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vrCHEM .S:tTE ADMINSTRATIVB RECOBn~IHPEX ~.O SPI'E IDENTIFTCA"TION SDMS Document 1111111111111111111111111111111111111111 114885 1 .. 1 . Correspondence -.. R?quest. for inspection .from· G.e:o~ge ."" ...... """' .......... , .... , USEPAEnforcement· toRichard-:;:S~lki,e, ·,'fls.EPA ~ Rem;o;v:al~ :P%pgrams, January 23, 1989 1:.2 .' -Erel iminary' 'Assessment ~epart ~ - .USEPA Te-ch.."li:cal Assi1;.tanceTeam ~('T1I.:T) I~~: ,:FebrUary:.1,O, 1:989 L. 3 A)ata~' Tables· -' USEPA TAT,' March: {l9.89 1'.4 Preliminary :Assessment Report - USEPA>FO'!'m 2070.-:12 r,·~tlay '1:9£9 . . L 5 PoJ:r:ep. 1.,,25,3 .. - 2.0 .. REMOVAL' 'RESPONSE 2 .1 Ac.tion "M.emorahdum signed August 8, 1989 inclUding 'attachments 3.0 .ENFORCEMENT 3.1 RCRK.Ehf:orceme:r:t Interim Repo:r,t, .... September, ,.9,_, 19.85 3.2 RCRA Enforcement 'Interim:. Repo:r:t, March.. ,1.:9'86 4.0 HEALTH ASSESSMENTS '4.1 site Safety Plan (latest revision) 5.0 'PUBLIC PARTICIPATION 5.1 Community Relations Plan .... __ --...,. _. '-' ..... ' " ..... '-' ! 1..-1..1,1 L-nt'-n P.2 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY DATE: JAN .%31889 "REGION II :0:\,- c; :: Ill~iJc~t:i~l'1 ~f th<!; Isle.ndCh~m!e8.l Oi~e ill C~. O]!tOill, -r: .. : USV! to determine if a Removal Action is warranted • ~,~"O~~ under CERCLA. 0 A. _ FROM: ~~\p....I~ George Pav!ou, Associat.e Director TO: Enforcement Programs. Hicnara ~alkie, Associate ~!rector Removal Programs. On NovembE~r 9th, representatives from EPA and the Department of Planning & Natural Resouroe CDPNR) conducted a site visit of the Island ehE!mlcal Sica. The t!iittrl visit revealed that a portion of the main building contains large amounts of stored chemicals in bags and (!rums. Some of the chemica~s included: sodium --- hydroxid@, toluen~, snlf~min ~n1d (qr~nular), potassium sulfate and benzyl chloride. Many of the baqs and drums have ruptured and their contents have spilled onto th~ floor; there are pools of liquidfJ , and powders dispersed throughout. Many of the drums hQ.vt::::! !-'vz. L.~VH:::O v£ L.1n::i1: IIYid-':ofI ~u.t.6d I oth~r.., she" 4a",,~.!:" s!iJftS such as bulkin9, pitting, and vial]:)le accumulation around the tops. You should also know that the PRP is conducting a ReM §3013 invt!!stigation pursuant to an AO with EPA. It is rec<:nlllnended that this site be evaluated by your staff and/or contractor to determine whether a removal aotion is warranted. If your staff has any questions, please contact Ms. Sla:=LLlZll D. H~m.:y 6.E i\\y st.aff at (212) 2C4. -OC,!. oc: Carlos O'Neill, CFO REGION II 'OA .. 1320--1 (1186) .- '. \' '( j :l ' -~i\.. ~ \: 0 I 0 \'\/"' ~~"..~~ ~~[A LA.J~J\~.u ~ I L5 Suite 201, 1090 King Georges Post Road, Edison, NJ 08837 • (20 I) 225-6116 TECH~ICAL ASSISTANCE TEAM FOR E.\1ERGENCY RESPONSE REMOVAL AND PREVENTION EPA COl\TRACT 68-01-7367 TAT-02-F-05117 TO: Doug Kodama, OSC u.s. EPA Response and Prevention Branch FROM: Michael Mentzel, TAT-~ Jeff Bechtel, TAT-2 ~ SUBJECT: Virgin' Islands Chemical Company (VI CHEM) Removal site Evaluation and Site Investigation. DATE: February 10 '.' 1989 INTRODUCTIOII; On Tuesday, January 31, 1989, the u.S. EPA Response and Prevent.ion Branch conducted a Preliminary Assessment and Remova.l Evaluation at the Virgin Islands Chemical Company (VI CHEM) site in st. Croix, U. S. V. I. This action is in reply to a request from George Pavlou, Associate Director Enforcement Programs dated January 23, 1989. PERSONNEL Doug Kodama u.s. EPA R & P Branch Adalberto Bosque U.S. EPA CFO Michael Mentzel Jeff Bechtel TAT-2 Arnaldo Martinez TAT-21 (201) 906-6905 Edison, N.J. (809) 729-6915 Santurce, P.R. (201) 225-6116 Edison, N.J. (809) 723-8466 Santurce, P.R. (809) 773-0565 st. Croix, V. I. Francine Lang Leonard Reed Henry Thomas Greg Rhymer V.I. Department (DPNR) of Planning and Natural Resources Roy F. Weston, Inc. SPILL PREVENTION & E.\tERGENCY RESPONSE DIVISION 1.20 TAT 2/10/89 ASSESS RPT In Association with ICF Technology, Inc., C.C. Johnson & ,~aJhotra, P.C., Resource Applications, Inc., Geo/Resource Consultants, Inc., and Environmental Toxicology International, Inc. BACKGROUND AND HISTORY The Virgin Island Chemical Company (VICHEM) site is located on the Island's south side. The site is situated on Route 66, approximately 0.5 miles due north of the Alexander Hamilton Airport. The site covers approximately 3.5 acres and is bordered to the north by an intermittent stream that originates on the north side of the Island and discharges into the Caribbean Sea. \ See Figure 1) A number of residences and industries are located as close as one-tenth of a mile from the site. In addition, several well fields are located in the vicinity of the site. The st. Croix prison is located 1/4 mile downwind from the site. DPNR stated it would be very difficult to evacuate prisoners in the event of a chemical fire at the site. Presently occupying the site is th-e company VIAG Fuels, Inc. VIAG utilizes some office space in the main building and also has ethanol stored in four Qf the aboveground tanks. The principals of the firm plan to begin an alcohol dehydration project on-site in the near future. The 3.5 acre site is owned by Charles H. Steffey, Inc. On May 1, 1969 Steffey leased the property to Houston Chemical Industries, Inc. Houston Chemical assigned the lease to Caribe Chemical Company, Inc., (subsequently known as Pierrel America, Inc.) on March 20, 1972. On June, 1978, Pierrel America assigned the ground lease to Cooper Laboratories, Inc. (Cooper). On October 30, 1979 Cooper Laboratories assigned the lease to its subsidiary, Island Chemical Company (ICC). On November 1, 1979, Cooper Laboratories sold all of the stock of ICC to the predecessor of Berlex Laboratories, Inc. (Berlex). On September 14, 1984, ICC sold its assets to Virgin Island Chemical Company (VICHEM). This background information has been supplied by the Virgin Islands Department of Planning and Natural Resources (DPNR). Limited PRP (Berlex) site clean-up and soil excavation has taken place in the recent past under a RCRA enforcement action. Berlex is currently finalizing a scope of work for a remedial investigation/feasibility study addressing soil and groundwater ~contamination. The Governors office Department of Fire Services was contacted to assess local chemical fire control capabilities. Three fire companies are located on the island with the nearest to the site being Grove Place. All firefighting personnel are equipped with SCBA, however, only some have had formalized chemical hazard training. A limited amount of foam capability is available. 2 ST. CROIX c::7 ~'---' .~-; . .. : .. 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Inc. 3 . _.; .. .. .. ~- .. EPA PM KODAMA TAT ?M MENTZEL FIGURE 1 SITE LOCATION VI CHEM. SITE ST. CROIX US VI CHRONOLOGY OF EVENTS Thursday 1/26/89: Monday 1/30/89: Tuesday 1/31/89: Wednesday 2/1/89: Thursday 2/2/89: Gear sent to st. Croix from Edison, N.J. TAT personnel in st. Croix, supplies and gear prepared. Initial site entry. PRP (Southerland) interviewed by OSC. TAT and DPNR perform inventory of materials. Report generated, community survey conducted and gear shipped back to N.J. INITIAL SITE CONDITIONS The site consists of a main warehouse building including offices, the reactor and centrifuge buildings and twenty-two aboveground tanks. Living on-site adjacent to the main warehouse building are anywh~re from 15-25 guard dogs stored in individual kennels. (See Figure 2). A house loading restroom 24, 28,29 Also living on-site is the kennel operator, Kate Wesp. trailer is located on the concrete surface near the dock. It is also apparent that Wesp uses the facilities and kitchen area in the main building (rooms Figure 3), as living quarters. The initial entry into 'the main warehouse building was made at 0930 hrs. on January 31, 1989. All safety procedures were followed for a level "B" entry in a hot climate. Air monitoring was conducted with OVA, HNU, CGI, Radiation Detector, HCN Monitox, H2S Monitox and pyridine Draeger tubes. All ambient air monitoring readings were equivalent to background (taken off site), except for Room 5 which showed ambient conditions 1-2 units above background on the OVA. All further entries were made in level "C" with continuous air monitoring. This preliminary assessment was coordinated with and observed by DPNR personnel. DPNR's primary concerns with this site are the threat of fire/explosion, and the threat (or actual) migration of spilled materials to the surrounding soil and groundwater. On Wednesday, February 1, 1989, three TAT members and one DPNR person compiled a full inventory of lab chemicals, drums and tanks located throughout the site. The inventory consisted of listing information found on container labels as well as recording any observations. Refer to Tables 1 and 2 for a complete listing of containers and volumes. No samples to confirm the identity of any material were taken at this time. 4 • ""Ell a6 I s J C~"C' O I O :. - '2 , .. II"Q 1 - 5 2 G:J GJ CI!:J&4 co,..c~eTE SURFACE Wa,. "o"l . $19 ~ OS o olie T, n _ $17 <=Q CO CIJ&3 (2J CQ 2 CD ~ I &2 • c::J GJ CD c::J 2"& F H'" $1 = 2 ~ o .. u .. :2 :J .. > .. ~ • .. • ° • • ~ • ~ o CONC~E T E SURFACE _____ $10' ... 0, , In a 1:;=-- II -- A I, ttl.C I . ' ......... .. p.c C 0"0 _II ~ --21 Cuo •••• .. ---1_ 1 o COOII"OO c::::J 0 To • . , ~ ~f;:)O 0 I 5.5. " •• cto, A" , I r i 00 1011 . , . c:::=:J 0 DOe e e 08 I SI,,,'" O"ln Alr~ RI02 AlaI 000 0c.nl. 00 0. " .. , 10' lu.ICllno o 01 , •• A •• clo, ", • • R.O . unit AnllD w o t . , SIO"O ' o CI2 510"0 . SIO'" 0, .. " co. C oo.lnO WEll • '\.AHT !HT~"'HCf ~~ S?'L!... PGE" l ENnON & E~AE::;Gc::-IC( ~E~?ONSE DIVISION In ~liun "",lh ICFTcchnoiOlflllnc.. C.":john...,n '* '\-''iOCWc:::s. Inc., R<eSOurcc .\pplic:luoru. Inc.. GclJl Rooun::c Con..,ult:lntS. Inc.. :lI\cJ EnvironmcnQJ To~i(oIOICY 100ent:lUOn:l.l. Inc. 5 EPA PM KODAMA TAT PM MENTZEL e1S &16 e15 ') ,,-, ",,- "., A "" U (Ii ·fi o. ". , a'o, A"II '1,. 1""'.11 S .. "III"e o H ' ~ : Se al. FIGURE 2 SITE DIAGRAM :J VI CHE.'1 SrTE ST . CROIX US VI .. ~ 006-5 I Lo~dlhg Oock ~ 6 B CONCRETE SURFACE Wsr.hou~$ o HOUSE TR.ULER LaB ~ (alt. 29 24 , • • , 11 ~ ,,! ... 1.- !a"t~ 27 .- "') L ... 411 "'" L. • loJ IJ"I 1 0 ~tll Cl~5 - 18 14 1 • ' .,....., -I 26 n-'- 20 9 l131 17 \....I 8 211 ! _ i 25 ~ I. 23 ! ,111:,1 16 : ll7 I , O (MT) --"r (MT) --- DRUM AREA = 1,3,4,5,6 LAB AREA = 11,15,18,22 WORK AREA/= 2,7,8,10,12,13,14, NO CHEMICALS 16,17,19,20,21 O?FICE = 23,24,25,26,27,28,29 c=J(1/4) c:J (MT) c::J (3/4) CJ "" TAlrKS (volume) o ,.. DRUMS ~ SPILL PREVENTION & EMERGENCY RESPONSE DIVISION EPA PM KODAl'1A In .\.ss()ciation with ICFTechnology Inc.. C.C.johnson &: As. ... x:iates. Inc. Resource .. \pplicuions. Inc.. GeoiRe50urce Consultants. Inc .. ;lnd En~;ronment:1.l Toxicology International. Inc. 6 TAT PM MENTZEL 5 4 3 f • - 2 ~.jL 1 r-----\ ; PAINT', /'} 0 :\. CAJ.'J"S \ v(J 0 ----, CDRUMS \) (""'. : TRASH \ . I I' 0 / ~I D( 31 4) 0(1/4) DC 1/4) t N FIGURE 3 MAIN BUILDING VI CHEM SITE ST. CROIX US VI Photographs of site conditions were taken and are included as Appendix I. DESCRIPTION OF MATERIALS Three areas were delineated based upon the type of material located in each. These areas are: A. The laboratory (Rooms 11, 15, 18 and 22 Figure 3). B. The drum storage warehouse (Rooms 1, 3, 4, 5 and 6 Figure 3). C. The grounds outside the building including the centrifuge and maintenance buildings and the reactor area. (Figure 2). , Each of these areas will be described below. A. Laboratory , 813 containers of laboratory reagents and unknown liquid and solid material are located in this area. Room 22 is the main lab area, Room 18 is the lab storage area, Room 15 contains unmarked glassware and Room 11 contains only a few items. Some of the more dangerous items of note are as follows: 1. Sodium metal (2 boxes). Water reactive. (Photo #7). 2 . Ethyl Ether (6 cans). Potential explosive. (Photo #12). 3. Diisobutyl aluminum hydride (4 lecture bottles). Spontaneously combusts in air. 4. Potassium cyanide (2 bottles). Poisonous. Stored near acids, potential for release of hydrogen cyanide gas. 5. Phosphorous pentoxide (1 bottle). Reactive. 6. Sodium hydride (1 pound). Water reactive. 7. Two flammable storage cabinets containing various materials and unknowns. (Photo #12). 8. Two office type storage cabinets. One cabinet has spilled material on the top shelf which has dripped downward to mix with other chemicals. (Photos #10 and #11). Many other chemicals exist in the laboratory, as well as many containers with unknown materials. All the chemicals which had dates are at least five years old. Refer to Table 1. 2. Drum Storage Warehouse In the main warehouse are located approximately 400 drums, 7 and bags of material of these, 211 are green painted drums which have the words ETHYL ALCOHOL stenciled on the lid. The condition of the ethyl alcohol drums vary from fairly sound to extremely deteriorated. Some of the drums consist of only a rusted shell with gaping corroded holes. A rough estimate shows that half are empty and half contain material. This material may be some type of sludge. A summary of other materials found are as follows. Refer to Table 2 for a complete inventory of drums. 1. Laboratory unknowns (75 containers less than 1 gal. ) 2. Methanol (5 x 55 gal.) 3. Glacial acetic acid (13 x 55 gal.) 4. Benzyl acetate (21 x 55 gal.) 5. Toluene (8 x 55 gal.) 6. Antifreeze/glycol (20 x 55 gal.) 7. Benzyl chloride (28 x'~5 gal.) 8. Salicilic .acid (27 fiber drums) 9. Methyl isobutyl carbinol (12 x 55 gal.) 10. Sodium hydroxide (12 x 55 gal.) 11. Bulging drum, unmarked (1) 12. Drums in which some type of reaction has taken place, lid popped off (2) (Photo #6). 13. Many other drums with contents as shown in table 2. 14. Drums of known and unknown material. 15. Paint (97 x 5 gal. - 21 x 1 gal.) 16. Cylinder chlorine (1). (Photo #14). 17. Cylinder hydrogen chloride (1). 18. One drum of sulfamic acid, broken and leaking its contents. (Photo #17). 19. A cistern with PVC pipe leading to a pumping system outside the building. 20. Another cistern is located in the NW corner of Room 6. c. outside Grounds An inspection of the maintenance and centrifuge buildings, the reactor area and the entire site property revealed various production materials including lubricating oils; propane, oxygen and acetylene cylinders; filter media; ethanol; assorted paints and some sodium hexa-meta phosphate. Some of the oil drums are leaking. Scattered around the facility are eight stainless :steel tanks with quantities of unknown liquid varying from empty to three quarters full (see Figure 2). A large storage tank is on site along with numerous pressure and reaction vessels. Fourteen large green storage tanks are also on- site. Ten are planned to be used in the alcohol dehydration 8 project. Four of the ten are full of ethanol. The other six are empty. The remaining four not being used are empty and unsound. Two abandoned tank trucks are also left on-site. The status and ownership of these tank trucks is unknown. Also three transfcrmers located on a power pole inside the west fence line were observed to be leakin~ their contents, (possibly PCB oil), onto the ground. THREAT An imminent hazard from direct exposure to chemicals through contact, ingestion, or through inhalation exists directed at persons and workers who are on-site. All personnel have free access to the laboratory and drum storage areas. Only an unlocked wooden door exists between the laboratory and the presently occupied office. area (see photographs #5 and #6). Some of the persons who daily'"visit or live on-site have no knowledge of the hazards associated with the stored chemicals. Also affected are the dogs which are housed on site (see photograph #2) • Incompatible materials are stored in close proximity in the laboratory area. The potential for adverse reactions is real and will continue to increase as the chemicals age. At least three examples of reactions taking place are evident in the drum storage area. These consist of one bulging drum and the tWD drums in which an unknown foam like material has exerted enough pressure to push the drum lids up 2-3 inches (see photograph #16) . Another pathway of exposure to a release is through fire or explosion. Nearby residences, a local engineering/construction firm and the VI prison population could be severely impacted by toxic laden smoke. Although steps have been taken to implement a chemical emergency preparedness program, the fire department may not be able to control a chemical fire and evacuate affected persons during a life threatening emergency. The third pathway to exposure is through groundwater contamination. Chemical discharges into a local intermitted stream have been documented by the EPA and DPNR. Chloroform was detected in the on-site well at a level of 130 ug/l by the EPA RCRA Enforcement Branch. Wells located off-site were sampled and analyzed by this branch in March and November, 1988. Chloroform contamination was found in five wells located near the site in concentrations ranging from 11 ug/l to 75 ug/l. 9 TABLE 1 Laboratory Reagent Inventory CHEXICAL NAl.'1E l,3-dinitrobenzene I-butanol 1-chlorobutane I-propanol 18-Crown-6 99% 2,2-oxydiethanol 2,6-dimethoxybenzoic acid99% 2,6-ditertiarybutyl p-cresol 2-hydroxybenzyl alcohol 99% 2-hydroxyethyl ether 2-methyl-l-butanol 99% 2-methylbutyl amine 3,3-dimethoxy benzidene 3-hydroxybenzoin acid 4-chlorobenzene sulfonamide 4-hydroxy 4methyl 2pentanone 4-hydroxybenzoic acid 4-methylbenzo phenone 97% 9-hydroxyflourene Acetic acid Acetone Acetonitrile Alkalinity C,D,E,G Aluminum Chloride Aluminum chloride Ammonium acetate Ammonium acetate Ammonium acetate purified Ammonium hydroxide Ammonium persulfate Ammonium persulfate Ammonium thiocyanate Amyl alcohol Arsenic trioxide Barium c:::loride Barium chloride Barium chloride Barium hydroxide Benzaldehyde Benze!"1e COMPANY Aldrich Chemical J . T . Baker" -Chemical MCB J.T.Baker Chemical Aldrich Chemical Kodak Aldrich Chemical Biesterfeld Aldrich Chemical Aldrich Chemical Aldrich Chemical American Laboratorie Kodak Aldrich Chemical Aldrich Chemical Aldrich Chemical Aldrich Chemical Aldrich Chemical Aldrich Chemical MCB Fisher Scientific Supelco Mogul Corporation Mallinckrodt wit co Chemical Fluka Aldrich Chemical Jarchem Industries Sargent Welch Scient J.T.Baker Chemical J.T.Baker Chemical Fisher Scientific Mallinckrodt Fisher Scientific Dre'N' Chemical Mallinckrodt Fisher Scientific Fisher Scientific J.T.Baker Chemical Tenneco Oil 10 QTY 100 g 500 ml 4 L 500 ml 25 g 1 kg 25 g 500 g 25 g 1 kg 10 g 15 g 100 g 100 g 100 g 500 g 50 g 50 g 2x25 g 2x5 lb 4 L 1 box 4x2 oz 1 lb 500 g 1 kg 2 kg 250 g 500 ml 2.5 kg 500 g 500 g 1 pt 2xl13g 1 qt 500 g 1 lb 1 Ib 500 ml 2x1gal STATE ===== solid liquid liquid liquid solid liquid solid solid liquid liquid liquid liquid solid solid solid liquid solid solid solid liquid liquid liquid liquid solid solid solid solid solid liquid solid solid liquid liquid solid liquid solid solid solid licuid liquid Benzhydrol Benzoic acid Benzoin Benzoin 98% Benzophenone Benzophenone Benzophenone Benzophenone 99+% Benzoyl chloride Benzyl acetate 99% Benzyl alcohol Benzyl benzoate Benzyl chloride Benzyl chloride Benzyl cinnamate 98% Benzyl ether Benzyltriethylammoniumchlori Bismuth subnitrate Bromine Bromophenol blue Brucine sulf?'l.te Buffer solution pH 1e.00 Buffer solution pH 4.00 Buffer solution pH 7.00 CAO-3 BHT Calcium sulfate anhydrous Cello-Seal Chloride 'E' Chlorodiphenyl metha:-:::a 98% Chloroform Chromotropic acid Na salt Cinnamaldehyde citric acid anhvdrous citricacidtrisodiumdihydrate Cobalt chloride Color standard 4 Congo red Copper metal Cupric sulfate Cupric sulfate DPD #1,2,3 Reagents Dibenzo 18-Crown-6 98% Dibenzoyl tartaric acid Dichloroethane 99% Dichlorophenyl methane 99% Dichlorotoluene 99% Diethylene glycol Diisobutyl aluminum hydride Diphenylmethane 99% Diphenylthiocarbazone Eosin Y Ether anhydrous Ethoxyguin Ethyl acetate Ethyl acetate Ethyl benzene Ethyl ether 99% Ferric ammonium sulfate Kodak Mobay Chemical Fluka Aldrich Chemical Aldrich Chemical H£S Chemical Upjohn Aldrich Chemical Mobay Chemical Aldrich Chemical Mallinckrodt Aldrich Chemical unknown Velsicol Aldrich Chemical Aldrich Chemical Aldrich Chemical MCB Fisher Scientific Fisher Scientific Fisher Scientific Fisher Chemical Fisher Scientific Fisher Chemical Shen.Jin Williams W.A.Hamrnond Drierite Fisher Scientific Mogul Corporation Aldrich Chemical Fisher Scientific Fisher Scientific unknown J.T.Baker Chemical Aldrich Chemical Fisher Scientific unknown Fisher Scientific Fisher Scientific Fisher Scientific Mallinckrodt Taylor Chemical Aldrich Chemical Knoll Fine Chemicals Aldrich Chemical Aldrich Chemical Aldrich Chemical Fisher Scientific Texas Acres Aldrich Chemical Fisher Scientific Aldrich Chemical Fisher Scientific unknown Aldrich Chemical MCB Dupont Fisher Scientific Fisher Scientific 11 100 g 1 lb 2x1 kg 4x500g 500 g 1 bag 500 g 50 g 1 lb 100 g 1 pt 100 g 4 oz 500 g 100 g 1 kg 25 g 1 lb 113 g 5 g 1 oz 500 ml 500 ml 500 ml 1 bag 4x5 Ib 25 g 3 oz 100 g 4 L 25 g 2x1 kg 500 g 1 kg 2x1 lb 1 oz 25 g 500 g 500 g 500 g 3x1 oz 50 g 1 kg 1 kg 25 g 100 g 1 qt 4 cyl 500 g 25 g 25 g 4 qt 4 oz 5 gal 5x1gal 1 qt 6x500g 500 g solid solid solid solid solid solid solid solid solid liquid liquid liquid liquid liquid solid liquid solid solid liquid solid solid liquid liquid liquid solid solid liquid liquid solid liquid solid liquid solid solid solid liquid solid solid solid solid liquid solid solid liquid solid selid liquid gas liquid solid solid liquid liquid liquid liquid liauid liqiud solid Ferric chloride Ferric chloride Ferric chloride anhydrous Ferric chloride anhydrous Ferrous ammonium sulfate For:nic acid Glacial acetic acid Hydrazine sulfate Hydrazine sulfate Hydrochloric acid Hydrochloric acid Hydroxylamine hydrochloride Hydroxylamine hydrochloride Iodine Iron chloride anhydrous Isoamyl alcohol Isobutyl alcohol Lead acetate Lead nitrate Lithium perchlorate Magnesium sulfate Medical oxygen Mercuric chloride Hercuric oxide Mesityl oxide Methanol Methenamine Methyl alcohol Methyl orange Methyl red Monochlorobenzene N-methylaniline Na salt of ME salicylate Niaci!1 N.F. Nitric acid concentrated Nitrobenzene Non aqueous buffer saln. Nutrizyme oil #3 Paraffin oil Parafo~aldehyde Paraformaldehyde prills 91% Perchloric acid Phenol red Phenopthalein Phenylhydrazine Phenylhydrazinehydrachloride Phosphorous pentoxide Piperazine Potassium bromide Potassium butoxide Potassium chloride Potassium cyanate Potassium cyanide Potassium dichromate Potassium ferrocyanide Potassiu~ hydroxide Potassium hydroxide unknown Fisher Chemical Pennwalt corporation Kodak Fisher Chemical unknown Fisher Chemical Fisher Scientific Fisher Scientific MCB Fisher Chemical Fisher Scientific MCB Fisher Scientific BASF Fisher Scientific J.T.Baker Chemical MCB Fisher Scientific Aldrich Chemical Fisher Scientific MSA Fisher Scientific Fisher Scientific Aldrich Chemical Fisher Scientific Fisher Scientific Mallinckrodt Fisher Scientific Fisher Scie~tific PPG Industries Kodak Sattra Chemical Nepera Chemical J.T.Baker Chemical Fisher Scientific Bec~~an Instruments Merck Frich Oil Fisher Scientific MCB Celanese Chemical MCB Fisher Scientific Fisher Scientific Fisher Scientific Fisher Scientific Fisher Scientific MCB Fisher Scientific Callery Chemical Beckman Instruments Fisher Scientific Fisher scientific Fisher Scientific Fisher Scientific Mallinckrodt Fisher Scientific 12 100 ml 1 lb 5x500g 500 9 1 lb 200 9 5 lb 4 oz 100 9 2x6 lb 3x1 L 1 kg 4 oz 500 9 500 9 500 ml 500 ml 1 lb 100 9 500 9 500 9 1 cyl 2x100g 500 9 100 9 4 L 500 9 1 gal 113 9 2x10 9 10 oz 1 kg 1 bag 250 9 2x8 lb 1 qt 1 pt 2 oz 5 gal 1 qt 1 qt 1 lb 2x8 Ib 5 9 1 oz 4x4 oz 2 lb 1 lb 100 9 5x500g 50 9 2x6 oz 1 lb 500 9 500 9 3 kg 2xl lb 500 9 liquid solid solid solid solid liquid liquid solid solid liquid liquid solid solid solid solid liquid liquid solid solid solid solid gas solid solid solid liquid solid liquid solid liquid liquid solid solid liquid liquid liquid solid liquid liquid liquid solid liquid solid solid liquid solid solid solid solid solid solid solid solid solid solid solid solid potassium iodide Potassium iodide pot~ssium periodate Potassium platinate Potassium sulfate Potassium sulfate potassium sulfate Potassium thiocyanate Resorcinol salicylaldehyde 99+% salicylic acid salicylic acid salicylic acid sodium salt sicapent Silica gel dessicant Silver nitrate silver nitrate Sodium Chloride Sodium acetate Sodium acetate anhydrous Sodium acetate anhydrous Sodium amide Sodium benzoate Sodium benzoate Sodium benzoate Sodium benzoate Sodium borohydride Sodium carbonate Sodium carbonate anhydrous Sodium chlorate Sodium dichromate Sodium formate Sodium hydride Sodium hydroxide Sodium metal Sodium nitrite Sodium nitro ferricyanide Sodium sulfate Sodium tartrate Sodium tartrate Sodium thiosulfate Succinic anhydride Succinic anhydride Sulfamic acid Sulfanilic acid sulfite O,P,Q Sulfuric acid Tetraphenolboron sodium 99% Thiopene Total alkylinity indicator Tributyl borate Trichloroethylene Triethyl borate 97% Triethylenediamine Weedox CjR 250 herbicide Xylene 7' .,. ~ 4o.oI.lr1C C:l.J...orl-.e zir.c chloride ar.hydrous Ore T"; Chemical Fisher Scientific Fisher Scientific Varlacold Chemical Indiana A=my &~o Plant Aldrich Chemical unknown Fisher Scientific Koppers Aldrich Chemical Aldrich Chemical Aceto Chemical Aldrich Chemical MCB Davison Chemical J.T.Baker Chemical Sargent Welch Scientific Fisher Scientific Sattra Chemical Niacet Co'rporation COF Chimie Noth America Farchan Research Lab Sattra Chemical Oastech International Ishihara Corporation Pfizer Fisher Scientific Fisher Scientific Mallinckrodt Hooker Chemical Fisher Scientific unknown ThiokoljVentron Division Mallinckrodt RJlI Fisher Scientific MCB Fisher Scientific J.T.Baker Chemical Fisher Scientific Fisher Scientific MCB Aldrich Chemical Fisher Scientific H&S Chemical Mogul Corporation J.T.Baker Chemical Aldrich Chemical Kodak Ore'..; Chemical Aldrich Chemical Mallinckrodt Aldrich Chemical Air Products Southern Mill Creek Prod. Fisher Scientific Fisher Scientific Mineral Research 13 1 qt 2x500g 100 9 5 9 250 9 500 9 50 9 500 9 3 bags 100 9 100 9 500 9 100 9 2.8 L 2xl qt 1 oz 30 9 500 9 3 bags 250 9 2x500g 500 9 1 bag 1 bag 250 9 100 lb 4x25 9 1 kg 1 Ib 1 box 10 kg 5 lb 1 lb 500 9 2 boxs 2x500g 4 oz 500 9 2 oz 6xl13g 2x1 lb 6x250g 2x1 kg 500 9 1 bag 3x2 oz 10 lb 25 9 100 9 1 qt 750 9 1 pt 100 9 250 9 2x5gal 5xl L 500 9 1 Ib liquic. solid solid solid solid solid solid solid solid liquid solid solid solid solid solid solid solid solid solid solid solid solid solid solid solid solid solid solid solid solid sol,id solid solid solid solid solid solid solid solid solid solid solid solid solid solid liquid liquid solid liquid liquid liquid liquid liquid solid liquid liquid solid solid p-chlorobenzene sulfonamide p-naptholbenzein p-toluenesulfonicmonohydrate pH indicator A z Miscellaneous unk~owns z Miscellaneous unknowns .~:. H&S Chemical Fisher Scientific Aldrich Chemical Mogul Corporation on site lab glassware on site one oz bottles 14 2 bags 25 g 500 g 2 oz 280bot 238bot solid solid solid liquid misc. liquid Chemical Name Acetone Acetylene Activated carbon All-weather patch Amersite 2 Ashland MeOH Benzyl acetate Benzyl chloride Chlorine Chlo!:"oform Crofox material Crystal Clear floor finish Degreaser Drewtrol 8500 Ethyl alcohol Filteraid Glacial acetic acid Glycol Humisorb Hydrochloric acid Hydrogen chloride Insulation (asbestos??) Insulation fiberglass Lubricating oil TABLE 2 Drum Inventory Company Ashland Chemical VI Gas Calgon Corporation Revere Chemical Valley Freight Syst. Ashland Chemical Island Chemical Velsicol Corporation VI Gas unknown Cerfact Laboratories Cerfact Laboratories unknown Valley Freight Syst. unknown unknown Celanese Chemical Island Chemical Culligan certified Laboratory VI Gas unknown unknown Texaco Texaco Lubricating oil Magnesium sulfate Methanol trihydrate Tcmita Pharmaceutica Ashland Chemical Methanol Methyl isobutyl carbinol Methyl isobutyl ketone Micro media filter sheets Oxygen Oxygen Paints Paints Paints Paints Para-phenetidin Pentosin Potassium acetate Potassium sulfate Powdered filter media Propane Purafil II Quinine sulfate Rinseline injector fluid unknown Van Waters & Rogers Ashland Chemical Ertel Engineering VI Gas Santa Maria Gases unknown unknown International Paint International Paint unknown Deutsche Pentosin Jarchem Industries unknown Ionics unknown unknown Kimafarma Bob Chamber Ltd. 15 Qty 55 G 2 cyl 30 bag 55 G 55 G 5 G 21x55G 28x55G 1 cyl 55 G 55 G 2x20 G 55 G 55 G 115x55 10x30G 13x55G 20x55G 30 G 55 G 1 cyl 13 box 7 box 2xl0 G 5x55 G 6x25kg 5x55 G 3x55 G 12x55G 55 G 18 box 3 cyl 1 cyl 44x5 G 53xl G 97x5 G 21x1 G 55 G 20 L 8xl00# 50 bag 2 boxs 4 cyl 15xl0G 20 G 55 G state ===== liquid gas solid solid liquid liquid liquid gas liquid liquid liquid liquid liquid liquid solid liquid liquid solid liquid gas solid solid liquid liquid solid liquid liquid liquid liquid solid gas gas liquid liquid liquid liquid liquid liquid solid solid solid gas solid liquid liquid Rout Salicylic acid Salt Soda ash Sodium acetate anhydrous Sodium acetate anhydrous Sodium bicarbonate Sodium hexa-meta phosphate Sodium hydroxide Sodium hydroxide Spent toluene/acetone Sterling salt crystals Sulfamic acid Tartaric acid Thinner Thinner Toluene Toluene Triethylamine Waste oil z Empty drums z Miscellaneous unknowns Cerfact Laboratories Rhone-Poulenc unknown Allied Chemical unknown Jarchem Industries Stauffer Chemical FMC Mantek Manuel del Valle Inc unknown unknown Dupont Pfizer Chemical unknown Advance Ashland Chemical unknown Air Products unknown unknown on site containers 16 20 G 27drum 2x30 G 15x100 50 lb 200 lb 8xlOO# 200 lb 55 G 12x55G 2x55 G 50 lb 400 lb 15xlOO 6x1 G 55 G 3x55 G 5x55 G 55 G 2x55 G 130 25 solid solid solid solid solid solid solid solid liquid liquid liquid solid solid solid liquid liquid liquid liquid liquid liquid n/a misc. SHdW~O.LOHd .. I XIGN3:ddV ,_. Photo 1 1. Virgin Island Chemical Company Alcohol dehydration apparatus Photo ~2. Dog kennel operating on site Photo #3. Xaintenance building Photo #4. View of tanks, main building, and alcohol dehydration unit .. - --..~- ~ "~~' "-- r-.-.' - - . '~:- . ..:. ~ . . .... "'-::--..:...." . . - . . ~ .- --- - 81 Ba~B UT T BJ~= =r.T?OS i UBdwoJ le ~J w a 4J p~ 2 ~S: ~ ; Z; T ~ ' L~ C J O~ ~ Photo ~9. Incocpatable storage of lab reagents Photo ~lO. Incocpatable and leaking storage of lab reagents Photo :! ~L . lnc oc?atable and leaking storage of lab reagents ~- ?\1oC ,) ~~C ( l:7: :J;lC,lh L c: sc o r.:l!<;<! of l.:lb re.:lgenCs Photo #15. Drums in area 4; note water on t he floor Photo #16. Drum contents undergoing a re action ~ Ea~E ul sl~qap pUE Sllin~a iuedlliOJ lE~lllia4J PUBIS} Ul~~l~ 'Ll ~ O JO~i L· \,. •• -, 07/14/89 TABLE 1 Laboratory Reagent Inventory CHEMICAL NAME l,3-dinitrobenzene 1-butanol l-chlorobutane I-propanol 18-Crown-6 99% 2,2-oxydiethanol 2,6-dimethoxybenzoic acid99% 2,6-ditertiarybutyl p-cresol 2-hydroxybenzyl alcohol 99% 2-hydroxyethyl ether 2-methyl-1-butanol 99% 2-methylbutyl amine 3,3-dimethoxy benzidene 3-hydroxybenzoin acid 4-chlorobenzene sulfonamide 4-hydroxy 4methyl 2pentanone 4-hydroxybenzoic acid 4-methylbenzo phenone 97% 9-hydroxyflourene Acetic acid Acetone Acetonitrile Alkalinity C,D,E,G Aluminum Chloride Aluminum chloride Ammonium acetate Ammonium acetate Ammonium acetate purified Anh~onium hydroxide Ammonium persulfate Ammonium persulfate Ammonium thiocyanate Amyl alcohol Arsenic trioxide Barium chloride Barium chloride Barium chloride Barium hydroxide Benzaldehyde Benzene Benzhydrol Benzoic acid Benzoin Benzoin 98% COMPANY _ .. _----_ .. Aldrich Chemical J.T.Baker Chemical MCB J.T.Baker Chemical Aldrich Chemical Kodak Aldrich Chemical Biesterfeld Aldrich Chemical Aldrich Chemical Aldrich Chemical American Laboratorie Kodak Aldrich Chemical Aldrich Chemical Aldrich Chemical Aldrich Chemical Aldrich Chemical Aldrich Chemical MCB Fisher Scientific Supelco Mogul corporation Mallinckrodt witco Chemical Fluka Aldrich Chemical Jarchem Industries Sargent Welch Scient J.T.Baker Chemical J.T.Baker Chemical Fisher Scientific Mallinckrodt Fisher Scientific Drew Chemical Mallinckrodt Fisher Scientific Fisher Scientific J.T.Baker Chemical Tenneco Oil Kodak Mobay Chemical Fluka Aldrich Chemical !' 1.30 DATA TAT 7/89 QTY 100 g 500 ml 4 L 500 ml 25 g 1 kg 25 g 500 g 25 g 1 kg 10 g 15 g 100 g 100 g 100 g 500 g 50 g 50 g 2x25 g 2x5 Ib 4 L 1 box 4x2 oz 1 Ib 500 g 1 kg 2 kg 250 g 500 ml 2.5 kg 500 g 500 g 1 pt 2x113g 1 qt 500 g 1 Ib 1 Ib 500 ml 2xlgal 100 g 1 Ib 2xl kg 4x500g TABLES STATE ----- ----- solid liquid liquid liquid solid liquid solid solid liquid liquid liquid liquid solid solid solid liquid solid solid solid liquid liquid liquid liquid solid solid solid solid solid liquid solid solid liquid liquid solid liquid solid solid solid liquid liquid solid solid solid solid 07/14/89 TABLE 1 Laboratory Reagent Inventory CHEMICAL NAME Benzophenone Benzophenone BE>TIzophenone Benzophenone 99+% Benzoyl chloride Benzyl acetate 99% Benzyl alcohol Benzyl benzoate Benzyl chloride Benzyl chloride Benzyl cinnamate 98% Benzyl ether Eenzyltriethylammoni~~chlori Bismuth subnitrate Bromine Bromophenol blue Brucine sulfate Buffer solution pH 10.00 Buffer solution pH 4.00 Buffer solution pH 7. r:,() CAO-3 BHT Calcium sulfate anhydrous Cello-Seal Chloride F Chlorodiphenyl methane 98% Chloroform Chromotropic acid Na salt Cinnamaldehyde citric acid anhydrous Citricacidtrisodiumdihydrate Cobalt chloride Color standard 4 Congo red Copper metal Cupric sulfate cupric sulfate DPD #1,2,3 Reagents Dibenzo 18-Crown-6 98% Dibenzoyl tartaric acid Dichloroethane 99% Dichlorophenyl methane 99% Dichlorotoluene 99% Diethylene glycol Diisobutyl aluminum hydride Diphenylmethane 99% COMPANY Aldrich Chemical H&S Chemical Upjohn Aldrich Chemical Mobay Chemical Aldrich Chemical Mallinckrodt Aldrich Chemical unknown Velsicol Aldrich Chemical Aldrich Chemical Aldrich Chemical MCB Fisher Scientific Fisher Scientific Fisher Scientific Fisher Chemical Fisher Scientific Fisher Chemical Sherwin Williams W.A.Hammond Drierite Fisher Scientific Mogul Corporation Aldrich Chemical Fisher Scientific Fisher Scientific unknown J.T.Baker Chemical Aldrich Chemical Fisher Scientific unknown Fisher Scientific Fisher Scientific Fisher scientific Mallinckrodt Taylor Chemical Aldrich Chemical Knoll Fine Chemicals Aldrich Chemical Aldrich Chemical Aldrich Chemical Fisher Scientific Texas Acres Aldrich Chemical .- QTY 500 g 1 bag 500 g 50 g 1 Ib 100 g 1 pt 1.00 g 4 oz 500 g '100 g 1 kg 25 g 1 lb 113 g 5 g 1 oz 500 ml 500 ml 500 ml 1 bag 4x5 lb 25 g 3 oz 100 g 4 L 25 g 2x1 kg 500 g 1 kg 2x1 lb 1 oz 25 g 500 g 500 g 500 g 3xl oz 50 g 1 kg 1 kg 25 g 100 g 1 qt 4 cyl 500 g STATE ----- ----- solid solid solid solid solid liquid liquid liquid liquid liquid solid liquid solid solid liquid solid solid liquid liquid liquid solid solid liquid liquid solid liquid solid liquid solid solid solid liquid solid solid solid solid liquid solid solid liquid solid solid liquid gas liquid 07/14/89 TABLE 1 Laboratory Reagent Inventory CHEMICAL NAME Diphenylthiocarbazone Eosin Y Ether anhydrous EthoX'},guin Ethyl acetate Ethyl acetate Ethyl benzene Ethyl ether 99% Ferric ammonium sulfate Ferric chloride Ferric chloride Ferric chloride anhydrous Ferric chloride anhyflrous Ferrous ammoni~~ sulfate Formic acid Glacial acetic acid Hydrazine sulfate Hydrazine sulfate Hydrochloric acid Hydrochloric acid Hydroxylamine hydrochloride Hydroxylamine hydrochloride Iodine Iron chloride anhydrous Isoamyl alcohol Isobutyl alcohol Lead acetate Lead nitrate Lithium perchlorate Magnesium sulfate Medical oxygen Mercuric chloride Mercuric oxide Mesityl oxide Methanol Methenamine Methyl alcohol Methyl orange Methyl red Monochlorobenzene N-methylaniline Na salt of ME salicylate Niacin N.F. Nitric acid concentrated Nitrobenzene COMPANY Fisher Scientific Aldrich Chemical Fisher Scientific unknown Aldrich Chemical MCB Dupont Fisher Scientific Fisher Scientific unknown Fisher Chemical Pennwalt corporation Kodak Fisher Chemical unknown Fisher Chemical Fisher Scientific Fisher Scientific MCB Fisher Chemical Fisher Scientific MCB Fisher Scientific BASF Fisher Scientific J.T.Baker Chemical MCB Fisher Scientific Aldrich Chemical Fisher Scientific MSA Fisher Scientific Fisher Scientific Aldrich Chemical Fisher Scientific Fisher Scientific Mallinckrodt Fisher Scientific Fisher Scientific PPG Industries Kodak Sattra Chemical Nepera Chemical J.T.Baker Chemical Fisher Scientific -' QTY 25 g 25 g 4 qt 4 oz 5 gal 5xlgal 1 qt 6x500g 500 g 100 ml 1 lb 5x500g 500 g 1 lb 200 g 5 lb 4 oz 100 g 2x6 lb 3xl L 1 kg 4 OZ 500 g 500 g 500 ml 500 ml 1 Ib 100 g 500 g 500 g 1 cyl 2xlOOg 500 g 100 g 4 L 500 g 1 gal 113 g 2xl0 g 10 oz 1 kg 1 bag 250 g 2x8 Ib 1 qt STATE ===== solid solid liquid liquid liquid liquid liquid liqiud solid liquid solid solid solid solid liquid liquid solid solid liquid liquid solid solid solid solid liquid liquid solid solid solid solid gas solid solid solid liquid solid liquid solid liquid liquid solid solid liquid liquid 07/14/89 TABLE 1 Laboratory Reagent Inventory CHEMICAL NAME Non aqueous buffer soln. Nutrizyme oil #3 Paraffin oil Para formaldehyde Paraformaldehyde prills 91% Perchloric acid Phenol red Phenopthalein Phenylhydrazine Pheny1hydrazinehydrochloride Phosphorous pentoxide piperazine Potassium bromide Potassium butoxide Potassium chloride Potassium cyanate Potassium cyanide Potassium dichromate Potassium ferrocyanide Potassium hydroxide Potassium hydroxide Potassium iodide Potassium iodide Potassium periodate Potassium platinate Potassium sulfate Potassium sulfate Potassium sulfate Potassium thiocyanate Resorcinol Salicylaldehyde 99+% Salicylic acid Salicylic acid Salicylic acid sodium salt Sicapent Silica gel dessicant Silver nitrate Silver nitrate Sodium Chloride Sodium acetate Sodium acetate anhydrous Sodium acetate anhydrous Sodium amide Sodium benzoate COMPANY ._------ Beckman Instruments Merck Frich Oil Fisher Scientific MCB Celanese Chemical MCB Fisher Scientific Fisher Scientific Fisher Scientific Fisher Scientific Fisher Scientific MCB Fisher Scie~tific Callery Chemical Beckman Instruments Fisher Scientific Fisher Scientific Fisher Scientific Fisher Scientific Mallinckrodt Fisher Scientific Drew Chemical Fisher Scientific Fisher Scientific Varlacold Chemical Indiana Army Ammo Plant Aldrich Chemical unknown Fisher Scientific Koppers Aldrich Chemical Aldrich Chemical Aceto Chemical Aldrich Chemical MCB Davison Chemical J.T.Baker Chemical Sargent Welch Scientific Fisher Scientific Sattra Chemical Niacet Corporation CDF Chimie Noth America Farchan Research Lab Sattra Chemical QTY 1 pt 2 oz 5 gal 1 qt 1 qt 1 lb 2x8 lb 5 g 1 oz 4x4 oz 2 lb 1 lb 100 g 5x500g 50 g 2x6 oz 1 lb 500 g 500 g 3 kg 2x1 lb 500 g 1 gt 2x500g 100 g 5 g 250 g 500 g 50 g 500 g 3 bags 100 g 100 g 500 g 100 g 2.8 L 2xl qt 1 oz 30 g 500 g 3 bags 250 g 2x500g 500 g 1 bag STATE ----- ----- liquid solid liquid liquid liquid solid liquid solid solid liquid solid solid solid solid solid solid solid solid solid solid solid solid liquid solid solid solid solid solid solid solid solid liquid solid solid solid solid solid solid solid solid solid solid solid solid solid 07/14/89 TABLE 1 Laboratory Reagent Inventory CHEMICAL NAME Sodium benzoate Sodium benzoate Sodium benzoate Sodium borohydride Sodium carbonate Sodium carbonate anhydrous Sodium chlorate Sodium dichromate Sodium formate Sodium hydride Sodium hydroxide Sodium metal Sodium nitrite Sodium nitro ferricyanide Sodium sulfate Sodium tartrate Sodium tartrate Sodium thiosulfate Succinic anhydride Succinic anhydride Sulfamic acid Sulfanilic acid Sulfite O,P,Q Sulfuric acid Tetraphenolboron sodium 99% Thiopene Total alkylinity indicator Tributyl borate Trichloroethylene Triethyl borate 97% Triethylenediamine Uranyl acetate Weedox C/R 250 herbicide Xylene Zinc chloride Zinc chloride anhydrous p-chlorobenzene sulfonamide p-naptholbenzein p-toluenesulfonicmonohydrate pH indicator A z Miscellaneous unknowns z Miscellaneous unknowns COMPANY Dastech International Ishihara corporation Pfizer Fisher Scientific Fisher Scientific Mallinckrodt Hooker Chemical Fisher Scientific unknown Thiokol/Ventron Division Mallinckrodt RMI Fisher Scienti:ic MCB Fisher Scientific J.T.Baker Chemical Fisher Scientific Fisher Scientific MCB Aldrich Chemic,: Fisher Scientific H&S Chemical Mogul corporation J.T.Baker Chemical Aldrich Chemical Kodak Drew Chemical Aldrich Chemical Mallinckrodt Aldrich Chemical Air Products unknown Southern Mill Creek Prod. Fisher Scientific Fisher Scientific Mineral Research H&S Chemical Fisher Scientific Aldrich Chemical Mogul corporation on site lab glassware on site one oz bottles QTY === 1 bag 250 g 100 Ib 4x25 g 1 kg 1 lb 1 box 10 kg 5 lb 1 lb ·500 g 2 boxs 2x500g 4 oz 500 g 2 oz 6xl13g 2x1 lb 6x250g 2xl kg 500 g 1 bag 3x2 oz 10 lb 25 g 100 g 1 qt 750 g 1 pt 100 g 250 g 500 g 2x5gal 5x1 L 500 g 1 lb 2 bags 25 g 500 g 2 oz 280bot 238bot STATE ===== solid solid solid solid solid solid solid solid solid solid solid solid solid solid solid solid solid solid solid solid solid solid liquid liquid solid liquid liquid liquid liquid liquid solid solid liquid liquid solid solid solid solid solid liquid misc. liquid Page No. 1 07/14/89 Chemical Name Acetone Acetylene Activated carbon All-weather patch material Amersite 2 Ashland MeOH Benzyl acetate Benzyl chloride Chlorine Chloroform Crofox Crystal Clear floor finish Degreaser Drewtrol 8500 Ethyl alcohol Filteraid Glacial acetic acid Glycol Humisorb Hydrochloric acid Hydrogen chloride Insulation (asbestos??) Insulation fiberglass Lubricating oil Lubricating oil Magnesium sulfate trihydrate Hethanol Methanol Methyl isobutyl carbinol Methyl isobutyl ketone TABLE 2 Drum Inventory Company Ashland Chemical VI Gas Calgon Corporation Revere Chemical Valley Freight Syst. Ashland Chemical Island Chemical Velsicol Corporation VI Gas unknown Cerfact Laboratories Cerfact Laboratories unknown Valley Freight Syst. unknown unknown Celanese Chemical Island Chemical Culligan ("'2.r,ti f ied L2.Dora tory VI Gas unknown unknown Texaco Texaco Tomita Pharmaceutica Ashland Chemical unknown Van Waters & Rogers Ashland Chemical Qty --- 55 G 2 cyl 30 bag 55 G 55 G 5 G 21x55G 28x55G 1 cyl 55 G 55 G 2x20 G 55 G 55 G 115x55 10x30G 13x55G 20x55G 30 G 55 G 1 cyl 13 box 7 box 2x10 G 5x55 G 6x25kg 5x55 G 3x55 G l2x55G 55 G state Cond Dates ===== liquid gas solid solid liquid liquid liquid liquiq gas liquid liquid liquid liquid liquid liquid solid liquid liquid solid liquid gas solid solid liquid liquid solid liquid liquid liquid liquid ==== ===== good sooq good fair fair good fair fair poor good poor good good poor poor poor good poor 1984 fair poor poor good good good good fair good fair good 1984 good Page No. 2 07/14/89 Chemical Name Micro media filter sheets Oxygen Oxygen Paints Paints Paints Paints Para-phenetidin Pentosin Potassium acetate Potassium sulfate Powdered filter media Propane purafil II Quinine sulfate Rinseline injector fluid Rout Salicylic acid Salt Soda ash Sodium acetate anhydrous Sodium acetate anhydrous Sodium bicarbonate Sodium hexa-meta phosphate Sodium hydroxide Sodium hydroxide Spent toluene/acetone Sterling salt crystals Sulfamic acid Tartaric acid Thinner TABLE 2 Drum Inventory Company Ertel Engineering VI Gas Santa Maria Gases unknown unknown International Paint International Paint unknown Deutsche Pentosin Jarchem Industries unknown Ionics unknown unknown Kimafarma Bob Chamber Ltd. Cerfact Laboratories Rhone-Poulenc unknown Allied Chemical unknown Jarchem Industries Stauffer Chemical FMC Mantek Manuel del Valle Inc unknown unknown Dupont Pfizer Chemical unknown Qty 18 box 3 cyl 1 cyl 44x5 G 53xl G 97x5 G 21xl G 55 G 20 L 8xlOO# 50 bag 2 boxs 4 cyl 15xlOG 20 G 55 G 20 G 27drum 2x30 G 15xlOO 50 Ib 200 lb 8xlOO# 200 lb 55 G 12x55G 2x55 G 50 lb 400 lb 15xlOO 6xl G State Cond Dates ----- ----- solid gas gas liquid liquid liquid liquid liquid liquid solid solid solid gas solid liquid liquid solid solid solid solid solid solid solid solid liquid liquid liquid solid solid solid liquid ==== ===== good good good fair fair fair fair fair 1983 fair good good good good good good good poor good good poor good poor poor good poor good fair poor poor poor fair ... Page No. 3 07/14/89 TABLE 2 Drum Inventory Chemical Name Company Qty state Cond Dates --- ===== ==== ===== Thinner Advance 55 G liquid fair Toluene Ashland Chemical 3x55 G liquid fair Toluene unknown 5x55 G liquid good Triethylamine Air Products 55 G liquid good 1984 waste oil unknown 2x55 G liquid good z Empty drums unknown 130 n/a fair z Miscellaneous unknowns on site containers 25 misc. poor " 07/14/89 TABLE 3 CERCLA Hazardous Substances and Statutory Codes (40 CFR Sec. 302.4) Chemical 1,3-dinitrobenzene I-butanol 3,3-dimethoxy benzidene Acetic acid Acetone Acetonitrile Ammonium acetate Ammonium hydroxide Ammonium thiocyanate Arsenic trioxide ll .. sbestos Benzene Benzoic acid Benzoyl chloride Benzyl chloride Chlorine Chloroform Copper metal Cupric sulfate Ethyl acetate Ethyl benzene Ethyl ether 99% Ferric chloride Ferrous ammonium sulfate Formic acid Glacial acetic acid Hydrochloric acid Isobutyl alcohol Lead acetate L,ead nitrate Mercuric chloride Mercuric oxide Methanol Methyl alcohol Methyl isobutyl ketone Nitric acid concentrated Nitrobenzene Para formaldehyde Potassium cyanide Potassium hydroxide Resorcinol Silver nitrate Sodium hydroxide Sodium metal Codes ----- ----- 1 4 4 1 4 4 1 1 1 1,4 2,3 1,2,3,4 1 1 1,4 1 1;2,4 2 1 4 1,2 4 1 1 1,4 1 1 4 1,4 1 2 2 4 4 4 1 1,2,4 1 1,4 1 1,4 1 1 1 -- 07/14/89 Chemical Sodium nitrite Sulfuric acid Toluene Trichloroethylene Triethylamine Uranyl acetate Xylene Zinc chloride TABLE 3 CERCLA Hazardous Substances and Statutory Codes (40 CFR Sec. 302.4) Codes ----- ----- 1 1 1,2,4 1,2,4 1 1 1,4 1 1= Clean Water Act (CWA) Section 311 (b) 4 2= Clean Water Act (CWA) Se-:tion 307 (a) 3= Clean Air Act (CAA) Section 112 4= Resource Conservation Recovery Act (RCRA) Section 3001 -~ '07/14/89 TABLE 4 Hazard Categories For Lab Reagents Chemical Name 1,3-dinitrobenzene I-butanol l-chloro}:;utane I-propanol 2,2-oxydiethanol 2,6-dimethoxybenzoic acid99% 2,6-ditertiarybutyl p-cresol 2-hydroxybenzyl alcohol 99% 2-hydroxyethyl ether 2-methyl-l-butanol 99% 2-methylbutyl amine 3,3-dimethoxy benzidene 3-hydroxybenzoin acid 4-chlorobenzene sulfonamide 4-hydroxy 4methyl 2pentanone 4-hydroxybenzoic acid 4-methylbenzo phenone 97% 9-hydroxyflourene Acetic acid Acetone Acetonitrile Alkalinity C,D,E,G Aluminum chloride Ammonium acetate Ammonium hydroxide Ammonium persulfate Ammonium thiocyanate Amyl alcohol Arsenic trioxide Barium chloride Barium hydroxide Benzaldehyde Benzene Benzhydrol Benzoic acid Benzoin 98% Benzophenone 99+% Benzoyl chloride Benzyl acetate 99% Benzyl alcohol Benzyl benzoate Benzyl chloride Benzyl cinnamate 98% Benzyl ether Benzyltriethylammoniumchloride HAZCAT Poison B BNA BNA BNA BNi\ BNA BNA BNA Bl''iA BNA BNA BNA BNA BNA BNA BNA BNA BNA Corrosive F~:..ammable Flammable BNA Corrosive OPJ1-E corrosive BNA ORM-E BNA Poison B BNA BNA Combustible Flammable BNA ORM-E BNA BNA Corrosive BNA BNA BNA Corrosive BNl-. BNA BNA :" '07/14/89 TABLE 4 Hazard Categories For Lab Reagents Chemical Name Bismuth subnitrate Bromine Bromophenol blue Brucine sulfate Buffer solution pH 10.00 Buffer solution pH 4.00 Buffer solution pH 7.00 CAO-3 BHT Calcium sulfate anhydrous Chlorodiphenyl methane 98% Chloroform Chromotropic acid Na salt cinnamaldehyde ci tric acid anhydrc.".ls Citricacidtrisodiumdihydrate Cobalt chloride Color standard 4 Congo red Copper metal Cupric sulfate DPD #1,2,3 Reagent: Dibenzo 18-Crown-6 98% Dibenzoyl tartaric acid Dichloroethane 99% Dichlorophenyl methane 99% Dichlorotoluene 99% Diethylene glycol Diisobutyl aluminum hydride Diphenylmethane 99% Diphenylthiocarbazone Eosin Y Ether anhydrous Ethoxyguin Ethyl acetate Ethyl benzene Ethyl ether 99% Ferric ammonium sulfate Ferric chloride Ferrous ammonium sulfate Formic acid Glacial acetic acid Hydrazine sulfate Hydrochloric acid Hydroxylamine hydrochloride Iodine Iron chloride anhydrous HAZCAT BNA Corrosive BNA BNA BNA BNA BNA BNA BNA BNA ORM-A BNA BNA BNA BNA BNA BNA BNA BNA ORM-E BNA BNA BNA BNA BNA BNA BNA Flammable Gas BN~. BNA BNA BNA BNA Flammable Flammable Flammable ORM-E ORM-B ORM-E Corrosive Corrosive BNA Corrosive BNA BNA ORM-B -- · 07/14/89 TABLE 4 Hazard categories For Lab Reagents Chemical Name Isoamyl alcohol Isobutyl alcohol Lead acetate Lead nitrate Lithium perchlorate Magnesium sulfate Medical oxygen Mercuric chloride Mercuric oxide Mesityl oxide Methanol Methenamine Methyl alcohol Methyl orange Methyl red Monochlorobenzene N-methylaniline Na salt of ME salicylate Niacin N.F. Nitric acid concentrated NitroLenzene Non a~2eous buffer soln. Nutrizyme oil #3 Paraffin oil Para formaldehyde Perchloric acid Phenol red Phenopthalein Phenylhydrazine Phenylhydrazinehydrochloride Phosphorous pentoxide Piperazine Potassium bromide Potassium butoxide Potassium chloride Potassium cyanate Potassium cyanide Potassium dichromate Potassium ferrocyanide Potassium hydroxide Potassium iodide Potassium periodate Potassium platinate Potassium sulfate Potassium thiocyanate HAZCAT BNA Flammable ORM-E Oxidizer BNA BNA .- Non Flammable Gas Poison B Poison B Flammable Flammable BNA Flammable BNA BNA BNA BNA BNA BNA Oxidizer Poison B BNA BNA Combustible Combustible ORM-A oxidizer BNA BNA BNA BNA Flammable BNA BNA BNA BNA BNA Poison B ORM-A BNA Corrosive BNA BNA BNA BNA BNA 07/14/89 TABLE 4 Hazard Categories For Lab Reagents Chemical Name Resorcinol Salicylaldehyde 99+% Salicylic acid Salicylic acid sodium salt Silica gel dessicant silver nitrate Sodium acetate anhydrous Sodium amide Sodium benzoate Sodi.um borohydride Sodium carbonate anhydrous Sodium chlorate Sodium chloride Sodium dichromate Sodium formate Sodium hydride Sodium hydroxide Sodium metal Sodium nitrite Sodium nitro ferricyanide Sodium sulfate Sodium tartrate Sodium thiosulfate Succinic anhydride Sulfamic acid Sulfanilic acid Sulfite O,P,Q Sulfuric acid Tetraphenolboron sodium 99% Thiopene Total alkylinity indicator Tributyl borate Trichloroethylene Triethyl borate 97% Triethylenediamine Uranyl acetate Weedox C/R 250 herbicide Xylene Zinc chloride p-chlorobenzene sulfonamide p-naptholbenzein p-toluenesulfonicmonohydrate pH indicator A HAZCAT ORM-E BNA BNA BNA BNA Oxidizer BNA Flammable BNA BNA BNA Oxidizer BNA ORM-A BNA Flammable Corrosive Flammable Oxidizer BNA BNA BNA BNA Organic Peroxide BNA BNA BNA Corrosive BNA BNA BNA BNA Flammable BNA BNA Radioactive Poison B Flammable ORM-E BNA BNA BNA BNA 07/14/89 TABLE 5 Hazard Categories For Drums Chemical Name Acetone Acetylene Activated carbon All-weather patch material Ashland MeOH Benzyl acetate Benzyl chloride Chlorine Chloroform Crystal Clear floor .finish Degreaser Ethyl alcohol Filteraid Glacial acetic acid Glycol Humisorb Hydrochloric acid Hydrogen chloride Insulation (asbestos??) Insulation fiberglass Lubricating oil Magnesium sulfate trihydrate Methanol Methyl isobutyl ketone Micro media filter sheets Oxygen Paints Para-phenetidin Potassium acetate Potassium sulfate Powdered filter media Propane Purafil II Quinine sulfate Rinseline injector fluid Salicylic acid Salt Soda ash i Sodium acetate anhydrous Sodium bicarbonate Sodium hexa-meta phosphate Sodium hydroxide Spent toluene/acetone Sterling salt crystals Sulfamic acid HAZCAT -----_ .. Flammable Flammable Gas BNA BNA Flammable BNA Corrosive :" Non Flammable Gas ORM-A BNA Flammable Flammable BNA Corrosive BNA BNA Corrosive Non Fla~~able Gas ORM-C BNA Combustible BNA Flammable Organic Peroxide BNA Non Flalnmable Gas Flammable Poison B BNA BNA BNA Flammable Gas BNA BNA Flammable BNA BNA Corrosive BNA BNA BNA Corrosive Flammable BNA BNA 07/14/89 Chemical Name Tartaric acid Thinner Toluene Triethylamine Waste oil .~ TABLE 5 Hazard Categories For Drums NHAZCAT ~----­ BNA Flammable Flammable Flammable Combustible '" TABLE 6 Summary of Toxicological Effects of Some Identified Compounds Chemical Name 1,3-dinitrobenzene I-butanol 3,3-dimethoxy benzidene Acetic acid, Acetone Acetonitrile Ammonium acetate Ammonium hydroxide Ammonium thiocvanate Arsenic trioxide Benzene Benzoic acid Benzoyl chloride Benzyl chloride Chloroform Copper metal cupric sulfate Ethyl acetate Ethyl benzene Ethyl ether 99% Ferric chloride Ferrous ammonium sulfate Formic acid Hydrochloric acid Isobutyl alcohol Lead acetate Lead nitrate Mercuric chloride Mercuric oxide Methanol Nitric acid concentrated Health Effects Codes A,B,E,I A,E A,B,C,E,F A,I A,E A,B,C,D,E,I A,E A,E A,E A,B,C,D,E,F A,E,F,I A,E A,E A,E A,B,C,E,F A,B,C,E A,E A,E A,E,I A,E,I A,E A,E A,B,C,E A,E A,E A,E A,E A,E A,E A,E,I A,E .- A= Eye, skin, respiratory and mucous membrane irritant B= Liver Damage C= Kidney Damage D= Lung Damage E= Toxic by inhalation, ingestion, or dermal contact F= carcinogenic G= Teratogenic H= Mutagenic I= Central Nervous system effects TABLE 6 (Continued) Summary of Toxicological Effects of Some Identified Compounds Chemical Name Nitrobenzene Para formaldehyde Potassium cyanide Potassium hydroxide Resorcinol Silver nitrate Sodium hydroxide Sodium metal Sodium nitrite Sulfuric acid Trichloroethylene Xylene Zinc chloride Chlorine Asbestos Methyl isobutyl ketone Toluene Triethylamine Ura,nyl acetate Health Effects Codes A,B,C,E,I A,E A,E A,E A,E A,E A,E A,E A,E,F A,E A,B,C,E,F,I A,B,C,E,I A,E A,E D,E,F A,E A,B,C,E,I -- A,E A,B,C,D,E,F,G,H,I A= Eye, skin, respiratory and mucous membrane irritant B= Liver Damage C= Kidney Damage D= Lung Damage E= Toxic by inhalation, ingestion,or dermal contact F= Carcinogenic G= Teratogenic H= Mutagenic I= Central Nervous system effects VICHEM (VIRGIN ISLAND CHEMICAL) SITE, MELVIN EVANS HIGHWAY FREDERIKSTED DISTRICT, ST CROIX, US VIRGIN ISLANDS In compliance with Section 113k of CERCLA government documents are now available for public review relating to the U.s. Environmental Protection Agency (EPA) removal action of potentially hazardous materials and wastes under the Superfund program at the VIChem site. The documents, which are a part of the site administrative record, include various reports and studies which form the basis of EPA's remedy for the problems posed by this facility. Presently, several hundred laboratory chemicals, drums and tanks containing hazardous materials exist on-site. Several classifi- cations of materials are represented including flammable solvents, corrosive liquids, oxidizers, and potentially explosive compounds. EPA plans to begin the removal of these materials on E:'A I S act~' on will address stabilization and disposal of aboveground containe~ized substances. These materials will be treated on-site or shipped off-site for disposal once the proper facilities have been selected. The administrative record is available for review during normal business hours at the following locations. 1. Department of Planning and Natural Resources Watergut Homes Building Ill, Apt 14-F Christiansted, st. croix, U.s. Virgin .Islands 2. USEPA - Region II Woodbridge Avenue Edison, New Jersey Page No. 4 07/14/89 TABLE 7 Hazard ID and Disrosal Classification For Reagents Chemical Name Barium chloride Barium hydroxide Benzoic acid Chloroform Cobalt chloride cupric sulfate Diphenylthiocarbazone Ferric ammonium sulfate Ferrous ammonium sulfate Hydrazine sulfate Hyd~oxylamine hydrochloride Iodi.ne Lead acetate Mercuric chloride Mercuric oxide N-methylaniline Na salt of ME salicylate Nitrobenzene Paraformaldehyde Potassium bromide Potassium but oxide Potassium chloride Potassium cyanate Po~assium cyanide Potassium dichromate Potassium ferrocyanide Potassium iodide Potassium platinate Silver nitrate Sodium acetate anhydrous Sodium benzoate Sodium dichromate Sodium nitro ferricyanide Tetraphenolboron sodium 99% Zinc chloride p-chlorobenzene sulfonamide p-naptholbenzein p-toluenesulfonicmonohydrate Uranyl acetate HAZCAT Poison B Poison B ORM-E ORM-A Irritant ORM-E Irritant ORM-E ORM-E Irritant Irritant Irritant ORM-E Poison B Poison B Irritant Irritant Poison B ORM-A Irritant Irritant Irritant Poison B Poison B ORM-A Poison B Irritant Irritant oxidizer Irritant Irritant ORM-A Poison B Irritant ORM-E Irritant Irritant Irritant Radioactive ID Number Disp.Cat ========= ======== 7 7 7 D025 7 7 7 7 7 7 7 7 7 U144 7· 7 7 7 7 F004 7 7 7 7 7 7 P09S 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 1. Landfill 3. Waste water treatment 5. On-site destruction 7. Special handling 2. Incineration 4. ~eutralization/landfill 6. Plastic wrap/landfill page No. 1 07/14/89 TABLE 7 Hazard ID and Disposal Classification For Reagents Chemical Name Bismuth subnitrate Bromophenol blue Calcium sulfate anhydrous Copper metal Eosin Y Magnesium sulfate Methyl orange Methyl red Niacin N.F. Non aqueous buffer soln. Phenol red Phenopthalein Silica gel dessicant Sodium chloride Sodium carbonate anhydrous I-butanol l-chlorobutane I-propanol 2,2-oxydiethanol 2-hydroxybenzyl alcohol 99% 2-methyl-l-butanol 99% 2-methylbutyl amine 4-hydroxy 4methyl 2pentanone Acetone Ace.toni trile Amyl alcohol Benzaldehyde Benzene Benzhydrol Benzoin 98% Benzophenone 99+% Benzyl acetate 99% Benzyl alcohol Benzyl benzoate Benzyl cinnamate 98% Benzyl ether CAO-3 BHT Chlorodiphenyl methane 98% Cinnamaldehyde DPD #1,2,3 Reagents Dibenzo l8-Crown-6 98% Dibenzoyl tartaric acid Dichloroethane 99% Dichlorophenyl methane 99% Dichlorotoluene 99% Diethylene glycol HAZCAT BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA Flammable Flammable Flammable Flammable Flammable Flammable Flammable Flammable Flammable Flammable Flammable Combustible Flammable Combustible Combustible Combustible Combustible Combustible Combustible Combustible Combustible Combustible Flammable Combustible Combustible Combustible Irritant Flammable Flammable Flammable Combustible ID Number :;:======== DOOI DOOI DOOI DOOI DOOI DOOI DOOI DOOI F003 DOOI DOOI DOOI D019 DOOI DOOI DOOI DOOI DOOI DOOI DOOI DOOI DOOI DOOI DOOl DOOI DOOl DOOI DOOl DOOl DOOl Disp.Cat 1 1 1 1 1 1 1 1 1 1 1 1 l~ 1 1 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 1. Landfill 3. Waste water treatment 5. On-site destruction 7. Special handling 2. Incineration 4. Neutralization/landfill 6. Plastic wrap/landfill Page No. 2 07/14/89 TABLE 7 Hazard ID and Disposal Classification For Reagents Chemical Name Diphenylmethane 99% Ethoxyquin Ethyl acetate Ethyl benzene Ferric chloride Isoamyl alcohol Isobutyl alcohol Mesityl oxide Methenamine Methyl alcohol Monochlorobenzene Nutrizyme oil #3 Paraffin oil Resorcinol Sodium amide Thiopene Trichloroethylene Triethyl borate 97% Weedox CjR 250 herbicide Xylene Alkalinity C,D,E,G Ammonium hydroxide Benzoyl chloride Benzyl chloride Bromine Buffer solution pH 10.00 Buffer solution pH 4.00 Buffer solution pH 7.00 Chromotropic acid Na salt Citric acid anhydrous Citricacidtrisodiumdihydrate Color standard 4 Congo red Formic acid Glacial acetic acid Hydrochloric acid Potassium hydroxide Potassium .. sulfate Sodium hydroxide Sulfamicacid Sulfuric acid Total alkylinity indicator pH indicator A Aluminum chloride 2,6-dimethoxybenzoic acid99% 1. Landfill 3. Waste water treatment HAZCAT Flammable Combustible Flammable Flammable ORM-B Flammable Flammable Flammable Flammable Flammable Flammable Combustible Combustible Combustible ORM-E Flammable Flammable Flammable Flammable Poison B Flammable BNA Corrosive Corrosive Corrosive Corrosive BNA BNA BNA BNA BNA BNA BNA BNA Corrosive Corrosive Corrosive Corrosive Corrosive Corrosive Corrosive Corrosive BNA BNA Corrosive Combustible ID Number ===:::::::===== DOOI DOOI F003 F003 DOOI FOOS DOOI DOOI F003 DOOI DOOI DOOI DOOI U20l DOOI DOOI FOOl DOOI F003 D002 D002 D002 D002 D002 D002 D002 D002 D002 D002 D002 D002 D002 DOOI Disp.cat 2 2 2 :2 :2 2 :2 2 :2 2 :2 :2 2 .... ~ :2 :2 :2 2 2 2 :2 3 3 3 3 3 3 J 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 4 5 5. On-site destruction 7. Special handling 2. Incineration 4. ~eutralization/landfill 6. Plastic wrap/landfill Page No. 3 07/14/89 TABLE 7 Hazard ID and Disposal Classification For he agents Chemical Name 2,6-ditertiarybutyl p-cresol 2-hydroxyethyl ether 3,3-dimethoxy benzidene 3-hydroxybenzoin acid 4-chlorobenzene sulfonamide 4-hydroxybenzoic acid 4-methylbenzo phenone'97% 9-hydroxyflourene Ammonium persulfate Benzyltriethylammoniumchloride Brucine sulfate Diisobutyl aluminum hydride Ether anhydrous Ethyl ether 99% Lead nitrate Lithium perchlorate Medical oxygen Nitric acid concentrated Perchloric acid Phenylhydrazine Phenylhydrazinehydrochloride Phosphorous pentoxide Piperazine Potassium periodate Potassium thiocyanate Salicylaldehyde 99+% Salicylic acid Salicylic acid sodium salt Sodium borohydride Sodium chlorate Sodium formate Sodium hydride Sodium metal Sodium nitrite Sodium sulfate Sodium tartrate Sodium thiosu11:ate Succinic anhydride Sulfanilic acid Sulfite O,P,Q Tributyl borate Triethylenediamine l,3-dinitrobenzene Ammonium acetate Ammonium thiocyanate Arsenic trioxide HAZCAT Combustible Flammable Combustible Combustible Irritant Combustible Combustible Irritant Oxidizer Irritant Poison B Flammable Gas Flammable Flammable Oxidizer Oxidizer Non Flammable Gas Oxidizer Oxidizer Irritant Irritant Flammable Irritant Oxidizer Irritant Irritant Irritant Irritant Irritant Oxidizer Irritant Flammable Flammable Oxidizer Irritant Irritant Irritant Organic Peroxide Irritant Irritant Combustible Combustible Poison B ORM-E ORM-E Poison B eID Number 0001 0001 0001 0001 0001 D001 D001 D001 F003 N/A DOOl DOOl DOOl 0001 DOOl P012 Disp.Cat 5 5 5 5 5 5 5 5 5 5 5 5 5- 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 7 7 7 7 1. Landfill 3. waste water treatment 5. On-site destruction 7. Special handling 2. Incineration 4. ~eutralization/landfill 6. Plastic wrap/landfill 07/14/89 TABLE 8 Hazard ID and Disposal Classification For Drums Chemical Name Activated carbon All-weather patch material Filteraid Humisorb Insulation fiberglass Magnesium sulfate trihydrate Micro media filter sheets Potassium acetate Potassium sulfate Powdered filter media Purafil II Quinine sulfate Salicylic acid Salt Sodium acetate anhydrous Sodium bicarbonate Sodium hexa-meta phosphate sterling salt crystals Sulfamic acid Tartaric acid Acetone Benzyl acetate Benzyl chloride Crystal Clear floor finish Degreaser Ethyl alcohol Glycol Lubricating oil Methanol Paints Rinseline injector fluid Spent toluene/acetone Glacial acetic acid Hydrochloric acid Soda ash Sodium hydroxide Acetylene Chlorine Hydrogen chloride Oxygen Propane Insulation (asbestos??) Methyl isobutyl ketone Para-phenetidin Chloroform HAZCAT BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA Flanm:able BNA Corrosive BNA Flammable Flammable BNA Combustible Flammable Flammable Flammable Flammable Corrosive Corrosive Corrosive Corrosive Flammable Gas Non Flammable Gas Non Flammable Gas Non Flammable Gas Flammable Gas ORM-C Organic Peroxide Poison B ORM-A ID Number .- Disp.Cat 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 F003 2 2 P028 2 2 DOOI 2 DOOI 2 2 DOOI 2 F003 2 DOOI 2 DOOI 2 F005/F003 2 D002 3 D002 4 D002 4 D002 4 DOOI 5 N/A 5 D002 5 N/A 5 DOOI 5 N/A 6 F003 7 7 D025 7 1. Landfill 3. Waste Water Treatment 5. On-site destruction 7. Special handling 2. Incineration 4. Neutralization/landfill 6. Plastic wrap/landfill page No. 1 02/21/89 TABLE 8 Haza=d ID and Disposal Classification For Drums Chemical Name HAZCAT ID Nu:mber Disp.Cat Activated ca=bon All-weather patch material Filte=aid Hu:misorb Insulation fiberglass Magnesiu:m sulfate trihydrate Micro media filter sheets Potassiu:m acetate potassiu:m sulfate Powdered filter media Purafil II Quinine sulfate Salicylic acid Salt Sodiu:m acetate a~~ydrous Sodiu:m bicarbonate Sodiu:m hexa-meta phosphate sterling salt crystals Sulfamic acid Tartaric acid BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA ==- :..== 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 These materials may be disposed of at an approved hazardous waste landfill. The following is a list of the quantities present: 28 X 55 gallon drums 1 X 400 pound bag 13 X 30 gallon drums 2 X 200 pound bags 1 X 20 gallon drum 117 X 100 pound bags 15 X 10 gallon drum 2 X 50 pound bags 27 X cubic yard boxes .' Page No. ~ 02/21/89 TABLE 8 Hazard ID and Disposal Classification For Drums Chemical Nallle Acetone Benzyl acetate Benzyl chloride crystal Clear floor finish Degreaser Ethyl alcohol Glycol Lubricating oil Methanol ?aints Rinseline inj~ctor fluid Spent toluene/acetone HAZCAT ===== Flammable BNA Corrosive BNA Flammable Flammable BNA Combustible Flammable Flammable Flammable Flammable ID-Number Disp.Cat ,#fl?'==~~~~~= ~==== F003 :2 :2 P0:28 :2 :2 DOOl :2 DOO~ :2 :2 DOOl :2 F003 :2 DOO:: :2 DOOl :2 F005/F003 :2 These materials may be disposed of at an approved hazardous waste incinerator. ':'";';e following is a_list of the quantities present: 202 X 55 gallon drums 2 X 20 gallon drums 2 X 10 gallon drums 142 X 5 gallon drums 74 X 1 gallon drums .' Page No. ~ 02/21/89 "TABLE 8 Hazard ID and Disposal Classification For Drums Chemical NaJIle "HAZCAT ID"Number Disp.cat ===== ====== ======= Glacial acetic acid Corrosive D002 3 These materials may be disposed of at an approved waste water treatment facility. The following is a list of theqnanti,ties present: 13 X 55 gallon drums ,~ Page No. 1 02/21/89 TABLE 8 Haza=d ID and Disposal Classification For Drums Chemical Name HAZCAT IO--Nwnber Oisp.Cat ===== ~~===== ========= Hydrochloric acid Corrosive 0002 4 Soda ash Corrosive 0002 4 Sodium hydroxide Corrosive 0002 4 These materials may be disposed of after neutralization at a municipal landfill. The following is a lis~ of the quantities present: 14 A 55 gallon drums 15 X 100 pound bags .. '. Page No. 1 02/21/89 TABLE 8 Razard ID and Disposal Classification For Drums Chemical Name HAZCAT === Acetylene Flammable Gas Chlorine Non Flammable Gas Hydrogen chloride Non Flammable Gas Oxygen Non Flammable Gas Propane Flammable Gas These materials may be disposed of via on-site destruction. The following is a list of the quantities present; 12 gas cylinders of various sizes ID"Number =~- -=- -= D001 N/A D002 N/A 0001 ~Disp. Cat '==-====== 5 5 5 5 5 Page No. ~ 02/21/89 TABLE 8 Hazard ID and Disposal Classification For Drums Chemical Name HAZCAT ID Number Disp.Cat -==-== -======== ==== Insulation (asbestos??) ORM-C N/A These materials may be disp~sed of by packing in plastic and landfilling. The following is a list of the quantities present: 13 X cul:.ic yard boxes .~ 6 , . - . Page No. 1 02/21/89 TABLE 8 Hazard ID and Disposal Classification For Drums Chemical Name HAZCAT --",=--- Methyl isobutyl ketone Organic Peroxide Para-phenetidin Poison B Chloroform ORM-A Tl.ese materials require special handling fot' disposal. The following is a list of the quantities present: 15 X 55 gallon drums ID·Nwnber F003 D025 Disp.Cat 7 7 7 i.40 PRELIM ASSESS RPT USEPA FORM 2070-12 5/89 POTENTIAL HAZARDOUS WASTE SITE L IDENTIFICA nON SEPA PRELIMINARY ASSESSMENT Cl STATEr'lSlT'ENUWER PART 1· SliE INFORMAnON AND ASSESSMENT VI EOON7 II. SITE NAME AND LOCA nON 01 SlTENAMEf"-_or __ ot_ 02 STREET. "<:lUTE NO .• OR sPEClFlC LOCA T10N IOEN1lF1ER VI Chem (Island Chemical) Routt! 66 03 CITY 04STATEr~ZlPCOOE I~COUNTY r7~l06~ st. Croix USVI 00820 Christiansted Oli COOAO<NA TES LA TlTUOE I LONGlTlJOE 1r 42' 26" 64° 47' 23" -- -- --"- --- -- --"- 10 O<R::CTIONS TO SlTEI~ _____ From Alexander Hamilton Airport- Take airport road to Melvin Evans Highway" (Rt.66) Make a left onto Melvin Evans. Make first U-Turn. Turn left onto property at the last driveway before the ,light. 111. RESPONSIBLE PARTIES 010WNER(. __ 02 STl'IEET ( ___ Charles H. Steffey Holding Corp. 540-Baltimore Annapolis Blvd ,~-~ 03 CITY 04 STATEl O~ lJPCOOE 101S TEJ..El>MONE NUM8ER , Severna Park MD 21146 ( I unk 07 OPERA-OR ,. _____ oa STREET , __ - . Fred Schubert Ponds ide East Road . Oli CITY 10 STATE 11 I ZlPCOOE 112~NUM8ER ! Richmond MA 01254 (413) 698-2258 I 1 J TYPE OF OWNERSHIP ,CIt __ ~ .... PfWATE a a. FeOCAAl.: o C.STArE ac.couNTY o e. MUNICIPAL '-'- a F.OTHER: :SOKhJ OG.UNKNCWN 1 " C'NNERIOPERA TOR NOnFlCA nON ON FILE iCltoeJr .. __ C A. RCRA 300 1 OA TE RECEIVED: na , I C 6. UNCONmou...eo WASTE SlTE(c~1ICI.A 'Ole} OATE RECEJVEl): I , o C.NONe OOCHT>< OA Y YEAA 1oOOHT>t 'jAy YEN! IV. CHARACTERIZATION OF POTENTIAL HAZARD 01 ON SITE INSPECTION 8Y fCltoeJr .. __ :lCWES DATE. 1 ,31£ 89 x~ A.EPA x~ S. EPA CONTRACTOR xS{C.STATE a O. OTHER CONTRACTOR ONO ..aNT>< DAY YEAI'I a e. LOCAL HEALTH OFFICIAL a F.OTHER: CONmACTOR NAME(S): Roy F. Weston TAT 1-" 02Sr::STAruStClt~ 03 Ye.AAS OF OPERA TlON I ~ A.AC71VE a a.INACTIVE o C.UNKNCWN 5/1/69 Present o U~~KNOWN aEG'1'HHG vE"" e .... 04HG "(EMIt 04 O€SCRIPnoN OF SUSST -'NCES POSSIBL. Y PRESENT. KNOWN. OR ALLEGEO **SEE ATTACHED TABLES** 05 OESCRIPTlON OF POTENTIAL HAZARO TO ENV~NMENT -'No/OR POPUt..AT1ION Direct contact to persons and dogs living and working on-site. Risk of fire/explosion, prison located downwind. Groundwater contamination with chloroform. Incompatable materials stored in close proximity. v. (lRIORITY ASSESSMENT Jl PRtORfT"'V FOA INSPeCnONf~"" .'f,...OI~".ctteC."'. c~."""z· w .. , ... ~..,,..,, l·o.sc,...,...,oI"'~""""'COl'dlOOrt • .,.,,~ nA.HIGH - a B.MEOIUM C C.LOW o '.NONE ---"' t __ t.,,~,Oft,.... ....... o...I 1"*'1wt1:/'ttM'-=1IOft.......,.~~~,."..., VI. INFORMATION AVAILABLE FROM 01 -:ONTACr 02 OF tA..,.c .. O~ __ , 03 TE\'£?MONe NUMSER Francine Lang Dept of Planning and Natural Resources (809) 773-0565 O. ?EASON RESPONSIBLE FOR ASSESSMENT 05 AGENCY I oe CRGANIlATlON lOT rEL..EpI-1ONE NUMSER 080Are Doug Kodama EPA R & P Branch (201) 906-6905 2 £10,89 ~f1oI ;JAY Ye.~ , EP .. FORM 2070.12 (T·81, I " POTENTIAL HAZARDOUS WASTE SITE L IDENTIF!CA TION SEPA PRELIMINARY ASSESSMENT 01 STATE /02 SITE NU04E" VI EOON7 PART 2 • WASTE INFORMA nON II. WASTE STATES, QUANTITIES, ANO CHARACTERISTICS 0' PHvSlCALSTATES ,CMc·,, __ , 02 WASTE QUANnTY AT SlTt: 03 WASTE C"'ARACTERISTICS ,CMe'" __ , 1 ............ 01..., • ...., ..... ~ E SOLUSl.E ~ I. ......... LYVOUTlLE x: A SOLo":) :: 1:. SLURRY tftWaI Off ROIIO~fl x: A. TOXIC x.:: a r>OWOER. FlN£S * F i...'OUIO TONS :It" a C~ROSIVE :.: F :"-IFECTIOUS _ J. f).pl.OSilie :It: C. Si.UOGC ~ G.GAS x: C RAOIOACTI'.iE X G. F(.AIotMASl..E x: K RI: ~CTIVe C,;8IC y AAOS :x: O. PERSISTENT X .... iGloIT A5U :x:: I.. lNCC_ATIIII.! C O.OTM€R 400+ :: .... NOT APPUCA8I..E Is...u., NO. OF ORUIoIS 111. WASTE TYPE CATEGORY SiJasT AHCE NAME 01 GRess AMOUNT 102 UNIT OF MEASURE 03 COMMENTS SLU SLUDGE 100 SSg drums ~ ~LAB 813 various Lab containers (table 1) SOL SOLVENTS 250 approx SSg drums ( table 2) PSO PESTICIOES ace OTHER ORGANIC CHEMICAI..S 45 approx, SSg drums ICIC INORGANIC CHEMICAI..S 65 approx 100ft bags ACO ACIOS 30 approx SSg drums 9AS BASES 12 approx SSg drums MES HEAVY METAI..S 20 approx various Laboratorv containpr<=: IV. HAZARDOUS SUBSTANCES ,s.._ .... _"_ ..... CAS-., ,j. CATEGORY I 02 SUSSTAHCE NAME 03 CAS NUMSER 04 STORAGEiOCSPOSAL ... E rHOO 05~Nm,TlOH oe IofEJ\Sl; n:l OF CONe"... 110N **SEE ATTACHED LISTS** I . . V. FEEDSTOCKS ,$HA_""CAS_ CATEGORY 01 FEEOSTCICKNAME 02 CAS NUMSER CATEGORY o. FEeOSTOCKNAME 02 CAS NUMSER Fe:; **SEE ATTACHED LISTS * FOS "OS FOS I FOS FOS Fe:; FOS VI. SOURCES OF INFORMA TION 'c,. "' ...... ,.'.,.,<0. 0 g .. ..... ' ..... .-.. .,...,. .... __ , **SEE ATTACHED LISTS** I E!'A';ORM.07C.·'2 (1·8., POTENTIAL HAZARDOUS WASTE SITE l. IDENTIFICA nON & EPA PRELIMINARY ASSESSMENT at s,""rel 02 Sire N'.J~ VI EOON7 PART 3' DESCRIPTION OF HAZARDOUS CONDITIONS AND INCIDENTS II. HAZARDOUS COND:TIONS AND INC:OENTS 01.JtX~. GflOUNOWATEF! CONTAMINATION 02 :: OBSEf\VED (OA TE. 1 1 I R R ) XX POTENTIAL :: Au..;:GEO C;; "C?ULA TION POTEN11AU:{ AFFECTED: 400 04 NARRA TI"./E OEs.:;FlIP irON Wells which are used as a source of public drinking water have been found to be contaminated with Chloroform at between 11 and 75 ppb. RCRA enforcement reports 130 ppb Chloroform in the on-site well. 01 ~::g. SURFACE WATER CONTAMINAnON 20 02 c: OBSERVEC (OAfE; 11 j 11 ~\} ) X3 POTENT'.At,. C A1...LEG.EO 03 POPULA 110N POTENTIAL!. Y AFFECTED: 04N~RATIVEoesc~PT1ON An intermittent stream originates on the north side of the Island, flows adjacent to the site, and discharges into the Caribbean Sea. , 01 :lQC. CONTAMINATlON OF AIR 100 02 c: 08SEFM:D(OAfE; 1 /111 89 I o POTEN11A1.. ~AU...EG£O 03 POPULA i:ON POTEN11,l.LL Y AFFECTED: 04 NARRATIVE~ ... All ambient air monitoring was equivalent to nackground, however, many open and leaking containers were observed which may release compounds into the air. I 01 Z2O. FIRE/EXPLOSIVE CONOrTlONS 100 020 OBSERVED ,DATE. 1/31 / ~~ ) Xi§: POTENTW. o .i.U...E"....EO 03 POPULA noN POTENTIAL!. Y AFFECTED: 04 NARRATIVE DESCRIPTION Ethyl ether, sodium metal, diisobutyl aluminum hydride and incompatable materials are stored haphazardly throughout the site. These mater1.a.lS have the potential to cause an explosion. 01 2S~. DIRECT ::;Qr<TACT 4-10 02:: OBSERVED (DATE: 1/11/89 ) ~poTENTW. c: AU.EGEO 03 POPULA noN POTEN11ALL Y AFFECTED: 04 NARRATIVE DESCfllFnON One person lives on-site in a trailer, several people are on-site each day as workers. Guard dogs which have access to the chemical storage areas are moved to banks each night, potentially spreading contamination. The site is fenced. 01 ~*. CONTAMINATION OF SOIL 02 C OBSERVED (OA TE: 1 n 1 1 R q I o POTENTW. YGAU..EGEO 03 AA~ POTEN11AU. Y AF;:eCTED: 3.5 04NARRAnveOESCR~noN A small patch of potenr~ly PCB oil soaked ground observed. Reports of past spills of pyridine and other laboratory chemicals presented by RCRA enforcement in March 1986. 01 2'~. DRINKING WATER CONTAMINATION 400 02 c: OBSERVED (OA TE. 11/ ~ ~ ) ~POTENnAl.. C AU..EGEO 03 POPULATION POTENTiAL!. Y AFFECTED: 04 HARRA nve DESCRIPT10N VI Port Authority wells have shown Chloroform contamination downgradie~t of the site. I 01 2S::lA. WORKER EXPOSUP.E.oINJURY 4-10 02 2 OBSeRVED (OA TE. 1 1111 89 I ~ POTENTIAl.. iJ AU..EGE.oO 03 WORKERS POTEN11ALLY AFFECTED: 04 NARRATIVE DESCRIPTION Kate Wesp operates a dog kennel and lives on-site. Her assistants as well as owners and operators from VIAG Fuels are on-site and inside the buildings on a regular basis. 01Xj<i. P0PULATlON EXPOSUREINJU~Y 400 02 C OBSERVED (0", TE. 1/11 /8 g ) 2G POTEN11AI.. CAl.LEGEO 03 PO PULA TlON PQT::"ITIALL Y AFFECTED: 04 NARRATIVE DESCRIPTION Several industries, businesses,residences, an airport and a prison are located in the general vicinity of the site. M""?":" !OP .. FOAM 2070·'211·01) POTENTIAL ~AZARCOUS WASTE S:TE I. IDENTlFICA TlON ~EPA PRELIMINARY ASSESSMENT 01 STATEt2 SITE NUMSE.q PART 3· oeSCRIPTlON OF HAZARDOUS CONDITIONS AND INCIDENTS VI EOON7 II. HAZARDOUS CONOITlCHS AND IHC:OENTSc-_, 01 C J, DAMAGE TO FLORA 02 C Qese;;va) ,DATE. I CJ POTEtmAL C AU..EGEO 04 ;,jARAATTVE ~ No observed damage to flora. o~ K. DAMAGE "'0 FAUNA 02 C 08S£."lVED (DAiE; !iL82 I CJ POTENTIAL X:l!J AU.EGeO 04 NARRATIVE DESCRIPTION 1 __ ,,01_ Bats were observed in the warehouse, damage unknown. o tXIX L CONT At.41NA TION OF Fcoe CHAIN , 02C08SERVEO(DATE: 1731/89 I Q POTENTIAL X:1!l ALJ.EGa) , 0 .. ,,;ARAA nve DESCRIPTION I The prison located within 1/4 mile of the site 9~erates a farm which sells I vegetables to the local population ! I 01 3t~, JNSTASLE CONTAINMENT OF WASTES 02 i:." OSSEAVEO (DATE: 1/31/89 I :lQ POTENTIAL o ALJ.EGa) r __ ' ___ - 100 03 POPU1.A TION POTEN1'1AU. Y AFFECTED: 04 NARRA nve 0ESCRIP'Tl0N . Two drums have had their lids popped off by some unknown reaction. Lab chemicals observed dripping contents down storage cabinet shelves. 01 12J4iI. DAMAGe TO CFFSITE ?f1OPEi'lTY 020 OasaNEO (DATE: 1/31/82 ) o POTENllAL 10;;: AI..1.EGED 0" NAMA TM DESCFaPTlOH Groundwater contamination and the pot~utial for past illegal discharges exists. 01 ~~. CONTAMINATION OF SEWERS. STOI\M DRAINS. ~ 02 C OBSEF\lEO (OATE: 101L82 I o POTENTIAL nAU...EGeD 04 HARAA TM DESCRIPTION The intermittent stream acts as the storm water runoff system. 01 ~~. ILLEGAI.IUNAUTHCRIZEO DUMPING 02 C OBSERIIEO (OA TE: 3/ 13 / 86 I CJ POTENTIAL :lG: AU...-=GEO 04 NARRA TlVE DESCl'UPT1CN RCRA enforcement reported spills of pyridine and a potentially leaking laboratory drainage system. Also process spills of toluene. 05 OeSCRIPTlCN OF ANY OTr1E.::; KNOWN. PCTENTlAL.. OR ALLEGED HAZARDS III. TOTAL POPVLA TION POTE.~TlAU Y AFJ=ECTEO: {fQQ I IV. COMMENTS ~ V. SOURCES OF INFORMA nON ,c...IHC-"<: ..... ....,., • ; .:01< ..... '-""_'" ._ ... , RCRA enforcement report ~~13/86. DPNR summary of site conditions. VIChem letter to Centerchem 2/1/85. TAT site evaluation report 2/10/89. _~T St. Croix well survey 10/25/88. ---- ::". FOAM .070·12 (7·/11) · 07/14/89 TABLE 1 Laboratory Reagent Inventory CHEMICAL NAME 1,3-dinitrobenzene I-butanol l-chlorobutane I-propanol 18-Crown-6 99% 2,2-oxydiethanol 2,6-dimethoxybenzoic a9id99% 2,6-ditertiarybutyl p-cresol 2-hydroxybenzyl alcohol 99% 2-hydroxyethyl ether 2-methyl-l-butanol 99% 2-methylbutyl amine 3,3-dimethoxy benzidene 3-hydroxybenzoin acid 4-chlorobenzene sulfonamide 4-hydroxy 4methyl 2pentanone 4-hydroxybenzoic acid 4-methylbenzo phenone 97% 9-hydroxyflourene Acetic acid Acetone Acetonitrile Alkalinity C,D,E,G Aluminum Chloride Aluminum chloride Ammonium acetate Ammonium acetate ~~onium acetate purified Ammonium hydroxide Ammonium persulfate Ammonium persulfate Ammonium thiocyanate Amyl alcohol Arsenic trioxide Barium chloride Barium chloride Barium chloride Barium hydroxide Benzaldehyde Benzene Benzhydrol Benzoic acid Benzoin Benzoin 98% COMPANY Aldrich Chemical J.T.Baker Chemical MCB J.T.Baker Chemical Aldrich Chemical Kodak Aldrich Chemical Biesterfeld Aldrich Chemical Aldrich Chemical . Aldrich Chemical American Laboratorie Kodak Aldrich Chemical Aldrich Chemical Aldrich Chemical Aldrich Chemical Aldrich Chemical Aldrich Chemical MCB Fisher Scientific Supelco Mogul Corporation Mallinckrodt Witco Chemical Fluka Aldrich Chemical Jarchem Industries Sargent Welch Scient J.T.Baker Chemical J.T.Baker Chemical Fisher Scientific Mallinckrodt Fisher Scientific Drew Chemical Mallinckrodt Fisher Scientific Fisher Scientific J.T.Baker Chemical Tenneco oil Kodak Mobay Chemical Fluka Aldrich Chemical QTY 100 g 500 ml 4 L 500 ml 25 g 1 kg 25 g 500 g 25 g 1 kg 10 g 15 g 100 g 100 g 100 g 500 g 50 g 50 g 2x25 g 2x5 lb 4 L 1 box 4x2 oz 1 Ib 500 g 1 kg 2 kg 250 g 500 ml 2.5 kg 500 g 500 g 1 pt 2xl13g 1 gt 500 g 1 Ib 1 Ib 500 ml 2xlgal 100 g 1 Ib 2xl kg 4x500g STATE ----- ----- solid liquid liquid liquid solid liquid solid solid liquid liquid liquid liquid solid solid solid liquid solid solid solid liquid liquid liquid liquid solid solid solid solid solid liquid solid solid liquid liquid solid liquid solid solid solid liquid liquid solid solid solid solid 07/14/89 TABLE 1 Laboratory Reagent Inventory CHEMICAL NAME Benzophenone Benzophenone Benzophenone Benzophenone 99+% Benzoyl chloride Benzyl acetate 99% Benzyl alcohol Benzyl benzoate Benzyl chloride Benzyl chloride Benzyl cinnamate 98% Benzyl ether Benzyltriethylammoniumchlori Bismuth subnitrate Bromine Bromophenol blue Brucine sulfate Buffer solution pH 10.00 Buffer solution pH 4.00 Buffer solution pH 7.00 CAO-3 BHT Calcium sulfate anhydrous Cello-Seal Chloride F Chlorodiphenyl methane 98% Chloroform Chromotropic acid Na salt Cinnamaldehyde citric acid anhydrous Citricacidtrisodiumdihydrate Cobalt chloride Color standard 4 Congo red Copper metal Cupric sulfate Cupric sulfate DPD #1,2,3 Reagents Dibenzo 18-Crown-6 98% Dibenzoyl tartaric acid Dichloroethane 99% Dichlorophenyl methane 99% Dichlorotoluene 99% Diethylene glycol Diisobutyl aluminum hydride Diphenylmethane 99% COMPANY Aldrich Chemical H&S Chemical Upjohn Aldrich Chemical Mobay Chemical Aldrich Chemical Mallinckrodt Aldrich Chemical unknown Velsicol Aldrich Ch€mical Aldrich Chemical Aldrich Chemical MCB Fisher Scientific Fisher Scientific Fisher Scientific Fisher Chemical Fisher Scientific Fisher Chemical Sherwin Williams W.A.Hammond Drierite Fisher Scientific Mogul corporation Aldrich Chemical Fisher Scientific Fisher Scientific unknown J.T.Baker Chemical Aldrich Chemical Fisher Scientific unknown Fisher Scientific Fisher Scientific Fisher Scientific Mallinckrodt Taylor Chemical Aldrich Chemical Knoll Fine Chemicals Aldrich Chemical Aldrich Chemical Aldrich Chemical Fisher Scientific Texas Acres Aldrich Chemical .- QTY 500 g 1 bag 500 g 50 g 1 Ib 100 g 1 pt 100 g 4 oz 500 g 100 g 1 kg 25 g 1 1b 113 g 5 g 1 oz 500 ml 500 m1 500 ml 1 bag 4x5 lb 25 g 3 oz 100 g 4 L 25 g 2xl kg 500 g 1 kg 2xl lb 1 oz 25 g 500 g 500 g 500 g 3xl oz 50 g 1 kg 1 kg 25 g 100 g 1 gt 4 cyl 500 g STATE ===== solid solid solid solid solid liquid liquid liquid liquid liquid solid liquid solid solid liquid solid solid liquid liquid liquid solid solid liquid liquid solid liquid solid liquid solid solid solid liquid solid solid solid solid liquid solid solid liquid solid solid liquid gas liquid 07/14/89 TABLE 1 Laboratory Reagent Inventory CHEMICAL NAME Diphenylthiocarbazone Eosin Y Ether anhydrous Ethoxyguin Ethyl acetate Ethyl acetate Ethyl benzene Ethyl ether 99% ~ Ferric ammonium sulfate Ferric chloride Ferric chloride Ferric chloride alli~ydrous Ferric c~loride anhydrous Ferrous ammonium sulfate Formic acid Glacial acetic acid Hydrazine sulfate Hydrazine sulfate Hydrochloric acid Hydrochlo~ic acid Hydroxylamine hydrochloride Hydroxylamine hydrochloride Iodine Iron chloride anhydrous Isoamyl alcohol Isobutyl alcohol Lead acetate Lead nitrate Lithium perchlorate Magnesium sulfate Medical oxygen Mercuric chloride Mercuric oxide Mesityl oxide Methanol Methenamine Methyl alcohol Methyl orange Methyl red Monochlorobenzene N-methylaniline Na salt of ME salicylate Niacin N.F. Nitric acid concentrated Nitrobenzene COMPANY Fisher Scientific Aldrich Chemical Fisher Scientific unknown Aldrich Chemical MCB Dupont Fisher Scientific Fisher Scientific unknown Fisher Chemical Pennwalt Corporation Kodak Fisher Chemical unknown Fisher Chemical Fisher Scientific Fisher Scientific MCB Fisher Chemical Fisher Scientific MCB Fisher Scientific BASF Fisher Scientific J.T.Baker Chemical MCB Fisher Scientific Aldrich Chemical Fisher Scientific MSA Fisher Scientific Fisher Scientific Aldrich Chemical Fisher Scientific Fisher Scientific Mallinckrodt Fisher Scientific Fisher Scientific PPG Industries Kodak Sattra Chemical Neoera Chemical J.T.Baker Chemical Fisher Scientific QTY 25 g 25 g 4 qt 4 oz 5 gal 5x1gal 1 qt 6x500g 500 g 100 ml 1 lb 5x500g 500 g 1 lb 200 g 5 lb 4 oz 100 g 2x6 lb 3xl L 1 kg 4 oz 500 g 500 g 500 m1 500 ml 1 lb 100 g 500 g 500 g 1 cyl 2xl00g 500 g 100 g 4 L 500 g 1 gal 113 g 2xlO g 10 oz 1 kg 1 bag 250 g 2x8 lb 1 qt STATE ===== solid solid liquid liquid liquid liquid liquid liqiud solid liquid solid solid solid solid liquid liquid solid solid liquid liquid solid solid solid solid liquid .liquid solid solid solid solid gas solid solid solid liquid .solid liquid solid liquid liquid solid _.solid liquid .-1iquid UI/.lJi/'d':;J TABLE 1 Laboratory Reagent Inventory CHEMICAL NAME Non aqueous buffer soln. Nutrizyme oil #3 Paraffin oil Para formaldehyde Para formaldehyde prills 91% Perchloric acid Phenol red Phenopthalein Phenylhydrazine Phenylhydrazinehydrochloride Phosphorous pent oxide piperazine Potassium bromide Potassium butoxide Potassium chloride Potassium cyanate Potassium cyanide Potassium dichromate Potassium ferro cyanide Potassium hydroxide Potassium hydroxide Potassium iodide Potassium iodide Potassium periodate Potassium platinate Potassium sulfate Potassium sulfate Potassium sulfate Potassium thiocyanate Resorcinol Salicylaldehyde 99+% salicylic acid Salicylic acid salicylic acid sodium salt Sicapent Silica gel dessicant Silver nitrate Silver nitrate Sodium Chloride Sodium acetate Sodium acetate anhydrous Sodium acetate anhydrous Sodium amide Sodium benzoate COMPANY Beckman Instruments Merck Frich Oil Fisher Scientific MCB Celanese Chemical MCB Fisher Scientific Fisher Scientific Fisher Scientific Fisher Scientific Fisher Scientific MCB Fisher Scientific Callery Chemical Bec~~an Instruments Fisher Scientific Fisher Scientific Fisher Scientific Fisher Scientific Mallinckrodt Fisher Scientific Drew Chemical Fisher Scientific Fisher Scientific Varlacold Chemical Indiana Army Ammo Plant Aldrich Chemical unknown Fisher Scientific Koppers Aldrich Chemical Aldrich Chemical Aceto Chemical Aldrich Chemical MCB Davison Chemical J.T.Baker Chemical Sargent Welch Scientific Fisher Scientific Sattra Chemical Niacet corporation CDF Chimie Noth America Farchan Research Lab Sattra Chemical QTY 1 pt 2 oz 5 gal 1 gt 1 qt 1 lb 2xS lb 5 9 1 oz 4x4 oz 2 Ib 1 lb 100 9 5x500g 50 9 2x6 oz 1 Ib 500 g 500 9 3 kg 2x1 lb 500 9 1 gt 2x500g 100 9 5 9 250 9 500 9 50 9 500 9 3 bags 100 9 100 9 500 9 100 9 2.S L 2x1 gt 1 oz 30 9 500 9 3 bags 250 9 2x500g 500 9 1 bag STATE ===== liquid solid liquid liquid liquid solid liquid solid solid liquid solid solid solid solid solid solid solid solid solid solid solid solid liquid solid solid solid solid solid solid solid solid liquid solid solid solid solid solid solid .solid solid solid solid solid solid solid 07/14/89 TABLE 1 Laboratory Reagent Inventory CHEMICAL NAME Sodium benzoate Sodium benzoate Sodium benzoate Sodium borohydride Sodium carbonate Sodium carbonate anhydrous Sodium chlorate Sodium dichromate Sodium formate Sodium hydride Sodium hydroxide Sodium metal Sodium nitrite Sodium nitro ferricyanide Sodium sulfate Sodium tartrate Sodium tartrate Sodium thiosulfate Succinic anhydride Succinic anhydride Sulfamic acid Sulfanilic acid Sulfite O,P,Q Sulfuric acid Tetraphenolboron sodium 99% Thiopene Total alkylinity indicator Tributyl borate Trichloroethylene Triethyl borate 97% Triethylenediamine Uranyl acetate Weedox C/R 250 herbicide Xylene Zinc chloride Zinc chloride anhydrous p-chlorobenzene sulfonamide p-naptholbenzein p-toluenesulfonicmonohydrate pH indicator A z Miscellaneous unknowns z Miscellaneous unknowns COMPANY Dastech International Ishihara Corporation Pfizer Fisher Scientific Fisher Scientific Mallinckrodt Hooker Chemical Fisher Scientific unknown ". Thiokol/Ventron Division Mallinckrocft RMI Fisher Scientific MCB Fisher Scientific J.T.Baker Chemical Fisher Scientific Fisher Scientific MCB Aldrich Chemical Fisher Scientific H&S Chemical Mogul Corporation J.T.Baker Chemical Aldrich Chemical Kodak Drew Chemical Aldrich Chemical Mallin::krodt Aldrich Chemical Air Products unknown Southern Mill Creek Prod. Fisher Scientific Fisher Scientific Mineral Research H&S Chemical Fisher Scientific Aldrich Chemical Mogul Corporation on site lab glassware on site one oz bottles QTY 1 bag 250 g 100 lb 4x25 g 1 kg 1 lb 1 box 10 kg 5 lb 1 lb 500 g 2 boxs 2x500g 4 oz 500 g 2 OZ 6xl13g 2xl lb 6x250g 2xl kg 500 g 1 bag 3x2 OZ 10 lb 25 g 100 g 1 qt 750 g 1 pt 100 g 250 g 500 g 2x5gal 5xl L 500 g 1 lb 2 bags 25 g 500 g 2 oz 280bot 238bot STATE ===== solid solid solid solid solid solid solid solid solid solid solid solid solid solid solid solid solid solid solid so:id solid solid liquid liquid solid liquid liquid liquid liquid liquid solid solid liquid liquid solid solid solid solid solid liquid misc. liquid Page No. 1 07/14/89 Chemical Name Acetone Acetylene Activated carbon All-weather patch material Amersite 2 Ashland MeOH Benzyl acetate Benzyl chloride Chlorine Chloroform Crofox Crystal Clear floor finish Degreaser Drewtrol 8500 Ethyl alcohol Filteraid Glacial acetic acid Glycol Humisorb Hydrochloric acid Hydrogen chloride Insulation (asbestos??) Insulation fiberglass Lubricating oil Lubricating oil Magnesium sulfate trihydrate Methanol Methanol Methyl isobutyl carbinol Methyl isobutyl ketone TABLE 2 Drum Inventory Company Ashland Chemical VI Gas Calgon Corporation Revere Chemical Valley Freight syst. Ashland Chemical Island Chemical Velsicol Corporation VI Gas unknown Cerfact Laboratories Cerfact Labor~tories unknown Valley Freight syst. unknown unknown Celanese Chemical Island Chemical Culligan Certified Laboratory VI Gas unknown unknown Texaco Texaco Tomita Pharmaceutica Ashland Chemical unknown Van Waters & Rogers Ashland Chemical Qty 55 G 2 cyl' 30 bag 55 G ,55 G 5 G 2lx55G 28x55G 1 cyl 55 G 55 G 2x~0 G 55 G 55 G 115x55 10x30G 13x55G 20x55G 30 G 55 G 1 cyl 13 box 7 box 2xlO G 5x55 G 6x25kg 5x55 G 3x55 G l2x55G 55 G state Cond Dates ===== liquid gas solid solid liquid liquid liquid liquid gas liquid liquid liquid liquid liquid liquid solid liquid liquid solid liquid gas solid solid liquid liquid solid liquid liquid liquid liquid ==== good good good fair fair good fair fair poor good poor good good poor poor poor good poor fair poor poor good good good good fair good fair good good ----- ----- 1984 1984 Page No. 2 07/14/89 Chemical Name Micro media filter sheets Oxygen Oxygen Paints Paints Paints Paints Para-phenetidin Pentosin Potassium acetate Potassium sulfate Powdered filter media Propane Purafil II Quinine sulfate Rinseline injector fluid Rout Salicylic acid Salt Soda ash Sodium acetate anhydrous Sodium acetate anhydrous Sodium bicarbonate Sodium hexa-meta phosphate Sodium hydroxide Sodium hydroxide Spent toluene/acetone Sterling salt crystals Sulfamic acid Tartaric acid Thinner TABLE 2 Drum Inventory Company Ertel Engineering VI Gas Santa Maria Gases unknown unknown International Paint International Paint unknown Deutsche Pentosin Jarchem Industries unknown Ionics unknown unknown Kimafarma Bob Chamber Lcd. Cerfact Laboratories Rhone-Poulenc unknown Allied Chemical unknown Jarchem Industries Stauffer Chemical FMC Mantek Manuel del Valle Inc unknown unknown Dupont Pfizer Chemical unknown Qty === 18 box 3 cyl 1 cyl 44x5 G 53x1 G 97x5 G 21x1 G 55 G 20 L 8x100# 50 bag 2 boxs 4 cyl l5x10G 20 G 55 G 20 G 27drum 2x30 G 15x100 50 lb 200 lb 8x100# 200 lb 55 G 12x55G 2x55 G 50 lb 400 lb 15xlOO 6xl G state Cond Dates ----- ----- solid gas gas liquid liquid liquid liquid liquid liquid solid solid solid gas solid liquid liquid solid solid solid solid solid solid solid solid liquid liquid liquid solid solid solid liquid ==== ===== good good good fair fair fair fair fair 1983 fair good good good good good good good poor good good poor good poor poor good poor good fair poor poor poor fair Page No. 3 07/14/89 TABLE 2 " Drum Inventory Chemical Name . Company Qty state Cond Dates -==- ===== __ m=- ===== Thinner Advance 55 ' G liquid fair Toluene Ashland Chemical 3x55 G liquid fair Toluene unknown 5x55 G liquid good Triethylamine Air Products 55 G liquid good 1984 waste oil ':\ unknown 2x55 G liquid good z Empty drums unknown 130 n/a fair z Miscellaneous unknowns on site containers 25 misc. poor '*iI, \\ " 1.50 POLREPS U.S. ENVIRONMENTAL PROTECTION AGENCY POLLUTION REPORT DATE: Augus t 8, 1989 Region II Response and Prevention Branch Edison, New Jersey 08837 TO: W. Muszynski, EPA S. Luftig, EPA R. Salkie, EPA (201) 548-8730 - CommerClal and FTS 24 Hour Emergency M. Randol, EPA G. Pavlou, EPA ERD, WH-548B POLREP NO.: INCIDENT/SITE NO.: POLLUTANT: CLASSIF:CATION: SOURCE; LOCATION: AMOUNT: WATER BOD),,: 1. S 1 rUAT I ON Three (3) N/A (E-Mail) B. Sprague, EPA G. Zachos, EPA P. Gelabert, EPA A. Smith, VIDPNR LEPC TAT Lab Chemlcals, Alcohols, Solvents, Acids Major Vlrgin Island Chemical Company (VIChem) St. Croix, USVI 800 Lab Chemlcals, 400 Drums, 22 Tanks Groundwater, Carlbbean Sea A. Same as prevlous POLREPs. Slte conditions have not slgniticantly changed. 2. ACTION TAKEN A. June 14, 1989, conference call conducted between ORC, NYCCB, OSC and F. Schubert (owner of VIChem). Mr. Schubert explalned that he will not be able to finance a clean-up at the facillty. EPA informed him that due to the significant hazards presented by the site, Region II is prepared to conduct a removal action and remove the chemicals from the facility. EPA lntormed Mr. Schubert that he will have approximately one month to contact facllities which may be interested in bUYlng some of the materials on-site. EPA will send him a Letter of Intent form to be used during these recycling efforts. Mr. Schubert had no Objectlon to EPA removlng all chemicals from the slte and further stated that he would not be obstructive to EPA .~ cleanup. B. ,j \j 1 Y i 0 .J...'...J , 1989, Actlon Memorandum finallzed and sent to NY office for concurrence and approval. , OSC received a copy of a letter from Mr. Schubert to NYCCB, stating that he has a potential buyer for the site and requesting EPA to hold off on the removal action. OSC coordinated with NYCCB on th~s matter. C. July 25, 1989, Chief RPB coordinated with ORC on potential sale of VIChem. D. August 1, 1989, recelve fax from NYCCB concerning VIAG's request to start operat~on shortly and install a water treatment unit for the~r ethanol dehydration operation. E. August 4, 1989, conference call conducted with OSC, ORC, NYCCB and F. Schubert. The potential'sale of VIChem has fallen through and It appears do~btful that a sale with other potential buyers Will occur. Mr. Schubert assured EPA that all prospective buyers 01 VIChem are aware of EPA's ~nterest ~n hav~ng the site cleaned-up. ORC informed Mr. Schubert that EPA will proceed with our- plans for a Superfund clean up, EPA will send him an access agr~ement form for h~s signature and wanted to be sure that all pruspectlve buyers have received copies of the March 13, 1989 Notlce Letter to VIChem. F. August 8, 1989, Consent for Access to Property form sent by ORC to F. Schubert. Acting Regional Administrator approves Action Memorandum. FUTURE PLANS AND RECOMMENDATIONS: A. OSC Will ln~t~ate a Delivery Order for D.H. Materials to conduct the site clean up. B. OSC wlll lnform USVI DPNR about the Action Memorandum approval. C. OSC will coordinate contingency planning meeting for appropriate U.S.V.I. public agencies. FURTHER PDLREPS FINAL POLREP ____ FDRTHCDMING~SUBMITTED BY ~~~- On~Scene Coordinator Response and Prevention Branch DATE RELEASED Secl,? \'{ 8'3,. U.S. ENVIRONMENTAL PROTECTION AGENCY POLLUTION REPORT DATE: June 7, 1989 Region II Response and Prevention Branch Edison, New Jersey 08837 TO: W. Muszynski, EPA S. Luftig, EPA R. Salkie, EPA (201) 548-8730 - Commercial and FTS 24 ~our Emergency M. Randol, EPA G. Pavlou, EPA ERD, WH-548B- -,-- (E-Mail) B. Sprague, EPA G. Zachos, EPA P. Gelabert, EPA A. Smith, DPNR LEF'C TAT POLREP NO.: Two (2) INCIDENT/SITE NO.: N/A POLLUTANT: CLASSIFICATION: SOURCE: LOCATION: AMOUNT: WATER BODY: 1. SITUATION: Lab chemicals, Alcohols, Solvents, Acids Major Virgin Island Chemical Company (VIChem) St. Croix, U.S. Virgin Islands 800 Lab Chemicals, 400 Drums, 22 Tanks Groundwater, Caribbean Sea A. Same as previous pol rep. Site conditions have not significantly changed. 2. ACTION TAKEN: A. OSC discusses contents of Notice Letters with aRC and Enforcement Programs. On March 13, 1989 Notice Letters were issued to the following Potentially Responsible Parties (PRPs): Berlex Laboratories, Island Chemical Company, CHS Holding Company (land owner), Virgin Island Chemical Company, and VIAG Fuels. . B. March 30, OSC receives copies of Notice Letter replies from Berlex, VIChem and ~IAG Fuels. None of the PRP's are willing to conduct or finance a CERCLA response. OSC informed verbally that Region II will conduct a removal action at this site ............................................................ .. I & ., C. April 5, asc contacts D. Weston of VIAG Fuels and requests him to inform Enforcement Programs of VIAG's intended use of ethanol, paints and water treatment chemicals, thus averting the need for EPA to dispose of these materials. D. OSC drafts memo to Enforcement Programs concerning enforcement issues which must be addressed prior to an EPA removal action. Issues include material owned or planned for purchase by VIAG and temporarily evacuating VIAG and St. Croix Security Kennels (SCSK). Memo issued April 20, 1989. E. Draft Action Memorandum prepared and distributed for comment on May 17, 1989. Comments due June 2. F. OSC contacts Fred Schubert, President ,of VIChem and receives verbal permission for access to the site during the week of May 22~ 1989. Mr. Schubert was not aware that there were hydrogen chloride and chlorine ~;liners on-site and knew nothing about the cans of ether stored in the labs. Mr. Schubert informed the OSC that he is making plans to repair the warehouse. G. asc discusses proprosed removal action with representatives from DPNR on May 22. Discuss possibility of having DPNR order VIAG and SCSK to leave the site during on-site removal activities and monitoring the site prior to EPA's mobilization to the site. asc will write a formal request for DPNR to carry out these tasks. H. May 23, 1989, asc discusses with Lt. Steve Hanewich, the possibility of using the US Coast Guard HazMat unit in San Juan for technical and contractor oversight assistance during the removal. USCG will need a Memorandum of Understanding (MOU) for reimbursemewnt of lodging/per diem and disposable personnel . . protect~ve gear. I. asc briefs the Caribbean Regional Response Team on EPA's proposed removal action at VIChem. FEMA recommends that during on-site treatment activities or a fire at the facility that the nearby prison not be evacuated. J. asc visits VIChem with OH Materials Project Manager on May 25, 1989 to review site conditions and discuss proposed clean up activities for the site. Conditions within the labs remains the same. Drums within the warehouse have been restaged in an orderly fashion however they are not staged by compatibility groups. The warehouse floor has been swept clean and the leaking drum of sulfamic acid has been overpaCked, according to VIChem's President, however this drum was not located. One drum labeled "skin cleaner" was leaking. According to D. Weston of VIAG~ the company remains inactive and is having trouble getting ethanol from Europe. Within the tank farm, the first four tanks contain ethanol and the fifth tank contains diesel fuel. The red tank truck contains water VIAG has had wate~ f~om the on-site well analyzed and dete~mined that it was f~ee of contamination and suitable fo~ thei~ t~eatment p~ocess. OSC inqui~ed if chlo~ofo~m was included in these analyses, M~. Weston was not su~e. K. May 26, 1989, OSC meets with Winston Tu~nbull, Di~ecto~ fo~ VI Fi~e Se~vices and Kirk G~ybowski, Di~ecto~ fo~ VI Eme~gency Management Se~vices and b~iefed them on EPA's p~oposed ~emoval action. Grybowski ~ecommended meeting with the St. Croix hospital administ~ato~ and EMS's Deputy Di~ector on St. C~oix to discuss EPA's on-site decontamination p~ocedures since neithe~ the hospital o~ EMS is p~epared to ~eceive contaminated pe~sonnel. L. May 30, OSC ~eceives copies of letters from VIChem (thru Enforcement P~og~ams) stating that .. VIChem is p~epared to make its best effo~t to unde~take the clean-up at the site" and "As you know, 1 feel the clean up needed at the site is quite manageable ...... This cont~adicts VIChem's ~eply to the Notice Lette~ in which VIChem stated " ..• 1 have to indicate fo~ the ~eco~d that Vi~gin Island Chemical Company has no funds with which to have any ~equi~ed wo~k ca~~ied out and has no staff to pe~fo~m sLich WO~k." M. OSC coo~dinates with Enfo~cement P~og~ams and is info~med that ORC and NY/CC will meet on June 1 to develop an enfo~cement st~ategy. N. June 2, 1989, OSC has ~eceived comments on draft action memo from AD-REPP and at his suggestion will include resampling of wells contaminated with chlo~ofo~m in the scope of work fo~ this removal. 3. FUTURE PLANS AND RECOMMENDATIONS: A. OSC will investigate the possibility of developing a MOU with USCG fo~ MSO-San Juan HazMat assistance during the removal action. B. OSC will ~equest ATSDR to notify and info~m the St. Croix hospital and EMS of EPA's p~oposed activities and decontamination p~ocedu~es which will be available. C. OBC will prepa~e notification p~ocedu~es and a contingency plan fo~ the p~ison at Golden G~ove. D. OSC will develop CAMEO plume models fo~ various weather conditions and ai~ ~elease scena~ios. ~ E. OSC will formally request DPNR to monitor the site prior to EPA's mobilization, investigate the possibility of DPNR ordering SCSK and VIAG off-site during EPA's removal action, and request a list of appropriate agencies and politicians to notify concerning the proposed removal action. FURTHER ~~ POLREPS FINAL POLREP FORTHCOMING.-)L:,SUBMITTED BY A. ~JYl'a..:.;. Dougl s R. Kodama OSC -,- Response and Prevention Branch DATE RELEASED::r~ I, \q ~ , , u.s. ENVIRONMENTAL PROTECTION AGENCY POLLUTION REPORT DATE: February 8, 1989 Region II Response and Prevention Branch Edison, New Jersey 08837 TO: W. Muszynski, EPA S. Luftig, EPA R. Salkie, EPA (201) 548-8730- Commercial and FTS 24 Hour Emergency M. Randol, EPA G. Pavlou, EPA ERD, WH-548B POLREP NO: INCIDENT/SITE NO.: POLLUTANT: CLASSIFICATION: SOURCE: LOCATION: AMOUNT: WATER BODY: 1. SITUATION: One (1) N/A (E-Mail) B. Sprague, EPA G. Zachos, EPA P. Gelabert, EPA A. Smith, DPNR LEPC TAT Lab Chemicals, Alcohols, Solvents, Acids Major virgin Island Chemical Company (VI CHEM) st. Croix, US Virgin Islands 800 Lab Chemicals, 400 Drums, 22 Tanks Groundwater, Caribbean Sea A. The Virgin Island Chemical Company (VICHEM) site is located on the Island's south side. The site is situated on Route 66, approximately 0.5 miles due north of the Alexander Hamilton Airport. The site covers approximately 3.5 acres and is bordered to the north by an intermittent stream that originates on the north side of the Island and discharges into the Caribbean Sea. A number of residences and industries are located as close as one-tenth of a mile from the site. In addition, several well fields are located in the vicinity of the site. The st. Croix prison is located 1/4 mile downwind from the site. DPNR stated it would be very difficult to evacuate prisoners in the event of a chemical fire at the site. B. The site consists of a main warehouse building including offices, the reactor, centrifuge and maintenance buildings and fourteen above ground tanks. Living on-site adjacent to the main warehouse building are anywhere from 15 to 25 guard dogs housed in individual kennels. Also living on-site is the kennel operator, Kate Wesp. A house trailer is located on the concrete surface near the .'" loading dock. It is also apparent that Wesp uses the restroom facilities and kitchen area in the main building as living quarters. C. Presently occupying the site is the company VIAG Fuels, Inc. VIAG utilizes some office space in the main building and also has ethanol stored in four of the aboveground tanks. The principals of the firm plan to begin an alcohol dehydration project on-site in the near future. D. The 3.5 acre site is owned by Charles H. Steffey, Inc. On May 1, 1969 Steffey leased the property to Houston Chemical Industries, Inc. Houston Chemical assigned the lease to Caribe Chemical Company, Inc., (subsequently known as Pierre I America, Inc.) on March 20, 1972. On June, 1~78, Pierrel America assigned the ground lease to Cooper Laboratories, Inc. (Cooper). On October 30, 1979 Cooper Laboratories assigned the lease to its subsidiary, Island Chemical Company (ICC). On November 1, 1979, Cooper Laboratories sold all of the stock of ICC to the predecessor of Berlex Laboratories, Inc. (Berlex). On September 14, 1984, ICC sold its assets to Virgin Island Chemical Company (VICHEM). This background information has been supplied by the Virgin Islands Department of Planning and Natural Resources (DPNR). E. Limited PRP (Berlex) site clean-up and soil excavation has taken place in the recent past under a RCRA enforcement action. Berlex is currently finalizing a scope of work for a remedial investigation/feasibility study addressing soil and groundwater contamination. 2. ACTION TAKEN: A. On Tuesday, January 31, 1989, the u.s. EPA Response and Prevention Branch conducted a Preliminary Assessment and Removal Evaluation at the VICHEM site. This action is in reply to a request from George Pavlou, Associate Director Enforcement Programs dated 1/23/89. B. This preliminary assessment was coordinated with and observed by DPNR personnel. DPNR's primary concerns with this site are the threat of fire/explosion, and the threat (or actual) migration of spilled materials to the surrounding soil and groundwater. C. The initial entry into the main warehouse building was made at 0930 hrs. on January 31, 1989. All safety procedures were followed for a level "B" entry in a hot climate. Air monitoring was conducted with OVA, HNU, CGI, Radiation Detector, HCN Monitox, H2S Monitox and pyridine . .... Draeger tubes. All air monitoring readings were equivalent to background (taken off-site), except for in room 5 of the drum warehouse which showed ambient conditions 1 unit above background on the OVA. All further entries were made in level He". D. Three areas were delineated based upon the type of material located in each of these areas are: A. The laboratory (main building). B. The drum storage warehouse (main building). C. The grounds outside the building including the reactor and centrifuge. Each of these areas will be described below. 1. Laboratory 813 containers of laboratory reagents and unknown liquid and solid material are located in this area. Some of the more dangerous items of note are as follows: a. Sodium metal (2 boxes). Water reactive. b. Ethyl Ether (6 cans). Potential explosive. c. Diisobutyl aluminum hydride (4 lecture bottles). Spontaneously combusts in air. d. Potassium cyanide (2 bottles). Poisonous. Stored near acids, potential for release of hydrogen cyanide gas. e. Phosphorous pentoxide (l bottle). Reactive. f. Sodium hydride (I bottle). Water reactive. g. Two flammable storage cabinets containing various materials and unknowns. h. Two office type storage cabinets. One cabinet has spilled material on the top shelf which has dripped downward to mix with other chemicals. Many other chemicals exist in the laboratory, as well as many containers with unknown materials. All the chemicals which had dates are at least five years old. 2. Drum Storage Warehouse In the main warehouse are located approximately 400 drums, of these, 211 are green painted drums which have the words ETHYL ALCOHOL stenciled on the lid. The condition of the ethyl alcohol drums vary from fairly sound to extremely deteriorated. Some of the drums consist of only a rusted shell with gaping corroded holes. A rough estimate shows that 100 are empty and 100 contain material. This material may be some type of sludge. Other materials found are as follows: .-'" a. Laboratory unknowns (75 containers less than 1 gal. ) b. Methanol (5 x 55 gal.) c. Glacial acetic acid (13 x 55 gal.) d. Benzyl acetate (21 x 55 gal.) e. Toluene (8 x 55 gal.) f. Antifreeze/glycol (20 x 55 gal.) g. Benzyl chloride (28 x 55 gal.) h. Salicilic acid (27 fiber drums) i. Methyl isobutyl carbinol (12 x 55 gal.) j. Sodium hydroxide (12 x 55 gal.) k. Bulging drum, unmarked (1) 1. Drums in which some type of reaction has taken ~lace, lid popped off (2) m. Drums of known and unknown material. n. Paint (97 x 5 gal. - 21 x 1 gal.) o. Cylinder chlorine (1 poor condition). p. Cylinder hydrogen chloride (ldeteriorated condition). q. One drum of sulfonic acid, broken and leaking its contents. r. A cistern with PVC pipe leading to a pumping system outside the building. 3. Outside Grounds An inspection of the reactor and centrifuge and maintenance buildings revealed various production materials including lubricating oils; propane; oxygen and acetylene cylinders; filter media; ethanol; assorted paints and some sodium hexa-meta phosphate. Some of the oil drums are leaking. Scattered around the facility are eight stainless steel tanks with quantities of unknown liquid varying from empty to three quarters full. A large storage tank is on site along with numerous pressure and reaction vessels. Fourteen large green storage tanks are also on-site. Ten are planned to be used in the alcohol dehydration project. Four of the ten are full of ethanol. The other six are empty. The remaining four not being used are empty and unsound. E. The Governors office Department of Fire Services was contacted to assess local chemical fire control capabilities. Three fire companies are located on the island with the nearest to the site being Grove Place. All firefighting personnel are equipped with SCBA, however, only some have had formalized chemical hazard training. A limited amount of foam capability is available. .~ 3. FUTURE PLANS AND RECOMMENDATIONS: A. The USEPA CERCLA Enforcement Program is actively pursuing PRP involvement in a site clean-up and drum removal. B. An action memo and disposal plan will be drafted by this branch in the event the PRP's fail to act promptly. FURTHER POLREPS FINAL POLREP FORTHCOMING X SUBMITTED BYk~~ OSC Response and Prevention Branch DATE RELEASED \=e...~ ~/\C\~ • DATE: I3JECT: FROM: TO: UNITED STATES ENVIRONMENTAL PROTECTION AGENCY AUG 8 1:789 REGION II Preliminary Assessment, Removal site Evaluation, and Funding Authorization Request for a CERCLA Removal Action at the Virgin Island Chemical Company, Inc. site, st. Croix, u.s. virgin Islands - ACTION MEMORANDUM I) \ Douglas R. Kodama, On-Scene Coordinator ~ ~ ~.~~"""-. Response and Prevention Branch ~ William J. Muszynski, P.E. Acting Regional Administrator 11iRU:~"\stePhen D. Luftig, Director~1V\Sq/,",G~c-Q I Emerge~cy and Remedial Response Division I. EXECUTIVE SUMMARY On January 23, 1989, Mr. Geor.ge Pavlou, Associate Director for Enforcement Programs, formally requested that the Response and Prevention Branch conduct a removal evaluation at the Virgin Island Chemical Company sit~ in st. Croix, U.s. Virgin Islands. A preliminary assessment, site iLspection and removal site evaluation were conducted o~ January 31 and February 1, 1989. Unstable and reactive hazardous materials are present in a building and on the grounds at this inactive chemical plant. Unknown contaminants are migrating off-site into the adjacent soil and potentially the g~ound water. Hazardous substances present include chlorine and hydrogen chloride, both of which are contained in extremely deteriorated cylinders, sodium metal a water-reactive material posing a threat of fire and potassium cyanide. Other reactive materials include diisobutyl aluminum hydride (a pyrophoric liquid), phosphorus pentoxide, sodium borohydride, sodium hydride and ethyl ether (potentially shock- sensitive). Five businesses are adjacent to the facility and the st. Croix Prison at Golden Grove is located approximately one-quarter mile downwind from the site. An air release or fire at this chemical plant could adversely affect the prison, businesses and area residents. The proposed removal action will address all above ground containerized materials and is expected to take eight to ten months to complete. The estimated project ceiling is $1,840,000 of which $1,262,000 is for mitigation contracting. 2.10 ACTION MEMO, SI 8/8/89 REGION II FORM 1320-1 (9/85) -2- II. BACKGROUND A. site Setting/Description The Virgin Island Chemical Company (VIChem) is located on Plot 13Q of Estate Bethlehem Middle Works off of the Melvin Evans Highway (Route 66) in st. Croix, u.s. Virgin Islands. Located on the south side of the island near the western end of St. Croix (Figure I), the 3.5 acre site has a gently rolling topography ranging in elevation from 10 to 30 feet above sea level. The site is bordered on the north by an intermittent stream which originates on the north side of the island and discharges to the Caribbean Sea. Runoff from the site enters this unnamed intermittent stream. ' The Caribbean climate is typical of the Neotropics. Temperatures vary from 70°-95° Fahrenheit with a relative humidity in excess of 60%. Winds are fairly constant at 10-20 miles per hour and are generally from the eastern quadrant as they pass over the Caribbean Sea. Seasonal rains in winter and summer are common. Hurricanes and tropical storms may occur at any time during the year, but are more likely during the summer and fall. The surrounding area is predominantly commercial with five businesses adjacent to the site. Downwind, approximately one- quarter mile northwest of the site is the st. Croix Prison at Golden Grove (Figure 1). Several residences are located one- third mile north of the site at Upper Bethlehem and three- quarters of a mile northwest of the site at Golden Grove. South of the site (upwind) is one residence within one-tenth of a mile, a quarry, the Melvin Evans Highway and the Alexander Hamilton Airport. The site property is currently owned by the Charles H. Steffey Holding Corporation. This landowner originally leased the land on a 30 year lease to Houston Chemical Industries on May I, 1969. On March 20, 1972, Houston Chemical assigned the lease to Caribe Chemical Company, Inc. (subsequently known as Pierrel America, Inc.). On June 30, 1978, Pierrel America assigned the ground lease to Cooper Laboratories, Inc .. On July 21, 1978, Cooper Laboratories incorporated Island Chemical Company as its sUbsidiary to assume its production activities at the facility. On October 30, 1979, Cooper Laboratories assigned the lease to its subsidiary, Island Chemical Company. On November 1, 1979, Cooper Laboratories sold all of the stock of Island Chemical Company to the predecessor of Berlex Laboratories, Inc. (a sUbsidiary of Schering-Berlin Inc.). On September 14, 1984, Berlex sold Island Chemical Company assets and assigned the lease to Virgin Island Chemical Company (VIChem). VIChem is currently inactive and attempting to sell company assets and reassign the lease. -3- Prior to 1980/ it is believed that the facility was used for the manufacture of pharmaceutical chemicals, primarily phenacetin, ethoxyquin and quinidine. Berlex reportedly used this facility to make quinidine gluconate used for the production of quinine. Quinine is an antimalarial medicine and flavoring in carbonated beverages. VIChem produced benzyl acetate by reacting benzyl chloride with acetic acid. Benzyl acetate is used in perfumes, flavorings, resins, lacquers, polishes, printing inks and varnish removers. In 1985, VIChem also began producing benzyl salicylate which is used as a perfume fixative, solvent for synthetic musk, sun-screening lotions and soap odorant. In 1984, U.S. Resources and Chemicals, Inc. began leasing a portion of the racilrty from VIChem, and shortly thereafter started an alcohol dehydration operation. U.S. Resources transferred the lease and operation to.~IAG Fuels, Inc. (VIAG). VIAG currently owns the alcohol dehydration process equipment and is presently inactive. According to David Weston, President of VIAG, there is an oral agreement between Chase Manhattan Bank (VIChem's mortgage bank), VIChem and VIAG in which VIAG currently provides site security. Also on-site at the present time is the st. Croix Security Kennels (SCSK). Dog kennels for 20 to 30 guard and attack dogs are present and the Secretary/Treasurer for SCSK lives on-site in a trailer. B. Quantity and Tvoes of Substances Present The VIChem process facility was set up for batch and semi- continuous chemical manufacture. The process area, east of the maintenance and utility building (Figure 2) consists of two open- bay reactor areas and a centrifuge/dryer building. The six reactors are either glass-lined or stainless steel and are agitated, jacketed and have overhead condenser systems. Four of these reactors are also equipped with distillation columns. The centrifuge/dryer building contains various centrifuges, dryers, filters and grinding equipment. During the January 1989 preliminary assessment, inspection of accessible areas of the reactors and the centrifuge/dryer building revealed that they were empty of raw materials and product. West of the main building is the tank farm which contains fourteen 8000 gallon tanks. Four of these tanks contain ethanol and one tank contains diesel fuel owned by VIAG and used to fuel their alcohol dehydration process. The remaining tanks in the tank farm are empty. The main building and warehouse (areas 1/3,4/5 and 6 on Figure 3) contain approximately 400 drums (drum inventory, Table 2). Two hundred of these drums are labeled ethyl alcohol and half of these are empty. The condition of the ethyl alcohol drums varies from fairly sound to extremely deteriorated. Some of the other materials in the warehouse which are in deteriorated or leaking - " -4- containers include a cylinder of chlorine, one cylinder of hydrogen chloride, one unlabeled bulging drum, two drums with unknown contents in which a reaction has taken place causing the lids to come off and dispersing a white crystalline material, one drum of sulfamic acid which is broken and is leaking its contents. The deterioration of these containers has been accelerated by leaks in the warehouse roof, causing portions of the warehouse floor to be flooded after it rains. The accumulation of rain water on the floor allows spilled materials to mix and is eventually discharged to the ground east of the warehouse near the septic tank. The majority of the remaining drums contain flammable, poisonous, combustible or corrosive materials. A~though some of these drums are in poor condition, they have not yet been severely impacted by rain water from the leaking roof. The two laboratories within the main building (areas 11,15,18 and 22 on Figure 3) contain over 800 laboratory reagent containers (lab inventory, Table 1). Some of the more dangerous materials within the labs are: sodium metal (water-reactive), ethyl ether (formation of shock-sensitive peroxides), diisobutyl aluminum hydride (air-reactive), potassiun cyanide stored near acids (hydrogen cyanide air release), phosphorus pentoxide (water-reactive), sodium hydride (water-reactive), sodium borohydride (water-reactive), and approximately 75 unknown materials in reagent-size containers. At the time of EPA's removal site inspection on February 1, 1989, the water from the leaking warehouse roof had not affected the lab areas. According to the June 1978 "Quinidine Sourcing Project" written for Cooper Laboratories and attached as Exhibit B to civil Action No. 88-1346-Y "Certification of Michael C. Chester", both di- isobutyl aluminum hydride and sodium metal were necessary for converting cinchona bark into quinidine gluconate. According to Exhibit C of this document, Cooper Laboratories experimented with this process from November 1978 to October 1979. Table 3 lists materials on-site which are CERCLA hazardous substances and the statutory source for this designation. Table 4 lists toxicological effects of some of the compounds found at the site. C. National Priorities List Designation This site is not on the National Priorities List. It has not been submitted for ranking. -5- III. THREAT A. Threat of Exposure to the Public and the Environment Five categories of threats exist at this site: threat of fire/ explosion, threat of direct contact, threat of an air release from the deteriorated hydrogen chloride and chlorine cylinders, the multiple threats posed by the leaking roof in the warehouse, and the improper storage of reactive hazardous materials at this inactive facility. Neither of the two companies presently operating at the site (SCSK, VIAG) have qualified personnel to safely handle or monitor hazardous materials stored at the facility. The threat of exposure through direct contact, ingest~on or inhalation exists for personnel employed by these companies. All personnel have free access to the labs and, warehouse area. Tampering with some of the reactive materials or materials in deteriorated containers CQuid result in serious injury or death. Incompatible materials are stored in close proximity in the laboratories and the warehouse. In addition, the potential for adverse reactions is real and will continue to increase as the chemicals age in a hot and humid climate and are subject to persistent ~inds laden with saline moisture from the Caribbean Sea and rain water from the leaking warehouse roof. At least three examples of reactions taking place are evident in the drum storage area. These consist of one bulging drum and two drums in which an unknown crystalline material has exerted enough pressure to push open the drum lids and dispersed this material to the surrounding floor (photo #16). An unknown lab reagent has leaked its contents within one of the reagent storage closets (photo #10 and #11). During a fire, explosion or air release from VIChem, "nearby residences, businesses, the st. Croix prison and people using the Melvin Evans Highway could be severely impacted by toxic-laden smoke or plume. There are three fire departments on st. Croix which would respond to a fire at this facility. Although they have a number of self contained breathing apparatus, the required OSHA training is limited for qualified responders to hazardous material incidents. In addition, there is another exposure pathway for direct contact and ingestion. Groundwater contamination by chloroform has been well documented by EPA for potable wells in the immediate vicinity of the VIChem facility. The March 13, 1986 RCRA Enforcement investigation, conducted by the Surveillance and Monitoring Branch, revealed chloroform contamination in the on-site production well. During March and November 1988, the Response and Prevention Branch conducted well sampling and -6- analyses at the nearby Fairplains wells. These wells are located between VIChem and the st. Croix prison and are a major source of drinking water on the island. Chloroform contamination was found in Fairplains wells number 6, 8 and 9 in concentrations ranging from 11 ug/l to 75 ug/l (ug/l=micrograms per liter). The Virgin Island Port Authority (VIPA) well number 2 is located approximately one-half mile west of the site and was also contaminated with chloroform at a concentration of 11 ug/l. During the March 1986 RCRA Enforcement investigation, the inspectors observed four empty 55 gallon drums of chloroform. During the Response and Prevention Branch's site investigation in January 1989, one 55,gallon drum and one four liter bottle of chloroform were observed. There are no other known chemical industries in the Upper Bethlehem/Gol~~n Grove area. B. Evidence of Extent of Release The warehouse area of the main building contains several drums which have leaked or are presently leaking. A 55 gallon fiber drum of sulfamic acid has been extremely deteriorated by the flooding of the warehouse floor from the leaking roof (photo #17). Two unlabeled drums show signs of an uncontrolled reaction and have dispersed some of their contents to the surrounding warehouse floor (photc #16). Bags of tartaric acid have deteriorated and released some of the acid to the floor as well (photo #21). Several unlabeled drums are in such poor condition that any material in them has already been released (photo #19). There may be other releases which have occurred which are not as obvious as those presented in the photodocumentation. Air monitoring in the warehouse area during the initial entry in January 1989 revealed minor elevated readings on the organic vapor analyzer (1 to 2 units above background). No other elevated air monitoring readings were observed. Leaks in the warehouse roof have allowed for the mixing of spills in the warehouse and their subsequent release to the environment. As the rain water accumulates on the warehouse floor it eventually reaches a point where the water flows out of the east side of the warehouse (areas 2 and 4, Figure 3) and is discharged to the soil adjacent to this area of the warehouse. Investigations conducted by the Surveillance and Monitoring Branch (SMB) in 1985 and 1986 revealed that process waste water from the facility was discharged into the intermittent stream adjacent to the site. Analyses of sediments from this creek bed downstream from the discharge point showed that contamination consisted of xylene, di-n-octyl phthalate, 1,4-dichlorobenzene, 1,2-dichlorobenzene, napthalene, fluorene, phenanthrene, aliphatic and aromatic hydrocarbons, arsenic, beryllium, chromium, copper, lead, nickel, antimony, and zinc. The on-site production well had detectable levels of arsenic, beryllium, "-7- cadmium, chromium, copper, mercury, antimony, and zinc in addition to the previously mentioned chloroform contamination. There are four possible sources for the contamination listed above. 1) A 17,000 gallon underground concrete pit used to contain production wastewater and sludges. This pit was abandoned and sealed with concrete in 1985. 2) The former wastewater drainage line leading from the process water pit to the intermittent stream was constructed of welded 55 gallon drums. This pipeline was excavated and replaced when it was discovered that numerous leaks and punctures had allowed wastewater to contaminate the surrounding soil. 3) Soil contamination as a result of leakage from a broken drainage line originating at a laboratory drain. 4) Spills associated with material transfer and tank or- process line leakage. C. Previous Actions to Abate Threat "~ As part of the sales contract with VIChem, Berlex (Island Chemical Company) was required to clean up any contamination present at the site. Berlex hired Enviro-Sciences, Inc. (ESI) of Denville, NJ, to survey the site and certify it as environmentally clean. ESI's sampling survey disclosed four areas of contamination. Two areas within the tank farm were found to be contaminated, primarily with toluene. This contamination was thought to be from process or transfer spills. The other two areas, underneath the concrete loading dock and a nearby trench were contaminated primarily with pyridine. This contamination is believed to be from the leaking laboratory drain. The quantity of contaminants was estimated at 125 pounds of toluene and 120 pounds of pyridine. ESI recommended on-site treatment of the contaminated soil. The toluene contaminated soil was to be placed in a drying oven equipped with carbon filters, so that emission rates did not exceed the 200 ppm Threshold Limit Value (TLV) for toluene. The pyridine contaminated soil was to be treated by cutting the concrete pad and tilling the soil every two to three days and allowing the soil to aerate. A structure was to be built over the area to prevent soil saturation from rainfall. During 5MB's September 1986 investigation these two on-site treatment procedures were confirmed, however some discrepancies were noted from the process outlined above. The drying oven was employed for the volatilization of toluene from the soil, but the charcoal filters to absorb the volatilized material were not observed. The contaminated soil was tilled and aerated using a backhoe and then covered with a large synthetic liner. No permanent structure had been built to prevent future saturation of the soil from rainfall. The synthetic liner was not owned by Berlex but was rented. During RPB's January 1989 investigation -8- this area was covered by concrete and a new loading dock had been built. It is adjacent to the dog kennel area and trailer used for living quarters by the kennel operator. In addition, on October la, 1985, 5MB was informed by Dr. A.L. Kyles, Vice President, Enviro-Sciences, that 192 55 gallon drums of waste were removed by Berlex for disposal. This material consisted of process pit water and sludge, drums and soil from the wastewater drainage line, one 55 gallon drum of water/toluene, and toluene contaminated soil. No copies of manifests were received to confirm these shipments. At the time (1985) an additional 33 drums of waste belonging to Berlex were staged on site awaiting sample analyses and disposal. Data on the sampling performed by Berlex was never received by 5MB to confirm the clean up by Berlex. Also, the re-routing of existing laboratory discharges to a self-contai~ed unit was not observed. When Region II became aware of chloroform contamination in the pUblic wells in st. croix a health evaluation was conducted. According to the Agency for Toxic Substances and Disease Registry (ATSDR), chloroform is a B-2 carcinogen and has been shown to be a carcinogen in animals but not in humans. The Maximum contaminant Level (MCL) for chloroform is 100 parts per billion (ppb). If other halogenated organics were present along with the chloroform, the 100 ppb MCL would be for all halogenated organics present. Chloroform contamination ranged from 11 to 75 ppb and no other contaminants were detected. Since the MeL was not exceeded, a CERCLA/SARA response was not initiated. D. Current Actions to Abate Threat The threat of direct contact to the general public is currently being limited by a perimeter chain link fence and site security maintained by VIAG and SCSK. There is evidence that at times the guard dogs are allowed to roam through the yard of the facility. In a letter dated March I, 1989, to Region II's New York/ Caribbean Compliance Branch, Fred Schubert, President of VIChem, informed EPA that during his February 21-23, 1989 site visit "a small amount of non-contaminated rain water was swept out of the warehouse floor, the floors of the warehouse were swept and all sweepings were collected in an open head drum which was covered and remains on the site and a single five gallon pail of a laboratory solvent was placed in a second open head drum which was covered and remains on the site". No sampling/analyses were conducted to verify if the rain water or floor sweepings were contaminated. The type of laboratory solvent overpacked is unknown. Mr. Schubert also stated "non-chemical waste (empty boxes, waste paper, etc.) was removed from the site". Cans of paint were staged in one location outdoors. -9- IV. ENFORCEMENT Berlex Laboratories, Inc. has submitted a work plan to EPA for the performance of environmental sampling at the site. The work plan is being finalized, after which it is expected that Berlex will implement the work called for by the work plan, pursuant to an Administrative Order to be issued by EPA. On March 13, 1989, Notice Letters were sent to the following Potentially Responsible Parties (PRPs): Berlex Laboratories, Inc., Island Chemical Company, Inc., CHS Holding Corporation, Virgin Island Chemical Company, and VIAG Fuels, Inc .. None of these PRPs indicated that they were willing to conduct or finance a drum removal or otner appropriate CERCLA response. VIChem has indicated that it would not-object to or obstruct EPA's performance of the removal action described herein. EPA will also seek VIAG's andSCSK's agreement to not operate or have personnel (or dogs) on-site during working hours of the removal action or if conditions at the site (stability) warrant evacuating the site of non-essential personnel. It may be desirable to have SCSK maintain site security during interim periods when EPA has temporarily demobilized for analytical and transportation/disposal coordination. The dog kennel is a very effective deterrent for potential tres~assers or vandals. Further, EPA will seek to ensure that VIAG properly removes its numerous paint cans and two drums of water treatment chemicals at the site. Four of the tanks currently contain ethanol. VIAG does not own this ethanol; however, they intend to buy this material when their company becomes fully operational. Enforcement Programs will seek assurances from VIAG that VIAG intends to buy the ethanol from the current owner of this alcohol, Ethanol Corp. of Birmingham, Alabama, and that VIAG will take responsibility for this material by using and storing it properly. This action will generate a cost savings to the Region in that 40,000 gallons of product will not have to be disposed of or recycled by EPA. The tanks appear sound and should provide continued safe storage of the ethanol. V. PROPOSED PROJECT AND COSTS A. Objective of the· Project The overall objective of this removal action will be to reduce the threat of fire, explosion, air release and direct contact. The scope of this response will be to continue site security, stabilize reactive, leaking or weakened containers, and dispose of above ground containerized materials and resample public wells contaminated with chloroform. '. -10- For the purposes of planning, this response will be divided into three phases. The first phase of the project will involve activities at the site which reduce the most immediate potential for fire/explosion or air release and stabilize leaking and weakened containers. A security service will be provided during those times of the removal action when work is not being performed at the site. The activities and actions of the first phase are listed below. Phase 1: 1) Stabilize, detonate/treat, or recycle air-reactive, water- reactive and shock-sensitive materials, and the deteriorated cylinders. 2) Sample and overpack or transfer to-new drums all other containerized materials. 3) Ccntact potential recyclers in the Caribbean area (USVI and Puerto Rico) and coordinate recycling of usable product if possible and appropriate. Recyclers outside the Caribbean area may not be considered. This is due to the possibility of a recycler rejecting a product. If this were to occur with a united States mainland recycler, the cost of transportation from and back to the site would far exceed any potential cost savings to be realized through recycling. 4) Segregate materials by nazard class, and separate incompati- ble materials. Relocate and stage all overpacked ~ontainers in an area of the warehouse where they will not be impacted by rain water from the leaking roof. If dry warehouse space is limited, overpacked drums will be placed on pallets and covered with waterproof tarps. 5) Conduct sampling of the Fairplains and VIPA wells and analyze for chloroform contamination. EPA will not make capital improvements to the main building by repairing the leaking warehouse roof. All sound and usable tanks will be left on site. Except for the 40,000 gallons of ethyl alcohol discussed previously, the contents of other tanks will be disposed of. Anyon-site treatment or detonation (on- or off-site) will be fully coordinated with the st. Croix Local Emergency Planning Committee (LEPC) and U.S. Virgin Islands Emergency Response Commission (VIERC). If these~commissions are not established or fully functional by this time, these actions will be coordinated with the Virgin Islands Department of Planning and Natural Resources (DPNR) and appropriate emergency management agencies. -11- Phase 2: 1) continue recycling efforts. 2) Conduct verification analyses for known materials and waste characterization for unknown materials or labeled materials which may have been tampered with. 3) Conduct disposal analyses for bulked unknown samples. 4) Based on this analytical information, coordinate the transportation and off-site disposal of all remaining materials. Phase 3: 1) continue recycling efforts. ~ 2) Package and label containers lor transportation to the pre- arranged disposal facility. 3) site demobilization and discontinue site security. Use of disposal facilities in Puerto Rico will be considered. However, these facilities may not ~e in compliance with appropriate RCRA regulations. Due to the fact that transportation for off-site disposal will be by water carrier, all drums leaving the site will be overpacked or in new drums. Materials will not be bulked in tanks or sealed roll-off containers in order to avert the possibility of an adverse reaction occurring during ±ransportation. The increase in cost due to this action will ~utweigh the risks associated with a mode of transportation whi~h will take a relatively long period of time during which mixing by wave action on the ship and heat from the tropical environment persists. B. Project Estimated Costs The following synopsis of the estimated costs is based on information obtained from several sources. The ERCS cost data is based on the OSC's copy of the ERCS contract. Several OSCs and OSC Reports were consulted for on-site treatment cost estimates and typical costs for field purchases, rental equipment and other items while working in the Caribbean. This is the first drum removal conducted in the U.S. Virgin Islands by Region II. Delays from the weather (rain storms, heat stress), supply and equipment deliveries, and other logistical complications are expected. Consequently, the ERCS contingency factor has been increased to 30%. -12- O.H. Materials will be the ERCS contractor for this removal, since they are the only Region II ERCS contractor to service the Caribbean area. REMOVAL PROJECT CEILING COSTS EXTRAMURAL COSTS ERCS Cleanup Contractor $971,000 30% contingency Factor $291,300 Rounded Mitigation Contracting Tot~l $1,262,000 TAT Costs ,~; $105,000 Subtotal Extramural Costs $1,367,000 20% Contingency of Extramural Costs $273,400 Total Extramural Costs $1,640,40C INTRAMURAL COSTS Direct Costs $50,000 Indirect Costs $150,000 TOTAL PROJECT CEILING $1,840,400 ROUNDED TOTAL PROJECT CEILING $1,840,000 C. Project Schedule Approximately one month prier to the anticipated start date, the OSC and Response Manager from O. H. Materials will visit the site and review the scope of work, and develop strategies and a work plan. This will be necessary to determine which equipment and supplies will have 'to be shipped from the mainland. Mobilization of equipment will take two~weeks and mobilization of personnel will take two days. The fiTSt~phase should take approximately three weeks. Analytical, ,transportation and disposal coordination will be the ~ost time-consuming phase and may take six to eight months. After all disposal approvals have been obtained, the final phase for packaging, labeling and off- site shipment is anticipated to take three weeks. -13- All disposal activities will be conducted in accordance with CERCLA's off-site disposal policy and other applicable or relevant and appropriate regulations. VI. RECOMMENDATIONS Conditions at the VIChem site meet the criteria for a removal action under'40 CFR 300.65(b) (2) of the November 20, 1985 National Oil and Hazardous Substances contingency Plan (NCP). These criteria are: 1) Actual or potential exposure to hazardous substances or pollutants or contaminants by nearby populations, animals or food chain (Section 300.65 (b) (2) (i» ; 2) Actual or potential contamination of drinking water supplies or sensitive ecosystems (S~ction 300.65(b) (2) (ii»; 3) Hazardous substances or pollutants or contaminants in drums, barrels, tanks or other bulk storage containers, that may pose a threat of release (Section 300.65(b) (2) (iii»; 4) Weather conditions that may cause hazardous SUbstances or pollutants or contaminant: ~o migrate or be released (Section 300.65(b) (2) (v»; 5) Threat of fire or explosion (Section 300.65(b) (2) (vi»; A removal action addressing containerized surface contaminants, pollutants and hazardous SUbstances is consistent with section 104(b) (2) of CERCLA as amended by SARA, in that this response will contribute to the efficient performance of long term remedial actions planned for this site. The funds requested to initiate and complete this removal action will come from the Removal Advice of Allowance for Fiscal Years 1989 and 1990. Obligation of the necessary funds to complete this removal will occur in the first quarter of FY 1990. This action is in accordance with OSWER Directives 9360.0-18 and 9200.3-05. I, therefore, recommend your approval of this request for a removal action under CERCLA as amended by SARA for the Virgin Island Chemical Company site. The estimated project ceiling Ior this removal is $1,840,000 of which $1,262,000 is for mitigation contracting. -14- Your authority to approve these project funds is pursuant to Assistant Administrator J. Winston Porter's May 25, 1988, redelegation memorandum, Delegation Number R-14-1-A. APPROVED: W~~.2. // DISAPPROVED: ____________________ __ cc: (After approval is obtained) J. Marshall, 2DRA S. Luftig, 2ERR R. Salkie,2ERR-ADREPP B. Sprague, 2ERR-RPB M. Randol, 20EP E. Schaaf, 20RC-NYCSUP R. Gherardi, 20PM-FIN S. Anderson, PM-214F T. Fields, OS-210 A. smith, VIDPNR C. Moyik, 2ERR-PS L. Guarneiri, OS-210 J. Rosianski, 20EP P. McKechnie, 2IG ~ D. Henne, 2TAT~ .. ' (EXPRESS MAIL) DATE: 0J.t DATE: ______________ _ ATTACHMENT 1: ERCS CLEANUP CONTRACTOR COSTS PHASE 1 Mobilization (personnel and equipment) Personnel Costs (Labor, Per ~iem, Travel) Equipment (Trailers, Heavy Equipment, Monitoring Equip.) Materials Total Costs for Phase 1 PHASE 2 Analytical Services (includes transportation) ,-' Contingency for Resampling Total Costs for Phase 2 PHASE 3 Mobilization (personnel and equipment) Personnel Costs (Labor, Per Diem, Travel) Equipment (Trailers, Heavy Equipment, Monitoring Equip.) Materials Transportation and Disposal of Wastes Total Costs for Phase 3 TOTAL MITIGATION COSTS $30,000 $180,000 $32,000 $18,000 $260,000 $80,000 $30,000 $110,000 $30,000 $90,000 $15,000 $16,000 $450,000 $601,000 $971,000 ST. C~C) IX c- ~, .. ./ .... r/-'\l''-. r" ~I/j --- ' • ~ ~I I . ...1 \ ,,/ )._:::-V'»~:- ~ ... : ,. \ ...... ··;·1:. (~.:.::~:-<.~: =: '.: '. .~" ..•.... , .~ ... ~. v' f' ,\\~ , , _ -' ' J • I. _ : ._!foI1·t.:co;': ) ", )W'~\~" . I ,~-.J ~ ,:.,>':', , ') J ). .-- ' ':--r~'~ .. -" , l r. \ ". '/ .••.•• ~. " . ; " . fl': .,,"' \ ; ~ :.t< ' -I }. -j .• ••• ' .' -:- ' I" - .. ( ,~- -. ' .. ~ ~ , ___ r·· ' . - .- Q. - i' , ........ t,· ~/ :--~ '\ ~I '. SPILL PRE··/ENTION & E~.1E::1GENCY RE~?ONSE DIVISION 10 .\. ...... >c.:~u .. o..,lh ICF TC't:hnol0'C'Y loc .. C-C-Jonn. .... n.:t . .u.,\Ocx~I.,.". 10.: •• R~un:e .\ppli=uon. ... Inc... c..,o/R~urce Con. .. uluo~. In<: .. .:lnt.! En\,ronmcnuJ To"j~'ul()'O' lOlenullOruJ. In.:. ,~T (. '. \,,::; \ }- '·0- ~ :./ :-:. .... :: \~ ... .~. r-,4J - , ~~~-. ;:;;:---'-). P I - I.. -~~ ~/ ',1:"._ 'j': .~.... )~~r- ~ '~. ,("" I ....... ":" '. 'l- ' y~ -.~'~, \ j ,,-' -- "\,,, 110 - tv I~ ~ " / -V ' - - , . :-. '-;"-j , , - . .' -' " . .;. ~'\ ':".- -. , .,.' - r, . ,::'\1 \ .' '.-.r- r:" ,..." • I I ;'\\." \ 'l ---::-, I . - - " I L' \\- "~ ...... ,'. i' \' :%oC ~ tl:/ . ~\-~ 'J_ ' (:all~: ,,~ ,g,(,\\. EPA PM KODAMA TAT PM MENTZEL FIGURE 1 SITE LOCATION VI CHEM SITE ST. CROIX US VI .wEl.1. 1 • $ .. ~ 2 L G:J GD GJ CONCRETE SURFACE l.oa41"9 9...2..:! ~ .. t."ou •• c:::J OSoplle Tonll GJ iG:) G:J r CQ I G:J :t G:J a: ... • c:J G:J CZJ * C2:J ! ! Sepllc ,I t T.,," o ::t « o « U « ::l Q ... > « &. • co • o • CONCRETE SURFACE _----Slo'III O,alna ~=== I~ ••• ~vC It. tt ",ac." It c.,. ••.• , COIIIP. ~II --I = I ~ CooUng I . 0 o I Towo, o ~~<::><> 0 S.S. o 0 c::::J 0 Ro.Clo, onE> 88 Ar •• t ,t e 8 ! I SIO'" O,aln Ai, Comll ' RIO:! 1'4101 OOOOCUI. 00 aano,,, 10' 1I,,1I41ng o QI ••• R •• ctor "r •• SIO'III O,a,n T;).". F:u .. co ~ I"I.ANT ENTRANCE R.O. U"U A"40 wa,e, Slor.~. o CI2 Slorago COoling WEl.l. • SPILL PREVENTION & EMERGENCY RESPONSE DIVISION EPA PM KODAMA In As5ociation with ICFTcchnology Inc •• C.C.joilnson Jr. A.s.-.oci':IlCS. Inc.. RC'50UI"CC Appli=tiol15. Inc.. ~o/Rc:sourcc Col15ulunts. Inc •• :lnd em,'ironmenuJ Toxicololty Intcrn.:uion.:LI. Inc. TAT PM MENTZEL Cantrll"g. An4 O,yo, a,,1I4lng "';, ~ ~ t ~ Gano,1I0' And FI, a 1""11111 a"U4lng o ! S c alo 35' J I FIGURE 2 SITE DIAGRAM VICHEM SITE ST. CROIX US VI ~ --- I FIGIJHE 3 Virgin Island Chernical Corn pony Main Building Inventory Zones ,.._ .. _ .. _ .. _ .. _ .. _ .. _ .. _ .. _ .. _ .. _ .. _ .. -._ .. _ .. -.. _ .. _ .. _ .. _ .. _ .. - ._ .. _ .. -.. _ .. _ .. _-._ .. _ .. -.. _ .. _ .. -.. _ .. _ .. _ .. _ .. _ .. -.-.. -.. -.. -.. -.. -.. -.. -.. -.. ,-----------------~ // II I .. .. 1--1 29 28 2~ 26 25 Dog I<ennels Concrete I Surface Loading Dock I Q) 01 S~ Labl11 I 24 .. '. +-J 15 22 (f) I 10 L 1,8. 14 1 I 9 120 '17 13 8 21G; 12 23 I 19 16 I 7 d 6 Warehouse 5 4 3 I 2, 1 V '/ ............ / .....,.,., TABLE 1 Laboratory Reagent Inventory CHEMICAL NAME l,3-dinitrobenzene I-butanol 1-chlorobutane I-propanol 18-Crown-6 99% 2,2-oxydiethanol 2,6-dimethoxybenzoic acid99% 2,6-ditertiarybutyl p~cresol 2-hydroxybenzyl alcohol 99% 2-hydroxyethyl ether 2-methyl-l-butanol 99% 2-methylbutyl amine 3,3-dimethoxy benzidene 3-hydroxybenzoin acid 4-chlorobenzene sulfonamide 4-hydroxy 4methyl 2pentanone 4-hydroxybenzoic acid 4-methylbenzo phenone 97% 9-hydroxyflourene Acetic acid Acetone Acetonitrile Alkalinity C,D,~/G Alumin~~ Chloride Aluminum chloride ~~onium acetate Ammonium acetate Ammonium acetate purified &~~onium hydroxide Ammonium persulfate Ammonium~ersulfate Ammonium thiocyanate Amyl alcohol Arsenic trioxide Barium chloride Barium chloride Barium chloride Barium hydroxide Benzaldehyde Benzene Benzhydrol Benzoic acid Benzoin Benzoin 98% COMPANY Aldrich Chemical J.T.Baker Chemical MCB J.T.Baker Chemical Aldrich Chemical Kodak Aldrich Chemical Biesterfeld Aldrich Chemical Aldrich Chemical Aldrich Chemical American Laboratorie Kodak Aldrich Chemical Aldrich Chemical Aldrich Chemical Aldrich Chemical Aldrich Chemical Aldrich Chemical MCB Fisher Scientific Supelco Mogul Corporation Mallinckrodt Witco Chemical Fluka Aldrich Chemical Jarchem Industries Sargent Welch Scient J.T.Baker Chemical J.T.Baker Chemical Fisher Scientific Mallinckrodt Fisher Scientific Drew Chemical Mallinckrodt Fisher Scientific Fisher Scientific J.T.Baker Chemical Tenneco oil Kodak Mobay Chemical Fluka Aldrich Chemical .- QTY 100 g 500 ml 4 L 500 ml 25 g 1 kg 25 g SOD g 25 g 1 kg 10 g 15 g 100 g 100 g 100 g 500 g 50 g 50 g 2x25 g 2x5 Ib 4 L 1 box 4x2 oz 1 Ib 500 g 1 kg 2 kg 250 g 500 ml 2.5 kg 500 g 500 g 1 pt 2xl13g 1 qt 500 g 1 Ib 1 Ib 500 ml 2xlgal 100 g 1 Ib 2xl kg 4x500g STATE ----- ----- solid liquid liquid liquid solid liquid solid solid liquid liquid liquid liquid solid solid solid liquid solid solid solid liquid liquid liquid liquid solid solid solid solid solid liquid solid solid 1 iquid liquid solid liquid solid solid solid liquid liquid solid solid solid solid 07/14/89 TABLE 1 Laboratory Reagent Inventory Ch'LMICAL NAME Benzophenone Be;mzophenone Benzophenone Benzophenone 99+% Benzoyl chloride Benzyl acetate 99% Benzyl alcohol Benzyl benzoate Benzyl chloride Benzyl chloride Benzyl cinnamate 98% Benzyl ether Benzyltriethylammoniumchlori Bismut~ subnitrate Bromine Bromophenol blue Brucine sulfate Buffer solution pH 10.0C Buffer solution pH 4.00 Buffer solution pH 7.00 CAO-3 BHT Calcium sulfate.anhydrous Cello-Seal Chloride F C~lorodiphenyl ~ethane 98% Chloroform Chromotropic acid Na salt Cinnamaldehyde Citric acid anhydrous Citricacidtrisodiumdihydrate Cobalt chloride Color standard ·4 Congo red Copper metal Cupric sulfate Cupric sulfate DPD #1,2,3 Reagents Dibenzo 18-Crown-6 98% Dibenzoyl tartaric acid Dichloroethane 99% Dichlorophenyl methane 99% Dich1orotoluene 99% Diethylene glycol Diisobutyl aluminum hydride Diphenylmethane 99% COMPANY Aldrich Chemical H&S Chemical Upjohn Aldrich Chemical Mobay Chemical Aldrich Chemical Mallinckrodt Aldrich Chemical unknown .- Velsicol Aldrich Chemical Aldrich Chemical Aldrich Chemical MCB Fisher Scientific Fisher Scientific Fisher Scientific Fisher Chemical Fisher Scientific Fisher Chemical Sherwin Williams W.A.Hammond Drierite Fisher Scientific Mogul Corporation Aldrich Chemical Fisher Scientific Fisher Scientific unknown J.T.Baker Chemical Aldrich Chemical Fisher Scientific unknown Fisher Scientific Fisher Scientific Fisher Scientific Mallinckrodt Taylor Chemical Aldrich Chemical Knoll Fine Chemicals Aldrich Chemical Aldrich Chemical Aldrich Chemical Fisher Scientific Texas Acres Aldrich Chemical .- QTY === 500 g I bag 500 9 50 9 I Ib 100 9 1 pt 100 9 4 oz 500 9 100 9 1 kg 25 g 1 Ib 113 g 5 9 1 oz 500 ml 500 ml 500 ml 1 bag 4x5 Ib 25 9 3 oz 100 9 4 L 25 9 2xl kg 500 9 1 kg 2xl Ib 1 oz 25 9 500 9 500 g 500 9 3x1 oz 50 9 1 kg 1 kg 25 g 100 9 1 qt 4 cyl 500 9 STATE ===== solid solid solid solid solid liquid liquid liquid liquid liquid solid liquid solid solid liquid solid solid liquid liquid liquid solid solid liquid liquid solid liquid solid liquid solid solid solid liquid solid solid solid solid liquid solid solid liquid solid solid liquid gas liquid 07/14/89 TABLE 1 Laboratory Reagent Inventory CHEMICAL NAME Diphenylthiocarbazone Eosin Y Ether anhydrous Ethoxyguin Ethyl acetate Ethyl acetate Ethyl benzene Ethyl ether 99% Ferric ammonium sulfate Ferric chloride Ferric chloride Ferric chloride anhydrous Ferric chloride anhydrous Ferrous ammonium sulfate Formic acid Glacial acetic acid Hydrazine sulfate Hydrazine sulfate Hydrochloric acid Hydrochloric acid Hydroxylamine hydrochl~ride Hydroxylamine hydrochloride Iodine Iron chloride anhydrous Isoamyl alcohol Isobutyl alcohol Lead acetate Lead nitrate Lithium perchlorate Magnesium sulfate Medical oxygen Mercuric chloride Mercuric oxide Mesityl oxide Methanol Methenamine Methyl alcohol Methyl orange Methyl red Monochlorobenzene N-methylaniline Na salt of ME salicylate Niacin N.F. Nitric acid concentrated Nitrobenzene COMPANY Fisher Scientific Aldrich Chemical Fisher Scientific unknown Aldrich Chemical MCB Dupont Fisher Scientific Fisher Scientific unknown Fisher Chemical Pennwalt corporation Kodak Fisher Chemical unknown Fisher Chemical Fisher Scientific Fisher Scientific MCB Fisher Chemical Fisher Scientific MCB Fisher Scientific BASF Fisher Scientific J.T.Baker Chemical MCB Fisher Scientific Aldrich Chemical Fisher Scientific MSA Fisher Scientific Fisher Scientific Aldrich Chemical Fisher Scientific Fisher Scientific Mallinckrodt Fisher Scientific Fisher Scientific PPG Industries Kodak Sattra Chemical Nepera Chemical J.T.Baker Chemical Fisher Scientific ." QTY ==== 25 g 25 g 4 gt 4 oz 5 gal 5xlgal 1 gt 6x500g 500 g 100 ml 1 lb 5x500g 500 g 1 Ib 200 g 5 lb 4 oz 100 g 2x6 Ib 3xl L 1 kg 4 oz 500 g 500 g 500 ml 500 ml 1 lb 100 g 500 g 500 g 1 cyl 2xlOOg 500 g 100 g 4 L 500 g 1 gal 113 g 2xl0 g 10 oz 1 kg 1 bag 250 g 2x8 Ib 1 qt STATE ===== solid solid liquid liquid liquid liquid liquid ligiud solid ~liquid solid solid solid solid liquid liquid solid solid liquid liquid solid solid solid solid liquid liquid solid solid solid solid gas solid solid solid liquid solid liquid solid liquid liquid solid solid liquid liquid 07/14/89 TABLE 1 Laboratory Reagent Inventory CHEMICAL NAME Non aqueous buffer soln. N +- • . u,-r~zyme oil #3 Paraffin oil Para formaldehyde Para formaldehyde prills 91% Perchloric acid Phenol red Phenopthalein Phenylhydrazine ~henylhydrazinehydrochloride Phosphorous pentoxide Piperazine Potassium bromide Potassium butoxide Potassium chloride Potassium cyanate Potassium cyanide Potassium dichromate Potassium ferrocyanide Potassium hydroxide Potassium hydroxide Potassium iodide Potassium iodide Potassium periodate Potassium platinate Potassium sulfate Potassium sulfate Potassium sulfate Potassium thiocyanate Resorcinol Salicylaldehyde 99+% Salicylic acid salicylic acid Salicylic acid sodium salt Sicapent Silica gel dessicant Silver nitrate Silver nitrate Sodium Chloride Sodium acetate Sodium acetate anhydrous Sodium acetate anhydrous Sodium amide Sodium benzoate COMPANY Beckman Instruments Merck Frich oil Fisher Scientific MCB Celanese Chemical MCB Fisher Scientific Fisher Scientific Fisher Scientific Fisher Scientific Fisher Scientific MCB Fisher Scientific Callery Chemical Beckman Instruments Fisher Scientific Fisher Scientific Fisher Scientific Fisher Scientific Mallinckrodt Fisher Scientific Drew Chemical Fisher Scientific Fisher scientific Varlacold Chemical Indiana Army Ammo Plant Aldrich Chemical unknown Fisher Scientific Koppers Aldrich Chemical Aldrich Chemical Aceto Chemical Aldrich Chemical MCB Davison Chemical J.T.Baker Chemical Sargent Welch Scientific Fisher Scientific Sattra Chemical Niacet corporation CDF Chimie Noth America Farchan Research Lab Sattra Chemical QTY === 1 pt 2 oz 5 gal 1 gt J. gt 1 lb 2x8 lb 5 g 1 oz 4x4 oz 2 lb J. lb J.OO g 5x500g 50 g 2x6 oz J. lb 500 g 500 g 3 kg 2x1 lb 500 g 1 gt 2x500g J.OO g 5 g 250 g 500 g 50 g 500 g 3 bags 100 g 100 g 500 g 100 g 2.8 L 2xl gt 1 oz 30 g 500 g 3 bags 250 g 2x500g 500 g 1 bag STATE ----- ----- liquid solid liquid liquid liquid solid liquid solid solid liquid solid solid solid solid solid solid solid solid solid solid solid solid liquid solid solid solid solid solid solid solid' solid liquid solid solid solid solid solid solid solid solid solid solid solid solid solid 07/14/89 TABLE 1 Laboratory Reagent Inventory CHEMICAL NAME Sodium benzoate Sodium benzoate Sodium benzoate Sodium borohydride Sodium carbonate Sodium carbonate anhydrous Sodium chlorate Sodium dichromate Sodium formate Sodium hydride Sodium hydroxide Sodium metal soc:.ium nitrite Sodium nitro ferricyanide Sodium sulfate Sodiu..'U tart:::-ate Sodium tartrate Sodium thiosulfate Succinic anhydride Succinic anhydride Sulfamic acid Sulfanilic acid Sulfite O,P,Q Sulfuric acid Tetraphenolboron sodium 99% Thiopene Total alkylinity indicator T:::-ibutyl borate Trichloroethylene Triethyl borate 97% Triethylenediamine Uranyl acetate Weedox C/R 250 Jlerbicide Xylene Zinc chloride Zinc chloride anhydrous p-chlorobenzene sulfonamide p-naptholbenzein p-toluenesulfon±cmonohydrate pH indicator A z Miscellaneous unknowns z Miscellaneous unknowns COMPANY Dastech International Ishihara Corporation Pfizer Fisher Scientific Fisher Scientific Mallinckrodt Hooker Chemical Fisher Scientific unknown .- Thiokol/V~ntron Division Mallinckrodt RMI Fisher Scientific MCB Fisher Scientific J.T.Baker Chemical Fisher Scientific Fisher Scientific MCB Aldrich Chemical Fisher Scientiiic H&S Chemical Mogul corporation J.T.Baker Chemical Aldrich Chemical Kodak Drew Chemical Aldrich Chemical Mallinckrodt Aldrich Chemical Air Products unknown Southern Mill Creek Prod. Fisher Scientific Fisher Scientific Mine:::-al Research H&S Chemical Fisher Scientific Aldrich Chemical Mogul corporation on site lab glassware on site one oz bottles QTY 1 bag .250 g 100 lb 4x25 g 1 kg 1 lb J. box J.O kg 5 Ib J. lb 500 g 2 boxs 2x500g 4 oz 500 g 2 oz 6xl13g 2x1 lb 6x250g 2x1 kg 500 g 1 bag 3x2 oz 10 lb 25 g loa g 1 qt 750 g 1 pt 100 g 250 g 500 g 2x5gal 5x1 L 500 g 1 lb 2 bags 25 g 500 g 2 oz 280bot 238bot STATE ----- ----- solid solid solid solid solid solid solid solid solid solid solid solid solid solid solid solid solid solid solid solid solid solid liquid liquid solid liquid liquid li~id liquid liquid solid solid liquid liquid solid solid solid solid solid liquid misc. liquid Page No. 1 07/14/89 Chemical Name ==========:::;::::::= Acetone Acetylene Activated carbon All-weather patch material Amersite 2 Ashland MeOH Benzyl acetate Benzyl chloride Chlorine Chloroform Crofox Crystal Clear floor finish Degreaser Drewtrol 8500 Ethyl alcohol Filteraid Glacial acetic acid Glycol Humisorb Hydrochloric acId Hydrogen chloride Insulation (asbestos??) Insulation fiberglass Lubricating oil Lubricating oil Magnesium sulfate trihydrate Methanol Methanol Methyl isobutyl carbinol Methyl isobutyl ketone TABLE 2 Drum Inventory Company a:::======= Ashland Chemical VI Gas Calgon Corporation Revere Chemical Valley Freight Syst. Ashland Chemical Island Chemical Velsicol corporation VI Gas unknown Cerfact Laboratories Cerfact Labora~ories unknown Valley Freight syst. unknown unknown Celanese Chemical Island Chemical Cti11igan Certified Laboratory VI Gas unknown unknown Texaco Texaco Tomita Pharmaceutica Ashland Chemical unknown IVan Waters & Rogers Ashland Chemical Qty ;::== 55 G 2 cyl 30 bag 55· G ~5 G 5 . G 21x55G 28x55G 1 cyl 55 G 55 ',G 2x20 G 55 G 55 G 115x55 10x30G 13x55G 20x55G 30 G 55 G 1 cyl 13 box 7 box 2xlO G 5x55 G 6x25kg 5x55 G 3x55 G 12x55G 55 G state Cond Dates ===== , liquid gas solid solid liquid liquid liquid liquid gas liquid liquid liquid liquid liquid liquid solid liquid liquid solid liquid gas solid solid liquid liquid solid liquid liquid liquid liquid ==== ===== good good good fair fair good fair fair poor good poor good good poor poor poor good poor 1984 fair poor poor good good good good fair good fair good 1984 good .. Page No. 2 07/14/89 Chemical Name Micro media filter sheets Oxygen Oxygen Paints Paints Paints Paints Para-phenetidin Pentosin Potassium acetate Potassium sulfate Powdered filter media Propane Purafil II Quinine sulfate Rinseline injector fluid Rout Salicylic acid Salt Soda ash Sodium acetate anhydrous Sodium acetate anhydrous Sodium bicarbonate Sodium hexa-meta phosphate Sodium hydroxide Sodium ,hydroxide Spent toluene/acetone sterling salt crystals Sulfamic acid Tartaric acid Thinner TABLE 2 'f Drum Inventory Company Ertel Engineering VI Gas Santa Maria Gases unknown unknown International Paint International Paint unknown Deutsche Pentosin Jarchem Industries unknown Ionics unknown unknown Kimafarma Bob Chamber Ltd. Cerfact Laboratories Rhone-Poulenc unknown Allied Chemical unknown Jarchem IndUstries Stauffer Chemical l<'MC Mahtek Manuel del Valle Inc unknown unknown Dupont Pfizer Chemical unknown Qty =;--"'" 18 box 3 cyl 1 cyl 44x5 G 53X1 G 97x5 G 21xl G 55 G 20 L 8xl00' 50 bag 2 boxs, 4 cyl 15xl0G 20 G 55 G 20 G 27drum 2x30 G l5xlOO 50 lb 200 lb 8xl00# 200 lb 55 G l2x55G 2X55 G 50 lb 400 lb l5xlOO 6xl G State Cond Dates =:::=== solid g'as gas liquid liquid liquid liquid liquid liquid solid solid solid gas solid liquid liquid solid, solid' solid, solid solid, solid solid solid liquid liquid liquid solid solid solid liquid ==== ===== good good good fair fair fair fair fair 1983 fair good good good good good good good poor good good poor good poor poor good poor good fair poor poor poor fair Page No. 3 07/14/89 TABLE 2 Drum Inventory Chemical Name Company Qty state cond Dates === ===== ==== ====== Thinner Advance 55 G liquid fair Toluene Ashland Chemical 3x55 G liquid fair Toluene unknown 5x55 G liquid good Triethylamine Air Products 55 G liquid good 1984 waste oil unknown 2x55 G liquid good z Empty drums unknown 130 n/a fair Z Miscellaneous unknowns on site containers 25· misc. poor " 07/14/89 TABLE 3 CERCLA Hazardous Substances and statutory Codes (40 CFR Sec. 302.4) Chemical 1,3-dinitrobenzene I-butanol 3,3-dimethoxy ~enzidene Acetic acid Acetone Acetonitrile Ammonium acetate Ammonium hydroxide Ammonium thiocyanate Arsenic trioxide Asbestos Benzene Benzoic acid Benzoyl chloride Benzyl chloride Chlorine Chloroform Copper metal Cupric sulfate Ethyl acetate Ethyl benzene Ethyl ether 99% Ferric chloride Ferrous ammonium sulfate Formic acid Glacial acetic acid Hydrochloric acid Isobutyl alcohol Lead acetate Lead nitrate Mercuric chloride Mercuric oxide Methanol Methyl alcohol Methyl isobutyl ketone Nitric acid concentrated Nitrobenzene , Paraformaldehyde Potassium cyanide Potassium hydroxide Resorcinol Silver nitrate Sodium hydroxide Sodium metal Codes ===== 1 4 4 1 4 4 1 1 _1 1,4 2,3 1,2,3,4 1 1 1,4 1 1,2,4 2 1 4 1,2 4 1 1 1,4 1 1 4 1,4 1 2 2 4 4 4 1 1,2,4 1 1,4 1 1,4 1 1 1 .- " UI/J..4t/O::1 TABLE 3 CERCLA Hazardous Substances and Statutory Codes (40 CFR Sec. 302.4) Chemical Sodium nitrite sulfuric acid Toluene . Trichloroethylene Triethyla~ine Uranyl acetate Xylene Zinc chloride ...codes ..w::=::=:c:::: 1 1 ".1,2,4 .J. ,.2,4 1 1 1,4 1 1- Clean Water Act (CWA)SectiC)Il 311 (b) 4 2- Clean Wate~- Act (CWA) Section 307 (a) 3- Clean Air Act (CAA) Section 112 4- Resource Conservation Recovery Act (RCRA) Section 3001 .. ." ." Page No. 1 02/16/89 TABLE 4 Summary of Toxicological Effects of Some Identified Compounds Chemical Name l,3-dinitrobenzene l-butanol 3,3-dimethoxy benzidene Acetic acid Acetone '''Acetoni trile ~Ammonium acetate ,,%Ammonium hydroxide Ammonium thiocyanate Arsenic trioxide Asbestos Benzene Benzoic acid Benzoyl chloride Benzyl chloride Chlorine Chloroform Copper -metal CUpric sulfate Ethyl acetate Ethyl benzene Ethyl ether 99% Ferric chloride 4Pexxous ammonium sulfate Formic acid Hydrochloric acid Isobutyl alcohol Lead acetate Lead nitrate Mercuric chloride Mercuric oxide Methanol Methyl isobutyl ketone Nitric acid concentrated Nitrobenzene ' Para formaldehyde Potassium cyanide Potassium hydroxide Resorcinol Silver nitrate Sodium hydroxide Sodium metal Sodium nitrite Sulfuric acid Health Effects Codes -=-- A,B,E,I A,E A, B ,-C,'"'E, F A,I A,E" A,B,C;D,E"I A,E.- A,E A,E A, B, C,"D, E;F O,E,F A,E,P',I A,E A,E A,E A,E A,B,C,E,F A,B,C,E A,E A,E A,E,I A,E,I A,E A,E A,B,C,E A,E A,E A,E A,E A,E A,E A,E,I A,E A,E A,B,C,E,I A,E A,E A,E A,E A,E A,E A,E A,E,F A,E Page No. 2 02/16/89 Chemical Name c...:..----=====-===- Toluene Trichloroethylene Triet.hylamine Xylene Zinc chloride TABLE 4 Summary of Toxicological Effects of Some Identified Compounds Health Effects Codes - • A,B,C,E,1: A, B, C, E,F;r A,E A,B,C,E,I A,E A- Eye, skin, respiratory and mucous membrat.e irritant B- Liver damage C- Kidney damage D- Lung namage E- Toxic by inhalation, ingestion, or derm.~' contact F- Carcinogenic G- Teratogenic H- Mutagenic 1- Central nervous system effects 9 ---.. --- ~:..~ sn:)I? JI?udc 1I01:)I?.1ph qap l oQ0::lTV hUI?UWOJ TI?::llU1aQJ pU£?TsI uT 21 1A "l/J o:)°lld ". :nun tl01=I'L'.lphqap TOllo:>Tc puc '~uTP1Tnq tlTCUI 'S)jlll!:J JO l'\ a l1\ o'IC o:Jotld ':." . :.";, ..•.• . J . . ~- - - .. - : ',. ,.:.;...0....---. . ':~~ --"---p -_.-.-,.,.. " " ,'.' ,.' .:-- -._.- - "1 I J b'l EdJ£: liT TL':)<:JIU IIIn1poS "1I p.dtllo:) T e:) T 1U<l1(J plllq S I l11 i!.1 T!I . Lli o:)oqd Photo (19. Incompatable storage of Lab reagents I'huto no, lllCOIl1I);JtalJlc ilnd Lcakil1g storage of lab reagents . ' Photo iltl. lncompatable and leaking storage of lab reagents ~ --- .::: . '~ L: ; ::~~. --- .- - Plloto if t2. Incompatable storage of lab reagents " j . ~', I CI U I .:10 11 F> J 0 J;) P \I TI .r:J .', I // 0 1 0 I( d 1 -eel]!? liT SllL':> :jllJ!?,J .(JI.! o:jol[d ; I lLIIW~~~~~=:II!Y · - Photo illS. Drums in area 4; note water on the floor Photo ;/ 16. lJrum contents undergoing a reaction ~ e ;:)J l! lIT SIUII.! (! ·81 (: ('1 () lj,1 ~ calC uy sTlqap pue swnlO AIICdlllo J Tc::qUlaqJ pucl SI 111~Lq,\ . L T {! o::)0ttcl .. ~ . .... .. -,.- ~ ..... - ..... ." -..... .;. ...... ~ ') 1: 0 .1 r: 1:1 S1111.J( 1 · 7.7./: l ) :)lllj.l ill Generator IJ Tr ansporter ill TSD " 0"" Participating Personnel: Report Prepared by: Approved for the Director by: 3.10 RCM ENFORCE INTERIM RPT 9/985 : .. - ,_RCRA Enforcement: Betlex Laboratories, (a subsidiary of Island Chemical Co., Inc.) St. Croix, Virgin Islands VID80651095 September 9, 1985 U.S. Environmental Protection A2!ncy __ Louis DiGuardia, Geologist Carol Price, Environmental Scientist Darvene Adams, Environmental Scientist Berlex Laboratories, (rCC) Alec A. Smith, Vice President of Or~rations Raymond Hays Armando Morales, Process Engineer ~LCj~JLJL· . Louis DiGuardia, Geologist Source Monitoring Section Spear, Chief ce • Monitoring Branch TABLE OF CONTEN~::; SUM..~.ARY Objective ------------------------------------------ i Findings ------------------------------------------ i DISCUSSION Applicable Regulations ---------------------------- 1 Purpose of Study ---------------------------------- 1 Facility History ---------------------------------- 1 Facility Description and Operation ---------------- 2 Water usage and Treatment ------------------------- 3 Waste Streams ------------------------------------- 3 Treatment Methodology ----------------------------- 4 Waste Storage ------------~------------------------ 5 Manifested Shipments ------------------~~~~-------- 6 Sampling Procedures ------.".------------ 6 Sample Resul ts ----------------------------------.-- 7 Reference Docume~ts ------------------------------- 9 ATTACHMENTS Attachment I - Receipt for Samples Attachment II - Chain of Custody Form Attachment III - Sample Data Sheets Attachment IV - Waste Manifests PHOTOGRAPHS TABLE Table I - Results of Organics Analysis on Samples LIST OF FIGURES Figure 1 - Facility Location Map Figure 2 - Berlex (Island Chemical) Plot Plan Showing Areas of Contamination Figure 3 - Berlex (Island Chemical) plot Plan Showing Location of Dryer / Figure 4 - Sample Location Map - Drying Oven Figure 5 Sample Location Map - Lab Waste:ID:ainage Area , ,:T Berlex Laboratories (rCC) St. Croix, VI Objective VID80651095 SUMMARY This compliance evaluation and sampling inspection was conducted at the request of the Solid Waste Branch to support and verify the decontamina- tion and removal by Berlex (ICC), St. Croix, VI of soil contaminated with toluene and pyridine. Find ings 1) Sampling results indicate: .;.. o Organic analysis on samples 1087001 and 4087002 (drying oven) detected the followinf. organic compounds ranging in values from 460 ppb to 15000000 Pfb: toluene, flourene, bis(2-ethylhe~il) phthalate, benzophenone and di-n-octyl phthalate (detected only in sa~ple 1087002). o Organics analysis on samples 1087003, 1087004, 1087005, and 1087006 (lab waste drainage area) detected the following organic compounds ranging in values from 360 ppb to 75,000 ppb: toluene, bis(2-ethylhexyl) phthalate, di-n-octyl phthalate, chloroform, benzene and di-n-butyl phthalate. From the results, the toluene values were found to be within the acceptable level range of 2 ppm (reference document 12). Due to the late arrival of guidance protocol from EPA Research Laboratories, Cincinnati, no analysis of pyridine was performed. 2) Confirmation of on-site treatment of soil by Berlex (rCC) for toluene and pyridine was made. o Toluene The drying oven was employed for the volatilization of toluene from the soil, but the necessary charcoal filters to absorb the volatil- ized material were not observed. o pyr idine The contaminated soil was tilled and aerated using a backhoe and then covered over by a large synthetic liner. No permanent structure had been built to prevent future saturation of the soil from rainfall. The present liner was not owned by Berlex but rented. -ii- 3) No data on the sampling performed by Berlex was ever received by the USEPA, Environmental Services Division, Edison, NJ to confirm the clean-up. by Ber lex. 4) The re-routing of existing laboratory discharges to a self-contained unit and portable toilet facilities was not observed. 5) On October la, 1985, Dr. A. L. Kyles, Vice President, Enviro-Sciences, the consultant working with Berlex (ICC) informed me that 192, 55- gallon drums of waste was removed from Berlex for disposal. The material consisted of the following: o Process pit water and sludge. o Drums and soil from the wastewater drainage line. o 1, 55-gallon drum of water/toluene •. ' o Toluene contaminated soil. No manifest copies were received to confirm this shipment. 6) Hazardous material was stored on-site for greater than 90 days and in quantities greater than 1000 kg. Berlex is then subject to the regulations 40 CFR Parts 262 and 264. None of these regulations were observed to have been followed. 7) In r~view, a question is raised that a possible source of contam- ination is that of the dry creek bed. Process wastewater was dis- charged via a drainage line to the creek bed. Since the drainage line and soil associated with the line was found contaminated, the possibility of soil contamination in the creek is likely and should be investigated. Berlex Laboratories (ICC) St. Croix, VI Applicable Regulations 40 CFR Parts 262 and 264. Purpose of Survey VID80651095 DISCUSSION A RCRA compliance evaluation and sampling inspection (CEI) was con- ducted at Berlex Laboratories (ICC), St. Croix, VI on Septemoer 9, 1985. The survey was conducted at the request of the Solid Waste Branch to support and verify Berlex's decontamination and removal of soil contaminated with toluene and pyridine. The elements of the s9rvey included a compliance record review, site survey and sampling. Facility History .-- The Berlex Laboratories, Inc~ plant, under the name Island Chemical Company (ICC), produced quinidine from November, 1979 after purchasing the site from Cooper Laboratories, until late 1982. In October 1982, Berlex notified EPA of the forthcoming closure and removal of waste materials and excess chemicals (xylene, toluene) from the site to Island Chemical of Puerto Rico. EPA assigned Berlex the ID No. VID80651095. Prior to the removal, Berlex was operating as a small quantity generator. Berlex sold the site in September 1984, 21 months after the shut-down of operations to Virgin Island Chemical Co. The sales contract for the site called for the contractor Enviro-Sciences, Inc. (ESI), 19 Copeland Road, Denville, NJ to survey the site and certify it as environmentally clean. An ESI sampling survey initiated in September 1984 disclosed two areas of soil contamination, with the compounds of concern being toluene and pyridine. On December 21, 1984 Enviro-Sciences, Inc. delivered a progress report describing ESI's sampling and analysis of soil at the Berlex site on St. Croix and included recommendation for treatment of the pyridine (U196) and toluene (U220) contaminated areas. The recommended on-site treatment was selected by ESI as a more economi- cal method than the alternative off-site shipment of drummed soil to the U.S. mainland for placement in an approved landfill. The proposed method of clean-up includes the drying of toluene contaminated soil (which is _presently stored at the facility in drums) and degration of pyridine contaminated soil. This would occur by exposure to ambient air causing soil aeration. Soil saturation by rainfall would be prevented by covering the area with a synthetic liner. -2- The toluene contamination resulted from soil leaks/spills at a tank site and pyridine contamination from leaks from a laboratory drain line. The estimated quantity of the two materials (toluene and pyridine) are less than 245 pounds. On May 15, 1985, ESI reported the intended initiation of clean-up activ- ities on June 6. 1985. Facility Description and Operation The Berlex Laboratories, Inc. (Berlex) plant under the name Island Chemical Co. (ICC). located in St. Croix, Virgin Island started producing quinidine gluconate in November 1979 and operated for 2 years. During operations Berlex emptoyed 215 people on a 2 shift. 5 day/week. work schedule. Maximum production output was estimated at 50 tons/year, but this level was never reached. The first p~Qduction batch by Berlex was November 1, 1979 (see Site Location Map, Figure 1). ~.:..'" Berlex (ICC). St. Croix, VI ma~ufactured as their sole product quinidine gluconate. The basic raw materials used in production included quinine sulfate, toluene. and methanol. Production involved the conversion of quinine sulfate into quinine gluconate by the addition of toluene in a reaction vessel. The liquid was then distilled with methanol to produce the cystalline solid. quinidine gluconate. Within the production area, the facility housed the following reaction vessels: Reaction Vessels Number of Vessels 4 1 1 1 3 ~~terial Construction Stainless Steel Carbon Steel ..cGlass Lined Glass Lined Glass Lined (Receivers) Capacity 1200-1500 gallons 1200 gallons 3000 gallons 2000 gallons 2000 gallons Bulk raw materials arrived in tank trucks and were stored on-site in 14, 8000 gallon raw ma:erial,tanks (see photograph 11). -3- Water Usage and Treatment Groundwater was the primary source of water used in production. Approximately 20,000 gallons were used, of which, 10,000 gallons were recovered. Water was pretreated by filtering and adjusting pH (with sulfuric acid) due to the high carbonate concentration in the groundwater. The facility also housed the following systems (and tanks): Number of Tanks Capacit;( Systems 1 15,000 gallons Boiler System 1 15,000 gallons Drinking Water (rainwater) 4 50,000 gallons Recirculated Cooling Water 1 20,000 gallons Reduction/Oxidation Unit 1 250,000 gallons Firetank " Wastewater from production operations (prim~r~ly cooling water) was collected in a 17,000 gallon underground concrete,'process pit. No treatment was applied but pri~ to discharge, the pit was sampled to see if any product was released by &ccident. If nothing showed in the sampling, the water was discharged via an underground pipe to a dry creek. adjacent to f'acili ty property. Waste Streams Hazardous wastes at Ber1ex (ICC) were generated from the following sources: 1) Process Pit Water and Sludge The 17,000 gallon underground concrete pit used to contain pro- duction wastewater and accumUlate settled sludge from this waste- water. 2) Former Main Wastewater Drainage Line The underground pipe (constructed of welded 55-gallon drums) from the process pit to dry creek bed. The pipeline was excavated due to the finding of numerous leaks and punctures from which waste- , water had contaminated the soil (see Figure 2, areas of contamination) • 3) Contaminated Soil Due to Drainage Line Leakage A) Contaminated soil associated with the ~xcavation of the main wastewater drainage line. B) Contaminated soil due to drainage lineaeakage from the lab- oratory drain. -4- 4; Co~taminatec soil from raw material spillage - toluene, pyridine. The spills associated with material transfer and tank or line leakage. Includes soil under the concrete surface loading dock, along trench number 4, under concrete slab number 3, between tankS numbered 8 and 9, and along trench number 9 (see Figure 2, areas of contamination). 5) Contaminated or off-specification raw materials which could neither be reworked nor sold. Prior to the facility's shutdown, Berlex (ICC) was said to be operating as a small quantity generator. What Berlex did with waste prior to the requested hazardous waste shipment (October 27, 1982) is unknown. " Treatment Methodology As a result of sampling performed by Envir~Science, Inc. (ES!) to certify how environmentally c~aan the site was, ESI disclosed two areas of soil contamination by toluene and pyridine (see figure 12, Plot Plan Showing Areas of Contamination). In response to such a disclosure, ESI recommended on-site treatment as an alternative to the economically unfeasible transport of the waste to the U.S. mainland. Reference document II, contained the following methodology of treatment which was to be followed: o Toluene ~'" The toluene cont~~inated soil would be placed on trays in a dryer 10cated within the facility (see Figure 3, location of drying oven). Soils with low and high toluene concentration Were permitted to be mixed to insure uniform drying. The empty drums from which the excavated material was stored would be washed with a nonphosphate detergent, rinsed with tap water and then air dried. Drum washings would be collected and later evaporated in the dryer. These same drums would be used to store the air-dried soil until laboratory analysis indicates that it is free of toluene or has very low concentration. If the soil is found to be free of toluene or at very low levels (2 ppm, reference document 12), it will be redis- tributed on the site. Prior to beginning the drying operation, calculations will be~ade using the fan speed, oven temperature, and stack diameter to~nsure that emission rates for toluene do not exceed 200 ppm TLV. This concentraion in air is not flammable. If calculations show that this control rate is marginal, then a carbon pot will be added to insure this limit would not be exceeded (see photographs ,4 & 15). -5- o Pyridine The pyridine conta~inated area would be treated in a 3 step approach. 1) The pyridine contaminated area wo~ld be covered over to prevent the saturation of soil from rainfall (see photograph f6). 2) The concrete surface loading dock in the vicinity of the pyridine contaminated areas would be removed using a backhoe and hauled to a landfill or used to stabilize the bank along the dry river bed. The Department of Public Works would be contacted for permission to do the latter. 3) The pyridine contaminated soil would be tilled and aerated using a backhoe at 2-3 day intervals. Soil turning would allow exposure of the contaminated soil to ambient air. ,~ ~.~~ Samples would be taken at the beginning of the cleaning operation and continue at weekly intervals until acceptable pyridine levels are reached (2 ppm, reference document '2). When the pyridine level has decreased to zero or an acceptable level the area will be restored and resurfaced according to the owner's requirements. Waste Storage Berlex at the time of inspection was storing waste mater.ial in two areas: 1) Outside Fenced Storage Area During facility operations, this was used as a raw material storage area. It consists of a 50' x 20' concrete pad surrounded by a chain-link fence. At the time of inspection, 1, 55-gallon drum containing approximately 40 gallons of a water/toluene mixture was being stored. Other empty 55-gallon drums were also present (see photograph f2 & f3, Outside Drum Storage Area). 2) '"Warehouse Storage This area was used by Berlex as their major raw material storage area. At the time of inspection, 20, 55-gallon drums of tolUene ""contaminated soil were being stored pr ior to treatment in the drying Oven (see photographs f12, '13, & 114). Large numbers of 55-gallon drums containing raw materials used in production were also being stored in the warehouse. -6- Manifested Shipments After the shutdown of plant operations in late 1982, the raw materials which remained on-site in the facility's above-ground storage tank were removed (including toluene and xylene). The transporters and TSD used for these shipments were as follows: Transporters Trailer Marine Transport Corp. PRD980644579 Isla Grande, Puerto Rico Transporte Diaz PRD980526834 Zoni Portuaria, Pue~to Nuevo, San Juan, Puerto Rico TSD : ...... Island Chemical of P.R. Inca:, PRD090399718 Km 51, Highway '2, Manati, Puerto Rico The manifests are enclosed as Attachment IV. According to Dr. A. L. Kyles, Vice President of Enviro-Science, the consultant working with Berlex (ICC), 192, 55 - gallon drums of waste was removed from the Berlex (ICC) facility on October 10, 1985. The drum contents consisted of the following 'ate~ial: o Process pit water and sludge o Drums and soil from the wastewater drainage line o 1, 55-gallon drum of water/toluene o Toluene contaminated soil No manifest copies Were ever received on the shipments from Dr. Kyles. Sampling Procedures On September 9, 1985 samples were taken at Berlex (ICC), St. Croix, Virgin Island from the following areas: o Composite soil sample from the drying oven (left side). Sample '087001 o Composite soil sample from the drying oven (right side). Sample '087002 o Surface soil composite from the north side of the Lab Waste Drainage Area. Sample 1087003 -7- o S~~s~rface soil composite from the north side of the Lab Waste Drai:1age Area. Sa:i,;le 1087004 o Surface soil composite from the south side of the Lab Waste Drainage Area. Sa:nple ,087005 o Subsurface soil composite from the south side of the Lab Waste Drainage Area. Sa:nple '087006 Attachment III contains copies of the sample data sheets. Within the drying oven, the soil was placed on steel trays and stacked in 13, 20 tray bins. A-division of the dryer into the left side and right side was made and a composite sample was taken from a represen- tative number of trays. See Figure 4, for s.Cll!Iple locations. Photographs '4 and .5, show the location of the drying oven. < .. \ To take a more representati~e sampl~ of the Lab Waste Drainage Area, the area was divided into two sections: north and south. Surface soil samples were taken using trowels and subsurface soil samples (approx. 3 foot depth) were taken using dedicated bucket augers. Due to the very resistant nature of the soil (impermeable clay) only a sample depth of three feet could be obtained. See Figure 5, for sample locations. Photographs ,7, t8, '9, '10, and tll, shows the areas of sampling. Sampling equipment and containers were prepared according to EPA stan- dard procedures prior to sampling •. A total of six samples were taken. The samples were analyzed for purge able (POA) and non-volatile (NVOA) organic priority pollutants. All analyses were performed in EPA's Edison, New Jersey laboratory. EPA standard procedures were followed for the collection of samples throughout the survey. Samples were not split with facility representatives. Receipt for samples (Attachment I) and chain-of- custody methods forms (Attachment II) were employed for all samples taken. Sample Results Sample results are given in Table I. Organic analysis on samples t087001 and .087002 (drying oven) detected the following organic . compounds ranging in values from 460 ppb to 15,000,000 ppb: toluene, flourene, bis(2-ethy1 hexyl) phthal, benzphenone and di-n-octyl phthalate (detected only in ~amp1e 1087002). -8- Organic analysis on samples '087003, '087004, '087005 and '087006 (lab waste drainage area) detected the following organic compounds ranging in values from 360 ppb to 75,000 ppb: toluene, bis(2-ethylhexyl) phthalate, di-n-octyl phthalate, chloroform, benzene and di-n-butyl"phthalate. From the results the toluene values were found within the acceptable range of 2 ppm. No laboratory analysis was performed for pyridine due to late arrival of guidance on pyridine protocol from EPA Research Laboratories, Cincinnati. " .-- .... ;..~ Reference Documents 1) Enviro-5cience Inc., Progress Report, Island Chemical Company. Inc. (Ber1ex), April 4, 1985. 2) u.s. Environmental Protection Agency, Review of a Report on Pro- posed Soil Decontamination by Enviro-Sciences, Inc. 3) U.S. Environmental Protection Agency, Fact Sheet, Requests to Treat Contaminated Soil at St. Croix Plant Site, February 5, 1985. 4) U.S. Environmental Protection Agency, ICC!Berlex Plant Site, St. Croix Fact Sheet Including Preliminary Analytical Results on Nearby Well Fields. / .. . -'" ,.--' Berlex Labs, Inc. St. Croix, VI VID80651095 Table I Resul:s of Organics Analysis on Samples Sa::xple!l Sample!; Sample# Samplell Organic Compounds 087001 087002 087003 087004 ug/kg ug/kg ug/kg ug/kg Toluene 460 560 420 440 Flourene 9200 1300 I Bis(2-ethylhexyl)Phtha- 13000 4700 16000 1900 -late , , Benzophenone 15000000 2600000 Di-n-octyl Phthalate 500J . -- 4200 , .- Chloroform 200K Benzene J ....... 200K Di-n-butyl Phthalat_~~ -' Sample 1087001 - ~rated Soil Composite f!~m Storage Room (left side) Sample #087002 - Aerated Soil Composite from Storage Room (right side) Sampleli 087005 ug/kg 360 51000 600J - Samplerl 087006 ug/kg 400 36000 2000 75000 Sample 1087003 - Surface Soil Composite from North Side of Lab WaateJDrainage Area Sample #087004 - Subsurface Soil Composite from North Side of Lab Waste Drainage Area Sample 1087005 - Surface Soil Composite from South Side of Lab Waste Drainage Area Sample 1087006 - Subsurface Soil Composite from South Side of Lab Waste Drainage Area K - Actual value known to be less than value given J - Estimated value Blank Space - Material Analyzed but not detected I FIGURE 1 " FREDERtKSTED FACILITY lOCATION SOURCE: COMPREHENSIVE WATER RESOURCES MANAGEMENT PLAN FOR THE UNITED STAT~S VIRGIN ISLANDS. 1883. I t·, FACILITY LOCATION MAP o 5,000 10,000 n.n I I I A ® ~ -... CONCl1ETE PADDING 6 ~ 7 e 6 .. nl 2 UI 1 J 7c::E:) C!D OD CJD r.:ro ij1 CD c::::l1 CD CD o::J CD CO C!J • 113 TANK FAAM 5 -- FENCED STORAGE FlGURE. ~ .a&l .. nw'~ M""I& ... ~. "" c"...., • a; c • c..Dn~'." YO"~I. D 11 W ® Cfton 'a" o ,,..,.,.,.c.a. T •• c, ~. ,~.ut"rO&~ )1. ___ ~!!_. ah{ e~ / ::J I 3:1 ~ 0 ~GliliI~tl'~LI ~:8 er ~ D •• ~ Nn" • ~ •• -_. .~oc., -. - . . -~~ . AtOI .... ~:rO-o. 0" .. ", !.JOQ..; crw, •• ~taI , .... ~. • &a.C't'ft1. /J. &U& 1/ 12 • G. ... '" ••• ~ .-T &a "'/11 c:::x!) " U ~ "a ~,..., ,.,." ~ o "EJ • > . ca .. f t.A ~"' .. l ,.&C. ~w •• ."04, TRENCHES '-12 ._, 1 I .------.,.,// 1 \::. ... -1 o 50" loe RadeA! SCALE .... 4 .. ., C"'~C~"c.' _ISLAND CHEMICAL PLOT PLAN t :ONC~ETE PA:):)ING I .I l( 1 ~L-.- 1 CEJ C!D ~ I CJD OD on CD c:a2 CD c:::::::J 1 CD CD CD CD CD CD • 113 TANK FARM !> ~ - ·'_ ._4 ...... _ . _ • • ~ ... . "'~ . .. ..... , '.' ,. t"I.V I t"'I.AN :;)HUVVING LOCATION OF DRYER D .. fH:,U~E. 3 FENCED STORAGE LOADING DOCK ",,&& , .. ,' .,&1 """"I. "'arn .... co YO.'" ® 11 4"on t. .. L o ,.,..,.,..c.a. ., .... , ... .,..! '" : D r---i ""~ (] J~1· II. IUC'TO&..x- '---oJ 2 .1 .. 16 ~~ D 1Ill{-------- o n ~. i":~tDn e ~ ...,."", .. , .K , .. &.~&. ~ __ ~ "~I' ,aw:.r./ ... OKflL .~ . . crw'.A'~ '-a A.ot .... ~ro-ao"~. ! . .D Q..; •• a, ..... ewt .. ~ :::l .",~ t/ 12 ·.:4""" .... ~ .... TU ~ c::M!> . c.t .. ruyn .. l "&~ ....... • .. oc.. U I""'- 'ta'~" ..,.U~ o TRENCMES ,·12 \ -------'~7r\. 0q • • .~ o 50' 100' b3aHHsj SCALE 9\.& .I'-&::CT C& .. " JSLANO CHEMICAL PLOT PLAN Berl~x Laboratories St. Croix, VI DRYING OVEN - tolu~'1e contaminated soil Right Side [~ o ( Top View ) - .~D :~-O -."- ~ '0 o (North Side) CJ DO rloor ...:; NORI'H Carp::>si te soil~sarrple:fran :drying oven o #087001 - ~eft ,side (south side) o #087002 - .:right side'inorth side) VID 80651095 door Left Side (South Side) ( Not to Scale) .c* ...Each.xectanglerepresents one bin containing a -stack of 'tYlenty + trays. Figure 4 - Sample Location Map -IDl:ying Oven -.::: NORI'H Berlex Laboratories St. Croix, VI ® .. ® ~ ® VID 80651095 lAB WASTE DRAmAGE AREA - pyridine contaminated soil Building --.,.- , , ® ® ® ® (fonrer lo.a.ing dock area) ® - SaIrple locations for ccrrposite Soil sarrple fran· north side of the ~ wast.eJ)rainage Area o Surface - #087003 o~surface - #087004 Soil sarrple fran south side of the Lab <,waste~ge Area o SUrface - #087005 0 Subsurface - .087006 ( Not to Scale ) Figure 5 - S~le IDeation Map - Lab Waste:Drainage!!"Area .. .- ..1..; ATTACHMENT I Receipt For Samples Berlex Laboratories St. Croix. VI September 9, 1985 :~""'!!"" - . .jj. ~ ..... -i ~ ~ ~; . ;: t .- -t· ~ ~ - k1:CBIT ~ ~~ :FiolA ..... nJ: t"llC;Ylj[) Y RH:-&RD 'tNVlION.ENTAL PIOllCTION .. OENeT - .IOION " Environmental Serviees Division EDISON, NEW JIIS£T 01117 ...... f U,,; .... " .... r· .. L bo \ . C d -OJ Ber'~"" - :-~:-.~ V .'"T. e.r-t\. ~ ' •• ~I. N., ••• , Q'n~\ ~?7~ ~~"7,:r3 p~7JA ~7~ VID ~OG:slO"S: .. ".It.r • f ." •• i ... rt \ ~ ~ ;L., 2 , o. .. ,;,.i ••• f ' •• pl •• Q{. - f'-.W~~ 7Ae.rJr~~, \ - Co~,k ~ ~\ -V.~~ .s' Q-\ - NIJOP-, j' P1~ ~'. \ - ~~,k ~ 1'ot" I \J .:.l.s ,"- r Ctt- ~~~ 1 ~~-~ ~'t 1 - Cc~,~ ~ ~\ \J~ .) G..~. -t---~0P, 75 I,.-l:::-, c""" - \ _11.. ~"o;h ~ ~\ \[.:..\s ~ t)~.:l ~<..<e ~, I ~' CA, - ~uoPl-Z r-. ~- \ - ('. ~k ~ r-.1.. \I~\!; ::>s:rT • ...:::.. ~g, ~ " ea, 10; (85 ~~b .).. \ ~ \ .)... CB.. -\~ ~ P; -; Suk~.r.:t' ~ ~ I) - c.t)~t', ~ 'TO ~ I,(.~S ~ 1------'--- rr=-' P_ A ..... i ... I ....... i .. il;., f., S •• ple: , .... ,. N ...... . , •• ~I. ....... S •• ~I. N ....... 1 .... 1. ........ , •• li .. "'vI...... I." l.'i .. ",,,i ..... I" a.li .. ",,,i ..... I" •• Ii .. ~vi.h •• I yo: - .... i ..... I." na. D_ l.eei ..... I" 'i •• Oet. •• e.i ..... I,: Ti.. Det. l.c ..... 4 'y: TI •• 0 ... TI •• .. ..... fer a. ....... c .. IOt ... , ._ fer C ......... e" ••• ", • ..... , .. C ......... c ....... , • ••••• fer Ch." .... c ....... , P ••• N .. 0 ••• \ <.;.. -~- ATTACHMENT II Chain of Custody Form Ber1ex ~aboratories st. Croix. VI September 9, 1985 ........ A, ..... , ,. ., ..... , •• , ...... . ~J ZJi. A .. ...., ,. ., ..... , .. , ....... Tl .l- ~.)~ ~¢ rt>~~'~ A,..,.., ,. ...... , .., ....... . ... .. ~ /'" ~'(\ \~ ~ ~\lr<"'l ~~J\~ ~ 'i-""O ~J~ ' t'~'" t'l~ ~'/t"'t ~' ,.., "'¥')\} ~ ~/~ .-;_~'Jf'\") -~' .. ~\/M ~\Im ~'Ii1 .,'" ("'I ~I"O .usnr MJN 'NOSlal U01S1A~ sa~lA~as leluamuo~1Aul " NOlon - ":lNJOY NOU:lJ1014 'Y1NJWNO ..... NJ ~t'J('\ ~'~ t")~l" 1'-'J ~ ~~f)~ ->OJ: '1-"'6 ~'/\ \~ ~ 'd~t'l ~ '*1) ~\~!" ,~ C3~ 'ij~ ~~.~~ ~~' {\ )"-' O~ ~~ -=-~ ''''6 I.'~ •. ~ , .... ! ... ~ ~ \ --e \ "C , ~ , ~ , 'C , \~L-%O .I e er-"'N ,. .. ·1·· .. -I···S \ .... , .. p-- ATTACHMENT III Sample Data Sheets Berlex Laborato ~es St. Croix. VI September 9, 1985 .... ~FIEtD DATA~SHEET ENVIRONMENTAL PROTECTION AGENCY· Region II, E"",:c., .. ,,:,' Jersey ENVIRONMENTAL SERVICES DIVISION l.-' ~ l== PrOject Name 6<"': r '''' '" Ie - ? oJ .. T •• • ," ... Collector(s) D, C·· uS'" cl: 5 SAMPLING METHOD (Circle) Kemmerer Dredge Ponar Niskin Net Seine Trawl ~~ Cream Oipper ~atic Manual Bucket Affiliation U.> ~ y, LDMS CODE _______ _ OAT A BASE CODE __________ _ STA. TYPE CQO,c:.E ______ _ ~her ................................................................. ___ ! suaSTRATE TYPE (CirCle) Aqueous Sediment .sludge 011 -tllological Solvent Extract 9 s.;;), \ Plastic Jar Drum-'-' Metal _ ("!OA Vial ~~ I .. _.- . nHn i Test Well Depth: Process Stream Holding Pond -Cubitainer Acetate Core Paper Cap C::e!lon §b. Foil Cap Other ______ ___ Acid _____ _ SOlyent ..... ___ _ Chemical _____ _ ~ Dry Ice Ambient Other ____ _ Sample Location Description: ~her: ~I ___ ~_' ____ ~ ____ ~ Etfluent-Hon CI 1_......... ,SlUdge Truck Ambient Lake Stream Pond lWeliS I=a~ Monitoring Production Drinking Private c. c ...... ~+tc.~ :;,u;) ~-po~; k {:rc...~ ~ ivy ~ <... ¥ VV ~ l I c.J -l .s Ide) Remarks: -.l ""' , . t . -, J::,I) l l' c-1 . ~ '- \ - .VVGH ;)- ""'iv tr0 P \",.!-) Lct""'\~c;;;.~,,,"i kJ ~'l\ 4.-..... I .... r '"' < ~f" \\ . r " '"' '"'""' Form: FT'8 RPO-" .c·2 Samples to: I a.::j Sl~. I c:r I Other I smttOA'IIo. ~l?Pk'kl(, ~ I' lul7 b-j I Sample Depth (Ft.)/Fac. Loc. Code [3 b 10101 i.abNumber 087001 Type of Sample Grab Comooslte Collection -(Ending) Oate 111 r5101' loi~ I Ending Time (24 Hr) J J I J I DIO J Beginning bate J 1jr sl cli°,,/ oj, I Beginning nme (24 Hr) II b biGI pH I I I I I Sample Temp. (-C) I I I I I 00 (mgfl) I I I I I Cond. (uMHOSlCM) I I I I I I , Sa lin ltyW.'> I -1 I I I Sample Split o Yes ~NO If Yes With Whom? Receipt DYes o No FIELD DATASHEET U£F ENVIRONMENTAL PR;)TECTION AGENCY - Region II. ::=-..=,',cr., Nt,,,, J'3r5~:' .. ENVIRONMENTAL SERVICES DIVISION PrOject Name 0'"' ;}. k-2 R~l', 'C"" I , ,,!. -~ , •••• ',' / y .. Collector(s) \", / .. 'fl ~ ,l ,~ SAMPLING METHOD (Circle) Kemmerer Dredge Ponar Niskin Net Seine Trawl ~dI Cream Dipper ~atic Manual Bucket ~her ________________________ __ Affiliation f.. F'fo .. f :: P u:>MS CODe _______ _ OATABASECODE _______ __ ST A. TYPE CODE " ______ __ SUBSTRATE TYPE (Circle) AQUeous Sediment "Sludge 011 8io1ogical Acid _____ _ SOivent ____ _ Chemical ___ _ tWetl~ Oryrce Ambient Other ____ _ Solvent Acetone ~~ ~;;;Iene Chlori~ Other (Specify): - Sample location Oescriptlon: Extr3d e ~:) Effluent : .. - Drum Process Stream Test Well Holding Pond Depth: Drum I Other: Waste Pile , Storage Tank tnfluent Top Effluent-Ci MIddle Effluent-Non CI Sludge Ambient Lake Stream Pond Ocean Estuary Monitoring Production Drinking Private At:, t", ~ C J, :$0: f (~po.:>' +to . ~ trn"\ r I ~ t1.t "!: ~I ( c! ... _ .. t_-rr~\t: rt""c,"" ?h.J~ ("6t"\t~,.,Ci::) t::n\-f(OOf .J Remarks: t-..J\} (; ~ - { ,-'....0 de. (l" , f ('" I • -- J - -. \,c, V <. ~~' ~:j .... _ ,C\-l...,J \- C·~, :. ( (:;.... \ Go om', n CA + , J !5a 0 I \ -h C'"'rP\ -i 0 \ v 'e"'Y\ c:: Sf ·ll Form: FTB RI'O-11-&2.2 Samples to: I ~ct~ ~o StatkHl Mo. Chem ....- Other f{tks-l~§ k k II k bEl I Sample Depth (Ft.)/Fac. Loc. Code ~k k?l/l Lab Number I 087002 Type of Sample Grab CompOSite InmeJ~' _ Collection (Ending) Date 1 ~ISi6 iq 1019 I &ldlng Time (24 Hr) I J 1/1/ 131 Beginning Oate I?,s-loj~ lojq ) Beginning Time (24 Hr) JI/llolo/ H 1 i I' I I I I Sample Temp. ~ I I I I I 00 (mgfl) I I I I I Cond. (uMHOSlCM) I I I I I I I Salinity(%.) I '/ 1 I I Sample Split DYes .,. No If Yes With Whom? Receipt DYes o No FJELD DATA SHEET ENVIRONMENTAL PROTECTION AGENCY· Region II, Edison,New Jersey ENVIRONMENTAL SERVICES DIVISION LJEF Project Name & " h~',( L '! ':¢ I :t !"")( • ;n. ( r y) J( ,V'l Samples to: " I vr( I ~her I Collector(s) f") I (~ ... c , • J :'1 Affiliation (.,~£"?~ I Bact -J Bio -.~.------ SAMPLING METHO~ (Circle) LOMS CODE Station 110. Kemmerer Dredge Ponar Manual ~lv]i1~JI0k lsi, k;19kl Niskin Net Seine Trawl Bucket DATA BASE CODE I (Trow:!) Cream Dipper ST A. TYPE CODe Automatic Sampte Dapttl <Ft.)/Fac. Loc. Code Other 1.31~lcl~' ~ .. , - SUBSTRATE TYPE (Circle) Aqueous Sediment Sludge 011 Biological J...ab Number Solvent "Extract eh3< ~~,\ , I tl87003 I se:: -- ::;gad Supplied DYes o No Source: Type of Sample Sample Preparation (Circle) , Sample Source Type (CIrcle) Grab Composite Cont Ilin.e.t. Cleani~ Procedure Landfill Industrial It " J TIme I sV" I - ~ass Jar :.!) • Detergent Wasli' \ LNchate Effluent ... ( Water Rinstl Process sttNm - Pla~r • Drum Collection (EndIng) Dete Metal Acid Rinse Test ~ell Holding Pond 115 IS I~~ loi41 . ~v~~ Solvent Rinse' Depth: Drum Other: Waste Pile Itamer .Acetone Acetate Core Hexane Municipal Treatment Ending Time (2" Hr) : \: ~e~n! Cfi!or~ II jc7lolol Paper Cap Storage Tank Influent C:0~ Other (Specify): Top Effluent-CI Middle Effluent·Non CI Beginning Date Other Bottom Sludge j 'SIr SIQj°C) IOI~ I Truck Ambient Preservation Drum Lake Acid Tank Stream Beginning TIme (2" Hr) Solvent Other Pond [il, 1'1101 Chemical Ocean Cjvet 10 Wells Estuary .,.- - -,£~- pH Dry Ice Monitoring I i I I I Ambient Production Other Drinking Private Sample Temp. c-G) [ I I I I Sample Location Description: .5lAf [~( C ~C),' C.~~fO~'-k. {'r,,"~ nO.,,,* h OO(mOn) :> ,C\ <:. J~Q'Jc:.. I I I I I <.Jf JabuY'" q J-u., I 4-,)q l~ c.,-('G Cond. (uMHOSlCM) I I I I I I I Sallnlty(%.) Remarks: I I I I I ~ 1 I - j~ NVD.4 J C\." I( C J ~" :;ample Split d - '"i u -srvJ Pv~ VI~ ,~ 1J Yes ~NO If Yes With Whom? C\:;,'Y ~'"' "I' .) ~~c. ..... hq..J ~t ~eceipt DYes o No Form: FTB RP[).11-C!.2 FJELD DATA SHEET U£I- ENVIRONMENTAL PROTECTION AGENCY· Region II, Edison, New Jersey ENVIRONMENTAL SERVICES DIVISION i' PrOject Name"9c ( \ ... ~ La t~( (ft-or • ~ ~ Co.. ~ \,.., ",,4 ~. ((.) ) Samples to: Coli ector(s) L.... (~ --,.'"1 r cJ a.. Affiliation E::- 0;.. - £ '£.1:>1 r -=8&=-. -c-t.-jr--::B-iO-rl-=c~~-e-"!"'I-O-t-he-r--', SAMPLING METHOD (Circle) LDMS CODE Station No. Kemmerer Dredge Ponar Manual r--r--:lr-"T-"-T--r-r-"T-"-,----"--' ~ Net Seine Trawl Bucket DATA BASE CODE ~ P>~ 10 k ~ I' r..)l-; t-I I ~ Cream Dipper STA. TYPE CODE ______ _ Automatic Sample Depth (Ft.)/Fac. Loc. Code Other g; k ID I~ I SU8STRATE TYPE (Circle) Aqueous Sediment Sludge Oil Biological Lab Number Solvent Extract S( 'S.~. 1 ) "'-'--0-8-7-0-0-4--'" 800 - Seed Supplied 0 Yes 0 No Source: Type of Sample Sample Preparation {Circle' . . Sample Source Type (Circle) -Grab Composite :: C"..nn.t.ainer CI~ning Procedure Landfill Industrial I t Time I s~e I ...: (@lass..o}Ji\ ~tergent was1i) leachate Effluent ,-~ . _.. pi;Stic Jar "Water Rins~ Drum >' Process Stream Collection (ending) Date • ~ Acid Rinse Test Well Holding Pond L Vr I Mo CDaY J ~ Solvent Rinse: Depth: Drum ~ V . D ft IQ li_ Cubitainer Acetone Other: Waste Pile Acetate Core I;::!.!i!.xane _ Municipal Treatment Ending Time (2" Hr) ~ Giliy'ene ChlonAA> Storage Tank Influent II IJ 1: L I ~ Other (Specify): Top Effluent-CI . . e ~ . Foil Cap Middle Effluent·Non CI Beginning Date Other Bottom Sludge L Y!.. ~ Mo bOaY I Truck Ambient ~ p e f1 _ f1 . Preservation Drum Lake Acid Tank Stream Beginning Time (2" Hr) ~::~~I Other ~:n /1 /1 R p I ~ Wells Estuary ~P=H~=====~=--------- Dry I~e Monitor~ng I I 1 I I Ambient ProductIon . . _ _ . Other Drinking Private Sample Temp. rc) Sample Location Description: ! I I I I ~ J b "- '-' ( -!:' (t'" .so · \ sa..." h ..{., C"r7I /cJ" Cl r c , nQ r r-OO--'r-(m"';:'C-i fl)..-......-..., D' '-A.- . I I I I I Cond. (uMHOSlCM) -- I I I I I I ) Sallnlty(%.) \oJ \.1 :e:ark: \ G \. c: It\ ~~)~r I I I I I __ I. •. ', . - Sample Split " '-(- /. - - I, ~" V \ ~ . / o+-'-~ .., ...- i 0 Yes )0 No .:.. l c. . ~ ( '-\ - ~, i If Yes With Whom? .' Receipt 0 Ves 0 No Form: FTB Apt). 11-82·2 • FIELD DATA SHEET ENVIRONMENTAL PROTECTION AGENCY - Region II, Edison. New Jersey ENVIRONMENTAL SERVICES DIVISION PrOject Name k'" r • c- J!. --Q) .. '.... ..c-"" ....... ]I" v Collector(s) D, C~ I",.t <. r d 9 SAMPLING METHOD (Circle) Kemmerer Dredge Ponar Niskin Net Seine Trawl ~!0 Cream Dipper Automatic Manual Bucket CXher __________________________ ___ Affiliation V) E pA LDMS CODE _______ _ DATA BASE CODE _______ __ STA. TYPE CODE _______ _ SUBSTRATE TYPE (Circle) Aqueous Sediment Biological Solvent Extract Drum Metal CPOA Vial -;» Cobitainer Acetate Core I ----- -m___ I Test Well Depth: Effluent .-- Process Stream Holding Pond Drum CXher __________ _ Acid _______ _ Ambient Other ________ _ Acetone Hexane @hylene Chl~ Other (Specify): $ample Location Description: CXher: 1 ______ . --- t-::U-:-,-,n-,,.-_I-n"-I~T~'.-A-t""-.n-t---i Top Middle Effluent-Non CI 1 _____ ... I Sludge . Truck . Ambient Lake Stream r='=~I:::n .. Wells Estuary Monitoring Production Drinking Private ,:)" .. " r G{ e.. ~.) (~fC~) k .f-.". ~~ SIde. c' 'q~v ~ q fu .... / .....0Q.>k d ~~I":,)<!.. Q f"""t: G . Remarks: J- '11- NV6!4 v.c, I", 1- J ( cd ;> "~N p(;A c (~'iC 'l ~l J Form: FTB Rpt).'HI2·2 ~ Samples to: I Sac!] Sio Ilfl CXher Station No. ~trlq~loklsl, IQ191~1 I Sample Depth (Ft.)/Fac. Loc. Code 13~ 10141 Lab Number 087005 l Collection (Ending) Date I~ Y6loi~ IOlj I Ending Time (2" Hr) Ill, Is I~I Beginning Date 11~r5 bi; loi;] Beginning Time (2" Hr) /tll/Lj/D/ pH I I I I I Sample Temp. ('C) I I I I I DO (mgll) I I I I I Cond. (uMHOSlCM) I I I I I I I Salinity("/ • .> I I I I I Sample Split aVes "'No If Yes With Whom? Receipt DYes o No FJELD DATA'!SftEET UE..F ENVIRON"'ENT AL PROTECTION AGENCY. Region II. Edison, New Jersey ... ENVIRONMENTAL SERVICES DIVISION PrOject Name 1",)11';' "<. ~ 6.'""- -..... ns-. s- - ',"'", ... .T:(!!J (HI S, -- Collector(s)"1. ' [_. -'(, r .d ..... SAMPLING METHOD (Circle) Kemmerer Dredge Ponar Net Seine Trawl Dipper Manual Bucket Affiliation t:. ('I - E:.: L LOMS CODe _______ _ DATA BASE CODE _____ _ STA. TYPE CODE ______ _ SUBSTRATE TYPE (Circle) AQUeous Sediment Sludge 011 8i060g ica I ACid _____ _ SOlvent ____ _ Chemical ___ _ ~ Ambient Other ____ _ Solyent Extract e S~. , Drum -', I .. _.- ..... _- I Test Well Process Stream Hofdlng Pond Drum Acetone Hexane EiiY ... le .. it-e-C .... ~~lo ... r-ld'=""'® Other (Specify): Depth: Other: tyv~a_8~I~e_r~lI~e __________ ~ UI."i,.., .... JliI T .... tnw.nf Effluent-Non CI 1-- ___ n 1 Sludge Truck Ambient Lake Stream I· 1 Pond wells=~ Monitoring Production Drinking Private Sample Location Description: <; _' \:."': . I' :' r ~~ If (.... ~ ) c.:..h tf, D. 'r"\Ct~l a"C 0- Remarks: tJ ... i - !-. ~~ c, \ ,., !:.'- '(:..,r h ~ \ c I c.. ~ '_ V '-: i, -- /' - :...,.c· L .. " .( Form: FTS Rpt).11-&2·2 Samples to: I BactA ao I 'j?j Other lbtlonWo. I'A ·liislol dsl t b h k-I I Sample Depth (Ft.)/Fac. loco Code 13~ k?I~1 Lab Number D87006 Type of Sample Grab Composite In~ISpa~ Collection (Ending) Date 1~j'SJ 9°~loi~f Ending Time C24 Hr) I/I~ 13101 Beginning Date 18751oi~ /Dj91 Beginning Time C24 Hr) II P;lol~ r H I I t I Sample Temp. ("C) I I I I I 00 (mgll) I I I I I Cond. (uMHOSlCM) I I I I I I I Salinlty('/a.) I I 1 I I Sample Split DYes o No If Yes With Whom? Receipt DYes o No • " ~-- , ... i_' ATTACHMENT IV Waste Manifests Berlex Laboratories St. Croix. VI September 9, 1985 I· ri u .. w . . i I IIIIII/I'! ~'I 11'.'11 ---......;~--....;.;.;.....I..- .- -------- .. - -- ----------t--------~..;...:.~------' :tt;J Y.II -. : I : I • .LtlYd . , . -- - - - --- .. -. -- ......... . -- . . --. ~ - . . - - - _. -- - ---. -- ---- - ------. ----- ---- _ .. -------_ .... - . '. ,.' , .... ... .. 1".1 IV II\' II • • 1 --~--~.~Vll . ,~-.--r--- m rn IT; f""l'(TZTlf"SiZT61 SJJS 1~: ..... _ ....... .,.. ... _......,.,~~ .. Ja../.,~ ... ~I ··- : · ; 11\ II111104SlIWl .... je-.. *"--II ...... tL """":JI! I 0II'J1..oJ'>!'r:41 ~fAl ,t;' ;-l- - 1uaP~S.~d i I ~"'Pnl .'H ili/ae, . ____ ~u~~~w~~~~n~ll~'~~IJ_l~ _____ tl~I.~~mr; J~I~~ ___ ~ __ ~ __________ ~~ __ ~~!----------·~.~--~ ..... ~1~~~"~~~~~1~~~~r.~' , . ' 11 • . 1 .. ""'- ... ,.,~ .. " .. ,,...~ .,... ...... ,...,.."" ......... ~''')I ............... ;-1" •• _,.. ·_._ .... ~ __ IIU ........ ,..., -'-1 .. -0. _·t _", ... 1-.. -·I ... ' .. ' ......... ).--~...., ...... "'llId' ...... ~ .. ,..'4Jl .......... ·11. __ ...... - ...... ~ ...... ''''''"'._ ... _ ...... __ ' .. · .. ·, .... _r ... ~_' •• _~ .. r.' ... '_~ .......... ,._ ........ _"'11 .... -..uIe •• IIII1I1OUQIUIDtllOl",;a1') I I , I j J J I eO JJ ---:.-= ---=---- - ~- .-;,,- .;.. -_ .. _ .. _.. C"l' rf.- J.'~VIJI'ONMENTAl QUALITY BOA I . Akr~ ~LASl ~fYJ":.,,{ ~y-, ~A.ZA D U.S/l.~STE M~S v.v I ~~ ... "T • .: . ,.-.,/ ~'-"~ ~ DOCUUE P II Ie 07 -:-;u.-uiiii~ '-¢ ". , ,,"0111 ". II Ita Iel&r\d O'Iernical Xo. Inc. (809) 778-2200 I Im~U ; j ' v,I,D,9,S(O,6,5,'O _ t (state 130 , (state Bethlehem, St. Croix, U.S.Virgin Islands ' ~CI · . . t. Trailer Narine TranSport Corporation rn &001II$1 Isla Crande, Puerto Rico lAlWOIIn. 10 1 Transporte Diaz $ITt .t.OOII U . 1 . . . Zona Portuaria, Puerto Nuevo; San Juan, Puerto nu,1W.t ITOIWil CIa , QISPOS.AlfTSOl'..arnlnland Chemical Of P.R., Inc. 5Ill AIIOIlSS . , : I . . Km. 51, Hiqnway , .%, Manati, 'Puerto Rico ,,"Pltl t009) 721-1313 1'1111I0Il (U[l9) 792-7999 Rico '"ra09) 8~-1090 • ~ .. 1'fIO lMaVOIITtS MI TO. IITIJ2II. III "" 111 fOUDWWC AS ~TI ., " . ., 1 tOTAL. L,.. f1IIST _1ST tcIC\Ml., l1li IS . ' 1M!. ,.,. IS II!) rtIDrI:l US, OOT • ~! f ~ "'cws I .:a. 1 fORM t .T ~"'I . QUtUllIlY I' Xylene ~ nam. Liquid .H07 L I 'I ~ 21 01 , ~ I, : I I I I ! I . 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" :~ ·~·?fi1£j - =~&::~;;:..:s;.j y.fr.1.~ ·' 1 · r nusrom • ., , .ICU II., IaI --=-~ --- r _ .. , ,,, .... , :=- -' ~--:.:, ' ,-- ; '. . - . . . . 1t~R AT llIIS '£IIfOMnOIi £#,-,3//5'C, -------------~-------- -- -' ~ ~=-. ---=..:. .A ~ - - :- - -~ - - - - - - - - - - -- - - - - - - - - - - - - -~=~-~~;l ~~ 1·lr,~,tl'I'r' I'I'I~ It r ......... __ '_ - ~.yL! • ::> gil 1 ... \ C. . . . - . . . . . . $~.IIO I .1IAT\Jl , :iiII ... ~ ~ii(_ .. _fI)lf ------/--:-/-..-:~----..,.,-:OA::-n=-::o~I .I-::IY!:-:IIf-='7::-u--r?- ~ .. ca ....... tnt'y If ., .I ~'" t";" £.........,.1. ~ ..... llOtJ 7l!>.U2 10/10 ~~:;,~ Jr:--- . .Jr..... ~ .~ "':-::. _SJ _. ~~ tJOCUMHii ~o::::~·, p" - .J: .... :: '? r .~ L+- ... ..' .... PHOTOGRAPHS Berlex Laboratories St. Croix. VI -S~~t~lliber 9, 1985 ?:-:::-:G ;:,;..;' 1-:S Photo ~l - Aboveground raw material storage tanks. Berlex, VI ~.::~~ ~~ ... P~c~o #2 - O~tside material storage area. Ber~ex, VI FHO':'OCRA?HS Photo 13 - Outside material storage area. Berlex, VI .~ ... ~ '" - ~ - ~ ~-.. ~ photo 14 - Location of toluene drying oven. Berlex, VI , .... ~"'".;: , ~ • • )< .. ~ p :-; J ':" :)G ~~F HS pyridine contaminated to prevent saturation - PHC':'OGRAPHS Photo ,7 , '8 - Pyridine contaminated area. Lab waste drainage area, surface sampling using trowels. Berlex, VI ~~ .. :,p. c r~" ,)G~ ~ f' ~8 - .. "~"""-.,.01 .'.~--:"";;"~. '-::.0." . .. '-~ ,~-- ~ - ;-... ~ ?--.. - - :." .. Photo '9 - Pyridine contaminated area. Lab waste drainage area, surface sampling using trowels. Berlex, VI photo flO - Pyridine contaminated area. Lab waste drainage area, subs~rface sampling using bucket augers. Berlex, VI -:. P:-:~':' -=l\.:~!'?:-lS Photo ,:1 - Pyridine contaminated area. Lab waste drainage area, subsurface sampling using bucket augers. Berlex, VI photo t12 _ 55-gallon drums of toluene contaminated soil warehouse. Berlex, VI ~ PHC':'OGR..;PHS photo '13 - Close-up vie~ of toluene contaminated soil stored in ~arehouse. Berlex, VI Phot~ ,:4 - 55-gallon drums of ra~ materials stored in warehouse. Berlex, VI EI Generator TI l·ransport~r IJ TSD Participating Personnel: Report prepared by: Approved for the Director by: I 3.20 RCM ENFORCE INTERIM RPT 3/13/86 RCRA Enforcement Interim Report- No Analysis data Berlex Laboratories St. Croix, VI VID980651 095 March 13, 1986 Environmental Protection Agency - carol Price, Environmental Scientis t Joseph Cosentino, Environmental Sci. enti Steven Hale, Env. Protection Specia.l.ist Michael Glogower , Life Scientist Berlex Laboratories (ICC) Allan Kyles, Vice-President, Enviro-Sciences, Inc. (ESI) Ra}'l!!ond .Hays, ~ilit:.y Handyman c.~ ~olll~~ Carol Price, Environmental SdEmtis t toring Table of Contents Summary Objective ... .. . .. . ..... .. . . ... . . ... . . . . ... ....•.. ........ •. i Findings and Recommendations ••••••.•.••••••••••••••••••••••• i Discussion Purp<>se of survey ••••••••••••••••••••••••••••••••••••••••••• 1 Facility his"tory ...•.•...........•...........•..........••.. 1 Facility areas/treatment units inspected •••••••••••••••••••• 2 Sampling procedures ••••••••••••••••••••••••••••••••••••••••• 4 Results of analysis .••.••••..••••••••••••••••••••••••••••••• 5 ~ist of Figures and Tables Figure 1 Figure 2 Figure 3 Table 1 Table 2 Table 3 Map of facility: contaminated areas Drums in storage Map of sampling points Organic compounds analyzed Results of organic analysis- organic compounds detec~ed Results of metals scan analysis List of Attachments Attachment 1 A.ttachment 2 Attachment 3 Report of September 9, 1985 inspection Copies of manifests Chain of custody and sampling paperwork Berlex Laboratories (ICC) St. Croix, VI Objective VID980651095 Swrunary This RCRA enforcement inspection was conducted of Berlex Laboratories (ICC) at the request of the Solid Waste Branch in order to gather information necessary to determine the £acility's compliance with applicable RCRA regulations. Findings and Recommendations 1. Drums of hazardous material are being stored on the Berlex (ICC) site. Environmental Sciences, Inc. (ESI), the facility's contractor claims that these drums of chemicals have not been declared "waste" yet and so are not subject to accumulation and storage requirements. Most of the drums are the property of Virgin Island Chemical; no representative of this company was present on the site. ESI claims that thirty-three of the drums in storage belong to Berlex (ICC).~e other drums (approximately 155) ESI says belong to Virgin Island Chemical. The attached inventory (Attachment 2), prepared by a Virgin Island Chemical representative but given to EPA by ESI, contains a listing of the drums in storage. The number in the inventory does not match the number counted by EPA. 2. A storm sewer that collects run-off from the facility discharges into a intermittent stream behind the Berlex (ICC) property. The facility does not have a NPDES permit. 3. The results of the analyses for organics, metals, and PCB's revealed the following: o Phthalates appeared in all of the samples ranging from 1000 ug/kg to 17,000 ug/kg in the soil samples and 3.9 ug/l to 280 ug/l in the water sample. o Organics contamination was higher in the sample taken from the gut sediments at the point of the drainage pit discharge than in the other samples. This contamination consisted of xylene, di-n-octyl phthalate, 1,4-dichlorobenzene, 1,2-dichlorobenzene, napthalene, ,£lourene G phenanthrene, and aliphatic and aromatic hydrocarbons. o Chloroform appeared in the on-site well at a level of 130 ug/l. o PCB's were detected below the detection limit in all six of the samples. o The metals arsenic (estimated value), beryllium (estimated value),~hromium (ranging from 10 ug/kg to 52 ug/kg), copper (ranging from 40 ug/kg to 58 ug/kg), lead (estimated value), nickel (ranging from 19 ug/kg to 32 ug/kg), antimony (ranging from 8.4 ug/kg to 10 ug/kg), selenium (estimated value), and zinc (ranging from 63 ug/kg to 360 ug/kg) were all detected in the sediment samples. Arsenic, beryllium, cadmium, chromium, copper, mercury, antimony, and zinc were all detected in the water sample at estimated values. Berlex LaboratorIes (ICC) St. Croix, VI Purpose of Survey VID9806S1095 A RCRA enforcement inspection was conducted at Berlex Laboratories (otherwise known as Island Chemical Company or ICC ), St. Croix, VI. The survey was conducted at the request of the Solid Waste Branch to generate additional information necessary to determine the facility's co.pliance with RCRA regulations. The elements of the survey included a review of the facility's history; inspection of the facility; and the sampling of the stream sediments behind the plant, the laboratory waste pit, and an on-site well. Facility History The Berlex (ICC) facility has undergone many changes in ownership since it opened. The owner of the land itself, that the facility is built on, has remained constant. A local landowner originally leased the land on a 99 year lease. The first operator of the plant was Pierell America, Inc., who started operations in 1972. There were several other owners of the facility until 1979, when Berlex Laboratories (ICC) obtained the facility, having merged with the then current owner, Cooper Laboratories. Berlex Laboratories (ICC), a subsidiary of Schearing, began operating in November 1979. Their process involved taking quinidine (found in the eucalyptus tree) and changing isomers in the substance to convert it to quinine. This process continued through late 1982. In October 1982 Berlex (ICC) notified EPA of the forthcoming closure and removal of waste materials and excess chemicals (xylene, toluene) to Inland Chemical of Puerto Rico. EPA aSSigned Berlex (ICC) the RCRA identification number VID80651095. Prior to this removal, Berlex (ICC) was operating as a small quantity generator. In 1984 Berlex (ICC) sold the facility to Virgin Island Chemical. Virgin Islan& Chemical planned to produce benzyl acetate at the site by reacting benzyl chloride with acetic acid. This process was in operation for approximately 6-8 months, but ceased when the market price of benzyl acetate plummeted. As part of the sales contract with Virgin Island Chemical, Berlex (ICC) was required to clean up any contamination present at the site. Berlex (ICC) hired Enviro-Sciences, Inc. (ESI) of Denville, NJ, to survey the site and certify it as environmentally clean. ESI's sampling survey disclosed four areas of contamination. Two areas, between tanks 8 and 9 and concrete slab #3 (see Figure 1) were found to be contaminated, primarily with toluene. This contamination was thought to be from process spills. The other two areas, along trench #9 and underneath the concrete loading dock, were contaminated primarily with pyridine, thought to be from a leaking laboratory drain. The quantity of contaminants was estimated at 125 pounds of toluene and 120 pounds of pyridine. ESI recommended on-site treatment of this contaminated soil. The toluene contaminated soil was to be placed in a drying oven equipped with carbon filters, so that emission rates did not exceed the 200 ppm TLV for toluene. -2- The pyridine contaminated soil was to be treated by cutting the concrete pad and tilling the soil every 2-3 days to allow the soil to aerate. A structure was to be built over the area to prevent soil saturation from rainfall. ESI reported by letter on May 15, 1985 that this clean-up would be initiated on June 6, 1985. The Environmental Services Division conducted an inspection of Berlex Laboratories (ICC) on September 9, 1985. The findings of this inspection are summarized in the attached report (Attachment 1) • On October 10, 1985, 192 fifty-five gallon drums of waste were shipped from Berlex (ICC) to Chemical Waste Management in Alabama lsee Attachment 2 - Hazardous waste manifests). This waste included: o Toluene contaminated soil which had been treated in the drying oven o Process pit water and sludge o Drums and soil from the wastewater drainage line The pyridine contaminated soil remained in place. As of March 13, 1986, Virgin Island Chemical is not operating the facility. A warehouse full of drums exists on the site. ESI claims that approximately 33 of these drums belong to Berlex (ICC). According to ESI the drums contain mostly laboratory reagents, washings, and miscellaneous materials. These have been sampled by ESI and analysis is currently underway. The remaining drums belong to virgin Island Chemical. These drums contain raw materials, product, and other incidentals used in the Virgin Island Chemical process. A count of these drums yielded a number of approximately 155. According to an inventory of drums by Virgin Island Chemical, which ESI possessed, the number should have been approximately 208. According to ESI, this inventory may have not been accurate because some of the materials may have been re-sold on the island. 'A representative of Virgin Island Chemical was not present during the inspection. A listing of the drum inventory is provided as Figure 2. Presently, plans are being developed for U.S. Resources, Inc. to lease the site from Virgin Island Chemical. A representative of U.S. Resources was present on the site on ~~e day of the inspection and some of the company's equipment was present on-site. U.S. Resources, Inc. plans to operate the facility as an alcohol conversion plant. The process involves dehydrating alcohol contaminated with water, which is then used to make gasohol. ,FaCility areas/treatment units inspected During the March 13th inspection the following areas were inspected and/ or sampled: ~Process pit The process pit is an 8,000 gallon underground concrete pit that was used to contain process wastewater and sludge that settled from this wastewater. This pit was cleaned out in 1982 when Berlex <ICC) shut down operations. The sludge and wastewater present in the tank were -3- disposed of locally. In 1985 ESI tested water which was found accumulating in the tank. The results from this analysis showed contamination consist- ing of benzyl chloride and some heavy metals. The pit was cleaned again and the contents were shipped to Chemical Waste Management in Alabama as -hazardous waste liquid, N.O.S ft • This tank was not sampled during the March 13th inspection, as originally planned, because it was sealed with concrete after the 1985 clean-out. °Toluene drying oven The oven used for the treatment of toluene contaminated soil was found to be empty during the March 13th inspection (see photos 1 and 2). According to ESI's representative, the soil present during EPA's September 9, 1985 inspection was shipped to Chemical Waste Management in October 1985. Opyridine contaminated pad The concrete pad located behind the Berlex (ICC) facility was ~~e area of pyridine contamination. The pad was broken up and the soil tilled every 2-3 days as treatment for the removal of~ridine as specified in ESI's workplan. At the time of the March 13 inspection the area was uncovered, and according to ESI, had not been tilled recently. Two samples, #085254 and #085255, were taken from this area. A composite of the soil from the surface to a three foot depth was obtained. A sample, #085252, was also taken from a suspected area of seepage into the intermittent stream behind the Berlex (ICC) plant. This soil sample was a composite from the surface to approximately 10 inches in depth. A background soil sample, #085251, was also taken up~r.ream of the Berlex property for comparison purposes. °Storm water sewer According to ESI, the original storm water sewer at the facility consisted of old, clean toluene drums welded together and attached to a concrete line. In October 1985 the line was excavated and the drums were found to be corroded. Sludge was found to be accumulated in the bottom of the line. The drums, sludge, and two feet of soil were removed and shipped out. A new PVC line was installed (see photo 3). Although this storm water sewer discharges into an intermittent stream located at the edge of the property, the facility does not possess a NPDES permit. Sampling done earlier in this area by ESI revealed higher than background levels of zinc, cadmium, chromium, and lead. A soil sample,f085253, was taken at the point of discharge to the intermittent stream. During sampling, a tropical rainstorm developed, and water wasq~bserved discharging from the pipe (see photos 4 and 5). °Production well During the inspection a production well was discovered on-site. The well was not in use at the time, but was still operable. ESI had no knowledge -4- of ~~~ 2urpose~ depth, or construction th~ facIlIty had 1nstalled or used 1t. taken from this well (see photo 6). °Drum storage area of the well or which owner of A water sample, #085256, was A variety of chemicals are presently being stored in a warebouse located on the Berlex (ICC) property. According to ESI, the drums contain raw materials, product, and incidentals from virgin Island Chemical and Berlex (ICC) • Approxi- mately 188 drums were found to be stored during the March 13th inspection (see photos 7, 8, 9, and 10). Attachment 2 lists the name and quantity of waste stored, according to virgin Island Chemical's inventory and ESI's statements. Sampling procedures A total of six samples were t4ken from the Berlex (ICC) facility (see Figure 2- Map of sampling points). Three of the six samples were taken from the intermittent stream (known as the -gut·) that runs along the edge of the Berlex (ICC) property. The first sample taken, 1085251, was a 6ackground soil sample to be used as a comparison to the other samples taken from the gut. The sample was taken from the surface mud using polyethylene scoops and mixed on Benchkote paper to insure repesentative split samples. The sample was analyzed for purgeable organiCS (POA's), non-volatile organics (NVOA's), PCB's, and metals. The second and third samples, 1085252 and 1085253, were soil samples taken from areas of the gut directly behind the Berlex (ICC) facility. Sample j085252 was taken from an area behind the laboratory drainage pit where drainage may have seeped into the gut. Sample 1085253 was taken from the area of the gut where the storm sewer discharges. Both of these soil samples were taken from the surface to a depth of 10· using a stainless steel hand auger. The first core from the auger was discarded to minimize cross-contamination; the remaining cores were mixed on Benchkote paper in order to obtain a well- mixed representative sample. Both of the samples were analyzed for POA's, NVOA's, PCB's and metals. Two soil samples were obtained from the laboratory waste drainage pit. The first sample, 1085254, was taken approximately 10 feet from the bUilding, and the second,f085255, approximately 20 feet from the building. The stainless steel bucket auger (rinsed with water and deionized water) was used to obtain cores to a depth of 3 feet. The cores were mixed on Benchkote paper in order to obtain a representative and well-mixed sample. Both of the samples were analyzed for POA's, NVOA's, PCB's, and metals. The sixth sample, 1085256, was obtained from the production well located on the site. Since the well was of indeterminate diameter and depth, a precise determination of the volume of water to be fremoved could not be made. By considering the average depth to groundwater in the area of the Berlex (ICC) facility, and the apparent size of the well casing, it was estimated that purging 150 gallons from the well would remove 3-5 times the well volume and samples representative of the groundwater would be obtained. Consequently, the well was pumped for 6 minutes and 20 seconds, removing 170 gallons of water. The sample was then taken directly form the plastic hose attached to the well head to minimize damage to the :.wellx;head. -5- All samples were split, with ESI acting for the facility. The samples were collected in appropriate contai~ers and preserved according to EPA protocol. All samples were shipped on ice the following day to EPA's Edison laboratory. Results of Analysis The results of the analysis of the sediment and water samples are summarized on three tables. Table 1 presents a list of organic compounds for which analyses were conducted. This list does not include compounds which the laboratory may have identified as major peaks. Table 2 shows the organic compounds that were identified in the samples collected. Table 3 lists the results of the metal scan analysis. Most of the samples showed some organics contamination. All of the samples, including the background sample taken in the gut, contained phthalates, chiefly di-n-octyl phthalate, with butyl benzyl phthalate and bis(2-ethyl hexyl phthalate also appearing in a few samples.-These values ranged from 1000 ug/kg to 17,000 ug/kg in the soil samples and 3.9 ug/l to 280 ug/l in the water sample. The results from the sample taken in the gut, at the point where the drainage line discharges (#085253), showed more contamination. This sample contained xylene, 1,4-dichlorobenzene, 1,2-dichlorobenzene, di-n-octyl phthalate, napthalene, flourene, phenanthrene, and aliphatic and aromatic hydrocarbons. The on-site well results showed contamination with chloroform. The PCB analysis results showed the presence of PCB's below the detection limit in all of the samples. The results of the metals analyses, for the sediment samples, showed varying levels of arsenic, beryllium, chromium, copper, lead, nickel, antimony, selenium, and zinc. The results of the metals analyses for the water sample showed estimated levels of arsenic, beryllium, cadmium, chromium, copper, mercury, antimony, and zinc. The value for chromium in the sediment samples increased from the background level of 10 ug/kg to 52 ug/kg at the point of the drainage pit discharge, finally leveling off to 25 and 27 ug/kg in the lab waste pit. The value for copper remained fairly constant through all the samples. The value for zinc decreased from background to the point where the lab waste pit seeped into the gut, but increased to a high of 360 ug/kg at the point where the drainage pit discharged into the gut. The value leveled off to 79 and 80 ug/kg in the lab waste pit. The value for nickel was also higher at the point where the drainage pit discharged into the gut, with as value of 32 ug/kg. () Berlex Laboratories VID9806S1095 St. Croix, VI 2. Former toluene drying oven. 1. OVen formerly used for the drying of toluene contaminated earth. . " j : . J; . ' f~I~~. a .. .A .. ~~ ..... '*~ . j -.. ~"-" , # : .. ~ -6- e Berlex Laboratories (ICC) St. Croix, VI ., _w .,-.... .... .... -..... , VID980651 095 -,,- ' .. I. -: ,' ~. ;"f... . ' ~_ .. .'t: ~ -~~" .;1 • :-r... , ....... ,,~ .. .. ~ ', ' .;. ... ~. ' .... , Ij ~-1'~ '~""1 :- '.~ ~ ~ . .J ie.';" · ,~~l,~ . .. '~,.:.':':";"'''' -",/' " ~1"~~'1:5 ~w..~~ . ~~ ' - 3. Polyethylene storm sewer line replacedin 1985. -7- 4. Storm sewer discharge into intermittent stream behind Berlex property during tropical storm. Berlex Laboratories (ICC) St. Croix, VI • VID980651 095 5. Sampling of intermittent stream bed during discharge of storm sewer. 6. Production well located on-site. -8- Ber 1e .. .. '_,., ... l.es (ICC) VID9806S109S St. Crc~ " , .'l 7. Warehouse used for drum storage- first room of drums __ e~~ . , ~'" -. ' t ·_ z _ ....... .......; -....., ~ . 8. Warehouse used for drum storage- second room of drums -9- :3~.: l e x La i.>or a t v •. i e.£ .st. Croix, VI '<.. ; . ,,, ,...,\ ........ _'-) 9. Lab pack drums stored in warehouse. 10. Close-up of drums of benzyl chloride in warehouse. -10- VID9806S109S ,. ..... -- ~ - ~ ~ ~ -, I 1 CONCRETE ""DDING 7 e 5 2 1 !JL- 7 OD aD CiD CID on i\ CD c::::::Jl CD CI) CD CD CIJ CD ~ 113 TANK FARM 5 Figure 1 - Map-of facility: Contaminated areas .. ,,&& .I.&a •• &, .. "",~ c,ot)&. 'Me ~o..,~tL ~ ® 11 a,tL c,,*tt . .: c U ""on foaL o ITn&6c.&. T ••• , ~., I &UC'7a& • :0 • " :t 4 ___ _ U 1, \ .. !~__ • I ~~ . ~ [] il~~OlI: :rali~f::tl D D ~ .8 ... _____ a .... -~ ~- 0 ..,.~.~ . A~ ' _ .... ~. iOOOlo ....... • • LJ:aQ.... tL b. • ... :lc1&ACWt 1/ 12 a.G. ... T .... a:::JC:). -L'> -" ..,... "'"" <.y U ..... &.~ ", 6ft,. D ·~ GNl~a'tft& ~,.~ , C'.EU9nC.' •• &~ ... --. a6.CNt. TRENCHES 1-12 -71 L _0. . .. .-1 ...... '-----"'/ \ o 50· 10C HeHSF31 SCALE ft.& .. ~ C .. ., ..... "', ISLAND CHEMICAL PLOT PLAN Figure 2 - Drums in storage Virgln Island Chemical drums: Type of material Waste # Anti-freeze Miscellaneous detergent/ Salt Toluene / U220 Lube oil Modul Herbicide' Benzyl chloride P028 Methyl isobutyl carbonyl Salicylic acid Sodium hydroxide, Acetic acid Triethylamine (TEA) Acetone U002 Methyl isobutyl ketone- U161 Sulfanic acid, S.::>d.i urn acetate Sodium hexametaphosphate Benzyl acetate Toluene-acetone mix U002,U220 Methanol Sodium hydroxide (solid) /~ Chloroform drums (empty) Berlex (ICC) drums: Type of material Lab chemicals (Aceto-nitrate, Acetic acid) Washings CUt up drums Miscellaneous materials Crystallized material Size of drum 55 gallon 20 gallon, 15 gallon 35 gallon (fiber) 55 gallon 55 gallon 35 gallon (fiber, steel) 55 gallon (plastic) 55 gallon 55 gallon 55 gallon (fiber) 55 gallon (plastic) 55 gallon 55 gallon 55 gallon 55 gailon 55 gallon (fiber) 35 gallon 35 gallon 55 gallon 55 gallon 55 gallon 55 gallon 55 gallon Quantity 33 (total) Quantity 19 13 2 10 5 2 1 28 12 27 33 18 3 1 1 1 1 1 22 2 4 2 208 4 Figure 3 ~~?f -s~h.£l9~.:i::h~ ::# O't"SB!S1 ~ O<g5S5.2 X- _-__ _ .... -~----. ~ . ..J/ ...L , • : • • • • CD mJ C!::) c::c : Il~ - c::!) ~.~ c:.o CD CD c::o ' ... , ..... * • -"I !er rn-, • Cr, T .. ~ .... ...... .U& ~ L .. == i 0 0 ......... - - __ . C.':" _ .. , ) .' - J~: .\:r:-~ ~J. D ·11<.------ D ~ I ';ID~. e . o c:::t ':8 8 e ....... - ... ....a... __ . I ::.. ..... / -- _ .. _ ~-O-o. 0.. ... .,... LJUi •• ; L.;..J ............. .... A., ........ U~·1 .. « ......... ' ....""" c=o ... , •••• u - -. "'0 -€) _'0& -- I ..... C"II c::::::= t· I' \\~ ~ -, I • ---,,/ 1 '-\,~~~~;~.;-;;;~~ • to ,ot SiiI::::E!I e! __ I s:· .. f ~ "' ........... , ISLAND CHEW'CAL !"LOT !"LAN O'f5.:2~3 x = Sampling point • = Production ,-reIl No"!: to scale. I ..... tv I Table 1 - O~anic_ CCITpOUnds which analysis was'conducted !,c I(~ .. (~~Il' 1(" I!~.~~ ~L~.!~.~ !!·l.!"'~'~ ~!~q~':..~J_ .. __ ._. __ .. e::: clh ,1 ~~! )~·'I ~-.c. ~el~~~ _____ _ 2-c , 01'011 If'flO ---. ···r :.,. -:-. -.-..... - ~ : tH I~~:h~'~ilj;;~: . -.. 2-nn r-( "Ii(!~}\-" -___ --1--_. _. ··' .. ··~I-· .,--. 4-n 'n)l"~flOl .. --. --I· . -....... -.--.----. ~ !.~~~~ II! ,i ~ ~~')!!<:~!-:_::_1-~-- 4,1l-«I " ' ... o-n-cr~sol - .--.. I·'· --.. - .. -.------ ... (lPn' ac ,I orollhmM1' ~_ •. _ .•. _. ..J .. ___ . ____ . __ _ I '~!l4.)! _ ... " __ ' __ " __ _ !~~~!:!!"'~~t .• ·~ I f'~~,~!!¥ls !1<:~"i\1 J~I~ h("It! .... __ . __ . ___ . tlfm7. cll"~ 1',2,4-' .... iril iorOiM~nze_.lO- _.--- r'exi,cl'tlm iJH!iiz(>.lC --.. -- ...... i . . ... - .. - .----.- he x (trill OHH" hann !i~~.~ ?-:-('i,ii)n~i l'yl1'-:~~~ ____ ~ 2-chlonll'ill",t ha lene -.. - --I . ... . -... ----.- ) ,2-t' t:hlOl ohpllzene 1:1-(lld,lo .. alC'llzene----·--- -- .. - -, . _ .... _ ......... __ ._---- I ,4-tl ch I 01 o'lC'nzeno -.... . . .... . -. .. -. -·i-,-.----.-- 1.1 t ·tlichlnrohpnzld ne 2~ii'-(IiI·,it ic,i()hlP.no -- ------ 2 :-';-ti l.lI i i(,i(,hlP.n.· -- ... ----- 'j ~ :i-a I i~j";"vli'v(:ti~az 100------_. ((tA 870a.h,7,nll4!) - .-- '" ... ·1' .. . . .. .... -----.--- r "IOn ... ' 'PI .. ! - _ .... ., ..... .. -............ -.... . . ~ -:.~h h.-rot d,C'ny' I ~~(.'~'y'! __ «:.~~tet .. I\~~!,!~~~!_~~!.. (~ol'l~)unds "-hHJ1lO~lC"II ~lCnll ether 1;1 s=f2'= ciJ IorOI s¥O(lf.l1 eillei': hi fi( 2-dlloroelhOJ(~thane --- i tU)liich lorohulil<tlene - V:(~~~!~~!~!ltlKlle~ __ _ i,i)IJ,iha I.-!ne--------- i, I , .. Ollf-mze-ne-,---.----· - ~~:{ ~%:~ ~n~~!k~i~ :'ne hlsf2-ei I,-[tmitll' ,a'lI'alate- i".frrllen~y.rrr_iT,~lale-·--. ::: =~=lli:o/1: ~~~~{:: ;,~~----.. ·'r]--.Y -- L. ___ . __ ---- ::, ::\l'r.-.. JlI~,~T.1Il{e------~-. . . ._if_1. ___________ _ ht!nzo(a)anthrocene i)(H'Z()l~i)r':coo-- ------.--- ~i .~-henZf)rlU()rantrlCne ------ hi!fl7.olkrf ItXlr:ani]~,ie-'----- '" ----------- c 'ry.~e~_ .... _. ____ _ . ac~!~~[~~~~Y.!.f!!~. _____ _ illl'hracenc 1~!i,z~rij~l.rilCfy'ene . __ _ r'tlOrene i~ ,efllmt hi:--ane' _._ .. --- d 11)(~nzol a ~.,,) anthracene ~ r .. ~~i~fI~ '2 '!.!-ai.h)Y..--ene-_-_-~~ pyr~,!lC __ ... _. __________ . ___ .. Volat lies acrolein oc..-lOilftrl I'e---.-.... -... ben5"·--- ------ - --- -- carhor,tetrachlor-itie- -.- a,IOH)henzene------- -. r,2-'(ual1c)rooil"-.ne -.--- T;T , 1- t. i I chi oroo' ii~ne- - ------::;,--,.- ------. ---' .. - I,I-dlch oroethane 1.! i ,2-fro !~;~~7~~!,~~_ --.. I , , ,2,2, - tel rach loroell'iln~ cf,lc:JroeUui,ltj--'- ---- ... --,- . _. ----:- -_ ......... .-:--,----- _ ... _ .. ~.cl-hIO£~~!.!.!'Y)- .~.!Jl~~ _ en orofonn .-----:il-... - ----f----~--·· I ,l-dlchtoroel lene T: 2-tr ailS':''' rat ior:(~Tt.ene- .. r:2-e:IlCl, I'()r(\)"(-nne' .. -. ..... - '-r-;--.-'-". __ 1(1 •. _-_ ... -... - ~.!.:!-~I~d'.~~~!~.>i~o(l~~!~ ___ ._ :tr.!~:-~~-:d.loil(,e- - --.- ··T·---·Y--" --- .-........ -.. -.- en I oronn. halle In-oooetl,ai;e-" ---- -.. ---.-. . ______ . __ 0""---- _ .. _ ... hr-unof olln (llchjorohra';ioot.r.anc- --- -- . ,it t=TClllo.urTtiororwii Imne - . (UcTaloroil n \K)[(lne' liano .. -- .. ·_··1--· .. ·_··_------ .. - ..... - . ch IOH:x' hfUllunet.hane letraatlmoe,KTene' -.-. . ..... - ---- ....... . Y _. __ .. - .. toluene tilCilror(:H;U, lene ------ . -. v1"'" cllf(,i-l~e- --_ .. - --. -- -Y--- _ ...... _______ . _._ ... _ .. "P~j' k lclps - ._- illtla'" fllC'l(ldn --.- d'lo"i''''e- . - -·1 - .-- _ .... - 4 ,4 -lUI' '1 - I' .. -.'. - •.. -. • •. -. .-. 'I ,of -In·; -4 ~-IP .. i)lii ---.- c·,-)( i'-,sI.1 r ail-l- endof" i I fan· i j' -- el. 10m. i ian m i i f ili 'p- --- - .. 1'1 .. - .... e'"n· n f!'lIidii ai(l~ -ie - -. . ... _ .... ___ Y' .. __ .. _ . h(~l" ildllor i -· .'-'-' .. _ .. ---- ---,-. --. '('[It neh I or epox c 1(, flii( .. rd ;Iia---' . . - (_ ... _--- -_. l"I('-IIe'" a -"'- -- ,._._-_.--- IUK'··')'! 'a 1\1 I( •. ( ;illUil i,('niHl-- Pet\ I r',,, iii ;i.- i ) 2. r --- --- 1'<'1\-1212 1l('il-lHo-- . i)(~Ii·T](,o-- -. - -. - _,0 .. __ • _____ • __ _ PCH--lUlll .- -.- --I·· -- _.--._. ~_())wpll('ne ____ _ .,Iox IllS '). " -, • n -• (!, I .wlt, or CJ( I i p_-(lIo xill ... ___ . List does not inclme cx::rrp:>uros identified as other major peaks. Berlex LlB6rat.ories st.. Croix, Virgin Islands Table 2 - Result.s of Organic Analysis- Organic Compounds Det.ect.ed ComPQund name Gut Back .. Lab waste ground· pit seep VOA #085251 #085252 Xylene Chloroform -------------- ------ ------ NVOA Butyl benzyl phthalate 1000 Di-n-octyl phthalate 17000 9000 1,4 dichlorobenzene 1,2 dichlorobenzene Napthalene Flourene Phenanthrene Bis(2-ethylhexyl)phthalate Aliphatic & aromatic hydrocarbons --------------. ------ ------ PCB PCB-1016 1000K 1000K PCB-1221 1000K 1000K PCB-1232 1000K 1000K PCB-1242 1000K 10001< PCB-1248 1000K 1000K PCB-1254 1000K 1000K PCB-1260 1000K 1000K --- ------------ ,-- *All values in ug/kg except where otherwise stated. K ~ Actual value known to be less than value given. M = Presence of material verified but not quantified. Drainage pit disch. #085253 470 ---_ ... - 7700 970 2900 2100 2000 2400 M 1000K 1000K 1000K 1000K 1000K 1000K 1000K Blank space means compound was not detected in sample analysis. Lab waste Lab waste pit # 1 pit # 2 #085254 '085255 ----_ ...... ..... _---- \ 4900 3200 I ....._---- 1000K 1000K 1000K 1000K 1000K 1000K 1000K 1000K 1000K 1000K 1000K 1000K 1000K 1000K VID990651095 •• ,\ On-site well (ug/l) #085256 130 .... _---- 2K 3.9 280 ."...------ 1'1< 1K 1K 1K 1K 1K 1K Berle:lf'Laboratories St. Croix, Virgin Islands Table 3 - Results of Metals Scan Analysis ComEQund name ~ample location/Sample # Gut Back- Lab waste Drainage Lab waste Lab waste ground* pit seep pit disch. pit ,. 1 pit ,. 2 1085251 1085252 '085253 1085254 1085255 Silver Arsenic 2J 1J 0.8J 0.8J 2J Beryllium 7J 8J 7J 7J Cadmium \ Chromium 10 22 52 27 26 Copper 40 45 52 55 58 Mercury " Lead 30J " Nickel 19 20J 32 25 27 Antimony 10 8.4 Selenium 1J 0.8J 0.8J Thallium Zinc 100 63 80 79 - 1 36: J -------~---- ---.~ - _.- -'-- -- ---- _.- ---- *All values in mg/kg except where otherwise stated. J - Estimated value. M = Presence of material verified but not quantified. Blank space means compound was not detected in sample analysis. VID980651 On-site well (ug/l) /. , 1085256 2J 5J 3J 7J 8J 0.6J 3J 20J ------- --------- Attachment 1: ESD Report of September 9, 1985 Berlex Laboratories (ICC) VID980651 095 ~rch 13, 1986 ill Generator r=r Transporter ill TSD .-' Participating Personnel: Report Prepared by: Approved for the Director by: .RCRA Enforcement Berlex Laboratories, (a subsidiary of Island Chemical Co., Inc.) St. Croix, Virgin Islands VID80651095 September 9, 1985 u.S. Environmental Protection A2ency Louis DiGuardia, Geologist Carol Price, Environmental Scientist Darvene Adams, Environmental Scientist Berlex Laboratories, (ICC) Alec A. Smith, Vice President of Operations Raymond Hays Armando Morales, Process Engineer "L Cj~ 9:LJL. Louis DiGuardia, Geologist Source Monitoring Section Spear, Chief ce , Monitoring Branch TABLE OF CONTE1';':'~ SUMI-I.ARY Objective ------------------------------------------ i Findings ------------------------------------------ i DISCUSSION Applicable Regulations ---------------------------- 1 Purpose of Study ---------------------------------- 1 Facility History ---------------------------------- 1 Facility Description and Operation ---------------- 2 Water Usage and Treatment ------------------------- 3 Waste Streams ------------------------------------- 3 Treatment Methodology ----------------------------- 4 Waste Storage ---------------------------~--------- 5 Manifested Shipments ------------------------------ 6 Sampling Procedures ------~------------------------ 6 Sample Results ------------------------------------ 7 Reference DOcume~ts ------------------------------- 9 ATTACHMENTS Attachment 1 - Receipt for Samples Attachment II - Chain of Custody Form Attachment III - Sample Data Sheets Attachment IV - Waste Manifests PHOTOGRAPHS TABLE Table I - Results of Organics Analysis on Samples LIST OF FIGURES Figure 1 - Facility Location Map Figure 2 - Berlex (Island Chemical) Plot plan Showing Areas of Contamination Figure 3 - Berlex (Island Chemical) plot ?lan Showing Location of Dryer Figure 4 - Sample Location Mnp - Drying Oven Figure 5 - Sample Location Map - Lab Waste Dtainage Area ..... ~ Berlex Laboratories (ICC) St. Croix, VI Objective VID80651095 SUMMARY This compliance evaluation and sampling inspection was conducted at the request of the Solid Waste Branch to support and verify the decontamina- tion and removal by Berlex (ICC), St. Croix, VI of soil contaminated with toluene and pyridine. Findings 1) Sampling results indicate: o Organic analysis on samples 1087001 and 1087002 (drying oven) detected the following organic compounds ranging in values from 460 ppb to 15000000 ppb: toluene, flourene, bis(2-ethylhexyl) phthalate, ben:ophenone and di-n-octyl phthalate (detected only in sample 1087002). o Organics analysis on samples 1087003, 1087004, 1087005, and 1087006 (lab waste drainage area) detected the following organic compounds ranging in values from 360 ppb to 75,000 ppb: toluene, bis(2-ethylhexyl) phthalate, di-n-octyl phthalate, chloroform, benzene and di-n-butyl phthalate. From the results, the toluene values were found to be within the acceptable level range of 2 ppm (reference document 12). Due to the late arrival of guidance protocol from EPA Research Laboratories, Cincinnati, no analysis of pyridine was performed. 2) Confirmation of on-site treatment of soil by Berlex (ICC) for toluene and pyridine was made. o Toluene The drying oven was employed for the volatilization of toluene from the soil, but the necessary charcoal filters to absorb the volatil- ized material were not observed. o Pyridine The contaminated soil was tilled and aerated using a backhoe and then covered over by a large synthetic liner. No permanent structure had been built to prevent future saturation of the soil from rainfall. The present liner was not owned by Berlex but rented. -ii- 3) No data on the sampling performed by Berlex was ever received by the USEPA, Environmental Services Division, Edison, NJ to confirm the clean-up by Berlex. 4) The re-routing of existing laboratory discharges to a self-contained unit and portable toilet facilities was not observed. 5) On October 10, 1985, Dr. A. L. Kyles, Vice president, Enviro-Sciences, the consultant working with Berlex (ICC) informed me that 192, 55- gallon drums of waste was removed from Berlex for disposal. The material consisted of the following: o Process pit water and sludge. o Drums and soil from the ~aste~ater drainage line. o 1, 55-gallon drum of water/toluene. o Toluene contaminated soil. No manifest copies were received to confirm this shipment. 6) Hazardous material was stored on-site for greater than 90 days and in quantities greater than 1000 kg. Berlex is then subject to the regulations 40 CFR Parts 262 and 264. None of these regulations ~ere observed to have been followed. 7) In review, a question is raised that a possible source of contam- ination is that of the dry creek bed. Process ~astewater was dis- charged via a drainage line to the creek bed. Since the drainage line and soil associated with the line was found contaminated, the possibility of soil contamination in the creek is likely and should be investigated. Berlex Laboratories (ICC) St. Croix, VI Applicable Regulations 40 CFR Parts 262 and 264. Purpose of Survey VID8065l095 DISCUSSION A RCRA compliance evaluation and sampling inspection (CEI) was con- ducted at Berlex Laboratories (ICC). St. Croix, VI on Septemoer 9, 1985. The survey was conducted at the request of the Solid Waste Branch to support and verify Berlex's decontamination and removal of soil contaminated with toluene and pyridine. The elements of the s~rvey included a compliance record review, site survey and sampling. Facility History The Berlex Laboratories, Inc~ plant, under the name Island Chemical Company (ICC), produced quinidine from November, 1979 afte~ purchasing the site from Cooper Laboratories, until late 1982. In October 1982, Berlex notified EPA of the forthcoming closure and removal of waste materials and excess chemicals (xylene, toluene) from the site to Island Chemical of Puerto Rico. EPA assigned Berlex the ID No. VID80651095. Prior to the removal, Berlex was operating as a small quantity generator. Berlex sold the site in September 1984, 21 months after the shut-down of operations to Virgin Island Chemical Co. The sales contract for the site called for the contractor Enviro-Sciences, Inc. (ESI), 19 Copeland Road, Denville, NJ to survey the site and certify it as environmentally clean. An ESI sampling survey initiated in September 1984 disclosed two areas of soil contamination, with the compounds of concern being toluene and pyridine. On December 21, 1984 Enviro-Sciences, Inc. delivered a progress report describing ESI's sampling and analysis of soil at the Berlex site on St. Croix and included recommendation for treatment of the pyridine (U196) and toluene (U220) contaminated areas. The recommended on-site treatment was selected by ESI as a more economi- cal method than the alternative off-site shipment of drummed soil to the U.S. mainland for placement in an approved landfill. The proposed method of clean-up includes the drying of toluene contaminated soil (which is+presently stored at the facility in drums) and degration of pyridine contaminated soil. This would occur by exposure to ambient air causing soil.eration. Soil saturation by rainfall would be prevented by covering the area with a synthetic liner. -2- The toluene contamination resulted from soil leaks/spills at a tank site and pyridine contamination from leaks from a laboratory drain line. The estimated quantity of the two materials (toluene and pyridine) are less than 245 pounds. On May 15, 1985, ESI reported the intended initiation of clean-up activ- ities on June 6, 1985. Facility Description and Operation The Berlex Laboratories, Inc. (Berlex) plant under the name Island Chemical Co. (ICC), located in St. Croix, Virgin Island started producing quinidine gluconate in November 1979 and operated for 2 years. During operations Berlex employed 215 people on a 2 shift,S day/week, work schedule. Maximum production output was estimated at 50 tons/year, but this level was never reached. The first prQduction batch by Berlex was November 1, 1979 (see Site Location Map, Figure 1). Berlex (ICC), St. Croix, VI manufactured as their sole product quinidine gluconate. The basic raw materials used in production included quinine sulfate, toluene, and methanol. Production involved the conversion of quinine sulfate into quinine gluconate by the addition of toluene in a reaction vessel. The liquid was then distilled with methanol to produce the cystalline solid, quinidine gluconate. Within the production area, the facility housed the following reaction vessels: Reaction Vessels Number of Vessels 4 1 1 1 3 Material Construction Stainless Steel Carbon Steel Glass Lined Glass Lined Glass Lined (Receivers) Capacity 1200-1500 gallons 1200 gallons 3000 gallons 2000 gallons 2000 gallons Bulk raw materials arrived in tank trucks and were stored on-site in 14, 8000 gallon raw materialctanks (see photograph #1). -3- Water Usage and Treatment Groundwater was the primary source of water used in production. Approximately 20,000 gallons were used, of which, 10,000 gallons were recovered. Water was pretreated by filtering and adjusting pH (with sulfuric acid) due to the high carbonate concentration in the groundwater. The facility also housed the following systems (and tanks): Number of Tanks Capacit~ Systems 1 15,000 gallons Boiler System 1 15,000 gallons Drinking Water (rainwater) 4 50,000 gallons Recirculated Cooling Water 1 20,000 gallons Reduction/Oxidation Unit 1 250, 000 gallons Firetank Wastewater from production operations (primar~ly cooling water) was collected in a 17,000 gallon underground concrete, process pit. No treatment was applied but prior to discharge, the pit was sampled to see if any product was released by &ccident. If nothing showed in the sampling, the water was discharged via an underground pipe to a dry creek adjacent to t'cicili ty property. Waste Streams Hazardous wastes at Berlex (ICC) were generated from the following sources: 1) Process Pit Water and Sludge The 17,000 gallon underground concrete pit used to contain pro- duction wastewater and accumulate settled sludge from this waste- water. 2) Former Main Wastewater Drainage Line The underground pipe (constructed of welded 55-gallon drums) from the process pit to dry creek bed. The pipeline was excavated due to the finding of numerous leaks and punctures from which waste- water had contaminated the soil (see Figure 2, areas of contamination) • 3) Contaminated Soil Due to Drainage Line Leakage A) Contaminated soil associated with the ~xcavation of the main wastewater drainage line. B) Contaminated soil due to drainage line~eakage from the lab- oratory drain. -4- 4) Contamihatec soil from raw material spillage - toluene, pyridine. The spills associated with material transfer and tank or line leakage. Includes soil under the concrete surface loading dock, along trench number 4, under concrete slab number 3, between tankS numbered 8 and 9, and along trench number 9 (see Figure 2, areas of contamination). 5) Contaminated or off-specification raw materials which could neither be reworked nor sold. Prior to the facility's shutdown, Berlex (ICC) was said to be operating as a small quantity generator. What Berlex did with waste prior to the requested hazardous waste shipment (October 27, 1982) is unknown. Treatment Methodology As a result of sampling performed by Enviro-Science, Inc. (ESI) to certify how environmentally clean the site was, ESI disclosed two areas of soil contamination by toluene and pyridine (see figure t2, Plot Plan Showing Areas of Contamination). In response to such a disclosure, ESI recommended on-site treatment as an alternative to the economically unfeasible transport of the waste to the U.S. mainland. Reference document tl, contained the following methodology of treatment which was to be followed: o Toluene The toluene contaminated soil would be placed on trays in a dryer located within the facility (see Figure 3, location of drying oven). Soils with low and high toluene concentration were permitted to be mixed to insure uniform drying. The empty drums from which the excavated material was stored would be washed with a nonphosphate detergent, rinsed with tap water and then air dried. Drum washings would be collected and later evaporated in the dryer. These same drums would be used to store the air-dried soil until laboratory analysis indicates that it is free of toluene or has very low concentration. If the soil is found to be free of toluene or at very low levels (2 ppm, reference document t2), it will be redis- tributed on the site. Pr ior to beginning the drying operation, calculations will be 'made using the fan speed, oven temperature, and stack diameter to+insure that emission rates for toluene do not exceed 200 ppm TLV. This concentraion in air is not flammable. If calculations show that this control rate is marginal, then a carbon pot will be added to insure this limit would not be exceeded (see photographs t4 & t5). -5- o Pyridine The pyridine contaminated area would be treated in a 3 step approach. 1) The pyridine contaminated area wo~ld be covered over to prevent the saturation of soil from rainfall (see photograph 16). 2) The concrete surface loading dock in the vicinity of the pyridine contaminated areas would be removed using a backhoe and hauled to a landfill or used to stabilize the bank along the dry river bed. The Department of Public Works would be contacted for permission to do the latter. 3) The pyridine contaminated soil would be tilled and aerated using a backhoe at 2-3 day intervals. Soil turning would allow exposure of the contaminated soil to ambient air. - Samples would be taken at the beginning of the cleaning operation and continue at weekly intervals until acceptable pyridine levels are reached (2 ppm, reference document 12). When the pyridine level has decreased to zero or an acceptable level the area will be restored and resurfaced according to the owner's requirements. Waste Storage Berlex at the time of inspection was storing waste material in two areas: 1) Outside Fenced Storage Area During facility operations, this was used as a raw material storage area. It consists of a 50' x 20' concrete pad surrounded by a chain-link fence. At the time of inspection, 1, 55-gallon drum containing approximately 40 gallons of a water/toluene mixture was being stored. Other empty 55-gallon drums were also present (see photograph 12 & 13, Outside Drum Storage Area). 2) Warehouse Storage This area was used by Berlex as their major raw material storage area. At the time of inspection, 20, 55-gallon drums of toluene contaminated soil were being stored prior to treatment in the drying oven (see photographs 112, 113, & 114). Large numbers of 55-gallon drums containing raw materials used in production were also being stored in the warehouse. -6- Manifested Shipments After the shutdown of plant operations in late 1982, the raw materials which remained on-site in the facility's above-ground storage tank were removed (including toluene and xylene). The transporters and TSD used for these shipments were as follows: Transporters Trailer Marine Transport Corp. PRD980644579 Isla Grande, Puerto Rico Tr ansporte Diaz PRD980S26834 Zona' Portuaria, PUerto Nuevo, San Juan, Puerto Rico TSD Island Chemical of P.R. Inc._, PRD090399718 Km 51, Highway .2, Manati, Puerto Rico The manifests are enclosed as Attachment IV. According to Dr. A. L. Kyles, Vice President of Enviro-Science, the consultant working with Berlex (ICC), 192, 55 - gallon drums of waste was removed from the Berlex (ICC) facility on October 10, 1985. The drum contents consisted of the following '~terial: o Process pit water and sludge o Drums and soil from the wastewater drainage line o 1, 55-gallon drum of water/tol~ene o Toluene contaminated soil No manifest copies were ever received on the shipments from Dr. Kyles. Sampling Procedures On September 9, 1985 samples were taken at Berlex (ICC), St. Croix, Virgin Island from the following areas: o Composite soil sample from the drying oven (left side). Sample '087001 o Composite soil sample from the drying oven (right side). Sample '087002 o Surface soil composite from the north side of the Lab Waste Drainage Area. Sample '087003 -7- o SubsJrface soil composite from the north side of the Lab Waste Drainage Area. Sa:n;:le t08i004 o Surface soil composite from the south side of the Lab Waste Drainage Area. Sample f087005 o Subsurface soil composite from the south side of the Lab Waste Drainage Area. Sample f087006 Attachment III contains copies of the sample data sheets. Within the drying oven, the soil was placed on steel trays and stacked in 13, 20 tray bins. A oivision of the dryer into the left side and right side was made and a composite sample was taken from a represen- tative number of trays. See Figure 4, for s~ple locations. Photographs f4 and f5, show the location of the drying oven • . ' To take a more representati~e sample of the Lab Waste Drainage Area, the area was divided into two sections: north and south. Surface soil samples were taken using trowels and subsurface soil samples (approx. 3 foot depth) were taken using dedicated bucket augers. Due to the very resistant nature of the soil (impermeable clay) only a sample depth of three feet could be obtained. See Figure 5, for sample locations. Photographs f7, 18, 19, tlO, and fll, shows the areas of sampling. Sampling equipment and containers were prepared according to EPA stan- dard procedures prior to sampling •. A total of six samples were taken. The samples were analyzed for purgeable (POA) and non-volatile (NVOA) organic priority pollutants. All analyses were performed in EPA's Edison, New Jersey laboratory. EPA standard procedures were followed for the collection of samples throughout the survey. Samples were not split with facility representatives. Receipt for samples (Attachment I) and chain-of- custody methods forms (Attachment II) were employed for all samples taken. Sample Results Sample results are given in Table I. Organic analysis on samples f08700l and f087002 (drying oven) detected the following ~rganic·compounds ranging in values from 460 ppb to 15,000,000 ppb: toluene, flourene, bis(2-ethyl hexyl) phthal, benzphenone and di-n-octyl phthalate (detected only in sample f087002). -8- Organic analysis on samples '087003, ,087004, '087005 and '087006 (lab waste drainage area) detected the following organic compounds ranging in values from 360 ppb to 75,000 ppb: toluene, bis(2-ethylhexyl) phthalate, di-n-octyl phthalate, chloroform. benzene and di-n-butyl phthalate. From the results the toluene values were found within the acceptable range of 2 ppm. No laboratory analysis was performed for pyridine due to late arrival of guidance on pyridine protocol from EPA Research Laboratories, Cincinnati. .-' Reference Documents 1) Enviro-Science Inc., Progress Report, Island Chemical Company, Inc. (Ber1ex), April 4, 1985. 2) u.s. Environmental Protection Agency, Review of a Report on Pro- posed Soil Decontamination by Enviro-Sciences, Inc. 3) U.S. Environmental Protection Agency, Fact Sheet, Requests to Treat Contaminated Soil at St. Croix Plant Site, February 5, 1985. 4) U.S. Environmental Protection Agency, ICC/Berlex Plant Site, St. Croix Fact Sheet Including Preliminary Analytical Results on Nearby Well Fields. .-' Berlex Labs, Inc. St. Croix, VI VID80651095 Table I Results of Organics Analysis on Samples Sa:nple# Samplett Sample# Sample7f Organic Compounds 087001 087002 087003 087004 ug/kg ug/kg ug/kg ug!kg Toluene 460 560 420 440 Flourene 9200 1300 I Bis(2-ethylhexyl)Phtha- 13000 4700 16000 1900 -late / Benzophenone 15000000 2600000 - Di-n-octyl Phthalate 500J 4200 , <' Chloroform 200K Benzene 200K Di-n-butyl Phthalate I Sample 1087001 -Aerated Soil Composite fLm Storage Room (left side) Sample 1087002 - Aerated Soil Composite from Storage Room (right side) Sample!1 087005 ug/kg 360 51000 600J Sampletl 087006 ug/kg 400 36000 2000 75000 Sample 1087003 - Surface Soil Composite from North Side of Lab Waste Drainage Area Sample 1087004 - Subsurface Soil Composite from North Side of Lab Waste Drainage Area Sample 1087005 - Surface Soil Composite from South Side of Lab Waste Drainage Area Sample 1087006 - Subsurface Soil Composite from South Side of Lab Waste Drainage Area K - Actual value known to be less than value given J - Estimated value Blank Space - Material Analyzed but not detected I I FIGURE 1 ,- CHRIS"'IAN8TED FREDERIKSTED FACILITY lOCATION SOURCE: COMPREHENSIVE WATER RESOURCES MANAGEMENT PLAN FOR THE UNITED STATES VIRGIN ISLANDS. 1983. i t" FACILITY LOCATION MAP o 5,000 10.000 FEET I I , ~ ® ~ - ~ - CONCI=IETE PADDING 6 ~ 7 e 6 .. n' 2 UI 1 I 7 C!D aD on OD lJD ti CD c::::::::l , CD CD CD .CD CD CO • 113 TANK FARM s -- FENCED STORAGE FH3URE. ~ ""1& ... ,. .UI."",,~ ~ ..... , '0'''" !1 W ® D 4eon , ... o 'Tl"JC.Ac.&. f ••• , ,,~ '''''~'.: • • IUCfM.t:::l It. U I': ~~~!~_. c::;:~ D il~~Olle er.-tml"",tl'~LI/ ~ ~ ........ il @ I ••• MoIL O D •. g ..... ___ _ ...... • ~""~'~~!.!&~':""'=-:,;:;: c:::::z L.. . cru' •• '" 'effl .. tOt • .,.. ~ro-o. 0" .. ". • 41!'11.1"\ • .. -~.~ .... U • '.C"'ft.. /J. ::l ."'. (f 12 .0. .... ., ••• ~ ..., ,. 9"/toi c:::J<!) . ~h.tU"~Ll ,·&t ....... U "'"'- ,f, ,~. """"......-.... o ."K. TRENCHES , -12 ._/. ~ I .......// 1'· .. "-l o so' 100 HASHSI SCALE "'A"'~ C,.?C ... ,t ISLAND CHEMICAL PLOT PLAN t CONC~ETE PAO;)INCi ~ J I ~ 1 UL-.. 7 C!D C!D i. l on C!D on CD ~2 CD C=::l1 CD CD CD CD CO CD • 113 TANK FARM ~ ~ - PLOT PLAN SHOWING LOCATION OF DRYER I' lj f H:, \.J RE. 3 FENCED STORAGE LOADING DOCK CZ'W' •• 'ft& '. t=:J N.&& ... ,' ® .Ul ""..", " .fton (,u o '''''''c.&. T' •• , AIOI .... jt)-O-o. 0" .. ,., ! . .D Q..': """"~~I "'PN"" .~ .. .~l'. . ... C't'ftL ~ :::J au. II 12 _tllt4l.'f ••• ~ _TU "".Ii COO . ca"ru",.. .. l 't&t. P" ... U C"'"'- ",1ft.. .....(1 .............. o • .. 0Ct. TAENCI-IES , -12 -I"~ I I -----"",,/ / r \.. .. .. ---1 o 50' 100' "'" •• ,,-& sri. & ... ", HeHHSI SCALE ISLAND CHEMICAL PLOT PLAN Berlex Laboratories St. Croix I VI DRYING OVEN - tolue.'1e contaminated soil ( Top View ) r-------- .... "",",,"~~ VID 80651095 -~.------... door r~ D D---O Right Side D o Left Side (North Side) CJ .0 0 (South Side) -..:; NORI'H D D "0'0 door Ccrrposite soil$"samplefran drying oven o #087001 - left side (south side) o #087002 -::right side (north side) ( Not to Scale )* ~chrectangle represents one bin containing a stack of twenty trays. Figure 4 - Sample IDcation Map- .. Drying (Nen 'Ill: NORI'H Berlex Laboratories St. Croix, VI ® .. ® ® ® VID 80651095 lAB WASTE DRAINAGE AREA - pyridine oontaminated soil Building , .- ® ® ® ® (fonner lo..cung dock area) ® - Sarrple locations for carposite Soil sample fran· north side of the lab Waste Drainage Area o Surface - #087003 0 Subsurface - *087004 Soil sample fran south side of the lab Waste Drainage Area o Surface - #087005 0 Subsurface - *087006 ( Not to Scale ) Figure 5 - Sample IDeation Map - Lab Waste DrainagecArea .. ATTACHMENT I Receipt For Samples Berlex Laboratories St. Croix. VI Septembt'!r 9, 1985 ~ ~ .~ ~ ~ , i m ~.k · t -- :. ~. ;....li,i,: ~·E ~ Rec€\IT ~ ~~ "'CHAIN OF CUSTOD Y RECORD ENVI.ONMENTAl P.OTECTION AGENCY _ IIGION II Environmental Serviees Division fDISON. NEW J£lSfY 01117 N ..... f Ufti' 0"'\ A~~'·"L \ \ . C d -n\ Ber'~"" _no:-~:- .~ V .'"T. ~\~.J S •• ~I. N ... It.r Q~~\ ~?7~ ~~7D;3 D~~ ~7~ VID ~OCoslO"S: H",.It., .f ."t.i~.n \ ~ ~ ~ I .2 ~ .. rI~;." .f , •• ,1 •• Q-t - ~O~ 7Ae.~~~, \ - Co~\k ~ r.\ ~\_~ .s Q-\ - N\Jo~ 7 I\~ ~', \ - G~--k ~ ~ ( \J \~.s ] .' - Ct+- ~*>~ l~-t~~ ~'I) - ~~,k ~ ~\ \J~ ..,) ~ . :\.. - ..... '00 ~ 7 c- I. j::.., C""' - \ - fl t."'; ~ ~ ~~ \1".:..\.1',.) .-'>J,!::).:)J ~ ~~~ ~ \ I ~' Q\ - ~uo~ 7 ~ - \ (\ k ~. ~~ V...:.\S ,.)S'''r~~- ~~, - ~~, ~ Ie; 185 ~~6 \ ..l. l ~ \ ~ CB.. -\N~~7 ~~.r*~ ~I I - ~c~~,~ 't-c ~ \( ,~S ..) ....... A ..... i ... 1 ........ II.ili.y I., S •• ,I.: , •• ,1. ........ , ••• ,1. ...... , 5 •• ,1. ........ , S •• ~I. ......... , •• II .. ~ .. Is ... ~ I" •• li .. ""I ...... I.,: •• Ii .. ~ .. i.h.~ I.,: 1.li .. " .. i ...... I.,: ...... 1 ..... I", 1 ... 1 .... I." •• e.i .... I.,: •• e.i .... I,: Ti •• n.. O.te a ...... f.r e ... " ••• f C.".'" Ti.. 0 ... 1_ ... fe, c ... " ••• J c ....... ., TI.. O.t • I ...... f., CII." ••• f e ..... '" TI.. O.t • I •••• " f., e ........ 1 C ... ,.ely , ....... Do •• \ ... ATTACHMENT II Chain of Custody Form Ber1ex Laboratories St. Croix. VI September 9, 1985 , \ !i--t..: .;l.iN OZ :.'. ~,,"" : ":f\'t ; ·,"II"CO:'ftD .... n"" c ,,,,";;v. ", ~.. ~p; 'I\. ENVIRONMENTAL "OT(CTlON AGENCY - lEGION II Environmental Services Division IDISON. HEW JlUH 0 .. 17 H .... • 1 URit .ft" A""'r·" 1 BeAe)£. LCI..~-:-.;'\~t'"~ e.s T~. ~ ~ , Cf"O\)( ./ \I \.C'"~.:. T.sL.k. WQ S ••• I. Hu ••• r O~'7~\1 ·i~1 N ...... ' .1 \ ~ , ~ \ ~ \ ~ , ;)... \ ~ o..cri~i ••• 1 J •• ~I •• Q-t.:T'.c- ~ ~ w t \c.c.. ~c ~t V ~~ls. ~J\~ at.:J'.r ~~ u.r I \Ct. ~<;) ~t VI--'\~ IM/,~ Q.:~. ~ ~\(~~ ~I \~ -' Lto "'\ V,ols ,-J~ 9..1:-. :r~ ~v~A ~{\ut. "k> rr--.( \/L .... b ~/,~ G:X . ~t"" \.YJ~ I.J/\~ '\-Q..-..l V \ .. b ~/.ce. Qt.:t..- ~\[~~ 1.AT1\~ Lto ~\ v\~ ~/4 ,·c·".,,_ ...... 1 ...... ~ ... ilHlity fe, S •• ~I. : VI\) ~Q'-S\C9S; Ti •• De •• .. \f~ h hhs I •• ~ I . ~".C5.v- fr.."...(a: ~p~ De •• I ...... f., C ..... , •• , C.".'" ~ . l.r~' "'>"'f!'"'.o.:. 0\ ~e~ +~ ~ •• " ." .. i ...... I r. .... 1" ... I r. Det. ~ •• 1 •• "" •• 10." ''rI I •• e i ... " I " n.. D ... I ...... f.r Ch ... , •• 1 C.".'" .~ RUlJ1'lt~ -1i1 {~ •• 1 .... ,,1 ...... ''rI I ...... f., CII.", •• 1 e ..... 4, £;1ryf7~ ~~ ~ 1'~ a...Q N()CX+~ ''' ..... .. .' ATTACHMENT III Sample Data Sheets Berlex Laboratories St. Croix. VI September 9, 1985 FIELD DATA SHEET ENVIRONMENTAL PROTECTION AGENCY· Region It, EI.!;;;:';., . ,;':,' Jersey ENVIRONMENTAL SERVICES DIVISION L.A ~'f= 'fll" Project Name ~ ... Ie" b'- b!> l' n( . 51 ( .,.1->:" , V J:. Samples to: Collector(s) D, c.~ l.A 5 P' d: 5 Affiliation U.> £" P1 I ~jei~'1 c:r I Other I SAMPLING METHOD (Circle) LDMSCODE Statton "'Wo. Kemmerer Dredge Ponar Manual ~)r'~k'kl(,kll lul71s1 I Niskin Net Seine Trawl Bucket OAT A BASE CODE ~ Cream Dipper STA. TYPE CODE utomatic Sample Depth (Ft.)fFac. loco Code Other L3 bIola 1 --- suaSTRATE TYPE (Circle) Aqueous Sediment -Sludge 011 :.elological - Lab "umber Solvent Extract ~ S':),\ 1 : I 087001 I SOD - Seed Supplied DYes o No~ Source: Type of Sample - Sample PreparaUon (Ctrc6e) Sample Source Type (Circle) Grab Composite ... cOnt.ainer Cleanino fIrocedufe Landfill Industrial .. - l' ,]~~ - ([lass Jar- I ') ( Detergent WaSh') Laachate Effluent , Plastic Jar < Water Rinse:;) Drum ,. Process Stream Collection -cending) Date '- Metal Acid Rinse Test Well HoldIng Pond .. j1Irc;IOj,loi~ ~AVial-D "Solvent Rinse: Depth: Drum -Cubltainer .Acetone Other: Waste Pile Acetate Core Hexane Municipal Treatment Ending Time 124 Hr) . 11111010 ] Paper cap i c:::!«'elh9Tene ChIO~ Storage Tank Influent 0~ Otnenspecify): Top Effluent-CI Foil cap Middle Effluent-Non CI Beginning bate Other Bottom Sludge , 117 sl S1°'jI tij, I Truck Ambient Preservation Drum Lake Acid Tank Stream Beginning Time (24 Hr) Solvent Other Pond It b 1'-1 G1 Chemical Ocean ~ Wells Estuary pH Dry Ice Monitoring I I I I I Ambient Production , Other Drinking Private Sample Temp. ('Ie) I I J 1 I . Sample Location Description: C. r' ..- c:; +t c.~ :;.c.; I c.., ""' fO~; I-c. -t= r'- ....., 00 (mgll) ~ivY~<.. y UiJ ~ I c.J ..J .s , de) I I ] I I Cond. (uMHOSfCM) I I I I I I I Sailnltyc-; • ., Remarks: I ] I I I ,vv0A . -, \ - l~' J ~ "" l " (. eel Sample Split d" '-tv P'J P""A v' , ) ) DYes )(NO if Yes With Whom? lc ...... ic;;;.t"'>'"""oolr"""'<:; k d ~.)\ (,,~~ Receipt o Ves o No 4-..... I ..... r r"') < !)y' \l . Form: FT8 RPO-1H12·2 FIELD DATA SHEET U£r ENVIRONMENTAL PROTECTION AGENCY· Region II. t'2J::'cr., Nf:'.., J'.m.i<:'~J ENVIRONMENTAL SERVICES DIVISION Project Name &';;;U' "'r..? V 'I 'k" ,+ , I ..... Collector(s) "",\:, I.., ... of J ,c- Affiliation £'?I< -f ~ P SAMPLING METHOD (Circle) LDMS CODe ________ _ Kemmerer Dredge Ponar Manual Niskin Net Seine Trawl Bucket OATABASECODE ________ __ ~dI Cream Dipper ~atic STA. TYPE.CODE C»her __________________________ _ SUBSTRATE TYPE (Circle) AQUeous Sediment "Sludge 011 Biological Solvent Extract e So:) ... Test Well Depth: C»her. I ~aQ~ -;hYlene Chlori~ C»her (Specify): I Top Middle ~ Etfluent-Non Cl C»her I Bottom Sludge Ambient Lake Acid Tank Stream Solvent C»her Pond Chemical Ocean ~~ Wells Estuary Dry ce Monitoring Ambient Production C»her Drinking Private Sample Location Description: AtC, .... ,",cJ. >o~1 (C'""mpO.;).~.ft~¥I~tl .. "$,,"!( C.( '_--\-'-'f £ C"\t! r,..Cr'l1 ?\\J~ ('"6t"'\t~ •• 'i(::.i:3 t::rY\ -{(OOf Remarks: t-.l\) (; t; - T-C-,t-':. - ..J I ,-, . ..0 dc, (> , , J ('" i i - - J • -. \/c, V ~ --:::.' ~~;."'- ,- .... '- ( (.;.- .... \ e;. .. ...".\ n (..l +" J $0. \ -h C"Y"r\ -to\v+~c Form: FTB RPO-l1.a:/·2 Sf ·11 Samples to: I ~ct~ Sio StatIonHo. Chem "...- Other ktt5j~kkkl/kbfll Sample Depth (Ft.)fFac. Loc. Code 13k bill Lab Number I 087002 T~pe of Sample Grab CompOsite J1ime]~J • Collection (Ending) Date 1~,S]6i~ loit} I ending Time (2" Hr) I J II] I 131 Beginning Oate 1?,s-IOf~ IOOjlj I Beginning Time (2" Hr) 1/1/10101 pH I I I I I Sample Temp. rG) I I I I I DO (mgfl) I I I I I Cond. (uMHOSlCM) I I I I I I I Salinlty(%.) I ., ] I I Sample Split DYes .,. No If Yes With Whom? Receipt DYes o No FIELD DATA SHEET ENVIRONMENTAL PROTECTION AGENCY· Region II, Edison, New Jersey ENVIRONMENTAL SERVICES DIVISION UEF Project Name "Cr ,.. \ C ,( L <! ~ i 1 Q(, • >t. C r D 1 )( ; vt Samples to: I zr~ I O1her I Collector(s) n I (~ i. C " • J , S Affiliation v~ £" PPJ I Bact .] B;o ~, -~~--~~-,~ -~- SAMPLING METH~D (Circle) LDMS CODE Station tic. Kemmerer Dredge Ponar Manual Ivli1~,lok lsI, k;19kl Niskin Net Seine Trawl Bucket OAT A BASE CODE I (fro;;!) Cream Dipper ST A. TYPE CODE Automatic Sample Depth (Ft.)/Fac. loco Code Other 1.3ldlcI~1 _~0 _ ~ __ ~~~ .... ~~ SUBSTRATE TYPE (Circle) Aqueous Sediment Sludge 011 Biological Lab Number Solvent -Extract e3< ~~., , I {)87003 I SOC --- ~ad Supplied DYes o No Source: Type of Sample Sample Preparation (Circle) / Sample Source Type (Circle) .- Grab Composite I' Conta~ Cteaninc Procedure Landfill Industrial 1 - ~Iass Jar - .!) • Detergent WaSh~ leachate Effluent 'Inmels~ ... ( Water Rin~~ Drum Process strum - Plasm;orar _ Collection (Ending) Date Metal Acid Rinse Test Well Holding Pond lz,sl~, IJi4 I . ~vias;D Solvent Rinse Depth: Drum O1her: Waste Pile Ilainer Acetone Acetate Core Hexane Municipal Treatment Ending Time (2" Hr) II 1;>10101 Paper Cap ~ ~e~n! Cf1lori~ Storage Tank Influent ~IO~ Other (Specify): Top Effluent-CI I p Middle Effluent-Non CI Beginning Date Other Bottom Sludge J 'SIr sloi09ldj~ I - Truck Ambient Preservation Drum Lake Acid Tank Stream Beginning Time (2" Hr) Solvent Other Pond II " )'f 101 Chemical Ocean CWetl~ Wells Estuary pH Dry Ice Monitoring I I I I I Ambient Production Other Drinking Private Sample Temp. (-C) I I I I I Sample location Description: 5c...(! c;( c ~C)', C.C'--f0.l.' -k (' rQrw""\ nO.,-l ~ 00 (mgn) ~ .etc::. J~Q'';)c.. I I I I I (.)4- JQbU"q'lo~1 4,...,,)ql~ c.r("'; Cond. (uMHOSlCM) I I I I I I I Sallnlty(%,) Remarks: J I I I I I - j~ NVo A j "'" 1 I (c: d ~. Sample Split d· .... u ,..,.J ?v A V, q , ~ o Yes ~NO If Yes With Whom? C\:;,'( ~U'I' .J ~l"'¥"'\c. ....... hq1 ~t Receipt DYes o No FCImI: FT8 APO-11.a;z·2 FIELD DATA SHEET U£r- ENVIRONMENTAL PROTECTION AGENCY· Region II, Edison, New Jersey ENVIRONMENTAL SERVICES DIVISION SAMPLING METHOD (Circle! Kemmerer Dredge Ponar ~ Net Seine Trawl ~ Cream Dipper Automatic Manual Bucket Other ________________________ _ LDMS CODE _______ _ DATA BASE CODE _____ _ STA. TYPE CODE ______ _ SUBSTRATE TYPE (Circle) Aqueous Sediment Sludge Oil Biological Solvent £xtract 9< 'S.~.I .. ~ I n_._ ..... _- I Test Well Process Stream Holding Pond Drum Cubitaifler Acetate Core ~ ~ Foil cap Other ____ _ Acid _____ _ SOivent ___ _ Chemical ___ _ ~ Dry Ice Ambient Chher ____ _ Acetone H~xane Sample Location Description: Depth: Chher: l~n~a~sl~e-~-I~le~--------~ Top Middle Effluent·Non CI I ~ .. -... I Sludge . Truck . Ambient Lake Stream I r I Pond ~=====1 Ocean Wells Estuary Monitoring Production Drinking Private S,-, b c;.. v ( .!:, {(" sa...." I{ ./rc-r-n /CJ:, el,. a ,nar .so, \ {>. < •. a..- Remarks: \oJ \.' (\ I \ G t c; to .... ~)('t ('" \ . -; ::, ~,.-; ~ V \ ~ ..- • oJ {"-,. - r ,( .. \ ......! , ..... _}~ '\( .... , ::.,0, \ .' Fonn: FT8 APO-11-82·2 Samples to: "ct. j 810 I c~ I Other StetionNo. fJil p>~ 10 b ~ I, f0 b k-I I Sample Depth (Ft.)fFac. Loe. Code li k 10 I~ I ab Number 087004 Type of Sample 'Grab Composite fTjmel~ Collection (Ending) Date [vr I Mo bDaY J $' Oft ''7 Ending Time (24 Hr) II II ~ !i I Beginning Date ~ 15 ~MA botJ Beginning Time (24 Hr) Ell R f I pH I I I I I Sample Temp. <-C) ! I I I I DO (mgfl) I I I I I Cond. (uMHOS/CM) J I I I I I I Sallnlty(%.) I I I I I Sample Split o Yes )fJ No 'If'Yes With Whom? Receipt DYes o No .. FIELD DATA SHEET ENVIRONMENTAL PROTECTION AGENCY - Region II, Edison, New Jersey ENVIRONMENTAL SERVICES DIVISION Project Name ........ '. ,~ -WI _. _.." .,. v Collector(s) 0, G ~ <. , d . 9 Affiliation V) (:" pI) SAMPLING METHOD (Circle) LDMS CODE _______ _ Kemmerer Dredge Ponar Niskin Net Seine Trawl Manual Buc\(et DATA BASE CODE _______ __ ~!!) Cream Dipper STA. TYPE CODE ______ _ Automatic C»her __________________________ _ SUBSTRATE TYPE (Circle) Metal QOA vial-;J) Aqueous Sediment Sludge Oil Biological Solvent Extract e Sci' Effluent .' Process Stream Holding Pond Drum Cobitainer Acetone Hexane ~hYlene Chlo~ Other (Specify): C»her: .. . 1-1 M~u-n-ic-i~D-a-I-:::T:-r-ea-tm-e-n-t----1 C»her _____ _ Ambient Other _____ __ Effluent-Non CI 1 _____ '" I Sludge Truck Ambient . Lake Stream Pond I ,()cean Wells I Estuary Monitoring Production Drinking Private Sample Location Description: :;,°o~ h();\ It .:> "" f f G l e.. .5c..l.) ( ~r () ~ d·e. .f-.... '->~ S,dc. (;)~ jG:j~vt'q~ .... t ....vCi.)K d""~'''''Jc.. 01"'1::<1 Remarks: J- 91- NV6A G ,(C"d ;) . ..., ~ ~ Pu A Y I C. ,~ j C(;"~C'l ~, I Form: FT8 RPO-11.c·2 ~ Samples to: I SaC!] 6io I tt:1 C»her Station No. ~klijrlok lsi, IQ191~1 I Sample Depth (Ft.)fFac. Loc. Code 13P 10141 Lab Number I 087005 Collection (Ending) Date I~ Yi51 oi~ IODjj I Ending Time (24 Hr) 1111 Is I~I Beginning Date lllr~ bi, I~t; ] Beginning Time (24 Hr) n II I~IDI pH I I I I I Sample Temp. (-C) I I I I I 00 (mgll) I I I I I Cond. (uMHOSfCM) I I I I I I I Salinity(%.) I I I I I Sample Split o Ves "No If Yes With Whom? Receipt DYes o No FIELDDATA~flEET Ut.F ENVIRONMENTAL PROTECTION AGENCY· Region II, Edison, New Jersey -... ENVIRONMENTAL SERVICES DIVISION Project Name I A • ~,.. ,==". -...... - ~ _ •. ...- -- "h' ,-- ..... ~~~ \, T!("-O 1 UJ .I Collector(s) -:L. , {;. -'C, (.d ' .~ SAMPLING METHOD (Circle) Kemmerer Dredge Ponar Net Seine Trawl Cream Dipper Automatic Manual Bucket Other ______________________ _ Affiliation t:. (-/. - l.:.: L LOMS CODe _______ _ DATA BASE CODE _____ _ STA. TYPE CODE ______ _ SUBSTRATE TYPE (Circle) Aqueous Sediment Sludge 011 Biological Solvent Extract e S~. , Drum .' Process Stream Test Well Holding Pond Depth: Drum Acetone I Other: Waste Pile Hexane ~etflYll!!"I1! C::flIOrjd~ Storage Tank Influent Other (Specify): Top EffluentoCl Middle Effluent·Non CI Bottom Sludge Ambient lake Acid ____ _ Stream Solvent ____ _ Pond Chemical ___ _ Ocean Estuary Monitoring ~ Ambient Production Other ____ _ Drinking Private Sample Location Description: S...:\:~ ,I' !( ~~I( (...r("""rt1 )~ d,tit'iCJ~t ar'Co- Remarks: _ l • ~ ~ i"!-. ~ - ~ .1'- ,~ .. (' ~... C.\f'.~ ... _ ~r \ - . , C Ie. ~"_ vl~': ..; :...-c· I· Form: FT8 RPI).11-C·2 Samples to: I Bact.! ao I j?j Other 'Station tAo. I'A .1~!101 ~Isl t b h k-j I Sample Depth (Ft.)/Fac. Loc. Code 13R; k?1~1 Lab Number D87006 Type of Sample Grab Composite Inme I SpaL;!J Collection (Ending) Date I ~I'S] 9 0 <11 oi~f Ending Time (2" Hr) 1/1~131ol Beginning Date 181r51oi~ IDjC;1 Beginning Time (2" Hr) II kLlold pH I I I r I Sample Temp. r'C) I I I I I 00 (mgll) I I I I I Cond. (uMHOSlCM) I I I I I I I Salinlty(%.) I , 1 I I Sample Split o Yes o No If Yes With Whom? Receipt DYes o No • ATTACHMENT IV Waste Manifests Ber1ex Laboratories St. Croix. VI September 9, 1985 -~ :,.~~::,::~~ · t -- . -" .. _- " '" ,. ~, .,. o I'll lC08 It.UIIII'" l I I \\ \J 1,'"o~1 hlW\d ChllllUcal1Co'. Inc. "(UII'/) 77U-nllll .,. ..... "'il " I.. J [_tete 1)0 • r.tiate Bethlehem, St. Croix, U.S.Virl/in isl;)nlh 11WlSI'OIM1 110 I I l' ;. 11 ·,l I""fl" Trailer Har ne TrW'l~ort Corporation lItO'l ) 721-1313 811 ~u .. -----.- IU III 110 lv, J ,0,9, U, 01 (,' 5,1 0,9 1 >\ Ip,ll,lJl '1,11,0, ",4,4,51 7,91 Isla Grande; Puerto Rico l ... ",sr~lIJ 110 1 I"';':~' . - .-- -- . Tronsporte Diaz (~II"IL "/'}'L.7'J'r' 1m ADO_" ,; 1 1" Zona PortUliria, Puerto Nuevo, S8"1 Juan, Puerto Hi, '" 1IUTMlWIITDI"5I 01 ' ]-1' 1""\"'" ------.- DISP'OSIoL /TSllI fAtarn Inland ' Chemical of P.R., Inc. ~1If1cJ) W>4-10')() ~:,o'\t .ug~~y' " 2, Hanati.~ Puerto Rico .-. -.. ------ l"IU,Il, '), u, at s,2t 6\ 8,),41 I~ fI, 9, 0, ),9, 9, 7, 1, 81 ... nil TlIoUI T'Ml ~ ... TO. :'::Jf'14 lIlT 11( ,guOWUCC AS A/'HU,'I,\I, , i ' : ' I i ' , h'" 1_1$110 . • 11tlll. - '" flllST Mo\IIIIISI QCk:tl!.:1 :,1 "II I. I' PIOf'U US DO'! j! I ~"' III - f -'--;;-1: $IIII'IWC ..... \' i' ""'Q,Q$ 111 .... 11 ,p,·,t ,~IAIIII" y("~' 'Xylene RO ' I U· nam, liquid 130? __ , !I I~,~;~.r;r gnl , 1 II Ie ,0 ,0 , - I UM.lU.if,J W. • IrA tcail" --r "~-! .(~- IU.I _~ST! 1m " I J JjJ i hlKI lJ lEI OICI:l .-. t· ·· ... · • ~ : . 1 . J i . ,I , !:I i LLLL.L I I ,:,.! '1'- .. ---I .... J ! 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I' '~.. i ~1r;:;a7-i1i1 U'1CIlU $.Rlhl1 DAn II I · , ' , '" I 11 110 1 IftJ}J I '7' . Jero H. ludwi . PresidenJ_ .. _ -r:':Ir =m!'.:.......::::::-+_-nr- ...... _~~_...I,:;._ T~:.Ii!.Mlfftl.1IO I SlCIlAYUII,. ....... ., .......... _ .. "" 'MNS~I(II~" IIA H H!llMO " .. _ •. I .... a.:"'"' .. ~-i ____ "".., ........ --'.,, ·· ~"IC./l sees l2..ll!!!J~JlLJ ~..! ~ L.L.J __________ ~-_---------..&.:.:..I.;:IiO~ "" "'" ~ I.- ~i! -- ----- . . !!!.!--..:.::.- I II All ,\I " .• $ "". 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Puerto Rico IPIR1D(9r8,Or 6,4, ~ ~ 7 1 1'1111111 (UIl9) 792-7999 ' .... wOlln. 110 2 1 ran sp 0 rt e Oi 8Z I P 1 R, 0, 9, 8, 0, 5, 2, 6, 8, 3 Sill ADOIISS _ r •. - Zona Portueria, Puerto Nuevo~ San Juan, Puerto Rico IPIR, 0,0,9,0,:5,9,9,7,' lIU'I1IIl.1. 1T0IWil 1M I 1~1 ~fT1Ol'Aa/T'flnland Chemical Of P.R., Inc. (009) BS4-1090 IIll AOOIlSS . 1 : I : . Km. 51, HighWay ' .2, Manati,'Puerto Rico , ........ NO lIMsPOIIMS MIl TO. un.-. RlIUI .. fOl.l.OWlllC AS ~TI 1lI$ 10IIII15 10 -, ; ' , • a TOTAl • ...1.....: ,. hItS'T _1ST ~lIl '"' 1$ PR_ II.C.Or 7 1 I ( I f'II)fI£l US GOT ' ,! -.am .. ~1IAM1 1 :_ MlMOQAIS ... 11 fORM .r 1I\N1IIY UNlIS COlI 1&1", RS 1~: 100tl' 110 1m [c~~ Wlsn - -I' Xyhne R'l Flam. liquid I-H07 L J,3t 2,01 J gal luj W l!! I!t..9.. :: , J LuJ W U Lu J LuJ LJ U lLL J , I· . I ! J LuJ l.1J U Lu ~ I LuJ W U Lu , J luJ lLJ U ~ ~I' Clio, "':',,0:"" 1'151"V(1I01;5 tHCUJOIH~ tOll l A!11I~ lIlWl1OII\\. IOIliTII011011 01 AIlOlllilloAl W.\:iIlS III!.LUUIU lit :;'1"''111111 til A NO,,",lJ.'llOU~ /$A'UKl WIIICII 00 ItOl IlAWi TO • MAwrsnDJ I - j Glt4IfU,I011sa.rutCAllOf; n...iiD-an."~""_ ........ _ .... "-"iilnlliCt""",_~._"",d"_.,.,,,_I ,_, ... ,,.i""p,,,~,,, .. "'" Ie ...... ~ .~._ eI .. Dtt~- ., II~ .1 ('A ..... C-..... ," 'Ire _Mit :Ina~ -. _ •• t_"."" I .......... __ of lhe ,,,"_., s.. .... 0-'" f .... _ : .... _ ......... "' •• __ ............. ,.,. ........ 10 1 .. ...,_ .... ""...,....., ...... _t .. ",UI.IItt ..... "" _.... i "til -..11)11 S $ll;IIA'~ j I Jerome H. ludwig TMIISPOIIIIIl IIU I OAlI IIIt(1l1tD "',_ . ,"-o.:ct,"'''' "--' ~ .. - ...................... -1:':" SEeS 1912181 2 11,910, U-l L.1..J LI "11 OAT n TI AM Al 'H;S 1 AI 011.1 "';~ ~:~~~=~:~~~~~~~~=~=;==:=:=~~=~~~~~~~~-~~~~~~:=~~~ PART 8 CIII l,A CI. IV,Ir OI918 ,O,6,51 1,O.9! tIU vvOl!1J. 110 , $1;11& luItl1_.tr "'- '''-'* .... 04 ... _If'" 0: Il OwVl" n ......... _ ... , .. 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(00'1) nll-22on '" SIIIADI)IU$ ------.-- . ~_t!lljU IJ'('I J 1 U '} , [state 130, [state Bethlehem, St. Croill, U.S. Vir!)in Island!=; _1 1 1 1 T1',USl'O«TI~ 110 I rH\I~1 • - --- - -- Trailer Marine Trrts;>ort Corporation (60':1) 721-1313 ST! AOOIISS '. ------1 ~'_J[Uo.!S.!.lJ..n.11o 14 'lllS I~ Isla Grande, Puerto R1CO T"'"SI'()IIll~ 110 2 ~- - _.+----.--- , Transporte Diaz ---1u!n~)ln-J.2?2... .. " i l, ' sm ADDIlU . . 1.:,1I;l>!,} II! ,Il, J .:,,6 ,u,~ ,I Zona Portuar18, Puerto Nuevo, San Juan, Puerto Rico lnm9) 8S4-1090 TIIU Mit. STOIIAGol 011 IIi$I'OSAI /T~)jI&tlITY Inllfld Chemical or P.R., Inc. ~ ,R,D,O,9,O,3,9,9,',' ,f 5IT1 AtIIIIII ss Km. 51, Highway' 2, Haneti, Puerto Rico f MOM TIWI TWO lMII~omllS All TD • 1/Tl1ZUI. fll lIlT till fOUOWllG AS AnIIOrIA n nus , OMI IS 110' Of a toTAl Of _1 -'1M( fItS' IWIflST 00C\J0I( 1fT 110 IS , II II, (, '0, 6. PIIOrlajlSDor ' II DOT &II I I.' IDIIAIMtr.> ~~~ IlJafl~l .......... 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LLLJ LJ..J I I I , • $ 6 Sl'{CW HoUIOUMI> IIST'IWC11OIIS IIItlUOING tOllTAII.UI 01..,1lOIII .... IDlIITIfItATIOII Of ADDl1II*Al WAS1U ..cuao II SHII'M(IIT Of A MlIIIIAlAIIDOUS .... lUll WHICH DO CI'f !lAW TIl • IIWIIFESlUII - ~---:-. . ~_'# ..... + .. -' ~-;;"~...'1 ~S~~·~ .. ~ ItMGPOmUO I _ ~. c~~~ ·. ' _ .~ "_""~"'_"" -----=-. ff~::.,:.:. ~-:- ~~~.t ............. _.IIW .. 1 I I I I , -~';;§;4ifi~'tF 'lt"'("~: ' - '" C#- .? po, ~~ . ,-~- =~~ ... ~~":' __ ~_ . _____________ ~A!~na:.?~!O~ ___ !:;.. __ :!!!.~.c _______ _ - --:-:- -_ _ " ..&. - I _. 1·"'~"1·1'1"'1·1~,1! .,- 1W.AnEWl STOIIAGI ~ DISl'DSAI ImITT TTDltA1lOIII Of AlIT OflE1lfllC£S .TWft~ MAMIJ(ST AIIO $HIPMtIiT ()II USTltIC OIIIlASOIIS .. _ •• ~'fI<l" .... i _eo, ,oO; .... (_ •• 0...0" 1Nr. (1091 72~1I9Z Jo/ao ~.~-:';,~ ,,(' ......... .-=- .... 11 ~. _ "".L r/ DOCUMENT NO~ ' , P PI ~~:;. .,. J..: . • "!.:: ,., ,.e, . r.- ~ SS61 '6 laqma~das 11\ ·X!Ol;) ·~S Sa!101eloqe~ xa1lag SHdVClDO..tOHd ;~;~ Pli C'':'OGF..;?HS Photo ~l - Aboveground raw material storage tanks. Berlex, VI P~ ot o .2 - Outside material storage area. Berlex, VI PHOTOGRAPHS Fhoto .3 - Outside material storage area. Berlex, VI . .,; .... ~ '- - -::-=-. ~ ---:~~ 4OL- photo 14 - Location of toluene drying oven. Berlex, VI o .... ""*'.. PYO';'OGRAPHS ~ photo 16 - pyridine contaminated to prevent saturation " PHOTOGRAPHS Photo ,1 , '8 - Pyridine contaminated area. Lab waste drainage area, surface sampling using ~rowels. Berlex, VI • :>P'O '; 'JC;~ ;' P!-:lS Photo '9 - Pyridine contaminated area. Lab waste drainage area, surface sampling using trowels. Berlex, VI Photo '10 - pyridine contaminated area. Lab waste drainage area, subsurface sampling using bucket augers. Berlex, VI ~ PHcr.'OGRAPHS Photo tIl - Pyridine contaminated area. Lab waste drainage area, subsurface sampling using bucket augers. Berlex, VI photo t12 _ 55-gallon drums of toluene contaminated soil warehouse. Berlex, VI ~ PHOTOGRAPHS photo 113 - Close-up view of toluene contaminated soil stored in warehouse. Berlex, VI Photo 114 - 55-gallon drums of raw materials stored in warehouse. Berlex, VI Attachment 2: Hazardous waste manifests Berlex Laboratories (ICC) VID980651 095 March, 1 3, 1 986 l~!~eTi *» Hl;\lAriUUWVVA:) I t:·MAN.lI-l:~ I I . (As Required By The Alabama Department of Environmental Management) (Furm ~$19 . >e<11o, <lse 0" .I"e (12·tlllch) ty~w,itt!f ) ' . G.".t. ,O' • us EPA 10 No , ,-" I 9 1, I () I ~ ,r. ~ )I'7If!I~ I . ... CHEMICAL WASTE MANAGEMENT, INC. Emelle Fac,lIry AI~. H I.,-V 17.1 M,le M.,u, 163 Emelle, A lebem . 35459 . ~, "'YIO\IIe, 243032 '. ID us EP" '0 Nu_r 11. US DOT Deea...-. ~,.,."., SIttMMtw .... ~ c.tua. .,., ID II..".." Ole I . '" I ...... .. T 0 " ~ Co CWM P'of,l. Numr.r AJt.A£ ~,,~¢ CWM "0"11 Number ,It" IC,/I"'M -i'~ .. ,.~ •. L> B f ;M~ Jt.c • "4V _/ H,;q b.Ot!>I d. AOdZ' lOnal ''''o'INIIOn, _' .A./ ',p ~ L - JltAc-~~ ~ -............... ~-""'.:7 _ -.ev , ~«/,.,A ".try decla .. ' .... llhe _ ..... of I"'" COft.'9" .... ", .... 1,,11y allll _","ely descrlbecl ._ try ~ .,,~"' MIN .nd II. c1en,f,ed, pedllCI. martl.ed . • nd .... led. end a,. In I II rtllopeCtl In proper eoMIuon for trlftlPCW1 by ~ -.Ii", lID ICIP-* _uona' .nd Nuonal eowemlNlfl' regulal' t , .. ' ~ .. 4 Uft.... 1 .'" • __ II QU.MI\'( "'-". WftO hal ...." .. elftPled by I1.IIUI. 01 regul .. 1Oft from me dury to INk-. • _.,. ""n''''iulton ~If_ion 'under SectIClft 3002(1)1 of I'IC"A. , . 110 ten,tv IN' I M .... progr.", on pllce 10 .edllC. the ""ume .ftC! .... Cf1'/' Gil ".11 ...... ' .. Id 10 lhe dI!g'" , ....... e-t.,,,,,necI to .. __ 11y pr.c:tIClIII •• nd 1 ".... " 'ectad the II'IItI'lod of ""''''tnt. -.01. Of ddcIoMl -.mly "/lllalli' UI _ wtvch """,mlzft I .... or_m .nd flllur. ",",1110 hulN" heI't'" . ftC! the .", .. ron", ... t tn1ecvl",.., N. m • . /~N L. ~t'JiI ~ 17.Trerwoonlf' ~"~enl of "_.pl of M.II"ala A '01 ~ arne '" Onea~e S Iransport Inc : Nor~on C. M. Burt ~ , ' .Tranaportet 2 Adl_"d;e d "ec:.erpl of M.,.rllls T E " , , 1I.01Krepancy indlClllon S~ ~~~oo-oo~~----~----~~--~------------------~L-----~~~~----________ ~~------------1 , CettrflCllton 01 rec:.elpt of "'1.,110", ma,."." , NClpt •• not~ ", h. ", 19 . ., .--- ... - lIIIon.II Da, , • ., ',,' ~j,._"'A "-.700.22 CR_ . .... &) Pr_lCIrto«> is obaoIel. I.., ......... / '" Of ~ (Form du.gnl!d for U51! on I!"'I! (1 :Z.p."h) 'Vpl!w;':lf~r Fo'~" App'O:l!cl 0 .... 61110 "1000 ~~ r.porr57 3186 UN I FORM HAZA R DOUS 121 . Generator, US A J No an. est . age - ~o,,,,a1l0n.n 'nl! St"ladea ,reas WASTE MAN I F EST V '1' / n '1,oocument No I :! ... not ,eQult ed by Feder,l (Continuation Sheet) / ..b (! (:J ~ J / " .,..j r e t:JO,:i' Z6f'L law. J.Gl!ne,atO'·, NBml! r.n:..;>14NJ C'''''{"A'~'- ~"""'''''''1'' .roc ,,, ~~~r:.p A'crSD • /'1$/0 L . State Jo4an,fa .. ~~ !.u~ber Trailer Number ~ CWMA ~~~ TMIZ 680365 M.Stata GeOifltor'. 10 eV.4fI~ ;'flea) ~r!Y dICfdSI: n, .:?,,;-~?¢. - 4~-DO 24. Trlnaponlr:;::iCompeny-"Name ~0'#&C'Jl,. A/A"'~AIIfI~ 25 --US EPA ID ~umbe' ~t.tiIfin~~ J~ ~ ~ -'-..tt..:.!I_c 8 C.5 9? 7 . rl~r '. I'i\Oni -x: ~ R' \ ..... ,..0 "A ",.. ~n -27. Us-IfiA. 10 Number 1 ___ ' nn"7""''''c-/c I P. Stetl Trenapon.,...----m- fO.lre~ ·. fItIone~l R-4~Q-h?4Q 29. Con'I,nar. I 3O~ -~ Toc.1 Un" I R. T_ OUlnlttY . WI"I No. No 21. US DOT OHcrtpltOn (IncNdHtf "'''' ~ N.",.. HM.,d CIu.s.. .rtd ID NumIH" .. {(iUAUtJ(!d ~ upvuz N4f~~'!-a=;; _~44 _ .. ~AA<60 - "'7'7711""/ CWM Prof,l. Numbe, ~ ~ b. ~ I:I/we P~VAIJ A/IIJ"(~IK«IIIV. ,~ •. \ '7/11t7 1I~", ---";TTT'f"I'r- C. 1Z. ~4 .; , ;~: -:; !"- ' .... ~ ' . - ~ ': ... ; ... ; .; i H , •• . ' .~. ; . .'~,y :,.-.:. . ~:. <;"~~:. ' ;'-..- : d . \~:~B:~'~~~-).;~.j~: It CWM "'of,l. N,,~' .:~ ... ;. !.."':'.:' : ~" ; o. x~:;~;) S! • CWM P'of,le Numbe, , .,. : "~ . 'r ... .. f. CWM I',of, •• Nu",.,.r •• CWM Prof,l. Nllmbet' h. CWM Profil. N"",.,.r i. CWM Profile Number +' ~. " - .' . ' ., ;~So%>'i0 . . .. ' . .. ~ . :·-::'''' ie .. . • . '. . ~ .... .... --- ,.' :.~ .. ~ ."':. .,' ,:.5. Add;tionel.%CI'ipri~'/M'-t.'ieKilted Abcwe,c. ., ... L4.WI Lit • ~tS ... , Jtt~ T. Handling Code, fot 'lieu., L.ilted Abow i):~)Z:;~- . ~ - ewe{; I I . d. g. b. e. h. ~ .., I ~-i c. f. i. 32.~C: }d;;:r;::;ziti:njlA~~ f~»JlIiC.e6' aa/~ of Recl,pt of Materie', Oete MOftl1l Dey 'y;;;' ~ . /1 Q I o!t! I~ " ii"aDA ~'+ .~~A Form 8700'22A (3..a4) STATE OF ALABAMA (Must Accomoonv Shioment) 't~ t I Le r ' . '1 / nM.~M-n!JVUw VY M\J I ... ~1WI,"I~11 ... ,., I , (As Required By The Alabama Department of Environmental Management) .. (Fo,," daslgf'>«llo, ""/! ; n ?/nJ ! 12 ,p/~chJ 'y~""'fI'a' ) 1. Ganerelor 5 us EPA 10 Plio. ,. V, I..P , 9,8· c ,~ ,.r, ,/ ,e I ~ enecelor, H.me en" Me,ltl'jl AGel,." I.r~#}oMI) t'jI;£A,t(!8t- C""'N.Vy 100 ~~~~"".I?~ 4'A~~ A/r:~ .,fiL.l.ty .;)?JIb c?~~ • G."".lo,·$ Phone ( .::l 0/ ) ~ '7~ - ~/,ao ,.n CHEMICAL WASTE MANAGEMENT. INC. e",.lI. Flciltty AJlbema H,~_V 17 al M,le Merur 163 e",.lIl . Al.bem. lS459 , 1. US DOT 0-_1Oft (~~ SIttMwy NMM. HM."I Cia&. M41D ItIwrrItMJ No. Fo,mAp/Nov.d OMBND 2000·0404 Elp,,~s 7.3 '.8 15 2 . P.". 1 Informat.on.n . "'" 5hao~a ale" ~ 15 nOI 'IQu".d by Fed.'a' of ~ I.w. ~urnenl Numbe, 24 3033 '1 10 ,.,...,.r:, 10 . T,.~ ·, PhoNi G: Suu ","lily', ID H.~ ' ....... 205/652-9721 T,... 13, TGU' OtMim"" l W ... No. 0 1 • . [ .. : . C.NT;"'-C -ry 7'·' CWM 'rof,le Number;k,A E61J8~ : ~-~~~~~~;;;nr~~~~~~nrJ~~~~~A~~~~~ij~~~~~~~~~~~~~~ij~~~iTt-~~~'-~~~-r--t_~-- . -----j T • ~ ", ~·t o dJA!JfII~ AlA 9/1'9 II CWM P'oftle Number //(// J)~,~ , ... "- c.. 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Ift'Nmiu11On ceni1'Clllon under Sectoon 3002(bl of "eRA. I .Iao .:en .. ., ,,.., I Nt .... "'Ge'.'" ,n pIec. 10 r_..c. IhI ""ume and JOIIC.ty 01 .1'1. "-",_ 10 the dI" •• 1 "-" .',""Ined UI be __ "., ",Iet_bl •• ncs I Nt... MI.acted ,.. _1hod of ,,..Im.nl. 1I1If.1I" IIf d ...... 1 Cynlnll'f' .... 'I.b .. '0 m. """,eh Ift'ntM'DS the .. _m Ind ''''~ "v .. , 10 "umen "'11" and , .. _ .... 'onme'" ,"NMir-.~u -- ---- I s~~ 01 M.'.'lIls 01 M.'."al, 19 OIKfICNlRC:Y lno.c.alton Space Of ()pet. 101: CemhullOft of rlCllpl 01 ,., E~A "- 8700-22 (An. ".5) Pr_.srtion ... OCI5oIeI • . .. • 'to ~ III 0' ~ (Form desl9n~d f?' .;sr "" ~II!~ 1" '/;;1,"" 'vp~ .... "t~r' OM8 "40 ~OOO ()4()4 E.p.,~. 73' 86 UNIFORM HAZARDOrJS·~·d" I-:.i"rt;·~·'~·rator sU i:: A I No enillSI n ormallon,nlheSt'laoedareas WASTE MANIFEST . ...JDocumenl No IS nol reQuired by federal (Continuation Sheet) V /.if) 9 e c G S I 0 9 S-I rc~ / II"'" ""'J .Gener.1or·, N,me '.A r.r~IJ~ C' ""r.l?l(!4(.. c...,."""",;wy 3<70 -rA"~~~ Z~ t!J 7<r7o 41~A"~, A/~ .rU/.[y Q < ~ 24. Traneportar::;t comp,eny Jiiame R .... .....s:<A.. -NA r"'*Vw,~ 26. TranlClQnl B-peny flame ....cvnCD ~a." I ,..r-1"'\. Trailer Number lll'MZ; 274676 re, A4.1'-~?ttr. ~,,~ rlN- ~---.... U~E~A ,0 Humber 9g".go~9'71 L .T~."lnlf.1t DocumentJifumber CWMA Z43Q.:{3 ~ta Genii.tor', 10 ~ • -. - nn.,n""C7n Ia:T,a~.r a n)On~l Q_.ll"l;a _ ~?[l O ---T.IiIiiJIiW ... I., 28. US DOT Onctiption (Including P,.,., S/upplng "'am., Haz.,d Cleu. and ID Number W R. H .... o. a.~ A~A4_e Mt9~ e"M"D"""u •• _.,~~.tr · /.::r1~A .. ~=-;:,:::;;: ::::::-::;;;;j ~lA4' . " ....... , ..... -:_ . ~.' I! Of . :~ c.h9~ . !'. : .... '-. d~- ~" .~:_ . '~'~~"""_ ~ ... ';;\:~.-\~~~~ • CWMPro"'eNumbir ~ /d ., ... :.: .. '_ ........ . A • • .. T '.., J o -I CWM Profl'e Number . ' . I J f . t ."., .- CWM Prof"e Number .. CWM Pro','. Number tao CWM Prof"e Number i. CWM ProfIle Number 5: ~jtiona. OeIcriptlonl for Mater .. l, Lilted Abo ... IT. HIIndling Code, for WUle, Listed Above ., ~~.:- ~_ J . _".. .....,.. a . d. ~~ -. ~ .. b. e. Ir~'~ c. f . 32. SDM:Iif. II .. O:'ng .nstr\.lctlpn, end AddItIonal Informlllon • ~K.' ~"--t'"."v.r~ /M.- {//6. /,f'~./r- ~c! 'U..t~!i~ Hy' V'JP/' __ ?~ r~I''''Jt" ... 70 .#~PC'~ /t'(£.;; ~~~ ,rr,. CA'"l'-«" ~v.w~ /.va~('A'"~ ~ Reca.pt of Mat"~I' or ReceIpt of Materiel, .~~~ /cy6fY.FJ DI-+ ~ EPA Form 8700-22A (3-84) c\TATF OJ: AI ARAMA .. IM"ct A~,.. __ ... ,....... c:a...: .............. , g. h. i. Oale ---- Monrh Dey Ylle' 1 ,. 01 1 71 A c, • t ~ ". Of ~ (Form Ors'9ned I~ ' .,sr .,,, pl. ! t (, '·r.'!Ch) IvDr"",,!pr ) OMB "10 ]000 ()4()4 E 'p.,u 7 3' 86 UNIFORM HAZARDOi}S·n -I-j'r t;·(I .'~·ralor . s U c A I No ant eSl n ormallon In IneSnaOrdareas WASTE MAN I FEST .-1_ Document No IS nOl reQuored by federal (Continuation Sheet) v /.Jt) 98 c G S' / C 9 S-.l r CO() /. lew "'3.Grne rltor·s Name . A r.r£c9AkJ C' Nrn-t!4" c. .,.,.,..,,,,.:wy 3e?o .rA/L~~ Z~ ~ .,tno W~""~/ Al't!P/ rUJ'.[Y d ( " 24. Tran~.~ Company-fliame R;#~cA.-~"'~w~ 2'0. T,anapon E~n y - Hame ..o vn c-o OA ... ,. ,-~ Trailer Number R.'IHZj 274676 L :-S~le Memfest -Document Number CWMA Z45Q33 ~ . S~te Ginerator', 10 ", A#;,-~?¢ ~/~ r<rY- 25. ~£PA /0 Number ~ . ~Iat. T,anepon.,., 10- I ~~ ' P fill " . f1~ ~ 97·1 . ra~ 'a ".;one ~ 27. uS PAlO Number ~~;t.t. Tranepon.r. lO- t .-, ... nn7nn')t:7 I"1 'anec»n.,I, ,,;on~1.Q.':11.~Q_ ~?D O 2-9. Contalnerl T___ --..., 28. US DOT Duc:rlPttOn (/~,., ~ropM Shipping N.",..lfaz.rd CI.u. MJd ID Nu~r W R. N am o. a. b . 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Month D.y Y •• , • i~~~~~~~~~~:naw~tlaog.::::ma::n;t~M:-AR~~~1:Pt~odfIM~a~t.:r:ia~I.~1-~~~~~~~~~~==~==~::L-__ I I If !74ru,EiiC Lau£'!.+ lir'~2_1:?f 1 l ' 01 1 7 f B.......5 Date r~""r~ncy Indacation Spece c , L • l~ EPA Form 8700-22A (3-84) C:;TATF (\I: -At ,ARAMA tMllc~ A~~,..""",,,,,.¥,, c"": .............. , ., I In .. ,..... I..,,, '-'v ""\.Ill ~~lnl~11 ... '" . .. '~ , . ~ ., .. " / (As Required By The Alabama Department of Environmental Management) (Fat", (j~SJgn~ lor lise on e/ire (1 2 ·pirch) type_it.,.} 1 Gene'alorS US EPA 10 No V II '.P I ?,e I (J Ib 1.), II (J ~ ? I ,..' alor i Him, , nes Milling AdOI.U Zr-~ ~/t'CA~~L C"...u.y ';0() A~II~", ~ aj,. ~ Ari!bI Je.t:r~ #1"'- eJ 'N~ ~9d -~1t:JO I~/c.~ .. CHEMICAL WASTE MANAGEMENT. INC. Em«lIe FK.liry Almeml HI~ _Y 17 It MIll Mlrker 163 Em«l1e. AlIDlml 35459 Trailer Number RI'MZ 251880 11. us DOT o-a.uon ~ fIT..., ~ "'-. ,.,..-C __ .-IO "'-*'1 No ~tNlJI App'tw«! 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"QT\ .. d for uU O"~ ; re (12,p'IC h ) Tvpe"""'T .. r ) Fo,",4pp'oved OMS No 2()()1,j 0404 [oo" ps 7 31 H rw.M Pf'lnl V' I' .... UN IFORM HAZARDOUS 21 lJ~"trllor I A I ~? M.n.I,,1 - WASTE MAN'If:~ d -lDocumenl No (Continuat ioGiS"h~ V I' I) T 80 6.5'/ C ~.s I ~.ge Z",rL TnTormal.on .n the sh"ded areas .s not reQuored by Feder. 1 law. 23.Gener. tor·1 N.m I~MP C'".,E"I'C"'- ~~ .rtZ' /,"'.Lp~ £a:2P #1 '7"70 ..w"",vMC #.1 ~ ~UJ./..Y'- 9tS Trailer Number RTMZ 251880 rcYi:A fel1 ~;r3~3/ IM.S~se Gineresor', ID -' (1/ A 9«. - 1'1t%' ,. T,enlOO"a, e:ompeny Neme Rt',vu,e-.ve"AnII~ 25. USE'PA~ ' I'll. S.-e uTraNPOrter's ID ". , . ~ ~ 8 () 8 D J r;? 7 O. T,anaponee'. JihOM 26 f,antlPl.es;=compenr Neme n"~f" 1"I DII.II.It~rO 27. uS EPA 10 Numb4tt I~ ~ .. ta T,entpOrte", ' Uf . ranapone,'. iihOM~, 9.- Lf:l;Q'?/.!O 29. Cons.,nera 28. us DOT Description (Including "'OIM' Shipping Ha"... Huard Class. aflll 10 Hllmbe'~ I No Twe R. WNteNo ,If4'~,utN&!. et'2 ' d < '1 -""' ... "'c "'-V6t4'C,!If ~ •• - .~ /Va 9/n .~L7f'7 t7~~~ CWM Prvf.te Number ,tI:2 .1.'..,,1 V_ ---- "--;7 ·ltJi il;11 b. ~.fJIJfU M'Na ~V.(O NN(~"~'~~ ,,~ 'f!&- fItIW "'1' _. --. .. 'HI' u , CWM Profila Numbar AGI'I J) "K""'~ ... 3~ Co ~ -.:-... ~f . - • ..!".- • I d. - - /}~ • I' .' CWM Prof"a Nun'\ba' ~ ~...:.-~ • , 0 • a. ~3 CWM Profile Numbe' . .:.." . :: ' c: . .;. - . ... . ~ -:.: : .... I f. CWM Profile Number n;;~t~~~ .. CWM Profill Number ~~~~~1{~:'- 1'1. CWM Profile Number ~~~~~!!:? ~- '~ :' .. ~ .. , . I. ... : i; y,. . ~~.-~ ~ .- . $ . ...! .~ : ... , CWM Profill Number S . .. Additional Oescriptions for Met"~11 Lilted Above .L4 4-M,I,I..,-..$ /Y' FA( JO"'uzr6 .£, c , ,_ .,,<: " ~ . T, Handling Codes for Was_ Listed Above ~~:i:t:Y~ e. . d. ',. · 9· " ; b. e. 1'1. c. f. i. -~ & ~.rA(1-r'''''",ac CN# 7 ~ . 33. T,enapone,_· _i.cknowl~mant of Recllpt of Materi4tl, • , • • nc c; " : 34. Traneporte, 3-Ac&nowIedge"..nt or Receipt of Mllerial, T Pr~edlT~ Name IJ L L I (/taelr, /YJ vnotUrj\~ ~ '! I 35. Dl8Clapancy Indiiation Space c , L I II EPA Form R7nn."a l't...A.AI f....JIJ-- ~T A TC 1'\1: A' A D A .... .6. ( All Itri At"t""'''''''''''''''''' c:k ............. \ Attachment 3: Copies of chain of custody and sampling paperwork Berlex Laboratories (ICC) VID980651 095 March' 1 3, 1 986 t:ttAIN Ut tu:> I VU I I(~"'V'UJ J(e ce', r- -Fer £.~p C-!) INVIIOHM£NTAL 'IOTECTlON AGENCY - :'IGION It SUIVt.lLANCE & ANALYSIS DIVISION EDISON, NEW JEUEY 01117 \/rD1 ~D(,S-I OCiS" No ••• 1 Unit .ft. A •• ,eu: Berle=. 'I=- • La...bcwo...+C (' l~ S •• pl. N" ••• r ~ I Nil .... ' ., S+· (.n:>.)(. l'V,,-'l'l-'\ I~lAr\ds De.enp'i .... 1 S •• pl •• ~ LtD .-1. ~,~ ~ ... 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Iy: •• Iin'lviah." ay: •••• i".d Iy: I.U"'1"i,h.d Iy: I ••• i"." Iy: Ti.. 0.,. ....... f., Ch ...... f C.".d" Ti.. Dot. 1_ ... f.r Ch ...... f C ..... d" Ti.. Oet • a ...... fM Ch..... .1 C" ••• d" n.. 0.,. a ....... , Ch ...... f C .. ".d" ........ i ,....... .- .- ,~, ~. :.- i ~ t i: - .. t., .. _ ..... r-! t·· ,-. ~ ' "",' ...... ~, ... ~ i t;, p, ? i J_r \ ~ £=-~ . -' .. t .. = .. - • 1" f j 4 , ~ N •••• f u .. it ..... A44,.u: b(" I( « IHYltONMENTAL ,tOTECnON AOENCY - HOION II SUIVEILLANCE & ANALYSIS DIVISION EDISON. NEW Jllny 01117 . (' . ( , r. <,:.., --' L I'" LC'o f C' ..... c.; • v'l. , '" "r:- V j D"( f {!r'".>Jr 9~ DeKripti .... S •• ,I •• ~.., .. t~, .. I • / I_f-.. I (It 1'", - j -I'~ , : (~ ... r ~ C;;. 1Ior" , , 1'( c.· 1 , , - .', r i". -- ", j r ~ '" '/" .. .. , . - ,.. ,. i..>" (\.;-..: ~ 1"\ ~ ... r-I \.1 • , \ J I r-' -Ij.., 'P't.(, ....... 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Iy: I TI •• I Oat. ....... fo. ClI ...... f C.sto"y n •• Dat. a_ •• f •• e ...... of C ....... y •••• N •• I I FIt:LD UA I A ::iMI:I: I ENVIRONMENTAL PROTECTION AGENCY· Region II, Edison, New Jersey ENVIRONMENTAL SERVICES DIVISION PrOject Nam&R -- ' . - ' .. - '_. -, _. ".., l f ~ • ~ ..,... Samples to: Collector(s) I • (f Affiliation U· S E. .R. jr-~8a::-C-t--rI~B-iO-"'I-~----Ot-her-"""1 SAMPLING METHOD (Circle) lOMS CODE __ .;...0'"\ _____ _ ~ DATA BASE CODE_--&.H~ ___ _ STA. TYPE CODE _--'f ___ _ Dredge Ponar Seine Trawl Dipper Kemmerer Niskin Net Trowel Cream Automatic Station No. I ~Zl~ ~F It) I £,1 ~I 16\9\?1 Sample Depth (Ft.)IFac. Loc. Code Other ______________________ __ SUBSTRATE TYPE (Circle) <:;:;;;,;i> 011 Biological Aqueous Sludge 1311101 a Lab Number ; Solvent Extract Other ( 085251 Type Of Sample Sample Source Type (Circle) Grab Composite landfill Industrial) ............ ' Time I Space J Effluent Plastic Jar ~, D, J Drum Process Stream " - ~ Acid Rinse Test Well Holding Pond Solvent Rinse: Deptt:l: Drum Cubitalner e.~,.rid) Other: Acetate Core e::~ Other (Specify): Top Collection (Ending) Date I rire., I djo~ I fjY31 Ending Time (2" Hr) 11\311j8"1 Foil Cap Middle I Effluent"""'" ,..1 '. Other Bottom Sludge lien Beginning Date I I r I jO I Day I tak.- Acid Tank Stream Solvent Other Pond <=> Ocean Wells Estuary Dry Ice Monitoring Ambient Production Other Drinking Beginning Time (2" Hr) I I ) I l .--- pH [ . ......,.-, ~l -r---II , 'ate Cond. (uMHOSlCM) I , I I I I I Sallnlty(Of •• ) Remarks: r -:-::. 1\ . 1 _ qo 1""(\\. V,t\.\~ "t"1.)f ,0 ~~:"I~ c; cy U C" t ~'c. <$5 j,Q r +Ot' t-.J\.IQA A...In45 'S I - '\ v 0 t''' 5 \ c. 'S 5 J.ct r ..f.o r ?c..B t:V'f)a..{ '1 S f.5 \ - C, \.y'". r -t c:~ le-."S~ J c. r faY' Y'T'1 c.. fa (~ a I1C~' '1 S"S . . : .J . 'I. L J... I;,..~.··-" (' ,.."It ,. c.. ( .... -,...i'"::><---". c: .", r;;(-t:- o 'rl' ", -, - iii <So ","P'<"''':. f ~c cf I I 1'1 Sample Split ~ o No to. ( ~ \ I t·... I, If Yes With Whom? ( eY\ f"Y be" < ' Receipt ~ Yes 0 No Fonn: FTB RP[).11..a:z-2 ~"'O"t'~""'_,::;>;~ FIELD DATA SHEET ENVIRONMENTAL PROTECTION AGENCY· Region II. Edison. New Jersey ENVIRONMENTAL SERVl(i.i;~ DIViSION ~~" Project Name B t: r I t: >c Lt'.< \.;70' D.~f·C" lSi. C ro~'( yr Samples to: ~~, 't7. 'eWColiector(s) ( I ( ~ Affiliation U ~ t:::... 'Pf1 I Bact I Blo I ~ Other I Y;;;;);#:r SAMPLING METHOD (Circle) (Y\ LDMS CODE Station No. Kemmerer Dredge Ponar ~ H Ig~1Bilol~15111~1~~ Niskin Net Seine Trawl cket DATA BASE CODE Trowel Cream Dipper ST A. TYPE CODE 1= Automatic Sample Depth (Ft.)IFac. Loc. Code ~ Other 131 \ 101 , I ~i~"D SUBSTRATE TYPE (Circle) Aqueo~ Sludge Oil Biological Lab Number Solvent Extract Other ( ) I 085252 I BOD - Seed Supplied DYes o No Source: Type of Sample Sample Preparation (Circle) Sample Source Type (Circle) Grab . Composite Contaill!tr Cleani", Procedure Landfill Industrial I ~Time I Space I ~Iassja!) Q!tergent Wa~:.:> Leachate Effluent - . PfaSflc Jar i ~te( Rinse ) Drum Process Stream .Collect.i()r1 .. ~ndlng) Date ~~lal Acid Rinse Test Well Holding Pond ~ I ~O~··l~:3l POA .;ral J Solvent Rinse: Depth:·' Drum Cubitainer Acetone Other: Waste Pile ®~;J Ending Time (24 Hr) Acetate Core Municipal Treatment ~ ~thylene Chlor~ Storage Tank Influent I J 1.31 ~st Other (SpecITY): Top Effluent-CI eftOnC8P Foil Cap Middle Effluent·Non CI Beginning Date Other Bottom Sludge J Yr I Mo I Oay I Truck Ambient - I I I Preservation Drum Lake Acid Tank Stream Beginning Time (24 Hr) Solvent Other Pond I I I I I Chemical Ocean @t~ Wells Estuary pH Dry Ice Monitoring I I 1 I I Ambient Production Other Drinking Private Sample Temp. (-C) I I I I I Sample Location Description: . $ah'r> P J £ .fr-t.T'n1 . $ +r c ~ (~v-t) be ~ I nd pIc, J11 - 00 (mgn) ( I a 10 W~S+t!' f' t .s.c. c p~ cr- orc.A....) I I I I I ~v y .f...c, r C -1-0 I D" Cond. (uMHOSlCM) I I I I I I I SallnltyW •• ) Remarks: I I I I I Cl: J.f 0 h'l ( \II A 1 ~ -h:,... V 0 A ~ ~ 5" I.S ,- '1uar i :J Ilt~ Jt)1"'~foY ~O/) c;LA"\~~i ~ Sample Split \ - 4 v 0 ' -t ' ~ I u ~ J (;) t f.o r" I ..Ice a-ncd1 SI S ~es o No If Yes With Whom? F6 , i /, b quo ,,-/ c f (l 5.6 j t2'" fo r yYlC lett:. OA'1Ct-':J5 / : /i r r . --- j.:J '- <,..,.. c .............. --:. ....... ". <' c-. ~ r ,.. C"' f) Receipt j4 Yes o No ,J;j )...J ... \ ~ . t. ~ ( f C \ ' ( i. cf.... I '" ~ rC :. L . . I ~o..- P (-::. . (,. . Form: FT8 RPO-11.Q·2 •• ENVIRONMENTAL PROTECTION AGENCY - Region II, Edison, New Jersey ENVIRONMENTAL SERVICES DIVISION Project Name L;t":.' Ie. 'IL __ c' PP' RAP' Ie:. -- f ..,j' - • ..-" ~ ~ ~~ Collector(s)' . r e SAMPLING METHOD (Circle) Kemmerer Dredge Ponar ~;V LDMS CODE yY\ Niskin Net Seine Trawl Bucket DATABASECODE __ ~t1~ ____ __ - Trowel Cream Dipper STA. TYPE CODE _---.lrL--__ __ Automatic ~her ________________________ __ SUBSTRATE TYPE (Circle) Aqueous (S!dlme§) Sludge Solvent Extract Other ( Drum . Metal ~ I .. _.- . · ... n I Test Well Depth: Cubltainer Acetone Oil Biological Process Stream Holding Pond Drum ~ ~ I I MUlllvlPill 1."111111"111 eth\ef;e Chi; StnrAnR TAnk InfluAnt Other (Specify): SOlvent ___ _ Chemical ___ _ ~ Dry Ice Ambient ~her ______ _ Effluent·Non CI Top Middle Bottom I ·· I Sludge Truck Ambient Lake Stream I ~=! =~I:e:n WellS Estuary Monitoring Production Drinking ?rlvate Sample Location Description: - $o.V'\"\p k .fr0Y\'"\ 'S+r~(9V{) bch'''''of ?r~, d r a, .-"\CIt'"\<- , • .., ~ c' I ~cka t'1~ 0 YC:~ SVY +0 (" e. --tt:. d.. W,"01C. 1D ..... c. t." '.i Remarks: .2 - "-I (..> ~,. V I~ I ~ 4 ..... 70/\ o..J'ha(~::.; ~ ( _ C uo .. 1:" ~("'!..;. ~ D r' -f..c:,~ 1JV(j A ~::" -:. I - ~1 U G r 1 (, ( c, ': S JC::H-mt=t. 8 Cl V'OJ 1 ~ I .~ • )- ~ uC .. Y-1 ~ G.!..S jet rfur rnc-le-{s ~s,~ (, "c-4 ". ,) \_ .Y. I c· ,~ G SfC r I l-. c. "~p~"" r-' c"'< • 1'\ '("{t' I ;., , I s ~ f.' C ~ • f (" r d F«m: f"T8 "PO-"~·2 Samples to: I Bact I Blo I~ Other Station No. I q3f~,I~lol J~,lol'f l;f Sample Depth (Ft.)fFac. Loc. Code I:?>" loIG?! Lab Number 085253 Type of Sample Grab Composite ~ Inme/space I Collection (Ending) Date Ii '" lojOa\ ~iY:J Ending Time (24 Hr) 1/141~lol Beginning Date y I jO r-,y I Hr) pH I I I I I Sample Temp. ("C) I I I I I DO (mgll) I I I I I Cond. (uMHOSlCM) I I I I I I I Sailnity(%.) I I I I , Sample Split D""fe. 0 No If Yes With Whom? Fc-r.I'''1 ~r~IIt:;(l< Receipt CJ-"t'IS' 0 No - ... ---- -.-~ - . ~. ':- t'1t:LU UA I A ~nl:l: I ENVIRONMENTAL PROTECTION AGENCY· Region II, Edison. New Jersey ENVIRONMENTAL SERVICES DIVISION Project Name f· c.. ( l Cc \...a bl.: ( A! 0 r ,'c -... I Si. r r" 11. V..l.- Samples to: Collector(s) Xt', (l Affiliation (2 St.? A .1 r ~Ba--:;'C-t"::"'I'::"""'B:-I-o--"-C-he-~-'--ther SAMPLING METHOD (Circle) lDMSCODE m Kemmerer Dredge Ponar ~ DATA BASE CODE-.-!:! Niskin Net Seine Trawl uck.et Trowel Cream Dipper ST A. TYPE CODE F Automatic Other __________________ _ SUBSTRATE TYPE (Circle) Aqueous <!?im~ Sludge Oil Biological Plastic Jar Metal €~ Cubitainer Acetate Core Paper Cap Solvent Extract Other ( Drum I n_._ .. · .. n I Test Well Deptb: Effluent Process Stream . - Holding Pond Drum Other: r:L~.':'" ~--:-=---:-_-:-_-; ~ ~ Effluent·Non CI Other ____ _ Acid ____ _ SOlvent ___ _ Chemlcal ___ _ ~ Dry Ice Ambient Other ____ _ 1-' ... I Sludge Truck Ambient Lake Stream Pond I I Ocean Wells Estuary Monitoring Production Drinking Private Sample location Description: ( ~po~'~ .t;;~ <;..v(.(occ 4-0 L...a b U-?C'!:. +~ -r 1+ t::l" e<D- 3 +-c,.e~ Remarks: ;;>_ 1.../0 ...-nt. Vlol~ .+o~ -Po A ~~'3 ,_ Cot UOM ff.~S~ J&t r -f-o,. I\:)voA C,/.A'\a-Lt~t·-S \ _ ~ u a r -{ ~ 16 s~ JG1 r: +O-r'-pc.e O-N'\ ~s I ~ 1_ ~ ua .... 1 '-./ ,Jio<;.~ J Dr . ...f-o-r tnt: h:t':$ s("~ t J f . \ 6.. r ~ p <. ~ ( ( c ~ p (C ,', ( , • 1 C I C'. t P. I' ~:'d~I_,~ P k:. f,.. r d. \ , ! \ t' C \ Fonn: "" RPl).11-C.2 Station No. Ivl:IJ li~ ~ 01 ~51' klql it Sample Depth (Ft.)IFac. Loc. Code 131~lolol Lab Number 085254 Type of Sample Grab Com~slte 5 4/flme/ Collection (Ending) Date I ~ 7 c., I Ojo 31 rjY ~ I Ending Time (24 Hr) 11/ !5fdst Beginning Date I I r I jO I Day 1 Beginning Time (24 Hr) I I I I I pH I I I I I Sample Temp. ('C) I I I I I 00 (mgn) I I I I I Cond. (uMHOSlCM) I I I I I I I Sallnlty(%.) I I I I I Sample Split ~ ONo If Yes With Whom? Fe. c ; I,'+. I c.e"'71 hd ct.,- Receipt O~ 0 No .- - ---~. . -;.~- FIELD DATA SHEET ENVIRONMENTAL PROTECTION AGENCY· Region II, Edison, New Jersey ENVIRONMENTAL SERVICES DIVISION PrOject Name &7t(-~ Ln be r ; .. .f2:".c <, I -S -+ . (to- '" \IT. Collector(s) t'( . ( e Affiliation U $ E. RA. SAMPLING METHOD fCircle) Kemmerer Dredge Ponar ~ Niskin Net Seine Trawl Bucj{et LDMSCODE Oi DATA BASE CODE H -----:=----- Trowel Cream Dipper STA. TYPE CODE F Automatic Other __________________ ~ ____ __ SUBSTRATE TYPE (Circle) Aqueous ~9 Sludge 011 BiOlogical Solvent Extract Other ( BOD - Seed Supplied DYes o No Source: Sample Preparation (Circle) Sample Source Type (Circle) Co.n1a.iner Cleani.c.a Procedure (?Iassj!!:) Plastic Jar MetaL <POA Vial:> Landfill Leachate Drum Test W~II Depth: Other: Cubltainer Acetate Core Paper~ @onp~ Storage Tank FOil Cap Other _____ _ Preservation Acldl ____ _ SOlvent ____ _ Chemlcal ____ _ G"&i~ Dry Ice Ambient Other _____ _ Sample Location Description: Top Middle Bottom Truck Drum Tank Other Wells Monitoring Production Drinking Private (' " :10 ~ I +c .f.r Cl'"'>-"-n ~ -' f·+.. C. LA.-"'; VL-'G S~ ~ '"P,t· ore CAo.. Remarks: ~ Industrial Effluent Process Stream Holding Pond Drum Waste Pile Municipal Treatment Influent Effluent-Ci Effluent-Non CI Sludge Ambient Lake Stream Pond Ocean I Estuary ~ ~ct- ;;:l - LJ 0 Y""l I. V , td c; fo t' 1>0 A aA"'I Cl..~.!. is ! _ 1L.>6t{ /4'1"t~ Jar..f.o.,. NVO'/1 L!I/Yl~~;S I - '1 LJC( t ,~/-f(t ~ ';.. f r /-z... ~ ?Ce, ~ Q. 't:.' S . I - r-C; \.) CU t J ~1 ( c;. S 5 jar ~. rY"l~ -.b ~ ~ ~J..~t; '.; tJv'~ I t',,~,.t" .:J€ 'C·- "'i-'o,,' c( . t("r' 'c. f. t'-r'c-t A , \ s~1' (':;. ,(, ~ c:J Form: FT8 RPt).11-82·2 Samples to: Bact Bio Cht?3' Other Station No. IViII~91~lol,lsl/lol9Id Sample Depth (Ft.)/Fac. Loc. Code 131~lo III Lab Number 085255 Type of Sample Grab Com~slte S I ~nmel Collection (Ending) Date 18,r,.1 oj 031 ,i31 Ending Time (2" Hr) \,lSlI/la/ Beginning Date I r I jO I Dt y I Beginning Time (2" Hr) I I I I I pH I I I I I Sample Temp. ("C) I I I I I DO (mgll) I I I I I Cond. (uMHOSlCM) I I I I I I I Sallnlty(%.) I I I I I Sample Split !!"ves o No If Yes With Whom? F"'PI ~ ,·.L.1 ~~~oclz:;, Receipt O!"'Yes o No " - -.-- ---.. - -.~ ~ ;:SF..r:;: ;?, !i'~ F:ElD DATA SHEET ENVIRONMENTAL PROTECTION AGENCY - Region II, Edison, New Jersey i;i'J'!lRONMENTAL SERVICES DIVISION ProjectName . 6cc tel Lr; hC>r'(",h""c .. ,5+ ('0.1( VI. ColleClons) \/" " Affiliation U·~ £. EA. SAMPLING METHOD (Circle) Kemmerer Dredge Ponar Niskin Net Seine Trawl Trowel Cream Dipper Automatic ~ &. I,,,. Manual Buckel LDMS CODE (Yl DATA BASE CODE __ H ___ _ ST A. TYPE CODE F SUBSTRATE TYPE (Circle) G;o;) Sediment Sludge 011 Biological Solvent Extract Other ( BOD - Seed Supplied DYes o No Sample Preparation (Circle) Container (!!ass Jar::S Plastic Jar Metal Acetate Core ~ etlon 01 Cap Other ____ _ Preservation ~ ti R1'" 2 SOlvent ___ _ Chemical ___ _ ~ Orylce Ambient Other ____ _ CleanlJ1g Procedure r~rg~ ter Bm Acid Rinse Solvent Rinse: Acetone tf8x a n'i) @ethYlene ChlOl'Id0 Other (Specify): Sample Location Description: 0", ~ I +~ U-' f!: I J Remarks: Source: Sample Source Type (Circle) Landfill Industrial Laachate Effluent Drum Process Stream Test Well Holding Pond Depth: Drum Other: Waste Pile Municipal Treatment Storage Tank Influent Top Effluent-CI Middle Effiuent-Non CI Bottom Sludge Truck Ambient Drum Lake Tank Stream Other Pond Ocean Wells I Estuary Monitoring Production Drinking Private ....;. L/ D Y?'l I. V f r~ I! -fe.x Tc 1\ a na.1t.t.::..' s .::.> _ I /. IT" bo + f Ie::. h,y NUO /l ~CL0::.,.; Samples to: Bact Bio I Ch~ Other Station No. I \IIi I~ GI~lol(.lsl/1 0\ rid- Sample Depth (Ft.)lFac. Loc. Code 131Dlo101 Lab Number 085256 Type of Sample Grab Composite F1 Time I Space I Collection (Ending) Date I %7~ 16j°.3I,Dj'3l Ending Time (24 Hr) /,I,,/o/Si Beginning Date I ,r I jO I jY I Beginning Time (24 Hr) I I I I I pH I I I I I Sample Temp. ('C) I I I I I 00 (mgn) I I I I I Cond. (uMHOSlCM) I I I I I I I Sallnlty(%.) I I I I I Sample Split Mea 0 No I /1 k: r bo-l-l If' £, ("( ~ ah7O-. .LLt" I ~ /1 f · J .... )r"./\.'"I( /--:,-" I If Yes With Whom? r 1\ (""Y) C I..- .., I f CJ I y-. ( r fz> of' f" ..; - u..~ .'£' .1,;, C~~nl("C, LVI fINO::.1u r;H .~~ . J Receipt rt"Yes f c- (o);~~re.. . 4t o No r - , ! . ( '. ~ I) Ii .s O:;:I'-;'1~ =-' ,r cd" 'c. '. , ., '( , , Form: FT8 RPO-11-82·2 --.~ TAT-02-F-05356 community Relations Plan Virgin Island Chemical Company st. Croix, u.s. Virgin Island Prepared By: Jeff M. Bechtel Mike Mentzel Weston/SPER Division Edison" New Jersey- 08837 / Prepared For: nc~g Kodama, ose Response and Prevention Branch, U.S. EPA Edison, New Jersey 08837 Date Issued: July 10, 1989 RELAT PLAN I. Background community Relations Plan Virgin Island Chemical Company st. Croix, u.s. Virgin Islands A. Site Description/History The Virgin Island Chemical Company (VIChem) site is located on the Islands south side. The site is situated on Route 66, approxima~ely 0.5 miles due north of the Alexander Hamilton Airport. The site covers approximate~y 3.5 acres and is bordered to the north by an intermittent stream that originates on the north side of the Island and discharges into the Carribean Sea. .~ / A number of busihesses are located adjacent to the site and several residences are within one-half mile of the facility. In addition, several well fields are located in the vicinity of the site. The st. Croix prison is located one-quarter mile downwind from the site. Presently occupying the site is the company VIAG Fuels, Inc. VIAG utilizes some office space in the main building and also has ethanol stored in four of the above ground tanks. The principals of the firm plan to begin an alcohol dehydration project on site in the near future. The site .is uwned by Charles H. Steffey, Inc. On May 1, 1969, Steffey leased the property to Houston Chemical ~ndustries, Inc. Houston Chemical assigned the lease to Caribe Chemical Company, Inc. (subsequently known as Pierrel America, Inc.) on March 20, 1972. In June 1978, Pierrel America assigned the ground lease to Cooper Laboratories, Inc. (Cooper). On October 30, 1979, Cooper assigned the lease to its subsidiary, Island Chemical Company (ICC). On November 1, 1979, Cooper sold all of the stock of ICC to the predescessor of Berlex .. Laboratories Inc. (Berlex). On September 14, 1984, ICC sold its assets to VIChem. The site~consists of a main warehouse building including offices, reactor and centrifuge buildings, and twenty-two above ground tanks. Also on site is a kennel for guard dogs and a house trailer where the kennel operator resides. B. Quantities and Types of Substances Present Two hundred and twenty different lab chemicals are present in numerous containers stored in the on-site laboratories. Another sixty-six chemicals are stored in numerous drums throughout the site. C. National Priorities List Designation Th3.s site is not on the National Priorities List. II. Threat A. Public Exposure An imminent hazard from direct exposure to chemicals through contact, ingestion, and inhalation exists for persons who are on- site. All personnel have free access to the laporatories and drum storage areas. Some of the persons who visit the facility or live there have no knowledge of the hazards posed by the chemicals. This threat of direct exposure for the general public has been reduced due to the 24 hour site security maintained by VIAG and the kennel operation. Incompatible materials are stored in close proximity to each other posing the threat for an adverse reaction, fire, or explosion. Loca: industries, residents, the airport and the prison could be affected by airborne toxics. Groundwater and surface water contamination is also possible via chemical.releases. Chemical releases into an intermittent stream have been documented. contaminants have .also"been discovered in a well field adjacent to the site. B. Evidence of Release Bulging drums, empty drums, puddles of chemicals, and documented releases have all contributed to the evidence that materials are being released into the environment at the V~Chem site. C. Previous Actions to Abate Threat Limited clean-upand~soil excavation has been performed by Berlex, a potential responsible party (PRP) , under a RCRA enforcement action. Berlex is currently finaliizing a scope of work for a remedial investigation/feasibility .. study addressing soil and groundwater contamination. 2 III. Proposed Project A. Objective The objective of this proposed action is to mitigate the exisiting threat to the public and the environment posed by the substances foud at the Virgin Island Chemical Company. To accomplish this objective, it is necessary to remove and properly dispose of all containerized and spilled material at the site. B. Objective of the Community Relations Plan 1. Make available accurate, understandable information to interested local citizens, elected officials, and the media • . ( 2. Integrate the local government, state and federal responses. 3. Assist public acceptance of the chosen response action. 4. Enlist the assistance of local officials as needed. The information and groups Ior whom the plan is aimed are: local citizens, citizen groups, school principals, local businesses, elected officials, local, state, and federal agencies working in association with Region II EPA. The information will be~upplied by EPA's Office of External Programs (OEP) with the cognizance of the Office of the Regional Administrator. 3 C. Community Relations Activities Date(s) 9/13/89 Prior to start of removal action Activities 1. Meeting with state and Local officials 2. Press release ;- 3. 4. 5. .;< Fact Sheet Briefings Public meetings (As neces- sary or upon re- quest) objective To discuss community relations needs To brief !.o::::al coItlIi1unity and press. Provide community with information _ on progress of . - the action To provide information for affected/ interested public on activity at key decision points To inform :.state and local offi- cials,about on- going "develop- 1llents at the site To discuss the need for response to and rev.iew.of key decision points ,.explain the cleanup method "and respond-to concerned residences Staff OSC OEP Rep TAT * OSC OEP Rep OSC OEP Rep OSC OEP Rep OSC OEP Rep *TAT~~tands for the U.S. EPA authorized contractor, Technical Assistance Team, Roy F. Weston, Inc. 4 D. List of Key Officials and contacts: Federal Agencies EPA Region II Response and Prevention Branch - Doug Kodama - John Higgins EPA Office of External Programs - Margaret Randal - Rich Cahill - Herman Phillips - Lillian Johnson Federal Officials u.s. Delegate to Congress .~ - Ron DeLugo .... .. st. croix« U. S. VI Agencies st. Croix Department of Planning and Natural Resources st. Croix, u.s. VI Officials Governor Alexander A. Farrelly .Local Officials Phone (201) 906-6905 (201) 906-6614 (212)'264-4913 (212) 264-8504 (212) 264-1044 (212) 264-2515 (809) 774-4408 (809) 773-0565 (809) 773-1404 'Commisioner Alan Smith (809) 774....:3320 Fire Department (Grove Place) (809) 778-2410 .Police Department (Christiansted) ,( 809) 773-::~530 Media The Daily News Associated Press st. Croix Avis WSVI TV Channel 8 WTJX TV Channel 12 5 (809) 774..;;.8772 (809) 776-2~49 (809) 773-2300 (809) 778":.5008 (809) 774-6255