Letter to Ms. Sherrel Taylor-Domville, U.S. EPA, Region II, Emergency and Remedial Response Division (ERRD), from Mr. Jason Schindler, Associate Geologist, Harding Lawson…

Collection: Federal Reference
Sub-shelf: EPA SEMS (Superfund, Region 2)
Kind: Government Report
Island: St. Croix
Date: 1995-04-07
Pages: 432
Text: Native Text

Download the original document · Plain text (TXT) · Browse the archive · How this archive works

Original source: https://semspub.epa.gov/work/02/115542.pdf

SHA-256 e59d1d9b11f78e0dd252a5b2899bee8e738eda4b8a0208309772316dbd819dac

Re-using this document

CERCLA administrative record

Our description, tagging, arrangement, extracted text and machine transcripts are released under CC0 1.0. We assert nothing about the document itself.

Archive identifier LF-e59d1d9b11f7

Document text

Harding Lawson Associates April 7, 1995 29872 06.1 SDMS Document 115542 Ms. Sherrel Taylor-Domville United States Environmental Protection Agency Section II Emergency and Remedial Response Division 290 Broadw^ay Newf York, New York 10007-1866 \ Results of Soil and Initial Groundwater Sampling Island Chemical Company, St. Croix, U.S. Virgin Islands Dear Ms. Taylor-Domville: Enclosed are the raw data for pyridine analyses performed on the subject samples. Analyses were performed by PACE Incorporated Environmental Laboratories. These raw data were not included in the data packages forwarded to EPA on April 5, 1995. These data are subsets of PACE report groups 95010, 95020, and 95022. No pyridine data were generated for report group 95026. Harding Lawson Associates is currently validating these data. Until data validation is complete, all results should be considered preliminary. Please call me if you have any questions. Yours very truly, HARDING LAWSON ASSOCIATES y-- Jakon ScEindler . Associate Geologist •iMS\skb \WORK\29872\01\EPA-011.LET Enclosures 300257 Engineering and Environnnental Services 131 North Third Street, Philadelphia, PA 19106-1903 215/627-4505 Fax 215/627-4250 A Subsidiary of Hardin/; Associates • Offices Nationwide j^'yz.Qi^ ENVIRONMENTAL LABORATORIES April 5, 1995 Steve Bmckner Harding Lawson & Associates 131 North Third Street Philadelphia, PA 19106 Dear Steve: Please find enclosed the pyridine analysis supporting raw data for Report Groups #95010, 95020 and 95022. We apologize for the omission of this raw data in your original reports. If you have any questions, comments, or concerns please feel fi'ee to contact me or Molly McGraw at (504) 469-0333. Sincerely, Elaine Wild QA Officer c: QA Log #2255 Mike Phillips Harding Lawson & Associates - Denver 300258 U0ilBp!iBAqLP9l9ns«*«a 161 James Drive West, Suite 100 SI. Rose, LA 70087 TEL: 504-469-0333 FAX; 504-469-0555 An Equal Opportunity Employer • Data Subject To Validation 300259 '•SI .t MASS SPECTRUM 11/09/94 9:26:00 + 8:33 SAMPLE: DFTPP 244-92-PERF CONDS.: RTX-5 0.25MM X 30M l.OUM 45/4-3251220 «512 TO #514 AUERAGED - #585 XI.Qo DATA: BP110994A tt513 CALI: BP110994A #1 IHST B BASE M/2: 198 RIC: 14672. 100.0-1 M80. 2480. I M< .c DATA: BPl10994A #512 CALI: BP110994A #1 100.0-1 RIC 11/09/94 9:26:00 SAMPLE: DFTPP 244-92-PERF CONDS.: RTX-5 0.25MM X 30N l.OUM 45/4-325e20 IN'-J B RANGE: G 1.. 700 LABEL: N 0. 4.0^_QUAN: A 0.. 1.0 J Q BASE: U 29.. -J SCANS 495 TO 54= RIC I a t 51 ^ . o 3 CO o o to o\ M i l z 49; 500 582 50g 505 50? 509 J I XiGrM. )V3 • J i i j L 52S 534 500 8:20 510 8:30 520 8:40 530 3:50 53S_ 541 cr .^ l-l 9:00 •-.d:-: SCAN TIHE l i i J f 100.0n 184 21 P, '?-. ^ I C n 51 ^. o 3 DATA: BP110994A #512 CALI; BPlie994A #1 RIC+MASS CHROMATOGRAM 11/09/94 9:26:00 SAMPLE: DFTPP 244-92-PERF CONDS.: RTX-5 0.25MM X 30M l.OUM 45/4-325(220 INST B RANGE: G 1.. 700 LABEL: N 0. 4.0 QUAN: A O. l.O J O BASE: U 20.. 614 SCANS 600 TO 700 LO O O to to 184.055 ± 0.500 625 21504. 603 607 625 629 635 E42 648 65: • - , • I M - • I I I II >JO 665 600 10:00 620 10:20 640 10:40 I 660 11:00 570 S?? 631 6S5 689 c'db 6S0 11:20 7Liy ^CAN 11:40 TIME Mass List n/09/94 9:26 Sample: DFTPP • Conds. #512 39 443 Mass : RTX-5 to #514 Data: BP110994A 00 + 8:33 C a U : BP110994A 244-92-PERF 0. 25MM X 30M 1. OUM averaged - #505 XI. 00 513 1 45/4-325^20 O. 00 7. RA Inten. Minima Max ima Mass Min # Inten: 0 •/. RA Base RIC: m/z; 198 14672. INST B 0. Inten. 39? 50? 51? 52? 57? 69 74 75 76 77 78 79 80 81 93 98 99 101 107 110 111 117 127 128 129 141 167 175 179 ISO 186 187 196 198 199 204 205 206 207 217 221 224 225 227 244 255 256 274 275 276 S S s s s s s s s s s s s s s 5 s s s s s s s s s s s s s' s s s 9 s s s s s s s s s s s s s s s s s 3. 19 7. 10 31. 73 1. 05 3. 55 41. 09 2. 94 5. 48 1. 17 41. 61 2. 86 2. 26 1. 17 3. 47 3. 31 2. 78 2. 42 1. 13 9. 88 22. 38 3. 59 4. 68 45. 56 3. 55 14. 40 2. 14 OS 41 54 13 9. 44 1. 53 3. 71 100. 00 6. 41 2. 62 4. 35 19. 44 2. 66 4. 48 6. 81 9. 27 1. 53 3. 23 7. 58 37. 30 5. 24 2. 14 21. 17 1. 94 5. 1. 2. 1. 79. 176. 787. 26. 88. 1019. 73. 136. 29. 1032. 71. 56. 29. 86. 82. 69. 60. 28. 245. 555. 89. 116. 1130. 88. 357. 53. 126. 35. 63. 28. 234. 38. 92. 2480. 159. 65. 108. 482. 66. 111. 169. 230. 38. 80. 188. 925. 130. 53. 525. 43. 296 365 423 441 442 443 S S S s s 3. 79 1. 33 1. 98 5. 32 44. 76 8. 19 94. 33. 49. 132. 1110. 203. 300263 Data Subject To Validation GC/MS Tuning and^Mass Calibration DECAFLUOROTRIPHENYLPHOSPHINE Case Number: Laboratory: GULF Contract: Inst ID: B Sens Date: *ll/09/94 Sens Time: 9:26:00 Lab ID: BP110994A Cali Date: 10/02/91 Analyst: JAM Data release authorized by: M/E Ion Abundance Criteria Spec # 51! 51 30 to 607. of mass 198 31.73 68 less than 27. of mass 69 0.00 ( 0.00) 1 69 mass 69 relative abundance 41.09 70 less than 27. of mass 69 0.00 ( 0.00) 1 127 40 TO 607. of mass 198 45. 56 197 less than 17. of mass 198 0.00 198 base peak, 1007. relative abundance 100.00 199 5 TO 97. of mass 198 6.41 275 10 TD 307. of mass 198 21. 17 365 greater than 17. of mass 198 1. 33 441 less than mass 443 5.32 442 greater than 407. of mass 198 44. 76 443 17 TO 237. of mass 442 8. 19 (18.29) 2 1 - value in parenthesis is '/. of mass 69 2 - value in parenthesis is 7. of mass 442 300264 Data Subject To Validation DATA FROM FILE: BSl10994A SCANS 363 TO 1103 ACQUIRED: 11/09/94 9:48:00 CALI: BSl10994A #1 SAMPLE: SSTD050 290-02-SU25 CONDS.: RTX-5 0.25MM X SOM l.OUM 45/4-325520 INST B . ' S| J tn c TU ft 400 _t 6:40 600 . 10:00 700 . 11:40 800 13:20 900 . 15:00 :< 1000 . OIK. So o i f ml I I -• 100.07. ( 61888.) ;S50 2-FLUOROPHENOL 0.6 (SS-5> tnOQ D1-1..4 DICHLOROBENZENE <IS-1> €575 1.2-CL2BENZENE-D4 0.4 (SS-8) M ^ ^ D5-NI TROBENZENE 0.2 < SS-1) d ^ t 2 A, bTk I BROMOPHENOL OBi •^MO D3-NAPHTHALENE <IS-2) CS25 2-FLUOP.OB I PHENYL 8.7 <SS-2) •^i50 DIO-ACENAPHTHENE (IS-3) ClgQ Dl0-PHENANTHRENE (IS-4) CS30 D14-P-TERPHENYL 8.5 (SS-3) ^ •rr. CD ' • * « > DATA FROM FILE: BS110994A SCANS 1103 TO 2012 ACQUIRED: 11/09/94 9:48:00 CALI: BS110994A #1 SAMPLE: SSTD050 298-02-SU25 CONDS.: RTX-5 0.25MM X 30M l.OUM 45/4-325520 INST B 1200 -I 20:00 1400 _ 23:28 1608 . 26:40 a % Z\ 1800 . ^ 3 0 : 0 0 51 ^. o 3 mi 1 I -• 100.0:: ( 41664.) XI70 D12-CHRYSENE (IS-5) CO O o CI75 D12-PERYLENE (IS-6) 99300£ Quantitation Report File: BS110994A ^ Data: BS110994A. TI 11/09/94 9:48:00 ^^ample: SSTD050 290-02-SV25 ^PEonds. : RTX-5 0. 25MM X 30M l.OUM 45/4-325^20 Formula: X X X Instrument: B Submitted by: Analyst: JAM INST B Weight: 1. 001 Acct. No. : AMOUNT=AREA * REF AMNT/(REF AREA * RESP FACT) Resp. fac. from Library Entry No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 Name CI30 CI40 CI50 CI60 CI70 CI75 CS50 CS45 CS20 CS25 CS55 CS30 CS70 CS75 C315 C325 C330 C335 C340 C320 C310 C319 C345 C350 C355 C357 C365 C370 C375 C410 C415 C420 C425 C430 C435 C440 C445 C450 C455 C460 C465 C470 C510 C515 C520 C525 C530 D4-l,4 DICHLOROBENZENE DS-NAPHTHALENE DIO-ACENAPHTHENE DIO-PHENANTHRENE D12-CHRYSENE D12-PERYLENE 2-FLUOROPHENOL D5-PHEN0L D5-NITR0BENZENE 2-FLUOROBIPHENYL 2,4,6TRIBROMOPHENOL D14-P-TERPHENYL 2-CHL0R0PHEN0L-D4 1,2-CL2BENZENE-D4 *PHENDL BIS(2CHL0R0ETHYL)E 2CHL0R0PHEN0L 1,3DICHL0R0BENZENE *1,4DICHL0R0BENZENE ANILINE N-NITROSODIMETHYLAMINE PYRIDINE BENZYL ALCOHOL 1,2DICHL0R0BENZENE 0. 2METHYLPHEN0L 0. Ef 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. NIE 6 8 2 7 5 8 4 8 7 8 6 5 (IS-1) (IS-2) (IS-3> (IS-4) (IS-5) (IS-6) (SS-5) (SS-4) (SS-1) (SS-2) (SS-6) (SS-3) (SS-7) (SS-8) T 4 7 z > ' OXYBISdCHLOROPR 4METHYLPHEN0L 0. ?<NITROSOPROPYLAMINE 0. HEXACHLOROETHANE 0. NITROBENZENE 0. ISOPHORONE 0. *2-NITR0PHENDL 0. 2,4-DIMETHYLPHENOL O. BENZOIC ACID BIS(2CHL0RDETH0XY) 0. *2,4DICHL0R0PHEN0L 0. 1, 2, 4TRICHLOROBENZ 0. NAPHTHALENE 0. 4-CHLOROANILlNE *CL6BUTAD1ENE «-4CHL0R03METHYLPHEN^0. 2 2METHYLNAPHTHALENE 0. 4 S<CL6CYCL0PENTADIENE •ft246TRICHLOROPHNEOL 0. 2 2, 4, 5TRICHL0R0PHEN 0. 2 2CHL0R0NAPHTHALENE 0. 8 2-NITROANILINE T T T T T T !.) 300267 313 Subject To Validation No 48 49 50 No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 '24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 43 •,49 50 Name C535 C540 C545 m/z 152 136 164 188 240 264 112 99 82 172 330 244 132 152 94 93 128 146 146 93 74 79 108 146 108 45 108 70 117 77 82 139 107 122 93 162 ISO 128 127 225 107 142 237 196 196 162 65 163 152 138 - DIMETHYL PHTHALATE ACENAPHTHYLENE 3-NITROANILINE Scan 503 ' 620 779 912 1176 1471 385 476 557 716 850 1053 487 521- 477 • 482- 488 500 . 505- 478-. 211 211 519. 522- 530- 531 543- 544 550 559 579 587 590- 601 • 598 609 616 622 628 636 670 683 702 711 • 715' 727 740 755 766 777 Time 8: 23 10:20 12: 59 15: 12 19: 36 24: 31 6: 25 7: 56 9: 17 11: 56 14: 10 17: 33 8: 07 8: 41 7: 57 8: 02 S: 08 8: 20 8: 25 7: 58 3: 31 3: 31 S: 39 8: 42 8: 50 8: 51 9: 03 9: 04 9: 10 9: 19 9: 39 9: 47 9: 50 10: 01 9: 58 10: 09 10: 16 10: 22 10: 28 10: 36 11: 10 11: 23 11: 42 11: 51 11: 55 12: 07 12: 20 12: 35 12: 46 12: 57 Ref 1 2 3 4 5 6 1 1 2 3 3 5 2 2 2 2 2 2 2 2 2 2 2 2. 2 3 3 3 3 3 3 3 3 0. 0. 0. 0. 1. 0. 0. 1. 0. 0. 0. 0. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 3 RRT 000 000 000 000 000 000 765 946 898 919 091 895 968 036 948 958 970 994 004 950 419 419 032 038 054 056 080 082 093 902 934 947 952 969 965 982 994 003 013 026 081 102 901 913 918 933 950 969 983 997 Me^h A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A BB BB BB BB BB BB BB BB BB BB BB BB BB BB BB VB BB BV VB BV BB BB BV BB VB BB BB BB BB BB BB BB BB BV BB BB BB BB BB BB BB BB BB BV VB BB. BB BB BB BB Area(Hght) 10117. 35918. 18998. 28570. 24201. 26539. 1300B. 16823. 12528. 25242. 2741. 23005. 13739. 9031. 20036. 17559. 13810. 15346. 15S00. 17744. 7921. 12487. 7186. 14368. 13071. 15708. 13081. 7645. 5778. 12527. 25019. 7053. 9618. 5414. 16183. 10898. 11841. 38036. 12577. 5396. 10029. 25612. 6802. 7534. 8127. 23632. 6058. 27175. 3S1S4. 3177. S S I D ^ pll'^l'iH^ Amount 20. 000 20. 000 20. 000 20. 000 20. 000 20. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 ^«^._ r»..L»_ _ PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB «. "r « / 7.Tot 0. 0. 0. 0. 0. 0. 95 95 95 95 95 95 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19. 300268 f > fl .• Data Subject To Validation No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 Ret(L> Ratio 8:23 1 10:20 1 12: 59 1 15: 12 1 19:36 1 24:31 3 6: 25 1 7: 56 1 9: 17 1 11:56 1 14:10 i 17:33 1 8:07 i 8: 41 i 7: 57 J 8:02 J 8:08 i 8: 20 1 8: 25 3 7: 58 3 3: 31 i 3: 31 1 8: 39 3 8:42 3 8: 50 3 8: 51 3 9:03 3 9:04 3 9: 10 3 9: 19 3 9: 39 3 9: 47 3 9: 50 3 10:01 3 9: 58 3 10:09 3 10:16 1 10:22 10: 28 10: 36 11: 10 11: 23 11: 42 11: 51 11: 55 12:07 12: 20 12: 35 12: 46 12: 57 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 L. 00 L. 00 L 00 L. 00 L 00 L 00 L 00 L. 00 L 00 L. 00 L 00 L 00 L 00 L. 00 i. 00 L 00 L 00 . 00 . 00 . 00 L 00 I. 00 L. 00 L. 00 L. 00 L. 00 I. 00 I. 00 I. 00 1. 00 l. 00 I. 00 1. 00 1. 00 1. 00 1. 00 1. 00 I. 00 RRT(L) 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 0. 765 0. 946 0. 898 0. 919 1. 091 0. 895 0. 968 1. 036 0. 948 0. 958 0. 970 0. 994 1. 004 0. 950 0. 419 0. 419 1. 032 1. 038 1. 054 1. 056 1. 080 1. 082 1. 093 0. 902 0. 934 0. 947 0. 952 0. 969 0. 965 0. 982 0. 994 1. 003 1. 013 1. 026 1. 081 1. 102 0. 901 0. 913 0. 918 0. 933 0. 950 0. 969 0. 983 0. 997 Ratio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00, 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 Amnt ' 20. 00 20. 00 20. 00 20. 00 20.^00 20. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 Amnt(L) 20. 00 20. 00 20. 00 20. 00 20. 00 20. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 R. Fac R. 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 1. 029 1. 330 0. 279 1. 063 0. 115 0. 760 1. 086 , 0. 714 1. 584 1. 388 1. 092 1. 213 1. 249 1. 403 0. 626 0. 987 0. 568 1. 136 1. 034 1. 242 1. 034 0. 605 0. 457 0. 279 0. 557 0. 157 0. 214 0. 121 0. 360 0. 243 0. 264 0. 847 0. 280 0. 120 0. 223 0. 570 0. 286 0. 317 0. 342 0. 995 0. 255 1. 144 1. 608 0. 134 Fac(L) Ral 1.000 3 1.000 3 1.000 3 1.000 3 1. 000 3 1.000 3 1.029 3 1.330 3 0. 279 3 1.063 3 0. 115 3 0. 760 3 1. 086 3 0. 714 1. 584 1. 388 1. 092 1. 213 1. 249 1. 403 0. 626 0. 987 0. 568 1. 136 1. 034 1. 242 1. 034 0. 605 0. 457 0. 279 0. 557 3 0. 157 0. 214 0. 121 0. 360 0. 243 0. 264 0. 847 0. 280 0. 120 0. 223 0. 570 0. 286 0. 317 0. 342 0. 995 0. 255 1. 144 1. 608 0. 134 iio L. 00 L. 00 L 00 I. 00 L. 00 L. 00 l. 00 I. 00 . 00 . 00 L 00 L. 00 I. 00 I. 00 I. 00 I. 00 I. 00 I. 00 I. 00 I. 00 1. 00 I. 00 I. 00 I. 00 t. 00 I. 00 I. 00 I. 00 I. 00 I. 00 I. 00 I. 00 I. 00 I. 00 I. 00 I. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 300269 Data , . ,, To Validation Subject >o v« Quantitation Report File: BS110994A Data: BS110994A. TI 11/09/94 9:48:00 .Sample: SSTD050 290-02-SV25 PConds. : RTX-5 0. 25MM X 30M l.OUM 45/4-325@20 Formula: X X X Instrument: B Submitted by: Analyst: JAM INST B Weight: Acct. No. 1. 001 AMOUNT=AREA * REF AMNT/(REF AREA * RESP FACT) Resp. fac. from Library Entry No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 No 51 52 53 54 55 56 57 58 Name C550 C321 C555 C560 C565 C570 C543 C5S0 C585 C590 C595 C610 C615 C625 C630 C635 C640 C645 C650 C655 D200 C647 C715 C720 C725 C730 C740 C735 C760 C765 C770 C775 C780 C785 C790 m/z 153 232 184 109 168 165 165 149 - *ACENAPHTHENE 0. 8 2,3,4,6-TETRACHLORDPHENOL 8<2, 4DINITR0PHEN0L 5<4N I TROPHENOL DIBENZOFURAN 2,4DINITR0T0LUENE 2,6DINITR0T0LUENE DIETHYL PHTHALATE 4CHL0R0PHENYL PHEN FLUORENE 4-NITROANILINE 0. 8 0. 2 0. 2 0. 4 0. 9 4,6DINITR02METHYLPH ^DIPHENYLAMINE 4BR0M0PHENYL PHENY CL6BENZENE ^PENTACHLOROPHENOL PHENANTHRENE ANTHRACENE DI-NBUTYLPHTHALATE ^FLUORANTHENE 0. 1 0. 1 0. 05 0. 7 0. 7 0. 6 1,2-DIPHENYLHYDRAZINE CARBAZOLE PYRENE 0. 6 BUTYLBENZYLPHTHALATE 3,3'CL2BENZIDINE BENZO(A)ANTHRACENE 0. 8 BIS(2ETHYLHEXYL)PHTH CHRYSENE 0. 7 <^D I-N-OCTYLPHTHALATE BENZO(B)FLUORANTHE BENZO(K)FLUORANTHE *BENZO(A)PYRENE INDENOd. 2, 3CD)PYR DIBENZO(A,H)ANTHRA BENZO(G, H, DPERYLE Scan Time Ref 782 13:02 3 1. 810 13:30 3 1. 785 13:05 3 1. 791 13: 11 3 .1. 796 13: 16 3 1. 798 13: 18 3 1. 763 12:43 3 0. 817 13:37 3 1. 0. 7 0. 7 0. 7 0. 5 0. 4 0. 5 RRT 004 040 008 015 022 024 979 049 T T T Meth A A A A A A A A BB BB BB BB BB BB BB BB Area(Hght) 21761. 6923. 3045. 2043. 33674. 8215. 7070. 25268. Amount 25. 25. 25. 25. 25. 25. 25. 25. 000 000 000 000 000 000 000 000 PPB PPB • PPB PPB PPB PPB PPB PPB ._ /« Tot 19 19 19 19 19 19 19 19 300270 Data Subject To Validation No 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 m/z Scan Time P 204 166 138 198 169 248 284 266 178 178 149 202 : 77 167 202 : 149 : 252 228 : 149 ; 228 ; 149 252 : 252 252 276 278 : 276 824 13:44 827 13:47 835 13:55 835 13:55 836 13: 56 868 14:28 883 14:43 899 14:59 914- 15: 14 918" 15: 18 959 15:59 1022. 17:02 839 13: 59 933 15:33 1044- 17:24 1098 18:18 1167 19:27 L173- 19:33 1163 19:23 1180- 19:40 1262 21:02 1372 . 22: 52 1378- 22: 58 1455' 24: 15 1836. 30:36 L844- 30:44 1954' 32:34 Ret(L) Ratio R R T ( L : 13: 02 13: 30 13: 05 13: 11 13: 16 13: 18 12: 43 13: 37 13: 44 13:47 13: 55 13: 55 13; 56 14: 28 14: 43 14: 59 15: 14 15: 18 15: 59 17: 02 13: 59 15: 33 17: 24 IS: 18 19: 27 19: 33 19: 23 1.00 1.004 1.00 1.040 1. 00 1. OOS 1.00 1.015 1.00 1.022 1. 00 1. 024 1. 00 0. 979 1.00 1.049 1.00 1.058 1.00 1.062 1.00 1.072 1.00 0.916 1.00 0.917 1. 00 • 0. 952 1.00 0.968 1.00 0.986 1.00 1.002 1.00 1.007 1.00 1.052 1. 00 1. 121 1.00 0.920 1.00 1.023 1.00 0. SSS 1.00 0.934 1. 00 0. 992 1.00 0.997 1. 00 0. 989 lef 3 3 3 4 4 4 4 4 4 4 4 4 4 4 5 5 5 5 5 5 6 6 6 6 6 6 6 RRT- 1. 058 1. 062 1. 072 0. 916 0. 917 0. 952 0. 968 0. 986 1. 002 1. 007 1. 052 1. 121 0. 920 1. 023 0. SSS 0. 934 0. 992 0. 997 0. 989 1. 003 0. 858 0. 933 0. 937 0. 989 1. 248 1. 254 1. 328 1 Ratio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 , 00 . 00 . 00 . 00 . 00 . 00 . 00 -JlBth A A A A A A A A A A A A A A A A A A A A A A A A A A A / 21 21 BB BB VB BB BB BB BB BB BV VB BB BB BB BB BB BB BB BV BB VB BB BV VB BB BB BB BB ^mnt 5. 00 5. 00 25. 00 2; 21 2: 2: 2! 21 2! 2: 2: 2: 2i 2' 2; 21 2! 21 2 2 2 2 2 2 2 2 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 Area(Hght) 11718. 25536. 3381. 4567. 13787. 6636. 6712. 4827. 36191. 37037. 45041. 36201. 29659. 23056. 39401. 19861. 4348. 31949. 28211. 29396. 45403. 33707. 25784. 28854. 31409. 23544. 25748. Amnt(L) 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 SSTDfp^ a^iKj-iiH/^ Amount 25. 000 25. OOO 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 R. Fac R. F 0. 0. 0. 0. 1. 0. 0. 1. 0. 1. 0. 0. 0. 0. 0. 0. 1. 1. 1. 1. 0. 0, 1. 0 0 1 0 916 292 128 086 418 346 298 064 493 075 142 128 386 186 188 135 013 037 261 014 . 830 . 646 , 302 . 657 . 144 . 056 . 933 PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB ac(L) 0. 916 0. 292 0. 128 0. 086 1. 418 0. 346 0. 298 1. 064 0. 493 1. 075 0. 142 0. 128 0. 386 0. 186 0. IBS 0. 135 1. 013 1. 037 1. 261 1. 014 0. 830 0. 646 1. 302 0. 657 0. 144 1. 056 0. 933 7.1 4 Rat: "ot 19 19 19 19 19 19 19 19 19 19 19 19 - 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 Lo 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 , 00 . 00 . 00 Data Subject To Validation 300271 No 78 79 80 81 82 83 84 85 Rel 19: 21: 22: 22: 24: 30: 30: 32: ;(L) 40 02 52 58 15 36 44 34 Ratio 00 00 00 00 00 00 00 00 RF 1. 0. 0. 0. 0. 1. 1. 1. ?T<L) 003 858 933 937 989 248 254 328 Ratio 00 00 00 00 00 00 00 00 - Amnt 25. 00 25. 00 25. 00 25. 00 25.^00 25.*00 25. 00 25. 00 SSTD -^flKP Amnt(L) ps^ 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 i i U R. Fac R. 0. 972 1. 369 1. 016 0. 777 0. 870 0. 947 0. 710 0. 776 Fac(L) 0. 972 1. 369 1.016 0. 777 0. 870 0. 947 0. 710 0. 776 Rat: io 00 00 00 00 00 00 00 00 • 300272 Data Subject To Validation DATA FROM FILE: BS110994B SCANS 361 TO llOl ACQUIRED: 11/09/94 10:28:00 CALI: BS110994B #1 SAMPLE: SSTD160 290-02-SU80 CONDS.: RTX-5 0.25MM X 30M l.OUM 45/4-325228 INST B I' ^< > 488 _• 6:48 500 J 8:28 688 . 10:00 700 . 11:40 800 _t 13:20 '^mam 900 . 15:00 C ^- 1000 J 'A 16:40 L_ ii M r w o 3 CS50 2-FLUOROPHENOL 0.6 (SS-5) GG16 D5 PHENOL J 188.8;; ( 179712.) 8.3 (SS-4) rrnn—D'l i..^ DI CHLOROBENZENE ( I S- i) CS75 1..2-CL2BENZENE-D4 8.4 (SS-8) -Cvi'8 D5-NI TROBENZENE 8.2 (SS-1) nPBTHntEME -<IS-2) CS25 2-FLUOROBIPHENYL 8.7 (SS-2) LIT.Q PlCACENnPHTHENE (IS-3) CS55 2.4,bTRIBROMOPHENOL (SS-6) ajEy^==ti&r4) TbSS D14-P-TERPHENYL 8.5 (SS-3) ^ Z-1 CD l".-i V V r 7 PA . I S | .* DATA FROM FILE: BSl189346 SCANS 1181 TO 2888 ACQUIRED: 11/89/94 18:28:88 CALI: BS110994B #1 SAMPLE: SSTD168 290-02-SU30 CONDS.: RTX-5 8.25MM X 30M l.OUM 45/4-325@20 INST B 1200 . 20:00 1408 _ 23:28 I 1600 _ 26:40 cn ^ 1800 _ §. 30:00 u> £ O | Q 1 O (U to 'rr" it* m J -• 100.0;; ( 97920.) .4i.yjJ~P-lJ*eWHTIBIilB I -(IS-5) TT?r~Cil2-PERYLENE (IS-6) Quantitation Report File: BS110994B Data: BS110994B. TI 11/09/94 10:28:00 Sample: SSTD160 290-02-SV80 Conds.: RTX-5 0. 25MM X SOM l.OUM 45/4-325(220 Formula: X X X Instrunjent: B Submitted by: Analyst: JAM INST B Weight: Acct. No. 1. 001 AMDUNT=AREA * REF AMNT/(REF AREA * RESP FACT) Resp. fac. from Library Entry No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 33 39 40 41 42 143 44 45 46 47 Name CI30 CI40 CI50 CI60 CI70 CI75 CS50 CS45 CS20 CS25 CS55 CS30 CS70 CS75 C315 C325 C330 C335 C340 C320 C310 C319 C345 C350 C355 C357 C365 C370 C375 C410 C415 C420 C425 C430 C435 C440 C445 C450 C455 C460 C465 C470 C510 C515 C520 C525 C530 D4-l,4 DICHLOROBENZENE DS-NAPHTHALENE D10-ACENAPHTHENE DIO-PHENANTHRENE D12-CHRYSENE D12-PERYLENE 2-FLUOROPHENOL D5-PHEN0L D5-NITR0BENZENE 2-FLUOROBIPHENYL 0. 6 0. 8 O. 2 O. 7 2,4,6TRIBROMOPHENOL D14-P-TERPHENYL 0. 5 2-CHL0R0PHEN0L-D4 0. 8 1,2-CL2BENZENE-D4 0. 4 <tPHENOL O. B B1S(2CHL0R0ETHYL)E 0.7 2CHL0R0PHEN0L O. 8 1,3DICHL0R0BENZENE O. 6 *1,4DICHL0R0BENZENE 0.5 ANILINE N-NITROSODIMETHYLAMINE PYRIDINE BENZYL ALCOHOL 1,2DICHL0R0BENZENE O. 4 2METHYLPHEN0L 0. 7 2. 2'OXYBISdCHLOROPR 4METHYLPHENDL 0. ScNITROSOPROPYLAMINE 0. HEXACHLOROETHANE 0. NITROBENZENE 0. ISOPHORONE 0. •fr2-NITROPHENOL 0. 2,4-DIMETHYLPHENOL 0. 2 BENZOIC ACID BIS(2CHL0R0ETH0XY) 0.3 #2, 4DI CHLOROPHENOL 0.2 1, 2, 4TRICHL0R0BENZ 0.2 NAPHTHALENE 0. 7 4-CHLOROANILINE «CL6BUTADIENE *^4CHL0R03METHYLPHEN 0. 2 2METHYLNAPHTHALENE 0. 4 8<CL6C YCLOPENTAD I ENE *246TRICHLOROPHNEOL 0. 2 2, 4, 5TRICHL0R0PHEN 0.2 2CHL0RDNAPHTHALENE 0. 8 2-NITRDANILINE (IS-1) (IS-2) (IS-3) (IS-4) (IS-5) (IS-6) (SS-5) (SS-4) (SS-1) (SS-2) (SS-6) (SS-3) (SS-7) (SS-8) T T T T T T T Data Subject To Vajidation. 300275 No Name ~. 48 C535 DIMETHYL PHTHALATE 49 C540 ACENAPHTHYLENE 1.3 50 C545 3-NITROANILINE m No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 m/z 152 136 164 IBS 240 264 112 99 82 172 330 244 132 152 94 93 128 146 146 93 74 79 108 146 108 45 108 70 117 77 82 139 107 122 93 162 180 128 127 225 107 142 237 196 196 162 65 163 152 138 Scan 501 • 619 779 912 1176 1470 378 474 556 717 851 1053 484 519- 475- 480- 486 497' 502' 475- 199 199 518- 520- 529' 530 543' 544 548 558 579 587 590- 606- 597 609 615 622 628 635 670 683 702 711. 715' 728 740 755 766 778 Time 8: 10: 12: 15: 19: 24: 6: 7: 9: 11: 14: 17: 8: 8: 7: 8: 8: 8: 8: 7: 3: 3: 8: 8: 8: 8: 9: 9: 9: 9: 9: 9: 9: 10: 9: 10: 10: 10: 10: 10: 11: 11: 11: 11: 11: 12: 12: 12: 12: 12: 21 19 59 12 36 30 18 54 16 57 11 33 04 39 55 00 06 17 22 55 19 19 33 40 49 50 03 04 08 18 39 47 50 06 57 09 15 22 28 35 10 23 42 51 55 OS 20 : 35 : 46 : 58 Ref 1 2 3 4 5 6 1 1 2 3 3 5 2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3 0. 0. 0. 0. 1. 0. 0. 1. 0. 0. 0. O. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0, RRT 000 000 000 000 000 000 754 946 898 920 092 895 966 036 948 958 970 992 002 948 397 397 034 038 056 053 084 086 094 901 935 948 953 979 964 984 994 005 015 026 082 103 901 913 91S 935 950 969 ,983 . 999 Meth A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A BB BB BB BB BB BB BB BV BB BB BB BB BB BB BB VB BB BV VB BV BB BB BV BB VB BB BB BB BB BB BV BB BB BB BB BB BB BV BB BB BB BB BB BV VB BB BB BB BB BV Area(Hght) 10939. 35684. 19437. 29068. 16948. 14695. 43413. 56555. 43696. 86333. 9091. 58906. 48498. 31477. 69261. 58496. 49203. 52936. 53578. 62900. 27527. 38346. 27515. 48977. 44010. 58365. 47818. 27149. 19653. 41541. 85142. 27172. 34263. 20908. 57086. 37579. 39249. 119980. 52848. 18199. 35080. 82161. 24614. 25837. 28707. 82689. 21530. 88163.. 109S42. 17982. SZTOl''^ •QSHP'ilHB Amount 20. 20. 20. 20. 20. 20. SO. SO. SO. SO. 80. BO. BO. 80. 80. 80. 80. SO. 80. 80. BO. BO. 80. 80. 80. 80. 80. 80. 80. 80. SO. SO. 80. SO. 80. 80. 80. 80. 80. 80. 80. 80. 80. SO. SO. 80. 80. 80. SO. 80. FN-i 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 ooo 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 1.^ C.iV PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB iiortTi 7.Tot 0. 0. 0. 0. 0. 0. 31 31 31 31 31 31 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 300276 r> Valid !atio No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 Ret(U) Ratio 8: 10: 12: 15: 19: 24: 6: 7: 9: 11: 14: 17: 8: 8: 7: 8: 8: 8: 8: 7: 3: 3: 8: S: 8: S: 9: 9: 9: 9: 9: 9: 9: 10: 9: 10: 10: 10: 10: 10: 11: 11: 11: 11: 11: 12: 12: 12: 12: 12: 21 3 19 3 59 3 12 3 36 3 30 3 18 3 54 3 16 3 57 3 11 3 33 3 04 3 39 55 00 06 17 22 3 55 3 19 3 19 3 38 3 40 3 49 3 50 3 03 3 04 3 OS 3 19 3 39 3 47 3 50 3 06 3 57 3 09 3 15 3 22 3 28 : 35 . 10 . 23 3 42 3 51 3 55 3 08 3 20 3 35 3 46 3 58 3 L 00 I. 00 L. 00 i. 00 L. 00 I. 00 L 00 L. 00 L. 00 L. 00 L. 00 L. 00 L. 00 I. 00 L. 00 I. 00 I. 00 I. 00 I. 00 L. 00 L. 00 L. 00 L. 00 I. 00 L. 00 L 00 L 00 L. 00 L. 00 L 00 L. 00 I. 00 L. 00 L. 00 L. 00 L. 00 L. 00 I. 00 I. 00 L. 00 I. 00 L. 00 L. 00 I. 00 L. 00 L. 00 L. 00 I. 00 L 00 L. 00 RRT(L) 0. 0. 0. 0. 1. 0. 0. 1. 0. 0. 0. 0. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 000 000 000 000 000 000 754 946 898 920 092 895 966 036 948 958 970 992 002 948 397 397 034 038 056 058 084 086 094 901 935 948 953 979 964 984 994 005 015 026 082 103 901 913 918 935 950 969 983 999 Ratio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 - ._ Amn t 20. 00 20. 00 20. 00 20. 00 20.00 20. 00 80. 00 SO. 00 SO. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 SO. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 SO. 00 80. 00 BO. 00 80. 00 80. 00 80. 00 80. 00 SO. 00 SO. 00 SO. 00 80. 00 80. 00 80. 00 80. 00 SO. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 SO. 00 Amnt(L) 20. 00 20. 00 20. 00 ,20. 00 20. 00 20. 00 SO. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 SO. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 SO. 00 SO. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 SO. 00 80. 00 SO. 00 80. 00 80. 00 80. 00 80. 00 80. 00 ssTDm> Vu^^'f^ R. Fac R. 1. 1. 1. 1. 1. 1. 0. 1. 0. 1. 0. 0. 1. 0. 1. 1. 1. 1. 1. 1. 0. 0. 0. 1. 1. 1. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 0. 1. 1. 0. 000 000 000 000 000 000 992 293 306 110 117 869 108 719 583 337 124 210 224 438 629 876 629 119 006 334 093 620 449 291 596 190 240 146 400 263 275 841 370 128 246 576 317 332 369 064 277 134 413 231 Fac(L) 1. 1. 1. 1. 1. 1. 0. 1. 0. 1. 0. 0. 1. 0. 1. 1. 1. 1. 1. 1. 0. 0. 0. 1. 1. 1. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 0. 1. 1. 0. 000 000 000 000 000 000 992 293 306 110 117 869 108 719 583 337 124 210 224 438 629 876 629 119 006 334 093 620 449 291 596 190 240 146 400 263 275 841 370 128 246 576 317 332 369 064 277 134 413 231 Ratio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 300277 Data Subject To Validation Quantitation Report File: BS110994B m Data: BS110994B. TI 11/09/94 10:28:00 ample: SSTD160 290-02-SV80 onds.: RTX-5 O. 25MM X SOM l.OUM 45/4-325620 Formula: X X X Instrument: B Submitted by: Analyst: JAM INST B Weight: Acct. No. 1. 001 AMOUNT=AREA * REF AMNT/(REF AREA * RESP FACT) Resp. fac. from Library Entry No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 SO 81 82 83 84 85 No 51 52 53 54 55 f56 57 58 Name C550 C321 C555 C560 C565 C570 C543 C5S0 C585 C590 C595 C610 C615 C625 C630 C635 C640 C645 C650 C655 D200 C647 C715 C720 C725 C730 C740 C735 C760 C775 C780 C7S5 C790 C765 C770 m/2 153 232 184 109 168 165 165 149 ' ^ACENAPHTHENE 0. 8 2,3,4,6-TETRACHLOROPHENOL 8<2, 4DINITR0PHEN0L «<4N I TROPHENOL DIBENZOFURAN 0. 8 2,4DINITR0T0LUENE 0. 2 2, 6DINITR0T0LUENE 0.2 DIETHYL PHTHALATE 4CHL0R0PHENYL PHEN 0. 4 FLUORENE 0. 9 4-NITROANILINE 4,6DINITR02METHYLPH «-D I PHENYL AM INE 4BR0M0PHENYL PHENY 0. 1 CL6BENZENE 0. 1 ^PENTACHLOROPHENOL 0. 05 PHENANTHRENE 0. 7 ANTHRACENE 0. 7 DI-NBUTYLPHTHALATE ^^FLUORANTHENE 0. 6 1,2-DIPHENYLHYDRAZINE CARBAZOLE PYRENE 0. 6 BUTYLBENZYLPHTHALATE 3,3'CL2BENZIDINE BENZO(A)ANTHRACENE 0.8 BIS(2ETHYLHEXYL)PHTH CHRYSENE 0. 7 *^D I -N-OCTYLPHTHALATE «BENZO.(A)PYRENE 0.7 INDENOd, 2, 3CD)PYR 0.5 DIBENZO(A, H)ANTHRA 0.4 BENZO(G, H, DPERYLE 0.5 BENZO(B)FLUDRANTHE 0.7 BENZO(K)FLUORANTHE 0.7 Scan Time Ref RRT 733 13:03 3 1.005 811 13:31 3 1.041 786 13:06 3 1.009 792 13: 12 3 1. 017 796 13: 16 3 1. 022 799 13: 19 3 1. 026 764 12: 44 3 0. 981 818 13: 33 3 1. 050 T T T Meth A A A A A A A A BB BB BB BB BB BB BB BV Area(Hght) 73858. 23130. 13193. 7050. 100613. 28467. 25972. 86344. Amount 80. 000 80. 000 80. 000 SO. 000 30. 000 SO. 000 SO. 000 80. 000 PPB PPB PPB PPB PPB PPB PPB PPB 7.Tot 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 3 00278 Data Subject To Validation No 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 33 84 85 No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 m/z 204 166 133 198 169 243 284 266 178 178 149 202 77 167 202 149 252 228 149 228 149 252 276 278 276 252 252 Scan T 825 13 828 13 836 13 836 13 837 13 363 14 884 14 900 15 915- 15 919' 15 960 16 1023- 17 840 14 934 15 1044- 17 1098 18 1170 19 1174- 19 1164 19 1181- 19 1263 21 1457- 24 1845- 30 1851- 30 1959. 32 1374- 22 1380- 23 Ret(L) Ratio 13: 13: 13: 13: 13: 13: 12: 13: 13: 13: 13: 13: 13: 14: 14: 15: 15: 15: 16: 17: 14: 15: 17: 18: 19: 19: 19: 03 31 06 12 16 19 44 38 45 48 56 56 57 23 44 00 15 19 00 03 00 34 24 IS 30 34 24 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 ime Ref :45 : 48 : 56 : 56 : 57 :23 :44 :00 : 15 : 19 :00 :03 : 00 : 34 :24 : 18 : 30 : 34 : 24 : 41 : 03 : 17 :45 : 51 :39 : 54 :00 RRT(L; 1. 005 1. 0,41 1. 009 1. 017 1. 022 1. 026 0. 981 1. 050 1. 059 1. 063 1. 073 0. 917 0. 918 0. 952 0. 969 0. 987 1. 003 1. 008 1. 053 1. 122 0. 921 1. 024 0. 383 0. 934 0. 995 0. 993 0. 990 3 3 3 4 4 4 4 4 4 4 4 4 4 4 5 5 5 5 5 5 6 6 6 6 6 6 6 > Ri RRT- 1. 059 1. 063 1. 073 0. 917 0. 918 0. 952 0. 969 0. 987 1. 003 1. 008 1. 053 1. 122 0. 921 1. 024 0. 888 0. 934 0. 995 0. 998 0. 990 1. 004 0. 859 0. 991 1. 255 1. 259 1. 333 0. 935 0. 939 atio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 , 00 00 00 00 , 00 , 00 , 00 00 00 00 Meth A BB A BB A VB A BB A 5B A BB A BB A BB A BV A VB A BB A BB A BV A BB A BV A BB A BB A BV A BB A VB A BB A BB A BB A BB A BB M XXQ" M XX^ Amnt 80. 00 80. 00 80. 00 80. 00 80. 00 SO. 00 SO. 00 80. 00 80. 00 30. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 SO. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80.-00 Area(Hght) 41368. 85355. 6199. 17099. 44417. 21013. 20744. 16937. 117430. 108240. 138531. 107516. 101039. 56049. 110303. 50539. 4149. 76809. 69532. 68758. 101813. 54980. 49665. 40850. . 42508. n'1 69212. ^ 57276. Amnt(L) 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 SO. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 SO. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 30. 00 30. 00 30. 00 SO. 00 80. 00 •gfji^ji^i^ Amount 80. 000 80. 000 30. 000 SO. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 SO. 000 SO. 000 80. 000 80. 000 80. 000 SO. 000 80. 000 SO. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB R. Fac R. Fac(L) 0. 0. 0. 0. 1. 0. 0. 1. 0. 1. 0. 0. 0. 0. 0. 0. 1. 0, 1. 0. 0. - 0. 1. 0. 0. 1. 1. 950 297 170 091 294 366 334 111 532 098 080 147 382 181 178 , 146 010 , 931 191 , 925 869 , 482 , 627 , 746 • , 061 133 , 026 0. 950 0. 297 0. 170 0. 091 1. 294 0. 366 0. 334 1. Ill 0. 532 1. 098 0. 080 0. 147 0. 332 0. 181 0. 178 0. 146 1. 010 0. 931 1. 191 0. 925 0. 869 0. 482 1. 627 0. 746 0. 061 1. 133 1. 026 Data Subject To- 7.Tot Rat: 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 io 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 Vajidatipn 300279 No 78 79 80 31 82 83 34 85 Ret(L> 19:41 21:03 24: 17 30: 45 30: 51 32: 39 22: 54 23:00 Ratio 00 00 00 00 00 00 00 00 ' RRT(L) 1. 004 0. 859 0. 991 1. 255 1. 259 1. 333 0. 935 0. 939 Ratio 00 00 00 00 00 00 00 00 - Ar 'so. 30. SO. 80. 80. 80. 80. SO. nnt 00 00 00 00 ^00 *00 00 00 Amnt(L) 80. 00 SO. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 SrvDl('P -^fimi^li R. Fac R. 1. 014 1. 732 0. 935 0. 845 0. 695 0. 723 1. 177 0. 974 Fac(L) 1. 1. 0. 0. 0. 0. 1. 0. 014 732 935 845 695 723 177 974 Rat: io 00 00 00 00 00 00 00 00 Data Subject To Validation 300280 DATA FROM FILE: BS110994C SCANS 362 TO 1102 ACQUIRED: 11/09/94 11:08:00 CALI: BS110994C #1 SAMPLE: SSTD828 29e-e2-SU10 CONDS.: RTX-5 0.25MM X 30M l.OUM 45/4-325@20 INST B liiJi 408 _ 6:48 500 8:20 I 600 . 10:00 700 11:40 800 _ 13:20 ; C, \f < 5i9 t l o c; to 908 . 15:00 11000 _ H6:40 tm CS50 2-FUJOROPHENOL CS45 D5-PHEN0L J 100.0,-^ ( 57024.) 0.6 (S'5-5) 8.8 (SS-4) CI30 D4-1.4 DICHLOROBENZENE (IS-1) CS75 1,2-CL2BENZENE-D4 0.4 (SS-S) CS20 D5-NITROBENZENE 0.2 (SS-1) CI40 DS-NAPHTHALENE CS25 2-FLUORuBIPHENYL 0.7 (SS-2) CI50 DIO-ACENAPHTHENE CS55 2.4.6TRIBR0M0PHEN0L (SS-6) (IS-2) (IS-3) CI60 DIO-PHENANTHRENE (IS-4) /. ^^~ CS30 Di4-P-TERPHENTL 0.5 (SS-3) Co V -ft '•*«•» DATA FROM FILE: BS110394C SCANS 1102 TO 2000 ACQUIRED: 11/09/94 11:08:00 CALI: BS110994C #1 SAMPLE: SSTD020 298-e2-SU18 CONDS.: RTX-5 0.25MM X 30M l.OUM 45/4-325820 INST B 1200 _ 28:8f 1400 _| £-•..1 . j ^ V 1600 _ 26:40 O r-T a> cn J : 1808 . ,g 30:90 o 'S^ t o j ^ CO |=*. to ;0 Tm i I 108.8:^ ( 33344.) CI70 D12-CHRYSENE (IS-5) CI75 D12-PERYLENE (IS-6) Quantitation Report File: BS110994C J Data: BS110994C. TI 11/09/94 11:08:00 • Sample: SSTD020 290-02-SVlO tonds. : RTX-5 0. 25MM X SOM l.OUM 45/4-325^20 INST B ^ Formula: X X X Instrument: B Weight: 1.001 Submitted by: Analyst:* JAM Acct. No. : AMOUNT=AREA * REF AMNT/(REF AREA * RESP FACT) Resp. fac. from Library Entry No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 23 29 30 31 32 33 34 35 36 37 38 39 40 41 42 ,43 44 45 46 Name CI30 CI40 CI 50 CI60 CI70 CI75 CS50 CS4 5 CS20 CS25 CS55 CS30 CS70 CS75 C315 C325 C330 C335 C340 C320 C310 C319 C345 C350 C355 C357 C365 C370 C375 C410 C415 C420 C425 C430 C435 C440 C445 C450 C455 C460 C465 C470 C510 C515 C520 C525 D4-1.4 DICHLOROBENZENE DS-NAPHTHALENE DIO-ACENAPHTHENE DIO-PHENANTHRENE D12-CHRYSENE D12-PERYLENE 2-FLUOROPHENOL O. 6 D5-PHEN0L O. 8 D5-NITR0BENZENE 0.2 2-FLUOROBIPHENYL 0.7 2, 4,6TRIBR0M0PHEN0L D14-P-TERPHENYL 0. 5 2-CHL0R0PHEN0L-D4 O.8 1, 2-CL2BENZENE-D4 0. 4 «-PHEN0L O. 8 BIS(2CHL0R0ETHYL)E 0.7 2CHL0R0PHEN0L 0.8 1, 3DICHL0R0BENZENE 0.6 *1, 4DICHL0R0BENZENE 0.5 ANILINE N-NITROSODINETHYLAMINE PYRIDINE BENZYL ALCOHOL 1,2DICHL0R0BENZENE 0. 2METHYLPHEN0L , O. 2,2'0XYBIS(1CHL0R0PR 4 7 4METHYLPHENDL 8<N ITROSOPROP YL AM I NE HEXACHLOROETHANE NITROBENZENE ISOPHORONE ^^2-NITROPHENOL 2,4-DIMETHYLPHENOL BENZOIC ACID BIS(2CHL0R0ETH0XY) *2,4DICHL0R0PHENDL 1,2,4TRICHLOROBENZ NAPHTHALENE 4-CHLOROANILINE *CL6BUTADIENE <^4CHL0R03METHYLPHEN , 2METHYLNAPHTHALENE '8<CL6CYCLOPENTADIENE «246TRICHLOROPHNEOL 2,4,5TRICHL0R0PHEN 2CHL0R0NAPHTHALENE 47 C530 2-NITROANILINE 0. 0. 0. 0. 0. 0. 0. 0. 0. O. 0. (IS-1) (IS-2) (IS-3) (IS-4) (IS-5) (IS-6) (SS-5) (SS-4) (SS-1) (SS-2) (SS-6) (SS-3) (SS-7) (SS-8) T T O. 2 0. 4 0. 2 0. 2 0. 8 T T T 300283 Data Subject To Validation No 48 49 50 No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 Name C535 C540 C545 m/z 152 136 164 188 240 264 112 99 82 172 330 244 132 152 94 93 128 146 146 93 74 79 108 146 108 45 108 70 117 77 82 139 107 122 93 162 180 128 127 225 107 142 237 196 196 162 65 163 152 138 - DIMETHYL PHTHALATE ACENAPHTHYLENE 3-NITROANILINE Scan 502 620 780 913 1176 1470 3S0 474 556 717 S51 1053 485 520 475 480 486 498 503 476 201 202 518 521 529 530 542 543 549 553 578 587 590 599 597 609 615 622 629 636 671 683 703 711 716 728 740 755 766 773 Time 8:22 10:20 13: 00 15: 13 19:36 '24: 30 6: 20 7: 54 9: 16 11: 57 14: 11 17: 33 8:05 8:40 7: 55 8:00 8:06 8: 18 3: 23 7: 56 3:21 3:22 8: 38 8: 41 8: 49 8: 50 9: 02 9: 03 9: 09 9: 18 9: 33 9:47 9: 50 9: 59 9: 57 10:09 10: 15 10: 22 10: 29 10: 36 11: 11 11: 23 11:43 11: 51 11: 56 12: 08 12: 20 12: 35 12: 46 12: 58 Ref 1 2 3 4 5 6 1 1 2 3 3 5 2 2 2 2 2 - 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3 0. 0. 0. 0. 1. 0. 0. 1. 0. 0. o. 0. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 3 RRT 000 000 000 000 000 000 757 944 897 919 091 895 966 036 946 956 968 992 002 948 400 402 032 038 054 056 OSO 082 094 900 932 947 952 966 963 982 992 003 015 026 082 102 901 912 918 933 949 968 982 997 Meth A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A BB BB BB BB BB BB BB BB BB BB BB BB BB BB BB VB BB BV VB BV BB BB BV BB VB BB BB BB BB BB BB BB BB VB BB BB BB BB VB BB, BB BB BB BV VB BB BB BB BB BB Area(Hght) 11275. ' 33585. 20925. 31218. 24953. 26606. 5253. 6726. 5634. 11506. 1158. 10177. 5724. 4123. 8656. 7634. 6285. 6749. 6861. 6826. 3086. 4918. 2917. 6199. 6378. 7359. 6168. 3317. 2479. 5422. 10522. 3287. 4247. 2454. 7241. 4994. 5190. 17066. 5289. 2485. 4375. 10825. 2651. 3523. 3603. 10456. 2826. 11556. 17369. 913. jnD<p2Jp S^ll^'iTVC/ , Amount 20. 000 20. 000 20. 000 20. 000 20. 000 20. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 Data Sublet PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB 7.Tot 2. 20 2. 20 2. 20 2. 20 2. 20 2. 20 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 300284 ::t To Validation No Ret(L) Ratio RRT(L> Ratio - 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 8:22 10: 20 13: 00 15: 13 19: 36 24: 30 6:20 7: 54 9: 16 11: 57 14: 11 17: 33 8: 05 B: 40 7: 55 8: 00 8: 06 8: 18 8: 23 7: 56 3:21 3: 22 8: 38 8: 41 8:49 8: 50 9:02 9:03 9: 09 1.00 1.000 1.00 9: 9: 18 38 9: 47 9: 50 9: 59 9: 57 10: 09 10: 15 10: 22 10: 29 10: 36 11: 11 11:23 11: 43 11: 51 11: 56 12: OS 12: 20 12: 35 12: 46 12: 58 1. OO 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 1. 00 00 1. 00 00 00 1. 00 1 1 1 00 00 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 000 1. 000 1. 000 1. 000 1. 000 0. 757 0. 944 0. 897 0. 919 1. 091 O. 895 0. 966 1. 036 0. 946 0. 956 O. 968 0. 992 1. 002 O. 94B O. 400 0. 402 1. 032 1. 038 1. 054 1. 056 1. 080 ,1. 082 1. 094 0. 900 0. 932 O. 947 0. 952 0. 966 0. 963 0. 982 0. 992 1. 003 1. 015 1. 026 1. 082 1. 102 0. 901 0. 912 0. 918 O. 933 0. 949 O. 968 0. 982 0. 997 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 00 00 00 00 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 Amnt 20. 00 20. 00 20. 00 20. 00 20.^00 20. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 Amnt(L) R.Fac R.Fac(L) Ratio 20. 00 20. 00 20. 00 20. 00 20. 00 20. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 0. 932 1. 193 0. 292 1. 100 0. Ill 0. 816 1. 015 0. 731 1. 535 1. 354 1. 115 197 217 211 547 872 1. 1. 1. 0. 0. O. 518 1. 1. 1. 1. 0. 100 131 305 094 5SB 0. 440 0. 0. O. 0. 0. 0. 281 545 170 127 375 0. 259 0. 269 0. 885 0. 274 0. 129 0. 0. 0. c;c;/ 561 253 0. 337 0. 344 999 270 105 660 087 0. 0. 1. 1. 0. 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 0. 932 1. 193 292 100 111 816 015 731 535 354 115 197 217 211 547 0. 872 O. 518 100 131 305 094 5SS 440 >B1 545 170 220 127 0. 375 0. 259 0. 269 0. 885 O. 1. 0. O. 1. 0. 1. 1. 1. 1. 1. 1. o. 1. 1. 1. 1. o. o. 0. o. o. o. 0. o. 0. o. o. 0. 0. 0. o. o. 1. 1. 274 129 227 561 253 337 344 999 270 105 660 0. 087 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 00 00 00 00 00 00 1. 00 00 00 1. 00 00 00 00 00 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 00 00 00 00 SZTop^^ 300285 Data Subject 7c \hU'h'>--- Quantitation Report File: BS110994C r Data: BS110994C. TI 11/09/94 11:08:00 • Sample: SSTD020 290-02-SVlO Conds.: RTX-5 0. 25MM X SOM l.OUM 45/4-325@20 .1 Formula: X X X Instrument: B Submitted by: Analyst: JAM INST B Weight: Acct. No. 1. 001 AMOUNT=AREA « REF AMNT/(REF AREA # RESP FACT) Resp. fac. from Library Entry No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 32 83 84 85 No 51 52 53 54 55 56 57 58 Name C550 C321 C555 C560 C565 C570 C543 C580 C585 C590 C595 C610 C615 C625 C630 C635 C650 C655 D200 C647 C715 C720 C725 C730 C740 C735' C760 C765 C770 C775 C780 C785 C790 C640 C645 m/z 153 232 184 109 168 165 165 149 ' ^ACENAPHTHENE 0. 8 2.3,4,6-TETRACHLOROPHENDL &2,4DINITROPHENOL 8<4NITROPHENOL DIBENZOFURAN 2,4DINITR0T0LUENE 2,6DINITR0T0LUENE DIETHYL PHTHALATE 4CHL0R0PHENYL PHEN FLUORENE 4-NITROANILINE 0. 8 0. 2 0. 2 0. 4 0. 9 4,6DINITR02METHYLPH ^DIPHENYLAMINE 4BR0M0PHENYL PHENY CL6BENZENE *PENTACHL0R0PHEN0L DI-NBUTYLPHTHALATE ^FLUORANTHENE 0. 1 0. 1 0. 05 0. 6 1,2-DIPHENYLHYDRAZINE CARBAZOLE PYRENE 0. 6 BUTYLBENZYLPHTHALATE 3,3'CL2BENZIDINE BENZO(A)ANTHRACENE 0. 8 BIS(2ETHYLHEXYL)PHTH CHRYSENE 0. 7 #DI-N-OCTYLPHTHALATE BENZO(B)FLUORANTHE BENZO(K)FLUORANTHE *^BENZO(A)PYRENE INDENOd, 2, 3CD)PYR DIBENZO(A, H)ANTHRA BENZO(G, H, DPERYLE PHENANTHRENE ANTHRACENE Scan Time Ref 7S3 13:03 3 1. 811 13:31 3 1. 786 13:06 3 1. 792 13:12 3 1. 796 13: 16 3 1. 798 13: 18 3 1. 763 12: 43 3 0. 817 13: 37 3 1. 0. 7 0. 7 0. 7 0. 5 0. 4 0. 5 0. 7 0. 7 RRT 004 040 008 015 021 023 978 047 T T T Meth A A A A A A A A BB BB BB BB BB BB BB BB Area(Hght) 9553. 3119. 1100. 686. 14138. 3534. 2928. 10779. Amount 10. 10. 10. 10. 10. 10. 10. 10. 000 000 000 000 000 000 000 000 PPB PPB PPB PPB PPB PPB PPB PPB 7.Tot 10 10 10 10 10 10 10 10 Data Subject To ya!idatJoj>„ 300286 No 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 m/z 204 166 138 198 169 248 284 266 149 202 77 167 202 149 252 228 149 228 149 252 252 252 276 278 276 178 178 Scan Time F ] 825 13:45 827 13:47 835 13: 55 835 13: 55 836 13: 56 869 14:29 884 14:44 900 15:00 960 16:00 1022 17:02 839 '13:59 933 15: 33 1044 17:24 1098 IB: 18 1167 19:27 1173 19:33 1163 19:23 1179 19:39 1262 21:02 1371 22:51 1376 22:56 1453 24: 13 1B36 30:36 1842 30:42 1950 32:30 915 15: 15 918 15: 18 Ret(L) Ratio R R T ( L : 13: 13: 13: 13: 13: 13: 12: 13: 13: 13: 13: 13: 13: 14: 14: 15: 16: 17: 13: 15: 17: 18: 19: 19: 19: 19: 21: 03 31 06 12 16 18 43 37 45 47 55 55 56 29 44 00 00 02 59 33 24 18 27 33 23 39 02 1.00 1.004 1. 00 1. 040 1. 00 1. 008 1.00 1.015 1.00 1.021 1. 00 1. 023 1.00 0.978 1.00 1.047 1.00 1.058 1.00 1.060 1.00 1.071 1. 00 0. 915 1.00 0.916 1.00 0.952 1.00 0.968 1. 00 0. 986 1.00 1.051 1. 00 1. 119 1. 00 0. 919 1.00 1.022 1. 00 0. 888 1.00 0.934 1.00 0.992 1. 00 0. 997 1.00 0.989 1.00 1.003 1.00 0.859 lef 3 3 3 4 4 4 4 4 4 4 4 4 5 5 5 5 5 5 6 6 6 6 6 6 6 4 4 1 Ri RRT^ 1. 058 1. 060 1. 071 0. 915 0. 916 0. 952 0. 968 0. 986 1. 051 1. 119 0. 919 1. 022 0. 888 0. 934 0. 992 0. 997 0. 989 1. 003 0. 859 0. 933 0. 936 0. 988 1. 249 1. 253 1. 327 1. 002 1. 005 3ti 0 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 , 00 , 00 , 00 , 00 , 00 , 00 , 00 , 00 , 00 . 00 . 00 . 00 Meth A BB A BB A VB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BV A BB A VB A BB A BV A VB A BB A BB A BB A BB Area(Hght) 5345. 11505. 1539. 1896. 6620. 2962. 2889. 1684. 19015. 16186. 11572. 13167. 16994. 8488. 3485. 14398. 11639. 13060. 19173. 13884. 12380. 12605. 13221. 10243. 11093. M XXOiihA'/ 15659. M xx' ^ 16210. Amnt 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10.-00 Amnt(L) 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 sjrD()>-i-p dZli9'i5^^ Amount 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. ooo 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 R. Fac R. F 0. 0. 0. 0. 1. 0. 0. 1. 0. 1. 0. 0. 0. 0. 0. 0. 1. 1. 0. 0. 1. 0. 0. 1. 0. 1. 1. Data 913 298 105 066 351 338 280 030 511 100 147 121 424 190 185 108 218 037 741 844 362 680 279 154 933 , 047 PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB ac(L) 0. 913 0. 298 0. 105 0. 066 1. 35i 0. 338 0. 280 1. 030 0. 511 1. 100 0. 147 0. 121 0. 424 0. 190 0. 185 0. 108 1. 218 1. 037 0. 741 0. 844 1. 362 0. 680 0. 279 1. 154 0. 933 1. 047 y.Tot Rat: , 441 1. 441 1. ^ 3002) I Subject To Validation 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 Lo 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 37 ~~ . y No 73 79 80 31 82 83 84 85 Ret(L) 22: 51 22: 56 24: 13 30: 36 30: 42 32:30 15: 15 15: 18 Ratio 00 00 00 00 00 00 00 00 RRT(L) 0. 933 0. 936 0. 988 1. 249 1. 253 1. 327 1. 002 1. 005 Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 _ Amnt TO. 00 10. 00 10. 00 10. 00 10. 00 lO.'OO 10. 00 10. 00 Amnt(L) 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 i'JTP*^* '^sn^'ii'ic R. Fac R. 1. 044 0. 931 0. 948 0. 994 0. 770 0. 834 1. 003 1. 039 Fac(L) 1. 044 0. 931 0. 948 0. 994 0. 770 0. 834 1. 003 1. 039 Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 Data Subject To Validation 300288 'f«J DATA FROM FILE: BS110994D SCANS 362 TO 1102 ACQUIRED: 11/09/94 11:48:00 CALI: BSU0'394D #1 SAMPLE: SSTD120 298-82-SU60 CONDS.: RTX-5 0.25MM X 30M l.OUM 45/4-525@20 INST B 400 . 6:40 500 . 3:20 600 . 10:00 700 . 11:40 800 _ 13:20 O di g» 900 5: 15:00 o ft ^ 1000 -• - O g 16:40 J- l l f?i J 00 \ vo I ± CS58 2-FLUOROPHENnL 8.6 (SS-5) 188.8.'; ( 143872.) ^ - GGin D6 PIIEHQL 0.8 (SS-4) OlOn D-1 1..4 DICHLOROBENZENE (IS-1) - CS75 1..2-CL2BENZENE-D4 0.4 (SS-8) JuSSe- D5-NITROBENZENE 0.2 (SS-1) "TiMO DO'MllPHTHALENE (IS-2) CS25 2-FLUOROBIPHENYL 0.7 (SS-2) CI58 CHe-ACENAPHTHENE (IS-3) CS55 2.4.6TRIBROMOPHENOL (SS-6) £yE====tiS-4) C53S D14-P-TERPHENYL 0.5 (SS-3) <:o (• r < • I'i; J DATA FROM FILE: BSl183940 SCANS 1102 TO 2888 ACQUIRED: 11/89/94 11:48:88 CALI: BSl109940 #1 SAMPLE: SSTD120 29e-02-SU60 CONDS.: RTX-5 0.25MM X 30M 1.0UM 45/4-325620 INST B 1200 . 20:00 1408 _ 23:20 1600 . 26:40 C w r-r p . cn "H": 1800 . §. 30:00 5* O Ci- tOi 5* vo 1 3 o Si -I I I 100.0^ ( 76800.) •«Tqr-1!rfawigfflTfftNE (IS-5) CI75 D12-PERYLENE (IS-6) Quantitation Report File: BS110994D # ! Data: BS110994D. TI 11/09/94 11:48:00 Sample: SSTD120 290-02-SV60 onds.: RTX-5 0. 25MM X SOM l.OUM 45/4-325(520 Formula: X X X Instrument: B Submitted by: Analyst: JAM INST B Weight: Acct. No. 1. 001 AMOUNT=AREA * REF AMNT/(REF AREA * RESP FACT) Resp. fac. from Library Entry No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 IB 19 20 21 22 23 24 25 26 27 23 29 30 31 32 33 34 35 36 37 33 39 40 41 42 43 44 45 46 47 Name CI30 CI40 CI50 CI 60 CI70 CI75 CS50 CS4 5 CS20 CS25 CS55 CS30 CS70 CS75 C315 C325 C330 C335 C340 C320 C310 C319 C345 C350 C355 C357 C365 C370 C375 C410 C415 C420 C425 C430 C435 C440 C445 C450 C455 C460 C465 C470 C510 C515 C520 C525 C530 6 8 n O. 7 D4-l,4 DICHLOROBENZENE D8-NAPHTHALENE D10-ACENAPHTHENE D10-PHENANTHRENE D12-CHRYSENE D12-PERYLENE 2-FLUOROPHENOL D5-PHEN0L D5-NITR0BENZENE 2-FLUOROBIPHENYL 2,4,6TRIBR0M0PHEN0L D14-P-TERPHENYL O. 5 2-CHL0R0PHEN0L-D4 0.8 1, 2-CL2BENZENE-D4 0. 4 *PHENOL 0. 8 BIS(2CHL0R0ETHYL)E 0.7 2CHL0R0PHEN0L 0.8 1, 3DICHL0R0BENZENE O. 6 *1, 4DICHL0R0BENZENE 0.5 ANILINE N-NITROSODIMETHYLAMINE PYRIDINE BENZYL ALCOHOL 1,2DICHL0RDBENZENE 0. 4 2METHYLPHEN0L 0. 7 2, 2'OXYBISdCHLORDPR 4METHYLPHEN0L 0.6 &NITROSOPROPYLAMINE O. 5 0. 3 0. 2 0. 4 0. 1 0. 3 0. 2 0. 2 0. 7 (IS-1) (IS-2) (IS-3) (IS-4) (IS-5) (IS-6) (SS-5) (SS-4) (SS-1) (SS-2) (SS-6) (SS-3) (SS-7) (SS-8) HEXACHLOROETHANE NITROBENZENE ISOPHORONE <t2-N I TROPHENOL 2,4-DIMETHYLPHENOL 0.2 BENZOIC ACID BIS(2CHL0R0ETH0XY) *2,4DICHLOROPHENOL 1,2,4TRICHLOROBENZ NAPHTHALENE 4-CHLOROANILINE «CL6BUTADIENE *4CHL0R03METHYLPHEN 0. 2 2METHYLNAPHTHALENE 0. 4 ?<CL6CYCL0PENTADIENE *246TRICHLDR0PHNE0L 0.2 2, 4, 5TRICHL0R0PHEN O. 2 2CHL0R0NAPHTHALENE 0. 8 2-NITROANILINE T T T T T 300291 Data Subject To Validation ^ No ^ 48 ^ 49 ^ ^ 50 ^ ^ No 1 2 3 4 5 6 7 B 9 10 11 12 13 14 15 16 17 IS 19 20 21 22 ^ ^ 2 3 A 24 - ^ 25 26 27 28 29 30 31 32 33 34 35 36 37 33 39 40 41 42 43 44 45 46 47 ^ 4 8 ^ • 4 9 ^ 5 0 Name C535 C540 C545 m/z 152 136 164 188 240 264 112 99 82 172 330 244 132 152 94 93 128 146 146 93 74 79 108 146 108 45 108 70 117 77 82 139 107 122 93 162 ISO 128 127 225 107 142 237 196 196 162 65 163 152 138 ~ DIMETHYL PHTHALATE ACENAPHTHYLENE 3-NITROANILINE Scan 502 . 620 780 913 1177 1471 378 474 557 717 852 1054 485 520- 476- 481- 486 498- 503- 476' 199 199 518- 521- 530- 530 543- 545 549 559 579 537 590 • 606- 593 609 616 622 629 636 671 684 703 711 716' 728 741 756 767 779 Time 8: 22 10:20 13:00 15: 13 19: 37 24: 31 6: 18 7: 54 9: 17 11: 57 14: 12 17: 34 8: 05 8: 40 7: 56 8: 01 8: 06 8: IS 8:23 7: 56 3: 19 3: 19 8: 38 8: 41 8: 50 8: 50 9: 03 9: 05 9: 09 9: 19 9: 39 9: 47 9: 50 10: 06 9: 58 10:09 10: 16 10:22 10: 29 10: 36 11: 11 11; 24 11:43 11: 51 11: 56 12: OS 12: 21 12: 36 12:47 12: 59 Ref 1 2 3 4 5 6 1 1 2 3 3 5 2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3 1. 3 RRT 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 0. 753 0. 944 0. 898 0. 919 1. 092 0. 895 0. 966 1. 036 0. 948 0. 958 0. 968 0. 992 1. 002 0. 943 0. 396 0. 396 1. 032 1. 038 1. 056 1. 056 1. 082 1. 086 1. 094 0. 902 0. 934 0. 947 0. 952 0. 977 0. 965 0. 982 0. 994 1. 003 1. 015 1. 026 1. 082 1. 103 0. 901 0. 912 0. 913 0. 933 0. 950 0. 969 0. 933 0. 999 Meth A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A BB BB BB BB BB BB BB BV BB. BB BB BB BB BB BB VB BB BV VB BV BB BB BV BB VB BB BB BB BB BB BV BB BB VB BB BB BB BV BB BB BB BB BB BV VB BB BB BB BB VB AreatHght) 10537. 35662. 19566. 29511. 18310. 16752. 32550. 42973. 31873. 60592. 7146. 47947. 35752. 22656. 51743. 45939. 36433. 40853. 41213. 45849. 20700. 29433. 19544. 38563. 33006. 42716. 32504. 20736. 14837. 34432. 65071. 19786. 23894. 17435. 44033. 28289. 29790. 89113. 38328. 13762. 27336. 66210. 17508. 19552. 22302. 59680. 17201. 65299. 91731. 9340. jrroJT-v B^D^I ^ ' \ Q Amount 20. 000 20. 000 20. 000 20. 000 20. 000 20. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 ry-it^-i ^iihie PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB 7.Tot 0. 41 0. 41 0. 41 0. 41 0. 41 0. 41 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 300292 ciToVairdation ^ - J 1 * -_ - M \ J No 1 2 ^ 3 i ^ 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 1^28 • 2 9 ^ 3 0 31 32 33 34 35 36 37 33 39 40 41 42 43 44 45 46 47 43 49 50 ^ Ret(L) 8:22 10:20 13: 00 15: 13 19:37 24:31 6: 13 7: 54 9: 17 11: 57 14: 12 17: 34 8: 05 8: 40 7: 56 8:01 8: 06 8: IS S: 23 7: 56 3: 19 3: 19 8: 38 8:41 8: 50 8: 50 9: 03 9: 05 9: 09 9: 19 9: 39 9: 47 9: 50 10: 06 9: 58 10: 09 10: 16 10:22 10: 29 10: 36 11: 11 11:24 11:43 11: 51 11: 56 12:03 12:21 12:36 12:47 12: 59 Ratio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 , 00 . 00 . 00 . 00 RRT(L) 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 0. 753 0. 944 0. 393 0. 919 1. 092 0. 895 0. 966 1. 036 0. 943 0. 958 0. 968 0. 992 1. 002 0. 94B 0. 396 0. 396 1. 032 1. 038 1. 056 1. 056 1. 082 1. 086 1. 094 0. 902 0. 934 0. 947 0. 952 0. 977 0. 965 0. 982 0. 994 1. 003 1. 015 1. 026 1. 082 1. 103 0. 901 0. 912 0. 91S 0. 933 0. 950 0. 969 0. 983 0. 999 Ratio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 . 00 , 00 , 00 . 00 ^ Amnt "20. 00 20. 00 20. 00 20. 00 20.^00 20.*00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 Amnt(L) 20. 00 20. 00 20. 00 20. 00 20. 00 20. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 VOT»/I^ 'szmw^ R. Fac R. 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 1. 030 1. 359 0. 298 1. 032 0. 122 0. 873 1. 131 0. 717 1.637 1. 453 1. 153 1. 292 1. 304 1. 450 0. 655 0. 931 0. 618 1. 220 1. 044 1. 351 1. 028 0. 656 0. 469 0. 322 0. 603 0. 185 0. 223 0. 163 0. 412 0. 264 0. 278 0. 833 0. 363 0. 129 0. 256 0. 619 0. 298 0. 333 0. 380 1. 017 0. 293 1. 112 1. 563 0.159 Fac(L) 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 1. 030 1. 359 0. 298 1. 032 0. 122 0. 873 1. 131 0. 717 1. 637 1. 453 1. 153 1. 292 1. 304 1. 450 0. 655 0. 931 0. 618 1. 220 1. 044 1. 351 1. 028 0. 656 0. 469 0. 322 0. 608 0. 185 0. 223 0. 163 0. 412 0. 264 0. 278 0. 833 0. 363 0. 129 0. 256 0. 619 0. 298 0. 333 0. 330 1. 017 0. 293 1. 112 1. 563 0. 159 Ratio 1 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 , 00 00 .00 . 00 . 00 . 00 . 00 . 00 . 00 300293 Data Subject To Validation Quantitation Report File: BS110994D f Data: BS110994D. TI 11/09/94 11:48:00 ^beample: SSTD120 290-02-SV60 UPconds. : RTX-5 0. 25MM X SOM l.OUM 45/4-325e20 * Formula: X X X Instrument: B Submitted by: Analyst: JAM INST B Weight: Acct. No. 1. 001 AMOUNT=AREA « REF AMNT/(REF AREA * RESP FACT) Resp. fac. from Library Entry No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 31 32 83 84 35 No 51 52 53 54 55 56 57 58 Name C550 C321 C555 C560 C565 C570 C543 C5S0 C5S5 C590 C595 C610 C615 C625 C630 C635 C640 C645 C650 C655 D200 C647 C715 C720 C725. C730 C740 C735 C760 C775 C780 C785 C790 C765 C770 m/z 153 232 184 109 168 165 165 149 ' ^ACENAPHTHENE 0.8 2,3,4,6-TETRACHLOROPHENOL ?<2, 4DINITR0PHEN0L 8<4NITROPHENOL DIBENZOFURAN 0.8 2, 4DINITR0T0LUENE 0. 2 2,6DINITR0T0LUENE 0.2 DIETHYL PHTHALATE 4CHL0R0PHENYL PHEN 0.4 FLUORENE 0.9 4-NITROANILINE 4,6DINITR02METHYLPH ^DIPHENYLAMINE 4BR0M0PHENYL PHENY 0. 1 CL6BENZENE 0. 1 ^PENTACHLOROPHENOL 0. 05 PHENANTHRENE 0. 7 ANTHRACENE 0. 7 DI-NB UTYLPHTHALATE *FLUORANTHENE 0. 6 1,2-DIPHENYLHYDRAZINE CARBAZOLE ' PYRENE 0. 6 BUTYLBENZYLPHTHALATE 3,3'CL2BENZIDINE BENZO(A)ANTHRACENE 0.3 BIS(2ETHYLHEXYL)PHTH CHRYSENE 0. 7 *DI-N-OCTYLPHTHALATE *BENZO(A)PYRENE 0.7 INDENOd, 2, 3CD)PYR 0.5 DIBENZO(A, H)ANTHRA 0.4 BENZO(G, H, DPERYLE 0.5 BENZO(B)FLUORANTHE 0.7 BENZO(K)FLUORANTHE 0.7 Scan Time Ref RRT 783 13:03 3 1.004 812 13:32 3 1.041 787 13:07 3 1.009 793 13:13 3 1.017 797 13: 17 3 1. 022 800 13:20 3 1.026 764 12:44 3 0.979 818 13:38 3 1.049 T T T Me A A A A A A A A 'th BB BB BB BB BB BB BB FB Area(Hght) 52715. 18594. 10409. 5381. 75675. 22170. 17232. 61901. Amount 60. 60. 60. 60. 60. 60. 60. 60. 000 000 000 000 000 000 000 000 PPB PPB PPB PPB PPB PPB PPB PPB_ 7.Tot 1. 23 1. 23 1. 23 1. 23 1. 23 1.23 1. 23 . y-.23- 300294 Data Subject To Validation No 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 I75 76 77 m/z 204 166 138 198 169 248 284 266 178 178 149 202 77 167 202 149 252 228 149 228 149 252 276 278 276 252 252 Scan T 826 13 829 13 837 13 837 13 838 13 869 14 885 14 901 15 916- 15 920- 15 961 '16 1023- 17 841 14 935 15 1045- 17 1098 18 1170 19 1174. 19 1164 19 1181 19 1264 21 1457 24 1843 30 1851 30 1961 32 1374- 22 1380- 23 Ret(L) Ratio 13: 13: 13: 13: 13: 13: 12: 13: 13: 13: 13: 13: 13: 14: 14: 15: 15: 15: 16: 17: 14: 15: 17: 18: 19: 19: 19: 03 32 07 13 17 20 44 38 46 49 57 57 58 29 45 01 16 20 01 03 01 35 25 18 30 34 24 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 ime F :46 :49 : 57 : 57 : 58 :29 :45 : 01 : 16 :20 : 01 :03 :01 : 35 : 25 : 18 : 30 :34 :24 : 41 :04 : 17 :43 : 51 :41 : 54 :00 R R T ( L : 1. 004 1. 041 1. 009 1. 017 1. 022 1. 026 0. 979 1. 049 1. 059 1. 063 1. 073 0. 917 0. 918 0. 952 0. 969 0. 987 1. 003 1. 008 1. 053 1. 120 0. 921 1. 024 0. 388 0. 933 0. 994 0. 997 0. 989 lef 3 3 3 4 4 4 4 4 4 4 4 4 4 4 5 5 5 5 5 5 6 6 6 6 6 6 6 • R< RRT~ 1. 059 1. 063 1. 073 0. 917 0. 918 0. 952 0. 969 0. 987 1. 003 1. OOS 1. 053 1. 120 0. 921 1. 024 0. 383 0. 933 0. 994 0. 997 0. 939 1. 003 0. 859 0. 990 1. 253 1. 258 1. 333 0. 934 0. 933 atio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 , 00 . 00 . 00 Meth A BB A BB A VB A BB A BB A BB A BB A BB A BV A VB A BB A BB A BB A BB A BB A BB A BB A BV A BB A VB A BB A BB A BB A BB A BB M xxa»")' M XX^ Amnt 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60.00 Area(Hght> 32173. 68643. 6633. 12852. 36106. 15838. 16296. 12616. 93076. 94272. 112068. B3216. 74249. 41797. 79977. 41173. 4604. 60473. 55996. 55856. 84020. 46588. 44926. 34808. 36370. '1'^ 57638. •i- 48508. Amnt(L) 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 smn? ^SIKI^IIIO Amount 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 R. Fac R. F 0. 0. 0. 0. 1. 0. 0. 1. 0. 1. 0. 0. 0. 0. 0. 0. 1. 1. 1. 0. 0. 0. 1. 0. 0. 1 1 898 317 177 092 289 378 294 055 543 169 113 145 408 179 184 143 051 065 266 940 839 472 456 750 - , 084 . 101 . 019 Data ^1 PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB ac(L) 0. 898 0. 317 0. 177 0. 092 1. 239 0. 378 0. 294 1. 055 0. 548 1. 169 0. 113 0. 145 0. 408 0. 179 0. 184 0. 143 1. 051 1. 065 1. 266 0. 940 0. 839 0. 472 1. 456 0. 750 0. 084 1. 101 1. 019 y.Tot 1. \ , Rat: 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 io 00 00 00 00 00 00 00 , 00 00 00 , 00 00 00 00 00 00 00 , 00 00 00 00 00 00 00 , 00 . 00 . 00 300295 ihiprt Tn , Valii Satic No 78 79 80 81 82 83 84 85 Ret(L) 19:41 21:04 24: 17 30:43 30: 51 32:41 22: 54 23:00 Ratio 00 00 00 00 00 00 00 00 RF 1. 0. 0. 1. 1. 1. 0. 0. ?T<L) 003 859 990 253 258 333 934 938 Ri atio 00 00 00 00 00 00 00 00 - Amnt Amnt(L) 60. 00 60. 00 60. 00 60. 00 60.'00 60. 00 60. 00 60. 00 •^Sll<>'i'iHO 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 R. Fac R. 1. 017 1. 672 0. 927 0. 894 0. 693 0. 724 1. 147 0. 965 Fac(L) 1. 017 1. 672 0. 927 0. 894 0. 693 0. 724 1. 147 0. 965 Rat: io 00 00 00 00 00 00 00 00 300296 Data Subject To Valldationi iMii DATA FROM FILE: BS110334E SCAHS 367 TO 1197 ACQUIRED: 11/09/94 12:29:08 CALI: BS110994E #1 SAMPLE: SSTDO80 290-02-SU40 CONDS.: RTX-5 0.25MM X 38M 1.0UM 45/4-325228 488 J 6:40 508 8:20 600 . 10:00 J a i 700 _ 11:40 800 . 1 3 •'^'0 i tn • c a)° a •—{ Ui % M ) a, VO 5i -J fee 988 . 15:60 >1000 . >16:40 ?i INST B — J 100.8^ ( 92888.) esse 2-FLUOROPHENOL 8.6 (SS-5) "6545 D5-PHEN0L 0.8 (SS-4) dlOO D'l 1,4 DICHLOROBENZENE (IS-1) CS75 L2-CL2BENZENE-D4 8.4 (SS-8) -GS20 D5-NITROBENZENE 0.2 (SS-1) GI-1Q DO NMPHTHALEME -=^-—CI^.£i Die-ACENAPHTHENE (IS-2) CS25 2-FLUORnBIPHENYL 8.7 (SS-2) (IS-3) CS55 2..4.6TRIBR0M0PHEN0L (SS-6) joma i.r.Mi.i.ifliif-PHFMnNTHPFMF (IS-4) CS30 D14-P-TERPHENYL 8.5 (SS-3) o • < : CD 4*- ZD . '•»< Jl DATA FROM FILE: BS110334E SCANS 1187 TO 2808 ACQUIRED: 11/89/94 12:29:80 CALI: BS110994E #1 SAMPLE: SSTDOSO 290-02-SU40 CONDS.: RTX-5 0.25MM X 38M 1.8UM 45/4-325@20 INST B 1288 . 20:00 1408 4 23:20 1688 . 26:48 1888 J .30:00 I •J 100.0,"^ ( 55488.) JTffl OianCMRYSENE (IS-5) CI75 D12-PERYLENE (IS-6) o o o* to ^ vo w^ 00 I m -• :3 Quantitation Report File: BS110994E Data: BS110994E. TI 11/09/94 12:29:00 ample: SSTDOSO 290-02-SV40 onds.: RTX-5 0. 25MM X 30M l.OUM 45/4-325^20 Formula: X X X Instrument: B Submitted by: Analyst: JAM INST B Weight: Acct. No. 1. 001 AMOUNT=AREA « REF AMNT/(REF AREA * RESP FACT) Resp. fac. from Library Entry No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 23 29 30 31 32 33 34 35 36 37 33 39 40 41 42 '43 44 45 46 47 Name CI30 CI40 CI 50 CI60 CI70 CI75 CS50 CS45 CS20 CS25 CS55 CS30 CS70 CS75 C315 C325 C330 C335 C340 C320 C310 C319 C345 C350 C355 C357 C365 C370 C375 C410 C415 C420 C425 C430 C435 C440 C445 C450 C455 C460 C465 C470 C510 C515 C520 C525 C530 D4-l,4 DICHLOROBENZENE DS-NAPHTHALENE DIO-ACENAPHTHENE D10-PHENANTHRENE D12-CHRYSENE D12-PERYLENE 2-FLUOROPHENOL 0. 6 D5-PHEN0L 0. 3 D5-NITR0BENZENE 0.2 2-FLUOROBIPHENYL 0.7 2,4,6TRIBROMOPHENOL D14-P-TERPHENYL O. 5 2-CHL0R0PHEN0L-D4 0. 3 1,2-CL2BENZENE-D4 0. 4 *PHENOL 0. 8 BIS(2CHL0R0ETHYL)E 0.7 2CHL0R0PHEN0L 0.8 1,3DICHL0R0BENZENE 0.6 *1,4DICHL0R0BENZENE 0.5 ANILINE N-NITROSODIMETHYLAMINE PYRIDINE BENZYL ALCOHOL 1,2DICHL0R0BENZENE 0.4 2METHYLPHEN0L O. 7 2,2'0XYBIS(1CHL0R0PR 4METHYLPHEN0L 0. S<N I TROSOPROP YLAM INE 0. HEXACHLOROETHANE 0. NITROBENZENE 0. ISOPHORONE 0. *f2-NITR0PHEN0L 0. 2,4-DIMETHYLPHENOL 0. BENZOIC ACID BIS(2CHL0R0ETH0XY) 0. *2, 4DICHLOROPHENOL 0. 1,2, 4TRICHL0R0BENZ 0. NAPHTHALENE 0. 4-CHLOROANILINE «-CL6BUTADIENE »4CHL0R03METHYLPHEN O. 2METHYLNAPHTHALENE 0. 8<CL6CYCLOPENTADIENE i*246TRICHL0R0PHNE0L 0. 2, 4, 5TRICHL0R0PHEN 0. 2CHL0R0NAPHTHALENE 0. 2-NITROANILINE (IS-1) (IS-2) (IS-3) (IS-4) (IS-5) (IS-6) (SS-5) (SS-4) (SS-1) (SS-2) (SS-6) (SS-3) (SS-7) (SS-8) T T T T T T T 3 300299 Data Subject To Validation No Name - 48 C535 DIMETHYL PHTHALATE 49 C540 ACENAPHTHYLENE 1.3 50 C545 3-NITROANILINE No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 m/z 152 136 164 188 240 264 112 99 82 172 330 244 132 152 94 93 128 146 146 93 74 79 108 146 108 45 108 70 117 77 82 139 107 122 93 162 180 128 127 225 107 142 237 196 196 162 65 163 152 133 Scan 507' 622 7S0 913 1177 1471 394 481 560 718 852 1054 491 525- 482. 487- 493 504 . 509. 483- 229 227 522 • 526. 533. 534 546. 547 553 562 581 590 592- 605. 600 611 618 624 630 637 672 635 703 712. 716- 729 741 756 767 779 Time 8: 10: 13: 15: 19: 24: 6: S: 9: 11: 14: 17: 8: 8: 8: 8: 8: 8: 8: 8: 3: 3: 8: 8: 8: 8: 9: 9: 9: 9: 9: 9: 9: 10: 10: 10: 10: 10: 10: 10: 11 11 11 11 11 12 12 12 12 12 27 22 00 13 37 31 34 01 20 58 12 34 11 45 02 07 13 24 29 03 49 47 42 46 53 54 06 07 13 22 41 50 52 05 00 11 18 24 30 37 12 25 43 52 56. 09 21 36 47 59 Ref 1 2 3 4 5 6 1 1 2 3 3 5 2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3 0. 0. 0. 0. 1. 0. 0. 1. 0. 0. 0. 0. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0 0 0 0 0 0 0 0 RRT 000 000 000 000 000 000 777 949 900 921 092 895 968 036 951 961 972 994 004 953 452 448 030 037 051 053 077 079 091 904 934 949 952 973 965 982 994 003 013 024 080 101 901 913 918 935 950 969 983 999 ME A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A 'th BB BB BB BB BB BB BB BV BB BB BB BB BB BB BB VB BB BV VB BV BB BB BV BB VB BB BB BB BB BB BV BB BB VV BB BB BB BV VB BB BB BB BB BV VB BB BB BB BB BB Area(Hght) 10393. 36125. 19679. 29242. 19946. 18707. 20743. 28455. 21251. 44688. 4729. 35386. 23521. 15358. 33732. 28830. 22939. 26119. 26109. 30327. 13412. 19137. 11839. 23613. 19870. 26404. 21332. 12475. 9384. 21442. 40927. 12547. 16209. 10139. 28210. 18083. 19931. 63233. 23529. 9186. 16605. 42392. 10697. 12762. 13506. 40555. 10137. 41643. 60635. 4997. irro^i'ff'^. ?<r!H>'i'i4^ Amount 20. 000 20. 000 20. 000 20. 000 20. 000 20. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. boo 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 Data Sub PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB y.Tot 0. 61 0. 0. 0. 0. 0. 61 61 61 61 61 22 22 22 22 22 22 22 22 22 . 22 . 22 . 22 . 22 . 22 . 22 . 22 . 22 .22 22 22 . 22 22 . 22 22 22 22 22 . 22 22 . 22 . 22 . 22 . 22 . 22 . 22 . 22 . 22 . 22 . 22 . 22 . 22 . 22 . 22 r,.nA-r2S 300300 iect To Valid atior No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 IS 19 20 21 22 23 24 25 26 27 23 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 43 49 50 1 Ret(L) 8: 10: 13: 15: 19: 24: 6: 8: 9: 11: 14: 17: S: 8: 8: 8: 8: 8: S: 8: 3: 3: 8: 8: 8: 8: 9: 9: 9: 9: 9: 9: 9: 10: 10: 10: 10: 10: 10: 10: 11: 11: 11: 11: 11: 12: 12: 12: 12: 12: 27 22 00 13 37 31 34 01 20 58 12 34 11 45 02 07 13 24 29 03 49 47 42 46 53 54 06 07 13 22 41 50 52 05 00 11 18 24 30 37 12 25 43 52 56 09 21 36 47 59 Ratio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 , 00 , 00 RRT(L) 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 0. 777 0. 949 0. 900 0. 921 1. 092 0. 895 0. 968 1. 036 0. 951 0. 961 0. 972 0. 994 1. 004 0. 953 0. 452 0. 448 1. 030 1. 037 1. 051 1. 053 1. 077 1. 079 1. 091 0. 904 0. 934 0. 949 0. 952 0. 973 0. 965 0. 9S2 0. 994 1. 003 1. 013 1. 024 1. OSO 1. 101 0. 901 0. 913 0. 918 0. 935 0. 950 0. 969 0. 983 0. 999 Ratio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 ^ . Amnt '20. 00 20. 00 20. 00 20. 00 20.,00 20. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 Amnt(L) 20. 00 20. 00 20. 00 20. 00 20. 00 20. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. OO 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 SiiPpl^<i^ ^/)I<^?J'/P^ R. Fac R. 1. 1. 1. 1. 1. 1. 0. 1. 0. 1. 0. 0. 1. 0. 1. 1. 1. 1. 1. 1. 0. 0. 0. 1. 0. 1. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 0. 1. 1. 0. 000 000 000 000 000 000 997 368 294 135 120 887 131 739 622 386 103 256 255 458 645 920 569 135 955 270 026 600 451 297 566 174 224 140 390 250 276 875 326 127 230 587 272 324 343 030 258 058 542 127 Fac 1. 1. 1. 1. 1. 1. 0. 1. 0. 1. 0. 0. 1. 0. 1. 1. 1. 1. 1. 1. 0. 0. 0. 1. 0. 1. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 0. 1. 1. 0. :(L) 000 000 000 000 000 000 997 368 294 135 120 887 131 739 622 386 103 256 255 458 645 920 569 135 955 270 026 600 451 297 566 174 224 140 390 250 276 875 326 127 230 587 272 324 343 030 258 058 542 127 O 1 Ratio in-a I 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 , 00 00 , 00 00 . 00 . 00 , 00 . 00 . 00 11 Data Subject To Validation Quantitation Report File: BS110994E Data: BS110994E. TI 11/09/94 12:29:00 Sample: SSTDOSO 290-02-SV40 Conds.: RTX-5 0. 25MM X SOM l.OUM 45/4-325^20 Formula: X X X Instrument: B Submitted by: Analyst: JAM INST B Weight: Acct. No. 1. 001 AMOUNT=AREA * REF AMNT/(REF AREA * RESP FACT) Resp. fac. from Library Entry No 51 52 53 54 55 56 57 53 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 SO 81 82 S3 84 35 No 51 52 53 54 55 56 57 58 Name C550 C321 C555 C560 C565 C570 C543 C580 C585 C590 C595 C610 C615 C625 C630 C635 C640 C645 C650 C655 D200 C647 C715 C720 C725. C730 C740 C735 C760 C765 C770 C775 C780 C735 C790 m/z 153 232 184 109 168 165 165 149 ' •ACENAPHTHENE 0. 8 2,3,4,6-TETRACHLOROPHENOL ?<2, 4DINITR0PHEN0L &4NITR0PHEN0L DIBENZOFURAN 2,4DINITR0T0LUENE 2,6DINITR0T0LUENE DIETHYL PHTHALATE 4CHL0R0PHENYL PHEN FLUORENE 4-NITRDANILINE 0. 8 0. 2 0. 2 0. 4 0. 9 4,6DINITR02METHYLPH *DIPHENYLAMINE 4BR0M0PHENYL PHENY CL6BENZENE •PENTACHLOROPHENOL PHENANTHRENE ANTHRACENE DI-NBUTYLPHTHALATE •FLUORANTHENE 0. 1 0. 1 0. 05 0. 7 0. 7 0. 6 1,2-DIPHENYLHYDRAZINE CARBAZOLE PYRENE 0. 6 BUTYLBENZYLPHTHALATE 3,3'CL2BENZIDINE BENZO(A)ANTHRACENE 0. 8 BIS(2ETHYLHEXYL)PHTH CHRYSENE 0. 7 •DI-N-OCTYLPHTHALATE BENZO(B)FLUORANTHE BENZO(K)FLUORANTHE •BENZO(A)PYRENE INDENOd, 2, 3CD)PYR DIBENZO(A,H)ANTHRA BENZO(G, H, DPERYLE Scan Time Ref 783 13:03 3 1. 812 13:32 3 1. 787 13:07 3 1. 792 13: 12 ,3 1. 797 13: 17 3 1. 800 13:20 3 1. 764 12: 44 3 0. 818 13:38 3 1. 0. 7 0. 7 0. 7 0. 5 0. 4 0. 5 RRT 004 041 009 015 022 026 979 049 T T T Meth A A A A A A A A BB BB BB BB BB BB BB B'B Area(Hght) 35503. 11928. 6113. 3253. 49328. 14478. 10781. 41159. *% « *^ A O 3uuovj^ Amount 40. 40. 40. 40. 40. 40. 40. 40. 000 000 000 000 000 000 000 000 PPB PPB PPB PPB PPB PPB PPB PPB 7.Tot 22 22 22 22 22 22 22 22 Data Subject To Validation ,'-\ f^ r^ • No 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 30 81 82 83 84 85 No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 •75 76 77 m/z 204 166 138 198 169 248 234 266 173 173 149 202 77 167 202 149 252 228 149 228 149 252 252 252 276 278 276 Scan Time F 326 13:46 323 13:43 336 13: 56 336 13: 56 837 13:57 869 14:29 835 14:45 901 15:01 915- 15: 15 920' 15:20 961 16:01 1023- 17:03 840 14:00 935 15:35 1045- 17:25 1099 18: 19 U 6 9 19: 29 1174* 19:34 1165 19:25 dSl- 19:41 1264 21:04 L374 22:54 L380 23:00 1457 24:17 1842 30: 42 1851 30: 51 1959 32:39 Ret(L) Ratio RRT(L- 13: 13: 13: 13: 13: 13: 12: 13: 13: 13: 13: 13: 13: 14: 14: 15: 15: 15: 16: 17: 14: 15: 17: 18: 19: 19: 19: 03 32 07 12 17 20 44 33 46 43 56 56 57 29 45 01 15 20 01 03 00 35 25 19 29 34 25 1.00 1.004 1. 00 1. 041 1.00 1.009 1.00 1.015 1.00 1.022 1.00 1.026 1.00 0.979 1.00 1.049 1. 00 1. 059 1.00 1.062 1. 00 1. 072 1.00 0.916 1. 00 0. 917 1. 00 0. 952 1.00 0.969 1.00 0.987 1.00 1.002 1. 00 1. 008 1.00 1. 053 1. 00 1. 120 1. 00 0. 920 1. 00 1. 024 1.00 0.883 1.00 0.934 1.00 0.993 1. 00 0. 997 1. 00 0. 990 !ef 3 3 3 4 4 4 4 4 4 4 4 4 4 4 5 5 5 5 5 5 6 6 6 6 6 6 6 RRT- 1. 059 1. 062 1. 072 0. 916 0. 917 0. 952 0. 969 0. 987 1. 002 1. 008 1. 053 1. 120 0. 920 1. 024 0. SSS 0. 934 0. 993 0. 997 0. 990 1. 003 0. 859 0. 934 0. 933 0. 990 1. 252 1. 258 1. 332 Ratio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 ._MG A A A A A A A A A A A A A A A A A A A A A A A A A A A th BB BB VB BB BB BB BB BB BV VB BB BB BB BB BB BB BB BV BB VB BB BV VB BB BB BB BB Amnt 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 Area(Hght 20137. 409£ 2. 5296. 7939. 21070. 102S 9. 10934. 7670. 57213. 60407. 75335. 59498. 45689. 29B52. 57772. 29411. 4134. 43367. 39027. 39284. 53391. 37710. 33547. 33359. 34289. 26078. 28595. Amn t(L) 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 00 40. 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 ^su(^^5iy~ ) Amount 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. OOO 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 R. Fac R. F 0. 0. 0. 0. 1. 0. 0. 1. 0 1 0 0 0 0 0 0 0 1 1 1 0 0 1 0 0 1 0 902 303 155 033 253 368 274 046 513 041 135 136 360 175 187 131 978 • 033 2S8 017 781 510 448 737 104 087 978 Data Suk PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB ac(L) 0. 902 0. 303 0. 155 0. 083 1. 253 0. 363 0. 274 1. 046 0. 513 1. 041 0. 135 0. 136 0. 360 0. 175 0. 187 0. 131 0. 978 1. 033 1. 288 1. 017 0. 781 0. 510 1. 448 0. 737 0. 104 1. 087 0. 978 iect To \ y.Tot 1. Rat 3 MiA. 22 22 22 22 22 22 22 22 22 22 22 22 22 22 . 22 22 22 22 22 22 22 22 22 22 22 22 22 io 00 00 00 00 00 00 00 00 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 00303 ^ftnrB No 78 79 80 81 82 83 84 85 Ret(L) 19: 41 21:04 22: 54 23:00 24: 17 30: 42 30: 51 32: 39 Ratio 00 00 00 00 00 00 00 00 / RRT(L) 1. 003 0. 359 0. 934 0. 933 0. 990 1. 252 1. 25S 1. 332 Ratio 00 00 00 00 00 00 00 00 Amnt "^0. 00 40. 00 40. 00 40. 00 40.^00 40. 00 40. 00 40. 00 Amnt(L) 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 SJ'TO(pl^ip Sfn9>')JiB R. Fac R. 0. 935 1. 561 1. 008 0. 897 0. 905 0. 916 0. 697 0. 764 Fac(L) 0. 98,5 1. 561 1. 008 0. 897 0. 905 0. 916 0. 697 0. 764 Rat: io 00 00 00 00 00 00 00 00 m 300304 Jata Subject To Validalion I n i t i a l C a l i b r a t i o n Data m Instrument Identifier: B Calibration Date: 11/09/94 IN RF: SW<?<) = . 05 . CLP = . 01 OR BELOW AX 7.RSD: SW(*) = 307.v/ CLP = 20. 57. Compound RF 10 BF 25 RF 40 RF 60 RF 80 Mean RF 7.RSD CS50 CS45 CS20 CS25 CS55 CS30 CS70 CS75 2-FLUOROPHENOL O. 6 D5-PHEN0L 0. 3 D5-NITR0BENZENE 0. 2 2-FLUOROBIPHENYL 0. 7 2,4,6TRIBR0M0PHEN0L 0. 932 1. 193 0. 292 0. 279 1. 100 1. 063 1. 029 O. 997 1. 330 1. 363 D14-P-TERPHENYL 0. 5 2-CHL0R0PHENDL-D4 O. B 1,2-CL2BENZENE-D4 0. 4 C315 *PHENOL 0. 8 C325 BIS(2CHL0R0ETHYL>E 0.7 C330 2CHL0R0PHEN0L 0.3 C335 1,3DICHL0R0BENZENE 0.6 C340 *1, 4DICHL0R0BENZENE 0.5 C320 ANILINE 0. Ill 0. 816 1. 015 0. 731 1. 535 354 115 197 217 1. 211 0 C310 C319 C345 C350 C355 C357 365 N-NITROSODIMETHYLAMINE 0. 547 0. 626 PYRIDINE BENZYL ALCOHOL 1, 2DICHLOROBENZENE 0. 4 2METHYLPHEN0L 0.7 2, 2'OXYBISdCHLOROPR 4METHYLPHEN0L 0.6 0. 872 O. 987 0. 51S 0. 568 1. 100 1. 131 1. 305 1. 094 370 S<NITROSOPROPYLAMINE O. 5 0. 538 1. 030 0. 992 1. 359 1. 293 294 0. 298 0. 306 135 1. 032 1. 110 120 0. 122 0. 117 887 O. 873 0. 869 131 1. 131 1. 108 714 0. 739 0. 717 O. 719 584 1. 622 1. 637 1. 583 1. 453 1. 337 1. 153 1. 124 1. 292 1. 210 1 1 0 O. 931 569 0. 618 135 1. 220 955 1.044 270 1. 351 0. 115 0. 760 1. 086 0 1 1. 388 1. 092 1. 213 1. 249 1. 403 0. 1. 0. 0. 1. 1. 386 1. 103 1. 256 255 458 645 920 136 034 242 034 1. 1. 0. O. 0. 1. 0. 1. 292 304 450 655 1. 026 1. 028 1. 438 0. 629 O. 876 0. 629 1. 119 1. 006 1. 334 1. 093 605 0. 600 O. 656 0. 620 0. 0. 0. 0. C375 HEXACHLOROETHANE C410 NITROBENZENE C415 ISOPHORONE C420 •2-NITROPHENOL C425 2,4-DIMETHYLPHENOL C430 BENZOIC ACID C435 BIS(2CHL0R0ETH0XY) C440 ^2,4DICHL0R0PHEN0L C445 1,2,4TRICHLOROBENZ C450 NAPHTHALENE C455 4-CHLOROANILINE C460 *CL6BUTADIENE C465 •4CHL0R03METHYLPHEN C470 2METHYLNAPHTHALENE C510 5<CL6CYCLOPENTADIENE C515 •246TRICHLOROPHNEOL 0.2 C520 2, 4, 5TRICHL0R0PHEN 0. 2 C525 2CHL0R0NAPHTHALENE 0.8 C530 2-NITROANILINE C535 DIMETHYL PHTHALATE C540 ACENAPHTHYLENE 1.3 C545 3-NITROANILINE 0. 3 0. 440 0. 457 0. 451 0. 469 0. 449 0. 279 0. 297 0. 322 0. 291 O. 557 0. 566 O. 603 O. 596 0. 157 0. 174 0. 185 0. 190 0. 3 O. 2 0. 2 0. 7 0. 2 0. 4 0. 281 0. 545 0. 170 0. 220 0. 127 0. 375 0. 259 0. 214 0. 121 0. 360 0. 243 0. 224 0. 223 0. 240 0. 140 0. 163 0. 146 0. 390 0. 412 0. 400 0. 250 0. 264 0. 263 0. 269 0. 264 0. 276 O. 273 O. 275 0. 885 0. 847 0. 875 O. 833 0. 841 0. 326 0. 363 0. 370 O. 127 0. 129 O. 128 0. 230 0. 256 0. 246 0. 274 O. 129 0. 280 0. 120 0. 223 C550 •ACENAPHTHENE # 321 2. 3, 4, 6-TETRACHLOROPHE 0. 293 0. 292 0. 303 0. 317 0. 561 0. 570 0. 537 0. 619 0. 576 O. 253 0. 286 0. 272 0. 298 0. 317 0. 337 0. 317 0. 324 0. 333 0. 332 0. 344 0. 342 0. 343 0. 380 0. 369 0.999 0.995 1.030 1.017 1.064 0. 270 0. 255 0. 258 0. 293 0. 277 1. 105 1. 144 1. 058 1. 112 1. 134 1.660 1.608 1.542 1.563 1.413 0. 087 0. 134 0. 127 0. 159 0. 231 0. 902 0. 898 0. 950 0. 297 0. 8 0. 913 0. 916 555 S<2, 4DINITR0PHEN0L 0. 105 0. 128 0. 155 0. 177 0. 170 0. 996 1. 309 0. 294 1. 089 O. 117 0. 841 1. 095 0. 725 1. 593 1. 384 1. 118 1. 234 1. 251 1. 393 0. 621 918 581 143 035 301 056 614 y 454 294 575 0. 176 0. 225 O. 140 0. 383 256 273 857 323 127 237 583 286u^ 329 356 022 271 111 558 143 0. 916 0. 302 0. 148 300305 0. 0. 1. 1. 1. 1. o. 0. 0. O. 0. O. o. 0. o. o. 0. 0. 0. 0. 1. 0. 1. 1. 0. 3. 995 5. 431 3. 356 3. 738 3. 682 6. 244 4. 378 1. 442 2. 483*^ 3. 217 2. 070 3. 203 2. 729 >^ 7. 431 6. 844 5. 114 7. 700 4. 025 6. 216 3. 454 3. 334 267 405 843 624 408 «^ 263 392 5. 192 3. 5 9 9 ^ 2. 181 2. 632 13. 890 2. 817 k/ 5. 883 ^ 3. 826 8. 481 2. 390 t^ 4. 938 2. 705 5. 698 3. 013 5. 944 36. 016 2. 235 ix 3. 154 20. 351 4 2 5 4 7 4 11 Data Subject To Validation m C570 C543 C580 535 C590 C595 C610 C630 C635 C640 C645 C650 C647 C715 C720 C725 C730 C740 C735 -m C560 &4NITRDPHEN0L C565 DIBENZOFURAN 0.8 2. 4DINITR0T0LUENE 0. 2 2, 6DINITR0T0LUENE 0. 2 DIETHYL PHTHALATE 4CHL0R0PHENYL PHEN 0. 4 FLUORENE 0. 9 4-NITROANILINE 4,6DINITR02METHYLPH C615 •DIPHENYLAMINE C625 4BR0M0PHENYL PHENY 0. 1 CL6BENZENE 0. 1 •PENTACHLOROPHENOL 0. 05 PHENANTHRENE 0. 7 ANTHRACENE O. 7 DI-NBUTYLPHTHALATE C655 •FLUORANTHENE 0. 6 D200 1,2-DIPHENYLHYDRAZINE CARBAZOLE PYRENE 0. 6 BUTYLBENZYLPHTHALATE 3.3'CL2BENZIDINE BENZO(A)ANTHRACENE 0. 8 BIS(2ETHYLHEXYL)PHTH CHRYSENE O. 7 C760 •DI-N-OCTYLPHTHALATE C765 BENZO(B)FLUORANTHE 0.7 C770 BENZO(K)FLUORANTHE 0.7 C775 •BENZO(A)PYRENE 0.7 C780 INDENOd, 2, 3CD)PYR 0.5 785 DIBENZO(A,H)ANTHRA 0.4 C790 BENZO(G, H, DPERYLE 0.5 0. 066 0. 086 0. 083 1. 3 5 1 1 . 418 1. 253 0. 338 0. 346 0. 368 0. 230 0. 298 0. 274 1. 030 1. 064 1. 046 0. 511 0. 493 0. 513 1. 100 1.^075 1. 041 0. 147 0.'l42 0. 121 0. 128 0. 424 0. 386 0. 360 0. 190 0. 186 0. 1.75 0. 185 0. 188 0. 187 0. 108 0. 135 0. 131 1. 003 1. 013 0. 978 1. 039 1. 037 1. 033 1. 21S 1. 261 1. 233 1. 037 1. 014 1. 017 0. 741 0. 830 0. 781 0. 844 0. 646 0 1. 362 1. 302 1 0. 680 0. 657 0. 737 0. 279 0. 144 0. 104 1. 056 1. 087 0. 933 0. 972 1. 369 1. 016 0. 777 948 0. B70 0. 905 994 0. 947 0. 916 0. 092 1. 289 0. 378 0. 294 1. 055 0. 548 1. 169 0. 135 0. 113 0. 136 0. 145 0. 408 0. 179 0. 184 0. 143 1. 051 1. 065 1. 266 0. 940 0. 091 1. 294 0. 366 0. 334 1. Ill 0. 532 1. 098 0. OSO 0. 147 0. 382 0. 181 0. 178 0. 146 1. 010 0. 931 1. 191 O. 925 0. 839 0. 369 0. 034^^ 12. 610 1. 154 0. 933 1. 047 1. 441 1. 044 O. 931 0. 0. O. 770 0. 334 0. 710 0. 697 0. 776 0. 764 510 O. 472 443 1. 456 O. 750 0. 084 1. 101 1. 019 1. 017 1. 672 1. 147 O. 965 0. 927 0. 894 0. 693 0. 724 0. 978 0. 985 1. 561 1. 008 0. 897 0. 482 1. 627 0. 746 0. 061 1. 133 1. 026 1. 014 1. 732 1. 177 O. 974 0. 935 0. 845 O. 695 0. 723 O. 1. 0. 1. 0. 0. 1. 322 0. 360 296 06a 520 097 124 136 0. 393 0. 183 0. 185 0. 133 1. 012 1. 021 1. 245 0. 987 0. 813 0. 591 1. 440 O. 714 0. 135 1. 107 0. 978 1. 007 1. 555 1. 079 0. 909 O. 917 0. 920 O. 713 0. 765 4. 830 4. 612 , 7. 923 2. 859 4. 050 4. 296 22. 337 8. 074 6. 2 7 1 ^ 3. 199 2. 014 11. 206-/ 2. 596 5. 074 3. 147 5. 122'Z 6. 225 26. 643 8. 529 5. 953 64.177 3. 472 4. 597 2. 924 9. 788 ^ 7. 264 8. 767 3. 334 i^ 6. 077 4. 571 5. 964 X ^ ' fi 'X n^"^' t/ y 300306 Data Subject "16 Validation . IU .* 188.0n 58.0- M/Z 100.0 a cn ,&58.0- a H cy ,.^ (T- 'zZZt ' 1—•> o :? Uil O : o ' IJJ O - J l MASS SPECTRUM 01/27/95 10:25:00 + 8:55 SAMPLE: DFTPP 290-04-PERF CONDS.: RTX-5 0.25MM X 30M DATA: BP012795C #535 CALI: BP012795C #1 BASE M/Z: 198 RIC: 14352. l.OUM 45/4-525620 INST B #534 TO #536 AUERAGED - #538 Xl.OO N/Z 219: 219: ^ .'<i^ RIC 01/27/95 10:25:00 SAMPLE: DFTPP 290-04-PERF CONDS.: RTX-5 0.25MM X 30M RANGE: G 1. 788 LABEL: N DATA: BP012795C #534 CALI: BP012795C #1 100.0-1 l.OUM 0.. 4.0 535 45/4-325§ , QUAN: A INST B 1.0 J 0 SCANS 520 TO 570 BASE: U 20, 3 30528. RIC tn c a DJ o' 3 LO O O CO O 00 523 527 520 8:40 530 8:50 J 544 sd? 47 559 56_2 564 548 9:00 550 9:10 560 9:20 570 SCAN 9:30 TIME I\l J RIC+MASS CHROMATOGRAM 01/27/95 10:25:00 SAMPLE: DFTPP 290-04-PERF CONDS.: RTX-5 0.25MM X 30M RANGE: G h 780 LABEL: N 100.0n 184 218.0- -••J lO o o CO o KD o 600 10:00 DATA: BP012795C #534 CALI: BP012795C #1 l.eUM 45/4-325e20 INST B 0/ 4.8. QUAN: A 8. 1.8 J 8 644 SCANS 600 TO 700 BASE: U 20.. 644 612 618 627 633 ess 663 682 620 10:20 I 640 10:40 660 11:00 —r-^ 680 11:20 689 52f 4176. 184.055 ± 8.500 9184. I 700 SCAN 11:40 TIME BP012795C # 535 BP012795C « 1 Mass List Data: 01/27/95 10:25:00 + 8:55 Cali: Sample: DFTPP 290-04-PERF Conds.: RTX-5 0. 25MM X 30M l.OUM 45/4-325620 #534 to #536 averaged - #530 Xl.OO 39 443 Mass 0. 00 7. RA Inten. Minima Maxima Mass Min Inten: # 0 7. RA Base m/z: RIC: 198 14352. INST B Inten. 39? 50? 51? 52? 57? 63? 69 74 75 76 77 78 79 SO 81 93 93 99 101 107 108 110 111 117 127 128 129 130 135 141 143 156 167 179 ISO 186 137 196 198 199 204 205 206 207 211 217 S S 5 S S s s s s s s s s s s s s s s s s s s s s s s s s s s s s s s s s s s s s s s s s s s s s s 4. 11. 47. 1. 3. 1. 52 27 99 55 70 19 53. 92 3. 79 6. 80 1. 73 "53. 01 2. 33 1. 51 1. 37 2. 05 2. 60 1. 87 1. 64 1. 32 11. 63 1. 55 26. 32 2. 74 5. 49. 2. 16. 1. 1. 1. 1. 1. 4. 2. 1. 10. 2. 3. 100. 6. 1. 3. 52 82 60 65 14 19 32 23 23 15 05 51 45 42 24 00 11 32 23 19. 93 2. 24 1. 14 3. 70 6. 48 1. 55 9. 12 2. 05 99. 247. 1052. 34. 81. 26. 1182. 83. 149. 38. 1162. 51. 33. 30. 45. 57. 41. 36. 29. 255. 34. 577. 60. 121. 1092. 57. 365. 25. 26. 29. 23. 23. 91. 45. 33. 229. 53. 71. 2192. 134. 40. 72. 433. 49. 25. 81. 142. 34. 200. 45. 227 244 246 255 256 258 274 275 276 296 365 423 441 442 443 S S 5 S S S S S S S S S s s 2. 87 7. 48 1. 19 39. 23 5. 75 1. 46 2. 55 21. 03 1. 96 2. 97 1. 41 1. 32 4. 70 41. 01 7. 66 63. 164. 26. 860. 126. 32. 56. 461. 43. 65. 31. 29. 103. 899. 168. 300310 Data Subject To Validation GC/MS Tuning tfnd. Mass Calibration DECAFLUOROTRIPHENYLPHOSPHINE 'Case Number: Laboratory: GULF Contract: Inst ID: B Sens Date: *01/27/95 Sens Time: 10:25:00 Lab ID: BP012795C Cali Date: 10/02/91 Analyst: JAM Data release authorized by: M/E Ion Abundance Criteria Spec # 534 51 30 to 607. of mass 198 68 less than 27. of mass 69 69 mass 69 relative abundance 70 less than 27. of mass 69 127 40 TO 607. of mass 198 197 less than 17. of mass 198 198 base peak, 100% relative abundance 199 5 TO 97. of mass 198 275 10 TO 307. of mass 193 365 greater than 17. of mass 198 441 less than mass 443 442 greater than 407. of mass 198 443 17 TO 237. of mass 442 1 - value in parenthesis is 7. of mass 69 2 - value in parenthesis is '/. of mass 442 47. 99 0. 00 53. 92 0. 00 49. 82 0. 00 100. OO 6. 11 21. 03 1. 41 4. 70 41. 01 7. 66 ( ( 0. 0. (18. 00) 00) 69) 300311 Oata Subjed To Validatiors DATA FROM FILE: BS012795A SCAHS 386 TO 1121 ACQUIRED: 81/27/95 11:35:88 CALI: BS812795A #1 SAMPLE: SSTDBSO 298-04-PERF CONDS.: RTX-5 0.25MM X SOM l.OUM 45/4-.325e2e INST B • 11( .* a Di m t n rr cr n> a o* ^ rrr a. to o o CO to 408 _ 6:48 500 . 8:20 600 . 10:00 I CS50 2-FLUORnpHENOL 8.6 (SS-5) 100.0,"? ( 48000.) ei30 D4-l,4 DICHLOROBENZENE (15-1) CS75 L2-CL2BENZENE-D4 0.4 (SS-8) 550- D5-NITROBENZENE 0.2 (SS-1) , 700 . 11:48 800 _ 13:20 900 _ 15:00 1000 J 16:40 0148 DS-NAPHTHALENE (IS-2) CS25 2-FLUOROBIPHENYL 8.7 (SS-2) 0158 DIO-ACENAPHTHENE (IS-3) CS55 2.. 4.. 6TRI BROMOPHENOL (SS-6) riTRn nilVPHENANTHRENE (IS-4) ^V i-lrfc^- CS3U DI4-P-TERFHENYL 8.5 (SS-3) ^ f V Zri /<,.# DATA FROM FILE: BS012795A SCANS 1121 TO 2280 ACQUIRED: 01/27/95 11:35:00 CALI: BS012795A #1 SAMPLE: SSTD850 298-e4-PERF CONDS.: RTX-5 0.25MM X 38M l.OUM 45/4-325(?20 IHST B 100.0:: ( 36544.) 1200 _ 20:00 1408 _ 23:20 - 1680 _ 26:48 1888 _ • • •« r 1 r^ T "T" ~~-~- CIf5 1 D12-FERYLENE 1 1 Til2-CHRYbENE (IS-6) (IS-5) 38:88 D c 2000 33:20 (jj 5< o » CO CJ O J I o" ^W J I! ill -_J Quantitation Report File; BS012795A 0. Data: BS012795A. TI - _ 01/27/95 11: 35:00 Sample: SSTD050 290-04-PERF Conds.: RTX-5 0. 25MM X 30M l.OUM 45/4-325620 ormula: X X X Instrument: B Submitted by: . Analyst: JAM INST B Weight: Acct. No. 1. 001 AMDUNTeAREA • REF AMNT/(REF AREA • RESP FACT) Resp. fac. from Library Entry No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 23 29 30 31 32 33 34 35 36 37 33 39 40 41 42 43 |44 '45 46 47 Name CI3Q CI40 CI 50 CI60 CI70 CI75 CS50 CS45 CS20 CS25 CS55 CS30 CS70 CS75 C315 C325 C330 C335 C340 C320 C310 C319 C345 C350 C355 C357 C365 C370 C375 C410 C415 C420 C425 C430 C435 C440 C445 C450 C455 C460 C465 C470 C510 C515 C520 C525 C530 0. 6 0. 8 0. 2 O. 7 D4-l,4 DICHLOROBENZENE DS-NAPHTHALENE DIO-ACENAPHTHENE D10-PHENANTHRENE D12-CHRYSENE D12-PERYLENE 2-FLUOROPHENOL D5-PHEN0L D5-NITRDBENZENE 2-FLUOROBIPHENYL 2,4,6TRIBROMOPHENOL D14-P-TERPHENYL 0. 5 2-CHL0R0PHEN0L-D4 0. 8 1,2-CL2BENZENE-D4 •PHENOL BIS(2CHL0R0ETHYL)E 2CHL0R0PHEN0L 1,3DICHL0R0BENZENE •1,4DICHL0R0BENZENE ANILINE N-NITROSODIMETHYLAMINE PYRIDINE BENZYL ALCOHOL 1,2DICHL0R0BENZENE 0.4 2METHYLPHENaL 0.7 0. O. 0. 0. O. 0. 4METHYLPHEN0L 0. 6 8<NITR0S0PR0PYLAMINE 0. 5 0. 3 0. 2 0. 4 0. 1 (IS-1) (IS-2) <IS-3) (IS-4) d S - 5 ) (IS-6) (SS-5) (SS-4) (SS-1) (SS-2) (SS-6) (SS-3) (SS-7) (SS-8) HEXACHLOROETHANE NITROBENZENE ISOPHORONE •2-NITROPHENOL 2,4-DIMETHYLPHENOL 0.2 BENZOIC ACID BIS(2CHL0R0ETH0XY) 0.3 •2,4DICHL0R0PHEN0L 0. 2 1,2, 4TRICHLOROBENZ 0.2 NAPHTHALENE 0.7 4-CHLOROANILINE •CL6BUTADIENE •4CHL0R03METHYLPHEN 0. 2 2METHYLNAPHTHALENE 0. 4 8<CL6CYCLOPENTADIENE •246TRICHL0R0PHNE0L 0.2 2. 4, 5TRICHL0R0PHEN 0.2 2CHL0R0NAPHTHALENE 0. 8 2-NITRDANILINE T T T T T T 300314 ZB No Name 48 C535 DIMETHYL PHTHALATE 49 C540 ACENAPHTHYLENE 1.3 50 C545 3-NITROANILINE No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 ?4 '^5 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 150 m/z 152 136 164 IBS 240 264 112 99 62 172 330 244 132 152 94 93 128 146 146 93 74 79 108 146 108 45 108 70 117 77 82 139 107 122 93 162 180 123 127 225 107 142 237 196 196 162 65 163 152 133 Scan 521' 640 802 936 1221 1559 397 490 575 737 874 1081 503 539 491 • 498- 504 517- 522- 494- 225 224 535- 540- 546- 549 559- 562 569 577 597 606 607- 617- 616 627 635 642 647 656 689 704 723 73r 735 749 761 776 788 799 Time 8: 41 10:40 13:22 15: 36 20:21 25: 59 ' 6:37 B: 10 9: 35 12: 17 14:34 18: 01 8: 23 B: 59 8: 11 8: 18 8: 24 8: 37 8: 42 8: 3: 3: 8: 9: 9: 14 45 44 55 00 06 9: 09 9: 19 9: 22 9: 29 9: 37 9: 57 10: 06 10: 07 10: 17 10: 16 10:27 10: 35 10: 42 10: 47 10: 56 11:29 11: 12: 12: 12: 12; 12: 12: 44 03 11 15 29 41 56 13: 08 13: 19 Ref 1 2 3 4 5 6 1 1 2 3 3 5 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 2 2 2 2 2 2 2 2 2 2 ZI 3 3 3 3 3 3 3 3 0 O o 1 RRT 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 0. 762 940 898 919 090 0. 885 0. 965 J. 035 0. 942 0. 956 0. 967 0. 992 1. 002 0. 948 0. 432 0. 430 1. 027 036 048 054 073 1. 079 1. 092 0. 902 0. 933 0. 947 0. 948 0. 964 0. 962 0. 980 0. 992 1. 003 1. Oil 1. 025 1. 077 1. 100 0. 901 0. 911 0. 916 O. 934 0. 949 0. 963 0. 9S3 0. 996 Meth A QB A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A BB BB BB BB BB BB BB BB BB BB BB BB BB BV VB BB BV VB BV BB BB BV BB VB BB BB BB BB BB BB BV BB VB BB BB BB BB BB BB BB BB BB BB BB BB BB BB BB BB Area(Hght) 7195. 27590. 14911. 20564. 16127. 15005. 11302. 15661. 11265. 18265. 1864. 15609. 12238. 6348. 16736. 14990. 10612. 11540. 11782. 13890. 7003. 12239. 6730. 10685. 10372. 19391. 10527. 7327. 4645. 11691. 23739. 6092. 6391. 3700. 14993. 8023. 8257. 29209. 7166. 3574. 8842. 20610. 1952. 5269. 5682. 1B616. , 5334. 20215. 23242. 872. Amount 20. 000 20. 000 20. 000 20. 000 20. 000 20. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 ^25. 000 25. 000 25. 000 25. 000 PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB fSik>]T=tl^^ •/.Tot 0. 95 0. 95 0. 95 0. 95 0. 95 0. 95 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 300315 Dst3 $;.ibiea jec: i.'Z va'idatior' .m No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 bo 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 Ret<L) 8:41 10:40 13:22 15:36 20:21 25: 59 6:37 8: 10 9:35 12: 17 14:34 18: 01 8:23 8: 59 8: 11 8: 13 8: 24 8: 37 8:42 8: 14 3:45 3: 44 8: 55 9: 00 9:06 9: 09 9: 19 9: 22 9: 29 9:37 9: 57 10: 06 10:07 10: 17 10: 16 10: 27 10: 35 10:42 10: 47 10: 56 11:29 11: 44 12:03 12: 11 12: 15 12:29 12: 41 12: 56 13:08 13: 19 Ratio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 . 00 , 00 . 00 , 00 , 00 . 00 . 00 . 00 , 00 , 00 , 00 RRT(L) 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 0. 762 0. 940 0. 898 0. 919 1. 090 0. 885 0. 965 1. 035 0. 942 0. 956 0. 967 0. 992 1. 002 0. 948 0. 432 0. 430 1. 027 1. 036 1. 048 1. 054 1. 073 1. 079 1. 092 0. 902 0. 933 0. 947 0. 948 0. 964 0. 962 0. 980 0. 992 1. 003 1. Oil 1. 025 1. 077 1. 100 0. 901 0. 911 0. 916 0. 934 0. 949 0. 968 0. 983 0. 996 Ratio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 , 00 00 00 , 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 Amnt - . 20. 00 20. 00 20. 00 20. 00 20. 00 20.,00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 Amnt(L) 20. 00 20. 00 20. 00 20. 00 20. 00 20. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. OO 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 jyfi>4iS:f ifpl>9'i^J^ R. Fac R. 1. 000 1. 000 1.000 1. 000 1. 000 1.000 1. 257 1. 741 0. 327 0. 980 0. 100 0.774 1. 361 0. 706 1. 861 1. 667 1. ISO 1. 283 1. 310 1. 544 0.779 1. 361 0. 748 1. 188 1. 153 2. 156 1. 170 0. 815 0. 516 0. 339 0. 690 0. 177 0. 185 0. 107 0. 435 0. 233 0. 239 0. 847 0. 208 0. 104 0. 256 0. 598 0. 105 0. 283 0. 305 0. 999 0. 313 1. 085 1. 515 0. 047 Fac<L) 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 1. 257 1. 741 0. 327 0. 980 0. 100 0.774 1. 361 0. 706 1. 861 1. 667 1. 180 1. 283 1. 310 1. 544 0. 779 1. 361 0. 748 1. 188 1. 153 2. 156 1. 170 0. 815 0. 516 0. 339 0. 690 0. 177 0. 185 0. 107 0. 435 0. 233 0. 239 0. 847 0. 208 0. 104 0. 256 0. 598 0. 105 0. 283 0. 305 0. 999 0. 313 1. 085 1. 515 0. 047 Ratio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 300316 Data Subled To Validation Quantitation Report File: BS012795A Data: BS012795A. TI 01/27/95 11: 35:00 Sample: SSTDOSO 290-04-PERF Conds.: RTX-5 0. 25MM X 30M l.OUM 45/4-325620 ^Formula: X X X Instrument: B Submitted by: Analyst; JAM INST B Weight: Acct. No. 1. 001 AMOUNT=AREA » REF AMNT/(REF AREA • RESP FACT) Resp. fac. from Library Entry M No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 SO 81 82 83 34 85 No 51 52 53 54 55 56 57 58 Name C550 C321 C555 C560 C565 C570 C543 C580 C585 C590 C595 C610 C615 C625 C630 C635 C640 C645 C650 C655 D200 C647 C715 C720 C725 C730 C740 C735 C760 C765 C770 C775 C780 C735 C790 m/z 153 232 184 109 168 165 165 149 •ACENAPHTHENE 0.8 2,3,4,6-TETRACHLORDPHENOL ?<2, 4DINITROPHEN0L S<4N I TROPHENOL DIBENZOFURAN 0. 8 2,4DINITRDT0LUENE 0. 2 2,6DINITR0T0LUENE 0.2 'DIETHYL PHTHALATE 4CHL0R0PHENYL PHEN 0.4 FLUORENE 0. 9 4-NITRDANILINE 4,6DINITRD2METHYLPH •DIPHENYLAMINE 4BR0M0PHENYL PHENY 0. 1 CL6BENZENE 0. 1 •PENTACHLOROPHENOL 0. 05 PHENANTHRENE 0.7 ANTHRACENE 0. 7 DI-NBUTYLPHTHALATE •FLUORANTHENE 0. 6 1,2-DIPHENYLHYDRAZINE CARBAZOLE PYRENE 0. 6 BUTYLBENZYLPHTHALATE 3,3'CL2BENZIDINE BENZO(A)ANTHRACENE 0.8 BIS(2ETHYLHEXYL)PHTH CHRYSENE 0. 7 •DI-N-OCTYLPHTHALATE BENZO(B)FLUORANTHE 0.7 BENZO(K)FLUORANTHE 0.7 •BENZO(A)PYRENE 0. 7 INDENOd. 2, 3CD)PYR 0.5 DIBENZO(A, H)ANTHRA 0.4 BENZD(G,H, DPERYLE 0.5 Scan Time Ref RRT 804 13:24 3 1.002 833 13: 53 3 1. 039 807 13:27 3 1.006 310 13:30 3 1.010 818 13:38 3 1.020 320 13:40 3 1.022 784 13:04 3 0.973 338 13:58 3 1.045 T T T Meth A A A A A A A A BB BB BB BB BB BB BB BB Area(Hght) 15874. 4473. 2009. 1420. 23970. 6942. 5340. 19056. r Amount 25. 25. 25. 25. 25. 25. 25. 25. y i a : 000 000 000 000 000 000 000 000 7.Tot PPB 1 PPB 1 PPB 1 PPB 1 PPB 1 PPB 1 PPB 1 PPB 1 30031 Jub;ec'~"rr;^.!;w.,w 19 19 19 19 19 19 19 19 7 "br-L No 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 No >51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 .75 h 77 m/z 204 166 138 198 169 248 284 266 178 178 149 202 77 167 202 149 252 228 149 228 149 252 252 252 276 278 276 Scan Time F 847 14 850 14 855 14 857 14 858 14 891 14 908 15 923 15 939- 15 943' 15 983 16 1050- 17 862 14 956 15 1072- 17 1131 18 ] 3 ] 1210 20 L218- 20 1207 20 1225- 20 1322 22 : : 1445. 24 L452- 24 1541. 25 L984- 33 1991. 33 2116- 35 Ret(L) Ratio 13: 13: 13: 13: 13: 13: 13: 13: 14: 14: 14: 14: 14: 14: 15: 15: 15: 15: 16: 17: 14: 15: 17: 18: 20: 20: 20: 24 53 27 30 38 40 04 58 07 10 15 17 18 51 OS 23 39 43 23 30 22 56 52 51 10 18 07 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 :07 : 10 : 15 : 17 : 18 : 51 :0B :23 :39 :43 :23 :30 :22 : 56 : 52 : 51 : 10 : 18 :07 :25 :02 :05 : 12 :41 :04 : 11 : 16 RRT(L; 1. 002 1. 039 1. 006 1. 010 1. 020 1. 022 0. 978 1. 045 1. 056 1. 060 1. 066 0. 916 0. 917 0. 952 0. 970 0. 936 1. 003 1. 007 1. 050 1. 122 0. 921 1. 021 0. 878 0. 926 0. 991 0. 993 0. 989 lef 3 3 3 4 4 4 4 4 4 4 4 4 4 4 5 5 5 5 5 5 6 6 6 6 6 6 6 > Ri RRT 1. 056- 1. 060 1. 066 0. 916 0.917 0. 952 0. 970 0. 986 1. 003 1. 007 1. 050 1. 122 0. 921 1. 021 0. 878 0. 926 0. 991 0. 998 0. 989 1. 003 0. 848 0. 927 0. 931 0. 988 1. 273 1. 277 1. 357 atio 00 00 00 00 00 00 00 00, 00 00 00 00 00 00 00 , 00 , 00 , 00 , 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 Meth -A A A A A A A A A A A A A A A A A A A A A A A A A A A 1 BB BB BB BB BB BB BB BB BV VB BB BB BB BB BB BB BB BV BB VB BB BV VB BB BB BB BB ^mnt 25. 00 2! 5. 00 25. 00 2! 2: 21 21 21 2: 21 2: 21 21 2' 2! 2 2 2 2 2 2 2 2 2 2 2 2 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. PO AreaCHgh^ 9134. 19252. 1425. 3345. 8394. 4209. 4135. 3018. 27144. 27860. 37509. 28498. 30939. 7463. 28875. 16421. 4033. 22130. 22924. 20774. 34423. 18353. 17974. 16664. 16437. 12604. 13703. Amnt(L) 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 JjmD^i^ BZq^ltnrA b) Amount 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 R. Fac R. F 0. 0. 0. 0. 1. 0. 0. 1. 0. 1. 0. 0. 0. 0. 0, 0. 1 1, 1 1 1 0 1 0 0 1 1 852 240 108 076 286 372 286 022 490 033 076 130 327 ,164 161 , 117 . 056 . 034 . 459 . 109 . 204 . 290 . 432 . . 315 . 200 . 098 . 137 PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB ac(L) 0. 852 0. 240 0. 103 0. 076 1. 236 0. 372 0. 236 1. 022 0. 490 1. 033 0. 076 0. 130 0. 327 0. 164 0. 161 0. 117 1. 056 1. 084 1. 459 1. 109 1. 204 0. 290 1. 432 0. 815 0. 200 1. 098 1. 137 y.Tot Rat: 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 Lo 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 , 00 , 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 3d0"3l8 - ' -i r_ i !j„i; Data Subjed To Validation No Ret(L) Ratio RRT<L) Ratio Amnt Amnt(L) R.Fac R. Fac(L) Ratio 78 20:25 1.00 1.003 1.00 " J35. 00 25.00 1.031 1.031 1 00 79 22:02 1.00 0. 848 1.00 25.00 25.00 1.835 1.835 1 00 80 24:05 1.00 0.927 1.00 25.00 25.00 0.978 0.978 i oO 81 24:12 1.00 0.931 1.00 25.00 25.00 0. 958 0.958 l'00 82 25:41 1.00 0.988 1.00 25.00 25.00 0.888 0.888 1.00 83 33:04 1.00 1.273 1.00 25.^0 25.00 0.876 0.876 1 00 84 33:11 1.00 1.277 1.00 25.00 25.00 0.672 0.672 1.00 85 35: 16 1.00 1.357 1.00 25.00 25.00 0.731 0.731 1.00 '^^^1^9'irA 300319 Data Subject To Validation m Calibration Check Instrument Identifier: B ~ -- Calibration Date: 11/09/94 Standard File: BS012795A ate: 01/27/95 Time: 11:35:00 IN RF: SW(8<) = .05 CLP = . 01 OR BELOW MAX y.D: SW(«) = 307. CLP = 257. CS50 CS45 CS20 CS25 CS55 CS30 CS70 CS75 C315 C325 C330 C335 C340 C320 C310 C319 C345 C350 C355 £357 P365 C370 C375 C410 C415 C420 C425 C430 C435 C440 C445 C450 C455 C460 C465 C470 C510 C515 C520 C525 C530 C535 C540 C545 I&550 •321 C555 Compound 2-FLUOROPHENOL D5-PHENDL D5-NITR0BENZENE 2-FLUOROBIPHENYL 0. 0. 0. 0. 2. 4,6TRIBR0MDPHENDL D14-P-TERPHENYL 2-CHL0RDPHEN0L-D4 1,2-CL2BENZENE-D4 •PHENOL BIS(2CHL0R0ETHYL)E 2CHLDR0PHEN0L 1,3DICHL0R0BENZENE •1,4DICHL0R0BENZENE ANILINE 0. 0. 0. 0. 0. 0. 0. 0. 6 8 2 7 5 8 4 8 7 8 6 5 N-NITROSODIMETHYLAMINE PYRIDINE BENZYL ALCOHOL 1,2DICHL0RDBENZENE 2METHYLPHEN0L 0. 0. 2,2'0XYBIS(1CHL0R0PR 4METHYLPHEN0L 5<NITR0S0PR0PYLAMINE HEXACHLOROETHANE NITROBENZENE ISOPHORONE •2-NITROPHENOL 2,4-DIMETHYLPHENOL BENZOIC ACID BIS(2CHL0R0ETH0XY) •2,4DICHLOR0PHENOL 1,2, 4TRICHLOROBENZ NAPHTHALENE 4-CHLORDANILINE •CL6BUTADIENE •4CHL0R03METHYLPHEN 2METHYLNAPHTHALENE &CL6CYCL0PENTADIENE •246TRICHLOROPHNEOL 2,4, 5TRICHLDR0PHEN 2CHL0R0NAPHTHALENE 2-NITROANILINE DIMETHYL PHTHALATE ACENAPHTHYLENE 3-NITROANILINE •ACENAPHTHENE 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 0. 4 7 6 5 3 2 4 1 2 3 2 2 7 2 4 2 2 8 3 8 2, 3, 4, 6-TETRACHLDROPHE &2.4DINITR0PHEN0L Mean RF(I) 0. 1. 0. 1. 0. 0. 1. 0. 1. 1. 1. 1. 1. 1. 0. 0. 0. 1. 1. 1. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 0. 1. 1. 0. 0. 0. 0. 996 309 294 089 117 841 095 725 593 384 118 234 251 393 621 918 581 143 035 301 056 614 454 294 575 176 225 140 383 256 273 357 323 127 237 533 236 329 356 022 271 111 553 , 148 , 916 , 302 , 148 RF(0) •/. D 1. 257 1. 742 0. 327 0. 980 0. 101 0. 775 1. 361 0. 706 1. 861 1. 667 1. 180 1. 284 1. 311 1. 545 0. 779 1. 361 0. 749 1. 189 1. 154 2. 157 1. 171 0. 815 y y 0. 517 0. 339 0. 690 0. 177 0. 186 0. 108 0. 435 0. 233 0. 240 0. 847 0. 208 0. 104 0. 257 0. 598 0. 105 *y^ 0. 283 0. 305 0. 999 0. 314 1. 085 1. 516 0. 047 0. 852 0. 240 0. 108 i—^ 26. 164 33. 043 11. 140 9. 940 14. 452 7. 926 24. 320 2. 511 16. 859 y 20. 436 5. 594 3. 999 4. 798 y 10. 942 25. 462 48. 298 28. 896 4. 022 11. 519 65. 766 10. 933 32. 691 13. 926 15. 301 19. 995 0. 772 y 17. 386 23. 017 12. 161 9. 073 y ^ 12.087 1. 063 35. 540 17. 977 ^ 8. 461 l ^ 2. 532 63. 180 13. 984 <^^ 14. 297 2. 179 15.665 2. 348 2. 683 68. 091 7. 010, . 20. 342 26. 662 300320 Subject lb Vaiidatiors 0. 8 O. 2 0. 2 0, 0. 4 9 C560 «c4N I TROPHENOL C565 DIBENZOFURAN C570 2,4DINITR0T0LUENE C543 2,6DINITR0T0LUENE C5B0 DIETHYL PHTHALATE 585 4CHLDR0PHENYL PHEN 590 FLUORENE C595 4-NITROANILINE C610 A,6DINITR02METHYLPH C615 «DIPHENYLAMINE C625 4BR0MDPHENYL PHENY 0.1 C630 CL6BENZENE 0. 1 C635 •PENTACHLOROPHENOL O. 05 C640 PHENANTHRENE 0. 7 C645 ANTHRACENE O.7 C650 DI-NBUTYLPHTHALATE C655 •FLUORANTHENE 0.6 D200 1,2-DIPHENYLHYDRAZINE C647 CARBAZOLE C715 PYRENE 0.6 C720 BUTYLBENZYLPHTHALATE C725 3,3'CL2BENZIDINE C730 BENZO(A)ANTHRACENE 0. C740 BIS(2ETHYLHEXYL)PHTH C735 CHRYSENE 0. C760 •DI-N-OCTYLPHTHALATE C765 BENZO(B)FLUORANTHE 0. C770 BENZO(K)FLUDRANTHE C775 •BENZO(A)PYRENE C780 INDENOd, 2, 3CD)PYR 785 DIBENZO(A, H)ANTHRA 90 BENZO(G. H, DPERYLE .m 0. 0. 0. 0. 0. 8 0. 084 1. 322 0.360 0. 296 1. 062 0. 520 1. 097 0. 124 0. 136 393 183 185 133 012 021 245 0. 987 0. 813 591 440 714 135 107 0. 978 1. 007 1. 555 1. 079 0. 909 0. 917 0. 920 0. 713 0. 765 0. 0. 0. 0. 1. 1. 1. 0. 1. 0. 0. 1. 0. 077 / 1. 287 0. 373 0. 287 1. 023 0. 491 1. 033 0. 077 0. 131 0. 327 0. 164 0. 161 0. 118 1.056 1. 084 1. 460 1. 109 1. 204 0. 291 1. 433 0. 815 0. 201 1. 098 1. 138 031 836 979 959 889 0. 877 0. 672 0. 731 1. 1. 0. 0. 0. S. 512 2. 660 3.718 3. 146 3. 641 5. 659 5. 806 37. 867 3. 923 16. 10. 12. 11. 4. y 686 018 773 328 422 6. 168 17. 202 374.^ 172 811 471 14. 104 48. 740 763 295 348 026 ^ 260 440 105 659 729 400 12. 48. 50. 0. 0. 16. 18. 9. 5. 3. 4. 5. 4. y ^ 300321 ^«ia iuDject io Vaiidation * . i<t.» DATA FROM FILE: SOUQAOIP SCANS 384 TO 1119 ACQUIRED: 01/27/95 19:25:00 CALI: SWQA01P #1 SAMPLE: RBSO/012095 WATER HLA CONDS.: RTX-5 0.25MM X 30M l.OUM 45/4-325e20 INST B 400 _ 6:40 500 . o . ••)o 600 10:00 708 . 11:48 -r 888 . 13:20 900 _ 15:08 CO A. o 16:48 '-; u) . m Q. V 1— \ J O 3 C s b 2-FLUuRuF(lt:NuL ^ m ^ ^ ^ < ^^^SB.) CS45 D5-PHENnL 8.8 (SS-4.) CS7U 2-L:HLUR0PHEN0L-D4 8:B (5S-7) CI38 04-1.. 4 DICHLOROBENZENE (IS-1) CS75 1..2-CL2BENZENE-D4 8.4 (SS-8) CS20 D5-NITROBENZENE 0.2 (SS-1) CI40 DS-NAPHTHALENE (IS-2) CS25 2-FLUOROBIPHENYL 0.7 (SS-2) •' CI50 DIO-ACENAPHTHENE (IS-3) CS55 2.. 4.. 6TRI BROMOPHENOL (SS-6) 0168 D18-PHENANTHRENE (IS-4) - ^ = "ZP KXi CD * . ^ <jn 33 9 •> -it /'n • * . " * f^ o '---'-^....^..., CS38 D14-P-TERPHENYL 8.5 (SS-3) ' ^ « • » I c Bi- o 3 CO OJ to CO DATA FROM FILE: SUUQAOIP SCANS 1119 TO 2200 ACQUIRED: 01/27/95 19:25:00 CALI: SUUQAOIP #1 SAMPLE: RBSO/012095 WATER HLA CONDS.: RTX-5 0.25MM X 30M l.OUM 45/4-325528 INST B 1288 _ 28:88 X 1400 J 23:20 1600 _ 26:40 1808 30:00 2000 _ 33:20 •m^. J T^ I 100.0^ ( 21280.) CI70 D12-CHRYSENE (IS-5) CI75 D12-PERYLENE (IS-6) Quantitation Report File: SVVQAOIP . * Data: SVVQAOIP. TI 01/27/95 19:25:00 Sample: RBSO/012095 onds. : RTX-5 0. 25MM ormula: X X X Submitted by: WATER X 30M HLA 1. OUM 45/4-325<»20 Instrumejit: B Analyst:* JAM INST B Weight: Acct. No. : 1. 001 11911 AMOUNT=AREA • REF AMNT/(REF AREA • RESP FACT) Resp. fac. from Library Entry No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 No i 1 ' 2 3 4 5 6 7 3 9 10 11 12 13 14 15 No 1 2 3 4 5 6 7 8 r f Name CI30 CI40 CI 50 CI60 CI70 CI75 CS50 CS45 CS20 CS25 CS55 CS30 CS70 CS75 C740 m/z ! 152 136 164 188 240 264 112 99 82 172 330 244 132 152 149 D4-: ' 1,4 DICHLOROBENZENE DS-NAPHTHALENE DIO- DIO- D12- D12' -ACENAPHTHENE -PHENANTHRENE -CHRYSENE -PERYLENE 2-FLUOROPHENOL D5-PHEN0L D5-NITR0BENZENE 2-FLUOROBIPHENYL 2,4; D14- 0. 6 0. 8 0. 2 0. 7 ,6TRIBROMOPHENOL -P-TERPHENYL 2-CHL0R0PHEN0L-D4 1, 2-CL2BENZENE-D4 0. 5 0. 8 0. 4 BIS(2ETHYLHEXYL)PHTH Bean 519 639 801 936 1220 1558 392 487 575 737 874 1031 501 537 1205 Ret(L) Ra 8: 41 10:40 13:22 15: 36 20: 21 25: 59 6: 37 8: 10 9: 35 0. ' 0. ' 1. ' Time Ref 8: 39 1 10:39 2 13:21 3 15:36 4 20: 20 5 25: 53 6 6: 32 1 8: 07 1 9: 35 2 12: 17 3 14:34 3 13:01 5 8:21 1 8: 57 1 20: 05 5 0. 0. 0. 0. 1. 0. 0. 1. 0. RRT 000 000 000 000 000 000 755 933 900 920 091 336 965 035 938 tio RRT(L) Ratio DO 1.000 1. DO 1.000 1. DO 1. 000 1. DO 1. 000 1. DO 1.000 1. OO 1.000 1. 99 0. 762 0. 99 0.940 1. 00 0.898 1. 00 00 00 00 00 00 99 00 00 (IS-1) (IS-2) (IS-3) (IS-4) (IS-5) (IS-6) (SS-5) (SS-4) (SS-1) (SS-2) (SS-6) (SS-3) (SS-7) (SS-8) Meth A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB Amnt 20. 00 20. 00 20. 00 20. 00 20. 00 20. 00 63. 65 67. 76 49. 42 Area(Hgh 6358. 25444. 15236. 19564. 14697. 15965. 25426. 37512. 20537. 26233. 4194. 29937. 27615. 6S33. 1685. Amnt(L) 20. 00 20. 00 20. 00 20. 00 20. 00 20. 00 25. 00 25. 00 25. 00 t) Amount 20. 20. 20. 20. 20. 20. 63. 67. 49. 35. 55. 52. 63. 30. 2. R. Fac 3. 4. 0. 000 000 000 000 000 000 646 764 421 214 050 614 839 675 016 R. F, 000 000 000 000 000 000 , 199 720 , 646 PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB •PPB PPB PPB PPB PPB BC(L) 1. 000 1. 000 1. 000 1. 000 1. OOO 1. 000 1. 257 1. 741 0. 327 •/.Tot 3. 3. 3. 3. 3. 3. 11. 12. 9. 6. 10. 9. 11. 5. 0. Rat: 2. 2. 1. 70 70 70 70 70 70 78 54 15 52 19 74 82 68 37 Lo 00 00 00 00 00 00 55 71 98 300324 Dats ^uhiec' y VgHdaibn No Ret(L) Ratio RRT(L) Ratio ^ 10 11 12 13 14 12: 17 14:34 18:01 8: 23 8: 59 1. 00 1. 00 1. 00 1. 00 1. 00 0. 1. 0. 0. 1. 919 090 885 965 035 1. 00 1. 00 1. 00 1. 00 1. 00 15 20:07 1.00 0.989 1.00 ._ Amn t 35. 21 55. 05 52. 61 63. 84 30.i»8 2. 02 Amnt(L) 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 R. Fac R. Fac(L) 1.380 0.980 0. 220 1. 630 3. 475 0. 866 0. 092 O. O. 1. 0. 1. 100 774 361 706 137 R a t i o 1. 41 2. 20 2. 10 2. 55 1. 2 3 0. 08 0 300325 v r V •<* , - ^'•'' ^^^^ecf 7b V^/fcfafh. i M< •* ^0.7-1 O l . . -J 01 7- TARGET COMPOUND COMPARISON COMPOUND: C740 BIS(2ETHYLHEXYL)PHTH RAW DATA: SUUQAOIP #1205 01/27/95 19:25 SAMPLE: RBSO/012095 WATER HLA CONDS.: RTX-5 0.25MM X 30M l.OUM 45/4-325620 41 iL T^ 1—r"-l—r"1—I—r^ 1 — I — I — I — r ^ i — I — I — I — > — I — I 'I I — I — r ENHANCED DATA: SUUQAOIP #1205 BASE M./Z: 149 INST B RIC: 3992. I ' I ' i ' Xi. T^—r JLi f-1 1—I 1 1 1 r- 707. 1 r — 1 1 1 r ' - T 1 1 1 1 — I — I 1 1 1 I I 1 1 1 r- BASE M/Z: 149 RIC: 2404. 625. T — ' •• I ' — I — f - | — I — I — r - I • I - | — I 1 — r — I — r G tfl c ^ W LIBRARY FILE: SN #56 100.0-1 50.0- M/Z 100. 8-D 50.0 0.0-j - T - T — I > I 50 I ' l ' — I — f — r BASE M/Z: 149 RIC: 1586. r ^ \ ' r 1—'—I—'—r -50.0- -100.0- O CJJ O O CAJ t o 100 llll I I 150 208 -I—I I I •—r 258 r 1800. DATA FROM FILE: SUUQBOIP SCANS 384 TO 1119 ACQUIRED: 01/27/95 20:07:00 CALI: SUUQBOIP #1 SAMPLE: RBSO/O11995 WATER HLA CONDS.: RTX-5 0.25MM X 30M l.OUM 45/4-325520 INST B IU-* 408 _ 6:40 500 8:20 600 . 10:00 700 _ 11:40 800 . 13:20 'iy" 900 . w 15:00 •v/S c: yx' y i 1000 . Z 16:40 ihl 0 1 r-j 0 1 • CAi' y to -J o 1 r - r - t \ i m ± cio 2-FLUi: ORUpteT or -.T-J u.b ^§§-§5 44416.) -^=^^C^r^fJft0R0PHEN0L-&^ S l i k - 7 ) CI30 D4-1..4 DICHLOROBENZENE (IS-1) -— CS75 1,2-CL2BENZENE-D4 0.4 (SS-3) CS20 D5-NITROBENZENE 0.2 (SS-1) ;i40 D3-NAPHTHALENE (IS-2) CS25 2-FLUOROBIPHENYL 0.7 (SS-2) CI50 DIO-ACENAPHTHENE (IS-3) CS55 2.. 4, 6TRI BROMOPHENOL (SS-6) CI60 DIO-PHENANTHRENE (IS-4) • ^ DD NO cn 30 m rn : ^ m o CS38 D14-P-TERPHENYL 8.5 (SS-3) DATA FROM FILE: SUUQBOIP SCANS 1119 TO 2200 ACQUIRED: 01/27/95 20:07:08 CALI: SUUQB81P #1 SAMPLE: RBSO/011995 WATER HLA CONDS.: RTX-5 0.25MM X 38M l.eUM 45/4-325@28 INST B • M( .» 1200 . 20:88 1400 23:20 IbOO 26:40 1800 a, cu Oi c ay To 9. 2000 -• 5* 33:20 t ci ^51 J CO o o CO to 00 I I I -J 108.0?; ( 41280.) " I . , , _, - CI70 D12-CHRYSENE (IS-5) CI75 D12-PERYLENE (IS-6) Quantitation Report File: SVVQBOIP . « Data: SVVQBOIP. TI 01/27/95 20: 07:00 mple: RBSO/011995 WATER HLA nds. : RTX-5 O. 25MM X SOM l.OUM 45/4-325220 rmula: X X X Submitted by: Instrumept: B Analyst: JAM INST B Weight: 1.001 Acct. No. : 11911 AMOUNT=AREA • REF AMNT/(REF AREA • RESP FACT) Resp. fac. from Library Entry No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 .No h 2 3 4 5 6 7 .8 9 10 11 12 13 14 15 No 1 2 3 4 5. 6 7 .8 • ^ Name CI30 CI40 CI50 CI 60 CI70 CI75 CS50 CS45 CS20 CS25 CS55 CS30 CS70 CS75 C740 m/z ! 152 136 164 188 240 264 112 99 82 172 330 244 132 152 149 D4-: ' 1,4 DICHLOROBENZENE DS-NAPHTHALENE D IO- DIC- D12- D12- -ACENAPHTHENE -PHENANTHRENE -CHRYSENE -PERYLENE 2-FLUOROPHENOL D5-PHEN0L D5-NITR0BENZENE 2-FLUOROBIPHENYL 2.4; D14- 0. 6 0. 8 0. 2 0. 7 .6TRIBROMOPHENOL -P-TERPHENYL 2-CHL0R0PHENDL-D4 1, 2-CL2BENZENE-D4 0. 5 0. 8 0. 4 BIS(2ETHYLHEXYL)PHTH 3can 519 639 801 936 1219 1555 392 488 575 737 874 1080 501 537 1205 Ret(L) Ra' 8:41 10:40 13:22 15: 36 20: 21 25: 59 6: 37 8: 10 9: 35 0. < Time Ref 8: 39 10: 39 13: 21 15: 36 20: 19 25: 55 6: 32 8: 08 9: 35 12: 17 14: 34 18: 00 8: 21 8: 57 20: 05 tio R R T ( L ; DO 1.000 DO 1.000 DO 1.000 DO 1.000 DO 1.000 DO 1.000 79 0. 762 DO 0. 940 DO 0. 898 1 2 3 4 5 6 1 1 2 3 3 5 1 1 5 0. 0. 0. 0. 1. 0. 0. 1. 0. RRT 000 000 000 000 000 000 755 940 900 920 091 886 965 035 989 • Ratio 0. 00 00 00 00 00 00 99 00 00 (IS-1) (IS-2) (IS-3) (IS-4) (IS-5) (IS-6) (SS-5) (SS-4) (SS-1) (SS-2) (SS-6) (SS-3) (SS-7) (SS-8) Meth A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB Amnt 20. 00 20. 00 20. 00 20. 00 20. 00 20. 00 64. 81 66. 52 48. 24 . Area(Hght) 5172. 20853. 12188. 15450. 11065. 11377. 21061. 29953. 16429. 24148. 3050. 21566. 22283. 7264. 27351. Amnt(L) 20. 00 20. 00 20. 00 20. 00 20. 00 20. 00 25. 00 25. 00 25. 00 R. [ 3. 4. 0. Amount 20. 000 20. 000 20. 000 20. 000 20. 000 20. 000 64. 809 66. 517 48. 239 40. 437 50. 046 50. 343 63. 325 39. 797 43. 473 -ac R. Fi , 000 000 , 000 000 , 000 000 " 253 , 633 , 630 ( PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB 3C (L) 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 1. 257 1. 741 D. 327 y.Tot 3. 3. 3. 3. 3. 3. 11. 11. S. 6. 3. 3. 10. 6. 7. Rat: 2. 2. 1. 41 41 41 41 41 41 04 33 22 39 53 53 79 73 41 LO 00 00 00 00 00 00 59 66 93 3 00329 !lat3 Subject To Validation No 10 11 1^2 'l3 14 15 Ret(L) 12: 17 14:34 13:01 8: 23 8: 59 20: 07 Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 RRT(L> 0. 919 1. 090 0. 885 0. 965 1. 035 0. 989 Ratio 1. 00 1. OO 1. 00 1. 00 1. 00 1. 00 ^ -_ Amn t 40. 44 50. 05 50. 34 63. 33 39. SO 43. 47 Amnt(L) 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 R. Fac R. 1. 585 0. 200 1. 559 3. 447 1. 124 1. 977 Fac(L) 0. 980 0. 100 0. 774 1. 361 0. 706 1. 137 Ratio 1. 62 2. 00 2. 01 2. 53 1. 59 1. 74 Data 300330 Subiect To Validation t M< .• 100.On 50.0" '.'I . Z! , 43.9- 9.0-] 4.5- G "l? - w lyy.tiT tu cn J. 50.0d fD* Z, 0.0- ^ -50.0- Cl, o 3 •.-100.0- TARGET COMPOUND COMPARISON COMPOUND: C740 BIS(2ETHYLHEXYL)PHTH RAW DATA: SUUQBOIP #1205 81/27/95 28:07 SAMPLE: RBSO/011995 WATER HLA CONDS.: RTX-5 0.25MM X SOM l.OUM 45/4-325@20 BASE M/Z: INST B 149 RIC: 41344. I ' I — I — ' ^ — ' "I" '• I "•'—r*"'—r-^—r^—r-'—r-r- ENHANCED DATA: SUUQBOIP #1205 r 11088. T — ' — I — ' — I ' l — ' — I — r — \ — ' — I — f — 1 — ' — I — ' — I — ' — r BASE M/Z: 149 RIC: 36608. T~r ' I ' — I — f ^ — * • LIBRARY FILE: SN #56 _L ^ r 9744. J — T — | — 1 — p - T — I — I — ] 1 — I — r — T — I — I — I — | — T — j — , — I — r - BASE M/Z: 149 I ' I ' I I ' I ' I ' RIC: 1586. " I — ' — T — ' — I — ' — r 50 _ j — , — I — , — I — ^ — p 100 150 -i I I I I I I I j I I — I r 200 I ' I — ^ I ' I 250 .1.1. ...111. . ..ill. 1. til CO o o CO CO 1000. DATA FROM FILE: SUUQCOIP SCANS 384 TO 1119 ACQUIRED: 01/27/95 20:58:00 CALI: SUUQCOIP #1 SAMPLE: RBSO/011895 WATER HLA CONDS.: RTX-5 0.25MM X SOM l.OUM 45/4-325(520 INST B ' ii .* 400 . 6:40 500 . 8:20 680 . 10:00 700 - 11:40 800 . 13:20 908 _ ..^ 15:0( n 1800 . 16:40 Iz we OJ to ± Csbu 2-FLUuRuPkLNuL 57^ ^§§-§5 < 3^440.) -CS70 ?-ftLLW«ff--D4 0.8 < m ^ ^ - ' ' CI30 D4-1..4 DICHLOROBENZENE (IS-1) — CS75 1..2-CL2BENZENE-D4 0.4 (SS-8) CS20 D5-NITROBENZENE 0.2 (SS-1) CI40 DS-NAPHTHALENE (IS-2) CS25 2-FLUOROBIPHENYL 0.7 (SS-2) CI50 DIO-ACENAPHTHENE (IS-3) CS55 2.4.6TRIBROMOPHENOL (SS-6) CI68 DIO-PHENANTHRENE (IS-4) ^ Z^; O , I 1^ — CS30 D14-P-TERPHENYL 0.5 (SS-3) il\fJI DATA, FROM FILE: SUUQCOIP SCANS 1119 TO 2200 ACQUIRED: 01/27/95 20:50:88 CALI: SUUQC81P #1 SAMPLE: RBSO/011895 WATER HLA CONDS.: RTX-5 0.25MM X 30M 1.OUM 45/4-325228 INST B w aj t - . ST. a I cC 1200 . 20:00 1400 _ r'-'.i, -ifl 1600 _ 26:40 1800 _ 30:00 2800 . 33:20 ?51 J CO o o CJ CA) CO -• 100.0:^ ( 12672.) CI70 D12-CHRYSENE (IS-5) CI 75 D12-PERYLENE (IS-6) Quantitation Report File: SVVQCOIP - Data: SVVQCOIP. TI 'm 01/27/95 20: 50: 00 .^Sample: RBSO/011895 WATER M | o n d s . : RTX-5 0. 25MM X SOM ^^^ormula: X X X Submitted by: HLA l.OUM 45/4-325620 Instrument: B Analyst:* JAM INST B Weight: 1.001 Acct. No. : 11911 AMOUNT=AREA • REF AMNT/(REF AREA • RESP FACT) Resp. fac. from Library Entry No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 No 1 1 ' 2 3 4 5 6 7 8 9 10 11 12 13 14 15 No 1 2 3 4 5 6 7 8 h9 Name CI30 CI40 CI50 CI60 CI70 CI75 CS50 CS45 CS20 CS25 CS55 CS30 CS70 CS75 C740 m/2 ! 152 136 164 188 240 264 112 99 82 - 172 330 244 132 152 149 D4-: , 1,4 DICHLOROBENZENE DS-NAPHTHALENE DIO- DIO- D12- D12- -ACENAPHTHENE -PHENANTHRENE -CHRYSENE -PERYLENE 2-FLUOROPHENOL D5-PHEN0L D5-NITR0BENZENE 2-FLUOROBIPHENYL 2,4, D14- 0. 6 0. 8 0. 2 0. 7 .6TRIBROMOPHENOL -P-TERPHENYL 2-CHL0R0PHEN0L-D4 1,2--CL2BENZENE-D4 0. 5 0. 8 0. 4 BIS(2ETHYLHEXYL)PHTH Bean 519 639 801 936 1220 1557 391 487 574 737 874 1081 500 537 1205 Ret(L) Ra' 8: 41 10:40 13:22 15: 36 20:21 25: 59 6: 37 8: 10 9: 35 0. ' 0. 1. ' Time Ref 8:39 10:39 13:21 15:36 20: 20 25: 57 6:31 8:07 9: 34 12: 17 14: 34 18: 01 8: 20 8: 57 20:05 tio RRT(L) DO 1.000 DO 1.000 DO 1.000 DO 1.000 DO 1. 000 00 1. 000 98 0.762 99 0. 940 00 0. 898 1 2 3 4 5 6 1 1 2 3 3 5 1 1 5 0. 0. 0. 0. 1. 0. 0. 1. 0. RRT 000 000 000 000 000 000 753 938 898 920 091 836 963 035 988 1 Ratio 0. 00 00 00 00 00 00 99 00 OO (IS-1) (IS-2) (IS-3) (IS-4) (IS-5) (IS-6) (SS-5) (SS-4) (SS-1) (SS-2) (SS-6) (SS-3) (SS-7) (SS-8) Meth A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB Amnt 20. 00 20. 00 20. 00 20. 00 20. 00 20. 00 60. 00 60. 75 46. 26 Area(Hght 4958. 19994. 11572. 14693. 10396. 10213. 18692. 26222. 15105. 20508. 2823. 20256. 19710. 5561. 1602. Amnt(L) 20. 00 20. 00 20. 00 20. 00 20. 00 20. 00 25. 00 25. 00 25. 00 ) Amount 20. 20. 20. 20. 20. 20. 60. 60. 46. 36. 48. 50. 58. 31. 2. R. Fac 3, 4. 0. 000 000 000 000 000 000 002 745 257 169 787 328 431 732 710 PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB R.Fac(L) 000 000 000 000 000 000 , 016 , 231 . 604 ' 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 1. 257 1. 741 0. 327 y.Tot 3. 3. 3. 3. 3. 3. 11. 11. 3. 7. 9. 9. 11. 6. 0. Rat: 1. 1. 1. 1. 1. 1. 2. 2. 1. 38 88 83 88 83 88 65 79 98 02 47 77 34 17 53 Lo 00 00 00 00 00 00 40 43 , 85 300334 Data Subject To Validation -^ s? "ii ^ • ^ ^ No 10 11 ^ 1 2 |l3 ^14 15 Ret(L) 12: 17 14:34 18:01 8:23 8: 59 20:07 Ratio 1. 00 1. 00 1. 00 0. 99 1. 00 1. 00 RRT(L) 0. 919 1. 090 0. 885 0. 965 1. 035 0. 989 Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 _ Amnt "36. 17 48. 79 50.33 53. 43 31. 73 2.>1 Amnt(L) 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 R. Fac R. 1. 418 0. 195 1. 559 3. 180 0. 897 0. 123 Fac(L) 0. 980 0. 100 0. 774 1. 361 0. 706 1. 137 Ratio 1. 45 1. 95 2. 01 2. 34 1. 27 0. 11 300335 Data Subject To ValidatioR 63.8-1 !1.9- 57.0- 90 c;- TARGET COMPOUND COMPARISON COMPOUND: C740 BIS(2ETHYLHEXYL)PHTH RAW DATA: SUUQCOIP #1205 01/27/95 20:58 SAMPLE: RBS0/eilS95 WATER HLA CONDS.: RTX-5 8.25MM X 30M l.OUM 45/4-325@20 BASE M./Z: INST B 1 — ' — I — ' — I — ' — I — ^ - f - * T — I — K - i — I — I ' - I — I — I — r ENHANCED DATA: SUUQCOIP #1205 149 RIC: 1896. T - * - ' — I — f ^ T — ' — I — ' - T — ' — I — ' — r 1 — ' - ' - T — ' — I — ' — I — ' — I — ^ ' ' - i — ' — I — ' — I — ' — I — ' — I — ' — I — ' — I — ' — r BASE M/Z: 149 RIC: 1516. 638. 1—'—r - 1 — , — T — 1 — r 1 1 — I — I — r I ' l ' 570. C IU tn c a .0-: 50.0-J LIBRARY FILE: SN #56 ~ i — ' — I — ' — I — ' — I — ' — I — ' — I — ' - CJ o o CO CO o^ BASE M/Z: 149 RIC: 1586. T — ' — I — ' — I — ' — I — ' • • ' — I • " I I I — I — r T—'—T"'—I—'—I—^ r 1000. - I — ' 1 — r — I — r M/Z 100.0- 50.0^ 0.0-: -50.0-: iOi:i 0 - 50 1 1 « - 108 150 "P •! 280 250 \ ,.. . . - r » V ( ' 100.0-> 50.8- •7.1 M/Z 100! 0-1 MASS SPECTRUM 02/03/95 10:21:00 -K 8:16 SAMPLE: DFTPP 290-14-PERF CONDS.: RTX-5 0.25NM X SOM l.OUM #495 TO #497 AUERAGED - #498 Xl.OO O •LLJ DATA: BP020895J #496 CALI: BP820895J #1 51 39 —L- 57 jr.'' UJ : > LU a: 45/4-325e20 . INST B > 00 6Q 1 27 ' • ^ - 50 ?7 110 9t3 .. IL T-*-^ 11 100 ' ^ > ^ 186 141 167 179 I 198 158 T — f - T I . .1 206 BASE M/Z: 193 RIC: 11200. 224 255 244 T — ' — r - * T 280 ?50 1866. 1866. C f t ' sxs tn J50.0 n>° R. g M/Z CO o CO, CJ , v j i i75 296 3*5 423 442 479 \ ' 'I - I — r ?00 350 -T 1 1 . 1 1 p-T 1 X ,- 400 450 « DATA: BP020895J #495 CALI: BP020895J #1 SCANS 100.0-1 RIC o w Ol tj'li i.^ O" •'•X) n •~i O < O) a cu f-* O •-• CJ o o CJ CJ 00 « \^ 4 RIC 02/03/95 10:21:00 SAMPLE: DFTPP 290-14-PERF CONDS.: RTX-5 0.25MM X 30M 1.0UM 45/4-325@20 INST B RANGE: G 1, 650 LABEL: N O.. 4.8 QUAN: A O. l.O J O BASE: U 20. 496 \ 488 TO 538 8:00 16448. 484 487 43: cr. - - • . / ^ 5 0 7 511 514 .--•x. i.^zy ^16 521 490 8:10 500 8:20 -T 518 8:30 525 y\ 523 I 520 8:40 I 530 SCAN 8:50 TIME r . f y i ' 180.en RIC•^MASS CHROMATOGRAM DATA: BPe20395J #495 SCANS 550 TO 650 02/08/95 10:21:00 CALI: BP020395J #1 SAMPLE: DFTPP 290-14-PERF CONDS.: RTX-5 0.25MM X SOM l.OUM 45/4-325(520 INST B RANGE: G 1. 658 LABEL: N 8, 4.0 QUAN: A O, l.O J 8 BASE: U 28.. 3 591 5144. 184 184.055 ± 0.500 182.3n Q':'7C y :A^ !:.v RIC CJ; §! CO I CJ, vo. 554 559 n r 560 9:20 •^563 575 579 533 .' m ' ^ . ^ - " l . . . - L ^ -•^. . - " ^ 5.^2 gee c,iQ 515 g.-.., y \i-^., y-.. . - . . . . w^*. 5S8 9:40 I 600 10:00 620 10:20 651 .y\ 640 640 10:40 SCAN TIME »v,. Mass List Data: BP020B95J 4» 496 Base m/z: 198 02/08/95 10:21:00 + 8:16 Cali: BP020895J # 1 RIC: 11200. Sample: DFTPP 290-14-PERF onds. : #495 t 39 479 Mass 39? 50? 51? 52? 57? 69 74 75 76 77 78 01 93 98 99 107 110 111 117 127 120 1 129 ' 14.1 167 179 186 187 196 198 199 204 205 206 207 217 221 224 225 227 244 255 256 258 274 275 276 k 296 r 365 423 441 RTX-5 0.25MM X 30M l.OUM 0 #497 avera S S s s s s s s s s s s s s s s s s s s s s s s- s s s s s s s s s s s s s s s s s s s s s s s s s s 0. 00 Vm R A 2. 57 9. 16 33. 17 1. 61 1. 77 42. 50 2. 47 5. 04 1. 45 36. 87 1. 71 1. 66 4. 13 3. 16 2. 84 10. 61 20. 63 3. 59 7. 34 45. 44 3. 80 15.33 1. 34 4. 34 3. 48 10. OS 3. 22 3. 00 100. 00 6. 22 1. 45 4. 88 19. 67 1. 66 5. 95 8. 41 12. 33 2. 89 4. 02 9. 49 41. 75 5. 25 1. 34 2. 09 22. 99 2. 04 4. 23 1. 61 1. 66 3. 64 iged - #490 XI. 00 0. Minima Maxima Inten. Mass 48. 442 171. 443 619. 479 30. 33. 793. 46. 94. 27. 638. 32. 31. 77. 59. 53. 198. 385. 67. 137. 848. 71. 286. 25. 81. 65. IBS. 60. 56. 1866. 116. 27. 91. 367. 31. 111. 157. 230. 54. 75. 177. 779. 98. 25. 39. 429. 33. 79. 30. 31. 68. 45/4-325<a20 Min Inten: # 0 7. RA S 44. 43 S 8.09 S 1. 39 -»" -. INST B 0. Inten. 829. 151. 26. 300340 Data Subject To Valfdat/ore GC/MS Tuning and Mass Calibration DECAFLUOROTRIPHENYLPHOSPHINE Case Number: Laboratory: GULF Inst ID: B Sens Date: 02/08/95 Sens Time: 10:21:00 Lab ID: BP020895J Cali Date: 10/02/91 Data release authorized by: Contract: Sens Time: Analyst: 10:; JAM M/E Ion Abundance Criteria Spec # 495 51 30 to 607. of mass 198 68 less than 27. of mass 69 0.00 ( 0.00) 1 69 mass 69 relative abundance 70 less than 27. of mass 69 0.00 ( 0.00) 1 127 40 TO 607. of mass 198 197 less than 17. of mass 198 198 base peak, 100/i relative abundance 199 5 TO 97. of mass 198 275 10 TO 307. of mass 198 365 greater than IV. of mass 198 441 less than mass 443 442 greater than 407. of mass 198 443 17 TO 237. of mass 442 8.09 (18. 1 - value in parenthesis is 7. of mass 69 2 - value in parenthesis is 7. of mass 442 33. 0. 42. 0. 45. 0. 100. 6. 22. 1. 3. 44. 8. 17 00 50 00 44 00 00 22 99 61 64 43 09 Data 300341 Subiect To Validation DATA FROM FILE: BS020395B SCANS 348 TO 1083 ACQUIRED: 82/08/95 11:24:00 CALI: BS820895B #1 SAMPLE: 5STD050 290-12-SU25 CONDS.: RTX-5 0.25MM X SOM 1.0UM 45/4-325(520 INST B ' 100.0;; ( 59328.) 400 J 6:40 500 . 8:20 10:00 700 J 11:40 Rflfi 13:20 D CJ try C ^ n" a o^ g a, Ri E^ 3 CJ o o CO l(^ to 900 15:00 1000 16:40 m I CS50 2-FLUORuPHENOL 0.6 (SS-5) CS45 D5-PHEN0L 0.8 (SS-4) -e-130 D4-l,4 DICHLOROBENZENE (IS-l) CS75 1..2-CL2BENZENE-D4 8.4 (SS-8) ;C??8 D5-NITROBENZENE 0.2 (SS-1) CI40 DS-NAPHTHALENE (IS-2) CS25 2-FLUOROBIPHENYL 8.7 (SS-2) -«§a- D18-ACENAPHTHENE (IS-3) ;.. 4.6TRI BROMOPHENOL (SS-6) CI60 D10-PHENANTHRENE (IS-4) -?c CS30 D14-P-TERPHENYL 8.5 (SS-3) •V. •K,. DATA FROM FILE: BS020S95B SCANS 1033 TO 2108 ACQUIRED: 82/83/95 11:24:88 CALI: BSe20395B #1 SAMPLE: SSTD050 290-12-SU25 CONDS.: RTX-5 0.25MM X SOM l.OUM 45/4-325P20 INST B R^ c: a- ni' _! < CJ'CL, OK. 05" ^ \ CJl 1200 28:00 1400 J 23:20 1600 J 26:40 IS00 . 30:00 2000 J' 33:20 Wi I I -^ IOO.O,*; ( 50048.) PT7R=ITI7=CHRTSENE (IS-5) CI75 D12-PERYLENE (IS-6) r »V / • Quantitation Report File: BS020895B m Data: BS020895B. TI 02/08/95 11:24:00 Sample: SSTDOSO 290-12-SV25 Conds.: RTX-5 0. 25MM X 30M l.OUM 45/4-325^20 ormula: X X X Instrument: B ubmitted by: Analyst: JAM INST B Weight: Acct. No. 1. 000 AMOUNT=AREA * REF AMNT/(REF AREA • RESP FACT) Resp. fac. from Library Entry No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 33 39 40 41 42 43 44 45 46 47 Name CI30 CI 40 CI 50 CI60 CI70 CI75 CS50 CS45 CS20 CS25 CS55 CS30 CS70 CS75 C315 C325 C330 C335 C340 C320 C310 C319 C345 C350 C355 C357 C365 C370 C375 C410 C415 C420 C425 C430 C435 C440 C445 C450 C455 C460 C465 C470 C510 C515 C520 C525 C530 D4-l,4 DICHLOROBENZENE DS-NAPHTHALENE DIO-ACENAPHTHENE D10-PHENANTHRENE D12-CHRYSENE D12-PERYLENE 2-FLUDROPHENOL O. 6 D5-PHEN0L O. 8 D5-NITR0BENZENE O.2 2-FLUOROBIPHENYL 0.7 2,4,6TR1BROMOPHENOL D14-P-TERPHENYL 0.5 2-CHL0RDPHEN0L-D4 0. 8 1,2-CL2BENZENE-D4 «-PHENOL 0. 4 0. 8 (IS-1) (IS-2) (lS-3) (IS-4) (IS-5) (IS-6) (SS-5) (SS-4) (SS-1) (SS-2) (SS-6) (SS-3) (SS-7) (SS-8) BIS(2CHL0RDETHYL)E 0.7 2CHL0R0PHEN0L 0. 8 1,3DICHL0R0BENZENE 0. 6 #1,4DICHL0R0BENZENE 0.5 ANILINE N-NITROSODIMETHYLAMINE PYRIDINE BENZYL ALCOHOL 1,2DICHLOROBENZENE 0.4 2METHYLPHEN0L 0. 7 4METHYLPHEN0L S<NITROSOPRDPYLAMINE HEXACHLOROETHANE NITROBENZENE ISOPHORONE *2-NITR0PHENDL 2,4-DIMETHYLPHENOL BENZOIC ACID BIS(2CHLDR0ETH0XY) «2,4DICHL0R0PHEN0L 0. 6 0. 5 0. 3 0. 2 0. 4 0. 1 0. 2 0. 3 O. 2 T T T T 1, 2, 4TRICHLOROBENZ 0.2 NAPHTHALENE 0. 7 4-CHLOROANILINE *CL6BUTADIENE *4CHL0R03METHYLPHEN 0. 2 2METHYLNAPHTHALENE 0. 4 S<CL6C YCLOPENTAD 1 ENE *246TRICHLOROPHNEOL 0.2 2, 4, 5TRICHL0R0PHEN 0.2 2CHLDR0NAPHTHALENE 0. 8 2-NITROANILINE 300344 D:zco Subiec; To Vaiidatiott No Name 48 C535 DIMETHYL PHTHALATE 49 C540 ACENAPHTHYLENE 1.3 50 C545 3-NITRDANILINE No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 m/2 152 136 164 188 240 264 112 99 82 172 330 244 132 152 94 93 128 146 146 93 74 79 108 146 108 45 108 70 117 77 82 139 107 122 93 162 180 128 127 225 107 142 237 196 196 162 65 163 152 138 Scan 483 602 761 893 1149 .1411 358 457 538 699 832 1035 466 501- 458. 462- 467 479 • 484- 457- 179 178 500- 502. 512- 513 526. 526 530 540 561 569 573- 586, 531 591 593 604 613 613 654 665 684 693 • 698 ' 709 723 738 747 761 TJ 8: 10: 12: 14: 19: 23: 5: 7: 8: 11: 13: 17: 7: 8: 7: 7: 7: 7: 8: 7: 2. 2' 8: 8: 8: 8: 8: 8: 8. 9. 9. 9. 9 9: 9: 9: 9: 10: 10: 10: 10: 12. 12 12 12 ime 03 02 41 53 09 31 58 37 58 39 52 15 46 21 38 42 47 59 04 37 59 58 20 22 32 33 46 46 50 00 21 29 33 46 41 51 53 04 13 18 54 05 24 33 38 49 03 13 27 41 Ref 1 2 3 4 5 6 1 1 2 3 3 5 2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3 0. 0. 0. 0. 1. 0. 0. 1. 0. 0. 0. 0. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1 RRT 000 000 000 000 000 000 741 946 894 919 093 901 965 037 948 957 967 992 002 946 371 369 035 039 060 062 0B9 089 097 897 932 945 952 973 965 932 993 003 018 027 086 105 899 911 917 932 950 970 932 000 Meth A BB A BB A BB A BB A BB A BB A BB A BV A BB A BB A BB A BB A BB A BB A BB A VB A BB A BV A VB A BV A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BD A BV A VB A BB A BB A BB • A BB A BV A VB A BB A BB A BB A BB A BB Area(Hght) 9715. 33991. 20687. 27470. 24279. 21766. 11548. 16029. 11292. 26378. 3061. 24885. 14033. 9041. 17927. 16143. 13874. 15758. 17154. 13464. 7050. 9392. 8116. 15135. 11597. 13941. 12472. 6935. 5339. 11591. 22917. 7453. 8587. 4310. 15430. 11243. 13251. 37771. 6700. 6236. 8870. 24962. 1535. 7953. 8436. 23048. 4562. 26343. 34328. 413. *rrno(;?rp S^mhSZ^ — Amount 20. 000 20. 000 20. 000 20. 000 20. 000 20. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000' 25. 000 25. 000 25. 000 25. 000 25. O'OO 25. 000 25. 000 Data Sublet PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB 7.Tot 0. 0. 0. 0. 0. 0. 1 95 95 95 95 95 95 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 300345 .t To '/afidatiors No Ret<L) Ratio RRT<L) Ratio 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 23 29 130 '31 32 33 34 35 36 37 33 39 40 41 42 43 44 45 46^ 471 48 49 50 8:03 10:02 12:41 14:53 19:09 23:31 5:58 7:37 B: 58 11: 39 13: 52 17: 15 7:46 8:21 7:38 7:42 7:47 7: 59 8: 04 7:37 2: 59 2: 58 8:20 8:22 8: 32 8: 33 8: 46 8:46 8: 50 9: 00 9:21 9: 29 9: 33 9:46 9:41 9: 51 9: 58 10:04 10: 13 10: 18 10: 54 11: 05 11:24 11: 33 11: 33 11: 49 12:03 12: 18 12:27 12:41 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 00 00 00 00 00 00 00 00 1. 00 00 00 1. 00 00 00 1. 00 1. 00 00 00 00 00 00 00 1. 000 1. 000 1.000 1. 000 1. 000 1. 000 0.741 O. 946 0. 894 0. 919 1. 093 0. 901 0. 965 1. 037 0. 948 0. 957 0. 967 0. 992 1. 002 0. 946 0. 371 0. 369 1. 035 039 060 062 089 089 097 0. 897 0. 932 O. 945 O. 952 O. 973 0. 965 0. 982 0. 993 1. 003 1. 018 1. 1. 1. 0. 027 086 105 899 0. 911 0. 917 0. 932 0. 950 0. 970 0. 982 1. 000 1. 00 1. 00 1.00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 00 00 00 00 00 00 1. 00 00 00 00 00 00 00 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 00 00 00 1. 00 1. 00 1. 00 Amnt 20. 00 20. 00 20. 00- 20. 00 20. 00 20. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 Amnt(L) R. Fac R.Fac(L) Ratio 20. 00 20. 00 20. 00 20. 00 20. 00 20. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 .25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 0. 951 1. 320 0. 266 020 118 820 156 744 476 329 142 298 413 109 581 0. 773 0. 668 J46 955 148 027 571 0. 485 0. 273 0. 539 O. 175 202 113 363 265 312 0. 889 0. 153 0. 147 0. 209 0. 587 0. 059 0. 303 0. 326 0. 891 0. 176 1. 019 1. 347 O. 016 1. 0. 0. 1. 0. 1. 1. 1. 1. 1. 1. 0. 1. 0. 1. 1. 0. 0. 0. 0. 0. 0. 0. 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 0. 951 1. 320 0. 266 1. 020 0. 118 0. 820 1. 156 744 476 329 142 298 413 1. 109 0. 581 0. 773 0. 668 1. 246 0. 955 1. 148 1. 027 0. 571 O. 485 0. 273 0. 539 0. 175 0. 202 0. 113 0. 363 0. 265 0. 312 0. 889 0. 158 0. 147 0. 209 0. 587 0. 059 0. 308 0. 326 0. 891 0. 176 1. 019 1. 347 0. 016 00 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 00 00 00 00 00 00 00 00 1. 00 00 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 300346 Data Sijbiea To Vaiidationi Quantitation Report File: BS020895B Data: BS020B95B. TI 02/08/95 11:24:00 Sample: SSTDOSO 290-12-SV25 Conds.: RTX-S 0. 25MM X 30M l.OUM 45/4-325220 ormula: X X X Instrument: B Submitted by: Analyst: JAM INST B Weight: Acct. No. 1. 000 AMOUNT=AREA « REF AMNT/(REF AREA « RESP FACT) Resp. fac. from Library Entry No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 Bl 82 83 34 85 No 51 52 53 54 55 56 57 58 Name C550 C321 C555 C560 C565 C570 C543 C580 C585 C590 C595 C610 C615 C625 C630 C635 C640 C645 C650 C655 D200 C647 C715 C720 C725 C730 C740 C735 C760 C765 C770 C775 C780 C785 C790 m/z 153 232 184 109 168 165 165 149 •ACENAPHTHENE 0.8 2,3,4,6-TETRACHLORDPHENDL 8<2, 4DINITR0PHEN0L J<4NI TROPHENOL DIBENZOFURAN 0. 8 2,4DINITR0TDLUENE 0.2 2, 6DINITRDT0LUENE 0. 2 DIETHYL PHTHALATE 4CHLOR0PHENYL PHEN 0. 4 FLUORENE 0. 9 4-NITROANILINE 4,6DINITR02METHYLPH •DIPHENYLAMINE 4BR0M0PHENYL PHENY 0. 1 CL6BENZENE 0. 1 •PENTACHLOROPHENOL 0. 05 PHENANTHRENE 0. 7 ANTHRACENE 0. 7 DI-NBUTYLPHTHALATE •FLUORANTHENE 0. 6 1,2-DIPHENYLHYDRAZINE CARBAZOLE PYRENE 0. 6 BUTYLBENZYLPHTHALATE 3,3'CL2BENZIDINE BENZO(A)ANTHRACENE 0.8 BIS(2ETHYLHEXYL)PHTH CHRYSENE 0. 7 •DI-N-OCTYLPHTHALATE BENZO(B)FLUORANTHE 0.7 BENZO(K)FLUORANTHE 0.7 •BENZO(A)PYRENE 0. 7 INDENOd, 2, 3CD)PYR 0.5 DIBENZO(A, H)ANTHRA 0.4 BENZO(G,H, DPERYLE 0.5 Scan Time Ref RRT 764 12 793 13 763 12 775 12 778 12 731 13 746 12 BOO 13 44 3 1. 004 13 3 1.042 48 3 1.009 55 3 1.018 58 3 1.022 01 3 1.026 26 3 0. 980 20 3 1.051 T T T Meth A A A A A A A A BD BB BB BB BB - BB BB BB Area(Hght) 21439. 8026. 2423. 1704. 33046. 8310. 6376. 23687. Amount 25. 25. 25. 25. 25. 25. 25. 25. 000 000 000 000 000 000 000 000 PPB PPB PPB PPB PPB PPB PPB PPB • y.Tot 1. 19 1. 19 1. 19 1. 19 1.19 1. 19 1. 19 1. 19 3 0634'r Data Subiect To Valid'atton: No 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 No |51 '52 53 54 55 56 57 53 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 |76 F77 m/z 204 166 138 198 169 248 284 266 178 178 149 202 77 167 202 149 252 228 149 228 149 252 252 252 276 278 276 Scan Time R 807 13 809 13 818 13 818 13 818 13 850 14 865 14 881 14 895- 14 899' 14 943 15 1003- 16 821 13 914 15 1025- 17 4 J 1081 18 L143 19 1147. 19 1142 19 1153 19 1232 20 1325 22 1329 22 1397' 23 1740- 29 1745 29 1843 30 Ret(L) Ratio 12: 13: 12: 12: 12: 13: 12: 13: 13: 13: 13: 13: 13: 14: 14: 14: 14: 14: 15: 16: 13: 15: 17: 18: 19: 19: 19: 44 13 48 55 58 01 26 20 27 29 33 38 33 10 25 41 55 59 43 43 41 14 05 01 03 07 02 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 :27 :29 :38 :38 :3B : 10 :25 :41 : 55 : 59 :43 :43 :41 : 14 : 05 :01 :03 :07 :02 : 13 :32 :05 :09 : 17 : 00 :05 :43 RRT(L: 1. 004 1. 042 1. 009 1. 018 1. 022 1. 026 0. 980 1. 051 1. 060 1. 063 1. 075 0. 916 0. 916 0. 952 0. 969 0. 937 1. 002 1. 007 1. 056 1. 123 0. 919 1. 024 0. 892 0. 941 0. 995 0. 998 0. 994 ef 3 3 3 4 4 4 4 4 4 4 4 4 4 4 5 5 5 5 5 5 6 6 6 6 6 6 6 ) Ri RRT 1.060 1. 063 1.075 0. 916 0. 916 0. 952 0. 969 0. 987 1. 002 1.007 1. 056 1. 123 0. 919 1. 024 0. 892 0. 941 0. 995 0. 998 0. 994 1. 003 0. 873 0. 939 0. 942 0. 990 1. 233 1. 237 1. 306 atio 00 00 00 00 00 00 00 00 00 00 00 00 , 00 00 . 00 , 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 Meth A BB A BB A BB - A BB A BB A BB A BB A BB A BV A VB A BB A BB A BB A BB A BB A BB A BB A BV A BB A VB A BB A BV A VB A BB A BB A BB A BB Amnt 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00. 25. 00 25. 00 25. 00 Area(Hght] 13104. 25696. 1483. 4235. 9876. 7132. 7579. 3960. 34059. 34251. 47503. 39279. 25116. 7881. 43158. 20631. 5211. 33352. 29110. 30488. 44053. 29609. 24792. 24934. 24304. 19579. 21086.^ Amnt(L) 1 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 ^:r^zWr? 1 Amount 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB R. Fac R. Fac(L) 0. 0. 0. 0. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0, 0 0 0 0 1 1 0 0 1 0 0 1 0 831 310 094 066 278 321 266 916 507 994 057 123 288 , 208 . 221 . 115 . 992 . 997 . 383 . 144 . 731 . 230 . 422 . 680 . 172 . 099 . 959 0. 831 0. 310 0. 094 0. 066 1. 278 0. 321 0. 266 0. 916 0. 507 0. 994 0. 057 0. 123 0. 288 0. 208 0. 221 0. 115 0. 992 0. 997 1. 383 1. 144 0. 731 0. 230 1. 422 0. 680 0. 172 1. 099 0. 959 1. Rat: 300348 ot 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 io 00 00 00 00 00 00 00 00 00 00 00 00 00 , 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 Data Subjea To VaHdatiors! No Ret(L) Ratio RRT<L) Ratio Amnt Amnt(L) R.Fac R.Fac(L) Ratio 78 19:13 1.00 1.003 1.00 25.00 25.00 1.005 1.005 1.00 79 20: 32 I. 00 0. 873 1. 00 25. 00 25. 00 1. 619 1. 619 1. 00 80 22:05 1.00 0.939 1.00 25.00' 25.00 1.088 1.088 1.00 81 22:09 1.00 0.942 1.00 25.00 25.00 0.911 0.911 1.00 82 23:17 1.00 0.990 1.00 25.00 25.00 0.916 0.916 1.00 83 29:00 1.00 1.233 1.00 25.00 25.00 0.893 0.893 1.00 84 29: 05 1. 00 1. 237 1. 00 25. 00 25. 00 0. 720 0. 720 1. 00 85 30:43 1.00 1.306 1.00 25.00 25.00 0.775 0.775 1.00 300349 Data subject To Validation Calibration Check Instrument Identifier: B Calibration Date: 11/09/94 Standard File: BS020B95B Date: 02/08/95 Time: 11 WIN RF: SW(8<) = . OS / CLP 'MAX 7.D: SW(^) = 307.*^ CLP CS50 CS45 CS20 CS25 CS55 CS30 CS70 CS75 C315 C325 C330 C335 C340 C320 C310 C319 C345 C350 C355 C357 |C365 ^ 3 7 0 C375 C410 C415 C420 C425 C430 C435 C440 C445 C450 C455 C460 C465 C470 C510 C515 C520 C525 C530 C535 C540 C545 C550 1^221 ^ 5 5 5 Compound 2-FLUOROPHENOL D5-PHEN0L DS-NITRDBENZENE 2-FLUORDBIPHENYL 0. 0. 0. 0. 2,4,6TRIBROMOPHENOL D14-P-TERPHENYL 2-CHLDR0PHEN0L-D4 1,2-CL2BENZENE-D4 •PHENOL BIS(2CHL0RDETHYL)E 2CHL0R0PHEN0L 1.3DICHLDRDBENZENE •1,4DICHL0R0BENZENE ANILINE 0. 0. 0. 0. 0. 0. 0. 0. : 24: 00 = ' e 6 8 2 7 5 8 4 8 7 B 6 5 N-NITR OSODIMETHYLAMINE PYRIDINE BENZYL ALCOHOL 1.2DICHL0R0BENZENE 2METHYLPHEN0L 0. 0. 2,2'0XYBIS(ICHLOROPR 4METHYLPHEN0L &NITROSOPROPYLAMINE HEXACHLOROETHANE NITROBENZENE ISOPHORONE •2-NITROPHENOL 2,4-DIMETHYLPHENOL BENZOIC ACID BIS(2CHL0R0ETH0XY) •2,4DICHLOROPHENOL 1,2, 4TRICHL0R0BENZ NAPHTHALENE 4-CHLOROANILINE •CL6BUTADIENE •4CHL0R03METHYLPHEN 2METHYLNAPHTHALENE &CL6CYCL0PENTADIENE •246TRICHLOROPHNEOL 2,4,5TRICHL0R0PHEN 2CHL0R0NAPHTHALENE 2-NITROANILINE DIMETHYL PHTHALATE ACENAPHTHYLENE 3-NITROANILINE •ACENAPHTHENE 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1 0 4 7 6 5 3 2 4 1 2 3 2 2 7 2 4 2 2 , 8 . 3 . 8 2,3,4,6-TETRACHLOROPHE ?<2, 4DINITR0PHEN0L . 01 DR 257. Mean RF(I) 0. 996 1. 309 0. 294 1. 089 0. 117 0. 841 1. 095 .0. 725 1. 593 1. 384 1. 118 1. 234 1. 251 1. 393 0. 621 0. 918 0. 531 1. 143 1. 035 1. 301 1. 056 0. 614 0. 454 0. 294 0. 575 0. 176 0. 225 0. 140 0. 383 0. 256 0. 273 0. B57 0. 323 0. 127 0. 237 0. 583 0. 286 0. 329 0. 356 1. 022 0. 271 1. Ill 1. 558 0. 14S 0. 916 0. 302 0. 143 BELOW RF(D) 7. D 0. 951 1. 320 0. 266 1. 021 0. 119 0. 820 1. 156 0. 745 1. 477 1. 330 1. 143 1. 298 1. 413 1. 109 0. 581 0. 774 0. 669 1. 247 0. 955 1. 148 1.028 0. 572 y 0. 485 0. 273 0. 540 0. 176 0. 203 0. 114 0. 364 0. 265 0. 312 0. 889 0. 158 0. 147 0. 209 0. 583 0.060 y 0. 308 0. 327 0. 892 0. 177 1. 019 1. 347 0. 016 0. 832 0.311 y 0.094 y 4. 516 0. 857 9. 541 6. 253 1. 182 2. 499 5. 584 2. 827 7. 288 y 3. 936" 2. 244 5. 175 . 12. 999.^^ 20. 345 6. 438 15. 698 15. 130 9. 122 7. 645 11. 719 2. 657 6. 962 6. 978 7. 179 6. 153 0.071 y 9. 922 18. 788 6. 286 3. 3 9 2 ^ 14. 461 3. 837 51. 044 16.002 y 11.646 y 0. 848 79. 054 6. 4 3 1 ^ 8. 295 12. 700 34. 727 3. 274 13. 498 88. 834 9. 263 y 2. 976 36. 201 300350 Zata ^ubif. °"^" •" VaMdaho^ ^ ^ ^ r m C560 &4NITR0PHEN0L C565 DIBENZOFURAN 0. 8 C570 2,4DINITRDTDLUENE O.'2 C543 2.6DINITRDT0LUENE O. 2 C580 DIETHYL PHTHALATE C585 4CHL0RDPHENYL PHEN 0. 4 590 FLUORENE 0. 9 C595 4-NITROANILlNE C610 4.6DINITR02METHYLPH C615 •DIPHENYLAMINE C625 4BR0M0PHENYL PHENY 0. 1 C630 CL6BENZENE 0. 1 C635 •PENTACHLOROPHENOL 0. 05 C640 PHENANTHRENE 0. 7 C645 ANTHRACENE 0. 7 C650 DI-NBUTYLPHTHALATE C655 •FLUORANTHENE 0. 6 D200 1,2-DIPHENYLHYDRAZINE C647 CARBAZOLE PYRENE 0. 6 BUTYLBENZYLPHTHALATE 3,3'CL2BENZIDINE BENZO(A)ANTHRACENE 0.8 BIS(2ETHYLHEXYL)PHTH CHRYSENE 0. 7 C760 •DI-N-OCTYLPHTHALATE C765 BENZO(B)FLUORANTHE 0.7 C770 BENZO(K)FLUORANTHE 0.7 C775 •BENZO(A)PYRENE 0.7 C780 INDEN0(1,2, 3CD)PYR 0.5 C785 DIBENZO(A,H)ANTHRA 0.4 790 BENZO(G,H, DPERYLE 0.5 C715 C720 C725 C730 C740 C735 0. 084 1. 322 0. 360 0. 296 1.062 0. 520 1. 097 0. 124 0. 136 0. 393 0. 183 0. 185 0. 133 1. 012 1. 021 1. 245 0. 987 0. 813 0. 591 1. 440 0. 714 0. 135 1. 107 0. 978 007 555 079 909 917 0. 920 0. 713 O. 765 1. 1. 1. O. O. 0. 066 1.278 O. 322 O. 266 0. 917 0. 507 0. 994 0. 058 0. 124 0. 288 0. 208 0. 221 116 992 998 384 144 732 230 1. 423 0. 680 0. 172 1. 099 0. 960 1. 005 1. 620 1. 089 0. 912 0. 917 0. 894 0. 720 O. 776 y 0. 0. 0. 1. 1. 0. 0. 20. 787 3. 272 10. 490 10. 096 13. 661 2. 448 9. 378 53. 291 8. 922 26. 605 14. 066 19. 583 12. 895' 1. 913 2. 287 11. 116 15. 945 9. 931 61. 097 1. 187 4. 17. 0. 1. 0. 765 709 657 899 227 4. 131 ^ O. 914 0. 263 0.054 y 2. 818 0. 948 1. 409 300351 Data Subject Tc Vciiidatiofi! DATA FROM FILE: SU12098NB2 SCANS 346 TO 1081 ACQUIRED: 02/08/95 12:86:08 CALI: SU12898WB2 #1 SAMPLE: SBLKW WATER-12898WB2 CONDS.: RTX-5 0.25MM X SOM l.OUM 45/4-325@20 INST B ' • " 400 _ 6:40 500 fi'''0 CJ O o CJ C/1 to —« o ' CL. 600 . 10:00 7uy , 11:40 300 . 13:20 900 15:00 1800 . 16:40 m 'ubbU k'-hLUu4lFHENUL J.b (Sb-b) ' 109-0^ < 57856.) CS45 D5-PHEN0L 0.8 (SS-4) CI30 04-1,4 DICHLOROBENZENE (IS-1) CS75 1..2-CL2BENZENE-D4 0.4 (SS-3) CS20 D5-NITROBENZENE 8.2 (SS-1) 0148 DS-NAPHTHALENE (IS-2) CS25 2-FLUOROBIPHENYL 8.7 (SS-2) CI50 D10-ACEHAPHTHEHE (IS-3) -9555 2.. 4.. 6TRI BROMOPHENOL (SS-6) CI60 DIO-PHENANTHRENE (IS-4) CS30 D14-P-TERPHENYL 8.5 (S^-3) ^ n l O €n DATA FROM FILE: SU12898WB2 SCANS 1831 TO 2208 ACQUIRED: 82/88/95 12:86:88 CALI: SU12e9SWB2 #1 SAMPLE: SBLKW WATER-12e9SWB2 CONDS.: RTX-5 0.25MM X SOM l.GUM 4.5/4-325i520 1200 _| 20:00 1400 J 23:20 1600 - 26:40 ^. ^ " ft)' a -HI !<; 1300 30:00 2000 CJ o o CJ Ul CO o Tlr:E I INST B — ' 108.8^ ( 27584.) — CI78 D12-CHRYSENE (IS-5) CI75 D12-PERYLENE (IS-6) r h i • Quantitation Report File: SV1209BWB2 m Date: SV12098WB2. TI 02/08/95 12:06:00 Sample: SBLKW WATER-12098WB2 .Conds.: RTX-5 0. 25MM X 30M l.OUM 45/4-325^20 ormula: X X X Instrument: B Submitted by: Analyst: JAM INST B Weight: Acct. No. : 1. 000 12098 AMOUNT=AREA • REF AMNT/<REF AREA • RESP FACT) Resp. fac. from Library Entry No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 No 1 » 2 3 4 5 6 7 8 9 10 11 12 13 14 15 No Name CI30 CI40 CI50 CI60 CI70 CI75 CS50 CS45 CS20 CS25 CS55 CS30 CS70 CS75 C740 m/2 152 136 164 188 240 264 112 99 82 172 330 244 132 152 149 D4-1 .4 DICHLOROBENZENE DB-NAPHTHALENE DIO- DIO- D12- D12- •ACENAPHTHENE •PHENANTHRENE •CHRYSENE •PERYLENE 2-FLUDROPHENOL D5-PHEN0L D5-NITR0BENZENE 2-FLUDROBIPHENYL 2,4, D14- 0. 6 0. 8 0. 2 0. 7 6TRIBR0MDPHEN0L -P-TERPHENYL 0. 5 2-CHLOROPHEN0L-D4 0. 8 1. 2- BIS( Scan 481 601 760 892 1148 1410 351 453 537 698 831 1035 463 499 1141 -CL2BENZENE-D4 0. 4 :2ETHYLHEXYL)PHTH Time Ref 8: 01 10:01 12:40 14: 52 19: 08 23: 30 5: 51 7: 33 8: 57 11: 33 13: 51 17: 15 7: 43 8: 19 19: 01 1 2 3 4 5 6 1 1 2 3 3 5 1 1 5 RRT 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 0. 730 0. 942 0. 894 0. 918 1. 093 0. 902 0. 963 1. 037 0. 994 Ret(L) Ratio RRT(L) Ratio (IS-1) (IS-2) (IS-3) (IS-4) (IS-5) (IS-6) <SS-5) (SS-4) (SS-1) (SS-2) (SS-6) (SS-3) (SS-7) (SS-8) Meth A A A A A A A A A A A A A A A BB BB BB BB BD BB BD BB BB BB BB BB BB BB BB Amnt Area(Hght) 7994. 29932. 19243. 25386. 20434. 20336. 18361. 29176. 14996. 28764. 5375. 37113. 25181. 7916. 6721. Amnt(L) R. Amount 20. 20. 20. 20. 20. 20. 49. 55. 37. 29. 51. 44. 54. 26. 6. Fac 000 000 000 000 000 000 623 302 703 307 583 300 518 602 853 PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB R.Fac(L) . y.Tot 4. 4. 4. 4. 4. 4. 10. 11. 7. 6. 10. 9. 11. 5. 1. Rat: 20 20 20 20 20 20 43 62 92 16 84 31 46 59 44 Lo 1 8: 03 1. 00 1. 000 1. 00 20. 00 20. 00 1. 000 1. 000 1. 00 2 10:02 1.00 1.000 1.00 2 0 . 0 0 2 0 . 0 0 1.000 1.000 1.00 3 12:41 1.00 1.000 1.00 20.00 2 0 . 0 0 1.000 1.000 1.00 4 14:53 1.00 1.000 1.00 20.00 2 0 . 0 0 1.000 1.000 1.00 5 19:09 1.00 1.000 1.00 20.00 2 0 . 0 0 1.000 1.000 1.00 6 7 8 9 23: 5: 7: 8: 31 58 37 58 1. 0. 0. 1. 00 98 99 00 1. 0. 0. 0. 000 741 946 394 1. 0. 1. 1. 00 98 00 00 20. 49. 55. 37. 00 62^ 30" 70 20. 25. 25. 25. 00 00 00 00 1. 1. 2. 0. 000 883 920 401 1. 0. 1. 0. 000 951 320 266 1. 1. 2. 1. 00 9B 21 51 Data Subied To MdatLoR- " 300354 No 10 11 12 13 14 15 Ret<L) 11:39 13: 52 17: 15 7:46 8:21 19:02 Ratio 1. 00 1. 00 1. 00 0. 99 1. 00 1. 00 RRT<L) 0. 919 1. 093 0. 901 0. 965 1. 037 0. 994 Ratio 1. 00 1.00 1. 00 1.00 1. 00 1.00 Amnt 29. 31 51. 58 44. 30 54. 52 26. 60 6. 86 Amnt(L) 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 R. Fac R. 1. 196 0. 244 1. 453 2. 520 0. 792 0. 263 Fac(L) 1. 020 0. 118 0. 820 1. 156 0. 744 0.959 Ratio 1. 17 2. 06 1.77 2. 18 1. 06 0. 27 300355 Vn \!^<^°^'' TARGET COMPOUND COMPARISON COMPOUND: C740 BIS(2ETHYLHEXYL)PHTH RAW DATA: SU12098WB2 #1141 02/08/95 12:06 SAMPLE: SBLKW WATER-12098WB2 CONDS.: RTX-5 0.25MM X SOM l.OUM 45/4-S25e20 BASE M/Z: INST B 149 RIC: 9856. 100.0- 50.8- Jl I ll T — I — I ' - I — I •}• r I " I — I — 1 — j — - I — I — < — I — < — r - > — r ENHANCED DATA: SU12898WB2 #1141 r 3216. 1 — ' — I — > — I — f — I — ' — I — f ^ — • — r BASE M/Z: 149 X 1 — ' — r — ^ — f — i — I — ' — I — ' — r — r - RIC: 7624. 81.5-1 48.7- ii r-r-T T^—I—I—r—'—n-"—I—'—r-*—r r — •"* ^ LIBRARY FILE: SN #56 -J r**-i 1 1 1 , 1—I 1 1 1 1 1 1 1 1 1 1 1 1 1 1 i—Y BASE M/Z: 149 RIC: 1586. 31.1- 15.5- T - T — I ' I 1 — I ' l ' — I • I ' — I ' l ' — 1 • I ' I • I • I 1 — I — I — I — 1 I I I • ' I • M/Z 100.Ol ^50.0-: a) 1 0-0^ CD 5t-50.0-: o* : ^ a a Pi- rn 1.1 1.1 CA) .1 . - . 100 1 II 150 ' . •••» II 200 • 250 • . CL, o° o o CJ cn CJ\ 620. DATA FROM FILE: SUUSIOl SCANS 347 TO 1082 ACQUIRED: 02/03/95 13:32:00 CALI: SUUSIOl #1 SAMPLE: RBSO/012595 WATER HLA CONDS.: RTX-5 0.25MM X 30M l.OUM 45/4-S25e20 INST B 400 _ 6:40 500 . 8:20 600 . 10:00 700 . p:40 300 . 13:28 A. p.- c/v c: I.S: 00 qfiR <- 1000 - ^ 16:40 ; m t I CS50 2-FLUnROPHENOL ± U.b (bb-5) J 100.0." ( 96128.) J:S45 D5-PHEN0L 0.3 (SS-4) CI30 04-1,4 DICHLOROBENZENE (IS-1) CS75 1..2-CL2BENZENE-04 8.4 (SS-S) CS2e D5-NITROBENZENE 8.2 (SS-1) ;I40 D3-NAPHTHALENE (IS-2) - CS25 2-FLUnROBIPHENYL 8.7 (SS-2) CI50 D10-ACENAPHTHENE (IS-3) CS55 2.. 4.. 6TRI BROMOPHENOL (SS-6) • CI 60 DIO-PHENANTHRENE (IS-4) C530 D14-P-TERPHENYL 0.5 (SS-S) bs |0D » , 9? :yn, m ^ v : •'" •^y h j CJ £.seoo£ DATA FROM FILE: SUUSIOl SCANS 1082 TO 2100 ACQUIRED: 02/08/95 13:32:00 CALI: SUUSIOl #1 SAMPLE: RBSO/012595 WATER HLA rzCWS.: RTA-5 e.25m X SBM l . r m 4.5/4-32.5820 INST B 1200 . 20:00 1400 . 23:20 ,1 1600 . i 26:40 a,! yr' y CJ }(». 1800 J 30:00 o t a o loJ CJ \^. CJl o 00 '^ 2000 J 33:20 m -« ± I 1 •J 100.0:: ( 44096.) CI70 D12-CHRYSENE (IS-5) CI75 D12-PERYLENE (IS-6) i > . . Quantitation Report File: SVVSIOl m Data: SVVSIOl. TI 02/08/95 13:32:00 ample: RBSO/012595 WATER onds.: RTX-5 0. 25MM X SOM Formula: X X X Submitted by: HLA 1.OUM 45/4-325620 Instrument: B Analyst: JAM INST B Weight: Acct. No. : 1. 000 12098 AMOUNT=AREA * REF AMNT/(REF AREA • RESP FACT) Resp. fac. from Library Entry No 1 2 3 4 5 6 7 a 9 10 11 12 13 14 No , 1 2 3 4 5 6 7 8 9 10 11 12 13 14 No 1 2 3 4 5 6 7 8 9 .10 hi Name CI 30 CI40 CI 50 CI 60 CI70 CI75 CS50 CS45 CS20 CS25 CS55 CS30 CS70 CS75 D4-l,4 DICHLOROBENZENE DS-NAPHTHALENE DIO-ACENAPHTHENE DIO-PHENANTHRENE D12-CHRYSENE D12-PERYLENE 2-FLUORDPHENOL D5-PHEN0L D5-NITR0BENZENE 0. 6 0. 3 0. 2 2-FLUOROBIPHENYL 0. 7 2,4,6TRIBR0M0PHEN0L D14-P-TERPHENYL 0. 5 2-CHL0R0PHENDL-D4 0. 8 1,2-CL2BENZENE-D4 0. 4 m/z Scan Time F 152 136 164 188 240 264 112 99 82 172 330 244 132 152 482 8: 02 601 10:01 760 12:40 892 14: 52 1148 19:08 1410 23:30 357 5: 57 456 7: 36 538 8:58 698 11:38 331 13:51 1035 17: 15 465 7:45 500 8:20 Ret(L)^ Ratio R R T ( L : 8: 03 10: 02 12: 41 14: 53 19:09 23: 31 5: 58 7: 37 8: 58 11: 39 13: 52 1.00 1.000 1.00 1.000 1. 00 1. 000 1. 00 1. 000 1. 00 1. 000 1. 00 1. 000 1. 00 0. 741 1.00 0.946 1.00 0.894 1. 00 0. 919 1.00 1.093 [ef 1 2 3 4 5 6 1 1 2 3 3 5 1 1 RRT 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 0. 741 0. 946 0. 895 0. 918 1. 093 0. 902 0. 965 1. 037 ) Ratio 00 00 00 00 00 00 00 00 00 00 00 (IS-1) (IS-2) (IS-3) (IS-4> (IS-5) (IS-6) (SS-5) (SS-4) (SS-1) (SS-2) (SS-6) (SS-3) (SS-7) (SS-S) Meth A BB A BB A BB A BB A BB A BB A BB A BD A BB A BB A BD A DD A DB • A BB Amnt 20. 00 20. 00 20. 00 20. 00 20. 00 20. 00 49. 73 56. 28, 3S. 87 29. 41 54. 13 Area(Hght) 11307. 43515. 28751. 40184. 32031. 25474. 26734. 41999. 22474. 43130. 9212. 60506. 36459. 11031. Amnt(L) 20. 00 20. 00 20. 00 20. 00 20. 00 20. 00 25. 00 25. 00 25. 00 25. 00 25. 00 R. i 2, 0. 1, 0, Amount 20. 000 20. 000 20. 000 20. 000 20. 000 20. 000 49. 727 56. 282 38. 866 29. 412 54. 135 46. 074 55. 807 26. 208 -ac R. F , 000 , 000 , 000 , 000 , 000 , 000 , 892 . 972 ,413 , 200 . 256 PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB ac(L) 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 0. 951 1. 320 0. 266 1. 020 0. 118 . y.Tot 4. 4. 4. 4. 4. 4. 10. 11. 3. 6. 11. 9. 11. 5. Rat: 1. 1. 1. 1. 1. 1. 1. 2. 1. 1. 2. 20 20 20 20 20 20 44 81 16 17 36 67 71 50 io 00 00 00 00 00 00 99 25 55 IS 17 300359 Data Subject To ValidatioR No 12 13 14 Ret(L) 17: 15 7:46 8:21 Ratio 1. 00 1. 00 1. 00 RRT(L) 0. 901 0. 965 1. 037 Ratio 1. 00 1. 00 1. OO Amnt 46. 07. 55. 81 26. 21 Amnt(L) - 25. 00 25. 00 25. 00 R. Fac R. 1. 511 2. 580 0. 780 Fac(L) 0. 820 1. 156 0. 744 Ratio 1. 84 2. 23 1. 05 300360 Data Subject To VaUdption DATA FROM FILE: SU12153WB1 SCANS 347 TO 1882 ACQUIRED: 82/88/95 17:31:88 CALI: SU12158WB1 #1 SAMPLE: SBLKW WATER-12158WB1 CONDS.: RTX-5 0.25MM X SOM 1.8UM 45/4-S25(?28 INST B 480 _ 6:48 580 y. 8:20 10:00 a tn cr (0 o' 51 o ,1 i . V CJ , o; o C J l 700 11:40 800 13:20 900 15:00 lonn 15:40 m I I J -ci==: CS50 2-FLUOROPHENOL 0.6 (SS-5) 108.8^ ( 55104.) S a ^ D5-PHEN0L 0.8 (SS-4> CI30 04-1.4 DICHLOROBENZENE (IS-1) CS75 1..2-CL2BENZENE-D4 0.4 (SS-8) CS20 D5-NITROBENZENE 8.2 (SS-1) CI48 DS-NAPHTHALENE (IS-2) CS25 .2-FLUOROBIPHENYL 8.7 (SS-2) CI50 DIO-ACENAPHTHENE (IS-3) CS55 2.. 4.. 6TRI BROMOPHENOL (SS-6) CI60 D10-PHEMANTHRENE (IS-4) CS38' D14-P-TERPHENYL 8.5 (SS-3) /w r,. ^ 1 ZZZ .- t \ . . i DATA FROM FILE: SU12158WBr SCANS 1882 TO 2280 ACQUIRED: 02/08/95 17:31:80 CALI: SU1215SWB1 #1 SAMPLE: SBLKW WATER-12158WB1 CONDS.: RTX-5 0.25MM X SOM 1.8UM 45/4-325@28 INST B i 1200 J 20:00 1400 _ 23:20 1600 _| 26:40 a cn c ft K o" ':zf. 1300 _ 30:00 2000 33:26 m -J CO o o CJ to _L J 100.8.^ ( 20576.) CI70 D12-CHRYSEHE (IS-5) — CI75 D12-PERYLENE (IS-6) ..•>,< Quantitation Report File: SV12158WB1 tr. Data: SV1215BWB1. TI 02/08/95 17: 31:00 Sample: SBLKW Conds. : RTX-5 ormula: X X X Submitted by: WATER-12158WB1 25MM X 30M l.OUM 45/4-325S20 Instrument: B Analyst: JAM INST B Weight: Acct. No. : 1. 000 12158 AMDUNT>=AREA • REF AMNT/(REF AREA • RESP FACT) Resp. fac. from Library Entry No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 No 1 2 3 4 5 6 7 S Name CI30 CI40 CI50 CI60 CI70 CI75 CS50 CS45 CS20 CS25 CS55 CS30 CS70 CS75 C740 m/2 ! 152 136 164 138 240 264 112 99 82 172 330 244 132 152 149 D4-l,4 DICHLOROBENZENE DB-NAPHTHALENE DIO- DIO- D12- D12- -ACENAPHTHENE -PHENANTHRENE -CHRYSENE -PERYLENE 2-FLUOROPHENOL D5-PHEN0L D5-I NJ I TROBENZENE 0. 6 0. 8 0. 2 2-FLUOROBIPHENYL 0.7 2,4, D14- ,6TRIBROMOPHENOL -P-TERPHENYL 0. 5 2-CHLOROPHENOL-D4 0. 8 1,2--CL2BENZENE-D4 0. 4 BIS(2ETHYLHEXYL)PHTH scan 482 601 760 892 1151 1414 357 4 56 538 698 832 1036 465 501 1144 Ret(L) Ra 8:03 10:02 12:41 14: 53 19:09 23: 31 5: 58 7:37 Time Ref 8: 02 10: 01 12:40 14: 52 19: 11 23: 34 5: 57 7: 36 8: 58 11: 38 13: 52 17: 16 7:45 8: 21 19:04 1 2 3 4 5 6 1 1 2 3 3 5 1 1 5 tio RRT(L> Ri 00 1. 000 00 1.000 00 1. 000 00 1.000 00 1.000 00 1. 000 00 0. 741 00 0. 946 RRT 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 0. 741 0. 946 0. 895 0. 918 1. 095 0. 900 0. 965 1. 039 0. 994 atio 00 00 00 00 00 00 00 00 (IS-1) (IS-2) (IS-3) (IS-4) (IS-5) (IS-6) (SS-5) (SS-4) (SS-1) (SS-2) (SS-6) (SS-3) (SS-7) (SS-8) Meth A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB Amnt 20. 00 20. 00 20. 00 20. 00 20. 00 20. 00 63. 91 63. 59' Area(Hght) 7042. 26145. 16646. 21609. 17708. 17396. 21400. 31879. 17B1B. 37330. 6105. 38846. 29341. 10633. 6274. Amnt(L) 20. 00 20. 00 20. 00 20. 00 20. 00 20. 00 25. 00 25. 00 R. 1 2 3 Amount 20. 000 20. 000 20. 000 20. 000 20. 000 20. 000 63. 913 68. 594 51. 286 43. 969 61. 965 53. 507 72. 113 40. 563 7. 388 Fac R.F . 000 . 000 . 000 . 000 . 000 . 000 . 431 . 622 PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB ac(L) 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 0. 951 1. 320 •/.Tot 3. 3. 3. 3. 3. 3. 10. 11. 8. 7. 10. 9. 12. 6. 1. Rat 2 2, 43 43 43 43 43 43 96 76 79 54 62 17 36 95 27 io , 00 , 00 . 00 . 00 . 00 , 00 , 56 , 74 8:58 1.00 0.894 1.00 51, 25. 00 0. 545 0. 266 05 300363 Data Subjea ^b VaHdation No Ret(L) Ratio RRTtL) Ratio Amnt Amnt(L) R. Fac R.Fac(L) Ratio 10 11:39 1.00 0.919 1.00 43.97 25.00 1.794 1.020 1.76 11 13:52 1.00 1.093 1.00 61.97 25.00 0.293 0.118 2.48 12 17:15 1.00 0.901 1.00 53.51 25.00 1.755 0.820 2.14 13 7:46 1.00 0.965 1.00 72.11 25.00 3.333 1.156 2.88 14 8:21 1.00 1.037 1.00 40.56 25.00 1.208 0.744 1.62 15 19:02 1. 00 0. 994 1. 00 7. 39 25. 00 0. 283 0. 959 0. 30 300364 Data Subject To VallciatioR y 180.0- 50.0-: TARGET COMPOUND COMPARISON COMPOUND: C740 BIS(2ETHYLHEXYL)PHTH RAW DATA: SU12158WB1 #1144 82/08/95 17:31 SAMPLE: SBLKW WATER-1215SWB1 CONDS.: RTX-5 0.25MM X SOM l.OUM 45/4-325228 I-' • I '" I V^ - J — 1 — r -r-^—I—'—r-l—r BASE H/Z: INST B 149 RIC: 8768. 1 — f - ^ — ' — r 83.3-] 41.7- ENHANCED DATA: SU1215SWB1 #1144 -'—r—'—I— BASE M/Z: - p — ' — I — ' — I — ' — T " 149 RIC: -i"-i—I—r—j—r—r-l—I—,—r • ^ — r -r-T—r T — r — T - I- ?•: _L -1 1 1 1 1 1 r 7016. 904. - I — ^ — I — ' — I — ' — r — ' — I — ' — I — ' — I — ' — r 2428. 34.4- l>.2-i w c cr •.i> H O ) • 1 ^ o' 3 -50.0-: -180.8^ LIBRARY FILE: SN #56 - J — I — I — I — f — I — I — I — I — I — I I I—I M/Z 50 100 100.0-1 50.0 0.0-H T—I—I—1—I—I—r BASE M/Z: 149 RIC: • I ' I 1.1 I. CJ o o CJ cn 158 • T — I — I — I 1—I—1—I 1—I—1—T 200 1536. - I — I — I — I — r — " I — r Vv\mf a 250 r h i DATA FROM FILE: SUUTX04P SCANS 345 TO 1888 ACQUIRED: 82/83/95 19:35:00 CALI: SUUTX04P #1 SAMPLE: RBSOOl WATER HLA CONDS.: RTX-5 0.25MN X .SOM l.OUM 45/4-32.5i?20 INST B 400 J 6:40 500 . 600 _ 10:00 700 ,11:40 i su 5^ £ a, O CO o o CJ p.m 13:20 908 15:00 1000 16:40 3 <^ Krr py I X ± J 100.0:; ( 51968.) CS45 D5-PHEN0L 0.8 (SS-4) ;I30 04-1,4 DICHLOROBENZENE (IS-1) ' CS75 1..2-CL2BENZENE-D4 0.4 (SS-S) CS20 D5-NITROBENZENE 0.2 (SS-1) CI40 DS-NAPHTHALENE (IS-2) CS25 2-FLUOROBIPHENYL CI50 DIO-ACENAPHTHENE (IS-S) 2.. 4.. 6TRI BROMOPHENOL (SS-6) CI60 DIO-PHENANTHRENE (IS-4) •&SSQ D14-P-TERPHENYL 0.5 (SS-3) 0.7 (SS-2) <0 • > • • > tn DATA FROM FILE: SUUTX04P SCANS lOSO TO 2280 ACQUIRED: 02/03/95 19:35:08 CALI: SUUTX04P #1 SAMPLE: RBS081 WATER HLA CONDS.: RTX-5 8.25MN X SOM l.SUM 45/4-325i?2e IN'"T B pwnfTi— 1200 . 20:00 1400 J 23:20 1600 J 26:40 1300 _ 30:00 O & tn c a" "75° ^'000 _ ft I cC o' 3 '•'P. • '^'R m J ± I ± CJ o o CJ CJ\ sJ J 100.0?; ( 19168.) CI70 D12-CHRYSENE (IS-5) V CI75 D12-PERYLENE (IS-6) r h i Quantitation # ! Data: SVVTX04P. 02/08/95 19:35: Sample: RBSOOl onds. : RTX-5 Formula: X X X Submitted by: port File: SVVTX04P TI 00 WATER HLA 0. 25MM X SOM 1. OUM 45/4-325@20 Instrument: B Analyst: JAM INST B Weight: Acct. No. : 1. 000 12158 AMOUNT=AREA • REF AMNT/(REF AREA • RESP FACT) Resp. fac. from Library Entry No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 No 1 2 3 4 5 6 7 e 9 10 11 12 13 14 15 16 No 1 2 3 4 5 6 1 ^ Name CI30 CI40 CI 50 CI60 CI70 CI75 CS50 CS45 CS20 CS25 CS55 CS30 CS70 CS75 C580 C740 m/z J 152 136 164 188 240 264 112 99 82 172 330 244 132 152 149 149 D4-3 [,4 DICHLOROBENZENE DS-NAPHTHALENE DIO- DIO- D12- D12- -ACENAPHTHENE -PHENANTHRENE -CHRYSENE -PERYLENE 2-FLUOROPHENOL 0.6 D5-PHEN0L 0. 8 D5-NITR0BENZENE 0. 2 2-FLUOROBIPHENYL 0.7 2,4, D14- 6TRIBROMOPHENOL -P-TERPHENYL 0. 5 2-CHL0ROPHEN0L-D4 0. 8 1, 2- CL2BENZENE-D4 0. 4 DIETHYL PHTHALATE BIS(2ETHYLHEXYL)PHTH Bean 480 600 759 891 1150 1413 349 453 536 698 831 1035 462 498 793 1143 Ret(L) Ra 8: 03 10: 02 12:41 14: 53 19: 09 23: 31 5: 58 0. ' 0. ' Time F 8: 00 10: 00 12: 39 14: 51 19: 10 23: 33 5: 49 7: 33 3: 56 11: 33 13: 51 17: 15 7:42 8: 18 13: IS 19: 03 tef RRT 1 1.000 2 1. 000 3 1.000 4 1. 000 5 1.000 6 1.000 1 0. 727 1 0. 944 2 0. 393 3 0. 920 3 1. 095 5 0. 900 1 0. 962 1 1.037 3 1.051 5 0. 994 tio RRT(L) Ratio 99 1.000 00 1. 000 DO 1.000 00 1.000 00 1. 000 DO 1. 000 97 0. 741 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 0. 98 (IS-1) (IS-2) (IS~3) (IS-4) (IS-5) (IS-6) (SS-5) (SS-4) (SS-1) (SS-2) (SS-6) (5S-3) (SS-7) (SS-8) Meth A BD A BD A BD A BD A DB A DD A DD A BB A DB A BD A DD A BB A BD A BD A BB A DD Amnt 20. 00 20. 00 20. 00 20. 00 20. 00' 20. 00 63. 41 Area(Hght) Amount 6793. 24997. 14947. 19315. 16244. 16195. 20479. 30464. 16390. 38B61. 5625. 35054. 27341. 12420. 3324. 1362. Amnt(L) 20. 00 20. 00 20. 00 20. 00 20. 00 20. 00 25. 00 '. 20. 000 PPB 20. 000 PPB 20. 000 PPB 20. 000 PPB 20. 000 PPB 20. 000 PPB 63. 406 PPB 67. 953 PPB 49. 343 PPB 50. 975 PPB 63. 583 PPB 52. 635 PPB 70. 934 PPB 49. 116 PPB 5. 586 PPB 1. 748 PPB R. Fac R. Fac(L) 1.000 1.000 1. 000 1. 000 1. 000 1. 000 1.000 1.000 1. 000 1. 000 1. 000 1. 000 2. 412 0. 951 y.Tot 3. 3. 3. 3. 3. 3. ' 10. 11. 8. 8. 10. B. 11. e. 0. 0. Rat: 2. 300368 36 36 36 36 36 36 65 42 29 56 68 84 92 25 94 29 i 0 00 00 00 00 00 00 54 DaiaSubiecnbVa!i(iaUon No 8 9 10 11 12 13 14 15 16 Ret(L) 7:37 8: 53 11: 39 13: 52 17: 15 7:46 8:21 13:20 19:02 Ratio 0. 1. 1. 1. 1. 0. 0. 1. 1. 99 00 00 00 00 99 99 00 00 RRT(L) 0. 946 0. 394 0. 919 1. 093 0. 901 0. 965 1. 037 1. 051 0. 994 Ratio 00 00 00 00 00 00 00 00 00 Amnt 67. 95 49. 34 50. 97 63. 58 52. 64 70. 93 49. 12 5. 59 1. 75 25. 00 Amnt(L) R. Fac R.Fac(L) Ratio 2. 72 1. 97 2. 04 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 3. 583 0. 525 2. 030 0. 301 1. 726 3. 279 1. 463 0. 205 0. 067 1. 320 0. 266 1. 020 0. lis 0. 820 1. 156 0. 744 O. 916 0. 959 2. 2. 54 11 34 96 1. 0. 22 0. 07 3 003 69 Istd Subied Tr; VsHriation 100.0-1 50.0- 67.3-1 33.6- TARGET COMPOUND COMPARISON COMPOUND: C580 DIETHYL PHTHALATE RAW DATA: SUUTX04P #793 f12./0;-!/*^5 19:35 SAMPLE: RBSOOl WATER HLA CONDS.: RTX-5 0.25MM X SOM l.OUM 45/4-325(520 BASE M/Z: INST B 149 RIC: 4744. 1—I—I—I—I—I—I—I—I—r*-!—I—I—I—I—r^—I—I—I—I—I—I—rS—i—i—|—i—Hi—r-j—i—i—i—i—rh—r—i—i—|—i—r—T—i—[—i—i—i—rH—r ENHANCED DATA: SUUTX04P #798 -1——r—1—I—.—I—I—r—T—I—r 1—I—I—I I'l—I—I—I—I—I—I—r-'-T—I—.—I—I—M-i—I—I—r- S—I—I—I—I—i—T- r- O - I — I — I — I — r I ' l I • EASE M/Z: 149 RIC: 2932. -|—r—I—I—I—I—I—I—hH—I—r- 440. r 1642. r-f- in c ft I Cu Si. o° 5 LIBRARY FILE: SN #39 41.On 20.5- BASE M/Z: 149 RIC: 1660. 1 — I — I — I — I — I — I — I — I — 1 — I — I — I — I — I — I — i — I — I — I — I — I — 1 — I — I — I — I — I — 1 — r H — r - ] — I — I — I — ( — I — 1 — I — I — I — I — I — I — I — I — I — I — I — I — I ' ' 1 — I — 1 — I — r - l — i — i — i — f M/Z 100.0- 50.0-: 0.0- 60 -50.0- •100.0^ CJ O O CJ «>J O b0 100 120 148 150 160 I ' I I I I 130 I ' • 1000. 62.5- 31.2- ib.2- JUL TARGET COMPOUND COMPARISON COMPOUND: C740 BIS(2ETHYLHEXYL)PHTH RAW DATA: SUUTX04P #1143 02/08/95 19:35 SAMPLE: RBSOOl WATER HLA CONDS.: RTX-5 0.25MM X SOM 1.8U I • I BASE M/Z: 149 RIC: 1458. 45/4-S25@20 INST B "T—r- 1—'—r ENHANCED DATA: SUUTX04P #1143 1 • ' • 1 ' 1 ' 1 ' ' BASE M/Z: I ' l ' 149 I ' l ' RIC: i • 1 • 1 ' I ' • 1048. 1—'—r -1 1 1 1 r T—'—r •n 1 r - * ^ . J -|—'—r - T - * - | — r — 1 — 1 — I — I — r -| 1 — I — ! - 625. 525. a 5? tn c ,cr ft o 3 180.0-1 50. IV LIBRARY FILE: SN #56 M/Z 100.0- 50.0- 50 1 — I — 1 — I — 1 — I — I — I — I — I — 1 — I — I I ' r 100 0.0- -50.0- -100.0^ I i CJ o o CJ - J l - » BASE M./Z: 149 RIC: 1586. "1—'"^—I jgfc.'—r 150 ?00 I ' l ' — I ' l ' — r ' I—'—r 250 1088. o O O mcs • C / M qmuzo 300372 ^ Analjvtt. a.mfM j m t » t . ihsJiL. _ 7 a B t n » * n t t _ _ ^ Projact Z.O. (oIl«iit/OMV«dg) >. t a f t •tu«ax« Bate »oqal«lUM MxMatM* fer Mid-Tol«tll««i ce Condltlpna Hg W M K i g n g rioif « t r t 3 % . I V I B SCM r a a , . : JSiSfflt BMd prMcor* « 30 p»l « « » «**• c o l o n . yuigd SlDf^ c a p i l l a r y . Bl VOlt«g«J inm » o . u — . l.Oin f l l » -85P Injsetor fc"^-« Injector aod* i piod splltlegB GC dMClptors t ^UMPlg-SY. DFTPtMm c c progroB » 48 «4Biii\ t o aoo t i a / » l n >mrt;l»ite<» Mon-atanaazd Oonditions « -^ ltaint«uuie«/Frobl«Ba » — raz»aat«r M l a s « — Original M t * r U « d « i t h > j ; i . •'.asrsoojani t ,^ •/atfan— ^f Ay % •s> T.rY,tMt. .a'Ti^- P:^- sviT TB. S.'(^-P^-r/^iv^ jmsvx. 2f*-9V'yf^ . « u a y « l . ' pa-Md a U caritarla « « « p l a « t r i x a t f a c t ( a l M l a d l ^ t a QC « not applicabia axcuraiona, for axaapla, X8S , SS3 , aito.) CO carry-ovar o r contaaination «uapaot*l . RR . r a - « e t r a c t i o n r«5tulr«J I l V l « v a l . . . d U u t l o o rwiair«Vaagg«8tad l a v a l BR . . . . r a s w j raqolrad - m — T T TO/laval...too dllnta/auggaatad l a r a l D 0 f]ijTjiii;i:ri:ljf:I:C C CIHH- »AC8-«c/iia ZBsntnaarr OPBKXTZOM xoacaxn Analyst iQ. /Tj'FuJU > rair of t h a day Date ^ >l»7/tr parg. Std. + 12 h r a . sjur^r RKI-TOUTXU!B I l . ' l i i . o - ^ ? H J l r a runs within t i a a l l a l t s ^ ; f S ) HO (If no, c i z s l a o u t l i e r s ) TZXB OP rxttX XD cLxnr ZO (dii) AKT XKJ BJW TCK g i r MULT rxcT I . S . AR KT BOK REC 8TXTVB TAPE io:^f ^ VfSiinKc JUmL. 2JL gyir i i : 3 r B/4ii>ris'4 Sjra>»sv U L . t i U f DIJM^UMV S^liLr^ i ^ i>^7f Itea y y ir.oi SV\/ft^Hj^ 30OS' ^ t U . I H l O y y y y^ r. y jizazL Siyfa.^MC "ieezoi j y L IA fffo w / l y i ^ y ii'.-it' f\/Vfaitt-n J 001 U. j r 2 o y />L. i T ,r/}ir r^VftrajKe 3ee3e r.i- I ^ ytffe JZ y / P r i . ^^vrauit l o o J. j y L ± //7to yT-- y PL / : i i jiim (^//oyi/yto • j f O i - C L I'-la U . mo" >o OL y n:i:f- / / r . n o M A cre f/ //.)/, ffA)^f iPipi. # / ^ y i6'-n> r Y a t a i i f - S Ore CHECK fy iluj^r y . f i r / / 3 * If f7eJ-i't' T T ' l t i - j V / u i t t f / f II £ 1 ^ i£i£i svnuiitJif n i x j y I J inn y JtH. C - ^ ^ f ) * l f fi.&ioloi>o<i<r .^iL CD o • o o >c ro zi:tf2~ 'izi.y X / y /aruDT fi,i/ol ipiifir f '^ o>-r(r / / f i r M2IL y A ^ ± - - I , • • = ! — I M ^ M ^* T - aour aoDTR EWIROHKENTXI. UBORATORy page i of 2 O 6C/MS IMSTRDKEirr OPBRATIOK8 L0C8HEBT SEMI-VOLATILES O § Analyst: Q m ' f ^ Date: ' ' l ^ l n Instrument: P fjy (7 , — •O PpQJect I.D.•fcllent/case/sdol: •taadard Data Acquisitioo Paraaeters for Seai-Volatlles: ^ ^ S£_£21ldili2£is MS Conditions ^ ^ B H rata : 3,5 Pl^BlIT ' Scan ranqe: 35-500 amu ^ • p o pressure :, JP psi ; — . Scan, rate : 1 s/scan ^Wl>»n : Fused Silica Capillary. EM voltage: IT'II- 30TO X 0.32mw. l.Oum.f^)n Injector tenp.; 250 — — _ _ _ _ _ Injector, node : Hod Solitless CC desciptors ; sample-SV. DFTPP=IIM CC-.progran : 45 f4mlnl to 300 g y/pjn . . _ (optlniizedl •oB-standard Conditions : "" VaiataBaaea/ProblaBS t . Voxsastar Piles t ^ y / z f ' l y ^ - ' S /<» -_ • - • - Original Data riled with» ' • • • - ' •• Standard IdeBtificatlona 4 Spike Aaountst . . . Targets; :i'^P-r-. Tyitt-hfj- IS; 'S'l^-ihJyJZfltt.} DFTPP; i V / ' t y ' y / ^ y Today>a Reaposse rectorsi DeflaltioB of status/coBaents COIUBH on Run Log (page 3)t K' ^!J?^ni^'"'Kr'* ' " criteria ME sanple matrix effect (also indicate QC CD "°^ 'PP^^""^* » , ., excursions, for example, IS2t, SS2t, etc.) S;i«;C"H?f,^T " ","2?"^"°4'':! ?"°P*='^*'' RE.........re-extraction required DVlevel...dilution required/suggested level RH rerun required TD/level...too dilute/suggested I'evel eULP SOOTB EK7TROHKZNTXL LXBORATORY OC/aS IM8TRDXZ1IT OPBRATIOMS LOGSHBBT SBMI-VOLATILBS Analyst • ; RRF of the day Data 3 00 V TIXB OP r . ' ' <y- -I f- If.ef ' > - /i.Wif ' > - ii:3f m w 1— t - _ <>hh PILE ID t Z - l l ^ l l U SJii^iltA B(ili t t i e £r//<f T*" Uf ia^^<ia e J i n i m ^~~--~~..^^^ ^ Perf. Std. CLIENT ID + 12 h r s . (dil) e/Tf/' J r o t r p JSTOil-^ J'jro9->f- f/re.zf J/Toi'irf - - - . . ^ ^~-^^^^ ,_, : ^r'- AMT INJ :2^ ^lA ^../ U ZA ?^ ^ ^ 0 cc BATCH - " z — - ^- - ^ QLP 1 ^ . . -r "^ (If MULT FACT 1 ) ; / 1 1 \ I.S AR - - — - - - \ no, RT - - — - - - •X c i r c l e o u t l i e r s ) BOR REC -' ^ - - .- y \ ^ ^ 8TAT0S/ COKMEKTB y ] \ T ^ y J V : \ \ \ TAPE mi 1 1 --•Vf 3003 73 Data SubJert TX Zf-u/i-t'iriri 0 - : o . • o -o o t CO 9C/WM qmuxoM •Bo-vounus # . / h ^ * ^ inmlntt y . f / ' T * ^ p,ta . Mr •laatn—ntl /? Ptejaet Z.P. (oli«iit/caa«i/adg) t.". •taadard Oata teqaialtlaa Par—tora far •«Bl-Talatil«ai now rata ' ?•_' " l ^ * " Scan ranae; 35-500 am Baad praaaura Colnaa JB ni. Zajactor tanp.i, Injector aoda t, (X deaclptora i, CC prograa t. Fused Sillea Csptllarv- 30a JC 0.25—. l.Oua fll» Sean rata , n voltage \dfi laauL. UL. 23SU Mod Bplltlesa aaarple-SV. DPTPP-OM <5 f4ainl t o 300 > 12/M<n (gptUlttdl Mon-standard Cobditlena tZL Maintaoaaca/PtoblaBa i ^ rotaaatar PHaa zmMnizE Original Data PUad «ith<-. Standard Zdeatifioatlaaa • Splka Tawetat i^H -il'.cyZr M I Jf»-0-?--nay;?'f^ 1 af r \ ' ^ jsnnx_221z2Z±££!ZL- Bafiaitioa ef StatiM/Oeaaaata Ooloaa «a Saa liog (paga a| i .........analyalapaaaed a U eritarla m . . aaaple aatrlx affect (alee indlcata OC " •** applicable axcurslona, for oxaaple, ISS*. 883", etc.) co.........earzy-ovar or contaaination anapaotad . BK r»-axtractien taquirad DVlaval.. .dilntioa s«qiilra4/aagg«atad level RR reran raquixad TD/laTal...too dilnta/anggeatad level m m m -o -D -C- C- C- C C- C- C C E C 300374 Analvat i Q.fll'fdM * KRP of t h e dav Date / ^ n l ^ / f r Perf. Std. + 12 h r s . * cs <z> o fn * » • n m 0 A?:?' > //.-?¥ ' i - / J : W < ^ > 1x1 f '9' / ; y ^ ' i. iM-.ir^y li-ST' > m o a n:o^ > n-.Hr \ Irk (i:r^. • ii-^y> T-cUZ* -u:rf.' ' I z\ ^-^.__ p n u ZO - Si^P*/1S7 - &9-3*/ira ry«*wi^» - ^i/Kyi>it- . aidit,! • f/Vff*l - svntima „ /V/i/fl* If •• Wl'iyn^Jii iv/iycti f*- nfiiifruf) Ci/niri'i.i^' syvrf*'}f {vvrmf rV/TH4l K r/^sff) - r/vfvt) - j - / / / v » ^ ~--^~___ ~-—- CUOR 10 (dil) cyr/ii SSfD^Tp sui-i-y DircHAUB UttfetiTt /:/» /tmftiiit^y fit^iflpixiir S ^ W • " j u i r .XtLl'-'-' emu- r/? f$UL^ SL/iyi J-piKf ft/of<pi>'iir eB<oo\ c s u OMfifiTi lyf^'^ 0A-3- fw>- 0A-) t •r — • — _ y n u :_ :_ AMT ^.r* 27i M V j y . 'tr 7rJl ^*/ M Zhi-i \ f —- — J L . ^ . Wr TLS8 O.fte BATCB _ ' — ile^E \ \ I ixofy J- /»i-? /- / i ; r j ' 1 I ^~^^______ Are QLT / I / ;«> / / V V / 1 1 1 1 1 >t> *^ ~-~ runs vithln tlae l l a l t s r ^ y u ) HC (If no, clzcle outliers) MOLT FACT ID i-a -«!^ t)ata Su Z . B AR — w y y y y ^ y y y V .y A KT — — y ^ ^ y . y y - y y y ^ -- -- — y J. r* stni SJBC —- -- y ^^ y .^ — ..^ / . f .^ .-- -- ^ / I ' ^ — c BTATOS/ 1 y • g y y y y y y ^ y y y . y y y Tt illfJ. ' V J ' y^Y</fr -—_ 'f<i. y \ biect To VaUdafson] - a.w ff^^:^--^ ^"'" ^ ^ v A -070 vA ^^^ c/ ^y^' 300375 Data Subiect 'Ay ZzZddZor: "(« :* 100.0-1 50.0- ti/z 100. e a CD —1 o < ru a 0). 50.0- lo i o ! o ; Ui t >J ) (Tl M/Z MASS SPECTRUM 11/09/94 9:26:00 + 8:33 SAMPLE: DFTPP 244-92-PERF CONDS.: RTX-5 0.25MM X SOM 1.0UM 45/4-325e20 #512 TO #514 AUERAGED - #505 Xl.OO DATA: BP110994A #513 CALI: BP110994A »1 BASE M/Z: 198 RIC:- 14672. IHST B 198 (>> ^ G9 ?7 12? 51 39 1 , 57 110 .;^1 93 .., I I I I ' , , '• ' I , ' •' 117 L-a I — T — T 141 _J •T—r f .173 186 -f-M- 206 l-il T f*-T ;224 Uii 50 100 150 200 442 255 275 T—'—T T—'—r 296 I 250 300 365 - | — ' — I — ' — I — ' — I — ' — I — ' — I — I — I — I — I — I — I — I — I — 350 400 423 I T — • — r ^ — I — ' — 1 ^ 2480. r 2480. 450 • "<»•« RIC 11/09/94 9:26:00 SAMPLE: DFTPP 244-92-PERF CONDS.: RTX-5 0.25MM X 30M RANGE: G 1, 700 LABEL: N DATA: BP110994A #512 CALI: BP110994A #1 100.0-1 l.OUM 45/4-325620 0> 4.0. QUAN: A Q, 513 INST B 1.0 J 0 SCAHS 495 TO 545 BASE: U 20. RIC St) GO ilZ_ 500 502 Z.Z.E00E 500 8:20 23680. 513 522 525 t^':,'Zi . j i . i j 534 520 8:40 530 3:50 J28_541 543 540 9:00 SCAN TIME i ' U - ' 100.0-1 RIC+MASS CHROMATOGRAM 11/09/94 9:26:00 SAMPLE: DFTPP 244-92-PERF CONDS.: RTX-5 RANGE: G 1, 700 614 DATA: BP110994A «512 CALI: BPl10994A «1 0.25MM X SOM LABEL: N l.OUM 45/4-325620 0, 4.0, QUAN: A 0> INST B 1.0 J 0 SCAHS 600 TO 700 BASE: U 20, 3 9856. 184.055 ± 0.500 21504. 665 6?0 677 681 685 689 ese 600 10:00 620 10:20 640 10:40 660 11:00 680 11:20 700 SCAH 11:40 TIME BPai0994A m S13 BP110994A tt 1 Mass List Data; 11/09/94 9:26:00 •»• B: 33 Cali; Sample: DFTPP 244-92-PERF Condt. : RTX-5 O. 25MM X 30M l.OUM 45/4-325«20 «512 to tt514 averaged - ttSOS XI. 00 Base m/z: 198 RIC: 14672. INST B M 39 443 Mass 39? 50? 51? 52? 57? 69 74 75 76 77 78 79 80 81 93 98 99 101 107 110 111 117 127 128 129 141 167 175 179 180 186 187 196 198 199 204 205 206 207 217 221 224 225 227 244 255 256 274 275 276 S S s s s s s s s s s s s s s s s s s s s s s s s s s 5 s s- s s s s s s s s s s s s s s s s s s s s 0.00 7. RA 3. 19 7. 10 31.73 1. 05 3. 55 41. 09 2. 94 5. 48 1. 17 41. 61 2. 86 2.26 1. 17 3. 47 3. 31 2. 78 2.42 1. 13 9. 88 22. 38 3. 59 4. 68 45. 56 3. 55 14. 40 2. 14 5. 08 1. 41 2. 54 1. 13 9. 44 1. 53 3. 71 100. 00 6. 41 2. 62 4. 35 19. 44 2. 66 4. 48 6. 81 9. 27 1. 53 3. 23 7. 58 37. 30 5. 24 2. 14 21. 17 1. 94 0 Inten 79 176 787 26 88 1019 73 136 29 1032 71 56 29 86 82 69 60 28 245 555 89 116 1130 88 357 53, 126 35 63. 28. 234. 38. 92, 2480. 159. 65. 108, 482, 66, 111, 169. 230. 38, 80. IBS, 925. 130. 53. 525, 48, Minima Min Inten: Maxima tt 0 Mass ^ 7. RA Inten. 296 365 423 441 442 443 S s s s s s 3. 79 1.33 1. 98 5. 32 44.76 B. 19 94. 33. 49. 132. 1110. 203. 300379 Subjea To Vandcrir- GC/MS Tuning and Mass Calibration DECAFLUOROTRIPHENYLPHOSPHINE Case Number: Inst ID: Lab ID: Laboratory: GULF B Sens Date: 11/09/94 BP110994A Cali Date: . 10/02/91 Contract: Sens Time: Analgst: 9:26:00 JAM Data release authorized by: M/E Ion Abundance Criteria 51 30 to 60'/. of mass 198 68 less than 2% of mass 69 69 mass 69 relative abundance 70 less than 27. of mass 69 127 40 TD 607. of mass 198 197 less than 17. of mass 198 198 base peak> 100*/. relative abundance 199 5 TO 97. of mass 198 275 10 TD 307. of mass 198 365 greater than 17. of mass 198 441 less than mass 443 442 greater than 407. of mass 198 443 17 TO 237. of mass 442 1 - value in parenthesis is 7. of mass 69 2 — value in parenthesis is 7. of mass 442 Spec » 512 S B B S B S 31. 0. 41. 0. 45. 0. 100. 6. 21. 1. 5. 44. 8. ===== 73 00 09 00 56 00 00 41 17 33 32 76 19 ( < 0. 0. (18. 00) 00) 29) 1 1 2 300380 ^ta Subject 7b Vfeiidafion' 'U-* L-: DATA FROM FILE: BS110994A SCAHS 363 TO 1103 ACQUIRED: 11/09/94 9:48:80 CALI: BSU0934A «1 SAMPLE: SSTD050 290-02-SU25 COHDS.: RTX-5 0.25MM X SOM l.OUM 45/4-325620 IHST B 400 . 6:40 500 . 8:20 600 _ 10:00 700 . 11:40 800 13:20 900 . 15:00 < |1000 . ~ wil6:40 D. o '• •^ 00 I mi ^ ± ± ± J 100.0?: < 61888.) CS50 2-FLUOROPHEHOL 0.6 (SS-5) ^^gs7g^-g-mWHEHQL-D?-^0.<§^(lJ-7) -tVIOQ D1-l,4 DICHLOROBENZENE <IS-1) CS75 L2-CL2BEHHEHE-D4 0.4 (SS-8) ^CZSQ D5-HITR0BEHZEHE 0.2 (SS-1) -€f40 D8-HAPHTHALEHE (IS-2) CS25 2-FLUOROBIPHEHYL 8.7 (SS-2) — G i ^ D10-ACEHAPHTHENE (IS-3) i^5 i',4,bTRIBR0M0PHEH0L (SS-6) CIge 010-PHENANTHRENE (IS-4) CS30 D14-P-TERPHEHYL 0.5 (SS-3) ^ c> <o >'3 DATA FROM FILE: BS110994A SCANS 1103 TO 2012 ACQUIRED: 11/09/94 9:48:80 CALI: BS110994A »1 SAMPLE: SSTD050 290-02-SU25 CONDS.: RTX-5 0.25MM X SOM 1.0UM 45/4-325628 IHST B i ' U - ' 1200 _i 20:00 1400 . 23:20 16V30 . 26:40 1S00 - 30:00 Ui o o CO 00 to I I X J 100.0^ ( 41664.) XI70 D12-CHRYSEHE (IS-5) CI75 D12-PERYLEHE (IS-6) Z^...\ Quantitation Report File: BS110994A Data: BS110994A. TI 11/09/94 9:48:00 Sample: SSTDOSO 290-02-SV25 Conds. : RTX-5 O. 25MM X 30M 1. OUM 45/4-325e20 Formula: X X X Instrument: B 'submitted by: Analyst: JAM INST B Weight: Acct. No. 1. 001 AMOUNT-AREA « REF AMNT/(REF AREA • RESP FACT) Resp. fac. from Library Entry M No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 Name CI30 CI40 CI50 CI60 CI70 CI75 CS50 CS45 CS20 CS25 CS55 CS30 CS70 CS75 C315 C325 C330 C335 C340 C320 C310 C319 C34 5 C350 C355 C357 C365- C370 C375 C410 C415 C420 C425 C430 C435 C440 C445 C450 C455 C460 C465 C470 C510 C515 C520 C525 C530 D4-l,4 DICHLOROBENZENE DS-NAPHTHALENE DIO-ACENAPHTHENE D10-PHENANTHRENE D12-CHRYSENE D12-PERYLENE 2-FLUOROPHENOL 0. 6 D5-PHEN0L O. 8 D5-NITROBEN2ENE O. 2 2-FLUOROBIPHENYL 0. 7 2,4,6TRIBROMOPHENOL D14-P-TERPHENYL O. 5 2-CHL0R0PHEN0L-D4 0. 8 1,2-CL2BENZENE-D4 0. 4 •PHENOL 0. 8 BIS(2CHL0R0ETHYL)E 0.7 2CHL0R0PHEN0L 1,3DICHLOROBENZENE *1. 4DICHLOROBENZENE ANILINE N-NITROSODIMETHYLAMINE PYRIDINE BENZYL ALCOHOL 1, 2D I CHLOROBENZENE 0.4 2METHYLPHEN0L 0. 7 2, 2'OXYBISdCHLOROPR 0. 8 0. 6 0. 5 (IS-1) (IS-2) (IS-3) (IS-4) (IS-5) (IS-6) (SS-5) (SS-4) (SS-1) (SS-2) (SS-6) (SS-3) (SS-7) (SS-B) 4METHYLPHEN0L 0. S<N I TROSOPROP YLAM INE 0. HEXACHLOROETHANE 0. NITROBENZENE 0. ISOPHORONE 0. *2-NITR0PHEN0L 0. 2,4-DIMETHYLPHENOL 0. BENZOIC ACID BIS(2CHL0R0ETH0XY) 0. *2,4DICHL0R0PHEN0L 0. 1,2, 4TRICHLOROBENZ 0. NAPHTHALENE 0. 4-CHLOROANILINE *CL6BUTADIENE *4CHL0RD3METHYLPHEN*0. 2 2METHYLNAPHTHALENE 0. 4 ?<CL6CYCL0PENTADIENE *246TRICHLOROPHNEOL 0. 2 2, 4, 5TRICHL0R0PHEN 0. 2 2CHL0R0NAPHTHALENE 0.8 2-NITROANILINE T T T T T T v>t;: Subject lo V2=ldaii«^- - -*- 300383 No Name 48 C535 DIMETHYL PHTHALATE _ 49 C540 ACENAPHTHYLENE 1.3' 50 C545 3-NITROANILINE No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 [ m/2 152 136 164 IBB 240 264 112 99 62 172 330 244 132 152 94 93 12B 146 146 93 74 79 108 146 108 45 108 70 117 77 82 139 107 122 93 162 ISO 128 127 225 107 142 237 196 196 162 65 163 152 138 Scan 503' 620 779 912 1176 1471 385 , 476 557 716 850 1053 487 521- 477- 482- 488 500. 505- 478- 211 211 519. 522- 530- 531 543- 544 550 559 579 587 - 590- 601 • 598 609 616 622 628 636 670 683 702 711 • 715* 727 740 755 766 777 Time 6:23 10:20 12:59 15: 12 19: 36 24:31 6:25 7:56 9: 17 11:56 14: 10 17:33 8:07 8:41 7: 57 6:02 8:08 6:20 8:25 7: 58 3:31 3:31 8: 39 6:42 B: 50 8: 51 9:03 9:04 9: 10 9: 19 9:39 9:47 9: 50 10:01 9:58 10:09 10: 16 10:22 10:28 10:36 11: 10 11:23 11:42 11:51 11: 55 12:07 12: 20 12:35 12:46 12: 57 Ref 1 2 3 4 5 6 1 1 2 3 3 5 2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3 0. 0. 0. 0. 1. 0. 0. 1. 0. 0. 0. 0. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. RRT 000 000 000 000 000 000 765 946 B9B 919 091 695 968 036 948 958 970 994 004 950 419 419 032 038 054 056 080 082 093 902 934 947 952 969 965 982 994 003 013 026 081 102 901 913 918 933 950 969 983 997 Meth A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A BB fiB BB BB BB BB BB BB BB BB BB BB BB BB BB VB BB BV VB BV BB BB BV BB VB BB BB BB BB BB BB BB BB BV BB BB BB BD BB BD BD BB BB BV VB BB DD DB BD DD Area(Hght) 10117. 35916. 16996. 26570. 24201. 26539. 13008. 16823. 12528. 25242. 2741. 23005. 13739. 9031. 20036. 17559. 13610. 15346. 15600. 17744. 7921. 12487. 7186. 14368. 13071. 15708. 13081. 7645. 5778. 12527. 25019. 7053. 9618. 5414. 16183. 10898. 11841. 38036. 12577. 5396. 10029. 25612. 6802. 7534. 8127. 23632. 6058. 27175. 38184. 3177. sno^ ^ l i ' ^ ' i ' i S ^ Amount 20. 000 20. 000 20. 000 20. 000 20. 000 20. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 • \ ... •-.. 1 - ': • PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB_ - -T' * ,- 7.1 0. 0. 0. 0. 0. 0. ot 95 95 95 95 95 95 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 ._L9_ 300384 Data Sfibjed lb VaudaUof^ ^ M No 1 2 3 4 5 6 7 6 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 Ret(L) 6:23 10:20 12:59 15: 12 19:36 24:31 6:25 7:56 9: 17 11:56 14: 10 17:33 6:07 6:41 7:57 6:02 8:08 6:20 8:25 7: 58 3:31 3: 31 6:39 8:42 6: 50 8: 51 9: 03 9:04 9: 10 9: 19 9:39 9:47 9:50 10:01 9: 58 10:09 10: 16 10:22 10:28 10: 36 11: 10 11:23 11: 42 11: 51 11: 55 12: 07 12:20 12:35 12: 46 12: 57 Ratio 1.00 1.00 l.OO 1.00 1.00 1.00 1.00 1. 00 1.00 1.00 1. 00 1.00 1. 00 1. 00 1. 00 1. 00 1.00 1. 00 1. 00 1.00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1.00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 RRT(L) 1.000 1.000 1. 000 1.000 1.000 1.000 0. 765 0.946 0. 696 0.919 1. 091 0.695 0. 96B 1. 036 0. 94B 0. 958 0.970 0.994 1. 004 0. 950 0.419 0. 419 1. 032 1. 038 1. 054 1. 056 1. 080 1. 082 1. 093 0. 902 0. 934 0. 947 0. 952 0. 969 0. 965 0. 982 0. 994 1. 003 1. 013 1. 026 1. OBI 1. 102 0. 901 0. 913 0. 91B 0. 933 0. 950 0. 969 0. 983 0. 997 Ratio 1. 00 ^ 1.00 1.00 1.00 1. 00 1.00 1. 00 1. 00 1.00 1.00 1.00 1.00 1. 00 1. 00 1, 00 1. 00 1.00 1. 00 1. 00 1.00 1. 00, 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1.00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 Amnt 20. 00 - 20. 00 20.00 20.00 20. 00 20.00 2:^.00 25. 00 25. 00 25. 00 25. 00 25.00 25. 00 25. 00 25. 00 25. 00 25.00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 Amnt(L) 20.00 20.00 20. 00 20. 00 20. 00 20.00 25. 00 25. 00 25.00 25. 00 25. 00 25. 00 25.00 25. 00 25. 00 25. 00 25.00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 SSTO^ST> ^fllflllA R. Fac R. 1. 000 1.000 1. 000 1.000 1.000 1.000 1.029 1.330 0.279 1. 063 0. 115 0.760 1.066 0. 714 1. 584 1. 388 1.092 1.213 1.249 1.403 0. 626 0. 9B7 0. 568 1. 136 1. 034 1.242 1. 034 0. 605 0.457 0.279 0. 557 0. 157 0. 214 0. 121 0. 360 0. 243 0. 264 0. 847 0.280 0. 120 0. 223 0. 570 0. 286 0. 317 0. 342 0. 995 0. 255 1. 144 1. 608 0. 134 Fac(L) 1.000 1. 000 1. 000 1.000 1. 000 1.000 1.029 1.330 0.279 1.063 0. 115 0.760 1. 066 0.714 1. 584 1.388 1.092 1. 213 1. 249 1. 403 0. 626 0. 987 0. 568 1. 136 1. 034 1. 242 1. 034 0. 605 0. 457 0. 279 0. 557 0. 157 0. 214 0. 121 0. 360 0. 243 0. 264 0. 847 0. 280 0. 120 0. 223 0. 570 0. 286 0. 317 0.342 0. 995 0. 255 1. 144 1. 608 0. 134 Ratio 1. 00 1. 00 1.00 1.00 1.00 1.00 1. 00 1.00 1. 00 1.00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1.00 1. 00 1. 00 1.00 1. 00 1. 00 1. 00 1. 00 1. 00 300385 Diea To Validation Quantitation Report File: BS110994A Data: BS110994A. TI 11/09/94 9:46:00 Sample: SSTD050 290-02-SV25 Conds.: RTX-5 O. 25MM X 30M l.OUM 45/4-325220 kFormula: X X X Instrument: B FSubmitted by: Analyst: JAM INST B Weight: Acct. No. 1. 001 AMOUNT-AREA « REF AMNT/(REF AREA « RESP FACT) Resp. fac. from Library Entry No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 B5 No 51 52 53 54 55 56 57 58 Name C550 C321 C555 C560 C565 C570 C543 C580 C5B5 C590 C595 C610 C615 C625 C630 C635 C640 C645 C650 C655 D200 C647 C715 C720 C725 C730 C740. C735 C760 C765 C770 C775 C780 C7B5 C790 m/2 153 232 184 109 168 165 165 149 •ACENAPHTHENE 0. 8 2,3,4,6-TETRACHLOROPHENOL &2,4DIN1TR0PHEN0L 8t4NITROPHENOL DIBENZOFURAN 0. 8 2, 4DINITR0T0LUENE 0.2 2, 6DINITR0T0LUENE 0. 2 DIETHYL PHTHALATE 4CHL0R0PHENYL PHEN 0. 4 FLUORENE 0. 9 4-NITROANILINE 4,6DINITR02METHYLPH •DIPHENYLAMINE 4DR0M0PHENYL PHENY 0. 1 CL6BEN2ENE 0. 1 •PENTACHLOROPHENOL 0. 05 PHENANTHRENE 0. 7 ANTHRACENE 0. 7 DI-NBUTYLPHTHALATE •FLUORANTHENE 0. 6 1,2-DIPHENYLHYDRAZINE CARBAZOLE PYRENE 0. 6 BUTYLBENZYLPHTHALATE 3.3'CL2DENZIDINE BENZD(A)ANTHRACENE 0. 8 BIS(2ETHYLHEXYL)PHTH CHRYSENE 0. 7 •DI-N-OCTYLPHTHALATE BENZO(B)FLUORANTHE 0.7 BENZO(K)FLUORANTHE 0.7 •BENZO(A)PYRENE 0.7 INDEN0(1,2, 3CD)PYR 0. 5 DIBENZO(A, H)ANTHRA 0.4 BENZO(G, H, DPERYLE 0. 5 Scan Time Ref RRT 782 13:02 3 1.004 810 13:30 3 1.040 785 13:05 3 1.008 791 13: 11 3.1. 015 796 13: 16 3 1. 022 798 13:18 3 1.024 763 12: 43 3 0. 979 817 13:37 3 1.049 T T T Meth A BD A DD A DD A DB A DD A DD A BD A DD Area(Hght) 21761. 6923. 3045. 2043. 33674. 8215. 7070. 25268. Amount 25. 25. 25. 25. 25. 25. 25. 25. 000 000 000 000 000 000 000 000 PPD PPD PPB PPB PPD PPD PPD PPD 7.Tot 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 300386 ;nB SijhiecrTb Vdyy^-^- No 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 BO 81 82 83 64 85 No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 |76 77 fn/2 Scan Time Ref 204 166 138 196 169 246 264 266 176 176 149 624 13:44 627 13:47 635 13:55 635 13: 55 636 13: 56 666 14:26 663 14:43 699 14: 59 914- 15:14 918- 15: IB 959 15:59 202 1022.' 17:02 77 167 839 13: 59 933 15:33 202 1044- 17:24 149 1098 16: 18 252 1167 19:27 228 1173- 19:33 149 1163 19:23 228 1180- 19:40 149 1262 21:02 252 1372. 22: 52 252 1378- 22: 58 252 : 276 : 278 ; 276 : 1455' 24: 15 1836. 30:36 1844- 30: 44 1954' 32: 34 Ret(L) Ratio RRT(L: 13:02 13:30 13:05 13: 11 13: 16 13: 18 12: 43 13:37 13:44 13:47 13:55 13:55 13:56 14:28 14:43 14: 59 15: 14 15: 18 15:59 17:02 13: 59 15:33 17:24 16: 18 19:27 19: 33 19:23 1.00 1.004 1.00 1. 040 1.00 1.008 1.00 1.015 1.00 1.022 1.00 1.024 1.00 0.979 1.00 1. 049 1.00 1.058 1.00 1. 062 1.00 1.072 1.00 0.916 1.00 0.917 1. 00 0. 952 1.00 0.968 1.00 0. 986 1.00 1.002 1. 00 1. 007 1.00 1.052 1. 00 1. 121 1.00 0.920 1.00 1.023 1.00 0. 888 1.00 0.934 1.00 0.992 1.00 0.997 1. 00 0. 989 3 3 3 4 4 4 4 4 4 4 4 4 4 4 5 5 5 5 5 5 6 6 6 6 6 6 6 ) Ri RRT 1.058 1.062 1.072 0. 916 0.917 0.952 0. 968 0.986 1.002 1. 007 1.052 1. 121 0. 920 1. 023 0. BBS 0. 934 0. 992 0. 997 0.989 1. 003 0. 858 0. 933 0. 937 0. 989 1. 248 1. 254 1. 328 atio 00 00 00 00 00 00 00 , 00 00 00 00 00 00 00 00 ,00 , 00 , 00 , 00 ,00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 Meth A A A A A A A A A A A A A A A A A A A A A A A A A A A BB BB VB BB BB BB *BB BB BV VB BB BB BB BB BB BB BB BV BB VB BD BV VB BB BB BB BB Amnt 2! 2! 5. 00 5. 00 25. 00 2; 2; 5. 00 5. 00 25. 00 25. 00 2! 21 2: 2: 2: 2: 2: 21 2! 2i 21 21 2' 2 2 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 25. 00 2 2 2 2 5. 00 5. 00 5. 00 5. 00 Area(Hght) Amount 11716. 25536. 3361. 4567. 13767. 6636. 6712. 4627. 36191. 37037. 45041. 36201. 29659. 23056. 39401. 19861. 4348. 31949. 28211. 29396. 45403. 33707. 25784. 28854. 31409. 23544. 25748. Amnt(L) 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25.00 25. 00 25. 00 25. 00 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 R. Fac R. F 0.916 0. 292 0. 128 0. 086 1.418 0. 346 0.298 1. 064 0.493 1. 075 0. 142 0. 128 0. 386 0. 186 0. 188 0. 135 1. 013 1. 037 1. 261 1. 014 0. 830 0. 646 1. 302 0. 657 0. 144 1. 056 0. 933 PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB 7.Tot 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 • 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 ac(L) Ratio 0. 916 0. 292 0. 128 0. 086 1. 418 0. 346 0. 298 1. 064 0. 493 1. 075 0. 142 0. 128 0. 386 0. 186 0. 188 0. 135 1. 013 1. 037 1. 261 1. 014 0. 830 0. 646 1. 302 0. 657 0. 144 1. 056 0. 933 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 300387 i idsnoR No Ret(L) Ratio RRT(L) Ratio Amnt Amnt(L) R.Fac R.Fac(L) Ratio 76 19:40 1.00 1.003 1.00 25.00 25.00 0.972 0.972 1.00 79 80 81 62 63 21:02 22:52 22:56 24: 15 30:36 1.00 1.00 1.00 1. 00 1. 00 0.656 0.933 0.937 0. 969 1.246 1.00 1.00 1.00 1. 00 1.00 ~ - 25. 00 25.00 25. 00 25. 00 25.00 25.00 25. 00 25.00 25. 00 25.00 1. 369 1.016 0.777 0.670 0.947 1.369 1.016 0.777 0.870 0.947 1.00 1.00 1.00 1.00 1.00 84 30:44 1.00 1.254 1.00 25^.00 25.00 0.710 0.710 1.00 65 32:34 1.00 1.326 1.00 25.00 25.00 0.776 0.776 1.00 ssro fis^ 300388 D?^.yZrz^oZioZaMaAon {» . "(« :# DATA FROM FILE: BS110994B SCAHS 361 TO llOl ACQUIRED: 11/09/94 10:28:80 CALI: BS110994B #1 SAMPLE: SSTD160 290-02-SU80 CONDS.: RTX-5 0.25MM X S0M 1.0UM 45/4-325620 INST B C ^ fy 400 _ 6:40 500 . 8:20 600 . 10:00 700 ^ 11:40 800 _ 13:20 900 . u; 15:00 I o 1000 J wl ^ 16:40 o; r:-. O' o. • i' p U i I !-i CD VO o ^fi ± ± CS50 2-FLUOROPHEHOL 0.6 (SS-5) •^im.Q?. ( 179712.) «Bae GGIS D5 PIOIQL 0.8 (SS-4) ClOn Dt 1..^ DICHLQROBEHZEHE (IS-1) CS75 l,2-CL2BEf^ZEHE-D4 0.4 (SS-8) t ^ 0 D5-NITR0BENZEHE 0.2 (SS-1) nmrmtEHE -<IS-2) CS25 2-FLUOROBIPHEhfy'L 0.7 (SS-2) CIT.Q P18-AC6NnPHTHEHE (IS-3) C555 2,4,6TRIBR0M0PHEHQL (SS-6) TbSg D14-P-TERPHEHYL 0.5 (SS-3) I? «> < . . • > V % / 7 PJ '\%-* DATA FROM FILE: BS110994B SCAHS 1101 TO 2008 ACQUIRED: 11/09/94 10:28:80 CALI: BS110994B #1 SAMPLE: SSTD160 290-02-SU80 COHDS.: RTX-5 0.25MM X SOM l.OUM 45/4-32562© IHST B C r ' t t:: < a o' 3 1200 _ 20:00 - 1400 _ 23:20 1600 _ 26:40 I 1 1 . ~ U 7 ^ D12-PERYLEHE = ^ tIS-5) (IS-6) J 100.07. ( 97920.) 1800 _ ol S130:00 vo o SC m J Quantitation Report File; BS110994B Data: BS110994B.TI 11/09/94 10:26:00 Sample: SSTD160 290-02-SV60 Conds.: RTX-5 O. 25MM X 30M l.OUM 45/4-325^20 Formula: X X X Instrument: B Submitted by: Analyst: JAM AMOUNT-AREA • REF AMNT/(REF AREA • RESP FACT) Resp. fac. from Library Entry INST B Weight: Acct. No. 1. 001 No 1 2 3 4 5 6 7 6 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 6 8 2 Name CI30 D4-l,4 DICHLOROBENZENE CI40 DB-NAPHTHALENE CI50 DIO-ACENAPHTHENE CI60 DIO-PHENANTHRENE CI70 D12-CHRYSENE CI75 D12-PERYLENE CS50 2-FLUOROPHENOL CS45 D5-PHEN0L CS20 D5-NITROBENZENE CS25 2-FLUOROBIPHENYL CS55 2,4,6TRIBROMOPHENOL CS30 D14-P-TERPHENYL 0. 5 CS70 2-CHL0R0PHEN0L-D4 0.6 CS75 1,2-CL2BENZENE-D4 0.4 C315 •PHENOL 0. 8 C325 BIS(2CHL0R0ETHYL)E O;7 C330 2CHL0R0PHENDL 0. 8 C335 1, 3DICHLDR0BENZENE 0. 6 C340 •I. 4DICHL0R0BENZENE 0.5 C320 ANILINE N-NITROSODIMETHYLAMINE PYRIDINE BENZYL ALCOHOL 1,2DICHLOROBENZENE 0 2METHYLPHEN0L 0 2, 2'OXYBISdCHLOROPR (IS-1) (IS-2) (IS-3) (IS-4) (IS-5) (IS-6) (SS-5) (SS-4) (SS-1) 0.7 (SS-2) (SS-6) (SS-3) (SS-7) (SS-B) C310 C319 C345 C350 C355 C357 C365 4 7 C410 C415 C425 C430 C435 4METHYLPHENDL 0.6 C370 ?«N I TROSOPROP YLAM INE 0. 5 C375 HEXACHLOROETHANE 0.3 NITROBENZENE ISOPHORONE C420 •2-NITRDPHENDL 0. 1 2.4-DIMETHYLPHENOL 0. 2 BENZOIC ACID BIS(2CHLDR0ETHDXY) C440 •2,4DICHL0R0PHEN0L C445 1,2,4TRICHL0R0DENZ C450 NAPHTHALENE C455 4-CHLOROANILINE C460 •CL6DUTADIENE C465 •4CHL0R03METHYLPHEN 0. 2 C470 2METHYLNAPHTHALENE 0. 4 C510 &CL6CYCL0PENTADIENE C515 •246TRICHL0R0PHNE0L 0.2 C520 2.4,5TRICHL0R0PHEN 0. 2 C525 2CHL0R0NAPHTHALENE 0. 8 C530 2-NITROANILINE 0. 2 0. 4 0. 0. 0. 0. 0. 0. T T 300391 Data Subject To Validatiof No Name 48 C535 DIMETHYL PHTHALATE 49 C540 ACENAPHTHYLENE 1.^3" 50 C545 3-NITROANILINE No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 4B 49 50 m/2 152 136 164 168 240 264 112 99 62 172 330 244 132 152 94 93 128 146 146 93 74 79 iOB 146 108 45 108 70 117 77 82 139 107 122 93 162 180 128 127 225 107 142 237 196 196 162 65 163 152 138 Scan 501 • 619 779 912 1176 1470 378 474 556 717 851 1053 484 519- 475- 480- 486 497' 502* 475- 199 199 518' 520' 529' 530 543' 544 548 558 579 587 • 590. 606- 597 609 615 622 628 635 670 663 702 711. 715- 728 740 755 766 778 Time 6:21 10: 19 12:59 15: 12 19:36 24: 30 , 6: 16 7:54 9: 16 11: 57 14: 11 17:33 6:04 6:39 7: 55 6:00 6:06 6: 17 6:22 7: 55 3: 19 3: 19 8:38 8:40 8:49 8: 50 9:03 9:04 9: 08 9: 18 9:39 9:47 9: 50 10:06 9: 57 10: 09 10: 15 10: 22 10:28 10: 35 11: 10 11: 23 11:42 11: 51 11: 55 12: OB 12:20 12: 35 12:46 12: 58 Ref 1 2 3 4 5 6 1 1 2 3 3 5 2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3 RRT 1.000 1, 000 1,000 1. 000 1. 000 1. 000 0.754 0. 946 0. 898 0. 920 1. 092 0. 695 0. 966 1. 036 0. 946 0. 958 0. 970 0. 992 1. 002 0. 948 0. 397 0. 397 1. 034 1. 038 1. 056 1. 058 1. 084 1. 086 1. 094 0. 901 0. 935 0. 948 0. 953 0. 979 0. 964 0. 984 0. 994 1. 005 1. 015 1.026 1. 082 1. 103 0. 901 0. 913 0. 918 0. 935 0. 950 0. 969 0. 983 0. 999 Meth A BB A BB A BB A BD A BB A BB A BB A BV A BB A BB A BB A BB A BB A BB A BB A VB A BB A BV A VB A BV A BB A BD A BV A BB A VB A BB A BB A BB A BD A BB A BV A BB A BB A BB A BD A DD A DD A BV A BB A BB A BD A BB A BB A BV A VB A DD A DD A BB A DD A DV Area(Hght) 10939. 35684. 19437. 29068. 16948. 14695. 43413. 56555. 43696. 86333. 9091. 58906. 48498. 31477. 69261. 58496. 49203. 52936. 53576. 62900. 27527. 38346. 27515. 48977. 44010. 58365. 47818. 27149. 19653. 41541. 85142. 27172. 34263. 20908. 57086. 37579. 39249. 119980. 52848. 18199. 35080. 82161. 24614. 25837. 28707. 82689. 21530. 88163. 109842. 179B2. SSTOl^^ By/ic>^ni? Amount 20. 000 20. 000 20. 000 20. 000 20. 000 20. 000 60. 000 60. 000 60. 000 60. 000 60. 000 80. 000 60. 000 60. 000 80. 000 • 60. 000 60. 000 60. 000 60. 000 80. 000 60. 000 60. 000 80. 000 60. 000 60. 000 60. 000 80. 000 80. 000 60. 000 60. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 60. 000 60. 000 60. 000 80. 000 60. 000 80. 000 80. 000 BO. 000 80. 000 80. 000 80. 000 80. 000 PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB 7.Tot 0.31 0.31 0.31 0.31 0.31 0.31 1.24 1.24 1. 24 1.24 1.24 1.24 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 1.24 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 ' 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 1.24 1.24 1.24 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 300392 DataSubjecUoVaHdaiior^ No Ret(L) Ratio RRT(L> Ratio 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 6:21 10: 19 12: 59 15: 12 19:36 24:30 6: 16 7:54 9: 16 11:57 14: 11 17:33 8:04 6:39 7:55 8:00 6:06 8: 17 6:22 7: 55 3: 19 3: 19 8: 38 8:40 6:49 6: 50 9:03 9:04 : 9:08 9: 18 9:39 9:47 9: 50 10: 06 9: 57 10:09 10: 15 10:22 10:28 10:35 11: 10 11:23 11:42 11: 51 11: 55 12:08 12:20 12:35 12:46 12: 58 1.00 1.00 1.00 1. 00 1. 00 1.00 1.00 1. 00 1.00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1.000 1.000 1.000 1. 000 1. 000 1. 000 0. 754 0.946 0. 698 0. 920 1. 092 0. 695 0. 966 1. 036 0. 948 0.958 0. 970 0. 992 1. 002 0. 948 0. 397 0. 397 1. 034 1. 038 1. 056 1. 058 1. 084 0. 0. 0. 1. 086 1. 094 0. 901 O. 935 O. 948 953 979 964 0. 984 0. 994 1. 005 1. 015 1. 026 1. 082 1. 103 0. 901 0. 913 0. 918 0. 935 0. 950 O. 969 0. 983 0. 999 1. 00 1.00 1.00 1. 00 1. 00 1.00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 I. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 Amnt 20. 00 20. 00 20.00 20. 00 20. 00 20. 00 80*. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 Amnt(L) R. Fac R. Fac(L) Ratio 20. 00 20. 00 20.00 20. 00 20. 00 20. 00 80. 00 80. 00 80. 00 80. 00 60. 00 60. 00 80.00 80. 00 80. 00 60. 00 80. 00 80. 00 80. 00 60. 00 60. 00 80. 00 80. 00 80. 00 80. 00 80. 00 60. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 BO. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 1. 1. 1. 1. 1. 1. 1. 1. 1. 0. 000 000 000 000 000 1.000 0.992 1.293 0. 306 1. 110 0. 117 0. B69 1. 108 0.719 1. 583 1.337 124 210 224 438 629 0. 876 0. 629 1. 119 1. 006 1. 334 1. 093 0. 620 449 291 596 190 240 146 0. 400 0. 263 275 841 370 128 246 576 317 0. 332 0. 369 1. 064 0. 277 1. 134 1. 413 0. 231 O. 0. 0. O. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 1. 1. 1. 1. 1. 0. 1. 000 1. 000 1.000 1. 000 1. 000 1.000 O. 992 1.293 0. 306 1. 110 0. 117 0. 869 1. 108 0. 719 583 337 124 210 224 438 629 0. 876 0. 629 1. 119 1. 006 1. 334 1. 093 0. 620 O. 449 0. 291 0. 596 O. 190 0. 240 0. 146 0. 400 0. 263 0. 275 0. 841 0. 370 0. 128 0. 246 0. 576 0. 317 0. 332 0. 369 1. 064 0. 277 1. 134 1. 413 0. 231 1. 00 1. 00 1.00 1. 00 1. 00 1.00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 00 00 00 00 00 00 00 1. 00 1. 00 00 00 00 00 00 00 00 00 00 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 SJTDi'^ 300393 ''^f3 5ub;ea7c Vai andfn Quantitation Report File: BS110994B Data: BS110994B. TI 11/09/94 10:28:00 Sample: SSTD160 290-02-SVBO Conds.: RTX-5 0.25MM X 30M l.OUM 45/4-325e20 |Formula: X X X Instrument: B 'submitted by: Analyst: JAM INST B Weight: Acct. No. 1. 001 AMOUNT-AREA • REF AMNT/(REF AREA * RESP FACT) Resp. fac. from Library Entry No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 Bl 82 83 84 B5 No 51 52 53 54 55 56 57 58 Name C550 C321 C555 C560 C565 C570 C543 C580 C585 C590 C595 C610 C615 C625 C630 C635 C640 C645 C650 C655 D200 C647 C715 C720 C725 C730 0740- C735 C760 C775 C7B0 C785 C790 C765 C770 m/2 153 232 184 109 168 165 165 149 •ACENAPHTHENE 0. 8 2, 3, 4, 6-TETRACHLOROPHENOL «c2, 4DI NITROPHENOL &4NITROPHENOL DIBENZOFURAN 0. 8 2,4DINITR0T0LUENE 0. 2 2,6DINITR0T0LUENE 0. 2 DIETHYL PHTHALATE 4CHL0R0PHENYL PHEN 0. 4 FLUORENE 0. 9 4-NITROANILINE 4,6DINITR02METHYLPH •DIPHENYLAMINE 4BR0M0PHENYL PHENY 0. 1 CL6BENZENE 0. 1 •PENTACHLOROPHENOL 0. 05 PHENANTHRENE 0. 7 ANTHRACENE 0. 7 DI-NBUTYLPHTHALATE •FLUORANTHENE 0. 6 1,2-DIPHENYLHYDRAZINE CARBAZOLE PYRENE 0. 6 BUTYLBENZYLPHTHALATE 3,3'CL2BENZIDINE BENZO(A)ANTHRACENE 0.8 BIS(2ETHYLHEXYL)PHTH CHRYSENE 0. 7 •DI-N-OCTYLPHTHALATE •BENZQ(A)PYRENE 0.7 INDEN0(1,2, 3CD)PYR 0.5 DIBENZ0(A, H)ANTHRA 0.4 BENZO(G,H, DPERYLE 0. 5 BENZO(B)FLUORANTHE 0.7 BENZD(K)FLUDRANTHE 0.7 Scan Time Ref RRT 783 13:03 3 1.005 811 13:31 3 1.041 786 13:06 3 1. 009 792 13:12 3 1.017 796 13: 16 3 1. 022 799 13:19 3 1.026 764 12:44 3 0.981 818 13:38 3 1.050 T T T ' Meth A BD A BD A BD A BD A BB A BD A BD A BV Area(Hght) 73858. 23130. 13198. 7050. 100613. 28467. 25972. 86344. Amount 80. 80. 80. 80. 80. 80. 80. 80. i:-r;i, T i 000 000 000 000 000 000 000 000 1 1 PPB PPB PPB PPB PPB PPB PPB PPB 7.Tot 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 '300394 jDieciToVa Wdatiort No 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 m/2 Scan Time Ref 204 166 138 198 169 248 264 266 176 178 149 202 : 77 167 202 : 149 252 : 228 149 228 149 252 276 278 276 252 252 B25 13:45 628 13:48 636 13: 56 636 13:56 837 13: 57 668 14:26 884 14:44 900 15:00 915- 15:15 919* 15:19 960 16:00 1023-, 17:03 840 14:00 934 15:34 1044- 17:24 1098 IB: 18 1170 19:30 1174- 19:34 1164 19:24 1181. 19:41 1263 21:03 1457- 24: 17 1845- 30:45 1651- 30:51 1959. 32:39 1374- 22:54 1380- 23:00 3 3 3 4 4 4 4 4 4 4 4 4 4 4 5 5 5 5 5 5 6 6 6 6 6 6 6 Ret(L) Ratio RRT(L) Ri 13:03 13:31 13:06 13: 12 13: 16 13: 19 12:44 13:38 13:45 13:48 13: 56 13: 56 13:57 14:28 14:44 15:00 15: 15 15: 19 16:00 17:03 14:00 15:34 17:24 18: 18 19:30 19: 34 19:24 1.00 1.005 1.00 1.041 1.00 1.009 1.00 1.017 1.00 1. 022 1.00 1.026 1.00 0.981 1.00 1.050 1.00 1.059 1.00 1.063 1.00 1.073 1.00 0.917 1.00 0.918 1. 00 0. 952 1. 00 0. 969 1.00 0.987 1. 00 1. 003 1.00 1.008 1.00 1.053 1. 00 1. 122 1.00 0.921 1.00 1.024 1.00 0. BBS 1.00 0.934 1.00 0.995 1.00 0.998 1.00 0.990 RRT 1.059 1.063- 1.073 0.917 0.916 0.952 0.969 0.987 1.003 1.008 1.053 1. 122 0, 921 1. 024 0. 888 0. 934 0. 995 0. 998 0. 990 1. 004 0. 859 0. 991 1. 255 1. 259 1. 333 0. 935 0. 939 atio 00 00 00 00 00 00 00 00 00 00 00 00 00 ' 00 . 00 . 00 , 00 . 00 . 00 , 00 , 00 . 00 . 00 . 00 , 00 . 00 , 00 Meth A BB A BB A VB A BB A BB A BB A-BB A BB A BV A VB A BB A BB A BV A BB A BV A BB A BB A BV A BB A VB A BB A BB A BB A BB A BB M XXQ" M XX'' Amnt 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 Area(Hght) Amount 41368. B5355. 6199. 17099. 44417. 21016. 20744. 16937. 117430. 108240. 138531. 107516. 101039. 56049. 110303. 50539. 4149. 76809. 69532. 68758. 101813. 54980. 49665. 40850. , ., 42508. l^n 69212. ^ 57276. Amnt(L) 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 9/1/*5W'^ 60. 000 80. 000 60. 000 50. 000 80. 000 eo. 000 eo. 000 eo. 000 60. 000 60. 000 60. 000 60. 000 60. 000 BO. 000 60. 000 60. 000 60. 000 60. 000 80. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB R. Fac R. Fac(L) R 0. 950 0. 297 0. 170 0. 091 1.294 0. 366 0. 334 1. Ill 0. 532 1. 098 0. 080 0. 147 0.382 0. 181 0. 178 0. 146 1. 010 0. 931 1. 191 0. 925 0. 869 0. 482 1. 627 0. 746 • 0.061 1. 133 1. 026 1 1 0. 950 0.297 0. 170 0. 091 1. 294 0. 366 0.334 1. Ill 0. 532 1. 098 0. 080 0. 147 0. 382 0. 181 0. 178 0. 146 1. 010 0. 931 1. 191 0. 925 0. 869 0.482 1. 627 0. 746 0. 061 1. 133 1. 026 7.Tot 1.24 1.24 1.24 1.24 1.24 1.24 1.24 1.24 1.24 1.24 1.24 1.24 1.24 1. 24 1. 24 1.24 1.24 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 atio 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 ~ 3003 9^ Asts Subject 7b Val irfri-v,- No 7 8 7 9 80 81 82 6 3 84 65 R e t ( L } 1 9 : 4 1 2 1 : 0 3 2 4 : 17 3 0 : 4 5 3 0 : 5 1 3 2 : 3 9 2 2 : 5 4 2 3 : 0 0 R a t i o 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1. 00 RRT(L) 1 . 0 0 4 0 . 8 5 9 0 . 9 9 1 1 . 2 5 5 1.259 1 . 3 3 3 0. 9 3 5 0. 9 3 9 R a t i o 1 . 0 0 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Amnt 6 0 . 0 0 - 80. 00 8 0 . 0 0 8 0 . 0 0 60. 00 6 0 . 0 0 e a . 00 60. 00 Amnt(L) BO. 0 0 8 0 . 0 0 6 0 . 0 0 e o . 0 0 6 0 . 0 0 6 0 . 0 0 6 0 . 0 0 60. 00 jrvDiia^ •^/7/fify/? R. Fac R. 1 . 0 1 4 1 . 7 3 2 0. 9 3 5 0. 6 4 5 0 . 6 9 5 0 . 7 2 3 1. 177 0. 9 7 4 F a c ( L ) 1 . 0 1 4 1 . 7 3 2 0 . 9 3 5 0 . 6 4 5 0 . 6 9 5 O. 7 2 3 1. 177 0 . 9 7 4 R a t i o 1.00 1.00 1. 00 1.00 1. 00 1.00 1.00 1.00 300396 r . I'.ri To Validation Data Si^bi^^cx >o i^ DATA FROM FILE: BS110994C SCAHS 362 TO 1102 ACQUIRED: 11/09/94 11:88:00 CALI: BS110994C #1 SAMPLE: SSTD020 290-02-SU10 COHDS.: RTX-5 0.25HM X SOM l.OUM 45/4-325620 IHST B . I ii •# Q oD d r y vor^ 400 _ 6:40 500 8:20 600 . 10:00 700 . 11:40 800 . 13:20 900 . 15:00 1000 _ 16:40 m fVF ± CS50 2-FLUORnPHENOL 0.6 (SS-5) 100.0^ ( 57024.) •CS45 D5-PHEH0L 0.8 (SS-4) CI30 04-1,4 DICHLOROBENZENE (IS-1) ^ r - CS75 1,2-CL2BENZEHE-D4 0.4 (SS-8) "CS20 D5-HITR0BEHZEHE 0.2 (SS-1) CI40 D8-HAPHTHALEHE (IS-2) CS25 2-FLUOROBIPHEHYL 0.7 (SS-2) CI50 D10-ACEHAPHTHEHE (IS-3) CS55 2,4,6TRIBR0M0PHENnL (SS-6) CI60 D10-PHEHAHTHREHE (IS-4) t ^V CS30 D14-P-TERPHEHYL 0.5 (SS-3) (o ^ . ' U - * DATA FROM FILE: BS110994C SCAHS 1102 TO 2000 ACQUIRED: 11/09/94 11:08:00 CALI: BS110994C »1 290-02-SU10 COHDS.: RTX-5 0.25MM X SOM l.OUM 45/4-325628 SAMPLE: SSTD020 1200 _ 20:09 1600 _ 26:40 a trt c a., Pi. 1800 J 30:00 ^ fir ff J IHST B J 100.07. ( 33344.) CI70 D12-CHRYSEHE (IS-5) CI75 D12-PERYLEHE (IS-6) Ui o o Ui vo 00 Quantitation Report File: BS110994C Data: BS110994C. TI 11/09/94 11:08:00 Sample: SSTD020 290-02-SVlO Conds.: RTX-5 O. 25MM X SOM l.OUM 45/4-325620 ^Formula: X X X Instrument: B ^Submitted by: Analyst: JAM INST B Weight: Acct. No. 1. 001 AMOUNT-AREA • REF AMNT/(REF AREA • RESP FACT) Resp. fac. from Library Entry No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 3B 39 40 41 42 43 ;44 45 46 47 Name CI30 CI40 CI50 CI60 CI70 CI75 CS50 CS45 CS20 CS25 CS55 CS30 CS70 CS75 C315 C325 C330 C335 C340 C320 C310 C319 C345 C350 C355 C357 C365 C370 C375 C410 C415 C420 C425 C430 C435 C440 C445 C450 C455 C460 C465 C470 C510 C515 C520 C525 C530 0. 6 0. 8 0. 2 0. 7 0. 4 O. 8 0, 0, O, 0, 7 8 6 5 D4-l,,4 DICHLOROBENZENE DB-NAPHTHALENE DIO-ACENAPHTHENE D10-PHENANTHRENE D12-CHRYSENE D12-PERYLENE 2-FLUDROPHENOL D5-PHEN0L D5-NITR0BENZENE 2-FLUORDBIPHENYL 2,4,6TRIBR0M0PHEN0L D14-P-TERPHENYL 0. 5 2-CHLORDPHEN0L-D4 0. 8 1,2-CL2BENZENE-D4 •PHENOL BIS(2CHL0R0ETHYL)E 2CHL0R0PHEN0L 1,3DICHLDR0BENZENE •1,4DICHLOROBENZENE ANILINE N-NITROSODIMETHYLAMINE PYRIDINE BENZYL ALCOHOL 1,2DICHLOROBENZENE 0.4 2METHYLPHEN0L . 0.7 2,2'OXYBIS(1CHLOROPR • 4METHYLPHENDL O. 6 &NITROSOPROPYLAMINE 0.5 HEXACHLOROETHANE NITROBENZENE ISOPHORONE •2-NITROPHENOL 2,4-DIMETHYLPHENOL 0. 2 DENZOIC ACID BIS(2CHLDR0ETH0XY) •2,4DICHLOROPHENOL 1,2, 4TRICHL0R0DENZ NAPHTHALENE 4-CHLOROANILINE •CL6BUTADIENE •4CHL0R03METHYLPHEN 0. 2 I 2METHYLNAPHTHALENE 0. 4 ?<CL6CYCL0PENTADIENE •246TRI CHLOROPHNEOL 0.2 2, 4, 5TRICHLOR0PHEN 0.2 2CHL0R0NAPHTHALENE 0. 8 2-NITROANILINE (IS-1) (IS-2) (IS-3) (IS-4) (IS-5) (IS-6) (SS-5) (SS-4) (SS-1) (SS-2) (SS-6) (SS-3) (SS-7) (SS-8) 0. 3 0. 2 0. 4 0. 1 0. 3 0. 2 0. 2 0. 7 T T T T T T 300399 Uaia SuDiectloValWauoB No Name 48 C535 DIMETHYL PHTHALATE 49 C540 ACENAPHTHYLENE lT3- 50 C545 3-NITROANILINE No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 m/2 152 136 164 168 240 264 112 99 62 172 330 244 132 152 94 93 128 146 146 93 74 79 108 146 108 45 108 70 117 77 82 139 107 122 93 162 180 128 127 225 107 142 237 196 196 162 65 163 152 138 Scan 502 620 780 913 1176 1470 380 474 556 717 851 1053 485 520 475 480 486 498 503 476 201 202 518 521 529 530 542 543 549 553 578 587 - 590 599 597 609 615 622 629 636 671 683 703 711 716 728 740 755 766 778 Time 6:22 10:20 13:00 15:13 19:36 24:30 6:20 7:54 9: 16 11: 57 14: 11 17:33 8:05 8:40 7: 55 8:00 8:06 8: 18 8:23 7: 56 3:21 3:22 8:38 8:41 8:49 8: 50 9: 02 9:03 9:09 9: 18 9: 38 9:47 9: 50 9: 59 9: 57 10:09 10: 15 10:22 10: 29 10: 36 11: 11 11:23 11:43 11: 51 11: 56 12:08 12:20 12: 35 12:46 12: 58 Ref 1 2 3 4 5 6 1 1 2 3 3 5 2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3 0. 0. 0. 0. 1. 0. 0. 1. 0. 0. 0. 0. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0, 0. 0. 0. 0. RRT 000 000 000 000 000 000 757 944 897 919 091 895 966 036 946 956 968 992 002 948 400 402 032 038 054 056 080 082 094 900 932 947 952 966 963 982 992 003 015 026 082 102 901 912 918 , 933 949 968 , 982 997 Meth A BB A 'BB A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A BB BB BB BB BB BB BB BB BB BB BB BB BB VB BB BV VB BV BB BD BV BD VD BD BB BB BB BB BB BB BB VB BB BD BB BD VD BD BD BB BB BV VB BD DB DD DB DD Area(Hght) 11275. 38585. 20925. 31216. 24953. 26606. 5253. 6726. 5634. 11506. 1158. 10177. 5724. 4123. 6656. 7634. 6285. 6749. ' 6861. 6826. 3086. 4918. 2917. 6199. 6378. 7359. 6168. 3317. 2479. 5422. 10522. 32S7. 4247. 2454. 7241. 4994. 5190. 17066. 5289. 2485. 4375. 10825. 2651. 3523. 3603. 10456. 2826. 11556. 17369. 913. SrTD(p2.p '2.^ll9>'7TVO Amount 20. 000 20. 000 20. 000 20. 000 20. 000 20. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 r i 1 [ PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB 7.Tot 2.20 2.20 2.20 2.20 2.20 2.20 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 300400 z Data subject lb VaLdation No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 Ret(L> 6:22 10:20 13:00 15: 13 19:36 24:30 6:20 7:54 9: 16 11:57 14: 11 17: 33 8:05 6:40 7:55 8:00 6:06 8: 16 6:23 7: 56 3:21 3:22 6:38 8:41 6:49 8:50 9: 02 9:03 9:09 9: 18 9:38 9:47 9: 50 9: 59 9: 57 10:09 10: 15 10:22 10:29 10:36 11: 11 11:23 11:43 11: 51 11: 56 12:08 12:20 12:35 12:46 12:58 Ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 l.OO 1.00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1.00 1. 00 1. 00 1. 00 1.00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1.00 1. 00 1. 00 RRT(L) 1.000 1.000 1.000 1.000 1. 000 1. 000 0.757 0. 944 0.897 0. 919 1.091 0. B95 0. 966 1.036 0.946 0. 956 0.968 0.992 1. 002 0. 948 0. 400 0. 402 1. 032 1. 038 1. 054 1. 056 1. 080 1.082 1. 094 0. 900 0. 932 0. 947 0. 952 0. 966 0. 963 0. 982 0. 992 1. 003 1. 015 1. 026 1. 082 1. 102 0. 901 0. 912 0. 918 0. 933 0. 949 0. 968 0. 982 0. 997 Ratio 00 - 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 . 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 , 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 , 00 00 00 Amnt 20. 00 20. 00 20. 00 20.00 20. 00 20. 00 10. 00 10. 00 10.00 10. 00 10; 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 Amnt(L) 20.00 20. 00 20.00 20. 00 20. 00 20.00 10. 00 10.00 10.00 10. 00 10.00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 ' 10. 00 10. 00 10. 00 10.00 10. 00 10. 00 10.00 10. 00 10. 00 Sfropi^ R.Fac R. 1.000 1.000 1. 000 1.000 1.000 1.000 0.932 1. 193 0.292 1. 100 0. Ill 0. 816 1.015 0.731 1.535 1. 354 1. 115 1. 197 1.217 1. 211 0. 547 0. 872 0. 518 1. 100 1. 131 1. 305 1. 094 0. 588 0. 440 0. 281 0. 545 0. 170 0. 220 0. 127 0. 375 0.259 0.269 0. 885 0.274 0. 129 0. 227 0. 561 0.253 0. 337 0.344 0. 999 0. 270 1. 105 1. 660 0. 087 y 1 Fac(L) 1.000 1. 000 1, 000 1. 000 1.000 1.000 0.932 1. 193 0.292 1. 100 0. Ill 0. 816 1.015 0.731 ' 1. 535 1. 354 1. 115 1. 197 1.217 1. 211 0. 547 0. 872 0. 518 1. 100 1. 131 1. 305 1. 094 0. 588 0. 440 0. 281 0. 545 0. 170 0. 220 0. 127 0. 375 0. 259 0. 269 0. 885 0. 274 0. 129 0. 227 0. 561 0. 253 0. 337 0.344 0. 999 0. 270 1. 105 1. 660 0. 087 Ratio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 ,00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 300401 Data Subjed To Validation Quantitation Report File: BS110994C » Data: BS110994C. TI 11/09/94 11:08:00 Sample: SSTD020 290-02-SVlO Conds.: RTX-5 0. 25MM X 30M l.OUM 45/4-325620 ormula: X X X Instrument: B Submitted by: Analyst: JAM INST B Weight: Acct. No. 1. 001 AMOUNT-AREA • REF AMNT/(REF AREA • RESP FACT) Resp. fac. from Library Entry No Name 51 C550 •ACENAPHTHENE 0. 8 52 C321 2,3.4,6-TETRACHLOROPHENOL 53 C555 ttZ. 4DINITROPHENOL 54 C560 ««4N I TROPHENOL 55 C565 DIBENZOFURAN 0. 8 56 C570 2,4DINITR0T0LUENE 0. 2 T 57 C543 2, 6DINITR0T0LUENE 0.2 58 C580 DIETHYL PHTHALATE 59 C585 4CHLDR0PHENYL PHEN 0. 4 60 C590 FLUORENE 0. 9 61 C595 4-NITROANILINE 62 C610 4,6DINITR02METHYLPH 63 C615 •DIPHENYLAMINE 64 C625 4BR0M0PHENYL PHENY 0. 1 65 C630 CL6BENZENE 0. 1 T 66 C635 •PENTACHLOROPHENOL 0. 05 T 67 C650 DI-NBUTYLPHTHALATE 68 C655 •FLUORANTHENE 0. 6 69 D200 1,2-DIPHENYLHYDRAZINE 70 C647 CARBAZOLE 71 C715 PYRENE 0.6 72 C720 BUTYLBENZYLPHTHALATE 73 C725 3,3'CL2BENZIDINE 74 C730 BENZO(A)ANTHRACENE 0. 8 75 C740 BIS(2ETHYLHEXYL)PHTH 76 C735 CHRYSENE 0. 7 77 C760- •DI-N-OCTYLPHTHALATE 78 C765 BENZO(B)FLUORANTHE 0. 7 79 C770 BENZO(K)FLUORANTHE 0. 7 80 C775 •BENZD(A)PYRENE 0. 7 81 C7B0 INDEN0(1,2, 3CD)PYR 0. 5 82 C785 DIBENZO(A, H)ANTHRA 0. 4 83 C790 BENZO(G,H, DPERYLE 0. 5 84 C640 PHENANTHRENE 0. 7 85 C645 ANTHRACENE 0. 7 No m/2 Scan Time Ref RRT Meth Area(Hght) Amount 7.Tot 51 52 53 54 55 56 57 58 153 232 184 109 168 165 165 149 783 811 786 792 796 798 763 817 13: 03 13: 31 13:06 13: 12 13: 16 13: 18 12: 43 13: 37 3 3 3 3 3 3 3 3 1. 004 1. 040 1. 008 1. 015 1. 021 1. 023 0. 978 1. 047 A BB A BB A BD A DD A BD A BD A DD A BD 9553. 3119. 1100. 686. 14138. 3534. 2928. 10779. 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 PPB PPB PPB PPB PPB PPB PPB PPB 10 10 10 10 10 10 10 10 [ 300402 Oata Subject"foValidalior^ No fli/2 Scan Time Ref RRT Meth 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 .76 204 166 138 198 169 248 264 266 149 202 77 167 202 149 252 228 149 228 149 252 252 252 276 278 276 178 625 827 835 635 636 669 664 900 960 1022 839 933 1044 1098 1167 1173 1163 1179 1262 1371 1376 1453 1B36 1842 1950 915 13:45 13:47 13: 55 13:55 13:56 14:29 14:44 15:00 16: 00 17:02 13: 59 15:33 17:24 IB: 16 19:27 19:33 19:23 19:39 21:02 22: 51 22: 56 24: 13 30: 36 30: 42 32:30 15: 15 85 178 918 15: 18 3 3 3 4 4 4 4 4 4 4 4 4 5 5 5 5 5 5 6 6 6 6 6 6 6 4 4 1.058 1. 060 1. 071 0.915 O. 916 O. 952 O. 968 0. 966 1. 051 1. 119 0. 919 1. 022 0. 688 0.934 O. 992 0. 997 0. 989 1.003 0.859 O. 933 0. 936 0. 988 1. 249 1.253 1. 327 1. 002 1. 005 No Ret(L) Ratio RRT(L) Ratio 13:03 13:31 13: 06 13: 12 13: 16 13: 18 12:43 13:37 13:45 13:47 13: 55 13: 55 13: 56 14: 29 14:44 15:00 16:00 17:02 13: 59 15:33 17:24 18: 18 19:27 19: 33 19: 23 19: 39 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 00 00 00 00 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 004 1. 040 1. 008 1. 015 1. 021 1. 023 0. 978 1. 047 1. 058 1. 060 1. 071 0. 915 0. 916 0. 952 0. 968 0. 986 1. 051 1. 119 0. 919 1. 022 0. BBS 0. 934 0. 992 0. 997 0. 9B9 1. 003 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 A A A A A A A A A A A A A A A A A A A A A A A A A M M BB BB VB BB BB BB SB BB BB BB BB BB BB BB BB BV BB VB BB BV VB BB BB BB BB XX XX Area(Hght} 5345. 11505. 1539. 1896. 6620. 2962. 2889. 1684. 19015. 16186. 11572. 13167. 16994. 64BB. 3485. 14398. 11639. 13060. 19173. 13884. 123B0. 12605. 13221. 10243. 11093. 5659. 0. QiiW'.f 1565 ' ^1621 Amount XTot 10. 000 PPB 1. 10 10. 000 PPB 1. 10 10. 000 PPB 1. 10 10. 000 PPB 1. 10 10. 000 PPB 1. 10 10. 000 PPB 1. 10 10. 000 PPB 1. 10 10. 000 PPB 1. 10 10.000 PPB 1. 10 10.000 PPB 1. 10 10. 000 PPB 1. 10 10. 000 PPB 1. 10 10. 000 PPB 1. 10 10. 000 PPB 1. 10 10. 000 PPB 1. 10 10. 000 PPB 1. 10 10. 000 PPB 1. 10 10. 000 PPB 1. 10 10. 000 PPB 1. 10 10. 000 PPB 1. 10 10. 000 PPB 1. 10 10. 000 PPB 1. 10 10, 000 PPB 1. 10 10.000 PPB 1. 10 10. 000 PPB 1. 10 10. 000 PPB 1. 10 10. 000 PPB 1. 10 '77 21:02 1.00 0.859 1.00 Amnt 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 Amnt(L) R.Fac R.Fac(L) Ra 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 SfrDQil-P 0.913 0.913 1.00 0. 298 0. 298 1. 00 0. 105 0. 105 1. 00 0.066 0.066 1.00 1.351 1.351 1.00 0.338 0.338 1.00 0.280 0.280 1.00 1.030 1.030 1.00 0.511 0.511 1.00 1. 100 1. 100 1. 00 0. 147 0. 147 1. 00 0. 121 O. 121 1. 00 0.424 0.424 1.00 0. 190 0. 190 1. 00 0. 185 0. 185 1. 00 0. 108 0. 108 1. 00 1.218 1.218 1.00 1.037 1.037 1.00 0.741 0.741 1.00 0.844 0. B44 1.00 1.362 1.362 1.00 0.680 O; 680 1.00 0.279 0.279 1.00 1. 154 1. 154 1. 00 0.933. 0.933 1.00 1.047 1.047 1.00 1. 441 1. 441 1. 00 __ _ C\Z?\--r\ y^~y^ •-- - 300403 Data Subject:To Validstion i o r^ No 78 79 eo 61 82 63 84 65 Ret(L) 22:51 22:56 24: 13 30:36 30:42 32:30 15: 15 15: 18 Ratio 1.00 1. 00 1.00 1.00 1.00 1. 00 1.00 1.00 RRT(L) 0.933 0.936 0.968 1.249 1.253 1. 327 1.002 1.005 Ratio 1.00 1. 00 ^ 1.00 1. 00 1.00 1.00 1.00 1.00 Amnt 10. 00 -10. 00 10.00 10. 00 10.00 10. 00 10. 00 10. 00 Amnt(L) 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 Ssro »^0' ^fn^'ilic R. Fac R. 1.044 0.931 0.948 0. 994 0.770 0.834 1.003 1.039 Fac(L) 1. 044 0.931 0.948 0. 994 0.770 0. 634 1.003 1.039 Ratio 1.00 1.00 1.00 1.00 1. 00 1. 00 1.00 1.00 300404 Uaia Subied To VaUdatiorJ DATA FROM FILE: BS110994D SCAHS 362 TO 1102 ACQUIRED: 11/09/94 11:48:08 CALI: BSl109940 #1 SAMPLE: SSTD12e 290-02-SU60 CONDS.: RTX-5 e.25MM X 30M 1.0UM 45/4-325620 INST B . ' i i i - a Ci? o"' Ul i 6" 400 . 6:40 500 J 8:20 600 J 10:00 700 . 11:40 800 13:20 900 . 15:00 1000 . 16:40 ± I CS50 2-FLUOROPHEHOL nn<|S DR PI OIDL- 0.6 (SS-5) -• 100.07. ( 143872.) 0.8 (SS-4) -CTLtn Dl 1,4 DICHLOROBEHZENE (IS-1) -tS75 1/2-CL2BEHZEHE-D4 0.4 (SS-8) I^QSS©- D5-HITROBEHZEHE 0.2 (SS-1) niitn DO MriPHTHALEME (IS-2) CS25 2-FLUOROBIPHEHYL 0.7 (SS-2) •CISC PlO-nCEHnPHTHEHE (IS-S) CS55 2,4,6TRIBR0M0PHEN0L (SS-6) ifTlTffn rf«-D"trklAKITUDCMC =felS-4) = C530 D14-P-TERPHENYL 8.5 (SS-3) 'z-> O' DATA FROM FILE: BS110994D SCAHS 1102 TO 2000 ACQUIRED: 11/09/94 11:48:80 CALI: BS110994D #1 SAMPLE: SSTD120 290-02-SU60 CONDS.: RTX-5 0.25MM X SOM l.OUM 45/4-325620 IHST B ' ^ • * 1200 _ 20:00 1400 J 23:20 26:40 a CJ r - f at t n a" n 1800 30:00 m -1 I ± I J 100.07. ( 76800.) CITgl D13«CM,rfIHE (IS-5) CI75 D12-PERYLEHE (IS-6) Ui o o o Quantitation Report File: BS110994D Data: BS110994D. TI 11/09/94 11:46:00 Sample: SSTD120 290-02-SV60 Conds.: RTX-5 0.25MM X 30M l.OUM 45/4-325^20 INST B .Formula: X X X Instrument: B Weight: 1.001 PSubmitted by: Analyst: JAM Acct. No. : AMOUNT-AREA • REF AMNT/(REF AREA • RESP FACT) Resp. fac. from Library Entry No Name 1 CI30 D4-l,4 DICHLOROBENZENE (IS-1) 2 CI40 DS-NAPHTHALENE (IS-2) 3 CI50 DIO-ACENAPHTHENE (IS-3) 4 CI60 DIO-PHENANTHRENE (IS-4) 5 CI70 D12-CHRYSENE (IS-5) 6 CI75 D12-PERYLENE (IS-6) 7 CS50 2-FLUOROPHENDL 0.6 (SS-5) 8 CS4 5 D5-PHEN0L O.B (SS-4) 9 CS20 D5-NITROBENZENE 0.2 (SS-1) 10 CS25 2-FLUOROBIPHENYL 0.7 (SS-2) 11 CS55 2,4,6TRIBR0MDPHENDL (SS-6) 12 CS30 D14-P-TERPHENYL 0. 5 (SS-3) 13 CS70 2-CHL0R0PHEN0L-D4 0.8 (SS-7) 14 CS75 1,2-CL2BENZENE-D4 0.4 (SS-B) 15 C315 •PHENOL 0. 8 16 C325 BIS(2CHL0R0ETHYL)E 0.7 17 C330 2CHLDR0PHEN0L 0.8 18 C335 1,3DICHLOROBENZENE O. 6 19 C340 •1,4DICHL0R0BENZENE 0. 5 T 20 C320 ANILINE 21 C310 N-NITROSODIMETHYLAMINE 22 C319 PYRIDINE T 23 C345 BENZYL ALCOHOL 24 C350 1.2DICHL0R0BENZENE 0. 4 25 C355 2METHYLPHEN0L 0. 7 T 26 C357 2,2'DXYBIS(ICHLOROPR 27 C365- 4METHYLPHEN0L 0. 6 T 28 C370 &NITROSOPROPYLAMINE 0. 5 29 C375 HEXACHLOROETHANE 0. 3 T 30 C410 NITROBENZENE 0. 2 T 31 C415 ISOPHORONE 0.4 32 C420 •2-NITROPHENOL 0. 1 33 C425 2,4-DIMETHYLPHENOL 0. 2 34 C430 DENZOIC ACID 35 C435 B1S(2CHL0R0ETH0XY) 0.3 36 C440 ^2, 4DICHLOROPHEN0L 0.2 37 C445 1,2, 4TRICHLOROBENZ 0.2 38 C450 NAPHTHALENE 0. 7 39 C455 4-CHLORDANILINE 40 C460 •CL6DUTADIENE T 41 C465 •4CHL0R03METHYLPHEN 0. 2 42 C470 2METHYLNAPHTHALENE 0. 4 43 C510 8<CL6CYCLOPENTADIENE 44 C515 •246TRICHLOROPHNEOL 0. 2 T 145 C520 2, 4, 5TRICHL0R0PHEN 0. 2 T 46 C525 2CHL0R0NAPHTHALENE 0. 8 , 300407 47 C530 2-NITROANILINE No Name 48 C535 DIMETHYL PHTHALATE ^ 49 C540 ACENAPHTHYLENE 1. 3" 50 C545 3-NITROANILINE No 1 2 3 4^ 5 6 7 8 9 10 11 12 13 14 15 16 17 IB 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 ^50 m/2 152 136 164 168 240 264 112 99 B2 172 330 244 132 152 94 93 128 146 146 93 74 79 iOB 146 108 45 108 70 117 77 82 139 107 122 93 162 180 128 127 225 107 142 237 196 196 162 65 163 152 138 Scan 502. 620 780 913 1177 1471 378 , 474 557 717 852 1054 485 520- 476. 481- 486 498- 503- 476- 199 199 518- 521. 530- 530 543- 545 549 559 579 587 - 590- 606- 598 609 616 622 629 636 671 684 703 711 716' 728 741 756 767 779 Time 6:22 10: 20 13: 00 15: 13 19:37 24: 31 6: 18 7:54 9: 17 11: 57 14: 12 17:34 6:05 8:40 7: 56 8:01 8:06 8: 18 6:23 7: 56 3: 19 3: 19 8:38 8:41 8: 50 8: 50 9:03 9:05 9:09 9: 19 9:39 9:47 9: 50 10:06 9: 5B 10:09 10: 16 10:22 10:29 10: 36 11: 11 11:24 11:43 11: 51 11: 56 12:08 12: 21 12:36 12:47 12:59 Ref 1 2 3 4 5 6 1 1 2 3 3 5 2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3 RRT 1. 000 1.000 1.000 1.000 1. 000 1. 000 0.753 0. 944 0. 898 0. 919 1. 092 0, 895 0. 966 1. 036 0. 948 0. 958 0. 968 0. 992 1. 002 0. 948 0. 396 0. 396 1. 032 1. 038 1. 056 1. 056 1. 082 1. 086 1. 094 0. 902 0. 934 0. 947 0. 952 0. 977 0. 965 0. 982 0. 994 1. 003 1. 015 1. 026 1. 082 1. 103 0. 901 0. 912 0. 918 0. 933 0. 950 0. 969 0. 983 0. 999 Meth A BB A 'BB A BB A BB A BB A BB A BB A BV A BB A BB A BB A BB A BB A BB A BB A VB A BB A BV A VB A BV A BB A BD A BV A BB A VB A BB A BB A BB A BD A BB A BV A BB A BB A VB A BB A BD A BD A DV A BD A BD A BD A BB A BD A DV A VD A DD A DD A BD A DD A VD Area(Hght) 10537. 35662. 19566. 29511. 18310. 16752. 32550. 42973. 31B73. 60592. 7146. 47947. 35752. 22656. 51743. 45939. 36433. 40853. 41213. 45849. 20700. 29433. 19544. 38563. 33006. 42716. 32504. 20736. 14837. 34432. 65071. 19786. 23894. 17435. 44033. 28289. 29790. 89113. 38828. 13762. 27386. 66210. 17508. 19552. 22302. 59680. 17201. 65299. 91731. 9340. jrroJT-v B^))<^T»'^* Amount 20. 000 PPB 20. 000 PPB 20. 000 PPB 20. 000 PPB 20. 000 PPB 20. 000 PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 60. OOO PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 60. 000 PPB 7.Tot 0.41 0.41 0. 41 0.41 0. 41 0. 41 1.23 1.23 1.23 1.23 1.23 1.23 1. 23 1.23 1. 23 1.23 1. 23 1. 23 1. 23 1.23 1.23 1. 23 1.23 1. 23 1.23 1. 23 1. 23 1.23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1.23 1. 23 1.23 1. 23 1. 23 1. 23 1.23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 300408 -^ C 6 - «»•• 1 , f-S? J-l.?«> No Ret(L) Ratio RRT(L> Ratio 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 6:22 10:20 13:00 15: 13 19:37 24:31 6:16 7:54 9: 17 11:57 14: 12 17:34 6:05 B:40 7: 56 6:01 6:06 8: 18 8:23 7: 56 3: 19 3: 19 8:38 8:41 8: 50 8: 50 9:03 9: 05 9: 09 9: 19 9:39 9:47 9: 50 10: 06 9: 58 10:09 10: 16 10:22 10:29 10: 36 11: 11 11:24 11:43 11: 51 11: 56 12: 08 12:21 12:36 12:47 1.00 1.00 1. 00 1.00 1.00 1.00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1.000 1.000 1.000 1.000 1.000 1.000 0.753 0.944 0. 698 0. 919 1. 092 0. 695 0. 966 1. 036 O. 948 O. 958 0.968 0. 992 1. 002 O. 948 0. 396 0. 396 1. 032 1. 038 1. 056 1. 056 1. 082 1. 086 1. 094 0. 902 0. 934 O. 947 0. 952 0. 977 0. 965 0. 982 0. 994 1. 003 1. 015 1. 026 1. 082 1. 103 0. 901 0. 912 0. 918 0. 933 O. 950 0. 969 0. 983 1.00 1.00 1.00 1.00 1.00 1. 00 1.00 1.00 1.00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 00 00 00 00 00 00 00 1. 00 1. 00 1.00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 00 00 00 00 00 00 00 00 00 00 00 00 50 12:59 1.00 0.999 1.00 Amnt 20.00 20. 00 20. 00 20.00 20. 00 20. 00 60t 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 Amnt(L) R.Fac R.Fac(L) Ratio 20.00 20.00 20.00 20.00 20. 00 20.00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 1.000 1. 1. 1. 1. 1. 1. 1. 0. 000 000 000 000 000 030 359 296 1. 032 0. 122 0. 673 1. 131 0, 717 1.637 1.453 1. 153 1. 292 1. 304 1.450 0. 655 0. 931 0.618 1. 220 1. 044 1. 351 1. 028 0. 656 O. 469 0. 322 0. 608 0. 185 0.223 0. 163 0. 412 0.264 0. 278 0. 833 0. 363 0. 129 0. 256 619 298 333 380 017 293 1. 112 1. 563 0. 159 0. 0. 0. 0. 1. 0. 1.000 1. 000 1.000 1.000 1. 000 1.000 1.030 1.359 0.298 1. 032 0. 122 0. 673 1. 131 0. 717 1. 637 1. 453 1. 153 1. 292 1. 304 1. 450 0. 655 0. 931 0. 618 1. 220 1. 044 1. 351 1. 028 0. 656 0. 469 O. 322 0. 608 0. 185 0. 223 0. 163 0. 412 264 278 833 363 129 0. 256 0. 619 0. 298 0. 333 0. 380 1. 017 0. 293 1. 112 1. 563 0. 159 0. 0. 0. 0. 0. 1.00 1. 00 1. 00 1.00 1.00 1.00 1.00 1. 00 1.00 1. 00 1. 00 1. 00 1. 00 00 00 00 00 00 00 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 300409 Data Sijbjeo To VaUdatior Quantitation Report File: BS110994D Data: BS110994D. TI 11/09/94 11:46:00 ^ - Sample: 5STD120 290-02-SV60 Conds.: RTX-5 0.25MM X 30M l.OUM 45/4-325820 |Formula: X X X Instrument: B Submitted by: Analyst: JAM INST B Weight: Acct. No. 1. 001 AMOUNT-AREA • REF AMNT/(REF AREA « RESP FACT) Resp. fac. from Library Entry No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 No 51 52 53 54 55 56 57 58 Name C550 C321 C555 C560 C565 C570 C543 C580 C5B5 C590 C595 C610 C615 C625 C630 C635 C640 C645 C650 C655 D200 C647 C715 C720 C725 C730 0740^ C735 C760 C775 C7B0 C785 C790 C765 C770 m/2 153 232 184 109 168 165 165 149 •ACENAPHTHENE 0. 6 2,3,4,6-TETRACHLDROPHENOL &2.4DINITR0PHEN0L &4NITROPHENOL DIBENZOFURAN 0.8 2,4DINITR0T0LUENE 0. 2 2,6DINITR0T0LUENE 0. 2 DIETHYL PHTHALATE 4CHL0R0PHENYL PHEN 0. 4 FLUORENE 0.9 4-NITROANILINE 4,6DINITR02METHYLPH •DIPHENYLAMINE 4BR0M0PHENYL PHENY 0. 1 CL6DENZENE 0. 1 •PENTACHLOROPHENOL 0. 05 PHENANTHRENE 0. 7 ANTHRACENE 0. 7 DI-NB UTYLPHTHALATE •FLUORANTHENE 0. 6 1,2-DIPHENYLHYDRAZINE CARBAZOLE PYRENE 0. 6 BUTYLBENZYLPHTHALATE 3,3'CL2BENZIDINE BENZO (A) ANTHRACENE 0.8 BIS(2ETHYLHEXYL)PHTH CHRYSENE 0. 7 •DI-N-OCTYLPHTHALATE •DENZO(A)PYRENE 0.7 INDEN0(1,2, 3CD)PYR 0.5 DIDENZO(A, H)ANTHRA 0.4 BENZO(G,H, DPERYLE 0.5 BENZO(B)FLUDRANTHE 0.7 BENZO(K)FLUORANTHE 0.7 Scan Time Ref RRT 783 13:03 3 1.004 812 13:32 3 1.041 787 13:07 3 1.009 793 13:13 3 1.017 797 13:17 3 1.022 800 13:20 3 1.026 764 12:44 3 0.979 818 13:38 3 1.049 T T T Meth A BB A BB A BD A BD A DD A DB A DD A BD Area(Hght) 52715. 18594. 10409. 5381. 75675. 22170. 17232. 61901. Amount 60. 60. 60. 60. 60. 60. 60. 60. 000 000 000 000 000 000 000 000 PPB PPB PPB PPB PPB PPB PPB PPB 7.Tot 23 23 23 23 23 23 23 23 300410 Data Subjed To VaJidacior No 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 BO 61 82 B3 84 85 No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 m/2 204 166 138 198 169 246 264 266 176 176 149 202 77 167 202 149 252 228 149 228 149 252 276 278 276 252 252 Scan T i m e F 626 13:46 629 13:49 637 13:57 837 13: 57 636 13: 56 669 14:29 665 14:45 901 15:01 916- 15:16 920- 15:20 961 16:01 1023- 17:03 641 '14:01 935 15:35 1045. 17:25 1098 IB: 16 1170 19:30 1174. 19:34 1164 19:24 1181 19:41 1264 21:04 1457 24: 17 1843 30:43 1651 30: 51 1961 32:41 1374- 22:54 1380- 23: 00 tef 3 3 3 4 4 4 4 4 4 4 4 4 4 4 5 5 5 5 5 5 6 6 6 6 6 6 6 Ret(L) Ratio RRT(L) Ri 13: 13: 13: 13: 13: 13: 12: 13: 13: 13: 13: 13: 13: 14: 14: 15: 15: 15: 16: 17: 14: 15: 17: 18: 19: 19: 19: 03 32 07 13 17 20 44 38 46 49 57 57 58 29 45 01 16 20 01 03 01 35 25 18 30 34 24 1.00 1. 004 1,00 1.041 1,00 1.009 1,00 1.017 1.00 1.022 1. 00 1. 026 1.00 0.979 1.00 1.049 1,00 1. 059 1.00 1.063 1.00 1.073 1.00 0.917 1.00 0.918 1.00 0.952 1.00 0.969 1.00 0.987 1.00 1.003 1. 00 1. 008 1.00 1.053 1. 00 1. 120 1.00 0.921 1.00 1.024 1.00 0.888 1.00 0.933 1.00 0.994 1.00 0.997 1.00 0.989 RRT 1.059 1.063 1.073 0.917 0.916 0.952 0.969 0. 987 1. 003 1.008 1. 053 1. 120 0.921 1.024 0. 888 0.933 0. 994 0. 997 0. 989 1.003 0. 859 0. 990 1.253 1.258 1.333 0, 934 0.938 atio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 ,00 00 , 00 00 , 00 , 00 . 00 , 00 , 00 . 00 . 00 . 00 Meth A B B -A B B A VB A B B A B B A BB A BB A BB A B V A VB A BB A BB A BB A BB A BB A BB A BB A B V A BB A VB A BB A BB A BB A BB A BD M xxanj' M XX^ Amnt 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 ' Area(Hght} Amount 32173. 68643. 6633. 12852. 36106. 15836. 16296. 12616. 93076. 94272. 112068. 63216. 74249. 41797. 79977. 41173. 4604. 60473. 55996. 55856. 84020. 46588. 44926. 34808. , 36370. 'I';* 57638. * 48508. Amnt(L) 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB R. Fac R. Fac(L) 0. 898 0. 317 0. 177 0. 092 1. 289 0. 378 0. 294 1. 055 0. 548 1. 169 0. 113 0. 145 0. 408 0. 179 0. 184 0. 143 1. 051 1. 065 1. 266 0. 940 0. 839 0. 472 1.456 0. 750 • 0. 084 1, 101 1. 019 0. 898 0. 317 0. 177 0. 092 1. 289 0. 378 0. 294 1. 055 0. 548 1. 169 0. 113 0. 145 0. 408 0. 179 0. 184 0. 143 1. 051 1. 065 1. 266 0. 940 0. 839 0. 472 1. 456 0. 750 0. 084 1. 101 1. 019 7.Tot 1.23 1.23 1.23 1.23 1.23 1.23 1.23 1.23 1.23 1.23 1.23 1.23 1.23 1.23 1. 23 1.23 1.23 1. 23 1. 23 1.23 1. 23 1.23 1. 23 1. 23 1. 23 1. 23 1. 23 Ratio 1. 00 1, 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 '• 3 0 0 4 1 1 1 Data Subject; To Vali Idatior, No 78 79 60 81 82 83 84 85 Ret(L) 19:41 21:04 24: 17 30:43 30:51 32:41 22:54 23: 00 Ratio 1.00 1.00 1.00 1.00 1. 00 1.00 1.00 1.00 RRT(L) 1.003 0.659 0.990 1.253 1.256 1.333 0. 934 0. 936 Ratio 1.00 1.00 1.00 1.00 1.00 1.00 1. 00 1. 00 Amnt Amnt(L) 60. 00 - 60. 00 60.00 60. 00 60.00 60. 00 60. 00 60.00 60.00 60.00 60. 00 60.00 60.00 60.00 60, 00 60. 00 1 R. Fac R. 1.017 1.672 0.927 0. 694 0.693 0.724 1. 147 0. 965 Fac(L) 1.017 1.672 0.927 0.694 0. 693 0.724 1. 147 0.965 Ratio 1.00 1. 00 1.00 1. 00 1. 00 1.00 1, 00 1, 00 300412 DataSubiea'foVaiiriafion; «t'-* Ui Ci o M Ui DATA FROM FILE: BS110994E SCANS 367 TO 1107 ACQUIRED: 11/09/94 12:29:00 CALI: BS110994E #1 SAMPLE: SSTDO80 290-02-SU40 CONDS.: RTX-5 0.25MM X SOM l.OUM 45/4-325620 INST B 400 J 6:40 500 . 8:20 600 J 10:00 700 _[ 11:40 800 13:20 fe 900 . 15:00 1000 4 16:40 w -\ ± ± ± J 100.07. ( 92800.) CS50 2-FLUOROPHEHOL 0.6 (SS-5) -eS45 D5-PHEH0L 0.8 (SS-4) CI00 D1 1,4 DICHLOROBENZENE (IS-1) CS75 1,2-CL2BEHZEHE-D4 0.4 (SS-8) (IS-2) eS20 D5-HITR0BEHZEHE 0.2 (SS-1) G H Q DO NAPHTHALEHE C15Q DIQ-ACEHAPHTHENE CS25 2-FLUOROBIPHEHYL 0.7 (SS-2) (IS-3) CS55 2,4,6TRIBR0M0PHEN0L (SS-6) Tallinn n r n mn nirNAHTHREHE (IS-4) --K CS30 D14-P-TERPHENYL 0.5 (SS-3) 5c ' ^ t - DATA FROM FILE: BS110994E SCAHS 1107 TO 2000 ACQUIRED: 11/09/94 12:29:00 CALI: BS110994E ftl SAMPLE: SSTDO80 290-02-SV40 COHDS.: RTX-5 0.25MM X SOM l.OUM 45/4-325628 IHST B r 1200 4 20:00 1400 J ':"3..9i :20 1600 . 26:40 a £1! (J) I C. ! a" 175' o ; y it^ ; (5- rfi. a . 1800 . 30:80 3 ± ± ± J •nrO Dia«CHRYSEHE 100.0;j ( 55488.) (IS-5) CI75 D12-PERYLEHE (IS-6) Quantitation Report File: BS110994E Data: BS110994E. TI 11/09/94 12:29:00 Sample: SSTDOSO 290-02-SV40 Conds.: RTX-5 O. 25MM X 30M l.OUM 45/4-325620 INST B Formula: X X X Instrument: B Weight: 1.001 Submitted by: Analystj JAM Acct. No. : AMOUNT-AREA • REF AMNT/(REF AREA • RESP FACT) Resp. fac. from Library Entry No Name 1 CI30 D4-1.4 DICHLOROBENZENE (IS-1) 2 CI40 DB-NAPHTHALENE (IS-2) 3 CI50 DIO-ACENAPHTHENE (IS-3) 4 CI60 DIO-PHENANTHRENE (IS-4) 5 CI70 D12-CHRYSENE (IS-5) 6 CI75 D12-PERYLENE (IS-6) 7 CS50 2-FLUOROPHENOL 0.6 (SS-5) 8 CS45 D5-PHEN0L 0.8 (SS-4) 9 CS20 D5-NITR0BENZENE 0,2 (SS-1) 10 CS25 2-FLUOROB1PHENYL 0,7 (SS-2) 11 CS55 2,4,6TRIBRDM0PHEN0L (SS-6) 12 CS30 D14-P-TERPHENYL 0, 5 (SS-3) 13 CS70 2-CHL0RDPHEN0L-D4 0.8 (SS-7) 14 CS75 1,2-CL2BENZENE-D4 0.4 (SS-8) 15 C315 •PHENOL 0. B 16 C325 BIS(2CHLDR0ETHYL)E 0.7 17 C330 2CHLDR0PHENDL 0. 8 18 C335 1.3DICHL0R0BENZENE 0. 6 19 C340 •1,4DICHL0R0DENZENE 0, 5 T 20 C320 ANILINE 21 C310 N-NITROSODIMETHYLAMINE 22 C319 PYRIDINE T 23 C345 BENZYL ALCOHOL 24 C350 1,2DICHL0R0DENZENE 0. 4 25 C355 2METHYLPHEN0L 0. 7 T 26 C357 2,2'0XYBIS(ICHLOROPR 27 C365' 4METHYLPHEN0L 0. 6 T 28 C370 &NITRDSDPROPYLAMINE 0. 5 29 C375 HEXACHLOROETHANE 0. 3 T 30 C410 NITROBENZENE 0. 2 T 31 C415 ISOPHORONE 0.4 32 C420 •2-NITROPHENOL 0. 1 33 C425 2.4-DIMETHYLPHENOL 0. 2 34 C430 DENZOIC ACID 35 C435 BIS(2CHL0R0ETHDXY) 0.3 36 C440 •2,4DICHL0ROPHEN0L 0.2 37 C445 1,2, 4TRICHL0R0DENZ 0.2 38 C450 NAPHTHALENE 0. 7 39 C455 4-CHLOROANILINE 40 C460 •CL6DUTADIENE T 41 C465 •4CHL0R03METHYLPHEN 0. 2 42 C470 2METHYLNAPHTHALENE O. 4 43 C510 ?<CL6CYCL0PENTADIENE k44 C515 •246TRI CHLOROPHNEOL 0. 2 T '45 C520 2, 4, 5TRICHLDRDPHEN 0. 2 T 300415 46 C525 2CHL0R0NAPHTHALENE 0. 8 47 C530 2-NITROANILINE DataSubieci K< No Name 48 C535 DIMETHYL PHTHALATE _ 49 C540 ACENAPHTHYLENE 1. 3' 50 C545 3-NITROANILINE No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 ,25 '26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 4S 49 |po F m/2 152 136 164 168 240 264 112 99 62 172 330 244 132 152 94 93 128 146 146 93 74 79 108 146 108 45 108 70 117 77 82 139 107 122 93 162 180 128 127 225 107 142 237 196 196 162 65 163 152 138 Scan 507' 622 760 913 1177 1471 394 . 481 560 718 852 1054 491 525- 482. 487. 493 504. 509. 483- 229 227 522 . 526. 533. 534 546. 547 553 562 581 590 ' 592- 605. 600 611 618 624 630 637 672 685 703 712. 716- 729 741 756 767 779 Ti 6: 10: 13: 15: 19: 24: 6: 6: 9: 11: 14: 17: 8: 8: 8: 8: 8: 8: 8: 8: 3: 3: 8: 8: 8: 8: 9: 9: 9: 9: 9: 9: 9: 10: 10: 10: 10: 10: 10: 10: 11: 11: 11: 11: 11; 12: 12: 12: 12: 12: me 27 22 00 13 37 31 34 01 20 58 12 34 11 45 02 07 13 24 29 03 49 47 42 46 53 54 06 07 13 22 41 50 52 05 00 11 18 24 30 37 12 25 43 : 52 ;56 ;09 :21 : 36 : 47 : 59 Ref 1 2 3 4 5 6 1 1 2 3 3 5 2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3 0. 0. 0. 0. 1. 0. 0, 1, 0, 0, 0, 0, 1. 0, 0. 0, 0. 0. 0, 0. 0. 0. 0. 0. 0. 0. 0. 0. 0, 0. 0, 0. RRT 000 000 000 000 000 000 777 949 900 921 092 895 968 036 951 961 972 994 004 953 452 448 030 037 051 053 077 079 091 904 934 949 952 973 965 982 994 003 013 024 080 101 901 913 , 918 935 950 969 983 999 Meth A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A BB teB BB BB BB BB BB BV BB BB BB BB BB BB BB VB BB BV VB BV BB BD BV BB VB BB BD DD BB BB BV BB BB VV BB BB BD BV VB DD DD DD DB BV VD DD DD DD DD DD Area(Hght} 10398, 36125. 19679. 29242. 19946. 18707. 20743, 28455. 21251, 44688, 4729, 35386. 23521. 15358. 33732. 28830. 22939. 26119, 26109, 30327. 13412. 19137. 11839. 23613. 19870. 26404, 21332. 12475. 9384. 21442. 40927, 12547, 16209, 10139. 28210. 18083. 19931. 63233. 23529. 9186. 16605. 42392. 10697, 12762, 13506. 40555. 10137. 41643. 60685. 4997. >JT[0<^<f<^ ?^11V11H1. Amount 20.000 PPB 20. 000 PPB 20. 000 PPB 20. 000 PPB 20, 000 PPB 20. 000 PPB 40, 000 PPB 40. 000 PPB 40, 000 PPB 40, 000 PPB 40, 000 PPB 40, 000 PPB 40, 000 PPB 40, 000 PPB 40, 000 PPB 40, 000 PPB 40, 000 PPB 40, 000 PPB 40. 000 PPB 40. 000 PPB 40. 000 PPB 40, 000 PPB 40, 000 PPB 40, 000 PPB 40, 000 PPB 40. 000 PPB 40, 000 PPB 40. 000 PPB 40. 000 PPB 40. 000 PPB 40. 000 PPB 40. 000 PPB 40. 000 PPB 40. 000 PPB 40. boo PPB 40. 000 PPB 40. 000 PPB 40. 000 PPB 40. 000 PPB 40. 000 PPB 40. 000 PPB 40. 000 PPD 40, 000 PPD 40, 000 PPB 40, 000 PPB 40, 000 PPB 40. 000 PPB 40. 000 PPB 40. 000 PPB 40. 000 PPB 30 7.Tot 0.61 0.61 0. 61 0, 61 0. 61 0, 61 1.22 1.22 1.22 1.22 1,22 1. 22 1, 22 1, 22 1, 22 1,22 1, 22 1, 22 1, 22 1, 22 1, 22 1.22 1, 22 1. 22 1. 22 1, 22 1, 22 1, 22 1. 22 1, 22 1,22 1.22 1. 22 1.22 1. 22 1. 22 1. 22 1. 22 1,22 1. 22 1,22 1, 22 1, 22 1,22 1. 22 1. 22 1. 22 1. 22 1. 22 1. 22 0416 OataSubiea I O '-'<=•• iTKJ! No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 130 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 Ret(L) 6:27 10:22 13:00 15: 13 19: 37 24:31 6:34 6:01 9:20 11:58 14: 12 17:34 6: 11 8:45 8:02 8: 07 8: 13 8:24 8:29 8:03 3:49 3:47 8:42 8:46 8: 53 8: 54 9: 06 9: 07 9: 13 9:22 9:41 9: 50 9: 52 10: 05 10:00 10: 11 10: 18 10:24 10: 30 10: 37 11: 12 11:25 11:43 11: 52 11: 56 12:09 12:21 12:36 12:47 12: 59 Ratio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 , 00 00 , 00 00 , 00 , 00 00 00 , 00 , 00 , 00 . 00 . 00 . 00 . 00 RRT(L> 1.000 1.000 1.000 1.000 1. 000 1.000 0.777 0.949 0, 900 0. 921 1. 092 0. B95 0.968 1. 036 0.951 0, 961 0. 972 0,994 1, 004 0,953 0, 452 0, 448 1.030 1, 037 1, 051 1, 053 1, 077 1, 079 1, 091 0, 904 0, 934 0, 949 0. 952 0. 973 0. 965 0. 982 0. 994 1. 003 1.013 1. 024 1. 080 1. 101 0. 901 0. 913 0. 918 0. 935 0. 950 0. 969 0. 983 0. 999 Ratio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 , 00 00 00 , 00 00 , 00 , 00 , 00 , 00 . 00 . Amnt - .. 20. 00 20. 00 20. 00 20.00 20. 00 2 a 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40, 00 40, 00 40. 00 40. 00 40. 00 40, 00 40. 00 40. 00 40. 00 40. 00 40. 00 40, 00 40, 00 40. 00 40. 00 40. 00 40. 00 ' 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 Amnt(L) 20. 00 20.00 20. 00 20, 00 20, 00 20, 00 40. 00 40, 00 40, 00 40, 00 40, 00 40.00 40, 00 40, 00 40, 00 40, 00 40, 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40, 00 40, 00 40. 00 40, 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 syr^^t^ ?/)|OlHF. R, Fac R. 1.000 1. 000 1.000 1. 000 1.000 1.000 0.997 1.368 0.294 1. 135 0. 120 0. B87 1. 131 0. 739 1.622 1. 386 1. 103 1. 256 1. 255 1,458 0, 645 0, 920 0. 569 1. 135 0. 955 1. 270 1. 026 0. 600 0. 451 0. 297 0. 566 0. 174 0. 224 0. 140 0. 390 0, 250 0, 276 0. 875 0. 326 0. 127 0. 230 0. 587 0. 272 0. 324 0. 343 1. 030 0. 258 1. 058 1. 542 0. 127 Fac 1. 1. 1. 1. 1. 1. 0, 1. 0. 1. 0. 0. 1, 0, 1. 1. 1. 1. 1, 1, 0, 0, 0, 1. 0. 1. 1, 0, 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 0, 1. 1, 0 :(L) 000 000 000 000 000 000 997 368 294 135 120 887 131 739 622 386 103 256 255 458 645 920 569 135 955 270 026 600 451 297 566 174 224 140 390 250 276 875 326 127 230 587 272 324 343 , 030 , 258 . 058 . 542 . 127 Ratio 00 00 00 00 00 00 00 00 00 00 00 00 00 00. 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 300417 >;:;tr Subject l b Validation; Quantitation Report File: BS110994E Data: BS110994E. TI 11/09/94 12:29:00 Sample: SSTDOBO 290-02-SV40 Conds.: RTX-5 0. 25MM X 30M l.OUM 45/4-325^20 Formula: X X X Instrument: B Submitted by: Analyst: JAM INST B Weight: Acct. No. 1. 001 AMOUNT-AREA • REF AMNT/(REF AREA • RESP FACT) Resp. fac. from Library Entry M No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 No 51 52 53 54 55 56 57 58 Name C550 C321 C555 C560 C565 C570 C543 C580 C585 C590 C595 C610 C615 C625 C630 C635 C640 C645 C650 C655 D200 C647 C715 C720 C725 C730 0740 £735 C760 C765 C770 C775 C780 C7B5 C790 m/2 153 232 184 109 168 165 165 149 •ACENAPHTHENE 0.8 2,3,4,6-TETRACHLOROPHENOL 8<2, 4DINITR0PHENDL 8<4N I TROPHENOL DIBENZOFURAN 0.8 2, 4DINITR0T0LUENE 0.2 2, 6DINITR0T0LUENE 0. 2 DIETHYL PHTHALATE 4CHL0R0PHENYL PHEN 0. 4 FLUORENE 0, 9 4-NITROANILlNE 4,6DINITR02METHYLPH •DIPHENYLAMINE 4BR0MDPHENYL PHENY 0, 1 CL6BENZENE 0. 1 •PENTACHLOROPHENOL 0. 05 PHENANTHRENE 0. 7 ANTHRACENE 0. 7 DI-NBUTYLPHTHALATE •FLUORANTHENE 0. 6 1,2-DIPHENYLHYDRAZINE CARBAZOLE PYRENE 0. 6 BUTYLBENZYLPHTHALATE 3,3'CL2BENZIDINE BENZO (A) ANTHRACENE 0,8 BIS(2ETHYLHEXYL)PHTH CHRYSENE 0, 7 •DI-N-OCTYLPHTHALATE BENZO(B)FLUORANTHE 0.7 BENZO(K)FLUORANTHE 0.7 •DENZO(A)PYRENE 0.7 INDEN0(1,2, 3CD)PYR 0.5 DIDENZO(A, H)ANTHRA 0.4 BENZO(G, H, DPERYLE 0. 5 Scan Time Ref RRT 783 13:03 3 1,004 812 13:32 3 1,041 787 13:07 3 1.009 792 13:12 3 1.015 797 13:17 3 1.022 800 13:20 3 1.026 764 12:44 3 0.979 BIB 13:38 3 1.049 T T T Meth A BD A BD A DD A DD A DB A BD A DD A BD Area(Hght) 35503, 11928. 6113. 3253. 49328. 14478. 10781. 41159. - - - — 3uufiJ.o Amount 40. 40. 40, 40. 40. 40. 40. 40, 000 000 000 000 000 000 000 000 PPB PPB PPB PPB PPB PPB PPD PPB ~ — 7.Tot 22 22 22 22 22 22 22 22 Data Subject lb Validation No 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 >76 77 m/2 204 166 138 198 169 248 264 266 176 178 149 202 77 167 202 149 252 228 149 228 149 252 252 252 276 278 276 Scan T J 626 13 628 13 636 13 836 13 837 13 869 14 685 14 901 15 915* 15 920* 15 961 16 1023' 17 840 14 935 15 1045- 17 1099 18 1169 19 1174- 19 1165 19 llBl- 19 1264 21 1374 22 1380 23 1457 24 1842 30 1851 30 1959 32 Ret(L) Ratio 13: 13: 13: 13: 13: 13: 12: 13: 13: 13: 13: 13: 13: 14: 14: 15: 15: 15: 16: 17: 14: 15: 17: 18: 19: 19; 19: 03 32 07 12 17 20 44 38 46 48 56 56 57 29 45 01 15 20 01 03 00 35 25 19 29 34 25 1, 00 1, 00 1, 00 1, 00 1, 00 1, 00 1.00 1, 00 1. 00 1, 00 1. 00 1. 00 1. 00 1, 00 1. 00 1. 00 1, 00 1, 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 ime Ref :46 :4B :56 :56 : 57 :29 :45 :01 : 15 :20 :01 :03 :00 :35 :25 : 19 :29 :34 :25 : 41 :04 : 54 :00 : 17 :42 :51 :39 R R T ( L : 1. 004 1. 041 1. 009 1. 015 1, 022 1. 026 0. 979 1. 049 1.059 1, 062 1, 072 0, 916 0, 917 0. 952 0. 969 0. 987 1. 002 1. 008 1. 053 1. 120 0. 920 1. 024 0. 888 0. 934 0. 993 0. 997 0. 990 3 3 3 4 4 4 4 4 4 4 4 4 4 4 5 5 5 5 5 5 6 6 6 6 6 6 6 RRT 1.059-. 1.062 1.072 0.916 0. 917 0. 952 0. 969 0. 987 1.002 1.008 1. 053 1. 120 0. 920 1. 024 0. 888 0. 934 0. 993 0. 997 0. 990 1, 003 0, 859 0, 934 0. 938 0. 990 1. 252 1. 258 i. 332 > Ratio 00 00 00 00 00 00 00 00 . 00 , 00 00 , 00 , 00 , 00 . 00 , 00 . 00 , 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 Met ;h A BB A BB A VB A BB A BB A.BB A BB A BB A BV A VB A BB A BB A BB A BB A BB A BB A BB A BV A BB A VB A BB A BV A VB A BB A BD A BB A BB Amnt 40. 40, 40. 40. 40. 40. 40. 40. 40. 40, 40, 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 40, 40. 40, 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 Area(Hgh 20187. 40962. 5296. 7939. 21070. 10229. 10934. 7670. 57216. 60407. 75335, 59498. 45689, 29852, 57772. 29411. 4134, 43367, 39027. 39284, 58391, 37710. 33547, 33859. 34289, 2607B. 28595. Amnt(L) 40, 00 40, 00 40, 00 40. 00 40, 00 40, 00 40. 00 40, 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 XjTO*f^ ^riia55VJl t) Amount 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40, 000 40, 000 40, 000 40, 000 40, 000 40, 000 40. 000 40, 000 40. 000 40. 000 40. 000 40, 000 40. 000 40. 000 40. 000 40, 000 PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB R. Fac R, Fac(L) 0. 0, 0, 0, 1, 0, 0, 1. 0. 1. 0. 0. 0, 0, 0 0, 0 1 1 1 0 0 1 0 0 1 0 902 303 1 155 1 083 1 253 368 274 046 513 041 135 . 136 , 360 , 175 . 187 , 131 , 978 . 033 .288 . 017 .781 . 510 . 448 .737 . 104 . 087 . 978 0. 902 0, 303 0. 155 0, 083 1, 253 0, 368 0. 274 1. 046 0. 513 1, 041 0. 135 0, 136 0, 360 0, 175 0. 187 0, 131 0, 978 1. 033 1.288 1, 017 0. 781 0, 510 1, 448 0, 737 0, 104 1. 087 0,978 7.Tot 1. 22 1,22 1.22 1.22 1.22 1.22 1, 22 1,22 1.22 1.22 1.22 1. 22 1. 22 1. 22 1, 22 1. 22 1, 22 1, 22 1, 22 1, 22 1. 22 1,22 1, 22 1, 22 1, 22 1, 22 1. 22 Ratio 1, 00 1, 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1 300419 1 w — _ - - ;;eCi io VaiSGatiOfi: No 7 8 7 9 8 0 81 8 2 8 3 84 8 5 R e t ( L ) 19:41 2 1 : 0 4 22:54 23: 00 24: 17 30: 4 2 30: 51 3 2 : 3 9 R a t i o 1.00 1.00 1.00 1.00 1.00 1.00 1. 00 1. 00 RRT(L) 1.003 0.859 0.934 0.936 0.990 1.252 1.258 1.332 R a t i o 1. 00 1.00 1.00 1.00 1.00 1. 00 1. 00 1. 00 Amnt 40. 00 ' 40. 00 40. 00 4 0 . 0 0 40. 00 4 0 . 0 0 ACT. 0 0 40. 00 Amnt(L) 40. 00 40. 00 40, 00 4 0 , 0 0 4 0 . 0 0 40. 00 40. 00 40, 00 SPm(pl^(i> ifmiiSE R.Fac R. 0.965 1. 561 1.006 0.697 0.905 0 . 9 1 6 0.697 0.764 Fac(L) 0. 985 1. 561 1. 008 0.697 0.905 0 . 9 1 6 0. 697 0.764 R a t i o 1. 00 1.00 1.00 1.00 1.00 1. 00 1. 00 1,00 300420 w Subject 7o Vaiideiior Initial Calibration Data Instrument Identifier: B " -. Calibration Date: 11/09/94 MIN RF: SW(&) - . 05 y CLP » . 01 OR BELOW MAX 7.RSD: SW(^) - 307./ CLP - 20.57. . ^ ' ^ ^ ^ r - CS50 CS45 CS20 CS25 CS55 CS30 CS70 CS75 C315 C325 C330 C335 C340 C320 C310 C319 C345 C350 C355 C357 C365 C370 |C375 C410 C415 C420 C425 C430 C435 C440 C445 C450 C455 C460 C465 C470 C510 C515 C520 C525 C530 C535 C540 C545 C550 C321 ^555 r Compound 2-FLUOROPHENOL D5-PHEN0L D5-NITROBENZENE 2-FLUOROBIPHENYL 0. 0. 0. 0, 2,4,6TRIBROMOPHENOL D14-P-TERPHENYL 2-CHLDR0PHENDL-D4 1,2-CL2BENZENE-D4 •PHENOL BIS(2CHL0R0ETHYL)E 2CHL0R0PHEN0L 1,3DICHLOROBENZENE •1,4DICHLOROBENZENE ANILINE 0. 0, 0, 0. 0. 0. 0. 0, 6 8 2 7 5 6 4 6 7 8 6 5 N-NITROSODIMETHYLAMINE PYRIDINE BENZYL ALCOHOL 1,2DICHLOROBENZENE 2METHYLPHEN0L 0, 0. 2.2'0XYBIS(ICHLOROPR 4METHYLPHEN0L &NITRDSDPROPYLAMINE HEXACHLOROETHANE NITROBENZENE ISOPHORONE •2-NITROPHENOL 2,4-DIMETHYLPHENOL BENZOIC ACID BIS(2CHLDR0ETH0XY) •2,4DICHLOROPHENOL 1,2, 4TRICHLOROBENZ NAPHTHALENE 4-CHLOROANILINE •CL6BUTADIENE •4CHL0R03METHYLPHEN 2METHYLNAPHTHALENE &CL6CYCL0PENTADIENE •246TRICHLOROPHNEOL 2.4, 5TRICHL0R0PHEN 2CHL0R0NAPHTHALENE 2-NITROANILINE DIMETHYL PHTHALATE ACENAPHTHYLENE 3-NITROANILINE •ACENAPHTHENE 0, 0, 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1 0 4 7 6 5 3 2 4 1 2 3 2 2 7 2 4 2 2 8 3 8 2.3,4.6-TETRACHLOROPHE 8<2.4DINITR0PHEN0L F IF 10 0. 1. 0, 1, 0, 0, 1, 0, 1, 1. 1. 1. 1, 1, 0. 0. 0. 1. 1. 1. 1. 0. 0. 0. 0. 0. 0. 0. 0, 0, 0. 0, 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 1 0 0 0 0 932 193 292 100 111 816 015 731 535 354 115 197 217 211 547 872 518 100 131 305 094 588 440 281 545 170 220 127 375 259 269 885 274 129 227 561 253 337 344 999 270 105 660 087 913 298 105 F IF 25 1. 1. 0. 1. 0. 0. 1. 0. 1. 1. 1. 1. 1. 1. 0. 0. 0. 1. 1, 1. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0 1 1 0 0 0 0 029 330 279 063 115 760 086 714 584 388 092 213 249 403 626 987 568 136 034 242 034 605 457 279 557 157 214 121 360 243 264 847 280 120 223 570 286 317 342 995 255 144 608 134 916 292 128 - RF 40 0, 1. 0. 1, 0. 0, 1, 0. 1. 1. 1. 1. 1. 1. 0. 0. 0. 1. 0. 1. 1. 0. 0. 0. 0, 0. 0. 0, 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 0. 1. 1 0 0 0 0 997 368 294 135 120 887 131 739 622 386 103 256 255 458 645 920 569 135 955 270 026 600 451 297 566 174 224 140 390 250 276 875 326 127 230 587 272 324 343 030 258 058 542 127 902 303 155 RF 60 1. 1. 0. 1. 0. 0. 1. 0, 1, 1, 1. 1. 1, 1. 0, 0. 0. 1, 1, 1, 1. 0. 0. 0, 0. 0. 0. 0, 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1 0 1 1 0 0 0 0 030 359 298 032 122 673 131 717 637 453 153 292 304 450 655 931 618 220 044 351 028 656 469 322 608 185 223 163 412 264 278 833 363 129 256 619 298 333 380 017 293 112 563 159 898 317 177 RF 60 0, 1. 0, 1. 0, 0, 1. 0, 1. 1, 1. 1. 1. 1. 0. 0. 0. 1. 1. 1. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 0 1 1 0 0 0 0 Aa 992 293 306 110 117 869 108 719 583 337 124 210 224 438 629 876 629 119 006 334 093 620 449 291 596 190 240 146 400 263 275 841 370 126 246 576 317 332 369 064 277 134 413 231 950 297 170 •Zi 5i;bic Mean RF 0. 1. 0, 1. 0, 0, 1, 0. 1, 1, 1. 1. 1. 1, 0, 0, 0. 1. 1. 1, 1, 0, 0, 0. 0. 0, 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0 0 1 0 1 1 0 0 0 0 996 309 294 089 117 841 095 725 593 384 118 234 251 393 621 918 581 143 035 301 056 614 y 454 294 575 176 225 140 388 256 273 857 323 127 237 583 sea^ 329 356 022 271 111 558 148 916 302 7.RSD 3, 5, 3. 3, 3. 6, 4. 1. 2, 3, 2. 3. 2. 7. 6, 5, 7. 4, 6, 3, 3. 4, 2, 5, 4. 7. 4. 11, 5, 3, 2. 2. 13. 2. 5. 3. 8. 2. 4 2 5 3 5 36 2 3 148 ^^20 300421 995 431 356 736 682 244 376 442 483»^ 217 070 203 729 >^ 431 844 114 700 025 216 454 334 267 405 843 624 408 v^ 263 892 192 599 ^ 181 632 890 817.^ 883 ^ 826 481 390 ly 938 705 698 013 944 016 235;^ 154 351 ^- -^ C560 &4N I TROPHENOL 0,066 0,086 0.083 0.092 0.091 0. 084 ^ 12 610 C565 DIBENZOFURAN O.B 1.351 1.41B 1.253 1.289 1.294 1,322 4 BBO C570 2, 4DINITR0T0LUENE O. 2 0. 336 0. 346 0. 368 0. 378 O. 366 0. 360 4 fe C543 2. 6D1NITR0TDLUENE 0. 2 O."S80 0. 298 0. 274 0. 294 0. 334 O. 296 7 92 C580 DIETHYL PHTHALATE 1.030 1.064 1.046 1.055 1.111 1.062 2! B59 C585 4CHL0R0PHENYL PHEN 0. 4 0. 511 0. 493 0. 513 0. 548 0. 532 0. 520 4. 05 C590 FLUORENE 0.9 1,100 1.075 1.041 1.169 1.096 1.097 4,296 C595 4-NITROANILINE 0,147 0,142 0.135 0,113 0,060 0.124 22.337 C610 4.6DINITR02METHYLPH 0.121 0.128 0.136 0.145 0.147 0.136 B. 074 C615 *D I PHENYL AM INE 0.424 0.386 0.360 0.408 0.382 0.393 6. 271*^ C625 4BR0M0PHENYL PHENY 0. 1 0. 190 0. 186 0. 175 0. 179 0. 181 0. 183 3. 199 C630 CL6BENZENE 0. 1 0. 165 0, 168 0, 187 0. 164 0, 178 0, 185 2, 014 C635 •PENTACHLOROPHENOL 0. 05 0, 108 0, 135 0. 131 0. 143 0. 146 0. 133 11,206^ C640 PHENANTHRENE 0,7 1,003 1,013 0,976 1,051 1,010 1.012 2,596 C645 ANTHRACENE 0, 7 1, 039 1, 037 1, 033 1, 065 0. 931 1, 021 5, 0 C650 DI-NBUTYLPHTHALATE 1,218 1.261 1.288 1.266 1,191 1.245 3.147 C655 •FLUORANTHENE 0.6 1.037 1,014 1.017 0.940 0.925 0.987 5.122'' D200 1.2-DIPHENYLHYDRAZINE 0.741 0,830 0.781 0. B39 0.869 0,813 6,225 C647 CARBAZOLE 0, 8440, 646 0, 510 0, 472 0. 482 0, 591 26. 643 C715 PYRENE 0,6 1,362 1,302 1,448 1,456 1,627 1.440 8,529 C720 BUTYLBENZYLPHTHALATE 0,680 0.657 0.737 0,750 0,746 0,714 5,953 C725 3, 3'CL2BENZIDINE 0.279 0.144 0.104 0,084 0.061 0.135 64,177 C730 BENZO(A)ANTHRACENE 0,8 1.154 1,056 1,087 1,101 1,133 1,107 3.472 C740 BIS(2ETHYLHEXYL)PHTH 0.933 0.933 0,978 1,019 1.026 0,978 4,597 C735 CHRYSENE 0.7 1.047 0,972 0,985 1,017 1,014 1,007 2,924 C760 •DI-N-DCTYLPHTHALATE . 1,441 1,369 1.561 1,672 1,732 1,555 9,788, C765 BENZO(B)FLUORANTHE 0,7 1,044 1,016 1,008 1,147 1,177 1,079 7.264 C770 BENZO(K)FLUORANTHE 0,7 0.931 0.777 0.897 0.965 0.974 0,909 8.767 C775 •BENZO(A)PYRENE 0.7 0,948 0.870 0,905 0,927 0.935 0.917 3. 334 w C780 INDEN0(1,2, 3CD)PYR 0,5 0,994 0,947 0.916 0.894 0.845 0.920 6.077 C785 DIBENZD(A, H)ANTHRA 0.4 0.770 0.710 0.697 0.693 0.695 0.713 4.571 .C790 BENZO(G, H, I )PERYLE 0. 5 0. 834 0. 776 0, 764 0, 724 0. 723 0, 765 5, J z y 300422 100.0 MASS SPECTRUM 02/08/95 10:21:00 + 8:16 SAMPLE: DFTPP 290-14-PERF COHDS.: RTX-5 0.25NM X SOM 1.0UM 45/4-325620 #495 TO #497 AUERAGED - #490 Xl.OO O LJJ ?^ IJJ OC DATA: BP020895J #496 CALI: BPe20895J #1 BASE M/Z: 198 RIC: 11200. IHST B 198 J2 CO 1 4 <> i > ^ 50.0- r 1866. r 1866. fl, • RIC 02/08/95 10:21:00 SAMPLE: DFTPP 290-14-PERF COHDS.: RTX-5 0.25MM X SOM RAHGE: G 1, 650 LABEL: H DATA: BP020895J #495 CALI: BP020395J #1 100.0-1 RIC I i' ol O' to l.OUM 0, 4.0 436 K 45/4-325620 QUAH: A IHST B 0, 1.0 J 0 SCAHS 480 TO 530 BASE: U 20, 3 16448. 484 •*§! 43: / ^^5^ 507 5-^ 514 516 ,30 8:00 490 8:10 500 8:20 -T 510 8:30 521 525 y\ 529 526 8:40 530 SCAN 8:50 TIME .• » i . i RIC+MASS CHROMATOGRAM 02/08/95 10:21:00 SAMPLE: DFTPP 290-14-PERF COHDS.: RTX-5 0.25MM X SOM RAHGE: G 1, 650 LABEL: H 100. On DATA: BP020895J #495 CALI: BPO20895J #1 l.OUM 45/4-325620 IHST B 0, 4.0 QUAH: A O, l.O J O 591 SCAHS 550 TO 650 BASE: U 20, 3 184 5144. 184.055 ± 0.500 182.3-1 RIC OS •:/s 5" Q. U- - 4 O' <: v a &> , 1 1 w OH O rfi. to Ol 9376. \ 554 ?5gr_564 563 560 9:20 575 579 583 \ ^12 go6 S10 615 I 5S0 9:40 600 10:00 622 —r=*- 620 10:20 651 yy 640 640 10:40 SCAH TIME #: »V' I i.taarm 1.1»V Data: BP020B95J « 496 Base m/z: 198 02/08/95 10:21:00 •«• 8:16 Cali: BP020B95J « 1 RIC: 11200. Sample: DFTPP 290-14-PERF Conds.: RTX-5 0.25MM X SOM l.OUM 45/4-325(520 INST B «495 to #497 averaged - #490 Xl.OO 39 479 Mass 39? 50? 51? 52? 57? 69 74 75 76 77 78 81 93 98 99 107 110 111 117 127 123 129 \ 141 ' 167 179 186 187 196 198 199 204 205 206 207 217 221 224 225 227 244 255 256 258 274 275 276 296 k 365 " 423 441 S S S s s s s s s s s s s s s s s s s s s s s s s s s s s s s s s s s s s s s s s s s s s s s s s s 0. 00 7. RA 2. 57 9. 16 33. 17 1.61 1.77 42. 50 2. 47 5, 04 1. 45 36.87 1. 71 1, 66 4, 13 3, 16 2, 84 10, 61 20, 63 3. 59 7, 34 45, 44 3, 80 15. 33 1, 34 4. 34 3. 48 10, 08 3, 22 3. 00 100. 00 6. 22 1. 45 4. 88 19. 67 1. 66 5. 95 8. 41 12. 33 2. 89 4. 02 9. 49 41. 75 5. 25 1, 34 2. 09 22. 99 2. 04 4. 23 1. 61 1. 66 3. 64 0, Inten. 46. 171. 619. 30. 33. 793. 46. 94. 27, 688, 32. 31. 77, 59, 53, 198. 385. 67. 137. 848. 71. 286. 25. 81. 65. IBS. 60. 56. 1866. 116. 27. 91. 367. 31. 111. 157. 230. 54. 75. 177. 779. 98. 25. 39. 429. 38. 79. 30. 31. 68. Minima Maxima Mass 442 443 479 Min Inten: 0 # 0 7. RA Inten S 44, 43 629 S 8.09 151 S 1,39 26 •9 300426 • Data Subject To vaudaeiofv Case Number: Inst ID: Lab ID: B BP020895J CC/MS Tuning and Mass Calibration DECAFLUOR DTRIPHENYLPHDSPHINE Laboratory: GULF Contract: Sens Date: 02/08/95 Sens Time: 10:21:00 Cali Date: 10/02/91 Analyst: JAM Data release authorized by: M/E Ion Abundance Criteria Spec # 495 51 30 to 607. of mass 198 33, 17 68 less than 27. of mass 69 0, 00 ( 0,00) 1 69 mass 69 relative abundance 42, 50 70 less than 27. of mass 69 0. 00 ( 0.00) 1 127 40 TO 607. of mass 198 45,44 197 less than 17. of mass 198 0,00 198 base peak, 100% relative abundance 100.00 199 5 TO 97. of mass 198 6.22 275 10 TO 307. of mass 198 22.99 365 greater than 17. of mass 198 1,61 441 less than mass 443 3.64 442 greater than 407. of mass 198 44.43 443 17 TO 237. of mass 442 8.09 (18.22) 2 1 - value in parenthesis is 7. of mass 69 2 - value in parenthesis is 7. of mass 442 300427 Data S m y y VaUdanon tn Z?i° n DATA FROM FILE: BS020395B SCANS 348 TO 1083 ACQUIRED: 02/03/95 11:24:00 CALI: BS020895B #1 SAMPLE: SSTD050 290-12-SU25 COHDS.: RTX-5 0.25HH X 30M l.OUM 45/4-325620 IHST B 400 _ 6:40 500 . 8:20 _L I CS50 2-FLUOROPHENnL 8.6 <SS-5) 100.0^ ( 59328.) amom CS45 D5-PHEH0L 0.8 (SS-4) 10:00 700 _ 11:40 800 13''>R 900 . 45:00' « j ' CO O* Ci < O 1000 . w; rfi. 16:40 lO I 00 n. 5' ^CAN -e-130 04-1,4 DICHLOROBENZENE (IS-1> CS75 1,2-CL2BENZENE-D4 0.4 (SS-8) ^Cv?0 D.5-NITR0BEHZEHE 0.2 (SS-1) CI40 D3-HAPHTHALENE (IS-2) CS25 2-FLUOROBIPHENYL 0.7 (SS-2) -OSQ. D10-ACEHAPHTHEHE (IS-3) CS55 2,4,6TRIBR0M0PHEH0L (SS-6) CI60 D10-PHEHAHTHREHE mm (IS-4) y: CS30 D14-P-TERPHENYL 8.5 (SS-3) • * ^ : . • »N 1 • DATA FROM FILE: BS020895B SCAHS 1033 TO 2100 ACQUIRED: 02/08/95 11:24:80 CALI: BS020895B #1 SAMPLE: SSTD050 290-12-SU25 COHDS.: RTX-5 0.25MM X SOM l.OUM 45/4-.325620 INST B 1 iff. (T O --r-i V • • < (5.- r\ - ( j J o o to vo r 1200 _ 20:00 1400 J 23:20 c i 26:40 30:00 2900 J 33:201 I I J 100.07. ( aBMMHP =nr7H=lTT7=CF!RTSENE 50048.) (IS-5) CI 75 D12-PERYLENE (IS-6) cm ifft^ • « K p W • W 0«9WifcW0 7«i/i7 Data: BS020695B. TI 02/06/95 11:24:00 Sample: SSTD050 290-12-SV25 Conds.: RTX-5 O. 25MM X SOM l.OUM 45/4-325^20 INST B Formula: X X X Instrument: B Weight: 1,000 iSubmitted by: Analyst: JAM Acct. No. : AMOUNT-AREA • REF AMNT/(REF AREA • RESP FACT) Resp. fac. from Library Entry No Name 1 CI30 D4-l,4 DICHLOROBENZENE (IS-1) 2 CI40 DS-NAPHTHALENE (IS-2) 3 CI50 DIO-ACENAPHTHENE (IS-3) 4 CI60 DIO-PHENANTHRENE (IS-4) 5 CI70 D12-CHRYSENE (IS-5) 6 CI75 D12-PERYLENE (IS-6) 7 CS50 2-FLUOROPHENOL 0.6 (SS-5) 8 CS45 D5-PHEN0L O.B (SS-4) 9 CS20 D5-NITR0BENZENE 0.2 (SS-1) 10 CS25 2-FLUOROBIPHENYL 0.7 (SS-2) 11 CS55 2.4.6TRIBR0M0PHEN0L (SS-6) 12 CS30 D14-P-TERPHENYL 0.5 (SS-3) 13 CS70 2-CHL0R0PHEN0L-D4 0.8 (SS-7) 14 CS75 1, 2-CL2BENZENE-D4 0.4 (SS-B) 15 C315 •PHENOL 0. 8 16 C325 BIS(2CHL0R0ETHYL)E 0.7 17 C330 2CHL0R0PHEN0L 0. 8 18 C335 1,3DICHLOROBENZENE 0.6 19 C340 •I, 4DICHLOROBENZENE 0. 5 T 20 C320 ANILINE 21 C310 N-NITROSODIMETHYLAMINE 22 C319 PYRIDINE T 23 C345 BENZYL ALCOHOL 24 C350 1,2DICHL0RDBENZENE 0. 4 25 C355 2METHYLPHEN0L 0. 7 T 26 C357 2, 2'OXYBISdCHLOROPR 27 C365 4METHYLPHEN0L 0. 6 T 28 C370 ?<NITROSOPR0PYLAMINE 0. 5 29 C375 HEXACHLOROETHANE 0. 3 T 30 C410 NITROBENZENE 0. 2 T 31 C415 ISOPHORONE 0.4 32 C420 •2-NITROPHENOL 0. 1 33 C425 2,4-DIMETHYLPHENDL 0. 2 34 C430 BENZOIC ACID 35 C435 BIB(2CHL0R0ETH0XY) 0.3 36 C440 •2, 4DI CHLOROPHENOL 0.2 37 C445 1,2, 4TRICHLOROBENZ 0.2 38 C450 NAPHTHALENE 0. 7 39 C455 4-CHLOROANILINE 40 C460 •CL6DUTADIENE T 41 C465 •4CHL0R03METHYLPHEN 0. 2 42 C470 2METHYLNAPHTHALENE O. 4 43 C510 ?<CL6CYCL0PENTADIENE 44 C515 •246TRICHLOROPHNEOL 0. 2 T 45 C520 2, 4, 5TRICHL0RDPHEN 0. 2 T 46 C525 2CHL0R0NAPHTHALENE 0.8 47 C530 2-NITRDANILINE 300430 n-r? Subiect To VaHddtiG No Name 48 C535 DIMETHYL PHTHALATE 49 C540 ACENAPHTHYLENE 1.3 50 C545 3-NITROANILINE No 1 2 3 4 5 6 7 B 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 1 III/2 152 136 164 IBB 240 264 112 99 62 172 330 244 132 152 94 93 128 146 146 93 74 79 108 146 108 45 108 70 117 77 82 139 107 122 93 162 180 128 127 225 107 142 237 196 196 162 65 163 152 138 Scan 463 602 761 B93 1149 1411 356 457 538 699 632 1035 466 501- 458. 462- 467 479* 484- 457- 179 178 500. 502- 512- 513 526. 526 530 540 561 569 573- 586, 581 591 598 604 613 618 654 665 684 693 • 698 ' 709 723 738 747 761 Time 6:03 10:02 12:41 14:53 19:09 23: 31 5:58 7:37 6:56 11:39 13:52 17: 15 7:46 6:21 7:38 7:42 7:47 7: 59 6:04 7:37 2: 59 2:58 8:20 6:22 8:32 8: 33 8: 46 8:46 8: 50 9:00 9:21 9:29 9:33 9:46 9:41 9: 51 9: 58 10:04 10: 13 10: 18 10: 54 11: 05 11:24 11: 33 11:38 11:49 12: 03 12: 18 12:27 12: 41 Ref 1 2 3 4 5 6 1 1 2 3 3 5 2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3 RRT 1.000 1.000 1.000 1.000 1.000 1. 000 0.741 0. 946 0. 894 0. 919 1. 093 0. 901 0. 965 1. 037 0. 948 0. 957 0. 967 0. 992 1. 002 0. 946 0. 371 0. 369 1. 035 1. 039 1. 060 1. 062 1. 089 1. 089 1. 097 0. 897 0, 932 0. 945 0. 952 0. 973 0. 965 0. 982 0. 993 1. 003 1. 018 1. 027 1. 086 1. 105 0. 899 0. 911 0. 917 0. 932 0. 950 0. 970 0. 982 1. 000 Meth A BB A BB A BB A BB A BB A BB A BD A BV A BB A BB A BB A BB A BB A BB A BD A VD A BD A BV A VD A BV A BB A BD A BD A BB A BD A DD A DD A BD A DD A DD A DD A DD A DD A DD A BD A DD A DD A DV A VD A DD A DD A DD A DD A BV A VD A DD A DB A DD A DB A DD Area(Hght> 9715. 33991. 20687, 27470, 24279, 21766, 11548. 16029, 11292. 26378. 3061. 24885, 14033, 9041. 17927. 16143. 13874. 15758. 17154. 13464. 7050. 9392. 8116. 15135. 11597. 13941. 12472. 6935. 5889. 11591. 22917. 7453. 8587. 4810. 15430. 11243. 13251. 37771. 6700. 6236. 8870. 24962. 1535. 7953. 8436. 23048. 4562. 26343. 34828. 413. Amount 20. 000 PPB 20. 000 PPB 20. 000 PPB 20. 000 PPB 20. 000 PPB 20. 000 PPB 25. 000 PPB 25. 000 PPB 25. 000 PPB 25. 000 PPB 25. 000 PPB 25. 000 PPB 25, 000 PPB 25, 000 PPB 25. 000 PPB 25, 000 PPB 25, 000 PPB 25, 000 PPB 25. 000 PPB 25. 000 PPB 25. 000 PPB 25. 000 PPB 25. 000 PPB 25. 000 PPB 25. 000 PPB 25. 000 PPB 25. 000 PPB 25. 000 PPB 25. 000 PPD 25. 000 PPD 25. 000 PPD 25. 000 PPD 25. 000 PPD 25. 000 PPD 25. 000 PPD 25.000 PPB 25. 000 PPD 25. 000 PPD 25. 000 PPB 25. 000 PPD 25. 000 PPD 25. 000 PPB 25. 000, PPB 25. 000 PPB 25. 000 PPB 25. 000 PPB 25. 000 PPB 25. 0"00 PPB 25. 000 PPD 25. 000 PPD 7.Tot 0. 0. 0. 0. 0, 0, 300431 95 95 95 95 95 95 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 , 19 . 19 . 19 , 19 . 19 . 19 . 19 . 19 ii.ii, ju-jjiiCt io Vftiidaiioji! No Ret(L) Ratio RRT(L) Ratio 1 2 3 4 5 6 7 6 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 6:03 10:02 12:41 14:53 19:09 23: 31 5:58 7:37 e: 56 11:39 13:52 17: 15 7:46 6:21 7:38 7:42 7:47 7:59 6:04 7:37 2: 59 2: 58 6:20 8:22 8:32 8: 33 8: 46 8:46 8: 50 9: 00 9:21 9:29 9: 33 9:46 9: 41 9: 51 9: 58 10:04 10: 13 10: 18 10: 54 11:05 11:24 11: 33 11: 38 11:49 12:03 12: 18 12:27 12: 41 1.00 1. 00 1.00 1.00 1. 00 1. 00 1. 00 1. 00 1. 00 1, 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1, 00 1, 00 1, 00 1, 00 1. 00 1, 00 1. 00 1, 00 1, 00 1, 00 1, 00 1, 00 1, 00 1, 00 00 00 1, 00 00 00 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 1. 1. 1. 1. 1. 000 000 000 000 000 000 O, 741 0.946 O. 894 0, 919 1. 093 O. 901 0. 965 1. 037 O. 948 0. 957 0. 967 0. 992 1. 002 O, 946 0. 371 0. 369 1. 035 1, 039 1. 060 l: 062 1, 089 1, 089 1, 097 0. 897 O. 932 0. 945 0. 952 O. 973 965 982 0. 993 1. 003 018 027 086 105 899 911 917 0. 932 O. 950 O. 970 0. 982 1. 000 O. 0. 1. 1. 1. 1. 0. 0. 0. 00 00 00 00 00 00 00 00 00 1, 00 1.00 1. 00 1.00 1. 00 1. 00 1, 00 1. 00 1.00 1. 00 1. 00 1. 00 1, 00 1, 00 1, 00 1, 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 00 00 1. 00 00 00 1. 00 1. 00 1. 00 1. 00 Amnt 20,00 20.00 20. 00 20. 00 20.00 20. 00 25, 00 25, 00 25, 00 25, 00 25, 00 25, 00 25,00 25, 00 25. 00 25. 00 25, 00 25. 00 25. 00 25. 00 25. 00 25, 00 25, 00 25. 00 25. 00 25. 00 00 00 Amnt(L) R.Fac R, Fac(L) Ratio 25. 25. 25. 00 !5. >5. 00 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 00 00 00 00 25. 00 25. 00 25. 00 25. 00 25. 00 25 25 25 25 20. 00 20. 00 20. 00 20. 00 20.00 20.00 25. 00 25. 00 25, 00 25. 00 25. 00 25.00 25.00 25. 00 25, 00 25, 00 25, 00 25, 00 25, 00 25, 00 25, 00 25, 00 25, 00 25, 00 25, 00 25, 00 25, 00 25, 00 25, 00 25, 00 25, 00 25. 00 25. 00 25, 00 25. 00 25, 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00" 25. 00 25. 00 25. 00 25. 00 25. 00 1. 1, 0, 0, o, 1, 1.000 1. 000 1.000 1.000 1. 000 1. 000 0, 951 1.320 0. 266 1. 020 0. 118 0, 820 1, 156 0, 744 1, 476 1, 329 1, 142 1. 298 413 109 581 773 668 246 0. 955 1. 148 1, 027 0, 571 0. 485 0. 273 0. 539 0, 175 0, 202 0. 113 0. 363 0. 265 0. 312 0. 889 0. 158 0. 147 0. 209 0. 587 0. 059 0. 308 0. 326 0. 891 0. 176 1. 019 1. 347 0. 016 1. 000 1. 000 1.000 1. 000 1. 000 1.000 0.951 1.320 0.266 1. 020 0. 118 0. 620 1. 156 0. 744 1. 476 1, 329 1, 142 1, 298 1, 413 1. 109 0. 581 0. 773 0. 668 • 1, 246 0. 955 1. 148 1. 027 0. 571 0. 485 0. 273 0. 539 0. 175 0. 202 0. 113 0. 363 0. 265 0. 312 0. 889 0. 158 0. 147 0. 209 0. 587 0. 059 0. 308 0. 326 0. 891 0. 176 , 1. Ol 9 1. 347 0. 016 1. 00 1, 00 1, 00 1. 00 1, 00 1. 00 1, 00 1. 00 00 00 00 00 00 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 00 00 00 00 00 00 1. 00 00 00 00 00 00 00 00 00 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 300432 Daia Subjea lb V^-lidatiorii uuantttation Report File: BS020695B # Data: BS020695B. TI 02/06/95 11:24:00 Sample: SSTD050 290-12-SV25 Conds.: RTX-5 0.25MM X 30M l.OUM 45/4-325«20 Formula: X X X Instrument: B ubmitted by: Analyst: JAM INST B Weight: Acct. No. 1. 000 AMOUNT-AREA • REF AMNT/(REF AREA • RESP FACT) Resp. fac. from Library Entry # No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 170 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 No 51 52 53 54 55 56 ^^^ ISB Name C550 C321 C555 C560 C565 C570 C543 C580 C585 C590 C595 C610 C615 C625 C630 C635 C640 C645 C650 C655 D200 C647 C715 C720 C725 C730 C740 C735 C760 C765 C770 C775 C780 C785 C790 m/2 153 232 184 109 168 165 165 149 •ACENAPHTHENE 0. 8 2,3,4,6-TETRACHLOROPHENOL &2,4DINITROPHENOL &4NITROPHENOL DIBENZOFURAN 2,4DINITR0T0LUENE 2,6DINITR0T0LUENE DIETHYL PHTHALATE 4CHL0R0PHENYL PHEN FLUORENE 4-NITROANILINE 0. 8 0.2 0. 2 0. 4 0. 9 4,6DINITR02METHYLPH •DIPHENYLAMINE 4BR0M0PHENYL PHENY CL6BENZENE •PENTACHLOROPHENOL PHENANTHRENE ANTHRACENE DI-NBUTYLPHTHALATE •FLUORANTHENE 0. 1 0. 1 0. 05 0. 7 0.7 0. 6 1,2-DIPHENYLHYDRAZINE CARBAZOLE PYRENE 0. 6 BUTYLBENZYLPHTHALATE 3,3'CL2BENZIDINE BENZO(A)ANTHRACENE 0. B BIS(2ETHYLHEXYL)PHTH CHRYSENE 0. 7 •DI-N-OCTYLPHTHALATE BENZO(B)FLUORANTHE BENZO(K)FLUORANTHE •BENZO(A)PYRENE INDENOd, 2. 3CD)PYR DIDENZO(A. H)ANTHRA BENZO(G.H. DPERYLE Scan Time Ref 764 12:44 3 1. 793 13: 13 3 1. 768 12:48 3 1. 775 12:55 3 1. 778 12:58 3 1. 781 13:01 3 1. 746 12:26 3 0. BOO 13:20 3 1. 0. 7 0. 7 0.7 0. 5 0. 4 : 0. 5 RRT 004 042 009 018 022 026 980 051 T T T Meth A A A A A A A A DB DD DD DB DD DD DD DD Area(Hght) 21489. 8026. 2423. 1704. 33046. 8310. 6876. 23687. Amount' 25. 25. 25. 25. 25. 25. 25. 25. 000 000 000 000 000 000 000 000 . PPD PPD PPD PPD PPD PPD PPD PPD 7.Tot 1. 1. 1. 1. 1. 1. 1. 1. 19 19 19 19 19 19 19 19 300433 '••,'>i-.iri I r \yZ<iz-'fK No 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 No 51 52 53 54 55 56 57 53 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 m/2 204 166 138 196 169 246 264 266 176 176 149 202 77 167 202 149 252 228 149 228 149 252 252 252 276 278 276 Scan Time R B07 13 e09 13 eie 13 eie 13 616 13 650 14 665 14 681 14 695- 14 699. 14 943 15 1003- 16 621 13 914 15 1025- 17 1081 18 1143 19 1147. 19 3 1142 19 1153 19 J 1232 20 1325 22 1329 22 1397- 23 1740- 29 1745 29 1843 30 Ret(L) Ratio 12: 13: 12: 12: 12: 13: 12: 13: 13: 13: 13: 13: 13: 14: 14; 14: 14: 14: 15: 16: 13: 15: 17: 18; 19: 19: 19; 44 13 48 55 58 01 26 20 27 29 38 38 38 10 25 41 55 59 43 43 41 14 05 01 03 07 02 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1, 00 1, 00 1. 00 1. 00 1. 00 1. 00 1. 00 1, 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 :27 :29 :38 :36 :36 : 10 :25 :41 :55 :59 :43 :43 :41 : 14 :05 :01 :03 :07 :02 : 13 :32 ;05 :09 : 17 :00 :05 ;43 ef 3 3 3 4 4 4 4 4 4 4 4 4 4 4 5 5 5 5 5 5 6 6 6 6 6 6 6 RRT(L) Ri 1, 004 1. 042 1. 009 1. 018 1. 022 1. 026 0. 980 1. 051 1. 060 1. 063 1. 075 0. 916 0. 916 0. 952 0. 969 0. 987 1, 002 1, 007 1. 056 1. 123 0. 919 1. 024 0. 892 0. 941 0. 995 0. 998 0. 994 RRT 1.060 1.063 1.075 0.916 0.916 0.952 0.969 0.987 1. 002 1. 007 1. 056 1. 123 0. 919 1.024 0. 892 0, 941 0, 995 0.998 0. 994 1.003 0. 873 0. 939 0. 942 0. 990 1, 233 1, 237 1. 306 atio 00 00 , 00 , 00 00 00 00 00 00 , 00 00 00 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . QO . 00 . 00 . 00 Meth A BB A BB A BB A BB' A BB A BB A BB A BB A BV A VB A BB A BB A BB A BB A BB A BB A BB A BV A BB A VB A BB A BV A VB A BD A BD A DD A DD Amnt 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. oa 25. 00 25. 00 Area(Hght) 13104, 25696, 1463. 4235, 9676. 7132. 7579. 3960. 34059. 34251. 47503. 39279, 25116, 7BS1, 43158. 20631. 5211, 33352. 29110, 30488, 44053, 29609, . 24792. 24934. 24304. 19579. 21086. Amnt(L) 1 25. 00 25. 00 25. 00 25. 00 25, 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25, 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 •^$<l>zHir^ 1 Amount 25, 000 25. 000 25, 000 25, 000 25, 000 25. 000 25. 000 25. 000 25, 000 25, 000 25, 000 25, 000 25, 000 25. 000 25. 000 25, 000 25, 000 25, 000 25. 000 25, 000 25. 000 25. 000 25, 000 25. 000 25. 000 25. 000 25. 000 PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB • PPB PPB PPB PPB R. Fee R. Fac(L) 0. 831 0. 310 0, 094 0. 066 1,278 0.321 0. 266 0, 916 0. 507 0. 994 0.057 0. 123 0. 288 0. 208 0. 221 0. 115 0. 992 0. 997 1,383 1. 144 0.731 0. 230 1.422 0. 680 0. 172 - 1. 099 0. 959 0. 831 0, 310 0. 094 0. 066 1, 278 0. 321 0. 266 0. 916 0. 507 0. 994 0.057 0. 123 0. 288 0. 208 0. 221 0. 115 0. 992 0. 997 ,1, 383 1. 144 0.731 0. 230 1. 422 0. 680 0. 172 1. 099 0. 959 7.Tot 1, 19 1, 19 1.19 1. 19 1. 19 1, 19 1, 19 1, 19 1, 19 1, 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1, 19 1. 19 1, 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 1.00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 300434 Data z'Z-zed:7b ^/sii'datfof!) No R e t ( L ) R a t i o RRT(L} R a t i o Amnt Amnt(L) R.Fac R.Fac(L) Ratio 78 1 9 : 1 3 1.00 1.003 1.00 2 5 , 0 0 2 5 , 0 0 1,005 1,005 1,00 79 20:32 1.00 0 , 6 7 3 1.00 2 5 , 0 0 2 5 . 0 0 1.619 1.619 1,00 60 2 2 : 0 5 1.00 0.939 1.00 25.00 2 5 . 0 0 1.068 1.068 1,00 81 22:09 1,00 0.942 1,00 2 5 , 0 0 2 5 , 0 0 0 , 9 1 1 0.911 1,00 62 2 3 : 1 7 1.00 0.990 1.00 25.00 2 5 . 0 0 0 . 9 1 6 0 . 9 1 6 1,00 83 2 9 : 0 0 1.00 1.233 1,00 2 5 , 0 0 2 5 . 0 0 0 . 6 9 3 0.893 1,00 84 2 9 : 0 5 1.00 1.237 1.00 25.00 2 5 , 0 0 0.720 0.720 1.00 65 3 0 : 4 3 1.00 1.306 1.00 25,00 2 5 . 0 0 0,775 0.775 1,00 300435 Jata S;.;h;ec! To N/aHd-'iKu caiioratlon Check Instrument Identifier: B Calibration Date: 11/09/94 Standard File: BS020695B Date: 02/06/95 Time: 11:24:00 MIN RF: BW(8«) « - O ^ ^ CLP tMAX y.D: 8W(^} 307.' CLP # CS50 CS45 CS20 CS25 CS55 CS30 CS70 CS75 C315 C325 C330 C335 C340 C320 C310 C319 C345 C350 C355 C357 C365 iC370 C375 C410 C415 C420 C425 C430 C435 C440 C445 C450 C455 C460 C465 C470 C510 C515 C520 C525 C530 C535 C540 C545 C550 C321 555 0, 6 0, 6 0, 2 0,7 Compound 2-FLUORDPHENOL D5-PHEN0L D5-NITR0BENZENE 2-FLUOROBIPHENYL 2.4,6TRIBROMOPHENOL D14-P-TERPHENYL 0, 5 2-CHL0R0PHEN0L-D4 0. 6 1,2-CL2BENZENE-D4 0.4 •PHENOL 0. 8 BIS(2CHLDR0ETHYL)E 0.7 2CHL0R0PHENDL 0. B 1.3DICHLOROBENZENE 0. 6 • 1,4DICHL0R0BENZENE 0.5 ANILINE N-NITROSODIMETHYLAMINE PYRIDINE BENZYL ALCOHOL 1.2DICHLOROBENZENE 0. 4 2METHYLPHEN0L 0. 7 2. 2'OXYBISdCHLOROPR 4METHYLPHEN0L 0. 6 8<NITRDSDPRDPYLAMINE 0. 5 0. 3 0. 2 0. 4 0. 1 O. 0. 0. 0. HEXACHLOROETHANE NITROBENZENE ISOPHORONE •2-NITROPHENOL 2.4-DIMETHYLPHENOL 0. 2 BENZOIC ACID BIS(2CHL0R0ETH0XY) •2,4DICHL0R0PHENDL 1,2, 4TRICHLOROBENZ NAPHTHALENE 4-CHLOROANILINE •CL6BUTADIENE •4CHL0R03METHYLPHEN 0. 2 2METHYLNAPHTHALENE &CL6CYCL0PENTADIENE •246TRICHLOROPHNEOL 2,4, 5TRICHL0R0PHEN 2CHL0R0NAPHTHALENE 2-NITROANILINE DIMETHYL PHTHALATE ACENAPHTHYLENE 3-NITRDANILINE •ACENAPHTHENE 2,3,A,6-TETRACHLOROPHE S<2, 4D1NITR0PHEN0L 0. 4 0. 0. 0. 1. 3 0. 8 .01 DR BELOW 257. Mean RF(I) RF(0) 1. 1. 1. 0, 0. 0. 1. 1, 0, 996 1. 309 0, 294 1. 089 O. 117 0. 841 1. 095 0. 725 1. 593 1,384 1, lis 234 251 393 621 91B 581 143 035 1, 301 1, 056 0. 614 0. 454 0. 294 0. 575 0. 176 0. 225 0. 140 0. 388 0. 256 0. 273 0. 857 O. 323 0. 127 O. 237 0. 583 0. 286 0. 329 0. 356 1. 022 0. 271 1. Ill 1. 558 0. 148 0. 916 0. 302 O. 148 0. 1. 0, 1, 0, 0, 1, 0, 1. 1. 1. 1, 1, 1, 0, 0. 0. 1. 0. 1. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1 1 0 0 0 0 951 320 266 021 119 820 156 745 477 330 143 298 413 109 581 774 669 247 955 148 028 572 485 273 540 176 203 114 364 265 312 889 158 147 209 588 060 . 308 . 327 . 892 . 177 . 019 . 347 016 832 . 311 094 y / 7. D 4, 516 0. B57 9, 541 6, 253 1. 182 2.499 5, 584 2. 827 7. 288 y 3. 936" 2. 244 5, 175 y 12. 999>^ 20. 345 6, 438 15, 698 15. 130 9. 122 7, 645 11. 719 2. 657 6. 962 6. 978 7. 179 6. 153 O. 071 9. 922 18. 788 6. 286 3. 392 y 14. 461 3. 837 51. 044 16.002 y 11.646 y 0. 848 79. 054 6. 431*^ 8. 295 12. 700 34. 727 8. 274 13. 498 88. 884 . 9. 263 ^ 2. 976 36. 201 300436 Data Sijbiect To Validation; y C565 DIBENZOFURAN 0.8 1.322 C570 2,4DINITR0T0LUENE 0.2 0.360 C543 2, 6DINITRDT0LUENE O. 2 O. 296 C560 DIETHYLPHTHALATE 1.062 C5B5 4CHL0R0PHENyL PHEN O, 4 0. 520 C590 FLUORENE 0.9 1.097 595 4-NITROANILlNE 0. 124 C610 4,6DINITR02METHYLPH 0.136 C615 •DIPHENYLAMINE 0.393 C625 4BR0M0PHENYL PHENY 0. 1 0. 163 C630 CL6BENZENE 0. 1 0. 165 C635 •PENTACHLOROPHENOL 0. 05 0. 133 C640 PHENANTHRENE 0.7 1.012 C645 ANTHRACENE 0.7 1.021 C650 DI-NBUTYLPHTHALATE 1.245 C655 •FLUORANTHENE 0, 6 O, 987 D200 1,2-DIPHENYLHYDRAZINE 0,813 C647 CARBAZOLE 0, 591 C715 PYRENE 0.6 1.440 C720 BUTYLBENZYLPHTHALATE 0. 714 C725 3, 3'CL2BENZIDINE 0.135 C730 BENZO(A)ANTHRACENE 0, 8 1,107 C740 BIS(2ETHYLHEXYL)PHTH 0. 978 C735 CHRYSENE 0.7 1,007 C760 •DI-N-OCTYLPHTHALATE 1, 555 C765 BENZD(B)FLUORANTHE 0. 7 1.079 C770 BENZO(K)FLUORANTHE 0. 7 0.909 C775 •BENZO(A)PYRENE 0.7 0.917 C780 INDEND(1,2, 3CD)PYR 0.5 0.920 C785 DIBENZO(A, H)ANTHRA 0.4 0.713 C790 BENZO<G, H, DPERYLE 0. 5 0.765 0. 0. 0, 0, 1. V. 066 ' 1.278 0. 322 0.266 0.917 0. 507 O. 994 0. 058 0. 124 0. 2B8 0. 208 221 116 992 998 384 1. 144 0,732 0, 230 1, 423 0, 680 0, 172 099 960 005 620 089 912 917 894 720 776 1, 0. 1. 1, 1, 0. 0. 0. o. 0. . y i:u. 7B/ 3.272 10. 490 10. 096 13.661 2.448 9. 376 53. 291 6, 922 26, 605 14. 066 19. 563 12.695'^ 1.913 2,287 11, 116 15. 9 4 5 ^ 9, 931 61, 097 187 765 709 657 1, 699 0. 227 131 '^ 914 263 054 y 818 948 409 1, 4, 27. 0, 4, 0. 0, 0. 2. 0. 1. y^'' i{» T* 300437 ; 1 ',i^fj-*..» •-':• •- DATA FROM FILE: SU12098UB2 SCANS 346 TO 1081 ACQUIRED: 82/08/95 12:06:00 CALI: SU12093WB2 #1 SAMPLE: SBLKW WATER-12098HB2 COHDS.: RTX-5 0.25MM X SOM l.OUM 45/4-325620 IHST B J ' l U (b!:-b> ' 100-0^ < 400 _ 6:40 500 600 . 10:00 '.J -ffi Ui r,, o 700 11:40 800 13:20 900 . 15:00 / ^ 16:40 CD ' - I ; ri U'-.bU 2-hLUUKUHHtHUL 57856.) CS45 D5-PHEH0L 0.8 <SS-4) CI30 D4-l,4 DICHLOROBENHENE (IS-1) CS75 1,2-CL2BENZENE-D4 0.4 (SS-3) CS20 D5-HITR0BEHZEHE 0.2 (SS-I) CI40 DS-NAPHTHALEHE (IS-2) CS25 2-FLUOROBIPHEWL 0.7 (SS-2) CI50 D10-ACEHAPHTHEf€ (IS-3) ->;C55 2.. 4.. 6TRIBR0M0PHEH0L (SS-6) CI60 D10-PHEHAHTHREHE (IS-4) CS30 DI4-P-TERPHENYL 0.5 (S^-3) to -^> ^ p i • f I , • DATA FROH FILE: SU12098WB2 SCANS 1081 TO 2200 ACQUIRED: 02/08/95 12:86:88 CALI: SU12093UB2 #1 SAMPLE: SBLKW WATER-12098HB2 CONDS.: RTX-5 0.25MH X SOM l.OUM 45/4-325628 IHST B :t) •a 3* :x, "5° Ui O o U) vo 1200 _ 20:00 1400 _ 23:20 1600 . 26:40 1300 _ :-:0:0n 2000 _ T l i k -J \ ± 27584.) •J 100. o:; ( CI70 D12-CHRYSEHE (IS-5) CI75 D12-PERYLEHE (IS-6) t t . ( Quantitation Report File: SV12098WB2 Data: SV12096WB2, TI 02/06/95 12: 06:00 Sample: SBLKW WATER-12096WB2 Conds.: RTX-5 0. 25MM X SOM l.OUM 45/4-325^20 Formula: X X X Instrument: B Submitted by: Analyst: JAM INST B Weight: Acct. No. : 1, 000 12098 AMOUNT-AREA • REF AMNT/(REF AREA • RESP FACT) Resp. fac. from Library Entry No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 No 1 2 3 4 5 6 7 B 9 Name CI30 CI40 CI50 CI60 CI70 CI75 CS50 CS45 CS20 CS25 CS55 CS30 CS70 CS75 C740 m/2 ! 152 136 164 188 240 264 112 99 82 172 330 244 132 152 149 D4-l,4 DICHLOROBENZENE DB-NAPHTHALENE DIO-ACENAPHTHENE DIO-PHENANTHRENE D12-CHRYSENE D12-PERYLENE 2-FLUOROPHENDL D5-PHEN0L D5-NITR0BENZENE 2-FLUOROBIPHENYL 0. 6 0. 8 0. 2 0. 7 2, 4, 6TRIBR0M0PHEN0L D14-P-TERPHENYL 0. 5 2-CHLDRDPHEN0L-D4 0. 8 1,2-CL2BENZENE-D4 0. 4 BIS(2ETHYLHE X YL)P HTH 3can Time Ref 481 8:01 601 10:01 760 12:40 892 14: 52 1148 19:08 1410 23:30 351 5: 51 453 7:33 537 8;57 698 11:38 831 13:51 1035 17:15 463 7:43 499 8: 19 1141 19:01 Ret(L) Ratio RRT(L; 8:03 10:02 12:41 14: 53 19: 09 23:31 5: 58 7; 37 8; 58 1. 00 1. 000 1.00 1.000 1.00 1.000 1.00 1.000 1.00 1.000 1. 00 1. 000 0.98 0.741 0. 99 0. 946 1. 00 0. 894 1 2 3 4 5 6 1 1 2 3 3 5 1 1 5 RRT 1. 000 1. 000 1. 000 1, 000 1, 000 1. 000 0. 730 0. 942 0. 894 0. 918 1. 093 0. 902 0. 963 1. 037 0. 994 1 Ratio 0. 00 00 00 00 00 00 98 00 00 (IS-1) (IS-2) (IS-3) (IS-4) (IS-5) (IS-6) (SS-5) (SS-4) (SS-1) (SS-2) (SS-6) (SS-3) (SS-7) (SS-8) Meth A DB A DD A BB A BD A DB A DD A DD A DD A DB A DB A DD A DD A DD A DD A DB Amnt 20. 00 20. 00 20. 00 20. 00 20. 00 20. 00 49. 62 55, 30, 37. 70 Area(Hght) 7994. 29932. 19243. 25386. 20434. 20836. 18861. 29176. 14996. 28764. 5875. 37113. 25181. 7916. 6721. Amnt(L) 20. 00 20. 00 20. 00 20. 00 20. 00 20. 00 25. 00 25. 00 25. 00 Amount 20. 20. 20. 20. 20. 20. 49. 55. 37. 29. 51. 44. 54. 26. 6. R. Fac 2 0 000 000 000 000 000 000 623 302 703 307 583 300 518 602 858 PPD PPB PPB PPB PPB PPD PPD PPD PPD PPB PPD PPD PPD PPD PPD R. Fac(L) 000 000 , 000 000 . 000 . 000 . 888 . 92< D . 401 ' 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 0. 951 1. 320 0. 266 7.Tot 4. 4. 4. 4. 4. 4. 10. 11. 7. 6. 10. 9. 11. 5. 1. 20 20 20 20 20 20 43 62 92 16 84 31 46 59 44 Ratio 1. 1. 1. 1. 1. 1. 1. 1. 00 00 00 00 00 00 98 21 51 300440 No 10 11 12 13 14 15 Ret(L) Ratio RRT(L) Ratio 11:39 1.00 0.919 1.00 13:52 17: 15 7:46 6:21 19:02 1. 00 1.00 0.99 1. 00 1. 00 1.093 O. 901 0.965 1.037 0, 994 1.00 1.00 1. 00 1.00 1. 00 Amnt Amnt(L) R.Fac R, Fac(L) Ratio 29.31 25.00 1.196 1.020 1.17 51.56 25,00 0,244 0.118 2,06 44.30 25.00 1.453 0.620 1.77 54. 52 25, 00 2, 520 1. 156 2. 18 26.60 25.00 0.792 0.744 1.06 6. 66 25. 00 0, 263 0. 959 0, 27 300441 y.B Subied; To "/sfidatlon 100.0- 50.0- 81.51 40.7- U TARGET COMPOUHD COMPARISOH COMPOUHO: C740 BIS(2ETHYLHEXYL)PHTH RAW DATA: SU1209SWB2 #1141 02/08/95 12:06 SAMPLE: SBLKW WATER-12098WB2 COHDS.: RTX-5 0.25MM X SOM l.OUM 45/4-325620 BASE M/Z: 149 IHST B RIC: 9856. •'• , ••!. ••!' T " - ^ J JL T—' T '' I "'—I—'—r"'—T""'—I—'—r""—r EHHAHCED DATA: SU12093WB2 #1141 r 3216. T — " ^ T — ' — I — ' — T — ' — j — r — j — I — I BASE M/Z: 149 RIC: T—1—r 7624. r---T 4 T—i 1—r- T^—r-'—I ' 1 2620. I ' » — ' 1 ' — I • r ' — I ' I — ' — I '• I • ' — r ~ " ^ — I — ' — I — ' • — ^ 31.ll 15.5- LIBRARY FILE: SN #56 T — ' — I ' l ' — I ' l ' — I ' l ' — r M/Z 50 100 C 100.01 e-l ^ 50.0-d BASE M/Z: 149 RIC: 1586. r 1000. 0.0- a g -50.0d §" -100.0-' o IT Ui o o »t^ t o - I 1 1 1 r—I'-I—I r*.-| 1—I r — , — , 1 — , , — i — , — i 1 — r — , — i 1—i y 1 1 1—*,—i- 150 200 250 DATA FROM FILE: SUUSROl SCANS 346 TO 1081 ACQUIRED: 82/03/95 14:15:00 CALI: SUUSROl #1 SAMPLE: RBSO/012495 WATER HLA COMOS.: RTX-5 0.25MM K 30M l.OUM 45.''4-325620 IHST B r 400 6:40 500 . 8:20 600 . 10:00 700 11:40 300 4 13:20 C p.) f. 15:00" 75' tr; < 1000 _] &. 16:40 §' 5CHU HF J=r Cb50 2 - F L U U R U P M E H O L ' O . K ( 5 5 - ^ ^ ^ - ^^ < ^3200.) o o >ti j:.S45 D5-PHEH0L 0.3 (SS-4) C130 04-1.. 4 DI CHLOROBENZENE < IS-1) CS75 1..2-CL2BEHZEHE-04 0.4 ':SS-3> CS20 D5-HITR0BEHZEHE 0.2 <SS-1> CI40 DS-NAPHTHALENE (IS-2) CS25 2-FUJnROBIPHEHYL 0.7 (SS-2) C150 010-ACEHAPHTHENE (IS-3 > .feg,55 2 .• 4.. 6TRI BROMOPHENOL (SS-6 > — CI60 DIO-PHENANTHRENE (IS-4) esse D14-P-TERPHENYL 0.5 <SS-3) DATA FROM FILE: SUUSROl SCANS 1031 TO 2100 ACQUIRED: 02/03/95 14:15:00 CALI: SUUSROl #1 SAMPLE: RBSO/012495 WATER HLA CONDS.: RTX-5 0.25MM X 30M l.OUM 45/4-325620 IHST B 1200 _ 20:00 I I J 100.0," ( 39872.) CI70 D12-CHRYSEHE (IS-5) a r-i- fa tn cz -iP" d' SL al 1400 . 23:20 ,' 1600 _ I 26:40 1300 . 130:00 Ui o o '335 29 m \ CI75 012-PERYLENE (IS-6) Quantitation Report File: SVVSROl Date; SVVSROl. TI 02/08/95 14: 15: 00 Sample: RBSD/012495 WATER Conds.: RTX-5 0. 25MM X SOM ^Formula: X X X Submitted by: l.OUM 45/4-325620 Instrument: B Analyst: JAM INST B Weight: Acct, No. : 1. 000 12098 AM0UNT=AREA • REF AMNT/(REF AREA « RESP FACT) Resp. fac, from Library Entry No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 No 1 2 3 4 5 6 7 S 9 10 n Name CI30 CI40 CI50 CI60 CI70 CI75 CS50 CS45 CS20 CS25 CS55 CS30 CS70 CS75 D4-l,4 DICHLOROBENZENE DB-NAPHTHALENE D10-ACENAPHTHENE DIO-PHENANTHRENE D12-CHRYSENE D12-PERYLENE 2-FLUOROPHENDL D5-PHENDL D5-NITRDBENZENE 0. 6 0. 8 0. 2 2-FLUORODIPHENYL 0. 7 2,4;6TRIBROMOPHENOL D14-P-TERPHENYL 0. 5 2-CHLDRDPHEN0L-D4 0. 8 1,2-CL2DENZENE-D4 0.4 m/z Scan Time Ref 152 136 164 188 240 264 112 99 82 172 330 244 132 152 481 8:01 1 600 10:00 2 760 12:40 3 892 14;52 4 1150 19; 10 5 1412 23:32 6 353 5;53 1 455 7:35 1 537 8: 57 2 698 11:38 3 831 13: 51 3 1035 17; 15 5 464 7:44 1 499 8: 19 1 RRT 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 0. 734 0. 946 0. 895 0. 918 1. 093 0. 900 0. 965 1. 037 Ret(L) Ratio RRT(L) Ratio 8; 03 10: 02 12:41 14: 53 19: 09 23: 31 5; 58 7; 37 8; 58 11; 39 13: 52 1.00 1.000 1. 1.00 1.000 1. 1.00 1.000 1. 1.00 1.000 1. 1. 00 1. 000 1. 1.00 1.000 1. 0. 99 0. 741 0. 1.00 0.946 1. 1.00 0.894 1. 1. 00 0. 919 1. 1. 00 1. 093 1. 00 00 00 00 00 00 99 00 00 00 00 (IS-1) (IS-2) (IS-3) (IS-4) (IS-5) d S - 6 ) (SS-5) (SS-4) (SS-1) (SS-2) (SS-6) (SS-3) (SS-7) (SS-B) Meth A DB A BD A DD A BD A DB A DD A DB A DV A BB A DB A DD A DB A DB A DD Amnt 20. 00 20. 00 20. 00 20. 00 20. 00 20. 00 55. 98 62. 02 42. 25 30. B T 56. 67 Area(Hght) 10996. 42655. 28874. 40709. 30766. 24404. 29269. 45010. 23947. 45367. 9685. 58531. 38401. 11851. Amnt<L) 20. 00 20. 00 20. 00 20. 00 20. 00 20. 00 25. 00 25. 00 25. 00 25. 00 25. 00 R. 1 2, 3, 0 1, 0 Amount 20. 000 20. 000 20. 000 20. 000 20. 000 20. 000 55. 982 62. 023 42. 249 30. 806 56. 672 46. 403 60. 442 28. 953 -ac R.F 000 , 000 , 000 . 000 , 000 . 000 , 129 . 275 , 449 , 257 , 268 PPD PPD PPD PPD PPB PPD PPB PPD PPB PPB PPB PPB PPB PPD ac(L) 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 0. 951 1. 320 0. 266 1. 020 0. 118 7.Tot 3. 3. 3. 3. 3. 3. 11. 12. e. 6. 11. 9. 12. 5. Rat: 1. 1. 1. 1. 1. 1. 2. c l . 1. 1. 2. 97 97 97 97 97 97 12 32 39 12 25 22 00 75 io 00 00 00 00 00 00 24 45 69 23 27 300445 D: No 12 13 14 Ret(L) 17: 15 7-46 B:21 Ratio 1,00 1. 00 1, 00 RRT(L) 0,901 0, 965 1, 037 Ratio 1,00 1. 00 1. 00 Amnt 46, 40 60, 44 28. 95 Amnt(L) 25,00 25, 00 25, 00 R, Fac R 1, 522 2. 794 0. 862 Fac(L) R a t i o 0.820 1.86 1. 156 2. 42 O, 744 1. 16 300446 c o; p.' t/) C £ rc p. —1 o' t cu P4. o w o o l { ^ i t i -VJ DATA FROM FILE: SU12153WB1 SCANS 347 TO 1082 ACQUIRED: 82/88/95 17:31:09 CALI: SU12158WB1 #1 SAMPLE: SBLKW WATER-12158WB1 CONDS.: RTX-5 0.25MM X SOM 1.0UM 45/4-325620 INST B 400 _ 6:40 500 . 8."'0 10:00 700 . 11:40 800 . 13:20 900 . 15:00 1090 _ 1S: 40 S m I CS50 2-FLUOROPHEHOL 0.6 (SS-5) 100.0^ ( 55104.) 1 5 ^ D5-PHEN0L 0.8 (SS-4> CI30 D4-l,4 DICHLOROBEHZEHE (IS-1) CS75 1,2-CL2BEHZEHE-D4 0.4 (SS-8) CS20 D5-NITROBENZENE 0.2 (SS-1) CI40 D8-NAPHTHALENE (IS-2) CS25 2-FLUOROBIPHENYL 0.7 (SS-2) CI50 DIO-ACEHAPHTHEHE (IS-3) CS55 2..4,6TRIBR.0M0PHEH0L (SS-6) .CI60 DIO-PHEHAHTHRENE (IS-4) CS30 D14-P-TERPHEHYL 0.5 (SS-3) b . CZ: tb t. z.\ t tZ n . i DATA FROM FILE: SU12158WB1 SCAMS 1082 TO 2280 ACQUIRED: 02/88/95 17:31:88 CALI: SU12158WB1 #1 SAMPLE: SBLKW WATER-12158WBI COHDS.: RTX-5 0.25MM X SOM l.OUM 45/4-325620 INST B f ± I 1200 . 20:00 1400 J 23:20 1600 . 26:40 r f p u c r {•• r T p.; Ci ^ c u> o o It^ i t i 00 1300 30:00 1 ' 2000 ^.•^.' . i . i j m J J 100.0^ ( 20576.) CI70 DI2-CHRYSENE (IS-5) CI75 D12-PERYLENE (IS-6) n,. Quantitation Report File: SV121S8W61 Data: SV12156WB1. TI 02/06/95 17:31:00 Sample: SBLKW WATER-1215eWBl Conds.: RTX-5 0.25MM X 30M l.OUM 45/4-325e20 Formula: X X X Instrument: B Submitted by: Analyst: JAM INST B Weight: 1.000 Acct. No. : 12158 AMOUNT-AREA • REF AMNT/(REF AREA • RESP FACT) Resp. fac. from L i b r a r y Entry No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 No 1 2 3 4 5 6 7 B 9 Name CI30 CI40 CI50 CI60 CI70 CI75 CS50 CS45 CS20 CS25 CS55 CS30 CS70 CS75 C740 m/2 ! 152 136 164 188 240 264 112 99 82 172 330 244 132 152 149 D4-l,4 DICHLOROBENZENE DB-NAPHTHALENE DIO- DIO- D12- D12- -ACENAPHTHENE -PHENANTHRENE -CHRYSENE -PERYLENE 2-FLUOROPHENOL D5-PHEN0L D5-NITR0BENZENE 0,6 0,6 0. 2 2-FLUOROBIPHENYL 0. 7 2,4- D14- ,6TRIBROMOPHENOL -P-TERPHENYL 0, 5 2-CHL0R0PHENDL-D4 0, 8 1,2--CL2BENZENE-D4 0. 4 BIS(2ETHYLHEXYL)PHTH Bean 482 601 760 892 1151 1414 357 4 56 538 698 832 1036 465 501 1144 Ret(L) Ra 8:03 10:02 12:41 14:53 19:09 23:31 5: 58 7:37 8: 58 Time F • 8:02 10:01 12: 40 14: 52 19: 11 23:34 5: 57 7:36 8: 58 11: 38 13:52 17: 16 7:45 8:21 19:04 lef 1 2 3 4 5 6 1 1 2 3 3 5 1 1 5 RRT 1, 000 1, 000 1, 000 1, 000 1. 000 1. 000 0. 741 0. 946 0. 895 0. 918 1. 095 0. 900 0. 965 1. 039 0. 994 tio RRT(L) Ratio 00 1. 000 00 1. 000 00 1.000 00 1.000 00 1. 000 00 1.000 00 0. 741 00 0. 946 00 0. 894 00 00 00 00 00 00 00 00 00 (IS-1) (IS-2) (IS-3) (IS-4) (IS-5) (IS-6) (SS-5) (SS-4) (SS-1) (SS-2) (SS-6) (SS-3) (SS-7) (SS-8> Meth A BB A BB A BB A BD A BB A BB A BD A BB A BB A BB A BB A BB A BD A DD A BD Amnt 20. 00 20.00 20. 00 20. 00 20. 00 20. 00 63. 91 68. 59, 51. 29 Area(Hght) 7042. 26145. 16646. 21609, 17708. 17396. 21400. 31879. 17818. 37330. 6105. 38846. 29341. 10633. 6274. Amnt(L) 20. 00 20. 00 20.00 20. 00 20. 00 20. 00 25. 00 25. 00 25. 00 R. 1 2 3 0 Amount 20. 000 PPB 20. 000 PPB 20. 000 PPB 20. 000 PPB 20.000 PPB 20. 000 PPB 63. 913 PPB 68. 594 PPB 51. 286 PPB 43. 969 PPB 61. 965 PPB 53. 507 PPB 72. 113 PPB 40. 563 PPB 7. 388 PPB Fac R.Fac(L) .000 1.000 . 000 1, 000 ,000 1.000 .000 1,000 .000 1,000 . 000 1. 000 . 431 0. 951 .622 1. 320 . 545 0. 266 7.Tot 3. 3. 3. 3. 3. 3. 10. 11. 8. 7. 10. 9. 12. 6. 1. Rat 2 2 cL 43 43 43 43 43 43 96 76 79 54 62 17 36 95 27 io , 00 . 00 . 00 .00 . 00 . 00 . 56 . 74 . 05 300449 p. c;,,h;^-; Tb VsHda'ior ZZ?. Z.\ No Ret(L) R a t i o RRT(L) R a t i o Amnt Amnt(L) R.Fac R. Fac(L) Ratio 10 11:39 1.00 0.919 1.00 4 3 . 9 7 2 5 . 0 0 1.794 1.020 1.76 11 13:52 1.00 1.093 1.00 6 1 . 9 7 2 5 . 0 0 0 . 2 9 3 O. 118 2.48 12 17:15 1.00 0.901 1.00 53.5^1 2 5 . 0 0 1.755 0.820 2.14 13 7:46 1.00 0.965 1.00 72.11 2 5 . 0 0 3 . 3 3 3 1.156 2.88 14 6:21 1.00 1.037 1.00 4 0 . 5 6 2 5 . 0 0 1.208 0.744 1.62 15 19:02 1.00 0.994 1.00 7 . 3 9 2 5 . 0 0 0 . 2 6 3 0.959 0,30 300450 TARGET COMPOUND COMPARISOH COMPOUND: C740 BIS(2ETHYLHEXYL)PHTH RAW DATA: SU12158WB1 #1144 02/08/95 17:31 SAMPLE: SBLKW WATER-12158WBl COHDS.: RTX-5 e.25MM X SOM l.OUM 45/4-325620 BASE M/Z: IHST B 149 RIC: 8768. 100.0-: 50.0-: 1 J T^-r I ll 83.3-: 41.7-: - J — I — f - 1 — r - * * ' — I — I — I — I — r ^ i — I — I — r ~ ENHANCED DATA: SU12158WB1 #1144 I ' " I T—1—I—I j ' • I I I I—\—r—T' • BASE M/Z: 149 RIC: ' I • — P " ' 'i ' 7016. Ji I"'' I ' " I -r^—T"'—I—f—r -1—I - I I I — I — I i i — I — ' I ' — \ ~ r , — I — I t 'I—r- :?4.4- 17.2-: LIBRARY FILE: SN #56 BASE M/Z: 149 RIC: 1586. ' ' I ' M/Z 50 100.01 a «« 50.0-j tn IQ' 0.0- - 1 — I I I • — l ' j ' 100 I ' l ' 1 ' I 150 T - l — I ' l l — I ' l ' — I ' l ' — I •' I ' — I I 'I 200 250 o o'-SO.O- o i t i U l H 1 ; < tu 5X100.0 o 3 Tl ft I ll 2904. 2420. r 1000. DATA FROM FILE: SWTFOIP SCANS 343 TO 1033 ACQUIRED: 02/08/95 18:54:00 CALI: SUUTFOIP #1 SAMPLE: RBSO/012795 WATER HLA CONDS.: RTX-5 0.25MM X SOM l.OUM 45/4-32.5620 IHST B 400 6:40 500 . 8:20 600 . 10:00 700 A-=L , 11:40 800 ;§• ' w l 900 -•• •.tfi o ' 15:130 ;C , O ,i^ Ul 9a to O* 1000 _ p - - • - I I CS50 2-FLUnROPHENOL 0.6 (SS-5) -^100.0?; ( 60096.) C545 D5-PHEN0L 0.3 (SS-4) CI30 D4-l,4 DICHLOROBENZENE <IS-1> CS75 1,2-CL2BENZENE-D4 0.4 (SS-8) CS20 D5-HITR0BEHZENE 0.2 (SS-1) CI40 DS-NAPHTHALEHE (IS-2) CI50 DIO-ACEHAPHTHEHE CS25 2-FLUOROBIPHEHYL 0.7 (SS-2) (IS-3) -€£55 2,4.. 6TRI BROMOPHENOL (SS-6) CI50 DIO-PHENANTHRENE (IS-4) CS30 D14-P-TERPHEHYL 0.5 (SS-3) i ITZ DATA FROM FILE: SUUTFOIP SCANS 1083 TO 2200 ACQUIRED: 02/03/95 18:54:80 CALI: SUUTFOIP ftl SAMPLE: RBSO/012795 WATER HLA CONDS.: RTX-5 0.25MM K SOM l.OUM 45/4-325620 INST B 1200 J 20:00 1400 . 23:20 1600 J 26:40 1300 _J 30:00 % '\ p.' ', ' • ! ? ' T:i' O 12000 A S'3:^:20 - ! i«^ " - • ' - - ZT-PU m J I _L J 100.0?; ( 19136.) CI70 D12-CHRYSEHE (IS-5) CI75 D12-PERYLEHE (IS-6) Q u a n t i t a t i o n Report F i l e : SWTFOIP Data: SWTFOIP. TI 0 2 / 0 8 / 9 5 1 6 : 5 4 : 0 0 Sample: RBSO/012795 WATER HLA .Conds,: RTX-5 0. 25MM X 30M l.OUM 45/4-325620 ^Formula: X X X Instrument: B Submitted by: Analyst: JAM INST B Weight: Acct, No, 1. 000 12158 AMOUNT=AREA • REF AMNT/(REF AREA • RESP FACT) Resp. fac. from Library Entry No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 No 1 2 3 4 5 6 7 8 9 Name CI30 CI40 CI50 CI60 CI70 CI75 CS50 CS4 5 CS20 CS25 CS55 CS30 CS70 CS75 C740 m/z ! 152 136 164 188 240 264 112 99 82 172 330 244 132 152 149 D4-l,4 DICHLOROBENZENE DB-NAPHTHALENE DIO-ACENAPHTHENE DIO-PHENANTHRENE D12-CHRYSENE D12-PERYLENE 2-FLUDRDPHENDL D5-PHENDL D5-NITR0BENZENE 2-FLUDRDDIPHENYL 0.6 0. 8 0. 2 0. 7 2,4,6TRIBRDM0PHEN0L D14-P-TERPHENYL 2-CHL0RDPHEN0L-D4 1,2-CL2BENZENE-D4 0. 5 0. 8 0. 4 BIS(2ETHYLHEXYL)PHTH scan Time F 483 8; 03 601 10:01 760 12: 40 892 14; 52 1149 19:09 1412 23:32 360 6; 00 457 7:37 538 8;58 698 11;38 831 13: 51 1035 17:15 466 7:46 501 8;21 1142 19; 02 Ret(L) Ratio R R T ( L ; 8:03 10: 02 12:41 14: 53 19:09 23; 31 5; 58 7; 37 8; 58 1.00 1.000 1. 00 1. 000 1. 00 1. 000 1.00 1.000 1. 00 1. 000 1.00 1.000 1.01 0.741 1.00 0.946 1. 00 0. 894 tef 1 2 3 4 5 6 1 1 2 3 3 5 1 1 5 0. 0. 0. 0. 1. 0. 0. 1. 0. • Rat: RRT 000 000 000 000 000 000 745 946 895 918 093 901 965 037 994 Lo 00 00 00 00 00 00 01 00 00 (IS-1) (IS-2) (IS-3) (IS-4) (IS-5) (IS-6) (SS-5) (SS-4) (SS-1) (SS-2) (SS-6) (SS-3) (SS-7) (SS-B) Meth A DB A DD A DD A BB A DD A DD A BB A DB A DB A DB A DD A DB A BD A DD A BB Amnt 20. 00 20. 00 20, 00 20. 00 20. 00 20. 00 63. 21 66. 48* 48. 25 Area(Hght) 6911. 25946. 16487. 22342. 17596. 17196. 20771. 30322. 16635. 36612. 5878. 36639. 27712. 10593. 7404. Amnt(L) 20. 00 20. 00 20. 00 20. 00 20. 00 20. 00 25. 00 25. 00 25. 00 Amount 20. 20. 20. 20. 20. 20. 63. 66. 48. 43. 60. 50. 69. 41. 8. R. Fac 2 3 0 000 000 000 000 000 000 212 480 249 539 237 788 400 176 774 R. F, 000 000 , 000 . 000 . 000 . 000 . 404 . 510 . 513 PPB PPB PPB PPB PPB PPB PPD PPB PPB PPB PPB PPD PPB PPB PPD ac(L) 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 0. 951 1. 320 0. 266 7.Tot 3. 3. 3. 3. 3. 3. 11. 11. 8. 7. 10. e. 12. 7. 1. Rat; 2. 2, 1, 50 50 50 50 50 50 05 63 44 61 53 88 14 20 53 Lo 00 00 00 00 00 00 53 , 66 , 93 300454 Data SubiecT To Validation No 10 11 12 13 14 Ret(L) 11:39 13:52 17: 15 7:46 6:21 Ratio 1.00 1.00 1.00 1.00 1. 00 RRT(L) 0. 919 1.093 0. 901 0. 965 1. 037 Ratio 1.00 1. 00 1.00 1.00 1. 00 Amnt 43. 54 60.24 50.79 69. 40 41. 18 Amnt(L) 25. 00 25. 00 25,00 25,00 25. 00 R.Fac R 1.777 0.285 1.666 3.208 1.226 . Fac(L) 1.020 0, 118 0,820 1, 156 0, 744 Ratio 1,74 2,41 2.03 2,78 1,65 15 19:02 1.00 0,994 1,00 8,77 25,00 0,337 0.959 0.35 300455 I . ...J Data Subject To Vaiidation 100.0- 50.0^ ^ 41.2- 41 TARGET COMPOUND COMPARISON COMPOUND: C740 BIS(2ETHYLHEXYL)PHTH RAW DATA: SUUTFOIP #1142 02/08/95 18:54 SAMPLE: RBSO/012795 WATER HLA CONDS.: RTX-5 0.25MM X SOM l.OUM 45/4-325628 BASE M/Z: INST B '' I I—'I' I' I ''I—I I I—'i I *' I I 1 — ENHANCED DATA: SUUTFOIP #1142 • T — r 149 RIC: 9856. r 3464^ -*-| ' I-T 1 ' -1 ' f — ' 1 ' 1 ' I T-V-r- BASE M/Z: 149 RIC: 8192. T r- T^—r T^—I—'—I—'-T r ' l — ' — I — ' — r — ' - I ' I • — I ' l ' — I ' I r 2852. '-.n 28.9- 14.4- ^ y , 50.0-d ol ol •^ 0.0-H QJ -50.0d 109.0-J LIBRARY FILE: SN #56 - i — ' — I ' l ' — V ' I M/Z 50 100.01 - 1 — I — . — I — I — I — I — r 100 BASE M/Z: 149 RIC: 1586. 150 T — ' — I — I — l ' j ' — I — r — I — I — p - i — I — I — I — I — r 200 250 r 1008. » »V I • rMGR : TUNERf "DFTPP # GC/MS PERFOHMANCE STANDARD Decafluorotriphenylphosphine (DFTPP) Ion Abunciance B/z Criteria 51 30-60% of Bass 198 68 Less than 2% of nass 69 69 (reference only) 70 Z<ess than 2% of aass 69 127 40-60% of Bass 198 197 Less than 1% of Bass 198 198 Base peak, 100% relative abundance 199 5-9% of Bass 198 275 10-30% Of Bass 198 365 Greater them 1% of Bass 198 441 0-100% of Bass 443 442 Greater than 40% of Bass 198 443 17-23% Of Bass 442 % Relative Abundance Base Appropriate Peak Peak Status 57.37 0.00 84.88 .22 59.02 0.00 100.00 6.78 22.66 1.67 8.48 50.98 8.93 57.37' 0.00- 84.88* .26 59.02 0.00 100.00 6.78 22.66 1.67 94.95 50.98 17.52 Ok Ok Ok Ok Ok Ok Ok Ok Ok Ok Ok Ok Ok Injection Date: 02/02/95 Injection Time: 09:19 Data File: >H033A Scan: 427 300457 Data Subject To Validation £ 9 F i l e >He33A SOnsr l l » n « I * • SFTPP SI / 5 8 k 127 lee 148 2 9 e - e 4 - P E R F - 9 9 8 8 SUB HRM X 9 8 1 8 6 y 148 I I S O 2 8 0 2 5 5 JdJuv I 2 5 8 275 / -»^ ^ ^ ^ 4 ^ - • ( { 296 3 2 3 11 i r r i If I'I ISI I I ' H I I ' I I I I I I"I 11 n 11 r ( 3 8 8 3 5 8 4 8 8 Soan 427 7 . 6 3 Min. :118 ^ 8 8 i 9 8 ^ 8 i78 4 4 2 * 8 158 =48 E38 ^28 r l 8 8 Data F i l e n a m e : >H033A::D1 NaBe: 50ng DFTPP Misc: 290-04-PERF-5988 INST H BTL/ 1 Operator ID: DAVID Analysis Date/Time SUPER GRP. 2/02/95 9:19 300458 Data Subject To Validation: Analysis Date/Tiae: 2/02/95 9:19 . Data Filename and Sample ID: >H033A 50ng DFTPP 290-04-PERF-5988 INST H 427 SUB HRM File: >H033A Scan #: 427 Retn. time: 7.63 B/Z Int. B/z Int. B/z Int. B/Z Int. B/Z Int. 36.95 38.05 38.95 43.80 4 8 . 9 5 4 9 . 9 5 50.95 51.95 52.95 55.20 55.90 56.90 60.90 62.00 63.00 64.90 68.90 69.90 .73.15 '73.90 75.00 76.00 77.00 7 8 . 0 0 78.90 79.90 81.00 81.90 83.00 85.00 86.00 87.00 87.90 91.00 92.00 92.90 .439 1.096 4 . 0 0 3 .262 .620 18.116 57.365 2.926 .217 . 6 4 1 1.950 4 . 2 8 0 . 8 6 1 1.026 2.218 .659 8 4 . 8 7 5 .223 .433 6.300 1 0 . 0 4 1 2.507 61.344 3.973 4.367 3.356 4 . 4 2 1 1.162 .554 .798 2.029 .232 .150 .710 .978 7 . 6 2 1 96.90 98.00 99.00 100.90 103.00 103.90 105.00 107.00 108.00 110.00 111.00 112.00 117.00 118.00 121.40 122.00 123.00 124.00 125.00 127.00 128.00 129.00 130.00 132.00 134.00 135.00 136.00 137.00 138.00 141.00 142.15 146.00 147.00 148.00 148.90 151.15 .346 6.047 4.756 2.700 .557 1.499 1.291 17.418 2.297 32.118 5.647 .205 14.959 1.147 .066 1.342 1.683 1.081 .370 59.018 4.286 2 4 . 9 3 1 1.761 .214 .539 1.415 .515 .765 .108 2.348 .849 .533 1.062 3.076 .457 .412 154.15 155.00 156.15 157.00 158.00 160.15 161.00 162.00 165.00 166.00 166.95 167.95 169.95 172.95 173.95 174.95 176.05 176.95 178.05 178.95 180.95 182.80 184.05 185.05 186.05 187.05 188.05 188.95 190.95 191.95 193.05 195.95 197.95 198.95 199.95 201.45 .611 1.276 1.574 .238 .563 .527 1.225 .241 .780 .831 4.972 1.950 .292 .539 .969 1.616 .479 1.141 .352 3.853 1.129 .117 .457 1.523 12.930 3.531 .536 .819 .439 .873 1.035 2.838 100.000 6.784 .379 .632 202.95 204.05 205.05 206.05 207.05 208.05 211.05 216.05 216.95 218.05 221.05 223.05 224.05 224.95 226.05 226.95 228.05 228.95 230.95 236.95 240.95 241.95 243.05 244.05 244.95 246.05 247.05 255.05 256.05 257.05 257.95 263.95 265.05 273.05 274.05 275.05 .406 3.446 5.499 22.854 3.624 .939 1.008 .620 € . 7 7 5 .614 4 . 8 8 5 1.303 12.235 3.660 .268 5.063 .683 1.219 .370 .262 .412 .461 .996 10.155 1.282 1.743 .689 5 4 . 0 8 1 7.230 .412 2 . 9 7 1 .144 1.129 1.755 3.570 2 2 . 6 6 1 276.05 277.05 278.00 293.00 296.00 297.00 303.00 314.15 314.90 316.00 321.90 323.00 324.00 327.65 334.00 335.00 345.90 352.00 354.15 365.00 366.00 370.15 372.00 373.00 389.95 401.95 402.95 420.95 422.05 422.95 423.95 440.95 442.05 442.95 444.05 2.727 1.574 .343 .445 5.180 .867 .557 .196 .461 .283 .108 1.776 .157 .108 .915 .436 .241 .674 .707 1.667 .271 .087 .749 .364 .166 .319 .497 .391 .641 3.202 .373 8.482 50.975 8.933 1.114 Data ; U l ^ : 300459 QUANT REPORT Operator ID: DAVID Output File: <^H033A::BQ Data File: >H033A::D1 ame: 50ng DFTPP Misc: 290-04-PERF-5988 Quant Rev: 6 Quant Time: Injected at: Dilution Factor: INST H 950202 10:25 950202 09:21 1.00000 BTL# 1 ID File: ID DFT::DB Title: DFTPP/BENZIDINE/PENTACHLOROPHENOL PERFORMANCE Last Calibration: 950202 10:22 Compound R.T. Q ion Area 1} *IS/4 Phenanthrene-dlO 2) Pentachlorophenol 3) Benzidine * Compound is ISTD 7.42 188.2 7.20 265.9 9.19 184.2 177455 36193 134593 Cone Units q 20.00 ppb 85 25.00 ppb 98 25.00 ppb 90 300460 Data Sublec' Tc VaHdatio TOTAL ION CHROMATOGRAM Fii* >He33A i^.b-Sl6.6 AMU. 5fg9 DFTPP 29e-e4-l>£JRF-398^' 608888 958888 588888- 450888- 488880 358888 388888 258888- 288888- 158888- 188888- 58888- O- . 4 ,... t . . . . ~ . . . n t... .^.... 1,.. ^ v . . . . t . . • - " . . . . I . . . . " . . . . 1 . . . . " . . . . t . . . . " . . . . ; . . " f y . .8 i AS 5.8 • • • p i •••'!'I • I I J • •' '"1 •' 6.8 7.8 Ili || ||| 1 • I I I 8.8 i4-^ I • • - y v i 9.8 *4= I' I I • • 9 T^M f t 18.8 ^ ' ' L i 11.8 Data File: >H033A::D1 Name: 50ng DFTPP Misc: 290-04-PERF-5988 Quant Output File: *H033A::BQ INST H BTL/ 1 Id File: ID_DFT::DB Title: DFTPP/BENZIDINE/PENTACHLOROPHENOL PERFORMANCE Last Calibration: 950202 10:22 Operator ID: DAVID Quant Time: 950202 10:25 Injected at: 950202 09:21 300461 -. ^ c,.'-,iP.-iToVaudatioa y t m r P F N r r fcTftMi>oT>T> KyFcrwiM F i l e >H899P BENZIDINES SDT Bi>k Ab 1 8 8 . i e 2 8 - 2 1 - B E N Z - 5 e SUB HRM ^ ^ ^ 1 8 4 INST 1O0H 5 2 6 5 7 7 92 X17 ^ 1 i'"%"|iN * < " f ^ i » ' i y 4 0 8 0 * ' i y i ' I ^ ' i i*<¥*i ^ ' i • 1 3 0 * x ' 1^6 J 1 8 6 1 2 8 1 6 8 T™'' ' » I •• ZOO • ' I S c a n 2 5 3 8 2 4 . 9 7 M i n . K188 - I — i - r - p - » - ' 0 2 4 8 SAMPLE SPECTRUM <BACKGROUND SUBTRACTED) lii^i^liile?""' » " " 2 9 e - 0 4 - P E R F - 5 9 8 8 SI - >UB 1 8 4 S c a n 6 8 8 9 . 1 9 M i n . 4 8 8 8 8 : 5 2 Q ^ t i f - i 1 1 7 1 3 9 4 8 6 5 7 7 9 2 ^-V/ 1 3 8 * ? ' 1^6 8 8 1 2 8 1 6 8 1 hl88 253 • 1 • • • • ' 288 248 SAMPLE SPECTRUM <UNALTERED> File >He33A,58n9 DFTPP Bpk AL 66536. 48888: 52 eJ S^ \ 'r I •!•• 65 77 92 %• ' f ^ ' i ' t " I ' " ! •|ii'i'» 117 88 •|' ' 1 I ' l 128 298-e4-PERF-5988 184 1 3 8 ^ ' 156 ,!• |i. .••j...» ...nil . .iMii Scan 688 9.19 Min. 168 K8e 287 / 253 2 da *'* f 1 I '""f • f I X IT' Data File: >H033A::D1 Name: 50ng DFTPP Misc: 290-04-PERF-5988 Quant Time: 950202 10:25 Injected at: 950202 09:21 Compound No: 3 Compound Name: Benzidine Scan Number: 609 Retention Time: 9.19 min. Quant Ion: 184.2 Area: 134593 Concentration: q-value: 90 25.00 ppb Quant Output File: *H033A::BQ INST H BTL/ 1 Quant ID File: ID_DFT::DB Last Calibration: 950202 10:22 3 0 0 4 6 2 Date, Subjea lo VaHdatiori! TOTPL ION CHPCtlRTOGPfln F i i * >H0336 3 5 . e - S i e . e AiHU. SSTDOSe TIC see leeo isoe • • • • ' ' ' • • ' • • • • ' • • • • ' • • • • ' • • ' saeoee- £4oeoe- zeodecf 2*6-i£-§vSS aeee l i l l l l l -2500 I I I I I I I I ! ii.&&&&- 120000- •I J i 40oac^ ^ ^ { V • ! • 3080 • • • • ' • • • • ' ' TI I f £4 I ' ' ' I ' £8 3£ ^ % ^ ^ ^ 'eo to A- Data File: >H033B::D1 Name: SSTDOSO Misc: 290-12-SV25 Quant Output File: *H033B::BO INST H BTL« 2 Id File: ID_SH::DB Title: SEMIVOLATILES BY SW846-8270/EPA 625 Last Calibration: 950202 10:33 Operator ID: DAVID Ouant Time: 950202 10:52 injected at: 950202 09:43 300463 OTZ-l-^ Date S y z a . lb Validation. QUANT REPORT Operator ID: DAVID Output File: "H033B::6O la Pile: >H033B::D1 ime: SSTD050 Misc: 290-12-SV25 Ouant R ev: 6 Ouant Time: 950202 10:52 Injected at: Dilution Factor: INST H 950202 0 9 : 4 3 1.00000 BTL# 2 ID File: ID_SH::DB Title: SEMIVOLATILES BY SW846-8270/EPA 625 Last Calibration: 950202 10:33 Compound R.T. 0 ion Area Cone Uni ts fl 1 2 3 4 S 6 7 6 9 10 11 12 13 14 15 18 19 20 21 22 23 24 (25 26 127 '28 29 30 31 32 33 34 35 36 37 38 39 40 43) •IS#1 1,4-DiChIoroben2ene-d4 Pyr i d i ne N-Nitrosodimethylamine Phenol-d5 2-Chlorophenol-d4 2-FIuorophenoI An i I ipe PhenoI 2-Chlorophenol b i s(2-Chloroethyl)ether 1,3-D ichlorobenzene 1,4-Dichlorobenzene 1,2-D ichloroben2ene-d4 1,2-Di chlorobenzene BenzyI a Ic0h0 I 2,2'Oxybis-( 1-chloropropane) 2-Methy IphenoI N-N i troso-di-n-propylamine HexachI oroe t hane 4-Methy IphenoI •IS#2 Naphthalene-d6 N i t r obenzene-d5 N i t robenzene Isophor one 2-Ni t rophenoI 2 ,4-D imet hyIphenoI bis(2-ChI oroethoxy)methane 2 ,4-D i chI or ophenoI Benzo i c acid 1,2,4-Tr ichlorobenzene Naphthalene 4-ChI oroan iIine Hexachlorobutadiene 4-ChI oro-3-met hyIphenoI 2-MethyInaphthalene •IS#3 Acenaphthene-d10 Hexachlorocyclopentadiene 2,4,6-Tr ichlorophenol 2,4, 5-Tr ichlorophenol 2-Fluorobiphenyl 2-Ch I or onaph t ha I e!ne 2-N i t r oan i I i ne ' Dimethylphthalate 11.42'' 6.96 6.98 10.82 11.09 9.3S 10.93*' 10.84' 11. 12 10.98- 11.36 . 11.45. 11.76' 11.77- 11.65 . 11.90 11.84' 12. 14 12.31 12.07. 13.66 12,42 12.46 12.83 13.01 13.00. 13. 16 13.40 13.14. 13.67 13.70 13.79 13.96 14.59 14.92 16,86 15.30 15,45- 15,53r 15,57 15.81 16.03 16,32 152.0 79. 1 74.0 99.0 132.0 112.0 93.0 94.0 128.0 93,0 146,0 146,0 152.0 146.0 108, 1 44,9 108.0 70,0 117.0 108,0 136, 1 82,0 77.0 82.2 139.0 -107.0 93. 1 162.0 122.0 179,9 128, 1 127.0 224.8 107.0 142. 1 164,2 236,8 196.0 ' 196,0 172, 1 162,0 65.0 163. 1 27784 30623 21465 62223 41615 39638 76624 55674 42157 50916 47385 47863 26770 44127 25819 48964 36849 32460 20535 40765 101995 48881 60299 100539 21185 36448 61855 32333 21727 36681 115756 52131 22276 36596 70079 51488 18920 22493 25377 72365 69305 25687 86349 20.00 25,00 25.00 25,00 25,00 25,00 25,00 25.00 25,00 26,00 26,00 25,00 25.00 25,00 25.00 26,00 25.00 25.00 25,00 25,00 20.00 25.00 26,00 25,00 25.00 25,00 25,00 25.00 25,00 25,00 25,00 25,00 25,00 26,00 25.00 20.00 25.00 26.00 25.00 26.00 •26.00 2 6.00 26,00 ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb 99 87 96 90 88 76 99 60 87 93 97 93 96 96 93 97 94 78 90 99 99 82 94 98 96 86 93 84 93 96 98 92 96 85 94 94 93 81 95 93 95 66 89 300T64 0r2'2--*i5 ^ Data Subject 7b VsHd^vJorv , Compound R.T. 16.4^ 16.59 16.77 16.91 16.95 17. 19 16.99 17.21 17.47 17.66 17.75 17.83 17.90 18.30 19.64 18.04 17.95 17.97 18.64 18.97 19.27 19.93 19,58 19,67 21,78- 20.44 24.43 22.21- 22,36 23, 17 24,26 24.39 24 . 12 24.49- 28. 17 25.35 26.98 27.05- 27.99. 32.29 32.24 33.67 Q ion 165.0 152. 1 138.0 153. 1 184.0 168. 1 109.0 165. 1 232.0 149. 1 204. 1 166. 1 138.0 329.6 188.2 77.0 198.0 169, 1 248,0 283.8 265,9 167.0 • 178. 1 '178. 1 202.0 149.0 240.2 202.0 244.2 149. 1 252.2 .228.0 149.0 228.0 264.2 149.0 ^252.2 252.2 252.0 •276.2 "278. 1 '276.0 Area 19560 114316 22495 69289 8943M 93452 11042 24764 23244 9426 1 34489 69174 21335 14100 76966 119744 13289 48666 22336 29982 16842 92901 102364 102427 106406 166776 71342 112503 67151 66412 33713 97337 94883 90538 77372 152532 100196 88090 87017 98308 750 17 82611 Cone 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 26.00 25.00 25.00 20,00 25.00 25.00 25.00 25.00 26.00 25.00 25.00 25.00 25.00 25,00 25,00 20.00 25.00 25,00 25.00 25.00 25.00 25.00 25.00 20.00 25.00 25.00 25.00 25.00 25.00 25.00 26.00 U n i t s ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb p p b - ppb ppb ppb ppb ppb ppb ppb PPt> ppb ppb" ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb q 95 98 88 96 98 89 84 91 91 78 98 97 84 94 85 93 95 93 94 97 95 96 98 97 97 98 96 99 93 98 96 88 97 . 87 96 95 98 95 94 89 78 2,6-Din i trotoluene Acenaphthylene 3-Ni troaniIine Acenaphthene 2,4-Dini trophenol Dibenzofuran 4-Ni trophenoI 2,4-Di n i t rotoluene 2,3,4,6-Tet rachlorophenol Diethylphthalate 4-Chlorophenyi-phenylether FIuorene 4-Ni troaniIine 2,4,6-Tr i bromophenoI • IS#4 Phenanthrene-dlO 1,2-Di phenylhydrazine 4,6-Di n i t r o-2-melhyIphenoI Diphenylamine 4-Br omophenyl-phenylether Hexachlorobenzene PentachI orophenoI CarbazoIe Phenanthrene Anthracene Fluoranthene Di-n-butylphthalate «IS#5 Chrysene-d12 P'yrene Ter phenyl-d 14 Butylbenzylphthalate 3,3'-Dichlorobenzidine Benzo(a)anthracene bis(2-Ethylhexyl )phtha late Ch rysene • IS«6 Perylene-d 12 Di-n-octylphthalate Benzo(b)fluoranthene Benzo(k)tluoranthene Benzo(a)pyrene Indenot 1,2,3-cd)pyrene Dibenz(a,h)anthracene Benzo(g,h,i)perylene • Compound Is ISTD 300465 OTT.-'^-tS D z TOTAL ION CHROriBTOSRRtl File >He33C 35.0-510.0 M U . SSTDO60 89e-12-SV40 600 1080 1500 £000 . - £600 3008 ''' ^ ^ \ J.-' \ '<w Data File: >H033C::D1 Name: SSTDOSO Misc: 290-12-SV40 Ouant Output File: •H033C::BQ INST H BTL# 3 Id File: ID_SH::DB Title: SEMIVOLATILES BY SW846-8270/EPA 625 Last CaIibration: 950202 10:33 Operator ID: DAVID Quant Time: 950202 11:17 Injected at: 950202 10:29 300466 crr2.-'^-'^^ Data Subject To ValicSiio;: OUANT REPORT Operator ID: DAVID Output File: *H033C::BQ ita Fi i e : >H033C::D1 ime: SSTDOBO Misc: 290-12-SV40 Quant Rev; 6 Ouant Time: Injected at: Di lut ion Factor INST H 950202 11:17 950202 10:29 1.00000 BTL# 3 10 File: ID_SH::DB Title: SEMIVOLATILES BY SW846-8270/EPA 625 l.a5t Calibration: 950202 10:33 Compound R.T. O ion Area Cone Units • IS*»1 1,4-Di ch lor obenzene-d4 Pyr idine N-Nitrosodimethylamine Phenol-d5 2-ChI orophenoI-d4 2-FIuoropheno I An i I i ne PhenoI 2-ChI oropheno I b i s(2-ChIoroethyI )ether 1,3-Dichlorobenzene 1,4-D ichlorobenzene 1,2-DichI orobenzene-d4 1,2-D ichlorobenzene BenzyI a IcohoI 2,2'Oxybis-( 1-chI or opropane ) 2-Methylphenol N-N itroso-di-n-propylamine Hexachloroethane 4-Met hyIphenoI «iS«2 NaphthaIene-d8 N i t r obenzene-d5 N i t robenzene i sophor one 2-Ni t rophenoI 2,4-Dimethylphenol b i s(2-Chloroethoxy)me thane 2,4-Di chIoropheno 1 Benzo i c acid 1,2,4-Trichlorobenzene Naphtha Iene 4-ChI or oan iIine Hexachlorobutadiene 4-ChI oro-3-methyIphenol 2-Methy I naphthalene • IS#3 Acenaphthene-d 10 Hexachlorocyclopentadiene 2 ,4 ,6-TrIchlorophenol 2,4,5-Tr ichlorophenol 2-FIuor ob i pheny I 2-ChI oronaphthalene 2-N i t roan i I ine DimethyIph thaI ate 1 1 . 4 3 ' 6 . 9 7 7 . 0 0 1 0 . 8 3 1 1 . 10 9 . 3 6 1 0 . 9 4 , 10.se- l l . 14 1 0 . 9 9 . 1 1 . 3 7 - 1 1 . 4 6 ' 1 1 . 7 7 - 1 1 . 7 8 - 1 1 . 6 6 - 11.90 11.84 • 12. 15 12.32 1 2 . 0 9 . 1 3 . 6 7 12.43 12,46 1 2 . 8 3 1 3 . 0 2 1 3 , 0 0 - 13, 17 1 3 . 4 1 13, 18- 13,58 1 3 . 7 0 13,80 13,97 1 4 , 6 9 1 4 . 9 2 1 6 , 8 6 1 5 , 3 0 1 5 . 4 5 ' 1 5 . 5 3 ; 15,57* 1 5 . 8 1 1 6 , 0 3 1 6 , 3 2 1 6 2 . 0 7 9 . 1 7 4 . 0 9 9 . 0 1 3 2 . 0 1 1 2 , 0 9 3 . 0 9 4 . 0 1 2 8 . 0 9 3 . 0 1 4 6 , 0 146,0 1 5 2 . 0 1 4 6 . 0 108. 1 4 4 . 9 108.0 7 0 , 0 1 1 7 . 0 1 0 8 . 0 136. 1 8 2 . 0 7 7 . 0 8 2 , 2 139.0 • 1 0 7 , 0 9 3 , 1 162.0 122,0 179,9 128. 1 127.0 2 2 4 . 8 1 0 7 . 0 142. 1 164,2 2 3 5 . 8 ' 196.0 196.0 172. 1 1 6 2 . 0 6 5 . 0 163. 1 - 27297 60466 39434 86623 6 7 1 7 1 63563 116376 91124 67888 77113 75017 75153 45007 68796 41292 76978 58626 50355 3 2 6 3 1 61283 94086 61098 7 8 6 7 1 154985 34048 62263 97535 51647 35216 67897 174925 81003 33480 66374 107330 45735 32010 3 5 8 1 1 37984 119420 100660 41566 129797 2 0 . 0 0 6 0 . 2 4 4 6 . 7 5 4 2 . 2 1 4 1.07 4 0 . 8 0 3 8 . 6 5 4 1 . 5 0 4 0 . 9 8 3 8 . 5 4 4 0 . 2 8 3 9 . 9 5 4 2 . 7 8 3 9 , 6 7 4 0 . 7 0 3 9 . 4 8 3 8 . 4 0 3 9 . 4 7 4 0 . 4 3 3 8 . 2 5 2 0 . 0 0 4 4 . 9 6 4 2 . 3 9 4 1 . 7 8 4 3 , 5 6 3 8 , 8 6 4 2 . 7 3 4 3 . 2 9 4 3 . 9 3 4 2 . 7 8 4 0 . 9 5 4 2 . 11 4 0 . 7 3 4 1 . 7 6 4 1 . 6 1 2 0 . 0 0 4 7 . 6 2 4 4 . 8 1 4 2 . 13 - 4 6 . 4 5 4 0 . 8 4 4 5 . 5 4 4 2 . 3 1 ppb ppb ppb ppb ppb ppb ppb PP.b ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb 0 T - ^ - ' 2 _ - * % 5 3 00467 __ '.uZiia. ^uD;K':' iO VaiiciauO!-, 97 89 93 90 86 76 96 62 81 93 96 97 96 97 89 94 95 78 96 96 98 80 93 98 99 90 93 83 93 97 98 95 93 87 92 88 94 89 90 94 97 66 90 — - Compound R . T . Q ion Area Cone Units 2,6-Dinitrotoiuene Acenaphthylene 3-Nitroani i ine Acenaphthene 2,4-Dini trophenoI Dibenzofuran 4-Ni trophenol 2,4-Di n i t rotoIuene 2,3,4 ,6-Tet rachIorophenoI Diethylphthalate 4-ChIoropheny1-phenylet her F I uorene 4-Ni t roan iIi ne 2,4,6-Tr ibromophenoI •IS#4 Phenanthrene-dlO 1,2-Di phenylhydrazine 4,6-Di n i t ro-2-methyIphenol D i phenyI ami ne 4-Br omophenyl-phenylether H e x a c h l o r o b e n z e n e Pentachlorophenol CarbazoIe Phenanthrene Anthracene Fluoranthene Di—n-butylphthalate •IS#5 C h r y 5 e n e - d 1 2 Pyrene Terphenyl-d14 Butylbenzylphthalate 3,3'-Dichlorobenzidine Benzo(a)ant hracene bis(2-EthyIhexyl)phthalate Chrysene •IS#6 P e r y l e n e - d 1 2 Di-n-octylphthalate Benzo(b)fluoranthene Benzo(k)fluoranthene Benzo(a)pyrene lndeno( 1,2,3-cd)pyrene Dibenz(a,h}anthracene Benzo(g,h,i)perylene 16.4^9 16.59 16.78 16.92 16.95 17. 19 17.00 17.21 17.47 17.66 17.75 17.82 17.90 18.30 19.54 18.05 17.96 17.98 18.64 18.98 19.28 19.93 19.59' 19.67- 21.76- 20.44 24,42 22.20- 22.34 23, 16 24.26 165.0 152.1 138.0 153. 1 184. 1 168. 1 109.0 165. 1 232.0 149. 1 204. 1 166. 1 138.0 329.6 188.2 77.0 198.0 169. 1 248.0 283.8 265.9 167.0 178. 1 178. 1 202.0 149,0 240.2 202.0 244.2 149. 1 252.2 24.38-228.0 24. 11 24.48* 28. 14 25.34 26.96' 27.02- 27.97- 32.26 32.23' 33.63' 149.0 '228.0 264.2 149.0 252.2 '252.2 '252.0 '276.2 278. 1 276.0 29952 166139 33587 104731 15708M 141567 16747 37375 36016 141158 50916 105966 30530 21978 67969 184467 21266 72380 34227 42132 26759 137420 160246 152866 160358 235779 64028 169177 106569 99323 51372 143236 143242 133771 66330 224915 138074 132832 122112 141180 109650 117161 43.05 40.90 42.02 42.64 49.44 42.64 42.69 42.46 43.61 42. 15 41.65 43. 11 40.27 43.87 20.00 43.61 45.30 42. 10 43.38 39.78 44.98 41.88 41.65 42.25 42.66 42.58 20.00 41.89 44.21 41.66 42.45 40.99 42.05 41. 16 20.00 43.00 40, 19 43.97 40.92 41.88 42.62 41.36 ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb 96 96 95 95 95 67 82 85 92 78 99 96 93 95 87 92 94 95 96 97 97 96 98 97 98 96 96 96 99 94 94 88 96 . 95 97 96 97 93 92 84 82 « Compound is ISTD • 300468 £rr2-2--"»S •-,-.-••' S I ' b l e d ^•'•^ vaucw^--''- TOTfiL ION CHR0ttfiT05Rfit1 File >H033D 35.6-510.0 &mu. SSTDISO TIC SOO 1000 1500 uuLt 5D00O»i £000 .£500 3000 ' • • ' ^ 6 r- CO ^Q % D a t a F i l e : > H 0 3 3 D : : D 1 Name: SSTD120 M i s c : 2 9 0 - 1 2 - S V 6 0 Ouant O u t p u t F i l e INST H ^H033D::BO BTL# 4 Id File: ID_SH::DB Title: SEMIVOLATILES BY SWB46-8270/EPA 625 Last Calibration: 950202 10:33 Operator ID: DAVID Quant Time: 950202 11:52 Injected at: 950202 11:16 300469 £)r^'<^-*>S IZ'i >.^h b u D i e a ;G -ys ijoaoor OUANT REPORT Operator ID: DAVID utput Fi le: "H033D::BQ ata File: >H033D::D1 ame: SSTD120 Misc: 290-12-SV60 Ouant Rev: 6 Ouant Time injected at Dilut ion Factor INST H 950202 11:52 950202 11:16 1.00000 BTL# 4 ID File: ID_SH::DB Title: SEMIVOLATILES BY SW846-8270/EPA last Calibration: 950202 10:33 625 Compound R.T. O ion Area Cone Un i ts •IS#1 1,4-Dichlorobenzene-d4 Pyr idine N-N i trosodimethylamine Phenol-d5 2-ChIorophenoI-d4 2-FIuorophenoI An i i i ne Pheno I 2-ChIorophenoI bis(2-ChloroethyI)ether 1,3-p ichlorobenzene 1,4-Dichlorobenzene 1,2-Di chlorobenzene-d4 1,2-D ichlorobenzene Benzyl alcohol 2,2'Oxybis-(1-chloropropane) 2-MethyIphenol N-N i troso-di-n-propylamine HexachI or oet hane 4-Me thy Ipheno I •IS«2 Naphthalene-d8 N i t r obenzene-d5 N i t r obenzene 1 sophorone 2-Ni t rophenoI 2,4-Dimethylphenol b i s(2-Chloroethoxy)methane 2 ,4-Di chI or opheno I Benzoic acid 1,2,4-Tr ichlorobenzene Naphtha Iene 4-ChI oroan i i i ne HexachIorobutadiene 4-ChIoro-3-methyIphenol 2-MethyInaphthalene •IS#3 Acenaphthene-dIO Hexachlorocyclopentadiene 2,4 ,6-Tr ichlorophenol 2,4,5-Tr ichlorophenol 2-FIuorOb i phenyI 2-Chloronaphthalene 2-N i t roan i I ine Dimethylphthalate 11.42' 6.97 7.00 10.83 11. 10 9.35 10.93' 10.85' 11. 13 10.99' 11.36- 11.45. 11.75, 11.78. 11.66. 11.89 11.84, 12, 15 12.31 152.0 79.1 74.0 99.0 132.0 112.0 93,0 94.0 128.0 ' 93.0 146.0 146.0 152.0 146,0 108. 1 44.9 108.0 70.0 117.0 12.08^108,0 13,66 12.42 12.46 12.83 13.01 13.00' 13. 16 13.41 13.20- 13.57 13.70 13,79 13,96 14.69 14.91 16.85 15.29 15.45. 136. 1 82.0 77.0 82.2 139,0 107.0 93, 1 162.0 122.0 179,9 128. 1 127.0 224.8 107.0 142. 1 164.2 236.8 196.0 15.53''196.0 15.57 15,8 1 16,03 16.32 172. 1 162.0 65.0 163. 1 27076 87758 58125 121455 97022 92483 165440 130123 96029 110160 102447 106460 63741 97207 60908 108823 83066 74189 47508 88986 91384 114295 114352 228592 47148 74261 136694 73517 52960 78707 243704 113601 46630 78587 14608 1 42175 47345 50688 53663 162138 140371 56424 176478 20.00 73.52 69.47 59,66 59.81 59.85 55.39 69.74 58.44 56.50 55.46 67.06 61.08 56.51 60.52 67.02 54.85 58,63 69,35 56,00 20,00 65.24 63.44 63.44 62. 10 56.85 61.66 63.44 68.01 69.87 58.74 60.80 58.28 69.92 58. 16 20.00 76.37 68.78 64.54 68.38 61.82 67.04 . :62..3 8 ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb PPt> ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb 98 93 97 87 85 73 99 67 83 90 93 96 94 95 90 97 93 76 92 97 99 84 . 95 97 93 85 92 84 97 98 99 96 98 90 95 89 93 86 96 94 96 63 89 D^ts .• 5;i 30047 0 OTZI-;L'^^ Compound R.T. 0 ion Area Cone Units 2,6-Din i t rotoluene Acenaphthylene 3-Nitro«ni i ine Acenaphthene 2,4-Dinitrophenol Dibenzofuran 4-Ni t ropheno I 2,4-Din i trotoluene 2,3,4,6-Tet rachIorophenoI Diethylphthalate 4-ChIoropheny1-phenyI ether Fluorene 4-Ni t roan iIi ne 2,4 ,6-Tr ibromophenoI •IS#4 Phenanthrene-dlO 1,2-DiphenyIhydraz i ne 4 ,6-Di n i t ro-2-methy I phenol D i phenyI ami ne 4-Bromophenyl-phenylether HexachIorobenzene PentachIorophenoI Carbazole Phenanthrene Anthracene F I uoranthene Di-n-butylphthalate •IS#5 Chry5ene-d12 Pyrene Ter phenyl-d14 ButylbenzyIphthaI ate 3,3'-Dichlorobenzidine Benzo(a)ant hracene bis(2-Ethylhexyl)phi ha late Chrysene •IS#6 Perylene-d12 D i-n-oc tyIphtha I ate Benzo(b)fluoranthene Benzo(k ) I I uorant hene BenzoCa)pyrene Indenot 1,2,3-cd)pyrene Dibenz(a,h)anthracene Benzo(g,h,i)peryIene 16. 16. 16. 15. 16. 17. 17. 17. 17. 17. 17, 17. 17. 18. 19, 18, 17, 17. 18, 18, 19, 19, 19, 19, 21, 20, 24 2 2 . 22 23, 24 24, 24 24, 28 25, 26 27, 27 32, 32 33 ,4'9 ,59 ,78 ,91 .95 , 19 ,00 ,21 ,47 ,56 ,74 ,82 ,91 ,29 .63 ,04 .96 ,97 .63 .97 .27 .92 .68- .66' .76. .44 .42 ,20. .34 . 16 .24 .37- . 10 ,48- . 13 .33 .96< .03' .96 .26 .22- .53' 165.0 152. 1 138.0 153. 1 184. 1 168. 1 109.0 165. 1 232.0 149. 1 204. 1 166. 1 138.0 329.6 188.2 77.0 198.0 169. 1 248.0 283.8 265.9 167.0 178. 1 '178. 1 •202.0 149.0 240.2 202.0 244.2 149. 1 .262.2 228.0 149.0 •228.0 254.2 149.0 252.2 252.2 '252.0 '276.2 278. 1 '276.0 4 1458 233834 46347 143835 2294 IM 1914 13 22698 50799 47181 182551 70800 139695 40089 29751 59562 225817 30715 96306 43448 57535 35613 178282 198728 201067 211129 296237 64479 216388 138619 129079 66496 176982 180280 162700 57891 280346 191956 155023 160536 187123 149471 157789 64.62 62.43 62.88 63.36 78.29 62.51 62.74 62.61 61.95 59. 11 62.65 61.64 57.36 64.40 20.00 60.93 74.68 63.94 62.85 62.00 68.32 62.01 62.73 63.43 64. 11 61.05 20.00 62.97 67.68 63.63 64.57 59.53 62.20 58.83 20.00 61.4 1 64.01 58.80 61.64 63.60 66.67 63.82 ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb 97 98 95 95 97 75 89 90 92 91 97 95 79 91 85 96 94 96 97 97 97 96 98 96 98 97 97 98 91 98 96 88 98 89 98 96 96 93 92 88 82 « Compound is ISTD Mecr To Vafidaiio'- 300471 oruzi'^s TOTfiL ION CHR0HfiT06RflH File >H03S£ 3S.0-Sie.O thu. SST0168 • £9e-l£-SV80 TIC 500 1000 1500 £000 - £500 3000 ' • • • ' • ' • ' ' ' • ' • ' ' , I . . . . I . , I • . . . I 708000- 600000- 500000- 400800- 3S000tt- £eoee&j 1O0O9&H 'S- ^ • Ay\- -mM\ £8 .'-«A I'.'i '. • I • • ^ 1 ' ' ' I ' ' ' £4 i tc " % . . . ^'Z'" % y Data File: >H033E::D1 Name: SSTD160 Misc: 290-12-SV80 Ouant Output File: *H033E::BQ INST H BTL# 5 Id File: ID_SH::DB Title: SEMIVOLATILES BY SW846-8270/EPA 625 Last Calibration: 950202 10:33 Opera tor ID: DAVID Quant Time: 950202 12:42 I njected at: 950202 12:06 orr-'^-'^r Dai'^ Subject lo ZazyuQH 300472 QUANT REPORT Operator ID: DAVID Output File: ''H033E::BQ ta File: >H033E::D1 me: SSTD160 Misc: 290-12-SV80 Quant ReV: 6 Ouant Time: Injected at: Di I ut ion Factor; INST H 950202 12:42 950202 12:06 1.00000 BTL# 5 ID File: ID_SH::DB Title: SEMIVOLATILES BY SW846-8270/EPA 626 Last Calibration: 950202 10:33 Compound R . T . 1 1 . 4 2 ' 6 . 9 5 6 . 9 9 1 0 . 8 3 1 1 . 10 9 . 3 4 1 0 . 9 3 1 0 . 8 5 1 1 . 12 1 0 . 9 9 1 1 . 3 6 - 1 1 . 4 4 . 1 1 . 7 5 . 1 1 . 7 8 1 1 . 6 7 . 1 1 . 8 9 1 1 . 8 4 . 12. 15 1 2 . 3 0 1 2 . 0 8 ' 1 3 . 6 6 12.43 1 2 . 4 6 12.84 1 3 . 0 1 1 3 , 0 0 13, 17 1 3 . 4 1 1 3 . 2 2 - 1 3 , 5 7 1 3 , 7 0 1 3 , 8 0 1 3 , 9 6 14.69 1 4 . 9 2 16.85 15.29 1 6 . 4 5 . 15. 53^. 15.57 1 5 . 8 1 1 6 . 0 3 1 6 . 3 2 0 ion 1 5 2 . 0 7 9 . 1 7 4 . 0 9 9 . 0 1 3 2 . 0 1 1 2 . 0 9 3 . 0 9 4 . 0 1 2 8 . 0 9 3 . 0 1 4 6 . 0 1 4 6 . 0 1 6 2 . 0 1 4 6 . 0 108. 1 4 4 . 9 1 0 8 . 0 7 0 . 0 1 1 7 . 0 1 0 8 . 0 136. 1 8 2 . 0 7 7 . 0 8 2 . 2 139.0 • 1 0 7 . 0 9 3 . 1 1 6 2 . 0 ' 1 2 2 . 0 1 7 9 . 9 128. 1 1 2 7 . 0 2 2 4 . 8 1 0 7 . 0 142. 1 1 6 4 . 2 2 3 6 . 8 1 9 6 . 0 1 9 6 . 0 172. 1 1 6 2 . 0 6 5 . 0 163. 1 A r e a 28143 126166 70575 157283 128429 119155 2 1 5 0 9 1 166309 12805 1 140032 134214 137878 85232 124256 76894 141748 103955 90584 6 0 3 9 1 114007 91933 153461 143973 281703 6 4 3 0 1 98483 171264 95373 71355 101209 312518 141987 58767 102377 186664 45596 64535 66813 72543 212188 183654 70617 230067 Cone 2 0 . 0 0 1 0 0 . 8 8 8 1 . 15 7 4 . 3 3 7 6 . 17 7 4 . 19 6 9 . 2 8 7 3 . 4 6 7 4 . 9 7 6 7 . 8 8 6 9 . 9 1 7 1 . 10 7 8 . 6 8 6 9 . 6 0 7 3 . 6 1 7 1 . 4 5 6 6 . 0 4 6 8 . 8 8 7 2 . 5 8 6 9 . 0 3 2 0 . 0 0 8 7 . 0 8 7 9 . 3 9 7 7 . 7 1 , 8 4 . 19 7 4 . 9 4 7 6 , 8 0 8 1 . 8 1 9 1 . 0 9 7 6 , 6 3 7 4 . 8 8 7 5 . 5 4 7 3 . 17 7 7 . 5 9 7 3 . 8 8 2 0 . 0 0 9 6 . 2 9 8 2 . 6 0 . 8 0 . 7 0 ' 8 2 . 7 8 7 4 . 7 7 7 7 . 6 1 7 5 . 2 2 Uni t s ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb PPt> ppb ppb ppb PPb ppb ppb ppb ppb ppb q 96 93 97 86 9 1 77 97 68 89 95 96 93 97 95 92 97 93 79 92 97 98 84 . 91 99 94 89 92 85 95 96 99 93 98 88 95 97 94 92 9 5 97 94 72 95 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 m 43) • IS«1 1,4-DichI orobenzene-d4 Pyr idine N-Nitrosodimethylamine Phenol-d5 2-Chlorophenol-d4 2-FIuor ophenoI An iIi ne PhenoI 2-Chlorophenol b i s{2-Chloroethyl )ether 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-D ichlorobenzene-d4 1,2-D ichlorobenzene BenzylalcohoI 2,2'0xybis-( 1-chloropropane) 2-Methylphenol N-N i troso-di-n-propylamine Hexachloroethane 4-Met hyIphenoI •IS#2 NaphthaIene-d8 Ni t robenzene-d5 N i t robenzene Isophorone 2-Ni t r ophenoI • 2,4-DimethyIphenoI b i s(2-Chloroethoxy)me thane 2,4-D ichlorophenol Benzo i e acid 1,2,4-Tr ichlorobenzene Naphthalene 4-ChI oroan i I ine Hexachlorobutadiene 4-ChI oro-3-methyIphenol 2-Methy I naphthalene • IS#3 Acenaphthene-d 10 Hexachlorocyclopentadiene 2,4,6-Tr ichlorophenol 2,4,5-Trichlorophenol 2-Fluorobiphenyl 2-Chloronaphthalene 2-N i t r oan i I ine Dimethylphthalate 300473 ...r^^b. 5ubieci y vaVsaatiors Compound R.T. 0 ion Area Cone Uni ts 2,6-Din i trotoluene Acenaphthylene 3-Ni t roan iIine Acenaphthene 2,4-Dini trophenoI Dibenzofuran 4-Nitrophenol 2,4-Dinitrotoluene 2,3,4,6-Tet rachlorophenol Diethylphthalate 4-Chlorophenyi-phenylether F I uorene 4-Ni t roan iIi ne 2,4,6-Tr i bromophenoI •IS#4 Phenanthrene-dlO 1,2-Di phenylhydrazine 4,6-D i n i t ro-2-met hyIphenoI DiphenyI ami ne 4-Br omophenyl-phenylether HexachIorobenzene PentachIorophenoI CarbazoIe Phenant hrene Anthracene F l i j o r a n t h e n e Di-n-butylphthalate •IS#5 Chrysene-d12 Pyrene Te r phenyI-d 14 Butylbenzylphthalate 3,3'-Dichlorobenzidine Benzo(a)anthracene bis(2-EthyIhexyl)phtha late Chrysene •IS#6 Perylene-d12 Di-n-octylphthalate Benzo(b)tluoranthene Benzo(K)fluoranthene Benzo(a)pyrene Indenot1,2,3-cd)pyrene Dibenz(a,h)anthracene Benzo(g,h,i)perylene 16.50 16.59 16.78 16.92 16.95 17. 19 17.01 17.22 17.47 17.67 17.75 17.83 17.92 18.30 19.54 18.05 17.97 17.99 18.64 18.98 19.28 19.93 19.59- 19.67- 21.77 20.44 24.43 22.20- 22.35 23. 17 24.26 24.39' 24. 12 24.4 9.- 28. 15 25.35 26.99 27.06- 28.01 32.34' 32.29' 33.62- 165.0 152. 1 138.0 153. 1 184. 1 168. 1 109.0 165. 1 232.0 149. 1 204. 1 166. 1 138.0 329.6 188.2 77.0 198.0 169. 1 248.0 283.8 265.9 167.0 178. 1 178. 1 '202.0 149.0 240.2 202.0 244.2 149. 1 252.2 228.0 149.0 228.0 264.2 149.0 '252.2 '252.2 '252.0 276.2 '278. 1 ^276.0 52805 291343 64 199 180251 31851M 240450 30134 65093 59575 229746 86961 176160 62195 37250 58598 282808 37203 119233 54436 72109 47106 220687 247359 249656 267712 384807 66414 275460 176632 166343 83947 232012 237738 209625 57796 370470 242948 207662 210557 239136 191497 200209M 76. 13 71.95 80.57 73.44 100.54 72.64 77.04 74.20 72.36 68.81 71.20 7 1.89 69.06 74.58 20.00 77.55 91.93 80.45 80.03 78.97 91.84 78.00 79.35 80.04 82.62 80.60 . 20.00 77.41 82.69 78.71 78.72 ' 75.36 79.22 73.20 20.00 81.29 81. 15 78.86 80.98 81.41 85.43 81.11 ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb 93 98 84 96 84 77 69 84 91 87 98 98 91 94 88 93 96 93 96 99 97 98 99 95 98 96 94 97 98 98 94 89 95 96 97 99 98 95 94 86 « Compound is ISTD 300474 vrZ-t-'^S . t ^ y ^ ^ i , i ^ t^tiitWi-^ui. TOTfiL ION CHR0t1fiT06RRri F i i * >H033F 35.6-510.6 MU. 8STCI02O TIC £90-l£-SVie 320000- £88000- £40000- 280808- ifceeoe^ l£eO80- 8008^ 4c-'eo&- 600 1600 1500 £000 £500 3000 ' • • • ' • • • • ' • ' . • ' • • • • ' • • • • ' • • • ' ' I . . . . I . . . . I . . . . I . . . . I , . I 6 « !Q ^ I c i" a. £4 £6 Ja f ^ T' I I I I [ I I I I I 'I r 32 < , Data File: >H033F::D1 Name: SSTD020 Misc: 290-12-SV10 Quant Output File INST H 'H033F::BQ BTL# 6 Id File: ID_SH::DB Title: SEMIVOLATILES BY SW846-8270/EPA 625 Last Calibration: 950202 10:33 Operator ID: DAVID Quant Time: 950202 13:28 Injected at: 950202 12:52 3 00475 Date Subiect To Validation OUANT REPORT Operator ID: DAVID Output File: "H033F::BO ita Fi le: >H033F: :D1 ime: SSTD020 Misc: 290-12-SV10 Quant Rev: 6 Ouant Time: Injected at: Dllut ion Factor: INST H 950202 13:28 950202 12:52 1.00000 BTL# 6 ID File: ID.SH::DB Title: SEMIVOLATILES BY SW846-8270/EPA 625 Last Calibration: 950202 10:33 Compound R.T. O ion Area Cone Uni ts «IS#1 1,4-DI,ch I orobenzene-d4 Pyr idine N-Nitrosodimethylamine Phenol-d5 2-ChIorophenol-d4 2-FIuorophenoI An iIi ne PhenoI 2-ChIoropheno I b i s(2-ChIoroethyI )ether 1,3-D ichlorobenzene 1,4-Dichlorobenzene 1,2-Di chlorobenzene-d4 1,2-Di chlorobenzene Benzyl alcohol 2,2'Oxybis-( 1-chloropropane) 2-Methylphenol N-Nitroso-di-n-propylamine HexachI or oe thane 4-Me t hyIphenoI •IS«2 NaphthaIene-d8 N i t robenzene-d5 Ni t r obenzene Isophorone 2-N i t r ophenoI 2,4-Dimet hyIphenoI b i s(2-Chloroethoxy)me thane 2,4-D ichlorophenol Benzo i c acid 1,2,4-Tr ichlorobenzene Naphtha I ene 4-ChI oroan i Ii ne HexachIorobutadiene 4-Chloro-3-methyIphenol 2-MethyInaphthalene • IS<>3 Acenaphthene-dIO Hexachlorocyclopentadiene 2,4,6-Tr i chI or ophenoI 2,4,5-Tr ichlorophenol 2-FIuorob i phenyI 2-Chloronaphthalene 2-N i t r oan i I ine DimethyIphtha I ate 11.42^^152.0 6 . 9 8 7 9 . 1 6 . 9 9 7 4 . 0 1 0 . 8 2 9 9 . 0 1 1 . 1 0 1 3 2 . 0 9 . 3 6 1 1 2 . 0 1 0 . 9 3 / 9 3 . 0 1 0 . 8 4 / 9 4 . 0 1 1 . 1 3 1 2 8 . 0 1 0 . 9 8 / 9 3 . 0 1 1 . 3 7 / 1 4 6 . 0 1 1 . 4 6 / 1 4 6 . 0 1 1 . 7 6 / 1 5 2 . 0 1 1 . 7 8 / 1 4 6 . 0 i L e e ^ i o s . 1 1 1 . 8 9 4 4 , 9 1 1 . 8 3 ^ 1 0 8 , 0 1 2 , 1 4 7 0 , 0 1 2 . 3 2 1 1 7 . 0 1 2 . 0 7 / 1 0 8 . 0 13.67 1 3 6 . 1 1 2 . 4 2 8 2 . 0 1 2 . 4 5 7 7 . 0 1 2 . 8 2 8 2 . 2 1 3 . 0 0 1 3 9 . 0 1 3 . 0 0 ^ 0 7 . 0 1 3 . 1 6 9 3 . 1 13.40 1 6 2 , 0 13, 1 0 ^ 1 2 2 , 0 13.57 1 7 9 . 9 1 3 . 7 0 1 2 8 . 1 1 3 . 7 9 1 2 7 . 0 13.97 2 2 4 . 8 14.59 1 0 7 . 0 1 4 . 9 1 1 4 2 . 1 1 6 . 8 5 1 6 4 . 2 1 5 . 2 9 2 3 6 . 8 1 5 . 4 5 ' 1 9 5 . 0 1 5 . 5 2 / 1 9 6 . 0 15.56 1 7 2 . 1 1 5 . 8 0 1 6 2 . 0 1 6 . 0 2 6 5 . 0 1 6 . 3 1 1 6 3 . 1 26756 11911 8459 19577 16505 15260 39277 23376 17217 19879 18266 18968 12165 18191 10117 19454 15261 13183 84 17 16248 99742 20273 20956 39370 8639 13288 26963 13405 6842 15779 46914 2 1344 8257 14 176 30129 46436 6073 9543 10511 3 2 9 5 9 26824 10644 35354 2 0 . 0 0 10. 10 10.23 9 . 7 3 1 0 , 3 0 1 0 . 0 1 1 3 . 3 1 1 0 . 8 6 1 0 . 6 0 10. 14 1 0 . 0 0 1 0 . 2 9 1 1 . 7 9 1 0 . 7 0 10. 17 1 0 . 3 1 1 0 . 2 0 10,54 • 10.64 9 . 7 1 2 0 . 0 0 1 0 . 6 0 1 0 . 6 5 1 0 , 0 1 1 0 . 4 2 9 , 3 2 1 0 . 7 3 1 0 , 6 0 8 , 0 5 1 1 , 0 0 1 0 , 3 6 1 0 . 4 7 9 . 4 8 9 . 9 0 1 0 . 9 9 2 0 . 0 0 8 , 9 0 1 1 . 7 6 1 1 , 4 8 1 2 . 6 3 1 0 , 7 3 1 1 . 4 9 1 1 , 3 6 ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb 96 97 97 91 81 78 99 63 85 96 95 97 94 93 95 98 92 74 86 97 99 80 96 • 95 81 66 95 86 90 98 99 95 93 84 92 92 94 85 88 97 93 57 91 300476 ..^ Ta Validatsor Compound R.T. O Ion Area Cone Units 2,6-Din i trotoluene Acenaphthylene 3-Ni troaniIine Acenaphthene 2,4-Dini tropheno I Dibenzofuran 4-Ni trophenoI 2,4-Di n i trotoluene 2,3,4,6-Tet rachIorophenoI Diethylphthalate 4-ChIoropheny1-pheny lether F i uorene 4-Ni t roan iIi ne 2 ,4 ,6-Tr i bromopheno I •IS#4 Phenanthrene-dlO 1,2-Di phenylhydrazine 4 ,6-D i n i t r o-2-methyIphenol Di phenyI ami ne 4-Br omophenyl-phenylether HexachIorobenzene PentachIorophenoI CarbazoIe Phenan t h r ene Anthracene Fluoranthene Di-n-butylphthalate «IS#5 Chrysene-d12 Pyrene Ter phenyI-d 14 Butylbenzylphthalate 3,3'—D ichlorobenzidine Benzo(a)anthracene bi s(2-EthyIhexyl)phthalate Chrysene •IS«6 Perylene-d12 Di-n-octylphthalate Benzo(b)fluoranthene Benzo(k)fluoranthene Benzo(a)pyr ene lndeno( 1,2,3-ed)pyrene Dibenz(a,h)anthracene Benzo(g,h,i)pery I ene 16.49 16.58 16.76 16.91 16.94 17. 19 16.99 17.20 17.46 17.66 17.75 17.82 17.88 18.29 19.54 18.04 17.94 17.96 18.63 18.97 19.27 19.92 19.58- 19.66. 21.76- 20.43 24.41 22. 19 22.34 23. 16 24.24 24.37- 24. 10 24.47 28. 13 25.33 26.94 27.00 27.95 32.21 32. 16- 3 3.4 8' 165.0 152. 1 138.0 153. 1 184. 1 168. 1 109.0 165. 1 232.0 149. 1 204. 1 166. 1 138.0 329.6 188.2 77.0 198.0 169. 1 248.0 283.8 265.9 167.0 178. 1 ' 178. 1 '202.0 149.0 240.2 '202.0 244.2 149. 1 252.2 '228.0 149.0 <228.0 264.2 149.0 '252.2 '252.2 '252.0 •276.2 278. 1 276.0 7753 46 104 8674 30 171 2665M 37503 3569 9723M 9236 37465 13929 29175 8156 5442 71463 52630 4599 19867 8536 11435 5274 39613 41782 41897 44950 60841 68666 44239 30267 27023 13950 38054 37346 36787 74857 6044 1 38873 34810 33352 38975 29280 33329 10.98 11. 18 10.69 12.07 8.26 11. 12 8.96 10.88 11.01 11.02 11.20 11.69 10.60 10.70 20.00 11.83 9.32 10.99 10.29 10.27 8.43 11.48 10.99 11.01 11.37 10.45 20.00 10.23 11.72 10.58 10.76 10. 17 10.24 10.57 20.00 10.24 10.03 10.21 9.91 10.24 10.09 10.42 ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb PP> ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb PPt) ppb ppb ppb ppb ppb ppb 84 93 87 96 95 76 85 89 66 91 93 82 90 83 92 96 95 90 94 96 97 98 97 98 99 96 98 93 94 92 88 98 94 • 97 97 95 94 92 94 78 • Compound is ISTD oi"i- .a-*^ 300477 Dsvj; Subiect !o Validation Inttlat Cattbratlcn Oata «SL O M Mo: Cantraetort MCE 'contract Hot Imtnaant tOt S968'l Calibration Data: 02/02/95 MinlMi W for VCC U 0.05 Nuiaui X UD far CCC la SOX Laboratory IDi HKI33F HKOSt HXS5X HttSSO CROSSE Co^eund fyrldin* N-Hitrotodlwthylaatnt Phtnol-tf 2-Chlerephonel.(K 2*Fluorophanol AnUine Mimol 2-C»\iorophanol b{s(2*Chloro«thyt)tthtr 1 ,S>0\chlorobtnztne 1,4-DichlorobMUtnt 1.2-D<chlorob«nztrwd4 1, Z'O < dl I orobenzone tMuyl alcohol 2,2'0xybts*(1.chtoropropane) k-Ntthylphtnol MMachloreothant 4'Methytphtnol M1trobtnztnt-(5 Mitrobonztne Isophorone 2-111 trophtnol 2.«'D{Mthylph«nol bl a(2-Chlorotthoxy}Bethar« 2.4-Dichlorophanol ••nzolc acid 1,2,4'Trichlorobtnzone Naphthalom 4-diloroanlUno Hexach I orobutadi tne 4*Chlero'3-Mthytphcnol RF tF RF 10.00yiS.OO > < 0 . 0 ^ .89034 .«32S1 tF '«.00 > tF ^.WX Xm. ^ r .88174 1.10756 1.08039 1.11188 1.01438 .61805 .72231 .71558 .«2693 .66304 1.M337 1.50369 1.58668 1.49524 1.39718 1.48923 1.23374 1.19824 1.23037 1.194U 1 1.14086 ^ 1.19953 1.14217 1.14132 1.16429 1.138S6 1.05848 1.12896 2.93594 2.20628 2.13164 2.03674 1.91070 2.2U26 .1.74735 1.60881 1.66912 1.60195 1.47736 1.62092 1.28696 1.21385 1.24351 1.18222 1.13750 1.21281 1.48595 1.46605 1.41248 1.35618 1.24393 1.39292 1.36455 1.36438 1.37409 1.26123 1.19225 1.31130 1.41785 1.37815 1.37658 1.31051 1.22480 1.34158 .90858 .77080 .82439 1.35977 1.27057 1.26014 1 .75624 .74342 .75635 .78472 .75713 .80913 1.19672 1.10379 1.23820 .749841 .68307 .73778 1.45418 1.40985 1.39169 1.33972 1.25918 1.37092 1.14075 .98542 .62917 1.11860 1.07385 ' .93464 .59128 .92235 .59770 1.02263 .91334 .58487 .92345 .80468 .53647 t;0S586 X RSO CCC fPCC 11.615 7.7a 6.614 S.117 3.608 17.919 6.125 6.709 6.991 6.181 5.650 7.541 7.672 6.209 5.451 8.216 .91209^' 7.258 .58790 1.13978 1.17377 1.12252 1.09551 1.01275 1.10887 .40651 .42020 .78944 .17323 .26645 .52060 .26879 .13719 .31640 .94071 .42798 .16557 .28425 .38340 .39452 .78858 .16616 .28588 .48516 .25360 .17042 .28771 .90793 .40889 .17472 .28704 .43098 .41808 .82363 .18094 .27774 .51833 .27U7 .18715 .30768 .92960 .43047 .17792 .29959 .41690 .41711 .83381 .17198 .27088 .49861 .26816 .19318 .28709 .88894 .41437 .16972 .28665 .41732 .39152 .76606 .17486 .26781 .46573 .25935 .19404 .27522 .84985 .58612 .15981 .27840 .41102 .40829 .80030 .17343 .27375 .49769 .26488 .17640 .29482 .90341 .41357 .16955 .28719 S.683 5.480 4.311 3.435 3.476 3.070 2.945 * 4.637 3.134 13.538 5.689 3.982 4.308 4.249 2.696 . y . / ** • y * y /y RF RF »S0 m Rtaponse Factor (Subscript it anount In PPB) Avtragt Rttponsc Factor Ptrcent Relttlvc Standard Deviation -, CtUbritlon Check Coopouids (•) SPCC - Sytttn Perforaance Check Conpounds (**} Fora VI 300478 tnfttal Calibration Data •SL ^IWcant! Mo: Sentraeteri MCE ract Ma: InatruaMit 10: S968*R Calibration Data: 02/02/95 MfnlMB RF for 8KC la 0.05 Maxiwi X RSO fer CCC Is SOX Uberatory 10: »RQ33F HOSSB »«a33C HtfBSD tF tF tF tF 10.00 25.00 40.00 60.00 HRI33E tF 80.00 tF X tso CCC tPtt 2-Nethylnaphthaltnt «txaehlorecyeloptntadient 2.4,6-Trichlorophtnol 2.4.5-Trlehlorophtnol 2*Fluorob1phtnyl 2-Ch I oronaphthal ant 2-llitroantllnt AltKthylphthalatt 2,6-Oinitrotolutne Aetnaphthylant S-NitroanUine Actnaphthtne 2,4-Dinitrophtnol Sibenzofurtn 4-Mitrophtnol ||k4-Dinltrotolutnc «itthylphthtlatt 4-0> I orophtnyl-phenyl ether •fluorene ^-Nitroaniline 2,4,6-Tribrcanphtnot 1.2-Diphenylhydrazine 4,6-Dinitro-2-«ithylphenol Sipherrylnine 4-8roaophenyl-phenyIether Jlextch t orobenzene FentachIorophenoI Carfaatolt fhcnanthrtne Anthracene fluoranthtnt • m • « • * « • * • • • • • * • • « « « • • » • • • • • » • • • « > • • • • » • • • • • » • a .60414 .S4967 .57038 .53285 .50761 .55293 .26156 .29397 34995 J(7419 .S5384 .S2670 • .61102 J4949 .39151 .60062 .36085 .S8270 .65271 .S9430 .41526 .42413 .39775 .41683 1.41955 1.12438 1.50556 1.28147 1.16341 1.25887 1.15531 1.07683 1.09938 1.10943 1.00642 1.08947 .65BU .39911 .45442 .44595 .58719 .42902 1.52270 1.34166 1.41901 1.39481 1.261U 1.38792 .53392 .50423 32745 .52767 .28953 31656 1.98570 1.77620 1.81632 1.84812 1.59742 1.80475 .57359 .34952 .36719 .36631 .35200 .56172 1.29947 1.07658 1.1U98 1.13681 .98830 1.12923 4.642 'i4.S95 4.890 S.645 9.574 5.004 r.767 6.959 S.965 7.765 2.B&4 10.089 .11478 .13895 .17173 .18132 .17464 .15628./<8.168 1.61526 1.45202 1.54769 1.51285 1.31837 1.48924 7.540 .15372 .17157 .18309 .17940 .16522 .17060.^6.862 .41877 .38477 .40860 .40149 .35690 .59411 1.61362 1.46459 1.54322 1.44281 1.25968 1.46478 .59992 .53588 .55664 .55957 .47691 .54579 1.25657 1.07480 1.15848 1.10409 .96587 1.11196 .55128 .33149 .53377 .31685 .28618 .52391 .23439 .21908 .24028 .23514 .20424 .22662 1.47293 1.24464 1.35692 1.26398 1.20656 1.30901 .12871 .13813 .15644 .17192 .15872 .15078 .55601 .50584 .53245 .53905 .50869 .52841 .23895 .23215 .25178 .24319 .23224 .23966 .52003 .31164 .30994 .32204 .50764 .51426 .14760 .17506 .19685 .19934 .20097 .18396 1.10863 .96563 1.01090 .99791 .94153 1.00492 1.16933 1.06399 1.10525 1.11235 1.05532 1.10125 1.17255 1.06465 1.12453 1.125U 1.06512 1.11046 1.25799 1.10599 1.17964 1.18176 1.14215 1.17351 6.143 7.755 9.086 8.235 9.629 7.526 6.534 8.177 11.435 4.003 3.436 2.032 12.435 6.372 4.129 4.135 4.818 •• m y . ^ •• •• **y . y ^ y * «F «F 3RS0 Ratponat Factor (Subtcript I t aaount In PPB) Average Retponte Factor Percent Relative Standard Deviation « CaUbration Check Conpounds (*} SPCC - Systea Pcrforasncc Check Ceepotf^ (**) Fora VI Page 2 ef 3 300479 Data Subject Zo VaUdation I n i t i a l Catlbratlan Oata # " ' Cast Mo: raetert ^ACE Contract Me: InatriMnt 10: S968-R - Calibration Oata: 02/02/95 Ninli RF far tPCC la 0.05 Haxlaui X RSD fer CCC It SOX • laberatery ID: Coapomd Oi-n-butylphthalata •yrone Terphenyl-d14 tutylbenzylphthalate 3,3'-D{chlerobenzidine Rtnzo(a)anthracane liit(2-Ethylhexyl }phthalate Chrytene Oi-n-eetylphthtlate •enzo(b)fluoranthene •enzo(k)fluoranthene •enzo(a)pyrane Indenod ,2,3-cd)pyrene Oibenz(a,h)anthracene benzoCs.h, 1 )perylene HK>33F HRISSf >R033C M033D HKOX RF tF tF tF tF _ 10.00 25.00 40.00 40.00 80.00 tF 1.70273 1.62955 1.73446 1.65814 1.64172 1.67332 1.29043 1.26156 1.52112 1.52398 1.22071 1.2S356 .88287 .75300 .83221 .84815 .77852 .81891 .78824 .7a72 .77562 .78978 .73272 .76622 .40691 .57804 .40117 .40686 .57201 .59300 1.11001 1.09150 1.11854 1.08288 1.02817 1.08622 1.08936 1.06398 1.11859 1.10306 1.05354 1.08571 1.07305 1.015261.04463 .99549 .92896 1.01148 1.61484 1.57713 1.69542 1.61422 1.60249 1.62082 1.03859 1.03599 1.04081 1.10527 1.05089 1.05431 .93004 .91082 1.00130 .89261 .89782 .92652 .89135 .89973 .92049 .92436 .91078 .90934 1.04132 1.01647 1.06422 1.077U 1.03UO 1.04677 .78229 .77565 .82655 .86065 .82833 .81469 39047 .85417 .88317 .90854 .86602 .88047 XtSO 1 2.630 S.579 6.437 5.599 4.251 5.261 2.481 S.408 2.740 2.755 4.773 1.524 2.514 4.545 2.407 CCC tPCC . y . y tr RF XRSO # ^ tetpontt Factor (Siteeript I t aomnt In PPB) Average Response Factor Percent Relative Standard Deviation Calibration Check Conpounds (*} SPCC - Systea Perfortiance Check Coopourds (**} Fonn VI 300480 .->ci.c- .;;Uuj£ci 10 Validaiiom •e/MM a » t t t r o j e e t s . D . j c H a a t / a a a a / a ^ i t ^ ^ ( ^ , •taa«ax« a«to aaqaiaiUaa flCfiBaouiau ] ^ • • r • e m - V M a t U a a i nLGaotflUani ^ea «S .dSSaiS: • e preyna ^ ^ ^ ^ ^ ^ ^ •oih.»taadard eaetflUwM i . - nalataiMuwo/PvablaM y«na«t«r rUea erif I M J tata r u « « •Ithi*"^ t t X V t M t " i l t ^ - i l - f t l u>-.^ » 0 ^ ata I a«i«-eM- 9eAF aMlysls pesMd a U « r i t w S ^ * » J *'• • • • . . . . . . . B o t appllubla •«»«»• n aaapl. M t r l a affaet (alae Indieate oc «vxe.u...«uauo« raquiiS^SsSStS S ^ s ^ 2:::::::::5:;s*jSS^"^^^^ . • « . .to.) «l^«Tal...t«e ailate/wiwatad IceaX p ^ p . p . ^ - - •, I ^ —'"i - - j ' TGiei: -ee/M xnTxnonr onMnoaa boansiT •— asa^voxATZwa lyat « Cob > m r ef the day • '•~" &•!« I I . ? . «<5 p«rf. atd. • X3 hrs. ». jure tvrm o t OS vithln tlae llalta? tU^fio\ (If no, e l B l e eotlier*) m a fiai-tiij. <^:M3 I P V S illlk. rv-ix. ny>^ lS:CU t r ' - j Ife-15 n-cT. n-tf- 16^35 rt.vl oy MCOIC.-' O l ^:£b • ^ : t l l>-3g :•: -.n 2V£i 2111 gO'^fl 0C.14 n u ZB HCI33A ••; OI i 4 0 3 3 B . ' ' e i . 4 0 ^ 0 •-•° O l HCile .•: n wci^r.-.p) M(C?7fc::Pi MCr^UNDl HC73T--0' U C 3 7 X - O I UC33K.': 0 1 c u n r xs laii) S O " . -3JTS05«e> >»To oa<c ,FaT? ' ^ ^ asTp i < ^ _tL!»S3«» C c . OPTP/3. .yrpps" APriritC<C iiqiiu^&u Si^oir UC33L.-.0( tieoOm;;pi uca3<^--P' HC330.-.p< M033P---0( ^lQ3^s.^.^cx aA/Rusa. ICfl'3C)--'Pl HO3IY-;DI •ic^ju^Ji pC3lW-0t ^C^S3X••^^DI uc33y--0| iap«i&UL)fti fiLftiJic no«,6issi fiifloctPtr flW^UPIftB S'U-ffi; ZMJ SW>^i-s>lnt> ^-M-mp SWffLSI 5-M bM. S\A^I gj"^ 0075-3 sW(^L&>M OfnS-l SvV^USS CJQ - J iiqiiuifei jaS£!i. SvygLtpCf f»-5 aA/gLg>-7 s-3 y£22*i£L svA^f usq - l i e ? ! ? >T" EJirr\-\ 'ZVUllLcfiB m-c ^ T .tat ifliiifi. ao«.SLO O f 10i ITOLT r»cT I . t . XX KT •tnt u c 7 /^ • • ^ tT&TOS V»/ OOKXKVTf riTHi''^f^3=ii T i n t)r> :iiZit^a. sss^et y y: y y y ~ - 7 zy I I4»J> tiii*. Tn ..a) fi^lim»y- ^ryj^rpy-?.: A / r" Ui o o 00 l-» • *>r 7 - 7 . 5 ^ Data Sri^j'i- ;iUc.!.i W M U I FMGR : TUNER,"DFTPP n/z ^ R w i GC/MS PERFOKHftNCE STANDARD Decafluorotriphenylphosphine (DFTPP) Ion Abimdance Criteria % Relative Abundzmce Base Appropriate Peak PeeJc 51 30-60% of Bass 198 68 Less than 2% of mass 69 69 (reference only) 70 Less than 2% of aass 69 127 40-60% of aass 198 197 Less than 1% of mass 198 198 Base peaJc, 100% relative abundance 199 5-9% of nass 198 275 10-30% of mass 198 365 Greater them 1% of mass 198 441 0-100% of mass 443 442 Greater than 40% of mass 198 443 17-23% of mass 442 Injection Date: 02/17/95 Injection Time: 14:06 Data File: >H048A Scan: 394 Status 58.99 0.00 83.33 0.00 49.90 .35 100.00 6.38 21.30 1.93 9.28 58.05 11.24 58.99 0.00 83.33 0.00 49.90 .35 100.00 6.38 21.30 1.93 82.62 58.05 19.36 Ok Ok Ok Ok Ok Ok Ok Ok Ok Ok Ok Ok Ok GR : ,TDNDOC 300482 iii Suojtci, to vaiidaiioni F i i * >He48A Bpk M» 1 0 0 . XS.O: 1 8 0 : 9 0 ^ 69 80^ * « 5 0 : 40^ t 30^ 20^ 0^r 50nsr ]&FTPP 2 9 0 - 1 4 - P E R F SUB HRM 198 T 50 / ^ 77 X27 Jut 100 iJ 1861 255 275 / ^ - ^ % 'N^ Soatn 394 7 . 3 4 t t i n . :110 jlOO ^90 =60 ^ O '•faO Esa =30 4 4 2 148 I .1 I 296 323 g ^ ^ 1 5 0 200 250 3 0 0 350 400 1^0 : -10 Data Fileneme: >H048A::D2 Name: 50ng DFTPP Misc: 290-14-PERF INST H BTL/ 1 Operator ID: DAVID SUPER GRP. Analysis Date/Time : 2/17/95 14:06 300483 QiZr^^r--- T - \/- Analysis Date/Time: 2/17/95 14:06 Data Filename and Sample ID: >H048A song . DFTPP 290-14-PERF 394 SUB NRM File: >H048A Scan #: 394 Retn. time: 7.34 B/z Int. B/Z Int. B/z Int. B/Z Int. B/Z Int. 38.05 39.20 49.25 5 0 . 1 5 5 1 . 1 5 56.15 57.15 61.15 6 3 . 1 5 65.15 69.15 73.00 7 4 . 1 5 7 5 . 1 5 76.25 7 7 . 1 5 7 8 . 1 5 7 9 . 2 5 80.15 1.025 5.802 .838 17.219 58.988 1.766 3.507 . 9 1 1 1.286 1.310 83.327 .586 4.858 11.620 3.117 63.325 3.776 4.679 2.506 8 1 . 1 5 8 2 . 1 5 83.15 92.15 93.15 94.15 98.15 99.15 101.15 103.25 105.15 107.25 110.25 111.25 113.15 116.25 117.25 118.15 123.15 3.605 1.196 1.147 .985 6.608 . 7 8 1 4.793 3.646 1.619 .879 .920 13.752 30.027 5 . 1 5 1 .236 .692 10.408 1.009 .830 127.25 128.25 129.25 130.25 135.25 136.40 141.20 143.05 148.20 155.20 158.05 167.20 168.20 174.20 175.20 176.20 179.20 180.20 186.30 49.898 3.401 19.448 2.002 1.042 .277 1.815 .684 1.969 .846 .456 4.166 2.181 .700 1.001 .480 3.507 1.945 10.098 189.20 196.30 197.20 198.20 199.20 204.30 205.30 20iS.30 207.30 210.55 210.80 211.30 217.20 221.20 224.30 227.20 229.20 244.25 246.15 .618 2.978 .350 100.000 6.380 2.604 4.907 18.122 2.889 .488 .570 .879 5.664 6.290 10.367 3.882 .887 8.878 1.278 255.25 256.25 258.15 273.25 274.25 275.25 276.25 277.25 296.25 297.25 303.15 323.25 365.20 423.15 441.25 442.25 443.25 4 4 4 . 2 5 44.804 6.274 2.010 1.758 3.287 21.304 2.075 1.530 3.963 .708 .578 1.253 1.929 3.100 9.285 58.052 11.238 .692 300484 Data Subiect To Validatlorii OUANT REPORT Op*r a tor ID Ou tpu t File; Data F iI«: Name: 50ng DAVID 'H048A::BQ >HU4eA::D2 DFTPP Misc: 290-14-PERF Ouant -Rev Ouant Time: 950217 15:37 In jected at: Dilution Factor: INST H 950217 14:07 1.00000 BTL# 1 ID File: ID_DFT::DB Title: DFTPP/BENZIDINE/PENTACHLOROPHENOL PERFORMANCE Last Calibration: 950217 15:37 Compound R.T. O ion Area Cone Uni ts 1) •IS#4 Phenanthrene-dlO 2) Pentachlorophenol 3) Benz i d i ne 7,11 188.2 6.90 265.9 8.88 184.2 66332 154 18 44953 20.00 ppb 25.00 ppb 25.00 ppb 84 96 97 • Compound i s ISTD 300485 r > , t s '^"^•'•^ -,-,lj,.5.>|5Qp TOTftL ION CHROtlQTOSPftn lee TIC S9Z 380 400 500 ' • • ' • • • • ' • • • • ' • • • • ' • • • • ' • • , 1 1 . • • I . £90-14-P£PF m i n i 8C)€ I [ I I I r Z800G 4 . 0 «> c al £ o c u i. in e.o ^ . . . ^ 7 . 0 • I . I I I M I I I t.c- • • I • • 9.e 1'.'. '.' 1 1 . t'! Data File: >H048A::D2 Name: SOng DFTPP Misc: 290-14-PERF Quant Output File: '^H048A::BO INST H BTL# 1 Id File: ID_DFT::DB Title: DFTPP/BENZIDINE/PENTACHLOROPHENOL PERFORMANCE Last Calibration: 950217 15:37 Operator ID: DAVID Quant Time: 950217 15:37 Injected at: 950217 14:07 300486 Data Subject To Valldationi RrrcrTNCX s•rp^^l^^"^^ -. ? rcrRLUi Bf.i: fit- i ^ e . 1G<>J fw-lS £.C'7 l o i J - c - l - s T N I - S e 1 ' . : " S c i o cT.;s •U'l. lit.P . ; 4 . f : ' r..:r;. j 1-160 ^ > - • X i i r 117 i:*^ 1!.4 , ^ li": 1 l i t f e'e ' loo ' 3 20 ' 14 0 leo . - A LC-O SPnPLE SFLCTF:!.!ri frfiCKC-F.OlJND JLir'RftCTC?; j n i e >Hp4oP 1 BpK' fit. £534'' . ?0ri3 DFT r r c f i i - l - J - F E p r £-.S; :.-.:r.. ! (-1CU! 4 43 52 i.'i i>% 7 7 S5 92 11? 117 .ll --.x .. 3 03 1£0 130 154 ,^^ lis ! 184 r \ 'Z-^ .y ' ..^^' I l-;-3 lie i:i.?-. 200 SfiMPLE SFECTRUr; i'iJKflLTERED) File >H Bpk fib 20oe(> 0- 0480 sens DflF-p £3344. 39 5£ 65 ~~ ^2 H E H'^ / ../ P....A"..../ y . ' ' 40 t-0 S0 106 1£0 £?0-14-PERF ^'"^ 1?" .56 y y/- i 1 • I ' I " 140 1«,0 Se*n 572 8.SS Kir.. 154 A Kiee IfS 207 [ 1 . . • 1 • leO 200 Data File: >H048A::D2 Name: SOng DFTPP Misc: 290-14-PERF Quant Time: 950217 15:37 Injected at: 9502 17 14:07 Compound No: 3 Compound Name: Benzidine Scan Numbe r: 573 Retention Time: 8.88 min. Ouant Ion: 184.2 Area: 44953 Concentration: 25.00 ppb q-vaIue: 97 Quant Output File: "H048A::BO INST H BTL# 1 Quant ID File: ID_DFT::DB Last Calibration: 950217 15:37 300487 TOTfiL rOH CHROnRTOSRfin r i l e >K048B 3 5 . 0 - 5 1 0 . e a ^ u . SSTD050 TIC 2S'0-l2-J.VcJ 160000- 140000^ 120000- 100000- 60000^ 60000- 40000- 20000- i.i I I l i S00 I l l l l I -Ll 1000 l i l l l l l 1500 2000 - ' ' ' ' 25utf 0-'»=fi=fE 3000 I I i I I I Data Fi le: >H048B: Name: SSTDOSO Misc: 290-12-SV26 ;D2 Ouant Output File: "H04 8B::BQ INST H BTL# 2 Id File: ID_SH::DB Title: SEMIVOLATILES BY SW846-8270/EPA 625 Last Calibration: 950217 15:16 Operator ID: DAVID Quant Time: 9602 17 15:16 Injected at: 9502 17 14:29 300488 iJaiaSubjecUoVaiidatioi^ OUANT REPORT Ouant Rev: 6 Operator ID: DAVID Output File: *H048B::BO Data File: >H048B::D2 Name: SSTDOSO Misc: 290-12-SV25 ID F U e : ID_SH: :DB Tille: SEMIVOLATILES BY SW846-8270/EPA 625 L a s t C a l i b r a t i o n : 950217 15:16 6 Ouant Time Injected at Dilution Faclor INST H 9502 17 15: 16 950217 14:29 1.00000 BTL« 2 Compound R . T . O i o n A r e a Cone Un i ts 1 2 3 4 S 6 7 8 9 10 11 12 13 14 15 p6 17 18 19 20 2 1 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 12 43 •IS#1 1,4-DichIoroben2ene-d4 Pyr idine N-Nitrosodimethylamine Phenol-dS 2-ChIorophenoI-d4 2-FIuor ophenoI A n iIine PhenoI 2-Chlorophenol b i s(2-Chloroethyl )ether 1,3-D ichlorobenzene 1,4-D ichlorobenzene 1,2-Dichlorobenzene-d4 1,2-Dichlorobenzene Benzyl alcohol ,2,2'Oxybis-( 1-chloropropane) 2-Methy IphenoI N-N itroso-dl-n-propylamine HexachIoroethane 4-MelhyIphenoI •iS#2 NaphthaIene-d8 Ni t robenzene-dS N iIrobenzene Isophorone 2-N itrophenol 2,4-Dimethylphenol b i s(2-Chloroethoxy)methane 2,4-D ichlorophenoI Benzoic acid 1,2,4-Tr ichlorobenzene Naph thaIene 4-ChI or oan i I ine Hexachlorobutadiene 4-ChI oro-3-me thylphenol 2-Me thylnaphthalene •IS«3 Acenaphthene-dIO Hexachlorocyclopentadiene 2,4,6-Tr ichlorophenol 2,4,5-Trichlorophenol 2-FIuorob i phenyI 2-Chloronaphthalene 2-N i t r oan iIi ne D i m e t h y l p h t h a l a t e 1 1 . 0 8 ' 6 . 6 2 6 . 6 5 1 0 . 5 1 1 0 . 7 6 9 . 0 4 1 0 . 6 9 1 0 . 5 3 1 0 . 7 9 1 0 . 6 6 1 1 . 0 1 . 1 1 . 1 1 * 1 1 . 4 0 ' 1 1 . 4 3 - 1 1 . 3 2 - 1 1 . 6 6 1 5 2 . 0 7 9 . 1 7 4 . 0 9 9 . 0 1 3 2 . 0 1 1 2 . 0 9 3 . 0 9 4 . 0 1 2 8 . 0 9 3 . 0 1 4 6 . 0 1 4 6 . 0 1 5 2 . 0 1 4 6 . 0 ' 1 0 8 . 1 4 4 . 9 1 1 . 5 1 - ' 1 0 8 . 0 1 1 . 8 0 1 1 . 9 5 1 1 . 7 5 . 1 3 . 2 9 1 2 . 0 7 1 2 . 1 1 1 2 . 4 8 1 2 . 6 5 7 0 . 0 1 1 7 . 0 • 1 0 8 . 0 1 3 6 . 1 8 2 . 0 7 7 . 0 8 2 . 2 1 3 9 . 0 1 2 . 6 6 ' 1 0 7 . 0 1 2 . 8 2 1 3 . 0 5 1 2 . 8 1 . 1 3 , 2 1 1 3 . 3 4 1 3 . 4 3 1 3 . 6 0 14 . 24 1 4 . 5 4 1 6 . 4 7 1 4 . 9 2 1 5 . 0 7 ' 15. 7 5 ' 15. 19 1 5 . 4 3 1 5 . 6 5 1 5 . 9 5 9 3 . 1 1 6 2 . 0 . 1 2 2 . 0 1 7 9 . 9 12S. 1 1 2 7 . 0 2 2 4 . S 1 0 7 . 0 1 4 2 . 1 1 6 4 . 2 2 3 6 , 8 1 9 6 . 0 1 9 6 . 0 1 7 2 . 1 1 6 2 . 0 6 5 . 0 1 6 3 . 1 1 6 6 2 3 2 9 3 4 1 2 0 0 2 6 3 5 4 1 4 2 5 7 0 7 2 5 8 4 1 5 1 1 7 3 3 7 6 5 1 2 7 2 1 4 3 4 6 3 9 2 6 4 9 2 2 8 0 2 4 1 6 3 0 9 2 5 2 2 9 1 7 2 1 6 3 7 3 0 4 2 3 7 7 3 193 10 1 2 5 3 9 2 5 7 9 5 5 6 4 5 0 2 9 2 3 2 2 9 0 4 1 59 55 0 1 3 0 5 6 1 8 4 4 4 4 1 3 7 5 1 9 7 7 1 1 2 9 3 0 2 0 6 0 4 6 8 5 2 4 3 1 5 5 1 10 6 3 8 2 0 4 6 2 4 0 4 9 9 2 8 6 0 7 8 9 9 0 1 2 9 8 6 145 17 4 2 8 8 7 3 9 5 1 6 1 4 5 2 9 4 9 2 4 3 20 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 2 5 . 25 20 25 25 25 25 25 25 25 25 25 25 25 2,5 25 25 20 25 - 25 25 25 25 25 2 5 . . 0 0 . 0 0 . 0 0 . 0 0 00 . 0 0 00 . 0 0 00 . 0 0 00 . 0 0 00 . 0 0 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 p p b p p b p p b p p b p p b p p b p p b p p b p p b p p b p p b p p b p p b p p b p p b p p b p p b p p b p p b p p b p p b p p b p p b p p b p p b p p b p p b p p b p p b p p b p p b p p b p p b p p b p p b p p b p p b p p b p p b p p b p p b p p b p p b ,_, 98 93 76 96 89 74 93 75 8 1 90 90 95 95 92 9 1 89 96 84 9 1 97 98 83 90 98 96 97 94 82 93 96 97 93 96 94 96 97 93 93 97 95 93 74 96 300489 Data Subject T o va;>'-*<=•'-'" Compound # 44 45 46 47 4 8 49 50 61 52 53 54 65 56 57 •58 59 60 61 62 63 64 65 66 67 68 69 70 2 73 74 75 76 77 78 79 80 81 82 83 84 85 86 2,6-Di h i t roto I uene Acenaphthylene 3-N i t r oan iIi ne AcenaphIhene 2,4-Di n i t r opheno1 Di benzofuran 4-Ni t rophenoI 2,4-Dinitrololuene 2,3,4,6-Tet rachlorophenol Diethylphthalate 4-Chlorophenyi-phenylether Fluorene 4-N i t r oan i I i ne 2,4,6-Tr ibr omophenoI •IS#4 Phenanthrene-dlO 1,2-Di phenylhydrazine 4,6-D i n i t ro-2-methyI phenol D i phenyI ami ne 4-Br omophenyl-phenylether HexachIorobenzene Pentachlorophenol CarbazoIe Phenan t h r ene Anthracene FIuor an thene Di-n-butylphthalate •IS#5 Chrysene-dl2 Pyrene Terphenyl-d14 Butylbenzylphthalate 3,3'-Dichlorobenzidine Benzo(a)anthracene bis(2-Elhylhexyl)phthalate Chrysene •IS#6 Perylene-d12 Di-n-octylphthalate Benzo(b)fluoranthene BenzoCk)fIuoranthene Benzo(a)pyr ene lndeno( 1,2,3-cd)pyrene Dibenz(a,h)anthracene Benzo(g,h, ijperylene R.T. 16; 11 16.20 16.39 16.62 16.56 16.79 16.63 16.83 17.08 17. 19 17.36 17.42 17.51 17.89 19. 12 17.65 17.56 17.68 18.24 18.66 18.87 19.52 19. 17- 19.25' 21.34' 20.06 23.95 21.77. 21.93 22.77 23.81 23.91' 23.71 24.00- 27.32 24.84 26.26- 26.32' 27. 17' 31.01' 30.98' 32. 15- 0 ion 165.0 152. 1 138.0 153. 1 184. 1 168. 1 109.0 165. 1 232.0 149. 1 204. 1 166. 1 138.0 329.6 188.2 77.0 198.0 169. 1 248.0 283.8 265.9 167.0 178. 1 178. 1 202.0 149.0 240.2 202.0 244.2 149. 1 252.2 228.0 149.0 228.0 264.2 149.0 252.2 252.2 252.0 276.2 278. 1 276.0 A r e a 11209 62101 13009 39390 3528M 52412 4 178 14 182 14049 50016 19780 37955 12454 7585 37751 68771 6 124 26248 12480 15675 8479 46204 50449 50448 6 124 1 82854 29792 .50752 32883 32804 17041 42449 47018 39371 36870 74450 48273 40310 42121 54993 42523 45972 C o n e 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 20.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 20.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 20.00 25.00 26.00 25.00 25.00 25.00 25.00 25.00 Un i t s ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb q 89 95 91 97 94 92 93 74 97 90 98 93 91 90 90 87 96 94 97 97 96 98 98 95 97 99 92 97 91 95 95 87 98 95 99 92 91 94 92 92 93 • Compound i s 1 STD 300490 Data Suhjea 7b Widatlon ContlMiing tellbrrtfon OMCIC :->t! t #•. v--}~V»-1.«3.-.-..-~- .. C M * HO: ;> • Calibration M U : 02^7/95 Contractor: MCE - -, -. • . V I M : U:29 Contract Mo: Uboratoiy 10: HRKS Inotnwnt tO: S968-H . . Initial Calibration Mott: 62/02/95 Mlnlaui IF far »CC la 0.05 : .'. Maxlaa X Olff for CCC la SOX Ca^mnd ' •: t f '• OF / J B I f f CCC SPCC ryrldfn* ; - V v • ; ' » • • * * » ' • • " O T 39.20 H-Nltroaodfattlt^Ualna : - ;-> M 3 I H ,96577 45.36 «ianol-<5 .. 1J189ZS 1.7D<3« • U.tA . 2-Chlorephanol-d( £::.•>•: •i^;>iil.199S3 1.25718 v S - U i, . ; 2-Floorophanol - f v - ; V • ; ^ 1 . i a 9 6 1.24363 M^ .. . A n l l l n a / ' V V.;ir.^,:k--i-.^i--';2i^«26 2146276 .;..9.74-..>/.• 2-Chloraip»Mir»l';>i-fi^?^^vi^^/1.21^ bfa(2-Chloi^tt»yl>«thirl\»|:-i^1392a'^ii4^^ rr;i9.68 ' ' ^ ' : ; • 1,3-8lchlorobaniant^^U:;V~vMl!jiw 1 . 2 ^ 1,4-Olehlorobaraana'v?J;f;j^:;>;t|^Ji;3fi5a'J • / . ^,Z-0\thlordbiiam»^::Z^y.yZ909i3Ai7»U9 •••3.00 ';. 1,2-Olehlorob«u«na/;;5>:;i:':.;<V^J;25S20 1.2U17 .,.:.1.94 ....... •anxyi'alcoJiol - v::;^/i::i;;-fi;YL.73778i^;.«2854 -^ l^:;: V 2.2'flD()6tB.:(1tcfcloi^pr«pm);^37Dn ^3^\r-";-•',' •-'•'•>••. ' ; 2 H N * t h y l ^ l H M ^ 5 | ^ ^ i 5 ^ ; ^ ^ .viviv; '••Nftraie-dt-n-prdpylaat ••» 'iW. , Maxachleroetiun* 4-ltothylpj»wlvj:;(_^-i^fi;:ii^ ••< 11.95 Z y . i l t r o b i i m i m - t f ^ ^ -'•/Z « f t r o b « a « M ' ? ^ ^ ^ ^ ^ i ^ ; ; | ; i i | j / ^ 4 ^ 'AZ ' ' l » e t i i o n r i » ^ A ^ A ^ y - ^ l ^ f f ^ A - 0 Z ^ ^ ^^5.45;'. / • 2'»\tn(iimiaify^A^ • .. 2 . i - 9 i m t h Y l t i m i o i : ^ i ^ ^ •••.4.52 .' '-/ bU(2-Chlorettfcoxy)Mthane^£i.49769k.5S636 ;'l7.82 2,4-0lchloro(<»*nol.s;^\i^f(i^;i|^:vi26«8^^ .zS.n 1,2,4-Irlc*loriBbtnMotQ-Vf^-'^*29482'.X2905« v':1.U -Zl-' .Uaphthalane'.; A y & Z 7 ' t z . :^ v.:>90341 ^•^.97111 ; 7.49 - 4-Chloro«lllnt i•i;,•^vrv4i-i^.•^.41357. .U714 8.12 ««xaehlorobut«««» •>;•. • V V ' * ' 5 5 . 1 5 3 5 9 9.41 • / 4-Chloro-3-Ht}iylphanol..i 1...28719 ..28998 .97 * / /y.. IF , - iBsponM Factor frca dilly atandard f U a at 25.00 PPB IF y y / k t % n ^ Itaponaa Factor froa Initial Cat (brat f on Fora VI • SDiff • X DIffaranca froa original avaraga or curve CCC v'r/; Calibration Check " c ^ ^ ...J-i^y-:/yZyzy'.y-yA^wii.svi'\:*»a* A tizV-.A-:v..z--:r- .rA:-- • y m t : m ^ ^ 4 ' y ^ i : m y M . m i y y : . Z . ^.. ZyZZy;• ::,:;.• :z . 3 00491 Data Subject To Validatlori Continuing Calibration •St CaaaMo: Contractor: PACE Contract Mo: inatnamt t t t 5988-H Mlnlaui IF for SPCC la 0.05 Calibration Data: 02/17/95 Tiaa: U:29 Uboratory tO: HI048I Initial Calibration Data: 02/02/95 Naxlaui X Oif f for CCC la SOX Co^iound IF IF » l f f CCC SPCC 2-Nethylr^htiiatana Haxachlorocyclopontadiane 2.4.6-Trldilorophanol 2,4.5>TrlGhlorc(ihanol 2-Fluorobiphan/l 2*Ch loronaphtha tana 2-Mitro«iillna AlMthylphthalata 2.6-Oinltratoluane Acanaphthylon* 3-Mitroanlllne Acanifiitiiane 2.4-Olnltrophanol . Olbanzofuran 4-Mltrophanol : : ; 2,4-Oinltretoluane Zt^zA 2.3,4;6-Tatraciiior(^anot Oiathylphthalate.J V . 4*ChloreFhanyl-phanylath«r -Fluorana 'Z''', 4-Nitroantllna 2,4,6-Trlbraiaphanol 1,2-Olphanylliydrazina 4,6-fiinltro-2*aMthylphafwl OiphanylaHine 4-BroM|3hany( •phanylather Maxaciilorobanzan* : • Pantachlorophanol .' Carfaazola Phananthron* Anthracana Fluoranthana .55293 .57395 3.80 .32670 .25141/23.05 .38270 .36316 .41683 .40597 1.25887 1.19934 1.08947 1.10507 .42902 .40631 1.38792 1.37709 .31656 JS1346 1.80475 1.7S667 .36172 .36380 1.12923 1.10155 5.11 2.61 4.73 1.43 5.29 .78 .98 3.77 .57 ^2.45 .15628 .09866/36.87 1.48924 1.46571 /1.58 .17060 ;;11684/31.S1 • -...39411 >J»660 • . JTO45' j»288 ' 1.4647B lJ987t . .54579 .55315 1.11196 1.06142 U2391 ^34828 .22662 .21212 1.30901 1.45736 .15078 .12978 .52841 JS5623 .23966 .26U7 J1426 J3218 .18396 .17968 1.00492 .97913 1.10125 1.06909 1.11046 1.06907 1.17S51 1.08587 y-:res •: ^6.06 4.51 1.S5 ' 4.55 7.52 «.40 11.33 13.93 5.27 10.35 . s.ro 2.33 2.57 2.92 3.73 7.47 . / « / • . • • . . • • • * . ^.i:^ rr} '.-/- » • , . / Z{'' y Z Z \ -V •>?.•:?;:•.•>:.:*; •'•• ••• Z \ •z^my'^zzA^^Ay-my'-'Z, < : : M.:-.^. r " .^K*Jl;^•.••.^•;•• •'.';•• ' - • • • " • • > • . . ' i • . •i.->?i4ji,y>.^<s'!r-ito?ip.>'.y.s.v:- izZz^.^-. .-z 'yf':Z:Z-A'-X'ZAjy".AZ •'- '- k ' .'- AAZ'- ' Z y Z/^ Z'Z-: '.Zzy. •A'-y^-^ yi-ZAz/ 7A''-AA P-'-^-y •-'.-rry-'-^ ?^£.^^^^:?•..V!•ts^iii;•:•:^••^.•<. -. y "^yy7r'7^'*'-^y^<y^*^^^i--^A. '- *••^-:.-:N*. .4 'iJ77ZjZ. .V .•'•:; 5i",-* - * . . " ^ • Z ' A A '-' '-?.--Z - - * . ' * - . • ( • •'; -^r'r-izA z'y'Ar'.rX.y- . - . : i t . ' . . ' •''j.ti^.fy IF • latpona* Factor froa daily atandard f i l a at 25.00 PPB IF .- Avarage letponaa Factor frca Initial Calibration Fora VI ;-' • -ZiZ '•-'Azf/ SDiff - X Diffaranca froa original average or curve ., kCCC • Calibratlon Oiack Coapouxii (•) A- SPCC - Systea Perforavwe Check Coa^wnds (**) - •;:• . •.. -y ,..Zz .LAZ- - Fora VII / Page.'2 of. 3 ..'ZAyyAl y;y''\'-A'i''y-ZZ\Z'z-.ZZ-Z--- - • . . • . • • . . • . • • . - • . • " • ! • » • : • • • : • • - • •.•-.. • •• .'•.-.••.• •.•..-•! ,•.•.,..» ••!. .',••::-..•--..^-.--yp-.-'.yw- • • ( • - ; r^-ji :--';-..'t-- . - ^ i i ' " . - ; juu^./*. .-^.^:-./'•^.^/,;••;:Jr'i%<V^'^-^•::•^•^^;.'^^^^^ Z-Fyy^'yAZyAZii^Zyy Data Subject To Va!idation! /••'\y.: •• • - ' y •-: ... ••u i,r: /:^VV- Cariclmilnf Catlbratlan •AyAA'y..m Mo: Contractor: PACE Contract Me: .•.•.••,•:.••';.•: InatrtMnt 10: S9e8-M • • ^ ^ ' - . . . ^ • ^ . ; . „ , . ^ r , - . ^ , Z . • ' , . : • A • t - - Callbratlan tata: •2/17/95 Ttae: 14:29 taboratory » : >M048i Initial Cal Ibratlon'»aU: 82/02/95 -'Mlnlaui I F f o r SPCC la 0.05 -. ' •; N a x l u i X Olff f a r CCC l a SOX Compound IF IF aslff CCC SPCC • • •l-n-»)utylphtl»alata;j^i;?-.^ i-1.67332 1.75580 ;^v4.93 ;•:•.:•• • • Pyranav ••••••^••-^^'''V;'•-':•:;' 1.28356 1J6284 .;-.«.18 :.^ • .T*rphanyl-dl4 V'.v$::--.i_.^:-./... .81891. .88300..:; 7.83 . • • ', »utylt«ttyl|Ati»lata.'!/|Vhil^^;y^.76622 > ^88088 ;I.;U.96 -A-. -• - •. 3,3'-0lchlorobenxldiri^V;&:-::-^_ J9300.;J;457S0V-^16.«^ ^^^ .•rianzo<a>ar«thraiaBr>aji^ri:j&-^:y^^ 1.13988'ii;;4.94 A.. Z '• ••'- ^;lblaa•EtbyUMxyt)pht^lata\^^ 1.085^ >^ • Z-k-OiryUnt}Z0f&i0!;^0AZ^ • • . % C l ^ o c t y l p h t h a l r t i ^ ^ 1^«082'.1JS154i_^Vi33' y. z ^iantoOWfluoriintbana1«^;f^^ .1.04742'V!^;^;;.65 'A :'Z.ri^-z- •^•«lfl»iCk)flubrantban*:i'i^^I>••*:^;^ .92652 ^i»«7464 ••;>; 5.60 ^. 9.60 •• / : y :.51 - * • • ; •anxo<a>pyranaV'i^'^:5(^N;^::iVi90934 ;>;.91394 y :.51 - •« ;:;vJnbano(i,2,S-«6piinrwj^i|T^^ ;• elbanz(a>>antfaracana)«i^,^«>;H^^:.^1469 .92266 ..13.25 -7^m^mmm9m:i'm'!»mz^z .. •zzm^':z^m'''iyu^^^yyyyz'-.: • •• ^^> • • ' . • i ' - ' - • • ; • » ; . v . - • • ' V ' • • : • • : . • • • • . • - • • ' -•zzyy'>y'y:;mA.zA •.;• ••-. , . . I F • ' • " ' • ,.'.Vj?r/r iv.X- • . ' ^ ^ • ' ' ' . . ' ' ilasaonea Factor.froa daily atandard file at 25.00 PPB . .-.••; ~"t':->i-';-V»'•rf••-^^ ••'f-rVV'-rr \";'---\ •;•••.•• . ;•••.-••.*- :-' IF.;:7<:<rVAv*ragelaaponaa Factor froa Initial Calibration Fora VI : •, :-y:'''':z^<^z;.Z'''''Z}Zi^:^A^yiy:-y.'•^\Z'-' '..y-t'-'Z. z . • - • '., IDIff • !'X Oiffaranca^ froa original average or curve . *- > - < - - ' - V ; > - ^ ^ • ' ^ • • ' - ^ ^ • • f * > ^ ' - - ^ ^ ' ; ' ^ ' - • • - • < . • • . ; ' > ' • • • - • • • - - • • '. '-. •••<^im/j'f(rA>r'-'^-v^yy ^^'•'•': '-zr :• .-••:.;..•:• • '•• •• .'.'^> -t.t. ^ . . . . . . . . . . . t- ^ I - m ^ . • - . • ! < • • — • \''•<'. r*- 'Z •-. ' l i - . f ' ' - Coopowsis (**) . C..!-:;"^ 300493 '"r_ ^•Z-'Zy.;-:i']r^J'i TOTAL ION CHROMATOCRftM • • . • • • • • • " - • - - I • • • - " • • • . 1 • . . • " • • • t • • • . r . . . . I . . . . p . . . . I • • • • P . * * • , j , 160000 140000 1200O0 100000; 80000^ 60000; 40000- 20000- O T J ¥ I'* 1 ' ?« 86^ y-.- 4fe *7-A '<;: »y •Nl H /.yo. •A CN4 ica I I I I I I I I f i » * « r * > t f i a y ^»M*»a» 214 2 b - a f e - - Data File: >H048L::D3 Kane: 12158WB2 Misc: BNA LAB BLANK WATER Quant Output File: BATCH / 12158 ^H048L::BQ BTL/13 Id File: ID_SH::DB Title: SEMIVOLATILES BY SW846-8270/EPA 625 Last Calibration: 950217 15:16 Operator ID: DAVID Quant Time: 950217 22:48 Injected at: 950217 22:13 300494 Data Subjea Tc Validation QUAKT REPORT Operator ID: DAVID Output File: ''H048L::BQ Data File: >H048L::D3 Name: 12158WB2 Misc: BNA LAB BLANK KATER Quant Rev: 6 Quant Time: Injected at: Dilution Factor: BATCH # 12158 950217 22:48 950217 22:13 1.00000 BTL/13 ID File: ID SH:sDB Title: SEMIVOLATILES BY SH846-8270/EPA 625 Last Calibration: 950217 15:16 1] 4) 5] 6] 13] 21] 22] 36; 4o; 57 58 70 73 77 79 Compound *IS#1 1,4-Dichlorobenzene-d4 Phenol-d5 2-Chlorophenol-d4 2-Fluorophenol 1,2-Dichloroben2enc-d4 1 *IS/2 Naphthalene-d8 1 Nitrobenzene-d5 1 *IS#3 Acenaphthene-dlO 1 2-Fluorobiphenyl 1 2,4,6-Tribromophenol 1 *IS#4 Phenanthrene-dlO 1 *IS#5 Chry8ene-dl2 \ Terphenyl-dl4 ( bis(2-Ethylhexyl)phthalate \ *IS#6 Perylene-dl2 R.T. 11.08 10.52 10.77 9.04 11.41 13.30 12.08 16.46 15.20 17.91 19.13 23.95 21.94 23.71 27.33 Q ion 152.0 99.0 132.0 112.0 152.0 136.1 82.0 164.2 172.1 329.6 188.2 240.2 244.2 149.0 264.2 Area 11045 58016 44110 37836 14443 39395 32251 18695 44114 14168 26701 29405 45425 11539 29858 Cone Units 20.00 ppb 61.64 ppb 64.56 ppb 55.09 ppb 33.32 ppb 20.00 ppb 39.52.ppb 20.00 ppb 39.35 ppb 71.46 ppb 20.00 ppb 20.00 ppb 34.99 ppb 6.22 ppb 20.00 ppb q 98 92 89 79 98 99 88 97 97 87 93 98 95 91 97 * Compound is ISTD 300495 Daia Subject To Valldatiors KZrznttlZC iTfiNDSRD SrCCTSjri r»ie r-jfie tu nix-i 1-4? 103- llSl-:;.^ 40 ?c : ? o itT- ?.' LOT m z i i t t i 2 N I T :-4fi • i . sf j ttl 1 f . i f-lOO ,1^0 f.BnPLE SPCCTRL-:-. ap::.CKO.ri? ?-..:•• F i l e >HC4C.i. l i i ^ t U ' - . Bpl; fib 7 6 4 e . Zl- .71 !i:ir., i i : ' ~ I i •= '-r.--'-'.-. ^ 1 .ll*. Z'^HCZ £tirl u.'^: I-. M'*' - t ' . ' Z - t r : e .-. J-. ' i . * :M ; r.. : r 1 Data Flit: >HCJ48L : :D5 Name: 12 158WB:' Misr: BNA LAB BLANK WATER Ouant Time: 950217 22:48 Injected al: 950217 22: IS Ouant Output File: ''HC)48L::BO BATCH # 12 158 BTL« 13 Ouant ID File: ID_SH: :DE: Last Calibration: 960 2 17 15:16 Compou n d No: 7 7 Compound Name: bis|2-Ethylhexyl1phthalate Scan Numl^e r : 2 13 1 Retention Time: 23.71 min. O u a n t l o n : 1 4 9 . 0 A r e a : 1 1 5 5 9 C I) n (• e n t r a 1 I o n : 6 . 2 2 p p t> q - v a l u e : 91 300496 o.^^ CnKsPftTo Validatios-s TOTAL ION CHROMATOCRftM File >H048M 3S.0-S10.0 AMU. SyuUGOl HGS RBS0/^013195 HflTE SeO IOOO 15O0 2000 , 2500 3000 • • • • t . . • - ^ • . - • • - . 1 . . . . I • • . . • • . . . r . . . . I . . . . I . . . . I . . . . I - . , . . ^ ^ 220000- 200000-j 180000: 160000: 140000-i 120000-1 loeooo: 8 OOOO-! 6 0 0 0 0 40000M 2 0 0 0 0 0 •5 B "i ^ r ^ J i ^ ^ n r III S2 ' ' ' ' ' I 16 t 1^ .i I. l£2 M-F • * ^ J '^^^ 55 /9P5 1 J | I I I | 1 I I I I > ' I | 1 I I | ' | I T 24 [i Data File: >H048M::D3 Name: SVWGOl HLA Misc: RBSO/013195 WATER BATCH # 12158 Quant Output File: *H048M::BQ BTL#14 Id File: ID_SH::DB Title: SEMIVOLATILES BY SW846-8270/EPA 625 Last Calibration: 950217 15:16 Operator ID: DAVID Quant Time: 950217 23:31 Injected at: 950217 22:56 300497 Data Stjbiec' '10 ^/znoaxi^ QUANT REPORT • Operator ID: DAVID Output File: *H048M::BQ Data File: >H048M::D3 Name: SVWGOl HLA Misc: RBSO/013195 WATER Quant Rev: 6 Quant Time: Injected at: Dilution Factor: BATCH / 12158 ID File: ID SH::DB Title: SEMIVOLATILES BY SW846-8270/EPA 625 Last Calibration: 950217 15:16 950217 23:31 950217 22:56 1.00000 BTL/14 1] 4] s; e; 13] 21] 22] 36] 40] 57. 58, 70] 73 77, 79- Compound *IS/1 l,4-Dichlorobenzene-d4 Phenol-d5 2-Chlorophenol-d4 2-Fluorophenol 1,2-Dichlorobenzene-d4 *IS#2 Naphthalene-d8 1 Nitrobenzene-d5 1 *IS#3 Acenaphthene-dlO 2-Fluorobipheny1 > 2,4,6-Tribromophenol 1 *IS#4 Phenanthrene-dlO 1 *IS#5 Chrysene-dl2 1 Terpheny1-dl4 I bis(2-Ethylhexyl)phthalate 1 *IS/6 Perylene-dl2 R.T. 11.07 10.52 10.77 9.05 11.40 13.29 12.07 16.46 15.20 17.90 19.12 23.94 21.93 23.70 27.32 Scan/ 661 596 625 425 699 919 777 1288 1141 1455 1598 2159 1925 2131 2551 Area 15040 76304 55487 50263 18190 53465 41673 24881 52508 16551 32838 32545 53447 13268 35626 Cone 20.00 59.54 59.64 53.75 30.82 20.00 37.63 20.00 35.19 62.72 20.00 20.00 37.20 6.46 20.00 Units ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb q 98 93 89 74 99 98 86 94 98 90 89 98 96 88 97 * Compoimd is ISTD 300498 13at3 Subsec t •Tr F.E:F^^E.^Ct: jTfir.'DflFD fprcTRuri F i l e ;PCrcCt EN ril>--l trl.: fit' l e e . LOT 33 'JB Nfttl If;:T tear-, £?5£ I J ? lOCv 5 7 7 1 1 1 5 l 3 £ i-103 ^ J l f J l i H ^ W . * • » , .)fc«i 1,11, iL . l l , 40 i'." V c. - 'J -1—1—r-^ SAMPLE SPECTF.utl vE:?.C I::;=:OUN:I 'JUETtccTrr F i l e :-H04S;ri SVVV'r^Cii Bpl; fib 7975.- ,. J .. -. Ji) J K , hLK .•^r :.-LiB I J . - O ;::ir-.. I ;^--f i L I - t . c V -j !' ; 'Z . Data File: >Hu48M::D3 Name: S V W G O l HLA M I S C ; RBSO/013195 WATER Ouant Time: 950217 23:31 Injected at: 9502 17 22 : 56 Ouant Output File: 'H0^8M::BO BATCH n 12 158 Quan t I D F i I e : i D..SH: :DP Last Calibration: 950217 15:16 ETL** 14 Compou n d Nu: 7 7 Compound Name: b1s(2-EIhy I hexy I ) ph I ha I ate Scan Numbe r : 2 13 1 R e t e n t i o n T i m e : 2 3 . 7 0 m i n . Oua n : i o n : 149 . 0 A r e a : 1 3 2 6 8 C o n c e n t r a t i o n : 6 . 4 6 p p t; q - V a i u e : 8 8 300499 Data Subject To Validation O - '.o o x*t t *>»*»« I p - I S JA now smt« Bata l«i«Utt,iwi Bccanflitt a.a iimin. t a.a> i..j<& eels Xaj XnJ ec dMelptem «. wimlfffYi, BTnT-WL IB OBnaitlwia _ Sew M>Bg*;.,a5-gQB,Mg. ___ teaa z*t« t i •/•can «• I M g B l l t t S i - OC prosxMi t • «f<iiini tB aM t u/SSI Iriintainnoyri IIIIIMI »'• -^ rwaastwr rilaa i ' ~ * / OriglaU. tota Mlatf Vltbi. •taaterA X—ttitl—tte— « apika P T I i i t t M «f atatfaa/oeHwata o a l a n aa analysla'paaa«4 a l l eritarla . . . . . . . . . . n o t afrplieabla CO ...eazxr-fixrar e r e e w t a a l m t l n n aoapaotad n/la*al...dilBtlaa caqoitad/aaggastaa laval M l 7y>o -<S- »jnii>*o J»T»._£i£U±lli^lL as aa^Aa aatrlx aftaet (alae iadieata fiC axouraioaa. Cor axaapla, JM»', MS*, ate.) n ...ra-«ittzaotlea raqairad l t R . . . . . . . . . r u u a raqoixad n / l a T a l . . . t o e dilnta/eaggaatad laral D-D D D DCiC'C-r-tCC-C-C-C-C-C-C-C- wtiCB-Qe/wM XBBtmaoH oi D a t a 1 S n . c , s O o cr> CTJ TXHB 0 H:dw ul i w . - t ' i 1 e i ' i lUoM |le:MT n:3l \ ie:3o W.1i n:6«7 2o:««-f ai.-a-s 02.-/^ i-J.-MO Oo.lM 0 ( . t * 01'.sa- 1 ^ S 9 n u X9 - UO»J8A::£>2_ UOUeg.'.-OT, HOUAC ••••Ol- ucMe e .-.• Ox ut>«*«P.-.-D7 ucuaCf.'oi. uolfftH.-: o z . H o u e r . - : 02.851 JOU6 5.-:D» uoii'eK.-"i» U0U«l.-'-Dj HC)U«m;;D5 « a i * o . . : 0 - i ucueP.'O'i vteueo.v on ^.^ ^.. • n x n o m t t a t m a r • — • _ _ J t R r o f t i M d a y _ _ _ P « r f . S t d . • « h r a . SSTIOfl»P-.ft av/AffSl aM€*iS la iS«AiJ8w t t o i f aA*AffiR Rtt>-a SUVXAaito « u > T tianuu>iSL «*«>c. n . i S 6 U j « : i *i*.K. 5;iA/i.»rirnu r?.-^ 3Wi;**J,0-7 fh. - -7 ^.^ " • ^ ^ ^ "^^-.^^ --<. IDdld JU!. n i - T D U T X I M t , o - 2 . : o U AMT ZX7 - 2 . \ • « • ^ ^ ipT BMCH _ i" liiMK 12 Sti ITZMM 1 11-1 s e -. ~'"~'^>-^ . TT 73nni a r t O f "— — — ^ • 1 11.7 1 1 1 illij^' t u M w i t h i n t i a a l l a l ^ T m ^ NO (Xf n e , c l t c l a e o t l l a r a ) NULT n e t ') Z . I y t y ?f •* * tf- f^ y •y y i y > * • A KT m' y • r t .f y <-' .^ • • y y y y • / f' '7T u c y i . y f- • * * y * • y y y * • tl- y (^ COtOQDRfl • S U . ^ J t . siy 5*/ '(KJUi' s ^ Ada/fiti Shf <*K**+u^ S ^ S H nciti/Ctm <;^ Attti t e U / i i r •• n n t- • ^ *trz. UJ cn o o « . . . MVXB HTiaOMMSIRat. U a o U T O t T o •Q/v oanrnam onuTZoaa LOOSIUT o BBXX-TOUTZU* paga 1 e{ 3 Oatas. ««J y w j a e t Z.O. • (cllant/eaaa/adg) i, l l ixJlL. Xnatruaant J _ J E _ •taadard Data »e«ttisitlaa t a r a a a t a r a « e r •aal-Wolatilaai J l ^ n e w ^ H i a a d ^ • r e e l u e g e n n d l t l n n a ew r a t a l 3.8 al/alty^ praarara t jQ B»1I - Oeluan i ruaad s i l i c a c a n i w , ' ^ . Zajaetor taBp.t.j;ut_ I.pya r u i - ns CpntfUlcni scan ranoa! 3S-8oo aau •can- rata t i «/«ean ,«H voltaoai IT'It' U ^ a e t m m>i» x Hod S e l i t l a a . c e daaeiptera i Mai.ni«..«iv. PPTPP-UH ee.pvegraa t 45 f4alni t o aoo a n / - f » . . H.Dtt»t»«<H •taadard oeadiUoaa t "^ •alataaaaoa/rxoblaaa i ffaawatar r i l a a i S y / l P l A - ^ A%> dgrlviaal Bata r i l a d a i t h i •taadard I d a a t i U e a t l e s a a Splka aaeuatai Tareatai a4»->;:-j'vi»'*.r^ 1st •3't'}-il-JyCfHi^> •m Kaapeaaa Paotorai ~" orrppt i¥V'fi'yya/f p1>.-: -••St-.!: **<l*ltiea af Statua/Coaaaata celaaa aa Bus I«g (paaa S)i •• analyaie paaaad all critaria HE ' not applicabia O0.........carry-ovar or contaaination auapaetad • wi...•..•.. OVlaval...dilution raipiirad/auggaatad laval RK TO/laval.. .aaapla a a t r i s a f f a e t (also indlcata QC axcuraiona, for axaapla, ZS3t, SSSt, a t e . ) . r a - a x t r a c t i e n raquirad • ranin raquirad .toe diluta/au99oatad favel •OLP aooTB smnROMNZifna UBOMTORT •e/xa xasnoKzirr oMaATZOMs IIMSHEBT - ~ SBXZ-TOUTZUS Analyst i 0 ^ ^ ^ RRF of t h a day xJZ. Oata i I ' h h l Perf. Std. • IJ h r a . j J i l i L . payo a of 3 Ara n>na within t i a a l i a i t a ? \(ta) MO (Xf no, c i r c l e o u t l i e r s ) OP l i l ^ S M : i f li'iCt £:u_ »:>t g j l i 9 l H A o o CO r i L B ID n i ' i i n i i ^ S t i i t f ^ i * tiiiiwy. i f l a a ^ i e »JH*^1f' CLietrr ZD ( d i i ) t/rff J t r c try J j r e i t - f yjrer*f- SlTBi-if JXIofff AKT ZMJ M. iJ. U. U. LL U OC BATOI gur KOVt FACT I . S . AK RT ^ ; BOR RZC 8TAT08/ COKXZIITS TAPS SM l-n^iA 1 ^ X X X -.M Ui o o Ul o I Data Subject To Valldatlorf' • o •• o OS •iMlyt< ,gys±!L jiihL. t.%r fns«r/r»w^sd|)i:i. tt_£. S«C 2 g? Banflltlmw aetar aeda x j S Z S S S S L •e daaeiptera • aaani—gv. PWPIWW — «.«s f4alT.< t o >BP a i p / J ^ •LfiBBdittUni »saya« aa-ggfl ML. zata ' i,f/«e«" »oltaaat~77;t. I - rUaa .ZZ2Z22E erl«iaal Bata niad U t h i ^ •taadard XtetUiaaklaaa • • a r e f t lit, f,i.^ry:.r Ml J9»-»^-A0y/»»^ % :r *• % ^ i22LJZL££IiL. •aXiaitlaa af •tatha/OMHMata aal«* aa a n \m% lyava SM "'^VP^/Z'^fS^ » " oritarla « . . . .aaapla aatrlx aCfaet (alae ladieata flC .........aec appxieaaia aaooraiem. fer aaamla. 2ss*. ssa*. ate.i £>!;::;•••S?f27*« «*.?»«t««toatlea aaapaetaa « . . ; ca-aatraetlea r a ^ S d ' " • ' • " * • ^ • ' K/la*al...dUatiea raqalraVaagaatad laral Mt tana raqairad tS/Xa«al...tae dUBtVaav^aatad laaal D DMMCCC-L-C-C-C-C-C-C C C-i- A n a l v a t l Q , / U f * M . f. «BV a f t h a d a v . . u i^^p/z/fj- * • n © 0 tn iCk n n 0 iC:>i >» //:>y' Ji« n-.ti^-^ ly.iif J- / ; y v fc. <</r^ 2i /y-'n-^ > /r.je 9^ //.•-T ^ ll:>(f \ Ihkz ^J-vV ' i r - y ' •u-.iZ' •va-.n'' ' I \. -V. r pzta s» - » ^ 3 # / f J - T - s»i*nrs fHli^Vut^ . f^yKvt>it- - f y i i » t ^ . /VtW#/ - iViy*'irT*i ...f/vynif " f/li»na^tl (•/i^ycn ff- /Yiiirrun (vnirti->t> SVvTf-lf /i/VTmf r/KTH*i \^ r^Vsf*) - SViWf) - / v / / / » • » • ^ — . . ^ ^~~>- Parf. Std. •• 13 hrs. etosn sp^dii) £/r/^ srfD^sf S l U i r y 6itCMAlit OmPttin r-la /s/fi/tunr ^ i / r / c / i M r fiULf. ^u^r . / l i t w g'iJ- m Stut^ SiAyt- fftKt t U v l d i l i r tftiOOi Cfit, C^tufalin UtKiMA^ PA-> / w - » 0A-\ -r ...^ -——.^_^ / 1. •TDtasxuu l.jt; o.fte 2 ^ : 3 / AKI 2A.. Id.. Vi W III u. XT w a,-f 1 1 ^ _, lay 1 Wr aSlai m. - - iZeft / / i ixr>tr i /»!> i^ mry I :.^_^. . Ara OX* / » / 10 J 1 al 1 1 1 1 1 1 1 9* •^ "? y\ "^ ~- ram wlthia tiaa l i a i t a t H t e ) «D (Xf ae, elzBle eotlieri) im.T TACT J^ _ • C J -—>. .. ii'i. — - • ' if y y •^ y y y m^ y ^ A r*C _ — - < »-' *^ • .^ -^ y y y r - — a f y — ^ J?. r" U •ITB RSC - • ^^ y.. ..- y r ^ r - y y . y r ' •.^ y — #w ^ • " a STATyS/ -^ • y y y y y y i / t y y y y y y fa t l i f i fTZZqatir - OPS r-f-^t -1- 1 Sa^ w o o Ol o to Bata SubjectTo Val'dav!on -• - y 300503 Data Subject TcV^Udatlon ! • ' H - » I-i- in ZZ n. w o o tn o tt*- •ex. o ; i 'jy. (i -I 5 0 . 8 - fi'-Z 180.0 -1 59. S- MASS SPECTRUM 02/20/S5 9:31:00+8:03 SAMPLE: DFTPP 23Q-14-PERF CONDS.: 0.25 X 30M PJX-5 l.OUM 45/4-300212 INST C #488 TO #4S0 HUE.RAGED - #434 Xi.Sy DATA: CP322095H #483 CALI: CP022035A ttl 198 BASE M/Z: 198 RIC: 8672. f^Q 2 0 1995 M/Z GC/ti3 Tuning and Mass Calibration DECAFLUOROTRIPHEWYLPHOSPHINE Case Number: Laboratory; GULF Contract: Inst ID: C Sens Date: 02/20/95 Sens Time: 9:31:00 Lab ID: CP022095A Cali Date: 10/02/91 Analyst: SRA Data release authorized by: M/E Ion Abundance Criteria Spec # 488 51 30 to 607. of mass 198 68 less than 27. of mass 69 69 mass 69 relative abundance 70 less than 27. of mass 69 127 40 TO 607. of mass 198 197 less than 17. of mass 198 198 base peak> 100% relative abundance 199 5 TO 97. of mass 198 275 10 TO 307. of mass 193 365 greater than 17. of mass 198 441 less than mass 443 442 greater than 40X of mass 198 443 17 TO 237. of mass 442 1 - value in parenthesis is 7. of mass 69 2 - value in parenthesis is 7. of mass 442 43. 19 0. 00 50. 66 0. 00 50. 57 0. 00 100. 00 5. 58 21. 34 1. 72 8. 21 85. 06 14. 78 < ( 0. 0. (17. 00) 00) 37) 300505 Jata Subjectlb^/alldation 'U a C ra' n y- u> ::*. O o cn ' o DATA FROM FILE: CS022095A SCANS 410 TO 1190 ACQUIRED: 02/23/35 3:50:00 CALI: C5022095A #1 SAMPLE: SSTD050 290-12-SU25A CONDS.: 0.25 X 30M RTX-5 l.OUM 45/4-300212 O.OQ 600 . 10:00 700 . 11:40 800 . 13:20 909 . 15:30 1000 . 16:40 1105 . 13:20 iCpy I IML X INST C -• 100.0?: <: 39424.) CS50 2-FLUOROPHENOL 0.5 (SS-5) ~.i»i......_ eS45- D5-PHEN0L : ^ ^ r ^ ^ Z : ? 0 2-CHLCK0PHEN0L-D4 O.S (SS-7) 0.8 (SS-4) •^KiO-04-1,4 DICHLOROBENZENE (IS-1) 5Mi»«amau • .Cf7a 1. 2-CL2BENZENE-D4 0.4 (SS-8) CS20 D5-NITR0BEHZEHE 0.2 (SS-1) -CI40 D3-NAPHTHALENE CS25 2-FLUOROBIPHENYL 0.7 (SS-2) -CI50 DIO-ACENAPHTHENE CS55 2,4,6TRIBROMOPHENOL (SS-b) ^ ^ ^ ^ ^ ^ ^ <S^ 0^^^ (IS-2) (IS-3) X1£0 DIO-PHENANTHRENE (IS-4) DATA FROM FILE: CS022035A SCANS 1190 TO 2460 ACQUIRED: 02.^20/95 9:50:09 CALI: CS022095A #1 SAMPLE: SSTDOSO 290-12-SU25A CONDS.: 0.25 X 30M RTX-5 l.OUM 45/4-300@12 INST C -<«:* DJ t . ^ W tn c: ca" ^ 5 Q., OJ 00 o o cn o 1200 . 20:50 1403 . 23:20 1603 J 25:43 1300 . 33:03 2000 . 33:20 2260 . 36:45 rti r L 100.0?: ( 26880.) TS3F D14-P-TERPHENYL 0.5 (5S-3) -Gi?€u D12-CHRYSENE (15-5) •CI75 D12-PERYLENE (IS-6) > Quantitation Report File: CS025095A ' Data: CS022095A. TI ^2/20/95 9:50:00 ^Simple: SSTDOSO 290-12-SV25A . Xonds.: 0.25 X 30M RTX-5 l.OUM 45/4-300612 INST C Formula: Instrument: C Weight: 1.001 Submitted by: Analyst: SRA Acct. No. : AMOUNT=AREA • REF AMNT/(REF AREA « RESP FACT) Resp, fac. from Library Entry D4-l,4 DICHLOROBENZENE (IS-1) DS-NAPHTHALENE (IS-2) DIO-ACENAPHTHENE (IS-3) DIO-PHENANTHRENE (IS-4) D12-CHRYSENE (IS-5) D12-PERYLENE (IS-6) 2-FLUOROPHENOL 0.6 (SS-5) D5-PHEN0L 0.8 (SS-4) D5-NITR0DENZENE 0.2 (SS-1) 2-FLUOROBIPHENYL 0.7 (SS-2) 2, 4, 6TRII3ROMOPHENOL (SS-6) D14-P-TERPHENYL 0. 5 (SS-3) 2-CHL0R0PHEN0L-D4 0. 8 (SS-7) 1, 2-CL2I3ENZENE-D4 0.4 (SS-B) *PHENOL 0. 8 BIS(2CHL0R0ETHYL)E 0.7 2CHL0R0PHENDL 0.8 1. 3DICHL0R0BENZENE 0.6 *1, 4DICHL0R0BENZENE O. 5 T ANILINE N-NITROSODIMETHYLAMINE PYRIDINE T BENZYL ALCOHOL .1. 2DICHL0R0BENZENE 0.4 2METHYLPHEN0L 0.7 T 2,2'0XYBIS(1CHL0R0PR 4METHYLPHEN0L 0. 6 T 8<NI TROSOPROP YLAMINE 0. 5 HEXACHLOROETHANE 0. 3 T NITROBENZENE 0. 2 T ISOPHORONE 0. 4 »2-NITR0PHEN0L 0. i 2.4-DIMETHYLPHENOL 0.2 BENZOIC ACID BIS(2CHL0R0ETH0XY) 0.3 *2. 4DICHL0R0PHEN0L 0. 2 ll 2, 4TRICHLDR0BENZ 0.2 NAPHTHALENE 0. 7 4-CHLOROANILINE *CL6BUTAUIENE T *4CHL0R03METHYLPHEN 0. 2 2METHYLNAPHTHALENE 0. 4 t<CL6CYCL0PENTADIENE 3 00508 *246TRICHL0R0PHNE0L 0. 2 T ' 2, 4, 5 T R I C H L 0 R 0 P H E N 0. 2 T 2 C H L 0 R 0 N A P H T H A L E N E 0.8 ,,..,., ,.,,..-•;.,,,;...,. .:^ 2 - N I T R O A N I L l N E :-^::.^c. ...:,,..--, : U^ VCU..;: , No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 ^ 6 fy ' a 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 ^ ^ h ^ 3 AA 45 46 47 Name CI30 CI40 CI 50 CI60 CI70 CI75 CS50 CS45 CS20 CS25 CS55 CS30 CS70 CS75 C315 C325 C330 C335 C340 C320 C310 C319 C345 C350 C355 C357 C365 C370 C375 C410 C415 C420 C425 C430 C435 C440 C445 C450 C455 C460 C465 C470 C510 C515 C520 C525 C530 r No Name 48 ^9 h No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 ^ 2 h ^ 4 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 ^ ^ ie ^ 9 50 C535 C540 C545 m/z 152 136 164 188 240 264 112 99 82 172 330 244 132 152 94 93 128 146 146 93 74 79 108 146 108 45 108 70 117 77 82 139 107 122 93 162 180 128 127 225 107 142 237 196 196 162 65 163 152 138 DIMETHYL PH THAL/ ACENAPHTHYLENE 3-NITROANILINE Scan 590 745 960 1138 1473 1778 434 549 661 875 1055 1327 567 614 550 560 569 586 592 556 258 258 609 616 620 626 639 643 653 .664 690 702 702 711 713 729 740 748 757 767 808 831 857 865 870 890 904 925 943 954 Time 9: 50 12:25 16:00 18: 58 24:33 29:38 7: 14 9:09 11: 01 14:35 17:35 22:07 9:27 10: 14 9: 10 9:20 9:29 9: 46 9: 52 9: 16 4: 18 4: 18 10: 09 10: 16 10: 20 10: 26 10: 39 10: 43 10: 53 11: 04 11: 30 11: 42 11: 42 11; 51 11: 53 12: 09 12:20 12:28 12:37 12: 47 13: 28 13: 51 14: 17 14: 25 14: 30 14: 50 15: 04 15: 25 15:43 15: 54 Ref 1 2 3 4 5 6 1 1 2 3 3 5 2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3 ^TE 1. 3 RRT 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 0. 736 0. 931 0. 887 0. 911 1. 099 0. 901 0. 961 1. 041 0. 932 0. 949 0. 964 0. 993 1. 003 0. 942 0. 437 0. 437 1. 032 1. 044 1. 051 1. 061 1. 083 1. 090 1. 107 0. 891 0. 926 0. 942 0. 942 0. 954 0. 957 0. 979 0. 993 1. 004 1. 016 1. 030 1. 085 1. 115 0. 893 0. 901 0. 906 0. 927 0. 942 0. 964 0. 982 0. 994 Meth A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A VB A BB A BV A VB A BV A BB A BV A BV A BB A VB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BV A VB A BB A BB A BB A BB A BB Area(Hght) 6588. 26237. 12557. 12723. 9894. 10049. 9626. 12826. 11221. 15248. 1678. 9779. 10053. 6369. 15697. 15091. 10445. 11447. 11668. 15155. 5330. 5203. 7016. 10387. 10453. 14000. 10625. 8510. 4783. 12315. 24798. 7322. 7952. 3965. 15578. 7094. 8046. 30399. 5436. 4338. 7022. 19123. 2646. 4069. 3915. 14735. 4515. 14177. 22686. 1447. Amount 20. 000 20. 000 20. 000 20. 000 20. 000 20. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. OQO 25. 000 25. 000 25. 000 7.1 ot PPB 0. 95 PPB 0. 95 PPB 0. 95 PPB 0. 95 PPB 0. 95 PPB 0. 95 PPB ] PPB 1 PPB 1 PPB i PPB 1 PPB 1 PPB 1 PPB 1 PPB 1 PPB 3 PPB 1 PPB 1 PPB 1 PPB 1 PPB 1 PPB ] PPB - ] PPB 3 PPB 3 PPB 3 PPB 3 PPB 3 PPB 3 PPB ] PPB 3 PPB 3 PPB ] PPB ] PPB ] PPB ] PPB ] PPB PPB PPB PPB PPB PPB PPB PPB PPB PPD PPB PPB PPB 300 . 19 .19 . 19 . 19 . 19 . 19 . 19 . 19 . 19 . 19 . 19 . 19 . 19 . 19 . 19 . 19 . 19 , 19 . 19 . 19 . 19 I. 19 L 19 I. 19 . 19 I. 19 L. 19 L 19 I. 19 I. 19 I. 19 L 19 I. 19 I. 19 I. 19 I. 19 I. 19 1. 39 1. 19 1. 19 1. 19 3. 19 1. 19 1. 19 509 No 78 k79 "80 81 82 83 84 85 Ret(L) 24:38 26: 00 27: 57 28:04 29:21 35:42 35:43 37:34 Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 RRT(L) Ratio 1.003 1.00 0. 877 O. 943 0. 947 0. 990 1. 205 1. 205 1. 268 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 Amnt 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 Amnt(L) 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 R. Fac R. 1. 037 1. 441 0. 949 0. 996 0. 914 1. 044 0. 848 0. 882 Fac(L) 1. 037 1. 441 0. 949 0. 996 0. 914 1. 044 0. 848 0. 882 Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 . ^ ^ (!>' .ni , ^ 300510 DATA FROM FILE: CS0220S5B SCANS 403 TO 1133 .ACQUIRED: 02/23/95 10:35:03 CALI: CS022035B #1 SAMPLE: SSTD160 290-12-SUS0 CONDS.: 0.25 X 30M RTX-5 l.OUM 45/4-300212 INST C • u o w I - * 0,' n (.V 500 . 3:20 600 . 10:00 300 _ 13:20 900 . 15:00 1000 . 16:40 Ui o o in M 1100 . 18:20 SCAN I iHE rs5^ "T^FUIDRijTrthlJr 6.b kbb-D; -i 100.0?J ( 131840.) CS45 D5-PHEN0L 0.3 (SS-4) CS70 2-CHLCR0PHENCL-D4 0.8 (SS-7) « 5 0 04-1,4 DICHLOROBENZENE (IS-1) SS75 1,2-CL2BENZENE-D4 0.4 (SS-8) CS20 D5-HITROBENZENE 0.2 (SS-1) S66\ Q3Na\'^^ CS25 2-FLUOROBIPHENYL 0.7 (SS-2) Plii«nCEMriRMTwENE JZLS-3) C:S55 2,4,6TRI BROMOPHENOL (SS-6) P,n;,Q n.tQ~ph (IS-4) DATA FROM FILE: CS022035B SCANS 1183 TO 2315 ACQUIRED: 02/20/35 10:35:00 CALI: CS0220S5B #1 S.AMPLE: SSTD160 290-12-SUS0 CONDS.: 0.25 X 30M RTX-5 l.OUM 45/4-300ill2 INST C • "(i.'« G t - i - (/^ JT "ft)"" c- Q." Ui o o in M NJ 1230 . 20:80 1400 J 23:20 — . 1600 J 6:40 / o 1330 . .30:03 2000 . 33:20 2230 . 36:40 I ih!:. 100.0?. ( 91264.) CS30 D14-P-TERPriENYL 0.5 (S5-3) g^^^tt-HJHy-ynftV-^SrlS ^== iri75 D12-PERYLENE (IS-5) (IS-6) Quantitation Report File: CS0a2095B Data: CS022095B. TI /20/95 10: 35:00 mple: SSTD160 290-12-SV80 onds.: 0. 25 X 30M RTX-5 l.OUM ^5/4-300612 Formula: Instrument: C Submitted by: Analyst: SRA . ^c0 INST C Weight: Acct. No. 1. 001 AMOUNT=AREA « REF AMNT/(REF AREA « RESP FACT) Resp. fac. from Library Entry .m No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 ^ 6 fy 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 i^ h ^ 3 44 45 46 47 Name CI30 CI40 CI 50 CI60 CI70 CI75 CS50 CS45 CS20 CS25 CS55 CS30 CS70 CS75 C315 C325 C330 C335 C340 C320 C345 C350 C355 C357 C365 C370 C375 C410 C415 C420 C425 C435 C440 C445 C450 C455 C460 C465 C470 C510 C515 C520 C525 C530 C535 C540 C545 0. 6 0. 8 0. 2 0. 7 0. 4 0. 8 0. 7 O. 8 4 7 D4-l,4 DICHLOROBENZENE DS-NAPHTHALENE DIO-ACENAPHTHENE DIO-PHENANTHRENE D12-CHRYSENE D12-PERYLENE 2-FLUOROPHENOL D5-PHEN0L D5-NITR0BENZENE 2-FLUOROBIPHENYL 2,A.6TRIBR0M0PHEN0L D14-P-TERPHENYL 0. 5 2-CHL0R0PHEN0L-D4 0. 8 1.2-CL2BENZENE-D4 •PHENOL BIS(2CHL0R0ETHYL)E 2CHL0R0PHEN0L 1,3DICHL0R0BENZENE 0. 6 *1,4DICHL0R0BENZENE 0.5 ANILINE BENZYL ALCOHOL 1.2DICHL0R0BENZENE 0. 2METHYLPHEN0L 0. .2,2'0XYBIS(ICHLOROPR 4METHYLPHENOL O. 6 ?<NITROSOPROPYLAMINE 0. 5 HEXACHLOROETHANE NITROBENZENE ISOPHORONE *2-NITR0PHEN0L 2i 4-DIMETHYLPHENOL BIS(2CHL0R0ETH0XY) *2,4DICHL0R0PHEN0L 1.2,4TRICHLOROBENZ NAPHTHALENE 4-CHLOROANILINE *CL6BUTADIENE «4CHL0R03METHYLPHEN 0. 2 2METHYLNAPHTHALENE 0. 4 ?<CL6CYCL0PENTADIENE «246TRICHL0R0PHNE0L 0.2 2, 4, 5TRICHL0R0PHEN 0.2 2CHL0R0NAPHTHALENE 2-NITROANILINE DIMETHYL PHTHALATE ACENAPHTHYLENE 3-NITROANlLINE (IS-1) (IS-2) (IS-3) (IS-4) (IS-5) (IS-6) (SS-5) (SS-4) (SS-1) (SS-2) (SS-6) (SS-3) (SS-7) (SS-8) O. 3 0. 2 0. 4 0. 1 0. 2 0. 3 0. 2 0. 2 0. 7 T T 0. 8 1. 3 300513 No 48 ,49 bo No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 f 2 P3 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 tA7 h 49 50 Name C550 C321 C555 m/z 152 136 164 188 240 264 112 99 82 172 330 244 132 152 94 93 128 146 146 93 108 146 108 45 108 70 117 77 82 139 107 93 162 180 128 127 225 107 142 237 196 196 162 65 163 152 138 153 232 184 •ACENAPHTHENE 2,3. 0. 8 A.6-TETRACHLOROPHENDL 8<2, 4DINITR0PHEN0L Scan 583 742 959 1137 1471 1778 409 536 655 872 1054 1326 558 606 538 552 559 576 585 544 600 609 615 620 632 638 647 657 685 -697 699 711 724 737 74 5 751 765 807 829 855 865 869 889 903 925 940 954 963 999 965 Time 9:43 12:22 15:59 18: 57 24:31 29:38 6:49 8: 56 10: 55 14:32 17:34 22: 06 9: 18 10: 06 8: 58 9: 12 9: 19 9: 36 9:45 9: 04 10:00 10: 09 10: 15 10: 20 10: 32 10:38 10: 47 10: 57 11:25 11: 37 11: 39 11: 51 12: 04 12: 17 12; 25 12:31 12: 45 13:27 13:49 14: 15 14.25 14: 29 14:49 15:03 15:25 15: 40 15: 54 16:03 16: 39 16: 05 Ref 1 2 3 4 5 6 1 1 2 3 3 5 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3 3 3 3 RRT 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 0. 702 0. 919 0. 883 0. 909 1. 099 0. 901 0. 957 1. 039 0. 923 0. 947 0. 959 0. 988 1. 003 0. 933 1. 029 1. 045 1. 055 1. 063 1. 084 1. 094 1. 110 0. 885 0. 923 0. 939 0. 942 0. 958 0. 976 0. 993 1. 004 1. 012 1. 031 1. 088 1. 117 0. 892 0. 902 0. 906 0. 927 0. 942 0. 965 0. 980 0. 995 1. 004 1. 042 1. 006 Meth A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A BB BB BB BB BB BB BB BB BB BB BB BB BB BB BV VB BB BV VB BV BB BB VB BB BB BB BB BB BB BV BB BB BB BB BV VV BB BB BB BB BV VB BB BB BB BB BB BB BB BB Area(Hght) 7200. 28579. 13765. 13935. 12620. 12191. 34249. 47125. 44209. 55297. \ 5936. 39966. 36247. 23588. 54288. 46074. 36823. 37766. 39063. 50796. 26602. 36600. 38225. 50422. 40854. 29706. 16599. 43251. 87042. 20050. 31379. 53496. 27439. 26701. 103988. 22925. 14649. 30197. 63559. 11281. 16156. 15810. 50254. 17690. 51142. 75091. 1819. 44870. 12780. .y'°'- Amount 20. 000 20. 000 20. 000 20. 000 20. 000 20. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 SO. 000 80. 000 80. 000 SO. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPD PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB RPB 7.Tot 0. 0. 0. 0. 0. 0. mm 31 31 31 31 31 31 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 24 , 24 . 24 , 24 . 24.. , 24 24 24 24 24 CV ^ y Data S\A- K?Valir]r^ No 1 1^ F3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 C7 Is 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 Ret(L) 9: 12: 15: 18: 24: 29: 6: 8: 10: 14: 17: 22: 9: 10: 8: 9: 9: 9: 9: 9: 10: 10: 10: 10: 10: 10: 10: 10: 11: .11: 11: 11: 12: 12: 12: 12: 12: 13: 13: 14: 14: 14: 14: 15: 15: 15: 15: 16: 16: 16: 43 22 59 57 31 38 49 56 55 32 34 06 18 06 58 12 19 36 45 04 00 09 15 20 32 38 47 57 25 37 39 51 04 17 25- 31 45 27 49 15 25 29 49 03 25 40 54 03 39 05 Ratio 00 00 00 00 00 00 00 00 00 00 ' 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 RRT(L) 0. 0. 0. 0. 1. 0. 0. 1. 0. 0. 0. 0. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 1. 1. 000 000 000 000 000 000 702 919 883 909 099 901 957 039 923 947 959 988 003 933 029 045 055 063 084 094 110 885 923 939 942 958 976 993 004 012 031 088 117 892 902 906 927 942 965 900 995 004 042 006 Ratio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 , 00 , 00 . 00 Amnt 20. 00 20. 00 20. 00 20. 00 20. 00 20.00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 SO. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 30. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 SO. 00 80. 00 SO. 00 80. 00 80. 00 80. 00 80. 00 80. 00 Amnt(L) 20. 00 20. 00 20.00 20. 00 20. 00 20. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 R. Fac R. 1. 1. 1. 1. 1. 1. 1. 1. 0. 1. 0. 0. 1. 0. 1. 1. 1. 1. 1. 1. 0. 1. 1. 1. 1. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 0. 0. 0. 0. 000 000 000 000 000 000 189 636 387 004 108 792 259 819 805 600 279 311 356 764 924 271 327 751 419 031 576 378 761 175 274 468 240 234 910 201 128 264 556 205 293 287 913 321 929 364 033 815 232 , 138 Fac 1. 1. 1. 1. 1. 1. 1. 1. 0. 1. 0. 0. 1. 0. 1. 1. 1. 1. 1. 1. 0. 1. 1. 1. 1. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 0. 0. 0. 0. :(L) 000 000 000 000 000 000 189 636 387 004 108 792 259 819 885 600 279 311 356 764 924 271 327 751 419 031 576 378 761 175 274 468 240 234 910 203 128 264 556 205 293 287 913 321 929 364 033 815 232 133 Rat: LO 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 , 00 00 00 , 00 . 00 , 00 (i^ oV liF ^<P 300515 UaiaSuDsec; To VaUdatian ^ Quantitation Report File: CS022095B Data: CS022095B. TI ^|2/20/95 10:35:00 ^Pbmple: SSTD160 290-12-SV80 • Conds.: 0.25 X 30M RTX-5 l.OUM 4^/4-300612 Formula: Instrument: C Submitted by: Analyst: SRA INST C Weight: Acct. No. 1. 001 AMOUNT=AREA » REF AMNT/(REF AREA » RESP FACT) - Resp. fac. from Library Entry m m No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 ^6 ^7 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 No 51 52 53 .54 h 56 57 58 Name C560 C565 C570 C543 C580 C585 C590 C595 C610 C615 C625 C630 C635 C640 C645 C650 C655 D200 C647 C715 C720 C725 C730 C740 C735 C760 C765 C770 C775 C780 C785 C790 C430 C310 C319 m/z 109 168 165 165 149 204 166 138 &4NITR0PHEN0L DIBENZOFURAN 0. 8 2i4DINITR0T0LUENE 0. 2 2,6DINITR0T0LUENE 0. 2 DIETHYL PHTHALATE 4CHL0R0PHENYL PHEN 0. 4 FLUORENE 0. 9 4-NITROANILINE A.6DINITR02METHYLPH •DIPHENYLAMINE 4BR0M0PHENYL PHENY 0. 1 CL6BENZENE 0. 1 •PENTACHLOROPHENOL 0. 05 PHENANTHRENE 0.7 ANTHRACENE 0. 7 DI-NBUTYLPHTHALATE •FLUORANTHENE 0. 6 1,2-DIPHENYLHYDRAZINE CARBAZOLE PYRENE 0. 6 BUTYLBENZYLPHTHALATE 3,3'CL2BENZIDINE BENZO(A)ANTHRACENE 0.8 -BIS(2ETHYLHEXYL)PHTH CHRYSENE 0. 7 •DI-N-OC TYLPHTHALATE BENZO(B)FLUORANTHE 0.7 BENZO(K)FLUORANTHE 0.7 •BENZO(A)PYRENE 0. 7 INDENOd, 2, 3CD)PYR 0.5 DIBENZO(A, H)ANTHRA 0.4 BENZO(G,H, DPERYLE 0.5 BENZOIC ACID N-NITROSODIMETHYLAMINE PYRIDINE Scan Time Ref RRT 968 16:08 3 1.009 982 16:22 3 1.024 984 16:24 3 1.026 935 15: 35 3 0. 975 1007 16:47 3 1.050 1020 17:00 3 1.064 1024 17:04 3 1.068 1028 17:08 3 1.072 T T T T Meth A A A A A A A A BB BB BB BB BB BB BB VB Area(Hght) 8118. 63357. 15734. 13032. 48148. 23859. 51904. 2947. Am( 80. 80. 80. 80. 80. 80. 80. 80. sunt 000 000 000 000 000 000 000 .000 AiJLj' -'Zi PPB PPB PPB PPB PPB PPB PPB PPB 7.Tot 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 1.24 :\\ac's\OI% 300516 No 59 IbO Cl 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 1' W No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 K 3 h 75 76 77 m/z 198 169 248 284 266 178 178 149 202 77 167 202 149 252 228 149 228 149 252 252 252 276 273 276 122 74 79 Scan T 1032 17 1033 17 1078 17 1099 18 1120 18 1141 19 1146 19 1199 19 1286 21 1038 17 1162 19 1315 21 1383 23 1460 24 1468 24 1456 24 1477 24 1558 25 1678 27 1686 28 1763 29 2151 35 2153 35 2264 37 716 11 217 3 217 3 Ret(L) Ratio 16: 16: 16: 15: 16: 17: 17: 17: 17: 17: 17: 18: 18: 19: 19: 19: 21: 17: 19: 21: 23: 24: 24: 24: 24: 25: 27: 08 22 24 35 47 00 04 08 12 13 58 19 40 01 06 59 26 18 22 55 03 20 28 16 37 58 58 1. 00 1. 00 1. 00 1. 00 1. 00 - 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 ime Ref : 12 : 13 : 58 : 19 :40 :01 :06 : 59 :26 : 18 :22 : 55 :03 :20 :28 : 16 :37 : 58 : 58 :06 :.23 : 51 : 53 : 44 : 56 : 37 : 37 RRT(L 1. 009 1. 024 1. 026 0. 975 1. 050 1. 064 1. 068 1. 072 0. 908 0. 909 0. 948 0. 967 0. 985 1. 004 1. 008 1. 055 1. 131 0. 913 1. 022 0. 894 0. 940 0. 993 0. 998 0. 990 1. 004 0. 876 0. 944 4 4 4 4 4 4 4 4 4 4 4 5 5 5 5 5 5 6 6 6 6 6 6 6 2 1 1 RRT 0. 908 0. 909 0. 948 0. 967 0. 985 1. 004 1. 008 1. 055 1. 131 0. 913 1. 022 0. 894 0. 940 0. 993 0. 998 0. 990 1. 004 0. 876 0. 944 0. 948 0. 992 1. 210 1. 211 1. 273 0. 965 0. 372 0. 372 Ratio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 n p°y y Meth A BB A BB A BB A BB A BB A BV A VB A BB A BB A BB A BV A BV A BB A BB A BV A BB A VB A BB A BV A VB A BB A BB A BB M X X ^ A VVVjjtP M XX ' M XX » Amnt 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 Area(Hght) 8978. 17144. 11967. 12299. 9609. 60657. 63435. 81587. 60836. 78484. 6279. 61464. 34430. 11658. 53578. 48015. 50474. 80098. 55455. 42051. 45235. 47847. 44267. • 43990. ' 23061. 26430. ^ 29721. Amnt(L) 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 SO. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 Amount 80. 000 80. 000 80. 000 80. 000 80. OOO 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 80. 000 SO. 000 80. 000 80. 000 80. 000 80. 000 SO. 000 PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB R. Fac R. Fac(L) 0. 1. 0. 0. 0. 0. 0. 0. 0. 0 0 0 0 1 1 1 1 1 0 1 0 0 1 0 1 1 1 147 151 286 237 874 433 943 054 161 308 215 221 172 088 138 464 091 408 113 218 682 231 061 951 000 643 137 ,„.;ai,a Su'o^ 0. 147 1. 151 0. 286 0. 237 0. 874 0. 433 0. 943 0. 054 0. 161 0. 303 0. 215 0. 221 0. 172 1. 083 1. 138 1. 464 1. 091 1. 408 0. 113 1. 218 0. 682 0. 231 1. 061 0. 951 1. 000 1. 643 1. 137 cCl-loA 7.Tot 1.24 1.24 1. 24 1. 24 1. 24 1.24 1. 24 1.24 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 1. 24 Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 300517 m No 78 7*^ fso 81 82 83 84 85 RetCL) 28:06 29:23 35: 51 35:53 37:44 11: 56 3:37 3:37 Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1.00 1. 00 RRT(L) 0. 948 0. 992 1. 210 1. 211 1. 273 0. 965 0.372 0. 372 Ratio 1. 00 1. 00 1. 00 1.00 1. 00 1. 00 1. 00 1. 00 Amnt 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 Amnt(L) 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 80. 00 R.Fac R. 0.862 0. 928 0. 981 0. 908 0. 902 0. 202 0. 918 1. 032 Fac(L) 0. 862 0. 928 0. 981 0. 90S 0. 902 0. 202 0. 918 1. 032 Rat: io 00 00 00 00 00 00 00 00 M V <,"> , / >(? 300518 10 Vanijrvic;- DATA FROM FILE: CS022035C SCANS 405 TO 1185 ACQUIRED: 02/23/35 11:20:00 CALI: CS022035C #1 SAMPLE: SSTD020 230-12-SUlO CONDS.: 0.25 X 30M PJX-5 l.OUM 45/4-330(312 INST C . ' U ' a u> o o tn vo 530 . 3:20 _L CS50 2-FLUuRuP;-;£iNGL 0.6 (SS-5) -• 100.0:^ ( 25312.) =r-e;545 D5-PHENGL 3.8 (SS-4) S?0 2-CHLUR0PHEN0L-D4 3.3 (SS-7) €130 04-1,4 DICHLOROBENZENE (IS-1) 700 . 11:40 300 . 13:20 900 . L - j . t.'C.' 1030'. 16:40 1100 . 13:20 Tint €575 1,2-CL2BENZENE-D4 0.4 (SS-3) CS20 DS-NITROSENZENE 0.2 (SS-1) CI40 DB-NAPHTHALENE CS25 2-FLUOROBIPHENYL 0.7 (SS-2) (15-2) CI50 DIO-ACENAPHTHENE (IS-3) CS55 2,4,6TRIBROMOPHENOL (SS-6) CI60 DIO-PHENANTHRENE (IS-4) DATA FROM FILE: CS022035C SCANS 1135 TO 2433 ACQUIRED: 02/23/95 11:20:30 CALI: CS022095C #1 SAMPLE: S5TD020 290-12-SU10 CONDS.: 0.25 X 30M RTX-5 l.OUM 45.^4-303(312 INST C ' U a i i ' - > j . 20:03 1400 _ 23:20 1500 _ 1330 . 33 • i50 in c a" CD Q, r-l ^ - -- to Zo-'Z'j _ 33:20 . .^ 2230 _ 35:43 to o o in to o 35:43 - 1 m J — n . J ISi 130.0^ ( 12000.) CS30 014-P-TERPHENYL O.S (SS-3) I CI70 D12-CHRYSENE (IS-5) f "fir-vumi-M CI75 D12-PERYLENE (IS-6) ^ Quantitation Report File: CS052095C ^Wa Data: CS022095C. TI /20/95 11:20:00 ample: SSTD020 290-12-SVlO Conds.: 0.25 X SOM RTX-5 l.OUM 45/4-300612 Formula: Instrument: C Submitted by: Analyst: SRA AMOUNT=AREA • REF AMNT/(REF AREA • RESP FACT) Resp. fac. from Library Entry INST C Weight: Acct. No. 1. 001 .m No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 |16 I7 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 f l l2 43 44 45 46 47 Name CI30 CI40 CI 50 CI60 CI70 CI75 CS45 CS20 CS25 CS30 CS70 CS75 C315 C330 C335 C340 C345 C350 C355 C357 C365 C370 C375 C410 C415 C420 C425 C435 C440 C445 C450 C455 C460 C465 C470 C510 C515 C520 C525 C530 C535 C540 C545 C550 C321 C555 C560 D4-l,4 DICHLOROBENZENE DS-NAPHTHALENE DIO-ACENAPHTHENE DIO-PHENANTHRENE D12-CHRYSENE D12-PERYLENE D5-PHEN0L 0. 8 D5-NITR0BENZENE 0.2 2-FLUOROBIPHENYL 0.7 D14-P-TERPHENYL 0. 5 2-CHL0R0PHEN0L-D4 0.8 1,2-CL2BENZENE-D4 O.4 •PHENOL 0. 8 2CHL0R0PHEN0L 0.8 1. 3DICHL0R0BENZENE 0.6 • 1, 4DICHL0R0BENZENE 0.5 BENZYL ALCOHOL 1,2DICHL0R0BENZENE 0.4 2METHYLPHEN0L 0. 7 2,2'0XYBIS(ICHLOROPR 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. (IS-1) (IS-2) (IS-3) (IS-4) (IS-5) (IS-6) (SS-4) (SS-1) (SS-2) (SS-3) (SS-7) (SS-8) 4METHYLPHEN0L StNITROSOPROPYLAMINE HEXACHLOROETHANE •NITROBENZENE ISOPHORONE •2-NITROPHENOL 2,4-DIMETHYLPHENOL BIS(2CHL0R0ETH0XY) •2,4DICHL0R0PHEN0L 1,2,4TRICHLOROBENZ NAPHTHALENE 4-CHLOROANILINE •CL6BUTADIENE •4CHL0R03METHYLPHEN 2METHYLNAPHTHALENE &CL6CYCL0PENTADIENE •246TRICHL0R0PHNE0L 2,4,5TRICHL0R0PHEN 2CHL0R0NAPHTHALENE 2-NITROANILINE DIMETHYL PHTHALATE ACENAPHTHYLENE 3-NITROANILINE •ACENAPHTHENE 2, 3, 4, 6-TETRACHLOROPHENOL t^2, 4DINITR0PHEN0L «<4 NITROPHENOL T T 8 1. 3 0. 3 300521 'UDject JO AaMd^on « No 48 |9 lo No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 | 2 Is 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46' 1^ is 49 50 Name C565 C570 C543 m/z 152 136 164 188 240 264 99 82 172 244 132 152 94 128 146 146 108 146 108 45 108 70 117 77 82 139 107 93 162 ISO 128 127 225 107 142 237 196 196 162 65 163 152 138 153 232 184 109 168 165 165 DIBENZOFURAN ._ 0. 8 2. 4DINITR0T0LUENE 0.2 2, 6DINITR0T0LUENE 0.2 Scan 585 744 959 1137 1473 1780 541 658 874 1326 562 609 543 564 580 589 604 611 617 624 634 638 651 660 688 698 698 712 726 -737 747 753 765 808 829 854 866 870 883 904 924 941 952 963 1000 965 968 981 981 935 Time 9:45 12:24 15:59 18: 57 24: 33 29: 40 9:01 10: 58 14:34 22:06 9:22 10:09 9: 03 9: 24 9:40 9:49 10:04 10: 11 10: 17 10:24 10: 34 10:38 10: 51 11: 00 11: 28 11: 38 11:38 11: 52 12:06 12: 17 12:27 12: 33 12:45 13: 28 13:49 14: 14 14: 26 14: 30 14: 48 15:04 15: 24 15: 41 15: 52 16: 03 16: 40 16: 05 16: 08 16: 21 16:21 15: 35 Ref 1 2 3 4 5 6 1 2 3 5 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 RRT 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 0. 925 0. 884 0. 911 0. 900 0. 961 1. 041 0. 928 0. 964 0. 991 1. 007 1. 032 1. 044 1. 055 1. 067 1. 084 1. 091 1. 113 0. 887 0. 925 0. 938 0. 938 0. 957 0. 976 0. 991 1. 004 1. 012 1. 028 1. 086 1. 114 0. 891 0. 903 0. 907 0. 926 0. 943 0. 964 0. 981 0. 993 1. 004 1. 043 1. 006 1. 009 1. 023 1. 023 0. 975 -.. T Meth A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A BB BB BB BB BB BB BB BB BB BB BB BB BB BB BV VB BB BB BB BB BB BB BB BB BB BB BB BB BB BB BB BB BB BB BB BB BB BB BB BB BB BB BB BB BB BB BB BB BB, BB Area(Hght) 6246. 24826. 13146. 13330. 11594. 11728. 5540. 4892. 7230. 5215. 4035. 2622. 6764. 4198. 4376. 4227. 2800. 4060. 4274. 5589. 4455. 3264. 1763. 4982. 9627. 2541. 3305. 5871. 2905. 3084. 12457. 3555. 1599. 3227. 7734. 817. 1744. 1790. 6052. 2144. 6157. 9965. 1412. ' 5840. 1735. 637. 893. 8408. 1835. 1375. Amount 20. 000 20. 000 20. 000 20. 000 20. 000 20. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 7.Tot PPB 2. 20 PPB 2. 20 PPB 2. 20 PPB 2. 20 PPB 2. 20 PPB 2. 20 PPB \ PPB \ PPB \ PPB ] PPB \ PPB : PPB ] PPB 3 PPB ] PPB ] PPB \ PPB 3 PPB 3 PPB 3 PPB 3 PPB 3 PPB 3 PPB 3 PPB 3 PPB 3 PPB 3 PPB 3 PPB 3 PPB ] PPB ] PPB \ PPB ] PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB 10. 000 PPB V ^Mhlpn To V^iidalior' L. 10 L. 10 L. 10 L. 10 L. 10 L 10 I. 10 L. 10 L. 10 L. 10 L. 10 L. 10 l. 10 L. 10 L 10 I. 10 L. 10 L. 10 L. 10 I. 10 I. 10 I. 10 L. 10 L 10 L. 10 L. 10 L. 10 I. 10 I. 10 I. 10 I. 10 I. 10 I. 10 I. 10 L. 10 I. 10 I. 10 I. 10 I. 10 L 10 t. 10 I. 10 I. 10 I. 10 ^ipT 47 300522 .m No 1 i 2 ' 3 A 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 |27 Es 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 Ret(L) 9: 12: 15: 18: 24: 29: 9: 10: 14: 22: 9: 10: 9: 9: 9: 9: 10: 10: 10: 10: 10: 10: 10: 11: 11: 11: 11: 11: 12: 12: 12: 12: 12: 13: 13: 14: 14: 14: 14: 15: 15: 15: 15: 16: 16: 16: 16: 16: 16: 15: 45 24 59 57 33 40 01 58 34 06 22 09 03 24 40 49 04 11 17 24 34 38 51 00 28 38 38 52 06 17 27 33 45 28 49- 14 26 30 48 04 : 24 41 52 ;03 : 40 05 :08 : 21 :21 :35 Ratio 00 00 00 00 00 00 00 00 00 00' 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 , 00 , 00 . 00 ,00 . 00 . 00 00 , 00 . 00 . 00 , 00 RRTCL) 0. 0. 0. 0. 0. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 000 000 000 000 000 000 925 884 911 900 961 041 928 964 991 007 032 044 055 067 084 091 113 887 925 938 938 957 976 991 004 012 028 086 114 891 903 907 926 943 964 981 993 004 043 006 009 023 023 975 Ratio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 , 00 , 00 , 00 , 00 , 00 . 00 . 00 . 00 . 00 . 00 Amnt 20. 00 20. 00 20. 00 20. 00 20. 00 20. 00 10. 00 10. 00 10. 00 10.00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 y Amnt(L) 20. 00 20. 00 20. 00 20. 00 20. 00 20. 00 10. 00 10. 00 10. 00 10.00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10.00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 yt/ R. Fac R. 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 1. 774 0. 394 1. 100 0. 900 1. 292 0. 840 2. 166 1. 344 1. 401 1. 354 0. 897 1. 300 1. 369 1. 790 1. 427 1. 045 0. 565 0. 401 0. 776 0. 205 0. 266 0. 473 0. 234 0. 248 1. 004 0. 286 0. 129 0. 260 0. 623 0. 124 0. 265 0. 272 0. 921 0. 326 0. 937 1. 516 0. 215 0. 888 0. 264 0. 097 0. 136 1. 279 0. 279 0. 209 Fac 1. 1. 1. 1. 1. 1. 1. 0. 1. 0. 1. 0. 2. 1. 1. 1. 0. 1. 1. 1. 1. 1. 0. 0. 0. 0. 0. 0. 0. 0. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 0. 0. 0. 0. 0. 1. 0. 0. :(L) 000 000 000 000 000 000 774 394 100 900 292 840 166 344 401 354 897 300 369 790 427 045 565 401 776 205 266 473 234 248 004 286 129 260 623 124 265 272 921 326 937 516 215 888 264 097 136 279 279 . 209 Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 300523 Data Subject To Valida-iion, ^ Quantitation Report File: CS022Q.95C Data: CS022095C. TI /20/95 11:20:00 mple: SSTD020 290-12-SVlO Conds.: 0.25 X 30M RTX-5 l.OUM 45/4-300612 Formula: Instrument: C Submitted by: Analyst: SRA m INST C Weight: Acct. No. 1. 001 AMOUNT=AREA • REF AMNT/(REF AREA • RESP FACT) Resp. fac. from Library Entry M No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 ^ 6 %^ 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 No 51 52 53 ^4 h 56 57 58 Name C580 C585 C59d C595 C610 C615 C625 C630 C635 C640 C645 C650 C655 D200 C647 C715 C720 C725 C730 C740 C735 C760 C765 C770 C775 C780 C7B5 C790 C310 C319 C320 C325 C430 CS50 CS55 m/z 149 204 166 138 198 169 248 284 DIETHYL PHTHALATE 4CHL0R0PHENYL PHEN 0. 4 FLUORENE 0. 9 4-NITROANILINE 4.6DINITR02METHYLPH •DIPHENYLAMINE 4BR0M0PHENYL PHENY 0.1 CL6BENZENE 0.1 •PENTACHLOROPHENOL 0. 05 PHENANTHRENE 0.7 ANTHRACENE 0.7 DI-NBUTYLPHTHALATE •FLUORANTHENE 0.6 1,2-DIPHENYLHYDRAZINE CARBAZOLE PYRENE 0. 6 BUTYLBENZYLPHTHALATE 3i3'CL2BENZIDINE BENZO(A)ANTHRACENE 0.8 BIS(2ETHYLHEXYL)PHTH CHRYSENE 0. 7 •DI-N-OCTYLPHTHALATE BENZO(B)FLUORANTHE 0.7 -BENZO(K)FLUORANTHE 0.7 •BENZO(A)PYRENE 0.7 INDEN0(1,2, 3CD)PYR 0.5 DIBENZO(A, H)ANTHRA 0.4 BENZO(G,H, DPERYLE 0.5 N-NITROSODIMETHYLAMINE PYRIDINE ANILINE BIS(2CHL0R0ETHYL)E 0.7 BENZOIC ACID 2-FLUOROPHENOL 0.6 2,4,6TRIBR0M0PHEN0L Scan Time Ref RRT 1007 16:47 3 1.050 1019 16: 59 3 1. 063 1023 17:03 3 1.067 1027 17:07 3 1.071 1032 17: 12 4 0. 908 1034 17: 14 4 0. 909 1077 17:57 4 0.947 1100 18:20 4 0.967 T T T (SS-5) (SS-6) Meth A BB A BB A BB A BB A BB A BB A BB' A BB Area(Hght) 6417. 3058. 6401. 811. 951. 3988. 1546. 1727. Amount 10. 10. 10. 10. 10. 10. 10. 10. 000 000 000 000 000 000 000 000 PPB PPB PPB PPB PPB PPB PPB PPB y.Tot 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1. 10 1 IO 300524 'i%l No 59 ^ 0 ll 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 f W No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 ^ 3 h 75 76 77 m/z 266 178 178 149 202 77 167 202 149 252 228 149 228 149 252 252 252 276 278 276 74 79 93 93 122 112 330 Scan Time F 1119 18 1140 19 1145 19 1200 20 1287 21 1039 17 1163 19 1314 21 1384 23 1460 24 1469 24 1457 24 1477 24 1559 25 1677 27 1684 28 1762 29 2141 35 2143 35 2255 37 239 3 239 3 549 9 554 9 706 11 423 7 1054 17 Ret(L) Ratio 16: 16: 17: 17: 17: 17: 17: 18: 18: 19: 19: 20: 21: 17: 19: 21: 23: 24: 24: 24: 24: 25: 27: 28: 29: 35: 35: 47 1.00 59 1.00 03 1.00 07 1.00 12 1.00 14. 1.00 57 1. 00 20 1.00 39 1.00 00 1.00 05 1.00 00 1.00 27 1.00 19 1. 00 23 1.00 54 1.00 04 1.00 20 1.00 29 1.00 17 1. 00 37 1.00 59 1.00 57 1.00 04 1.00 22 1.00 41 1.00 43 1.00 :39 :00 :05 :00 :27 : 19 :23 : 54 :04 :20 :29 : 17 :37 : 59 : 57 :04 :22 :41 :43 : 35 : 59 : 59 : 09 : 14 :46 :03 :34 RRT(LJ 1. 050 1. 063 1. 067 1. 071 0. 908 0. 909 0. 947 0. 967 0. 984 1. 003 1. 007 1. 055 1. 132 0. 914 1. 023 0. 892 0. 940 0. 991 0. 997 0. 989 1. 003 0. 876 0. 942 0. 946 0. 990 1. 203 1. 204 tef 4 4 4 4 4 4 4 5 5 5 5 5 5 6 6 6 6 6 6 6 1 1 1 1 2 1 3 RRT 0. 984 1. 003 1. 007 1. 055 1. 132 0. 914 1. 023 0. 892 0. 940 0. 991 0. 997 0. 989 1. 003 0. 876 0. 942 0. 946 0. 990 1. 203 1. 204 1. 267 0. 409 0. 409 0. 938 0. 947 0. 949 0. 723 1. 099 1 Ratio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 , 00 00 00 , 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 Meth A BB A BV A VB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BV A VB A BB A BB ^^ M XX iTC M XX ''^ M XX M XX M XX M XX M XX M XX M XX Amnt 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 Area(Hght) 1110. 7847. 8305. 10022. 7262. 10014. 6544. 7722. 3988. 1663. 6468., 5573. 6430. 8288. 5811. 5992. 5237. ,.41 5028. p \ 4082. 4344. 2695. 4086. 9568. 6987. 1319. 3983. 693. Amnt(L) 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 rs-,- ;u.-.- Amount 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 R. Fac R. F 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 1. 1. 1. 1. 0. 1. 0. 0. 1. 0. 1. 1. 0. 1. 0, 0. 0. i-J^-t.,. 976 465 974 123 143 598 232 259 167 177 246 504 090 502 982 332 688 207 116 961 109 413 . , 991 022 . 893 , 857 .696.,. PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB ac (L) 0. 976 0. 465 0. 974 0. 123 0. 143 0. 598 0. 232 0. 259 0. 167 1. 177 1. 246 1. 504 1. 090 1. 502 0. 982 1. 332 0. 683 0. 287 1. 116 0. 961 1. 109 1. 413 0. 993 1. 022 0. 893 0. 857 0.,676 io'osis ~^ y.Tot Rat: 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 Lo 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 , 00 , 00 00 , 00 . 00 . 00 . 00 . 00 . 00 . 00, . ^ No. 78 ^9 po 81 82 83 84 85 Ret(L) 37:35 3: 59 3: 59 9:09 9: 14 11:46 7:03 17:34 Ratio 1. 00 1. 00 1.00 1. 00 1. 00 1. 00 1.00 1. 00 RRT(L) 1.267 0. 409 0. 409 0.938 0. 947 0. 949 0. 723 1. 099 Ratio 1.00 1. 00 1.00 1. 00 1. 00 1. 00 1. 00 1. 00 Amnt 10. 00 10. 00 10. 00 10. qo 10. 00 10. 00 10. 00 10. 00 Amnt(L) 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10. 00 R. Fac R. 0. 741 0. 863 1. 308 3. 064 2. 237 0. 106 1. 275 0. 105 Fac(L) 0. 741 0. 863 1.308 3. 064 2. 237 0. 106 1. 275 0. 105 Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 300526 Data Subjection- ' • \ t o r-i- ftl tn c (Z a SL a 5" DATA FROM FILE: CS022095D SCANS 404 TO 1184 ACQUIRED: 02/20/35 12:05:00 CALI: CS02-2035D »1 SAMPLE: SSTD120 230-12-SU50 CONDS.: 0.25 X 30M RTX-5 l.OUM 45/4-3001312 INST C 500 _ 8:20 700 . -1:40 300 . 13:20 I CS50 2-ri_UuR0Ph£iNUL 0.6 (SS-5) -J 100.0?! ( 91648.) CS45 D5-PHEN0L 0.8 (SS-4) 2 ^ GS?0 2-CHL0R0PHEN0L-D4 0.3 (SS-7) CI30 04-1,4 DICHLOROBENZENE (IS-1) CS23 D.5-N I TROBENZENE 0.2 (SS-1) BsoM C.t*|-9r-0?sr.|riPHTMriLEME (IS-2) ^is^msfSMB^imEawi 900 _ 15:03 1000 16:40 to §'1100. 1/1,18:23 to I lil'IC CI50 DIQ-ACENAPHTHENE J:XS-3) CS55 2,4,6TRIBR0M0PHEN0L (SS-6) FHRENE (IS-4) CS25 2-FLUOROBIPHENYL O.r (SS-2) DATA FROM FILE: CS022095D SCANS 1134 TO 2400 ACQUIRED: 02/20/95 12:35:00 CALI: CS022035D #1 SAMPLE: SSTD120 29O-12-SU60 CONDS.: 0.25 X 33M RTX-5 l.OUM 45/4-300(312 INST C . 'tl • I-i- C (Z Q. o i j.K.ti'j . 20:00 1400 4 23:20 1600 _ 26:40 1800 . 33:00 2000 33:2t t o o o Ul to 00 2200 35:43 '"p'-JM Ti/IE 1 ± -• 100.0?: ( 57664.) :b30 D14-P-TERPHENYL 0.5 (SS-3) ^^^^j'yTmif g;ggg==gtg»f>{RYSEM£ (IS-5) TT75 D12-PERYLENE (IS-6) ^ Quantitation Report File: CS022095D « : Data: CS022095D. TI 2/20/95 12: 05: 00 'ample: SSTD120 290-12-SV60 Conds.: 0.25 X 30M RTX-5 l.OUM 45/4-300612 Formula: Instrument: C Submitted by: Analyst: SRA INST C Weight: Acct. No. 1. 001 AMOUNT=AREA * REF AMNT/(REF AREA • RESP FACT) Resp. fac. from Library Entry M No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 A6 h 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 ^1 h A3 AA 45 46 47 Name CI30 CI40 CI50 CI60 CI70 CI75 CS45 CS20 CS25 CS55 CS30 CS75 C315 C325 C330 C335 C340 C320 C345 C350 C355 C357 C365 C370 C375 C410 C415 C420 C425 C435 C440 C445 C450 C455 C460 C465 C470 C510 C515 C520 C525 C530 C535 C540 C545 C550 C321 D4-l,4 DICHLOROBENZENE DS-NAPHTHALENE D10-ACENAPHTHENE D10-PHENANTHRENE D12-CHRYSENE D12-PERYLENE D5-PHEN0L 0.8 D5-NITR0BENZENE 0. 2 2-FLUOROBIPHENYL 0. 7 2.4i6TRIBR0M0PHEN0L D14-P-TERPHENYL 1,2-CL2BENZENE-D4 •PHENOL BIS(2CHL0R0ETHYL)E 2CHL0R0PHEN0L 1,3DICHL0R0BENZENE •1,4DICHL0R0BENZENE ANILINE BENZYL ALCOHOL 1,2DICHL0R0BENZENE 2METHYLPHEN0L 0. 0. 0. 0. 0. 0. 0. 0. 0. (IS-1) (IS-2> (IS-3) (IS-4) (IS-5) (IS-6) (SS-4) (SS-1) (SS-2) (SS-6) (SS-3) (SS-8) 4 7 T 6 T 5 3 T 2^T 4 1 n c 3 2 2 7 2,2 'OXYBIS(1CHLOROPR 4METHYLPHENOL 0. &NITROSOPROPYLAMINE 0. HEXACHLOROETHANE 0. NITROBENZENE ^ 0. ISOPHORONE 0. •2-NITROPHENOL 0. 2,4-DIMETHYLPHENOL 0. BIS(2CHL0R0ETH0XY) 0. •2,4DICHL0R0PHEN0L 0. 1, 2, 4TRICHL0R0BENZ 0. NAPHTHALENE 0. 4-CHLOROANILINE •CL6BUTADIENE T •4CHL0R03METHYLPHEN 0. 2 2METHYLNAPHTHALENE 0. 4 ?<CL6C YCLOPENT AD I ENE •246TRICHL0R0PHNE0L 0. 2 T 2, 4, 5TRICHLDR0PHEN 0. 2 T 2CHL0R0NAPHTHALENE 0.8 2-NITROANILINE DIMETHYL PHTHALATE ACENAPHTHYLENE 1.3 3-NITROANILINE •ACENAPHTHENE 0.8 2.3, A,6-TETRACHLOROPHENOL n 300529 Oata Subject To'-^''datioii ; No 48 11^9 4 No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 J|22 Jm^ 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 jmy WB 49 SO Name C555 C560 0565 m/z 152 136 164 188 240 264 99 82 172 330 244 152 94 93 128 146 146 93 108 146 108 45 108 70 117 77 82 139 107 93 162 180 128 127 225 107 142 237 196 196 162 65 163 152 138 153 232 184 109 168 &2,4DINITROPHENOL &4NITROPHENOL DIBENZOFURAN Scan 584 742 958 1137 1472 1778 539 656 872 1054 1326 609 542 553 560 581 585 548 602 611 616 620 635 640 647 659 685 698 700 -710 726 737 745 754 765 806 829 855 864 868 889 902 924 940 953 962 998 964 967 981 Time 1 9:44 12:22 15: 58 18:57 24:32 29: 38 8: 59 10: 56 14:32 17:34 22:06 10:09 9:02 9: 13 9:20 9:41 9:45 9:08 10:02 10: 11 10: 16 10:20 10: 35 10:40 10:47 10: 59 11:25 11: 38 11: 40 11: 50 12:06 12: 17 12:25 12:34 12:45 13:26 13: 49 14: 15 14: 24 14:28 14:49 15:02 15: 24 15:40 15: 53 16: 02 16: 38 16: 04 16: 07 16:21 Ref 1 2 3 4 5 6 1 2 3 3 5 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3 3 3 3 3 3 0. 0. 0. 1. 0. 1. 0. 0. 0. 0. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. / 0. 8 RRT 000 000 000 000 000 000 923 884 910 100 901 043 928 947 959 995 002 938 031 046 055 062 087 096 108 888 923 941 943 957 978 993 004 016 031 086 117 892 902 906 928 942 965 981 995 004 042 006 009 024 A. Meth A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BV A VB A BB A BV A VB A BV A BV A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A VV A BB A BB A BB A BB A BV A VB A BB A BB A BB A BB A BB A BB A BB A BB A BB. A BB Area(Hght) 6313. 23816. 12531. 12059. 10510. 11372. 32923. 29275. 38256. 4396. 27201. 15797. 37591. 35252. 25390. 27052. 26374. 32941. 18387. 24927. 26225. 33307. 27565. 19931. 11436. .29741. 59583. 19118. 20631. 35152. 17719. 17863. 70308. 9541. 9551. 19370. 43910. 7132. 10779. 10390. 35501. 11503. 36199. 55237. 846. 31670. 9052. 4846. 5217. 45705. ^ Amount 20. 000 20. 000 20. 000 20. 000 20. 000 20. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB y.Tot 0. 0. 0. 0. 0. 0. 41 41 41 41 41 41 23 23 23 23 23 23 23 23 . 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 Vi .0^ { f 300530 Dat. •.oj-fTU -i /. ••-. No 1 i 2 • 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 |27 he 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 Ret(L) 9: 12: 15: 18: 24: 29: 8: 10: 14: 17: 22: 10: 9: 9: 9: 9: 9; 9: 10: 10: 10: 10: 10: 10: 10: 10: 11: 11: 11: 11: 12: 12: 12: 12: 12: 13: 13: 14: 14: 14: 14: 15: 15: 15: 15: 16: 16: 16: 16: 16- 44 22 58 57 32 38 59 56 32 34 06 09 02 13 20 41 45 08 02 11 16 20 35 40 47 59 25 38 40 50 06 17 25 34 45- 26 49 15 24 28 49 02 24 40 53 02 38 04 07 21 Ratio 00 00 00 00 00 00 00 00 00 00' 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 RRT(L> 0. 0. 0. 1. 0. 1. 0. 0. 0. 0. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 000 000 000 000 000 000 923 884 910 100 901 043 928 947 959 995 002 938 031 046 055 062 087 096 108 888 923 941 943 957 978 993 004 016 031 086 117 892 902 906 928 942 965 981 995 004 042 006 009 024 Ratio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 Amnt 20. 00 20. 00 20. 00 20. 00 20. 00 20. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 Amnt(L> 20. 00 20. 00 20. 00 20. 00 20. 00 20. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 R. Fac R. 1. 000 1. 000 1. 000 1. 000 1. 000 1.000 1. 738 0. 410 1. 018 0. 117 0. 863 0. 834 1. 985 1. 861 1. 341 1. 428 1. 393 1. 739 0. 971 1. 316 1. 385 1. 759 1. 455 1. 052 0. 604 0. 416 0. 834 0. 268 0. 289 0. 492 0. 248 0. 250 0. 984 0. 134 0. 134 0. 271 0. 615 0. 190 0. 287 0. 276 0. 944 0. 306 0. 963 1. 469 0. 023 0. 842 0. 241 0. 129 0. 139 1. 216 Fac(L) 1. 1. 1. 1. 1. 1. 1. 0. 1. 0. 0. 0. 1. 1. 1. 1. 1. 1. 0. 1. 1. 1. 1. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 0. 0. 0. 0. 0. 1. 000 000 000 000 000 000 738 410 018 117 863 834 985 861 341 428 393 739 971 316 385 759 455 052 604 416 834 268 289 492 248 250 984 134 134 271 615 190 287 276 944 306 963 469 023 842 241 129 139 216 Rat: LO 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 ^ ,ifi ,<o 300531 ^ Quantitation Report F i l e : CS0Z2Q95D m Data: CS022095D. TI /20/95 12:05:00 'ample: SSTD120 290-12-SV60 Conds.: 0. 25 X 30M RTX-5 l.OUM 45/4-300ei2 Formula: Instrument: C Submitted by: Analyst: SRA INST C Weight: Acct. No. 1. 001 AMOUNT=AREA * REF AMNT/(REF AREA • RESP FACT) Resp. fac. from Library Entry m m No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 ^6 %7 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 No 51 52 53 ^4 |5 56 57 58 Name C570 C543 C5S0 C585 C590 C595 C610 C615 C625 C630 C635 C640 C645 C650 C655 D200 C647 C715 C720 C725 C730 C740 C735 C760 C775 C780 C785 C790 C765 C770 C430 C310 C319 CS70 CS50 m/z 165 165 149 204 166 138 198 169 2. 4DINITR0T0LUENE 0.2 2, 6DINITR0T0LUENE 0. 2 DIETHYL PHTHALATE 4CHL0R0PHENYL PHEN 0.4 FLUORENE 0. 9 4-NITROANILINE 4,6DINITR02METHYLPH •DIPHENYLAMINE 4BR0M0PHENYL PHENY 0. 1 CL6BENZENE 0. 1 •PENTACHLOROPHENOL 0. 05 PHENANTHRENE 0. 7 ANTHRACENE 0. 7 DI-NBUTYLPHTHALATE^ •FLUORANTHENE 0. 6 1.2-DIPHENYLHYDRAZINE CARBAZOLE PYRENE 0. 6 BUTYLBENZYLPHTHALATE 3,3'CL2BENZIDINE BENZO(A)ANTHRACENE 0.8 BIS(2ETHYLHEXYL)PHTH CHRYSENE 0.7 •DI-N-OCTYLPHTHALATE •BENZO(A)PYRENE 0.7 INDEN0(1,2, 3CD)PYR 0.5 DIBENZO(A, H)ANTHRA 0.4 BENZO(G, H. DPERYLE 0.5 BENZO(B)FLUORANTHE 0.7 BENZO(K)FLUORANTHE 0.7 BENZOIC ACID N-NITROSODIMETHYLAMINE PYRIDINE 2-CHL0R0PHEN0L-D4 0.8 2-FLUOROPHENOL 0.6 Scan Time Ref RRT 983 16:23 3 1.026 934 15: 34 3 0. 975 1007 16:47 3 1.051 1019 16: 59 3 1. 064 1023 17:03 3 1.068 1027 17:07 3 1. 072 1031 17: 11 4 0. 907 1033 17: 13 4 0. 909 T T T T (SS-7) (SS-5) Meth A BB A BB A BB A BB A BB A BB A BB A BB Area(Hght) 10979. 8739. 35154. 17776. 36393. 1853. 5771. 12526. Amount 60. 60. 60. 60. 60. 60. 60. 60. 000 000 000 000 000 000 000 000 • - — '^ ^ PPB PPB PPB PPB PPB PPB PPB PPB , - 300532 y.Tot 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 1. 23 Dat IB- >"b!ectTo V?^'(^yorf J& No 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 .85 No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 £3 N 75 76 77 m/z 248 284 266 178 178 149 202 77 167 202 149 252 228 149 228 149 252 276 278 276 252 252 122 74 79 132 112 Scan Time Ref 1078 17 1099 IB 1119 18 1140 19 1145 19 1200 20 1285 21 1039 17 1162 19 1315 21 1384 23 1459 24 1469 24 1456 24 1477 24 1559 25 1764 29 2148 35 2149 35 2263 37 1680 28 1686 28 713 11 223 3 223 3 557 9 414 6 Ret(L) Ratio 16: 15: 16: 16: 17: 17: 17: 17: 17: 18: 18: 19: 19: 20: 21: 17: 19: 21: 23: 24: 24: 24: 24: 25: 29: 35: 35: 23 1.00 34 1. 00 47 1.00 59 1.00 03 1.00 07- 1.00 11 1.00 13 1.00 58 1.00 19 1.00 39 1.00 00 1. 00 05 1.00 00 1.00 25 1.00 19 1.00 22 1. 00 55 1.00 04 1. 00 19 1.00 29 1.00 16 1. 00 37 1. 00 ' 59 1.00 24 1.00 48 1.00 49 1. 00 :5S : 19 :39 :00 :05 :00 :25 : 19 :22 : 55 :04 : 19 :29 : 16 :37 : 59 :24 :48 :49 :43 :00 :06 : 53 :43 :43 : 17 : 54 RRT(L 1. 026 0. 975 1. 051 1. 064 1. 068 1. 072 0. 907 0. 909 0; 948 0. 967 0. 984 1. 003 1. 007 1. 055 1. 130 0. 914 1. 022 0. 893 0. 940 0. 991 0. 998 0. 989 1. 003 0. 877 0. 992 1. 208 1. 209 A 4 4 4 4 4 4 4 4 5 5 5 5 5 5 6 6 6 6 6 6 6 2 1 1 1 1 RRT 0. 948 0. 967 0. 984 1. 003 1. 007 1. 055 1. 130 0. 914 1. 022 0. 893 0. 940 0. 991 0. 998 0. 989 1. 003 0. 877 0. 992 1. 208 1. 209 1. 273 0. 945 0. 948 0. 961 0. 382 0. 382 0. 954 0. 709 1 Ratio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 Me A A A A A A A A A A A A A A A A A A A M M M M M M A M th BB BB BB BV VB BB BB VB BV BV BB BB BV BB VB BB BB BB B B ( / XX % XX ^ XX XX XX XX Area(Hght) 8675. 8849. 6562. 41687. 45190. 56428. 39957. 53238. 4049. 42917. 22937. 7984. 35758. 30859. 34556. 51751. 32081. 34314. y 28249. vR 30196. 35261. 38557. 13871. 17923. 31532. BB t 24956. XX ' Amnt 60 60 60 60 60 60 60 60 60 60 60 60 60 60 60 60 60 60 60 60 60 60 60 60 60 60 60 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 « 24347. Amnt(L) 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 Amount 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 60. 000 PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB R. Fac R. Fac(L) 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 1. 1. 1 1 0 1 0 0 1 0 1 1 0 1 0 292 232 935 473 968 049 160 346 240 245 181 152 249 560 104 472 112 361 727 253 134 979 096 517 940 006 828 0. 292 0. 232 0. 935 0. 473 0. 968 0. 049 0. 160 0. 346 0. 240 0. 245 0. 181 1. 152 1. 249 1. 560 1. 104 1. 472 0. 112 1. 361 0. 727 0. 253 1. 134 0. 979 1. 096 1. 517 0. 940 1. 006 0. 828 y.Tot Rat 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 23 io 00 00 00 00 00 00 00 -«t 00/^e*' 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 Data SL- ToV 300533 No 78 79 JBO 81 82 83 84 85 Ret(L) 37:43 28:00 28:06 11: 53 3:43 3:43 9: 17 6: 54 Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. OO 1. 00 RRT(L) 1.273 0. 945 0. 948 0. 961 0. 382 0. 382 0. 954 0. 709 Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 'Amnt 60. 00 60. 00 60. 00 60. 00 60.00 60. 00 60. 00 60. 00 Amnt(L) 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 60. 00 R. Fac R. 0. 885 1.034 1. 130 0. 194 0. 946 1. 665 1. 318 1. 286 Fac(L) 0. 885 1. 034 1. 130 0. 194 0. 946 1. 665 1. 318 1. 286 Rat: io 00 00 00 00 00 00 00 00 ^ o-V lip" 300534 V''--i.S\M€- y vaHdEtk'^ •a * DATA FROM FILE: CS022035E SCANS 406 TO 1136 ACQUIRED: 02/20/95 12:51:i CALI: CS022035E U SAMPLE: SSTDOBO 2S0-12-SU40 CONDS.: 0.25 X 30M RTX-5 l.OUM 45/4-300212 INST C 500 . 8:20 600 . 10:00 700 _ 11:40 c;- 1-1 OJ ;.n O < !V_ a,. a' V\ to o o tn to 800 . 13:20 300 15:30 1000 . 16:40 to li^vj 1 ':•: ^o ^ SCf;U I i i r l - I Ju-^ CS50 2-FLUGROPHENOL 0.6 (SS-5) 100.0.^ ( 53504.) -^«45- D5-PHEN0L ;37> -CHL0R0PHEN0L-D4 O.S (SS-7) 0.8 (SS-4) 5-A130 04-1,4 DICHLOROBENZENE (IS-1) :SS?5 1,2-CL2BENZENE-D4 0.4 (S5-8) I .;ariwiPTTffi". irriTfri/!BBHaMBa»{rai> •CS20 D5-NITROBENZENE 3.2 (SS-1) ^g.nnPHTNALENE (IS-2) CS25 2-FLUOROBIPHENYL 0.7 (SS-2) CI 58 Ul'3-AC£NAPHTHENE (IS-3) CS55 2,4,6TRIBROMOPHENOL (SS-6) S661 tt2 «3# CUO rjlB-FfeiaiflHTHRRHF (IS-4) DATA FROM FILE: CS022095E SCANS 1186 TO 2400 ACQUIRED: 02/20/95 12:51:00 CALI: CSV322095E ttl SAMPLE: SSTDOSO 290-12-SU40 CONDS.: 0.25 X 30M RTX-5 l.OUM 45/4-300312 INST C -T-i 1200 20:0t 1400 4 23:20 1600 _ 26:40 1800 _ 30:00 2yyy _ .33:20 o ,: 2200 . i 35:40 to' oi Si I a\ : 1 r.i ± J 100.0:^ ( 33728.) 1330" D14-P-TEKPHENYL 0.5 (SS-3) •l^y:u*u^a^l!lJaLg^i^jJ^raff^-,- D12-GHRYSENE (IS-5) D12-FERYLENE (IS-6) ^ Quantitation Report File: CS022095E Data: CS022095E. TI i2/20/95 12: 51:00 Sample: SSTDOSO 290-12-SV40 Conds.: 0.25 X SOM RTX-5 l.OUM 45/4-300ei2 Formula: Instrument: C Submitted by: Analyst: SRA AMOUNT=AREA « REF AMNT/(REF AREA • RESP FACT) Resp. fac. from Library Entry INST C Weight: Acct. No. 1. 001 m No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 .16 Il7 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 33 39 40 ^1 1^2 43 44 45 46 47 Name CI30 CI40 CI 50 CI60 CI70 CI75 CS45 CS20 CS25 CS55 CS30 CS70 CS75 C315 C325 C330 C320 C345 C350 C355 C357 C365 C370 C375 C410 C415 C420 C425 C435 C440 C445 C450 C455 C460 C465 C470 C510 C515 C520 C525 C530 C535 C540 C545 C550 C321 C555 D4-l,4 DICHLOROBENZENE (IS-1) DS-NAPHTHALENE DIO-ACENAPHTHENE DIO-PHENANTHRENE D12-CHRYSENE D12-PERYLENE D5-PHEN0L D5-NITR0BENZENE 2-FLUOROBIPHENYL 2,A,6TRIBR0M0PHEN0L D14-P-TERPHENYL 2-CHL0R0PHEN0L-D4 1.2-CL2BENZENE-D4 •PHENOL O. 5 O. 8 O. 4 0. 8 BIS(2CHL0R0ETHYL)E 0.7 2CHL0R0PHEN0L 0. 8 ANILINE BENZYL ALCOHOL 1,2DICHL0R0BENZENE 0. 4 2METHYLPHEN0L 0. 7 2,2'0XYBIS(ICHLOROPR 6 5 3 2 4 1 (IS-2) (IS-3) (IS-4) (IS-5) (IS-6) 0. 8 (SS-4) 0. 2 (SS-1) 0.7 (SS-2) (SS-6) (SS-3) (SS-7) (SS-8) 4METHYLPHENOL 0. g^NITROSOPROPYLAMINE 0. 0. 0 0 0. -HEXACHLOROETHANE NITROBENZENE ISOPHORONE •2-NITROPHENOL 2,4-DIMETHYLPHENOL 0. 2 BIS(2CHL0R0ETH0XY) 0.3 •2, 4DICHL0R0PHEN0L 0.2 1, 2, 4TRICHL0R0BENZ 0.2 NAPHTHALENE 0. 7 4-CHLOROANILlNE •CL6BUTADIENE T •4CHL0R03METHYLPHEN 0. 2 2METHYLNAPHTHALENE O. 4 &CL6CYCL0PENTADIENE •246TRICHL0R0PHNE0L 0. 2 T 2, 4, 5TRICHL0R0PHEN 0. 2 T 2CHL0R0NAPHTHALENE 0. 8 2-NITROANILINE DIMETHYL PHTHALATE ACENAPHTHYLENE 1.3 3-NITROANILINE •ACENAPHTHENE 0. 8 2,3.4,6-TETRACHLOROPHENDL &2,4DINITR0PHEN0L -••1. , i ^ „ C ; •,---: 300537 = -• '^o Validaiiori! m No Name 48 C560 &4NITR0PHEN0L 9 C565 DIBENZOFURAN O. 8 0 C570 2, 4DINITR0T0LUENE 0. 2 T No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 1^ 13 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 |7 We 49 50 m/z 152 136 164 188 240 264 99 82 172 330 244 132 152 94 93 128 93 108 146 108 45 108 70 117 77 82 139 107 93 162 180 128 127 225 107 142 237 196 196 162 65 163 152 138 153 232 184 109 168 165 Scan 586 745 959 1138 1473 1779 543 660 876 1055 1326 563 610 544 556 566 550 605 611 618 625 636 640 651 662 689 700 700 713 "727 738 748 756 765 810 830 856 866 872 889 905 925 942 953 964 1001 967 969 982 983 Time 9: 12: 15: 18: 24: 29: 9: 11: 14: 17: 22: 9: 10: 9: 9: 9: 9: 10: 10: 10: 10: 10: 10: 10: 11: 11: 11: 11: 11: 12: 12: 12: 12: 12: 13: 13. 14 14: 14: 14 15. IS- IS 15 16 16 16 16 16 16 46 25 59 58 33 39 03 00 36 35 06 23 10 04 16 26 10 05 11 18 25 36 40 51 02 29 40 40 53 07 18 28 36 45 30 50 16 26 32 49 05 25 42 53 04 41 07 09 22 23 Ref 1 2 3 4 5 6 1 2 3 3 5 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3 3 3 3 3 3 3 0. 0. 0. 1. 0. 0. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. RRT 000 000 000 000 000 000 927 886 913 100 900 961 041 928 949 966 939 032 043 055 067 085 092 111 889 925 940 940 957 976 991 004 015 027 087 114 893 903 909 927 944 965 982 994 005 044 008 010 024 025 Meth A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A BB BB BB BB BB BB BB BB BB BB BB BB BB BV VB BB VV BB BB BB BB BB BB BB BB BB BV BB BB BB BB BB VV BB BB BB BB BB BB BB BB BB BB BB BB BB BB BB B& BB Area(Hght) 5425. 22368. 10935. 11022. 8939. 8778. 19874. 17611. 24347. 2482. 16348. 15319. 9781. 22516. 22173. 15413. 19513. 11033. 15387. 15584. 20123. 16771. 12184. 6838. 17905. 35440. 10722. 12335. 22063. 10782. 11240. 44395. 6102. 6036. 11176. 27218. 4458. 6095. 5926. 21064. 7022. 20542. 34424. 1187. 19688. 5406. 2433. 2315. 26410. 5900. (X Amount 20. 000 20. 000 20. 000 20. 000 20. 000 20. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 / 40. 000 *^40. 000 i rQTa '^iihie PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPD PPB PPB PPB PPB PPB PPB PPD PPB PPB PPB PPB PPB PPD PPB PPB PPB PPB PPJ3 PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB.. 7.Tot 0. 61 0. 0. 0. 0 0. 3C aTo Vauuuv 61 61 61 61 61 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 . 22 22 22 . 22 . 22 . 22 . 22 . 22 . 22 . 22 . 22 22 22 . 22 )0538 l U i t m No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 C 7 Es 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 1 Ret(L) 9:46 12:25 15:59 18: 58 24:33 29:39 9:03 11:00 14:36 17:35 22:06 9:23 10: 10 9:04 9: 16 9:26 9: 10 10: 05 10: 11 10: IS 10:25 10: 36 10: 40 10: 51 11:02 11: 29 11:40 11: 40 11: 53 12:07 12: IS 12:28 12:36 12: 45 13: 30- 13: 50 14: 16 14: 26 14:32 14: 49 15:05 15:25 15:42 15: 53 16:04 16:41 16:07 16: 09 16: 22 16: 23 Ratio 00 00 00 00 00 00 00 00 00, 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 RRT(L) 1. 000 1. 000 1.000 1. 000 1.000 1. ooo 0. 927 0. 886 0. 913 1. 100 0. 900 0. 961 1. 041 0. 928 0. 949 0. 966 0. 939 1. 032 1. 043 1. 055 1. 067 1. 085 1. 092 1. Ill 0. 889 0. 925 0. 940 0. 940 0. 957 0. 976 0. 991 1. 004 1. 015 1. 027 1. 087 1. 114 0. 893 0. 903 0. 909 0. 927 0. 944 0. 965 0. 982 0. 994 1. 005 1. 044 1. 008 1. 010 1. 024 1. 025 Ratio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 Amnt 20. 00 20. 00 20. 00 20. 00 20. 00 20. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 Amnt(L) 20. 00 20. 00 20. 00 20. 00 20. 00 20. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 R. Fac R. 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 1.832 0. 394 1. 113 0. 113 0. 914 1. 412 0. 901 2. 075 2. 044 1. 421 1. 798 1. 017 1. 418 1. 436 . 1.855 1. 546 1. 123 0. 630 0. 400 0. 792 0. 240 0. 276 0. 493 0. 241 0. 251 0. 992 0. 136 0. 135 0. 250 0. 608 0. 204 0. 279 0. 271 0. 963 0. 321 0. 939 1. 574 0. 054 0. 900 0. 247 0. Ill 0. 129 1. 208 0. 270 Fac(L) 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 1. 832 0. 394 1. 113 0. 113 0. 914 1. 412 0. 901 2. 075 2. 044 1. 421 1. 798 1. 017 1. 418 1. 436 1. 855 1. 546 1. 123 0. 630 0. 400 0. 792 0. 240 0. 276 0. 493 0. 241 0. 251 0. 992 0. 136 0. 135 0. 250 0. 608 0. 204 0. 279 0. 271 0. 963 0. 323 0. 939 1. 574 0. 054 0. 900 0. 247 0. Ill 0. 129 1. 208 0. 270 Ratio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 . 00 . 00 , 00 , 00 , 00 (C O.D'V w 300539 ^Jujcct \z yyri2\lon ^ Quantitation Report File: CS022095E Data: CS022095E. TI j|||02/20/95 12:51:00 •Pample: SSTDOSO 290-12-SV40 * Conds.: 0.25 X 30M RTX-5 l.OUM 45/4-300(212 Formula: Instrument: C Submitted by: Analyst: SRA INST C Weight: Acct. No. 1. 001 AMOUNT=AREA « REF AMNT/(REF AREA • RESP FACT) Resp. fac. from Library Entry M No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 166 1^7 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 No 51 52 53 ^4 h ^6 57 58 Name C543 C580 C585 C590 C610 C615 C625 C630 C635 C640 C645 C650 C655 D200 C647 C715 C720 C725 C730 C740 C73S C760 C775 C780 C785 C790 C765 C770 C595 C430 C335 C340 CS50 C310 C319 m/z 165 149 204 166 198 169 248 284 2, 6DINITR0T0LUENE 0.2 DIETHYL PHTHALATE 4CHL0R0PHENYL PHEN 0. 4 FLUORENE 0. 9 A.6DINITR02METHYLPH •DIPHENYLAMINE 4BR0M0PHENYL PHENY 0. 1 CL6BENZENE 0. 1 •PENTACHLOROPHENOL 0. 05 PHENANTHRENE 0.7 ANTHRACENE 0. 7 DI-NBUTYLPHTHALATE •FLUORANTHENE 0. 6 1.2-DIPHENYLHYDRAZINE CARBAZOLE PYRENE 0. 6 BUTYLBENZYLPHTHALATE 3,3'CL2BENZIDINE BENZO(A)ANTHRACENE 0.8 BIS(2ETHYLHEXYL)PHTH CHRYSENE 0. 7 •DI-N-OCTYLPHTHALATE •BENZO(A)PYRENE 0.7 - INDENOd, 2, 3CD)PYR 0.5 DIBENZO(A.H)ANTHRA 0.4 BENZO(G,H< DPERYLE 0. 5 BENZO(B)FLUORANTHE 0.7 BENZO(K)FLUORANTHE 0.7 4-NITROANILINE BENZOIC ACID 1,3DICHL0R0BENZENE 0.6 • 1.4DICHL0R0BENZENE 0.5 2-FLUOROPHENOL 0. 6 N-NITROSODIMETHYLAMINE PYRIDINE Scan Time Ref RRT 937 15: 37 3 0. 977 1008 16:48 3 1. 051 1019 16:59 3 1.063 1024 17:04 3 1.068 1033 17: 13 4 0. 90S 1035 17: 15 4 0. 909 1078 17:58 4 0.947 1100 18: 20 4 0. 967 T T T (SS-5) T M€ A A A A A A A A !th BB BB BB BB BB BB DB BB Area(Hght) 4S22. 18970. 10152. 20952. 3323. 8339. 5192. 5541. Amount 40. 40. 40. 40. 40. 40. 40. 40. 000 000 000 000 000 000 000 000 „,-'•• r , . . : U ..' PPB PPB PPB PPB PPB PPB PPP PPB y.Tot 1. 22 1. 22 1. 22 1. 22 1. 22 3. 22 1. 22 1.22 300540 ;ucjea 10 vairdatiopj « No 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 .85 No 51 52 S3 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 J 3 h A 5 76 77 m/z 266 178 178 149 202 77 167 202 149 252 228 149 228 149 252 276 278 276 252 252 138 122 146 146 112 74 79 Scan 1120 1141 1146 1200 1286 1040 1163 1315 1384 1460 1469 1457 1477 1559 1762 2144 2146 2257 1678 1685 1029 713 581 589 424 238 237 Time Ref 18:40 19:01 19:06 20: 00 21:26 17:20 19:23 21: 55 23:04 24:20 24:29 24: 17 24:37 25: 59 29:22 35:44 35:46 37:37 27: 58 28:05 17:09 11: 53 9: 41 9: 49 7: 04 3: 58 .3: 57 Ret(L) Ratio RRT(L] 15: 37 16:48 16: 59 17: 04 17: 13 17: 15 17: 58 18:20 18: 40 19: 01 19:06 20: 00 21:26 17:20 19:23 21: 55 23:04 24:20 24:29 24: 17 24: 37 25: 59 29:22 35: 44 35: 46 37: 37 27: 58 1. 00 1. 00 1. 00 1. 00 1. 00 . 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 0. 977 1. 051 1. 063 1. 068 0. 908 0. 909 0. 947 0. 967 0. 984 1. 003 1. 007 1. 054 1. 130 0. 914 1. 022 0. 893 0. 940 0. 991 0. 997 0. 989 1. 003 0. 876 0. 990 1. 205 1. 206 1. 269 0. 943 4 4 4 4 4 4 4 5 5 5 5 5 5 6 6 6 6 6 6 6 3 2 RRT 0. 984 1. 003 1. 007 1. 054 1. 130 0. 914 1. 022 0.893 0. 940 0. 991 0. 997 0. 989 1. 003 0. 876 0. 990 1. 205 1. 206 1. 269 0. 943 0. 947 1. 073 0. 957 0. 991 1. 005 0. 724 0. 406 0. 404 Ratio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 Me A A A A A A A A A A A A A A A A A M M M A M M M M M M th BB BV VB BB BB VB BB BB BB BB BV BB VB BB BB BB Area< 393 Hght) 2. 25819. 27063. 33674. 23471. 33484. 5003. 25477. 13220. 4810. 20454. 18096. 19950. 28811. 17230. 19109. BB ^fy f 15977. XXM.?> 16579. XX.)\V'\ 18018. XX BB y xx' XX XX XX XX XX , Amnt 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 .00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 20587. 1411. 7232. 16082. 17879. 14571. 9890. ' 16888. Amnt(L) 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 40. 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 Amount 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 40. 000 R. Fac R. F 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 1. 1. 1. 1 0 1 0 0 1 1 1 1 0 1 0. 0. 1. 220 867 464 958 151 401 236 251 177 171 228 528 065 519 227 425 739 269 144 012 116 641 981 088 910 944 026 PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB ac(L) R 0. 220 0. 867 0. 464 0. 958 0. 151 0. 403 0. 236 0. 251 0. 177 1. 171 1. 228 1. 523 1. 065 1. 519 0. 227 1. 425 0. 739 0. 269 1. 144 1. 012 1. 116 1. 641 0. 981 1. OSS 0. 910 0. 944 "^ 30 y.Tot at: 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 10 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 nA-r.pO.^ 0541 z 7 — .... ilO v'ciUUoi-.Ov^ m No 78 7"^ teo 81 82 83 84 85 Ret(L) 28: 05 17:09 11:53 9:41 9:49 7:04 3: 58 3: 57 Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 RRT(L) 0. 947 1. 073 0. 957 0. 991 1. 005 0. 724 0. 406 0. 404 Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 Af 40. 40. 40. 40. 40. 40. 40. 40. nnt 00 00 00 ©0 00 00 00 00 Amnt(L) 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 R. Fac R. 1. 173 0. 065 0. 162 1.482 1. 648 1. 343 0. 912 1. 556 Fac(L) 1. 173 0. 065 0. 162 1.482 1.648 1. 343 0. 912 1. 556 Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1.00 1. 00 A t^' .n/ / 300542 Dat? Subject Initial Calibration Data Instrument Identifier: C alibration Date: 2/20/95 IN RF: SW(8<) = . 05 CLP = . 01 OR BELOW MAX '/.RSD: SW(«) = 307. CLP = 20. 57.* CS50 CS45 CS20 CS25 CS55 \ CS30 "^ CS70 CS75 C315 C325 C330 C335 C340 C320 C310 C319 C345 C350 C355 ^ Q 5 7 -^1^365 C370 C375 C410 C415 C420 C425 C430 C435 C440 C445 C450 C455 C460 C465 C470 C510 C515 C520 C525 C530 C535 C540 C545 ^ ^ 5 0 ^ § 2 1 C555 Compound 2-FLUORDPHENOL D5-PHEN0L , D5-NITR0BENZENE 2-FLUOROBIPHENYL 0. 0. 0. 0. 2,4,6TRIBROMOPHENOL D14-P-TERPHENYL 2-CHL0R0PHEN0L-D4 1.2-CL2BENZENE-D4 •PHENOL BIS(2CHL0R0ETHYL)E 2CHL0R0PHEN0L 1,3DICHL0R0BENZENE •1,4DICHL0R0BENZENE ANILINE 0. 0. 0. 0. 0. 0. 0. 0. 6 8 2 7 5 8 4 8 7 8 6 5 N-NITR OSODIMETHYLAMINE PYRIDINE BENZYL ALCOHOL 1,2DICHL0R0BENZENE 2METHYLPHEN0L 0. 0. 2, 2'OXYBISdCHLOROPR 4METHYLPHEN0L &NITROSOPROPYLAMINE HEXACHLOROETHANE NITROBENZENE ISOPHORONE •2-NITROPHENOL 2,4-DIMETHYLPHENOL BENZOIC ACID BIS(2CHL0R0ETH0XY) •2,4DICHL0R0PHEN0L 1,2, 4TRICHLOROBENZ NAPHTHALENE 4-CHLOROANILINE •CL6BUTADIENE •4CHL0R03METHYLPHEN 2METHYLNAPHTHALENE &CL6CYCLOP ENTADIENE •246TRICHLOROPHNEOL 2,4,5TRICHL0R0PHEN 2CHL0R0NAPHTHALENE 2-NITROANILINE DIMETHYL PHTHALATE ACENAPHTHYLENE 3-NITROANILINE •ACENAPHTHENE 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 0. 4 7 6 5 3 2 4 1 2 3 2 2 7 2 4 2 2 8 3 8 2, 3.4,6-TETRACHLDROPHE ?,.2, 4DINITR0PHEN0L F }F 10 1. i. 0. 1. 0. 0. 1. 0. 2. 2. 1. 1. 1. 3. 0. 1. 0. 1. 1. 1. 1. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 0. 0. 0. 0. 275 774 394 100 105 900 292 840 166 237 344 401 354 064 863 308 897 300 369 790 427 045 565 401 776 205 266 106 473 234 248 004 286 129 260 623 124 265 272 921 326 937 516 215 888 264 097 F IF 25 1. 1. 0. 0. 0. 0. 1. 0. 1. 1. 1. 1. 1. 1. 0. 0. 0. 1. 1. 1. 1. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 0. 0. 0. 0. 169 557 342 971 107 791 221 773 906 833 268 390 417 840 647 632 852 322 269 700 290 033 581 376 756 223 242 121 475 216 245 927 166 132 214 583 169 259 249 942 288 903 445 092 841 236 095 RF 40 1. 1. 0. 1. 0. 0. 1. 0. 2. 2. 1. 1. 1. 1. 0. 1. 1. 1. 1. 1. 1. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 0. 0. 0. 0. 343 832 394 113 113 914 412 901 075 044 421 482 648 798 912 556 017 418 436 855 546 123 630 400 792 240 276 162 493 241 251 992 136 135 250 608 204 279 271 963 321 939 574 054 900 247 111 RF 60 1. 1. 0. 1. 0. 0. 1. 0. 1. 1. 1. 1. 1. 1. 0. 1. 0. 1. 1. 1. 1. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 0. 0. 0. 0. 286 738 410 OlS 117 863 318 834 985 861 341 428 393 739 946 665 971 316 385 759 455 052 604 416 834 268 289 194 492 248 250 984 134 134 271 615 190 287 276 944 306 963 469 023 842 241 , 129 RF 80 1. 1. 0. 1. 0. 0. 1. 0. 1. 1. 1. 1. 1. 1. 0. 1. 0. 1. 1. 1. 1. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. b. 0. 1. 0. 0. 0. 0, 189 636 387 004 108 792 259 819 885 600 279 311 356 764 918 032 924 271 327 751 419 031 576 378 761 175 274 202 468 240 234 910 201 128 264 556 205 293 287 913 321 929 364 033- 815 232 . 138 Mean RF 1. 1. 0. 1. 0. 0. 1. 0. 2. 1. 1. 1. 1. 2. 0. 1. 0. 1. 1. 1. 1. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 0. 0. 0. 0. ' - 253 708 386 042 111 852 301 834 004 915 331 403 434 042 858 239 932 326 358 771 428 0 5 8 ^ 592 395 784 223 270 157 481 236 246 964 185 132 252 598 179-^ 277 272 937 313 935 474 084 858 24 5 115./ 7.RSD 5. 6. 6. 5. 4. 6. 5. 5. 5. 12. 4. 4. 8. 28. 14. 33. 6. 4. 4. 3. 6. 3. 4. 4. 3. 15. 6. 27. 2. 5. 2. 4. 34. 2. 8. 4. 18. 5. 5. 2. 5. 2. 5. 93. 4. 5. 16. 300543 754 438 621 961 417 858 556 520 871 ^ 503 594 436 557.^ 062 120 721 875 186 623 211 427 576 410 341 991 662-t 349 097 410 081-« 902 371 077 256.^ 898 .< 578 764 161." 061 145 048 298 337 208 160^ 080 736 , _ „ . .w .„,.—...w-i. C560 8<4NITROPHENOL 0. 136-0. 116 0. 129 0. 139 0. 147 0. 134-' 8. 846 C565 DIBENZOFURAN O.S 1.279 1.178 1.208 1.216 1.151 1.207 3.992 C570 2, 4DINITR0T0LUENE 0. 2 0. 279 0. 261 0. 270 0. 292 0. 286 0. 278 4. 511 pA3 2, 6DINITR0T0LUENE 0. 2 0. 209 0. 206 0. 220 0. 232 0. 237 0. 221 6. 204 580 DIETHYL PHTHALATE O. 976 0. BBS 0. 867 0. 935 0. 874 O. 909 5. 095 C585 4CHL0R0PHENYL PHEN 0.4 0.465 0.435 0.464 0.473 0.433 0.455 4.087 C590 FLUORENE 0. 9 0. 974 0. 913 0. 958 0. 968 0. 943 0. 952 2. 541 C595 4-NITROANILINE 0. 123 0. 081 0. 065 0. 049 0. 054 0. 075 40. 127 C610 4, 6DINITR02METHYLPH 0.143 0.128 0.151 0.160 0.161 0.149 9.004 C615 *DIPHENYLAMINE 0.598 0.395 0.401 0.346 0.308 0.410 27. 362^' C625 4BR0M0PHENYL PHENY 0.1 0.232 0.225 0.236 0.240 0.215 0.230 4.297 C630 CL6BENZENE 0. 1 0. 259 0. 234 0. 251 0. 245 0. 221 0. 243 6. 195 C635 •PENTACHLOROPHENOL 0. 05 0. 167 0. 162 0. 177 0. 181 0. 172 O. 172 4. 629-^ C640 PHENANTHRENE 0.7 1.177 1.144 1.171 1.152 1.088 1.147 3.082 C645 ANTHRACENE 0.7 1.246 1.168 1.228 1.249 1.138 1.206 4.143 C650 DI-NBUTYLPHTHALATE 1.504.1.409 1.528 1.560 1.464 1.493 3.919 C655 •FLUORANTHENE 0.6 1.090 1.003 1.065 1.104 1.091 1.071 3. 765> D200 1, 2-DIPHENYLHYDRAZINE 1.502 1.352 1.519 1.472 1.408 1.451 4.796 C647 CARBAZOLE 0.982 0.496 0.227 0.112 0.113 0.386 95.302 C715 PYRENE 0.6 1.332 1.365 1.425 1.361 1.218 1.341 5.698 C720 BUTYLBENZYLPHTHALATE O. 688 0. 688 0. 739 0. 727 0. 682 0. 705 3. 761 C725 3, 3'CL2BENZIDINE 0.287 0.261 0.269 0.253 0.231 0.261 7.895 C730 BENZO (A) ANTHRACENE 0.8 1.116 1.069 1.144 1.134 1.061 1.105 3.408 C740 BIS(2ETHYLHEXYL)PHTH 0.961 0.908 1.012 0.979 0.951 0.963 3.971 C735 CHRYSENE 0.7 1.109 1.037 1.116 1.096 1.000 1.072 4.734 C760 •DI-N-OCTYLPHTHALATE 1.413 1.441 1.641 1.517 1.643 1.531 7.062.^ C765 BENZO(B)FLUORANTHE 0.7 0.991 0.949 1.026 1.034 1.137 1.028 6.816 C770 BENZO(K)FLUORANTHE 0.7 1.022 0.996 1.173 1.130 0.862 1.037 11.765 75 •BENZO(A)PYRENE 0.7 0.893 0.914 0.981 0.940 0.928 0.932 3.540-^ 80 INDENOd, 2, 3CD)PYR 0.5 0.857 1.044 1.088 1.006 0.981 0.996 8.749 C785 DIBENZO(A, H)ANTHRA 0.4 0.696 0.848 0.910 0.828 0.908 0.838 10.396 C790 BENZO(G. H, DPERYLE 0.5 0.741 0.882 0.944 0.885 0.902 0.871 8.819 .m V A" i 300544 --f'^ ^••b'ect "Tr V;->'i'^;'if!0- MASS SPECTRUM 02/21/95 10:16:00 + 7:56 SAMPLE: DFTPP 290-14-PERF CONDS.: 0.25 X 30M RTX-5 l.OUM «475 TO #477 AUERAGED - #470 Xl.OO BATA: CP022195A #476 CALI: CP0221S5A #1 BASE M/Z: 193 RIC: 7540. 45/4-300(212 INST C 100.0-J er o "+-:i ro 'IS RIC 02/21/95 10:16:00 SAMPLE: DFTPP 290-14-PERF CONDS.: 0.25 X 30M RTX-5 RANGE: G 1, 517 LABEL: N 100.8-1 DATA: CP022195A #475 CALI: CP022195A #1 l.OUM 45/4-300(512 INST C 0, 4.0 QUAN: A O, l.O J O 462 SCANS 440 TO 500 BASE: U 20, 3 -RIC 476 h 449 to o o tn »(^ t42 471 *^ "2 IJ to O »C7 492 440 7:20 450 7:30 460 7:40 • »v. 470 7:50 I 430 8:00 I 490 8:10 505 SCAN 8:20 TIt€ RIC+MASS CHROMATOGRAM 02/21/95 10:16:00 SAMPLE: DFTPP 290-14-PERF CONDS.: 0.25 X 30M RTX-5 RANGE: G 1, 628 LABEL: N DATA: CP022195A #475 CALI: CP022195A #1 l.OUM 0, 4.0 45/4-300(212 QUAN: A 0, INST 1.0 J SCANS 500 TO 600 BASE: U 20, 100.0-1 184 1 237.5- a w l-r OJ tn c j r y n r-r I: ol p< i o'i RIC to o o vJ 507 512 524 528 541 trctr 563 567 586 592 500 8:20 520 8:40 I 540 9:00 560 9:20 580 9:40 .2 I y t-J 2383. 184.055 i 0.500 OOI ^2. 660 SCAN 10:00 TIME Mass List Data: 02/21/95 10:16:00 + 7:56 Cali: Sample: DFTPP 290-14-PERF Conds.: 0.25 X 30M RTX-5 l.OUM #475 to «477 •veraged - #470 Xl.OO CP022195A # 476 CF022195A # 1 Base m/z: RIC: 198 7640. 45/4-300ei2 INST C • 39 444 Mass 39? 49? 50? 51? 52? 57? 63? 69 74 75 76 77 78 79 80 81 06 93 98 97 103 1 107 ' 103 110 113 117 127 12B 129 135 148 167 163 179 180 186 187 196 198 199 204 205 206 207 217 221 k 224 r225 227 244 S s s s s S 5 S S S S s s s s s s s s s s s s s s s 5 s s s s s s s s s s s s s s 5 s s s s s s s s 0.00 % RA 2.05 0.27 8.47 40. 29 1. 16 1. 70 0. 93 47. 15 3. 39 5. 17 1. 16 53. 48 3. 21 2. 14 1. 78 3. 03 0. 80 4. 10 2. 41 1. 34 0. 62 12. 57 1. 78 27. 90 3. 92 7. 31 47. 24 3. 12 17. 02 0. 62 0. 89 3. 48 0. 53 1. 78 1. 43 11.59 2. 85 1. 60 100. 00 6. 33 1. 69 3. 74 18. 81 2. 94 4. 55 5. 97 9. 80 2. 05 3. 43 7. 40 0. Inten. 23. 3. 95. 452. 13. 20. 11. 529. 38. 58. 13. 600. 36. 24. 20. 34. 9. 46. 27. 15. 7. 141. 20. 313. 44. 82. 530. 35. 191. 7. 10. 39. 6. 20. 16. 130. 32. 18. 1122. 71. 19. 42. 211. 33. 51. 67. 110. 23. 39. B3. Minima Maxima Mass 246 255 256 258 274 275 276 277 296 323 365 423 441 442 443 444 Min « S S s s s 5 S s s s s s s s s s Inten: 0 •/, RA 0.62 37.79 4.81 0. 89 2.41 20. 59 1. 52 0. 53 3.65 0. 89 1. 52 2. 58 5. BB B3. 33 15. 78 0. 71 , •r -- 0. Inten. 7. 424. 54. 10. 27. 231. 17. 6. 41. 10. 17. 29. 66. 935. 177. 8. - 300548 Data Subiect To Validation CC/MS Tuning and Mass Calibration DECAFLUOROTR IPHENYi-PHOSPHINE Case Number: Inst ID: J-ab ID: CP022195A Laboratorv: GULF Sens Date: 02/21/95 Cali Date: 10/02/91 Data raltase authorized by: M/E Ion Abundance Criteria Contract: Sens Time: Analyst: 10: 16:00 JAM Spec # 475 51 30 to 607. of mass 198 68 less than 27. of mass 69 69 mass 69 relative abundance 70 less than 27. of mass 69 127 40 TO 60y. of mass 198 197 less than 17. of mass 198 198 base peak, 100% relative abundance 199 5 TD 97. of mass 198 275 10 TD 30y. of mass 198 365 greater than 17. of mass 193 441 less than mass 443 442 greater than A07. of mass 198 443 17 TO 23y. of mass 442 1 - value in parenthesis is 7. of mass 69 2 - value in parenthesis is 7. of mass 442 40. 29 0. 00 47. 15 0. 00 47. 24 0. 00 100. 00 6.33 20. 59 1. 52 5. B8 83. 33 15.78 ( ( 0. 0. (18. 00) 00) 93) 1 1 . 2 300549 •.7'o VaHdstion DATA FROM FILE: CS022195A SCANS 391 TO 1171 ACQUIRED: 02/21/95 10:32:00 CALI: CS022195A #1 SAMPLE: SSTD050 290-12-SU25 CONDS.: 0.25 X 30M RTX-5 l.OUM 45/4-300(212 INST C C /—^ V.) c y. fi' o u o' 3' 400 _r 6:40 500 . 8:20 600 - 10:00 300 _ 13:20 'Of 15:00 1000 _E •15:40 to o o Ol Ol linn ° ^13:2 1 if'C CS50 2-FLUOROPHENOL 100.0^ < 368G4.) 0.6 (SS-5) = — CS45 D5-PHEN0L 0.8 (SS-4) CS70 2-CHL0R0PHEN0L-D4 0.8 (SS-7) -CI30 D4-1,4DICHLOROBENZENE (IS-1) ^ CS75 1,2-CL2BENZEHE-D4 0.4 (5S-8) C520 D5-NITRCBEH2ENE 0.2 (SS-D a4J»- DS-NAPHTHALENE (IS-2) CS25 2-FLUOROBIPHENYL 0.7 (SS-2) ..^immniM-tijuiuwiifwiwi'.Ml BEfB— r.TfiO OlO-ACENAPHTHENE (IS-3) ISTZSUffiC - iMHJU»jJ.MJWWllHJBim!J<raainh. CS55 2,4.. 6TRI BROMOPHENOL (SS-6) «=2£JS&=SiO=EHEt4AHTHRENE (15-4) V . ' > Qy . ^ , . : » V . DATA FROM FILE: CS022195A SCANS 1171 TO 2400 ACQUIRED: 02/21/95 10:32:80 CALI: CS022195A #1 SAMPLE: SSTD050 290-12-SU25 CONDS.: 0.25 X 30M RTX-5 l.OUM 45/4-300l?12 INST C 1230 J 20:00 1400 . 23:20 1600 . 26:40 1SO0 _ 30:00 c w tn u. o- a> o ( - » • ^ o , O- % o 3 2fii?0 •"^•*; • T-r^ )i2.>3 ^ f i 6 : 4 0 O 1 o ! Ul 1 Olj H : i.:'iz L 1. 180.07J ( 28320.) CS30 D14-P-TERPHENYL 8.5 (SS-3) =«^^—&i2-CHRYSENE (IS-5) JUX-UUUiMgBi Tn75 D12-PERYLEHE (IS-5) » i , • Quantitation Report File: CS022195A Data: CS022195A. TI 02/21/95 10:32:00 Sample: SSTDOSO 290-12-SV25 Conds.: 0.25 X SOM RTX-5 l.OUM 45/4-300C12 ormula: Instrument: C ubmitted by: Analyst: JAM AMOUNT-AREA * REF AMNT/(REF AREA « RESP FACT) Resp. fac. from Library Entry INST C Weight: Acct. No. 1. 000 No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 kl9 bo 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 |a4 Ps 46 47 Name CI30 CI40 CI50 CI70 CI75 CS45 CS20 CS25 CS55 CS30 CS70 CS75 C315 C325 C330 C335 C340 C320 C345 C350 C355 C357 C365 C370 C375 C410 C415 C420 C425 C430 C435 C440 C445 C450 C455 C460 C465 C470 C510 C525 C530 C535 C540 C545 C550 C321 C555 D4-1.4 DICHLOROBENZENE DS-NAPHTHALENE DIO-ACENAPHTHENE D12-CHRYSENE D12-PERYLENE D5-PHENDL D5-NITR0BENZENE 2-FLUOROBIPHENYL 2,4,6TRIBR0M0PHEN0L 0. 8 0. 2 0. 7 D14-P-TERPHENYL 0.5 2-CHLOR0PHEN0L-D4 0.8 1,2-CL2BENZENE-D4 0.4 •PHENOL 0. 8 BIS(2CHL0R0ETHYL)E 0.7 2CHL0R0PHEN0L 0. 8 1, 3DICHL0R0BENZENE 0. 6 • 1,4DICHL0R0BENZENE 0. 5 T ANILINE BENZYL ALCOHOL 1,2D1CHL0R0BENZE:NE 0.4 2METHYLPHEN0L O. 7 T 2,2'DXYB1S(ICHLOROPR 4METHYLPHEN0L O. 6 T &NITROSOPROPYLAMINE 0. 5 HEXACHLOROETHANE 0. 3 T NITROBENZENE 0. 2 T ISOPHORONE 0. •2-NITROPHENOL- 0. 2.4-DIMETHYLPHENDL 0. BENZOIC ACID BIS(2CHL0R0ETH0XY) •2,4DICHL0R0PHEN0L 1,2, 4TRICHL0R0DFNZ NAPm HALENE 4-CHLOROANILINE •CL6BUTADIENE •4CHL0R03METHYLPHEN 2METHYLNAPHTHALENE &CL6CYCLOPENTAD1ENE 2CHL0R0NAPHTHALENE O. 8 2-NITROANILINE DIMETHYL PHTHALATE ACENAPHTHYLENE 1.3 3-NITROANILINE •ACENAPHTHENE 0. 8 2, 3, 4, 6-TETRACHLOROPHENDL e<2, 4DTNITR0PHEN0L 0. O. O. 0. 0. 0. (IS-1) (IS-2) (IS-3) (IS-5) (IS-6) (SS-4) (SS-1) (SS-2) (SS-6) (SS-3) (SS-7) (SS-B) 300552 Data Subject To N/a!!dat;on No Name 48 C560 &4NITR0PHEN0L 49 50 No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 |25 '26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 r C565 C570 m/z 152 136 164 240 264 99 82 172 330 244 132 152 94 93 128 146 146 93 108 146 108 45 108 70 117 77 82 139 107 122 93 162 180 128 127 225 107 142 237 162 65 163 152 138 153 232 184 109 163 165 DI6E IMZOFURA N 2,4DINITR0TDLUENE Scan 571. 728 941 1450 1733 533 644 858 1037 1309 550 595' 534 . 542 . 553 566 574 536 ' 592 . 596 605- 609 623' 625 634 646 673 684 686- 700- 697 712 721 731 740 749 795 812 838 871 888 907 924 937 946 984 949 955 96^ 966 Time 9:31 12: OB 15:41 24: 10 28:53 B: 53 10:44 14: IB 17: 17 21:49 9: 10 9:55 B: 54 9:02 9: 13 9:26 9:34 B: 56 9:52 9: 56 10: 05 10: 09 10:23 10: 25 10:34 10: 46 11: 13 11:24 11: 26 11:40 11: 37 11: 52 12: 01 12: 11 12:20 12: 29 13: 15 13: 32 13: SB 14: 31 14:48 15:07 15:24 15: 37 15: 46 16: 24 15: 49 15; 55 16: 04 16: 06 Ref 1 2 3 4 5 1 2 3 3 2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3 3 3 3 3 1. 1. 1. 1. 1. 0. 0. 0. 1. 0. 0. 1. 0. 0. 0. 0. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0 0. 0. 0. 0. O.B 0.2 RRT 000 000 000 000 000 933 BBS 912 102 903 963 042 935 949 968 991 005 939 037 044 060 067 091 095 110 887 924 940 942 962 957 978 990 004 016 029 092 115 891 926 944 964 982 996 005 046 009 015 024 027 T Meth A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A BD BB BD BB BB BB BB BB BB BB BB BB BB VB BB BV VB BV BB BB BB BB BB BB BB BB BV BB BB VV BB BB BB BV BB BB BB BD BB BB BB BB BB BB BB BB BD DD DB DD " Area(Hght) 6056. 24401. 136B9. 12645. 121B9. 12197. 10821. 15422. 1990. 12391. 9295. 5634. 14426. 14110. 9220. 9806. 10833. 13184. 6129. 9303. 9011. 12693. 9782. 7476. 4165. 11715. 22977. 5682. 7500. 4006. 14040. 7262. 7486. 28314. 7316. 3738. 8017. 18325. 2147. 15169. 5537. 16138. 24341. 2985. 13916. 4362. 1690. 2039. 210B4. 5213. CS<t>%7J.'i^^ Amount 20. 000 20. 000 20. 000 20. 000 20. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 Data Subject PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPK PPB PPB PPB PPB PPD PPB PPB PPB PPD PPB PPB PPB PPB PPB PPB PPB PPB PPD PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPD PPD 7.Tot 0. 95 0. 95 0.95 0. 95 0. 95 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 - 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 ]. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 300553 To Validation No Ret(L) 1 2 3 9:31 12:08 15:41 4 24: 10 5 28: 53 6 7 B 9 B:53 10:44 14: IB 17:17 10 21:49 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 No ^1 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 9: 10 9:55 8: 54 9:02 9: 13 9:26 9:34 B: 56 9: 52 9: 56 10:05 10:09 10:23 10:25 10:34 10:46 11: 13 11:24 11:26 11:40 11:37 11: 52 12: 01 12: 11 12:20 12:29 13: 15 13: 32 13: 58 14: 31 14:48 15:07 15:24 15:37 15:46 16:24 15:49 15:55 16:04 16:06 Ratio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 RRT(L) 1. 000 1.000 1. 000 1. 000 1. 000 0. 933 0. 685 0. 912 1. 102 0.903 0.963 1. 042 0. 935 0.949 0. 968 0. 991 1. 005 0. 939 1. 037 1. 044 1. 060 1. 067 1. 091 1. 095 1. 110 0. 887 0. 924 0. 940 0. 942 0. 962 0. 957 0. 978 0. 990 1. 004 1. 016 1. 029 1. 092 1. 115 0. 891 0. 926 0. 944 0. 964 0. 982 0. 996 1. 005 1. 046 1. 009 1. 015 1. 024 1. 027 Ratio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 . 00 . 00 . 00 . 00 Amnt 20. 00 20. 00 20. 00 20.00 20.00 25. 00 25. 00 25. 00 25. 00 25.00 25. 00 25. 00 25.00 25. 00 25. 00 25. 00 25. 00 25.00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 Amnt(L) 20.00 20. 00 20. 00 20.00 20. 00 25.00 25.00 25. 00 25. 00 25. 00 25.00 25. 00 25. 00 25.00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 R.Fac R. 1.000 1.000 1. 000 1. 000 1. 000 1. 611 0. 355 0. 901 0. 116 0.784 1.22B 0.744 1. 906 1. 864 1. 218 1. 295 1. 431 1.742 0. BIO 1. 295 1. 190 1.677 1. 29? 0. 988 0. 550 0. 384 0. 753 0. 186 0. 246 0. 131 0. 460 0. 238 0. 24 5 0. 928 0. 240 0. 123 0. 263 0. 601 0. 125 0. 836 0. 324 0. 943 1. 423 0. 174 0. 813 0. 255 0. 099 0. 119 1. 232 0. 305 Fac<L) 1.000 1.000 1. 000 1.000 1.000 1.611 0.355 0.901 0. 116 0. 784 1. 228 0.744 1. 906 1. 864 1.218 1. 295 1. 431 1.742 0. 810 1. 295 1. 190 1. 677 1. 292 0. 938 0. 550 0. 334 0. 753 0. 186 0. 246 0. 131 0. 460 0. 233 0. 24 5 0. 923 0. 240 0. 123 0. 263 0. 601 0. 125 0. 836 0. 324 0. 943 1. 423 0. 174 0. 813 0. 255 0. 099 0. 119 1.232 0. 305 Ratio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 . 00 . 00 . 00 . 00 . 00 . 00 300554 >]cct lb Validation Quantitation Report File: CS022195A Data: CS022195A. TI 02/21/95 10:32:00 Sample: SSTD050 290-12-SV25 Conds.: 0 . 2 5 X 30M RTX-5 l.OUM 45/4-300612 formula: I n s t r u m e n t : C submitted by: A n a l y s t : JAM INST C Weight: Acct. No. 1. 000 AM0UNT«AREA * REF AMNT/(REF AREA • RESP FACT) Resp. fac. from Library Entry No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 ^ 9 lo 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 Name C543 C5B0 C5B5 C590 C610 C615 C625 C630 C635 C640 C645 C650 C655 D200 C647 C715 C720 C725 C740 C760 C765 C770 C775 C780 C785 0790 CI60 CS50 C310 C319 C515 C520 C595 C730 C735 2i 6DINITR0TDLUENE 0. 2 DIETHYL PHTHALATE 4CHL0RDPHENYL PHEN 0. 4 FLUORENE 0. 9 4,6DIN1TR02METHYLPH •DIPHENYLAMINE 4BR0M0PHENYL PHENY 0. 1 CL6BENZENE 0. 1 T •PENTACHLOROPHENOL 0. 05 T PHENANTHRENE 0. 7 ANTHRACENE O.7 DI-NBUT YLPHTHALATE •FLUORANTHENE 0.6 1,2-DIPHENYLHYDRAZINE CARBAZOLE PYRENE O. 6 BUTYLBENZYLPHTHALATE 3,3'CL2BENZIDINE DIS(2ETHYLHEXYL)PHTH •DI-N-DC TYLPHTHAL ATE BENZO(B)FLUORANTHE 0.7 BENZO(K)FLUORANTHE 0.7 •BENZO(A)PYRENE 0.7 INDENOd. 2. 3CD)PYR 0.5 DIBENZO(A,H)ANTHRA 0.4 BENZO(G,H, DPERYLE 0.5 DIO-PHENANTHRENE (IS-4) 2-FLUOROPHENOL 0.6 (SS-5) N-NITROSODIMETHYLAMINE PYRIDINE T •246TRICHLOROPHNEOL 0. 2 T 2. 4, 5TRICHL0R0PHEN 0. 2 T 4-NITROANILINE BENZD(A)ANTHRACENE 0.8 CHRYSENE 0. 7 No m/z Scan 51 165 52 149 m Time Ref 919 15: 19 99^ 16: 3J 204 1002 16:42 RRT Mpth 3 0. 977 A BB 3 1. 054 A BD 3 1. 065 A BD 54 55 56 i^ Is 166 198 169 248 284 1006 1016 1018 1061 1083 16: 16: 16: 17: 18 46 56 58 41 03 3 77 77 77 77 1. 0. 0. 0. 0. 069 908 910 948 968 A A A A A BD BB DD DD DB Area(Hght) 3959. 16005. 8147. 17307. 2409. 7070. 4275. 4408. Amount 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 • PPB PPB PPB PPD PPC PPB PPD ??Vi 7.T 01 1 1 1 .1 1 1 1 1 19 19 19 19 19 19 19 19 300555 Data ijULjucl io vaiiUcition No 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 B3 84 85 No |51 '52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 k^ ^ 7 ffl/Z 266 17B 178 149 202 77 167 202 149 252 149 149 252 252 252 276 278 276 188 112 74 79 196 196 138 228 228 Scan Time R 1103 18 1122- IB 1127- 18 1183 19 1268 * 21 1022 17 1146 19 1296' 21 1366 22 1439 23 1435 23 1533 25 1640- 27 1646* 27 1720' 28 2073. 34 2075- 34 2175. 36 1119 18 413 6 227 3 226 3 849- 14 855' 14 1014' 16 1447- 24 1453- 24 Ret(L) Ratio 15: 16: 16: 16: 16: 16: 17: 18: 18: 18: 18: 19: 21: 17: 19: 21: 22: 23: 23: 25: 27: 27: 28: 34: 34: 36: 18: 19 1.00 32 1.00 42 1.00 46 1.00 56 1. 00 58 1.00 41 1.00 03 1.00 23 1.00 42 1.00 47 1.00 43 1.00 08 1.00 02 1.00 06 1.00 36 1. 00 46 1.00 59 1.00 55 1.00 33 1.00 20 1.00 26 1.00 40 1. 00 33 1.00 35 1.00 15 1.00 39 1.00 ef :23 77 :42 77 : 47 77 :43 77 : 08 77 :02 77 : 06 77 :36 :46 :59 :55 :33 :20 :26 :40 :33 :35 : 15 4 4 4 4 5 5 5 5 5 5 5 :39 77 :53 :47 :46 :09 : 15 : 54 :07 : 13 RRT(L3 0. 977 1. 054 1. 065 1. 069 0. 90B 0. 910 0. 948 0. 968 0. 936 1. 003 1. 007 1. 057 1. 133 0, 913 1. 024 0. 894 0. 942 0. 992 0. 990 0. 885 0. 946 0. 950 0. 992 1. 196 1. 197 1. 255 1. 000 1 1 1 3 3 3 4 4 RRT 0.986 1.003 1.007 1.057 1. 133 0.913 1. 024 0. 894 0. 942 0. 992 0.990 0. BBS 0. 946 0. 950 0. 992 1. 196 1. 197 1. 255 1. 000 0.723 0. 398 0. 396 0. 902 0. 909 1. 078 0. 998 1. 002 Ratio 00 00 00 00 00 00" 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 . 00 . 00 . 00 . 00 Meth A A A A A A A A A A A A A A A A A A A M M M A A A A A BB BV VB ' BB BB BB BD BB BB - BB BB BB BV VB BB BB BB XX XX BV VB i BB I BV VB >P Amnt 2! 2! 5. 00 5. 00 25. 00 2: 2" 2 2 2 2 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 25. 00 2 2 2 2 5. 00 5. 00 5. 00 5. 00 25. 00 2 2 2 2 5. 00 5. 00 5. 00 5. 00 25. 00 2 2 2 2 2 2 5. 00 5. 00 5. 00 5. 00 * 5. 00 5. 00 20. 00 Area(Hght) Amount 2843. 21367. 23040. 27901. 20138. 28888. 7516. 21192. 10929. 3476. 15379. 24950. 150B9. 15075. 13860. 15278. 12124. 12964. "^15958. 7426. 6336. 9192. 4555. 4814. 1039. 17092. 16340. 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 20. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 PPD PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPD PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB Amnt(L) R.Fac R. Fac(L) 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 20. 00 frjvpjp 7/ifii.t/^r/ 0. 231 0. 935 0. 476 1. Oil 0. 121 0. 354 0. 214 0. 221 0. 143 1. 071 1. 155 1. 399 1. 010 1. 448 0. 377 1. 341 0. 691 0. 220 0. 973 1. 638 0. 990 0. 989 0. 910 1.003 • 0. 796 0. 851 1. 000 0. 231 0. 935 0. 476 1. Oil 0. 121 0. 354 0. 214 0. 221 0. 143 1. 071 1. 155 1. 399 1. 010 1. 448 0. 377 1. 341 0. 691 0. 220 0. 973 1. 638 0. 990 0. 989 0. 910 1. 003 0. 776 0. 851 1. 000 y.Tot 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 0. 95 1. 19 1. 19 ' 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1, 00 1. 00 Da.aS.fe<lI|^tr" No Ret(L) Ratio RRT(L) Ratio Amnt Amnt(L) R.Fac R.Fac(L) Ratio 7B 6:53 1.00 0.723 1.00 25.00 25.00 0.981 0.981 1.00 79 3:47 1.00 0.398 1.00 25.00 25.00 0.837 0.837 1.00 80 3:46 1.00 0.396 1.00 25.00 25.00 1.214 1.214 l.OO 81 14:09 1.00 0.902 1.00 25.00 25.00 0.266 0.266 1.00 ,82 14:15 1.00 0.909 1.00 25.00 25.00 0.281 0.281 1.00 83 16:54 1.00 1.078 1.00 25.00 25.00 0.061 0.061 1.00 84 24:07 1.00 0.998 1.00 25.00 25.00 1. 081 1.081 1.00 85 24:13 1.00 1.002 1.00 25.00 25.00 1.034 1.034 1.00 3 00557 "^^^^^*/-ToVate„„„ Calibration Check Instrument Identifier: C Calibration Date: 2/20/95 Standard Pile: CS022195A Date: 02/21/95 Time: 10:32:00 IN RF: SW(&) « .05 CLP « .01 OR BELOW AX XD: SW(«} 307. CLP = 257. CS50 CS45 CS20 CS25 CS55 CS30 CS70 CS75 C315 C325 C330 C335 C340 C320 C310 C319 C345 C350 C355 C357 ^ 6 5 R370 C375 C410 C415 C420 C425 C430 C435 C440 C44S C450 C455 C460 C465 C470 C510 C515 C520 C525 C530 C53S C540 C54 5 C550 |te21 •ss Compound 2-FLUOROPHENOL D5-PHEN0L D5-NITROBEN2ENE 2-FLUDR DBIPHENYL 0. 0. 0. 0. 2.4.6TRIBROMOPHENOL D14-P-TERPHENYL 2-CHL0R0PHEN0L-D4 1, 2-CL2BENZENE--D4 •PHENOL BIS(2CHL0R0ETHYL)E 2CHL0R0PHEN0L 1,3DICHL0R0BENZENE •1,4DICHL0R0BENZENE ANILINE 0. 0. 0. 0. 0. 0. 0. 0. 6 B 2 7 5 B 4 B 7 8 6 5 N-NITROSODIMETHYLAMINE PYRIDINE BENZYL ALCOHOL 1.2DICHL0R0BENZENE 2METHYLPHEN0L 0. 0. 2. 2'OXYBISdCHLOROPR 4METHYLPHEN0L &NITRDSOPROPYLAMINE HE X AC HLOR OETHANE NITROBENZENE ISOPHORONE •2-NITROPHENOL 2,4-DIMETHYLPHENOL BENZOIC ACID BIS(2CHL0R0ETH0XY) •2.4DICHL0R0PHEN0L 1.2,4TRICHL0R0BENZ NAPHTHALENE 4-CHLORDANILINE •CL6BUTADIENE •4CHL0R03METHYLPHEN 2METHYLNAPHTHALENE &CL6CYCL0PENTADIENE •246TRICHL0R0PHNE0L 2. 4,5TRICHL0R0PHEN 2CHL0R0NAPHTHALENE 2-NITROANILINE DIMETHYL PHTHALATE ACENAPHTHYLENE 3-NITROANILINE •ACENAPHTHENE 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 0 4 7 6 5 3 2 4 1 2 3 2 2 7 2 4 2 2 8 , 3 . 8 2,3.4.6-TETRACHLOROPHE 8<2, 4DINITR0PHEN0L Mc 'an RF(I) 1. 1. 0. 1. 0. 0. 1. 0. 2. 1. 1. 1. 1. 2. 0. 1. 0. 1. 1. 1. 1. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1, 0, 0. 0. 0 253 708 386 042 111 852 301 834 004 915 331 403 434 042 858 239 932 326 358 771 428 058 592 395 784 223 270 157 481 236 246 964 185 132 252 598 179 277 272 937 313 , 935 474 , 084 . BSB . 24 5 , 115 RF(0) 0. 9B1 1. 612 0.355 0. 902 0. 117 0. 784 1. 228 0. 745 1. 906 I. 864 1. 218 1. 296 1. 431 1. 742 0. 837 215 810 295 191 677 293 988 551 385 0. 754 0. 187 0. 246 132 461 239 246 0. 929 0. 240 0. 123 0. 263 0. 601 0. 126 0. 267 b. 282 0. 887 0. 324 0. 944 1. 423 ' 0. 175 0. 814 0. 255 0. 099 1. 0. 1. 1. 1. 1. 0. 0. 0. 0. 0. 0. 0. l y ^ y 7. D l y 21. 5. 7. 13. 5. 7. 5. 10. 4. 2. 8. 7. 0. 14. 2. 1. 13. 2. 12. 5. 9. 6. 6. 2. 3. 16. 8. 16. 4. 0. 0. 3. 29. 6. 4. 0. 29. 3. 3. 5. 3. 0. 3. 108. 5. 4. 13. 663 640 907 442 590 966 560 703 8 7 4 . / 661 453 647 \ 7 \ y 670 352 973 121 298 291 307 457 570 922 598 893 096 y 757 260 142 937 y 118 633 906 826 yp 3 6 3 ^ 631 531 782 y . 712 345 564 956 473 • 607 147 y 426 310 Sta Suziecl - - ~ " ' 300558 To Validation « # C560 J.4N I TROPHENOL C565 DIBENZOFURAN O. 8 C570 2,4DINITROTOLUENE O. 2 C54 3 2, 6DINI TROTOLUENE 0.2 C580 DIETHYL PHTHALATE C5B5 4CHL0R0PHENYL PHEN 0. 4 590 FLUORENE 0. 9 C595 4-NITROANILINE C610 4,6DINITR02METHYLPH C615 *DIPHENYLAMINE C625 4BR0M0PHENYL PHENY 0. 1 C630 CL6BENZENE 0. 1 C635 •PENTACHLOROPHENOL 0. 05 C640 PHENANTHRENE 0. 7 C645 ANTHRACENE O. 7 C650 DI-NBUTYLPHTHALATE C655 •FLUORANTHENE 0. 6 D200 1,2-DIPHENYLHYDRAZINE C647 CARBAZOLE C715 PYRENE 0.6 C720 BUTYLBENZYLPHTHALATE C725 3, 3'CL2BENZIDINE C730 BENZO(A)ANTHRACENE 0.8 C740 BIS(2ETHYLHEXYL)PHTH C735 CHRYSENE 0.7 C760 •DI-N-OCTYLPHTHALATE C765 BENZO(B)FLUORANTHE 0. 7 C770 BENZO(K)FLUORANTHE 0. 7 C775 «BENZO(A)PYRENE 0.7 C780 INDENO (1,2, 3CD)PYR O. 5 785 DIBENZO(A,H)ANTHRA O. 4 790 BENZ0((5, H. DPERYLE 0. 5 0 1 O 0 0 o 134 207 278 221 909 455 0. 952 0. 075 0. 149 0. 410 0. 230 0. 243 0. 172 1. 147 1. 206 1. 493 1. 071 1. 451 0. 386 1. 341 0. 705 0. 261 1. 105 0. 963 1. 072 1. 531 1. 028 1. 037 O. 932 0. 996 0. 838 0. 871 O. 120 *^ 1.233 0.305 0.232 0.936 0. 477 1. 012 0. 061 0. 121 0. 355 0. 215 0. 221 0. 143 1. 072 1. 156 1. 399 1. 010 1. 449 0. 377 1. 341 0. 692 0. 220 1. 082 0. 973 1. 034 1. 638 O. 991 0. 990 0. 910 1. 003 0. 796 0. 851 10. 591 2. 144 9. 7B1 4.736 2. 985 4.847 6. 32B 18. 168 18.611 13. 440'/ 6. 538 8. 669 17. 034 >/ 6. 585 4. 209 6. 296 5. 709 0. 164 2. 339 0. 047 1. 907 15. 469 2. 131 1. 112 3. 529 6. 964 y" 3. 600 4. 540 2.331 y 0. 739 5. 039 2. 292 y 300559 ,„.,c;„Kiect lb Validation J c y ^ •y""''i D? DATA FROM FILE: SU12244MB4 SCANS 391 TO 1171 ACQUIRED: 82/21/95 14:48:88 CALI: SU12244WB4 #1 SAMPLE: SBLKW WATER-12244WB4 CONDS.: 0.25 X 30M RTX-5 l.OUM 45/4-308(312 INST C C tr, ^-o' n ci" t-r o' 3 Ui o o tn a\ o 400 . 6:40 500 J 3:20 600 . 10:00 700 J .1:40 800 _ 13:20 303 . 15:00 16:40 iie'5 . 13:20 .1.::. I X J 100.0?J ( 23488.) CS50 2-FLUuROPHENOL 0.6 (SS-5) -''''cs^^-'mmomm..§P mk-?y CI30 D4-l,4 DICHLOROBENZENE (IS-1) - CS75 1,2-CL2BENZENE-D4 8.4 (SS-8) CS20 D5-NITR0BEN2ENE 8.2 (SS-1) CI40 D3-NAPHTHALENE (IS-2) CS25 2-FLUOROBIPHENYL 0.7 (SS-2) CI50 DIO-ACENAPHTHENE (IS-3) -€555- 2,4..5TRIBR0MGPHEN0L (S5-6) / CI60 DIO-PHENANTHRENE (IS-4). <b* # . K, • DATA FROM FILE: SU12244WB4 SCANS 1171 TO 2408 ACQUIRED: 82/21/95 14:48:00 CALI: SU12244WB4 #1 SAMPLE: SBLKW WATER-12244WB4 CONDS.! 0.25 X 30M RTX-5 1.0UM 45/4-300@12 INST C 1200 . 20:00 1400 _ 23:20 26:40 1800 J 30:00 a cn ZZ' Z) y rjl o'. Ui o o Ol H 2000 _ 33:20 . 2200 - 35:40 i I J r CI70 D12-CHRYSENE CI75 D12-PERYLENE (IS-6) 100.0^ ( 29215.) CS30 D14-P-TERPHENYL 0.5 (SS-3) (IS-5) Quantitation Report File: SV12244WB4 # Data: SV12244WB4. TI 02/21/95 14:48:00 Sample: SBLKW WATER-12244WB4 Conds.: 0.25 X SOM RTX-5 l.OUM 45/4-300812 ormula: Instrument: C Submitted by: Analyst: JAM IST C Weight: Acct. No. : 1.000 12244 AMOUNT-AREA * REF AMNT/(REF AREA * RESP FACT) Resp. fac. from Library Entry No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 No i 1 I2 3 4 5 6 7 8 9 10 11 12 13 14 15 No 1 2 3 4 5 6 7 B h.*? Name CI30 CI40 CI50 CI60 CI70 CI75 CS50 CS45 CS20 CS25 CS55 CB30 CS75 C740 CS70 m/z ! 152 136 164 188 240 264 112 99 82 172 330 244 152 149 132 D4-l,4 DICHLOROBENZENE DB-NAPHTHALENE DIO-ACENAPHTHENE D10-PHENANTHRENE D12-CHRYSENE D12-PERYLENE 2-FLUOROPHENOL D5-PHEN0L DS-NITRDBENZENE 2-FLUORDBIPHENYL 0. 6 0. 8 0. 2 0. 7 2.4,6TRIBROMOPHENOL D14-P-TERPHENYL 1,2-CL2BENZENE-D4 0. 5 0. 4 BIS(2ETHYLHEXYL)PHTH 2-CHL0R0PHEN0L-D4 Scan Time Ref 571^ 9:31 727 12:07 941 15:41 1120 18:40 1449 24:09 1734 28:54 415 6:55 531 8: 51 642 10:42 858 14:18 1037 17: 17 1309 21:49 595' 9:55 1435 23: 55 546 9:06 Ret(L) Ratio RRT(L] 9:31 12:08 15:41 18: 39 24: 10 28: 53 6: 53 8: 53 10:44 1.00 1.000 1.00 1.000 1.00 1.000 1.00 1.000 1.00 1. 000 1.00 1.000 1. 00 0. 723 1. 00 0. 933 1. 00 0. 885 1 2 3 4 5 6 1 1 2 3 3 5 1 5 1 0. 0. 0. 0. 1. 0. 1. 0. 0. > Rat: 0.8 RRT 000 000 000 000 000 000 727 930 883 912 102 903 042 990 956 io 00 00 00 00 00 00 00 . 00 , 00 (IS-1) (IS-2) (IS-3) (IS-4) (IS-5) <IS-6) (SS-5) (SS-4) (SS-1) (SS-2) (SS-6) (SS-3) (SS-8) (SS--7) Meth A BB A BB A BB A BB A BB A BB A BB A BB A BD A BB A BB A BB A BD A BB A BB Amnt 20. 00 20. 00 20. 00 20. 00 20. 00 20. 00 73. 48 ^ 66. 21 44. 65 Area(Hght) 4381. 17319. 9781. 11962. 9028. 8608. 157B9. 23369. 13718. 16858. 3815. 1B426. 4840. 1579. 17736. Amnt(L) 20. 00 20. 00 20. 00 20. 00 20. 00 20. 00 25. 00 25. 00 25. 00 R. 1 2 4 0 Amount 20. 20. 20. 20. 20. 20. 73. 66. 44. 38. 67. 52. 29. 3. 65. -ac 000 000 000 000 000 000 477 212 654 247 076 071 688 595 942 PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB R.Fac(L) 000 . 000 . 000 , 000 . 000 . 000 . 883 . 1 . 267 . 634 1. 000 1. 000 1.000 1. 000 1. 000 1. 000 0. 901 1. 611 0. 355 7.Tot 3. 3. 3. 3. 3. 3. 13. 11. 7. 6. 11. 9. 5. 0. 11. Rat: 1. 1. 1. 1. 1. 1. 2. 2. 1. 57 57 57 57 57 57 10 80 96 82 96 28 29 64 76 LO 00 00 00 00 00 00 94 65 77 300562 D-t? Z No Ret(L) Ratio RRT(L> Ratio Amnt Amnt(L> R.Fac R.Fac(L) Ratio 10 14:18 1.00 0.912 1.00 38.25 25.00 1.379 0.901 1.53 11 17:17 1.00 1.102 1.00 67.08 25.00 0.312 0.116 2.68 12 21:49 1.00 0.903 1.00 52.07 25.00 1.633 0.784 2.08 13 9:55 1.00. 1.042 1.00 29.69 25.00 0.884 0.744 l. 19 14 23:55 1.00 0.990 1.00 3.60 25.00 0.140 0.973 0.14 15 9:10 0.99 0.963 0.99 65.94 25.00 3.239 1.228 2.64 300563 Data Subject To Validation DATA FROM FILE: SUWAAOIP SCANS 384 TO 1164 ACQUIRED: 02.^21/95 15:33:00 CALI: SUWAA01P #1 SAMPLE: MW0004 HATER - HLA CONDS.: 0.25 X SOM RTX-5 l.OUM 45/4-300(512 INST C C t-t- QJ r: w ^ ' . ro n o' < tu O.. C-1 t - r o 3 , ta o o Ul i<^ 400 _ 6:40 500 . 0.-"T) 600 . 10:00 700 . 11:40 ' :-:flH . 13:20 _L I CS50 2-FLUCROPHE.SOL 0.6 (SS-5) 100.0:^ ( 28896.) 900 . 15:00 '1000 '15:40 ;1155 . I 1:5:20 l i i Z c i:s45 D5-PHENi:iL O.S <:ss.-4) :S?0 2-CHLrM'HhN0L-D4 0.8 \Sb^7) CI30 D4-1..4 DICHLOROBENZENE (IS-1) — CS75 1,2-CL2BEHZEHE-D4 0.4 (SS-8) CS20 D5-NITROBENZENE 0.2 (SS-1) CI40 DS-NAPHTHALENE <IS-2) CS25 2-FLUOROBIPHENYL 0.7 (SS-2) CI50 DIO-ACENAPHTHENE (IS-3) /:' CS55 2,4.. 6TRI BROMOPHENOL (SS-6) 0 7^ /. (f'A CI68 DIO-PHENANTHRENE (IS-4) a . t y i DATA FROM FILE: SUHAAOIP SCANS 1164 TO 2400 ACQUIRED: 02/21/95 15:33:00 CALI: SUWAA01P #1 SAMPLE: MW0004 WATER HLA COHDS.: 0.25 X 30M RTX-5 l.OUM 45/4-300512 INST C 1200 J 20:00 1400 . 23:-20 1500 _ 25:40 1800 _ 30:00 2900 v.: '•- ~ < • cZ o to o o Ul a\ cn 1 22'^Z^O _ 35:40 ^C'?y I \ CI70 D12-CHRYSENE 100.0?: ( 24928.) CS30 D14-P-TERPHENYL 0.5 (SS-3) (IS-5) CI75 D12-PtRYLEN£ (IS-6) <;n. Quantitation Report File: SVWAAOIP tf Data: SVWAAOIP. TI 02/21/95 15:33:00 ample: MW0004 WATER HLA onds.: 0.25 X 30M RTX-5 Formula: Submitted by: l.OUM 45/4-300612 Instrument: C Analyst: JAM INST C Weight: Acct. No. : 1. 000 12244 AMOUNT=AREA • REF AMNT/(REF AREA • RESP FACT) Resp. fac. from Library Entry No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Ho h 2 3 4 5 6 7 8 9 10 11 12 13 14 15 No 1 2 3 4 5 6 7 ^ ^ 1^ Name CI30 CI40 CI 50 CI60 CI70 CI75 CS45 CS20 CS25 CSS5 CS30 CS75 C740 CS50 CS70 m/z i 152 136 164 188 240 264 99 82 172 330 244 152 149 112 132 D4-1.4 DICHLOROBENZENE DB-NAPHTHALENE DIO-ACENAPHTHENE DIO-PHENANTHRENE D12-CHRYSENE D12-PERYLENE D5-PHEN0L DS-NITRDBENZENE 2-FLUOROBIPHENYL 0. 8 0. 2 0. 7 2.4,6TRIBROMOPHENOL D14-P-TERPHENYL 1,2-CL2BENZENE-D4 0. 5 0. 4 BIS(2ETHYLHEXYL)PHTH 2-FLUDROPHENOL 2-CHL0R0PHEN0L-D4 Scan Time Ref 564/ 9:24 725 12:05 940 15:40 1119 18:39 1448 24:08 1733 28:53 524 8:44 640 10:40 857 14: 17 1036 17:16 1308 21:48 590/ 9:50 1434 23:54 402 6:42 540 9:00 Ret(L) Ratio R R T ( L ; 9:31 12:08 15:41 18:39 24: 10 28: 53 8: 53 10: 44 14: 13 0.99 1.000 1. 00 1. 000 1.00 1.000 1. 00 1. 000 1.00 1.000 1.00 1.000 0. 98 0. 933 0. 99 0. 885 1. 00 0. 912 1 2 3 4 5 6 1 2 3 3 5 1 5 1 1 1. 1. 1. 1. 1. 1. 0. 0. 0. 1. 0. 1. 0. 0. 0. > Rat: 0. 6 0. 8 RRT 000 000 000 000 000 000 929 883 912 102 903 046 990 713 957 Lo 00 00 00 00 00 00 00 00 , 00 (IS-1) (IS-2) (IB-3) (IS-4) (IS-5) (IS-6) (SS-4) (SS-1) (SS-2) (SS-6) (SS-3) (SS-B) (SS-5) (SS-7) Meth A DD A BB A BB A BB A BB A DD A DB A BB A BB A BD A DB A BB A BD M XX A BB Amnt 20. 00 20. 00 20. 00 20. 00 20. 00 20. 00 44. 03 " 41. 30 41. 92 Area(Hght 4060. 15716. 8783. 10989. 9694. 10644. 14400. 11513. 16591. 1499. 15680. 5236. 1926. 8942. 11311. Amnt(L) 20. 00 20. 00 20. 00 20. 00 20. 00 20. 00 25. 00 25. 00 25. 00 ) Amount 20. 20. 20. 20. 20. 20. 44. 41. 41. 29. 41. 34. 4. 44. 45. R. Fac 2 0 1 000 000 000 000 000 000 027 298 918 351 266 656 084 903 379 PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB R.Fac(L) 000 000 000 , 000 , 000 . 000 . 837 . 586 . 511 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 1. 611 0. 355 0. 901 300566 DalaSubjectTo 7.Tot 4. 4. 4. 4. 4. 4. 9. 9. 9. 6. 9. 7. 0. 10. 10. Rat: 48 48 48 48 48 48 85 24 38 57 23 76 91 05 15 1 0 00 00 00 00 , 00 00 76 . 65 . 60 Validation No Ret(L) Ratio RRT(L) Ratio Amnt Amnt(L) R.Fac R. Fac(L) Ratio 10 11 12 13 14 17: 21: 9: 23: 6: 17 49 55 55 53 1. 1. 0. 1. 0. 00 00 99 00 97 1. 0. 1. 0. 0. 102 903 042 990 723 1. 1. 1. 1. 0. 00 00 00 00 99 29. 41. 34. 4. 44. 35 27" 66 08 90 25. 00 25.00 25. 00 25. 00 25. 00 0. 1. 1. 0. 1. 137 294 032 159 762 0. 116 0.784 0.744 0. 973 0.981 1. 1. 1. 0. 1. 17 65 39 16 80 15 9:10 0.98 0.963 0.99 45.38 25.00 2.229 1. 228 1.82 300567 Data Subject To Validation TARGET COMPOUND COMPARISON COMPOUND: C740 BIS(2ETHYLHEXYL)PHTH RAW DATA: SUWAA01P 1*1434 02/21/95 15:33 SAMPLE: MW0004 WATER HLA CONDS.; 0.25 X 30M RTX-5 l.OUM 45/4-300812 BASE M/2: INST C 149 RICr 3700. 9S.6n 49.; lU-4^ -r-^~l 1 1 1 •• • I'. r ' ' " r ' ' — I " ' I • ' — I " • I 1 — " - n — ' — I — ' — r — ' — I •' 1 • ' I — ' — I • I ' I — * — I — ' — I • I I ' i ' I 986. 77.1- 38.5- ENHANCED DATA: SUWAAOIP #1434 i • 1 ' t ' ,. 1 [ ll 1 ) • • ' • 1 • I ' l ' 1 ' • 1 ' 1 • 1 • BASE M/H: ..,, 1 1 , L , . 1 1 • T - 149 I ' l ' RIC: I ' l ' ' 2700. 1 • 1 • . 1 ' 1 ' 771. LIBRARY FILE: SN ^56 BASE M/Z: 149 RIC: 1585. 100.0-1 50.0- r 1000. a jM/z '^' ! 100.0- ?^ t J ; ZZ 75'i -|—I—I—,—I—I—I—I—i—I—I—I—j—I 1—I—I—I—I—I—1—I ' I ' 1—I—r"T—I—I—I—I—I—I—1—I—I—I—I—I—r 50 100 150 200 — I ' l ' — I • ' I ••• 250 50.0- tn '-* <Ti o Ki.K/ . a) -•3 -50.0- -100.0- lil • III • ll I. ll . » > . ii • w* 100.0-1 50.0 H/2 100.0 ZZ a -\ - \Ci y Ocr. mo 50.0 MASS SPECTRUM 03/03/95 11:10:00+7:43 SAMPLE: DFTPP 290-14-PERF CONDS.: 0.25 X 30M RTX-5 l.OUM 45/4-300S12 #462 TO #464 AUERAGED - »f458 Xl.OO DATA: CP030395A ^453 CALI: CP050355A #1 BASE M/2: 19S RIC: 14S96. INST C 158 ?7 ee 51 3S -T--r 57 X 127 110 iili '86 S. •i I iM- . 117 REVIEWED .MAR 0 3 1995 186 I i' i35 '•' 148 .. 161.'. ..178 .;, ,. ' • I . •' I ' .i I I . I i i ' I " I • •' 1 — • — r r-1^ 2i£.6 .:!' O'/c SlL 50 100 150 200 442 255 275 265 T—'—r 2S6 323 334 365 -f-'i—r M/Z 250 300 350 ^23 „,, -f-L,—I—I—r^ I 400 450 •U ' RIC 05/03/S5 11:10:00 SAMPLE: DFTPP 290-14-PERF CONDS.: 0.25 X 30M RTX-5 •RANGE: G 1, 667 cABEL: N 100.0- a RIC !D r-i- ft) tr> r; cr iZ- 5' ,.. !:' L'- t J o o in -J o 435 I 1 405 413 424 l.OUM 0, 4.'0 DATA: CP03e355h ^462 CALI: CP0303S5A #1 45/4-3S0(£l2 INST C uuAiS: A 0, i.0 J 0 453 SCANS 400 TO 550 I j r i ^ L . . U —Kit -J { L '400 6:40 420 7:00 I 440 7:20 460 7:40 481 430 8:00 492 505 514 520 528 53& C-.-.C; •j-tZ) I 500 3:20 520 8:40 540 3:00 SCAN TIHE . t l » 100.On RIC+MASS CHROMATOGRAM DATA: C.^030.335A S452 03/03/95 11:10:06 CALI: CP0363S5A #1 SAMPLE: DFTPP 290-14-PERF CONDS.: 0.25 X SOM RTX-5 l.OUM 45/4-300212 INST C RANGE: G 1, 667 LABEL: N 0, 4i0 QuA.N: A O, 1.0 J 5 555 SCANS 540 BASE: U 20, IU t4«3 184 50.9n t-> a', c RIC \. Ui o f . o Ul c- -JO 1 u - t . C<%/0 I 0.500 11840. =:"?7 Ol I 535 551 :<99 614 521 627 631 • — < . . • • • • I Pi.i—111—I , ^ p — • • ' , 1 1 — 9:40 600 10:00 620 10:20 640 SCAN 10:40 TIME Mass List 03/03/95 11:10:00 + 7:43 Sample: DFTPP 290-14-PERF Conds.: 0.25 X 30M RTX-5 l.OUM «462 to «464 averaged - #458 Xl.OO Data: CP030395A « 463 Base m/z: 198 Call:- CP030395A « 1 RIC: 14896. 45/4-300ei2 INST C 39 444 Mass 39? 49? 50? 51? 52? 56? 57? 63? 65? 69 74 75 76 77 78 79 80 81 82 83 86 9J 92 93 98 99 101 104 105 107 108 110 111 117 122 123 127 128 129 130 135 137 141 142 .147 f 148 155 156 161 165 S S s s 5 s s s s S S 5 S s s s s s s s s s s s s s s s s s s 5 s 5 5 s 5 S s s s s s s s s s 5 s s 0.00 7. RA 2, 35 0. 18 7.00' 34. 12 1. 61 0. 60 2. 21 1. 06 0. 41 42. 77 2. 44 5. 39 1. 80 49. 26 2. 72 1. 66 1. 34 2. 26 0. 37 0. 41 0. 69 0. 32 0. 41 2. 67 2. 12 1. 70 1. 01 - 0. 32 0. 32 11. 46 1. 34 27. 58 3. 27 4. 83 0. 28 0. 60 46. 82 2. 72 17. 27 1. 01 0. 74 0. 23 1. 15 0. 28 0. 69 1. 20 0. 51 0. 55 0. 55 0. 37 0. Inten. 51. 4. 152. 741. 35. 13. 48. 23. 9. 929. 53. 117. 39. 1070. 59. 36. 29. 49. 8. 9. 15. 7. 9. SB. 46. 37. 22. 7. 7. 249. 29. 599. 71. 105. 6. 13. 1017. 59. 375. 22. 16. 5. 25. 6. 15. 26. 11. 12. 12. 8. Minima Maxima Mass 167 168 174 175 177 179 180 IBl 185 186 187 189 192 193 196 198 199 204 205 206 207 211 217 221 223 224 225 227 229 244 24 5 246 255 256 258 265 273 274 275 276 277 296 323 334 365 423 441 442 443 444 Min « S S s s s s s s s s s s s s s s s s s s s s s 8 5 s s s s s s s s s s s s 5 s s s s s s s s s s s s Inten: 0 7. RA 3. 55 0. 74 0. 46 0. 74 0. 37 1. 75 1. 15 0. 37 0. 64 11. 10 3. 08 0. 28 0. 28 0. 41 J. 84 100. 00 5. 62 1. 75 3. 78 19. 94 2. 53 0. 51 4. 14 5. 43 0. 60 10. 04 1. 75 3. 13 0. 51 7. 37 0. 55 0. 97 39. 41 5. 57 1. 24 0. 23 0. 69 3. 45 22. 15 2. 81 1. 06 3. 87 i . 29 0. 51 1. 61 3. 45 9. 53 83. 24 14. 78 0. 83 0. Inten. 77. 16. 10. 16. B. 38. 25. 8. 14. 241. 67. 6. 6. 9. 40. 2172. 122. 38. 82. 433. 55. 11. 90. 118. 13. 218. 38. 68. 11. 160. 12. 21. 856. 121. 27. 5. 15. 75. 481. 61. 23. 04. 20. 11. 35. 75. 207. 180S. 321. 18. Dat, 300572 Subject To Vaiiaaiior CC/MS Tuning and Mass Calibration DECAFLUOROTRIPHENYLPHDSPHINE Case Number: Inst ID: Lab ID: CP030395A Laboratory:^ GULF Sens Date: 03/03/95 Cali Date: 10/02/91 Data release authorized by: M/E Ion Abundance Criteria Contract: Sens Time; Analyst: Spec « 462 11: 10:00 SRA 51 68 69 70 127 197 198 199 275 365 44 3 442 443 1 2 30 le ma le 40 le ba 5 10 gr le gr 17 valu val u to 607. SS than ss 69 r SS than TO 607. SS than se peak TO 97. 0 TO 307. eater t SS than eater t TO 237. e in pa e in pa of mass 198 34. 271 of mass 69 0. elative abundance 42. 27. of mass 69 0. of mass 198 46. 17m of mass 198 0. , 100% relative abundance 100. f mass 198 5. of mass 198 22. han 17. of mass 198 , 1. mass 443 9. han 407. of mass 198 83. of mass 442 14. renthesis renthesis IS is 7. 7. of of I mass mass 12 00 77 00 82 00 00 62 15 61 53 24 78 y ( 0.00) 1 ( 0. 00) 1 / (17. 75) 2 69 442 300573 Daia ';: ii < ^ , ^ - * DATA FROM FILE: CSO30395A SCANS 330 TO 1160 ACQUIRED: 03/03./35 11:30:00 CALI: CSO30395A #1 SAMPLE: SSTD050 29012-SU25A CONDS.: 0.25 X 30M RTX-5 l.^UM 45/4-300212 INST C 6:40 500 _ 3:20 ^ 1 100.0:; ( 54015.) r CS50 2-FLUOROPHENOL 600 _ 10:03 , 700 _ 11:40 SOO _ 13:20 1 i t'otj _ 15:40 o Sj 1100 J •^1 18:20 '! - f i t 0.6 (SS-5) • £$.45 DS-PHB-IQ 0., 3.(55-4) -€•130 04-1,4 DICHL0R0BEN2ENE (IS-1) •6575 1,2-CL2BEN2ENE-D4 0.4 (SS-8) -€520 05-NITROBENZENE 0.2 (SS-1) CMO DS-Mri.PHTHALEHE (IS-2) t M 5 ^ 2 s CS25 2-FLUOROBIPHENYL 0.7 (SS-2) CI50 DlO-ftCENAPHTHENE (IS-3) CS55 2,4,6TRIBR0M0PhEN0L (SS-6) KS^mxmc -€460 DIO-PHENANTHRENE (IS-4) j» •<t'» DATA FROM FILE: CS03w33S5A SCANS 1150 TO 23S0 ACQUIRED: 03/03/95 11:30:00 CALI: CSO30395A #1 SAMPLE: SSTD050 29012-SU25A CONDS.: 0.25 X BOM RTX-5 l.OUM 45/4-300012 INST C to o o Ol -J tn 1200 . 20:00 1400 23:20 -L 26:40 ISi^O . 30:00 2yy>:; . 33:20 36:40 m r 1 J -• 100.0^ ( 41792.) Tb30 D14-P-TERPHENYL 0.5 (SS-3) VSS3£iiEaiBSaS3SE£E5S TT73—UrZ=CRRYSENE (IS-5) CI75 D12-PERYLENE (is-e) Quantitation Report File: CS030395A m Data: CS030395A. TI 03/03/95 11:30:00 ample: SSTDOSO 29012-SVJ onds.: 0. 25 X 30M RTX-5 Formula: Submitted by: :5A l.OUM 45/4-300ei2 Instrument: C Analyst: SRA INST C Weight: 1.000 Acct. No. : AMQUNT=AREA * REF AMNT/(REF AREA » RESP FACT) Resp. fac. from Library Entry M No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 k^^ lis 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 ^ 2 h AA 45 46 47 Name C130 CI40 CI50 CI60 CI70 CI75 CS45 CS20 CS25 CSSS CS30 CS70 CS75 C315 C325 C330 C335 C340 C320 C345 C350 C3S5 C357 C365 C370 C375 C410 C415 C420 C425 C430 C435 C440 C445 C450 C455 C460 C465 C470 CSIO C515 C520 C525 C530 C535 C540 C545 0. 8 0. 2 0. 7 0. 0. D4-l,4 DICHLOROBENZENE DS-NAPHTHALENE DIO-ACENAPHTHENE D1O-PHENANTHRENE D12-CHRYSENE D12-PERYLENE D5-PHEN0L DS-NITRDBENZENE 2-FLUOROBIPHENYL 2,4,6TRIBRDM0PHEN0L D14-P-TERPHENYL 0. 5 2-CHL0R0PHENQL-D4 0. 8 1,2-CL2BENZENE-b4 0. 4 •PHENOL 0, 8 BIS(2CHLDR0ETHYL)E 0.7 2CHL0R0PHENDL 0. 8 1, 3DICHL0R0BENZENE 0.6 «1,4DICHLDR0BENZENE 0.5 ANILINE BENZYL ALCOHOL 1,2DICHL0R0BENZENE 2METHYLPHEN0L 2, 2'OXYBISdCHLOROPR 4METHYLPHENOL &NITROSOPROPYLAMINE HEXACHLOROETHANE NITROBENZENE ISOPHORONE •2-NITROPHENOL 2. 4-DinETHYLPHENOL 0.2 BENZOIC ACID BIS(2CHL0R0ETH0XY) «2.4DICHL0R0PHEN0L 1,2, 4TRICHL0R0BENZ NAPHTHALENE 4-CHLOROANILINE •CL6BUTADIENE •4CHL0RD3METHYLPHEN 0. 2 2METHYLNAPHTHALENE 0.4 &CL6CYCL0PENTADIENE •246TRICHLOROPHNEOL 2,A,5TRICHLDR0PHEN 2CHL0R0NAPHTHALENE 0. 8 2-NITROANILINE DIMETHYL PHTHALATE ACENAPHTHYLENE 3-NlTROANILINE 0. 6 0. 5 0. 3 0. 2 0. 4 0. 1 0. 3 0. 2 0. 2 0. 7 0. 0. 1. 3 (IS-1) (IS-2) (IS-3) (IS-4) (IS-5) (IS-6) (SS-4) (SS-1) (SS-2) (SS-6) (SS-3) (SS-7) (SS-8) 300576 Data Subjea To Validation .m No 48 49 50 No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 ^ 3 hA 25 26 27 28 29 30 31 32 33 34 35 36 37 38 29 40 41 42 43 44 45 46 47 1^8 %9 50 Name C550 C321 C555 m/z 152 136 164 188 240 264 99 82 172 330 244 132 152 94 93 128 146 146 93 108 146 108 45 108 70 117 77 82 139 107 122 93 162 180 128 127 225 107 142 237 196 196 162 65 163 152 138 153 232 184 •ACENAPHTHENE 2,3. 0.6 -- 4, 6-TETRACHLOROPHENOL &2,4D1NITR0PHEN0L Scan 560 715 926 1102 1425 1690 521 631 843 1021 1291 538 58? 522 531 540 556 563 526 580 584 593 597 610 612 ' 622 632 659 670 672 - 684 684 698 708 717 726 735 780 79S 824 835 840 857 873 894 908 922 930 968 934 Time 9:20 11:55 15:26 18:22 23:45 28: 10 8:41 10:31 14:03 17:01 21:31 8: 58 9:42 8:42 8: 51 9:00 9: 16 9:23 8: 46 9:40 9:44 9: 53 9: 57 10: 10 10: 12 10:22 10:32 10: 59 11: 10 11: 12 11: 24 11:24 11: 38 11:48 11: 57 12:06 12: 15 13: 00 13: IB 13:44 13:55 14: 00 14: 17 14:33 14; 54 15:08 15:22 15: 30 16: 08 15: 34 Ref 1 2 3 4 5 6 1 2 3 3 5 2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3 3 3 3 RRT 1.000 1. 000 1.000 1. 000 1.000 1.000 0. 930 0. 883 0.910 1. 103 0. 906 0. 961 1. 039 0. 932 0. 948 0. 964 0. 993 1. 005 0. 939 1. 036 1.043 1. 059 1. 066 1. 089 1. 093 1. Ill 0. 884 0. 922 0. 937 0. 940 0. 957 0. 957 0. 976 0. 990 1. 003 1. 015 1. 028 1. 091 1. 116 0. 890 0. 902 0. 907 0. 925 0. 943 0. 965 0. 981 0. 996 1. 004 1. 045 1. 009 Meth A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A BB BB BB BB BB BB BB BB BB BB BB BB BB BB VB BV BV VB BV BB BB VB BB BB BV^ BB BB BV BB DB VB BB BB BB BV BB BB BB DV BB BV VB BB BB BB BB BB BB BB BB Area(Hght) 103B3. 40931. 20164. 23641. 18268. 20252. 19665. 15917. 26717. 3352. 16502. 16750. 9639. 21544. 20414. 15061. 16772. 17740. 22950. - 7432. 16072. 14120. 17676. 12806. 10792. 6924. 16711. 33321. B690. 10196. 2534. 21710. 103B4. 12298. 46920. 10612. 6323. 11130. 30042. 5073. 6714. 7173. 25405. 7433. 24584. 38999. 3862. 21391. 6512. 1687. Amount 20. 000 20. 000 20. 000 20. 000 20. 000 20. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 PPB PPB PPB PPB PPB PPD PPB PPB PPB PPB PPB PPB PPB PPB PPD PPD PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPD PPB PPB PPB PPB PPB PPB PPD PPD PPD PPD PPD PPD PPD PPD PPD PPD PPD PPD ppn PPD PPD PPD PPB ^^?c5^r?4- 7.Tot 0.95 0.95 0. 95 0.95 0. 95 0. 95 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1.^9 300577 DataSL'bJ^'rfrbVafidatfo?^ m No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 k2S '27 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 4B 49 50 Ret(L) 9: 11: 15: 18: 23: 28: 8: 10: 14: 17: 21: 8: 9: B: 8: 9: 9: 9: 8: 9: 9: 9: 9: 10: 10: 10: 10: 10: 11: 11: 11: 11: 11: 11: 11: 12: 12: 13: 13: 13: 13: 14: 14: 14: 14: 15: 15: 15: 16: 15: 20 55 26 22 45 10 41 31 03 01 31 58 42 42 51 00 16 23 46 40 44 53 57 10 12 22 32 59 10 12 24 24 38 48 57 06 ' 15 00 IB 44 55 00 17 33 54 08 22 30 08 34 Ratio 00 00 00 00 00 00 00 00 00 00' 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 , 00 , 00 RRT(L) 1.000 1.000 1.000 1.000 1. 000 1.000 0. 930 0. BB3 0.910 1. 103 0.906 0. 961 1. 039 0. 932 0. 948 0. 964 0. 993 1. 005 0. 939 1. 036 1. 043 1. 059 1. 066 1. 089 1. 093 1. Ill 0. 834 0. 922 0. 937 0. 940 0. 957 0. 957 0. 976 0. 990 1. 003 1. 015 1. 028 1. 091 1. 116 0. 890 0. 902 0. 907 0. 925 0. 943 0. 965 0. 981 0. 996 1. 004 1. 045 1. 009 Ratio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 Amnt 20. 00 20. 00 20. 00 20.,00 20. 00 20.00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 Amnt(L) 20. 00 20. 00 20.00 20. 00 20. 00 20. 00 25.00 25. 00 25.00 25.00 25. 00 25. 00 25. 00 25.00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 R.Fac R. 1. 000 1.000 1.000 1. 000 1.000 1.000 1. 515 0. 311 1.060 0. 133 0. 723 1. 291 0. 743 1. 660 1. 573 1. 160 1. 292 - 1. 367 1. 768 0. 573 1. 238 1. OBS 1. 362 0. 937 0. 832 0. 533 0.327 0. 661 0. 170 0. 199 0. 051 0. 424 0. 203 0. 240 0. 917 0. 207 0. 124 0. 216 0. 5B7 0. 201 0. 266 0. 285 1. 008 0. 295 0. 975 1. 547 0. 153 0. 849 0. 25B 0. 067 Fac<L) 1. 000 1. 000 1. 000 1. 000 1.000 1.000 1. 515 0. 311 1. 060 0. 133 0. 723 1. 291 0. 743 1.660 1. 573 1. 160 1. 292 1. 367 1. 768 0. 573 1. 238 1. 038 1.362 0. 987 0. 832 0. 533 0. 327 0. 661 0. 170 0. 197 0. 051 0. 424 0. 203 0. 240 0. 917 0. 207 0. 124 0. 213 0. 537 0. 201 0. 266 0. 2B5 1. 008 0. 295 0. 975 1. 547 0. 153 0. 849 0. 253 0. 067 RatJ LO 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 . 00 , 00 00 . 00 . 00 . 00 . 00 Qy^ / ^ ' ./K- 300578 Data bu^j---"' Quantitation Report File: CS03q395A Data: CS030395A. TI 03/03/95 11:30:00 ample: SSTDOSO 29012-SV25A Conds.: 0.25 X SOM RTX-5 l.OUM ,45/4-300612 Formula: Instrument: C Submitted by: Analyst: SRA INST C Weight: Acct. No. 1. 000 AMOUNT«AREA • REF AMNT/(REF AREA • RESP FACT) Resp. fac. from Library Entry - " ^ K ^ f No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 |67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 No 51 52 53 54 1^ i6 57 58 Name C560 C565 C570 C543 CSBO CSSS C590 C595 C610 C615 C62S C630 C635 C640 C645 C650 C655 D200 C647 C715 C720 C725 C730 C740 C735 C760 C765 C770 C775 C780 C7B5 C790 C310 C319 CS50 m/z 109 168 165 165 149 204 166 138 S<4NITR0PHEN0L DIBENZOFURAN 0. 8 2. 4DINITR0TDLUENE 0. 2 2,6DINITR0T0LUENE 0. 2 DIETHYL PHTHALATE 4CHL0R0PHENYL PHEN 0. 4 FLUORENE 0. 9 4-NITROANILINE 4,6DINITR02METHYLPH •DIPHENYLAMINE 4BR0M0PHENYL PHENY 0. 1 CL6BENZENE 0. 1 •PENTACHLOROPHENOL 0. 05 PHENANTHRENE 0. 7 ANTI-IRACENE 0. 7 DI-NBUTYLPHTHALATE •FLUORANTHENE 0. 6 1, 2-DIPHENYLHYDRAZINE CARBAZOLE PYRENE 0. 6 BUTYLBENZYLPHTHALATE 3,3'CL2BENZIDINE BENZO(A)ANTHRACENE 0.8 BIS(2ETHYLHEXYL)PHTH ' CHRYSENE 0. 7 •DI-N-DCTYLPHTHALATE BENZO(B)FLUORANTHE 0.7 BENZO(K)FLUORANTHE 0.7 •BENZO(A)PYRENE 0.7 INDEND(1,2, 3CD)PYR 0.5 DIBENZ0(A, H)ANTHRA 0.4 BENZ0(G, H, DPERYLE 0. 5 N-NITRDSODIMETHYLAMINE PYRIDINE 2-FLUDROPHENOL 0. 6 Scan Time Ref RRT 941 15:41 3 1.016 948 15:48 3 1.024 950 15:50 3 1.026 904 15:04 3 0.976 976 16:16 3 1.054 987 16:27 3 1.066 990 16: 30 3 1. 069 998 16:38 3 1.078 T T T T (SS-5) Meth A A A A A A A A BB DB BB BB BV BB BKf VB Area(Hght) 2305. 3086?. 7440. 5691. 23900. 11701. 24431. 2849. Amount 25. 000 25. 000 25. 000 25. odo 25. 000 25. 000 25. 000 25. 000 Data Subjc - 3 n n i : - , ^ • ^ \d PPB PPB PPB PPB PPB PPD PPD PPD :ct To ' ^ . J / ^ 7.1 ot 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 Validaliof^i No 59 60 61 62 63 64 65 66 67 6B 69 70 71 72 73 74 75 76 77 78 79 80 Bl 82 83 84 85 klo 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 |4 h 76 77 m/z 198 169 248 284 266 178 178 149 202 77 167 202 149 252 228 149 228 149 252 252 252 276 27B 276 74 79 112 Scan 1000 1002 1045 1065 1086 1105 llll 1167 1250 1006 1130 1277 1348 1417 1422 1415 1428 1505 1605 1609 1678 1998 2000 2095 221 221 411 Time Ref 16:40 16:42 17:25 17:45 18:06 18: 25 18:31 19:27 20:50 16:46 18: 50 21: 17 22:28 23: 37 23:42 23: 35 23:48 25:05 26:45 26:49 27: 58 33: 18 33:20 34: 55 3:41 3:41 6: 51 Ret(L) Ratio RRT(L] 15: 41 15:48 15: SO 15:04 16: 16 16:27 16:30 16: 38 16:40 16:42 17:25 17:45 18:06 18:25 18:31 19:27 20: 50 16:46 IB: 50 21: 17 22:28 23: 37 23: 42 23: 35 23: 48 25:05 26: 45 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 - 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 016 1. 024 1. 026 0. 976 1. 054 1. 066 1. 069 1. 078 0. 907 0. 909 0. 948 0. 966 0. 985 1. 003 1. OOS 1. 059 1. 134 0. 913 1. 025 0. 896 0. 946 0. 994 0. 998 0. 993 1. 002 0. 891 0. 950 4 4 4 4 4 4 4 4 4 4 4 5 5 5 5 5 5 6 6 6 6 6 6 6 1 1 1 RRT 0.907 0. 909 0.948 0. 966 0.985 1.003 1. OOB 1.059 1. 134 0. 913 1.025 0. 896 0. 946 0. 994 0. 998 0. 993 1. 002 0. 891 0. 950 0. 952 0. 993 1. 182 1. 183 1. 240 0. 395 0. 395 0. 734 Ratio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 tie A A A A A A A A A A A A A A A A A A A A A A A A M M M th BB BB BB BB ETB BV VB BB BV BB BB BV BD BB BV BD VB BB BV VB BB BB BB BB XX XX XX Amnt 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . oo . 00 Areal Hght) 3177. 14511. 5959. 6533. 3909. 30670. 32205. 35180. 27208. 37753. 22407. 28627. 14392. 4740. 24409. 21444. 23550. 37093. 28226. 22186. 23045. 24971. 20161. , 21913. 6153. 12015. 11440. Amnt(L) 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 Amount 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 • 4 PPB PPB PPB PPB PPB PPB PPB PPB PPD PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPB PPD PPD PPD R. Fac R. Fac(L) Ra1 0. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0 0 0. 1. 1. 1 0. 1. 0. 1. 0 0 1 0 1 1. 1 071 224 295 226 948 464 969 113 108 . 491 202 221 132 038 090 190 921 278 758 254 630 208 069 939 031 465 115 D. 071 J 1.224 ] 0. 275 1 0.226 0. 948 0. 464 0. 969 0. 113 0. 103 0. 491 0. 202 0. 221 0. 132 1. 038 1. 070 1. 190 0.921 1.278 0. 753 1.254 0. 630 0. 208 1. 069 0. 939 1. 031 1. 465 1. 115 aot I. 19 I. 19 I. 19 I. 19 I. 19 I. 19 I. 19 I. 19 I. 19 I. 19 I. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 I. 19 1. 19 I. 19 1. 19 1. 19 I. 19 I. 19 I. 19 I. 19 I. 19 tio t. 00 I. 00 L. 00 I. 00 I. 00 I. 00 I. 00 I. 00 I. 00 I. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 utiiy>ubi^y PQ^rM!^^9^ML 300580 p'i / No Ret(L> Ratio RRT(L> Ratio ' Amnt Amnt(L) R.Fac R. Fac(L) Ratio 78 26:49 1.00 0.952 1.00 25.00 25.00 0.876 0.876 l.OO 79 27:58 1.00 0.993 1.00 25.00 25.00 0.910 0.910 l.OO 80 33:18 1.00 1.182 1.00 25.00 25.00 0.986 0.986 1.00 81 33:20 1.00 1.183 1.00 25.00 25.00 0.796 0.796 1.00 82 34:55 1.00 1.240 1.00 25.^00 25.00 0.866 0.866 1.00 83 3:41 1.00 0.395 1.00 25.00 25.00 0.474 0.474 1.00 64 3:41 1.00 0.395 1.00 25.00 25.00 0.926 0.926 1.00 85 6:51 1.00 0.734 1.00 25.00 25.00 0. BSl 0.881 1.00 c^"-^ . y 300581 Data Subject To Validation, Calibration Check m Instrument Identifier: C Calibration Date: 02/08/95 tandaril File: CS030395A ate: 03/03/95 Time: 11:30:00 MIN RF: SW(&> = .05 CLP « .01 OR'BELOW MAX XD: SW(^) = 307. CLP = 257. Mean Compound RF(I) RF(D) 7. D CS50 CS45 CS20 CS25 CS55 CS30 CS70 CS7S C315 C325 C330 C335 C340 C320 C310 C319 C345 C350 C3S5 P3S7 C365 C370 C375 C410 C415 C420 C425 C430 C435 C440 C445 C450 C455 C460 C465 CA70 CSIO C515 C520 CS25 C530 C535 C540 |if4S Pso C321 0555 2-FLUOROPHENDL D5-PHEN0L ' DS-NITRDBENZENE 2-FLUORDBIPHENYL 0. 0. 0. 0. 2,4.6TRIBRDM0PHENDL D14-P-TERPHENYL 2-CHLDRaPHENDL-D4 1,2-CL2BENZENE-D4 •PHENOL BIS(2CHLDRDETHYL)E 2CHLDRDPHEN0L 1,3DICHLDRDBENZENE •1,4DICHLDRDBENZENE ANILINE 0. 0. 0. 0. 0. 0. 0. 0. 6 8 2 7 5 B 4 8 7 B 6 5 N-NITRDSDDIMETHYLAMINE PYRIDINE BENZYL ALCOHOL 1,2DICHLDR0BENZENE 2METHYLPHEN0L 0. 0. 2, 2'DXYBIS(ICHLOROPR 4METHYLPHENDL ?<NITROSDPROPYLAMINE HEXACHLDRDETHANE NITROBENZENE ISOPHORONE •2-NITROPHENOL 2, 4-DIMETHYLPHENDL BENZOIC ACID BIS(2CHLDRDETHDXY) •2,4DICHLOROPHENOL 1. 2,4TRICHLOROBENZ NAPHTHALENE 4-CHLDRDANILINE •CL6BUTADIENE •4CHL0R03METHYLPHEN 2METHYLNAPHTHALENE &CL6CYCLDPENTADIENE •246TRICHL0RDPHNEDL 2,4, 5TRICHLDRDPHEN 2CHL0RDNAPHTHALENE 2-NITRDANILINE DIMETHYL PHTHALATE ACENAPHTHYLENE 3-NITRDANILINE •ACENAPHTHENE 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 0. 4 7 6 5 3 2 4 1 2 3 2 2 7 2 4 2 2 8 3 8 2,3, A, 6-TETRACHLDRDPHE 8<2, 4D1 NITROPHENOL 1. 1. 0. 1. 0. 0. 1. 0. 2. 1. 1. 1. 1. 2. 0. 1. 0. 1. 1. 1. 1. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 0. 0. 0. 0. 253 708 386 042 111 852 301 834 004 915 331 403 434 042 BSB 239 932 326 358 771 428 058 592 395 784 223 270 157 481 236 246 964 IBS 132 252 598 179 277 272 937 313 935 474 084 BSB 245 115 0. BB2 1. 516 0. 312 1. 060 0. 133 0.723 1. 291 0. 743 1. 660 1. 573 1. 161 1. 293 1. 367 1. 769 0. 475 926 573 239 088 362 0. 987 0. 832 0. 534 327 662 170 200 0. 051 0. 425 0. 203 0. 241 0. 918 0. 208 0. 124 0. 218 0. 588 0. 202 0. 267 0. 285 1. 008 0. 295 0. 976 1. 548 0. 154 0. 849 0. 259 0. 067 O. 0. 1. 1. 1. 29. 608 J| 11. 263 19. 228 1. 792 20. 680 15. 155 0. 740 10. 892 17. 141 - 17. 855 12. 775 7. 869 4. 643-* 13. 365 44. 665 25. 256 38. 538 6. 570 19. 835 23. 082 30. 856 i^ 21. 327 9. 746 17. 152 15. 658 23. 477 •- 26. 018 J^ 67. 602 11. 629 923 — 176 799 370 6. 045.^ 13. 5 9 1 ^ 1. 648 12. 870 3. 718 " 4. 908 7. 615 5. 603 4. 405 4. 990 83. 300 1. 019"^ 5. 833 41. 112 13. 2. 4. 12. 300582 Data Subject To Validation m C560 &4N I TROPHENOL 0._134 C565 DIBENZOFURAN 0.8 1.207 C570 2,4DINITR0T0LUENE 0.2 0.278 C543 2, 6DINI TROTOLUENE 0. 2 0. 221 580 DIETHYL PHTHALATE 0. 909 585 4CHL0R0PHENYL PHEN 0. 4 0. 455 C590 FLUORENE 0. 9 0. 952 C595 4-NITROANILINE 0. 075 C610 4,6DINITR02METHYLPH 0.149 C615 •DIPHENYLAMINE 0.410 C625 4BR0M0PHENYL PHENY 0. 1 0. 230 C630 CL6BENZENE 0. 1 0. 243 C635 •PENTACHLOROPHENOL 0. 05 0. 172 C640 PHENANTHRENE 0.7 1.147 C645 ANTHRACENE 0.7 1.206 C650 DI-NBUTYLPHTHALATE 1.493 C655 •FLUORANTHENE 0.6 1.071 D200 1, 2-DIPHENYLHYDRAZINE 1.451 C647 CARBAZOLE 0. 386 C715 PYRENE 0.6 1.341 C720 BUTYLBENZYLPHTHALATE 0. 705 C725 3, 3'CL2BENZIDINE 0.261 C730 BENZD(A)ANTHRACENE 0. 8 1. 105 C740 BIS(2ETHYLHEXYL)PHTH 0.963 C735 CHRYSENE 0.7 1.072 C760 •DI-N-DCTYLPHTHALATE 1. 531 C76S BENZO(B)FLUDRANTHE 0. 7 1. 028 C770 BENZD(K)FLUDRANTHE 0.7 1.037 C775 •BENZD(A)PYRENE 0.7 0.932 80 INDENOd, 2, 3CD)PYR 0.5 0.996 85 DIBENZD(A,H)ANTHRA 0.4 0.838 C790 BENZD(G, H, DPERYLE 0. 5 0.871 .m (Z>^ •>) (fi A^ 0. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 1. 1. 0. 1. 0. 1. 0. 0. 1. 0. 1. 1. 1. 0. 0. 0. 0. 0. 092 225 296 226 949 465 970 114 108 492 202 222 133 038 090 191 921 27B 759 254 631 208 069 940 032 466 115 877 911 987 797 866 31. 1. 6. 2. 4. 2. 1. 51. 27. 19. 12. 8. 22. 9. 9. 20. 14. 11. 96. 6. 10. 20. 3. 2. 3. 4. 8. 15. 2. 0. 4. 0. 296 503 373 216 402 232 899 756 509 878 048 630 977 4B9 616 242 002 925 401 4 50 580 201 254 407 758 286 52B 439 259 901 958 601 300583 c .K^Art To \/ar\dation. Data Subject lu ^ • w DATA FROM FILE: SU12522HB2 SCANS 3S3 TO 1163 ACQUIRED: 03/03/35 16:21:00 CALI: SU12522WB2 #1 SAMPLE: SBLKW kATER-12522H32 HLA CONDS.: 0.25 X BOM RTX-5 l.OUM 45/4-300@12 INST C 4lie' . 6:40 StiiJ _ '- t-yy . 10:80 700 . 11:40 S00 . 13:20 15:00 1000 . 16:40 U i I f>^ gi A 1100 . oil A 13:20 CO T-ME ! •J 100.0?J ( 49664.) CS50 2-FLUaROPHENOL 0.6 (SS-5) CS45 D5-PHEN0L 0.3 (SS-4) CS70 2-CHL0R0PHEN0L-D4 0.8 (5S-7) CI30 04-1,4 DICHLOROBENZENE (IS-1) CS75 1,2-CL2BEN2ENE-D4 0.4 (SS-8) CS20 D5-NITRGBENZENE 0.2 (SS-1) CI 40 D3-NAPHThAi_ENE (IS-2) © CS25 2-FLUOROBIPHENYL 0.7 (SS-2) CI50 DIO-ACENAPHTHENE (IS-3) CS55 2,4,6TRIBRJMGPHENOL (SS-6) CI 60 DIO-PHENANTHRENE (IS-4) • u * DATA FROH FILE: SU12522WS2 SCANS 1163 TO 2400 ACQUIRED: 0.3/03/95 16:21:00 C A L I : SU12522WB2 #1 SAMPLE: SBLKW WATER-125221^^62 HLA CONDS.: 0.25 X BOM RTX-5 l.OUM 45/4-380912 INST C P-' CT; rs tji o; SI CO. o o i l ••' 1203 . 20:00 1400 . 1600 . 26:40 1SO0 . 30:00 2000 _ 33:20 2200 _| 36:45 -• 100.0.^ ( 46144.) .1 f } CI70 D12-CHRYSENE CS30 D14-P-TERPHENYL 0.5 (SS-3) (IS-5) CI75 D12-PERYL£HE .' T i ~ _ - \ Quantitation Report File: SV12522WB2 ' Data: SV12522WD2. TI • 3/03/95 16:21:00 ample: SBLKW WATER-12522WB2 HLA • Conds.: 0.25 X SOM RTX-5 l.OUM 45/4-30021; Formula: Instrument: C Submitted by: Analyst: SRA INST C Weight: Acct. No. 1. 000 12522 AMDUNT=AREA • REF AMNT/(REF AREA • RESP FACT) Resp. fac. from Library Entry . # No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 ^ o h 2 3 4 5 6 7 B 9 10 11 12 13 14 No 1 2 3 4 5 6 7 8 ^ ^ F l l Name CI30 CI40 CISC CI70 CI75 CS50 CS45 CS20 CS25 CSSS CS30 CI60 CS70 CS75 m/z ! 152 136 164 240 264 112 99 82 172 330 244 188 132 152 D4-l,4 DICHLOROBENZENE DB-NAPHTHALENE DIO-ACENAPHTHENE D12-CHRYSENE D12-PERYLENE 2-FLUORDPHENDL D5-PHENDL DS-NITRDBENZENE 2-FLUORDBIPHENYL 0. 6 0. 8 0. 2 0. 7 2,4,6TRIBR0M0PHEN0L D14-P-TERPHENYL DIO-PHENANTHRENE 2-CHL0R0PHENDL-D4 1,2-CL2BENZENE-D4 Bean Time Ref 563 9:23 1 715 11:55 2 926 15:26 3 1424 23:44 4 1685 28:05 5 416 6:56 1 523 8:43 1 .633 10:33 2 843 14:03 3 1021 17:01 3 1290 21:30 4 1101 18:21 12 -541 9:01 1 585 9:45 1 0. 0. 0. 0. 1. 0. 1. 0. 1. 0. 5 0. 8 0. 4 RRT 000 000 000 000 000 739 929 885 910 103 906 000 961 039 Ret(L) Ratio RRT(L) Ratio 9:20 11: 55 15:26 23:45 28: 10 6: 51 8:41 10: 31 14: 03 17:01 21:31 1.01 1.000 1. 1.00 1.000 1. 1.00 1.000 1. 1.00 1.000 1. 1.00 1.000 1. 1.01 0.734 1. 1.00 0.930 1. 1.00 0.833 1. 1.00 0.910 1. 1. 00 1. 103 1. 1.00 0.906 1. 00 00 00 00 00 01 00 00 00 00 00 (IS-1) (IS-2) (IS-3) (13-5) (IS--6) (SS-5) (SS-4) (SS-1) (SS-2) (SS-6) (SS-3) (IS-4) (SS-7) (SS-8) Meth A BB A BB A DB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB Amnt 20. 00 20. 00 20. 00 20. 00 20. 00 78. 06 67. 77 45. 61 38. 19 66. 34 49. 4? Area( :Hght) 8026. 31623. 17464. 18011. 19126. 27610. 41209. 22435. 35348. 7704. 32205. 19910. 32409. 10926. Amnt(L) 20. 20. 20. 20. 20. 25. 25. 25. 25. 25. 25. 00 00 00 00 00 00 00 00 00 00 00 Amount 20. 000 20. 000 20. 000 20. 000 20. 000 78. 056 67. 775 45. 610 38. 190 66. 342 49. 486 20. 000 62. 577 36. 660 R. Fac R. F 1. 1. 1. 1. 1. 2, 4. 0. 1. 0. 1. V\a1 . 000 000 , 000 , 000 000 752 108 568 619 353 430 raSub^ec^ PPB PPD PPB ppn PPB PPB PPD PPH PPD PPB PPD PPD PPB PPB ac(L) 1. 000 1. 000 1. 000 1. 000 1. 000 0. 881 1. 515 0. 311 1. 060 0. 133 0. 72:-! 7.TDt 3. 3. 3. 3. 3. 13. 12. 8. 6. 11. 8. 3. 11. 6. Rat: 1. 1. 1. 1. 1. 3. 2. 1. 1. 2. 1. .... .f-uda^^oi- •\C ^Lti^-^ 54 54 54 54 54 82 00 08 76 75 76 54 08 49 io 00 00 00 00 00 12 71 82 53 65 98 300586 No R e t ( L ) R a t i o RRT(L) R a t i o 12 1 8 : 2 2 1.00 1.000 1.00 kl3 8 : 5 8 1.01 0 . 9 6 1 1.00 '14 9 : 4 2 1.01 1.039 1.00 Ar 20. 62. 36. nnt 00 58 66 Amnt(L) 20. 00 25. 00 25. 00 R. Fac R. 1. 000 3. 230 1. 089 Fac(L) 1. 000 1. 291 0. 743 Ratio 1. 00 2. SO 1.47 300587 •nZcliOi DATA FROM FILE: SUWAk'S3RE SCANS 375 TO 1156 ACQUIRED: 03/03/95 17:06:00 CALI: SUWAW03RE #1 SAMPLE: MU0003 WATER HLA CO.NDS.: 0.25 X 30M .RTX-5 l.OUM 45/4-300§12 INST C ' < * • « i f 6:40 5yiii . S:23 600 . 18:00 11:40 • : 890 . 13:20 .900 . 15:00 3.6 <SS-5) 100.0.^ ( 51520.) .':S.45 .D5-FHEWnL_^.,, ' , .OvS/LSS-4) Ub?y Z-L;HLIJKL!PRCN0L-D4 O.S (Sb-7) CI30 04-1,4 DICHLOROBENZENE (IS-1) = = = — CS75 1,2-CL2BEHZEHE-D4 0.4 (SS-3) - ^ C320 D5-NITROBENZENE G.2 (SS-i) ZKJ O <y» DO m < ^ Si Ci40 D3-NAPHTHALENE (IS-2) [ CS25 2-FLUOROBIPHENYL 0.7 (SS-2) 1030 15:4-^ * Ui o o Si 1100 - 00 l y : i O SCpN X I. iT'ih CI50 DIO-ACENAPHTHENE •'IS-3) \^_^ CS55 2,4,6TRI5R.j:-;0Pf-,l Kbb-b) CI60 DIO-PHENANTHRENE (IS-4) ii • i t ' - * DATA FROM FILE: SUWAW03RE SCANS-1156 TO 2335 ACQUIRED: 03/33/S5 17:06:00 CALI: SUWAwOBRE U SAMPLE: MWOOOB WATER HLA CONDS.: 0.25 X BOM RTX-5 l.OUM 45/4-3001212 INST C Zj •\--.i •M n I i i.t.iitj _ , 20:03 1403 _J 25:23 1560 _ 26:43 iSOO _ 30:00 33:20 i.i.'J'.t _ m j_ r CI70 D12-CHRYSEr€ 100.0!^ ( 51648.) CS30 D14-P-TERPHENYL 0.5 (SS-3) CI75 Di2-PERYL£HE (is-e) Quantitation Report File: SVWAW03RE m Data: SVWAW03RE. TI 3/03/95 17:06:00 ample: MW0003 Conds. : 0. 25 X Formula: Submitted by: WATER HLA SOM RTX-S l.OUM 55/4-300©12 Instrument: C Analyst: SRA INST C Weight: Acct. No. : 1. 000 12522 AM0UNT=AREA • REF AMNT/(REF AREA • RESP FACT) Resp. fac. from Library Entry No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 r No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 No 1 2 3 4 .5 h ^ 7 Name CI30 CI40 CI 50 CI60 CI70 CI75 CS45 CS20 CS25 CS30 C4S0 C740 CSSO CS75 CS70 CSSS m/z 152 136 164 188 240 264 99 82 172 244 128 149 112 152 132 330 D4- DS-I DIO- DIO- D12- D12- 1,4 DICHLOROBENZENE MAPHTHALENE -ACENAPHTHENE -PHENANTHRENE -CHRYSENE -PERYLENE D5-PHENDL DS-NITRDBENZENE 2-FLUDRDBIPHENYL D14--P-TERPHENYL NAPHTHALENE 0. 8 0. 2 0. 7 0. 5 0. 7 BIS(2ETHYLHEXYL)PHTH 2-FLUDRDPHENDL 1, 2-CL2BENZENE-D4 2-CHLDRDPHENDL-D4 2,4, Scan 556 713 926 1101 1423 1685 517 628 842 1289 718 1414 397 578 534 1020 Ret(L) Ra- 9: 20 11: 55 15: 26 18:22 23:45 28: 10 8: 41 0. 6 0. 4 0. 8 ,6TRIBROMOPHENOL Time Ref 9: 16 1 11: 53 2 15:26 3 18:21 4 23:43 5 28:05 6 8:37 1 10:28 2 14:02 3 21:29 5 11: 58 2 23:34 5 6: 37 1 9:38 1 8: 54 1 17:00 3 0. 0. 0. 0. 1. 0. 0. 1. 0. 1. bio RRT(L) Rat: 0. 99 1. 000 1. 1. 00 1. 000 1. 0. ' DO 1.000 1. DO 1. 000 1. DO 1.000 1. DO 1.000 1. 99 0.930 1. RRT 000 000 000 000 000 000 930 881 909 906 007 994 714 040 960 102 lo 00 00 00 00 00 00 00 (IS-1) (IS-2) (IS-3) (IS-4) (IS-5) (IS-6) (SS-4) (SS-1) (SS-2) (SS-3) (SS-5) (SS-8) (SS-7) (SS-6) Meth A BD A BB A BB A BB A BB A BB A BB A BB A BB A BB A BV A BB A BB A BB A BB A BB Amnt 20. 00 20. 00 20. 00 20. 00 20. 00 20. 00 5. 87 Area(Hght) 8335. 32507. 17912. 19972. 12531. 11872. 3705. 22537. 39116. 33441. 774. 10682. 751. 12366. 1958. 301. Amnt(L) 20. 00 20. 00 20. 00 20. 00 20. 00 20. 00 25. 00 Amount 20. 20. 20. 20. 20. 20. 5. 44. 41. 73. 0. 18. 2. 39. 3. 2. R. Fac 0. Data 000 000 000 000 000 000 867 571 204 856 519 155 044 953 640 527 PPB PPD PPB PPB PPB PPD PPD PPD PPD PPD PPD PPD PPD PPB PPD PPD R. Fac(L) 000 000 000 000 000 000 . 356 Subject T 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 1. 515 7."l 5. 5. 5. 5. 5. 5. 1. 12. 11. 20. 0. 5. 0. 11. 1. 0. Rat: 1. 1. 1. 1. 1. 1. 0. (ot 68 68 68 68 68 68 67 65 69 96 15 15 58 34 03 72 Lo 00 00 00 00 00 00 23 300590 0 Validation: No 8 9 10 11 12 13 14 15 16 Ret(L) 10:31 14:03 21:31 11:57 23:35 6:51 9:42 8:58 17:01 Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 0.97 0. 99 0. 99 1. 00 RRT(L) 0. 883 0. 910 0. 906 1. 003 0. 993 0. 734 1. 039 0. 961 1. 103 Ratio 1. 00 1. 00 1. 00 1. 00 1.00 0. 97 1. 00 1. 00 1. 00 Amnt 44. 57 41. 20 73. 86 0.p2 18. 15 2. 04 39. 95 3. 64 2. S3 Amnt(L) 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 R. Fac R. 0. 555 1. 747 2. 135 0. 019 0. 682 0. 072 1. 187 0. 188 0. 013 Fac(L) 0. 311 1. 060 0. 723 0. 917 0. 939 0. 881 0. 743 1. 291 0. 133 Ratio 1. 78 1. 65 2. 95 0. 02 0. 73 0. 08 1. 60 0. 15 0. 10 300591 iC^ata Subied 7b Vsfidatlorv '<«:• TARGET COMPOUND COMPARISON COMPOUND: C450 NAPHTHALENE RAW DATA: SUWAWOBRE ^^718 03/03/95 17:06 SAMPi-E: MW0003 WATER Hi-A 0.7 CONDS.: 0.25 X BOM DTV-.c' l.OUM 45/4-3001212 BASE M/2: INST C 136 RIC: 757. .3b. Dn Lt.'. .L 365. I I I I ' 1 1 1 I I I I I ^-TT^-A- 4- •4- I 1 I I I I I I 1 1 I I I V I 1 I I I I I I I I I I l i l l l l l 1 I I . I I I I I I I I T I I 1 I I I I' I I I I I I I I I I T i I I I I I I I I •! I I I I I I I I I ENHANCED DATA: SUWAW05RE #718 BASE M/2: 128 RIC: 129. 4.:3-i 2.4-^ I I ; I l l l l I 4- I 48. • f 1 . I I I t I I 1 I 1 I I i I'l . I 1 I 1 .; I I I 1 ' I I . I 1 1 I I 1 - I I I / ) I I !• I ' I I I I I I I I I I I 1 I I I I I I I I I 1 I I I I I » i I LIBRARY FILE: SH «24 BASE M/Z: 128 RIC: 1366. 100. 0-] 50.0- a • V? 133. On % 50.0^ I I ! I I I 1 1 , 1 1 1 1 I i I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I r i I I I I I I I I I I I I I I I I I I I I r 1000. 40 53 63 70 83 90 100 110 120 130 \y 0.8- ui\iZ <^Az -53.0-1 m ^ \ -100.0-^ i I I 11 -I ^ •<t '-* 100.0-1 50.0- 80.7T1 40.3 TARGET COMPOUND COMPARISON COMPOUND: C743 BIS(2ETHYLHEXYL)PHTH RAW DATA: SUWAW03RE ^1414 03/03/95 17:06 SAr.PLE: Mi'iOOSB WATER HLA CONDS.: 0.25 X 30M RTX-5 l.OUM 45/4-300012 INST C BASE M/2: 149 RIC: 20896. 1 ^ I ' I r — ] r L., , . i . \ , .ll ..l|.--.-ll. ENHANCED DATA: SUWAWOBRE #1414 I " • I • • 1 ' r 5296. I •"! ' \""'" I • 1 ' ' I ' T ' l ' I ' I ' I ' I ' I ' BASE M/Z: 149 RIC: 15600. • | M . I l"'| V ' l ' I "•' I •' I I " I r 4272. I ' I ' I • ' I ' l ' r ' I ' I ' I ' I ' T-»T—r-*i—r I ' •! . f • r o p-i P.) It'l •H 13.9n 3.4- M/2 108.0- 50.0- 0.0-: ^'•' U i • - - - _ . §: SrlOO-O-" to LIBRARY FILE: SH #56 BASE M/2: 149 RIC: 1586. r 1000. - I — I — I — I — r — T — 1 — I — r — T — I — I — I — p - T — 1 — I — r - 1 — p - ^ — I — r - ' Y ' ' I — ' I ' " • I — ' — T f — 1 — ' — T 50 130 150 200 .III. ..III...... ..II. I. ii. - T — J — r ' 1 ' I ' 'I ' 250 FMGR ; TONER, "DFTPP \. GC/MS PERFORMANCE STANDARD Decafluorotriphenylphosphine (DFTPP) B/Z Ion Abundance Criteria \ Relative Abundance Base Appropriate Peak Peak 51 30-60% of aass 198 68 Less than 2% of aass 69 69 (reference only) 70 Less than 2% of nass 69 127 40-60% of aass 198 197 Less than 1% of mass 198 198 Base peak, 100% relative abundance 199 5-9% of aass 198 275 10-30% of aass 198 365 Greater than 1% of aass 198 441 0-100% of aass 443 442 Greater than 40% of aass 198 443 17-23% Of aass 442 Injection Date: 02/02/95 Injection Time: 09:19 Data File: >H033A Scan: 427 Status 57.37 0.00 84.88 .22 59.02 0.00 100.00 6.78 22.66 1.67 8.48 50.98 8.93 57.37' 0.00' 84.88* .26 59.02 0.00 100.00 6.78 22.66 1.67 94.95 50.98 17.52 Ok Ok Ok Ok Ok Ok Ok Ok Ok Ok Ok Ok Ok 300594 Data Subject To Validatior £ 9 F i l e >He33A Sensr Bpk Ab xea. 1 1 * 1 leo: * 20: • 10: 0 DFTPP 51 / '•Um 127 50 Ja lee A 29e-04-PERF-5988 SUB NRM 198 186 y 1 5 0 280 2 5 0 255 275 ' p y ^ f '• ' L . ' y - ' ^ t ^ ^ ^ < ^ UQs -y 296 323 11 iT« I i T i ' i I ri'i 1^111't I ti*i l l l l i"i 11 n 11 r I 3 0 0 3 5 0 4 0 0 Scan 427 7 . 6 3 Min. 1^10 ^ 0 0 ^ 0 ^ 0 i70 442 p60 :50 i40 E30 ^ 0 rl0 0 Data Filename: >H033A::D1 Name: 50ng DFTPP Misc: 290-04-PERF-5988 INST H BTL/ 1 Operator ID: DAVID SUPER GRP. Analysis Date/Time : 2/02/95 9:19 3 0 0 5 9 5 Data Subject lb Va'idation Analysis Date/Tiae: 2/02/95 9:19 . Data Filename and Sample ID: >H033A SOng DFTPP 290-04-PERF-5988 INST H 427 SUB NRM F i l e : >B033A Scan #: 427 Retn. time: 7.63 a/z I n t . a/z I n t . a/z I n t . a/z I n t . a/z i n t . 36.95 .439 96.90 .346 154.15 .611 202.95 .406 276.05 2.727 38.05 1.096 98.00 6.047 155.00 1.276 204.05 3.446 277.05 1.574 38.95 4.003 99.00 4.756 156.15 1.574 205.05 5.499 278.00 .343 43.80 .262 100.90 2.700 157.00 .238 206.05 22.854 293.00 .445 48.95 .620 103.00 .557 158.00 .563 207.05 3.624 296.00 5.180 49.95 18.116 103.90 1.499 160.15 .527 208.05 .939 297.00 .867 50.95 57.365 105.00 1.291 161.00 1.225 211.05 1.008 303.00 .557 51.95 2.926 107.00 17.418 162.00 .241 216.05 .620 314.15 .196 52.95 .217 108.00 2.297 165.00 .780 216.95 6.775 314.90 .461 55.20 .641 110.00 32.118 166.00 .831 218.05 .614 316.00 .283 55.90 1.950 111.00 5.647 166.95 4.972 221.05 4.885 321.90 .108 56.90 4.280 112.00 .205 167.95 1.950 223.05 1.303 323.00 1.776 60.90 .861 117.00 14.959 169.95 .292 224.05 12.235 324.00 .157 62.00 1.026 118.00 1.147 172.95 .539 224.95 3.660 327.65 .108 63.00 2.218 121.40 .066 173.95 .969 226.05 .268 334.00 .915 64.90 .659 122.00 1.342 174.95 1.616 226.95 5.063 335.00 .436 68.90 84.875 123.00 1.683 176.05 .479 228.05 .683 345.90 .241 69.90 .223 124.00 1.081 176.95 1.141 228.95 1.219 352.00 .674 73.15 .433 125.00 .370 178.05 .352 230.95 .370 354.15 .707 73.90 6.300 127.00 59.018 178.95 3.853 236.95 .262 365.00 1.667 75.00 10.041 128.00 4.286 180.95 1.129 240.95 .412 366.00 .271 76.00 2.507 129.00 24.931 182.80 .117 241.95 .461 370.15 .087 77.00 61.344 130.00 1.761 184.05 .457 243.05 .996 372.00 .749 78.00 3.973 132.00 .214 185.05 1.523 244.05 10.155 373.00 .364 78.90 4.367 134.00 .539 186.05 12.930 244.95 1.282 389.95 .166 79.90 3.356 135.00 1.415 187^05 3.531 246.05 1.743 401.95 .319 81.00 4.421 136.00 .515 188.05 .536 247.05 .689 402.95 .497 81.90 1.162 137.00 .765 188.95 .819 255.05 54.081 420.95 .391 83.00 .554 138.00 .108 190.95 .439 256.05 7.230 422.05 .641 85.00 .798 141.00 2.348 191.95 .873 257.05 .412 422.95 3.202 86.00 .2.029 142.15 .849 193.05 1.035 257.95 2.971 423.95 .373 87.00 .232 146.00 .533 195.95 2.838 263.95 .144 440.95 8.482 87.90 .150 147.00 1.062 197.95 100.000 265.05 1.129 442.05 50.975 91.00 .710 148.00 3.076 198.95 6.784 273.05 1.755 442.95 8.933 92.00 .978 148.90 .457 199.95 .379 274.05 3.570 444.05 1.114 92.90 7.621 151.15 .412 201.45 .632 275.05 22.661 300596 i-'Sta Mbject To yildarior QUANT REPORT Operator ID: DAVID Output File: *fi033A:;BQ Data File: >H033A::D1 Name: SOng DFTPP Misc: 290-04-PERF-5988 Quant Rev: 6 Quant Tiae: injected at: Dilution Factor: INST H 950202 10:25 950202 09:21 1.00000 BTL/ 1 ID File: ID_DFT::DB Title: DFTPP/BENZIDINE/PENTACHLOROPHENOL PERFORMANCE Last Calibration: 950202 10:22 Compound R.T. Q ion Area Cone Units 1) 2) 3) *IS/4 Phenanthrene-dlO Pentachlorophenol Benzidine 7.42 7.20 9.19 188.2 265.9 184.2 177455 36193 134593 20.00 ppb 25.00 ppb 25.00 ppb 85 98 90 * Compound is ISTD 300597 i /sTS Z:.Z.!-". TOTftL ION CHROMATOCIWM > i i c >H03^A i s . 6 - 5 1 ^ . 6 AMU. SOosr »FXFP 2 9 0 - 0 4 - F E R F - 5 9 8 8 , 1O0 , S0O . 3 0 0 , 4 O 0 , 5O0 . . . 6 q 0 . . . . . . 7 . q O . .. 8 0 0 . . . . I . . . .-1 . . . . t . .. .-I . . . . 1 . . . .-T. . . . t .-.. . T . . . . I . . . .T . . . . 1 . . . . 1 . . . . I . . . . I . . . . 1 ,. , ,-y^ ^ 600000- a 550000- 500000- 450000 400000- 350000- 300000 250000-1 200000 150000 1O0OO0- 50000- 0- i l l " ' l rWv 4 . 0 I • • H I I I ' l r, I . I , J , , • I"! ••••! I •! ••• ' i l i • • I I p I •>> ! < ' • ' ' ' ' I ' • 1 ' I „ 5 . 0 6 . 0 7 . e 8 . e 9 . 0 1 0 . o N I' 1 1 1 1 (I ^ I I 11 j S 1 1 1 1 1 1 . 0 Data File: >H033A::D1 Name: SOng DFTPP Misc: 290-04-PERF-5988 Quant Output File: •'H033A::BQ INST H BTL/ 1 Id File: ID_DFT::DB Title: DFTPP/BENZIDINE/PENTACHLOROPHENOL PERFORMANCE Last Calibration: 950202 10:22 Operator ID: DAVID Quant Time: 950202 10:25 Injected at: 950202 09:21 300598 Data Subject "i^ Valldstic y F F g P g W C E STANT>ftP1> SygCTWliM F i l e >He99P BENZIDINES SDT Bpk Ab 1 O 0 . 1 0 2 8 - 2 1 - B E N Z - 5 e SUB NRM ^ ^ ^ INST 100-1 0- : 52 - 1 ^ 4 0 77 ' / " > ^ 1 3 0 > ? ' « 6 •f'*'^*'' H"'' • ''*'i i'**! r*' »"*»S '*'> 8 0 1 2 0 1 6 0 65 77 V / / I 1 8 6 . J i ^ . . • 200 Soain 2 5 3 8 2 4 . 9 7 M i n . Koo T—»" 1 I « ^ 0 240 SAMPLE SPECTRUM (BACKGROUND SUBTRACTED) File >He33A SOnsr PFTPP Bpk Ab 66536. * 40000: O- 52 40 £5 77 92 - 1 ^ 80 290-04-FERF-5988 SUB 184 1 3 0 " ' 156 J Scan 608 9.19 Min. 253 240 SAMPLE SPECTRUM (UNALTERED> File >HO33A^50nsr 66536. DFTPP 290-04-PERF-5988 184 40000- O-J 65 77 92 52 .1 X y .f. I 'I" I' I'i i -li'ij 117 130 139 156 BT 80 7 X ^ry >: i|ll., .J.I., , III. ,ji,|. , a j I , ^ 1 , 207 / 120 160 200 Sc&n 608 9.19 Min. KOO 253 24o Data File: >H033A::D1 Name: 50ng DFTPP Misc: 290-04-PERF-5988 Quant Time: 950202 10:25 Injected at: 950202 09:21 Compound No: 3 Compound Name: Benzidine Scan Number: 609 Retention Time: 9.19 min. Quant Ion: 184.2 Area: 134593 Concentration: 25.00 ppb q-value: 9 0 Quant Output File: *H033A::BQ INST H BTL# 1 Quant ID File: ID_DFT::DB Last Calibration: 950202 10:22 3 0 0 5 9 9 ZciXd Subf'^r? Tn, \Z-:-.\\--» -::•!:....., TOTPL ION CHRCnflTOGPfln Filt >K03?c; 35.6-510.0 *ixu. SSTOCSO 8Si0-12-SV25 500 1000 1500 2000 ' 2500 3000 • ' • • ' • • • • ' • • • • ' ' I . . . . I . . . . I • I , , • • I • • • , I • • 320000- 280000- 240000- 2eociec* leoeee^ iiCe-30- eeeoe- 4000^ .V / »•«.. Data File: >H033B::D1 Name: SSTDOSO Misc: 290-12-SV25 Ouant Output File INST H ^HD33B::BQ BTL# 2 Id File: ID_SH::DB Title: SEMIVOLATILES BY SWe46-8270/EPA 625 Last Calibration: 950202 10:33 Operator ID: DAVID Ouant Time: 950202 10:52 Injected at: 950202 09:43 300600 Data Subiect lb Va!ida?ior, QUANT REPORT Operator ID: DAVID utput File: "HOSSB: ta File: >H033B: ame: SSTDOSO Misc: 290-12-SV25 ^fa Quant Rev: 6 BO Dl Ouant Time: Injected at: Di I ut ion Factor: INST H ID File: ID_SH::DB Title: SEMIVOLATILES BY SW846-B270/EPA 625 Last Calibration: 950202 10:33 950202 950202 1, BTL# 2 10:52 09:43 00000 Compound R.T. O ion Area Cone Un i ts «IS#1 1,4-DichIoroben2ene-d4 Pyr idine N-N i trosodimethylamine Phenol-d5 2-Chlorophenol-d4 2-FIuor ophenoI An i M p e Phenol 2-ChIorophenoI b i s(2-Chloroethyl)ether 1,3-D ichlorobenzene 1,4-Dichlorobenzene 1,2-D ichlorobenzene-d4 1,2-Di chlorobenzene BenzyI a IcohoI 2,2'Oxybis-( 1-chloropropane) 2-Me thy IphenoI N-Ni troso-di-n-propylamine HexachI or oethane 4-Met hyIphenoI •IS#2 Naphthalene-d8 N i t robenzene-d5 Ni t robenzene Isophorone 2-N i t rophenoI 2,4-Dimethylphenol bis(2-Chloroethoxy)me thane 2,4-D i chI or ophenoI Benzo i c ac i d 1,2,4-Tr ichlorobenzene Naph thaIene 4-ChIoroan iIi ne Hexachlorobutadiene 4-Chloro-3-methyIphenol 2-Methy I naphthalene •IS#3 Acenaphthene-dIO Hexachlorocyclopentadiene 2 ,4,6-Tr ichlorophenol 2,4,6-Tr ichlorophenol 2-Fluorobiphenyl 2-Ch loronaphthaleine 2-N itroaniline ' Dimethylphthalate 11.42'' 6.96 6.98 10.82 11.09 9.35 10.93<' 10.84' 11. 12 10.98- 11.36 . 11.45. 11.76' 11.77- 11.65 . 11.90 11.84' 12. 14 12.31 12.07- 13.66 12.42 12.46 12.83 13.01 13.00. 13. 16 13.40 13. 14. 13.67 13.70 13.79 13.96 14.59 14.92 16.86 15.30 15.45- 15.53 15.57 15.81 16.03 16.32 152.0 79. 1 74.0 99.0 132.0 112.0 93.0 94.0 128.0 93.0 146.0 146.0 152.0 146.0 108. 1 44.9 108.0 70.0 117.0 108.0 136. 1 82.0 77.0 82.2 139.0 107.0 93. 1 162.0 122.0 179.9 128. 1 127.0 224.8 107.0 142. 1 164.2 236.8 196.0 ' 196.0 172. 1 162.0 65.0 163. 1 — ,.-.. . r^. 27784 30623 21465 52223 41615 39638 76624 55874 42157 50916 47385 47863 26770 44127 25819 48964 38649 32460 20535 40765 101995 48881 50299 100539 21185 36448 61855 32333 21727 36681 115756 52131 22276 36596 70079 51488 18920 22493 25377 72365 69305 25687 86349 - i. - ^ _ I. /., >; -- 20.00 25.00 25.00 25.00 25.00 25.00 26.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 20.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 20.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb Ppt> ppb ppb ppb ppb ppb ppb ppb ppb Or2-2--*^5, • ' . •• •; , - • - . 300601 99 87 96 90 88 76 99 60 87 93 97 93 96 95 93 97 94 78 90 99 99 82 . 94 98 96 86 93 84 93 96 98 92 96 86 94 94 93 81 95 93 95 66 89 TtsH Compound R.T. Q Ion Area Cone Units 2,6-Di n i t rotoIuene Acenaphthylene 3-Nitroaniline Acenaphthene 2,4-Di n i t rophenoI Dibenzofuran 4-Ni trophenoI 2,4-Di n i t rotoIuene 2,3,4,6-Tet rachIorophenoI OiethyIphthaI ate 4-ChIoropheny1-phenyI ether F I uorene 4-N i t r oan i I ine 2,4,6-Tr i br omophenoI • IS#4 Phenanthrene-dlO 1,2-DiphenyIhydrazine 4,6-D i n i t ro-2-methyIphenol Diphenylamine 4-Br omophenyl-phenylether HexachIorobenzene Pentachlorophenol CarbazoIe Phenanthrene Anth racene Fluoranthene Di-n-butylphthalate •IS#5 Chrysene-d12 Pyrene Te r phenyI-d 14 Butylbenzylphthalate 3,3'-Dichlorobenzidine Benzo(a)anthracene b i s(2-EthyIhexyl )phthalate Chrysene • IS#6 Perylene-d 12 Di-n-octylphthalate Benzo(b)f luoranthene Benzo(k)f luoranthene Benzo(a)pyrene I ndeno( 1,2,3-cd )pyrene Dibenz(a,h)anthracene Benzo(g,h, i jperylene 16.49 16.59 16.77 16.91 16.95 17. 19 16.99 17.21 17.47 17.66 17.75 17.83 17.90 18.30 19.54 18.04 17.95 17.97 18.64 18.97 19.27 19.93 19.58 19.67 21.78- 20.44 24.43 22.21- 22.36 23. 17 24.26 24.39. 24. 12 24.4 9- 28. 17 25.35 26.98. 27.05- 27.99. 32.29 32.24 33.57- 165.0 162. 1 138.0 153. 1 184.0 168. 1 109.0 165. 1 232.0 149. 1 204. 1 166. 1 138.0 329.6 188.2 77.0 198.0 169. 1 248.0 283.8 265.9 167.0 • 178. 1 '178. 1 202.0 149.0 240.2 202.0 244.2 149. 1 252.2 228.0 149.0 228.0 264.2 149.0 '252.2 252.2 252.0 •276.2 '278. 1 276.0 19560 114316 22495 69269 6943M 93452 11042 24764 23244 9426 1 34469 69174 21335 14100 76966 119744 13289 48666 22335 29962 16842 92901 102364 102427 106405 156775 71342 112503 67151 66412 33713 97337 94883 90538 77372 162532 100196 88090 87017 98308 75017 82611 26.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 20.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 20.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 20.00 25.00 25.00 25.00 25.00 25.00 26.00 25.00 ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb- ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb 95 98 88 96 98 89 84 91 91 78 96 97 84 94 85 93 95 93 94 97 95 96 98 97 97 98 96 99 93 9 8 96 88 97 . 87 96 95 98 95 94 89 78 • Compound is ISTD 300602 Data Subiect To Vey crz-'»--»s TOTOL ION CHROnRTOORRfl File >H053C35.0-510.0 AKU. S S T D O B O 2 9 e - 1 2 - S V 4 0 TIC 500 1000 1500 sooe -2500 3000 4 < a g l B 6 H ''''•'''''''''' ' I ' I '"''' I ''''*'''• ' I .... I . • ^ ^ ^y:-> ^ '«w Data File: >H033C::D1 Name: SSTDOSO Misc: 290-12-SV40 Ouant Output File: ^H033C::BO INST H BTL# 3 Id File: ID_SH::DB Title: SEMIVOLATILES BY SW846-8270/EPA 625 Last Calibration: 950202 10:33 Operator ID: DAVID Quant Time: 950202 11:17 Injected at: 950202 10:29 300603 err 2.-1---^5 QUANT REPORT Operator ID: DAVID Output File: *H033C::BQ ta Fl le: >H033C::D1 me: SSTDOSO Misc: 290-12-SV40 Quant Rev: 6 m Ouant Time: Injected at: Di I ut ion Factor: INST H 950202 11:17 950202 10:29 1.00000 BTL# 3 ID File: ID_SH::DB Title: SEMIVOLATILES BY SW846-8270/EPA last Calibration: 950202 10:33 625 Compound R.T. O Ion Area Cone Uni ts 1 2 3 •A 5 € 7 8 9 10 11 12 13 14 15 18 19 20 21 22 23 24 25 26 27 26 29 30 31 32 33 34 35 36 37 38 39 40 m A 3 ) • IS<»1 1,4-Di ch I orobenzene-d4 Pyr i d i ne N-N itrosodtmethylamine Phenol-d5 2-ChIorophenol-d4 2-FIuor ophenoI An iIi ne PhenoI 2-Chlorophenol b i s(2-Chloroethyl)ether 1,3-D ichlorobenzene 1,4-Dichlorobenzene 1,2-D ichlorobenzene-d4 1,2-D ichIorobenzene BenzyI a I cohoI 2,2'Oxybis-(1-chloropropane) 2-MethyIphenoI N-N i troso-di-^n-propylamine HexachI oroe t hane 4-Met hyIphenoI • IS«2 NaphthaIene-d8 N i t robenzene-d5 N i t robenzene I sophorone 2-N i t rophenoI 2,4-Dimethylphenol b i s(2-Chloroethoxy)me thane 2,4-Dichlorophenol Benzo i c acid 1,2,4-Tr ichlorobenzene Naph t ha Iene 4-ChIoroan iIi ne HexachIorobutadiene 4-ChIoro-3-met hyIpheno I 2-MethyInaphthalene •IS#3 Acenaphthene-dIO Hexachlorocyclopentadiene 2,4,6-Tr ichlorophenol 2,4,5-Tr ichlorophenol 2-Fluorobiphenyl 2-Chloronaphthalene 2-N i t r oan i Ii ne DimethyIphthaI ate 11.43' 6.97 7.00 10.83 11. 10 9.36 10.94. 10.85- 11. 14 10.99. 11.37- 11.46- 11.77' 11.78- 11.66- 11.90 11.84 • 12. 15 12.32 12.09. 13.67 12.43 12.46 12.83 13.02 13.00- 13. 17 13.41 13.IS- IS.58 13.70 13.80 13.97 14.59 14.92 16.86 16.30 15.45' 15.5 3-' 16.57 15.81 16.03 16.32 162.0 79. 1 74.0 99.0 132.0 112.0 93.0 94.0 128.0 93.0 146.0 146.0 152.0 146.0 108. 1 44.9 108.0 70.0 117,0 108.0 136. 1 82.0 77.0 82.2 139,0 •107.0 93. 1 162.0 122,0 179.9 128, 1 127.0 224,8 107.0 142, 1 164,2 236.8 • 196,0 196.0 172, 1 162.0 65,0 163. 1 27297 60466 39434 86623 67171 63563 116375 91124 67888 77113 75017 75153 45007 68796 41292 75978 58626 60355 32631 61283 94086 81098 78671 154985 34048 52263 97535 5 1647 35216 57897 174925 81003 33480 56374 107330 45735 32010 35811 37984 119420 100560 41566 129797 20.00 60.24 46.75 42.21 41.07 40.80 38,65 41.50 40.98 38.54 40.28 39.95 42.78 39.67 40.70 39.48 38.40 39.47 40,43 38,25 20,00 44.96 42.39 41.78 43.56 36.86 42.73 43.29 43,93 42,78 40.95 42. 11 40,. 73 4 1.75 41.51 20,00 47.62 44.81 42. 13 46,45 40.84 45,54 42.31 ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb 97 89 93 90 86 76 96 62 81 93 96 97 96 97 89 94 95 78 96 96 98 80 93 98 99 90 93 83 93 97 98 95 93 87 92 88 94 89 90 94 97 66 90 CT~"2--"2--'*5 300604 Compound R.T. Q ion Area Cone Units 2,6-Dini trotoluene Acenaphthylene 3-Nitroaniline Acenaphthene 2,4-Di ni t rophenoI Dibenzofuran 4-Ni trophenoI 2,4-Dini trotoluene 2,3,4,6-Tet rachIorophenoI Diethylphthalate 4-ChIoropheny1-phenyI ether FIuorene 4-Ni t roan iIi ne 2,4,6-Tr i bromophenoI •IS#4 Phenanthrene-d10 1,2-Di phenylhydrazine 4 ,6-D i n i t ro-2-methyIphenol D i phenyI ami ne 4-Br omophenyl-phenylether HexachI orobenzene PentachIorophenoI Carbazo t e Phenan t hrene Anthracene Fluoranthene Di-n-butylphthalate •IS#5 Chrysene-d12 Pyrene Terphenyl-d14 Butylbenzylphthalate 3,3'-Dichlorobenzidine Benzo(a)anthracene b i s(2-Ethy Ihexyl)phthalate Chr ysene •IS#6 Perylene-d12 Di-n-octylphlhalate Benzo(b)fluoranthene Benzo(k)fluoranthene BenzoCa)pyrene indenoC 1,2,3-cd)pyrene Dibenz(a,h)8nthracene Benzo(g,h,i)perylene 16.49 16.59 16.78 16.92 16.95 17. 19 17.00 17.21 17.47 17.56 17.75 17.82 17.90 18.30 19.54 18.05 17.96 17.98 18.64 18.98 19.28 19.93 19.59' 19.67' 21.76- 20,44 24.42 22.20- 22,34 23, 16 24.25 165.0 152.1 138.0 153. 1 184. 1 158. 1 109.0 165. 1 232.0 149. 1 204. 1 166. 1 138.0 329.6 188.2 77.0 198.0 169. 1 248.0 283.8 265.9 167.0 178, 1 178. 1 202.0 149.0 240.2 202.0 244.2 149, 1 252.2 24.38-228,0 24. 11 24.48 28. 14 25.34 26.96' 27.02 27.97 32.26 32,23' 33,53' 149,0 '228.0 264.2 149,0 •252,2 '252,2 '252.0 •276.2 278, 1 276.0 29952 166139 33587 104731 16708M 141567 16747 37376 36016 141158 60916 105966 30530 21978 67969 184457 21266 72380 34227 42132 26769 137420 150246 152866 160358 235779 64028 169177 106569 99323 61372 143236 143242 133771 66330 224915 138074 132832 122112 141180 109650 117161 43.05 40.90 42.02 42.54 49.44 42.64 42.69 42.48 43.61 42. 15 41.55 43. 11 40.27 43.87 20.00 43.61 45.30 42. 10 43.38 39.78 44.98 41.88 41.55 42.25 42.66 42.58 20,00 41.89 44.21 41,66 42,45 40.99 42.05 41. 16 20.00 43.00 40. 19 43.97 40,92 41,88 42.62 41.36 ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb 96 96 95 95 95 67 82 85 92 78 . 99 96 93 95 87 92 94 95 96 97 97 96 98 97 98 96 96 96 99 94 94 88 96 . 95 97 96 97 93 92 . 84 82 • Compound is ISTD 300605 ZO'^fr-rT ' f "••'^'V^-i-''.-'- TOTAL ION CHR0nRT05POM riu >He33D 35.e-5io.e Mtu. SSTDIEO 500 leoe 1500 aooo ' • • • ' • • • • ' • • ' • ' • • • ' ' • • . • ' • • • • ' • • • • ' ' 5ee00&i 6»fe-i&-sv^a 520000- 480000- 440000- 400000- 360000- 320000- aeoooe- 240000- 200000- leeoofr 120000- 60000- 4O0oe^ £500 . l i l l l l l 3000 1 1 1 1 1 I I I I liXi ^ ^ ^ ^ «fe r CD -Tc % Data File: >H033D::D1 Name: SSTD120 Misc: 290-12-SV60 Ouant Ou tput File: INST H 'H033D::B0 BTL# 4 Id File: ID_SH::DB Title: SEMIVOLATILES BY SW846-8270/EPA 625 Last Calibration: 950202 10:33 Operator ID: DAVID Quant Time: 950202 11:52 Injected at: 950202 11: 16 300606 •Jdia Subjed: To ZzZdztiorf; OUANT REPORT Operator ID: DAVID Output File: ''H033D::BO i ta Fi ie: >H0330::D1 me: SSTD120 Misc: 290-12-SV60 Ouant Re^: 6 Quant Time: Injected at: Di I ut ion Factor: INST H 950202 11:52 950202 11:16 1.00000 BTL# 4 ID F I Ie: ID_SH::DB Title: SEMIVOLATILES BY SW846-8270/EPA Last Calibration: 950202 10:33 625 Compound R.T. O I on Area Cone Uni ts 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 IB 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 36 39 40 43) «IS#1 1,4-OichIorobenzene-d4 Pyr i d i ne N-Ni trosodimethylamine Phenol-d5 2-ChIorophenol-d4 2-FIuor ophenoI Aniline PhenoI 2-ChIorophenoI b I s(2-ChIoroethyI)ether 1,3-Dichlorobenzene 1,4-D ichlorobenzene 1,2-Di chlorobenzene-d4 1,2-Dichlorobenzene Benzyl alcohol 2,2'Oxybis-(1-chloropropane) 2-Methy IphenoI N-N i troso-di-n-propylamine HexachI or oe t hane 4-Methy IphenoI •IS#2 Naphthalene-d8 Ni t robenzene-d5 N i t robenzene I sophorone 2-Ni t rophenoI 2,4-Dimethylphenol b i s(2-Chloroethoxy)me thane 2,4-Di chIorophenoI Benzo i c acid 1,2,4-Tr ichlorobenzene Naphtha Iene 4-ChI or oan iIi nc Hexachlorobutadiene 4-ChI oro-3-methyIphenol 2-MethyInaphthalene • IS#3 Acenaphthene-dIO HexachlorocycIopentadiene 2,4,6-Tr ichlorophenol 2,4,5-Tr ichlorophenol 2-Fluorobiphenyl 2-Chloronaphthalene 2 - N i t r o a n i I i ne D imet h y I p h t ha I a t e 11.42' 6.97 7.00 10.83 11. 10 9.35 10,93' 10.85' 11. 13 10.99' 11.36- 11.45. 11.75, 11.78. 11.66- 11.89 11.84, 12. 15 12.31 152.0 79. 1 74.0 99.0 132.0 112.0 93.0 94.0 128.0 • 93.0 146.0 146,0 152.0 146.0 108. 1 44.9 108.0 70.0 117.0 12.08'108,0 13,66 12,42 12,46 12,83 13,01 13.00' 13. 16 13.41 13,20' 13.57 13.70 13.79 13,96 14.59 14.91 16,85 15,29 15.45. 16,53,' 15,57 15.81 16.03 16.32 136. 1 82.0 77.0 82.2 139.0 107.0 93. 1 162.0 122.0 179.9 128. 1 127.0 224.8 107.0 142. 1 164.2 236.8 196.0 '196.0 172, 1 162,0 65.0 163. 1 27076 87758 58125 121455 97022 92483 165440 130123 96029 110160 102447 106450 63741 97207 60908 108823 83066 74 189 47508 88986 91384 114295 114352 226592 47148 74261 136694 73517 52960 78707 243704 113601 45530 78587 146081 42175 47345 50688 53663 162 138 140371 66424 176478 20.00 73.62 69.47 59.66 59.81 59.85 55,39 59.74 58.44 55,50 55.46 57.06 61.08 56,51 60.52 57.02 54.85 58.63 59.35 56,00 20.00 65.24 63.44 63.44 62. 10 56.85 61.66 63,44 68 . 0 1 59.87 58.74 60.80 68.28 69.92 68. 16 20.00 76.37 68.78 64.54 68,38 61.82 67.04 62.38 ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb 98 93 97 87 85 73 99 57 83 90 93 96 94 95 90 97 93 76 92 97 99 84 . 95 97 93 85 92 84 97 98 99 96 98 90 95 89 93 86 96 94 96 63 89 -J'-^ l U VCi aciaiioni CTZ^r?-'^ 300607 Compound R.T. Q ion Area Cone Units 2,6-Di n i trotoluene Acenaphthylene 3-NitroaniIine Acenaphthene 2,4-Di n i t rophenoI Dibenzofuran 4-Ni t rophenoI 2,4-DlnitrotoIuene 2,3,4,6-Tet rachIorophenoI Di ethyIphthaI ate 4-ChIoropheny1-phenyI ether Fluorene 4-Ni t roan iIine 2,4,6-Tr ibromophenoI •IS#4 Phenanthrene-dlO 1,2-Di phenylhydrazine 4,6-D i n i t ro-2-me thylphenol Diphenylamine 4-Br omophenyl-phenylether HexachIorobenzene PentachIoropheno I CarbazoIe Phenanthrene An t hracene Fluoranthene Di-n-butylphthalate «IS#6 Chrysene-d12 Pyrene Te r phenyI-d 14 Butylbenzylphthalate 3,3'-Dichlorobenzidine Benzo(a)anlhracene b i s(2-EthyIhexyl)phthalate Chrysene •!S#6 Perylene-d12 Di-n-octylphthalate Benzo(b)fluoranthene Benzo(k)fluoranthene Benzo(a)pyr ene lndeno( 1,2,3-cd)pyrene Dibenz(a,h)anthracene Benzo(g,h,i)perylene 16 16. 16 16. 16. 17. 17 17. 17 17. 17 17. 17 18 19 18 17 17 18 18 19 19 19 19 21 20 24 22 22 23 24 24 24 24 28 25 26 27 27 32 32 33 49 59 78 91 95 19 00 21 47 56 74 82 91 29 53 04 96 97 .63 97 ,27 92 .58- ,66. .76> 44 .42 20- .34 16 .24 .37- . 10 .48- . 13 .33 .96. .03- .96 ,26 ,22- .53 165.0 152. 1 138.0 153. 1 184. 1 168. 1 109.0 165. 1 232.0 149. 1 204. 1 166. 1 138.0 329.6 188.2 77.0 198.0 169. 1 248.0 283.8 265.9 167.0 178. 1 '178. 1 202.0 149.0 240,2 202.0 244.2 149. 1 .262,2 228.0 149.0 228,0 264,2 149.0 252,2 252,2 '252,0 •276.2 278. 1 '276,0 41458 233834 46347 143835 2294 IM 191413 22698 50799 47181 182551 70800 139695 40089 29751 59552 225817 30715 96305 43448 57535 35613 178282 198728 201067 211129 296237 54479 216388 138619 129079 66496 176982 180280 162700 5789 1 280346 191956 155023 160536 187123 149471 157789 64.62 62.43 62.88 63.36 78.29 62.51 62.74 62.61 61.95 59. 11 62.66 61.64 57.35 64.40 20.00 60.93 74.68 63.94 62.85 62.00 68.32 62,01 62.73 63,43 64. 11 61,05 20,00 62.97 67.68 63.63 64.57 59.63 62.20 58.83 20.00 61.4 1 64.01 58.80 61.64 63,60 66.57 63,82 ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb 97 98 95 95 97 75 89 90 92 91 97 95 79 91 65 96 94 96 97 97 97 96 98 96 98 97 97 98 91 98 96 88 98 89 98 96 96 93 92 88 82 • Compound i s ISTD OraL'$.'^J S'Mbfecf Tr? Vbrr^-xf, 300608 TOTAL ION CHROnftTOSRftn File >H033E 35.0-510.0 «k>u. 6ST016e TIC 700000- 600000- 500000- 400000- 3e0oet>- 203eec'- 1O0O0CH 0- E90-12-SVeO '• see leoo isee seeo sseo seee ' • ' • • • ' ' ' • • • ' • • • • ' ' • • • ' • • • • ' - - • • ' • • • • ' • • • • ' • • • ' ' • - • • ' • • • ' ' • • - • ' • ' t- y Data File: >H033E Name: SSTD160 Misc: 290-12-SV80 Dl Quant Output File: •H033E::BQ INST H BTL# 5 Id File: ID_SH::DB Title: SEMIVOLATILES BY SW846-8270/EPA 625 Last Calibration: 950202 10:33 Opera tor ID: DAVID Ouant Time: 950202 12:42 injected at: 950202 12:06 or^ .i.-*ijr 300609 "'-f-? ^1,%-,',.r.,-lT.. \ /-. Jf,»_ QUANT REPORT Operator ID: DAVID Output Fi le: '*H033Ei la File: >H033E: ime: SSTD160 Misc: 290-12-SV80 Quant Rev: 6 BQ iDI Quant Time: Injected at: Dilut i on Factor: INST H 950202 12:42 950202 12:06 1.00000 BTL# 5 ID File: ID_SH::DB Title: SEMIVOLATILES BY SW846-8270/EPA 625 Last Calibration: 950202 10:33 Compound R.T. O ion Area Cone Uni ts 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 43) • IS«1 1,4-DichI orobenzene-d4 Pyr i d i ne N-N i trosodimethylamine Phenol-d5 2-ChIorophenol-d4 2-FIuor ophenoI An iIi ne Pheno I 2-Chlorophenol bi s(2-ChloroethyI)ether 1,3-D ichlorobenzene 1,4-Dichlorobenzene 1,2-D ichlorobenzene-d4 1,2-Di chlorobenzene Benzyl a I cohoI 2,2'Oxybis-(1-chloropropane) 2-Methy IphenoI N-N i troso-di-n-propylamine Hexachloroethane 4-Me thylphenol «IS#2 Naphthalene-dB N i t robenzene-d5 Ni t robenzene 1 sophorone 2-N i trophenol • 2,4-Dimethylphenol b i s(2-Chloroethoxy)methane 2 ,4-Di ch1 or ophenoI Benzoic acid 1,2,4-Tr ichlorobenzene Naph thalene 4-ChI or oan i I ine Hexachlorobutadiene 4-Chloro-3-methyIphenol 2-MethyInaphthalene •IS#3 Acenaphthene-dIO Hexachlorocyclopentadiene 2,4,6-Tr ichlorophenol 2,4,5-Tr ichlorophenol 2-Fluorobiphenyl 2-Chloronaphthalene 2-N i t r oan i I ine Dimethylphthalate 1 1 . 4 2 ' 6 . 9 5 6 . 9 9 1 0 . 8 3 1 1 . 10 9 . 3 4 1 0 . 9 3 1 0 . 8 5 1 1 . 12 1 0 . 9 9 1 1 . 3 6 - 1 1 . 4 4 . 1 1 . 7 5 . 1 1 . 7 8 • 1 1 . 6 7 - 1 1 , 8 9 1 1 . 8 4 . 12. 15 1 2 . 3 0 1 2 , 0 8 ' 1 3 , 6 6 1 2 . 4 3 1 2 . 4 6 12.84 1 3 . 0 1 1 3 . 0 0 13. 17 1 3 . 4 1 1 3 . 2 2 . 1 3 . 5 7 1 3 , 7 0 1 3 , 8 0 1 3 . 9 6 1 4 . 6 9 1 4 , 9 2 1 6 . 8 5 1 5 , 2 9 1 5 , 4 5 . 1 5 . 5 ? , 15.57 1 5 . 8 1 1 6 . 0 3 16.32 1 5 2 . 0 7 9 . 1 7 4 . 0 9 9 . 0 1 3 2 . 0 1 1 2 . 0 9 3 . 0 9 4 . 0 1 2 8 . 0 9 3 . 0 1 4 6 . 0 1 4 6 . 0 1 5 2 , 0 1 4 6 . 0 108. 1 4 4 . 9 1 0 8 . 0 7 0 . 0 1 1 7 . 0 1 0 8 , 0 136. 1 8 2 . 0 7 7 , 0 8 2 . 2 1 3 9 . 0 ' 1 0 7 . 0 9 3 . 1 1 6 2 . 0 ' 1 2 2 . 0 17 9 . 9 128. 1 1 2 7 , 0 2 2 4 . 8 1 0 7 , 0 142, 1 1 6 4 , 2 2 3 6 . 8 ' 1 9 6 . 0 196.0 172. 1 1 6 2 , 0 6 5 . 0 163. 1 28143 125166 70575 157283 128429 119155 2 1 5 0 9 1 166309 128051 140032 134214 137878 85232 124256 76894 141748 103956 90584 6 0 3 9 1 114007 91933 153461 143973 281703 6 4 3 0 1 98483 171264 95373 71355 101209 312518 141987 58767 102377 186664 4 6 5 9 6 64535 65813 72543 212188 183554 70617 230067 2 0 . 0 0 1 0 0 . 8 8 8 1 . 15 7 4 . 3 3 7 6 . 17 7 4 , 19 6 9 . 2 8 7 3 . 4 6 7 4 . 9 7 6 7 . 8 8 6 9 , 9 1 7 1 . 10 7 8 , 5 8 6 9 . 5 0 7 3 . 5 1 7 1 . 4 5 6 6 . 0 4 6 8 . 8 6 7 2 . 5 8 6 9 . 0 3 2 0 . 0 0 8 7 , 0 8 7 9 . 3 9 7 7 . 7 1 . 8 4 , 19 7 4 , 9 4 7 6 , 8 0 8 1 . 8 1 9 1 . 0 9 7 6 - 5 3 7 4 . 8 8 7 5 . 5 4 7 3 . 17 7 7 . 6 9 7 3 , 8 8 2 0 . 0 0 9 6 , 2 9 8 2 . 6 0 8 0 , 7 0 8 2 . 7 8 7 4 , 7 7 7 7 . 6 1 7 5 . 2 2 ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb 96 93 97 86 9 1 77 97 58 89 95 96 93 97 95 92 97 93 79 92 97 98 84 . 91 99 94 89 92 85 95 96 99 93 98 68 95 97 94 92 96 97 94 72 95 0T2.'i.*i5 ubject so Validatior; 300610 Compound R.T. Q ion Area Cone Units 2,6-Dini trotoluene Acenaphthylene 3-Nitroaniline Acenaphthene 2,4-Dinitrophenol Dibenzofuran 4-Ni trophenol 2,4-Din i t rotoluene 2,3,4,6-Tet rachIorophenoI OiethyIphthalate 4-Chlorophenyi-phenylether FIuorene 4-Ni t roan iIi ne 2,4,6-Tr i bromophenoI •IS«4 Phenanthrene-dlO 1,2-DiphenyIhydraz i ne 4,6-Di n i t ro-2-methyIphenol D i phenyI ami ne 4-Bromopheny1-phenyI ether HexachI orobenzene PentachIorophenoI CarbazoIe P h e n a n t h r e; n e Anthracene F itior an t hene D i - n - b u t y l p h t h a l a t e • I S # 5 C h r y s e n e - d 1 2 P y r e n e T e r p h e n y l - d 14 B u t y l b e n z y l p h t h a l a t e 3 , 3 ' - D i c h l o r o b e n z idine B e n z o ( a ) a n t h r a c e n e b i s ( 2 - E t h y l h e x y l ) p h t h a late Ch r y s e n e • I S « 6 P e r y l e n e - d 1 2 D i - n - o c t y I p h tha I a t e B e n z o ( b ) f l u o r a n t h e n e 6 e n z o ( K ) f l u o r a n t h e n e B e n z o ( a ) p y r e n e l n d e n o ( 1 , 2 , 3 - e d ) p y r e n e D i b e n z ( a , h ) a n t h r a c e n e B(fnzo(g,h, i ) p e r y l e n e 16.60 16.69 16.78 16.92 16.95 17. 19 17.01 17.22 17.47 17.67 17.75 17.83 17.92 18.30 19.54 18.05 17.97 17.99 18.64 18.98 19.28 19.93 19,59- 19,67- 21.77 20.44 24.43 22.20- 22.35 23. 17 24.26 24.39- 24. 12 24.4 9.- 28. 15 25.35 26.99 165.0 162. 1 138.0 163. 1 184. 1 168. 1 109.0 165. 1 232.0 149. 1 204. 1 166. 1 138.0 329.6 188.2 77.0 198.0 169. 1 248.0 283.8 265.9 167.0 178. 1 178. 1 •202.0 149.0 240.2 202,0 244.2 149. 1 252.2 228.0 149,0 228,0 264.2 149.0 '252.2 27.06'252.2 28.01 32.34' 32.29' '252.0 276.2 278. 1 33.62''276.0 62805 29 1343 64 199 180251 31851M 240450 30134 65093 59575 229746 86981 176160 52195 37250 68598 282808 37203 119233 54436 72109 47106 220687 247359 249656 267712 384807 664 14 275460 175632 165343 83947 232012 237738 209625 57796 370470 242948 207562 210557 239136 191497 200209M 76. 13 71.95 80.67 73.44 100.64 72.64 77.04 74.20 72.36 68.81 71.20 71.89 69.06 74.68 20.00 77.55 91.93 80,45 80.03 78.97 91.84 78.00 79.35 80.04 82,62 80,60 20,00 77.41 82.69 78.71 78.72 75,36 79,22 73.20 20,00 81,29 81, 15 78,86 80.96 81,41 85,43 81,11 ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb Ppt> PPt> ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb 93 98 84 96 94 77 89 84 91 87 98 98 91 94 88 93 96 93 96 99 97 98 99 95 98 96 94 97 98 98 94 89 95 96 • 9 7 99 98 95 94 86 « Compound is ISTD 300611 Data Subied.To Vslidatior TOTAL ION CHROHATOGRAM £40000- 200000- leooac' 120000- 80000- 4C'C-0iN Filt >H033F 35.e-5ie.e M U . SSTDOSO £9e-i£-svie TIC 500 1000 1500 2000 '2500 3000 • • • • ' • - ' • ' • ' * • ' • • • • ' - - • • ' • • • • ' • • • • ' • - - • ' - • • • ' - • • • ' • • • • ' • ' • • ' • • • • ' • ' 32000&^ B80000- . I I I r-J I I 9> e 1 I.! . ' • • - • • I Ji " » % u. I I 6 ? in I ~£ s •c 1 I le 20 T - £4 .Ll ^LL T •H033F::D1 Name: SSTD020 Misc: 290-12-SVlO Ouant Output File INST H •H033F::BO BTL# 6 Id File: ID_SH::DB Title: SEMIVOLATILES BY SW846-8270/EPA 625 Last Calibration: 950202 10:33 Operator ID: DAVID Quant Time: 950202 13:28 Injected at: 950202 12:62 D^^*?.«=i5 uoJi^pii^A Oi P9[cinS^s_£0- 3 0 0 6 1 2 QUANT REPORT Operator ID: DAVID Output Fi le: "H033F::BO ta Fi ie: >H033F::D1 ime: SSTD020 Misc: 290-12-SVlO Quant Rev: 6 Quant Time In jected at: Oi lut ion Factor INST H 950202 13:28 950202 12:52 1.00000 BTL# 6 ID File: ID_SH::DB Title: SEMIVOLATILES BY SW846-8270/EPA Last Calibration: 950202 10:33 625 Compound R.T. 0 ion Area Cone Un i ts 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 36 39 40 •IS#1 1,4-DichIorobenzene-d4 Pyr idine N-Ni trosodimethylamine Phenol-d5 2-ChIorophenol-d4 2-FIuorophenoI An iIi ne PhenoI 2-ChIorophenoI b i s(2-ChIoroethyI)elher 1, 3-D ichIorobenzene 1,4-Di chlorobenzene 1,2-D ichlorobenzene-d4 1,2-D ichlorobenzene BenzyI a I cohoI 2,2'Oxybis-(1-chloropropane) 2-Me thylphenol N-N itroso-di-n-propylamine HexachI 0 r oe t hane 4-Met hyIphenoI • IS<»2 Naphthalene-d8 N i t robenzene-d5 N i t robenzene Isophorone 2-Ni t ropheno I 2,4-D imethylphenol bis(2-Chloroethoxy)me thane 2,4-Dichlorophenol Benzoicacid 1,2,4-Trichlorobenzene Naphtha Iene 4-ChI oroan i I ine Hexachlorobutadiene 4-ChI oro-3-met hyIphenoI 2-Methylnaphthalene •IS#3 Acenaphthene-dIO Hexachlorocyclopentadiene 2,4,6-Tr ichlorophenol 2,4,6-Tr ichlorophenol 2-FIuorob i phenyI 2-Chloronaphthalene 2-N i t roan i I ine Dimethylphthalate 1 1 . 4 2 ' 1 5 2 . 0 6 . 9 8 7 9 . 1 6 . 9 9 7 4 . 0 1 0 . 8 2 9 9 . 0 1 1 . 1 0 1 3 2 . 0 9 . 3 6 1 1 2 . 0 1 0 . 9 3 / 9 3 . 0 1 0 . 8 4 ^ 9 4 . 0 1 1 . 1 3 1 2 8 . 0 1 0 . 9 8 ^ 9 3 . 0 1 1 . 3 7 / 1 4 6 . 0 1 1 , 4 6 / 1 4 6 . 0 1 1 . 7 6 / 1 5 2 . 0 1 1 . 7 8 / 1 4 6 . 0 1 1 , 6 5 ^ 1 0 8 . 1 1 1 . 8 9 4 4 . 9 1 1 . 8 3 ^ 1 0 8 . 0 1 2 . 1 4 7 0 , 0 1 2 , 3 2 1 1 7 . 0 1 2 , 0 7 / 1 0 8 , 0 1 3 . 6 7 1 3 6 . 1 1 2 . 4 2 8 2 . 0 1 2 . 4 5 7 7 . 0 1 2 . 8 2 8 2 . 2 1 3 , 0 0 1 3 9 . 0 1 3 . 0 0 - 1 0 7 . 0 1 3 . 1 6 9 3 , 1 1 3 , 4 0 1 6 2 . 0 1 3 , 1 0 ^ 1 2 2 . 0 13.57 1 7 9 , 9 1 3 , 7 0 128, 1 1 3 . 7 9 1 2 7 . 0 1 3 . 9 7 2 2 4 , 8 1 4 . 5 9 1 0 7 . 0 1 4 . 9 1 142. 1 1 6 . 8 5 1 6 4 . 2 1 5 . 2 9 2 3 6 . 8 1 5 . 4 5 ^ 1 9 6 . 0 1 5 . 5 2 / 1 9 6 . 0 1 5 . 5 6 1 7 2 . 1 1 5 . 8 0 1 6 2 . 0 1 6 . 0 2 6 6 . 0 1 6 . 3 1 163. 1 26756 11911 8459 19577 16505 15280 39277 23376 172 17 19879 18255 18968 12155 18 19 1 10117 19454 15261 13183 8417 15248 99742 20273 20956 39370 8639 13288 25963 13405 6842 15779 46914 2 1344 8257 14176 30129 4 6 4 3 6 6073 9543 10511 32959 26824 10644 35354 2 0 . 0 0 10. 10 1 0 . 2 3 9 . 7 3 1 0 , 3 0 1 0 . 0 1 1 3 , 3 1 1 0 . 8 6 1 0 . 6 0 10. 14 1 0 . 0 0 1 0 . 2 9 1 1 . 7 9 1 0 . 7 0 10. 17 1 0 , 3 1 10,20 10.64 10,64 9 , 7 1 2 0 . 0 0 1 0 . 6 0 . 1 0 . 6 5 1 0 , 0 1 1 0 . 4 2 9 . 3 2 1 0 . 7 3 1 0 . 6 0 8 . 0 5 1 1 , 0 0 1 0 , 3 6 1 0 . 4 7 9 . 4 8 3 . 9 0 1 0 . 9 9 2 0 . 0 0 8 . 9 0 1 1 . 7 6 1 1 . 4 8 1 2 . 6 3 1 0 . 7 3 1 1 . 4 9 1 1 . 3 5 ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb 96 97 97 91 81 78 99 63 85 96 95 97 94 93 95 98 92 74 86 97 99 80 96 • 95 81 86 95 86 90 98 99 95 93 84 92 92 94 85 88 97 93 57 91 Data Subiect To Validation 300613 Compound R.T. Q ion Area Cone Units 2,6-Di n i t rotoluene Acenaphthylene 3-Ni troaniIine Acenaphthene 2,4-Dinitrophenol Dibenzofuran 4-Ni trophenol 2,4-Di n i t rotoluene 2,3,4,6-TetrachIorophenoI Diethylphthalate 4-Chlorophenyi-phenylether F I uorene 4-N i t roan i Ii ne 2,4,6-T r i b r omo phenol • I S#4 Phenanthrene-d 10 1,2-Di phenylhydrazine 4,6-D i n i t ro-2-methyI phenol DiphenyI ami ne 4-Br omophenyl-phenylether HexachIorobenzene PentachIorophenoI Carbazole Phenanthrene An t hracene Fluoranthene Di-n-butylphthalate •IS#5 Chrysene-d12 Pyrene Ter pheny1-d14 Butylbenzylphthalate 3,3'-Dichlorobenzidine Benzo(a)anthracene bi s(2-Ethy Ihexyl )phthalate Chrysene •IS«6 Perylene-d12 Di-n-octylphlha late Benzo(b ) f I uoranthene Benzo(K)fIuoranthene Benzo(a )pyr ene lndeno( 1,2,3-cd)pyrene Dibenz(a,h)anthracene Benzo(g,h,i)pery I ene 16.49 16.68 16.76 16.91 16.84 17. 19 16.99 17.20 17.46 17.66 17.75 17.82 17.88 18.29 19.54 18.04 17.94 17.96 18.63 18,97 19.27 19.92 19.58- 19,66< 21,76< 20,43 24,41 22. 19 22.34 23, 16 24,24 24,37< 24. 10 24.47 28. 13 25.33 26.94 27.00 27.95 32,21 32, 16' 33,48' 165.0 152.1 138.0 153. 1 164. 1 168. 1 109.0 165. 1 232.0 149. 1 204. 1 166. 1 138.0 329.6 188.2 77.0 198.0 169. 1 248.0 283.8 265.9 167.0 178. 1 ' 178. 1 '202.0 149.0 240,2 '202,0 244.2 149, 1 262.2 '228,0 149,0 r228.0 264,2 149.0 '252.2 '252.2 '252,0 -276.2 278, 1 276,0 7763 46104 8674 30171 2665M 37503 3569 9723M 9236 37465 13929 29175 8156 5442 71463 52630 4599 19867 8536 11435 5274 39613 41782 41897 44950 6084 1 68665 44239 30267 27023 13950 38054 37346 36787 74857 60441 38873 34810 33362 38975 29280 33329 10.98 11. 18 10.69 12.07 8.26 11. 12 6.96 10.88 11.01 11.02 11.20 11.69 10.60 10.70 20.00 11.83 9,32 10,99 10.29 10.27 8.43 11.48 10.99 11.01 11.37 10.45 20.00 10.23 11.72 10,58 10.76 10. 17 10.24 10.57 20.00 10.24 10.03 10,21 9,91 10,24 10,09 10,42 ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb PP-b ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb PPb ppb ppb ppb ppb ppb 84 93 87 96 95 76 85 89 66 91 93 82 90 83 92 96 95 90 94 96 97 98 97 98 99 96 98 93 94 92 88 98 94 • 97 97 95 94 92 94 78 •• Compound is ISTD o^^ .a-*^ 300614 Dsta Subject To Validation Initial Catlbratlen Data «Sl C u t io: Cantraetort PACt Fcontraet Me: Inatnamt let 9968-1 Calfbratlen »«tot 02/02/95 Mintaia IF fer SPCC Is 0.05 Maxfaua S K » fer CCC It SOX laboratory IDt HUSSF PUOO* i Cci^emd fyridint H-MttrModfHthylwtnt Mianol-d5 2-Chlereph«nol-d« 2-Fluorophanol Anllirw Manol 2-Chlorophinol feU(2-C»ilero*thyl)ithir 1,3-0ichlorobtnzene 1 >-D (ehlorobenztnc 1.2-0iehlorobenztr»-cK 1,2-D{chlorobtratr« ienzyt eleohol 2,2'Oxybis-(1-chloropropane) KrNethylphtnol R-Nitre(o-di-n*propylaa<ne MMachlerocthan* 4-M«thylphtnot Mftrcb«nzor»-(S Nitrobwtttne Isophorone 2-II itrophenol 2.«-DlMthylphenol bls(2-Chloroethoxy)BethBne 2,4-Dichlorophenol •enxole ectd 1,2,4-Trichlorobcnzene Maphthalene 4*ChloroanU{ne Mcxachlorobutedttne 4-Chtoro-3-Mthylphenol IF IF HRIS3C HRI33D 1 IF 10.00 yiS.00 >40.00/' IF '60.00 . ^80332 IF . 4 ^ . 0 0 / ^ 'Tr .89034 .88174 1.10756 1.08039 1.11188 1.01438 .«S2S1 .81805 .72231 .71558 .62693 .66304 1.4£337 1.50369 1.58668 1.49524 1.S9718 1.48923 1.23374 1.19824 1.23037 1 I.194U 1.14086 : 1.19953 1.14217 1.14132 1.16429 1.13856 1.05848 1.12896 2.93594 2.20628 2.13164 2.03674 1.91070 2.24426 1.74735 1.60881 1.66912 1.60195 1.47736 1.62092 1.28696 1.21385 1.24351 1.18222 1.13750 1.21281 1.48595 1.46605 1.41248 1.35618 1.24393 1.39292 1.36455 1.36438 1.37409 1.26123 1.19225 1.31130 1.41785 1.37815 1.37658 1.31051 1.22480 1.34158 .90858 .77080 .82439 .78472 .75713 .80913 1.35977 1.27057 1.26014 1.19672 1.10579 1.23820 .75624 .74342 .75635 .74984, r .68307 .73778 1.45418 1.40985 1.39169 1.33972 1.25918 1.37092 1.14075 1.11860 1.07385 1.02263 .98542 .62917 .93464 .59128 .92235 .59770 .91334 .58487 1.13978 1.17377 1.12252 1.09551 .40651 .42020 .789U .17323 .26645 .52060 .26879 .13719 .31640 .94071 .42798 .16557 .28425 .38340 .39452 .78858 .16616 .28588 .48516 .25360 .17042 .28771 .90793 .40889 .17472 .28704 .43098 .41808 .82363 .18094 .27774 .51833 .27U7 .18715 .30768 .92960 .43047 .17792 .29959 .41690 .41711 .83381 .17198 .27088 .49861 .26816 .19318 .28709 .88894 .41437 .16972 .28665 .92345 1;05586 .80468 .53647 XMD CCC SPCC 11.615 7.744 4.614 3.117 S.608 17.919 6.125 4.709 6.991 6.181 5.650 7.541 7.672 4.209 5.451 8.216 .91209^^ 7.258 .58790 1.01275 1.10887 .41732 .39152 .76606 .17486 .26781 .46573 .25935 .19404 .27522 .84985 .38612 .15981 .27840 .41102 .40829 .80030 .17343 .27375 .49769 .26488 .17640 .29482 .90341 .41357 .16955 .28719 5.683 5.480 4.311 3.435 3.476 3.070 2.945 * 4.637 3.134 13.538 5.689 3.982 4.308 4.249 2.696 y y . / •« • y - y /y IF IF »S0 €r lespense Fector (Siiscript ft anount in PPB) Average lesponse Factor Percent Relative Standard Deviation Calibration Check Conpouids (*} SPCC - Systea Perfomnce Check Conpoinds (**) For* VI Page 1 o f 3 3 0 0 6 1 5 • ' - - - ^ - ' ^ c c r To Validstion Initial Callbratten Data •SL ^ ^ B o n i Me: tantraetert M C E itraet Mot Imtnaant IDt S988-I Calibration Datet 02/02/95 Mfnlwa IF fer SPCC It 0.05 Ntxiwi S ISO fer CCC It SOX Laboratory IDt »IQ33F Hn338 HKBSC MRI330 HKI33E Ceapound 2>Methylnaphthal«ne Mtxachterocyclopontadian* 2.4.6-Triehlerephenol 2,4.5-1richlerephtnol 2-Fluorobiphanyl 2*Chlerenaphthalane 2-Hitroaniline DiMthylphthalate 2,6-Dinitreteluene Acanaphthylone S-litroMiline Acenaph thane 2.4'Dinitrophenol Dibenzofuran 4-lli trophenol ^H|,4,6-Tetrachlerophenol ^ffethylphthalate 4-Chlorophenyl-phenylether fluorene 4-Nitroaniline 2,4.6-TribraBophenol 1,2-Diphenylhydra2ine •4,6-Dlnitro-2-«»thylphenol Diphenylamine 4-8ro«ophenyl-phenylether MexachIorobenzene Pcntadilerophenol Carbazole Phenanthrene Anthracene Fluoranthene IF IF IF IF IF - ^ 10.00 25.00 40.00 M.OO 80.00 IF .60414 .54967 .57038 .S3285 .50761 .55293 .26156 .29397 .34995 37419 .35384 .32670 • .41102 .34949 .39151 .40062 .36085 .38270 .45271 .39430 .41526 .42413 .39775 .41683 1.41955 1.12438 1.30556 1.28147 1.16341 1.25887 1.15531 1.07683 1.09938 1.10943 1.00642 1.08947 .458a .39911 .45a2 .a595 .38719 .42902 1.52270 1.34166 1.41901 1.39481 1.261U 1.38792 .S3392 .30423 .32745 .32767 .28953 J1656 1.98570 1.77620 1.81632 1.84812 1.59742 1.80475 .37359 .34952 .36719 .36631 .35200 .36172 1.29947 1.07658 1.14498 1.13681 .98830 1.12923 XISD CCC SPCC 4.642 '^.395 4.890 S.645 9.374 S.004 7.767 4.959 s.9a 7.765 2.884 10.089 .11478 .13895 .17173 .18132 .17464 .15628^8.168 1.61526 1.45202 1.54769 1.51285 1.31837 1.48924 7.540 .15372 .17157 .18309 .17940 .16522 .17060/^6.862 .39779 .36116 .39375 .37290 .32665 .37045 1.61362 1.46459 1.54322 1.U281 1.25968 1.46478 .59992 .53588 .55664 .55957 .47691 .54579 1.25657 1.07480 1.15848 1.10409 .96587 1.11196 .35128 .33149 .33377 .31685 .28618 .32391 .23439 .21908 .24028 .23514 .20424 .22662 1.47293 1.24464 1.35692 1.26398-1.20656 1.30901 .12871 .13813 .15644 .17192 .15872 .15078 .55601 .50584 .53245 .53905 .50869 .52841 .23895 .23215 .25178 .24319 .23224 .23966 .32003 .31164 .30994 .32204 .30764 .31426 .14760 .17506 .19685 .19934 .20097 .18396 1.10863 .96563 1.01090 .99791 .94153 1.00492 1.16933 1.06399 1.10525 1.11235 1.05532 1.10125 1.17255 1.06465 1.12453 1.12544 1.06512 1.11046 1.25799 1.10599 1.17964 1.18176 1.14215 1.17351 6.143 7.755 9.086 8.235 9.629 7.526 6.534 8.177 11.435 4.003 3.436 2.032 12.435 6.372 4.129 4.135 4.818 • • » y . ^ • • * • _^ • • ^ . ^ y * IF • Ictponae factor (Subscript is BReunt in PPB) IF • Average lespense Factor XRSD • Percent lelative Standard Deviation ^ Fora VI Data 5.biectToV.V>da«oa Initial Calibration Oata Met jCentraeteri MCE ract Met ^ ^ c n t i ^ ^ o n t i InatruMDt IDt toes-M Calibration Dattt 02/02/95 HInlauB IF fer SPCC It 0.05 NaxlauB S ISO fer CCC It SOX laberatery IDt M033F >N0S38 M033C HROSD HBSX Coipouid Di-n-butylphthalate farphenyl-d14 •utylbenzylphtha late 3.3'-Dichlorobenzidine fenzo(a)anthracane bia(2-Ethylhtxyl)phthaltte Chrysene Di-n-eetylphthaltte •enzo(b)fluoranthene ienzo(k)fluoranthene •enzo(a)pyrane IndenoC 1,2,S-cd)pyrerw Dibenz(a,h)anthraeene «enzo(s,h,l)perylene IF IF IF IF IF __ 10.00 8.00 40.00 40.00 tO.OO IF 1.70273 1.62955 1.73446 1.65814 1.64172 1.67332 1.29043 1.26156 1.32112 1.32398 1.22071 1.28356 .88287 .75300 .83221 .84815 .77832 .81891 .78824 .7U72 .77562 .78978 .73272 .76622 .40691 .S7B04 .40117 .40686 .37201 .39300 1.11001 1.09150 1.11854 1.08288 1.02817 1.08622 1.08936 1.06398 1.11859 1.10306 1.05354 1.08571 1.07305 1.01526 1.04463 .99549 .92896 1.01148 1.61484 1.57713 1.69542 1.61422 1.60249 1.62082 1.03859 1.03599 1.04081 1.10527 1.05089 1.05431 .93004 .91082 1.00130 .89261 .89782 .92652 .89135 .89973 .92049 .92436 .91078 .90934 1.04132 1.01647 1.06422 1.077a 1.03a0 1.04677 .78229 .77565 .82655 .86065 .82833 .81469 .89047 .85417 .88317 .90854 .86602 .88047 SUO CCC SPCC 2.630 S.S79 4.437 S.399 4.251 S.261 2.481 S.408 2.740 2.755 4.773 1.524 2.314 4.345 2.407 . / . y IF IF »S0 • ^ Ittponse Factor (Subscript Is anotnt In PPB) Average lespense Factor Percent Relative Standard Deviation r Calibration Check Coeyowds (*} SPCC - SystM Perforsiance Check Coapounds (**} Form VI 300617 Data Subject To Validation vx s*t a fsvjeet s.o. (eXiMVaae/eat) •taa«ai« Sato Sevaiaitita SCJBaafliUfina •Y •«ai-«atotU««i «?y«-j8-aBQ.,a». Snjeetar S«3 -JO" « o.»*-« ^ fir, T l i r r r ^ W M f « i . J C S « • O d a t Mad « B l ^ * i . . . ^£!^2^** 'rswiyifY' Beaaai • c y r o f n a •«»-«aiiaa«« OsodiUoM i _ r M a i a t M a M a / v n U a M t ~ = » w » a r t a r P U a a t , « r i f U a l Data P U M Witht"*^ * y * * * ^ SteaUCioatlaaa • aailw TareataI •>*>c»- .t- tx»c -.^ eo ^ Btai • I t l '>.So-en-«>>JJi—o a«>»-oH' f eAF S^n (»aff« t ) i • a t l a t t i a a af ttatka/OoHHaU e e i a n a« . . . . . . . . . . A a X y s l a ' p a a a M d aXl e r i t a r l a ..w * »ot at>plleabla * - « * • n aaapla M t r i x a f f a e t (alae i M i e a t a oc g p . . . . . . . . . e a r r y - w r • » e e n t a a l n a t l e n Ti«n*rit.ri • * •itc««ralo«»a, Cor axaapla, ZtS*. a t a * . a t e . l «vi«ai...«u«uoB »va»Sv«wS3 SJSr^ S J::SH!2H!S-**««^ ' ' ' •"•' n v a a v a l . . . t M a u o t a / a w w a e t a a Saival w ^ w ^ w w r - r r - r-.»_P^.«^_P_iL.P-_PL_lL^» « rite/KM uantwuuff enourzoBs itfatmr yat 1 ( ^ I wur of tba «ay Data t t - W S ?erf, t t d . • 13 h r a . ana-TOXArzist O i OM > r a runa within t i a a l U l t a T S t t ' ^ n ) (If AO, e l t s l a e u t l i a r * ) TZXB ^•>S *iK 5.^il. vovi i^iUt. p.:0^ n-.y^ iS\-u i^Oe lfc:'5 n;cx HJti. (6:35 «::.) •5j:0t or n u zs • ^ : t l t v j g [•^tn 212L •21S>i gO:Mo ^Lii. WC31C.-: Ol M033A.:0| UCllB.-'oi •4©-jio .•; o I MClIt"..' Ol MOOTf .••Pl Htfyfr"P' Hf?3^<--P' " g ^ T . - . Q l ^C-J^J'-'O UC33K.-.-0I ucnu.-.-Qt ue'iOm::Di UQ33)J.--0i WC330:;p( M C T 3 P : : D ( SJ^IRIJO-) fegrl »fn'3c>::0l fiwi^t ^ 7 0075-3 e u n r le tdli) to.<^ c m f ' 3 < T & C » 9 * »»Tp cecc »»rD I X P 8?T 'fr*^ .7fTT » t « » S o .it. OgTR/ay =^ynat>sPt^ s»A/<?Lg>iins s-M-fftf »J swf^u&inti 5-M-mP H033S.':OI 2iJ^[iisfiH-__-£!IL5J_ HD33T.-:Pi HC3?U"-Pl UC33W-0> MCI3X-:DI ue33y.--0| iAC3:37t.D\ JS^TtLSi) &-H SvV^LSiS e)«^-J l i q U u J & T fetftLrt<, SvVgLaatf m-5 aA/gLeP~7 S-3 SWfUSft E/^m-i iiic73**'f'- '5v/v(?i-cpe m-& aS^ .TOI i i q i i v o goseoJ ew n'ln ITOLT FACT I . e . xx XT aim xsc BXATVS •01/ OOnCDTS zr y y y * .^ y y -7 rw.rrt.jy^gij-.T 9 i n ± 'ZZ^^^^k'-^" r a t y y ZP -P -y % CttJ Au<( T» .c) ejtli'i £j&uJZLZL •^D^aSbjectleValidafK 300618 FKGR : TUNER.-DFTPP ^V GC/MS PERFORMANCE STANDARD Decafluorotriphenylphosphine (DFTPP) m/z Ion Abundemce Criteria % Relative Abundemce Base Appropriate Peak PeaX Status 51 30-60% of mass 198 68 Less than 2% of mass 69 69 (reference only) 70 Less than 2% of mass 69 127 40-60% of mass 198 197 Less than 1% of mass 198 198 Base peak, 100% relative abundance 199 5-9% of mass 198 275 10-30% of mass 198 365 Greater than 1% of mass 198 441 0-100% of mass 443 442 Greater than 40% of mass 198 443 17-23% of mass 442 Injection Date: 02/23/95 Injection Tine: 12:16 Data File: >H054A Scan: 376 35.73 0.00 57.54 0.00 43.32 0.00 100.00 7.19 21.50 2.07 8.85 58.46 10.07 35.73 0.00 57.54 0.00 43.32 0.00 100.00 7.19 21.50 2.07 87.83 58.46 17.23 Ok Ok Ok Ok Ok Ok Ok Ok Ok Ok Ok Ok Ok 3 00619 Data Subject To Validction 69 Fil« >He54A Seny SFTPP Bpk Ab 100. llOn • 100: 90: 80: 70: 60: 5»: 40-i 20^ 10^ 0 = / t 50 M 127 kx ^ 290-14-Pi3{F SUB NRM 198 186 \ lOO ISO 200 2 5 0 255 S 275 H4 . / . » I- K: % 296 3 2 3 Scan 376 7 . 1 9 Min. I l i o iioo i90 ieo i70 J60 ^50 ^ =40 530 n20 -10 442 NE Y / 3 " 483 : 111 'r I 111 1*1 I ^ I I r 111 i'l 1111 I 'I 11 r)i 11 r O 300 3 5 0 400 Data Fileneune: >H054A::D1 Name: 50ng DFTPP Misc: 290-14-PERF INST H BTL/ 1 Operator ID: DAVID Analysis Date/Time SUPER GRP. 2/23/95 12:16 300620 Data Analysis Date/Time: 2/23/95 12:16 Data Filename and Seunple ID: >H054A song DFTPP 290-14-PERF IN ST 376 SUB NRM File: >H054A Scan #: 376 Retn. time: 7.19 m/z Int. m/z Int. m/z Int. m/z Int. m/z Int. 36.55 .212 98.00 2.314 153.00 .479 201.65 .452 257.00 .806 37.95 .507 99.00 2.257 154.00 .339 203.00 .380 258.15 1.545 38.95 3.148 99.75 .218 156.15 1.524 204.00 2.362 265.15 1.569 49.05 .569 101.00 1.260 157.00 .180 205.00 3.545 273.15 1.381 49.95 9.800 103.00 .410 157.25 .166 206.15 17.196 274.00 3.711 50.95 35.729 103.90 .561 158.00 .388 207.15 2.754 275.15 21.505 51.95 1.757 105.00 .961 159.00 .135 210.15 .244 276.15 2.778 54.80 .349 107.00 10.848 160.00 .323 210.75 .545 277.00 1.833 55.95 1.454 108.00 1.900 161.00 .646 211.00 .545 278.00 .317 56.95 3.045 109.15 .200 165.00 .515 214.40 .063 292.95 .539 60.95 .624 110.00 31.427 166.00 .489 214.65 .121 295.95 5.112 62.95 1.353 111.00 3.562 167.00 3.182 215.00 .125 296.95 1.020 63.70 .345 116.00 .442 168.00 1.375 217.00 4.428 301.95 .157 64.95 .602 117.00 7.555 171.75 .190 218.00 .339 308.95 .079 66.45 .190 118.00 .658 174.00 .743 221.00 4.402 323.05 2.304 66.80 .119 120.00 .137 175.00 .848 223.00 .824 333.95 1.658 68.95 57.535 121.90 .660 176.25 .434 224.15 9.914 346.05 .097 73.95 3.850 123.00 1.248 177.00 .678 225.15 2.893 351.95 .567 k74.95 5.633 124.00 .321 177.75 .345 226.00 .374 353.95 .561 '76.05 2.065 127.00 43.321 179.00 2.552 227.00 3.273 364.95 2.072 77.05 43.063 128.00 2.932 180.15 1.924 227.90 .612 366.05 .184 78.05 3.154 129.00 17.578 181.15 .464 229.00 .682 372.05 .862 78.95 2.875 130.00 .957 185.00 1.133 231.00 .462 402.05 .204 79.95 2.469 131.90 .240 186.00 8.908 233.00 .075 403.05 .549 80.95 2.879 132.25 .244 187.00 2.552 233.90 .228 421.05 .592 82.05 .624 135.00 1.492 188.00 .283 238.90 .149 422.05 .351 83.80 .202 137.15 .269 188.75 .125 243.15 .606 423.05 2.863 85.95 .781 141.00 1.290 190.00 .097 244.15 9.136 424.05 .757 86.95 .380 142.00 .416 192.00 .614 245.15 1.102 441.05 8.847 89.20 .117 144.00 .052 196.15 3.041 246.00 .836 442.05 58.456 90.95 .501 147.00 .640 198.00 100.000 255.00 42.998 443.05 10.073 92.05 .618 148.00 1.440 199.00 7.188 256.00 7.006 444.05 1.052 92.95 4.406 151.00 .355 200.00 .745 300621 DatE^> QUANT REPORT « Operator ID: DAVID Output File: *H054A::BQ ata File: >H054A::D1 ame: SOng DFTPP Misc: 290-14-PERF Quan t R e v : 6 Quant T i m e : 950223 16:49 ID File: ID_DFT::DB Title: DFTPP/BENZIDINE/PENTACHLOROPHENOL Last Calibration: 950223 15:49 Injected at: Dilution Factor: INST H PERFORMANCE 950223 12:18 1.00000 BTL# 1 Compound R.T. Q ion Area Cone Un i ts 1) 2) 3) «IS#4 Phenanthrene- Pentachlorophenol Benz idine d 10 6 . 9 4 188.2 6 , 7 3 2 6 5 , 9 8 . 7 1 184.2 213215 45578 115563 20, 25 25, 00 00 00 ppb ppb ppb 86 98 95 * Compound i s ISTD 300622 D-t3 Sub'ectTo VElidation TOTfiL ION CHROtlflTOGRfiM File >H054fl 35,e-5ie.0 &mu. 50n3 DFTPP £9e-14-PERF TIC lee see see 4e0 see - see 7ee eee • • • ' ' • ' ' • ' • ' • • ' • • " ' • • • • ' • • " ' ' ' • • ' • • • ' • • ' 1 . 1 1 • I • • . • I . • • • 1 • • 7eeeee- fiseeee- seeeee- sseeee- seeeee- 45eeee- 4eeeee- 350000- 300000- 250000- 200000- 150600- 100000- 50000- 0- c m g JC a. i sa '' " I ' ' ' ' I ' ' ' ' I ' ' ' ' I " '' r 0 5.0 6.0 u ' I ' ' ' ' I ' '' ' r ''' I " ' ' I ' " ' I ' ' " I ' '' 'I 7.0 8.0 9.0 10.0 11.0 Data File: >H054A::D1 Name: SOng DFTPP Misc: 290-14-PERF Quant Output File: *H054A::BQ INST H BTL# 1 • Id File: ID_DFT::DB Title: DFTPP/BENZIDINE/PENTACHLOROPHENOL PERFORMANCE Last Calibration: 950223 15:49 Operator ID: DAVID Quant Time: 950223 15:49 I n jected at: 950223 12: 18 300623 Data Subject To Validation REFERETNCE STflNDflRD SPECTRUM F i l e >H099P BENZIDINES SDT Bpk fib l e e . ie2e-2i-BENz-5e SUB NRtl 184 lee- 52 \ 65 / ^1.^ 102 ^ v 139 156 / ^ / / . A^ f I fi"!*^' * n'l vniS V'l' I <^\ 1*1' I f INST Sc»n 2538 24.97 «iin. -lee 186 40 80 ise i6e K, | " T I I [ I I I I I I I I I I I I I I I I P see 240 280 SAMPLE SPECTRUM (BfiCKGROUND SUBTRACTED) File >H054R 50ns DFTPP Bpk fib 81152, 29e-14-PERF SUB 184 50000- 52 \ ^ £ 1 0 3 1 1 7 139 156 65 »•** t..aait . « . . » l l . . •/. y Scan 553 8 . 7 1 m i n . 100 207 192 y I / y 253 / 40 • r I I I I I I I I ^ T ' t T" 80 120 160 200 240 280 SfiMPLE SPECTRUM <UNflLTERED) F i l e >H054R 5 0 ^ 3 DFTPP Bpk fib 8 1 1 5 2 . 290-14-PERF 184 Scan 553 8 . 7 1 i r i i n . 50000- 52 \ 65 / 92 103117 139 156 T 40 al .«< tl i /. T-I I r- I I ^ I T'^ I r 80 120 I ' ' ' I ' ' ' I 160 207 192 •; I ./ y 253 281 :Zi.i V 200 ' ' I ' • ' I 240 100 280 Data File: >H054A::D1 Name: SOng DFTPP Misc: 290-14-PERF Quant Time: 950223 15:49 In jected at: 950223 12: 18 Quant Output File: '"H054A::BQ INST H BTL# 1 Quant ID File: ID_DFT::DB Last Calibration: 950223 15:49 Compound No: 3 Compound Name: Benzidine Scan Number: 553 Retention Time: 8.71 min. Quant Ion: 184.2 Area: 115563 Concentration: 25.00 ppb q-vaIue: 95 300624 Data Subject To V£i;cdJO. TOTAL ION CHR0MRT08RRM File >He54B 35.0-510.8 M U . SSTDOSO TIC leee isee L j J - 480000^ 290-12-SV25 % '^A ^ ^ 7^ ^yz. < > 6> • t ^ PA % Data File: >H054B::D1 Name: SSTDOSO Misc: 290-12-SV25 Quant Output File: "H054B::BQ INST H BTL# 2 Id File: ID_SH::DB Title: SEMIVOLATILES BY SW846-8270/EPA 625 Last Calibration: 950223 15:48 Operator ID: DAVID Quant Time: 950223 15:49 Injected at: 950223 14:56 300625 -f-r, C,,,l, Svbject To Validation QUANT REPORT Operator ID: DAVID Output File: "H054B::BQ ^Data File: >H054B: :D1 ^Name: SSTDOSO Misc: 290-12-SV25 Quant Rev: 6 Quant Time: 950223 16:49 Injected at Dilution Fac tor INST H 950223 14:56 1.00000 BTL# 2 ID File: ID_SH::DB Title: SEMIVOLATILES BY SW846-8270/EPA Last Calibration: 950223 15:48 625 Compound R. 10. 6. 6. 10. 10. 8 10. 10 10. 10 10. 10 11 1 1 11 11 1 1 1 1 11 11 13 11 1 1 12 12 12 12 12 12 13 13 13 13 14 14 16 14 14 15 15 15 15 15 T, 96' 48 52 40 65 92 48- 42 67 54' 89- 99- 28- 3 1. 21' 45 40' 68 83 64' 17 .95 98 35 52 54- 70 .92 70 .08 20 .31 .47 . 12 .41 .3 1 .79 .94" . 0<V .05 .28 .51 .81 Q ion 152.0 79. 1 74.0 99.0 132.0 1 12.0 93.0 ' 94.0 128.0 93.0 146.0 146.0 152.0 146.0 108. 1 44.9 108.0 70.0 117.0 108.0 136. 1 82.0 77.0 82.2 139.0 10 7.0 93. 1 162.0 .122.0 179.9 128. 1 127.0 224.8 107.0 142. 1 164.2 236.8 196.0 196.0 172. 1 162.0 65.0 163. 1 Ar ea 42043 77237 52508M 82885 60211 66616 120502 88736 64987 86234 74907 76458 45932 72189 39981 79449 55726 52101 28616 60876 150205 65110 69840 153753 24 147 46512 105166 47529 29242 56934 179 178 75305 31598 55051 105065 70863 13660 30754 33922 1 13490 10 1467 35104 121821 Cone 20.00 25.00 26.00 25.00 25.00 25.00 25,00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 20.00 26.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 26.00 25.00 25.00 25.00 25.00 25.00 20.00 25.00 25.00 . 25.00 25.00 25.00 25.00 25.00 Uni ts ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb q 96 97 96 85 7 1 90 67 79 94 98 96 90 96 84 86 93 72 95 97 98 80 96 98 92 90 92 89 97 99 98 94 93 84 98 86 92 89 97 90 96 60 90 * IS# 1 1,4-DichI orobenzene-d4 Pyr i d i ne N-N itrosodimethylamine Phenol-d5 2-ChIorophenoI-d4 2-FIuor ophenoI An i I i ne PhenoI 2-Chlorophenol b i s(2-ChloroethylJether 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene-d4 1,2-Dichlorobenzene Benzyl alcohol 2,2'Oxybis-(1-chloropropane) 2-Me thylphenol N-N i troso-di-n-propylamine Hexachloroethane 4-Met hyIphenoI *IS#2 Naphthalene-d8 Nitr obenzene-d5 Nitrobenzene I sophorone 2-N i trophenol 2,4-Dimethylphenol bis(2-Chloroethoxy)me thane 2,4-Dichlorophenol Benzoic acid 1,2,4-Tr ichlorobenzene Naph t ha Iene 4-ChI or oan i I ine Hexachlorobutadiene 4-ChI or o-3-me thylphenol 2-Me thylnaphthalene •IS#3 Acenaphthene-dIO Hexachlorocyclopentadiene 2,4,6-Tr ichlorophenol 2,4,5-Tr ichlorophenol 2-fluorobiphenyl 2-Chloronaphthalene 2-N itroaniline D imethy Ipht ha I ate Data Subject To ^>Mr^|1^-2'6 Compound R.T. Q ion Area Cone Uni ts 2,6-Di n i t rot0 Iuene Acenaphthylene 3-Ni t roan iIi ne Acenaphthene 2,4-Di n i t ropheno I Di benzofuran 4-Ni t rophenoI 2,4-D i n i t rot 0 Iuene 2,3,4,6-Tet rachlorophenol Diethylphthalate 4-Chlorophenyl-phenylether Fluorene 4-N i t r oan iIine 2,4,6-TribromophenoI »1S#4 Phenanthrene-d 10 1,2-D iphenylhydrazine 4,6-D i n i t r o-2-me thylphenol D i phenyI ami ne 4-Br omophenyl-phenylether Hexachlorobenzene Pentachlorophenol Car bazo I e Phenanthrene Anthracene Fluoranthene Di-n-butylphthalate «IS#5 Chrysene-d 12 Pyr ene Te r phenyI-d 14 Butylbenzylphthalate 3,3'-Dichlorobenzidine Benzo(a)anthracene bis(2-Ethylhexyl)phthalate Chrysene *IS#6 Perylene-d12 Di-n-octylphthalate Benzo(b)fIuoranthene Benzo(k)fluoranthene Benzo(a)pyr ene Indeno( 1,2,3-cd ) pyrene Dibenz(a,h)anthracene Benzo(g,h, i )perylene « Compound is ISTD 1 5 . 9 8 1 6 5 . 0 1 6 , 0 4 1 5 2 , 1 1 6 . 2 4 1 3 8 . 0 1 6 . 3 7 153. 1 1 6 . 4 2 1 8 4 . 1 1 6 . 6 5 168. 1 1 6 . 4 9 1 0 9 . 0 1 6 . 6 8 1 6 5 , 1 1 6 . 9 3 2 3 2 . 0 1 7 , 0 4 1 4 9 . 1 1 7 . 2 1 2 0 4 , 1 1 7 , 2 7 166. 1 1 7 . 3 5 1 3 8 . 0 1 7 , 7 4 3 2 9 , 6 1 8 , 9 7 1 8 8 , 2 1 7 . 5 0 7 7 . 0 1 7 , 4 2 1 9 8 , 0 17.44 169. 1 1 8 . 0 9 2 4 8 . 0 1 8 . 4 1 2 8 3 . 8 1 8 . 7 1 2 6 5 , 9 1 9 . 3 5 1 6 7 . 0 1 9 . 0 1 ' 178. 1 1 9 . 0 9 ' 178. 1 2 1 . 16' 2 0 2 . 0 1 9 . 9 0 1 4 9 . 0 2 3 . 7 6 2 4 0 . 2 2 1 . 5 9 / 2 0 2 . 0 2 1.76 2 4 4 . 2 2 2 . 6 0 149. 1 2 3 . 6 3 2 5 2 . 2 2 3 . 7 2 ' 2 2 8 . 0 2 3 . 5 4 1 4 9 . 0 2 3 . 8 V 2 2 8 . 0 2 6 . 9 9 2 6 4 . 2 2 4 . 6 4 149.0 2 5 . 9 7 ' 2 5 2 . 2 2 6 . 0 2 ' 2 5 2 . 2 2 6 . 8 3 ' 2 5 2 . 0 3 0 . 4 9 , 2 7 6 . 2 3 0 . 4 5 , 2 7 8 . 1 3 1.57 276.0 21408 168 160 26195 108457 6742 137480 10122 30678 31412 133871 49854 106332 .24047 2098 1 105222 176003 1045 1 69393 3 1784 48347 22054 132319 148334 148594 153906 239500 103595 158218 106893 9 3 6 15 50098 142597 14532 1 13157 1 12 1839 240168 152868 142969 136746 174408 134290 146 145 25. 25. 25. 25, 25. 26. 25. 25. 25. 25. 25. 25. 25, 25. 20, 25. 25, 25. 25, 25. 25, 25, 25, 25, 25, 25, 20, 25, 25, 25, 25 25, 25 25, 20 25 25 25 25 25 25 25 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb p-pb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb 91 95 90 95 57 97 84 94 85 93 85 92 89 86 86 89 93 88 9 1 98 96 95 97 97 96 99 98 95 97 95 97 95 88 96 95 95 98 95 93 87 84 86 300627 Data Subject To Validation Centtnuins Calibration Check MSL Coi^ounde C u e No: Contractor: PACE Contract No: iMtruMnt 10: 5988-H Cal{brat(on Date: 02/23/95 Tia«: U:56 Laboratory IDt >H0S4S Initial Calibration Date: 02/02/95 Niniaui KF for SPCC ia 0. Confound NF NaxiBua X Diff for CCC ia SOX " - / - XDiff CCC SPCC Pyridine N-NitroaodiMtl«ylaMine Phenol-dS 2-Chlorophenol-d4 2-FIuorophenoI Aniline Phenol 2-Chlorophenol b{s(2-Chloroeth/l)ether 1,3-Dichlorobenzene 1,4-Oichlorobenzene 1,2-Dichlorobenzeoe-d4 1,2-Dichlorobenzene Benzyl alcohol 2,2'0xybia-(1-chloropropane) .2-Hethylphenol iN-Nitroso-di-n-propylanine Hexachloroethane 4-Nethylphenol Nitrobenzene-d5 Nitrobenzene laophorone 2-Nitrophenol 2,4-DiMthylphenol bis(2-Chloroethoxy)nethane 2,4-Dichlorophenot Benzoic acid 1,2,4-Trichlorobenzene Naphthalene 4-Chloroaniline Hexachlorobutadiene 4-Chloro-3-wthylphenol 1.01438 1 .66304 1.48923 1 1.19953 1 1.12896 1 .46968 .99919 .57715 .14570 .26758 2.24426 2.2929J 1.62092 1 1.21281 1 .68848 .23658 1.39292 1.64087 1.31130 1 1.34158 1 .80913 .42534 .45485 .87400 1.23820 1.37362 .73778 .76076 1.37092 1.51177 1.05586 1 .91209 .58790 1.10887 1 .41102 .40829 .80030 .17343 .27375 .49769 .26488 .17640 .29482 .90341 .41357 .16955 .28719 44.88 50.70 5.90 4.49 12.28 2.17 4.17 1.96 17.80 8.70 8.44 8.02 10.94 3.11 10.27 .06036 / .43 .99138 • .54451 .15836 .34678 .37197 .81890 .12861 .24775 .56012 .25314 .15574 .30323 .95431 .40108 .16879 .29320 ^ 8.69 7.38 4.46 15.63 8.89 2.32 25.85 9.51 12.54 4.43 11.71 2.85 5.63 3.02 .74 2.10 . / . / •*.' . / . / '.'... m NF • Responae Factor froM daily atandard file at 25.00 PPB NF - Averagt Response Factor froa Initial Calibration Foni VI XDiff - X Difference fro* original average or curve C - Calibration Check Compounds (*) SPCC - Systm Perfonnance Checic Compounds (**} For* VII 300628 C ""ats zyy^-^ zyyyt'^ Continuing Calibration Check NSL Coapounds Caae No: Contractor: PACE Contract No: Instrunnt ID: 5988-H Calfbratfcn Data: 02/23/95 Tlae; 14:56 Laboratory ID: >N054B Initial Calibration Date: 02/02/95 Niniwi NF for SPCC ia 0.05 NaxiKa X Diff for CCC la SOX m Coaipouxl 2-Methylnaphthalene Hexachlorocyclopentadiene 2,4,6-Trichlorophenol 2,4.5-Trichlorophenol 2-Fluorobiphenyl 2-Chloronaphthalene 2-Nitroaniline DiMthylphthalate 2,6-Dinitrotoluene Acenaphthylene 3-Nitroaniline Aceriaph thene 2,4-Dinitrophenol Dibenzofuran 4-Nitrophenol ^,4-Dinitrotoluene u,3,4,6-Tetrachlorophenol Diethylphthalate 4-Chlorophenyl-phenylether Fluorene 4-Nitroaniline 2,4.6-Tribrcsx)phenol 1,2-Oiphenylhydrazine 4.6-0initro-2-Mthylphenol Diphenylamine 4-BroBnphenyl-phenylether Hexachlorobenzene Pentachlorophenol Carbazole Phenanthrene Anthracene Fluoranthene RF RF .55293 .55958 .32670 .15421 i .38270 .34719 .41683 .38296 1.25887 1.28123 1.08947 1.14550 .42902 .39630 1.38792 1.37528 .31656 .24168 1.80475 1.89842 .36172 .29573 1.12923 1.22441 .15628 .07611 • 1.48924 1.55207 .17060 .11427 .39411 .34634 .37045 .35462 1.46478 1.51132 .54579 .56282 1.11196 1.20042 .32391 .27148 .22662 .23686 1.30901 1.33815 .15078 .07946 .52841 .52759 .23966 .24165 .31426 .36758 .18396 .16768 1.00492 1.00602 1.10125 1.12778 1.11046 1.12976 1.17351 1.17014 XDiff CCC SPCC / 1 . 2 0 ^52.80 9.28 8.13 1.78 5.14 7.63 .91 23.65 5.19 18.24 8.43 ''51.30 4.22 /33.O2 12.12 4.27 3.18 3.12 7.96 16.19 4.52 2.23 47.30 .15 .83 16.97 8.85 .11 2.41 1.74 .29 •* • / . / ** •• . / • / . / w RF • Response Factor froa daily atandard file at 25.00 PPB RF - Average Response Factor fron Initial Calibration Fora VI XDiff • X Difference froa original average or curve ., C ' Calibration Check Compounds (*) SPCC - Systea Performance Check Compovids (**) Fora VII 300629 •-idiri oizojeci io Validctiofi Continuing Calibration Check NSL Ca^wmda No: Contractor: PACE CaUbration Data: 02/23/95 T t a : 14:56 Contract No: Inatrxaant ID: 5988-H Laboratory ID: >H0548 Initial Calibration Date: 02/02/95 MiniauB RF for SPCC la 0.05 NaxiHa X Diff for CCC ia 30X Ccapowd Oi-n-butylphthalate Pyrene Terphenyl-d14 •utylbenzylphthalate 3,3'-D{chtorobenzidine Eenzo(a)anthracene bia(2-Ethylhexyl)phthalate Chrysene Di-n-octylphthalate Benzo(b}fluoranthene Benzo(k)fluoranthene Benzo(a)pyrene Indenod,2,3-cd)pyrene Oibenz(a,h)anthracene Benzo(g,h,{}perylene RF RF 1.67332 1.82091 1.28356 1.22182 .81891 .82547 .76622 .72293 .39300 .38688 1.08622 1.10119 1.08571 1.12222 1.01148 1.01604 1.62082 1.57695 1.05431 1.00374 .92652 .93874 .90934 .89788 1.04677 1.14517 .81469 .88175 .88047 .95959 8>iff 1 8.82 4.81 .80 5.65 1.56 1.38 3.36 .45 2.71 4.80 1.32 1.26 9.40 8.23 8.99 K C SPCC . / . / m RF - Response Factor froa daily standard file at 25.00 PPB RF - Average Response Factor froa Initial Calibration Form VI XDiff • X Difference froa original average or curve « CC - Calibration Check Corrpoixids (*> SPCC - Systea Performance Check Compounds (**> Fona VII 300630 f , „ . . . , C K - . r TOTAL ION CHROMftTOCRftM F i i * >He54C S S . e - S i e . B aiMU. 1 2 4 2 2 U B 1 bNA LAB ^ L ^ ^ B S T E . 5 0 0 1 O 0 0 1 5 0 0 2 0 0 0 2 5 0 0 - 3 0 8 0 700000-1 600000 5000O0- 400000-1 300000- 200000- looooe- 0-» -r*- ^ ^ g L -I f^ C- -IT a 1 A'-T"^l,'"'\k'''ii.'^^"'A I - I 1 •A / ^^v \ CM "x CL. |l . , 1 Ll-- I --.u- I LL' I • L' I LL' I 2b- '2fe- '^il- ' Z ' S ' 2 b ' 3 b ' 3 f e Data File: >H054C::D1 Name: 12422WB1 Misc: BNA LAB BLANK WATER BATCH/ 12422 INST H Quant Output File: *H054C::BQ BTL/ 3 Id File: ID_SH::DB Title: SEMIVOLATILES BY SW846-8270/EPA 625 Last Calibration: 950223 15:48 Operator ID: DAVID Quant Time: 950223 16:13 Injected at: 950223 15:39 300631 QUANT REPORT Operator ID: DAVID Output File: *H054C::BQ |Data File: >H054C::D1 ^Name: 12422WB1 Misc: BNA LAB BLANK WATER Quemt Rev: 6 Quant Time: Injected at: Dilution Factor: BATCH/ 12422 INST H 950223 16:13 950223 15:39 1.00000 BTL/ 3 ID File: ID_SH::DB Title: SEMIVOLATILES BY SW846-8270/EPA 625 Last Calibration: 950223 15:48 1) 4) 5) 6) 13) 21) 22) 36) 40) 57) 58) 70) 73) 77) 79) Compound *IS/1 l,-4-Dic:hlorobenzene-d4 Phenol-d5 2-Chlorophenol-d4 2-Fluorophenol 1,2-Dichloroben2ene-d4 *IS/2 Naphthalene-d8 Nitrobenzene-d5 *IS/3 Acenaphthene-dlO 2-Fluorobiphenyl 2,4,6-Tribromophenol *IS/4 Phenanthrene-dlO *IS/5 Chrysene-dl2 Terphenyl-dl4 bis(2-Ethylhexyl)phthalate *IS/6 Perylene-dl2 R.T. 10.92 10.37 10.61 8.89 11.25 13.14 11.92 16.29 15.04 17.72 18.94 23.74 21.75 23.53 26.97 Sc2m/ 646 582 610 410 684 903 762 1270 1124 1436 1578 2136 1905 2112 2511 Area 47264 258363 194532 197555 64649 165007 128771 78867 184982 68687 111340 105704 185646 29045 122982 Cone 20.00 69.32 71.85 65.95 31.30 20.00 45.01 20.00 36.61 73.54 20.00 20.00 42.55 4.90 20.00 Units ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb q 94 99 87 80 91 97 84 86 94 88 94 97 98 90 90 * Compound is ISTD 300632 REFERENCE STflNDflRD SPECTRUn File >pe9ae BN nix-i Bpk flb 100. 149 LOT 33356 SUB NRM INST Scan 28.60 100- 57 71 e^f f*r^i* ^1 ^'^ f ''" I'' 113132 2952 ain. 1-100 40 80 T-l—I ' 1—1 r • 120 160 180 279 -t- I • I • 200 240 • i ^ 280 T I ' 320 ' I ' l 360 SntlPLE SPECTRUM <BflCK6R0UND SUBTRACTED) File >H054C 12422UB1 Bpk fib 15073. 149 BNR LflB BLANK SUB UflTER B Scan 23.53 10000- 57 71 I y y. ll i. . 1 1 3 ^ " i y 40 -r 80 -r-"—I—r- 120 2111 n i n . 100 279 lee 200 -1—I I I" 240 • • — I — T 280 S20 ,•-0 360 SAMPLE SPECTRUM <UNflLTERED) File >H Bpk flb 10000; 054C 12422UB1 15073. V J A 1131^21 u. J i. , .. . p y 149 I 1 • 1 • 1 • 1 • 1 ' 1 ' 1 • *0 80 120 160 BNfl LflB BLANK UATER B Scan 2111 23.53 min. -100 207 279 . / \ 200 ' 240 ' 280 ' 320 , 1 . , , 360 D a t a F i l e : > H 0 5 4 C : : D 1 Name: 12422WB1 M i s c : BNA LAB BLANK WATER Quant T i m e : 950223 1 6 : 1 3 I n j e c t e d a t : 950223 1 5 : 3 9 Quant O u t p u t F i l e : " H 0 5 4 C : : B Q BATCH# 12422 INST H BTL# 3 Ouant ID F i l e : ID_SH::DB Last Calibration: 950223 15:48 Compound No: 77 Compound Name: bis(2-EthyIhexyI}phtha I ate Scan Number: 2 112 Retention Time: 23.53 min. Quan t Ion: 149.0 Area: 29045 Concentration: 4.90 ppb q-vaIue: 90 300533 'y^xz D(JD;ec. ro Vahdatjon TOTAL ION CHROMATOGRAM File >H054H 35.O-S10.O, anu. SyyAU04 HLA MMOOOl MATER 500 lOpO , -15,00 2000 , 2500 30,00 • ' • ' • • • • T • • • • ' • • • • ' ^ ' • • • ' • ' • ' • ' • • • ' • • • • l ^ ' ' • ' ' • - * • • l ^ ' • • • ' • • • • ' • • I I 220OO0O 2000000-^ L800OOO-: 16 00000-f L 400000-^ 1200000 loooooo: 800000-J 600000- 400000 200000 o H -t I I- IO 12 1 4 16 18 20 T I ] A % ^> /Pi ^^vT S IS: i n A t^"^i2ll''U"' b b ' 3 b - ' 3 ^ ' Data File: >H054H::D1 Name: SVWAW04 HLA Misc: MWOOOl WATER Quant Output File: '^H054H::BQ BATCH/ 12422 INST H BTL/ 8 Id File: ID_SH::DB Title: SEMIVOLATILES BY SW846-8270/EPA 625 Last Calibration: 950223 15:48 Operator ID: DAVID Quant Time: 950223 19:51 Injected at: 950223 19:17 i J 300634 nata ^-^-i QUANT REPORT # : Operator ID: DAVID utput File: *H054H::BQ ata File: >H054H::D1 Name: SVWAW04 HLA Misc: MWOOOl WATER Quant Rev: 6 BATCH/ 12422 Quant Time: Injected at: Dilution Factor: INST H 950223 19:51 950223 19:17 1.00000 BTL/ 8 ID File: ID_SH::DB Title: SEMIVOLATILES BY SW846-8270/EPA 625 Last Calibration: 950223 15:48 ^ 1 4 5 6 13 21 22 26 29 36 40 57 58 70 .73 7 79 Compound *IS/1 l,4-Dichlorobenzene-d4 Phenol-d5 2-Chlorophenol-d4 2-Fluorophenol 1,2-Dichlorobenzene-d4 *IS#2 Naphthalene-d8 Nitrobenz ene-d5 2,4-Dimethylphenol Benzoic acid *IS/3 Acenaphthene-dlO 2-Fluorobipheny1 2,4,6-Tribromophenol *IS/4 Phenanthrene-dlO *IS/5 Chrysene-dl2 Terphenyl-dl4 bis(2-Ethylhexyl)phthalate *IS/6 Perylene-dl2 * Compound is ISTD R.T. 10.93 10.38 10.61 8.90 11.26 13.14 11.92 12.53 12.61 16.30 15.04 17.72 18.94 23.74 21.75 23.52 26.96 Scan/ 646 582 609 410 684 902 761 831 841 1268 1122 1433 1575 2131 1900 2106 2504 Area 51376 225460 171549 151425 70919 166972 144792 106594 4468 71013 177647 15215 115328 109421 189001 16206 128879 Cone 20.00 55.65 58.29 46.50 31.59 20.00 50.01 51.54 3.44 20.00 39.05 18.09 20.00 20.00 41.85 2.64 20.00 Units ppb ppb ppb ppb ppb ppb PPh ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb q 94 99 88 74 92 99 87 84 72 83 92 86 91 99 96 88 94 300635 -i---^" Data 5u'0i« REFERENCE STANDARD SPECTRUM File >P092Y PHENOLS MIX Bpk Ab 100. LOT 35455 SUB NRM 107 122 INST 100- 39 77 65 / / 9 1 / 0-1 iiLiiijii[>ini iiiiHiiii, ii['llii niii,lii[i i.iiin Scan 1122 12.86 min. •100 1 2 4 4 0 8 0 ' I ' ' H054H SVWAU94 B p k Ab 5 8 8 0 8 . HLA MW0001 SUB UATER BATCH S c a n 8 3 1 1 2 . 5 3 m i n . •100 •-1 40000^ 0^ 39 .,li... .iH... 1 I T !• 77 65 / f......L. -r . I • 1 • 91 y ..L 107 y 122 ...— 1 1. .1 ' ' 1 1 ' 1 1 '•-^' ' 1 ' ' ' 1 ' 254 ' ' 1 ' ' ' 1 ' • ' 1 ' ' ' 4 0 8 0 1 2 0 1 6 0 2 0 6 M 0 SAMPLE SPECTRUM ( U N A L T E R E D ) F i l e >H054H SVWAWg4 B p k Ab 5 9 4 8 8 . HLA 1 0 7 MW0001 WATER BATCH S c a n 8 3 1 1 2 . 5 3 m i n . hieo 40000^ 39 ..I ,li.. 1 ' ' • 77 65 / ^:....k... , . . . 1 , 91 / , I , . y I. ' ' 1 122 ' ••'• •'-•l > ' ' 1 ' ' ' 1 £54 \ ' ' ' I •'•' ' i - ^ - ' 1 I 1 > 4 0 8 0 12G 1 6 0 2 0 y M 0 D a t a F i l e : > H 0 5 4 H : : D 1 Q u a n t O u t p u t F i l e : ' ' H 0 5 4 H : : B Q N a m e : SVWAW04 HLA M i s c : MWOOOl WATER BATCH# 1 2 4 2 2 INST H B T L # 8 Q u a n t T i m e : 9 5 0 2 2 3 1 9 : 5 1 Q u a n t ID F i l e : I D _ S H : : D B I n j e c t e d a t : 9 5 0 2 2 3 1 9 : 1 7 L a s t C a l i b r a t i o n : 9 5 0 2 2 3 1 5 : 4 8 Compound No: 26 Compound Name: 2,4-DimethyIphenoI Scan Number: 83 1 Retention Time: 12.53 min. Quan t Ion: 107 . 0 Area: 106594 Concentration: 51.54 ppb q-vaIue: 84 300636 Data S*iecttoVaV>da«^.^- REFERENCE STANDARD SPECTRUM File >H099Q HAZARDOUS MIX-1 Bpk Ab 100. 100- &J 51 39 50 I 'i I • i'l I 'I'l'I I I r 40 LOT LA 33941 SUB NRM 77 Scan 1195 13.43 min. 105 122 65 • n — I I I — I ' l I I—I I ' 1 ' I I 1 1 I I I—1 I I I I I 1 ' 1 I " I — l l l l — I — n — r - 60 80 100 120 100 1-0 SAMPLE SPECTRUM (BACKGROUND SUBTRACTED) File >H054H SVUAW64 Bpk Ab 1545. HLA MU0001 WATER BATCH Scan 841 SUB 12.61 min. 77 105 1000- I ll 50 J^ ^•^ll I ' 6 0 / 6 9 / I I ' ' ' I I I ' ' I ' 40 60 / 91 85 \ 95 II I I I. • r I I 107 IIJ I ' ' ' ' I 80 1 / ' I ' ' ' ' I ' 100 122 I .1 1-100 1£0 SfiMPLE SPECTRUM (UNALTERED) File >H Bpk Ab 2000- 054H SVUAW04 HLA 2226. •.— 55 / 50 / 69 "•^1 1 1 / 1 1 i l l ! 1 1 ll 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 40 60 M 77 1, W0001 79 \y \ • • • ! • • 80 WATER BATCH Scan 12.61 128 105 ^-.. / 91 „^ 107 115 '^ 95 ^ - / ,1 1. .r , , 1 / , . 1 1 1 . . , . . , , 1 . 1 , . , . 1 . 100 120 841 min. -100 -0 Data File: >H054H::D1 . Quant Output File: 'H054H::BQ Name: SVWAW04 HLA Misc: MWOOOl WATER BATCH# 12422 INST H BTL# 8 Quant Time: 950223 19:51 Quant ID File: ID_SH::DB Injected at: 950223 19:17 Last Calibration: 950223 15:48 Compound No: 29 Compound Name: Benzoic acid Scan Numbe r: 841 Retention Time: 12.61 min. Quan t Ion: 122.0 Area: 4468 Concentration: 3.44 ppb q-value: 72 300637 REFERENCE STANDARD SPECTRUM File >P0920 BN MlX-1 Bpk Ab 100. 149 LOT 33358 SUB NRM INST Scan 23.60 100- 57 71 / fA-^ 40 80 113132 •r r i' 120 ~ £952 min. -100 180 .1 / f !"•'• I 160 I ' I I I r 200 240 279 280 I ' I I r 320 T I I r 360 SAMPLE SPECTRUM (BACKGROUND SUBTRACTED) File >H054H SVWAW04 HLA Bpk Ab 9552. 149 10000- e- f j . ^ 104 128 11 .il.li... .( . i . ^ I »0 80 120 160 MW0001 WATER SUB 1 9 1 ^ ; ^ / 7. y t r 1 I r 1 -I—I . 1 . 1 . 200 240 280 BATCH Scan £106 23.52 min. • r 1 1 1 , 1 . 1 . 320 360 -100 -0 SAMPLE S PECTRUM (UNALTERED) File >He54H SVWflU04 HLA Bpk Ab 9552. 149 10000- 0- 57 7-. / Z 7 104 128 • ^ 1 •^ 1 ' 1 ' 1 ' 1 ' 1 ' 1 ' 1 ' 40 80 1£0 160 MU0001 191 3?" 1 • I • 1 £00 UATER 281 £40 £80 BATCH • 1 • 1 S£0 Scan 2106 £3 .52 min. 366 -100 -0 Data File: >H054H::D1 Quant Output File: "H054H::BQ Name: SVWAW04 HLA Misc: MWOOOl WATER BATCH# 12422 INST H BTL# 8 Quant Time: 950223 19:51 Quant ID File: ID_SH::DB Injected at: 950223 19:17 Last Calibration: 950223 15:48 Compound No: 77 Compound Name: bis(2-EthyIhexyI)phtha I ate Scan Number: 2 106 Retention Time: 23.52 min. Quan t Ion: 149 . 0 Area: 16206 Concentration: 2.64 ppb q-vaIue: 88 300638 "••5 ^.\t\-\(->r-tr T Q V2'ir'?~,t;r'"' TOTAL ION CHROMATOGRAM File >He54I 35.0-518.0 A M U . SyyAM05 508 1808 ^200000 2000000- 1800000- HL.A Mueioi UATER 500 1000 1508 28,88 2588 3808 ^ ?^ I S I ^Ss .:*^ ^ > ' % •O " I s & r ^ i _ ' 1 • !_ • I 24 26 ¥r [5^3 F Data File: >H054I::D1 Name: SVWAW05 HLA Misc: MWOlOl WATER Quant Output File: *H054I::BQ BATCH# 12422 INST H BTL# 9 Id File: ID_SH::DB Title: SEMIVOLATILES BY SW846-8270/EPA 625 Last Calibration: 950223 15:48 Operator ID: DAVID Quant Time: 950223 20:35 Injected at: 950223 20:01 300639 Data Subject lb Va'idation QUANT REPORT Operator ID: DAVID Output File: *H054I::BQ )ata File: >H054I::D1 lame: SVWAW05 HLA Misc: MWOlOl WATER Quant R6v: 6 BATCH# 12422 Quant Time: Injected at: Dilution Factor: INST H 950223 20:35 950223 20:01 1.00000 BTL# 9 ID File: ID_SH::DB Title: SEMIVOLATILES BY SW846-8270/EPA 625 Last Calibration: 950223 15:48 Compound R.T. 10.92 10.37 10.61 8.89 11.25 13.13 11.92 12.51 12.62 16.28 15.03 17.72 18.94 23.74 21.75 23.53 26.96 Scan# 639 575 603 404 677 895 755 824 836 1261 1116 1427 1569 2126 1895 2101 2499 Area 50746 206027 160627 141493 66941 177313 142156 86695 3835 81983 193177 17654 125370 113328 199682 26395 119375 Cone 20.00 51.48 55.26 43.99 30.19 20.00 46.24 39.47 2.78 20.00 36.78 18.18 20.00 20.00 42.69 4.15 20.00 Units ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb q 96 96 89 71 95 99 85 86 88 90 94 86 93 95 98 90 97 1 4 5 6 13 21 22 26 29 36 40 57 58 70 73 m *IS#1 l,4-Dichlorobenzene-d4 Phenol-d5 2-Chlorophenol-d4 2-Fluorophenol 1,2-Dichlorobenzene-d4 *IS#2 Naphthalene-d8 Nitrobenzene-d5 2,4-Dimethylphenol Benzoic acid *IS#3 Acenaphthene-dlO 2-Fluorobiphenyl 2,4,6-Tribromophenol *IS#4 Phenanthrene-dlO *IS#5 Chrysene-dl2 Terphenyl-dl4 bis(2-Ethylhexyl)phthalate *IS#6 Perylene-dl2 * Compound is ISTD 300640 REFERENCE STRNDRRD SPECTRUM File >P092Y PHENOLS MIX Bpk fib 100. 107 10&4 ^ 39 77 ^ A M i y i i ^ 91 / 123 LOT 35455 SUB NRM 124 INST Scan 1122 1 2 . 8 6 ttiin. -100 T ' W T * h ' l ' T ' l ' ^ » 1 " | ' ^ " l I'/'i I I I I I I I 1 I I I I I I I I I I I I I I I I I I M I I M ' I I I I I 40 80 120 160 200 240 £80 •-0 SAMPLE £ -PECTRUM <EfiCK5R0UND SUBTRRCTED> F i l e >H054I SVWflWOS HLfl M140101 Bpk fib 3 9 1 6 0 . SUB 107 40000- 0- 39 ' k 5 1 .iZ.i .li...i.. .1 / L 123 i I 1 1 1 1 1 1 1 1 1 1 1 1 1 < 1 1 1 1 1 1 1 1 1 1 ' . • 1 1 1 40 80 120 160 UflTER 1 1 1 1 1 1 1 1 1 1 1 1 200 240 BfiTCH Scan 823 1 2 . 5 1 m i n . 318 280 -100 -0 SAMPLE SPECTRUM (UNALTERED) F i l e >H054I SVUfiUOS HLfl Bpk flb 3 9 1 6 0 . 107 40000- 0- 39 ' k 5 1 .1.-..11.....1.....U....1., .k / L 1^23 I ll •tr- 1 , , , 1 , , , 1 , , , , , , , 1 , , , 1 , 40 80 120 MW0101 UfiTER BfiTCH Scan 823 1 2 . 5 1 m i n . -100 £54 318 -Cl 1 1 1 1 1 1 1 . . . 1 . . . 1 , , , 1 1 1 1 1 1 , . 1 . , , 1 . . , 160 200 240 280 Quant Output File: "H054 BQ Data File: >H054I::D1 Name: SVWAW05 HLA Misc: MW0 10 1 WATER BATCH# 12422 INST H BTL# 9 Quant Time: 950223 20:35 Quant ID File: ID_SH::DB Injected at: 950223 20:01 Last Calibration: 950223 15:48 Compound No: 26 Compound Name: 2,4-Dimethylphenol Scan Numbe r: 824 Retention Time: 12.51 min. Quan t Ion: 107 . 0 Area: 86695 Concentration: 39.47 ppb q-vaIue: 86 300641 r%^tr' Ci'Sr-f'' To T^^ ^/^p^i-.-.;, REFERENCE STRNDRRD SPECTRUM File >H099a HflZRRDOUS MlX-1 Bpk Rb 100. LOT Lfl 33941 SUB MRM 109- 0-* 51 Pl 105 77 65 ^ / 122 Scan 1195 13.43 min. 100 128 I I I I — I ' I I ' ' I—I I I I"I '' ' I ' ' — I I I ' ' — I I I I I ' — I ' M 80 120 160 200 I I ' 240 SAMPLE SPECTRUM (BRCKGROUND SUBTRACTED) File >H054I SVWRU05 Bpk flb 1805. HLA MU0101 SUB UflTER £000-1 105 12£ • 51 1000- 0J 40 67 I I .III 11 77 / BATCH Scan 836 12.63 min. •100 1£3 H054I SVWflU05 HLA MU0101 Bpk Ab £ 5 1 5 . 128 . £000- - e- 77 ^ ^ 5 / 51 / f l l ^ 67 l l l l , .III 11 9 1 11 y I L 1 1 , i WATER • s - 1 , i i 1 . . . 1 . , . 1 1 1 , 1 1 . 1 1 . 1 . 1 1 , . 1 1 1 40 88 120 160 BATCH Scan 836 1 2 . 6 2 m i n . £54 I [-100 -Pl • 1 • • • 1 • • • 1 • • £00 240 Data File: >H054I::D1 Quant Output File: "H0541::BQ Name: SVWAW05 HLA Misc: MW0101 WATER BATCH# 12422 INST H BTL# 9 Quant Time: 950223 20:35 Quant ID File: ID_SH::DB Injected at: 950223 20:01 Last Calibration: 950223 15:48 Compound No: 29 Compound Name: Benzoic acid Scan Numbe r: 836 Retention Time: 12.62 min. Quant I on: 122.0 Area: 3835 Concentration: 2.78 ppb q-vaIue: 88 300642 DE.t; C,.'..,:,--' T REFERENCE STflNDflRD SPECTRUM File >P0920 BN MlX-1 Bpk Rb 100. 149 100- O-i 57 71 / 113 f H ^ 132 / 40 *T* 'r'|''i^y 'i"! '*f r LOT 33358 SUB NRM 180 / INST Scan 28.60 2952 min. -100 1 — I — I I I — I — I 1 ( — I — I — I — I > I — 1 — f - 1 — I I I — 1 I 1 — I I I — r — T 80 120 160 200 240 280 320 360 279 SAMPLE SPECTRUM (BACK6R0UND SUBTRACTED) File >H054I SVWAU05 Bpk flb 15843. HLfl 149 MU01O1 SUB 10000- 0-" ./ l^ 113 i3£ .i i ..!..> ;09 UflTER £79 BATCH Scan 23.53 2101 min. 1-108 1 1 1 . 1 1 1 1 1 1 1 , ; 1 1 1 ; 1 1 . 1 1 1 1 ; 1 f . 1 . j 1 1 1 p 40 80 1£0 160 £00 £40 £88 320 366 SAMPLE £ PECTRUM (UNALTERED) File >H054I SVIJAU05 HLfl Bpk flb 16608. 149 loooo; 0^ 57 71 / ,^ 113 13£ .u . , 1 >i..y -^ I J 1 • 1 • 1 • 1 • 1 • 1 • 1 • 40 80 120 160 MU0101 207 L ' I ' l 200 UATER BATCH 279 £S£ yy 1 • 1 ' 1 • 1 • 1 • 1 £40 280 320 Scan £101 23.53 min. • 1 • 1 • 360 -100 -0 Data File: >H054I::D1 Quant Output File: "H054I::BQ Name: SVWAW05 HLA Misc: MW0101 WATER BATCH# 12422 INST H BTL# 9 Quant Time: 950223 20:35 Quant ID File: ID_SH::DB Injected at: 950223 20:01 Last Calibration: 950223 15:48 Compound No: 77 Compound Name: b i s ( 2-E t hy l.he)(_y I ) ph t ha I a t e Scan Number: 2 10 1 Retention Time: 23.53 min. Quan t I on: 149 . 0 Area: 26395 Concentration: 4.15 ppb q-vaIue : 90 300643 •^.,^-, C,,^;V': T") Validation FMGR : TUNER, >>DFTPP n/z GC/MS PERFORMANCE STANDARD DecafluorotriphenylphoBphintt (DFTPP) Ion Abundance Criteria % Relativs Abtindance Base Appropriate Peak PeaX 51 30-60% Of Bass 198 68 Less than 2% of sass 69 69 (reference only) 70 Less than 2% of nass 69 127 40-60% of Bass*198 197 Less than 1% of nass 198 198 Base peak, 100% relative abundsmce 199 5-9% Of mass 198 275 10-30% of mass 198 365 Greater than 1% of mass 198 441 0-100% of mass 443 442 Greater than 40% of mass 198 443 17-23% of mass 442 Injection Date: 02/24/95 Injection Time: 10:34 Data File: >H055A Scan: 372 Status 37.42 .45 53.54 .13 41.83 .27 100.00 7.27 24.98 2.47 12.06 74.45 16.09 37.42 .83 53.54 .24 41.83 .27 100.00 7.27 24.98 2.47 74.95 74.45 21.62 Ok Ok Ok Ok Ok Ok Ok Ok Ok Ok Ok Ok Ok SMG: R : ,TUNDOC 300644 DataSunje^ F i l e >He55A 50nff »FTPP Bpk Ab XB0. .\ ISO: 7 0 : SO: 40^ 3oi I O : o t 9 e - 1 4 - P E R F SUB NRM 198 INST H 69 5 1 '•Um 127 SO iW^ 166 \ 1 0 0 •'i't'f(i'ifil*il4'Ff 255 1 5 0 2 0 0 2 5 0 275 / % a- . y * . % \ 296 3 2 3 442 365 t 11 'r 1 ^ I f r f i ^ I f 1*1 111*1 I n M'' 11 ri t» 3 0 0 3 5 0 4 0 0 So&n 372 7 . 1 6 Min. 1:110 iioo ^ O ieo ?70 ^60 E5e E30 i20 r i o Data Fileneune: >H055A::D1 Naae: 50ng DFTPP Misc: 290-14-PERF INST H BTL/ 1 Operator ID: DAVID SUPER GRP. Analysis Date/Time : 2/24/95 10:34 3 0 0 6 4 5 Dr:ta Subject To Validation . . ( ' — m0...r.^t AJMiaH 4 C / 4 C 4 / y 9 2 . 0 : 3 4 Data Filename and Sasqple ID: >H055A SOng DFTPP 290-14-PERF INST H 372 SUB MRM Lie: >H055A Scan #: 372 Retn. time: 7.16 B/z Int. m/z Int. m/z Int. m/z Int. m/z int. 36.80 .646 9 3 . 0 0 3.687 151.75 .106 203.00 .473 277.05 1.799 3 7 . 8 0 .239 9 4 . 1 5 .272 154.00 .295 204.15 2.174 284.05 .176 3 8 . 0 5 .239 9 8 . 0 0 2 . 9 3 3 155.15 .732 205.15 3.775 285.20 .353 3 8 . 9 5 3.644 9 9 . 0 0 2.830 156.15 1.092 206.15 17.668 293.05 .371 4 0 . 9 5 . 3 3 1 100.00 .394 157.90 .299 207.15 2 . 3 9 7 294.95 .079 4 3 . 9 5 .189 101.00 1.821 160.00 .207 208.00 .844 296.05 4.392 4 9 . 2 0 .619 104.00 1.083 165.15 .720 210.25 .470 297.05 .556 5 0 . 0 5 9.117 105.00 .675 166.00 .410 211.15 1.074 303.20 .765 5 1 . 0 5 3 7 . 4 2 1 1 0 5 . 9 0 . 1 9 1 1 6 7 . 1 5 3.052 2 1 4 . 9 5 .083 304.20 .218 5 2 . 0 5 2.427 107.00 11.244 168.15 1.560 216.20 .270 316.05 .491 5 5 . 9 5 1.344 108.00 1.686 170.00 .126 216.95 4.527 323.05 2.125 5 6 . 9 5 2.830 109.00 .259 173.15 .786 221.05 3.534 327.05 .461 6 0 . 9 5 .563 1 1 0 . 0 0 27.618 174.15 .554 222.05 .448 328.05 .389 6 4 . 0 5 .353 111.00 3 . 1 8 1 175.15 1.110 222.95 .750 334.05 1.285 65.05 . 6 5 1 111.90 . 5 3 1 176.15 .279 224.05 10.118 346.20 .272 68.05 .446 112.15 .506 177.00 .783 225.05 3.469 352.05 .565 68.95 53.539 117.00 6.467 177.75 .293 227.05 3 . 4 3 1 353.05 .360 69.95 . 1 3 1 117.90 .547 179.00 2.598 228.05 .428 354.00 .606 7 1 . 2 5 .117 123.00 1.531 180.15 1.360 231.05 .536 365.00 2.467 7 3 . 0 0 .506 127.00 41.833 181.15 1.229 243.05 .779 365.90 .443 7 4 . 0 0 2.888 128.15 2.715 184.00 .205 244.05 10.114 371.00 .050 .00 6.296 129.00 16.570 185.00 1.096 245.05 1.686 372.15 1.436 .00 1.470 130.00 1.101 186.15 9.304 245.95 2.202 373.15 .527 77.00 41.102 130.75 .115 187.00 2.087 255.05 46.659 389.90 .259 78.00 2.253 133.00 .106 191.00 .484 256.05 6.852 402.00 .367 7 8 . 9 0 3.070 134.00 .308 192.00 .558 257.05 .387 421.15 .716 80.00 1.821 135.00 1.141 193.15 .657 258.05 2 . 2 6 5 422.00 .644 81.00 3.323 137.25 .738 196.15 2 . 4 1 1 259.05 .108 423.15 4.727 83.00 .813 141.00 1.335 197.15 .275 265.05 .732 424.15 .853 85.00 .259 142.00 . 6 5 1 198.00 100.000 273.05 1.292 441.15 12.063 85.90 . 6 7 1 147.00 .797 199.00 7.273 274.05 4 . 0 0 0 442.15 74.448 87.90 .153 148.00 1.306 200.15 .536 275.05 24.977 443.15 16.095 91.00 .648 149.15 .484 201.65 .302 276.05 2.987 444.15 1.492 92.00 .549 3 0 0 6 4 6 Data Subject To Vaf/datf, ation QUANT REPORT Operator ID: DAVID Output File: ^H055A::BQ Data File: >H055A::D1 ^ ^ e : song DFTPP ^Rsc: 290-14-PERF Quant Rev: 6 Quant Time: Injected at: Dilution Factor: INST H 950224 11:25 950224 10:34 1.00000 BTL# 1 ID File: ID DFT::DB Title: DFTPP/BENZIDINE/PENTACHLOROPHENOL PERFORMANCE Last Calibration: 950224 11:24 Compound R.T. Q ion Area Cone Units 1) *IS#4 Phenanthrene-dlO 2) Pentachlorophenol 3) Benzidine * Compound is ISTD 6.91 188.2 6.71 265.9 8.68 184.2 212523 20.00 ppb 86 53277 25.00 ppb 99 133255 25.00 ppb 97 300647 I' DataSubjcctToVaiidation TOTAL ION CHROMftTOCRftN F i l e VUte^A i^.O-Sib.A amu. f f ^ CITPF 2db-i4-P£V . . . I . . . . ~ . . . . t . . . . ^ . y . . . .i I • • • -T • . . . 1 . . . . " . . . . I . . . . " . . . . t . . . . ^ • • • 1 1 . . y . * ? y 700000. €00000- 500000. 400000 300000 200000 100000. 0- II'" I " i_'ll" '!• 4.0 5.0 Ji I i^.^it'M^i'in'i I I'i I'll I ' l i i ^ i M ) • t ^ ' I " ; - I - • " I " • • I ^ S.O 7.e 8.e 9.e le.e ii.e Data File: >H055A::D1 Name: SOng DFTPP Misc: 290-14-PERF Quant Output File: *H055A::BQ INST H BTL/ 1 Id File: ID__DFT::DB Title: DFTPP/BENZIDINE/PENTACHLOROPHENOL PERFORMANCE Last Calibration: 950224 11:24 Operator ID: DAVID Quant Tine: 950224 11:25 Injected at: 950224 10:34 300648 DataSubiectToVaUdatton pmntEweig «Tft»mftiw KPgCTiniM F i l e >H099P BENZIDINES SST 1028-21-BENZ-9e INST Scan 2538 Bpk tkh 1 0 0 . IJJI NRM 24.97 Min. lOOH I FIDO 3 52 M W 130 U ? 5 ^ * o^v» iH^'fToi »<% w • ^^t 1^1 f i ^ ' j i>» I lyrTTT I n . . i i i n i i n j t n | i i i | i i i i , .^^lo 40 80 120 160 200 ^ 8 4 0 S80 320 SAMPLE SPECTRUM CBftCKGROUNP SUBTRftCTEl» 184 0-^^!..•>»Htt7i»f»^t.«jii,iii»I A . i y * >^-, T^i • ,ffT. , ,ti. . , 1 . . . , . . . , , . . ,1. . . , • • . , , , , .Tito 40 80 120 160 200 240 280 320 SAMPLE SPECTRUM CUNALTERED) E*)»^?"g§§S..58n» PFTPP 290-14-PERF INST ^Scan 549 Bpk AL 92248. ^ 8.68 Min. 184 lOOOOOi -^ 1 3? 65 92 138 XS6 , L ,..p.,ii,*fri*r»^*''T^'*'*'i »»^it< <^'i <^' 114) 185 209 282 }o i \ i ' ' ' ^ ' \ ' : i £ ' ' ' ' ' ^ i S ' ' ^ ' * z A o ' ' ' 2 i o ' ' ' z i o ' ' ' 2 i o ' ^ ' ' Data File: >H055A::D1 Quant Output File: ^H055A::BQ Name: SOng DFTPP Misc: 290-14-PERF INST H BTL/ 1 Quant Time: 950224 11:25 Quant ID File: ID DFT::DB Injected at: 950224 10:34 Last Calibration: 95*0224 11:24 Conpound No: 3 Conpound Nane: Benzidine Scan Number: 549 Retention Tine: 8.68 min. Quant Ion: 184.2 Area: 133255 Concentration: 25.00 ppb q-value: 97 300649 Data Subject To Validation TOTAL ION CHROMATOGRAM H i e yuostsb ;^i5.6-5ib.A «MU. |{{l»b5& i*o-li-iU2S 500 . IOOO , iseo , «opo 25jeo..... 3000 C00000. 550000 500000^ 450000-! 400000^ 350000^ m 3000004 250000: 200000: isoooo: 100000 50000-3 o t^-L. 2V ' 215' • 2b' ' 3 b ' ' 3 b ' ' Data F i l e : >H055B::D1 Nane: SSTD050 Misc: 290-12-SV25 Quant Output F i l e ; INST H Id File: ID__SH: :DB Title: SEMIVOLATILES BY SW846-8270/EPA 625 Last Calibration: 950224 11:45 Operator ID: DAVID Quant Tine: 950224 11:47 Injected at: 950224 10:59 *H055B::BQ BTL/ 2 3 0 0 6 5 0 Data Subject To Validatior? QUANT REPORT Operator ID: DAVID Output File: *H055B::BQ 2ata File: >E055B::D1 ae: SSTDOSO Lsc: 290-12-SV25 Quant Rev: 6 (2uant Time: Injected a t : Dilution Factor: INST E ID File: ID 8H::DB Title: SEMIVOLATILES BY 5W846-8270/EPA 625 Last Calibration: 950224 11:45 950224 11:47 950224 10:59 1.00000 BTL/ 2 1) 2] 3; 4) 5] «) 7) 8; 9] 10) 11] 12] 13] 14] 15] M' m TB 19] 20] 21] 22' 23; 24 25 26 27 28, 29, 30 31. 32, 33 34 35 36 37 38 39 40 M l m ff Compound *IS/1 1,4-Dichlorobenzene-d4 Pyridine N-Nitrosodimethylamine Phenol-d5 2-Chlorophenol-d4 2-Fluorophenol Aniline Phenol 2-Chlorophenol bis(2-Chloroethyl)ether 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene-d4 1,2-Dichlorobenzene Benzyl alcohol 1 2-Methylphenol N-Nitroso-di-n-propylanine Hexachloroethane 4-Methylphenol 1 *IS/2 Naphthalene-d8 1 Nitrobenzene-d5 1 Nitrobenzene 1 Isophorone 1 2-Nitrophenol 1 2,4-Dimethylphenol 1 bis(2-Chloroethoxy}methane 1 2,4-Dichlorophenol 1 Benzoic acid 1 l,2,4-Trichloroben2ene 1 Naphthalene 1 4-Chloroaniline 1 Hexachlorobutadiene 1 4-Chlor0-3-methylphenol 1 2-Methylnaphthalene 1 *IS/3 Acenaphthene-dlO 1 Hexachlorocyclopentadiene 1 2,4,6-Trichlorophenol 1 2,4,5-Trichlorophenol 1 2-Fluorobiphenyl ) 2-Chloronaphthalene 1 2-Nitroaniline 1 Dimethylphthalate R.T. Q ion 10.91^152.0 6.42 79.1 6.47 74.0 10.35 99.0 10.60 132.0 8.88 112.0 10.43 93.0 10.38 94.0 10.62 128.0 10.50 93.0 10.85/146.0 10.93^146.0 11.23*^152.0 11.26^146.0 11.16/108.1 11.40 . 44.9 11.35-^108.0 11.64 70.0 11.78 117.0 11.59/108.0 13.12 136.1 11.90 82.0 11.93 77.0 12.30 82.2 12.47 139.0 12.49*^07.0 12.66 93.1 12.88 162.0 12.67-^22.0 13.03 179.9 13.16 128.1 13.26 127.0 13.42 224.8 14.08 107.0 14.36 142.1 16.27 164.2 14.74 236.8 14.89^96.0 14.97^196.0 15.02 172.1 15.24 162.0 15.46 65.0 15.77 163.1 -. Area 49355 88077 61551M 93564 75298 79894 143486 105499 78341 94590 84047 86913 52229 81476 48127 103553 70785 62956 36350 74346 168605 82279 83124 173878 33979 56265 123379 56502 37197 64622 204679 88195 34757 65891 113030 76650 25982 36198 39154 125809 113683 41187 141879 Cone Units 20.00 ppb 25.00 ppb 25.00 ppb 25.00 ppb 25.00 ppb 25.00 ppb 25.00 ppb 25.00 ppb 25.00 ppb 25.00 ppb 25.00 ppb 25.00 ppb 25.00 ppb 25.00 ppb 25.00 ppb 25.00 ppb 25.00 ppb 25.00 ppb 25.00 ppb 25.00 ppb 20.00 ppb 25.00 ppb 25.00 ppb 25.00 ppb 25.00 ppb 25.00 ppb 25.00 ppb 25.00 ppb 25.00 ppb 25.00 ppb 25.00 ppb 25.00 ppb 25.00 ppb 25.00 ppb 25.00 ppb 20.00 ppb 25.00 ppb 25.00 ppb 25.00 ppb 25.00 ppb 25.00 ppb 25.00 ppb q 96 85 94 81 75 99 73 80 85 95 98 93 97 92 82 96 71 89 99 98 82 97 99 87 86 93 81 92 99 99 98 96 80 95 85 89 93 98 94 99 66 -2_5,00_^Rb^^ ^ ^ 91 300651 Data Subject lb Validation CoBq;>ound ) 2,6-Dinitrotoluene ) Acenaphthylene } 3-Nitroaniline ) Acenaphthene ) 2,4-Dinitrophenol ) Dibenzofuran } 4-Nitrophenol } 2,4-Dinitrotoluene ) 2,3,4,6-Tetrachlorophenol ) Diethylphthalate ) 4-Chlorophenyl-phenylether ) Fluorene ) 4-Nitroaniline ) 2,4,6-Tribromophenol ) *IS/4 Phenanthrene-dlO ) 1,2-Diphenylhydrazine ) 4,6-Dinitro-2-methyIphenol ) Diphenylamine ) 4-Bromophenyl-phenylether ) Hexachlorobenzene ) Pentachlorophenol ) Carbazole } Phenanthrene ) Anthracene ) Fluoranthene ) Di-n-butylphthalate ) *IS/5 Chrysene-dl2 ) Pyrene ) Terphenyl-dl4 ) Butylbenzylphthalate } 3,3'-Dichlorobenzidine ) Benzo(a)anthracene ) bis(2-Ethylhexyl)phthalate ) Chrysene ) *IS/6 Perylene-dl2 ) Di-n-octylphthalate ) Benzo(b)fluoranthene ) Benzo(k)fluoranthene ) Benzo(a)pyrene ) Indeno(l,2,3-cd)pyrene ) Dibenz(a,h)anthracene ) Benzo(g,h,i)perylene R.T. Q ion 15.94 165.0 16.01 152.1 16.20 138.0 16.33 153.1 16.39 184.1 16.60 168.1 16.46 109.0 16.64 165.1 16.89 232.0 17.01 149.1 17.17 204.1 17.23 166.1 17.32 138.0 17.70 329.6 18.93 188.2 17.46 77.0 17.38 198.0 17.40 169.1 18.05 248.0 18.37 283.8 18.67 265.9 19.32 167.0 18.97'178.1 19.05'178.1 21.12^202.0 19.87 149.0 23.72 240.2 21.55^202.0 21.72 244.2 22.56 149.1 23.59 252.2 23.69'228.0 23.51 149.0 23.77/228.0 26.92 264.2 24.59 149.0 25.91'252.2 25.97^252.2 26.77/252.0 30.39'276.2 30.35'278.1 31.45/ 276.0 Area 26799 180088 32928 117872 8986M 149017 12100 36832 37138 157260 54223 113695 29532 24941 111496 200812 14833 76853 36359 53012 23368 145196 159298 159510 153520 266715 98539 159158 105320 104265 53953 138590 156178 124454 119849 252290 147770 139551 135406 170937 132349 135848M Cone 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 20.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 20.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 20.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 Units ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb q 96 97 96 94 99 74 91 96 93 79 91 90 86 87 90 91 85 93 92 95 94 97 95 96 98 97 96 94 95 96 95 88 91 96 96 97 90 94 91 87 « Conpound i s ISTD 300652 Data Subject To Valldatfon QUANT REPORT Operator ID: DAVID Output File: ''H055B::BQ ^ t a File: >H055B::D1 te: SSTDOSO (isc: 290-12-8V25 Quant Rev: 6 Quant Time: Injected at: Dilution Factor: INST B 950224 11:47 950224 10:59 1.00000 BTL/ 2 ID File: ID 8H::DB Title: SEMIVOLATILES BY SW846-8270/EPA 625 Last Calibration: 950224 11:45 1) 2; 3; 4) 5) 6; 7; 8] 9] 10] 11] 12; 13; 14 15j M' m n, 19] 20, 21 22 23; 24; 25; 26, 27] 28] 29, 30, 31] 32 33 34] 35; 36] 37, 38 39 40 41 m W Compound *IS/1 l,4-Dichlorobenzene-d4 Pyridine N-Nitrosodimethylamine Phenol-d5 2-Chlorophenol-d4 2-Fluorophenol Aniline Phenol 2-Chlorophenol bis(2-Chloroethyl)ether 1 1,3-Dichlorobenzene 1 1,4-Dichlorobenzene 1 l,2-Dichlorobenzene-d4 1 1,2-Dichlorobenzene 1 Benzyl alcohol 1 2,2'Oxybis-(1-chloropropane) 1 2-Methylphenol 1 N-Nitroso-di-n-propyleunine \ Hexachloroethane 1 4-Methylphenol 1 *IS/2 Naphthalene-d8 1 Nitrobenzene-d5 1 Nitrobenzene 1 Isophorone 1 2-Nitrophenol 1 2,4-Dimethylphenol 1 bis(2-Chloroethoxy)methane 1 2,4-Dichlorophenol 1 Benzoic acid 1 1,2,4-Trichlorobenzene 1 Naphthalene 1 4-Chloroaniline 1 Hexachlorobutadiene \ 4-Chloro-3-methylphenol \ 2-Methylnaphthalene \ *IS/3 Acenaphthene-dlO 1 Hexachlorocyclopentadiene 1 2,4,6-Trichlorophenol 1 2,4,5-Trichlorophenol \ 2-Fluorobiphenyl ) 2-Chloronaphthalene \ 2-Nitroaniline i Dimethylphthalate R.T. 10.91 6.42 6.47 10.35 10.60 8.88 10.43 10.38 10.62 10.50 10.85 10.93 11.23 11.26 11.16 11.40 11.35 11.64 11.78 11.59 13.12 11.90 11.93 12.30 12.47 12.49 12.66 12.88 12.67 13.03 13.16 13.26 13.42 14.08 14.36 16.27 14.74 14.89 14.97 15.02 15.24 15.46 15.77 Seem/ 639 118 123 575 603 403 584 578 606 592 632 642 677 680 668 696 691 724 740 718 896 754 758 801 821 823 842 868 844 886 900 912 931 1007 1040 1262 1084 1102 llll 1116 1142 1168 1204 Area 49355 88077 61551M 93564 75298 79894 143486 105499 78341 94590 84047 86913 52229 81476 48127 103553 70785 62956 36350 74346 168605 82279 83124 173878 33979 56265 123379 56502 37197 64622 204679 88195 34757 65891 113030 76650 25982 36198 39154 125809 113683 41187 141879 Cone 20.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 20.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 20.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 Units ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb - - ' 96 85 94 81 75 99 73 80 85 95 98 93 97 92 82 96 71 89 99 98 82 97 99 87 86 93 81 92 99 99 98 96 80 95 85 89 93 98 94 99 66 91 Data Subje ctToVaW idation 300653 Compound ) 2,6-Dinitrotoluene ) Acenaphthylene ) 3-Nitroaniline ) Acenaphthene ) 2,4-Dinitrophenol ) Dibenzofiiran ) 4-Nitrophenol ) 2,4-Dinitrotoluene ) 2,3,4,6-Tetrachlorophenol ) Diethylphthalate ) 4-Chlorophenyl-phenylether ) Fluorene ) 4-Nitroaniline ) 2,4,6-Tribromophenol ) *IS/4 Phenanthrene-dlO ) 1,2-Diphenylhydrazine ) 4,6-Dinitro-2-methyIphenol ) Diphenylamine ) 4-Bromophenyl-phenylether ) Hexachlorobenzene ) Pentachlorophenol ) Carbazole ) Phenanthrene ) Anthracene ) Fluoranthene ) Di-n-butylphthalate ) *IS/5 Chrysene-dl2 ) Pyrene ) Terphenyl-dl4 ) Butylbenzylphthalate ) 3,3'-Dichlorobenzidine ) Benzo(a)anthracene ) bis(2-Ethylhexyl)phthalate ) Chrysene ) *IS/6 Perylene-dl2 ) Di-n-octylphthalate ) Benzo(b)fluoranthene ) Benzo(k)fluoranthene ) Benzo(a)pyrene ) Indeno(1,2,3-cd)pyrene ) Dibenz(a,h)anthracene ) Benzo(g,h,i)perylene R.T. 15.94 16.01 16.20 16.33 16.39 16.60 16.46 16.64 16.89 17.01 17.17 17.23 17.32 17.70 18.93 17.46 17.38 17.40 18.05 18.37 18.67 19.32 18.97 19.05 21.12 19.87 23.72 21.55 21.72 22.56 23.59 23.69 23.51 23.77 26.92 24.59 25.91 25.97 26.77 30.39 30.35 31.45 Scan/ 1223 1231 1254 1269 1275 1300 1284 1305 1334 1347 1366 1373 1383 1428 1570 1400 1390 1393 1468 1505 1540 1616 1575 1584 1825 1679 2127 1875 1895 1992 2112 2123 2102 2132 2497 2228 2381 2388 2480 2899 2895 3022 Area 26799 180088 32928 117872 8986M 149017 12100 36832 37138 157260 54223 113695 29532 24941 111496 200812 14833 76853 36359 53012 23368 145196 159298 159510 153520 266715 98539 159158 105320 104265 53953 138590 156178 124454 119849 252290 147770 139551 135406 170937 132349 135848M Cone 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 20.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 20.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 20.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 Units ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb q 96 97 96 94 99 74 91 96 93 79 91 90 86 87 90 91 85 93 92 95 94 97 95 96 98 97 96 94 95 96 95 88 91 96 96 97 90 94 91 87 * Conpound i s ISTD 300654 Data SubjeclTo V'alidation eMtfnuIng Callbrttfon KL ^JPsont Hot Centraeterx PACE r K t Hot imtniMnt lOi 5988-11 C*(lhr*tl«n ftatet tZ/M/VS TiMt 10tS9 Ufaeratery U i MKSSi Inf t U l Caltfar»t)en tattt 02/02/95 MiniBJi IF for SPCC i t 0.05 (il % Olff fer CCC t* SOX Ceapotfid Pyridifw il-lf i troMdiwthylMiInt Mi«nol*dS 2-Chlorephtnol-d4 2-Fluor«phanol AnfKiw Phanol 2-Chler«fih«»l feU(2-ChlorMthyl)«thir 1,3-0 < ch I erobtnzww l.i-Dieiilerotwruant 1.2-Dtehlerob«a«n*-d4 1,2-Dichlorobtnzarw •cnzyl alcohol 2,2'Oxyb!i-C1-chleropropMW) •-U i troso-di •n-propy I onf ne Ntxachloroathcne 4-Ntthylphonot M<trobonz«n*-d5 Oitrobonzam iMphorcrw 2-Hltrophanol 2.i-0<Mthylphonol b{t(2-Chloro«thoxy)wthanc 2,«*Diehlerophinol ••nzotc acfd 1,2,4-Trichlorobcnztnc Kaphthalont 4-Chloroanilini Nixachlorobutadiant 4-Chloro-S-Mthylph«nol IF IF 1.01438 1.42765 .66304 .99769 1.48923 1.51659 1.19953 1.22051 1.12896 1.29501 2.24426 2.32578 1.62092 1.71004 1.21281 1.26984 1.39292 1.53322 1.31130 1.36235 1.34158 1 .80913 1.40878 .84658 1.23820 1.32065 .73778 1.37092 1 1.05586 1 .91209 1 .58790 1.10887 1 .41102 .40829 .80030 .17343 .27375 .49769 .26488 .17640 .29482 .90341 .41357 .16955 .28719 .78010 1.67850 1.14736 1.02046 ' .58920 1.20508 .39040 .39U1 .82502 .16122 .26697 .58541 .26809 .17649 .30662 .97116 .41847 .16492 .31264 «DHf CCC SPCC 40.74 50.47 1.84 1.75 14.71 3.63 5.50 4.70 10.07 3.89 5.01 4.63 6.66 5.74 22.U >«.67 ''^11.88 .22 8.68 5.02 3.40 3.09 7.04 2.48 17.63 1.21 .06 4.00 7.50 1.19 2.73 8.86 y • / • ^ • a / • ^ y * y : / ir IF • iMponct Factor froa dally Standard filt at 25.00 PPB IF • Avtragt Rasponac Factor froai Initial Calibration For* VI XDiff • X Oiffcrenct froai original average or curve Calibration Check Coopomds (•) SPCC • Systtn Perfornance Check Coopotfids (•*) For* VII 300655 Data Subject To Validation Continuing Calibration Okack ttl .\ ^mcanti Not Cantraetort PACE ract Mot InatrUMnt lOi 5988-1 Calibration Mto: Se/24/95 Tiaat 10:59 Uberatory lOt HI055B Initial Calibration Oata: 02/02/95 ainlBH IF fer SPCC ia 0.05 MaxlBUB X Biff for CCC ia SOX Coapewid 2-Nethylnaphthalana Naxachlerecyclepantadiane 2.4,6-Trichlorflphanol 2,4.5-Trichlerephanol 2-Fluorebiphanyl 2-Chlorenaphthalana 2-Mitreanillne Oiaethylphthalata 2,6-Oinltrotoluanc Acanaphthylana S-Nltroanlllne Acanaphthane 2.4-Oinltrophenol Oibanzofuran 4-llitrephanol ||.4-Dlnitrotoluane R,3,4,6-Tetrachlerophanol Oiethylphthalata 4-Chlorophonyl-phenylether Fluorene 4-NitroanllIne 2.4.6-Tribrowphenol 1,2-Diphenylhydrazina 4,6-Dinltro*2-Mthylphenol Oiphenylaaine 4-Broaaophenyl-pheny I ether Nexachlorobenzene Pentachlorophenol Carbazole Phenanthrene Anthracene Fluoranthene IF IF »iff CCC SPCC .55293 .53631 ^ . 0 1 J2670 .27118' .38270 .37780 .41683 .40865 1.25887 1.31308 1.08947 1.18652 .42902 .42987 1.38792 1.48080 .31656 .27970 1.80475 1.87959 .36172 .34367 1.12923 1.23024 17.00 •• 1.28 • y ^ 1.96 4.31 8.91 .20 6.69 11.64 4.15 4.99 . 8.94'^ • .15628 .09379^ 39.99 •• 1.48924 1.55530 .17060 .12629' .39411 .38442 .37045 .38761 1.46478 1.64133 .54579 .56593 1.11196 1.18664 .32391 .30823 .22662 .26031 1.30901 1.44086 .15078 .10643 .52841 .55143 .23966 .26088 .31426 .38037 .18396 .16767 1.00492 1.04180 1.10125 1.14299 1.11046 1.1U51 l . m S I 1.10153 ^ 4 . U '25.97 •• 2.46 4.63 12.05 3.69 6.72 4.84 14.86 10.07 29.42 • 4.36. • 8.85 21.04^ 8.86^* 3.67 3.79 3.07/ 6.13 • m IF • lesponae Factor froai daily atandard file at 25.00 PPB IF • Average leaponae Factor froa Initial Calibration Fora VI IDiff • X Difference froa original average er curve ^ • Calibration Check Compounds (*) SPCC • Systea Perfonnance Check Conpounds (**) Fora VII 300656 Csntinuins Calibration Oiack •SL Mo: Cantrsctor: PACE ^jjPntraet Nos ImtrtMnt 10: 5988-1 Calibration Date: 02/24/95 Tiaa: 10:59 Laberatery ID: >«055B Initial Calibration Data: 02/02/95 UlnlauB IF fer SPCC ia 0.05 Maxiaji X Diff fer CCC ia SOX Caapound Oi-n-fautylphthalate 7arphanyl>d14 •utylbenzylphthalata 3,3'-0ichlerebenzidine •enzo(a)anthracane bi8(2-Ethylhaxyl}phthalate Chrysene Di-n-octylphthalate •anzo(b)fluoranthene •anzo(k)fluoranthene •anzo(a)pyrone Indeno(1,2,3-cd)pyrene D{benz(a,h)anthracene •anzo{g,h,i)perylene IF IF 1.67332 1.91372 1.28356 1.29214 .81891 .85505 .76622 .84649 .39300 .43802 1.08622 1.12516 1.08571 1.26795 1.01148 1.01039 1.62082 1.68405 1.05431 .98637 .92652 .93151 .90934 .90384 1.04677 1.14102 .81469 .883U .88047 .90679 »lff CCC SPCC 14.37 .67 4.41 10.48 11.46 S.58 16.79 .iy 3.90'• 6.44 .54 . .60*^ • 9.00 O.U 2.99 IF > lesponaa Factor frca dally atandard file at 25.00 PPB IF . Average lesponaa Factor froa Initial Calibration Fora VI XDiff - X Diffaranca frea original average or curve • Calibration Check Coeipowds (•) SPCC - Systen Perforwncc Check Conpounds (•*) Fora VII Page 3 ef 3 • 300657 Data Subject To Validation TOTAL ION CHROHATOCBAM 800 1000 . 1500 , B O p O . 25,00 31 8O00O0- 7O00O0 6OO0O0 SO0OOO 4O0OO0 300000 200000- leoeoo-i i y '•1-9. \ zi "ife y i I ' / B r "A " iV ' A " 'I'a! ' ik'' ^fa'' 'ab' ' 2^" ' W 2^'' ab'' bb' ' 3^ Quant Output File: *H055K::BQ Data File: >H055K::D1 Hane: 12244WB5 Misc: BNA LAB BLANK WATER BATCH / 12244 INST H Id File: ID_SH::DB Title: SEMIVOLATILES BY SW846-8270/EPA 625 Last calibration: 950224 11:45 Operator ID: DAVID Quant Tine: 950224 19:01 Injected at: 950224 18:27 BTL/ 9 300658 aiidation QUANT REPORT Operator ID: DAVID Output File: ^H055K::BQ |Data File: >B055K::D1 ^Nane: 12244WB5 Misc: BNA LAB BLANK WATER Quemt Rev: 6 Quant Time: Injected at: Dilution Factor: BATCH / 12244 INST H 950224 19:01 950224 18:27 1.00000 BTL/ 9 ID File: ID_8H::DB Title: SEMIVOLATILES BY SW846-8270/EPA 625 Last Calibration: 950224 11:45 1] 4 5] 6] 13 21] 22] 36 40] 57] 58] 70] 73. 77. 79. Compound 1 *IS/1 l,4-Dichlorobenzene-d4 1 Phenol-dS 2'Chlorophenol-d4 1 2-Fluorophenol 1,2-Dichloroben2ene-d4 I *IS/2 Naphthalene-d8 1 Nitrobenzene-dS *IS/3 Acenaphthene-dlO 2-Fluorobiphenyl 1 2,4,6-Tribronophenol *IS/4 Phenanthrene-dlO 1 *IS/5 Chry6ene-dl2 1 Terphenyl-dl4 1 bis(2-Ethylhexyl)phthalate [ *IS/6 Perylene-dl2 R.T. 10.93 10.38 10.62 8.90 11.25 13.14 11.92 16.29 15.03 17.72 18.94 23.74 21.75 23.53 26.94 Scan/ 648 585 612 412 686 905 763 1272 1125 1438 1580 2137 1906 2113 2508 Area 49108 262128 208120 196707 62936 166618 142177 78171 178479 70450 110602 99731 168690 23040 118930 Cone 20.00 70.39 69.45 61.86 30.28 20.00 43.71 20.00 34.78 69.24 20.00 20.00 39.56 3.64 20.00 Units ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb q 95 98 85 77 91 98 88 89 94 89 85 96 99 81 92 * Conpound is ISTD 300659 Data Subject To Validation RETERENCE STRNDRRD SPECTRUM Fila >pe9ee B N nix-i Bpk Rb lee. 149 LOT 33356 SUB NRM INST Scan 28.68 X6^ 57 71 fA4 " 3 1 3 2 / / 40 88 n^i^r •"! •* £952 • in. -180 188 .[ / "•. I I 279 128 I ' I ' I • 168 288 I I I < 248 l-r-V ' T I I I I I I 288 328 ' I ' l 368 SAMPLE SPECTRUM (BRCKGROUND SUBTRACTED) rila >H855K 12244UB8 Bpk Rb 12676. 149 BNA LAB BLRNK UATER BAT SUB leeee-• 57 7 , ^ y- 113^2^ jf,J,.|:,,,>/..r^. 48 88 128 1 9 1 287 253 / \ 328 / I' •" I ^ I ' ' I ' — I — ' 128 168 288 -I—'—I—'—I I I 248 T—1 1 1 • I 288 328 Scan 2 3 . 5 3 355 / • ' I ' 2113 • i n . 1-188 368 SAMPLE SPECTRUM (UNALTERED) F i l e >He55K 12244UB5 Bpk Rb 1 2 6 7 6 . BNA LAB BLANK UATER BAT 149 18888- 57 48 / 71 U 113133 . / / r ee 128 I • I 1 6 6 / 1915f^ "s! ''< 328 / ' r ' I 280 I '' I ' I ' I ' I ' I 246 266 326 Scan 2 3 . 5 3 355 / 1 ' 1 2113 tlin. 188 368 D a t a F i l e : > H 0 5 5 K : : D 1 Quant O u t p u t F i l e : ' ' H 0 5 5 K : : B Q Name: 12244WB5 M i s c : BNA LAB BLANK WATER BATCH # 12244 INST H BTL# 9 Ouant T i m e : 950224 1 9 : 0 1 Ouant ID F i l e : ID_SH::DB I n j e c t e d a t : 960224 1 8 : 2 7 L a s t C a l i b r a t i o n : 950224 1 1 : 4 5 Compound No: 77 Compound Name: bis(2-Ethy I hexyI)phtha I atc Scan Number: 2 113 Retention Time: 23.53 min. Quant Ion: 14 9.0 Area: 23040 Concentration: 3.64 ppb q-vaIue: 8 1 300660 .H^. Subiect lb Validation ^ i 0.\.'mA ^-»V> 1- TOTAL ION CHRONATOGRAH File >H0S5M 35.0-510.0 enu. SyUAMei HE5 MM0005 UATER' S00 1000 , .1500 2000 2500 3000 6O000O-: 550000-f 5 00000-: 450000-: 400000 350000: 300000-= 250000^ 200000: 150000-: 100000-: 50000 0 J 1 4 lis ' ib 7 J 1 ^ fi s- CM "E. S t^ ;i3^TJrfi,-'"^'e-'irn 3b ' 3^ Data File: >H055M::D2 Quant Output File: Nane: SVWAWOl HLA Misc: MW0005 WATER BATCH / 12244 INST H Id File: ID_SH::DB Title: SEMIVOLATILES BY SWB46-8270/EPA 625 Last Calibration: 950224 11:45 Operator ID: DAVID Quant Tine: 950224 20:28 Injected at: 950224 19:54 ^H055M::BQ BTL/11 3 0 0 6 6 1 Data Subject TcV2nd2t>on QUANT REPORT m. Operator ID: DAVID putput File: *H055M::BQ ata File: >H055M::D2 Nane: SVWAWOl HLA Misc: MW0005 WATER Quant Rev: 6 Quant Tine: Injected at: Dilution Factor: BATCH / 12244 INST H 950224 20:28 950224 19:54 1.00000 BTL/11 ID File: ID_SH::DB Title: SEMIVOLATILES BY SW846-8270/EPA 625 Last Calibration: 950224 11:45 1) 4) 5) 6) 13) 21) 22) 36) 40) 57) 58) 70) 73) 77) l79) Conpound *IS/1 l,4-Dichloroben2ene-d4 Phenol-d5 2-Chlorophenol-d4 2-Fluorophenol 1,2-Dichlorobenzene-d4 *IS/2 Naphthalene-d8 Nitrobenzene-d5 *IS/3 Acenaphthene-dlO 2-Fluorobipheny1 2,4,6-Tribronophenol *IS/4 Phenanthrene-dlO *IS/5 Chrysene-dl2 Terphenyl-dl4 bis(2-Ethylhexyl)phthalate *IS/6 Perylene-dl2 R.T. 10.91 10.36 10.60 8.89 11.24 13.12 11.90 16.27 15.02 17.70 18.92 23.71 21.73 23.51 26.92 Scan/ 644 580 608 409 682 901 759 1267 1121 1433 1575 2131 1901 2107 2503 Area 49502 101563 92201 64167 58735 163628 130828 73484 160848 13929 106328 103198 142005 26388 122291 Cone 20.00 27.06 30.52 20.02 28.03 20.00 40.96 20.00 33.34 14.56 20.00 20.00 32.19 4.03 20.00 Units ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb q 96 98 86 69 96 98 84 82 91 95 93 96 94 85 97 * Conpound is ISTD 300662 SsJbied: To VaHdatio? RErERENCE STANDARD SPECTRUM File >P0926 BN ttlX-l Bpk Ab 188. 149 LOT 33358 SUB NRM INST Scan 28.68 188- 57 71 113132 2952 min. •188 186 48 88 128 168 279 I ' l l 288 248 -t-r-\ I ' I ' I ' I ' I 286 326 368 i-e SAMPLE SPECTRUM (BACKGROUND SUBTRACTED) File >He55M SVUAU61 Bpk Ab 14373. HLA 149 16606- 5T / 71 113 147 f.l4>,>...,^. > •^1 • I T ' I 46 88 Mueees SUB £69 / UATER BATCH Scan 23.51 2168 min. 180 279 \ 343 / 1 — r ^ — ' — I — ' — I • I — ' I ' l — I — I — ' — I — " — I — I — I — " — r — " — I — I — r 128 166 266 £46 286 326 366 i'-Q SfldPLE SPECTRUM <UHflLTERED> File >H655M SVUAU61 HLA Bpk Ab 14373. 149 ie00&; ' ^ 57 71 / y 113 133 1 l.i.i ...^.. / . 1 1 I 1 . , . , . , . , . , . 46 86 126 166 Mueees 191 2p7 1 ' 1 ' 1 ' 1 ' 266 246 WATER £81 1 ' 1 ' J 286 BfiTCH Scan 2168 23.51 min. 343 ' 1 ' 1 ' 1 ' 1 ' 326 366 [-186 -6 D a t a F i l e : >H055M::D2 Ouant O u t p u t F i l e : " H 0 5 5 M : : B Q Name: SVWAWOl HLA M i s c : MW0005 WATER BATCH # 12244 INST H BTL# 11 Quant T i m e : 950224 2 0 : 2 8 Quant ID F i l e : ID_SH::DB I n j e c t e d a t : 950224 1 9 : 5 4 L a s t C a l i b r a t i o n : 950224 1 1 : 4 5 Compound No: 77 Compound Name: bis(2-EthyIhexyI)phtha I ate Scan Number: 2 107 Retention Time: 23.51 min. Quan t Ion: 149.0 Area: 26388 Concentration: 4.03 ppb q-vaIue: 85 300663 TOTAL ION CHRONATOGRAM 500 1O00 , .1500 , 2000 . 25O0 3000 6O0O00- 550000- 900000- 450000 400000- 350000- 300000- 250000- 200000- 15OOOO 100000 50000- O- I r^ ~ 1 5 I « 5 IK IS 2r .& %[/; •'55? '&^ % acb |f,.^jJHJJ^., ^Ji'^iJ' 1 iV'l ^b- r 4 ' i 'Jv • '2'e"' 2b' • bb'' b Data File: >H055N::D2 Nane: SVWAW02 HLA Misc: RBGW02 WATER BATCH / 12244 INST H Quant Output File: *H055N::BQ BTL/12 Id File: ID_SH::DB Title: SEMIVOLATILES BY SWB46-8270/EPA 625 Last Calibration: 950224 11:45 Operator ID: DAVID Quant Tine: 950224 21:12 Injected at: 950224 20:38 300664 QUANT REPORT m. Operator ID: DAVID putput File: *H055N::BQ ata File: >H055N:;D2 Nane: SVWAW02 HLA Misc: RBGW02 WATER Quant Rev: 6 Quzmt Tine: Injected at: Dilution Factor: BATCH / 12244 INST H 950224 21:12 950224 20:38 1.00000 BTL/12 ID File: ID__SH::DB Title: SEMIVOLATILES BY SW846-8270/EPA 625 Last Calibration: 950224 11:45 1] 4] 5j 6] 13] 21] 22] 36] 40] 57] 58] 7o; 73] 77. j s : Conpound *IS/1 l,4-Dichlorobenzene-d4 Phenol-d5 2-Chlorophenol-d4 2-Fluorophenol 1,2-Dichlorobenzene-d4 *IS/2 Naphthalene-d8 Nitrobenzene-d5 *IS/3 Acenaphthene-dlO 2-Fluorobiphenyl 2,4,6-Tribronophenol *IS/4 Phenanthrene-dlO 1 *IS/5 Chrysene-dl2 i Terphenyl-dl4 ) bis(2-EthyIhexyl)phthalate ) *IS/6 Perylene-dl2 R.T. 10.91 10.36 10.59 8.88 11.23 13.11 11.90 16.27 15.01 17.70 18.92 23.71 21.72 23.50 26.92 Scan/ 644 580 607 408 681 900 759 1267 1121 1433 1575 2132 1901 2108 2504 Area 45418 200351 157897 134308 46447 165011 114808 77641 161984 72362 115180 102063 160477 13331 109873 Cone 20.00 58.17 56.97 45.67 24.16 20.00 35.64 20.00 31.78 71.61 20.00 20.00 36.78 2.06 20.00 Units ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb q 93 95 85 68 96 98 80 81 95 94 86 95 97 84 97 * Conpound is ISTD 300665 Data Subject ^oV3Ud£:^^c REFERENCE STANDARD SPECTRUM File >P8928 BN MlX-1 Bpk Ab 188. 149 LOT 33358 SUB NRM INST Scan 28.68 188- 2952 lain. -188 188 279 I ' I • I • I ' I I i""i I I I • I ' I ' r ' r r - l ' I ' I ' I ' I 48 88 120 168 286 248 288 328 368 i-H- SAMPLE SPECTRUM <BACK6R0UND SUBTRACTED) File >H855N SVIJAU82 Bpk Ab 5665. HLA 149 RBBuea SUB UfiTER BfiTCH Scan 23.50 4660- 8^ 57 70 y i Cl 112 135 48 - 1 — I — r 88 2107 tnin. 1-100 1„207 253 281 128 168 260 246 1 — I — 1 — I — I — I — 1 — 1 — 1 — 1 — 1 — r 286 328 360 SAMPLE SPECTRUM (UNALTERED) File >H Bpk fib 4066- 655N SVUfiU62 5665. V JZ" 96 135 y J I...V y . ( HLA 149 1 1 1 > 1 • 1 1 1 1 1 . , , • 6 86 126 166 RBGU02 UATER l„p- "^^ 231 1 ' 1 ' 1 ' 1 ' 1 ' 1 ' 1 206 £46 266 BfiTCH Scan 2167 23.56 min. -160 -Cr ' 1 ' 1 • 1 • 1 • 326 366 Data File: >H055N::D2 Quant Output File: "H055N::BQ Name: SVWAW02 HLA Misc: RBGW02 WATER BATCH # 12244 INST H BTL#12 Quant Time: 950224 21:12 Quant ID File: ID_SH::DB Injected at: 950224 20:38 Last Calibration: 950224 11:45 Compound No: 77 Compound Name: bis(2-EthyIhexyI ) phtha I ate Scan Numbe r: 2 108 Retention Time: 23.50 min. Quant I on: 149 .0 Area: 1333 1 Concentration: 2.06 ppb q-va I ue : 84 300666 FMGR : TUNER,"DPTPr GC/MS PERFORMANCE STANDARD I - '• Decafluorotriphenylphosphine (DFTPP) Ion Abundzuice n/z Criteria 51 30-60% of mass 198 68 Less than 2% of mass 69 69 (reference only) 70 Less thzm 2% of mass 69 127 40-60% of aass 198 197 Less than 1% of aass 198 198 Base peak, 100% relative abundance 199 5-9% Of mass 198 275 10-30% Of aass 198 365 Greater than 1% of aass 198 441 0-100% of aass 443 442 Greater than 40% of aass 198 443 17-23% Of aass 442 % Relative Abundance Base Appropriate Peak Pe2ik Status 31.59 0.00 49.76 0.00 40.01 0.00 100.00 6.16 21.93 2.42 12.69 75.58 14.29 31.59 0.00 49.76 0.00 40.01 0.00 100.00 6.16 21.93 2.42 88.81 75.58 18.91 Ok Ok Ok Ok Ok Ok Ok Ok Ok Ok Ok Ok Ok Injection Date: 02/27/95 Injection Tine: 12:17 Data File: >H058A Scan: 364 300667 \Zz^ •"- F i l e >HOS8A 9On0 Bpk Alt XOe. l i e : IBO: 9 » : »FTPP I SO: 1 40^ 30^ 0 290-14-PERF SUB NRH 198 INST H ^ 5 1 w! 5 0 M 127 Jki-M 1 0 0 , 166 i,v^j'^,,f,,fc.t>t..Af...i)i,4tli. 1 5 0 2 0 0 2 5 0 255 275 / 442 : " < l l A t % 296 3 2 3 365 *! 1 1 ^ 1 1 1 ' n ' l l l i V » ^ I f i ^ 11 t'l I I I I i i I I n 11 r I 3 0 0 3 5 0 4 0 0 Scan 3 6 4 7 . 0 9 Min. 1:110 ^ 0 0 ^90 •fio i70 ^o i50 r40 E30 ^o rlO 0 Data F i l e n a m e : >H058A::D2 Nane: 50ng DFTPP Misc: 290-14-PERF INST H BTL/ 1 Operator ID: DAVID SUPER GRP. Analysis Date/Tine : 2/27/95 12:17 300668 jwiaxj^vxi* WBY^e/xiae: atf21 f 9 5 1 2 t l 7 Data Filenane and Sanple ID: H058A 364 50ng DFTPP SUB MRM lie: >H058A Scan #: a/z « • — • ^ 35.70 38.05 38.95 49.95 50.95 51.95 53.05 53.30 55.95 56.95 60.95 62.05 62.95 64.20 64.70 65.20 68.95 73.05 74.05 74.95 76.05 ^77.05 78.05 78.95 80.05 81.05 81.95 83.20 84.30 85.05 85.95 91.05 91.95 92.95 94.00 94.40 97.90 Int. .312 .211 2.563 7.942 31.588 1.256 .224 .233 .833 2.642 .526 .560 1.179 .231 .302 .632 49.764 .074 1.774 5.905 1.735 42.599 3.081 2.317 2.145 2.462 1.069 .860 .113 .573 .582 .415 .826 3.487 .256 .135 2.472 B/Z 99.00 101.00 102.90 104.00 105.00 107.00 108.00 109.00 110.00 111.00 114.50 116.00 117.00 118.00 121.90 123.00 124.00 124.75 127.00 128.00 129.00 130.00 132.00 134.00 135.15 141.00 146.00 147.00 148.00 150.25 151.15 153.00 154.15 154.90 156.00 157.15 158.00 364 Int. »«>_«_..• 1.968 1.280 • 644 .580 .708 10.527 1.445 .214 28.130 3.357 .069 .580 5.873 .482 .585 1.226 .410 .393 40.006 3.457 15.535 1.297 .373 .258 .747 1.609 .364 1.049 .993 .140 .437 .781 .460 .818 1.607 .413 .469 290 I Retn. a/z 160.00 160.90 162.90 164.90 166.15 167.00 168.00 170.65 171.90 173.00 174.00 175.00 176.00 177.00 179.00 180.00 181.00 182.00 185.00 186.00 187.00 189.00 191.90 193.00 196.00 198.00 199.00 200.00 201.40 201.90 203.00 204.00 205.00 206.00 207.00 210.00 211.75 -14-PERF - tiae: Int. .575 .939 .066 .359 .546 2.801 1.268 .096 .211 .423 .627 1.214 .447 .799 2.098 1.718 .602 .265 1.659 9.094 2.511 .491 .541 .585 2.882 100.000 6.160 .627 .489 .268 .327 1.838 3.887 18.606 2.111 .425 .283 7.09 a/z 212.90 217.00 218.00 221.00 223.15 224.00 225.15 225.90 227.00 229.15 231.15 233.75 235.00 236.90 241.00 242.15 243.00 244.15 245.00 246.00 249.00 255.00 256.00 257.00 258.15 259.15 265.00 273.15 274.00 275.15 275.90 277.00 278.15 292.95 295.95 297.05 INST Int. »—»—»" .147 4.757 .317 4.278 1.007 10.684 3.337 .192 3.091 .573 .393 .258 .236 .467 .246 .727 .870 9.048 1.398 1.209 .322 47.494 7.254 .514 2.366 .302 .742 1.204 3.172 21.928 2.718 1.671 .300 .528 4.381 .654 H ^»/2 302.95 309.95 314.05 314.95 315.95 316.20 320.30 320.95 321.20 321.55 323.05 323.95 326.95 328.20 332.95 333.95 335.05 345.95 352.95 354.05 364.95 365.95 371.05 371.95 373.05 402.05 402.95 403.95 420.95 422.05 423.05 423.95 441.05 442.05 443.05 443.95 Int. »••>»••• .892 .074 .359 .754 .246 .236 .054 .236 .221 .150 2.184 .256 .273 .150 .179 1.376 .491 .506 .673 1.273 2.415 .167 .140 .875 .344 .536 .590 .442 .346 .774 3.981 .678 12.694 75.585 14.294 1.071 Data Sviby 300669 0X2> >BBLKC PEND2 REPRT OPTIONS: REPRT OPTIONS: 013) >HBLKD PEND2 REPRT OPTIONS: REPRT OPTIONS: Label Meth:5, Only types:T Label Meth: 5, Only types:T 12 2 M M M N N Dil-1.00000 BG Sub, Qion replaces Scan/ 13 2 N N N N N Dil«l.00000 BG Sub, Qion replaces Scan/ ID SH::DB ID S H : : D B End of seqpience f i l e . i00670 Data Subject To Validation QUANT REPORT if Operator ID: DAVID Output File: ''HD&8A::BQ ata Fi le: >H058A::D2 ame: 60ng DFTPP isc: 290-14-PERF Quant Rev; 6 Ouant Time: Injected at: Dilution Factor: INST H 950227 12:33 960227 12:18 1.00000 BTL# 1 ID File: ID_DFT::DB Title: D F T P P / B E N Z I D I N E / P E N T A C H L O R O P H E N O L PERFORMANCE Last Calibration: 950227 12:32 Compound R.T. Q Ion Area Cone Uni ts 1) •IS#4 Phenanthrene-dlO 2) Pentachlorophenol 3) Benz idine 6.84 188.2 6.63 265.9 8.60 184.2 182208 44168 93079 20.00 ppb 25.00 ppb 25.00 ppb 66 95 98 « Compound is ISTD 300671 Data Subject To Validation TOTfiL ION CHROnfiTOGRfitt File >He58R 35.e-5ie.e A*u. sens DFTPP TIC 2$fi-l4-PERr eeeeee- sseeee- 508808- • 458000- 408800- 358880- seeeeo- £56066- Se6666- 156066- 106660- 50660- 0- 180 200 300 408 600 608 700 800 • . • . I • 1 . • I . • • • I I • • . • I • • • . I • • • • 1 1 1 1 • I • • . • r I • • . • r . . • . I • • • • I • • .6 T E I r I I I I • l| I I I I i I I I I I I I I I I I •' I I T I 4." " " 5.6 6.6 7.6 i' I 11 I I I n I I 1 1 I 8.6 'I T-l J f W t ' ^ ' i I y I I I t I I I I I I I I I 9.6 16.6 11.6 Data File: >H058A::D2 Name: SOng DFTPP Misc: 290-14-PERF Quant Output File: ^H058A::BQ INST H BTL# 1 Id File: ID_DFT::DB Title: DFTPP/BENZIDINE/PENTACHLOROPHENOL PERFORMANCE Last Calibration: 950227 12:32 Operator ID: DAVID Quant Time: 950227 12:33 Injected at: 950227 12: 18 300672 '^ata Subject To Validation REFERENCE STfiNDRRD SPECTRUH File >He99P BENZIDINES SDT Bpk fib 100. 102e-£l-BENZ-50 SUB NRM 100- INST 8c«n £538 £4.97 ain. 184 " 188 39 5£ / 65 77 ' 1 9£ ,^,117 128 130 143 * i t n i|N'irt'|i'i'ii (itAi iivirin'nivi'i III iWi'i iiil'/'iii I'f'f'ii n'lt'^' 40 60 80 1£0 r*h i \ ' i v i ' t f i i f t ' ] i l l l l 140 168 180 ^0 SAMPLE SPECTRUM (BfiCKGROUND SUBTRACTED) File >He58ft SOna DFTPP Bpk Rb 50560. 290-14-PERF SUB 40000- INST ScAn 539 8.60 nin. 184 hiee 39 62 y 7 65 77 / / y ^ t • ' I I • » » j * 'I *^ ^ "I I I I i ^ i ' t U i'i I 92 / J I. 117 128 136 143 - R, . , . , ^P \ \y 7 " ' " 46 60 80 166 " I '' ••l] M l - i 120 pP'l"l I I I ^ ^ ^ ^ T " ! ^ 146 J i|"l * 1'f'f^<^9 I'l 1-0 166 166 SAMPLE SPECTRUM (UNALTERED) Fil« >H058fi Seng DFTPP Bpk fib 56566. 296-14-PERF 46666- IHST Sc*n 639 8.66 nin. 184 106 39 52 .y 7 65 77 / / 46 'I''" r "' I' 66 92 / ..ll.. 117 128 136 143 ,-, . . - , ^r y yy 7 T ^^• 66 I » » I < > ^'i I t lys'i T-7 I rrT*T'Y-i 166 126 ' ' I ' " ' I ' " ' I ' " ' I ' ' " I " 146 160 186 Data File: >H058A::D2 Name: SOng DFTPP Misc: 290-14-PERF Ouant Time: 950227 12:33 Injected at : 950227 12: 18 Quant Outpu t File: INST H 'H068A::BQ BTL# 1 Quant ID File: ID_DFT::DB Last Calibration: 950227 12:32 Compound No: 3 Compound Name: Benzidine Scan Numbe r: 640 Retention Time: 8.60 m i n . Quant I on: 184.2 Area: 93079 Concentration: 26.00 ppb q-va I ue : 98 300673 Data SubiectToV.nda«on TOTfiL ION CHROMfiTOSROM 'CA'!-s. % J % Data File: >H058B::D2 Name: SSTDOSO Misc: 290-12-SV25 Quant Ou tput File INST H 'H058B::BQ BTL# 1 Id File: ID_SH::DB Title: SEMIVOLATILES BY SW846-8270/EPA 625 Last Calibration: 950224 11:45 Operator ID: DAVID Quant Time: 950227 14:50 I njected at : 950227 14: 16 3 0 0 6 7 4 a. u-«rtToVaV\dation DataSubjecnovd QUANT REPORT Operator ID: DAVID Output File: "H0586::BQ Data File: >HOSeB::D2 ame: SSTDOSO 'Misc: 290-12-SV25 Quant Rev: 6 Ouant Time Injected at; Di I ut ion Factor INST H 950227 15:01 960227 14:16 1.00000 BTL# 1 ID File: ID_SH::DB Title: SEMIVOLATILES BY SW846-8270/EPA 625 last Calibration: 950227 15:00 Compound R.T. 0 ion Area Cone Uni ts •IS#1 1,4-DichIorobenzene-d4 Pyr idine N-N i trosodimethylamine Phenol-dS 2-ChIorophenol-d4 2-FIuorophenoI An iIi ne PhenoI 2-ChIorophenoI b i s(2-ChIoroethy I )ether 1,3-Dichlorobenzene ' 1,4-Dichlorobenzene 1^2-Di chlorobenzene-d4 1,2-Dichlorobenzene BenzyI a Icoho I 2,2'Oxybis-( 1-chloropropane) 2-Me t hyIpheno I N-N i troso-di-n-propylamine HexachI oroe t hane 4-Me thylphenol •IS#2 Naphthalene-d8 N i t robenzene-d5 Ni t robenzene Isophor one 2-Ni trophenol 2,4-Dimethylphenol b i s(2-Chloroethoxy)me thane 2,4-D ichlorophenol Benzo i c acid 1,2,4-Tr ichlorobenzene Napht ha Iene 4-ChI oroan i I ine Hexachlorobutadiene 4-ChI oro-3-methyIphenoI 2-MethyInaphthalene •IS#3 Acenaphthene-dIO Hexachlorocyclopentadiene 2 ,4 ,6-Tr ichlorophenol 2,4, 5-Tr ichlorophenol 2-Fluorobiphenyl 2-Chloronaphthalene 2-N itroaniline Dimethylphthalate 1 0 . 8 3 ' 6 . 3 3 6 . 3 8 1 0 . 2 8 1 0 . 6 2 8 . 8 1 1 0 . 3 5 1 0 . 3 0 1 0 . 6 4 1 0 . 4 2 . 1 0 . 7 7 " 10.8 5' 1 1 . 15^ 1 1 . IS- I I . 0 8 - 1 1 . 3 2 1 1 . 2 8 , 1 1 . 5 6 1 1 . 7 0 11.6 1. 1 3 . 0 3 1 1 . 8 2 1 1 . 8 5 1 2 . 2 2 1 2 . 3 9 1 2 . 4 1 - 1 2 . 5 8 1 2 . 7 9 1 2 . 6 8 - 1 2 . 9 5 1 3 . 0 7 13. 18 13.34 1 3 . 9 9 14.27 16. 18 1 4 . 6 6 1 4 . 8 1 ^ 1 4 . 8 8 ' 14. #3 15. 15 1 5 . 3 8 1 5 . 6 8 1 6 2 . 0 7 9 . 1 7 4 . 0 9 9 . 0 1 3 2 . 0 1 1 2 . 0 9 3 . 0 9 4 . 0 1 2 8 . 0 9 3 . 0 ^ 4 6 . 0 1 4 6 . 0 1 6 2 . 0 1 4 6 . 0 108. 1 4 4 . 9 108.0 7 0 . 0 1 1 7 . 0 1 0 8 . 0 136. 1 8 2 . 0 7 7 . 0 8 2 . 2 1 3 9 . 0 1 0 7 . 0 9 3 . 1 1 6 2 . 0 1 2 2 . 0 1 7 9 . 9 128. 1 1 2 7 . 0 2 2 4 . 8 1 0 7 . 0 142. 1 1 6 4 . 2 2 3 6 . 8 , 1 9 6 . 0 ' 1 9 6 . 0 172. 1 1 6 2 . 0 6 5 . 0 163. 1 -. 39645 66074 42499M 73380 57417 66786 96235 78932 69439 69567 66559 6 9 9 4 1 41018 63590 36 168 72813 6 1 4 6 1 43666 27940 63883 131934 60527 60083 126525 24867 38393 93195 4143 1 23433 4 8 9 1 3 155695 64159 28210 46328 87700 62584 4628 24983 29272 93385 85212 2 8 2 6 1 105009 Data Subiec 2 0 . 0 0 2 5 . 0 0 2 5 . 0 0 2 5 . 0 0 2 5 . 0 0 2 5 . 0 0 2 5 . 0 0 2 5 . 0 0 2 5 . 0 0 2 5 . 0 0 2 5 . 0 0 2 5 . 0 0 2 5 . 0 0 2 5 . 0 0 2 5 . 0 0 2 5 . 0 0 2 5 . 0 0 2 6 . 0 0 2 5 . 0 0 2 5 . 0 0 2 0 . 0 0 2 5 . 0 0 2 5 . 0 0 2 5 . 0 0 2 5 . 0 0 2 5 . 0 0 2 6 . 0 0 2 6 . 0 0 2 5 . 0 0 2 5 . 0 0 2 5 . 0 0 2 5 . 0 0 2 5 . 0 0 2 5 . 0 0 2 6 . 0 0 2 0 . 0 0 2 6 . 0 0 2 5 . 0 0 2 5 . 0 0 2 5 . 0 0 2 5 . 0 0 2 6 . 0 0 2 5 . 0 P_ ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb P.P.b. 97 89 93 84 68 94 72 82 87 95 95 92 97 9 1 83 97 73 96 96 99 86 95 99 87 92 91 88 88 97 99 97 94 89 97 83 85 88 95 92 96 62 95 300675 it To Validation Compound R.T. Q Ion Area Cone Units 2,6-Di n i trotoluene Acenaphthylene 3-Ni t roan i I i ne Acenaphthene 2,4-Di nIt rophenoI Dibenzofuran 4-NItrophenoI 2,4-Di n i t rotoIuene 2,3,4,6-Tet rachIorophenoI Diethylphthalate 4-Chlorophenyi-phenylether FIuorene 4-Ni troani Iine 2,4,6-Tr i bromophenoI •IS#4 Phenanthrene-dlO 1,2-Di phenylhydrazine 4,6-D i n i t ro-2-met hyIphenoI D i phenyI ami ne 4-Bromophenyl-phenylether HexachI orobenzene PentachIoropheno I CarbazoIe Phenanthrene Anthracene Fluoranthene Di-n-butylphthalate •IS#5 Chrysene-d12 Pyrene TerphenyI-d 14 Butylbenzylphthalate 3,3'-Dichlorobenzidine Benzo(a)anthracene bi s(2-EthyIhexyl)phtha late Chrysene •IS#6 Perylene-d12 Di-n-octylphthalate Benzo(b)fluoranthene Benzo(k)fluoranthene Benzo(a)pyr ene IndenoC 1,2,3-cd)pyrene Dibenz(a,h)anthracene Benzo(g,h,i )perylene 15.85 15.92 16. 11 16.24 16.29 16.51 16.36 16.55 16.80 16.92 17.08 17. 14 17.22 17.60 18.83 17.37 17.28 17.31 17.96 18.27 18.58 19.22 18.87- 18.95- 21.03- 19.78 23.61 2 1.46^ 21.62 22.46 23.49 23.57 23.41 23.66- 26.73 24.49 25.76 26.81 26.69 30. 10 30.06. 31. 12- 165.0 152. 1 138.0 153. 1 184. 1 168. 1 109.0 166. 1 232.0 149. 1 204. 1 166. 1 138.0 329.6 188.2 77.0 198.0 169. 1 248.0 283.8 265.9 167.0 178. 1 178. 1 202.0 149.0 240.2 202.0 244.2 149. 1 252.2 228.0 149.0 228.0 264.2 149.0 •252.2 '252.2 252.0 '276.2 278. 1 276.0 19334 134133 22318 69317 6992M 113511 8671 27635 25609 115523 40566 84033 19667 18714 85493 141466 10695 66297 26321 40508 17898 100797 117394 118075 118151 184953 76238 120219 77002 67901 35211 103107 106083 96326 91251 175423 116434 97101 99312 130113 99439 108565 25.00 26.00 26.00 25.00 26.00 25.00 25.00 25.00 25.00 25.00 26.00 25.00 26.00 25.00 20.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 20.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 20.00 25.00 25.00 25.00 25.00 25.00 25.00 25.00 ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb 99 97 91 94 98 91 90 91 93 87 92 96 92 91 90 86 93 91 94 94 97 96 97 96 98 98 92 98 97 96 93 89 94 95 96 96 89 96 90 86 84 • Compound is ISTD 300676 Data Subject To Validation Eontinuina Calibr«ti«n Gh«ek C M « M O : Cantraetort PACE Contract Mo: ImtrtMnt IDt S988-M ColIbratlon Doto: 82/27/95 T I M : 14:16 Uterotory ID: HOUa Inttiol Collbrotton Doto: 02/02/95 Mfnii RF fer t n c ia 0.05 Moxtui X Diff for CCC io SOX Coi^ound Pyridino N-NltrooodiMthyloaino fh«nol><S 2-Chler«phanol'd4 2-Fluorophonol Anilino fhanol 2-Chlero()hanol bis(2-Chloroathyl)othor 1,3-Oichlerobtnztne 1,4-0iehlorobtnt«nc 1,2-D<ehlorcbmz*ne-d4 1,2-Dichlorobonzone Btnxyl oicohol 2,2'Oxybto-(1-chlorcpropano) |M*M1tro>o-d1*n*propylMlrw Noxachloretthoni 4-Mtthylphanol Nltrebonzonc-dS Nitrobenzorw IsophoroTM 2-Nitrophonol 2,4-DfMthylphcnol bit(2-ChtorMthoxy)iaethane 2,4-Dichlorophtnol Benzoic ocid 1,2,4-Trichlorobenzene Naphthalene 4-Chloroaniline Mtxachlorobutadienc 4-Chloro-3*Bethylphenol RF " / 1.01438 1.33331 .66304 .85767 1.48923 1.48074 1.19953 1 1.12896 1 1.15862 1.14589 2.24426 1.94193 1.62092 1.59278 1.21281 1 1.19942 1.39292 1.40380 1.31130 1.34310 1.34158 1.41135 .80913 .82771 1.23820 1.28319 .73778 .72984 1.37092 1.46930 » i f f CCC SKC 31 . U 29.36 .57 3.41 1.50 13.47 y 1.74 "^ 1.10 .78 2.43 y 2.30 3.63 1.08 7.18 1.05586 1.05844 ^ . 6 5 .91209 .58790 1.10887 1 .41102 .40829 .80030 .17343 .27375 .49769 .26488 .17640 .29482 .90341 .41357 .16955 .28719 .88114*' .56380 1.08731 .36701 .36432 .76720 .15078 .23280 .56510 .25122 .14209 .29659 .9U08 .38904 .17106 .28092 ^ 3.39 • • 4.10 1.94 10.71 10.77 4.14 y 1 3 . 0 6 ^ 14.96 13.55 5.15*^ 19.45 .60 4.50 '•27 RF • Rosponae Factor froi daily atandard file at 25.00 PPB RF • Averaee Responae Factor froa Initial Calibration Fona VI XDiff • X Difference fro* original averaoe or curve -r CCC • Calibration Check Cotnpounds (*} SPCC - System Perfornance Check Compounds (**) For* VII 300677 Data Subject To VaHdation continuing Colibrotion Chodc taao Mo: Contractor: ^ACC Contraet Me: Inotruoont IDt S9e8-N Calibration Date: 02/27/95 Tiaa: U:16 Laboratory ID: >M0588 Initiol Colibrotion Doto: 02/02/95 NinlWB RF for SPCC lo 0.05 Maxioui X Diff for CCC lo 30X Canpowd RF RF XDiff CCC SPCC 2-Nethylnophtholone Nexochlerocyclopontadione 2,4,6-Trichlorofihonol 2,4.5-Trldilorophonol 2-Fluorobiphonyl 2-Chloronaphthalono 2-Hitreonillne DiMthylphthalate 2,6-Dini trotoluene Acenaphthylono 3-llitroanil1ne Acenaphthene 2,4-Dinitrophenol Dibonzofuron 4-llitrophenol |2,3,4,6-Totrochlorophenol Diethylphthalate 4-Chlorophenyl*phenylether Fluorene 4-Nitroaniline 2,4,6-1rlbraK9phcnol 1,2-Diphanylhydrazine 4,6-Oinitro-2-«othylphenol Diphenylaaine 4-Broaophanyl-phenylother Naxachlorobonzane Pentachlorophenol Carbazole Phenanthrene Anthracene Fluoranthene .55293 .53178/3.82 J2670 .05916"^ .38270 .31935 .41683 .37418 1.25887 1.19372 1.08947 1.08925 .42902 .36126 1.38792 1.34231 .31656 .24714 1.80475 1.71460 .36172 .28529 1.12923 1.14172 .15628 .08938 1.48924 1.45099 .17060 .11084 • .39411 .35325 .37045 .32736 1.46478 1.47671 .54579 .51855 1.11196 1.07418 .32391 .24999 .22662 .23922 1.30901 1.32376 .15078 .09914 .52841 .52680 .23966 .24630 .31426 .37905 .18396 .16748 1.00492 .94321 1.10125 1.09851 1.11046 1.10489 1.17351 1.10560 16.55'^ 10.23 5.18 .02 15.80 3.29 21.93 5.00 21.13 y "^42.81 •* 2.57 ^^5.03 •* 10.37 11.63 .81 4.99 3.40 22.82 5.56 1.13 34.25 1.77 20.62 8.96 « ^ 6.14 .25 5.79'^ RF • Responae Factor froa daily standard file at 25.00 PPB RF • Average Response Factor froa Initial Calibration Fora VI •Diff • X Difference froa original average or curve •r CCC - Calibration Check Coapounds (*) SPCC • System Perfonnance Check Conpounds (**) Fora VII 300678 Data Subiect To VaHdation Eominuini colibrotion Chock MSL Case No: Contractor: PACE I Contraet Mo: Instruaant ID: S988-M Calibration toto: 82/27/95 Tiae: 14:16 Laboratory ID: HI058B Initial Colibrotion Doto: 02/02/95 Niniaui RF for SPCC to 0.05 Naxiaui X Diff for CCC U SOX Cca^ouid Oi-n-butylphtholoto Pyrene Terpheny I'dU Butylbenzylphthalate S,3'-Dichlorobenzidinc •enzo(a)anthrocene bi8(2-Ethylhaxyl)phthalata Chrysene Di-n-octylphtholote Menzo(b)fluoronthene Menzo(k)fluoronthene •enzo(a}pyrone lndeno( 1,2,3-cd)pyrene 0{benz(a,h)anthracene Benzo(g,h, Dperylene RF RF 1.67332 1.73070 1.28356 1.26151 .61891 .80802 .76622 .71252 .39300 .36949 1.08622 1.08195 1.08571 1.10268 1.01148 1.01079 1.62082 1.53794 1.05431 1.0207B .92652 .85129 .90934 .87067 1.04677 1.14070 .81469 .87178 .88047 .95170 »lff CCC SPCC 3.43 1.72 1.S3 7.01 5.98 .39 1.56 .07 S.ll/* 3.18 8.12 y 8.97 7.01 8.09 # RF • Resporae Factor froa daily standard file at 25.00 PPB RF • Avorago Response Foctor froa Initial Calibration Fora VI XDiff • X Difference froa original average or curve •r _CCC • Calibration Check Conpounds (*) SPCC • Systea Perfornance Check Coapounds (**) I Fora VI1 \ Data Subject To Validation 300679 TOTAL ION CHROHATOGRAH Fii* >Hes8i 35.0-5ie.0 atMu. sv^AMes RDi GReaes HATB?—SS 588 1888 15,88 2888 2588 3808 658880- 608888- 550000- 500000- 450000- 400000- 350000 300000 250000 200000 150000 108888 58888 8 • ^ ' ^ ^ 6 8 18 12 14 . f . / ; • . •^ / Z 1 r. to i^iiii^i I a.»- 14 16 18 28 22 24 26 28 38 32 Data File: >H058I::D2 Name: SVWAW03 HLA Misc: WM0003 WATER BATCH #12422 INST H Id File: ID_SH::DB Title: SEMIVOLATILES BY SW846-8270/EPA 625 Last Calibration: 950227 15:00 Operator ID: DAVID Quant Time: 950227 21:24 Injected at: 950227 20:49 Quant Output File: *H058I::BQ BTL/10 DataSubiectTo 300680 Validation QUANT REPORT ^ % Operator ID: DAVID Output File: ^H058I::BQ ata File: >H058I::D2 ame: SVWAW03 HLA Misc: I9M0003 WATER Quant Rev: 6 Quant Tine: Injected at: Dilution Factor: BATCH #12422 INST H 950227 21:24 950227 20:49 1.00000 BTL/10 ID File: ID__SH::DB Title: SEMIVOLATILES BY SW846-8270/EPA 625 Last Calibration: 950227 15:00 1] 4 5, 6] 13; 21; 22; 29; 36 40 57; 58; 70' 73, 77, l» Compound *IS#1 l,4-Dichloroben2ene-d4 Phenol-d5 2-Chlorophenol-d4 1 2-Fluorophenol 1 l,2-Dichlorobenzene-d4 I *IS#2 Naphthalene-d8 1 Nitrobenzene-d5 1 Benzoic acid *IS#3 Acenaphthene-dlO 2-Fluorobiphenyl 1 2,4,6-Tribromophenol 1 *IS#4 Phenanthrene-dlO ! *IS#5 Chrysene-dl2 1 Terphenyl-dl4 1 bis(2-Ethylhexyl)phthalate ) *IS#6 Perylene-dl2 R.T. 10.83 10.27 10.51 8.80 11.14 13.02 11.82 12.56 16.17 14.92 17.59 18.81 23.60 21.63 23.41 26.74 Scan/ 631 567 594 396 668 886 746 832 1252 1107 1417 1558 2113 1884 2091 2475 Area 45917 20952 10140 7324 57495 159519 125678 10689 73005 168964 2966 109558 105691 167108 201394 111387 Cone 20.00 6.16 3.81 2.78 30.26 20.00 42.93 9.43 20.00 38.78 3.40 20.00 20.00 39.14 34.56 20.00 Units ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb q 93 96 87 86 94 98 84 95 88 93 98 92 97 99 93 98 * Compound is ISTD 300681 Data Subject To Validation REFERENCE STRNDPRD SPECTRUM F i l e >H099a HflZflRDOUS t 1 1 X - l Bpk Pb 1 0 0 . 100- 51 / LOT LP 33941 SUB NRM 105 / 39 eJi,i|', ;,,'| 77 65 / 46 ' I ' 68 I ' '•''' I I ee 122 ScAn 1195 13.43 ain. -lee 128 1 1 1 I i I I I'l 1 1 ] I I 1 1 r i I I 1 1 I 1 1 1 1 I 1 1 I 1 1 lee 128 140 SfiMPLE SPECTRUM <BnC.K6R0UND SUBTRRCTED) File >H058I SVUflW03 Bpk Pb 2952. 2009- HLP 77 / IJM0OO3 UfiTER BfiTCH # Scan 833 SUB 12.56 min. 105 / 122 39 y i l , l " " 74 • I I 40 85 100 / \ 157 60 I f'<' t 1 f I t ^ ^ " 1 ] i i i i i j i i i T | f i i T*^ I I I I [ I' r'T t ^ " 80 100 120 140 H 0 0 J 1.0 SfiMPLE SPECTRUM <UNfiLTERED> F i l e >H058I SVUfiW03 Bpk fib 2 9 5 2 . 2000- Hun 77 / UM0Q03 105 / WATER BfiTCH # Scan 833 1 2 . 5 6 m i n . 122 39 y il.i • 51 ^ , II.. \ T 40 60 T . .Ill 85 100 / \ 1-100 157 • ' I ' ' ' • I ' ' ' ' I ' ' • ' I ' ' ' • I 80 100 120 ' ' I ' ' ' ' I 140 D a t a F i l e : > H 0 5 8 I : : D 2 Name: SVVI/AW0 3 HLA Misc: WM0003 WATER BATCH #12422 INST H Quant Time: 950227 21:24 Quant ID File: ID_SH::DB Injected at: 950227 20:49 Last Calibration: 950227 15:00 Ouant Output File: ''H058I::BQ BTL#10 Compound No: 29 Compound Name: Benzoic acid Scan Number: 832 Retention Time: 12.56 min. Quant I on: 122 . 0 Area: 10689 Concentration: 9.43 ppb q-vaIue: 95 300682 iS Data Subject To Validation^ REFERENCE STRNDPRD SPECTRUM File >Pe92e BN MlX-l Bpk Rb 100. 149 LOT 33358 SUB NRM INST Scan 28.60 100- 57 71 / e^^ f^r4*f f'l^f^r i"! 4 113132 £952 min. -100 40 80 T ^ — I • I 120 180 ly 279 -rv-t 160 ' I -r 2 0 0 I ' I'"' 2 4 0 t - r ^ ' I ' I • I ' I ' I 280 320 360 SRMPLE SPECTRUM (BRCKGROUND SUBTRRCTEO File >H058I SVURW03 Bpk Rb 130748. HLR 149 UM0003 SUB, URTER BfiTCH # Scan 23.41 100800- 122 57 71 d f P^ r ^ ^ i~'T t I f ™i I T t 2091 min. •100 207 279 \ 341 / 40 80 120 -I—"—T 160 200 • • — I — ' — r 240 ' — 1 — ' I ' — I — " — r 280 320 ' — I — I — r 360 •-0 SfiMPLE SPECTRUM CUNfiLTERED) File >H058I SVWflW03 Bpk flb 131457. HLfi 149 100000- 122 ^^ 71 -,- / ^ 113 , i..i.l... . / / r 40 1^ 80 UM0003 yz UfiTER BfiTCH # Scan 23.41 2091 min. 100 279 \ I ' I ' I ' I ' T'l • I 120 160 200 341 / ' I ' I ' I—T-'—1—^ 240 280 320 360 Data File: >H058I::D2 Name: SVWAW03 HLA Misc: WM0003 WATER Quant Time: 950227 21; Quant Outpu t File BATCH #12422 INST H 24 Quant ID File "H058I::BQ BTL#10 ID_SH::DB Injected at: 950227 20:49 Last Calibration: 950227 15:00 Compound No: 7 7 Compound Name: bis(2-EthyIhexyI)phtha I ate Scan Number: 209 1 Retention Time: 23.41 min. Quan t Ion: 149.0 Area: 201394 Concentration: 34.56 ppb q-vaIue: 93 300683 Data Subject To Validation o o o o . • a / n Aaalyrtt. p.iffr'^ Jtetet. trajeet Z.P. (oUOTVcMi/aAg) i. ?A'/;f '.X^ t t » 9tmmaMX* Beta »a«alaltiM K BOTXttlBM .-VMatilMt cola ZBJeetar I. an w t , .. _ ^ i.iwa BBlltlWa QC dMolptoxs t ^|i^if-fiv. prm^m IrminmlwrnaX IB CgnflltigM aeaa rata i.l • / • B M m yaXfigmtZJS^ •ea-ataadaxtf OMtdltlana i, •alBtaaaBCM^Vre^laBa t] Vonwatar rilaa t] O r l g l M l Data M l a d «itb>' «Sr- •taadaM X«—tifioitta— • •pika 'ifi! ::fif-P9Sum4>*f -armr 2<f9-/v-ye/ry Paflatttaa of tathi/cioawMta Oelaaa • • Ma lag (paiga all .analyais'paaaad mil eritarla n M..aaapla aatrlx affaet (alao indloata QC - not applicabia aaooraioaa. Cor axaapla, ZSS*, U 3 * , ato.) CO oarxr-evar e r ooRtaalaatioB eo^aotad . n la aKtractice raqairad n / i a v a l . . . d i l u t i o n raeoirad/'aoMaatad laral n t . . . racva raqairad tO/laval...tao dUnta/aagtraatad laral D D D D D D D D M - f C C C C C r H - n c i - o c / » uaiauMMTt om&TxoM UMamr — ma-vouozus. Analrat i (I i^fiCC/ * m r ef tba day t /-Lp. e.y t'l Bata i^ *AAr Parf. std. 4 12 bra -ir-d jura nina within tiaa liaita? TES _ (Xf BO, elirla eutllara) HO Tzn OP r a » xs CLxm xo (dil) MR IXJ BSI kTCH OU KVLT 7XCT X.B. AR KT •UK U C RILTUB, roB/ CUMJUUTS r m if.it ly^iUfA CFTf/ U . QM I'-i^ CJ^3i-l1f/l Tjr*>tn> i t J L ^ k . //••»? sYixxfrB^ StUr^ ¥i / S a f y y V •zr- I X -jx s / i ^ y . j e i r fAifyr f-f/kJs u. ly y n.-u S t r m i i t - t i JXut-i- 3sJ. 12? (/i I U . ir:«^ J^rrAnl 2 H n r J l i y y y L t^-.jf r / i t i t i i u t i S B p t ^ hi. /»>v y 'JIU l2z;s±iiL f^Mpy £UjJt£EJL. I J J . y %,\li,Prl!^. r/^Afal CC^fVSiTE 2A. y (f-f* W^fiCat rrifil friif-l) y y IS-Si pfwAo 9 1 A i A i m i . " 3 y y miL p / ^ i c g r *lAtM<^'t y j V ^ A t - 9 l Wi^^fg-I laiL MAJAii.r'ir f/rf/f?>;?E 00 O O ro -4 7 o . 0 CO Dlcita SulSjetefto Validatigh I o CO me/m fiejaet Z.P. (eliaM/aaa^adg) i _ 5/5/f« •taa«a>« Bata Aaqaiaitlaa n e v rata i ai8.»l<^tTI Car laai-valatUaat O o l o n i yuaad Blllca C . p l l l . r v . ~ ~ a .30. « O.aSM. l . I h a fllTi acter taae.t aso aetar Mda t Med B u i i t i i i T BSJCaallxiflot i«-Jas8Pg MB.. Peaa rata i A P/iffin., W v o l t a p a i Z H i Z S Z OC daaeiptera i -aiianl—sv. DFTi»p.<m OC proqraa t 4S #4Mim ta aoo • l a / ^ ^ •oB-staadard Cewditiaea i. —Intanaae^/PretilaM i ' recaastar Mlaa tl Orlviaal Oata rilad Withil Xaf a * > f . •'fii r ' \ •taadard Zdaau'fieatlaaa l^Pel^a J a r o a t a i X ? o - /-a. - tvaTV* itat t^o- fo <^tHar^ jmrtx. l A o y H t ^ •baq (paffa S ) l Pafialtina of tatha/ocwaata Oolaaa aa analyaie'paaaad a l l eritarla ' n . . . aai^la aatrix affaet (alao inUeata OC ' net appUeabla aacaraiooa. fer aaaapla, ZS8*< P83*, ato.) CO oarcr-evar or eoetaainatiea aoapaotad . XS re-«xtsaetiee raqairad BI/iaTal...dUetieB caqoirad/aenaatad laval n rama raqairad n / l a v a l . . . t e o dilate/awagaatad laval ncB-ec/n u s t u M m omuiTxoas XMWBUT •-»• nia*-TOXATZUS a n a l v a t t lyZiatXy-yaay KSF o f t h a d a v . / ' C l t i " D a t a « ' 9 l f / f ^ P e r f . S t d . • 12 h r a . . T - S ' / O O o o U3 »o iiii Txn ^ / . • * IMO ,r'-n- fl-4*- ifr^ te-H (i'H l ^ : o ( i N , V OP 2 X > ;f A % I i ^ rxu xo eyetoiuit £409e>9<i/-» ^/cMrtnaii Wuencr' .^iiJtsiiOBiy ^ ^ e x o t f iimsruotjBz. *^y/A^nce • \ " ^ V CLXBR x o ( d i l ) ->*TW 'yi.TVOri <iZKUUjil Mdj^sr ^ifhJUjtJi /KIO-I/^ ^VUto. n n y j ^ ^ v * v^ \ ^ - ^ u M M R XW IMA 4^ '4- J. 1 k \ \'\( \\,r < -. BXTCS .... — Mf^ 4- J - i r f i tMt tirzti •-^^ "^^., Q t f f / / / i. / i- "'•^-.^ . . n o o nma within tiaa l i a i t f f ^ t ^ (Zf no, eixBla eatllars) MULT TJLCT f / ( / r / ^-^ J'I'V Z . I Ml ... . a^ y y y y "" , ^y. y y ' ^ y J2L1 BUB uc 1 — U- y y ^ y y >^1< BWkTOB/ • ^ . y 'isu.zy. y ' ^ y ^ . < • "-- aSBii-tK^ n t s f«?<" i ^,< "Yf* P f**!"* • - v ^ • 1 "^ 1 00 1 vo o n ,.. o . o o o Oi CD 1 Off a haalvati t T„.imOtimAr- l>»tai "a.-^3 ••»< ; ftejaet Z.P. feliaat/naaa hartal I ^ P T ^ tXltjCO U L A Pata aeqoiaitiM « canflltlwi new rata t a j al/ali. CelOMl 1 Juaad Blllea ear.111. Znjaoter ttmp.iijiSSl. app » g.asi., i.gw. Car Pwl taiat Ileal IB Cwiflitlgna _ _ _ _ _ Peaa raaaai 3S-S00 m n _ _ _ _ _ Peaa rata « l a/aean Bl veltaoat -tS^J * ^ < - Zajactor aoda i Mod a m i t i ^ S r ec prograa i 45 f«alni to aoo » la/ipTf jflBUaJ^SPOl. Ven-staiidard rwMlltleni i "- Paint anano^ftrebla— Veraaatar n i a a t] Original Oata riled Pithii iISBSSSZ Ptaadard ZdaaUCtoatlaaa • ppika Tamatat jufo- iX.-tiJXS -lax ^ ^ o - ^ S\;Tfiin>0 P>.^, K ppTPPi 2 ^ D - N - f e e r PafialttM ef Ptatfaa/OneaaBta Oelan aa analyaia'paaaad all eritarla " ....net applieabla CO earzy-ovar or eoBtaaiaatioa eaapaetad OI/leval...dilatioe reqairad/aaggaatad level Peg (pege aii •B ...eaapla aatria effect (alae iadioata QC exouraiona, fer axaapla, V a ' , M 2 * , ate.) PE.........ra-eKtractiea raqairad PR.........rerun raqairad n/leval...tee dilota/euggaited laval {lWHHHl-iHH?t-C-{H}C-C C CCC PKca-oc/Ka xasTxnanT opnxTzoes XIOMBMUT ~ > BBXz-ToukXxz«a Analyat t »n * aav ef tha day Data I 'i.-lzj.'K.-y tmrt. Std. • 13 hra. i s o : ^ Jix* nma within tiaa lialta? (Zf no, circle eutllara) tE<5N> &ef a •mCk a a a i y t i BlrmmfffiM- P f « 'Z-%'*-'\Si I X a l e e t Z . B . f a H - . » » i - a a > a d i r t i ^ P f [ pata Pefeisitiep' BB CQntfitlpnp _.• new tate ' » « ai»ii>»i •Pail miBHIaet ceioKi .. . t:iniairt?BixIct npiiii Seotar IZX«_ ao- « e.as—. i.ena fTiT i.l_2Sfi. . wad a n l l t l a a a OC PaietptorB * nrrr'-'*'v- P T P P ^ ^ M «C prograa • aa i4»it.i to aoo % la/BK^ # o B t i - i « a d i n i e e « - original Pata Mlad aitht ~ • B e o a d t t t c • aS*8Pl? BIB P e a a r a t a t \ a / a e a n a weltagai_ie£& V-' % - ^ •~r Ptaadard Zdaattf leetioM • svike Tareatai ^ i ^ , o - t A - S v a - f 5S!_£S£:£liiili«JJi. B , ^ . 29o-/V-/'rk/^ Beftaitiee ef Ptatfaa/otiawta oelaBa aa Paa Peg (pege P)i _. « __^ . , ^_. .. ^ analyaie'paaaad all eritarla KB aeaple aatrix af feet (alee ladi«te ec ..........net applieabla axearaieoa. ter exaapla, XPS , PS3 , ete.) 00 eartr-evar er wwitaalnaMon eaapaetad . PK.........ta extraetiee reqaired OI/lavel...«Uatien raqoire^aeggeatad level PX .rarwn raqairad _ , - v ~ - — ' - - " »/level...teo dUete/aaggaatad laval TiiH>iK:H[H:K:i:^:'i-c-c-cc-c-c c C- e i>cB-ec/in XPBTMIUMT OPBBXTXCVB Analyat « 03ag> » M P of tha day Data X •i.-T.^-^J Part. Std. 4- 13 hra jure rana within tiaa llaita? TE^^'Ti^ a.a.:'Zvi (Zf no, eitela eutliora) nxB U3--3H lO'-Sq < ( : M 4 a:3D l3:SS iljiii iS^o Ife'lg n-oo n-Mti >6.a-T w . i i W;6M 2£:2S. 2i:t3 22£(e. ^T^^ 3^z21 0 0 : i 6 -^••05^ O o : o A3 OP PM H 0 6 S A .V D I M Q S S f t . - r e i Lng?6Sf ••••P' HQSfiQ.-.PI Mossf.., f^i MPSsr.-; Dl MP6cfi.:.-OI HQgSM--" 01 n u XD SVU)EK<0| tVTBVc-f &/u>fetro3 SVUjfelc<fiU a/^^ig(e.<OS, St/LQgtefflfe upscr.-.f^i 5uaa£ Ical Hosgr.-; DC HogSK-: 0 ' uftSSCi.- f>-7 uossm^: P2 upgsw^; tn: AOoSO::* O'i- ^*OSSP--- D^ jflfij;iP.-i D 7 K ^ g ^ - ' ^'^ Knggr-- ^"^ uoKu-v e^ O i Z n T XD ( d i l ) 6°"s pn-^, CgTt«)Scr2 SVWg-flg| (r»smib--i st/OZSca. Mtonm-iAif fWUiCS'CH f>l^(«--:^ TiMXbae mhixiii-o 5\iWA\i}a.% v t m w i <i/iirfyoi lnc/Dgt3c/e?kqg: : ^ s: M R XW tS'rt bTCI I'L.X'.IM £»i3£J;_, L22S&. >7auM Qtr t.i-2- l-ew l:£k. LiJ Lc&- LOSL. 1.51 NVtiT n e t •Jo Z.B. Mt XT y -P y y y y £L •P Bint uc y Z7 IP y 'P' p "yVA y y y y PC- naroB, •OB/ C O B K X I T S »=>- '2. JcM^vi»-f<* i i t ^ a ^ c T M ^ ' I .-TO I(y5 L . ^ I 1 i J ^ ^ f e j e c t T^Vallefation 0 0 jvo I ro o o o me/m CO Paalvati D•T^^.^.^p^a.r— Betat ^ . . . a n . q c * n e j e e t Z.B. rnneiif^naaa^adnti fef T M C p HuA Ptaadard pata PeqaiBttiaa new rata i a.a «i/-iji. flkr .-velatUeei IB BBPtfltU Coloaa r Pua^ BlTlea Canilla aoa V e.aa—• I.IHM aa: Peaa r a a ^ i as»SOO aan Peaa rata i l a/aean veltagai_i2fi&. Xajeeter taae.t 250 Zajactor aeda I. Bed B B l i U m oc daaeiptera 1 «.^i—.fYr WTPP-PM ec prograa 1 4S lAninx to aoo a ia;^Jn (BrtiPt«imi. Poa-etaadavd OwiditieBe tJZ. IIBI ii**f ttvnF|/frpM a— 1 Pecaaater rilaa i"*" original Oata riled Pith«I3 missss: 1 of a A ' ^ y 'y. Ptaadard Zdaatlfieatiaaa • tareatat X«.0- i^-waX XS. a%o,»-,-<tf7SiA.e , AtO'H-Pe»F Pafiattioa ef Ptetka/eaaaiuta Oolaaa aa .........analyaia'paaaad all erlteria > net applieabla CO .earry-evar er eentaainatiea eaapaeted cyieval...dilation raqoira^aaggeatad level Peg (paga all PE aaapla iMtrix effect (alao indloata oc axearaiona, fer exaapla, ZSS', SS3'', ete.) PP.. ..ra-extraetiee raqairad XX.... ramn raqairad n/laval...teo dilota/aaggaetad level D -D Mi'i^i'-r-i-^-^-^-^-c-c-c-c-c-c- pKCB-ec/Ms anrxmoDR omATZovB UXMBXBT — BXXi-TouTZxaa Analyat i^C^W"^ » nsr ef tha day t Data 1 •J-a-"1-<TS ^Parf. Std. t " hra. 1 CO•• n j i x * runa within "Una llaita? n s XO (Zf no, eiaela eutllara) r*> 0 0 -vl I & . TZXB 0 12: n R N.-«|» fSrcO I S . H l * \m I S t M w.aj • i O i C b ^ : ^ «:33 aa.'it li«:i« n:i^ ' v . • f n u XD » I-1Q58A.-.- DO. M06S6;-- OS. Unser. S D>. H066D.V O:L uo.<;ftP7,-.- D ^ HOfirtF.v o a - HOSSfl .••• fi*. utxea.-: ox HOfWT.V (?3L. iKseT.^ 0:^ M066K.V 0>- Mosei^•'•B^ Mo&ew;; DT- " " ^ ^ ^ v ^ 60^., Dm>p * S T t ) C » 0 lamnuaBSL JtfVid »/ix>fi>c:ci «nnw* ayTuccpq nflSrtJu-a. s/ure.<Ba. aftsmu3-i» 5\/L0r.foc6 *ft*mu)-& |SVuaato3 0*0X37 A/tiJCCoi uiClDSi/otan si/tirCffii « ' '1 t r f t t ^ UUFCMZ 12MZ1_ fci* L H » t « ^ (7^21^7 . — ^ - ^ ^ V " - " • ^ ^ MR ZXI - 2 - ~'^«~... - XMca I Z H - i - J • "~--^^ n:> Q U .—. « IJOm. I.IX. / A e 1 < . S i 3« 1 1 » " ^ s ^ . ^ • a b u b MUI.T PXCT 1 I i 1 J 5 f? 1 1 2 o 1 1 1 - i %fT Z.I XX *- y y y • V' • f y y | L _ ttr XT • • • y y y V y ml y y y aU T c Bint uc —— a- • ^ • • y y y * ?V y y ar 44t OOlUUURB . «£= 1.^5 1=5 At?- l=2o -ee= • - ^ • ^ . ^ " • " ^ ^ r ^ TXPB ' HJ_,-^ CO 00 u> o o cn • e " ^ ^ "