2 ID: 0.530 (mm) Lab File ID: V0VTF02 Soil Extract Volume: CAS NO. (uL) Date Received: 01/30/95 Date Analyzed: 02/03/95 Dilution Factor: 1..0, Soil Aliquot Volume: COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG 74-87-3 74-83-9 75-01-4 75-00-3 75-09-2 67-64-1 75-15-0 75-35-4 75-34-3 540-59-0 67-66-3 107-06-2 78-93-3 71-55-6 56-: 75-27-4 78-87-5 10061-01-5- 79-01-6 124-48-1 79-00-5 71-43-2 10061-02-6- 75-25-2 108-10-1 591-78-6 127-18-4 79-34-5 108-88-3 108-90-7 100-41-4 100-42-5 1330-20-7— Chloromethane Bromomethane Vinyl Chloride Chloroethane Methylene Chloride Acetone Carbon Disulfide 1,1—Dichloroethene 1,l~Dichloroethane •1,2-D i c hi oroet hen e( total) Chloroform • 1 , 2 - D i c h l o r o e t h a n e •2-E<u tanone -1,1, l-Trichloroethane Carbon Tetrachloride -Bromodichloromethane -1,2-Dichloropropane -cis-1,3-Dichloropropene -Trichloroethene -D i b romo c h1o rome t han e -1,1,2-Tri chloroethane -Benzene - t r a n s - 1 , 3 - D i cl-iloropropene -E<romof orm -4-Methyl-2-Pentanone —2—Hexanone -Tetrachloroethene -1,1,2,2-Tetrachloroethane —Toluene -Chlorobenzene —Ethyl benzene —Styrene —Xylene (total) Q - 12 12 •* o .L 4C„ 12 / a ^ 23 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 , 12 12 12 12 12 10 12 12 12 1 1 ;u •|U :u ;u [ j i ^ u 'A^U3 !U ;u ;u ;u ;u ;u :uj ;u ;u :u ;u :u ;u ; u 'lU ;u ;u ;u :u :u:i ;u ;u ; j ;u ;u ;u :J 1 .(uL) FORM I VOA 302686T '>/90 IE VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS Lab Name: ETC/GULF SOUTH .ab Code: GULF Case No.: HLA Matrix: (soil/water) SOIL Sample wt/vol: 5.0 (g/mL) G Level: (low/med) LOW r.' Moisture: not dec. 18 GC Column: RTX-502.2 ID: O.530 (mm) Soil Extract Volume: (uL) Number TICs found: 4 Contract: SAS No.: EPA SAMPLE NO, ClOOOl SDG No.: 95020 Lab Sample ID: VTF002 Lab File ID: VOVTFO: Date Received: 01/30/95 Date Analyzed: 02/03/95 Dilution Factor: X_._0 Soil Aliquot Volume: CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG (uL) CAS NLJMBER 1. 76-13-1 2, 1634-04-4 3. 4. COMPOUND NAME =:=:z:r:=:=:=:—sr — Kz = : — = : = : = : = = = = = = : = : —u==:::= = 1 , 1,2-TRICI-iLORO-l ,2,2-TRIFLU ;2~METH0XY-2~METHYLPR0PANE UNKNOWN ;UNKNOWN RT - j = = = = = = = = 4 - 55 5.62 18.53 19.62 EST. = = ===: :.- CONC , 11 10 3 6 Q " * * * • " ' " " " " JN JN J^/ J A/ o LC FORM I VOA-TIC 302687 3/90 IA VOLATILE ORQANICS ANALYSIS DATA SHEET Lab Name: ETC/GULF SOUTH L a b Code: GULF Case No.: HLA Matrix: (soil/water) SOIL Sample wt/vol: 5.0 (g/mL) G Level: (low/med) LOW "; Moisture: not dec. 12 GC Column: RTX-502.2 ID: 0.530 (mm) Soil Extract Volume: _. (uL) Contract; SAS No,: EPA SAMPLE NO. C11618 SDG No,: 95020 Lab Sample ID: VTF0Q3 Lab File ID: V0VTF03 Date Received: 01/30/95 Date Analyzed: 02/03/95 Dilution Factor: l^.jO Soil Aliquot Volume: (uL) CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG Q 74-37-3 74-83-9 75-01-4 75-00-3 75-09-2 67-64-1 75-15-0 75-35-4 75-34-3 540-59-0 67-66-3 107-06-2 73-93-3 71-55-6 56-23-5 75-27-4 73-87-5 10061-01-5 79-01-6 124-48-1 79-00-5 71-43-2 10061-02-6- 75-25-2 103-10-1 591-78-6 127-18-4 79-34-5 103-83-3 108-90-7 100-41-4 100-42-5 1330-20-7 —Chloromethane Bromomethane Vinyl Chloride Chloroethar^e —Methylene Chloride — A c e t o n e Carbon Disulfide 1,1-Dichloroethene 1, l-Dichloroetl-iane 1 .,2-Dichloroethene( total )_ C h1o rofo rm 1,2-Dichloroe-thane —2-Butanone —1,1,l-Trichloroethane —Carbon Tetrachloride —Bromodichloromethane 1,2-Dichloropropane cis-1,3-Di chloropropene T r i c h l o r o e tl'iene D i t) r omo c b 1 a rome t han e 1,1,2-Tri chloroe tliane Benzene -1 ran s-1 , 3-D i c h 1 o ro p ro pen e_ Bromoform — 4 - M e th-/l-2-i-'en tanone — 2 - H e x a n o n e Tetrachloroethene 1 r, 1,2,2-Tetrachloroethane. Toluene Chlorobenzene Ethylben zene Styrene Xylene (total) FORM I VOA 302688 3/90 IE VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS HLA ' ab Name: ETC/GULF SOUTH Lab Code: GULF Case No. Matrix: (soil/water) SOIL Sample wt/vol: 5.0 (g/mL) G Level: (low/med) LOW ": Moisture: not dec. 12 GC Column: RTX-502.2 ID: 0.530 (mm) Soil Extract Volume: (uL) Number TICs found; 2 Contract: SAS No.: EPA SAMPLE NO. C11618 SDG No.: 95020 VTF003 V0VTF03 Lab Sample ID: Lab File ID: Date Received: 01/30/95 Date Analyzed: 02/03/95 Dilution Factor: ...1._"..0 Soil Aliquot Volume: (uL) CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG CAS NUMBER 1. COMPOUND NAME UNKNOWN UNKNOWN RT 13,57 19,60 EST. CONC. P J A/ 302689 FORM I VOA-TIC 3/90 IA VOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO, Lab Name: ETC/GULF SOUTH _.ab Code: GULF Case No.: HLA Matrix: (soil/water) SOIL Contract: SAS No. SDG No.: 95020 Lab Sample ID: VTF004 Sample wt/vol: Level: (low/med) '-:. Moisture: not dec. GC Column: RTX-502,; Soil Extract Volume; CAS NO. 5.0 (g/mL) G_ LOW 18 Lab File ID: V0VTF04 ID: 0.530 (mm) (uL) Date Received: 01/30/95 Date Analyzed: 02/03/95 Dilution Factor: 1.0 Soil Aliquot Volume: COMPOUND CONCENTRATION UNITS (ug/L or ug/Kg) UG/KG 74-87-3 74-83-9 75-01-4 75-00-3 75-09-2 67-64-1 75-15-0 75-35-4 75-34-3 540-59-0 67-66-3 107-06-2 73-93-3 71-55-6 56-23-5 75-27-4 78-87-5 10061-01-5 79-01-6 124-48-1 79-00-5 71-43-2 10061-02-6 75-25-2 108-10-1 591-78-6 127-18-4 79-34-5 103-83-3 108-90-7 100-41-4 100-42-5 1330-20-7 -Chloromethane -B romome thane -Vinyl Chloride -Chloroethane -Methylene Chloride -A ce ton e -Ca r bon D i su1f i d e - 1 , 1 - D i c h l o r o e t h e n e - 1 , 1 - D i c i i l o r o e t h a n e - 1 , 2 - D i c h l o r o e t h e n e ( t o t a l ) - C h l o r o f o r m - 1 , 2 - D i c h l o r o e t h a n e -2-Butanone -1,1,1-Tri chloroethane -Carbon Tetrachloride -Bromodi chlorome thar^e -1,2-Dichloropropane -cis-1,3-Dichloropropene -T r i c h 1 o r oe t he^n e -Dibromochloromethane -1,1,2-Trichloroethane -Benzene -trans-1,3-Dichloropropene -Bromoform - 4 - M e t h y l - 2 - P e n t a n o n e -2-Hexanorie . - T e t r a c h l o r o e t h e n e . — 1 , 1 , 2 , 2 - T e t r a c h l o r o e t h a n e - T o l u e n e -Chlorobenzene -Ethylbenzene -Styrene -Xylene (total) Z Q - 12 12 12 12 U ^ 16 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 ' 12 12 12 12 9 12 12 12 12 I 1 :u :u ;u ;u ' ^ u ; ^ t / 3 ;u :u ;u :u ;u ;u ; Ll -J ;u ;u ;u ;u ;u ;u ;LI :u ;u :u !U ;u :u 7 ;u :u '.J :u ;u ;u :u .(uL) < > FORM I VOA 302690 ;/90 IE VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS ' ab Name; ETC/GULF SOUTH L.ab Code: GULF Case No.: HLA Matrix: (soil/water) SOIL Sample wt/vol: 5.0 (g/mL) G Level: (low/med) LOW '; Moisture: not dec. 18 GC Column: RTX-502.2 ID: 0.530 (mm) Soil Extract Volume: (uL) Contract: SAS No.: EPA SAMPLE NO. C11820 SDG No.: 95020 Lab Sample.ID: VTF004 Lab File ID: V0VTF04 Number TICs found: 0 Date Received: 01/30/95 Date Analyzed: 02/03/95 Dilution Factor: 1^,_<) Soil Aliquot Volume: CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG .(uL) CAS NUMBER COMPOUND NAME RT E S T : CONC, Q 9^ \ ^ < s QC a FORM I VOA-TIC 302691 >/90 IA VOLATILE ORGANICS ANALYSIS DATA SHEET aiD Name: ETC/GULF SOUTH Contract: EPA SAMPLE NO. C12022 Lab Code: GULF Case No.: HLA SAS No.: SDG No.: 95020 Matrix: (soil/water) SOIL Sample wt/vol: 5.0 (g/mL) G_ Level: (low/med) LOW •-: Moisture: not dec. 1^5 GC Column: RTX-502.: Soil Extract Volume: CAS NO. COMPOUND Lab Sample ID: VTF005 Lab File ID: V0VTF05 II>= _.0.sJ;'30 (mm) (uL) Date Received: 01/30/95 Date Analyzed: 02/03/95 Dilution Factor: 1 .0 Soil Aliquot Volume: ..(uL) CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG 74-87-3 74-83-9 75-01-4 75-00-3 75-09-2 67-64-1 75-15-0 75-35-4 75-34-3 540-59-0 67—66—3 107-06-2 73-93-3 71-55-6 56-23-5 75-27-4 78-87-5 10061-01-5- 79-01-6 124-48-1 — 79-00 71-43-2 10061-02-6- 75-25-2 108-10-1 591-78-6 127-13-4 79-34-5 103-88-3 108-90-7 100-41-4 100-42-5 1330-20-7— Chloromethane Bromomethane Vinyl Chloride Chloroethane Methylene Chloride Acetone Carbon Disulfide 1,1-Dichloroethene 1,1-Dichloroethane 1,2-Di c h l o r o € ? t h e n e ( t o t a l ) C l T l o r o f orm • 1 , 2 - D i c h l o r o e t hane 2-Eu.i.tanorie •1,1, l-Trichloroethane Car bon Te t ra c h1o r i d e -Bromodichloromethane 1,2-Dichloropropane -cis-1,3-Dichloropropene -Tri chloroethene •Di bromoch 1 orome t harie 1,1 ,2-Tric.hloroet!-iane -Benzene -trans-l,3-Dichloropropene -Bromoform -4-Methyl-2-Pentanone -2-Hexanone -Tetrachloroethene -1,1,2,2-Tetrachloroethane -Toluene -Chlorobenzene -Ethylbenzene -Styrene -Xylene (total) 1^ ~_ 12 12 12 12 /2X J. o 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 4. ^ 12 12 12 15 12 12 12 Q U U S ^ ^ FORM I VOA 302692 5/90 IE VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS Lab Name: ETC/GULF SOUTH ab Code: GULF Case No.: HLA Matrix: (soil/water) SOIL Sample wt/vol; 5.0 (g/mL) G Level: (low/med) LOW "-,: Moisture: not dec. 15 GC Column: RTX-502.2 ID: 0.530 (mm) Soil Extract Volume: (uL) Contract: SAS No.: EPA SAMPLE NO. C12022 SDG No.: 95020 Lab Sample ID: VTF005 Lab File ID; V0VTF05 Number TICs found: 0 Date Received: 01/30/95 Date Analyzed: 02/03/95 Dilution Factor: l_-.0 Soil Aliquot Volume: (uL) CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG CAS NUMBER COMPOUND NAME RT EST-. CONC, Q <.\t. > -, > QC FORM I VOA-TIC 302693 3/90 IA VOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: ETC/GULF SOUTH ab Code: GULF Case No.: HLA Matrix: (soil/water) SOIL Sample wt/vol: 5.0 (g/mL) G Level: (low/med) LOW '; Moisture: not dec. 29 GC Column: RTX-502.2 ID: 0.530 (mm) Soil Extract Volume: (uL) Contract: SAS No.: EPA SAMPLE NO. D40001 SDG No.: 95020 Lata Sample ID: VTF006 Lab File ID: V0VTF06 Date Received: 01/30/95 Date Analyzed: 02/03/95 Dilution Factor: 3._„_0. Soil Aliquot Volume: CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG Q 74-87-3 74-83-9 75-01-4 75-00-3 75-09-2 67-64-1 75-15-0 75-35-4 75-34-3 540-59-0 67-66-3 107-06-2 78-93-3 71-55-6 75-27-4 ,78-87-5 10061-01-5- 79-01-6 .1.24-48-1 79-00-5 71-43-2 10061-02-6 75-25-2 108-10-1 591-78-6 127-18-4 79-34-5 103-88-3 108-90-7 100-41-4 100-42-5 1330-20-7 Chloromethane Bromomethane Vinyl L'hloride - — C h i o r o e tt-iane Methylene Chloride Ace-tone Car bon D i su1f i d e 1,1-Di chloroethene —1,1-Dichloroethane 1,2-Dichloroethene(total)_ Chloro'form 1,2-Di c i i l o r o e t h a n e 2~E<utanone 1,1,l~Tri chloroethane Ca r bon Te tra c h1o r i d e B romod i c I'll o rome t hane 1,2-Dichloropropane cis-1,3-Di chloropropene — T r i c h 1 o r oe t hen e Dibromochloromethane 1,1,2-Trichloroethane Benzene — trans-l ,3~Dicl'»loropropene Bromoform 4-Methyl-Til-Pen tan one 2—Hexanone. Tetrachloroethene 1,1,2,2-Tetrachloroethane. Toluene Chlorobenzene_ Ethylbenzene S t y r e n e X y l e n e ( t o t a l ) _ _ _~_] .(uL) FORM I VOA 302694 3/90 IE VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS ' ab Name: ETC/GULF SOUTH l_ab Code; GULF Case No.; HLA Matrix: (soil/water) SOIL Sample wt/vol: 5.0 (g/mL) G Level: (low/med) LOW T; Moisture: not dec. 29 GC Column: RTX-5Q2.2 ID: 0.530 (mm) Soil Extract Volume: (uL) NurtU)er TICs found: 1 Contract: EPA SAMPLE NO. D40001 )AS No.; SDG No.: 95020 Lab Sample ID: VTF006 Lab File ID: V0VTF06 Date Received: 01/30/95 Date Analyzed: 02/03/95 Dilution Factor: 1_,_0. Soil Aliquot Volume: .(uL) CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG CAS NUMBER —.=:=:=:: = ====:=:=:=;--=:=-.=: 1. 1634-04-4 COMPOUND NAME =:=:===:==•. =:=:E;========:==: =:===:=:=:==: 2-METH0XY-2-METHYLF'R0PANE RT ::-.=:=:=:—=:=;=: 5.62 EST. CONC. = = : = = = : = = : : : L-=:==::; 10 Q =:=:== JN > QC ( FORM I VOA-TIC 302695 5/90 IA VOLATILE ORGANICS ANALYSIS DATA SHEET Lata Name: ETC/GULF SOUTH _ab Code: GULF Case No.: HLA Matrix: (soil/water) SOIL Sample wt/vol: 5.0 (g/mL) G Level: (low/med) LOW ": Moisture: not dec. 14 GC Column: RTX-502.2 ID: 0.530 (mm) Soil Extract Volume: (uL) Contract: SAS No.: EPA SAMPLE NO, D41416 SDG No.: 95020 Lab Sample ID: VTF007 Lab File ID: V0VTF07 Date Received: 01/30/95 Date Analyzed: 02/03/95 Dilution Factor: l..r.i?. Soil Aliquot Volume: ..(uL) CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG Q 74-37-3 Chloromethane I 74-83—9 Bromomethane 1 75-01-4 Vinyl Chloride . ', 75-00-3 Chloroethane ! 75-09-2 Methylene Chloride ,^."?.... . C / I — . "1 - — -..-.. — A.i—.-.+ P-1. ,1 I o/—o't J. — Hcet.one i 75-15-0 Carbon Disulfide 1 75-35-4 1,1-Di chloroethene 1 75-34-3 1,1-Di chloroe thane 540-59-0 1,2-Di chloroe t hene (total ) ' 67-66-3 Chloroform 1 107-06-2 1,2-Dichloroethane 78-93-3 2-Butanone I 71-55-6 1,1,1-Trichloroethane ..'o .tia o — — Larbon Tetracl-iloi'ide 75-27-4 E< romod i chlorome thane 7Q_Q7_5 1,2-Dichloropropane 10061-01-5 cis-1,3-Dichloropropene 79-01-6 Trichloroethene 124-48-1 Dibromoclil oromet hane /v~u*j a 1,1,Jt—1 r 1 cliioroetllane /.I. '40—4:. — —tienzene 10061-02-6 trans-1,3-Dichloropropene 108-10-1 4-Methyl-2-Pen tanone 591-78-6 2-Hexanone 127-18-4 Tetrachloroethene 79-34-5 1,1,2,2-Tetrachloroethane 108-88-3 Toluene 108-90-7 Chlorobenzene 100-41-4 Ethyl ben zene 100-42-5 Styrene 1330-20-7 Xylene (total) -12 : 12 12 12 ; 16 • 12 ; 12 12 ; 12 12 • 12 12 12 12 12 12 ; 12 12 12 12 12 12 ; 12 12 12 12 ; 12 13 ! 12 ; 12 ; 12 1 '"v 1 ^ u ; Ll u LJ u u u : u u : LJ LJ 3 : LJ ; Ll u ; u ; ;u : u ; lU ; u ;u ;u ; ; u ;u : : u J ; ;u : :u I 1 1 1 ; u : u :u ; J : 1 1 <5 Qi 5 caa FORM I VOA 302696 5/90 IE VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS Lata Name: ETC/GULF SOUTH i_ab Code: GULF Case No.: HLA Matrix: (soil/water) SOIL Sample wt/vol; 5.0 (g/mL) G Level: (low/med) LOW '; Moisture: not dec. 14 GC Column: RTX-502.2 ID: O.530 (mm) Soil Extract Volume: (uL) Number TICs found; 2 Contract: SAS No.; EPA SAMPLE NO. D41416 SDG No.: 95020 Lab Sample. ID: VTF007 Lab File ID: V0VTF07 Date Received: 01/30/95 Date Analyzed: 02/03/95 Dilution Factor: I.O. Soil Aliquot Volume: CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG .(uL) CAS NUMBER 1. 2. 1634-04-4 COMPOUND NAME UNKNOWN 2-METH0XY-2-METHYLPROPANE RT 2.90 5.65 EST. CONC. 8 8 1 1 1 1 1 J A / JN o CD «1N ' O «:y •D 0) 0) > «-• Oi ra CE O FORM I VOA-TIC 302697 ;/90 IA VOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: ETC/GULF SOUTH uab Code: GULF Case No.: HLA Matrix: (soil/water) SOIL Sample wt/vol: 5.0 (g/mL) G Level: (low/med) LOW ': ^ioisture: not dec. 15 GC Column: RTX-502.2 ID: 0.530 (mm) Soil Extract Volume; (uL) Contract: SAS No.; EPA SAflPLE NO D42022 SDG No.: 95020 - Lab Sample ID: VTFOOS Lab File ID; V0VTF08 Date Received: 01/30/95 Date Analyzed: 02/O4/95 Dilution Factor: 1.0 Soil Aliquot Volume: .(uL) CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG Q 74-87-3 74-83-9 75-01-4 75-00-3 75-09-2 67-64-1 75-15-0 75-35-4 75-34-3 540-59-0 67-66-3 107-06-2 78-93-3 71-55-6 56-23-5 75-27-4 73-87-5 10061-01-5- 79-01-6 124-48-1 79-00-5 71-43-2 10061-02-6- 75-25-2 108-10-1 591-78-6 127-18-4 79-34-5 108-88-3 108-90-7 100-41-4 100-42-5 1330-20-7— -Chloromethane —Bromomethane -Vinyl Chloride -Chloroethane -Methylene Ch1oride —A c e ton e -Carbon Disulfide -1,1-Dichloroethene -1,1-Dichloroethane -1,2-Di chloroethene(total)_ -C h1o rofo rm -1,2-Dichloroethane •-2-Butanone — 1,1, l-Trichloroethane -Carbon Tetrachloride —Bromodichloromethane —1,2-Dichloropropane —cis-1,3-Dichloropropene —Trichloroethene —Dibromochlorometh£ine — 1,1,2-Trichloroethane —E<enzene —trans-1,3-Dichloropropene_ —Bromoform —4-Me t hyl-2-F'en tanone —2-Hexanone —Tetrachloroethene —1,1,2,2-Tet rachloroet thane. —Toluene —Chlorobenzene —Ethylbenzene —Styrene —Xylene ( total) \ FORM I VOA 3/90 302698 IE VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS Lab Name: ETC/GULF SOUTH .ab Code; GULF Case No.: HLA Matrix: (soil/water) SOIL Sample wt/vol: 5.0 (g/mL) G Level: (low/med) LOW ': Moisture: not dec. 15 GC Column: RTX-502.2 ID: 0.530 (mm) Soil Extract Volume: (uL) Number TICs found: 2 Contract: SAS No.: EPA SAMPLE NO, D420: SDG No.: 95020 Lab Sample ID: VTFOOS Lab File ID: VOVTF08 Date Received: 01/30/95 Date Analyzed: 02/04/95 Dilution Factor: 1,.0 Soil Aliquot Volume: ..(uL) CONCENTRATION UNITSu ( u g / L o r ug/Kg) UG/KG CAS NUMBER .-.7.^:=::=: = = = =:=:==:—=:==:=: 1, 2. 1634-04-4 COMPOUND NAME sr rr := r: =:==:=:=: :==:=:=:=:==:==:=:=: = =: = = : = = : s==: UNKNOWN 2~METH0XY-2~METHYLPR0PANE RT :::=:====:=: = 2.90 5.63 EST-. CONC. ; = = : = : = =:=:=:==.-=.•=:=;=; j 7 ; 9 ; Q JN CO CJ > > FORM I VOA-TIC 302699 J/90 IA VOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: ETC/GULF SOUTH .ab Code: GULF Case No.: HLA Matrix: (soil/water) SOIL Sample wt/vols 5.0 (g/mL) G Level: (low/med) LOW 'i Moisture: not dec. 7 GC Column: RTX-502.2 ID: 0.250 (mm) Soil Extract Volume; (uL) Contract: SAS No.: EPA SAMPLE NO. F21215 SDG No.: 95020 Lab Sample ID: VSR002 Lab File ID: V0VSR02 Date Received: 01/25/95 Date Analyzed: 02/02/95 Dilution Factor: 1,..Q Soil Aliquot Volume: .(uL) CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG Q 74-87-3 74-83-9 75-01-4 75-00-3 75-09-2 67-64-1 75-15-0 75-35-4 75-34-3 540-59-0 67-66-3 107-06-2 73-93-3 75-27-4 78-87-5 10061-01-5 79-01-6 124-48-1- 79-00-5 71-43-2 10061-02-6 75-25-2 108-10-1 591-78-6 127-18-4 79-34-5 108-88-3 103-90-7 100-41-4 100-42-5 1330-20-7 Chloromethane E'. romome thane Vinyl Chloride C hio roe t hane Methylene Chloride Acetone Carbon Disulfide 1,1-Dichloroet.hene 1, l-Dichloroeth^^ne 1,2-Dichloroethene(total). Chloroform 1,2-Dichloroethane 2-Butanone 1,1,l-Trichloroethane Carbon T e t r a c i i l o r i d e E<romodi chlorome t h a n e 1,2-Dichloropropane cis-1,3-~Di chloropropene Trichloroethene Dibromochloromethane 1,1,2-Trichloroethane E<enzene trans-1,3-Dichloropropene Bromoform 4-Methyl-2-Pentanone 2-Hexanone Tetrachloroethene 1,1,2,2-Tetrachloroethane. Toluene Chlorobenzene Ethylben zene S t y r e n e Xylene ( t o t a l ) Z ! FORM I VOA 302700 >/90 IE VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS Lab Name: ETC/GULF SOUTH _ab Code: GULF Case No.: HLA Matrix: (soil/water) SOIL Sample wt/vol; 5.0 (g/mL) G Level: (low/med) LOW 'i Moisture: not dec. ^7 GC Column: RTX-502.2 ID: 0.250 (mm) Soil Extract Volume: (uL) Number TICs found: 0 Contract: SAS No.: EPA SAMPLE NC F2121: SDG No.: 95020 Lab Sample ID: VSR0Q2 Lab File ID: VOVSRO: Date Received: 01/25/95 Date Analyzed: 02/02/95 Dilution Factor: j.,,,0 Soil Aliquot Volume: .(uL) CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG CAS NUMBER COMPOUND NAME RT :ST-. CONC. Q 01 Q:: FORM I VOA-TIC 302701 3 / 9 0 IA VOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: ETC/GULF SOUTH L-ab Code: GULF Case No.: HLA Matrix: (soil/water) SOIL Sample wt/vol: 5.0 (g/mL) G Level: (low/med) LOW :-: Moisture: not dec. 14 GC Column: RTX-502.2 ID: 0.250 (mm) Soil Extract Volume: (uL) Contract: SAS No.; EPA SAMPLE NO. F21820 SDG No.: 95020 Lab Sample ID: VSR003 Lab File ID: VOVSRO: Date Received: 01/25/95 Date Analyzed: 02/02/95 Dilution Factor: .1....0 Soil Aliquot Volume: (uL) CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG Q 74-87-3 74-83-9 75-01-4 75-00-3 75-09-2 67-64-1 75-15-0 7 5-35-4 75-34-3 540-59-0 67-66-3 107-06-2 73-93-3 71-55-6 56-23-5 75-27-4 78-87-5 10061-01-5- 79-01-6 124-48-1 79-00-5 71-43-2 10061-02-6- 75-25-2 103-10-1 591-78-6 127-18-4 79-34-5 108-83-3 108-90-7 100-41-4 100-42-5 1330-20-7— C hloromethan e Bromomethane Vinyl Chloride Chloroethane Methylene Chloride Acetor\e Carbon Disulfide 1,1-Dichloroethene 1,1-Dichloroethane 1,2-Dichloroethene(total)_ Chloroform 1,2-Dichloroethane 2-Bu t £in on e 1,1, l-Trichloroethane Cartoon Te^trachloride Bromodichloromethane 1,2-Di chloropropane cis-1,3-Dichloropropene Trichloroethene Dibromochloromethane 1,1,2-Trichloroethane Benzene trans-1,3-Dichloropropene_ Bromoform 4-Me t hyl-2-l-'en tanone 2-Hexanone Tetrachloroethene 1,1,2,2-Tetrachloroethane. To1uene Chlorobenzene Ethylbenzene S tyren e Xylene (total) ~ " ~ FORM I VOA 302702 5/90 IE VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS Lab Name: ETC/GULF SOUTH .\b Code: GULF Case No.: HLA Matrix; (soil/water) SOIL Sample wt/vol: 5.0 (g/mL) G Level: (low/med) LOW 'i Moisture: not dec. 14 GC Column: RTX-502.2 ID: 0.250 (mm) Soil Extract Volume: (uL) Number TICs found: 2 Contract: SAS No.: EPA SAMPLE NO, F21S20 SDG No.: 95020 Lab Sample ID: VSR003 Lab File ID; V0VSR03 Date Received: 01/25/95 Date Analyzed: 02/02/95 Dilution Factor: 1.0 Soil Aliquot Volume: .(uL) CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG CAS NUMBER 1. 76-13-1 2. 1634-04-4 COMPOUND NAME 1,1,2-TRICHLORO-l,2,2-TRIFLU 2-METH0XY-2-METHYPR0PANE RT 4.50 5-60 EST, CONC. 16 8 Q JN JN •> -rs QJ TO QC O FORM 1 VOA-TIC 302703 •>/90 IA VOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: ETC/GULF SOUTH _ab Code: GULF Case No.: HLA Matrix: (soil/water) SOIL Sample wt/vol; 5,0 (g/mL) G Level: (low/med) LOW *: Moisture: not dec. 13 GC Column: RTX-502.2 ID: 0,250 (mm) Soil Extract Volume: (uL) Contract: SAS No.; EPA SAMPLE NO F30001 SDG No.: 95020 Lata Sample ID: VSR004 Lab File ID: V0VSR04 Date Received: 01/25/95 Date Analyzed: 02/02/95 Dilution Factor: 1.0 Soil Aliquot Volume: .(uL) CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG 74-87-3 74-83-9 75-01-4 75-00-3 75-09-2 67-64-1 75-15-0 75-35-4 75-34-3 540-59-0 67-66-3 107-06-2 73-93-3 71-55-6 56-23-5 75-27-4 78-87-5 10061-01-5— 79-01-6 124-48-1 79-00-5 71-43-2 10061-02-6— 75-25-2 108-10-1 591-78-6 127-18-4 79-34-5 108-88-3 108-90-7 100-41-4 100-42-5 1330-20-7— Chloromethane Bromomethane Vinyl Chloride Chloroethane I l e t h y l e n e C h l o r i d e Acetone Carbon Disulfide 1,1-Di chloroethene 1,1-Dichloroethane 1,2-Dichloroethene(total)_ Chloroform 1,2-Dichloroethane 2-Butanone 1,1, l-Trichloroethane Carbon Tetrachloride Bromodichloromethane 1,2-Dichloropropane cis-1,3-Di chloropropene Tri chloroethene Dibromochloromethane 1,1,2-Trichloroethane Benzene t r a n s - 1 , 3 - D i c h l o r o p r Q p e n e _ E<romof orm 4-Methyl-2-Pentanone 2-Hexanone Tetrachloroe thene 1,1,2,2-Tetrachloroethane Toluene Chlorobenzene Ethylben zene ; S t y r e n e Xylene ( t o t a l ) _ ] ] "_.' 0 11 ; 11 ; 11 : 11 : 17 ; 11 ; 1 : 11 ; 11 : 11 11 ; 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 u U 1 u u iP u-2) U 3 J u u u u u uX " u u u u .u u u u :u u ;u .u^ ;u:7 :ucr ;ua :u3 !ua :ua :uj :u3 H-lt-'cj' FORM I VOA 302704 >/90 IE VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS Lab Name: ETC/GULF SOUTH _ab Code: GULF Case No.: HLA Matrix: (soil/water) SOIL Sample wt/vol: 5.0 (g/mL) G Level: (low/med) LOW "-: Moisture: not dec. 13 GC Column: RTX-502.2 ID: 0.250 (mm) Soil Extract Volume: (uL) Number TICs found: 2 Contract: SAS No.: EPA SAMPLE NO. F30001 SDG No.: 95020 Lab Sample ID: VSR004 Lab File ID: V0VSR04 Date Received: 01/25/95 Date Analyzed: 02/02/95 Dilution Factor: 1.0 Soil Aliquot Volume: (uL) CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG CAS NUMBER 1, 75-69-4 2, 76-13-1 COMPOUND NAME TRICHLOROFLUOROMETHANE ETHANE, 1,1,2-TRI CHLORO-1 ., 2, RT .93 4 . EST-. CONC. 7 12 JN JN # 302705 FORM I VOA-TIC 3/90 IA VOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name; ETC/GULF SOUTH _ab Codes GULF Case No.: HLA Matrix: (soil/water) SOIL Sample wt/vol: 5.0 (g/mL) G Level: (low/med) LOW '; Moisture: not dec. 10 GC Column: RTX-502.2 ID: 0.250 (mm) Soil Extract Volume; (uL) Contract: SAS No.: EPA SAMPLE NO F31415 SDG No.: 95020 Lab Sample ID: VSR008 Lab File ID: V0VSR08 Date Received: 01/25/95 Date Analyzed: 0.2/02/9.5 Dilution Factor: 1.0 Soil Aliquot Volume: .(uL) # CAS NO, COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG 74-87-3 74-83-9 75-01-4 75-00-3 75-09-2 67-64-1 75-15-0 75-35-4 75-34-3 540-59-0 67-66-3 107-06-2 73-93-3 71-55-6 56-23-5 75-27-4 73-87-5 10061-01-5- 79-01-6 124-48-1 79-00-5 71-43-2 10061-02-6- 75-25-2 103-10-1 591-78-6 127-18-4 79-34-5 108-88-3 108-90-7 100-41-4 100-42-5 1330-20-7— -Chloromethane —Eiromomethar^e -Vinyl Chloride -Chloroethane -Methylene Chloride -Acetone -Carbon Disulfide -1,1-Dichloroethene -1,1-Dichloroethane -1,2-Dichloroethene(total) -Chloroform —1,2-Dichloroethane —2-Butanone -1,1,1-Trichloroethane -Carbon Tetrachloride -Bromodichloromethane -1,2-Dichloropropane —cis-1,3-Dichloropropene —Tri chloroe t hene —Dibromochloromethane — 1,1,2-Tri chloroetiiane —Benzene —trans-1,3~Dichloropropene —Bromoform —4-Methy1-2-Pentanone —2-Hexanone —Tetrachloroethene — 1., 1 ,2,2-Tetrachloroethane —Toluene —Chloroben zene — E t h y l ben zene — S t y r e n e —Xylene " ( t o t a l ) ' " _ _]^_ 11 11 11 11 17 96 ^~% 4^ 11 11 11 11 1 1 11 11 11 1 1 11 11 11 1 1 11 11 11 11 11 11 11 11 11 11 11 11 11 Q ;u :u 3 :u :u ;B n ; j ;u :u :u ;u ;u ;u;r ;u !U ;u •lU : LJ :u ;u ;u ;u ;u ;u ;u ;u;r ;u :u ;u ;u ;u :u ;u tiff Y-" - »/ rtcr. H-'\', FORM I VOA 302706 >/90 IE VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS ' ab Name: ETC/GULF SOUTH L.ab Code: GULF Case No.; HLA Matrix: (soil/water) SOIL Sample wt/vol: 5.0 (g/mL) G Level: (low/med) LOW ": Moisture: not dec. 10 GC Column: RTX-502.2 ID: 0.250 (mm) Soil Extract Volume: " (uL) Number TICs found; 0 Contract; SAS No.l EPA SAMPLE NO, F31415 SDG No.: 95020 Lab Sample ID: VSR008 Lab File ID: V0VSR08 Date Received: 01/25/95 Date Analyzed: 02/02/95 Dilution Factor: 1.0 Soil Aliquot Volume: .(uL) CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG CAS NUMBER COMPOUND NAME RT EST. CONC. Q LLI ! < s > v. - c > * 302707 FORM I VOA-TIC S/90 IA VOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: ETC/GULF SOUTH Lab Code: GULF Case No.: HLA Matrix: (soil/water) SOIL Sample wt/vol: 5.0 (g/mL) G Level: (low/med) LOW ": Moisture: not dec. 11 GC Column: RTX-502.2 ID: 0.250 (mm) Soil Extract Volume: (uL) Contract: SAS No.; EPA SAMPLE NC F31320 SDG No-; 95020 Lab Sample ID: VSR009 Lab File ID: V0VSR09 Date Received: 01/25/95 Date Analyzed: 02/03/95 Dilution Factor: 1.0 Soil Aliquot Volume: (uL) CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG 7 4 - 8 7 - 3 7 4 - 8 3 - 9 75-01-4 7 5 - 0 0 - 3 7 5 - 0 9 - 2 6 7 - 6 4 - 1 75-15-0 75-35-4 7 5 - 3 4 - 3 5 4 0 - 5 9 - 0 6 7 - 6 6 - 3 107-06-2 7 8 - 9 3 - 3 7 1 - 5 5 - 6 56-23-5 7 5 - 2 7 - 4 7 8 - 8 7 - 5 10061-01-5 79-01-6 124-48-1 7 9 - 0 0 - 5 7 1 - 4 3 - 2 10061-02-6 7 5 - 2 5 - 2 103-10-1 591-78-6 127-18-4 7 9 - 3 4 - 5 1 0 3 - 3 8 - 3 1 0 8 - 9 0 - 7 1 0 0 - 4 1 - 4 1 0 0 - 4 2 - 5 1 3 3 0 - 2 0 - 7 •C h 1 o r ome t han e Bromomethane Vinyl Chloride Chloroethane —Methylene Chloride Acetone Carbon Disulfide 1,1-Dichloroethene 1,1-Dichloroethane 1,2-Dichloro©thene(total)_ Chloroform 1,2-Dichloroethane 2-Butanone 1,1,1-Trichloroethane Carbon Tetrachloride -El romod i c h 1 o r ome t hane 1,2-Dichloropropane —cis—1,3-Dichloropropene Trichlo roe t hen e E)ibromochlorome-thane 1,1,2-Trichloroethane E<erizene t r a n s - 1 , 3 - D i c h l o r o p r o p e n e . . E< romof orm 4-Methyl-2-Pentanone 2-Hexanone Tetrachloroethene 1,1,2,2-Tetrachloroethane. Toluene Chlorobenzene Ethylbenzene Styrene Xylene (total)_ " _] Q 11 11 ; 11 ; 11- ; 14 ; 38 ; 11 ; 11 11 11 ; 11 : 11 11 ; 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 U U 3 U U ^ c/j ASP V j IJ U u u u u uX "" LJ U U U LJ U u u LJ u ;u ^ « lu^r .r u ;u u ;u • U ;u .u 1 nrli t H.ll- V FORM I VOA 302708 5/90 IE VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS •ab Name: ETC/GULF SOUTH . Lab Code; GULF Case No.; HLA Matrix: (soil/water) SOIL Sample wt/vol: 5.0 (g/mL) G Level: (low/med) LOW ": Moisture: not d e c . 11 GC Column: RTX-502.2 ID; 0.250 (mm) Soil Extract Volume: (uL) Number TICs founds 4 Contract: SAS No.: EPA SAMPLE NO F31320 SDG No.: 95020 Lab Sample ID: VSR009 Lab File ID: V0VSR09 Date Received: 01/25/95 Date Analyzed: 02/03/95 Dilution Factor: 1.0 Soil Aliquot Volume: .(uL) CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG CAS NUMBER =3 — = = = : = : = = = : = = = : = = = : = 1. 76-13-1 2. 1634-04-4 3. 4. COMPOUND NAME 1,1,2-TRICHLORO-l,2,2-TRIFLO 2-METH0XY-2-METHYL-PR0PANE UNKNOWN ALDEHYDE UNKNOWN ALDEHYDE RT 4.53 5.62 13.57 19.60 EST. CONC. 7 13 5 5 Q JN JN J A/, J// 302709 CD a. FORM I VOA-TIC 5/90 ILCC LOW CONC. WATER SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO, Lab Name: ETC/GULF SOUTH >rb Code: GULF Case No.: HI^A_ Lab Sample ID: VSIOOl Lab File ID: SVV9I01 Contract: SAS No.: SDG No.: 95010 Sample volume: 1000 (ml) Concentrated Extract Volume: lOOQ Injection Volume: (ul) CAS HO. 1,0 (ul) COMPOUND Date Received: 01/27/95 Date Extracted: 01/30/95 Date Analyzed: 02/03/95 Dilution Factor: 1.0 pH; 6,6 CONCENTRATION ( u g / L ) Q 5 1 - 2 8 - 5 — 1 0 0 - 0 2 - 7 — 1 3 2 - 6 4 - 9 — 1 2 1 - 1 4 - 2 — G j 4 — 6 <')—.c:! 7 0 0 5 - - 7 2 - 3 - 8 6 - 7 3 - 7 — 1 0 0 - 0 1 - 6 — 5 3 4 - 5 2 - 1 — 8 6 - 3 0 - 6 1 0 1 - 5 5 - 3 — 1 1 8 - 7 4 - 1 - -.. / — 1.-.-....:.. ..I 8 5 - 0 1 - 8 120- 1 2 - 7 8 4 - 7 4 - 2 — 2 0 6 - 4 4 - 0 — 1 2 9 - 0 0 - 0 — • • r % , " t — ' / • 9 1 - 9 4 - 1 5 6 - 5 5 - 3 — 2 1 8 - 0 1 - 9 - 1 1 7 - 8 1 - 7 - 1 1 7 - 8 4 - 0 - ^ : . U . . i — v rr— iA.- 2 0 7 - 0 3 - 9 " 5 0 - 3 2 - 8 — 1 9 3 - 3 9 - 5 - 5 3 - 7 0 - 3 — 1 9 1 - 2 4 - 2 - - 2 , 4 - D i n i t r o p h e n o 1 -4-~N i t r o p h e n o 1 - D i b e n z o 7 ' u r a n - 2 , 4 - 1 ) i n i t r o t o l u e n e -I> i e t h y l p 111 h a 1 & t e - 4 - C h 1 o r o p lien y 1 - p h e n y 1 e t h e r - F 1 UO r e n c-? - 4 - N i t r o a n i 1 i n e - 4 , 6 - D i r I i t r o - 2 - M e t rv/1 p h e n o l ~II - hi i t r o ir-od i p h en •-/1.5.fn i n e ( 1) - 4 - B r o m o p |-ien y l - p l"ien y 1 e t tie r -1-le X a. c. h ]. o r o l:)en z eri e -F-'en t a c.i-i 1 o r o p h e n o 1._ _ - P h e n a n t l i r e n e ~ Ari -L ll r a cosr 1 e -D i - n - B u t y 1 p h t h a l a t e - F l u o r a n t h e n e -F'-/ren e - B u t y l b e i i z y l p l ' i t h a i a t e . - 3 , 3 ' - D i cl-iloroi:>en 7. i d i n e - B e n 7. o ( a ) A ri 1111 - a c e n e -Chrysene -bis(2-Ethylhexyl)Phthalate - D i - n - 0 c t y 1 P h t ha 1 a t e '. —E<eri / D (tj) F 1 u o r a r i t he-'fie - B e n z o (1.) F l u o r a n t l i e n e - B e n 2 0 ( a ) F-'yrene - I n d e n o ( 1 , 2 , 3 - c d ) I-'yrene _. - D i b e n 7 ( a , h ) A n t h r a c e n e - B e n z o (g , h , i ) P e r y 1 e n e _ F 20 : 20 ; 5 : 5 ; 1 : 5 ; 5 20 : 20 ; 5 5 2 0 r:^ 5 5 5 c: 5 5 5 JX*-cr' 5 5 5 5 ir 5 r: U u LJ u J U LJ Ll LJ U LJ t 1 LJ u U LJ LJ Ll LJ U U -i»rr- L.i U ; LJ lu ;u ;u u FORM I LCSV- Reviewcd Ey .__—™— Date ^ > 1 ^ ^ h ^ 302710 1 0 / 9 2 ILCF LOW CONC. WATER SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS EPA SAMPLE NO. ' h Name: ETC/GULF SOUTH L.ab Code: GULF Case No.: HLA Lab Sample ID: VSIOOl Lab File ID: SVVSIOl Sample volume: 1000 (ml) Concentrated Extract Volume: 1000 Injection Volume: .1.^0 (ul) Contract: SAS No.: (ul) SDG No.: 95010 Date Received: 01/27/95 Date Extracted: 01/30/95 Date Analyzed: 02/08/95 Dilution Factor: 1.0 pH: 6.6 Number TICs found: CAS NUMBER 1. COMPOUND NAME UNKNOWi^l RT 1 8 . 0 7 EST. CONC. ( u g / L ) Q N Reviewed By Date 302711 FORM I LCSV-TIC 1 0 / 9 2 HLA DATA QUALITY ASSURANCE REVIEW SUMMARY Semivolatile Organic Compounds Analysis CLOU/ COt^CrCf^TfATWbi) Case Number : Cj 5"0 | 0 Project Number ' Z ^ ' S I Z . \ d . Z - Site: ^ r ^ ^ J ) C l e ^ l t ^ C&YV^^. Contractor Laboratory: P/^^^g: ^ . ^ . ^ ^ ^ff^yf CTlA/t'^ Validator Validation Date: 'l^-^hf QC Reviewer. 0 t J c / < k < / ^ PO^<^ZyX^ Review Date: -?/.? <» / ? .r Sample Matrix: [ J ^ f c ^ ( 5") oampie iviaim. UU C»AlL. ^ (^ Q / Analytical Method- ^ P / \ C l P ^ » ^ V - / ^ / ^ ^ . ^ - j ^ ^ - t L . - ^ / ^ r y ^ v t ^ 5 o u 7 Sample Designations: RB^ool 5^00)1^ . ^ 0 ^ \\Ol Soo\Zo Son IZfT Data for the above samples are: Acceptable for use V Acceptable for use as qualified Unacceptable for use Is action required by the Pjco^ct Manager? Yes n ^ o ; Comments: ^ 0 ^ M ^ ^ ^ ^ J L ^ > A o . £ > A = ^ J^^^^yy^ :^pSrJl " U 6 ^ P f \ GfrY^Xic^ bru_l.doc 10U199* lOJ* Fonn BNA IJ) 3 0 2 7 1 2 DATA COMPLETENESS CHEC3CLIST Included, no problems Included, problems Not included NA Not ^plicable Quality Control Summary V Case Narrative ^ Surrogate Recovery Summary fslA MS/MSD Summary TI^ Reagent Blank Siunmary y GC/MS Instrument Performance Summary Sample Data • ^ Chain of Chistody Forms y Holding Times y Organic Analysis Data Sheets X Quantitation Reports V Reconstructed Ion Chromatograms X' Mass Spectra Printouts X" TIC Mass Spectra Library Searches Initial Calibration Data -^i^ Calibration Summary X Standards Quantitation Reports X Standards Reconstructed Ion Chromatograms Continuing Calibration Data |vJA Calibration Summary K\f\ Standards Quantitation Reports K\A Standards Reconstmcted Ion Chromatograms X Intemal Standards Summary Instrument Performance Data y DFTPP Mass Spectra y Reconstructed Ion Chromatogram y DFTPP Mass Listings boa.l.dx: 101*1994 lOM 2 Fonn BNA IJ) 302713 Reagent Blank Data yC Organic Analysis Data Sheets y Quantitation Reports X Reconstructed Ion Chromatograms y Mass Spectra Printouts X TIC Mass Spectra Library Searches Matrix Spike Data and Matrix Spike Duplicate Data NlA Organic Analysis Data Sheets fvj/^ Quantitation Reports NJ/\ Reconstructed Ion Chromatograms Laboratory Control Sample y Organic Analysis Data Sheets yC Quantitation Reports Y Reconstructed Ion Chromatograms X Mass Spectra Printouts X TIC Mass Spectra Library Searches Comments: " " ' " ^ ' ^ i Fonn BNA 1.0 302714 Harding Lawson Assodates SHEET OF . . _ . _ _ J Engineering and ; a ; = 1 ' Environinental Services JOB NO. PROJECT .ild^UtvL^ (jU^ift<jL^4^ C^ryf^-^aaA^M.^ COMPUTED BY C\.\JLX3:iS^ SUBJECT P<x±:fi> \ ] f l i ' u J i n i X O ' y ^ CHECKED BY j^fi^yyvyJaSbi UTP XSCC/V»''^»VL«<AM{. Z^so/oizo^f Soo\zo sJ^A-oo] 5BP3/0-zloiU>'iB' VhoooZ^ \J(S)A-OOZ- S3^ilzi>'Zi-lo}n*\5' Erj2.oz2- -siad'Ooz^ S^VZIo^D-Zoloim^ VZoozo \JC(9-003 52>^zli^'Z\lo\\^^f p^nzi \lQ?,^ov^ ^?>SoLoflt')f, ^ ^ Soows i % i " ^ ^ ^ S3^\l0.0-0.Fp\m^ £\ooof \JQC'003 R3^o/(0i^5'^6' sovizf \iex-oo\ 5BP)/0-l/o|^f^^ P\000l \/5l-£)DZ SgPl/e2.'24/o|^f^r PIZ22M- \/5X-P0ff SbCz/o-ljOlSO'^f CZODVI VTX-^Ol SdC-zjU-ZzloiSoOff CXZZOZ-L VTX-Ofit. SBCZJZiir-lLJOl^c^^' CZZ^ZCf VTX-OO^ RdSol 0130^)5' RBSooi VTX-ofitf I ^ 302715 SPECIFIC COMMENTS REGARDING ANALYSES Chain Of Custody Were samples properiy pr^e^d and received in good condition? ( Y ^ NO Were custody transfers cooaqdy and completely documented? Yes^ No Comments: "TjAHr O^-tOo^^ JlA^t^^ jJU^^^&J. Ct/vvfiC/rv y \ S < J L U > ^ cjlptr\^ j z P ^ Z^-U>(y C ; M I ^ yLO^XiSje^ cuc^^rut^^vr^ ^ ^ ^ ^ ^ ^ ^ • >'&'''^<^ j = ^ j^OiAfYsji^iMi^ JiA>-tAJi ^vtiA^l^-^-U-e^ J,^^^ S/e-»T^ CJdry^JLdOJ&y^ O A H ^ C Z ^ ^ A W U ^ J^jM^Aur^ Ja/>YU^ M ^ ^ VKx;^^ yvr Oi^jjoJu^^Ai^X^.^1^ ClchAyy^J<AJ^t^jteih^K^ Holding Times Were sample extractions TCxibrmed within holding times? nres) No Were sample analyses performed within holding times? /Yes) No Comments: yw- Instrument Tuning Did the instrument performance checks meet acceptance criteria? (Yes) No Were samples analyzed wijhin the 12-hour period following an acceptable pert'ormance check? /Yes) No Comments: TW boi.l.doc 10141994 1054 4 Fonn BNA li) 302716 • Initial Calibration Did the laboratory meet the method requirements regarding the minimum number of calibration standards for an acceptable initial calibrations-^. /Yes) No Did the initial calibration curves meet the linearity criteria for maximum percent relative standard deviation (%RSD)? ^ . ^ Yes mo) Did the initial calibration meet the minimum relative response factor (RRF) criteria? Comments: V JCry{.^ ( ^ < A x J l J h ^ Continuing CaUbration Did the continuing calibration curves meet the linearity criteria for maximum percent difference (%D)? Yes No Did the continuing calibration meet the minimum RRF criteria? Yes No Comments: U^rC^A/VVW^V^ GAjBAin.<itoBrvv<V J^yt'^Z- W » ^ O^yYlcJLKrKAnJl, bDa.Ldoc 10141994 1034 5 Fonn BNA IJ) 3 0 2 7 1 7 Surrogate Recoveries Were the surrogate spike repeveries within acceptance limits? nes) No If the spike recoveries were.«>acceptable. were the samples reanalyzed? /Yes) No NA Comments: iW' Matrix Spikes Were matrix spike analyses performed at the correct frequency and on a sample matrix representative of the samples in the sample delivery group (SDG)? Yes No Were the matrix spike recoveries and relative percent differences (RPDs) within acceptance criteria? Yes No Comments: V ] 4 a i ) v l ^ J ^ ' ^ J k t ( ^ ^ C J U A A U ^ juA^^A^ VUPt (Jlj^v^ o J t J^/jL JleuT Internal Standards Were the intemal standard;tfeas and retention times within the required limits? (Yes) No If the intemal standard requirements were npwnet, were the samples reanalyzed? Yes No ( N A ) Comments: yUv^ bna.Kdoc 10141994 1034 6 ^<x™ BNA IJ) 3 0 2 7 1 8 Blank Analyses Were the appropriate numbpwif blank analyses performed? /Yes) No Were analytes detected in tJj©>blanks? (^Yes) No If analytes were detected in the blanks, were the same analytes also detected in the associated investigative samples? ''Yes) No NA Did the sample results re^iwe qualification due to the presence of analytes in the associated blank samples? Yes) No Comments: y^iAKZ^AsJi (jlj^^OtAUuerv^ Jj&*-AJL yviO^JuL .^/yw ^i^bf-^ j d k > J b i . yv\-Cb{k.aiL_ oJiiy^cJj^'^'uJi c^ywwvwg^. Laboratory Control Samples Were laboratory control samcle (LCS) analyses perfonned at the correct frequency? /Yes) No NA Were the LCS recoveries within acceptable limits? n'es) No NA Comments: _yA^'njv^^X^rLC_ O u Y ^ Jl^jCtlAi.J^.pM$V^^^U^ - " J p f ^ Z o J i K c P A ^ 2 frvdr fdr I ^ CjeryvWu/Af^ AA'O^JIUtL . JiliA(\ZUL ^dwVu%itAt<. AJiC^v<^-t-^ bu_l.doc 10141994 1034 7 Form BNA 1^ 3 0 2 7 1 9 Sample Results Were target analytes repopedJn the investigative samples? Yes) No Were mass spectra provi(ted-for the target analytes reported in the investigative samples? /Ves) No Were the mass spectra of acs^table quality and analytes correctly identified? (YCSJ NO Were the quantitated results for target analytes calculated using the appropriate intemal standards and were the relative retention times (RRTs) acceptable? /Yes) No Comments: '^([mJL Tentatively Identified Compounds Were tentatively identified compound (TIC) searches conducted for all sample analyses? ^es) No NA Were all non-target peaks enaluated as required? /Yes) No Were the TIC mass spectra^-ssarches. identifications, and quantitated results acceptable? pCes) No Comments: YWvit boa.l.doc 10141994 1034 g Fonn BNA IJ) 302720 Log Books Were sample preparations imiDerly documented and performed in accordance with method protocols? (Yes) No WCTC sample analyses properiy docimiented and performed in accordance with method protocols? PYK), NO Conunents: % f Y ^ b(u_l.doc 10141994 1034 9 FoftD BNA iJO 302721 Calculation Checks Instmment Tuning Z f ^ W ^ 1 / 4 5 / Relative Abundance: Initial Calibration / 2 / ^ / ^ ^ f Continuing Calibration RRF: (VU^ O^cJU^^) %D: Surrogate Recovery S 0 0 ( I ^ / bai_l.doc ""*'»^'<»* 10 F=™,BNA1J) 302722 Matrix Spike Recovery (K^a^%/; RPD: (YM- a.wx%^) Sample Results CRQL: 5oo)2g Detected Result: TIC Result SOOII8 TIC ( U J U . ( U ^ _ 4 K ^ . ^ . ^ 1 K ^ . bru.l.doc 10141994 1034 , . ' ^ Fora BNA IS) 302723 HOLDING TIME QUALinCATION SUMMARY FORM Sample Idcnlificaliim Unaj^ iJJL^-^. 1 Date Sampled LtV^/»4- , A A ^y\JL Date Prepared \ \ A ^ J t ^ ' ' Z' Dale Analyzed Prep. Holding Time Analysis Holding Time \ Qualifier 1 1 — —11 UJ o M -J to Comments: buB.l.JlK 10141994 lOM 12 Fonn BNA 1.0 INITIAL CALIBRATION QUALIFICATION SUMMARY FORM ^ OJ o to <1 to cn Date/Time h-hl^^ |-*"T r ' -^ Insuiiment r. Analyte DJ-y^^i'.dyJfMM W-^ppw- RF ^ —' RSD ^ 3 . ^ Samples Affected fiQO ^ y v u r > j ^ j t ^ Qualifier ICf/-) T/UT 1 II Commenis: J J M ^ o U ddji J^^P^^l^ X>^^^^^ biK.l.iluc 10I419M lOM 13 Fonn BNA ) .0 CONTINUING CALIBRATION QUALIFICATION SUMMARY FORM Date/Time ( C d \AU Instrument iX' A/^v/1 Analyte \iiu^^>/) \ 0 o ^ RF %D Samples Affected Qualifier Co o to to Ol Comments: bna_l.doc 10141994 lOM 14 Fonn BNA 1.0 BLANK SUMMARY FORM LO O to lO <1 Blank ID |SgLKU)l I.^BLkU?, L<;gL\<iA;3 Analyte r ( ! A ^ " t 2 L c X y r i ^ X c t ^ ; e r ^ i L < 2 . { l ' f M ) M A ± i lly^(7-eW)z(M.JUti -T ~ / f~ iy^Jl-^Wl^A^L-^ 1 Blank Result (units) 1 (J/^I^) 2 T ^ / T (9.6»a- Action Level 10 ^0 10 6, Associated Samples Sooiif?, soonq ^9,no\zo\ \K Snoia-r RBSOoi 1 1 Coinin VX(rttX (X&^fr^^€- OAh^t^ Ouy^jJUhJut Oa- OAA^^J&ttetE^ (^U) C W ^ / t c u ^ bna^l.duc 10I4I994 1034 15 FomiBNA 1.0 Summary and Conclusions a u . rdrrtc^y^^^ £AAM^\^.^Cf^ Ctr L M ArP^LJKtin^i;f}^>o^v\f^,e0<. _^/H^G^)-K/'2.vd?ud:<>&T^ Q _ ^ ^ ^ ^ XAi-t.0. /Q^fA^^^AA^fiOQ . za^. . ^ „ • :7T/yhfA-^hh^,{> Yy\f.i~- (< Q/p<J2AAy ux:^£-^ Q f?At[V^4xi. nrlur) Alui zh ood'LLdi^rv^ iQsp ^ 3^% (Ler>^•fe^^) r>/r^. ^M'?»- (p- / a h i i s h ^ J,AVTt/l iaH.fl.l^^^L^JZ^ AA^ y\^inr\zS.rkjrtnO /ViAJj X ^ j / r ^ y . J l i r>yPry:f7iAAV\i^rrt7rr-^^' L (OniCk. Ch, p n^j^/rtaJ^iJie U,i^. PiA^ a u n aunlJLjJl &^a^ /T:;fe^| DJ? p)f^m X A^. Validator's Signature: ( \ ^ X < ^ / S • ) A i . . ^ ( 7 b ^ Validator's Initials: Validation Date: ^ f Z ^ f ^ B " QC Reviewer's Signatiu-e -Pk^X^^z^ QC Reviewers Initials PiPF Review Date: ? / 7 e > / ^ ^ bca_l.^oc 10141994 1034 16 £onii.BNA t-n 302728 ILCB LOU) COHC. WATER SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO, b Nc^me: ETC/GULF SOUTH i.ab Code: GULF C A S G N O . : HLA LAb Sample ID: VTXOO'q Contract: SAS No.! SDG No.: 95Q10 Lab File ID: JVVTXO^ Sample volume: .1.000 ,. (ml) Concentrated Extract Volume: 1000 In i e c t i on Vo1ume: (ul) CAS NO. 1.0 (ul) COMPOUND Date Received: 02/01/95 Date Extracted: 02/01/95 Date Analyzed: 02/08/95 Dilution Factor: 1.0 5.6 pH! CONCENTRATION (ug/L) Q 103-95-2- 111~44~4- 9 5-57--£3— 95-A8-7 108-60-1- 106-<^4-5- 621-64-7- 67-72-1— 9B~95~3— 105-67-9- 111-Vl-l- 120-33-2- :120-S2-1- 91-20-3 106-47-8 59-50 91-57 77-47 aci.. - i ^ > — 4 06-2 — -4 95-9 91-5 88-74-4— 131-11-3- 20B-96-8- 606-20-2- 99-09-2— 0%./ %J-.. / F" hen o 1 bis(2-Chloroethyi)Ether 2-C ll 1 o rop hen o 1 2 - M e t h y l p h e n o l 2 , 2 ' - o X y t ) i =;(1 - C l l 1 o r o p r o p > a r i e ) . 4~Methylphenol N-N i t r o s o - D i - n -F' r o py 1 ami n e He X A c h 1 o r o e t hian e N i t r o ben z en e _ Isophorone 2-Ni trophenol 2,4-Dimethylphenol t' i ?;; (2-C ll 1 o roe t ho x y) fie t lian e 2:, 4-Di cl-iloroF)henol 1,2,4-Trichlorobenzene Na p h t ha1en e 4-Chiloroani l i n e HeXacl"i 1 oj-o!:• utad iei"ie.._ 4 - C h l o r o - 3 - M e t h y l pt-ienol 2-Me t hy 1 n a p h t ha 1 en e H e X a c t-11 o r o c y c 1 o fj e n t a d i e n e __._ 2 , 4 , 6 - T r i ch 1 o r o p h e n o 1 2 ^ 4 , 5 - T r i c h 1 o r o p h e n o1 2 - C h l o r o n a p h t ha 1 en e 2.-Ni t r o a n i 1 i n e D i me t hyl P h t hala t e A c e n a f ' | j t h y l e n e _ _ 2,6-Dini trotoluene _. •3-Ni troari i 1 ine Ac.enapl'ithene 5 5 r: 0 . 3 2 0 5 c*. 5 5 n: 2 0 5 2 0 5 J C 5 2 0 5 Ll U u J L.l IJ U u l.l u 1.1 u .u .u :u :u ; u ; u Reviewed By Date FORM I LCSV~1 10/92 302729 ILCC LOW CONC. WATER SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. J b Name: ETC/GULF SOUTH 'Lab Code: GULF Case No.: HLA Lab Sample ID: VTX004 Lab File ID: SVVTX04 Sample volume: 1000 (ml) Concentrated Extract Volume: 1000 Injection Volume: Contract: SAS No.: SDG No.: 95010 (ul) CAS NO. 1.0 (ul) COMPOUND Date Received: 02/01/95 Date Extracted: 02/01/95 Date Analyzed: 02/08/95 Dilution Factor: 1.0 pH: 5.6 CONCENTRATION ( u g / L ) Q 5 1 - 2 8 - 5 1 0 0 - 0 2 - 7 1 3 2 - 6 4 - 9 1 2 1 - 1 4 - 2 8 4 - 6 6 - 2 7 0 0 5 - 7 2 - 3 8 6 - 7 3 - 7 1 0 0 - 0 1 - 6 5 3 4 - 5 2 - 1 8 6 - 3 0 - 6 1 0 1 - 5 5 - 3 - - 1 1 8 - 7 4 - 1 8 7 - 8 6 - 5 8 4 - 7 4 - 2 2 0 6 - 4 4 - 0 1 2 9 - 0 0 - 0 9 1 • 1 2 1 8 - 0 1 - 9 - 1 1 7 - 8 1 - 7 - 1 1 7 - 8 4 - 0 - 2 0 5 - 9 9 - 2 - 2 0 7 - 0 8 - 9 - 5 0 - 3 2 - 8 — 1 9 3 - 3 9 - 5 - 5 3 - 7 0 - 3 — 1 9 1 - 2 4 - 2 - 2 , 4 -D i n i t r o p hen o 1 -_ 4-N i t r o p h e n o 1 -_ D i ben z ofu ran 2 , 4 - D i n i t r o t o l u e n e D i e t h y l p h t h a l a t e 4~C h 1 o r o p hen y 1 - p hen y 1 e t he r F l uorene 4 - N i t r o a n i 1 i n e _ 4 , 6 - D i n i t r o - 2 - fi e t hi y 1 p 11 e r i o 1 N - N i t r o s o d i p l i e n y 1 a m i n e ( 1 ) 4 - B r o m o p 1-i e r i y 1 - p b e n y 1 e l h e i - _ He X a c I"i 1 o r o b e n z e n e F'er i t a c b 1 o r o p h e n o 1 F ' h e i i a n t h r e n e Anthracene D i - n ~ B u t y l p h t h a l a t e F1UO r a n t hen e F'yrene B u t y l b e n 7 y l p h t ! i a l a t e _ . 3 , 3 ' - D i c h l o r o b e n z id i n e — "Ben 7. o ( a) An t b r a cen e ChryisenC' b i s ( 2 - E t"hy:i liexy 1 ) P h t i i a 1 a te ~'D i -n - 0 c t y 1 F' h t l-ia ]. a t e _ - - - B e n zo ( b) F'luoran t h e n e Ben z o ( k ) F l u o r a n t h e n e Ben zo ( a ) F'yrene l n d e n o ( 1 , 2 , 3 - c d )F'yrene Di ben z ( a , 11)An t h r a c e n e _ _ E<en zo (g , h , i ) F ' e r y l e n e 2 0 • 20 ; 5 ; 5 : 21 ; 5 : 5 ! 20 ; 20 ! rt 1 r.:^ 1 5 2 0 1= 1 c: 5 5 1= Xi 13 c: i:: t: *.' tr 5 5 c: c tr. 5 L.1 U U U U U U L.l IJ L.l U L.l l.J L.1 U U L.1 L.l L.1 IJ U uT .u • u ; Ll ; 1.J ;u ;u Reviewed By Date FORM I LCSV-2 1 0 / 9 2 302730 ILCF LOW CONC. WATER SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS EPA SAMPLE NO. I '^b Name: ETC/GULF SOUTH f_ab Code: GULF Case No.: HLA Lab Sample ID: VTX004 Lab File ID: WVTX04 Sample volume: 1000 (ml) Concentrated Extract Volume: 1000 Injection Volume: _l-0 (ul) Contract: SAS No.: (ul) SDG No.: 95010 Date Received: 02/01/95 Date Extracted: 02/01/95 Date Analyzed: 02/08/95 Dilution Factor: 1.0 pH: 5.6 Number TICs found: 0 CAS NUMBER COMPOUND NAME RT EST. CONC. ( u g / L ) 0 Reviewed By Date FORM I LCSV-TIC 302731 10/92 ILCH LOW CONC. WATER SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. S00118 I -b Name: ETC/GULF SOUTH ^.ab Code: GULFl. Case No.: HU£L Lab Sample ID: VQCOOl Lab File ID: SVVQCOl Sample volume: 1000 (ml) Concentrated Eixtract Volume: 1000 I n j e c t J. on V o 1 unie: Contract: SAS No.: SDG No.: 95010 (ul) CAS NO. _L^0 (ul) COMPOUND Date Received: 01/23/95 Date Extracted: 01/24/95 Date Analyzed: 02/03/95 Dilutior^ Factor: 1.0 pH: 6.9 CONCENTRATION (ug/L) Q 108-95-2-- 111-44-4- 95-57-8— 95-48-7— 108-60-1- 106-44-5- 621-64-7- 67-72-1 — e-, I—J r-. rA - y _ •y .-A. - -7 ..l-o 73-59-1 — r-. f-, -7 i:: TA 105-67-9- 111-91-1- J . / L O — O v . ) — i U ~ 120-82-^~ 9i-20-3 106-47-8- 87-63-3 r; .—. c: t-. —t >.i ;- — ».iU •• / 91-57-6— 77-47-4 f;5S-06-2— r ; \" r ; r: .-t 91-58-7— 88-74-4 131-11-3- 208-96-8- 606-20-2- 99-09-2— -F" hen o 1 -bis (2-Chroroethyl) Ether ]] -2~C ll 1 o r o p hen o 1 -2-Methylphenol - 2 , 2 ' -oXy t>is> ( 1 -C b 1 o r o p roparie?) _. -4-Me t h y l p hen o1 -N-N i t r oso~D i - n -F' r o py 1 am i n e -He:». a c h 1 o rote t han e -N:i trobe^nzene - I s o p h o r o n e , - 2 • • N i 11 - o p l"i e r I o 1 __ -2,4-Dimethylphenol -bis (2-Cliloroethoxy) Methane -2,4-Dichlorophenol -1,2,4-Tr i cI'lloroben zene -Na p h t ha 1 ene -4-Chloroani lirie - i-i e X a c |-i 1 o r o !:• u t a d i. e ri e - 4 - C I'l ]. c:> I- a - 3 - M e "L b y 1 p T i e ri o ]. -2-Me t hyl n a p h t ha len e -HeXa c: \\ 1 oro cyc 1 open tad iene -7:!, 4 ,6-T r i ch 1 oropheno 1 -2,4,5-Tri chlorophenol -2~C h 1 o ron a p hi t ha len e -2-Ni troan i 1 ine -D i me thyl P h thala te -Acenaphthylene_ - 2., 6 - D 3. n i 11 - o L o 1 u e n e -3-Ni troan i1ine -Acenaphthene:- 5 5 ; 5 5 ; 5 5 ; 5 ! 5 ; tr. 1 C 1 c: 5 ; 5 5 ; 5 5 0 5 5 5 5 5 0 5 0 5 c:^ c \0 u u u u u u u u L.1 U l.l u L.l IJ U L.i u U L.1 1.J LJ u u Ll ,u .u :u ;u ;u Revie«e1 B, Q g ! V £ i ^ M i . FORM I LCSV-1 1 0 / 9 2 302732 ILCC LOW CONC. WATER SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET ^.b N5.me: ETC/GULF SOUTH 'Lab Code: GUL..F Case No.: HLA Lab Sample ID: VQCOOl Lab File ID: SVVQCOl Sample volume: 1000 (ml) Concentrated Extract Volume: 1000 Injection Volume: Contract; SAS No,: EPA SAMPLE NO. S00118 SDG No.: 95010 (ul) CAS NO. 1..0 (ul) COMPOUND Date Received: 01/23/95 Date Extracted: 01/24/95 Date Analyzed: 02/08/95 Dilution Factor: 1.,0 pH: 6.9 CONCENTRATION (ug/L) Q 51-28-5 100-02-7 132-64-9 121-14-2 r*./i / i '^ __' 7005-72-3 86-73-7 100-01-6 534-52-1 86-30-6 101-55-3 118-74-1 87-86-5- 85-' 120-12" 2 0 6 - 4 4 - 0 — 129-00-0 -> „ . C> 1"-.. " <:"• <: / 91-94-1 c. / „ c: n: "-"' _ %.< O *.• V.' *.> 218-01-9 117-81-7 117-84-0 205-99-2 207-08-9 50-32-8- 193-39-5 53-70-3 191-24-2 2 , 4-D i n i t ro p hen o 1 4-N itrophenol Di ben zofuran 2,4-Dinitrotoluene Diethylphthalate 4-C h1o rop hen y1-p hen y1e t he r. Fluorene 4-Ni troaniline 4,6-Din i tro-2-Methylphenol. N-N i t rOS od i pheny1amine (1). 4-B r omo p lien y 1 - p hen y 1 c? t lie i" I"lex a c h l o r o ben z e n e F'eri t a c hi 1 o ro p hei'n o 1 F'henan tl'irene An t h r a cen e _ D i - n -Bu t y 1 p l"i t ha 1 a t e F l u o r a n t h e n e F'yi'ene Bu Ly 11)en z y 1 p hit lia ]. a Le 3 , 3 ' -Dic.i-\lorotaenzidine Ben zo (^*) An t h r a c e n e C h r y s e n e b i s ( 2 - E t h y l " h e x y l ) P h t h i a l a t e D i - n - O c t y 1 P h t h a 1 a t e Ben z o (t)) F" 1 u o r an t hene_ _ B e i-i z o (1 ••.) F1 u o r a n t h e n e Ben zo ( a ) F'yrene. I n d e n o ( 1 , 2 , 3 - c d )i-'yrene D i t:>en z (.?., hi) An t h r a cen e Ben zo (g , h , i ) F ' e r y l e n e 2 0 20 ! 5 •~ t 5 5 ; 5 ; 20 ; 2 0 5 ; Ul U 1.1 L! L.1 U Li U L.1 U 20 K) , 5 ^ -z> U I T FORM I LCSV-2 10/92 302733 ILCF LOW CONC. WATER SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS EPA SAMPLE NO. I ab Name: ETC/GULF SOUTH -ab Code: GULF Case No.: HLA Lab Sample ID: VQCOOl Lab File ID: SVVQCOl Sample volume: 1000 (ml) Concentrated Extract Volume: 1OOP Injection Volume: 1.,0 (ul) Contract: SAS No.: (ul) SDG No.: 95010 Date Received: 01/23/95 Date Extracted: 01/24/95 Date Analyzed: 02/08/95 Dilution Factor: 1.0 pH: 6.9 Number TICs found CAS NUMBER 1. COMPOUND NAME UNKNOWN AMIDE RT 24. 50 EST. CONC. (uci/L) 4 Q Jlsl VAUDAJE Reviev/ed By Date mzsj^^ FORM I LCSV-TIC 302734 10/9: ILCB LOW CONC. WATER SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. I ^b Name: ETC/GULF SOUTH '_ab Code: GULF Case No.: HLA_ Lab Sample ID: VQBOOl Contract: SAS No.: SDG No.: 95010 Lab File ID: 5VVQB01 Sample volume: 1000 (ml) Concentrated Extract Volume: 1000 Injection Volume: (ul) CAS NO. 1.0 (ul) COMPOUND Date Received: 01/23/95 Date Extracted: 01/24/95 Date Analyzed: 02/08/95 Dilution Factor: 1. O pH: 6.8 CONCENTRATION ( u g / L ) Q 1 0 8 - 9 5 - 2 1 1 1 - 4 4 - 4 9 5 - 5 7 - 8 9 5 - 4 3 - 7 1 0 8 - 6 0 - 1 1 0 6 - 4 4 - 5 6 2 1 - 6 4 - 7 6 7 - 7 2 - 1 8 8 - 7 5 - 5 —— 1 0 5 - 6 7 - 9 1 1 1 - 9 1 - 1 12 0 - 8 3 - 2 1 0 6 - 4 7 - 8 i.t / "~ c> '.J"" Xj " " — — - c: f"i u: ('••,„.";•'.„_„ „ „ _ _ ^ . . „ . . _ _ _ , —7—;__^l ~7,._^> _ . „ „ - _ _ „ . 9 5 - 9 5 - 4 r\ •< ir. o , _ ~.' , ^ 1 3 1 - 1 1 - 3 2 0 8 - 9 6 - 8 6 0 6 - 2 0 - 2 9 - 0 9 - 2 F" h e n o l • b i s ( 2 - C h l o r o e ' t ' h y l ) E : t h e r ' • 2 - C h l o r o p h e n o l • 2 ~ M e t h y l p h e n o l •2 , 2 ' - o X y t' 11;. ("1 - C ii 1 o I'O p r o pari e ) . ^ - I l e t h y l p i - i e n o l • N - N i -t r o s o ~ D i - n -F" r o p y l a m i n e •He X a c In 1 o r o e t i"ian e •Ni t r o b e n z e n e • I s o p h o r o n e • 2 ' - N i t r o p h e n o l • 2 , 4 - D i mo? t h ' / l |J h e n o 1 • b i r:;. ( 2 - C hi 1 o r o e t hio x •/) M e L hi a ri e • 2 , 4 - D i c hi 1 o r o p h e n o 1 - 1 , 2 , 4 - T 1"i chiot' obenzerie IMa p i-i t ba\ 1 e n e 4 - C h i l o r o a n i l i n e I-leXachi 1 o r o b u t a d i e r i e _ _ 4 - C hi 1 o i- 0 - 3 - M e 11 r / l p h e n o 1 2 - M e t h y l n a p h t h a l e n e _ •Fie X a c hi 1 o i- o c y c 1 o pvj:u t a d i e n e 2 J 4 , 6 - T r i c h 1 o r o p h e n o 1 2 , 4 , 5 - T r i c h l o r o p h e n o l 2—C l"i l o r o ri a p i-i L hi ^i 1 e n e 2—N .1. L r o a n i i i n G D i fiie t h y l F' h t h a 1 a t e • A c e r i a p b t h i y ] . e n e 2 , 6 - D i n i 11"o to 1 uei-ie 3—Ni -Lroari i 1 irie _ •Ace i"i a pi t-i t b •:? n o 5 ; 5 ; 5 ; 5 5 5 ! 5 5 ; 5 5 ; 5 5 tr. ..1 5 c: c: 0 n: 5 c 5 C 0 1= 0 5 c: 5 0 5 U U Ll U L! U L.l U U U L.1 U Ll U L.l U U 11 U u 1..1 u u u .u u ;u .u ;u ;u Reviewed Date . — r ^ FORM I L C 3 V - 1 302735 1 0 / 9 2 ILCC LOW CONC. WATER SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. S00119 L--b Name: ETC/GULF SOUTH ..AC) Code: GULF Case No.: HLA Lata Sample ID: VQBOOl Lab File ID: SVVQBOl Sample volume: 1000 (ml) Concentrated Extract Volume: 1000 Injection Volume: Contract: SAS No.: SDG No.: 95010 (ul) CAS NO. J.O (ul) COMPOUND Date Received: 01/23/95 Date Extracted: 01/24/95 Date Analyzed: 02/03/95 Dilution Factor: 1.0 6.8 pH: CONCENTRATION (ug/L) Q 51-28-5 100-02-7— 132-64-9— 121-14-2— 84-66-2 7005-72-3- 86-73-7 100-01-6— r: ~y r, TA r-. .| .....J.' I — %.'/::.- .L — 86—30—6 101-55-3 118-74-1— 87-86-5- 35-01-8 120-12-7— 84-74-2 206-44-0— 129-00-0— 85-68-7 91-94-1 — 56-55-3- 218-01-9 117-81-7— 117-84-0— 205-99-2 207-03-9— ».iU — o.;.-(:) 193-39-5— 5 3 - 7 0 - 3 — 191-24-2— 2,4-Dinitrophenol 4-Nitrophenol Di ben z ofu ran 2,4—Din i trotoluene Diethylphthalate 4-C h1o rop hen y1~ p hen y1e t her F1 UO r en e 4-Ni troan iline 4 ,6-Dini tro-2-riethyl phieno 1 N-Ni trosodipheny 1 atnine (1). 4-B romo p hen yl - p hen y 1 e t her... He X a c h1oroben z en e F''en Lac 111 oro phenol i"'henan'tl"irene A n t h r a c e n e D i -n -E<u t y 1 p h t ha 1 a t e F l u o r a n t h e n e —F'yrene Butyl h'on zyl phthialate 3 ,3 ' -Di c I'll o r o benz id ine Ben z o ( a ) An t h r a c€vn e C h r y s e n e b i s (2-E t h y i hie x y 1) P hi t ha ]. a t e D i-n-O c ty1 P h t ha1a t e Ben ••/. o ( b) F1 uo r an t hiene B e n z o ( k ) F l u o r a n t h e n e Ben z o ( a) F-'yre-?ne l n d e n o ( 1 , 2 , 3 - c d )F'yrene I'i ben 7. ( a , h) An t h i r a c e n e Ben zo ( g , h , i ) F ' e r y l e n e 5" .^0 : 10 \ 5 5 ; 5 ! 5 5 ! :o ; ::o 5 I 5 ; 5 20 5 r tr: 5 5 5 5 A ^ 5 It: 5 5 c: s u ; u : U ! u ; L.1 : u I...I : u L.l ; I...I I L.1 ! 1 1 I L.1 ; Ll ; 1 \ ' u ; u ; l.l 1 IJ ; '-.1 1 u y j ^ i X ; LIT ; . Ll : . Ll ; LJ : 1 '--' I I I 1 1 U 1 :u I V Reviewed By Date FORM I LCSV-2 302736 10/92 * •- ILCF LOW CONC. WATER SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS EPA SAMPLE NO, Lab Name: ETC/GULF SOUTH .«D Code: GULF Case No.: HLA Lab Sample ID: VQBOOl Lab File ID: SVVQBOl Sample volume: 1000 (ml) Concentrated EHxtract Volume: 1000 Injection Volume: 1_._0 ( u 1) Contract: SAS No.1 (ul) SDG No.: 95010 Date Received: 01/23/95 Date Extracted: 01/24/95 Date Analyzed: 02/08/95 Dilution Factor: 1.0 pH: 6.8 Number TICs foundi O CAS NUMBER COMF'OUND NAME RT EST. CONC, ( u g / L ) Q Reviewed By Date VAIIDATI FORM I LCSV-TIC 1 0 / 9 2 302737 ILCB •LOW CONC. WATER SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE HO. Name: ETC/GULF SOUTH Xab Code: GULF Case No.: tlljl. Lab Sample ID: VQAOOl Lab File ID: SVVQAOl Sample volume: 1000 (ml) Concentrated Eixtract Volume: 1.000_ InjectiOil Vo 1 ume: 1.0 (i.i 1) Contract! SAS No.: SDG No.: 95010 (ul) Date Received: 01/23/95 Date Extracted: 01/24/95 Date Analyzed: 02/08/95 Dilution Factor: 1.0 pi-1: 7.1 CONCENTRATION CAS NO. COMPOUND ( u g / L ) Q 1 0 3 - 9 5 - 2 - 1 1 1 - 4 4 - 4 - 9 5 - 5 7 - 8 — 9 5 - 4 8 - 7 — 1 0 8 - 6 0 - 1 - 1 0 6 - 4 4 - 5 - 6 2 1 - 6 4 - 7 - 6 7 - 7 2 - 1 — 9 8 - 9 5 - 3 — 7 8 - 5 9 - 1 8 3 - 7 5 - 5 — 1 0 5 - 6 7 - 9 - 1 1 1 - 9 1 - 1 - 1 2 0 - 8 3 - 2 " 1 2 0 - 8 2 - 1 - 9 1 - 2 0 - 3 — 1 0 6 - 4 7 - 8 - . 3 7 - A « - 3 — 5<V'- 91- —;—> / / " 88- 95- 91- 88" 131 20f. 6 0 6 99- 83- 50 47 06 95 58 74 -1 f t y i!. 09 32 ... ~'.... .„/., ...4... /:. -..')- ...—• - / i . . . J.—...> 6 - 3 0 - 2 ' 'A'.. - 9 - F ' h e n o l tais(2-Chioroe-ti-iyl)Ether_l_l_.. 2 ~ C h l o r o p h e n o l 2 - M e t h y l phenol..___" I . . . " . 1 I _ . _ . 2 , Z^.' - o X y b i s ( 1 -Ci il o r o J::IrOparie ). 4 - M e t l - r / l p i - i e n o l N - H i •[. r o s o - D 1 - n—F' r o p y ]. am 'J. n e 1 - l e x a c h l o r o e ti'iane i'^l:i. t r o b e n z e n e ._ 1 s o p i^i o r a n e _ 2 - N :i. t r o p I' 1 e r 1 o 1 2 , 4 - D i m e t l - t y l p h e n o l _.. _ - b i '7> ( 2 - C h i o I'oe t ho y y ) Me t hari e 2 , 4 •••• D i c b 1 o r o p h e n o 1 ; 1 , 2 , 4 - T r i c l i l o r o t j e n z e n e . ._ - 1-iaphLhalerie _ 4 ~ C h l o r o a n i line-? I-l e X a c i"i 1 o r o 1:> v. t a cl i e r 1 e _ - — 4 - C h l o r o - 3 - r ' i e t h i y l p h e n o l — 2 - M e t h y l n a p h t h a l e n e ZZI...I HeXachi 1 o r o c / c l o p e n Lad i e n e _ 2 , 4 , 6 - 1 r i c i'l 1 o r o 1:) i-i o ri o 1 2 , 4 , 5 - T r i c: I'i 1 o r o p h e n o 1 2 - C il 1 o r o n a p b t lia 1 eri e — -2-l'-i:L t r o a n ;i. 1 i n e _ DinietIny 1 F'iitha 1 a t e A c e n a p h t h y l e n e 2 , 6 - D i n i t r o t o 1 u e n e 3-i>li t r o a n i 1 i n e A c e n .a p in 'L lie in e 5 ! 5 ; 5 ; 5 ; C'.| 1 5 ; c: 1 5 ; 5 5 ' '"1 i:: 1 1= 5 r: 20 I- 5 C"i 5 5 20 5 20 C # r: 5 20 t=^ U U u u u u u LJ LJ U U U Ll 1 t U u u u L.1 U . U U' : u ;i.j ;u !U ;u ;u :u ;LI Reviewed Date — FORM I L C 3 V - 1 302738 1 0 / 9 2 • • • ILCC LOW CONC. WATER SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO, S00120 I ab Name: ETC/GULF SOUTH .ctb Code: GULF Case No.: HLA Lab Sample ID: VQAOOl Lab File ID: SVVQAOl Sample volume: 1000 (ml) Concentrated Extract Volume: 1000 Injection Volume: Contract: SAS No-: SDG No.: 95010 (ul) CAS NO. 1.0 (ul) COMPOUND Date Received: 01/23/95 Date Extracted: 01/24/95 Date Analyzed: 02/08/95 Dilution Factor: 1.O pH: 7.1 CONCENTRATION ( u g / L ) Q 5 1 - 2 8 - 5 1 0 0 - 0 2 - 7 — 1 3 2 - 6 4 - 9 — 1 2 1 - 1 4 - 2 — 8 4 - 6 6 - 2 7 0 0 5 - 7 2 - 3 - 8 6 - 7 3 - 7 - 1 0 0 - 0 1 - 6 — 5 3 4 - 5 2 - 1 — 86—30-6 1 0 1 - 5 5 - 3 1 1 8 - 7 4 - 1 — £>7-86-5 8 5 - 0 1 - 8 1 2 0 - 1 2 - 7 — 3 4 - 7 4.-2 2 0 6 - 4 4 - 0 — 1 2 9 - 0 0 - 0 — t", VA / ,—, —.' 2 1 3 - 0 1 - 9 1 1 7 - 8 1 - 7 1 1 7 - 8 4 - 0 — 2 0 5 - 9 9 - 2 — 207-03-9 5 0 - 3 2 - 8 1 9 3 - 3 9 - 5 — 5 3 - 7 0 - 3 — 1 9 1 - 2 4 - 2 — -2,4~D i n i t r o p hen o1 -4-N i t r o p hen o1 -Di b e n z o f u r a n - 2 , 4 - D i n i t r o t o l u e n e -D i e> t h y l p h t ha 1 a t e -4~C h1o r o p hen y 1 - p h e n y1e t he r - F l u o r e n e - 4 - N i t r o a n i l i n e -4 , 6 - D i n i t r o - 2 - M e t hiy 1 pheno 1 -N-Hi t ro^;=od i p h e n y l a m i n e (1) -4-B romo p hen y 1 - p hen y 1 e^ t he r -1-le X a c In 1 o r o ben z en e -F'en t a c hi 1 o r o p hiG?ri o 1 -Phenanthrene . -Anthracene -Di-n-ButyIphthalate -F1UO r a n t h e n e -l^'yrene _ -Bu t y 1 ben 7. y 1 p h t lia 1 a t e ~ 3 , 3 ' - D L c in 1 o r o ta e n -ir. i d i n e -Ben z o (a ) An t h i-a c e n e -C In r y s e n e - b i s ( 2 - E : t h y l hie x y 1) F' h t hia 1 a t e -Di~n-Octyl Phthalate - Iv;6?n z o (L)) F1 UO r a n t fien e -E^en z o (I-..) F1 uo r a n t hen e -Ben zo ( a ) F'yrene. ~lndeno( 1,2.,3-cd )Pyrene -D i tien 'z ( a , hi) An t h vix. C€^n & -Ben zo (g ., h, i ) P e r y l e n e 2 0 2 0 5 5 ! Ctj 1 5 I 5 20 ; 20 ; S ' ^ • . tr 1 2 0 5 5 *-. 5 5 5 c:, 5 5 j p ^ 5 5 5 5 5 5 5 L.1 U U U LJ U LJ U U U U U U U U u u u u I.J LJ u j ^ U u r :u L.1 ;u • U ;u ;u Reviewed By Date _ — FORM I LCSV-2 302739 XQ/'. - - " ILCF LOW CONC. WATER SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS EPA SAMPLE NO. Lab Name: ETC/GULF SOUTH '«D Code: GULF Case No.: HLA Lab Sample ID: VQAOOl Lab File ID: SVVQAOl Sample volume: 1000 (ml) Con cen t rAted Extract Volume: 1000 I n j e c t i o n V o 1 u m e: ]._, 0 (u 1) Contract: SAS No.: (ul) SDG No.: 95010 Date Received: 01/23/95 Date Extracted: 01/24/95 Date Analyzed: 02/08/95 Dilution Factor: 1.0 pH: 7.1 Number TICs found: 0 CAS NUMBER COMPOUND NAME RT EST. CONC. ( u q / L ) Q VAL! DATED Revie-.ved By Date _ ^ ^ ^ FORM I LCSV-TIC 1 0 / 9 2 3 0 2 7 4 0 -^ ILCB LOW fc.^NC. WATER SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. b Name: ETC/GULF SOUTH Lab Code: GULF Case No.: HLA Lab Sample ID: VSIOOl Lab File ID: SVVSIOl Sample volume: 1000 (ml) Concentrated Extract Volume?: 1000 Injection Volume: 1.0 (ul) Contract: SAS No.: SDG No.: 95010 Date Received: 01/27/91 (ul) Date Extracted: 01/30/95 Date Analyzed: 02/03/95 Dilution Factor: 3,._0 pH: _<^L-_4 CONCENTRATION CAS NO. COMPOUND (ug/L) Q 108-95-2- 111-44-4- 95-57-8— 95-48-7— 108-60-1- 106-44-5- 621-64-7- 67-72-1— 98-95-3 /•::>~o / — 1 ~ - 88-75-5— 105-67-9- 111-91-1- 120-83-2- 120-82-1- 91-20-3 106-47-8- 87-68-3— 91 ./..._- 47-4-.- o o <..'<•.?-.«:.— 95-95-4— 91-58-7— 131-11-3- 208-96-3- 606-20-2- 99-09-2— 83-32-9— -F'henol.. -bis(2-Chloroethyl)Ether -2-C h 1 o r o p hen o 1 -2~Meth-;.'l phenol . - 2 , 2 ' — o x y b i s (1—Ciiloi-ofirof)arie)... -4-l1etlnylplneinol - N - N i "L r o s o - D 1 - n - F ' r o p y .1 am i n e -He X a c in 1 o i-oe t Inan e - N i L r o b e n z e n e . _ - 1 s o p Ino r o n e - 2 - H i. t r o p h e n o 1 - 2 , 4 - D i m e t In y 1 p h e n o 1...., - b i s ( 2—Chi 1 o r o e t he? x •/) Me "L i i a n e.. - 2 , 4 - D i c h l o r o p l n e n o l - 1 , 2 , 4 - T r i c h i l o r o L i e n z e n e _ -Napin Lha 1 e n e - 4 - C h i l o r o a n i 1 i r i e . _ -F-le X a c h 1 o r o b u t a d l e n e - 4 - C l l 1 o r o - Z > - ^ie Liiy!i. phienc?]. - 2 - M e t h y l n a p h t l n a 1 e n e -Fie? X a c h 1 o r o e y e 1 o f>e?n t a d i c?n GV - 2 , 4 , 6 - T r i c h l o r o p h e n o l - 2 , 4 , 5 - T r i c hi 1 o r o p hi.^no 1 - 2 - C1) 1 o r o n a p b •[. In a 1 e n e ~ 2 - N i t r o a n i 1 i n e - D i m e t h y l Phthalate"Z.__.l.]__"].^2!J]! -A c e n a p 111 h y l e n e _ _ - 2 , 6 - D i n i t r o t o J . u e n e - 3 - h i i t r o a n i 1 i n e _ _ _ _. _ - A c e n a p In t In e n e 5 5 ; 5 5 ; rr 1 * • ' 1 5 ; 5 ; 5 5 5 : 5 ITj s K: 5 0 . 4 2 0 5 r:^ L.1 U L.1 l.J Ll U LJ LJ U Ll U U Ll S.J U J u u LJ 2 0 r,: 2 0 5 Clj 5 2 0 LJ Ll ;u .u ;u ;u :u LJ Reviewed By Date J^ieWMJA FORI^-; I L C S V - 1 3 0 2 7 4 1 1 0 / 9 2 HLA DATA QUALITY ASSURANCE REVIEW SUMMARY Semivolatile Organic Compounds Analysis CLOU; CONJeerJTRATicPNJ^ Case Number : Q ^ O \ 0 Project Number 2 . ^ ' S I Z . W-T^ ^ A^/>r^i^ Chv^^.'ruJ^ g e n t y . ^ ^ Contractor Laboratory: __ PjlLcp- A ^ ^ ^ A A I ^ a t i r J Contractor Laboratory: Pj^^PL ^ r ^ ^ A ^ ^ a i r J / cr H!^;J^ Validator. Validation Date: 3J7-^h^ QC Reviewer ^^'U^cXU^ ^ / ^ X < / Z ^ Review Date: ? / ? «> / ? r Sample Matrix: \j) p f c . . ( 6") Analytical Method: ^ P P ^ Q A j p j . ^ OjryXfic::t^PPkL^ O A O ^ I A A M ^ S O Z J Sample Designations: RB>900 1 '?>00\\Q 9.0 fX \\C\ Sooszo SOD IZ^T Data for the above samples are: Acceptable for use ^ Acceptable for use as qualified Unacceptable for use Is action required by the Pjoject Manager? Yes / N O ) Comments: ^ Q ^ J^^^^^^ Jl^Hilu^CxI^a;^ J L A ^ I M ^ 3 C ^ " U 6 ^ P f \ G b r P i A P ^ biu,l.doc I014199< 1014 Fonn BNA IjO 302742 DATA COMPLETENESS CHECKLIST Included, no problems Included, probletns Not included NA Not applicable Quality Control Summary yP Case Narrative yf Surrogate Recovery Summary (slA MS/MSD Summary TJ^ Reagent Blank Summary yC GC/MS Instriunent Performance Summary .^^t- L^b^ctf&ry Ctvdrro[ ^amfU Summary Sample Data • ^ Chain of Custody Forms y Holding Times y Organic Analysis Data Sheets y Quantitation Reports y Reconstructed Ion Chromatograms y Mass Spectra Printouts y TIC Mass Spectra Library Searches Initial Calibration Data -?|^ Calibration Summary X Standards Quantitation Reports X Standards Reconstructed Ion Chromatograms Continuing Calibration Data l^l/V Calibration Summary Kl(\ Standards Quantitation Reports K\A Standards Reconstructed Ion Chromatograms >^ Intemal Standards Summary Instrument Performance Data / DFTPP Mass Spectra X Reconstructed Ion Chromatogram >^ DFTPP Mass Listings bDj.l.doc 'OMIWIOM 2 Fom. BNA 1.0 302743 Reagent Blank Data )C Organic Analysis Data Sheets y Quantitation Reports y Reconstructed Ion Chromatograms y Mass Spectra Printouts X TIC Mass Spectra Library Searches Matrix Spike Data and Matrix Spike Duplicate Data NlA Organic Analysis Data Sheets fj/^ Quantitation Reports N]/\ Reconstructed Ion Chromatograms Laboratory Control Sample y Organic Analysis Data Sheets y Quantitation Reports y Reconstructed Ion Chromatograms y Mass Spectra Printouts X TIC Mass Spectra Library Searches Comments: biu.l.doc 10141994 lOW 3 Form BNA 1.0 302744 Harding Lawson Associates .- . ^ J Engineering and " J = l j Environmental Services SHEET JOB NO. OF PROJECT X ^ A ^ J o ^ d C X A ^ V ^ K J L ^ ^ Cjyt^^i^aA^^ SUBJECT DATE 3 l ^ 1 - \ ^ ^ COMPUTED BY (\.lMXJjS^ CHECKED BY y^P(/yv^Jl(JlJl "S^V ySuA'v^'^»v^«^-AAd. CJAXA^J^ Z^So/oizo^f 5BP3/0''Zl0tZO'iB' ^ 5^ln-Hoi2Xi'=iF sevzlo.o-zolDimf SBB\U.^-Z0/f0H^^f SSBl/o.o-O.floW^ 53Pl/0'l/oi^f-9^ Sbcz/0'lloi3 0^f Sdcz^llo-Zzloi^oojf SbCzlzi\-2L\0{3C^5' RBSol 0130^)6' P3oooZ- SOOIM PZoozo Bi05Z0 P\000( DllZl^ P12JZ2Li- CZDCVi CZZOZZ. C224-Z6 Re>s 001 \]QtA-oo^ \IQC-007> \J6X-oo\ \I^X-ooz y s T - 0 0 3 sjry-DD 1 VTX-oo-Z. I ^ 302745 SPECMC COMMENTS REGARDING ANALYSES Chain Of Custody Were samples properiy pregetved and received in good condiuon? (Yes) No Were custody transfers copecdy and completely documented? CYQS) No Comments: nZjU^>-rr CJ^-t^Q^\^ jA>-f^^ j j ^ i ^ t i . ^ O ^ u H / r v y \ J < j i u x ^ O^Ptn^ j X - ^ Z^'(J(L QJ^^L^ yUWje^ Oj^c^jn^gj-^^L^ P ' M u . CLoC? • ;&yy^c^ jJLs^ Holding Times Were sample extractions ppifDrmed within holding times? /YCT) No Were sample analyses perfopned within holding times? /Yey No Comments: yw- Instrument Tuning Did the instrument performant^e checks meet acceptance criteria? (Ves) No Were samples analyzed within the 12-hour period following an acceptable performance check? f'es) .No Comments: evvje_ bQa_l.(k>c 10141994 1034 4 Form BNA 1 J 3 0 2 7 4 6 Initial Calibration Did the laboratory meet the method requirements regarding the minimum number of calibration standards for an acceptable initial calibratiop3-^ /Yes) No Did the initial calibration curves meet the linearity criteria for maximum percent relative standard deviation (%RSD)? ^ - . Yes n^o) Did the initial calibration meet the minimum relative response factor (RRF) criteria? MTes) No Comments: D x ' > t - - m ! f c a j 2 p t e L . M : ^ . ^ ^ V f r w ^ O ^ feP ^ 3 3 . 6 * ^ . O U A ^ I M J ^ M y ^Jly^ CJ^Pt^^o^^y^ jd^^exMJU C^e^x^iUi^ - M ^ W ^ Continuing Calibration Did the continuing calibration curves meet the linearity criteria for maximum percent difference (%D)? Yes No Did the continuing calibration meet the minimum RRF criteria? Yes No Comments: U&y&KAXKU^'^ CAjUrUatt^BrvuV XO^-'uC V l A ^ <XvU»2*>u:7fl^, 10141994 lOM 5 Fotm BNA 1.0 302747 Surrogate Recoveries Were the surrogate spike repeveries within acceptance limits? fes) No If the spike recoveries were/Uflacceptable. were the samples reanalyzed? /Yes) No NA Comments: YW^ Matrix Spikes Were matrix spike analyses performed at the correct frequency and on a sample matrix representative of the samples in the sample delivery group (SDG)? Yes No Were the matrix spike recoveries and relative percent differences (RPDs) within acceptance criteria? Yes No Comments: Y Y I G ^ K J ^ J ^ ^ A t ^ A ^ C J U A M ^ j^^AUrC VUPt Jlj&yu^ o J t j c l j L j U ^ ^ r Internal Standards Were the intemal standard;tfeas and retention times within the required limits? (Yes) No If the internal standard requirements were iram^et. were the samples reanalyzed? Yes No (NA Comments: vw^ bru_l.doc 10141994 1034 6 Fonn BNA 1.0 302748 Blank Analyses Were the appropniate numbpf-of blank analyses performed? /Yes) No Were analytes detected iiyb6>blaiJcs? (Y&SJ NO If analytes were detected in the blanks, were the same analytes also detected in the associrucd investigative samples? fYes) No NA Did the sample results regiHie qualification due to the presence of analytes in the associated blank samples? Yes) No Comments: j ^ ^ A K y u J i (;$j)^<Xi^ryUt Jj&^^KJi \ v U ) J l j L joAf^ J ^ b t ^ JcShyJiSi. \ \ ^ j d i L e i L Laboratory Control Samples Were laboratory control jle (LCS) analyses performed at the correct fi-equency? fes) No NA Were the LCS recoveries wixhin acceptable limits?.^ ^es ) No NA Comments: '(lJUU^Z\Ji Ozz^ dxjdc^^j^Jl^J^ JLx£zQjz\AA^ ' JQnjtr^AJiA(\t<>^^ CTL J j y j ^ l f \ h i P ^ ^ ^ bDl_l.doc 10141994 1034 Form BNA 1.0 302749 Sample Results Were target analytes reportecHn the investigative samples? (Yes) No Were mass spectra providpd-for the target analytes reponed in the investigative samples? /Yes) No Were the mass spectra of ace«)table quality and analytes correctly identified? (Ves) No Were the quantitated results for target analytes calculated using the appropriate intemal standards and were the relative retention times (RRJs) acceptable? (Yes) No Comments: yWt. Tentatively Identified Compounds Were tentatively identified cempound (TIC) searches conducted for all sample analyses? /Yes) No NA Were aU non-target peaks evaluated as required? (Ves) No Were the TIC mass specira«-searches, identifications, and quantitated results acceptable? A'es) No Comments: y w ^ bna^Ldoc 10141994 10J4 g Fonn BNA 1.0 302750 Log Books Were sample preparations DFOoerly documented and performed in accordance with method protocols? (Yes) No Were sample analyses properiy documented and performed in accordance with method protocols? (Yes) No Comments: yWju biu_LdDc 10141994 1034 9 Foim BNA IJ) 30275.1 Calculation Checks Instmment Tuning 2 / g / ^ ^ ) W 4 5 " Relative Abundance: Ofi^ Ta^Ajdt Pj-oX (UM^JliK.rxcje. KH? 275* _ 6 6 f l _ ^ , ^ Rjti^v^^^U^Ou^><^^ ' m^ i^s '~zz(yr^^oo^ 2^.3 Initial Calibration j z / s / ^ f j Continuing Calibration RRF: %D: (rict OyxaJe^j^) Surrogate Recovery S O O f I ^ / ~y—^j^>^loor 1 2 . 1 % ^ 2-^<^£v^<>^v^^ bDj_l.doc 10141994 1034 ' ^ Foim BNA 1 J) 302752 Matrix Spike Recovery (Y(A OlAV^J'^) RPD: (yy^ on^^i^ge/) Sample Results CRQL: 500)25 Detected Result: (|W^.^ OA^g^H^ j ^ . J^. ^UL. J ^ ^ . J ^ . ClA^^)e(^V^^^ ^ (3TTHfMX.vt_^ / ^ l ^ r - L*-^^^^^^'^*^^^^i=*^>T- TIC Result [ S O O H 8 boi.l.doc 10141994 1034 . . Fonn BNA 1.0 302753 HOLDING TIME QUALIHCATION SUMMARY FORM Sample Idcnliflcnlion Unoj^ iJA^^yt-. Date Siimplcd b n ^ A - .AAy4>y\X. Date Prepared l/k-ve^B "^ A Date Analyzed Prep. Holding Time Analysis Holding Time Qualifier Ui o to Comments: b<ii_l.d.«; IDI41994 lOM 12 Fom BNA 1.0 INITIAL CALIBRATION QUALIFICATION SUMMARY FORM ^ -: w o to -J Ul Ul Date/Time h./shfy [-*~T f—'-^ InsUniment r ^^ Analyie RF ^Di-y^^r^JjfMJlA "^TyT^ . RSD 33.5" Samples Affected nCjP .A(tAVVxjnPLu^ Qualifier T / U T I 1 II Commcnis: " ^ 4 U > ^ d 3 ^ CoSjJr^^^Xzir^r-- J-f^t^^ ^ • _ - - - -^ j j t ^ -Av jM^ix ddAiX^ (ixi(LWtu>— a^M4<Lx^cfcx<^ Kii.l.iluc 10141994 low 13 poimBNA 1.0 CONTINUING CALIBRATION QUALIFICATION SUMMARY FORM Dale/Time (dCX \AA Instrument IX' /VWYI Analyte \iiu^^/) \ ( ) o ^ RF %D Samples Affected ^ Qualifier I 1 1 U i o l O ^ U l o\ Commenis 3 •3 ) N i l l.tloc I0I4I994 1034 14 Fom BNA 1.0 BLANK SUMMARY FORM w o to Ul Blank ID 1 S^LV^U)! L^BLklA}2- L<;gLV(lAl^ Analyte }^A/^•feulXiW©V'^^>^2'^/<-«r^ \S/viA.f2-P:H)jnhiA±ii , \ ^ycil'^^z^cSiAi ^s^AZ'tvf)j^AAM Blank Result (units) 1 r>^/^) 2 T ' ^ / J- 0.(j>T Action Level (A^I>Z 10 ?0 10 G • Associated Samples S O O I J ^ , SOO/ \a , S/?<5(^0 1 -• 1' j »—«—1 ^ ^ • ^ ' ^ *^ Snniz^ 1 1 RBSOoi Coinincnts: I0NI994 lOM 15 Form BNA 1.0 Summary and Conclusions /?«..^A« .-.i^^H-:^^A)...O.J}. ...e,. ^ M.^ -i~\)^../}^npf^M.. J^^^ (Ifry^judbuxtJjeri^ oLai^ii. kAj^Q. /Q^SA^^^AA^Q()^ lAf^OA^ i.^J^^o w>o4~. iy Qjy^x^j^ kJj±Ls^QC^ /\^A(il A z i / f v ^ e . Zl A A ^ ^ h h j A r y f u i ^ v i ^ f j ^ j o r^^^-f-A 1 ^W1 y^ y i fX^ILAAi^H ^ A j r y i - U L ^XY^-MA^ OAAIXJ^ CkAAJ^ yHJjlAnJL ffnyy^AUJAXoTJj^ . f/n,Ai?£ ^^/y^jggwi^^ Jf\^y\~<^.^Q,^S^nOfitP J.ynA- fl.jJzldi£ PlA^ 5^% (li^^p^Jl Oi^r^ J j ^ l ^ m^i i^. XAhZf^ A W i ^ L C ^ J i ^ A/U M^ni^Zyj^CrlPn0 /ViA^j X ^ X Y U ^ ^ H L O^eryXffPX^.^ylTA^.. u y ^ . niA^ /^u (luaSji^r^ £ 4 ^ :G ^. lAif.^tJi/ Validator's Signature: Validator's Initials: Validation Date: 3 / ^ 3 / ^ ^ ^ QC Reviewers Signature: U ^ P ^ z^-y^XZZ^ QC Reviewers Initials MPf Review Date: ? / 7 o / f . bu.Ldoc IQ141994 t034 16 O A rioA BRA BO 302758 ILCB LOW COHC. WATER SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE IMO, LAb Name: ETC/GULF SOUTH '„<.At) Code: GULF Case No.: Hl-A Lab Sample ID: VTX004 L a b F i l e I D : Sjyjs^lJXO^I S a m p l e v o l u m e : 1S.>00__ (1111) C o n c e n t r a t e d E i i x t r a c t V o l u m e : 1 0 0 0 1 n .i e c t i ori Vo 1 u m e : 1 . O ( u 1 ) CQIIPOUND C o n t r a c t : SAS N o . : SDG No.: 9^010 (ul) CAS 103 111 95-- 9'o-- 108 106 621 67- O ;.";._ 78- 88- 1 0 •=. 1 1 1 120 :l 20 9;! — 106 NO. - 9 5 - -44- 57-& -^8-7 •60- -44- -6-<i- 72.-1 59-1 75-::. -67- -91- -83- -82- 20-v' -.47- 0. •V :i. • ..Vi 7 - .... •- — 9 1 '*> 1 .... e Date Received: 02/01/95 Date Extracted: 02/01/95 Date Analyzed: 02/03/95 Dilution Factor: 1.0 pH: 5.6 CONCENTRATION (uq/L) Q v:, -5/-6-- 77-47-4 88-06-2 9 5-95-4 91-58-7— r:8-74-';'i-' 131-11-3- 208-96-8- 606-20-2- 99-09-2— 83-32-9— F'henol bis(2-Chioroethyi)Ether 2-Chlorophenol 2 - r i e t h y l p h e n o l ~ ' " " ~ ' . ] ^ 1 1 _ ^ "- "2 , 2 . ' - o >: A'tf i => ( 1 -C111 o r o p r o p a n e ). 4 ~ M e t h y l p h e n o l h l - N i t r o s o " D i - n - P r o p y l a m i n e Hex a c h l o r o e t l ' i a n e j.,( .^ •]• f.. Q j . , ^::. PI J, ^:. ,..| ^^ Isophorone 2-hii trophenol _ 2 __ 4-Dimethyl phenol bii;; ( 2 - C l i l o r o e t h o x y ) f i e t h i a n e 2 H 4 - D i c h l o r o p ) l " i e n o l 1 , 2 . , 4 - T1" i r |-, 1 o r o t;i e n 7 e n e N a p h t h a l t 2 n e 4 - C I'l l o r o a n i 1 in€^_ _. — He X a c hi 1 o i " o !:>u t a d i eri (•:;• _ 4-Cb 1 or0-3-t'ie t b y l pbono 1 2 - M e 1.1-1 y 1 n a pint h a J. 0? n e _ H e X a c I-i 1 o r o c y c 1 o fj e n t a d :i. e n e _ 2 , 4 , 6 ) ~ T r i c h l o r o p h e n o l 2 , 4 , 5 - T r i c h l o r o p h € - > n o l - 2 - C |-i 1 (j r o n a p hi t hi a 1 e ri e 2~Ni troani1ine D i met h y l P h t h a l a t e Z Z H m ^ ^ Acenafihtt"iylene?_ _ _ _ _ 2 n 6 - D i n i t r o t o 1 u e ri e 3 - N i t r o a n i 1 i n e A cei"i a p hi t h e n e _ _ 5 5 c: *.' tr. • » - ' 5 5 5 S i:: 5 *^i 5 5 5 5 0.3 20 5 c:^ 5 T;. r:^ 20 XT. 20 * c 5 20 5 ;u :u ' i 1 • i 1 1 ' - ' :u :u : 1.1 ' ! 1 ; 1..1 ;u 1 L.l ; 1..1 :u ;u ' \ ' i '...' ; j ;u :u ; Ll ;i.j ;u ! u ;u ;u ; 1..1 ; L' ; u ; L! ; u : i.l Reviewed By Date "ORI-i 1 LCSV-1 302759 1 0 / 9 2 ILCC LOW CONC. WATER SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. I -b Name: ETC/GULF SOUTH .ab Code: GULF Case No.: HLA, Lab Sample ID: VTX004 Lab File ID: SVy.TX04_ Sample volume: 1000 (ml) Concentrate^d Extract Volume: 1000 In lection Volume: Contract: SAS No.: SDG No.: 95010 (ul) CAS NO. 1.0 (ul) COMPOUND Date Received: 02/01/95 Date Extracted: 02/0'l/95 Date Analyzed: 02/08/95 Dilu t i on Fa c tor: 1.O CONCENTRATION (ug/L) Q 5 1 - 2 8 - 5 1 0 0 - 0 2 - 7 1 3 2 - 6 4 - 9 1 2 1 - 1 4 - 2 8 4 - 6 6 - 2 — 7 0 0 5 - 7 2 - 3 8 6 - 7 3 - 7 1 0 0 - 0 1 - 6 5 3 4 - 5 2 - 1 8 6 - 3 0 - 6 1 0 1 - 5 5 - 3 - - ''>"'7_..0 X. —. ^'- — r'} v.- ,-• _ -f „.,.;-. ^., 1 2 0 - 1 2 - 7 8 4 - 7 4 - 2 " 2 0 6 - 4 4 - 0 1 2 9 - 0 0 - 0 <;> •..' — C.'f'.'.'.""" / ~ 5 6 - 5 5 - 3 ; 2 1 8 - 0 1 - 9 • 1 1 7 - 8 1 - 7 1 1 7 - 8 4 - 0 2 0 5 - 9 9 - 2 - 2 0 7 - 0 8 - 9 - 5 0 - 3 2 - 8 1 9 3 - 3 9 - 5 5 3 - 7 0 - 3 1 9 1 - 2 4 - 2 — - 2 , 4 - D i n i t r o p h e n o l - 4 ~ N i t r o p h e n o l -Di b e n 7 o f u r a n -2., 4 - D i n i t r o t o l u e n e •D i e t h y l p h t hia 1 a te_ - 4 - C IT 1 o r o p h e n y 1 - p h e n y 1 e t h e r __ - F l u o r e r i e - 4 - N i t r o a n i 1 i n e -4 , 6 - D i n i t r o - 2 - r ' l e t h y l phienol_ -N-Ni t r o t ' o d i p h e n y l am n.ne ( 1 ) _ - 4—B r on I o p T i e n y 1 — p fi e n y 1 & l hi e i • -HeX a c b 1 o r o b e n /. e n e •Per. t a c h i o r o p t - i e n o l _ _ _ - F" hi e 11 a n t hi r e n e -An thrac(:-?ne D i. - n -B\x t y 1 p h t h a 1 a t e - F l u o r £ ( . n t h e n e _ •—F" y r e I'l e _ — B u t y l b e n z y l p h t h a l a t e , . . —3 ,,3 ' - D i c h i l o r o b e n z i d i n e —Ben 7 o ( a ) An t hii"a c e n e — C h r y s e n e ;._ - b i s ( 2 - t : t h y l h e x y l ) P h t h a l a t e . . . — D i - n - O c t y l P h t h a l a t e _ Z. —Ben 7. o ( b ) F'l u o r a n thiene_ - - B e n 7 o C I--.) F 1 u o r ari 1;. hi e n e —Isen 7 0 ( a ) F ' y r e n e _ _ • - I n d e n o ( 1 , 2 , 3 - c d ) F ' y r e n e — D i b e n z ( a . , h ) An t h r a c e n e —Ben 7 0 (q , h ^ i ) F ' e r y l e n e 2 0 ; 2 0 ; 5 ; i:: 1 2 1 ; 5 : c: 1 2 0 ; ' - . , ' • • 1 i . . K> , 5 r: 1 • - ' t ir 1 2 0 t= 1 c: 5 5 r: XA U IJ U u U L.l U 11 u L.l U L.l U L.l LJ U L.l L.l L.l u T u Reviewed By Date _ FORM I L C 3 V - 2 302760 1 0 / 9 - ILCF LOW CONC. WATER SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS EPA SAMPLE NO, Lab Name: ETC/GULF SOUTH .cib Code: GULF Case No.: HL,A_ Lab Sample ID: VTX004 Lab File ID: SVVTX04 Sample volume: 1000 (ml) Concentrated Extract Volume-: 1000 In .1 ec t i on Vo 1 unie: __ 1 ._0 (u 1) Contract: SAS No.! (ul) SDG No.: 95010 Date Received: 02/01/95 Date Extracted: 02/01/95 Date Analyzed: 02/QG/95 Dilution Factor: 1.0 pH: 5.6 Mumber TICs found: CAS NUMBER COflF'OL.II>!D NAME RT EST. CONC. ( u g / L ) Q VALIDATED Reviewed By Date ^g/-?^ FORM I LCSV-TIC 302761 1 0 / 9 2 ILCB LOW CONC. WATER SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. I ^b Name: ETC/GULF SOUTH r.Ab Code: GULJj; Case No.: H-UlrL Lab Sample ID: VOCOOl Lab File ID: SVVQCOl Sam pie volume: .1.00.0.__ (ml) Concent i- a ted EL X t ract Vo 1 ume : 1.00>i. ]; n i e c t i o n V c. ]. u m e : Contract: SAS No.: SDG No.: 95010 (ul) CAG NO. 1.0 (ul) COMPOUND Date Received: 01/23/95 Date Extracted: 01/24/95 Date Analyzed: 02/08/95 Dilution Factor: 1.0 Pl"l • <^-9 CONCENTRATION ( u g / L ) Q 1 0 8 - 9 5 - 2 1 1 1 - 4 4 - 4 9 5 - 4 8 - 7 — 1 0 8 - 6 0 - 1 • 1 0 6 - 4 4 - 5 — 6 2 1 - 6 4 - 7 - — 6 7 - 7 2 - 1 - f'.r', r\ r.' "•' _ •/•::• • z ^ . i - ' o "• */' •"> .... •" Ci •* . /-./—. —J i:: r: i,'.''<"'"" z •..'* v,' 1 0 5 - 6 7 - 9 - - 1 1 1 - 9 1 - 1 1 2 0 - 8 3 - 2 — ~ 1 2 0 - 8 2 - 1 - 9 1 - 2 0 - 3 — - 1 0 6 - 4 7 - 8 — 5 9 - 5 0 - 7 — 9 1 - 5 7 - 6 - - — 7 7 - 4 7 - 4 f;jf;5-06-2~ - r;, w: _ ,r-. r: __.. .•\ „...,.._ 9 1 - 5 8 - 7 8 8 - 7 4 - 4 1 3 1 - 1 1 - 3 - — 2 0 8 - 9 6 - 8 6 0 6 - 2 0 - 2 r^ o __ Cx Q.... '"> »_ — _ O "*•' "^ '~> Q _ «_ „ - F ' h e n o l - b i s ( 2 ~ C h i o r o e t h y l ) E t h e r - 2 - C hi 1 o r o p h e n o l -2-Me t h y l pheno 1 __ _ - 2 , 2 ' - o X y t.l i S:- ( 1 - CJ hi 1 o r o p r o p a n e ) _.. -4-M(? t h y l p h e n o l - N—i-l i t r o 'y> o—D i. — ri—F-" r^ o p y 1 a m i ri e -He X a c h 1 o r o e t li-an e [ -N :i t r o b e n z e n e - I s o p h o r o n e , _ - 2 ••• N :i. 11 - o p hi e n o 1 __ "2,4-Dimethyl phenol ; - bis(2-Chloroetboxy)Methane -2,4-Di chlorophenol -1,2,4-Tri chlorobenzene _ -H.:x p b 11 "la 1 e n e - 4 - C h i l o r o a n i l i r i e - H e X a c hi 1 o r o !:• u t a d i e i "i e _ - 4 - C h 1 o i - o - 3 - M e t hiy 1 phieno 1 -2-Methylnaphthalene -He X a t: hi 1 o r o e y e 1 o p e n t a d i e n e • 2 , 4 , 6 - T r i c hi 1 o r i j | j h e n o 1 - 2 , 4 , 5 - T r i c hi 1 o r o p h e n o 1 -2.-C hi 1 o r o n a p hi 11 "la 1 eri e - 2 - N i ti-oan i i i ne _ -D i me t hiy 1 P hi t hia l a t e -A cen a p h t tiy 1 en e _ - 2 , 6 - D i n i L i - o t o 1 u e n o - 3 - N i t r o a n i 1 i n e - A c e \-\ a p h t h e n e 2 0 2 0 C ._l 2 0 tr ^ 1 c: ._t tz 2 0 U U U IJ u u L.t U L.l U Ll U Ll IJ LJ I) LJ Ll U L.J LJ U LJ LJ LJ U LJ LJ LJ l l Reviewed By Date VAUDAT ^342^3f^f FORM I L C S V - 1 302762 1 0 / 9 2 ILCC LOW CONC. WATER SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET I ab Name: ETC/GUi...F SOUTFI ,_ab Code: GjJlJI Case No.: HLA Lata Sample ID: VQCOOl Lab File ID: SVVQCOl Sample volume: 1000 (ml) Concentrated Extract Volume: 1000 Injection Volume: Contract: SAS No.: EPA SAMPLE NO. sooiia SDG No.: 9 5010 (ul) CAS NO. J:_;:.0 (ul) COMPOUND Date Received: 01/23/95 Date Extracted: 01/24./95 Date Analy7ed: 02/08/95 Dilution Factor: jl^iii> pH = _ii.:.Z CONCENTRATION ( u g / L ) Q 1 0 0 - 0 2 - 7 1 3 2 - 6 4 - 9 1 2 1 - 1 4 - 2 C>.-.- C ' I..'.. ^1. 7 0 0 5 - 7 2 - 3 £56—73— / 1 0 0 - 0 1 - 6 5 3 4 - 5 2 - 1 8 6 - 3 0 - 6 1 0 1 - 5 5 - 3 — 1 1 8 - 7 4 - 1 8 7 - 8 6 - 5 - 8 5 - 0 1 - 8 — 1 2 0 - 1 2 - 7 8 4 - 7 4 - 2 - — 2 0 6 - 4 4 - 0 1 2 9 - 0 0 - 0 O '•• -•• Z. C-'....~"' — —. 218- 117- 117^ 2 0 5 207^ 5 0 - 193- 53-" 1 9 1 - 0 1 - r-t -1 • t> J. - -84- -99" -08- 3 2-E - 3 9 - 7 0 - ; - 2 4 - • 9 - • 7 - - 0 - • i ' . — .9..- ;;- - 5 - ')— 2 , 4 ~ D i n i t rophienol „ 4~N i t r o p hen o 1 D i ben z o f u r a n 2 , 4 - D i n i t r o t o l u e n e D i e t h y l p hi t h a i a te._._ 4 - C h 1 o r o p iien y 1 - p h e n y 1 e t h e r _ F l u o r e n e 4-11 i t r o a n i 1 i n e 4 , 6-D i n :i. t r o - 2 - M e t hiyl fj lieri o 1 _ 1 •••I -1 i i t r o s o (J i. p h e n y 1 a 1 ii i n e ( 1 ) _. 4 - B r o m o p hi e 11 y 1 - fj b e ri y ]. e 111 e 1 - Fie X a c h 1 o r o b e n 7 e n e F'en t a c hil o r o p her 1 o 1 F ' h e i i a n t h r e n e An t h r a cen e_ D i - r^ - B 1.1. t y 1 (Vi hi t h a 1 a t e Fluoranthene F'yrene B u t y l ben z y l p | - i t h a l a t e 3 , 3 ' -1> i c hi 1 o I-"CD b(-3ri z :i. (J i I'l e Ben 7 o ( a ) An t hiracerie - C h r y s e n e b i s ( 2 - E t h i y l hiexyl ) P h t t . a l a Le. D i ~ n - D c t y l P h t h a l a t e . . . . __ Beri 7 0(1)) F1 uo I'an t hien e. Beri 70 ( k ) F l u o r a n t h e n e Ben 7c;i ( a ) F'yre-ne. I n d e n o ( 1 , 2 , 3 ~ c . d )F'yrene D i ben z ( a , hi) An t h i ' a c : e n e . Ben 7 o ( g , hi, i ) F'e r y 1 en e 20 20 20 ; 2 0 i r 5 1:: 2 0 1 . 1:: 0 . 4 n: K: r: LJ LJ U LJ U LJ IJ LJ J LJ LJ 11 ^ .^r s 5 '•-. 5 1= rr. rz u T '. LJ 1 1 ;u 11..1 ', LJ ! LJ 1 LJ u Reviewed By Date — VAllDATE FORM 1 l...CSV~2 10 A< 302763 ILCF LOW CONC. WATER SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS EPA SAMPLE NO. Lab Name: ETC/GULF SOUTH .b Code: GULF Case No.: HLA Lab Sample ID: VOCOOl Lab File ID: SVVQCOl Sample volume: 1000 (ml) C o n c e n t r a t e d E x t r a c t Volume: 100C> I n j e c t i o i l Vo 1 uine: L=..Q. (^^ 1) C o n t r a c t : SAS N o . : (ul) SDG No.: 95010 Date Received: 01/23/95 Date Extracted: 01/24/95 Date Analyzed: 02/0S/95 Dilution Factor: 1,. 0 pH: 6.9 1-lumber TICs found: 1 CAS NUMBER 1. COMPOUND NAME UhlKNOWhl AfllDE EST. CONC. ( u q / L ) 4 arJ VALID AT ED^ Reviev/ed By ]:=::M::£II/^LZZ^ Date 2 3 / ^ ^ FORI'i I LCSV-TIC 302764 i\>A92 ILCB LOW CONC. WATER SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. Lab Name: ETC/GULF SOUTH L_ib Code: GULF Case No.: HL.A. Lab Sample ID: VQBOOl Contract: SAS No.: SDG No.: 95010 Lab File ID: 5VVQB01 Sample volume: 1000 (ml) Concentrated Extract Volume: 3.^000. I n i e c t i ori V o l u m e : (ul) CAS NG. 1.0. (ul) COMPOUND Date Received: 01/23/95 Date Extracted: 01/24/95 Date Analyzed: 02/03/95 Dilution Factor: 1.0 pH: .._6.i8 CONCENTRATION (ug/L) Q 108-95-2- 111-44-4- 95-57-8— 95-48-7— :i. Ub-ou•-.l.- 106-44-5- 621-64-7- 67-72-1— 98-95-3 88-75-5 120-83-2 106-47-8 59-50-7 91-57-6— 77-47.-4.— 88-06-2— 95-95-4 — 91-58-7— 88-74-4— 131-11-3- 606-20-2- 99-09-2— 83-32-9— F-henol b i s(2-Chioroet hyl)E the r 2-Chlorophenol 2-Me t hylp hen o1 _ 2,2' -oXybiv-(].-Cli 1 oropro|::iarie )._ 4 - M e t h y 11 J hi e n o 1 hi-N i t r oi;io~D i - n - P r o p y l am i n e H e x a c h 1 o r o e 11 •i.:Ti.n e N i t robiZTi 7 e n e 1 s o p |-io r o i l e 2 - N :i. t r o p h e r 1 o 1 _ 2 , 4 ~ D i m e t h y l p h e n o l b i S-, ( 2 - C hi 1 o r o e t h o x y ) Me 11 i a n e 2,4-Di chlorophenol 1,2 ., 4-Tri chlorobenzene IMa p h t ha 1 en e 4-Chloroan i1ine 1-lexac.hlorobutadiene . . 4 - C h 1 o r o - Z - n o X b y l p h e n o 1 2 - M e t l i y ]. n a p h t h a l e n e '.[ h! e X a c: hi .1. o \ - o c y c 1 o p e 1-i L a cl i e n e _. 2 , 4 , 6 - T r i c hi 1 o r o p b e ri o ]. _ 2 , 4 , 5 - T r i c h l o r o p h i e n o l 2 — C h l o r o n a p h L h a l e n e _ 2—1^1:1. t r c j a n i 1 i n e D i me t h y l F' h t h a 1 a te.... A ce-;n .Tv p I'l L h i y l e n e 2 , 6 - D i n i t r o t o l u e n e 3—hil t r o a n i ] . i n e A c. e ri a p hi L h e I't e _ _ :o '-•n 2 0 U LJ LJ U U LJ LJ LJ U U U LJ Li LJ U LJ U LJ I..I LJ U U Ll LJ I! Reviewed Date M^ FORM I L C S V - 1 10/^ 302765 ILCC LOW CONC. WATER SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. L^b Name: ETC/GULF SOUTH '.^D Code: GULF Case No.: HLA Lab Sample ID: VQBOOl Lab File ID: SVVQBOl Sample volume: 1000 (ml) Coricentrated Extract Volume: 1000 In .i e c t i on Vo 1 ume: Contract: SAS No.: SDG No.: 95010 (ul CA'3 NU. .L-O (ul) COMPOUND Date Received: 01/23/95 Date Extracted: 01/24/95 Date Analyzed: 02/08/9 5 D i ]. u t i on F a c tor: 1.0 pH: 6.8 CONCENTRATION (ug/L) Q 100-02-7— 132-64-9— 121-14-2— 84-66-2- 7005-72-3- 86-73-7 100-01-6— 86-30—6 101-55-3 - 118-74-1— 87-86-5-- 85-01-8 - 120-12-7— 84-74-2 206-44-0— 129-00-0— r'. r.-. / .—. ~j (::• ^ . ^ - ' c > <;::••••• / 91-94-1 — c: ^ TA TA - y 218-01-9 117-81-7— 117-84-0— 205-99-2 207-08-9 50-32-8 193-39-5— 53-70-3—- 191-24-2— 2,4-Dinitrophenol 4-N i t ro p hen o1 Dit:«en zof uran 2 , 4 - D i n i t r o t o l u e n e D i e t h y l p h t hia 1 a t e 4-C h l o r o p hen y 1 - p hen y 1 e t he i- F1 uo r e n e 4 - N i t r o a n i l i n e 4 , 6 - D i n i t ro-2~Me t hiyl p hen o 1. N-Ni t r o s o d i p h e n y l a m i n e ( 1 ) . 4... p f- (-., ,|.| rj j... |..| £., p., y ] _ p |.., p p.| y 1 ,^. t h e r —i"le X -a c h 1 o r o ben z en e Pen t a c hil o r o p hen o l l-'hen an t h r e n e Anthracene?. _ D i -n -p.u t y 1 p h t ha 1 a t e f ' l u o r a n t h e n e • - F' y r e n e . - - B u t y l b e n z y l p h t t i a l a t e 3 , 3 ' -D i c hi 1 o r o beri z x d i n e Ben z o ( a ) A n t h r a c e n e Chrysene bis(2-EthylhexylVphthalate D i -n -0 c Ly 1 F' h t ha 1 a te — B e ll z o ( b) F1 u o r a n t hi e n e Ben zo ( k) F'luoran thene Ben zo ( a) F'yrene I n d e n o ( 1 , , 2 , 3 - c d ) F'yrene Di ben z ( a , h) An t h i r a c e n e --Ben zo ( g , h , .-i.) F ' e r y l e n e 20 : 20 : 5 r: 1 5 1 5 5 ; 2 0 2 0 n: 1 5 ; 5 I 2 0 5 5 5 r; ir. !;_! 5 5 5 ' " i u: - 5 5 C^ 5 LJ ; u ; LJ u ; LJ ; u ; LJ ; LJ ; LJ ! LJ I LJ ; > 1 1 LJ I.J ; LJ ; 1 ! ' u ; u ; Ll : IJ • t 1 IJ : L I T ; LJ ; . 1.J ; LJ ; ; Ll : ; Ll :u VAilDAJE Reviewed Ey Date FORM I L C S V - : 302766 1 0 / 9 2 ILCF LOW CONC. WATER SEMIVOLATILE OF<GANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS EPA SAMPLE NO. Lab Name: ETC/GULF SOUTH .o Code: GULF Case No.: HLA Lab Sample ID: VQBOOl Lab File ID: SVVQBOl Sample volume: 1000 (ml) Concentrated Ellxtract Volumes 1.000_ I n .i e c t i o n V o 1 u m e s _ 1_._0 ( u 1) Contract: SAS No.: (ul) SDG No.: 95010 Date Received: 01/23/95 Date Extracted: 01/24/95 Date Analyzed: 02/08/95 Diluti on F a c tor: 2^jjj pH" -A.-3. N u n IL j e r T I C s t" o u n d : 0 C A S NLJMBER COMPOUND NAME RT EST. CONC. ( u g / L ) Q VAIIDAT Reviewed By Date FORM 1 LCGV-TIC 1 0 / 9 2 302767 ILCB LOW CONC. WATER SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO, ' b Name: ETC/GULF SOUTH ' a b Code: GULF Case No.: HLA_ Lab Sample ID: VQAOOl Lab File ID: SVVQAOl Sample volume: 1000 (ml) Concentrated Ei!xtract Volumc.>: l.QOC)_ I n .1 e c t i o n V •;:) 1 u m e : 1.0 (i.' 1 ) Contract: SAS No.: SDG No.: 95010 (ul) Date Received: 01/23/95 Date Extracted: 01/24/95 Date Analyzed: 02/03/95 Dilution Factor: 1_.0 Pl-1= 7.1 CONCENTRATION CAS N O . COMPOUND ( u g / L ) Q 1 0 3 - 9 5 - 2 1 1 1 - 4 4 - 4 r> i:: c: -y._, c> ^ _„ 9 5 - 4 8 - 7 1 0 8 - 6 0 - 1 1 0 6 - 4 4 - 5 — 6 2 1 - 6 4 - 7 6 7 - 7 2 - 1 C ' ' " • • ' — • ' - " ' ''•• — "•'•' - "7 0 . . _ '" •"'• •' r--, fj_; __ - y r: „,. n: 1 0 5 - 6 7 - 9 •I •! -J ._.•::>•« ....-t , , 1 2 0 - 8 3 - 2 - 1 2 0 - 8 2 - 1 - 1 0 6 - 4 7 - 8 8 7 - 6 8 - 3 r:(-.....r:.-....-v...._ _.._ 1 — ..:> 7 7 - 4 7 - 4 — 8 8 - 0 6 - 2 - — 9 1 - 5 8 - 7 8 8 - - 7 4 - 4 — 1 3 1 - 1 1 - 3 r-.r\r-, t-. / r-. 6 0 6 - 2.0 •••• 2 9 9 - 0 9 - 2 F" h e n o l b i s ( 2 - C i-ii o r o e t hiy 1") E t h e r l . . . I _ ] J 2 - C h i l o r o p h € ^ n o l 2-Methylphenol _ 2 , 2 ' —oy.ybi^-.(. 1—Chi J. o r o J::-rop) a n e ) 4 - M e t l"iy 1 p i-ien o 1 N—hi i t roso—D S. -n—F' r o p y l am i n e . I-l o X a c h 1 o I" c> e t 'n a n e hhi. t r o b c / n z e n e . _ _ — — 1 'E ci I"' hi o r '-J Tl e _ _ _ 2-Nitrophenol — 2 , 4-Dimeth>'l phenol __ — — b i -z-. (. 2—C h l o r o e t ho v y ) Me t b a n e •- - - 2 , 4 - D i c: l"i 1 o r o p lien o ]. — 1 ., 2 , 4 - T r i c h i l o r o b e n z e n e . - l i a p l i t l ' i a l e n e 4 - C h i l o r c i a n i l i n e ? —I-leVach 1 oroI:• I..I.ta•;:! :i.ene — 4 - C; h 1 o I •• o - 3 - - M e L h y 1 p h e n.::) 1 - 2 - M e t h y l n a p h t h a 1 e n e I Z Z I I — 1-1 e X a c; h !1. o r o c: y c: 1 o p e n L a d :i. e n e "2 , 4 , 6 - T r i c h ]. o r o p hieri o 1 _ 2 ., 4 , 5-Tri chlorophenol — ;Z; - C h 1 o r o n a p h t l'i a 1 e n e — -2—hii-Lroani 1 ine _ D i me t hyl F' |-i thai a t elll^Z^Ii^^Z" A c: e n a p h t ll y 1 e n e 2 , 6 - D i n i t r o t o l u e n e - 3 •-1 ~l i 11- o a n j. 1 i n e (icei'i••:::pn •..liene ^ 1 ' c: 1 5 ; •f' '"i ' 5 ; c: 1 n;^ 1 5 5 ; 5 i;.- 5 in r: 5 2 0 .^r r: ^.1 i:: 5 5 2 0 n: 2 0 5 ' 5 2 0 LJ U U u u u u Li LJ L: LJ Ll LJ 1' LJ U Ll LJ U LJ u u LJ u .u • U ;u :u :u Reviewed " " ^ S ^ S ^ Date - ' ' ' ^ ^ ^ h y FORM I L C 3 V - 1 302768 1 0 / 9 2 ILCC LOW CONC. WATER SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO, S00120 Lab Name: ETC/GULF SOUTH b Code: GULF Case No.: HLA Contract: SAS No.: SDG No.: 95010 Lab Sample ID: VQAOOl Lab File ID: SVVQAOl Sample volume: 1000 (ml) Concentrated [".xtract Volume: 1.00^0. I n i e c t i o n V C' 1 u m e : 1-0 (u 1) COMPOUND (ul) CAS 5 1 - 1 0 0 1 3 2 1 2 1 8 4 - 7 0 0 8 6 - 1 0 0 5 3 4 8 6 - 1 0 1 1 1 8 8 7 - 8 5 - 1 2 0 8 4 - 2 0 6 1 2 9 < " > ' • • 9 I - - 56"" 1 1 7 1 1 7 2 0 5 2 0 7 5 0 - 1 9 3 5 3 - 1 9 1 NG. 2 8 - ^ - 0 2 - - 6 4 - - 1 4 - 6 6 - ; 5-7-; 7 3 - / - 0 1 - r: ^7.... 30-,r'' - 5 5- ...74.. 8 6 - ^ 01-'<T - 1 2 - 74-I' -44.. - 0 0 - ^•3-A ?4-:i f-'- ' ' • ' • . . . . " • - 0 1 - - 8 1 - - 8 4 - ....r,.r./.. - 0 8 - 3 2 - f - 3 9 - 7 0 - : - 2 4 - 1— 7- •9 \ . '-,.. 6 :!• • . " • " I 1- ^— (..- -7 0 -(>• • .... ,- •'? -7 -0 -'•? ..... - 5 >- Date Received: 01/23/95 Date Extracted: 01/24/95 Date Analyzed: 02/03/95 Dilution Factor: .1..O pH: 7.1 CONCENTRATION (ug/L) Q -2,4-D i n i t ro p hen o1 -4-Nitrophenol -Di ben zofuran -2,4-D i n i t ro to1uen e -Diethylphthalate " I__ - 4 - C hi 1 o I'O p h e n y 1 - p h e n y 1 e t h e r - F l u o r e n e - 4 - N i t r o a n i l i n e -4 ., 6 - D :i. n i t r o - 2 - M e t h i y l p h e n o 1 - N - II i L I'- o s o d i p h e n •/ ]. a m n. n e ( 1 ) -4—BI-oiTio p h e n y l — p hien y 1 e^ t lie r - i-I e X a c h 1 o r o b e n 7 e ri e . . . . _ -F'en t a c hi 1 o r o p h e n o 1 -l-'henan t h r e n e -An t l i r a c e n e . _ -D i - n -Bi.i. t y 1 p h t lia 1 a t e - F l u o r a n t h e n e - F ' y r e n e -Bu t y 1 b e n z y 1 p h t h a l a t e - 3 , 3 ' -D:i. chi 1 o r o b e r i z i i i i n G - B e n z '::> ( a ) An t hir a c e n e ... _. - C l i r - / : s e n e -b i s ( 2 - E t h y l h e x y 1 ) P h t h a 1 a t e -D i - n - O c t y ]. P h t h a 1 a t e I . . ^ . - B e n 7 o ( b ) F l u o r a n t h i e n e -Ben z o (I--.) Fluor<:-in t h i e n e _ - B e n 7 o ( a ) F' y 1" e? n e -IndenoC1,2,3-cd)Pyrene -Dibenz(a,h)Anthracene - B e n z o ( g , h , i ) F ' e r y l e n e 2 0 2 0 c: 5 5 5 5 2 0 2 0 s LJ U U U LJ U LJ U U tl 2 0 5 5 5 r: ...1 5 c 5 5 ^ J ^ C 5 r.'.^ C j ^ 1 5 C| LJ LJ LJ U U U LI l.J LJ 11 jt^^a L l T LJ Ll , L) U :u u 1 ..„».. u Reviewed By Date ^ 2 £ FORM I L C S V ~ 2 1 0 / ^ 302769 ILCF LOW CONC. WATER SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS Lab Name: ETC/GULF SOUTH .) Code: GULF Case No.: HLA Lab Sample ID: VQAOOl Lab File ID: SVVQAOl Sample vol ume : iOOjO__ (m 1) Con cen t ra ted Extract Vo 1 ume : 1..000. Injection Volume: _L=..9. (ul) Contract: SAS No.: (ul) EPA SAMPLE NO, SOO 1:20 SDG No.: 95010 Date Received: 01/23/95 Date Extracted: 01/24/95 Date Analyzed: 02/08/95 Dilution Factor: 1.0 pl-1 •- 7.1 lumber TICs found 0 CAS NUMBER RT EST. CONC (uq/L) Q Reviev/ed By Date FORM I LCSV-TIC VAilDAT^D P 302770 10/92 ILCB LOW CONC. WATER SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. I -b Name: ETC/GULF SOUTH r.ab Code: GULF Case No.: HLA Lab Sample ID: VSIOOl Lab File ID: SVVSIOl Sample volume: 1000 (ml) Concentrated Extract Volume: IOOO Injection Volume: 1 • 0 (u 1) COMPOUND Contract: SAS No.: (ul) CAS 108 111 95- 95- 108 106 621 67- /-..—. •? '.;;•- 78- 105 .1. .). J. 120 i ''.'(•••, 91- 106 . " . • - : ' n: f-i \.' 'Z ' " 91- 77- o'o- 95- 91- 88- 131 208 606 99- 83- NO. -95-2- -44-4- 5 7 - 8 — 4 8 - 7 — -60-1- -44..-^v- -64-7- 72-1 — /•% r: -/ .1 —,..» 59-1 — 7 5 - 5 — -67-9- " " ." . 1 . - . 1 . "•• -83-2- ...o ";•..-. 1 .... 20-3 -47-8- 68-3 50-7 57-6 - 47-4 — /• * f «•..'<;>-2 9 5 - 4 — '"':J ....-.' 74-4..-. -11-3- -96-8- -20-2- 0 9 - 2 — 32-9 — ( - — — - • " ^ ' • - - — SDG No.: 95010 Date Received: 01/27/95 Date Extracted: 01/30/95 Date Analyzed: 02/;0.3/25 D .i. 1 u t i on Facto r : 1 ;_0. pl-l = _.iLL<?i CONCENTRATION (ug/L) Q F' hen o 1 bis(2-Chloroethyl)Ether 2-C hi o r o p hen o 1 2 - Methyl p h e n o 1 2 , 2 ' — o X y i:> -J. <;;. (1 — C hi 1 o r o p r o p a n e ) . . 4-Me t hyl p hen o 1 hl-Ni troso-Pi-n-F'ropylamine .„ H e x a c h l o r o e t h a n e . _ _ N i L r o b e n z e n e _. J. s o p hi o r o n e _ 2 - N i t r o p h e n o 1 2 ,, 4 - D i m e L hi •-/1 p hi e n o 1 b ;i. Ai ( 2'.—C hi 1 o r o e L hio x'/ ) i'ie t i 1 a n e 2 , 4 - D i c h 1 o r o p h e n o 1 1 , 2 , 4 - T r i c h l o r o L i e n zene N a p l i L h a l e n e 4 - C : t i l o r o a n i 1 i n e . _ _ _ . H e x a c h l ci r o b \x t a c:l i. e n e •4 —Ch 1 oro-3-Mo:-> Lliy!l. phieno 1 2 - M e L h y 111 a ):> li L hi a 1 e n e _ _ -Ho X a c h ;i. o I'O eye: 1 o fieri t a d i e n e •2 ., 4 , 6 - T r i c hi 1 o r o p h e n o 1 . "f.^ 1 r i c hi 1 «:> r o p hien o 1 2—C I'l 11") i'-c>ri a p b "L hia 1 e n e 2 - h l i - L r o a n i 1 i n e D i ni e t h y 1 F' hi i:. hi a 1 a -L e ._ A c e n a p hi L hr/.1 e n e 2 , 6 - D J. n i L r o t o 1 u e n e .. 3 - N i t l ' Clan i 1 .i.ne_.. - A c e n a p h t h e n e 5 0 . 4 2 0 •'O 2 0 5 '.0 LJ U LJ l.J Ll U LJ LJ LJ LI LJ LJ LJ l.J U- J Ll LJ LJ Ll LJ I.J LJ LJ LJ U LJ LJ U I i Reviewed By Date FORr; I L C S V - 1 302771 10 A'-. ILCC LOW CONC. WATER SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO, SOO125 Lab Name: ETC/GULF SOUTH ..-lb C o d e : GLJLF" C a s e N o . : HLA Contract: SAS No.: SDG No.: 95010 Lab Sample ID: VSIOOl Lab File ID: SVyf>I01 Sample vo 1 ume: 1000 (m].) Concentrated Extract Volume: 1000 Injection Volume: 5:.j;..??. ( u l ) (ul) CAS NO. COMPOUND Date Received: 01/27/95 Date Extracted: 01/30/95 Date Analyzed: 02/08/95 Dilution Factor: 1.0 pH r ._6.:^/i CONCENTR AT I Oi'^l ( u g / L ) Q 1 0 0 - 0 2 - 7 1 3 2 - 6 4 - 9 1 2 1 - 1 4 - 2 t > * " t " - Cf <:> — *:. 7 0 0 5 - 7 2 - 3 8 6 - 7 3 - 7 1 0 0 - 0 1 - 6 I:: - y ri ir. r-. -i ».«%.-> ••; — ..1 / : . — J . 3 6 - 3 0 - 6 1 0 1 - 5 5 - 3 1 1 8 - 7 4 - 1 - E>7~86-5 - 120- 1 2 - 7 - — 8 4 - 7 4 - 2 2 0 6 - 4 4 - 0 1 2 9 - 0 0 - 0 r > ' • • „.. -f c > „ . , ~ ' ' „ . r.t / . _,. t : t : _.,":' .„ 2 1 8 - 0 1 - 9 1 1 7 - 8 1 - 7 1 1 7 - 8 4 - 0 2 0 5 - 9 9 - 2 2 0 7 - 0 3 - 9 5 0—3 2! - - f.) 1 9 3 - 3 9 - 5 5 3 - 7 0 - 3 — 1 9 1 - 2 4 - 2 " 2 , 4 - D :i. n i t r o p h e n o 1 - 4 - N i t r o p h e n o 1 .__ - D i b e n z o f u r a n - 2 , 4 - D i n i t r o t o l u e n e - D i e 11 i y 1 p h t h a 1 a t e - 4 - C hi 1 o !'• o I j h e n y 1 - p hi e n y 1 e t h e r -F" 1 u o r e n B -4-~Ni t r o a n i 1 i n e -4 , 6 - D i n i t r o - 2 - M e t t i y 1 p h e n o 1 • N -1-1 i t r o 'S o d i p h e n y ]. a m i n e ( 1 ) - 4 - B r o m o p hien y 1 - p hien y J. e t hie i" -I-leXach 1 o r o L i e n z e n e - F-' e n t a c: 1-11 o r o r> Li e n ci 1 . _ -F'hen a n t h r e n e - A n t h r a c e n e _ -D i - n - B u t y I p h t h a l a t e _ - F l u o r a n L b e n e " F ' - / r e n e _ - B u t y l ben z y l phthiala-Le. -3 , 3 ' -D:i. chloi' obenz id i n e ... - B e n z o ( a ) An L h n - a c e n e - C l ' i r y s e n e _ - b i s ( 2 - E t h y l h e x y ]. ) P h t hia 1 a t e - D i - n - Q c t y l P h t h a l a t e ]^ -Ben 7o( b ) Fluoran thene - B e n z o ( I .) P ' l u o r a n t i n e n e - B e n z o ( a ) F ' y r e n e - ]; n d c^n o ( 1 , 2 , 3 - cd ) F ' y r e n e - D i b e n z ( a , h ) A n t h r a c e n e . . - B e 11 z o ( g , hi, i ) F" e r y 1 e n e 2 0 ; 2 0 ; 5 ; 5 ! 1 ; 5 : 5 1 2 0 ; 2 0 * ' ' l * 5 i:: I 2 0 *^"t ='. tr.^ f:. C j r: U U LJ U J U LJ l.J LJ L! LJ 1 1. LJ LJ IJ LJ LJ I.J 1.J LJ U VAL! DATE! Reviewed By Date Sfe/2£_ uHt^ FORri I L C S V - 2 1 0 / 9 : 302772 ILCF LOW CONC. WATER SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS EPA SAMPLE NO, I b Name: ETC/GULF SOUTH *ab Code: GLJLF Case No.: HLA Lab Sample ID: VSIOOl Lab File ID: SVVSIOl Samp1e volume: 1000 (ml) Con c:en L rated E x t r a c: t Vo 1 ume: 1000 Injection Vo 1 ume: .1.0 (u 1) Contract: SAS No.: (ul) SDG No.: 95010 Date Received: 01/27/95 Date Extracted: 01/30/95 Date Analyzed: 02/03/9 5 Dilution Factor: 1_^0. pH: 6.6 Number TICs found: 1 CAS NUMBER 1. COMPOUND NAME UNKNOWN RT = =:=: = = = 1 8 . 0 7 EST. CONC. ( u g / L ) r;=:=: = =:=:r z = --.i=:zz = zz 9 Q =:r=r=r=:= ^H VAllDAJE Reviewed By Date FORM I LCSV-TIC 302773 10/9: HLA DATA QUAUTY ASSURANCE REVIEW SUMMARY Semivolatile Organic Compound Analysis Case Number: 95010 Project Number: 29872 10.1 Site: Island Chemical Company Contractor Lab: Pace Incorporated, New Orleans Validator: Kirsten Meier QC Reviewer: 0 ' ^ - ^ ^ > d / " ^ ^ i ' C A ^ Validation Date: 11 April, 1995 Review Date: f - /.? - f j - Sample Matrix: Water Analytical Method: SW 846, Method 8270, Pyridine only Sample Designations: Client ED (Lab Sample ID) S00118 SOO 120 SO0119 SO0125 RBSOOl Data for the above samples are: [ ] Acceptable for use [x] Acceptable for use as qualified [ ] Unacceptable for use Is action required by the Project Manager? Yes No[x] Comments: The investigative samples were validated in accordance with the "USEPA CLP National Functional Guidelines for Organic Data Review", February 1994. bm.clec.l I 12291994 1330 302774 BNA 1.1 CocNunten MOID PicfoclNuiiiier 29872 10.1 Site ID: bkud Q m b a d Coopn^ DATA COMPLETENESS CHECKUST [x] Included, no problems [*] Included, problems [O] Not included [NA] Not applicable Quality Control Summary X Case Narrative _x Surrogate Recovery Summary * MS/MSD Summary Reagent Blank Sununary GC/MS Instrument Performance Summary Sample Data X Chain of Custody Forms X Holding Times * Organic Analysis Data Sheets X (Quantitation Reports * Reconstructed Ion C!hromatograms X Mass Spectra Printouts NA TIC Mass Spectra Library Searches Initial Calibration Data X Calibration Summary X Standards (Quantitation Reports * Standards Reconstructed Ion Chromatograms Continuing Calibration Data * C^ibration Summary X Standards (Quantitation Reports * Standards Reconstructed Ion Chromatograms * Intemal Standards Summary Instnunent Performance Data X DFTPP Mass Spectra X Reconstructed Ion Chromatogram X DFTPP Mass Listings bat.elcc.ll 12291994 1330 2 Fonn BNA l.l 302775 Doe NuiAer 93010 PngedNunbcr: 29S72 10.1 Site ID: bksd Cfaemica] Cewnfmny Reagent Blank Data X Organic Analysis Data Sheets X (Quantitation Reports * Reconstructed Ion Chromatograms X Mass Spectra Printouts NA n c Mass Spectra Library Searches Matrix Spike and Matrix Spike Duplicate Data * Organic Analysis Data Sheets X (Quantitation Reports * Reconstmcted Ion Chromatograms Laboratory Control Sample NA Organic Analysis Data Sheets NA (Quantitation Reports ^NA Reconstmcted Ion Chromatograms NA Mass Spectra Printouts - NA TIC Mass Spectra Library Searches Comments: The Reconstmcted Ion Chromatograms showed peak areas from the scan 350 and higher, while the compound of interest. Pyridine, appears at aproximately scan 210. A visual comparison of data for Pyridine was not possible. bm elec.ll 12N19W 1530 3 Fom, BNA 1.1 302776 C u e Nucdn-. 93010 PniectNunben 29872 10.1 Sile ID: bbnd Cfaemkml Cenpujr SPECmC COMMENTS REGARDING ANALYSES Chain Of Custody Were samples properly preserved and received in good condition? Yes[x] No Were custody transfers correctly and completely documented? Yes[x] No Comments: None Holding Times Were sample extractions performed within holding times? Yes[x] No Were sample analyses performed within holding times? Yes[x] No Comments: None Instrument Tuning Did the instmment performance checks meet acceptance criteria? Yes[x] No Were samples analyzed within the 12-hour period following an acceptable performance check? Yes[x] No Comments: None bm.elec.ll 12291994 1330 Fonn BNA 1.1 302777 Cue Nuater. 93010 PiojectNiMiter 29872 10.1 Sile ID: bbnd Chwnkal Cewnjmny Initial Calibration Did the laboratory meet the method requirements regarding the minimum number of calibration standards for an acceptable initial calibration? Yes[x] No Did the initial calibration curves meet the linearity criteria for maximum percent relative standard deviation (%RSD)? Yes[x] No Did the initial calibration meet the minimum relative response factor (RRF) criteria? Yes[x] No Comments: This review is only based on the evaluation of Pyridine. The initial calibration QC criteria were met for Pyridine. As stated previously, the chromatograms do not show the scans for Pyridine and N-Nitrosodimethylamine, a visual evaluation was not possible. The possibility that the injection peak or other factors might have interfered or affected the quantitation of the target analyte Pyridine, cannot be evaluated. The concentrations of the initial and continuing standards are listed in the header as twice as high as the concentrations used in the quantitation section of the data. The injection volume is not clearly defmed, but appears, that the same amount of 1.0 ul was used for standards and samples. Since no detections of Pyridine were reported, no qualification of data is necessary. Continuing Calibration Did the continuing calibration curves meet the linearity criteria for maximum percent difference (%D)? Yes No[x] Did the continuing calibration meet the minimum RRF criteria? Yes[x] No Comments: This review is only based on the evaluation of Pyridine. The continuing calibration on 1-27-95, 11:35, shows a percent difference for Pyridine of 48.3%, exceeding the limit of 25%. Therefore, the results for Pyridine in the associated samples SCX)120, SO0119 and SO0118 were qualified as estimated (J). As stated previously, the chromatograms do not show the scans for Pyridine and N-Nitrosodimethylamine, a visual evaluation was not possible. The possibility that the injection peak or other factors might have interfered or affected the quantitation of the target analyte Pyridine, cannot be evaluated. bm.ekc.ll 12291994 1330 5 Form BNA 1.1 302778 Caie Niinber: 93010 PiDJeoNmber 29872 10.1 Site ID: bbnd Cfaaniod Coinpany Surrogate Recoveries Were the surrogate spike recoveries within acceptance limits? Yes[x] No If the spike recoveries were unacceptable, were the samples reanalyzed? Yes No NA[x] Comments: None Matrix Spikes Were matrix spike analyses perfonned at the correct frequency and on a sample matrix representative of the samples in the sample delivery group (SDG)? Yes[x] No Were the matrix spike recoveries and relative percent differences (RPDs) within acceptance criteria? Yes[x] No Comments: The matrix spikes were performed with a 8270 mixture, which does not include Pyridine. The lab provided a summary of matrix spike recoveries, some recoveries were not within 8270 QC limits. No qualification of data. Internal Standards Were the internal standard areas and retention times within the required limits? Yes[x] No If the intemal standard requirements were not met, were the samples reanalyzed? Yesx[x] No NA Comments: No intemal standard area and retention time summaries were provided. The associated peak responses were compared and the QC criteria were met. No qualification of data. bna.elec.n 12291994 1330 6 Fonn BNA 1.1 3 02779 Cue Nianber 93010 PiojeelNunlier: 29872 10.1 Site ID: bbnd Cbemial Coapuiy Blank Analyses Were the appropriate number of blank analyses performed? Yes[x] No Were analytes detected in the blanks? Yes No[x] If analytes were detected in the blanks, were the same analytes detected in the associated investigative samples? Yes No NA[x] Did the sample results require qualification due to the presence of analytes in the associated blank samples? Yes No[x] Comments: This review is only based on the evaluation of Pyridine. The target analyte was not detected in the associated prep blanks and qualification of data was not necessary. Laboratory Control Samples Were laboratory control sample (LCS) analyses performed at the correct frequency? Yes No NA[x] Were the LCS recoveries within acceptable limits? Yes No NA[x] Comments: Not applicable. boi.elcc.l 1 12N>9« 1530 7 Fonn BNA 1.1 302780 CueNunben 93010 PngeaNiMnben 29872 10.1 Site ID: bbad Cbemicil Canpniy Sample Results Were target analytes reported in the investigative samples? Yes No[x] Were mass spectra provided for the target analytes detected in the investigative samples? Yes No NA[x] Were the mass spectra of acceptable quality and analytes correctly identified? Yes No NA[x] Were the quantitated results for target analytes calculated using the appropriate intemal standards and were the relative retention times (RRTs) acceptable? Yes[x] No Comments: As stated previously, the chromatograms do not show the scans for Pyridine and N-Nitrosodimethylamine, a visual evaluation was not possible. The possibility that the injection peak or other factors might have interfered with or affected the quantitation of the target analyte. Pyridine, cannot be evaluated. Therefore, the reported results for Pyridine in the investigative samples were qualified as estimated (J). Tentatively Identified Compounds Were tentatively identified compound (TIC) searches conducted for all sample analyses? Yes No NA[x] Were non-target peaks evaluated as required? Yes No Were the TIC mass spectra, searches, identifications, and quantitated results acceptable? Yes No Comments: Not applicable. bm.elec.ll I 2 » l » < 1530 8 Fonn BNA l.l 302781 CueNwsber 93010 tn^oaNiMiixr. 29872 10.1 Sile uy. bind Cbentieal Ccn^uqr Log Books Were sample preparations properly documented and performed in accordance with method protocols? Yes[x] No NA Were sample analyses properly documented and performed in accordance with method protocols? Yes[x] No Comments: None bm elec.n '22»'»*' "30 9 Fonn BNA 1.1 302782 Cue Nunber 93010 Pit^eetNunber. 29872 10.1 Sle ID: bind CfaemiGal Omniury Calculation Checks Instmment Tuning m/z of 127, 1-27-95, 10:25:00 Relative Abundance: 1092 X 100 = 49.82 2192 Initial Calibration Std 50, 11/9/94, D5-Phenol RRF: 16823 * 20 = 1.330 10117x25 %RSD: 0.071 *100% = 5.422 1.309 Continuing Calibration Std 50, 11/9/94, Pyridine RRF: 12239 X 20 = 1.3608 7195 X 25 %D: 0.918- 1.361 xlOO% = -48.257 0.918 Surrogate Recovery SO0120, 2-FIuorophenol 25426 X 20 = 63.6286 6358 X 1.257 63.63 X 100 = 84.84% recovery 75 bm elec.ll 12»1»*"530 10 Fonn BNA 1.1 302783 C u e N m k e r 93020 PnysaNiKter 29872 10.1 Sile ID: bbnd Chrink»l Conqny Matrix Spike Recovery Detected concentrations not known RPD: Batch 12098, Phenol 2 I 8 - 14 I = -54.54 I 8 -H4 I Sample Results CRQL: Water san:^)le Detected Result: No detection TIC Result Not required bm elec.ll ,12291994 1330 H Fonn BNA 1.1 302784 Cue Number: 95OI0 ProjcoNumber: 29872 10.1 Site ID: Utand Cliemical Company HOLDING TIME QUAUFICATION SUMMARY FORM Ui o to •o 00 Ul Sample Identification Date Sampled Date Prepared . Date Analyzed Prep. Holding Time Analysis Holding Time Qualifier Comments: None biM.elec.ll 12291994 l.VO 12 Fomi BNA l.l Cue Number: 95010 ProjectNumber: 29872 10.1 Sile ID: bland Chemical Com^Mtny INITIAL CALIBRATION QUALIFICATION SUMMARY FORM Date/Time Instmment Analyte - RF . RSD Samples Affected Qualifier Ui o to 00 Comments: None bm.elec.ll 122919*1 1330 13 Fonn BNA l.l Cajc Number: 95010 ProjcclNumber: 29872 10.1 Site ID: Ubnd Chemical Company CONTINUING CALIBRATION QUALIFICATION SUMMARY FORM Date/Time 1-27-95, 11:35 Instmment B 1 Analyte Pyridine > RF %D 48.3 Samples Affected S00120, S00119, SO0118 Qualifier J/UJ Co o to CO Comments: None b m . e l e c . l l 1229I99J 1530 14 Fonn BNA 1.1 C«»e Number; 95010 ProjectNumber: 29872 10.1 Sile ID: bland Cbemioal Company BLANK SUMMARY FORM Blank ID Analyte Blank Result (units) Action Level Associated Samples LO o to ^ 00 00 Comments: None bm elec.ll 122919*1 1330 15 Form BNA l.l Cue Nunber 93010 PiojeoNunber: 29K72 10.1 Site ID: bbnd Cbemiad r n n y n y Summary and Conclusions The analytical results for Pyridine are acceptable for use as qualified. The reported results for Pyridine in the investigative samples were qualified as estimated (J) since a visual comparison of the peak acquisition was not possible. The results for Pyridine in the investigative samples SOO 120, S00119 and SOO 118 were qualified as estimated (J) due to exceeding continuing calibration criteria. Validator's Signamre: ^iXoictA. H A C y t / ^ Validator's Initials: ^/f^ Validation Date- ^-//- 93 QC Reviewer's Signature: ^^'U...cjC^.ty 7 ^ ^ Z ^ y P / t ^ QC Reviewer's Initials: pf/>/> Review Date: i - i ^ - 9 r bm.elec.ll 12291994 1330 1 6 Form BNA 1.1 302789 ENVIRONMENTAL LABORATOmES REPORT OF LABORATORY ANALYSIS Analytical Results - Semivolatile Organics by Method 8270 Harding Lawson Associates Client ID: S00118 Description: NA Sample ID: VQC-OOl Matrix: Vater Wet/Dry Basis: NA Collected: 01/18/95 Received: 01/23/95 Prepared: 01/24/95 Analyzed: 01/27/95 Percent Moisture: NA CAS No. 110-86-1 P a r a m e t e r Pyridine Concentration, ug/l (ppb) Sample ND Blank ND Detection Limit 10.0 U 3 ND-Not Detected a t or above the detection limit s t a t e d . Reviewed By Date VALIDATED k'li- "^s 201 161 James Drive West, Suite 100 Sl. Rose. U 70087 TBL 504-46M333 FAX: 504-469-0555 An Equal Opportunity Employer 302790 ENVIRONMENTAL LABORATORIES REPORT OF LABORATORY ANALYSIS Analytical Results - Semivolatile Organics by Method 8270 Harding Lawson Associates Client ID: S00119 Description: NA Sample ID: VQB-OOl Matrix: Water Wet/Diry Basis: NA Collected: 01/19/95 Received: 01/23/95 Prepared: 01/24/95 Analyzed: 01/27/95 Percent Moisture: NA CAS No. P a r a m e t e r Concentration, ug/l (ppb) Sample Blank Detection Limit 110-86-1 Pyridine ND ND 10.0 U3 ND-Not Detected at or above the detection limit stated. VALipATED Date 161 James Drive West. Suite 100 St. Rose. LA 70087 TEL: S04-4«»«i33 FAX 504-46W)555 202 An Equai Opportunity Employer 3 027 91 I N C - O R P O R A T E O ENVIRONMENTAL LABORATORIES REPORT OF LABORATORY ANALYSIS Analytical Results - Semivolatile Organics by Method 8270 Harding Lawson Associates Client ID: S00120 Description: NA Sample ID: VQA-OOl Matrix: Water Wet/Dry Basis: NA Collected: 01/20/95 Received: 01/23/95 Prepared: 01/24/95 Analyzed: 01/27/95 Percent Moisture: NA CAS No. 110-86-1 P a r a m e t e r Pyridine Concentration, ug/l (ppb) Sample ND Blank ND Detection Limit 10.0 03 ND-Not Detected at or above the detection limit stated. Reviev Date _ VAL ^ HATED 203 161 James Drive West. Suite 100 SI. Rose, U 70087 TEL: S04-46W333 FAX: 504-469-0555 An Equal Opportunity Employer 302792 ENVIRONMENTAL LABORATORIES REPORT OF LABORATORY ANALYSIS Analytical Results - Semivolatile Organics by Method 8270 Harding Lawson Associates Client ID: SO0125 Description: NA Sample ID: VSI-001 Matrix: Water Wet/Dry Basis: NA Collected: 01/25/95 Received: 01/27/95 Prepared: 01/30/95 Analyzed: 02/08/95 Percent Moisture: NA CAS No. 110-86-1 P a r a m e t e r Pyridine Concentration, ug/l (ppb) Sample ND Blank ND Detection Limit 10.0 0 3 ND-Not Detected at or above the detection limit stated. Reviewed By Date VALIDATED, (I'll - I S 204 161 James Drive West. Suite 100 St. Rose. LA 70087 TEL: S04-46W)333 FAX: 504-46W3555 An Equal Opportunity Employer_ 3 027 93 REPORT OF UBORATORY ANALYSIS REV. 1 03/23/95 Analytical Results - Semivolatile Organics by Method 8270 Harding Lawson Associates Client ID: RBSOOl Description: NA Saaple ID: VTX-004 Matrix: Water Wet/Dry Basis: NA Collected: 01/30/95 Received: 02/01/95 Prepared: 02/02/95 Analyzed: 02/08/95 Percent Moisture: NA CAS No. 110-86-1 P a r a m e t e r Pyridine Concentration, ug/l (ppb) Sample ND Blank ND Detection Limit 10.0 02 ND-Not Detected at or above the detection limit stated. VALIDATED Reviewed By llXXU-^^- hUt< Oate 205 161 James Drive West. Suite 100 SL Rose. LA 70087 TEL: 504-469-0333 FAX; 504-469^)555 An Equal Opportunity Emptoyef 3 027 94 k f HLA DATA QUALITY ASSURANCE REVIEW SUMMARY Semivolatile Organic Compound Analysis Case Number: 95020 Project Number: 29872 10.2 Site: Island Chemical Company Contractor Lab: Pace Environmental Labs, St.Rosa, LA Validator: Kirsten Meier QC Reviewer: <J?^t-ti>(l^ ::^. ^Z^^CZZ/*^ Validation Date: Review Date: 3 April 1995 y-^e - ? J - Sample Matrix: Soil Analytical Method: CLP OLM03.0 Sample Designations: SBF2/12-15/012495 (F21215) SBF3/18-20/012495 (F31820) SBCl/18-20/012795 (Cil820) SBD4/20-22/012795 (D42022) SBF2/18-20/012495 (F21820) SBBl/24-26/013195 (B12426) SBCl/20-22/012795 (C12022) SBBl/0-1/013195 (BlOOOl) SBF3/0-1/012495 (FJOOOl) SBCl/0-1/012795 (ClOOOl) SBD4/0-1/012795 (D40001) SBBl/6-8/013195 (B16008) SBF3/12-14/012495 (F31214) SBCl/16-18/012795 (C11618) SBD4/14-16/012795 (D41416) SBBlOl/0-1/013195 (BlOlOl) • - () = Sample ID on Form I Data for the above samples are: [ ] Acceptable for use [x] Acceptable for use as qualified [ ] Unacceptable for use Is action required by the Project Manager? Yes No[x] Comments: The data was reviewed in accordance with the Functional Guidelines, February 1994. bai_ek<:.12 12291994 1530 Fonn BNA 1.1 302795 OwNuDlicr. M020 Praject NtzslcT: 2K72 10.2 Sile ID: Ithmd Cfaeimcml O j o ^ n j DATA COMPLETENESS CHECKLIST [x] Included, no problems [*] Included, problems [O] Not included [NA] Not applicable Quality Control Sununary X Case Narrative * Surrogate Recovery Summaiy * MS/MSD Summary * Reagent Blank Summaiy _x GC/MS Instrument Performance Summaiy Sample Data * Chain of Custody Forms X Holding Times X Organic Analysis Data Sheets X Quantitation Reports X Reconstructed Ion Chromatograms X Mass Spectra Printouts X TIC Mass Spectra Library Searches Initial Calibration Data X Calibration Summary X Standards (Quantitation Reports X Standards Reconstructed Ion Chromatograms Continuing Calibration Data * Calibration Sunmiary X Standards Quantitation Reports X Standards Reconstructed Ion Chromatograms x^ Intemal Standards Summary Iiutnmient Performance Data X DFTPP Mass Spectra X Reconstructed Ion Chromatogram X DFTPP Mass Listings boi_elcc.l2 12291994 13X1 <-\ n .'~i %»?:•*>'•' 302796 Cue Nunber: 9X>3D PK^eel Nunber: 29B72 10.2 Sile ID: bbnd Chrrorml C1wr^m^y Reagent Blank Data X Organic Analysis Data Sheets X (Quantitation Reports X Reconstructed Ion Chromatograms X Mass Spectra Printouts X TIC Mass Spectra library Searches Matrix Spike and Matrix Spike Duplicate Data X Organic Analysis Data Sheets X Quantitation Reports X Reconstructed Ion Chromatograms Laboratory Control Sample NA Organic Analysis Data Sheets NA (Quantitation Reports NA Reconstructed Ion Chromatograms NA Mass Spectra Printouts NA TIC Mass Spectra Library Searches Comments: None bo>_eke.l2 122^1994 1330 3 P ^ BNA 1.1 302797 CueNmber: 93020 PiojcO Ninter 29S72 10.2 SiK ID: k i n d Oxmial Cen^mny SPECEFIC COMMENTS REGARDING ANALYSES Chain Of Custody Were samples properly preserved and received in good condition? Yes[x] No Were custody transfers correctly and completely documented? Yes[x] No Comments: The Chain of Chistody forms submitted with this data package were not signed and dated by the lab upon receipt of the samples. No qualification of data. Holding Times Were sample extractions performed within holding times? Yes[x] No Were sample analyses performed within holding times? Yes[x] No Comments: None Instrument Tuning Did the instrument performance checks meet acceptance criteria? Yes[x] No Were samples analyzed within the 12-hour period following an acceptable performance check? Yes[x] No Comments: None tia>_elcc.l2 12N1994 1330 4 Fora, BNA l.l 302798 Cue Number: 93020 Prcgea Ninter: 29872 10.2 Sile n>; Ilfaoil Clnnkni r'.aiiiMiiji Initial Calibration Did the laboratory meet the method requirements regarding the minimum number of calibration standards for an acceptable initial calibration? Yes[x] No Did the initial calibration curves meet the linearity criteria for maximum percent relative standard deviation (%RSD)? Yes[x] No Did the initial calibration meet the minimum relative response factor (RRF) criteria? Yes[x] No Comments: None Continuing Calibration Did the continuing calibration curves meet the linearity criteria for maximum percent difference (%D)? Yes No[x] Did the continuing calibration meet the minimum RRF criteria? Yes[x] No Comments: The compounds in the associated continuing calibrations that exceeded the QC criteria, are listed in the table "Continuing Calibration Summary". The results for the listed compounds in the investigative samples were qualified as estimated (J). biB_elec.|2 12291994 1330 5 Form BNA 1.1 302799 CUE Nunber: 93020 Pn>ieet Nisnben 29S72 10.2 Sile ID: bhed Cbemjcol Ounpeny Surrogate Recoveries Were the surrogate spike recoveries within acceptance limits? Yes[x] No If the spike recoveries were imacceptable, were the samples reanalyzed? Yes No NA[x] Comments: One acid and one base/neutral surrogate exceeded QC criteria in the investigative sample C1(X)1. (Qualification is only required when two surrogates from the same fraction are out of compliance, no qualification of data. Matrix Spikes Were matrix spike analyses performed at the correct frequency and on a sample matrix representative of the samples in the sample delivery group (SDG)? Yes[x] No Were the matrix spike recoveries and relative percent differences (RPDs) within acceptance criteria? Yes No[x] Comments: The matrix spike performed on the investigative sample B12426 was within QC criteria. The matrix spike performed on the investigative sample F3(XX)1 had several problems: 2,4-Dinitrotoluene (95% and 95%, high), 4-Chloro-3-methylphenol (120%, high) and Pentachlorophenol (RPD=105%, high). These problems appear to be sample specific, since the blank spike from that day and the other matrix spike have no problems. Therefore, the result for Pentachlorophenol in the investigative sample F30001 was qualified as estimated (J). Two blank spikes were performed, on 2-21-95 and on 2-27-95. The spike on 2-27-95 has 4 base/neutral compounds and 2 surogates out of QC criteria. No qualification of data, since it appears to be a prep related, singular incidence. The matrix spike concentrations presented in Form III have slightly (less than 1 %) different values than the values in the raw data. The recoveries were not affected by it, no qualification of data. Internal Standards Were the intemal standard areas and retention times within the required limits? Yes[x] No If the intemal standard requirements were not met, were the samples reanalyzed? Yes No NA[x] Comments: None beB_elee.ll 12291994 1530 6 Fora BNA 1.1 302800 CueNuaben 93020 Picjeel Nunber. 29«72 10.2 Sile ID: bhmd Ctnnicl Ccnpmgr Blank Analyses Were the appropriate number of blank analyses performed? Yes No[x] Were analytes detected in the blanks? Yes[x] No If analytes were detected in the blanks, were the same analytes detected in the associated investigative samples? Yes[x] No NA Did the sample results require quialification due to the presence of analytes in the associated blank samples? Yes[x] No Comments: Two blanks were extracted, one with each extraction batch. However, the samples were analyzed on three different days and no blank was analyzed on 2-24-95. No qualification of data. See table "Blank Summaiy" for blank contaminants and associated samples and qualifiers. Detections of the listed analytes in the investigative samples below the action level were qualified as undetected (U). Results which were less than the Contract Required (Quantitation Limit (CRQL) were raised to the CRQL. Laboratory Control Samples Were laboratory control sample (LCS) analyses performed at the correct frequency? Yes No NA[x] Were the LCS recoveries within acceptable limits? Yes No NA[x] Comments: Not applicable bra eke.l2 12^1994 1330 7 f ^ BNA 1.1 302801 Cue Nunber 93020 Proiect Nunber 29S72 10.2 Sile ID: bbnil O n n i e l Compuijr Sample Results Were target analytes reported in the investigative samples? Yes[x] No Were mass spectra provided for the target analytes detected in the investigative samples? Yes[x] No Were the mass spectra of acceptable quality and analytes correctly identified? Yes[x] No Were the quantitated results for target analytes calculated using the appropriate intemal standards and were the relative retention times (RRTs) acceptable? Yes[x] No Comments: The analytical instrument is set up in such way, that the raw data concentration has been adjusted for extract volume, GPC factor, soil sample amount and percent moisture and lists the concentration in ug/kg (ppb-dry). A more standard approach is to have the raw data in ug/l, then concentrations can be easier compared to each other. No qualification of data. Tentatively Identified Compounds Were tentatively identified compound (TIC) searches conducted for all sample analyses? Yes[x] No NA Were non-target peaks evaluated as required? Yes[x] No Were the TIC mass spectra, searches, identifications, and quantitated results acceptable? Yes[x] No Comments: TICs were qualified as tentatively identified (NJ). bna^elcc.i: 12291994 1530 8 Form BNA l.l 302802 Caae Nux^er 93020 Proiect Nunber 29S72 10.2 Sile ID: bbnd Chcmiail Cosveiq' Log Books Were san:^)le preparations properly documented and performed in accordance with method protocols? Yes[x] No NA Were sample analyses properly documented and performed in accordance with method protocols? Yes[x] No Comments: None bra_elec.l2 12291994 1530 9 Fonn BNA l.l 3 02803 Ca^Nwofaer 9»20 Prcgect Nuaber 39872 10^ Sle ID: bknd CbBtnic*] Ci;^m,iy Calculation Checks Instrument Tuning, 2-21-95, 7:45, 275 m/z Relative Abundance: 455 ~ X 100% = 24.8362 1832 Initial Calibration, 2-20-95, Std50, Phenol RRF: ( 12164 ) X ( 40 ) (6977) X ( 5 0 ) %RSD: 0.1280 X 100% = 8.4779 1.5098 Contmuing Calibration, 2-24-95, 9:09, Phenol RRF: ( 15869 ) X ( 40 ) ( 8847 ) X ( 50 ) %D: 1.510- 1.435 X 100% = 4.9669 1.510 Surrogate Recovery, B12426, Phenol-d5 % Recovery: 1945.53 X 100% = 77.82 2500 1.3948 1.4350 bm_elec.l2 122919*' 1530 1 0 Fora BNA 1.1 302804 Cue Nunber 93020 Pnigea Nunber: 29872 10.2 Sile ID: bbnd Ctaesnal Cecn^uy Matrix Spike Recovery, B12426MS, Phenol % Recovery: 2494.69- 0 X 100% = 80.71 3090 RPD: 2 I 81 - 76 81 + 76 X 100% = 6.4 Sample Results CRQL: Detected Result, B16008, Bis(2-ethylhexyl)phthalate 10675 X 925.999 14931 X 1.208 TIC Result, B16008, Ketone RT = 7.00 6922.62 X 925.999 x 2 43023 X 1 548.053 297.99 bra_clec.l2 12291994 1530 1 1 Fora BNA l.l 302805 C»se NvsTiWr. 950» Projecl Number: 29S72 10.2 Site ID: bland Chemical CocniMny HOLDING TIME QUALXHCATION SUMMARY FORM o to 00 o Sample Identification Date Sampled Date Prepared Date Analyzed Prep. Holding Time Analysis Holding Time Qualifier Comments: None bni.elee.l2 122919*1 1530 12 Fora DNA l.l Caae Number: 93O20 ProjeO Number: 29872 10.2 Sile ID: bbnd Chemical Company INITIAL CALIBRATION QUAUFICATION SUMMARY FORM Date/Time Instrument Analyte RF RSD Samples Affected Qualifier w o to 00 o Comments: None bra.elce.12 12;9I9'>4 1530 13 Fora BNA l.l Ca«: Number: 95020 Projecl Number: 29ff72 10.2 Site ID: bland Oiemicsl Company CONTINUING CALIBRATION QUALIFICATION SUMMARY FORM LO O to CO O 00 Date/Time 2-21-95 2-24-95 Comments: None Insfrument B B • Analyte No Outliers 4-ChIoroaniline Hexachlorcyciopentadiene 3-Nitroaniline 2,4-Dinitrophenol 4-Nitrophenol 4-Nitroaniline 4,6-Dinitro-2-methyl phenol Carbazole 2,4,6-Tribromophenol (Surrogate) RF %D 25.9 59.1 59.8 57.5 35.4 54.9 33.8 25.7 25.6 Samples Affected ClOOOl, C11618, C11820 C12022, D40001, D41416, D42022, F21215, F21820, F31214, F3001 C12022, D40001, D41416, D42022, F21215, F21820, F31214, F3001 C12022, D40001. D41416, D42022, F21215, F21820, F31214, F3001 C12022, D40001, D41416, D42022, F21215, F21820, F31214, F3001 C12022, D40001, D41416, D42022, F21215, F21820, F31214, F3001 C12022, D40001, D41416, D42022, F21215, F21820, F31214, F3001 C12022, D40001, D41416. D42022, F21215, F21820, F31214, F3001 C12022, D40001, D41416, D42022, F21215, F21820, F31214, F3001 C12022, D40001, D41416, D42022, F21215, F21820, F31214, F3001 Qualifier None J/UJ J/UJ J/UJ J/UJ J/UJ J/UJ J/UJ J/UJ None bmclec.ll 12291994 1530 14 Fora BNA l.l Caae Number: 95O30 Projecl Number: 29872 10.2 Site ID: bland Chemical Company CONTINUING CALIBRATION QUAUHCATION SUMMARY FORM Date/Time 2-27-95 Instrument B Analyte 4-Ch!oroani!ine Hexachlorcyciopentadiene 3-Nitroaniline 2,4-Dinitrophenol 4-Nitrophenol 4-Nitroaniline 4,6-Dinitro-2-methyl phenol Pentachlorophenol 3,3'-Dichlorobenzidine Di-n-octyiphthaiate RF %D 29.7 57.3 60.2 48.0 37.5 57.7 27.8 36.5 34.3 -29.4 Samples Affected F31820, B12426, B16008, BlOOOl, BlOlOl F31820, B12426, B16008, BlOOOl, BlOlOl F31820, B12426, B16008, BlOOOl, BlOlOl F31820, B12426, B16008, BlOOOl, BlOlOl F31820, B12426, B16008, BlOOOl, BlOlOl F31820, B12426, B16008, BlOOOl, BlOlOl F31820, B12426, B16008, BlOOOl, BlOlOl F31820, B12426, B16008, BlOOOl, BlOlOl F31820, B12426, B16008, BlOOOl, BlOlOl F31820, B12426, B16008, BlOOOl, BlOlOl Qualifier J/UJ J/UJ J/UJ J/UJ J/UJ J/UJ J/UJ J/UJ J/UJ J/UJ Comments: None u> o IO 00 o vo bnB_elcc.l I 12291994 H30 15 Fora BNA l.l Case Number; 95020 Project Number: 29872 10.2 Site ID: bland Owmioal Company BLANK SUMMARY FORM Blank ID SBLKLl 1 SBLKL2 Analyte Ketone, RT=7.38 min Ketone, RT=7.83 min Bis(2-ethy!hexyl)phthalate Ketone, RT=7.07 min Ketone, RT=7.52 min Unknown, RT= 15.30 min Blank Result (units) 480 110 34 210 66 120 Action Level 2400 550 340 1050 330 600 Associated Samples ClOOOl, Cl 1618, Cl 1820, C12022, D40001, D41416, D42022, F21215, F21820, F31214, F3001, F31820 ClOOOl, Cl 1618, Cl 1820, C12022, D40001, D41416, D42022, F21215, F21820, F31214, F3001, F31820 BI2426, B16008, BlOOOl, BlOlOl B12426, B16O08, BlOOOl, BlOlOl B12426, B16008, BlOOOl, BlOlOl | B12426, B16008, BlOOOl, BlOlOl Comments: Detections of the listed target analytes in the investigative samples below the action level were qualified as undetected (U). Results which were less than the Contract Required Quantitation Limit (CRQL) were raised to the CRQL. Sample concentrations of TICs identified as blank contamination or artifacts were qualified as rejected (R) when below the action level noted above. CO o IO 00 o bro_elec.il 12:91994 1530 16 Foim BNA 1.1 Caae Nunber: 93020 Piojeet Nunber: 29K72 10.2 Sile ID: bbad ChemicBl Company Summary and Conclusions The analytical results for the semivolatile analyses are acceptable for use as qualified. The results for analytes exceeding the continuing calibration criteria were qualified as estimated (J). See report for detailed list. The result for Pentachlorophenol in the investigative sample F30001 was qualified as estimated (J) due to a high RPD in the matrix spike. Several analytes were qualified as imdetected (U) due to blank contamination. See the table "Blank Summary" for detailed listing. Sample concentrations of TICs identified as blank contamination or artifacts, were qualified as rejected (R) when below the action level. TICs were qualified as tentatively identified (NJ) as required in the Functional Guidelines. Validator's Signature: Validator's Initials: QC Reviewer's Signature QC Reviewer's Initials: l<jy, ICA^ HzA-'t/ KM ^Z^Xcjicuc/ ^ . T^yCUZ^ MPf • Validation Date: ^ ^ - S ' ^ - S Review Date: V- /o - f f bni_elec.ll 12291994 1330 17 Fora BNA 1.1 302811 si;;.M:i:voL..ATiLi;: OF<GANICS A N A L Y S I S DATA SI-IEET ClOOOl L a b - N a m e : ETC/GUI...F SOUll-l L a b C o d e : GULF Car>Gv N o . : Hi^.A C o n t r ^ i c t : SAS No.. : SDG N o . : 9 5 0 2 0 M a t r i x : ( s o i l / w a t e r ) SOIL. Banifjle w t / v o l : ._3..Q..-.P_ (gZiuL) G. I... e V e l : ( 1 o w./ m e ci) !:::.Q.W '::. N o i s i - t u r e ; __1.S d e c a n t e d : ( Y / N ) N Con ceI'l l.ra t.ed Ex 11'-ac L. Vo 1 urne : .^iQlD .._0 ( u L ) I ri.;! e c t i on VCJ 1 Lune :; .2_.;J^ ( uL..) G r-' C C1. e a I-1 u p :: ( Y / N ) Y p H:: 1_0 .;;..^ CAS N O . CONPOUND Lab Sample ID: !in"_F002. Lab File ID: SVVTF02 Date l^eceived: 0Ay^0Z2.X. Date Extracted: Q2/03/95. Date Analyzed: 02/21/9:.:. D i 1 Ll t :L ori F a c t o r ?, 1 - C CONCENTFi: AT 1 ON UN ITS;; (ug/L. or ug/Kq) UG/.KG 1 0 8 - 9 ! ; ; . - 2 - 1 1 0 - B 6 - 1 - •1 -\ -\ . • • n . - y - n . . . f-. i:: ._ ii: • 5 4 1 - 7 3 - 1 - - 1 0 6 - 4 6 • 7 - 9 !;.•,•••• 50 •1 — 9 i::,.... 4;:::;.... 7 10 5 — 6 7 - 9 :l 1 1 - v l - l 1 2 0 - ; ; i 3 - 2 •I 9 0 - H :••••••-I - • - • - - -T-' ll e r I CKI. _. _ _. _ • - —- F' y i ••• i d 1 n e, _ • - b :i. ^: ( 2 - 1 " r 11 zx r o e t l^i y !1. ) E t b e i" - •• 2 •• •• (" I'l 1 o I" o p h e r 1 o 1 1 ,3—D:i. c;I'l 1 Cjr'oberi 7erie_ 1 ,, 4 •- D :i. c h 1 o !'• o i:) e n z e n e — 1 ,. 2-D:i. i;;hlorc)ben 2 e n e _ - 2 -• N e t h y 1 p h e;": o 1 - o X y l:;i J. i-f- ( 1 ~ C I' i ]. o r o |;:i i" o |:) a n e ) a- •—1-^1—Wi t rCJ;;e — Di — ri•••• F-' I-opy 1 a m i I'le_ " • - l"l e X a c; I'i .1. zx r o e 'L h a i "i e Ni 1:robzzri 7.erie_ _ I s o p ; ' i o r o n e _ 2.--\--\'.'... 'K.rzxpI'lerio.1. _ • - 2 ., 4 •• • D :i. rn e t h y 1 p ' "• e i "i o 1 _ _ b i ';;• ( 2 •••• C I' 11 o i" o e 'i;. n o x y ) l''ie A I' lai'i e 2 ., 4 ••• D i c I "I ]. o I''o o i "1 eri o 1 .1. , . T r i r b ] . o I ' o b e n z e n e 91-57- 77-47 o;:-:;....0A C". V.'. r ; v: ; • . . • • • • • • / -..' 91-58 —; .r\ . 1 . -..;• . 1 . •• • . 1 . '.•••f"i ;":;-• •'",•' •• <::• • fX . . . - • " I . "•• I'l.:VI. |::i I'l 1.'. I'I•:':!. .1. <::!I'l e 4 •••• G i "11 o I" o a i"i :i. 1 1 r i e I-leXa'7.b 1 oI"obyx'^zixd i e i " i e 4 -G I'11 o I"z.x- 3-T' 1 e A \ \ y 1 fj l"iei"io 1 - 2 -l'''le 'I. h'/11 "I a \x I "I t h a 1 e n e _ 1-!eX ac:^11 zx ••-•::>cyc 1 opei'i •!;.a^l :i.erie 2 ,, 4 ., 6 - T r i z:. b 1 o i-o p I lei "i o 1 ^ 2:., 4 ,, 5 - T r ;i. c h l o r o p h e r i o l _ _ 2 - G I'l 1. CM' o i'l a p h'l;. h a 1 e i"i e _ 2—l'-l:i 'I;.!'oaii i I ;i.rie _ 1) i ir. e •!;. I "i y 1 F b 111 a 1 a t e - A c: e 1 "I a fl ^ 111" I y 1 o i "i o _ 2 n 6"T':i. I'l i 'I. i'i:> lc:6. i.i.ei'ie 3-1-1 .i. t i"oai"i 11 ;i.I'le Up. 4 0 0 4 0 0 40.0 4 0 0 4 0 0 4 0 0 4 0 0 o I'-. ..-• Q 400 :u 400 ; u 11 400 : u 400 ; u 400 ; u 400 ; u 400 ; u 400 ; L.I 400 ; u 400 400 400 ;u 400 : u 400 ; u 400 ; u I o I I I 11 400 400 400 400 400 980 400 980 400 400 ;u : u ; u !U ;!..! ; F' I I...I I l-i ! I.-.' ; L.l 302812 SEl'IIVOLATILE OF^'GANICS ANALYSIS DATA SHEET ClOOOl Lab Name: ETC/GULF SOUTH Lab Code: GULF Case No.: HLAL Matrix: (soil/water) SOIL, Sample wt/vol: 30.0 (g/mL) G Level: (low/med) LOUl :•.'. Moisture: 18 decanted: (Y/N) N Contract: SAS No.: SDG No.: 95020 Cori cen t ra ted b. :>; t ra c t Volume: 500 .. O ( uL ) I n i e c t i cjri Vo 1 Lune: 2_„ 0 ( uL ) GF'C Cleanup: (Y/N) Y pM: l„g.,_5 CAS NO. COMPOUND Lab Sample ID: VJ£002 Lab File ID: i>VVTr02._. Date Received: 0^^30/95^ Date Extracted:; 02ZjZAiZXX:. Date Analyzed: 02/2:l./9.5 D i ]. u -l'. :i. o r i F a c: t o i": 1 .. 0 CONCENTF^ATION UNITS:; (uq./L or ug/Kg) UG./KG 8 3 - 3 2 - 9 51 -28--5 1 0 0 - 0 2 - 7 1 3 2 - 6 4 - 9 1 2 1 - 1 4 - 2 — - — 8 4 - 6 6 - 2 7 0 0 5 - 7 2 - 3 8 6 - 7 3 - 7 100—01—6 ir. -y ^r\ TA r.\ .1 8 6 - 3 0 - 6 - 1 0 1 - 5 5 - 3 1 1 8 - 7 4 - 1 — 8 7 - 8 6 - 5 - ••"• i:. .... TJ •' .... C> .1./;.U .1..:;. - .'• r-. / —I f\ r-, 8 4 - 7 4 - 2 2 0 6 - 4 4 - 0 1 2 9 - 0 0 - 0 8 5 - 6 8 - 7 — - 9 1 - 9 4 - 1 — — 2 1 3 - 0 1 - 9 - 1 1 7 - 8 4 - 0 - 2 0 5 2 0 7 5 0 - 1 9 3 L: '•:'. _.. 1 '•? 1 - 9 9 - 0 3 •jj .t' - - 3 9 7 0 - ...:.^:') *.. ....^:> .-•. .... ir: •Tr _ ....'"• —A c e r 1 a ps b t lie ri e —2.., 4 - D i n i t r o p h e n o l . . . . _ ^ -_ f,|.j .\^ y. Q p |-,(.;, r I <7, 1 _ _ _ - - D i b e n z o f u r a i ' i _ _. — 2 ,4-Dini trotoluene —D i e t h y l p h t h a l a t e.._.. -~4-CI'l 1 orop^lei"1 y 1 - p l i e n y 1 e't.iiei' " - F l u o r e n e — 4 - N i t r o a r i :i. 1 i n e -~4 , 6~D i n i t r o ~ 2 ~ M e t h y l p h e n CJ 1. —I'^l—Ni t r o s o d i p l i e n y l a m i r i e ( 1 ) 4 -Bromophiei"i'/1 -pheI'l'/].e LI'iei- _ H e x a c i ' i l c j r o b e n z e n e _ _ _ •—F' e I "I L a c I' 11 o r o ]'x! "i e i "i o .1. --F'heriaii t h r e n e An L1 "I I"a cei'l e _ C a I '• Ll a z o 1 e _ _ D i -i"i - B u t y 1 p b 11 "la 1 a Le F" 1 i..t o r' a 11 L I' I e n e _ - - F' y I" e I "I e _ B u t y l b e n z y l p h t h a l a t e , , - - 3 ,, 3 ' —D i •:: I"i 1 o vobc^ri z i <.A i i"i e Bei'i z o ( a ) Ai'i 'i.ht-"ac:ene_ —C l"i r y s e i"i e _;. - b i n; ( 2 - E : L liy 1 h e x y 1 ) F' h L ha 1 a t e . —D i - n - 0 c. t y 1 F' h t h a 1 a t e - - B e i"i z o ( l:>) F" 1 u o i" a ri t h e n e - - B e n z o ( k ) F l u o r a n t h e n e _ - Den z o ( a ) F'yi- e n e -—Indcjno ( 1 , 2 ., 3--cd ) F ' y r e n e _ D'.i. Lien z ( a ., I'i) An LliracjcMM;:-' Bei'i z o ( ci „ I'l „ i ) F'ei-vlei'ie ( 1 ) — Cai'M'iO'L l;>e s e p a r a L e c l 'from D:i. |;jhe!"iyla(i'iii"ie FOF^i'M I 8 V - 2 ; 4 0 0 : 9 3 0 1 9 8 0 ; 4 0 0 ; 4 0 0 ; 4 0 0 4 0 0 : 4 0 0 ; 9 8 0 ; 9 8 0 ; 4 0 0 1 4 0 0 ; 4 0 0 ; 9 8 0 ) 4 0 0 i 4 0 0 ; 4 0 0 ; 4 0 0 ; 4 0 0 ; 40C' ; 4 0 0 ; 4 0 0 ; 4 0 0 ; 4 0 0 ; . 4 4 0 ; 4 0 0 4 0 0 ; . 4 0 0 ; 4 0 0 : 4 0 0 ; 4 0 0 ; 4 0 0 r [ LJ L.l LJ LJ LJ LJ ..... Ll LJ LJ LJ LJ LJ LJ 1 ! LJ LJ •...• LJ t » LJ LJ LJ 1 1 1 I LJ L.i LJ LJ LJ 302813 TENTATIVELY IDEi'^TIFIED COMPOUNDS Lab Names ETC/GULF SOUTH Contract: Lab Code: GULF Case No.: Hl-^A SAS No.: Matrix: (soil/water) SOIL Sample wt/vol: ,30.0 (q/mL) G Level: (low/med) UDJii "; Moisture: .18 decanted: (Y/N) N G o n c e n t r a t e d E x t r a c t V o 1 u m e : 5.0 0. .0 ( u L ) '.r. I'l j e c. Li ori V o 1 u m e : __ .2.n..0. ( LVI... ) GPC Cleanup: (Y/N) Y. p H : .10.:;..?. ClOOOl SDG No.: 95020 Lata Sample ID: yTF002 Lab File ID: SVyTFO^^ Date Received: 01/30/95 Date Extracted: OZ/03/95 Date Analyzed: Q2/2L1/.9.5 Di 1 ution Fac'tor : :l. .. N u m I j e r T J. C s 1" o u n cJ C A S NUI'IBER CONCENTRATIOM UNITS: (ug/L or ug/Kg) UI5Z!<G„ COMPOUND NAME KETOhlE UN KNOWN HYDROCARBON UN KNOWN HYDROCARBON UNKl'^iOWH EST. CONC. 310 " 7 .<. (-1 n Q Iff •fAir^jy 4 , J'A.\'\ 1 3 V - T I C 0203.10 302814 3 / 9 0 •oLM 1 VOL AT I L.L UFCG AN 1 CS ANAL. Y i;> 1 b i)f\ I A OHLLC. I C 1 1 6 1 S Lab Name: ETC/GULF SOUTH Contract: Lab Code: GULP Case No.: FILA SAS No.: I 'i a 11- i X : (soi ]. / water) Si.Q_l L.._._._ Sample? wt/vol: 30.. 0 (g/mL.) G_ Level: (low/med) L(;KJJ r: Mo i <;i Lu r e : 1.2 d e c a n t e d : ( Y / N ) N Ccu'i c e n LraLecl E.-: Li-ac'L V o l u m e : .5>00.p (ul...) 1 n .:i e c. L i o r i V o 1 u m e ;; X^.\:.Q, ( u L.) GPC C l e a n u p ; ; ( Y / N ) Y _ pH^i; _.9.;,.0 CAS NO.. COMPOUND SDG N o . : 9 5 0 2 0 L a b S a m p l e I D : y i j l 0 0 3 L a b F i l e I D : §ALAJX.OXJ. D a t e R e c e i v e d : 0 1 / 3 0 / 9 . 5 D a t e E x t r a c t e d : 02/0.3./9.5 D a t e A n a l y z e d : Q2:/2^1/95 D :i. 1 u t :L o n F' a c L o i" : 'J. - ( CONCENTRATION U N I T S : ( u g / L o r u g / K q ) UG/KG 1 0 8 - 9 5 - 2 - 1 1 0 - 8 6 - 1 - 1 1 1 - 4 4 - 4 - .::> r : : r : • • • . ' . . , < : > 1 0 6 - 4 6 - 7 " 9 5 - 5 0 - 1 9 5 - 4 3 - 7 1 0 8 - 6 0 - 1 • ;; OA....44 •:3.. . * ' . . . ' . . . . ' • • ' . . ' . . - • j , . . | j , . . | . . . . / -J ..-• --I • '1.0 5-67•-'' l l l - 9 1 - : )6- - 4 / - . . . . ( - • , - . • " ' . • • • - . - VA ..••-, -i-'i'lertcj.1. _ _ _ _ - F' y I' • :i- cl i i"i '^ - L!' i ^iH 2 - CI "I J. o i'' o e 'LI "1 y!!.) I!' L h e r "»•.!—L. I "11 ZX I'O p I'len zx .1. • -1 ,, .:>—I.>:i. c:h.i.orober'i zei'ie • 1 .,4 - D i c I'l 1 o i - o •:) e i"i z e n e -1 ., 2—Di c l ' i l o r o b e r i zer'ie_.. _.. • 2 - M e L1' 1 y 1 p 1-1 e i-l o ]. 2 ,, 2 ' —o XyLji lii ( 1—C h 1 o rcj pi"o p a n e ) -4 - rie L i'ly 1 p! "IenQ1 •• N -I'-Li. 'LI"oiiio—D i — I "1—F' |-o f;• y 1 afi'i i r'l e - r l e x a c I ' l l o r o e Ll'iai"le •• I'l:i. L r o b e n zet^e " .1. ili-O p 1 lO i "Ol "1 CO - 2 - N :l. t i - o p I "I e fl o 1 -2 ,, 4 -Dirnetl'iyl phei"iol _ - Ll i --z (, ^:!—C I'l 1 zx i"c>e L l"io x y ) l''ie "c hari e ".c;! ., 4 -.(.';!. C! Ll A. '7) i"0 p riCM"i o .1. - 'A ., A.'.,, 4 — f I" ;i. c: Ll .1. o i"o beri ZOT'IO -l'la pl'rL i'lalcoi "le ...<}...• i 370 370 370 370 370 370 370 37'.'> 370 37C' T ••'* I ••) 3 7 C' 3 /'.'.'} 370 c.- I'I .1. zx I C'.i.;:'U"l :i. .1. .1.1 "1 '7; -",'--/..../.}.--,>....,'.). 9 5 - 9 5 - 4 9 1 - 5 8 - 7 8 8 - 7 4 - 4 1 3 ' ; . - l l - 3 - -y-izzX a c 11.1.Cji"o \XKX'caci ;i. ei"i e _ _ - 4 - (•; ill zx i" o - 3 - I'Me L h •;/1 o Li eri zx 1 • 2-l^'le L l"i•/1 ri a IJ I'vL Lia ]. e 1 "1 e -Flexac:h 1 z)roc:yc 1 operi 'Lad i . e n e -2 ., 4 ., 6 - T i " i c:l"i!l. oi"opl"iCM"ic>l -2 ., 4 ., 5-TI"i c;Li 1 zxrCJpheriCJ 1 _ "»;! —L/ l"i .1. o I'-C'l'I a p i"i 'L l"ia .1. eri o» -2: —I'-Li. "Lr"0:Vvi-i ;i. 1 i r i e _._ -Dime t h y l F^'htLialate : , , '% I-l'...':::I'I<-.'.I'.ji"1 'c11'••/.1.er'le - 2 ., 6—D i:"! i \. 1' o L zx 1 yx e i "1 zz 3- LLi, A I'oan :i. ]. i n e > / o V/O V70 '.AC) -/ .1. O 3 7 0 9 1 0 3 7 0 AA/i'j 3 7 0 91O F-G:-<!'i I SV LJ LJ LJ LJ 1 ; LJ LJ I i 1 I 302815 SEMIVOLATILE OF<GANICS ANALYSIS DATA SHEET C 1 1 6 1 B Lab Name: ETC/GULF SOUTH Contract: Lab Code: GULJF- Case No.: HLA SAS No.: ilatrix: (soil/water) SOIL Sample wt/vol: .30.0 (g/mL) G Level: (low/med) LOW :•.'. Moisture: 12. decanted: (Y/N) N Concen'trated Ex'tract Volume: 5vOf>i_0_ (ul„) 11"1 ji ect:i.ori K'o 1 u m e : ^.-.0 (uL_) GPC Cleanup: (Y/N) Y pH: „.9...p CAS NO. COMPOUND SDG N o . : 9 5 0 2 0 L a b S a m p l e I D : y i F 0 0 3 L a b F i l e I D : SVVTF03 D a t e F< e c e i v e d : 01../..50./2L5 D a t e E x t i" a c t e d : 0 2/0^3./9 5 D a t e A n a l y z e d : Q2A21Z2.:Z D:i. :L U L i ori F a c t.o r : I . C CONCENTRATION UNITS: I (ug/L or ug/Kg) !JG/j<G 8Z>~32-9 AcenaphtLie-^ne 51 - 2 8 - 5 2., 4 - D i n i t r o p h e n o 1 1 0 0 - 0 2 - 7 4 - N i t r o p h e n o l _.... 1 3 2 - 6 4 - 9 D i b e n z o f u r a n _..._ ..._ 121-14-2 - —2,4-Dinitrotoluene 8 4 - 6 6 - 2 — Diethylphthalate _..... _ „. 7 0 0 5 - 7 2 - 3 4 - C h i o r o p h e n y 1 - p h e n y 1 e t n o r 8 6 - 7 3 - 7 — - - F l u o r e i " i e 1 0 0 - 0 1 - 6 4 - N i t r o a n i 1 i n e , 5 3 4 - 5 2 - i — 4 , 6 - D i n i t r o - 2 - M e t h y l p h e n o l . . . 8 6 - 3 0 - 6 N - N i t r o s o d i p L i e n y ] . a m i n e ( 1 ) _.._ 1 0 1 - 5 5 - 3 — 4 - B r o m o p h e n y l - p h e r i y l e t h e r _ 1 1 8 - 7 4 - 1 " - F-le X a c h i o r o b e n z erie. 87'—86- 5"-- -• F'ei "I t a c h 1 o " o p heri o 1 35—01 --'3- —F* I'l e fl a r'l t h i" e r^ e __ __ 1 2 0 - 1 2 - 7 A n t h r a c e ri e _ 8 6 - 7 4 - 8 - — C a r b a z o l e _ 84-74-2 Dn.-n-Butyl phthal ate 206-44-0 Fluoranthene ._ _X. 129-00-0 • - -Pyrei'ie :.. 8 5 - 6 8 - 7 - — B u t y l b e n z y l p h t l ' \ a l a t e _ . . 9 1 - 9 4 - 1 -— - 3 , 3 ' - D i c h l o r o b e n z i d i n e . _ Z-Z'. 5 6 - 5 5 - 3 - - Ben z o ( a ) An t f i r a c e n e _ 2 1 8 - 0 1 - 9 — Cl'ii-ysene „.!."I.'.'ZI-1.„1.._'.^ 1 1 7 - 8 1 - 7 — b i s ( 2 - E t h y l h e x y 1 ) F' Li L Lta 1 a -re. 1 1 7 - 8 4 - 0 - D i - n - O c t y l P h t l i a l a t e I " 2 0 5 - 9 9 - 2 • - B e n z o ( h ) F l u o r a n t l i e n e 2 0 7 - 0 8 - 9 — — Bei"izo( k ) F l u o r a n tl'iene 1 9 3 - 3 9 - 5 — I n d e n o ( 1 , 2 , 3 - c d ) P y r e n e _ 5 3 - 7 0 - 3 Di b e n z ( a ., h) An t l i r a c e n e - ' 1 9 1 -2--'--2 - -Ben z o ( g , I'i., i ) F ' e r y ] . e n e 370 ( 1 ) — Canrio'L b e s e para'Leo ci "i''i"0!ri Di |:jhc?n-y']. amini FOfA't I 8 V - 2 Ll o / <A 910 910 370 370 370 370 370 ;u :u 1 LJ ;u ; Ll ;u 1 1 1 1 '-• :u 910 ; LJ %'•• ' ' ' • ) 'AU 10 :11 370 ; u 3 7 0 ; u 54 ; J 370 : LJ 370 ; u 370 ; u 370 ; A 370 370 ;u 11 p'J UJ c a •7-,/ -.' ^r~ f.. r \ <-\ #T4_^ 302816 SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS Lata Name: ETC/GULF SOUTH Lab Code: GULF Case No.: HLA Contract: SAS No.: C11618 SDG No.: 95020 Ma Lr i X : ( soi .1 /wa ter ) SOIL S a m p :i. e wt/vol: _...'iQ^0 ( g / m L ) G Level: (1ow/med) LOW ".: Moisture: _12. decanted: (Y/N) N Con cei-i t ra Led E x t ra c t Vo 1 ume: 500 .. 0 (uL) lri.:i (v;ctiori Volume : .2 ..O ( uL„) GPC Cleanup: (Y/N) Y pH: _..9...0 Lata Sample ID: VTF003 Lab File ID: SVVTF03 Date Received: 0j!:./30/£5. Date Extracted: 02/()3./95 Date Analyzed: 02./2i/2.& Dilution F a c L o i": "J .. 0 N u m ta e r T I C s f o u ri d : CAS NUMBER CONCENTRATION UNITS: (ug/i._ or ug/Kq) UG/j<G COl^iF-OLJi'-lD NAM! KETDili;: KlITOl-iC RT •W- ES" _ _ , r ^ rirfr- Q.-H- - ^ •"frrBejZ 4 0 0 \ J H UNKNOUJL! AMIDE .1. >-; FORi B V - T H : 3 / 9 0 302817 SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: ETC/GULF SOUTH Contract: Lab Code: GULJF Case No.: HI...A SAS No.: Matri X : ( soi 1 /water ) SjDi; 1_ '•:>am pie w t/v61: ._30.r...Q. (g /mL..) G _._ Level: (low/med) LO^. _ ".: Moisture: ...IsL decanted: (Y/r-1) N Concen tra'Led Exti ac:L Vulcune: 50.0.0 (uu.) 1 r 1 .:i e c: L i o n V o ]. u iiie : 1!:JAXL (^-^' -) GPC Cleanup:; (Y/N) Y pH: ...9_...2 CAS NO., COMPOUND _i I-l i:.ii--ii'il 'i..!.-.. M ; C11820 SDG No.: 95020 Lab Sample ID: V J F O M Lab File ID: EZyjZ04.... Date Received:: 0.1./30£9^ Date Extracted: 02/03/9.5 Date Analyzed: Q2/21/95 D i 1 u L :i. c>n F a c tCJ r : 'J. . C CONCENTRATION UNIIS: (ug/L or ug/Kc;) UG/.Ki.3 LJ 1 0 8 - 9 5 - 2 — 1 1 0 - 8 6 - 1 :: 1 1 - 4 4 - 4 .—. ;:: ii: "V .—. _ '.>" . . ' " " - . . ' . • ' ' . : > 5 4 1 - 7 3 - 1 - 106—46—7— 9 5 - 5 0 - 1 - - 9 5 - 4 8 - 7 — •- 1 0 8: - 6 0 — 1 - 1 0 6 - 4 4 - 5 6 2 1 - 6 4 - 7 - 6 7 - 7 2 - 1 10 5 - 6 7 - 9 1.11-91-:! 1 2 0 - 8 3 - 2 — 1 2 0 - 8 2 - 1 — ;l Q.i,..;.^7... O 9 1 - 5 7 - 6 - -'-.•....n-;~..'x.... '•:.Ai — \>t-:--'.-:A- 9 5 - 9 5 - 4 O •[ .... •:: •-;•.._ -;.' ?;;;;:;;;• •• 7 . q - 4 1 3 1 - 1 1 - 3 -F" h e n o l - F' y r i (J i I'l e -b:i.•;;. ( 2 -Cli!l.c11"oe L hy!!. ) 'F. Llie 1"_ .._ - 2 - C h 1 o r C5 p I'l e n o J. • i , 3—Di ci'l].oI"obei 1 z e n e ; - 1 , 4 - D i c i'l 1 o r o IJ e n z e n e -1,2—Di chloroben zene. • 2—i'ie':: i-iy ]. p b e 11 o ]. _ __ • 2 , 2 ' - o X y LJ i zz ( 1 - C Li 1 o 1 "O p r o p a n e ) - 4 •"! ''I c-> t I'l 'y 1 |ii Ll GO n o 1 "1-1-N i t r o s o - D i - r • -F' r"o p y l am i n e - r 1 e ;•: a c Li ]. o 1 • ci e L Li a n co - N J. 11" Cj b e n z e n e _ _ __ _ -1 s o p I'l o 1" o n e -2—1-1 ;i. "LrCJpheno]. • 2 , 4 - D i rn e L h y 1 p h e i"i o 1 - L) i 'i (2—L; h 1 o I" CJ e 'L i'i o x y ) i''i e 'L Li a n e _ - 2 , 4 • D i c: 1'1 ]. C;J I - o p I'i e |-i zx 1 - 1 ., 2 , 4 - T r i c L i l o i - c j b e n z e n e - N a p i'i L t'1 a 1 e n e - 4 - C h l o f o a n i 1 :i.rie -1-! e X a c i"i 1 o r o L>u 'L a d "i. ei'i e - 4 - C: 111 o i" zx - 3 - i''l e 'L I'l y ]. p Li e n o 1 - 2 - M e t I'l •>'1 n a p I'l t i"i a 1 e n e -F'le X a ci'i 1 oi"co z.yz:. .1.0rjen 'Lac! j. Z7\'\ zx - 2 , 4 , 6 — T r i c:l'iIoi''0|:)i'ienol - 2 , 4 , 5—Tr".i. c:Ll 1 o 1 " o p h e n o l . _ -2--L::i ' L r : o a n i ] i n e -Dimethyl Phthalate. - A c CO n a r.o I'i 'L I'i y .1. e n c-.' -'•:'., 6. -n;• |-| . Li"c> Lo.i-uenz.-. 400 400 400 400 400 .'*). t -J i'-} 400 4-OC' 400 4 C' C' 400 400 400 400 400 •^ (' () 1'.'.( 'll' ) 400 400 400 400 400 40C> 400 400 400 980 400 980 400 400 40C' 980 LJ ; i.j ; L.i ; LJ L! Ll l.J LJ Ll LJ I I I.,.I 11 Q «t < : FO'AA. I ^;;v-1 302818 SEMIVOLATILE OF"<GANICS ANALYSIS DATA SHEET Lata Name: ETC/GULF SOUTH Contract: Lab Code: GULF Case No.: HLA SAS No.: ........ EPA SAMPLE Ni Cil820 Matrix: (soil/water) SOIL Sample wt/vol: __3.Q.......O ( g /m!._) G Level: (low/med) L.Oli! 'r-: Moisture: 1^8 decanted: (Y/N) N Concentrated Extract Volume: 50sLi^.Q (.'-'•'-) I n J tn c 't i on Vo 1 ume: ?:..y..9.'' ^ i'- ) GPC Cleanup: (Y/N) Y pH: ._9...J? CAS NO. COMPOUND SDG No. : 9!i020. Lata Sample ID: VTF004 Lab File ID: SVVTF04 Date Received: 01/30/95 Date Extracted: 02/03/95 Date Analyzed: 02/21.£2Xi D :i. 1 u t i o n F a c: t o r : 1 . 0 CONCENTRATION UNITS: (ug./l.. or ug/Kg) UG/KG Q 83-32-9— - 51-23-5 — 100-02-7-- 132-64-9 121-14-2-- 84-66-2- — 7005-72-3 - A c: e ri a pi li L i' - 2,4~Dini-l: —4-Nitrop!' - - - D i l::i co n z o 'fv 100-01-6- 86 101-55-3 118-74-1 • 120-12-7' - 86-74-8 84..-7.a:..2 — 206-44-0 129-00-0 85-63-7 91-94-1— r.: y r.: v.: ":• 2 1 3 - 0 1 - 9 — 117-81-7- 117-84-0 20 5-99-2- 207-03-9 — 50—32—£5-^ 1 -.-• v.> — • . . : • • . : • — . . ' - 53-70-3 191-2'.;-2 - ene : r o p hen o i ie n o 1 _ _ u" a n _ - 2,4 - D :i. n :i. 11" o t o 1 u e n e . — D i e t hy 1 p h t I'la 1 a te — 4 - C I'll o r o p i'len y 1 - p lien y 1 e L !ic/ r - - F' 1 V.U:M" e n e 4-Ni Li-oani 1 ine... 4 ,6-D i n i t ro-2-Me t hy 1 p bor, o l. N-!'-li L rosod i plienylamine ( 1 ). — 4 — B I " o I'll o p b e n'/1 - p' i'i e n y 1 e L I'i e i"... H e x a c l ' i l o r o b e r i z e n e _ F' e n t a c h 1 o r o p h e ii o 1 _ F' I'l (00 n a. ii t I'i i" e i'i co. A n 'L I'l I' a c: e n e (.; a 1" b a z o .1. e —D1 - n - B u t y i p h t h a l a te,..,. - —F !1. i: zx r a n L I'i e ri e - B u t y l b e n z y l ph'L^1ala'Le - 3 , 3 ' — D i c; i 11 o i'' o b e n z i cl i n e Euoon z o ( a ) An t h r a c e r ^ e - - C h I •• y-iii e n e _ - - - b ii. s ( 2 - E t h y l h e x y 1 )!-' I'i L I'lal a t e . - — D ii. -1-1 - CJ c L y 1 F b t I'i a 1 a L e - B e n z o (to) F'luc'iran t h e n e Bei'i zcio ( k ) F l u o i - a n L h e n e —B;en z o ( a ) i-'yi"erie - IncienoC 1 ,2,3-ci(il )l-'yi"ene Dii b e n z ( a , h) An t L i r a c e n e . . . Ben z o ( g , h ,, i ) i-'ei " / l e n e 400 930 930 4C'0 400 400 4C'0 400 980 980 400 400 400 400 400 400 400 400 400 400 400 97 400 400 400 400 400 400 400 ..... LJ • 1 • I u '..' ..... !.J l.J LJ l.J ,7 L) U 1 • U 1 r '-..' LJ _.. LJ ;! LJ ( 1 ) - Canno'L 1: )e SCO p a I "-'i.'L cod Ti-ciiiii )..)". pl'icorr-/laiiiii. n e FORM I S V - 2 ; / 9 0 302819 TENTATIVELY IDEI^ITIFIED COMPOUNDS Lata Name: ETC/GULF SOUTH Contract: Lab Code: GULF Case No.: hlLA SAS No.: ',a t r i X : (so i 1 / w a te r) Sg.I.i_. Sample wt/vol: _30^P. (g/mL) G_ Level: (low/med) !_0W ": Moisture: C11Q20 SDG No.: 95020 Lata Sample ID: VJJiiJQ'Oii.. Lab File ID: SVVTF04 .1.8 decanted: (Y/N) N Con cen t rA ted Extract Vo 1 ume: 5.0.0.J..0. (uL) 111 .i e c t ii. on V o 1 u m e : .2.-..Q. (*-^^~) GPC Cleanup: (Y/N) Y pH s _9..,2 Date Received: 01/3c;)/9.5 Date Extracted: Q2/03./9.5 Date Analyzed: Q2/2.1/9.5 Dii. I u t i on Fa c tciii': 1 - C N u m t> e r T I C s -f o u n d : CAS NUMBER COMPOUND NAME CONCENTRAT I ON LJN I T S : ( u g / L o r u g / K g ) U.G/J<Lv RT KETOI-IE 9 ^ 7 ^ CONC - i f ^ n s^aCT.'.". f r t ^ Z/''' •icA^ VA... I UllE UNKNOWN AMIDE f^Ay 1 1 0 t^tr^.Z^i .VIZ.. . o o J / Y F-ORM I S V - T I L 020351 77/ -yo 302820 I B S F M I V O L . . A T I L E O R G A N I C S A N A L Y S I S D A T A S H E E T E P A S A I \ r L E N O . BlOOOl !..ab N a m e : E T C / G l J L ^ F . . . S O l J T H . b C o d e : G]jj...F C a i i i e N o . : !::iJ:.v.d,. M a L r i x : (•ir>o i 1 / w a t e i") SO 11... L/Oi'i " L i ' a c t : S a m p l e w L / v o l : L e v e j ".-^ M c i ' i s t u r e : . 1 C o n c e n L i"--x "Lec' E x 'L i" 1 n .:i e c L ii. o n Vc' ] v.x.o: ;• ;;Oj..y (q/ml..) G ( low.-'i'rieiiil) l._Ol'J d e Ci a n t e d : (Y / i-i) N (•'., C l i' I i i "i : SDG No.: 95(D20_ Lab Sample ID: W.G002 Lab File ID: SVVVG02 Da tCO Ro ce i ve(il: 02./03./9 5 Date Extracted: 02/06/95 Date Analyzed: Q2/2.7/9.5 D ii. ]. u "t :i. CO n F a c L o i";; 1 „ ( . e a n c i . i I ! / i'-l !- I li>;-t ;; <:;• .. i x COi''iF'OL;MD C O N C E N T R A ( u g / L ( j r I .1. .1. .1, — .;-> i:: f:: 6 0 - 1 / — ? — . • • • - , r-. I , •; 1 ! I'.-.-.'i I'...l.l, — 1 - ' y I" i (ii i n CO _ — b ii -iii ( 2 - C ; I'l 1 Cil r o e t h y l ) F. 'L I'le r - .A. --'...'.b .1. CO I' O p !'1 e i'l (iO ]. — J. -i 3-- D ii. Ci I'l ] CO I-" (ii toen z e n e _ - 1 , 4 - D ii. (ii i'l 1 (io r(io iioen z e n e . . — 1 , 2—Dii. Ci I'll oi--otioeri z e n e . . 2 - l ' ' ' i e ' L h y l p h e n o l . . . — 2 , 2 ' —CO X y t.l ii. ^ii (!i. —C- I'l 1 CO i"o p I'co p a n e i — il-—i'''i e 'L I'l y 1 [io h e n (io 1 _ 1.,1.... |.,| .j t |.",.., .::.,•••,... J) -j .... |-|.._ f :• |.- r, p y ] ,y, f,-| -j p., i::.^ ...I -.- - - .1. - —.' i:- i;; 1. t .. .1. . _ ... j . . -.--. .1. '.. y ^..'L.l (-.-.'I I .:'. C i l I • ^ -iiiO liOl'KiO ! "'iiOri ZX •2-1-1 ii. •Lr(iiifitieri(i/i 2 , 4 - - D ii. I'!'; e L i"i y 1 |io I'i e n (io 1 Lil il. i-- ( 2 - (Ii i 11 zx i-"(ioe L t i e x y ) t'ie L r i a n OJ — .1. .:;. I <")/,-• r% -» .... i ; : —,• ___ ,;-. ;;; 9 • • " ' r : KA* .1. 3-06- 5-95- '\ — 53- 3-74- 31 -1 -,'.|. „ '-.-1 -4 ..•7 ..4 — .-3- .... — I. I ;.. .1. '.. .. -I 1-1 ::M..M I I.. I I::'. .l.(-..'l \<::: - 4 - C t i l c o r o a n ii, 1 i n e - -1-1 e X a c I'l 1 (io I- CO to u 'L z:\ (ii i e i"j e - 4 - L ; i'l 1 o i-ri - 3 - I ' i e L t i y J. p t i e n c; 1 - 2 •-1^1 e L Ll • / 1 n a ;io i-i 'L h a 1 e n e I-1 <-z: 7. ix (ii i'l .1. (io I - o (ii y (ii .1. o p e I'l 't a (ii ii. e n (oo — - - - 2 . , 4 , 6—Ti^'ii (il il(iorophcon(io]. - 2 ;, •- , 5—"(Vii. c i t i l o r o p t i e r v o l . 2 - - IJ I'i 1 (io I" (io n -Zl lio i'l 'L ti iTi ]. e I'l (oo . • - -2—Nil. L I' C'l a n ii. 1 i n e D ii, 111 e L h • / 1 i'-' i'l 'Lli iTi. 1 a t e — Ac'vion a|io ti L t i y ] . e n e ---'A., 6 -Dii.ri ii. L r o L o l u e n e 7>-r-lii, t r o a n ii. 1 ii.nco lOi'^l U N I T S : q / l < ( i ; ) L J G / K G "ORM 1 S V ~ 1 410 410 410 4;i 0 410 410 410 410 410 I I Q 4 ;• 0 410 410 410 410 4 1 0 ; u 410 ; Ll 4 1 0 ; u ;u ; LJ I Z : 1 1 1 1 (.1 1 u ; LJ :u ; LJ I t I I LJ t ' " • : L J 410 \i\U 410 ;u 410 410 410 410 990 410 990 410 410 410 990 :u :u :U:J ;u ;u ;u ;u 1 LJ ;u ;u ; U J _ 1 3 / 9 0 302821 B2 IC SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET ab Name: EXP/GLJ^LP .SIJ1.J1;H _ _ C(Dntract: 1—I".-^ O . ^ l v l l " ' ' |— I.l.—. r.l- I-1 91-1I il i..l.-_ 111.... „ BlOOOl d e : GLJL£ C a s e N o . . : HLA _ M a t!" ii. X : ('ii- o ii. 1 / w a L e 1 -) S.O I L S a f 11 p !l. e w t / V o 1 : ...-30^0 ( q / m L.) G (l(iow/me(ii ) \AJ}Ai .1.9 ( i i O L . a r i L>.-.-j'..i: ( 1 .'• bi ,1 m SDG No.: 9502C Ueve.L: •:.: Moisture Lab Sample ID: yVG002. Lab File ID;: SVyVG02.... D a L e File(r.(-i:'ii. v(tO(i!: C'2./(J3./95 C CO n (ii e n L1^' a L e (i! 1:! x L r a (ii L V ( J 1 (.((11 co: 5 0 0 - .0 I ri .1 e c t ii con Vco 1 uine ;; 2 . 0 . ((,it..) Gi-'C i!;].coaru.'!io;; (Y/i-!) Y _ pl-1: CniiB l-iG - COI'iF'OLJND D a L c-o Ei! x 11-' a ci t co ci : ( u 1...) D a t (00 A n a 1'/ z e d ;; Tl i 1 u 'L ii. o n F" a c 'L o 1 - C 0 i'^i C F. H • I i^ A T I O i'^l U i i :F T 8 : (ug/l... o r u g / K q ) Uj'Lii'.KG -'06/^ .1. (.A.) -IJ., .1 .-A. 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F-' tie n a n L ti I • e n e -i'-'-i n "z n I'' a (ii (io n (-00 —i...i •::( r iio a i^i CO .1. CO D i —i'l --Byx t y I p ti L t i a 1 a 'Le I"' 1 u CO I-' a n 'L11 e n e . _ _ - -1-'yron e B u t y i t toc;i'i z y l p t i L t i a l a L e . 3 , 3 ' —D ii. Ci i'l 1 (j rco toei'i z i (il i ri e — Ben z o ( a ) An L t i r a c e n e C tl r y iii e n e . _ . 11 ii. s ( 2 - F;: L t ,y 1 tl e X y 1 ) F-' ti 'L ti a 1 a L e _ — D ii. - n - O c Ly 1 P b t h a l a t e .„..„II Be n z o ( to) F-1 u (io I •' a n L tl e n e - B e n z(j (l-i.) I"].i..i.(ioi "an Ll'iei'ie Ben z o ( a ) F ' y i ' e n e • - --Ii'Kileno ( 1 ,, 2 ., 3—ciil) F V ^ e i i e Dii, toeni/ ( a ,, to) i-in ttii'acienco Ben z(io (g ., Ii,, ii.) l-'ei "/lei'ie ... ;i. (.) '•r I. l.J 4 1 0 4.1.0 4 1 0 4 1 0 9 9 0 V *'•.*' r "-| 4:i.O -'•10 '••\- J ' ' • ' 4;i.O 4 il. 0 4 :i C' 4 1 0 4 1 0 4 1 0 •••^ . 1 . ' w ' 4 1 0 4 1 0 4 1 0 4 :l. 0 4 1 0 4 1 0 4 1 0 4 1 0 4 1 0 4 1 0 I:-! ; L' J : u j ;u ; LJ ; LJ ;u : u j ; L ] J : l.J : F : J ' 11 ;u ;ua :u :u ^10 > ^ '^ IZ ; i-'3 : 1.1 ;u 1 LJ :u ; LJ ;u OJ iij"^ Q5 L.i a n n (io 'L iio co iz- o; ro -ix r a 'L co (ii "i • 1'I"(ioiii I)ii.liolK-iOi'iylamii.nco FORLl I S y - 2 3 / 9 0 302822 EPA SAM!-1...17 l--|ij, SEMIVOi...ATILE ORGANICS ANALYSIS DATA SHEET TENT AT I VELY I DEI\T' IF IED COMPOUNDS BlOOOl l...a to Name •; F T C / G U L F . J M UTH to i:;iio(iie;: GLk^P Ca^:.e N(i>.. ;: H.i....A M a t r ii. X : ( z i o i 1 / w a tei--) GL)IL S a m p l e w L / v c o l : 3(o.. 0 (ci/rii!,..) G i... (-iov(oo .1.: i.. 1 (iil i.'-.i.--'I'll (ioc! 1 '..III',' "-.; r'i(ioii,-iii'Lcu "(Oi-;: J. 9 cie(iiai'i'Leiii;; ( Y / M j C(i>n c e n Li "aLc .1 ri.:i(ioc'i.ii.(ion Vci- Gl-'C 171 e -Y^!'! (.' ii;;; i'-iuiiilioei" 7 I i " O 1. i.e.. Con t r a c t : . . _ 1 303 N o . : . . SDG No „ r Z ^ X X M L L a b S a m p l e I D : yVG0.02 Lab I-ii. ;ie I D : GVy:vG.02 D a t e R e c e i v e d ; : 0 2 / 0 3 . / 9 5 I I'i'ate E!x "LraCi'Led :; 02/C)6/'95 J.!oa'Le Ana.!. y z o ( i l ;; 'ZZ.P-^A.Z.'z.zZ. D ii. 1 u 'L ii. o n F a Ci Leo r ;; J .. 0 i n ; > lii i-i: i '..><.X\ , >.A ',', L.-i...i:^i....-c:.i-i I i-.i-i i 1 L.ii-i Li.'i.i. 1 --.-.;; (u(i|/L.. or' u(ii/!-((ii) LJG/!(L- ri07ii-"'GL;;7D •-iAr;7: ; , . . . . . . • i . . , - i ' . ; . , . : LJi-IKi'-lGUJM ! Lil-IKNOl'Ji'i ; i,.ir-! KNOW r-i 1 L.''--i-i.i'-i(JjJ!-; ;.':> ! . LiL. ,' nrrZ-'*'."^ \A^J^>X 1 1 . 2 7 ; 1;:;5.. 7 0 I ^ . - 1 - : • : - 1 - • , ' 1 ' " . I:: .—. i:: i !l. -.i'i Q 47 .1. <:;••..-• 3 1 0 A/J f/j 1 Qv5 I \ < > CD (.1 ro Q : O l-'Gr;:l''i I 3V--T7i:C 302823 0201b4 I B S E M I V O L A T I L E ORGANICS A N A L Y S I S DATA SllEET 1.. a lio N a III e ;; Fi! J C£G i J i..> . 3 0 LJ T H t,i Liiorie;: G.LiL,r_.. C a s e No,,:; FlL A.. M a L r ii. X ;; (^ii (j :i. ]. / w a t e i • ) S O I L ci-;-i:i (11 ii.i ii. e w L/V(io 1 : ....3Q.;/..y. ^ 9 "' 'i'i'•-- - & L e v e l ; ; (l(iOw/riicou ) LOJ'-J r-,', i''l(io ii.-iii'i.,i.,i I'C-.*;: '.\.o Cl Co Ci a n'c (-00 Cl: i^ i.'''t'-i) r--i C(i?n t r a c t : I. Ul... ,• 7 . 0 ( u'... > EPA SiiAMPLE liii).. I : Bioioi I I . . _ SDG No.: 95;020_.. l...ab Sample ID;; yVG004 L _ |,, r-- .; 1 ... T T\ . i--. 1 II ll ir--/"-i .1 ..«:U.i |- .1. .1. I.-.-.' .1..!...': •"•'y.V-.y.-.vlxi"' D a L e R e c e i v e ( i l : 0 2 / 0 3 / 9 5 D a t e Fiix t r a c t e d : Q2Z06Z9Ji D a L e Analyze(ii :; Q2/2:7,/9 5 D il. il. u L :i. o n F" a ci L o i- : 1 „ 0 111-'I 1 ; / I'--: I 1 Li^li-i^ i-i I) .. C0i^F'0U!-4D CONCENTRATION UNITS: ( u (ii / i... o I-" u g / K g ) U G / j< G 103-95—2- 1 1 0 - 3 6 - 1 - 1 1 : ; , - 4 4 - 4 - i-• neon o .i. —l-'yi--ii.(il ii.ne _ _ — toii^i ( 2 — G t i l o r o e t t i y l )Fiitti(oor 2 - L; I'l il. (io 1-- (io |io h e n (io 1 - J. , ^ii - I.o ii. (ii ti .i. o rco to con zi (-oon e XK>Zy- (A.:..'-- A.--- '1 ,--t I:T f lA--..^.^—- '"-' •-"•... - - ' I - .... i:: -I ,---. It: .' •"• 1—• .1. \,-' -..I-•-•::> / - - -;•- —- . i . . 1 , . 1 . - - - ' • ; - * . : . - - . i . - - • 9"i—-20--i7 il.(0 6-47'—8 — ' - . ' . A . . . . . . I - A , ' ; . . . - . 1 9 5 - 9 5 ^ - - 7 .r. 1 3 , • ; . • • «.'::•' .. . - ; . .;• --74-4-.- :l. - l l - 3 - ;:";...,Q,,',,..,.;-.:;.. 6--2v>-2- --09-2 1 ,, 2 - D i ctil orotoen z e n e . \ '/;! — I'l(iO L Ll'-/]. D '-iCi'l'l CJ .1. _ .... -. - - 2 ,, 2 '—- cio V y to ii. -ii- ( 1 - C11 il- CO I-- o p i" o p a n CO) . 1 — 4 - M e t h y l p h e n o l _ 1 - - l-i - t-l ii. L r CO iii o - D ii. — n—F-' i- o p y 1 a r ii ii. I'l e 1 t r •• . . . f . • I rli.-.-.' .K .-.X I... I I A. I...I;- I...II.-.-.' I.. I l-::'.l I l.J . 1 t-l ii, 'L I' (io t^en zerKii' . .1. iii(io|ioil(ior'(ioi'ie _ 7!- - tl ii. L rciop tien (io .1, _ i /:!,, 'i-i—Dii.lioe'Ll'Vyl jiol'iei'Kiol _ 1 to ii. iii. 1.7' —C i l l (io i--ooo 'L tiiijx y ) t'ie L t i a r i e _ 1 2 ,, 4 -D i (ii i'l l o r o p h e n o l ', 1 , 2 , 4 - TI" i c tl ii. CO r CO lio e 11 z e n e . . 1 —l'--la(iol'i Ltia .1.cio|-|i-ii' . _ . , —4 - C11 il. CO I'' CO a n i il. i n e 1 --Flex a (iihl(ioi-"oliou'La(il icone _ 1 — 4 - C tl il, o i-'(i)- 3-r'le t tiy il. p tien o il. ; - - 2 - M e L I'l y 1 n a p ti L h a 1 e n e ; •—I-l Ci' X a Ci tl il, (io i-' CO c y (ii ]. co p e n L a ci ii. e n e 1 - 2 , 4 , 6 - - TI" i (ii h 1 (io i" o p i i e n o 1._ ; — 2 - C I'l 1 (io rcofi -:';i. |io !'i 'L tia il. e n e —2-Hii. t r o a n ii 1 ii.ne —D ii. 1II e L hy 1 p',, L i'i a ]. -a L e — Aci(ionapti'Lliyl(jrie •-2 , 6 -Dii.n ii. Lr^iO'Lcilue-ie — 7>-l'-lii. L I-CO a n ii. 1 ii.ne FORi-'i 1 -.'•• 9 (..i' 3 9 0 3'-i''0 zy-y'j -.i •-:••'( i' 3 9 (J ;u I u I 1 I I '—' ! l-J : 1.J I l.J I i Ll ;u 1 1 1 1 C.I ;u ; LJ : i 1 LJ ; LJ 1 1 1 1 ( J ; LJ 3 ;u '.I I 9 5 0 ; u 390 ; u 3 9 0 ; u 3 9 0 ; u 9 5 0 ; u j I M^li^pZ 302824 LlJ J IC SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET EPA $vAMPLE yn BlOlOl Lata Name: FIC/Gy;^F_.GGUT! I.b Code: GULF Ciiiin L i - ' a c t : : i-i I... f'l C a s e M M a t r i x : ( s ( j i 1 / w a t e r ) SO Ji L. S a m p l e w L / v c o l : _..30;^.0 ( q / m L ) G l . . e v e l : ( l ( i j w / m e ( j ) j-Jii)!^ "v; M c i i i s t u r e : 1 6 d e c a n t e d : ( Y / N ) N. C(jri ccoi'i LI ".i-:!. Le'.ii I... .\ L i "a (ii L Vci' .1. UIIK-OO ;; 5' I n J e c L i o n V o il. ume ;: .2,.;..0 (i.il .) GF'C L'lcoai'iUjiii: --. r, lio;-i:; SDG t-lo . : 9.502CO i...-:':ilio Sampli-io I.D: 'y!.}ALQ.£ZlB— L a b F i l e I D : SVyy.G.04 D<V'. I.V- I"'!y':.' Civ> !t. *\''(•!•'C.I « ' " ' ' . i ! , ' 0•.^>.P y •..' D a t e E x t r a c t e d : 0 2 / 0 6 / 9 5 D a L e A n a l y z e d : 0 2 / 2 7 / 9 5 D ii. ii. u L ii. (io r I F' a c L o i - : 1 . 0 CAS NG COMPOUND CONCELITRP (U(i|./I... (iO!" 121- 84-. 700 100 •' ..- - .1. '- !.6- ::,....- y ---^.. - Q> ii .... ' 2 7 .... - Z.:.- .1. .1. .-.-.:•-•.'- ' .1. .-::.o— .1, ,::i" - —1-1 Cien a |io n c neon co 2.1 4 "D ii, n ii. L r(io ro l i e n (io ]. _. 4 - N ii. L i-o,lio tien co 1 _ —D ii. lio e n z (io "f (.(ian 2 , 4 — D i n ii. triiO'Lolcuoone. — D i!. e -L h y 1 p h t h a 1 a L e - 4 --CI-| 1 o rzx p tiei'i y 1 - p tien y ii. e L tie r. - - — F l u o r e n e . - - 4 - N i t r o a n i 1 i n e - - - 4 , 6—Dii.n ii. 't r i i o - 2 - i ' ^ i e L i i ' / l ptiei'uioil. N—Nii. •Li"o-i-i(iocl i pi'ienyil a m i n e ( ii ). 't—B i^'(iJiii(io p iKiOi"! y 1 — pi Koon y l e 'Ll'icoi" - 1-le x a Ci ti .1, I.il I" Lil t.ien z e n e ; —!-'eri La(iii'i.i.(ioi'(ioiiolien(io.i. 1-' 11 e n a! 'i L ti r e n c- - 1-1 i'l t j-, 1-- a (ii e n e 2 0 6 - 4 4 - 0 8 5 - 6 3 - 7 5 6 - 5 5 - 3 2 1 3 - 0 1 - 9 D ii. — n - B V. t y 1 p i'i J. ti ivv il. a L e F il. u. (ij I-- a n L ti e n e I-' y I- ei'i (io . . _ - B u t y l toen z y l p t i L h a l a t e . . 3 , 3 ' — D ii. (ii i'l J. Cl r o to e I'l z ii. (il i n e _ -- Bcoriz(io ( a ) An Ltii-aciene _ ._ • C h I" y s. e i'i e bi-iii ( 2 - E t t v / 1 tie x y 7 > F' t v L t i a l a L e . 1 1 7 - 3 4 - 0 — D ii. - n - 0 c t y 1 P h t h a l a t e .._' 2 0 5 — 9 9 - 2 B e n z o ( t o ) F " l i . i o r a r i t t i e n e 207—(iiJ3—9 -—Ben z(io ( l-i) I ' l u o r a i ' i L h e n e 5 0 - 3 2 - 8 Ben z o ( a ) P y r e n e I I I Z Z ' ' 1 9 3 - 3 9 - 5 Ii-iiilei-i(j( 1 , 2 , 3 — c d ) F ' y i " o n e 57>—70—3-- - Dii. toen z ( a ., ti) An Ltn-acerKio. 1 9 1 — 2 4 - 2 — —Benzcii(g , i i , i ) l--'ei":/lei'ie ( 1 ) — C a n n o ' L toe s e p a i " a t e ( i i T^rcini D i |io h e n y l am ii.ne F0i7Li 1 S V - 2 I C m LJi'-iiLTS: qZ\<Q) UG/KG D " • ' ' • • / ' ' ' ' 9 50 950 390 .'!• y o ; u ;ua ; u3 I u :'. 1 I I 1 - T , (-1 J ' ! i3 1 : J O 70 : u 7 -.^ ^..-' "- ( J !--. 39'ri ;L;:I ; LJ I LJ 1 • I ! LJ , 3 9 0 ; u 3 9 0 : U J 3 9 0 ; u U>-;'(..-' LJ 3 9 0 ; u 3 9 0 ; u 3 9 0 ;LJ 3 9 0 1 LJ < I 302825 1 F SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET TENT AT I VELY I DENT IFI ED COMF'OUNDS LaL) Name : FIQ/GULF. SOUTH. (ho Code:: GULP C A B O H O . . T , !;;iLA._._....„ Matrix: (soil/water) SOIL Samfoil.e w L / v c o l : ..XxO:.0 (g/m!..) G Leveil.: (loui/iiie(i;) LOW ^; M c o i s t u r e : ; 16 d e c a n t e d : (Y./ii) N Con cie;':'Lra'Lc-(il liiix ci-aciL Vcolume;; ilinj eiiitiicon Voitumc';; X...:.Q.(. ul -) GF'C Cil-eai'u,'.iio;; (Y./i-;) Y pi-i Contract: t-. /-, I—- I-1 ^- „ EPA SAMPLE NO. BlOlOl SDG No.: 9 5020. Lab Sample ID: yyG004. II .1 t. ,1 ( ul |--ii..U!liiJe|- t .1. L.S "fXiOUl'Kil L a b Fiile I D : S V V V G 0 4 D a t e R e c e i v e d : OZ/y3/.2.7i D a t e Extracted;; 02./06./9;i D a 'Le AI'l -lio J. yz e(i!;; 02./27/.2.'•) D' ii. il u 'L :i. (io n F a c 'L co i -: ii. .. ( C O N C E N T R A T I Oi'-I U N I T S : (uq /i... (i) r u g / K g ) UG./j<.G CAS NLJi''lBER CGi''ir'nLJi-MD t-lAMIiii 1 '-' , .PCf....-?.- i Ui"!i... ; t-:.!::. I Ui'-ll::. 1 LJi'-n<t-!Ol'Ji--! I I M. I I---:, ll—.T,ti. t I l..i|Mr\|--|I.Ji.-'-.'l-! ; LiNKI-iGlo-JH. ; Ui-ii<J'-:OUJN ; i ii-ii\i'--iC)W!--.i ; i.iNKNuUisi -r¥rr ; . . i j ^ 1 1 „ 2 7 ; 16 13 .1..:::. .:!.7 . 37 — f " . - • • „ '"/Ci .<'.'.-• ; A&T4'>^ A/J K.J i ) j VJ /? ^ V . CD > >v— I .i.(..- I X 302826 SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET B12426 Lata Name: ETC/GUl-F SOUTH Contract: Lab Code: GULF Case No.: FlL A SAS No.: Matrix: ( soii. 1 /wa ter) SC)IL. Siiample w t / v o l : _„30.^0 ( g / m L ) (3. L e v e l : ( l o w / m e d ) yJW ; ':. r - l o i s t u r e : 1 9 d e c a n t e d : ( Y / N ) H Ciion ciii-ioi'1 Li-'-iri t (i-d Fiii«i Lr-.-H. r L VoTcimco'-' -"i(ii'0 . O (u!._) iii n .'i CO Ci t ii con V o .1 umco: _ .?l.r...Q '^ '-^'-) GF'Lii C l e a n u p : ( Y / N ) Y p H : . . . 3 . M ^ CAS NO. COMPOUND SDG No.: 95020 Lata Sample ID: VVG005 Lab File ID: SVyyG05 Da te Recei Vc:-d : 02:./0 7../95 Date Extracted: 02;/06/.95 Date Analyzed: Q2./2.7/.95 D :i. 1 u t i o n Fact o r : 1 .. 0 CONCENTRATION UNITS: (ug/L or ug/Kq) U(5/.KG Q ;1 ri9....95...2 1 1 0 - 8 6 - 1 - •I 'I -1 - - 4 4 - 4 - 1 0 6 - 4 6 - 7 9 5 - 5 0 - 1 9 5 - 4 3 - 7 1 0 3 - 6 0 - 1 1 0 6 - 4 4 - 5 6 2 : 1 . - 6 4 - 7 r I ' .1. .1. .1. - 7 .1, - - .) - - :! 2 0 - 8 2 - 1 - :i. ''.'>(::•-''•-, / - - - ( : > - 5 9 - 5 0 - i^' 9:L —57--6 (•-. i:; f". TA / I ."> i . _ i:: •—» —? 13 :l, - • 1 "- — F ' t i e n o l F' y r i ci i n e - — to i -iii ( 2 - C tl ]. o r o e L h y l ) Fi L tie i- 2 - C h ]. o I" o p h e n o 1 — —:!. ^ 3 - D ;i. Ci 11 il. o r o Lo e n z e n e _ - 1 , , 4 - D i. c I'l il. (io r o ta e n z e n e - - - :i. , 2 - D ii. Ci 11 il. o I- o to e n z e n e... _ 2-i''!e'Lti'/lphen(:oil. — -2 , 2 ' - o x y b i s ( 1-C t i l co rco p r o p a n e ) - ~ 4 - M e t h y l p h e n o l _..... - N -1 •! ii. t r o iii o - D ii. - n - F' r o p y ]. a m ii. n e - l - l e x a c h l c i o r c o e L h a n e _ N i t r c ' t j e n z e n e i. s (io p bi:>r o n e — 2- - l-i ii, 'L I" CO p I'le n co ii. 2 , 4 -D ii. rne 'L h y 1 p tien (io il. t o i s ( 2 - C V i l c o r i i o e ' L h o x y ) l ' ' i e t t i a n e 2 , 4—Di cl'iii.oropl'ien(iol 1 ,7:,, 4— i r i'.. Ci tl .1 CO I'O toen zi con co I, I t.. .1. >.. „ - _ ri•::•. |..i 1 I 1.. I I<:'. .1. 1-.-.'I I i.J 4 — C t i l CO 1" CO a n ii. il. ii. n e . -i-HeX a (ii li 1 (ior(io liu.v t a d ii. e n e 4 - C tl il, (io I' (io - -7> - -i"*!e L t l y ]. p tlen (j il. 2 - !'''l (J t I'l y il, n a p tl L h a 1 e n co F-lexactiii. (ji-oci'/c il.O p e n "Laiilii, ene_ 2 , 4 , 6—Trii, (iiLil(ijr(iO|iot'iei'i(jl .. 2 , 4 ,, 5 - T r i c t i l c i o r o p h e n o l . '.-.:-i...i ti ?i. CO I "(ion .:X p I'l t Lia 1 e n co . 2 — 1-1,;. Li-(ioai'i .i. il ii nco D ii. iiie L l'iy 1 F' h L ha I a tco"" '", — 1^-1 iii eri a p riL i'ly.i- e n e . 2 , 6 - Ii' ii. 11 ii. -L;-- o 'L co 1 u e n e - — A - I -; ii LI - (0.-,(n ii, ii. ii, n zz. _ FORLi 1 S V - 1 4 :i. 0 4 1 0 4 :i. 0 4 :i. 0 4 :i. 0 4 1 0 4 1 0 4 1 0 4 :i. o 4 :l. 0 4 1 0 4 1 0 4 :i. 0 4 :i. 0 4 :i. 0 4 1 0 4 :i. 0 .'(-; r-l ;- .1. -:,- 4 : 4 1 Ol 4'i O 4 1 0 4 :i. Co 4:i. 0 4 1 0 4 1 O 3 02 827 I LJ ; u : LJ ; LJ : LJ : LJ 1 1 1 1 L.l : I! 11 4 1 0 ; u ILi ILJ ;u ; i-l ;u ; u 3 : LJ 4 :i. 0 ; u ", l-J ; LJ J : LJ 4 :i. 0 ; 1J rrr'A..,'--. I I I ;L. I > ) Si, MS SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET B12426 Lab Name: ETC/GULF SOUTH Lab Code: GULF Case No.: L M l - lla t r i X : (so i 1 / wa te r) SOIL S a m p l e w t / v o l : 3 0 . 0 (g/mL) f L e v e l : ( 1 o w / m o d ) I.XJ.W. ".: M c o i s t u r e : Contract: GAS No.: 1.9 d e c a n t e d : ( Y / N ) N. i:; /A <^. y^ I n .i CO c: t i ciin Vco 1 ufiie: .2.:i..0, ( uL.) GPC C l e a n u p : ( Y / N ) Y p H : CAS NO. COMPOUND (uL) SDG No. : 950.20. t..ata . Samj:) 1 e ID: VVG005 Lab File ID: SyyVGO.5 Date Received: 02/03i./95 Date Extracted: 02/g6./9 5 D a t e i-ii I i:i 1 y z e d : 0.-rAZA..z.:-f. A A' D i J. u t '.i. o n F" a c L o r : 1 . 0 COi--ICENTRA (u(.l/L. o r I. '^-^' Acenaphthene 51-28-5 2., 4-Din i trophenol 100-02-7- 4-Nitroptienol 132 - 6 4 - 9 - - — D i b e n z o f u r a n :l. 2 :i. - :L 4 - 2 - - - 2 ,, 4 - D ii. n ii. "t r o t co ]. u e n e 8 4 - - 6 6 -- 2 - D ii. e t h y 1 p h L I'l a 1 a L e... 7 0 0 5 - 7 2 - 3 4 - C ti 1 o i"o p t i e n y ] - p tien y il. e L tie r 8 6 - 7 3 - 7 - - F 1 u o r e n e _ 1 0 0 - 0 1 - 6 4 - N i t r o a n i l i n e . . . . . 5 3 4 - 5 2 - 1 4 , 6 - D i n i t r o - 2 - M e t h y l p h e n o l 8 6 - 3 0 - 6 N - N i trcostiod i p t i e n y l a m i n e ( i ) 1 0 1 •- 5 5 -•• 3 - 4 - D r o m co p ti e n y 1 - lio i 1 e n y ]. e L ti e i" :l. :i. 8 - 7 4 - 1 He X a c h 1 co r co toen z e n e . 8 7 - 3 6 - 5 - - - — F ' e n t a c ti ii. o r co p tien (io.!. i i h - 0 : t - 3 —- F-'tien ai'i t t i r e r i e A n 'L h I'' a Ci e n e C a r ho a z o 1 e _ _ —- D i - n - B u t y l p h t h a l a t e F"il. u c o r a r r L l i e n e — 1 - ' y 1^ CO n e . _ -- B u t y l toen z y l pti t h a l a t e 3 , 3 ' — D ii. c ll 1 Ci) I" (i) toe n z ii. (il ii. n e 5 6 - 5 5 - 3 - — Ben z o ( a ) An t t i r a c e n e 2 1 8 - 0 1 - 9 — C h r y s e n e . _ ' . . . . . . . 1 - "...- :l. 17-8:1. - 7 - - — b i s ( 2 - E t tiyl tie x y l ) F'ti L h a l a t e 1 1 7 - 8 4 - 0 ; - D i - n - O c t y l P h t h a l a t e 2 0 5 - 9 9 - 2 - — B e n z o ( b ) r l u o r a n t t i e n e 2(i)7—03—9 - B(-?n z o ( k ) F l u . i i j r a n Lheriooo 5(ii' —32--3 - liien z o ( a ) F'yr"ei'ie_ 1 9 3 - 3 9 - 5 — I n d e n o ( 1 , 2 , 3 - c d ) P y r e n e . . . ! - D i b e n z ( a , ti) An t h r a c e n e _ I.'.'., i: 1 2 0 - 1 2 - 7 — 8 6 - 7 4 - 8 8 4 - 7 4 - 2 - - 2 0 6 - 4 4 - 0 - 1 2 9 - 0 0 - 0 — 8 5 - 6 8 - 7 — 9 1 - 9 4 - 1 - H r-. -I ' - . .-1 r ; -1. -/ .1. — Z . . - y - - .lA (:i.) — Li; a I'l I'l CO't iioe -Bei'1 Z(j ( i j , I'l, i ) F'coi "ylei'i I O N U N I T S : g / K g ) yG/J<G L' 4 1 0 ; u 9 9 0 ; u 1 9 9 0 ; LJ 3 4 1 0 : u 4 i... y.) 4 . 1 (iio ; u I LJ 9 9 0 ; u j 410 ;u 4 :i. 0 ; JJ 4 :i. 0 ; LJ 990 ;u J 410 ;u 410 ;L. 410 ;u 41< ; I..J 410 ;u 410 ;u 410 ;u r r ; : ^ 410 ;u Q ^ 4 1 0 ; u • • N^ (^10 j i ^ :A^Af(Z J J 410 ',Uj 4 1 0 ;LJ 4 1 0 ; u 4 1 0 ; u 4 :L 0 ; i J 4 1 0 ;LJ 4 1 0 ill 'Le(il 'friiom Dii. pliei'i'-'lamii.i'ie 1- L.ii 'iri .1. :->V —.<:: 302828 SEMIVOLATILE OF<GANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS Lata Name: ETC/GULF SOUTH Contract: Lab Code: GULF Case No.: F!L..A SAS No.: Matrix: (so i1/wa te r) SOIL c> a m p 1 e wt/vol: „3 P.i^O ( g / m L.) G. Level: (low/m(-?d) L.OU! "; Moisture: 1.9 decanted: (Y/N) N. Con cen LraLed Extract V(jlume: 5C>Oj..O (uL.) I n .;i e ci t :i.con Vco 1 (.une : i2... 0 ( uL ) GPC Cleanup: (Y/N) Y pH: „.3.,.9 Numlioei" TIC-s "found : 3 B12426 SDG No.: 95020 Lata Sample ID: VVG005 Lab File ID: SVVVG05 Date Received: 02/03/95 Date Extracted: Q 2/0.6/.9 5 T)/^te Analyzcii'vJ •• 02.-''27'.-/9 5 D i il.u t i on Fac tor u 1 „ 0 CONCENTRATION UNITS: (ug/L or ug/Kg) y(jyj<.G CAS NUMBER d... M x!f „ COMPOUND NAME I'.l.- 1 L.l I'll.. Kl::. 1 L.ir-!!::. UNKNOlMi'- ' AMIDE _ RT .' . ......- , 18.37 ; EST. t 1 1 1 CONC. ; Q , r:i('s>....1.:.'.r, JL....r^' 1 T-1.1.'."..' '*' 1 ":,..•. 1 rrrrr* Ai^ ', 240 AI^J ; 1 1 1 .._ 1 < - •- ; .i.i.i r2n25ri 302829 SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET Lata Name: ETC/GULF SOUTH Contract: Lab Code: GUL.JF; Case No.: HLA. SAS No.: Matrix: (soil/water) SOIL Sample^ wt/vol: 30. 0 (q./mL) G^ Level: (low/med) LOW 'A: M o i s t u r e : .28 d e c a n t e d : ( Y / N ) N C c o n c e n t r a t e d E x t r a c t V o l u m e s 5CoO..O ( n l ) iii 11 ji (io Ci L ii. con Vco 1 umco: _ 2 . 0 (ul...) GPC Cleanup: B16008 SDG No.: 95020 Lab Sample ID: VVG003 Lab File ID: SVVVG03 Date Received: 02/03/95 Date Extracted: 02/06/95 r>i + ci Anal'^'zed: 02./27/95 Dilution Factor: 1 . 0 ( Y / N ) Y p H : _.8.., COMF'OUND CONCENTRATION U N I T S : ( u g / L o r u g / K g ) !JG/.KG. Q 1 0 8 - 9 5 - 2 - 1 1 0 - 8 6 - 1 - 1 1 1 - 4 4 - 4 - 5 4 1 - 7 3 - 1 - 1 0 6 - 4 6 - 7 1 0 3 - 6 0 - 1 — 1 0 6 - 4 4 - 5 - -- <. ''.•• ! .... y. / ' . .... ~ ' . . , o •">.... "7 '••.... t"" 10 5 - 6 7 - 9 - 9 1 - 2 0 - 3 - 1 0 6 - 4 7 - 8 ' : > ' " • ' . . . . / •'"• _ „ " T ^\ V -• ^, 0 - • ' / 9 1 - 5 7 - 6 - - 7 7 . - 4 7 - 4 — -. 8 8 - 0 6 - 2 c > ''•'• _ . . < : > ' " - : . . . . / ; . . _ < ; > 1 . . . . ^ - >'.'.'.•.... " ' • ' 3 3 - 7 4 - 4 1 3 1 - 1 1 - 3 — P h e n o l F'y I" i d i n e b i s ( 2 - C tl 1 o r o o t t i y l ) E t tie r. 2 —C i'l .1. (io i--iij p i'K-ion (j 1 1 , 3 - D i c tl 1 o r CO toen z con (oo 1 , 4 - D i c: tl 1 o r o Ijen z e n co... 1 , 2 ~ D i c t i l CO rco toen z e n e — 2 - M e Ltiy 1 phen(io 1 2 , 2 ' — o X'/' to j . iii (1—C I'l it CO I" CO f 01'' o |;o a n e ) . • 4 - M e t h y l p h e n o l . . . . —I'l—t-l ii L1"(io ii: CO—D ii.—n—F' r o piy 1 am ii. n e —l"le X a (ii tl il. o r o e L tian e N i t r o to e n z e n e — I s o |io h o r o n e — 2 - 1 ' - : i 11''cop h e n o 1 • - - 2 , 4 - D ii. I'll e L h y 1 p h e n ci 1 b i -Si ( 2 - C tl 1 o r o e L hco x y ) l''le t t i a n e 2 , 4 - ~ D i cLij.oi "Ciphcoi'Kjl - 1 , 2 , 4 - T r i c t i l o r ( i o b e n z e r i e Na |io i'l Li'ia l e n (J . 4 —Ctiil corcoan ii. il. ii.ne 1-1 e x a (ii I'l il. CO r (io b u t a (il i e n co 4 —(i,i tl .1. CO 1--C0—3—i"';(-i- L ti'-/.t p ticon o .1, 2—l'le'Ltiy].ria|iol'ithalcone Fie X a Ci ti 1 co r co ciy c 1 co p e n 'tad i e n e — 2 , 4 , 6 - T r i c ti 1 o r o p heri (io 1 — 2 , 4 , 5 - T r - i , c t i l ( i j r c o p t i e n o l . . . ~2-Chil.(ioi " o n a p h ' L h a l e n e _ — O - M - l •!- .;:> 1.0 •;::•--.:;: I.O — / il 'Ll "(ioan il. .1. il.ri(io -D i me t tiyl P111 tia 1 a t e . A(iieria;ioI I'Ltiy 1 e n ( j - 2 , 6 — D i n i 'Lr(iO'L(iol(.icone - -3—i-i il. t I'coan ii. il. i n e F"nF::i''i l ' 460 460 460 460 460 460 460 460 460 460 460 460 460 460 460 460 460 460 460 460 460 460 460 460 460 460 1100 460 1100 460 460 460 '1 'i 00 J 3 ! 1 Di LlJ U 3 < > LJ LJ U J r o n O f • -• 302830 SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET B16008 Lab Name: ETC/GULF SOUTH Lab Code: GULF Case t-to.: HLA Matrix: (soil/water) SOIL , Sample wt/vol: 30.0 (q/mL) G Level: (low/med) l_.O.W ::. Moisture: 2.8 d e c a n t e d : ( Y / N ) N Con cen tra ted E x t r a r t V n 1 u m e '. tXA£:.j.X>. ^> -•- > I n ..i e Ci t i on Vo 1 ume-; 2:..v..9.. (i-^l-•) GPC Cleanups (Y/N) Y pH: _JLt.2 CAS NO. COMPOUND Contract: SAS No.: : SDG N o . : 9.5020 Lata S a m p l e I D : y V G 0 0 3 L a b F i l e I D : SVyVGOG.. Date Received: 02./0.3/.9]> Date Extracted: 02/06/95 Date Anal;/zad: 02/27/£.5 D ii- il. u 't :i. o n F a c t o i -: :i, „ 0 CONCENTRATION UNITS: (uq/L_ o r ug/Kq) UiiLLJlG 0 S 3 - 3 2 - 9 5 1 - 2 9 - 5 1 0 0 - 0 2 - 7 - — J. JC.. .1. J. *-v JU, * • 8 4 - 6 6 - 2 7 0 0 5 - 7 2 - 3 — — 8 6 - 7 3 - 7 1 0 0 - 0 1 - 6 in -.' A\ IT '-V -! ^.U.^'•7 " v.lXl. • .1. r,> /. "^ (\ / -_ -- 1 0 1 - 5 5 - 3 — 1 1 8 - 7 4 - 1 8 5 - 0 1 - 3 - 1 2 0 - 1 2 - 7 - — 8 6 - 7 4 - 8 8 4 - 7 4 - 2 - 2 0 6 - 4 4 - 0 — 129—00—0 - <;>' .'.'I —•->'.;:;— / ' - 9 1 - 9 4 - 1 i:' / i;: r:: ~y _ 2 1 3 - 0 1 - 9 1 1 7 - 3 1 - 7 — - 1 1 7 - 3 4 - 0 - 20 5-99-2 2 0 7 - 0 8 - 9 5 0 - 3 2 - 3 1 9 3 - 3 9 - 5 - :i. 9 1 - 2 4 - 2 — A cen a p ti t tien co 2 , 4 - D i n i t r o p h e n o 1 _ 4 - I'-l ii. L r CO p tl e n o il. D i b e n z o 'f u r a n 2 ,, 4 - D it n it L r o L o 1 v. e n e D i e t h y l p h t h a 1 a t e... 4 - C til o \-o p tien •^/l — p tic-on y]. co t tie i'. F il. u o r e n e _ ; 4 - N j. LI •• CO a n i 1 i n e 4 p 6 - D i n i Lro-2-l^'l(-io LLi'/1 pii(iono 1 N~Ni t r o s o d i p h e n y 1 a m i n e ( 1 ) . • 4 - BI - c^ 111 (io |i) l"i e ri y 1 - p h e n y 1 e L h e i"._. l-|it.i X a c tl 1 o r o tien z e n e F' CO n t a c Ll ii. o r o p Li (oo ri o ii. - - F' tl e n a n t i-11-- e n e f-in t h r a cen o Liar ho a z oil o - -D i-n-Butyl phthal ate F"lucoi-ari Lriene F' y I' e n e Bu t ' / 1 b e n z y 1 p h t tia 1 a t e 3 , 3 ' -.D i cI'l 1 o i"o bton z ii.(ii in(io Ben z o ( a ) An t t i r a c e n e C tl i"ysen e _ _ - - b i s ( 2 - E t h y 1 h e x y 1 y P h T h a l a te^ D ii. - n - • 0 c L y il. F' I i t ti a ]. a L e - - Ben z CO (t)) F' 1 uco r a n t tien e _ Btionzo( k)Flv.uiiiran LlKione Ben z o ( a )F-'yi''-'"i(- I n d e n o ( 1 , 2 ,, 3 - c d ) P y r e n e Dii. tovii'n z ( a ,, ti) An Ltii' a(ii(-ioru"o B e n zci (g ,, h , i ) F'eryii.ene 460 1100 1100 460 460 460 460 460 1100 1100 460 460 460' 1100 460 460 460 460 460 460 460 460 460 460 550 460 460 ^ 6 0 460 460 460 I G J lua I LJ ; LJ ;u ; LJ ; LJ : LJ:T :u3 ; u ;u ; u ;u3 ; LJ I r < ; Li I u 1 I-l ; u ;B ;u3 : LI 1 1 1 I '...I : LJ ;u : 11 Cannvio't u'Kio'L lioe s e p a r a L e i i fr(ioiii Dii.pi'ien'/laciine FORM I 3 V - 2 021 y? 302831 bL.MIVOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS Lab Name: ETC/GULF SOUTH Lab Code: GULF Case No.: HLA Contract; B16003 t-lo. SDG No.: 95020 Matrix: (soil/water) SOIL Sample wt/vol: ^JZLLO. (g/mL) G l_evel: (low/med) LJOW ";: Moisture: 28. decanted: (Y/N) N Con cen trated Ex tract Vo1ume: 500.0 (11L) ili n .:i o c. t ii. (ion V o it u m e ? : 2.J..0 (ul..) Pi-1= _B.:;.£ Lata Sample ID: VVGOO:;;. Lab File ID: SVVVG03 Date Received: 02/03./95 Date Extracted: 02/(26./£5 Date Analyzed: 02AZ7Z2X:. Di 1 ution Factor': 1 . 0 GPC Cleanup: (Y/N) Y Number TICs -f^cjund : 7 CONCENTRATION UNITS: (ug/L or ug/Kg) yG/J<G. CAS NUMBER COMPOUND NAME KETONE RT 7 . OO EST„ CONC. TX^rty 0 rftH- z......<J 670 X . . 1 ...I 330 860 570 4 . 5 . 98-36- /-... UNKNGi.ilN CARBOXYLIC ACID BENZENEMETHANOL ^ . AL_F'HA „ -MliH' ETHANONE, 1-FHENYL- UNKNOUiN CARBOXYLIC ACID LJN KNOWN AMIDE 8 . 0 2 8,. 97 9..05 10.,03 JhJ J .'i V JfJ "OPx'\ 1 SV-TIC 302832 SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET F31B20 Lab Name: ETC/GULF SOUTH Lab Code: GULF Case No.: HLA Ma L r i X : ( so i 1 /wa te r ) SOJtL S a m p 1 e wt/vol: 30 .0 ( g / m L ) G_ Level: (low/med) jJDW v.: Moisture: 11 decanted: (Y/N) N Contract: SAS No.: SDG No.: 95020 Lab Sample ID: VSR009 Lab File ID: SVVSR09 Date Received: 01/2i f-,.,.,.-—..- .1. .k CU- } 1 n J CO c t ii. con V o 1 u m e : .2.^.0 (^.lL.) GF'C C l e a n u p : (Y/l-l) Y CAS NO.. COMPOUND Date Extracted: 02/03/95 Date Ana.1.yzod : 02/.ALZZPE.'^I D i 1 u 'L i on F ^( c to i": :1. „ 0 pl-l: CONCENTRATION UNIT S: (ug/L or ug/Kg) UG./K.G 0 :i 0 3 - 9 5 - 2 P h e n o l 1 1 0 - 3 6 - 1 - - - F'yi"id i n e . 1 1 :l. - 4 4 - 4 — to i ^ ( 2 ~ C til CO r o e L h y l ) E t tie r 2 "Ci Ll 1 o r o jio Licoi"! (J 1 — 1J 3 - Di chlcorcolioen z e n e 1 , 4 - D i (.": Ll 1 o I'lij tjcon z e n o - • —i M2-Di c t i l c o r o b e n z e n e r> ir i:: —,. -j r.^......a/.. I.-.. / — .' / . : . - :l <o S - 6 0 - :1. - 2 , 2 ' - CO X y to i vi ( 1 - C^ tl 1 CO I" CO p I" o p a I'l e ) . _ 1 0 6 - 4 4 - 5 4 - M e t tiy il. p I'len o 1 6 2 1 - 6 4 - 7 — - H - N i t r o s o - D i - n - i - ' r o p y i a m i n e — l-lexachloi-(ioetl'iane -1 -I ii. L r CO to e n z e n e 1 s CO p i 1 o 1" o n e 7:—1-1 ii, 'LI "iiiO|io tK-ion CO i. 2 ,1 4 - D i m e t h y l pheiKiol - b ii. -Hi ( 2 - C til o r o e t tio x y ) Me'L tian e - • 7:, 4 -- D i c I'l 1 (J r (J p tl e n CO il. - :l. , 2 , 4 - TI ii. Ci i'l ii. CO I" o P e r 1 z e n e - - N a |ij 11 L I'l a ii. e n e - 4 - LM'iil, oriioan ii. il. i n e -1-ie X a (ii i'l il. (J I'CO bu Lad i e n e _ - 4 - ii; tl ii. CO I - o - 3 - l'l e L tl y il. p tl e n o il 2 - M e t l i y l n a p l ' i t h a l e n e - - t i e X a c tl il, o rco e y e il. o p e n Lad i e n e .... 2 „ ^t J, 6—T r i (r Ll .L (iil i--(J pI'len CO L _ - 2 , 4 , 5 - - T I- ii. Ci I'l ]. o I" o p tl e i'l (io il. - - 2—C I'l 1 CO I-' (ion a p h L 1-| a il. e n e - 2—Nii. 'Li-iijan ii, 1 ii.ne _ D ii. m e 'L I'i y 1 !-• ti L Li a 1 a 'L e - - A (ii CO n a pA\ L n ' / J. co n co..... .... .. _ 2 ,6—Dii.n ii. 'Lr(j'L(ioil.(.lenco - 3—Nii Li-oan ii. ii. ii.ne F"GF 7 1 .1. :i. 1 c: 9 7 P'.' 0 :i. 2 .:'.. "l 0 V .1. 7 r\ v.: '~ -/ ... -7 7 " . . . . . • : " . 1-9 --|.....;;j A-'rA - •'•'•'' c . A-4 -63 ... i-,r ir —? - .-1 / -47 — ~: -1 . . . . ' • • -V / . 1 . " • i y - '."••••• .... - r 7- -6 -.- /.I f", -1 . 1 . ' • • • ^l •1 J. p.\ — o8-06—2 9 5 - 9 5 - 4 — 9 1 - 5 3 - 7 Ti- •"/ .... "'.* ^\ .... ''I .... 370 370 370 370 370 370 370 370 370 370 370 370 370 370 370 370 370 370 ; 370 370 370 370 '3 "70 370 7)70 370 900 370 900 370 370 370 . LJ U LJ U LJ U U U LJ U U LJ LJ i..; i...i U LJ U LJ L; (J 1 l.J 11 Ll LJJ l.J LJ U LJ 1 1 \.) • 1 » 1 1 1 1 t 1 1 1 1 1 t I 1 1 1 1 1 1 1 t ; » t : \ : \ ; - ^ @ ^ ' ^ ^ >j 1 <• r- > - ( 1 < • CE •>C>C> UJ 302833 SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: ETC/GULF SOUTH Contract: Lab Code: GULF Case No.: HLA SAS No.: Matrix: (soil/water) SOIL Sample wt/vol: 30.0 (g/mL) G l_evel: (low/med) LOIO ": Moisture: 11 decanted: (Y/N) N F31820 SDG I'^lo. : 9.5.0_20_ Lata Sample ID: VSR009 Lab File ID: SVVSR09 Date Received: 01/25/95 Date Extracted: 02/03/95 I. l.M™ } I r i j e c ' t i o n Volume: 2 • 0 (uL) GPC C l e a n u p : ( Y / N ) Y p H : _8_._6 CAS NO. COMPOUND Dace An a 1 y z e q : o 2 / 2 / / v 5 D -j. ]. u t i o n F' a c t o i": 1 . 0 CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG J>x:.—7 IZ -I *-.f-i c^ ».l .1. - i..!.'. X) 1 0 0 - 0 2 - 7 1 3 2 - 6 4 - 9 1 2 1 - 1 4 - 2 8 4 - 6 6 - 2 7 0 0 5 - 7 2 - 3 8 6 - 7 3 - 7 1 0 0 - 0 1 - 6 f:: "•' / J f= ';> •* 8 6 - 3 0 - 6 1 1 8 - 7 4 - 1 — •- ^ti ' y >".> / .... i:: ..„ „ „ _ _„ _.. _ 8 5 - 0 1 - 8 1 2 0 - 1 2 - 7 - .--.I /. —> yi o . . _.. 2 0 6 - 4 4 - 0 1 2 9 - 0 0 - 0 9 5 - 6 8 - 7 9 1 - 9 4 - 1 — n: / TA TA -T' ».l C) — ».l %.l - - v.> 2 1 8 - 0 1 - 9 1 1 7 - 8 1 - 7 — 1 1 7 - 8 4 - 0 - --. 2 0 5 - 9 9 - 2 — 2 0 7 - 0 8 - 9 5 0 - 3 2 - 3 -— 1 9 3 - 3 9 - 5 - 5 3 - 7 0 - 3 — - — 1 9 1 - 2 4 - 2 - A c e n a p t i t t i e n e - 2 , 4 - D i n i t r o p Li & n (j 1 - 4 - N i t r o p h e n o 1 -- D ii. lio e n z (i>-f u i" a n -2,, 4 - D i n i trotoluc-one ~D i e t h y l p h t ha 1 a t e ' Z 1ZZZ.ZZ. - 4 ~ C t i l Cj i"o fo t i e n y l - p ticon y 1 eo t tie r -r-" 1 u o r e n o - 4 — N i t r c o a n i 1 i n e - 4 , 6 - - D i n i t r o ~ 2 ~ M e t h ' > ' i p h e n o i . _ -I'M-Ni t r o s o d 'j. p>tien'/la(rr.i.nco ( 1 ) - .4.- I-i 1^ o m o p I'l e 11'/1 - pi h e n ' / 1 e L ti e 1-- - F l e x a c h i c o r o toen z e n e - !-• e n t a c I'i 1 o r o p ti (cn o 1 - F" tl e n a n L ti r eo n co _ -Anthracene _ _ - C a r b a z o l e - D i - n ~E:u L'/l pih Lha 1 a Le - F 1 u CO r- a n L I" I e n e _ • F' y I' c? n e _ . - B u t y 1 to e n z y 1 p h L11 a 1 a L e - 3 , 3 ' - D i c h l i o r o b e n z id inzx - B e n z o ( a ) An t ti r a cc-jn (•? - C !i I" y s e n e ; - b i s ( 2 - E t h y l i ' i e x y l ) Pti t h a l a t e . ' l " - D i - n - O c t y l P h t h a l a t e _~.l". —E>cori z o (to) F" 1 uco r a n L tici-n e - B e n z o ( k ) F 1 uco r a n L h (ion o _ -Ben zo ( a ) F'yi"corie - I n ( i i e n o ( 1 , 2 , 3 - c c l ) F'yrei'ie_ —Di toen z ( a , ti) An t ti rac(-oorie - B e n z o ((ij, h ,, d.) 1-' e I" y 1 e n e 370 900 900 370 370 370 370 370 900' 9 O'O 370 370 370 '9C'0 370 370 370 370 370 370 z>2'. 370 370 370 370 370 370 ;u :u J ! LJ 3 ;u I ! 1 I '- .1 :u ;u ;u ; LJ : J ; u 3 ; u :u ! I.J ; Ll J ; LJ I I I I •-"' ;u :u :u ;u ;u ; LJ : J ;u ;u ; J ; LJ 3 :u : u :u 1 LJ : L.: ( 1 ) — L7:Ti.i"'ii'iii.':i'L toco si-ii'pai " a L e d fi'Cifii ii^'ii. liohconyil. aminci- FORM I S V - 2 302834 ( I ^ l.J U Jl 4 3 / 9 0 SEiiMIVOLAiILE ORGANICS ANALYSIS DATA SFIEET TENTATIVELY IDENTIFIED COMPOUNDS Lab Name: ETC/GULF SOUTH Lab Code: GULF Case No.: HLA Matrix: (soil/water) SOIL Sample wt/vol: 30.0 (g/mL) G Level: (low/med) I.-OUI :.; Moisture: l_i decanted: (Y/N) N. Concentrated Extract Volun^e: 500.0 (.i ili n :i Oi* c t i o n V o l u m e : .2.-_.0 (uL.) GPC Cleanup: (Y/N) Y Contract: SAS No.: F3i820 SDG No.: 95020 Lata Sample ID: VSR009 Lab File ID: SVVSR09 Date Received: 01/25/95 Date Extracted: 02/03/95 V> .. -1. ... A .. .. 1 ^•, ; _. ,J pH: Number TICs found: 02/2//95 Di1ution Factor: 1.0 CONCENTRATION UNITS: (ug/L or ug/Kg) UG/.KG. CAS NUMBER COMPOUND NAME KETOt-lu — UETOL-IE UNKNOWN AMIDE R"T / .'JC-l EST. CONC. Q '!V!'....y.:f.?.: •hX\J-Jcf', -irr^ f^'iilij • ^ , 21 J^/ O^ ) \ < > FORM I SV-TIC 302835 3/9C V/ ..» , — Lata N-ame: ETC/GUI..F SOUTH C o n t r a c t : Lata C o d e : GLJLT: C a s e N o . : HLA SAS N o . : l a t r i X : ( s o i 1 / wa t e i") S.O_I.l:.-. £ > a m p l e w t / v o l : _ 3 0 . ^ ( i ( g / m L ) G L e v e l : ( l o w / m e d ) LOUl "; Moisture: .1J5. decanted: (Y/N) N._ Ccm cen tra ted Extract Volume: 500. 0 (ul...) ili n :i e c t i o n V o il. u m e : 2,_~Sl (i-it..) GPC Cleanup: (Y/N) Y...:.. pH: _..8..^.5 CAS NO. COMPOUND SDG No. : 9502( Lata Sample ID: yTFOO.5 Lab File ID: SyyTF05..... D a t e l ^ e c e i v e t J : Oj:./750/.9.5 D a L e E x t r a ci t e c l : 0 2 : 7 0 3 / 9 . 5 D a t e A n a l y z e d : 0 2 / 2 . 4 . / 9 . 5 D i 1 u t icon Faci t o i " : :i . 0 CONCENTRATION U N I T S : ( u q / L o r u g / K g ) Ujij/jxG^ 1 0 8 - 1 1 0 - :t :i. :i - 9 5 - ' 5 4 1 - - 9 5 - 2 - • 8 6 - 1 - 4 4 - 4 - •-7-8 — 7 3 - 1 - F" ti<sri Cl .1. p y r n. (J i n e b i s ( 2 - C h l o r o e t h y l ) E t h e i - . " . 2 - C Ll 1 ("i r o |'.o Lico n co 1 1 ^ 3 - D i citiloroben z e n e . 1.06-46-7- - - 1 , 4 - D i chlorcoiioen z e n e '•5-50-1— - 1 ,2-Di chloroben zene —2-Methylphenol — 2 , 2 ' — o x y toil-iii ( :1.—L.i toil. CO I "CO'1 I'CO p a n e ). - - 4 - M e L tl y 1 p h e n (io 1 , 6 2 :l - - 6 4 - 7 — - —t^l - i'-l ii. t r' o vio - D ii. — n — F-' i" co p y ii. a m ii. n e 6 7 - 7 2—:l. 1-i e X a c h 1 o r o e t tl a 11 e ._ 9 3 - 9 5 - 3 - N i ' L r o toen z e n e _. 78—59—:i. -— I s o p I'l cor'(ion CO c:'i-J— -.-'t'l—5- — 7:—Mi 'Li-"CO|iotien(ioJ. ; :l. 0 5 - - 6 7 - 9 - 2 , 4 -D ii. m e t l'iy ii, p tien (io 1. f-i TA y\ .—, —f -y ...1 — i - t i - j — - ..- :i. 03—60—;i. - 1 0 6 - 4 4 - 5 - • b i s (2-Clilcor(iO(- 'ico t tiai'ico :i. 2 0 - 3 3 - 2— - — 2 , 4 - D ii. (ii i'i 1 (io r o p Li e n (io 1 :!. 2 O - 3 7: - - :1. 1 , 2 , 4 ••- T' I- ii. Ci tl il. CO I-'- (io to e n z co n (;o 9 :l. - - 2 0 - 3 N a |io 11 'L ti a l e n e :!. O6 — 4 7 — iii; - - - 4--Li; tl ii. (io I"(io a n ii. il. ii. n zx 3 7—6 'ii; -- 3 - ~ H e X a (ii i'i ii. (io r (io to i.rL a (il ii. e n e 5 9 - 5 0 - 7 - 4 - C tl 1 o r " o - 3 - M e t h y il p tien o 1 9:!. - 5 7 -- 6 — 2 - M e L 1'1 y 1 ri a p ti L ti a ]. e 11 e 7 7—4 7—4 - Fie x a (ii ti il. (io i" (io ci y ci ii, co p e n L a ci ii. e n e . a fii: - 0 6 - 2 — 2 , 4 , 6 - T r ii. (i; h il. o i" o p h e n (io 1._ 9 5 - 9 5 - 4 - - - 2 , 4 , 5 - T r ii. c ti il. o r zx p ti e n o 1 9 1 - 5 8 - - 7 - - - 2 - Li; i-1 ii. (i) I- (io n a p h L li a 1 e n e 8 S - 7 4 - 4 - 2 - t-l ii. -t \- CO a n it il. ii. n e ..; 131-1:1-3- - Dimethyl Phthalate 2 0 3 - 9 6 --3 - - A c e n a p h t h y 1 e;'i e 6 0 6 - - 2 0 — 2 - 2 ,, 6—D ii. n ii. L i-" (J L (io 11..( e i": co 9 9 — 0 9 — 2 - — 3-Hii, 'Lrco-i;i.n ii. ii, ii,ne 'ORi'^ ^i^Vl•.> 3 9 0 .i>yo 3 9 0 3 9 0 3 9 0 3 9 0 3 9 0 •'A>0 V. ; LJ ' 11 I •"• 1 1 1 : i . j IJ ; L.1 : LJ 3 9 0 IL'ZI 3 9 0 3 9 0 3 9 0 , 3 9 0 9 4 0 3 9 0 9 4 0 3 9 0 3 9 0 3 9 0 9 4 0 _ — , - « . . - V / - ^ 302836 ; l-J ; LJ ;u:r ; l-i 'i u 1 '—' ! LJ ; Li ; !.-j :LJ ;L;3 X.'J ci2o; Lata N-ame: ETC/GULF SOUTH Lab Code: GULF Case No.: HL^j. la tri x: (s(i)il/water) SOIL Sample wt/vol: 30.0 (g/mL) G Level: (low/med) L.Q.W "•: Moisture: IJi. decanted: (Y/N) N Concentrated ExtracL Volumo;?: 5.0.0^.J> (uL) ili r 1 .:i (00 Ci t X o n V o 1 L.Kmo: Z.r..O (ut..) GPC Cleanup: (Y/N) Y p H : ._.8.....5 CAS NO. COMPOUND Contract: SAS No.: SDG l^lo. : 9.5^i2(i).. Lata Sample ID: VTF005 Lab File ID: SVVTF05 Da te R&ce i ved : 01./30/9 5 D a t e E x t r a c t e d : 0 2 / 0 3 / 9 5 D a t e A n a l y z e d : Q 2 / 2 4 / . 9 5 D i l u t i o n F a c t o r : :l . CONCENTRATION U N I T S : ( u g . / L o r u g / K g ) LKi'i/JICJ. I-l o ••-•;.... -T "•.'•... o 5 1 - 2 8 - 5 - - 1 0 0 - 0 2 - 7 1 3 2 - 6 4 - 9 — .1. x;. .1. " " .1. '"-v A : Z ' " " ~ ~ 8 4 - 6 6 - 2 — 7 0 0 5 - 7 2 - 3 8 6 - 7 3 - 7 1 0 0 - 0 1 - 6 - 5 3 4 - 5 2 - 1 8 6 - 3 0 - 6 - 1 0 1 - 5 5 - 3 - 1 1 8 - 7 4 - 1 3 7 - 8 6 - 5 - 3 5 - 0 1 - 8 — 1 2 0 - 1 2 - 7 - 8 6 - 7 4 - 8 - 3 4 - 7 4 - 2 — 2 0 6 - 4 4 - 0 1 2 9 - 0 0 - 0 - A c e n a p h t tien e 2 , 4 - D i n i t r o p i'u-?n o 1 4 - N i t r o p h e n co 1 . D i lioei"i z (io'f yx r a n 2 , 4 - D i n i t r c o t o i l u e n e D i e L h y ]. p ti t i'i a 1 a Le - 4—Ctl 1 COi-(i:ipticonyii - p ticony 1 co Ltico i". F11.1 o r e n e - - 4 - N i trcoan i 1 ii.ne 4,6-Din itro-2-Methyl phenol... - - i'-l - I'-l ii. L I- o <ii CO d ii. [io tl e n y it a :'ii i n e (:l. )... 4 -BrCOmcopheny 1 -pbei'i;>' 1 e tl'iei-_ rlci' X a Ci tl i. (i.i I'CO ho eri';; con eo F-'con t a (ii Li icoi "(ii'pLicoi"i (ioil. -— F" tien a n t t l I ' e n e . A n L h I" a c: e n e " C a r b a z o l e D ii. • - n — B u L y 1 jio h t tl a ii. a L e —F il. u (io I" a r I L i 1 e 11 e _ _ F ' y i ' e n e 8 5 - 6 3 - 7 B u t y i l bei'izyil p t i t t i a l a t e . . . 9 1 - 9 4 -1 - - 3 , 3 ' -D ii. (ii tl il. (io r (io toe!"• z ii. • ii ii. 11 e 1.Z......... 5 6 - 5 5 - 3 B e n zco ( a ) An L t i r a c i e r i e 2 1 8 - 0 1 - 9 — C h r y s e n e 1 1 7 - 8 1 - 7 — - b i s ( 2 - E t h y l h e x y l ) P h t h a i a t e . . . 1 1 7 - 8 4 - 0 D i - n - O c t y l P h t h a l a t e Z. 2 0 5 - 9 9 - 2 - - - - — B e n z o ( b ) Flucoi-an t t i e n e 2 0 7 - 0 3 - 9 - B e n z o ( i O F l u ( i o r a n t h e n e 50—32—8 Benz(io ( a )Pyrzxr)<;x 1 '.:> -I ....'7'.-I . . „ ' .1. / .1. . ( . . V A - Ii'KiierKio ( 1 , 2 , 3-i,ii(:' ) F-''y:-ei-M D i lioconz ( a ,, ti i An t t i r a c e n e T - . V — . ' •- ' - . -: - l - i . . . 1 . . . - - . b l j l I Z 1...' '.. ...j , 1 1 , .1. ,' i ' '::• . --,' I. (-.-.'I IC.'-. ( 1 ) — lianiKioL lioe s e p a i "a'Lco(ii -n-coii Dii. |iO:"ieri'/il. aiiiii. nco r" r-,;--, 1-,. /--: i .-. I- 111'. . ! J .- . -.t -— J : 390 ; u 940 i U J 940 ; LJ J 390 ; u 390 : u 390 ; u 390 ; u 390 ; IJ 940 ; U.J 940 !U:J 390 ; u 302837 TENTATIVELY IDENTIFIED COMPOUNDS Lata i^lame: ETC/GULF SOUTH Contract: C12022 Lab Code: GULF Case No.: HLA ;AS N O . : SDG No.: 95020 Matrix: (soi1/wa ter) SOIL Sample wt/vol: _3.Q..0_ (g/ml.) G Level: (low/med) LCJW "•- t'j o i s t u r e : 1.5. decant e d : (Y / N) H Con cen tra ted Ex t rAc t Vo 1 ume: 5.00^0 ( uL) I l'i .:i CO c t i o n V o 1 u m c-o s ^..-..Q. (u L..) Lata Sample ID: VLIIOCL!:L. Lab File ID: SVVTF05 Date Rece i Ve(J: 01/30/95 Date Extracted: 02/03,/95 Date Analyzed: 02/24/95 D i ]. u t i CO n F a c L co i": 1 ,. 0 ^-GPC Cleanup: (Y/N) Y Nu.ml'.o(?r TIC^s •fcourKil: CAS NLJMBER 6 CONCENTRATION U N I T S : ( u g / L o r u g / K g ) UG/J<G CGl'iPOUND NAME TOi^Iri TONE RT E S T . CONC. ; Q ;A7.J ^ r-%i:;. LJNKNOWi^l FIYDROCAFVBON UN KNOI'JL; HYDROCARBON UNKNOWN HYDROCARBON UN Kl-inLij|-.l 1-IYDR0CARB01--1 A, At,. ,i) :i- vi:' .L >.J 1000 3 .£, Co 130' j y j .1 jfV '^^ •=CJ ^ ) ' 3 > < S > • - : CC c -Lli': 17 ; V - T l L i 302838 3/V(.o ^_Jl \\-/i"ii '( ^. ^ ' w i f-iiMfiL- I <^x<:) ut-'t 1 I I oriCLt:. I : D40001 Lata Name: ETC/GULF SOUTH L-ato C o d e : GSJLJF. CA=ZG N O . : HLA M a 11- j . X : ( s o i 1 . / w a't e I' ) S (i) .IJ.-.,. Sample-) w t / v o l : 3 0 . 0 ( g / m L . ) G 1.. e s-* e 1 : ( l o w / m eo (ii) L_0 W ":; fl o ii. ?i t u I" e : 2 9 . d e c a n t e d : ( Y /1-1) N C o n ccon t r a t ( i ? ( i E x t r a c t Volume-:?: 5.Q0;. Q ( uL.) ili n J e Ci t ii. CO n V (io ]. u m e : 2^.;:. O ( o. L '} GPC C l e a n u p : ( Y / N ) Y. pH: _3j,6_ CAS H O . COMF'OUi'-ID Contract: SAS No.: SDG No.: 95020 Lata Sample ID: VTF.0.0;6._ Lab File ID: GVyiEiQi:.... D a t e R e c e i v e d : 0.1_/13 0./.9.5i Date Extracted: 02/03/95 DaLe Analyzed: 02/24/95 D :L ]. u L :L o n F a ci L co r : :i. „ C CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG iii) 1 0 3 - 9 5 - 2 1 1 0 - 8 6 - 1 - 1 1 1 - 4 4 - 4 f:^ r: , __ t:: ":.'.._C' „ 5 4 1 - 7 3 - 1 - - • 1 0 6 - 4 6 - 7 r;, iv, .... c:^^-,.... •) 9 5-48-7- - 1 0 3 - 6 0 - 1 - 1 0 6 - 4 4 - 5 - - 6 2 1 - 6 4 - 7 6 7 - 7 2 - 1 - - 98-95-3- - 73-59-1- - • 88-75- 10 5-67 111-91 120-33 120-32 91-20- i:: -9- .1 ... 1 ... —.-.-. — - .1. - Z.i .1. (.-I ^•: : . — ' : • / — ; : : > 59-50-7 91-57-6 - 77-47-4 - . 8 8 - 0 6 - 2 9 5-95-4- •• 203-96-3 - - 6 0 6 - 2 0 - 2 9--;•.-09-2 F' tien o 1 _ F' y i" i (J i n e b i s ( 2 - C t i l o r o e t t i y l ) E t h e r 7:—I..; i'l .1 CO rcop ti(-ion (io ]. :l. , 3 - D i Citil CO rco toen z e n e _ 1 , 4 — D i ci'llor(iotoen z e n e : i . , 2—Di citilciorcoliien z e n e 2—I'le Li'iyii. p t i e n o 1 7:., 7:' —CO x y to ii. iii ( 1 —C; ti l o i "co p i "(io p a n e ) 4 - M e t h y l p h e n o l N - N i t rcosco-D i - n - I - ' r(io p y l am i n e_ 1-1 e x a (ii tl 1 o r CO e t h a n e N i Lr(iotoen z e n e . .1. "iii (io p i'l (io 1" (io I'l e • 2—t-l i 'LI" CO |io tl e n (io 1 _ ' - I . n "j--, -: L I - . . * ' ... I.V — . - - -' A., n '-I- - ) . , ' . I . 1111.-.-' I..I l y . l . {..Illi.-Ji M.J.I. to ii. ^i ( 2 - C t i l CO r coe L toco x y ) Me L t lari e A.-.'., 'i-i- —.I..J ii. (iitil (iO r(iO|iol'iii-ion (io .L L- I I-- ii. C i t i l o r o b e i ' i zo\"<zx_ •'. p !i 'L I'l a ii. e n e 4--Ciliii.coi-(ioai-i ii. ii. ii, nC' .1. , A.. , . I-. 1 .••. I - . I - . - I - !- - - 4 -- C l'i il. (io r iii - 3 - t'l e 'L ti y il. p ti e i'i co il. -1-le X a Ci tl il. (io rco ciy (ii 1 co p e n tac: i, e n co - 2 , 4 ., 6 •- TI" 'i. c b 1 (io I-" o jio l'i e n (io 1 •—1 / I TA -(- . . . .; _. 1.. , ... , ... 1 , -I -.'.:. , '•, , - . . I — I l- .1. 1... I i.i.i..,i|- i . i p i r.-.-'l p.,1.1. ";::: --1..; to ,1. (io z- zx y. .AX p l'i L i'l a J. e n e -2 —I'-lii, 'Li-C'ian i 1 i n e -D i me L ti'y 7 P ti L i'la il. a 'Le -1-1 Ci CO n :'-'i. |io t i ' L t l ' - / 1 CO ;• I f-i-i' -2 , 6 -Dii.i'i i. 'Ll "(ioL(ioli..i.ei'ici' 'oa: 1 il, i. ii. nci' 460 460 460 460 ''.' r-l 460 460 460 460 460 460 460 460 460 460 aA.o '•;• .—. I. . •'-I- •::> i-.-i 460 460 460 • 460 1100 460 1100 460 460 460 :i. :i. O'O LJ LJ l.J 3 LJ Li 11 '..,' 1 1 '..J 1 ; i.ja 1 , < > D > 1 • i . 1.J II L: 3 !-fiiL-':;''i •r f—' • 302839 D40001 Lab Mame: ETC/GULF SOUTH Contract: Lab Code: GULF Case No.: HLA SAS No.: Matrix: (soil/water) SOIL Sample wt/vol: 30.0 (g/mL) G Level: (low/med) l-Ol»J :•; Moisture: 29. decanted: (Y/N) N_ SDG No.: 95020 Lab Sample ID: VTF006 Lab File ID: SVVTF06 Concentrated Extract Volume: 500.0 Injection Volume: ^2....0(uL) GPC Cleanup: (Y/N) Y pH: CAS NO. COMPOUND (uL) Date Received: 01/30/95 Date Extrac'Led: 02./.03.,/9.5 Date Analyzed: 02/24/95 D iL 1 u L i on Fa c to r: 1. 0 CONCENTRATION U N I T S : (u Q /1_ o r u g / 1-C g ) U G./K.G EJ3-32-9 5 1 - 2 8 - 5 1 0 0 - 0 2 - 7 1 3 2 - 6 4 - 9 1 2 1 - 1 4 - 2 8 4 - 6 6 - 2 7 0 0 5 - 7 2 - 3 8 6 - 7 3 - 7 1 0 0 - 0 1 - 6 5 3 4 - 5 2 - 1 8 6 - 3 0 - 6 - —- 1 0 1 - 5 5 - 3 1 1 8 - 7 4 - 1 — 8 7 - 8 6 - 5 8 5 - 0 1 - 8 - — 1 2 0 - 1 2 - 7 — <:> S6-74-S 2 0 6 - 4 4 - 0 1 2 9 - 0 0 - 0 - 2 1 8 - 0 1 - 9 1 1 7 - 8 1 - 7 — 1 1 7 - 8 4 - 0 — 2 0 5 - 9 9 - 2 — - 2 0 7 - 0 3 - 9 %.' K) — •_) i:. — c> •\ r:v'T..„~TO,...'"'.....'._ 5 3 - 7 0 - 3 - 1 9 1 - 2 4 - 2 —A c e n a p h t h e n e — 2 , 4 - - D i n i t r o p h e n (j 1 — 4 - N i troptu-?ncol —D i ta e n z o 'f u i" a n _. — 2 , 4~D i n i t r o t o 1 u e n e . . . — D i e t |-i y i p i'i t h a 1 a t o _ — 4 ~ C b 1 o r o ; o t i e n y 1 - p t i e n y 1 e L b o r . —F1 u o r (e n e - - 4 - Ll ii. LI - CO a n i 1 i n e —• 4 , 6 - D i n i 11"o-2 -Me Lli-/]. pihen(io 1. —N-t-1 :i. t ro'iiCKil i plu-sny 1 aminc-o ( 1 ) . —4 - B r o III (io p tl e ri'/1 - |ij ti (-io n y ]. e L ti e i" ... Fl e X a ci tl 1 CO r o to e n z e n e _ —F't-oon t a (ii ti 1 o r(io p Licon (io I _ - - F-' tl & n a n L111" o n o _ -—A n L tl r a c: e n e _ -—Car to a zco 1 CO --D i - n -Eu.i t y 1 p ti L h a ]. a Leo F"l uco r a n t t i e n e . _. -—F' y I'' CO n e - - B u t y l b e n z y l p h t t i a l a t e 3 , 3 ' - D i chlfjrolioen z ifJ i n e -—Ben z o ( a ) An t t i r a f i i e n e _ —C tl I" y s CO n e b i s ( 2 - E t t i y l i h e x y l ) P h t h a l a - L e . — D i - n - O c t y l P h t h a l a t e . - B e n z o ( b ) F" 1 i.uiii r a n L tien e... B e n z (io ( k) F' 1 u (j r a n L h e n c; --Benzco ( a ) F'yi'fjrKoo IiKileriiio ( 1 , 2 , 3 —cd ) F-'yi"snco. -—Di t)(-;on z ( a , ti) An t tii"a c:cori co -—)E;ei'i z o ( g , h , ii.) l-'ei-"/7conco Q — _ __ «...._ „ - ^ _ . 460 1100 1100 460 460 460 460 460 1100 1100 460 460 460 1100 460 460 460 32 460 460 460 460 460 460 75 460 460 460 460 460 460' 460 ~ "- U U3 '-'3 IJ U LJ I.J l.J U3 U 3 U LJ LJ LJ IJ I...1 U3 J u l.J LJ U LJ U J 1 1 '.J LJ IJ LJ LJ 1 ! LJ • " • • * " I 1 1 1 t 1 1 1 1 1 1 1 t 1 1 ) 1 r 1 ; \ : \ v <1 Ck' . r N -U 5;^ *; c D ( 1 ) — L/ann(io'L toe se|ioai"a'Le(J 'froiii Dii. p tien yil. am ii.ne FORM I 3 V - 2 302840 w.._. 1.1. vui_i-f 1 xi_iz. u r < . i j i - m i u i 3 Hr-iHi_ T i3Xi:> i>ft t A I b H E L T TENTATIVELY I D E N T I F I E D COMPOUNDS Lab Name: ETC/GULF SOUTH Lab Code: GULF Case No.: HLA Contract: SAS No.: D40001 SDG No.: 95020 Matrix: (soil/water) SOilL ,.,, Sample wt/vol: „30_.;_0. (g/mL) G l_ e V e 1: (1 o w / m e d ) LOW :.' M o i s t u r e : ^ 9 d e c a n t e d : (Y/N) N C o n c e n t r a t e d E x t r a c t Vol umco: 5 0 0 . 0 (uL) iF n ji CO c t -j. on Vco 1 ume : 2 . 0 (ul..) GPC Cleanup: (Y/N) I'-lumtjcior TICs -fcnund: _ CAS NUMBER Lab Sample ID: VTF006 Lab File ID: S"yVXF.g6._ Date Received: 01/30/9 5 Date Extracted: 02/03/95 Date Analyzed: 02/24/95 D i 1 '.I t i ori Factor: :'. . C pH: CONCENTRATION U N I T S : ( u g / L o r u g / K g ) UG/KG COMF--nUND NAl'lE KETOtJi: RT EST. CONC. ; Q . . _ _ . _ _ _ . ™. . - _ I .C!!f...%y.?..-!^ — - • - ^ '-iS^ . C .'— ! „ 47 ^ UNKNOWN AMIDE 140 J^7 UJ 2^ Jrsk cc FORLl 302841 u ^ U O C O 3 / 9 0 D41416 Lab Name: ETC/GULF SOUTH Contract: Lab Code: GLJLF Case No.: HJLA SAS No.: M;x t r i X : (so i 1 / wa te r ) SO I.L Sample w t / v o l : ^JiCL^X!. (g/mL) G Level: (low./mG^d ) LO.W. ".; M o i s t u r e : ...14 d e c a n t e d : ( Y / N ) N C o n c e n t r a t e d E x t r a c L V o ]. u m e : 5^0_0.. 0. ( u L ) 1 I'l j e Ci t i con V(io 1 ume : . 2..;.0 ( ul...) GPC C l e a n u p ; ; ( Y A H ) Y pH;; ._S..^3. CAS NG. COMPOUND SDG No.: 95020 Lab Sample ID: VTFOOZ Lab File ID: SW.T.F..0.7 Date Received: 0i/30./95. Date Extracted: 02,/0.3/9.5 Date Analyzed: 02/24/95 D '.i. 1 u t i o n F a c 'fco i": CONCENTRATION UNITS: (ug/L a r ug/Kg) UG/KG 1 0 3 - 9 5- 1 1 0 - 8 6 - 1 1 1 - 4 4 - 9 Ll — A A — 'i: 1 0 6 - 4 6 - 9 5—50—:i 9 5 - 4 7 7 - 7 1 0 3 - 6 0 - 1 0 6 - 4 4 - 6 2 1 - 6 4 - 6 7 - 7 2 - 1 ' JCI. 1 — . '1 .... -1 ,1 ...._ ./ -1 5— -7 — - •• - F-' tl e n (iJ il. - - - P y I" 1 d i n e b ii. iii ( 2 - C tl 1 o I' o e t t i y l ) E t tie r — 2 - C I'l 1 CO r CO p h e n o l 1 , 3 — D i Ci t i l CO i"(ij toen z e n e - 1,4—D i c tl J. o r o b e n z e n e - - - - - :l , 2 - D ii. Ci tl ]. CO I" o Lo e n z e n e 2 - M e t h y ]. p ti e n (i> 1 - — 2 ^ 2 ' — o X y b i lii ( 1 — iii! ti 1 co i-- o p i' co p a n e ) . , , — 4 - M e t h y l p h e n o l __ - - t-l-l-l ii L r (ioiiico-D ii. —n -F" rco p y l aiii ii. n e - - i-1 CO X a c h 1 (j 1" (io e L ti A n o — —t-l ii. LI - CO lio CO n z e l'i e — il. s'iii'P'tl CO I" (io ri (io - 2 - t - l i trcoptuo'ncol 2 , 4 - D ii. Ill e L tl y il. p ri e n (io il. _ - to i s ( 2 - C 111 CO r coe L hco x y ) t'ie t tian e . . . - 2 , 4 - D ii. c l"i 1 o r' (j p l'i e n (io 1 - — - :1 , , 2 , 4 -- T i-' ii. Ci tl il. CO I" CO to e n z e n e _ tJa|ioi'l LI'la 1 e n e -- 4 —Ctiii.corcoan ii il. ii n e . - - - l-i e X a Ci tl il. 1 io I'' o to u 'L a (ii i e n e - - 4 - C t i i l coi''rj--3-rMe'Ltiyil.ptienoI"""II!'ZI • - - 2 -!'• 1 CO L I'l y ii. n a p 1'11 l'i a ]. e n e 7 7 — 4 7 — 4 Fi e X a ci ti 1 (io i" co c'/ ci il. o p e n 'L a ci ii. e n e 3 3 - 0 6 - 2 -2 , 4 , 6 - T i - i c h l (iorijp tien (iol 9 5 - 9 5 - 4 - 7:, 4 , 5 - 7 7 - 1 chlcorcopherKiol 9:1. - - 5 c-—7— —2 - - C i'l ii. CO I" (io I'l a p I'l L i'l a il. e n e & B - 7 4 - 4 - 2 - - i-l ii L r co a n ii. it ii. n e :l. 3 :l. - - 'L :l. - 3 D ii. me L i'i v71. I-' ti t h a 1 a t e [ ZZ...Z.. 2 O B - 9 .-A — 3 - A Ci e I'l a p i'i L11 v71. e n co 60.-:'-, -7:0- - 2 - 7:,, 6 — D ii. n ii. L r (io A(io 11..(ei'i e '-:-'"7'- (i'9 —7: — - 3--i'-lii Li-c.ian ii, ], ii nc' F'GRLi I 3 v - l ~/.-.7;.... I-,'-.:;..... 1 .—.,—. —.' r; i:; .'.-.-..z...-" ... ....--- 10 5 - 6 7 - 9 - 1 1 1 - 9 1 - 1 - 1 2 0 - 3 3 - 2 - 1 2 0 - 3 2 - 1 - 9 1 - 2 0 - 3 1 0 6 4 7 - 3 - 3 7 - 6 3 - 3 i : - , • : " ' . . . . ' : : ; - , . . . . — . ' (—1 . ' i ; : - - • , ' / J . - --1 / --(::• 380 3 '3 '^' 380 380 330 380 3 'ci' '0 ri (!) 3 8 0 ; U 3 3 0 ; U :u 3 8 0 3 8 0 ; u 3 8 0 ; u 380 ; u 1 C.I ; l-J ; u ;u ; LJ ; Ll : LJ I ' t 3 3 0 3L)0 3 8 0 3 3 0 •.i:"-'(...' 3 3 0 cii 3 0 3 3 0 9 3 0 3«iJ0 9 3 0 3 3 0 3 3 0 ;u 1 i 1 ;LJ3 ! LJ 1 LJ ILJ ; LJ 3 ! I.J : 11 : 1 t 1 ' • " • 1 l-J ; i : ! LJ ; o j 302842 u ^ u "^ I D '< ^/..... .J. vi.>t_r-i , x l - c L.ir«.OHlNXUt> Hf-IHU T t i X t i L>fi I A S H E E C Lab Name: ETC/GULF SOUTH Contract: Lab Code: GULF Case Ho.z HLA SAS No.: ,1atrix: (soil/water) SOIL Sample wt/vol: 30.0 (g/mL) G Level: (low/med) LOUl r-.; Moisture: .1.4 decanted: (Y/N) !;i_... Concen'trated Extract Volume: 500 .0 (uL) In.'i (00c tion Vo 1 umco: . 2.-.0[(uL-) GF'C Cleanup: (Y/N) Y pH: ...8.:^8 CAS NO. COMPOUND D41416 SDG No.: 95020 Lab Sample ID: VTF007 Lab File ID: SVVTF07 Da te Received: 0..L/3()_./9 5 Date Extracted: 02/03/9.5 Date Analyzed: 02^4./9;;i, D i it u t. :i. o n F a c t o r : 1 „ 0 CONCENTRATION UNITS: (ug /1.. o 1" ug / Kg ) UG./..KG 8 3 - 3 2 - 9 — O J. "" ^t'l <-*"~ O ~" 1 0 0 - 0 2 - 7 — 1 3 2 - 6 4 - 9 — 1 2 1 - 1 4 - 2 8 4 - 6 6 - 2 7 0 0 5 - 7 2 - 3 - 8 6 - 7 3 - 7 - 1 0 0 - 0 1 - 6 — 5 3 4 - 5 2 - 1 — fi &>—3 C' - tJ 1 0 1 - 5 5 - 3 — 1 1 8 - 7 4 - 1 — 8 7 - 3 6 - 5 8 5 - 0 1 - 3 .L .<:.(.,'— I . i l . - / — C . t , - / '•h — C.. 3 4 . . - 7 4 - 2 2 0 6 - 4 4 - 0 — 1 2 9 - 0 0 - 0 - - 8 5 - 6 3 - 7 - - 9 1 - 9 4 - 1 5 6 - 5 5 - 3 - 2 1 8 - 0 1 - 9 — 1 1 7 - 8 1 - 7 — 1 1 7 - 8 4 - 0 2 0 5 - 9 9 - 2 — 2 0 7 - 0 8 - 9 — 5 0 - 3 2 - 3 1 9 3 - 3 9 - 5 5 3 - 7 0 - 3 - 1 9 1 - 2 4 - 2 — A cen a p Li t tie^n e. _ 2 , 4 - D i n i t r o p htcn (j 1 : 4 ~ N i t r CO [io ti co n o 1 Di tac^n z o f u r-?.n _ _ 2 , 4 - D i n i ' L r c o t c o l u e n e _ . . . D i e t ll y 1 p h L ti a 1 a L e _. 4 - C tl 1 o r o p tien y 1 - p tien y 1 e L tie r. F l u o r e n e 4 - N i t r o a n i 1 i n e 4 , 6 - D i n i t i'-iO-2-Mco t tv/]. phiion(J 1. N - N i t rcosod ii. p t i e n y l a m i i . n e ( 1 ) 4-BroiiKiopi-ieny 1 -pI'lei'iy 1 e Ltiei" _. r i e x a c t i l c o r o toen z e n e F'ooori "La c ti 1 co r co p IK-OOI i co 1 F" tl e n a n t h r' e n e — A n t ll i-- a I ii e n e._ £,A. r b a z Cil 1 co. Di-n-Butylphthalate F l u o r a n t t i e n e F" y r' e n e . B u t y l bcon z y l p h t i ' i a l a t e . . 3 , 3 ' —iDi c|-iloi-<i)li)iOiori z ri.iil ii.nco _. E:en z o ( a ) An t ti!"a cicoonz;;_ C I'l r y s (i? n c? . b i s ( 2 ~ E t h y l h e x y l ) P h t h a l a t e . D i - n - 0 c t y l P b t h a ii. a Le - — B e n z o ( to) F' 1 i.i.oran Lti«-ionco. Ben z o ( V.) F 1 uco r a n Lhen e _ Ben zco ( a ) F'yrconco In(i)enco( 1 , 2 , 3 - c ( i ! ) F ' y r e n e D i b e n z ( a , ti) An t h r a c e n c o Eenz(io(q , h , i i F ' e r y l e n e 330 930 93'0 3'BO 3 8 0 3 8 0 7>'7JO 9 3 0 9 3 0 3 8 0 3 3 0 3 8 0 9 3 0 3 3 0 3 3 0 3 8 0 3 3 0 i380 C^o'^..' 380 330 380 380 330 330 3PO ' x > Cani'KiO'L o e Sl e p a r a t e ( i ! •fr'iom Dii. p tien y l a m ii.ne r-QRM I 8 V - 2 L-! LJ U 3 :.J 3 LJ LJ U LJ LJ '-.1:1 U 3 U U 11 ua LJ LJ 1 1 ..) 11 11 n 9 n /11 -r 302843 ti - , / • / ' J >. vwi_i-i .-i_i_ uir\.i->i-iin±'oc> t-il-iML. I O X S i/H I f-1 iDLltt. I TENTATIVELY IDENTIFIED COMPOUNDS Lab Name: ETC/GULF SOUTH Contract: Lab Code: GULP Case No.: HL.^.A SAS No.: Matrix: (soi1/wa ter) SOU- Samf) 1 e wt/vol: . .30.0 ( g/mL) G^ Level: (low./me(ii) L.QW_ "; Moisture: 1.4 decanted: (Y/N) t-L C o ri c e n t r a t e d E x t r a c t V o 1 u in 'e : 5 O 0;.. 0 ( ui!._) ili n .i CO c t i on Vo it umeo: ^_"..0 (uL_) GPC C l e a n u p : ( Y / N ) Y _ pl-l: JLi.iB D41416 SDG No.: 95020 Lab Sample ID: Lab File ID: VTF007 SVVTFjCyZ Date R(-?ceived: 0jl./.30./9j7 Date Extracted: 02/03/95 Date Analyzed: 02./24/9J7 Dili.rLion Factor: 1.0 N u m lij CO 1 - T I C s -f o i..\ ri d : CONCENTRATION UNITS: (ug/L or ug/Kg) y.G_/i;.!<.G. CAS NUMBER COMF'OUND NAME KETOLIE UNl-;l-JOWN Ai'i I D E UNKNOWN A M I D E Q rf/?/'...y:./-- JKJ j y -f'lR: SV-TIC /-• r\ r\ J ^ O 3 / 9 0 302844 w^ u. «.^ A'l t ( i-i v.>r tk-L. I D420: Lab Name: ETC/GULF SOUTH Contract: Lab Code: GULF Case No.: HLA SAS No.: SDG No.: 95020 Ttatrix: (soil/water) SGTL. S a m pie wt/vol: ...3.^?_.i.P. (Q / n^ I--) G L. o \> e l : ( l o w / m (io d ) !:-.Q.W. ".i Moisture: 1,5 decanted: (Y/N) N Coi"i c e n 11'' a L(ed 17. x t r a c t V o 1 ti.mo : 5 0 0 • O ( uL ) I n j eci'Lii. con V c o l u m e : 2 . 0 ( u L . ) GPC C l e a n u p : ( Y / N ) Y p H : .Ji?..::.3 CAS NG. COMPOUND Lab Sample ID: yj.F003. Lab File ID: SVVTF03 Date R e c e i V e c j: 01/3 0,/ 9 5 Date Extracted: 02/03/.95 Date Analyzed: 02.A2A/9.A. D11 u t i on F" A c Lo i-": .1... 0 CONCEt-ITR AT I Ot-I UN I T S : (u g./!_ o I - u g /Kg) U G./.K G 1 0 8 - 9 5 - 1 1 0 - 3 6 - 1 1 1 - 4 4 - 9 5-57-;ii -..1' -; .i. — / ,.>- 1 0 6 - 4 6 - 9 5 - 5 0 - : 9 5-43-!: :!. (il3-6^i>- 1 0 6 - 4 4 - 62:: -64- .*-.'..— -1 .,'1 ., .1. -7 — . "I .5 --' !(.'5-67-9 1 1 1 - 9 1 - 1 120 3 3 - 2 1(0/:.-'.;/-H- 8 / -6!!? -3 5 ' 7 - - 5 0 - 7 -/ 1 — > . ' . ' —'-> i:.-.z.}-y.}..-t—- A.. r\ 1- o I -/ .1. — ...I.::' - / 8 3 - 7 4 - 4 - 1 3 1 - 1 1 - 3 - F-' 11 e n o 1 - - F' y r • i (J ii. 11 e _ — - - to i s ( 2 - C tl 1 o I-oe t t i y l ) E t tie r - 2 - C i'l I (io r 0 p i"i e n o 1 1 , 3—Di ci I'll COi--(i)toen z e n e 1 , 4 - D i c h l o r ( j i i o e n z e n e _ - 1 . , 2 - D i c h l o r o b e n z e n e 2 -M e "L l'i y 1 p h e I'l o ii. 2 ., 2 ' -(io X y b ii. s ( :1. - C ti 101--co p 1"co p a n e ) — —4-Methylphenol --- N - N ii. 11" cosci-D i - n - P rco p y l am i n e - I-1 e X a c tl 1 0 r o e L h a n e 1-1 il. 'L i' CO lio e n z e n e . _ - il. --ii CO |io tl (io r (io n e - 2 - N ii. LI" CO p h e n (io ]. 2 , 4 - L> ii. m e 'L i'l y il. p ti e n (j it b i s ( 2 - C t i l c o i " c o e t h c o x y ) L i e t t i a n e 2 ,, 4 - D i c;l'i 1 (j i-"(io p i'leri (io 1 :i. , 2 , 4 - T r i (iitiil.coi-"cotoeri z e n e i'-l a p tl t tl <:<. ii. e i'i e 4 - C! 11 il. (io I" (io a n i il. ii. n e —i-I e X a c i'l il. (io r (io 1J 1.1 L a (il ii. e n e - 4 -- Ci; tl ii. (iil I" 0-- 3 - M e t t i y il. p tien (io 1 2 -1' i e L tl y ii. n a p I'l t tl a 1 e n e ••- - t! (io X a Ci 11 il. 01 •" o c y c: il. (j p e n L a cl i. e n e -—2 , 4 ,6—T I" i c: h 1 o i-o p h e i i o 1 - 2 , 4 , 5 - T r i c ti il. 01 - o p ti e n co ]. 2•-Li: ll ]. (io I"(iori a p tl t h a ii. e n e 2—I'-lii, Lr'coan il 1 i i ' i e .c:,'.,0(:>-- -/ •:::. — (::' ."'-,('0 ..-••.--''.'• I ' V - . . :.'-'• — Dii.metLi'/ii. P b t h a ] . a Le — A (ii CO I'l -Al p l'i L tl'-/ -i. (io n CO — 2 ,6—D i. n i L1-0 "L(io ii. u e n co 3—Nii. 'Lr'co.::'.n i il. ii. i":e ^) .J: X,[ 9 0 90 90 •i-y'O -J:- -."'-...' •.'-y-?c> • Q ^ 1 sv-:i. i-.i 3 9 0 ! U --5'9C' '1 Li 3 9 0 ; U -••?•::•.'-•. I > ' 3 9 0 ; u 3 9 0 ! LJ 7>90 ; LJ 3 9 0 ; u 3 9 0 ; LJ 3 9 0 ; LJ ^:. -X '-..-I , •...! — •::> /--, ;u ( I I ; LJ 3 • I i t — ; LJ '1 LJ 390 ',u:! 390 390 390 390 3 9 0 ;'...} 9.40 ; LJ 3 9 0 ; u 9 4 0 ; LJ 3 9 0 ; u 3 9 0 ; L,i 3 9 0 ; LJ 9 4 0 ; LJJ r . n n A or. 302845 OCIIJ-VUL-H I J-L-Ul UKL3HNJ.UO HINHL-T^DX^ U H I H iaMlr.tu I D4202: Lab Name: ETC/GULF SOUTH Contract: Lab Code: GULF Case No.: HLA SAS No.: .latrix: (soil/water) SOIL Sample wt/vol: 30.0 (g/mL) G Level: (low/med) LQiiL. :.' Moisture: 15, decanted: (Y/N) N Concentrated Extract Volume: 5LOO..,_0 (uL) Ini<JCtion Volume: 2..Jl\(^'1-) GPC Cleanup: (Y/N) Y pHu ..8.;iii> CAS NO. COMPOUND SDG No.: 95020 Lata Sample ID: VTF008 Lab File ID: SVVTF03 Date Received: O.J:./3ji7/9.5 Date Extracted: 02/03/95 Date Analyzed: 02/2.4/9 5 Dilu'Lion Factor: :i. .'D CONCEl-ITR AT I ON UN ITS: (u g A I. a r u g /1< g ) UG/KG A c e n a p ti L tien eo 5 1 - 2 8 - 5 — 2 , 4 ~ D i n i t r o p h e n o l . . . 1 0 0 - 0 2 - 7 4 - N i t r o p h e n o l . . . 1 3 2 - 6 4 - 9 D i b e n z o f u r a n . . . . . . 1 2 1 - 1 4 - 2 2., 4 - D ii. n ii. t. r o L co il. cv e n e 84-66-2 Diethylphthalate 7 0 0 5 - 7:2 - 3 4 - C111 co i" (io jio ti e n ' / 1 - p t i e n y 1 '2 'L ti e i" 86—73—7 F l u o r e n e . . 1 0 0 - 0 : t - 6 4-N;i. t r o a r i i 1 i n e ; 5 3 4 - 5 2 - 1 4 , 6 - D i n i t r o - 2 - M e t h y i p h e n o l . . . 8 6 - - 3 (!.) - 6 — - t-1 - l-I J. L I" CO iii o d i p ti e n ' / l a m :i. ri co ( :t ) 1 1 8 - 7 4 - 1 8 5 - 0 1 - 3 1 2 0 - 1 2 - 7 8 6 - 7 4 - 3 - P,a-'7<-:>--'?-- -—4 -)ii! r o m o p LiCion'-/1 - p 11en •/1 e L tie i" —Fle X a Ci ti 1 (io rco toen z e n e —F'v?n 'La c h 1 o r o p ticon co 1 —F'tien a n Lti r e n e — A Tl L h i-- a c (io i-i CO - ~ C! a r li) a z CO il. e _ — D i-n-Butyl phthal ate '.' 2 0 6 - 4 4 - 0 - F ' l u o r a n t tien vio 1 2 9 - 0 0 -- 0 F' y 1" e n e 8 5 - 6 8 - 7 Bu'Lyil bei'i z y l p h t t i a l a t e 9 1 - 9 4 - 1 - 3 , 3 ' -Dii. c i'l 1 CO I" o to CO I'l z i(i' i n e 5 6 — 5 5 - 3 BGonzo( a ) An Lti r a c e n e 2 J. 3 - 0 1 - 9 - C tl I" y s e i-l e _ 1 1 7 - 8 : 1 - 7 — b i s ( 2 - E t t ^ y l h e i ^ i y l )F^ht tia l a t e . . 1 1 7 - f iJ 4 - 0 D ii. - n - (i) (ii t y 1 F' h t i'i a ii. a L e 2 0 5 - 9 9 - 2 - B e n z o ( b )1-1 u o r a n L t i e n e . 2(!)7-0(ii. -9 B e n z o ( k ) F 1 i..i(ioran L l i o n e 5 0 - 3 2 - 8 — - - B e n z o ( a ) P y r e r i e . . . _ 17'3—...'•'-/— 5i • .Ln cien CO ( 1., '2,3— cici ) I '-/rei-ico.. 5 3 - 7 0 - 3 - 1 9 1 - 2 4 - - 2 — -Dii. toen z ( a , ti) An 'Ltu-a.iiiei'ie. -Ben z(io (i.ii , h , i ) Pzxry il.ei'ie (i'.l - L;.ii^l'1^(io L liiC\- s e jio-A I "a'Lco(il -i-i-"cofii Dii. |J! i(iO:-iy l a i n ii.ne i L.l I'.. I I J. •::•',' — ;:. Q 3 9 0 9 4 0 9 4 0 3 9 0 3 9 0 3 9 0 3 9 0 3 9 0 9 4 0 9 4 0 390 390 940 390 Z.-f ' - i - 3 9 0 390 390 390 3 9 0 3 9 0 1 2 0 3 9 0 39';.ii 3 9 0 3 9 0 3 9 0 3 9 0 3 9 0 U U3 LJ3 U LJ LJ LJ LJ UJ LJ 3 ; 1 1.J LJ L) LJ L.l 3 3 J :..J IJ 1 i 1 1 LJ LJ LJ LJ LJ LJ IJ i.J L) 1 1 t 1 t 1 1 1 ( t 1 ' ; 1 1 1 17 1 o R^ RU fa CKi, .LJ ' < f- > I -> 1 .-* 1 1 . • > ' c. cr ;' 302846 TENTATIVELY IDENTIFIED COMPOUNDS Lata Name: ETC/GULF SOUTH Contract: Lab Code: GULF Case No.: HLA SAS No.: Matrix: (soil/water) SO 11.- Sample wt/vol: 30.0 (g/mL) G Level: (low/med) LQUL_ :•: Moisture: ___J:.5. decanted: (Y/N) H Concern tra ted Extract Volumtco: 500 .0 (uL) I n .i e c t i on Vo 1 ume: 2.0 ( uL ) GPC Cleanup: (Y/N) Y pH: _.8..-j; D4202: SDG No.: 95020 Lata Sample ID: VTFOOS Lab File ID: SVVTFOS Date Received: QjL./:;0./95 Date Extracted: 02/03/95 Date Analyzed: 0£/24,/95 Dilution Factor: 1.0 N u m ta e r TICs f o u n ci CONCENTRATION UNITS: (ug/L or ug/Kg) LiG/.K.(j. CAS NUMBER COMPOUND NAME KETONE RT E S T . CONC. : Q , C!r?...v.-/.«.- y.a.n -T%ie e^-tA. KETOl'-lE LJNKNOWt-l AMIDE UNKNOWN UNKNOl/JN 7..45 1 3 . 4 2 1 8 , 5 2 2 4 . 0 5 2 0 ; AB J -Ur 4 . :JA/ 73 : J A / ,10 ; J A / -J CD O CZ cc C 302847 L a b N a m e : ETC/GI.JLF SOLITF-I L a b C o d e : GULF C a s e N o . : HLA M a t r i x : ( s o i 1 / w a t e i") SC) I L S a m p l e w t / v o l : ._3_Q..X?. ( g / m L ) G l_ e V (51: ( 1 o w / m co (il ) '^.SM "::. Moisture: _ _..7. decanted: (Y/N) N _.. Con cen t rated Ext r a c t Vo ]. ume: 500.-0 ( uL.) ili r 1 ji e c t ii. co n V o l u m e : Xi.-:.Q. ( u I...) GPC C l e a n u p : ( Y / N ) Y_. p H : ...5:.,.6 CAS NG. COMPOUND Con tract: SAS No.: ; F21215 I I _ . _ _ _„ - _ „ _ « „ SDG No.: 95020 Lab Sample ID: y$5;R002__. Lab File ID: SVV3R02 Date Received: 01/25/95 Date Extracted: 02/03/95 Date Analyzed: 02/24/9 5 D i il. (.(t iii CO n F" a (ii L o r ' : 1 . ri CONCENTRATION UNITS:; (u q / L o 1" ug/Kg) UG/KG XOQ-^'^t-Z— 1 1 0 - 3 6 - 1 — 1 1 1 - 4 4 - 4 — 9 5 - 5 7 - 8 5 4 1 - 7 3 - 1 - 1 0 6 - 4 6 - 7 9 5 5 0 - 1 - '.-./ '-,.... .-T ;->.... —'.._ "1 'DfV—60- :!. — 1 0 6 - 4 4 - 5 - (:>*:..) — o ' V " / f —,1 — J J—, J O . ' "• / X.. •" .1. 1 0 5 - 6 7 - 9 - 1 1 1 - 9 1 - 1 •• 'T' /"^.... '*"' "•* .... O 1.''>6---47--o-•" - r > •"•'.... / . < " • . . . . "•':" 5 9 - 5 0 - 7 - - 9 1 - 5 7 - 6 - 7 7 - 4 7 - 4 o.-.-.'..... f-". ..? '-.-I f"i i:; r-. i:: .'i -/ , . i — -,' -..I •' — - - F-' tl e n CO il... _ - F' y 1" i (j i n e - b i s ( 2 - C h i o r o e t h y il.) E t tie r - '2 - - iij l'i ii. CO I- CO p Ll (OO n c:i 1 • 1 ^ 3 - D ii. c tl 1 CO I" o to e n z e n e -1.14 -• D ii. (r. i'l il. o i - o !."o o ri zi (-"• n (ii' -1 ,2—Dii-Citil CO rco toen z e n e • — M ^ . - I - l•^•.,-^ Br:-74-4 1 3 1 - - 1 1 - 3 - 2 0 3 - 9 6 - 8 - 6 0 6 - 2 0 - 2 - 9 9 - ' : ' i ' v - 2 e t I'l y 1 p I'l e n CO 1 - 2 , 2 ' - o x y l i o i s ( l - C t i l o i - c o p r ( i o p a n e ) - 4 - rl e L tl y 1 p h e n co il. - N - t-l ii. t r CO Ci o—D ii. — n — F-' i'' (io po y il. a m ii. n e - Fl e x a c: 1"1.'. o r o e L l'i a n e -I'-l i L r CO toen z e n e .._ - 1 s o p I'Kio i-(jn e ~ 2 - L i i Li"op hen(io 1 - 2 , 4 - D i m e t h y l p h e n o l - t o i s ( 2 - C h l o r o e t h o x y ) L l e t h a n e . - 2 , 4 - D i (iil'ilorcophei'Kiol - :l. , 2 ,, 4 - - T I- ii. c tl it (io I" (io to e n z e n e -Lla |i) tl t h a il. e n co . - 4 - C h i corcoan i 1 i n e . - i-I e x -i^ (ii Ll ]. (iil I •• (io to (.I. L a (i: ii. e I'l e - • 4 - C i 1 il. (io i" (i) - 3 - f I e L tl yil, p l'i e n o ii, - 2 - M e t i'l'/ ii. n a |io l-i L i'i a il. e n e - t i e V a (ii tl it o I' CO c y Ci 1 o p e n Lad ii e n e - 2 , 4 ,, 6 - T i - i cl'il(ior(i)pheri(iol —7: ^ •'!', Ll—r |-ii. Ci tl .1. CO I "CO |ii ticon C.I .t —'2.—^... l'i .1. (io I "(ion .:Ti. jio ti 'L tia 1 (ion (oo - 2 - l ' - i i tr(io."in i 1 i n e - D il. (!ico Ll'v/l I-' i'l 'L l'i a 1 a 'Le _ - A (iien a p l'i 'L toy 1 e n co - 2 , 6 - D i n il. Ll "(io'tcoluei'ie.. - 3 - M i i t r f i i i a n i 1 ii.nco ..J . . I ' . . ' 3 5 0 3 5 0 CO-'i'^O 350 350 3 50 3 5 0 8 6 0 3 5 0 8 6 0 3 5 0 3 5 0 3 5 0 7'AC' L' 3 50 350 350 350 350 350 350 I u 'iU I LJ ;u ;u ;u ; l-J iiO : 1.J ILiO- ;u :'-' ; LJ ' ! [ I u '; I 1 i-J ; LJ ; LJ 3 1 LJ 1 1 1 1'-' iU3 1 '—' ; LJ 1 ' • • ' 1 1 1 1'-..' ; 'i..j 1 1 1 1 t 1 *. 1 F"OI-;:i'i I S V - l ) / y r -, 302848 v.jL-1 I a. v(.ji_i~t I j.i_c. i-ir'.ui-tiMXL^CJ Miit-ii_. I OX.-J i-'fi I I-l srict:. I F21215 Lab Name: ETC/GULF SOUTH Contract: Lab Code: GULF • Case No.: HLA SAS No.: Matrix: (soil/water) SOIL Sample wt/vol: 30.0 (cj/mL) G Level: (low/mted) LOUl r: Mo i s tu re: 7. d e c^in ted : (YZH) N C o n e e n 11--a t o d Ex t r a c t V(io 1 urne: 5iC>0.j,._0. ( uI...) I n ji (-00 c t i on V o 1 umco: "iX-O. (^-^l- ) GPC Cleanup: (Y/N) Y pH: _.5.;i.ii CAS NO. COMPOUND SDG No.: 95020 Lab Sample ID: yj5R002_ Lab File ID: SVySr702._ Date Received: 01/25/91' Date Extracted: 0 2/£3 / 9 5; Date Analyzed: 02/24,/9 5, D ii. il.u t i on Fac'to i" : 'J. . C CONCENTF;; AT ION UN ITS : (ug/L or ug/Kq) IJiVKG -A c e n a p ti t t i e n e 5 1 - 2 8 - 5 2 , 4 ~ D i n i t r o p h e n o l 1 0 0 - 0 2 - 7 - - 4 - !••! i t r o p h e n co il. 17')2 - 6 4 - 9 - — D ii. l;o e n z o'f u r an 1 2 1 - 1 4 - 2 - 2 , 4 - D i n i t r o t o 1 u e n e . . _ 8 4 - 6 6 - 2 D i e t h y l p h t h a 1 a t e . . . 7 0 0 5 - 7 2 - 3 4 - C h l o r o p h e n y l ~ p t i e n y l e t h e r . o 6 — 7 3 - 7 — -—i~ 1 u (Cl r co n o _ 1 0 0 - 0 1 - 6 4 ••" N ii. 11 - o a n i 1 i n e 5 3 4 - 5 2 - 1 4 ,, 6 - D ii. ri i t r o - 2 - M e ••:. i'i';•' 1 p l-ienc-1 8':f)-30-6 N - N i t r o s o d i fo h e n ' / I a m i nco ( 1 ). 10:1. - 5 5 - 3 4 - B. I" CJ 111 (iil p h e n -/1 - p Li (-io 11 y il. e L ti e r._. ' .1. — o 1 2 0 - 1 2 - 3 6 - 7 4 - 8 ( j ' - i - / ' . T - 7 — 1- con La (- I'l .1. o r o |io neon (io .i. . F - ' t i e r i a r i L h r e n e _ _ - A n t l'i I" a c e II e - - C a r t o a z o l e ^ 4 - 7 4 - 2 — - D i - n - B u t y l p l ' i t i - i a i i a t e 2 0 6 - 4 4 - 0 - F l u o r a n t h e n e 1 2 9 -0(io - -0 F'y i"ene 3 5 - 6 3 - 7 B u t y l b e n z y l p h t h a l a t e 9 1 - 9 4 - 1 - - 3 , 3 ' - D ii. (ii l'i 1 (ij I" o li) e n z i (ii i n e _ 5 6 - 5 5 - 3 - - - - B e n z c o ( a ) An t t i r a c e n e 2 1 8 - 0 1 - 9 — - C h r y s e n e ....L..Z ^1......" 1 1 7 - 8 1 - 7 - b i s ( 2 - E t h y i h e x y l ) Pti t h a T a t ( s H . . 1 1 7 - 8 4 - 0 D ii. - n - 0 (ii Ly il. P b t tia 1 a t e 2 0 5 - 9 9 - 2 - - - - B e r i z o ( lio)F"lu(ioranLLierie 207—C''.ii —9 - - li-i'ioii'ii z o (li) i - ' l u o r a n 'Lli(ioi"ie 5 0 — 3 2 - 3 - - B e n z o ( a ) F ' y r e n e 1 9 3 — 3 9 - 5 ]! n (il e n (io ( 1 , 2 , 3 - c (il ) F' y r'e n e 1 9 1 - 2 4 - 2 - -—Ben z (io ( g , h , i ) l-'e i"y 1 e n e L.i.;(i'ii'i(iO'L Loe sepai".^-.. Led 'f'i''(i)m D i i . p t i e n y l a f H i L n e r L.l 1'..I I J. .-.',• — .:;. 860 350 350 350 350 A,AO 3 5 0 L>60 3 5 0 3 5 0 I j - 7 ' TA .-> ^.' 350 350 350 350 350 350 Z).:i'-j 0 350 ;u 860 ;U 3 ;u3 ;u :u : 11 ;u3 :U:J ; i-J ; u ;u I t t : u ; LJ 3 ', LJ I I I 1 '--I ; LJ 1 1 1 1 ' - ' ; u ;u ^o ;u 3 5 0 ;Li ~;:'i(o ' i 1 302849 0204B2 1U.J- 3 5 0 5 3 3 5 0 3 5 0 350 ---'^•..'•-1 ;u 1 71 ;u '. 1.) ;u 1 1 1 Livs^ a ^ ^ M -U < i > 1 v o u . v.^«„i I I j,*_i_ *-^i\t_»ru-t J. ws-> r - i n n i _ i t-j x >.j x / r - \ i i i or'n::.EL I TENTATIVELY IDENTIFIED COMPOUNDS Lab Name: ETC/GULF SOUTH Contract: Lab Code: GULF Case No.: HL.J1. SAS No.: Matrix: (soil/water) SOIL Sample wt/vol: 30. 0 (g/mL) G. 1_ e V e 1: (1 o w / m e (ii) !=0 W r-- Moisture: _ 7 decanted: (Y/N) N __ F21215 SDG No.: 95020 Concentrated Extract Vc)lume: 500 .0 (uL) ili n .i CO c t ii. on Vo it umco: ^2 ,.0 ( u!...) GPC Cleanup: (Y/N) Y pH: ._.5...6 Lata Sample ID: yS.R.g;;)2. Lab File ID: SVVSR02 Date R e c e i V e (j : 0_1./L2.5./_9 5 Date Extracted: 02/03/95 Date Anal'/zed: QI7/2.4./.9..5. D i ]. u t i on Fa c to i- : 1 . 0 I'-l u m ta (•:• r T I C s f o u ri d CONCENTRATION U N I T S : ( u g / L . o r u g / K g ) UG/K]3 CAS NUMBER COMF'OUND NAME KETOL, RT EST- CONC. ; Q , C7IT...'C.'.''.^ , I i.'..i'-i ( I ..-' 1..' KETni-.i!; 4. UNKNOWN AMIDE UNKNOWN AMIDE :l. 8 . 4 5 22 ..02 22(0 6 2 0 ; JA/ ; JA/ 1- L.l lv i'l .li '.•-;V-T I C CD Q l 302850 0204^:3 S b u M I V O L i - i f l L e ORGANICS A N A L Y S I S DATA SHEET F 2 1 8 2 0 Lata N a m e : E T C / G U L F SOUTH L a b C o d e : GULF C a s e N o . HLA C o n t r a c t : 5AS N o . : SDG N o . : 9 5 0 2 0 M a t r i x : ( s o i l / w a t e r ) S O I L SJampjle w t / v o l : 3 0 . 0 ( g / m L ) G L e v e 1 : ( l o w / m e d ) LOW •:-:. M o i s t u r e : 1.4 d e c a n t e d : ( Y / N ) H C o n c e n t r a t e d E x t r a c t V o l umco: 5 0 0 - 0 . ( u L ili I'l ji (Oi' Ci t J. CO n V o il. u m e ;; 2 . 0 ( u I...) GPC C l e a n u p : ( Y / N ) Y p H : ..ZJIJQ: CAS N O . COMPOUND Lata S a m p l e I D : V 3 R 0 0 3 Lata F i l e I D : SVVSi-<03 D a t e R e c e i v e d : 0 1 / 2 5 / 9 ! : D a t e E x t r a c t e d : 0 2 / j 0 3 / 9 5 Da t e An -, il y r eH :: 02,£24 "'95 D i 1 u t i o n F a c t co i - : CONCENTRATION U N I T S : ( u g / L o r u g / K g ) U G / K G 1 . 0 li) 1 0 8 - 9 5 - 2 — P h e n o l . . . _ 1 1 0 - 3 6 - 1 P y r i d i n e 1 1 1 - 4 4 - 4 b i s ( 2 - C L 9 5 - 5 7 - 3 2 - ii: Ll 1 o i-' c 5 4 1 - 7 3 - 1 1 .,3-Di ct 1 0 6 - 4 6 - 7 1 ^4-D:i.c 9 5 - 5 0 - 1 - - 9 5 - 4 3 - 7 :l 0 3 - 6 0 - 1 1 0 6 - 4 4 - 5 - 11 o I" o CO L t l ' / 1 ) Ei t h e r p h e n (i) il. . _ 1 cor CO b e n z e n e l o r o b e n z e n e 1 , 2 - D ii. c tl 1 CO I--0 toen z f;ori o 2—I'l e t l'i'-/1 p l'i 'OiO n o .1.._ 2;, 2.' -co X y to 'j. Iii (:l. —C ti it co rco pi i" co pian eo).. 4 - M e -L h y 1 p ii e n (io 1 6 2 1 - 6 4 - 7 - / . • " • ' . . . . ' " / ' ' . " • . . . . •• c-. .•••. r ; tv. •-.•' •y r-. •• • 7 . . . t — \ . > 7 3 - 5 9 - 1 ... -j -1 .—I -1 .1 .1 . L . 1 . - ;•- . 1 , . 1 . :!. 2 (..>-•":; .ir-7: 9 :i. —20--3 — 1 0 6 - 4 p. -/.-... .<-., ;::> 59.-. ^ , 0 - 7 9 1 - 5 7 - 6 7 7 - 4 7 - 4 8 3 - 0 6 - 2 / --(:.. 1-1—Ll ii. 11" o s o ~ D i — n—F' r 0 pi'/1 a m ii. n co I-l (j X a (i: tl 1 (J 1-- o Ci 111 a n (oo N j t r o toen z e n e . . . 1 s (io p I'l (J r o n e 2 - N i t r o p t i e n o l _ 2 , 4 - D i i . m e L l i y l p i ' i e n i i o l LJ ii. -i:- (2-C;!'11 o r (io e 'L ti o x y ) i'l e 'L11 a n e 2 ,'--1-—L' ii. Ci l'i J. (.01" CJ I'j i'i CO n CO ]. - - 1 , 2 , 4 - TI" ii c tl il. CO I-" (io to e n z e n e i'-l a p h 'L tl a ]. e !'1 e - - 4 - (i! I'l ii. I io r' o -LU'I ii. il. ii. r 1 e l-lexacl'iil.(ioi--('ot)i.i.'La(il ii, e n e 4 - (i; i'l il. o 1" CO—3—i' i e 'L i'l y ii. p i'i e n (io il.. • - — 2 - M e L h ' / ]. n a lio h t h a 1 e n e Fie X a c t i l co 1 "O ci'/ci 1 co [ioeri Laiil i e n e . — 7: , '-V , •:':'— I I" ii. (-I'll iiO;-"iiiO|iii i'lCOi'i (iil 1 _ 9 5 - 9 5 -1 - - - - 2 , 4 , 5 - 1 ' i-" ii. Ci ti il. • io r o p ii o n co ii.. 9 1 - 5 8 - 7 - - - 2 - C tl 1 o r o n a p 111 halene....... 3 3 - 7 4 - ••: 2 - i-1 i 'L r (io a n ii. il. ii, n e 131 - 1 :l. - 3 —D i 1 n e t h y 1 P b t b a i a L e .::(..'8 — '•;' r... — 'r.:. — A C e n a p \"i 'L tl'-/'.1. COn -i-OO_ _ __ 6 0 6 - • 2 0 - 2 2 ., 6 — D ii. ri ii. L r o L co 11..1 co n e 9 9 - 0 9 - 7 : - - 3 - - M i trciiari :i. 1 inco FORM iii S'A- 3 8 0 ; u 3 8 0 ; u ; LJ :u ; u ;u ;u w><;:;i-..' 380 380 ~~ Ao 330 330 7>30' 380 380 380 380 ZZ<:...o 330 330 330 Zj'.A.'..: 330 • T ' r : ,-•••, 930 380 930 330 380 330 ; LJ :u I I I • I..." ' I I I l.J I I I I ' - ' 3 3 0 :11 ', LJ ;u ;u LJ U 3 3 0 ; u 3 .ii3(.!' ' LJ 11 ;u ; LJ ' u :u 302851 0k:U4bJ bti-riiVULA. xLE ORGANICS ANALYSIS DATA SHEET F21820 Lata Name: ETC/GULF SOUTH Lab Code: GUL7F Case No.: FILA Matrix: (soil/water) SOIL S a (fl p ]. e w t / vol: 30 .0 (g / m L ) G. Level: (low/med) LOlO :':. Moisture: IJi, decanted: (Y/N) N Concentrated Extract Volume: 500.0 (uL) In.i octic^on V(io 1 u m c o : £D_"...Q.(i'l~ ) GPC C l e a n u p : ( Y / N ) Y p H : 7 . 0 CAS NO- COMPOUND C o n t r a c t : No, SDG N o . : 9 5 0 2 0 Lata S a m p l e I D : y 3 . R 0 0 3 L a b F i l e I D : GVySr!;03_.... D a t e R e < : e i v e d : 0.1^;2.5/.95 D a t e E x t r a c t e d : 0 2 / 0 3 / 9 5 D a t e A n a l y z e d : 0 2 / 2 4 / ^ S Iio :i. 1 u t it CO I'l F a ci t co i - : :1.. < COLiCENTRATION U N I T S : ( u g / L Ol" u g / K g ) UjEi/JiG 8!3-377-9 A cconaph t t i e n e 1 0 0 - 0 2 - 7 — 1 3 2 - 6 4 - 9 — 1 2 1 - 1 4 - 2 8 4 - 6 6 - 2 7C>05-72-3- 3 6 - 7 3 - 7 — 1 0 0 - 0 1 - 6 2 , 4 - D i n i t r o p ht^n o 1 4 - IM ii. t r o p tl CO n o 1 D ii. b e n z co -f u i'- a n 2 , 4 - D i n i t r ( j t c o l u e n e Dii. e t h y l p l i t h a ] . a t e - - 4 - C111 o I" o p ti e n y 1 - p i'i e n y il. e L ti e r. - — F 1 u(io r e n e_.. -- --'4-l'-l'.i. 'trc'jan i 1 i n e 5 3 4 - 5 2 - 1 — 3 6 - 3 0 - 6 1 0 1 - 5 5 - 3 1 1 8 - 7 4 - 1 — 8 7 3 5 12 8 6 3 4 2 0 12 - 3 6 - - 0 1 - r)-12 - 7 4 - - 7 4 - 6-4'-- 9 - 0 0 5 - -7 8 - '"^.... .<. -(!> --0 4 , 6 - - D ii. n i t r o - 2 - M e 'L l'i y 1 p ti e n co 1 . . —t-l—t-li 'ti"(jsoci i pitnoji'iylai'iiine ( 1 ).. — 4—BI-- o I'll (ij p I'l(io n y 1 — p h eon •/ ]. co L i'i(io i" Fl e X a c tl 1 o r CO to e n z e n e _ — 1 - ' (io Tl "L a o b 1 or' co |iii Li(io n (iii .1. F"' tl e n a n 'L to r e n e A n L h r a (n e 11 e L ! a r b a z o l e D i - n — B (.1 L y il. p i'i L |-i a il. a 'L e F it u (io I" a n L tl e I'l e . - F ' y r e n e - - B u t y l toen z y l p h t h a l a t e . 9 1 - 9 4 - 1 3 , 3 ' -Dii. c h l o r ( i j i i o e n z i d i n e 5 6 - 5 5 - 3 - - - — B e n z (io ( a ) A r i L l'i r' a Ci e n co 2 1 8 - 0 1 - 9 C h r y s e n e . . . _ _ . . . L Z I Z Z Z Z I 1 :t 7 - 8 1 - 7 - b ii. -i ( 2 - E t t i y l h e x y ] . ) P ti t tia il. a t e . . 1 1 7 - ci: 4 - 0 D ii. - n - 0 c L'/ ]. I-' i'i L Li a il. a L e 205—99—2 -- -••- B e n z o (lio) F'il.utioran L t i e n e 2 0 7 - 0 3 - 9 - —Bcon z(io ( k ) F l u ( i o r a n L h e n e 5 0 — 3 2 - 8 B e n z co ( a ) F-'yi"erie 1 9 3 - 3 7 - - 5 - In(iien(io ( 1 . , 2 ,3—c(il) F ' y r e n e . . . 57> - 7 0 - 3 - - Dii. toenz ( a., ti) A n • L t i i " a c e n e _ 1 9 : 1 - 2 4 - 2 Benz(io((3 , h , i ) F ' e r y l e n e ( :i. ) - L!an i'l (io'L toe sepa'-a'Le(il -frzxui D j . ptienyii. ai';iii. n e FORi-'i I 3 V - 2 3 8 0 9 3 0 9 3 0 :3 3 0' ( > 330 9~AQ> 7)I7\> 3 8 0 r% f t .' <.'.> 3 8 0 3 8 0 ^i);;:;.',.-' 3 3 0 :u ; l-J J \ u l :u 3 8 0 ; LJ 3 3 0 :u ; l-J : LJ ; '...'.n : L' 3 LJ J.J 3 11 3 3 0 ; Li 3 3 0 ; u 3 3 0 ; LJ 3 3 0 ; u 3 3 0 ; 11 ; J ;u ; LJ ; l-J 1 LJ :u : I..J 1 1 1 o^2 ^4 <i 302852 TENTATIVELY IDENTIFIED COMPOUNDS Lab Hame: ETC/GULF SOUTH Contract: Lab Code: GULF Case No.: HLA SAS No.: Matrix: (soil/water) SO.IJ__ Sample wt/vol: 30.0 (g/mL) G Level: (low/med) l_OW -.: Moisture: jv^ decanted: (Y/N) N Concentrated Extract Volumes .50.0..-.0 (uL) J! n _i eo c: t .i. (ion Vco 1 umco: ^2._..0 ( ul...) GPC Cleanup: (Y/N) Y pH: F21820 SDG No.: 95020 Lata Sample ID: yS!i003 Lab File ID: GVySROo Date Received: 01Z2^.ZXlX^. Date Extracted: 07:/.g3/.95 Date Analyzed: 0!2/24/9 5 D i 1 u t it CO n Factor; 1 .. O 7 _ O N u m 1J CO r T I C iii- f o u n cl CONCENTRATION U N I T S : ( u g / L o r u g / K g ) yG/J<G CAS NUMBER COMPOUND NAME KETOt' RT ; EST. ccNc. ' ri V-'o,- - t r ^ 7f« !ABJ M KETONE ALCOHOL ! ADJ \.JlJ . - I » : . OO Q UJ ^y CJ cc o FORM T S V - T I C 302853 3 / 9 0 bl;:.ri.tVOLAI ILL ORGAN I Co ANALYSIS DATA SHEET Lata Name: ETC/GULF SOUTH Contract: Lab Code: GLJLF Case No-: HLA SAS t-io.: Ma t r i X : (s-oi 1 /wa ter ) SO.ili.L S'-n'!iple wt/vol: 30. 0 (g/mL.) G I... o 'v e 1: (1 o w / m e d ) Li5.W :;; Moisture: 1.3 decanted: (Y/N) N CCOn c o n L i"a te(il E x t r a c t V o l um(io: 500.., ji) (uL) 1 n J e Ci t ii o n Vco ]. u m e : Z.=.7^ ('-'•^-) GPC Cleanup: (Y/N) Y. pH: .J3..;.2 F30001 SDG No.: 95020 Lata Sample ID: VSR004 Lab File ID: SVV3R04 Date Received: 01/25/95 Date Extracted: 0£/03/.95 Date An a 1 yz e(ii: 02/24/9:-i D ii. 1 u t il o n F" a ci t co r ;: :l. „ (!!' 10. COMPiJUND CONCENTRATION UNITS: ( u g / L o r u g / K g ) U G/..!:{.Li. 1 1 0 :i. :l, :!, 9 5 - 5 7 - 3 - 5 4 1 - 7 3 - : f. h e n o ii. _ • 1 — F-' y I" i (il i n e b i s ( 2 - C h l o r o e t h y l ) E t h e r . 2—Li: l'i 1 o I" (io p h e n o 1 — :l. , 3 - D i c tl 1 o rco toen z e n e . 106-46-7- - 1 , 4-Di chloroben zene 9 5 - 5 0 - 1 - - - 1 ., 2 - D i c t i l o r o b e n z e n e 9 5 - 4 ?i; - 7 - 2 - M e t l'i y ]. p ti e n o il. :1.03 --60-:i. - 2., 2 ' —oxyiijii-s (1—C t i l coro pi'(iOpane ).. 1 0 6 - 4 4 - 5 4 - M e L I-l y 1 p l'i e n c. ]. 6 7: :i. — 6 4 - 7 -— - t-l—1-1 i 't i-- co ^i o—D ii. — n - F" r o p y J. a m i n e 6 7 - - 7 2 - :i —i-! e X a (ii I'l 1 (io r Cl e "L i'l a n e . . 977-9 5-3-— — N i 'L rco toen z e n e . . . .1. iii (io p l'i (io r (io n e 2 - N ii. 'L r o p ti e i"i (io il. _ __ 2 , 4 -D i me L i'ly 1 p tlen CO 1 _ to ii. Iii ( 2 - C ll il. CO r (io e 'L ti co x y ) l'i e 'L ti a n e -• 2 , 4 — D ii. (ii tl 1 CO I" o p tl e n (io ]. .._ :1. ,, 2 , 4 —T r ii. Ci ri 1 o rcoiioen z e n e - - 1--I a p i'1 L tl a 1 e I-l e - —4 —Ctil coi-fioan ii-1 ii.ne -—l-iiiox a(iil'ilor(iobu'La(il ii.ene 4 - C1-1 il. CO I- iii, - 3 - Li e L ti y il. p ti e n (io il. - — 2 - M e t h y l n a p h t h a l e n e - — Fle X a Ci tl it zx r o (i:'/ ci il. co p e n L a d :i. e n e - 2 ., 4 , 6 - T r i c h l o r o p h e n o l _ - — - 2 , 4 , 5—T1" ii, Ci ti ii. (i) r' CO p tl e n (io 1 . 2—C tl ii. (io 1" CO n a p i'l L ti a il. e n e 2—Nii, Li'fioan ii. 1 ii.ne . - Dii m e t h y l P h t t i a l a t e . . -AciCi-n a pti'L riy 1 e n e _ _ . 6 O 6 - 2 0 -- 2 2 ., 6—D i n ii. 'L r (io L (io 1 u e I'l e 9'-;''- 0 9 -2 —- —3--L;ii, L r o a r i ii. il. ii.'-ie 10 5 - 6 7 - 9 1 1 1 - 9 1 - 1 .1. x:!'-..-' • " • < : : • • . ! : • • " " * : . 1 2 0 - 8 2 - 1 9 1 - 2 0 - 3 - 1 0 6 - 4 7 - 3 C.'.''"^ .... Z. ^.TJ ...."•'•'.... 5 9 - 5 0 - 7 - 9 1 - 5 7 - 6 - 7 7 - 4 7 - 4 - 3 3 - 0 6 - 2 - 9 5 - 9 5 - 4 - 9 1 - 5 3 - 7 - f", 1.....,.-.!. 2 O fii; -9 C> ;:;>'.-' 3 3 0 3 8 0 3 8 0 3 3 0 3 3 0 3 3 0 3 8 0 7>80 .... f.. 3i:>0 3 Li O 3 8 0 3 3 0 A. 3 0 3 8 0 Z)b>u 3 8 0 9 2 0 3 3 0 9 2 0 3 3 0 3 3 0 FORI''! I S V - l L-i I LJ •| tJ ! LJ : 1..J ', LJ ; l-J ; LJ :u ! LJ ! LJ 1 1 1 ! j ; u I ! t I •—' 1 LJ 330 730 330 .:••;.":•'•..-* ; u i ; LJ ; i.l 1 ' - 1 ; LJ 3 ; l-J ; Li 1 1 1 1 ( - I i.J <C ^ 920 ;ua 302854 \J£.\JU J i.. CjU-riJ.VUl_Fi I IL.t;. UKO(-ir-lJ.L-t> HI-li'-IL. T ;:>J. o i>H H i3l-IC:.l::. F30001 Lata Name: ETC/GULF SOUTH Lab Code: GULF Case No.: HLA Matrix: (soil /wa te r) SO.I L Sample wt/vol: _3>0.i.0. (g/mL) G Level: ( l(i)w/m(iod ) LOJiJ rv. Moisture: 13 decanted: (Y/N) N Contract: SAS No.: SDG N o . : 9 5 0 2 0 C o n c e n t r a teoiJ E x t r a (i: t Vco il. um'Oio: 5'00 . 0 ( u l - ) ili n J e c t i o n V o ]. unie : .2.-..0. (ul...) GPC Cleanup:; (Y/N) Y pl-i;; ....8.-.Z CAS NO. COI'iPOUND Lab Sample ID: yJ:;R004. Lab File ID: Syy3R04..... Date Received: 01./2.5/.9.5 i)a te EX11-aci Lecl : 02/03/95 Date Analyzed: 02/24,-795 D ii. ]. l.l. t i o n F" a c Lco i- : :1. . ( CONCENTRATION UNIT3: (u g / L- o I-- u g / K g ) Li (3 ./J< G > 2 - 9 - A c e n a pi ti t ti eo n o 8 3 i : -1 . , . r \ . - ^ j . . i - . „ 1 0 0 - 0 2 - 7 — 1 3 2 - 6 4 - 9 121-14-2—• 8 4 - 6 6 - 2 7 0 0 5 - 7 2 - 3 - r-, / ":"".v -7 <Ti..Al— .' ......-- A 1 0 0 - 0 1 - 6 4 - N i t r o a n i 1 i n e _ .._. 5 3 4 - 5 2 -• :L 4 ,, 6 - D ii. n ii. t r' CO - - 2 - i'l e L i'l y it p i'l e n (i 1 il. 8 6 - 3 0 - 6 --I'-l-t-li 'trcoscod i p h e n y l a m i n e ( 1 ) :l. 0 :l— 5 5 - 3 - 4 - B r o rn (io p h e n y it — p ll e n y il. e 't ti e i" — 2 , 4 - iD i n i t r o p ti o n o 1 — 4 - H i L r o p tien o l . - - • D ii. b e n z CO 'f u r a n - - 2 , 4 - D ii. n :L 't I" CO t O il. (.I e n e — D i e L h y l pti Lha 1 a t e 4 - C tl 1 o r o p h e n y i l - p tien y l e L tie r Fluoi-coriii-2 Fle X a (ii tl it o rco toen z e n e 1-'con 'L-:7'. Ci i'l I. (io i-(io |ii' l'i(-00I'l (io 1 . - F' tl e n a n L tl r e n e An't. tl r a (iie n e . Ca r toaii'i (io.:.'iio. D ii. — n — B i.( L y ii. p i'i L l'i a 1 a L e - F l u c o r a n L t i e n e 1 1 8 - 7 4 - 1 — 3 7 - 3 6 - 5 - 8 5 - 0 1 - 8 1 2 0 - 1 2 - 7 — 8 6 - 7 4 - 8 6 4 - 7 4 - 2 2 0 6 - 4 4 - 0 - 1 2 9 - 0 0 -0— 1"'yI"en co _ 8 5 —68—7 —Bu Ly 1 toen z y l p h L tia 1 a 'Le 9 1 --94 •-1 - - 3 , 3 ' - D ii. Ci tl 1 (iO i" (io io e n z ii. (il ii. n e 5 6 - 5 5 - 3 - - B e n z CO ( a ) An L ti i"a ciene 2 1 8 --• 0 :l. - - 9 lii! i'l I" y s e n e 1 :l. 7 - 8 : l . - 7 - to ii. -iii ( 2 - E : t t i y it tie x y 1 ) P Li L L,ail. a Le 1 1 7 - 8 4 - 0 - D i - I ' l - 0 r -Lyii. F' ti LI'la 1 a Le '_ 2 0 5 - 9 9 - 2 - - B e n z co ( to) F- il, u (io r a ri t ti e n e ...Z' " 2 (i> 7 - 0 3 •- 9 - - - B e n z CO ( k ) F 1 u (io i" a n L ti e n e 5 0—32—Li; - - iii; e n z CO ( a ) F-' y I'- e r I e 1 9 -.ii' - - .i> ----' -- Ll " .i. n (il (-001'I (io (. : l . , 7 : , ..i3 •- (ii (ii 11-' 'y' 1" c? :'i eo _ 5 A, -- 7 0 - 3— - D :i. Lo e n z ( a , ti) i-i n 'L '11" a ci e n e . 1 9 1 - 2 4 - 2 Ben zo ((;; ,, h ,, ii.) F ' e r y l e n e ..ZZZZZZ (:l. ) - (i!ann(iO'L toe iiiep-fAi-'a'Le(i! 'fi''(iom li'ii, p l i e n / l a i i i i r i c o 330 920 920 ; LJ ; LJ 3 ;u3 380 330 920 920 .i:'0'-.' 330 380 900 •^.Pn 1 '..J :u ;u3 n 1 • 1 •-•' 1 1 ) 1 '—' I t-J ; T « : ' ;u3 3;ii)0 7'30 330 490 3V:5 0 3 <•• "•'"' 330 720 ' 330 330 380 330 330 380 390 302855 \J { . . K J K J 1 i-J I ' i 1 l-J ! t-J ' 11 I '...' 1 ' • • ' ; u ! LJ ;u ; LJ 11-,-- ^ 0 G1 L L J ^ K ^ <t-^^ 94 _iJ < r= A 3/90 i>i;:.ruvuuAI XLt. UKUAr-liLb ANALYi:>lS DA) A SH£t7T' TENTATIVE1_Y IDENTIFIED COMPOUNDS Lab Name: ETC/GULF SOUTH Contract: Lab Code: GULF Case No.: HLA SAS No.: Ma t r i X: (soil/wa te r) SOIL Sample wt/vol: . .30.^.0. (g/mL) G Level: (1 o w / m c? (J) L.0 W ";; Moisture: 13 decanted: (Y/N) t-l F30001 SDG No.: 95020 Lata S a m p l e I D : y S I v 0 0 4 . L a b F i l e I D : iiyVSF704 ... D a t e R e c e i v e d : 0 1 / 2 5 / 9 5 C o n c e n t r a t e d E x 11- a c t V ( J 1 u m e : 15 0.0 .O ( u L ) I n ji e c t i con Vco 1 ume : JiX:.0 ( u t - ) GPC C l e a n u p : ( Y / N ) Y p M : . . . 8 - 2 D a t e A n a l y z e d : 0 2 / 2 4 y ' 9 : 5 D ii. ]. u "t i o n F" a Ci "t o r : :l. , 0 NuiTitacor T I C s f ( i ) u n d : CAS NUMBE CONCENTRATION UNITS: (ug/1_ or ug/Kg) UG/J<G. •^Hr- COMF'OUND NAME -KW- RT 7-4:"i EST- CONC. ! Q I nrr...r:(.';; ^rBAt—tr: KETOF'IE UNKNOWN UNKt-lOWN UNKLIGWN LJL-IKNOWI-4 UNKNOWN UNKNOWN LJt-IKNOWL! UNi-d'-lGWN LJN KNOWN UNKNOWN LJNKLIOWt-l l.JN KNOWN LJNKNDWi-l LJI--ll-<t-inwi-i IJMKNOl^l)-.! Lil-il-il-IOWI'-l UNKNOWi--! iitlKi-inwi-.! Ui-i 1-7-10 Wi-l UNKNOW «q-5<3 ! A.Lil J -fc^; 1 0 , 1 :l. 1 2 , 1 4 , 1 5 , 1 6 . '},. 7 -* f - f . 1 . ' , . . , , 20. HYDROCARBON HYDROCARBON l-IYDI-;;OCARBOt-l FlYDF;;0L!AF:;B0i7 HYDROCARBON HYDI-;:OCARBON F-IYDROCARBON HYDROCARBON FlYDROCAFvBOLI F-IYDROCARBOK, l-IYDROCARBOH HYDF;;ncAF-;Bn---i HYDROCARBON N l-lYDROCAlvBON 12.53 -j 2 „ p.p. 13-35 13 n 62 13-97 14-77 14..98 15-05 •1 n : '"t r.: .1. ».i,. *:. ..I 1 5 ., 4 5 :l. 5 - 62 16 - 00 16-13 16.22 :i. lA., /'.-.-.-/ 13-25 26.25 i : . P . . < ^ . 67 170 230 130 310 330 450 1100 970 300 190 840 Ti^QTi I'-TA/ ; J \ J '. J 1 ^ ' \ J 1J 1J '. J ..'..'.'...I , ' - . ^ 560 ; j UJ 310 ','.•! L U 'S^ (1> cc i-"Gi-':i'i I S v - T i r ; 302856 0^0504 / 9 ' _i I -I v.yi-ii II ' i_i;:. 1 ^ 1 SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET F31214 Lata Name: ETC/GULF SOUTH Contract: Lab Code: GULF Case No.: HLA._. SAS No,: Ma t r i X : ( so :L 1 / wa te r ) SOiF.L. Sam p 1 e w t/ vrj 1 : _3i;..-..'2. ( 71 /"' 1^- ) G Level: (l(jw./med) LJiBf^ :.: Moisture: 11.. decanted: (Y/N) H. C o n o o i - i ii I•"a •!• p^rl I-' v -1-1- r..-1 y i Q 11..,.,.v. - <;^'0'7.-.;0. ( LI!-.. ili 11 j e c t ii. con Vco 1 u m e : . i2...0 (ul...) 61-'C; C l e a n u p : (.A AH) Y p H ; ; ...6,:...5 CAS NO. COMPOUND SDG No.: 95020 Lab Sample ID: ySR007 Lab File ID: SAV3B02. Date Received: 01/25/7 5 Date Extracted: 02/03./£5 D a Ll-.-.' Al i<:i..1. )''Z(oo(ii: o::7/':74-.'95 D :i. !1. u L :i. o n F' a c t co r : :l. .. ( CONCENTRATION UNITS: (ug/L or ug/Kg) yG./.l<G. •1 /--,.--. ,—, r; '"I I". 1 , "1 .1. ( . ' ( - , - •;-- -..1 —.<;. 1 - I n-.-.'l 11...1 .i. :L:!. 0 - - 3 6 — 1 F' y I- i (d :i. n e _ :l, 11 - 4 4 - 4 -bii.s ( 2 - C h l o r o e t t i y l ) E t h e r - 3 2 — C i'l ii. o r (io p i-i e n (io il, ') - :l. -— - — :L , 3 — D ii. Ci tl il. CO r co to e n z e n e 10 6 - - 4 'i'^ -• 7 - 1 , 4 - D ii. ctil (io 1" o ta e n z e n e.. :!. - 1 , 2 - D ii. c 11 il. CO I" CO to e ri z e n e p i:: .... i: r.: ..-1 -• r-t i:: c: 9 5 - 4 8 - 7 -2-Me thyil. p h e n o l •I ,•••-, .' J-] .-I i;: o ' ; : ! 1 —•<•>*"} — / ' • \i> ./• ••••..' <;:!"•• 1. r ; r ; r: r.: - ' 'z r i ' ' " " ' / •_'"•'%.> 7 3 - 5 9 - 1 1 0 5 - 6 7 - 9 - 1 2 0 - 3 3 - 2 - 1 2 0 - 3 2 - 1 - 9 1 - 2 0 - 3 1 0 6 - 4 7 - 3 - 3 7 - 6 3 - 3 9 1 - 5 7 - 7 7 - 4 7 - 3 3 - 0 6 - 9 5 - 9 5- 9 1 - 5 3 - 13 :i. -- :i,: • 6 - • . - : ! , • • • • -2.-- -4-.. - 7 - 7:, 7:' — o x y to:i. s (1—L; ti J. corcopi-copane ) - - 4 -1^1 e t tl y 1 p in e n o il. i-l—N:1, -L1"(io AZO—Dii- -ri—1-'rzx pyJ. am ii. n e —1-leXacI'l 1 (ior(ioe L h a n e N ii. t r zx lio e n z e n e 1 scojioi'i(ioi--(ioi'ie - 2 - t-i ii, 'LI" (io p ti e I'l (io ]. 2 , 4 - - D ii. m e t i'l y ii. p l-i e n CO 1 — t o ii. Iii ( 2 -- ii; ll il. CO I-" o e L ti co x y ) t'l e 'Ltia n e . - — 2 ,, 4--D ii. (ii l'i il. (io I--CO p 'nen (io il. . . —:l, , 2 , 4 — 1 ' r i c: ti it co i" co to e n z co I'l e --N a p 1'1 L I'l ;ii. il. e n co 4—L; ti il CO 1-" iio a n ii. il. ii, n e - tl e X a (ii tl il. o r <:> by\ 't a(ii ii, e n e — 4 - C tl ii. (io 1- CO--Z-- I'le t. |-iy il. p tien o il. — 2 - M e t h y l n a p h t h a l e n e Z-Z..Z.-. - Fl CO X a (ii tl .L CO i - (io (ii -/ (ii .1. co |io co n L a (il ii. eo n 'i-io. 2 , I'l-, ('::•--1 I"ii. (iiI'l 1 (iorco|iJiie;-i(io.1. r-. /I n; -t- ... .- ... 1.. •] .. ,.. 1 , -1 - . ; : . , — , - , . 1 r .1, 1... I I I,'.,.1 I- 1...1 |.i 1 H - J I II...1 .1, A.—i..; i'l .1. (io r (io 11 a |io i 1 L i'i a 1 <"•• n e . - --.i;:—t-l il, -Li-"(ioai'i ii. .1. ii. ri (io — - D ii. f 11 e L ll y il. F' li 'L ti a ii. a -i-. e 6 li > •;• --i-1 ciconar.oI'l (.ii')--'.i.coi'i(io --'z.'., 6—Dii.I'l ii. 'Lrco t'iiolucoriiiio — ,i.-'-i--lii. Li-"co-::',nil .! ii,nCi' r'0i7;''l I 370 ; u 370 : u 370 ; u 370 ; u 370 : LJ 370 370 :7o I 1 I I L J : LJ 370 ; tJ 11 Z ' / O 1 LJ 3 7 0 ,i)./' (..' 370 370 370 3 7 0 3'7(0 3 7 0 'z..7C.> 77,"'0 3 7 C} 3 7 0 3 7 0 3 7 0 9 0 0 370 9 liii 0 3 7 0 - : > ..-• (...' 7:70 9 0 0 ;u I tj ! LJ : u 1 l.J I '<' 1 LJ ; l-J 'lUJ 1 '-.J 1 L.l ; 1J ;L!3 1 LJ ; LJ U-J 1 1 1 1 l-J ; I ' J 1 1 7 _ ' . N./ 0 j 5^ cb4 - ^ - — - - _J \ ^ ^ •w < r^ > 7; 1 0 cr 302857 SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET F31214 Lata Name: ETC/GULF SOUTH Lata C o d e : GULJF Case N o . : HLA M a t r i x : ( s o i 1 / w a t e r ) SOIL S a m p l e w t / v o l : . , 3 0 . 0 (g/iiiL_) G L e v e l : ( l o w / m e d ) L.Q.L'L. ": Moisture: 11. decanted: (Y/N) tl C(i)n c(•?n t ra ted E x t r a c t V o 1 u m e : 5 0 0 - O (uI. i> 1 n .:i CO c t i (TJ n V CJ 1 u m o : ^2_.._0 ( u L ) GPC Cleanup: (Y/N) Y pH: _6...1 CAS NO „ COi'-iF'OULID Contract: SAS No.: S D G N o . : 9.50.20.. Lata Sample ID: VSR007 L a b F i l e I D : D a t o R (••• c (3 i V Ci (J: D a t e E x t r' a c: t eo cl:; p .7. 1-.-::. Ji. 1-. ?. 1 - - ' -z -;:• d : D ii. 1 u t i o n F a c t co i " CONCENTRATION U N I T S : (u g /1... o I" u g / K g ) UOZiyQ SVVSRO: O l . / 2 5 / j 0 2 / 0 3 / ^ I'S r-. / ' - . .1 .' I-. I :i. - 0 G' A c o n a p ti t ti e n * - 2 , •4~.Liin i t r o p h c o n o l _ C>^.) —Cj.i.'.— > r: H '-I.—1 i:: . . i \ lA-IAZ! ,.1 1 0 0 - 0 2 - 7 - 4 - N i t r o p h e n o l . _ 1 3 2 - 6 4 - 9 D i IJ e n z o 'f' u r a n _ 1 2 1 - 1 4 - 2 — - 2 , 4 - D i n i t r c o t v j l u e n e Ji) ii. o: t \~\ y ]. p Ll t I'l a 1 a't (io _ _ 4 - C tl 1 o r o p tl e n y 1 ~ p tl e n y il e L tl e i" F 1 u CO r e n e 4—Ni t r o a r i i 1 i n e - - 4 , 6 - D i n ii. t r o - 2 - M e t h y il. p h e n (io I. ~N-N i t r o?iocl J. fo tien y l am ii. n zz. ( 1 ) 4 - BI-- om CJ I'.o l'i Ci n ' / 1 — p i'i co n y 1 e L ti coo i" I-l e X a c h 1 CO i" o to e n z e n e F' e n t a c i'i 1 co i' co |io i i co n o .i. - - F-' tl e n a n L tl 1" e n e _ An t h r a c e n e . - C a I" lio a z o il. e 8 4 — 7 4 - 2 Dii. — n -Bu Ly). pio Lii-iiiil.a'Le _ 2 0 6—4 4 — 0 — F' 1 u (01 - a n t 1'1 e n e 1 2 9 - 0 0 - 0 •—F'yi'"«i"ie..... B 5 ~ 6 B - 7 - - - - - - B 1.1 L yil. toe n z y 1 p to L ti a il, a t -io 9 :l. • - 9 4 — :l. — 3 , 3 ' — D i (ii 171. o r c) lio e n z ii. (il ii. n e 5 6 - 5 5 - 3 - B e n z o ( a ) An t t i r a c e n e 2 1 8 - 0 1 - 9 C h r y s e n e . . [ 117-8:1 - 7 b i s ( 2 - E t h y l h e x y l ) P trii ha l a t e 1 :l. 7 - 8 4 - 0 - D i - n - 0 c L y i I-' 1'11 ti a ii. a L e 2 0 5—99—2—- — B e n z o ( to) F-'J.u cor ai'i Ltiene... 2 O 7 - O (i7 - 9 - B e i'l z o ( k ) 1~ 1 u (io r a n L I'l e n e 5 0 - 3 2 - 8 -- - - - B e n z o ( a ) F-"yrene _ _„.. 1 9 3 - 3 9 - 5 — - - I n d e n o ( 1 , 2 , 3 - c d ) Pyrcone i^ZZZZZ 5 7 7 - 7 0 - 3 - D i b e n z ( a ,, ti) An t h r a c e n e 1 9 1 - 2 4 - 2 - - Benzc. (g , ti, i ) l - - ' e r y l e n e 8 4 - 7 0 0 8 6 - 1 0 0 5 3 4 8 6 - 1 0 1 :l. :i. 3 8 5 - 1 2 0 'APff.'.'f"" 6 6 - 2 5 - 7 2 7 3 - 7 - 0 1 - - 5 2 - 3 0 - 6 -'zZzy- - 7 4 - 3 6 - 5 01—3 - 1 2 - 7 4 - 3 _.. - - T . . . . 6 1 X_-y - 1 — "/' ( :i.) - (ii:anriCO'L iioco s e p a i - a t e ( i i 'friiom Dii. |io lien'/lain ii.ne F-"OFi;M I 3V-2 370 9(00 900 3.''0i 370 37'i) 370 370 900 "x"/ \X\ 1:7 C) 3 A 0 900 37'!o 370 370 370 3./'-.!' 370 37'!io 65 37(0 370 370 3 /'..' 370 370 ;uJ lUT 1.1 LJ LJ LJ U L J J U 3 LJ 11 l.i ua LJ LJ l.J LJ I.J LJ U .1 l.l 302858 SEMIVOLh.ILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS Lata Name: ETC/GULF SOUTH Lab Code: GULF Case Ho.z HLA Contract: SAS No.: F31214 SDG No.: 95020 Matrix: (soil/water) SOIL Sample wt/vol: 30.0 (g/mL) G Level: (low-/med) !_0.W r: M o i s t u r e : 1.1. d e c a n t e d : ( Y / N ) N C o n c e n t r a t e d Frlx t r a c t V o l u m e : 50,0 . 0 ( u L ) ln.:i (ioction V o l umco: 2 - 0 ( uL.) L a b S a m p l e I D : yj5RC>.(37 L a b F i l e I D : SVVSR07 D a t e R e c e i v e d : 0jLZ:2.'7/9.5 D a t e E x t r a c t e d : 0 2 / 0 . 3 / 9 ; 5 . D a t e A n a l y z e d : 0 2 / 2 4 / 9 ^ 5 D il 1 u t it o n F a c t o r ' : :i. ., O GPC C l e a n u p : ( Y / N ) Y_ pl-l: _i 6 - 5 N u m li) (-J r T I (i^ s- f o (.i n d CAS LIUMBE 7 CONCENTRATION U N I T S : ( u q / ! _ . o I - u g / K g ) U G / K G COMF'OUND NAME KETOtlE RT il.i . A ' J - ^ 2 ,-'l "•• E S T . CONC. 3 5 0 Q !:^r.('...'r.r.'.° AJJ..7 r i ^ . KETOtlE A ^ Z ^ , 7 . UNKNOWi:-i HYDROCARBON UL-I KNOWt-1 HYDROCARBON UN KNOWN HYDROCARBON UN KNOWN 1-I YD!-<OC AF;&ON UNKNOWN A M I D E 11 . 0 2 11 - 92 1 2 . 5 3 15 - 0 5 '••••.•'-• r "7 f) 110 '-'.P.O j p l .1 J .T J/ .-.'/vy FORM I SV-TiiiC 3 02 859 HLA DATA QUALITY ASSURANCE REVIEW SUMMARY Low Concentration Semivolatile Organic Compound Analysis Case Number: 95020 Project Number: 29872 10.2 Site: Island Chemical Company Contractor Lab: Pace Environmental Labs, St. Rosa, LA Validator: Kirsten Meier QC Reviewer: <^'>W(1</' ^ ^Z^yCX^/^ Validation Date: Review Date: 4 April 1995 y- Q^ r r Sample Matrix: water Analytical Method: Low Concentration CLP Semivolatiles Sample Designations: RBSO/012495 (SO0012) RBSO/012795 (SO0127) RBSO/013195 (BS0013) ( ) = Lab Sample ID Data for the above samples are: [ ] Acceptable for use [x] Acceptable for use as qualified [ ] Unacceptable for use Is action required by the Project Manager? Yes No[x] Comments: The data was reviewd in accordance with the EPA Functional Guidelines, February 1994. bm.ekx.ll I2N19*1 1330 Fonn BNA l.l 302860 CucNusker: 93020 Pnijoci NuBkcr: 29872 lOJ Sile ID: bbmd Cbcaaaal CUII|MUJI DATA COMPLETENESS CHECKUST [x] Included, no problems [*] Included, problems [O] Not included [NA] Not applicable Quality Control Summary X Case Narrative X Surrogate Recovery Summaiy NA MS/MSD Summary * • Reagent Blank Summary X GC/MS Instrument Performance Summary Sample Data * Chain of Custody Fonns X Holding Times X Organic Analysis Data Sheets X (Quantitation Reports X Reconstructed Ion Chromatograms X Mass Spectra Printouts X TIC Mass Spectra Library Searches Initial Calibration Data * Calibration Summary X Standards Quantitation Reports X Standards Reconstructed Ion Chromatograms Continuing Calibration Data * Calibration Summary x_ Standards Quantitation Reports X Standards Reconstructed Ion Chromatograms X Intemal Standards Summary Instrument Performance Data X DFTPP Mass Spectra X Reconstructed Ion Chromatogram X DFTPP Mass Listings bm.elec.ll I22919W 1530 2 Fotm BNA l.l 302861 Case Number: 9 JO20 PiDJect Nwnhen 29872 10.2 Site ID: bbnd '"t^^'Sfml rj»wp«iy Reagent Blank Data X Organic Analysis Data Sheets X Quantitation Reports X Reconstructed Ion Chromatograms X Mass Spectra Printouts X TIC Mass Spectra Library Searches Matrix Spike and Matrix Spike Duplicate Data NA Organic Analysis Data Sheets NA Quantitation Reports NA Reconstructed Ion Chromatograms Laboratory Control Sample X Organic Analysis Data Sheets X Quantitation Reports X Reconstructed Ion Chromatograms X Mass Spectra Printouts NA TIC Mass Spectra Library Searches Comments: None b n elec.ll I22919M 1530 3 Fonn BNA l.l 302862 Caie NiMoben 93O20 Pn^eet Nianber 29B72 10J2 Site ID: blBad CbennoU Ctxafmay SPECinC COMMENTS REGARDING ANALYSES Chain Of Custody Were samples properly preserved and received in good condition? Yes[x] No Were custody transfers correctly and completely documented? Yes[x] No Comments: The Chain of Custody forms submitted with the data were not signed and dated by the lab upon sample receipt. No qualification of data. Holding Times Were sample extractions performed within holding times? Yes[x] No Were sample analyses performed within holding times? Yes[x] No Comments: None Instrument Tuning Did the instrument performance checks meet acceptance criteria? Yes[x] No Were samples analyzed within the 12-hour period following an acceptable performance check? Yes[x] No Comments: None bm.elec.ll 1IWI994 1530 4 Fonn BNA 1.1 302863 Cue Nunber: 95O20 Piojeot NtBdKf: 29S72 10.2 Sile ID: bland Cbcmkml ^.—|""j Initial Calibration Did the laboratory meet the method requirements regarding the minimum number of calibration standards for an acceptable initial calibration? Yes[x] No Did the initial calibration curves meet the linearity criteria for maximum percent relative standard deviation (%RSD)? Yes No[x] Did the initial calibration meet the minimum relative response factor (RRF) criteria? Yes[x] No Comments: See table 'Initial Calibration Summary". The investigative samples SOOO 12 and SOO 127 were analyzed directly after the initial calibration. Therefore, the qualification criteria for continuing calibrations apply for these samples. Continuing Calibration Did the continuing calibration curves meet the linearity criteria for maximum percent difference (%D)? Yes No[x] Did the continuing calibration meet the minimum RRF criteria? Yes[xJ No Comments: See table "Continuing Calibration Summary". No investigative samples are associated with the continuing calibration on 2-10-95. bna.ekc.ll 122919M 1530 5 Fonn BNA l.l 302864 Cue Nunber 95020 Pnjeet Number: 29872 10.2 Sile ID: bhnd Cbemical Cam|Kiy Surrogate Recoveries Were the surrogate spike recoveries within acceptance limits? Yes[x] No If the spike recoveries were unacceptable, were the samples reanalyzed? Yes No NA[x] Comments: None Matrix Spikes Were matrix spike analyses performed at the correct frequency and on a sample matrix representative of the samples in the sample delivery group (SDG)? Yes No NA[x] Were the matrix spike recoveries and relative percent differences (RPDs) within acceptance criteria? Yes No Comments: Not applicable Internal Standards Were the intemal standard areas and retention times within the required limits? Yes[x] No If the intemal standard requirements were not met, were the samples reanalyzed? Yes No NA[x] Comments: None boi.ekc.ll 12291994 1530 6 Fonn BNA l.l 302865 Cue Nunber: 95O20 Prifee) Nunter: 29872 10.2 Sile ID: lalml Cbemial Ceo^imy Blank Analyses Were the appropriate number of blank analyses performed? Yes[x] No Were analytes detected in the blanks? Yes[x] No If analytes were detected in the blanks, were the same analytes detected in the associated investigative samples? Yes[x] No NA Did the sample results require qualification due to the presence of analytes in the associated blank samples? Yes[x] No Comments: See table "Blank Summary" for blank containinants and associated samples and qualifiers. Detections of the listed analytes in the investigative samples below the action level were qualified as imdetected (U). Results which were less than the Contract Required Quantitation Limit (CRQL) were raised to the CRQL. Three blanks were extracted, one with each sample. However, the samples were analyzed on different days than the third blank and no blank was analyzed on 2-27-95 with the samples. No qualification of data. Laboratory Control Samples Were laboratoiy control sample (LCS) analyses performed at the correct frequency? Yes[x] No NA Were the LCS recoveries within acceptable limits? Yes No[x] NA bf».elec.ll 12291994 1530 7 Fonn BNA 1.1 302866 d u e Nunber: 95020 Projecl Nunber. 29S72 10.2 Sito ID: bbmd Cbemioel Compioy Comments: Two LCSs were analyzed with the investigative samples and as many as 6 out of 15 analytes exceeded the QC criteria. The table below lists the outliers and the associated qualifiers. Qualification was applied to all the investigative samples. Sample ID SLCSOl SLCS02 Analjfte Hexachloroethane Isophorone 1,2,4-Trichlorobenzene Napthalene 4-Chloroaniline N-Nitrosodiphenylamine Isophorone Napthalene N-Nitrosodiphenylamine % Recovery 31 45 41 47 31 122 46 54 121 Limit 33 49 44 56 35 120 49 56 120 Qualifier J/R J/R J/R J/R J/R J/- J/R J/R J/- No detections were reported for N-Nitroso-diphenylamine, qualification was not necessary. bm.elec.ll 12291994 1530 Fonn BNA 1.1 3 02 867 Cue Nunber 95020 Praged Nunber 29K72 10.2 Sile ID: bkmd Cfaemical Compmy Sample Results Were target analytes reported in the investigative samples? Yes[x] No Were mass spectra provided for the target analytes detected in the investigative samples? Yes[x] No Were the mass spectra of acceptable quality and analytes correctly identified? Yes[x] No Were the quantitated results for target analytes calculated using the appropriate intemal standards and were the relative retention times (RRTs) acceptable? Yes[x] No Conmients: None Tentatively Identifled Compounds Were tentatively identified compound (TIC) searches conducted for all sample analyses? Yes[x] No NA Were non-target peaks evaluated as required? Yes[x] No Were the TIC mass spectra, searches, identifications, and quantitated results acceptable? Yes[x] No Comments: TICs were qualified as tentatively identified (NJ). bm.elec.ll 12291994 1530 9 Fonn BNA l.l 302868 Caae Nmber: 93020 Prefect Number 29972 10.2 Site ID: Iilud CfaenucKl Coafury Log Books Were sample preparation.s properly documented and performed in accordance with method protocols? Yes[x] No NA Were sample analyses properly documented and performed in accordance with method protocols? Yes[x] No Comments: The investigative sample BS0013 and the associated two LCSs were analyzed on 2-10-95, but not submitted. Then these samples were reanalyzed on 2-27-95, those results were submitted. Since the samples were analyzed within hold time, the second set of data is acceptable, no qualification of data. bm elec.ll '='"»"530 10 Fonn BNA 1.1 302869 Cue Nunber 95020 Piojea Nunber. 29872 10.2 Sile ID: bfamd QEmJeal C^wnpany Calculation Checks Instmment Tuning, 2-8-95, 11:45, 275 m/z Relative Abundance: 665 X iOO% = 29.3210 2268 Initial Calibration, 2-20-95, StdOOS, Phenol RRF: (2318) x ( 2 0 ) ( 6277 ) : %RSD: 0.1136 1.6284 x ( 5 ) X 100% = Continuing C^ilibration, 2-27-95, RRF: ( 11797 )x ( 6682 ) x %D: 1.628- 1.765 : ( 2 0 ) ( 2 0 ) 11:49, 6.9748 Phenol ^ X 100% = -8.4152 1.628 Surrogate Recovery, SOOO 12, Phenol-d5 % Recovery: 20.722 40 X 100% = 51.8050 1.4771 1.7655 bm.efcc.ll >2291»« 1530 1 1 Fonn BNA 1.1 302870 Cue Nunber 95O20 Piojea Nunber 29872 10.2 Sile ID: bbml Cbcmical Com^siv LCS Recovery, SLCSOl, Phenol % Recovery: 29000-0 X 100% = 72.5 40000 Sample Results CRQL: Detected Result, BS0013, Diethylphthalate 4552 X 20 = 5.2732 18231 X 0.947 TIC Result, S00012, Unknown RT=18.05 30495 X 20 61185 X 1 9.9681 bm.elec.ll 12291994 1530 1 2 Fonn BNA I.l 3 02 871 C^Mc Number: 95020 . Projecl Number: 29r72 10.2 Sile ID: bbnd ChemJ<sl Companx HOLDING TIME QUALIFICATION SUMMARY FORM Sample Identification Date Sampled Date Prepared Date Analyzi'.d Prep. Holding Time Analysis Holding Time Qualifier CO o CO 00 to Comments: None bm.elec.ll 12:91994 1530 13 Fomi BNA 1.1 Ui o IO CD < I U i CMMC Number: 95020 Pmjed Number: 29r72 10.2 Sile ID: bbnd Chemical Cofnpany INITIAL CALIBRATION QUAUFICATION SUMMARY FORM Date/Time 2-8-95 Instrument C Analyte Di-n-octyl Phthalate RF RSD 33.5 Samples Affected S00012, S00127 BS0013 Qualifier JAJJ J/- Comments: See report for comments. bm.elec.ll I229I9W 1530 14 Fonn BNA l.l o IO c» Ca« Number: 95020 Projecl Number: 29»T2 10.2 Sile ID: Ulord Oiemioal Company CONTINUING CALIBRATION QUAUFICATION SUMMARY FORM Date/Time 2-10-95, 1348 2-27-95 Instrument C C Analyte 2,2'-oxybis(l-Chloropropane) N-Nitroso-di-n-propylaraine Nitrobenzene Hexachlorocyclopentadiene 4-Nitrophenol Pentachlorophenol 3,3'-Dichlorobenzidine 2,4,6-Tribromophenol (Surrogate) Bis(2-Chloroethyl)ether 1,2,4-Trichlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene 2-Nitroaniline RF %D -29.8 -25.7 -26.7 -40.1 -42.2 -28.1 29.0 -45.4 -28.6 28.2 35.2 56.5 27.0 Samples Affected None None None None None None None None BS0013 BS0013 BS0013 BS0013 BS0013 Qualifier — — — — — — — — J/UJ J/UJ J/UJ J/UJ J/UJ Comments: None Ira.clcc.l I 12291994 15V) 15 Forni BNA l.l Ui o to CO (Jl C»»c Number: 95020 Projecl Number: 29»72 10.2 Sile ID: bland Chemical Company CONTINUING CALIBRATION QUAUHCATION SUMMARY FORM Date/Time 1 2-27-95 Instrument C Analyte 2,4-Dinitrophenol 3,3 'Dichlorobenzidine Di-n-octyl phthalate 2,4,6-Tribromophenol RF %D 26.3 65.1 -44.1 45.5 Samples Affected BS0013 BS0013 BS0013 BS0013 Qualifier J/UJ 1 J/UJ J/UJ J/UJ Comments: None bm.elec.l 1 12291944 1530 16 Fotm BNA l.l C«K Number: 95030 Projecl Number: 29«72 10.2 Sile ID: bland Chemioal Company BLANK SUMMARY FORM Blank ID 1 SBLKWl 1 SBLKW2 1 SBLKW3 Analyte Bis(2-ethylhexyl)phthalate Bis(2-ethylhexyl)phthalate Bis(2-ethylhexyl)phthalate Blank Result [ug/l] 1 0.6 0.8 Action Level [ug/l] 10 6 8 Associated Samples S00012 S00127 BS0013 o to 00 - J Comments: None bm.elec.ll 12291994 I5.V) 17 Forni BNA l.l Caae Nunber 95020 Project Nunber 29872 10.2 Sile ID: bland Chemical Coo^Miy Summary and Conclusions The analytical results for the low concentration semivolatUe analyses are acceptable for use as qualified. The results for Di-n-octylphthalate in the investigative samples SOOO 12 and SOO 127 were qualified as estimated (J) due to exceeded QC criteria in the initial calibration. The results for several analytes were qualified as estimated (J) due to exceeding QC criteria in the continuing calibrations. See the report for detailed listing of analytes and associated samples. The detections of Bis(2-ethylhexyl)phthalate in the investigative samples were qualified as undetected (U) due to blank contamination. The LCS recoveries were not within QC criteria and therefore, the results for several affected analytes were qualified as estimated (J) for detections and were rejected (R) for non-detections. TICs were qualified as tentatively identified (NJ). Validator's Signature: Validator's Initials: QC Reviewer's Signature: QC Reviewer's Initials: ciXh^AA \ijy<i/ UP\ ypTlXcX^uU' >^ Z^.y<-^P^<r^ Mrr Validation Date: Review Date: ^-^'fS V - ^ - 9 S - bm.elec.ll 12291994 1530 1 8 Fonn BNA 1.1 302877 • LOW CONC. WATER SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: ETC./GULF SOUTH Lab Code: GULF" Ca?;e No. : F!l..i^. Contrrtct: SAS No.: S00127 SDG No.: 95020 Lab Sample ID: VTFOOl____ Lab F'ile ID: BVVTFOl S a fii I j ]. e V o 1 u f 11 e : .1..Q.Q.0 . (in 1 ) C o n c e n t r a t e d E;!.xtr<?.ct Vo'lume: 1.0C)CL J.I'l 'i ZXi~•'.'.i.oI'l '•,'i;.> 1 . u f . ' i ' . 7 " ( u . I ) D a •': e R e c e i v e d : 0.1 /J3p,-'' 9 'A D a t e E x t r a c t e d : Q 2 / 0 1 . / 9 5 D a t e A n a l y z e d : 0 2 / J 0 3 / 9 5 D i l u t i o ri F" a c t o i- : 1_».C^. iji-l: 5 . B CAS N O . :l. 0 8 - 9 5-2- 1 1 1 - 4 4 - 4 - y . . . I — o J / ..I *-TC..> / 1 0 8 - • 6 0 - l - 106••••44••••!••|• 621••••l:^4••••7• 6 7 ••72 - l < • • . . — . , - - , i : : - • ' ' . ' ( • > "/• 1..' "•"• •..•> 7 8 - 5 9 - 1 1 1 1 - - 9 1 - 1 - 1 2 0 ^ - 8 3 - 2 - 120^^^82-1^^ 9 1 •2 0 - 3 - • 1 0 6 - 4 7 - £ i - R7--68^^^3 u : I--. e : ,•"•, —,» ^.1 •.-/ ^.iK.y— / y 1 ••"• l.l.' -z... "/"-' — .<> '7- -.0. 9;:::; ...QZ,...^ 9i:;,....9^:,....n 9 1 ^ - 5 8 - 7 8 S - - 7 4 - 4 2 0 8 - 9 6 - 8 - 6 0 6 - - 2 0 - 2 - 9 9 - 0 9 • 2 O "•': .... " 7 '".*'.... ''."^ COnl-'OUND - F-' l"i e n o 1 _ _ - b i s ( 2 - C h i o r o e t h y i ) E t h e r • 2—C t-11 o r o p tl e r i o 1 _ •• 2 - I'l e 111 y 1 p b e n o 1 - 2 H 2 ' - o x y b i s ( 1 - C h l o r o p r o p a n e ) • 4 • -1"! e t h y 1 p h e n o 1 •• I-l - H i t r Cj zz o - D i •••• n - F-' r o p y ]. a n i i r i e -1 •! e X a cl'I ]. o r o e t h a n e • H i 't I "obfi'i'izene • 1 3 o p h o I'" o n e _ • 2 - N i t r o p h e n o l •2,, 4 - D i m e t h y l p | - i e n o l • b i s C 2 - C h l o r o e t h o x y ) M e t h a n e . -2., 4 -D:i. z:.b 1 oropi"iei"ii:j]. •1 , 2 n 4 — T r i c l i l o i ' o t j e r i ;-:erie -!'•! a p i 11 i'l a 1 ei"i e ••4-Chlproai"'i i 1 i r i e _ "F-le X a c 1 "i 1 orcjhzi 'tad i e n o • 4 - C i' 11 o I" o ••" 3 - T'l e 11"! y 1 p tl e i-l CJ 1 . • 2 - II e t. |-i y 1 n a p |-i 't I "I a ]. e i "i e "I "Ie X a c; Fi 1 o r o c y c 1 o p e n 'Lad i ei "i e . . • • 2 , 4 , 6 - TI" 1 c h 1 o r o IJ h e i-i Cl 1 • 2 , 4 , 5 - T r i c h l o r o p h e n o l - 2 - C i "I I o I" o n a p h 11 "I a 1 e n e •^•••Ni -t.roan i 1 i n e _ ,. - D i m e t h y l F'h t h a i a t e - A c e n a p l v l ; . h y l e n e _ • 2 ,, 6 •••• D i n i 't i" o t o 1 u e i"i e •3^-l-!i "trcjan i 1 :i.ne - A c: eri a p lrU"ieri e CONCENTRATIOH ( u g / L ) Q 5 ' " i 5 ;u u l U 2 0 •'f'l 2 0 IJ Li •Z^ R u L.l U •Z<K 'iZiR J^R LJ L.l L.1 LJ LJ LJ LJ LJ Lt LJ Li LJ LJ Re -J By VALIDATED Date ^-^^i •ORM I L C S V - 1 3 0 2 8 7 8 L.UW uuHC. WAILK SLniVOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: ETC/GULF SOUTH Lab Code: GULF Case No.: HL_A_ Lab Sample ID: VTFOOl Lab File ID: SVVTFOl Contract: SAS No.: S00127 SDG No.: 95020 Sample volume: 1 J?.0 <) „_ (ml) Concentrated Extract Volume: 1.0.OC). In.:iection Volume: .1-.0 (ul) COMPOUND (ul) Date Received: 01/30/9^5 Date Extracted: 02/01/9 5 Date Analyzed: 02/087.95 D i 1 u t. i o n F" a c t o r : 1.0 CAS 5 1 - 1 0 0 1 3 2 1 2 1 8 4 - 7/'00 8 6 - 1 0 0 5 3 4 8 6 - 10:1 I I P 8 7 - 8 5 - 1 2 0 2 0 6 1 2 9 8 5 - 91-- 5 ,''•. •• •• 2 1 3 1 1 7 1 1 7 2 0 5 2 0 7 5 0 - 1 9 3 %.' *.> ••• 1 9 1 NO. 2 8 - ^ - 0 2 - - 6 4 - - 1 4 - ...... .-7 .9 r-, 6 6 - 2 5-7:- / z> —.' - 0 1 - 30-0 „„ VA \'~ „ ...74.- 8 6 - ; : 0 1 - 8 - 1 2 - 7 4 - : - -...'4-q-. - 0 0 - 68—7 94-:i IU r.-. ,.,.-.•• - 0 1 - - 8 1 - - 8 4 - .-99... - 0 3 - 32-(; - 3 9 - 70-1';' — •-> / I . . . ...3...._ .i. .... ..-. — •1 - 3 1 7 - •0 0 • - - • 9 / • • — — • - • 0 '"'.' r"' ^..„ ; 5 '-;. ».-..._ CONCENTRATIOiM (ug/L) Q •2 p 4 - D i n i t r o p hern o l -4-Ni t r o p h e n o l . _ •Di tjen z ot" u rarr -2 p 4-I)in i t r o t o l u e n e -D i e t hyl p b t \\A 1 a t e . -4 -Ch 1 orop'nen•/]. — pLieI'l y 1 ex Lhe 1 • - F" 1 u o r e r^ e -4-Ni. t r o a n i 1 i n e • 4 ,, 6 - D i r 1 i 11-"o -2•••• I''!e LI'iy ]. f> i'^eno 1 - N - N i tro-:"Cii:.1 i |:;l'ier'iyj.aiiiirie ( 1 ) • 4 - B r- o m o p h e ri y 1 - f j l'i e ri y 1 e t. i 1 e r -F^le X a c: l""i 1 o r o o e n •z eri e . •F-'en Lac::li 1 o r o p h e r i o 1 -F' l"ien ari t i'i reri e_ •An L h r a c e n e . . . - D i •••• n •••• B u t y 1 p 1'1 L1' 1 a 1 a t e -F" 1 uo r ari t lien e - P •/ r e n e •Bu t y l ben 'zylp b t ha 1 a t e - 3 ., 3 ' - D i c h ]. o r o b e n z: i t;l i. n e •Ben zo ( a ) An LFiracene. - C h I'- y s e I'l e •• L) i s ( 2 - E t h y 1 i'1 e x y 1 ) F • F1 L I'1 a 1 a L e •D i - n - 0 c t y i F' |-i t ha 1 a t e •Ben7.o ( b )F'-' 11.1.0ran LI lene. _ -Ben z o (I-'.) F1 u o r a n t tieri e "Ben zo ( a ) Pyre.rto_,_ _. , - I n d e n o (1 , 2 , 3 - c d ) P y r o n o •Di ben7 ( a , h ) An tl'iracerie_ "Ben zo (g , Fi, i ) F ' e r y l e n e ;^ 20 20 C ^1 20 20 2O1 S o Ll 11 U L) I I LJ LJ LJ LI:J I I U LJ LJ LJ l.j Re'v- - .:d By Date VALIDATED , (P'?~^S FORH I LC .'.;'/ 3 02 87 9 L.UW CUNU. WATER SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS Lab Name: ETC/GULF SOUTH Lab Code: GULJF Case No.: HLA_ Lab Sample ID: yT.F.001 L a b F i l e I D : SVVTFOl Sarii p i e v o 1 ume : .10.00 (in ].) CoI'l c e n t r a t e d Fix t r a c ; t Vo 1 ufiie : 1 0 0 0 1 ri j e c L i ori Vci 1 ij rne: . 1 . 0 ( u ]. ) C o n t r a c t : SAS N o . : ( u l ) SOO127 SDG N o . : 9 5 0 2 0 D a t e R e c e i v e d : 01./30./95 D a t e E x t r a c t e d : 0 2 / 0 1 / 9 5 D a t e A n a l y z e d : Q2/08/;9.5 D i :i. Ll. t i on Fa c t o r : 1, 0 •••I urn tier T I C s i'ound ; 0 CAS NLJI-'IBER coriF'OUND NAr'ii; RT EST. CONC. ( u g / L ) RFV . Date VALIDATED , :d By FORn ]; LCSV-TIC - ^ 1 0 / 9 2 302880 LOW CONC. WATER SEnlVOLATILE ORGANICS ANALYSIS DATA SHEET l'i CM-i:'lr L..!;^ H Lab Name: ETC/GULF SOUTH Lab Code: GULF Case Ho.: HL_..A_ Lab Sample ID: VS.Rpjjl Lab File ID: ^XL^iRQl. Sam p i e v o 1 time: 1 0 0 0 (fn 1 ) CCln ceri -t ra ted E x L ra c t Vo 1 ufne ii 1.C)0CL. 1 n :i o c. t i on Vo 1 u m e : Contract: SAS No.: SOOO12 SDG No.: 95020 (ul) CAS NO, 108-95-2- 111-44-4- 9 5-57-8— 95-48-7-- 108-60-1- 106-44-5- 621-64-7- 67-72-1 98-95-3 73-59-1 B.''.:-i — y^7<-- A 105-67-9- 111-91-1- 120-83-2- 120-82-1- 91—20^-3 106-47-£5~ JA-SLPI 0.1.1) COMPOUND Date Received: 0_l.,/2 5/9 s Da te E x t rA c ted : 0.1/30,/9 5 Date Analyzed: 02/08/95 Dilution Factor: ;U 0 F'i-I" ..AILI CONCENTRATION ( u q / L ) Q 9 1 - 5 7 - 6 — 77-47^-4 — 8 n - 0 6 - 2 9 5 - 9 5 - 4 •• 9 1 - 5 8 - 7 8 8 - 7 4 - 4 1 3 1 - 1 1 - 3 - 2 0 8 - 9 6 - 8 6 0 6 - 2 0 - 2 - 9 9 - 0 9 - 2 8 3 - 3 2 - 9 - — F ' h e n o l . i — b i s ( 2 ~ C h i o r o e t h y l ) E t h e r ; -— 2 - C F11 o r o f) FI €•? ri Cj 1 ; - - 2 - M e t h y l pheno 1 I l l l H I I I i r i l ! 2 ., 2 ' — o X y t > i s ( 1 -CFi 1 orcj]:• r o p a r i e ) ; - 4 - M e t h y l p h e n o l . ''" [ —N-Ni troso-Di~n-Propylamine ; - - I-l e X a c Fl 1 o r o e i;. h a n e ; -—F-l :i. F1^o t;ieri:;: eri e ' - „ I "-" 1 •Bo p I'Io r oI'l e I "" 2 - F-l i t r o [:• l'i e n o 1. ; - - 2 , 4 - D -j. me t h ' / l in I "leci o 1 . . ' ; "~ b i s ( 2 - C Fl 1 o r o e t Fio x y ) Met Fiari e ; - -^ 2 , 4 •••• D i c l"i 1 o I" o p 1 "I e i"i ci 1 ; 1 ;.2 , 4 - T r i cF\loroi;)en:Kene ; —Na|:'j| rLi""ialei"ie _ ' —4~Chloroaniline _ ; -"- F^l e X a c Fi 1 ci i - o b i_i. t a zi i e i'i e ', - - 4 - C Fl 1 cj r o - 3 - r ' l e t Fryl p i "lei "i o 1 ; • -2-l''le 'L |-iy 1 n a |J Fi 'LI "ia 1 ei"i e ' ; • - F l e x a c F11 o r o c: y c; 1 o p e i "i t a d i e r i e ; —2., 4 , 6"-Tr i c l ' i l o r o p F i e n o l ; '"•'2, 4 H 5 - T r i c Fi ]. o r o p iiei "i o 1 ; 2 - L ; I "I .i. z.) rovi -A p b L Fia 1 eri o ' - 2-FM-.i. t r o a r i ;i. 1 i n e ; - D i m e t F1 y 1 !"' h t h a 1 a L e ^ ~ • " ; - A c e n a p Fi L Fiy ]. e n e ; —2., 6—'Din i ' L i - o t o l u e r i e ; -3•••• F-li t r o a r i i 1 i r i e . . . ; " A c e n a p l rLFierie. ' ;u IU :u ! U ; LJ :u ;u 1 LJ Rev . Date 'ORM I I...CSV-1 c: ^ 1 n: IT. v.: 0 . 20 VJ 5 5 i:: 2 0 I." 2 0 • 1 = X . ' 5 * tr 2 0 5 ;u ;u ; LJ • 1 1 1 ' •' 'i-WR 4 : .3 ' K W R ', LJ ' , 1 ' ;u :u ;u : LJ :u ; LJ :u :u ; LJ ;u :u 1 _ VALIDATED _ „j By u y y ^ f ^ ^ (^'(('9S ICj/'? 302881 . LOW CONC. WATER SEMIVOLATILE OF^GANICS ANALYSIS DATA SHEET Lab Name: ETC/GULF SOUTH Lab Code: Gl.JL_F:. Case No.: HL.^A. L a b S a m p l e I D : VSJI^OOl C o n t r a c t ; SAS N o . l 5 0 0 0 1 : SDG N o . : 9 5 0 2 0 L a b F i l e I D : II I.—. r-..^. .1 ' VDf O l 5 a til \:i 1 e v o l u m e : l.Q<>.Q..... (f' ^ ) Cori c e n t r a t e d E x t r a c: t Vo 1 u i n e : 1.0CJC>.. Inji e c t i o i i Vi::>].ume :; 1_...0 ( u 1) ( u l ) CAS NO, 5 1 - 2 8 - 5 1 0 0 - 0 2 - 7 1 3 2 - 6 4 - 9 1 2 1 - 1 4 - 2 8 4 - 6 6 - 2 1 0 0 - 0 1 - 6 . . i ^ . > . - i - - : . i i : . - - .1. - 3 6 - 3 0 - 6 — 1 0 1 - 5 5 - 3 - 1 1 8 - 7 4 - 1 - - r-.—j r-. .- TA i.-/ / iZii.-..--- . 1 - 8 5 - 0 1 - 8 1 2 0 - 1 2 - 7 8 4 - 7 4 - 2 - 2 0 6 - 4 4 - 0 — 1 2 9 - 0 0 - 0 — (;:: 5 —<•:><;>••••/ - 91-94-1 218-01-9 117-81-7 117-34-0 *;. *..• -..' "•' ' z '.' ~ " *;. — 207-03-9 • 50-32-8 - "I O"^ ~TO..„i".„ —.. 53^ 70-3 — 191-2^!-2- COMPOUND 2,, 4-Din i tropheno 1 4-Nitrophenol - Di ben zoY"urari _ _. — 2,4-Din i trotoluene D i e 't Fl y 1 p Fi t. h a 1 a t o? - 4 - 0 l"i 1 o 1 - o Cl |-i e ri •/ ]. • - ("i h e n •/1 e t hi e r F" 1 Ll o r e n e 4 - N i t r o a n i 1 i n e • - 4 ,, 6""D i ri 3. t r o - 2 ~ M e t Fiy 1 p>beri Cj 1 _ • - F-l •" N i 11" o •iii o d i p h e n y 1 a rn i n e ( 1 ) . - 4•••• B roniCJ f> Fieri y.1 - |;:i Fien y 1 e L Fiei-.... lie X :7i. c I'l 1 o r o l::ien z e n e -F'ei'i LacFi].oropFierio 1 • • F'henari t h r e n e - "AnLFu"acerie... . ~ - D i •- n - B u t •/ ]. p h t h a 1 a t e . F' 1 u o r a n t Fien e p y r e? n e _ - B u t y l Fjen z y l p h t F > a l a t e _ ' 3 , 3 ' - D i c h l o r o b e i " ! z i d ino;^ Beri z o ( a ) Ari t F i r a c e i ' i e (!^ h r y s e I'l e Date Received: 01/25/95 Date Extracted: 01/30/195. Date Analyzed: 02/08/95 Dilut i ori F"ac toi- : .1.. 0 pi-!: _ 6 . A ^ . CONCENTRAT I OF-; ( u g / L ) Q y l ) P h t h a l a t e . h a l a t e b i s ( 2 - E t h y l h e x •— - D i - n - O c t y l Ph-F Bo>:-ri z o (t;i) F ' l u o r a n t h e n e B e 11 z o (I'..) F 1 Ll o r a ri t h e n e Ben z Cl ( a ) F'yre>ne I n d e n o ( 1 , 2 , 3 - c d ) F ' y r e n e —Di t'.ieri ;;•: ( a , Fi) Ari LFiraceri•;::•_ - — B e n z o v g , Fi,, i ) P e r ' / l e n e 2 0 2 0 Zl ^1 t:: 5 •'. 0 A TA ^ 1 i:: , . l s u 5 5 ' " i O £Krr rr i:: ._t 5 5 5 ^ 1 LJ 1..I LJ LJ LJ JKI o U J LJ LJ U U LJ VALIDATED Re'A..,od By [ ^ 1 ^ / ^ ^ ^ c X •0RF1 I Date LCSV-2 (/-({'fs 10 A\ 302882 • i_uw UUNC. WATER SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS Lab Name: ETC/GULF SOUTH Lab Code: GULJ" CA^^G NO.: HLA Lab Sample ID: VSROOl Lab File ID: SVVSROl Sample vol u m e : 1.Q.0 0 _. (ml) CoI'l ceri t r a ted Extra c t Vo 1 LIme : 1000 I n _i e c t i. ori Vi:j 1 LIme: LuPt. ('^ 1) C o n t r a c t : SAS N o . : ( u l ) S00012 SDG N o . : 95020 Date R e c e i v e d : OIZTXMUX Date E x t r a c t e d : 0:F/30/95 Date Analyzed: Q2/0B/9J7;, D i l u t i o n F a c t o r : 1.0 NuoiFier I ICs f o u n d CAG NUMBER 1 . COMPOUND NAME LJNFd-iOWN RT 1 8 . 0 5 T. CONC, ( u q / L ) 10 a A/ pevi''.vd By VALIDATED Date — y-^-9s FORM 1 LCSV-TIC .]. -.} Z / /:. 302883 M I u.rv ot::.! I-*i-Ji-i-i I J-l-Ui ui\iJHl-l i.i--o H l - i H l _ I o i o UH I H i:)riL-.L:. I Lab Name: ETC/GULF SOUTH L a b C o d e : GULF Case N o . : FLLA L a b S a m p l e I D : W G O O l C o n t r a c t : SAS N o . : BSOOi; Lab File ID: SVVVGOi: Sample volume: 1000 (ml) Con cen t ra ted E x t rAc t Vo1ume: 1000 Injection Volume: ;l:_-.0. (ul) COMF'OUND (ul SDG Ntj. : 95020 Date Received: Q 2 A2.3../ 9 5 Date Extracted: <)2:/.06./95 Date Analyzed: Q£/27/95 Di 1 Ll L:i.ori F a c t o r : 21.^.0. pi'l" _J>jJi CA$; 1 oe 111 9 5 - •95- l O f 10.:^ 62:1 6 7 - 9 8 - 7 3 - ' B :::;'• •• 105 1 1 :i 12C :i 2C 9 1 - :F 0/ 3 7 - i:: r • , .y ... 7 7 - r<p.-- f. i:: 9 1 - \'.fC'"' 1 3 1 2 0 b 6 0 6 9 9 - 0 3 - F-IO. „_ Q c: o ..-4,:i-4 5 7 - 8 - 4 3 - 7 - -60"" 1 - 4 4 - 5 - 6 4 - 7 7 2 - 1 - 9 5 - 3 - 5 9 - 1 - 7 5 - 5 - - 6 7 - 9 - 9 1 - 1 - 8 2 - 1 2 0 - 3 - - 4 7 - 8 6 8 - 3 - 5 0 ^ - 7 - i:: •"• ' „ .::i7....4.... 0 6 - 2 - 9!v,.....q.... i : : . — , ••:• ...1 ( : : • • - / • ••• -AA---'<-\-- - 1 1 - 3 r - . <• - 2 0 - 2 0 9 - 2 - 3 2 - 9 — F-'henol... _. b i s ( 2 ~ C h l o r o e t h y i ) E t h e r l " . ^ ^ ^ 2 - C h 1 o r o p Fien o 1 _ 2 - M e t h y l p h e n o l . . . _ 2^ 2 ' -oxyL":iis( 1—CFil o r o p r o p a n e ) - 4 - M e t h y 1 p h e n o ]. _ F-l - F-l :i. t r o -s o - D i - ri - F"' i- o !:• •/ ]. a iii i n e I-l e X a c l"i 1 o r' o e L hi a ri e N i L r o F.l e n z e n e •"- — 1 s o p h o r o n e • - 2"•• F-li t ropFlerio 1 _ 2 , 4 - D i m e t h y l p F i e n o l b i s (2""CFl 1 o r o o t Fioxy) I''l31hai'ie"I' 2 , 4 - D i e I "11 Cl r o n b e n o 1 1 , 2., 4 - T r i cFiloroFjori z e n e . N a IJ h t Fi a 1 e n e _ 4 - C F11 CJ I" Cl a ri i l i ri e j-le X a c h 1 o r o b u t a d i e n e — 4 - C F i l o r o - 3 - M e t F i y l p h e n o l • - - •••• 2 - I'^l e 11-I'/1 ri a p h L h a l e n e Fl e X a c Fl 1 Cj r CJ c: y c ;L o p e n L a cl i e ri e 2 , 4 , 6 " T r i c h l o r o p h e n o l . _ ZZ..... -- —'2 ,1 4 ., 5—Tl-ii. L:FiloropFieriol_ 2-1-1 i t r o a n i 1 i r i e . . . — D i m e t h y l P h t h a l a t e A c e n a p F i L Fiy 1 e n e 2 , •:?>-D -.i. n i t i'"o Lo 1 Lien e —3—i-li t r o a n i 1 :i, i le - A c e I'l a I"! hi L hi e ri e CONCENTRATION ( u g / L ) 1= .^1 5 c: ' " i i:: n: r j 5 in r: 13 rr 5 ' • • i ' " i 2 0 r: 0. t I B ; 1. J 3 ; LJ ; LJ ;u :u :u \yrR ; u :>^R ; I..J !U ; LJ : LJ \ V ^ R 'i-WR 'ZtiR \U3 ^.1 •' Tl :. K.' LJ J I I LJ LJ UJ Ll LJ LJ LJ I. J VALIDATED By Date ±±zl£. FTiRM 1 i...ci:; :,.<•.> A ' 302884 LOW CONC. WATER SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: ETC/GULF SOUTH Contract: Lab Code: GULF Case No.: HLA SAS No.: Lab Sample ID: VVGQOl Lab File ID: SVVVGOIZ Samp1e vo1ume: lOOp _ (ml) Con cen t ra ted Extract Volume: 1000 (u1) J'.ri i e c t ion V o 1 uf.ie : BS0013 SDG No.: 95020 1 A f , , 1 CAS 51- 100 132 121 84- 700 86- 100 534 86- 101 113 87- 85- :120 84- 206 129 85- 91- 56- 213 -.1 '.! 7 117 205 207 50- 193 i:: "."' 191 NO. 28-5 -02- -64- -14- 66-2 5-72 73-7 -01 - -52- 30-I;:' -"55- ..-7.CV- 86-;: 01-8 -12- 74-2 ...ai!\- -00- 68-7 94-1 TA TA .... -.- - 0 1 - ....QJ... -34- -99- -03" 32-r - »J T •" 70-3 -24- 7- 9- Ji. . —3 -.._.. 6- 1- ..._. 3— 1- — 7- 0- 0- ~ 9.... 7.... 0- r". A.. t? ..- 5- COMPOUND 2,4-Din i trophenol... 4-N i t r o p hen o 1 Di ben zoTuran 2j4"-Dini trotolLiene DiethylphtFialate 4-C Fl 1 o ro Cl l"ien y 1 - p hen y 1 e t lie r. 1-"1 u o r e n e 4-Ni t r o a n i 1 i n e 4 p 6 - D i n i t r o- 2- t'le t Fiy 1 p> Fien o 1 N-Ni t r o s o d i phenylamine ( 1) -4-B roino \x Fier 1 y 1 - p Fien y 1 e t Fie r._ F-le x a c Fi 1 o ro beri z en e F'en t a c Fi 1 o r o f ) Fieri o 1 F'lienan t h i r e n e _ A n t Fl r a c e n e _ J.. —D i -n —Eu.i t y l p Fi t hia 1 a t e F l u o r a n t h e n e F'yroi'ne ._ Bu t y l Fien z y 1 p h t Fia 1 a te_. 3,3'-Di chloroben z id ine - - Ben zo (a ) Ari tFiracene C Fl r • yz:> e n e _ — b i s (2-E thyi hexyi) Phthal ate, — D i -n -0 c ty ]. Ph t ha 1 a te... E<enzo( b)Fluoran thenos Ben zo ( k) Fl LIO ran th-ene Ben zo ( a) F'yrene Indeno (1,2,3-c.d ) F-/rene.. . _ -- -Di ben ?: ( a , Fi) An tFiracene Ben zo (g ., h , i ) F'eryleno? Date R e c e i v e d : 02/03/9;^5 Date E x t r a c t e d : 0 2 / 0 6 / 9 5 Date Analyzed: 0.Z/27./95 D i l u t i o n F a c t o r : ^^0 p H : 6.8 CONCENTRATION (ug/L) 20 20 5 5 Q : u j u lU u 20 20 5 5 5 20 5 Ct r: 5 5 5 5 5 5 S PZ- TZ ».l 5 5 5 5 5 5 . _. -.. _....- _-. .„ U LJ u U u u u LJ u u Li LJ U3 Ll l.j Pi>'^U ua u u u u u u VALIDATED, Rcr... . d B y l < ^ ^ (iPXLl Date ^ ' ^ 1 ' ' 95 FORM I LCSV-2 10/9; 302885 . LUW l.UNC. WATER SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS Lab Name: ETC/GULF SOUTH Contract: Lab Code: GULF Case N o . : HLA SAS N o . : Lab Sample ID: WGO.0.1 Lab File ID: SVVVGOIZ Sample v o 1 u m e'.: IjO 0_Q.... (m 1) C o 11 c e n t r ^i t e ci E! x t r a c t V o 1 u rn e : j^O 0 0_ In .i e c t i o n Vci 1 umo?: 1 - O (i.i 1 ) (ul) BS0013 SDG No.: 95020 Date Received: 02/03/95 Date Extracted: 02/06/9.5 Date Analyzed: Q2/27/.9.5 Dilution Factor: 1.^0... pH: _6..^8 II l.l (IIF J (^'r TlCii- i'oLind ;; 0 CAS NUMBER ; COMPOUND NAME R- EST. CONC- ( u g / L ) P Date VALinATED, • Cy liUy>'U^ /O^CZ^ ?S FORM T I C 302886