Data Package: Harding Lawson & Associates (HLA) Data Quality Assurance Review Summary, Semi-volatile Organic Compound Analysis, April 12, 1995.

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Kind: Government Report
Date: 1995-04
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HLA DATA QUALITY ASSURANCE REVIEW SUMMARY Semivolatile Organic Compound Analysis Case Number: Site: Contractor Lab: Validator: QC Reviewer: Sample Matrix: 95020 Project Number: Island Chemical Company Pace Incorporated, New Orleans Kirsten Meier /z^ytyyo^y-y^. 7^y7Zyy<y^ Validation Date: Review Date: Water 29872 10.1 11 April, 1995 ^ ~ / y - 9J~ Analytical Method: SW 846, Method 8270, Pyridine only Sample Designations: Client ID O^^b Sample ID) SO0012 S00119 SO0127 BS0013 Data for the above samples are: [ ] Acceptable for use [x] Acceptable for use as qualified [ ] Unacceptable for use Is action required by the Project Manager? Yes No[x] Comments: The investigative samples were validated in accordance with the "USEPA CLP National Functional Guidelines for Organic Data Review", February 1994. SDMS Document 115543 bm_elec.ll 12291994 1530 Form BNA l.l 300689 Cue Number: 9S020 PrajeclNumber: 29872 10.1 Site ID: Island CbcmicaLl Company DATA COMPLETENESS CHECKLIST [x] Included, no problems [*] Included, problems [O] Not included [NA] Not applicable Quality Control Sununary X Case Narrative X Surrogate Recovery Summary * MS/MSD Summary X Reagent Blank Summary X GC/MS Instrument Performance Summary Sample Data X Chain of Custody Forms X Holding Times * Organic Analysis Data Sheets X Quantitation Reports * Reconstructed Ion Chromatograms X Mass Spectra Printouts NA TIC Mass Spectra Library Searches Initial Calibration Data X Calibration Summary X Standards Quantitation Reports * Standards Reconstructed Ion Chromatograms Continuing Calibration Data * Calibration Summary X Standards Quantitation Reports * Standards Reconstructed Ion Chromatograms "* Internal Standards Summary Instrument Performance Data X DFTPP Mass Spectra X Reconstructed Ion Chromatogram X DFTPP Mass Listmgs bm_elec.ll 12291994 1530 2 FofmBNAl.l 3 0 0 6 9 0 Cue Number: 95020 ProjectNumber: 29872 10.1 Site ID: bland Chemical Compazy Reagent Blank Data _x_ _x_ * NA Organic Analysis Data Sheets Quantitation Reports Reconstructed Ion Chromatograms Mass Spectra Printouts TIC Mass Spectra Library Searches Matrix Spike and Matrix Spike Duplicate Data * Organic Analysis Data Sheets X Quantitation Reports * Reconstructed Ion Chromatograms Laboratory Control Sample NA Organic Analysis Data Sheets NA Quantitation Reports NA Reconstructed Ion Chromatograms NA Mass Spectra Printouts NA TIC Mass Spectra library Searches Comments: For the instrument B the Reconstructed Ion Chromatograms showed peak areas from the scan 350 and higher, while the compound of interest. Pyridine, appears at aproximately scan 210. A visual comparison of data for Pyridine was not possible. bra_elec.ll 12291994 1530 Fomi BNA 1.1 300691 Caae Number: 95O20 ProjectNumber: 29872 10.1 Site ID: Isbtiid Cbemical Company SPECIHC COMMENTS REGARDING ANALYSES Ciiain Of Custody Were samples properly preserved and received in good condition? Yes[x] No Were custody transfers correctly and completely documented? Yes[x] No Comments: None Holding Times Were sample extractions performed within holding times? Yes[x] No Were sample analyses performed within holding times? Yes[x] No Comments: None Instrument Tuning Did the instrument performance checks meet acceptance criteria? Yes[x] No Were samples analyzed within the 12-hour period following an acceptable performance check? Yes[x] No Conunents: None boa_elec.il 12291994 1530 4 - Foim BNA 1.1 300692 Case Number: 95020 ProjectNumber: 29872 10.1 Site ID: Island Cbemical Company Initial Calibration Did the laboratory meet the method requirements regarding the minimum number of calibration standards for an acceptable initial calibration? Yes[x] No Did the initial calibration curves meet the linearity criteria for maximum percent relative standard deviation (%RSD)? Yes[x] No Did the initial calibration meet the minimum relative response factor (RRF) criteria? Yes[x] No Comments: This review is only based on the evaluation of Pyridine. The initial calibration QC criteria were met for Pyridine. As stated previously, the chromatograms for instrument B do not show the scans for Pyridine and N-Nitrosodimethylamine, a visual evaluation was not possible. The possibility that the injection peak or other factors might have interfered or affected the quantitation of the target analyte Pyridine, cannot be evaluated. The concentrations of the initial and continuing standards are listed in the header as twice as high as the concentrations used in the quantitation section of the data. The injection volume is not clearly defined, but appears, that the same amount of 1.0 ul was used for standards and samples. Since no detections of Pyridine were reported, no qualification of data is necessary. Continuing Calibration Did the continuing calibration curves meet the linearity criteria for maximum percent difference (%D)? Yes No[x] Did the continuing calibration meet the minimum RRF criteria? Yes[x] No Comments: This review is only based on the evaluation of Pyridine. The continuing calibration on 2-17r95, 14:06, shows a percent difference for Pyridine of 39.2%, exceedmg the limit of 25%. Therefore, the result for Pyridine in the associated sample BSOOO was qualified as estimated (J). As stated previously, the chromatograms for instrument B do not show the scans for Pyridine and N-Nitrosodimethylamine, a visual evaluation was not possible. The possibility that the injection peak or other factors might have interfered or affected the quantitation of the target analyte Pyridine, cannot be evaluated. 300693 bna_elec.ll 12291994 1530 5 Form BNA 1.1 Case Number: 95020 ProjectNumber: 29872 10.1 Site ID: Island Cbemical Cotnpany Surrogate Recoveries Were the surrogate spike recoveries within acceptance limits? Yes[x] No If the spike recoveries were unacceptable, were the samples reanalyzed? Yes No NA[x] Comments: None Matrix Spikes Were matrix spike analyses performed at the correct frequency and on a sample matrix representative of the samples in the sample delivery group (SDG)? Yes[x] No Were the matrix spike recoveries and relative percent differences (RPDs) within acceptance criteria? Yes[x] No Comments: The matrix spikes were performed with a 8270 mixture, which does not include Pyridine. The lab provided a summary of matrix spike recoveries, some recoveries were not within 8270 QC limits. No qualification of data. Internal Standards Were the internal standard areas and retention times within the required limits? Yes[x] No If the internal standard requirements were not met, were the samples reanalyzed? Yesx[x] No NA Comments: No internal standard area and retention time summaries were provided. The associated peak responses were compared and the QC criteria were met. No qualification of data. 300694 biii_clcc.ll 12291994 1530 6 Form BNA 1.1 Cue Number: 95020 Pn>jectNumber: 29872 10.1 Site ID: Island Cbemical Company Blank Analyses Were the appropriate number of blank analyses performed? Yes[x] No Were analytes detected in the blanks? Yes No[x] If analytes were detected in the blanks, were the same analytes detected in the associated investigative samples? Yes No NA[x] Did the sample results require qualification due to the presence of analytes in the associated blank samples? Yes No[x] Comments: This review is only based on the evaluation of Pyridine. The target analyte was not detected in the associated prep blanks and qualification of data was not necessary. Laboratory Control Samples Were laboratory control sample (LCS) analyses performed at the correct frequency? Yes No NA[x] Were the LCS recoveries within acceptable limits? Yes No NA[x] Comments: Not applicable. 300695 bai_elcc.ll 12291994 1530 7 Form BNA 1.1 CaK Number: 95020 ProjectNumber: 29872 10.1 Site ID: Isiand Cbemical Company Sample Results Were target analytes reported in the investigative samples? Yes No[x] Were mass spectra provided for the target analytes detected in the investigative samples? Yes No NA[x] Were the mass spectra of acceptable quality and analytes correctly identified? Yes No NA[x] Were the quantitated results for target analytes calculated using the appropriate internal standards and were the relative retention times (RRTs) acceptable? Yes[x] No Comments: As stated previously, the chromatograms for instrument B do not show the scans for Pyridine and N-Nitrosodimethylamine, a visual evaluation was not possible. The possibility that the injection peak or other factors might have interfered with or affected the quantitation of the target analyte. Pyridine, cannot be evaluated. Therefore, the reported results for Pyridine in the investigative samples S00012, S00119 and SOO 127 were qualified as estimated (J). Tentatively Identifled Compounds Were tentatively identified compound (TIC) searches conducted for all sample analyses? Yes No NA[x] Were non-target peaks evaluated as required? Yes No Were the TIC mass spectra, searches, identifications, and quantitated results acceptable? Yes No Comments: Not applicable. bMelecll 12291994 1530 8 Form BNA l.l 300696 Case Number: 95020 ProjectNumber: 29872 10.1 Site ID: Isbtnd Cbemical Company Log Books Were sample preparations properly documented and performed in accordance with method protocols? Yes[x] No NA Were sample analyses properly documented and performed in accordance with method protocols? Yes[x] No Comments: None bni_elec.ll 12291994 1530 Form BNA 1.1 300697 Case Number: 95020 ProjeaNumber: 29872 10.1 Site ID: Isbnd ChemicU Cocnpany Calculation Checks Instrument Tunmg m/z of 127, 2-2-95, 9:19, Instrument H Relative Abundance: Calculation not possible, only relative abimdance was provided Initial Calibration Std 50, 11/9/94, D5-Phenol RRF: 16823 * 20 = 1.330 10117x25 %RSD: 0.071 *100% = 5.422 1.309 Continuing Calibration Std 50, 2-8-95, 11:24, Pyridine RRF: 9392 X 20 = 0.7734 9715 X 25 %D: 0.918 - 0.775 X 100 = 15.58 0.918 Surrogate Recovery SO0127, 2-Fluorophenol 20771 X 20 = 63.2071 6911 X 0.951 63.21 X 100 = 84.28 % recovery 75 bna_elec.ll 12291994 1530 1 0 Form BNA 1.1 300698 Case Number: 95020 ProjectNumber: 29872 10.1 Site ID: Isbmd Chemical Company Matrix Spike Recovery Detected concentrations not known RPD: Batch 12098, Phenol 2 I 8 - 14 I = -54.54 I 8 -t- 1 4 I Sample Results CRQL: Water sample Detected Result: No detection TIC Result Not required bai_eleo.ll 12291994 1530 H Form BNA 1.1 300699 Case Number: 95020 ProjectNumber: 29872 10.1 Site ID: Island Chemical Cocnpany HOLDING TIME QUAUFICATION SUMMARY FORM o o -J o o Sample Identification Date Sampled Date Prepared Date Analyzed Prep. Holding Time Analysis Holding Time Qualifier Comments: None lma_elco. 11 12291994 1530 12 Foim BNA l.l Case Number: 95020 ProjectNumber: 29872 10.1 Site ID: Island Chemical Company INITIAL CALIBRATION QUALIFICATION SUMMARY FORM Date/Time Instrument Analyte RF RSD Samples Affected Qualifier Comments: None w o o • J o i I229I9')4 1530 13 FomiBNA l.l Case Number: 95020 ProjectNumber: 29872 10.1 Site ID: Island Chemical Company CONTINUING CALIBRATION QUALIHCATION SUMMARY FORM Date/Time 1 2-17-95, 14:29 1 ^ Instrument H Analyte Pyridine RF %D 39.2 Samples Affected BS0013 Qualifier J/UJ Comments: None o o to b™_eIco.ll 12291994 1530 14 Fomi BNA 1.1 Case Number: 95020 ProjectNumber: 29872 10.1 Site ID: bUnd Chemical Cotnpany BLANK SUMMARY FORM Blank ID Analyte Blank Result (units) Action Level • Associated Samples w o o •-J o OJ 1 Comments: None 1 btia elec.ll 12291994 1.530 15 Poem BNA l.l Case Number: 95020 ProjectNumber: 29872 10.1 Site ID; bbnd Cbemicad Company Siunmary and Conclusions The analytical results for Pyridine are acceptable for use as qualified. The reported results for Pyridme m the investigative samples SO0012, SOO 119 and SOO 127 were qualified as estimated (J) since a visual comparison of the peak acquisition was not possible. The results for Pyridine in the investigative sample BSO013 was qualified as estimated (J) due to exceeding continuing calibration criteria. Validator's Signature: Validator's Initials: QC Reviewer's Signature: QC Reviewer's Initials: <JLyie^/^ FOA'-C/ UK <h^^..cyUjy -^, TzyCUT^ tlFP t Validation Date: // / i p y j l 9 - S Review Date: V- /^ - f J " 300704 baa_elec.il 12291994 1530 1 6 Form BNA "l.l ENVIRONMENTAL LABORATORIES REPORT OF LABORATORY ANALYSIS Analytical Results - Semivolatile Organics by Method 8270 Harding Lawson Associates Client ID: S00012 Description: NA Sample ID: VSR-001 Matrix: Water Wet/Dry Basis: NA Collected: 01/24/95 Received: 01/25/95 Prepared: 01/30/95 Analyzed: Percent Moisture: NA CAS No. 110-86-1 P a r a m e t e r Pyridine Concentration, ug/l (ppb) ' Detection Sample Blank Limit ND ND 10.0 U3 ND-Not Detected at or above the detection limit stated. VALIDATED Reviewed By / • ^ ' ^ • ^ ' ^ ^ - ^ Date ^ ~ l ( - f ^ 201 161 James Drive West, Suite 100 St. Rose. LA 70087 TEL: 504-469-0333 FAX: 504-469-0555 An Equal Opportunity Employer 300705 ENVIRONMENTAL LABORATORIES REPORT OF LABORATORY ANALYSIS Analytical Results - Semivolatile Organics by Method 8270 Harding Lawson Associates Client ID: S00119 Description: NA Sample ID: UQB-001 Matrix: Water Wet/Dry Basis: NA Collected: 01/19/95 Received: 01/23/95 Prepared: 01/24/95 Analyzed: 02/08/95 Percent Moisture: NA CAS No. 110-86-1 P a r a m e t e r Pyridine Concentration, ug/l (ppb) Sample ND Blank ND Detection Limit 10.0 0 3 ND-Not Detected at or above the detection limit stated. VALIDATED Reviewed By /<^^u-^ 'f€^v-i_ /- ^~ P ~ f J " Date 300706 202 161 James Drive West. Suite 100 St. Rose. LA 70087 TEL: 504-46 W033 FAX: 504-469-0555 An Equal Opportunity Employer ENVIRONMENTAL LABORATORIES REPORT OF LABORATORY ANALYSIS Analytical Results - Semivolatile Organics by Method 8270 Harding Lawson Associates Client ID: S00127 Description: NA Sample ID: VTF-001 Matrix: Water Wet/Dry Basis: NA Collected: 01/27/95 Received: 01/30/95 Prepared: 02/02/95 Analyzed: 02/08/95 Percent Moisture: NA CAS No. 110-86-1 P a r a m e t e r Pyridine Concentration, ug/l (ppb) Sample ND Blank ND Detection Limit 10.0 U 2 ND-Not Detected at or above the detection limit stated. Reviewed By Date VALIDATED uyicy. yyt.. ( i - i y f ^ 203 161 James Drive West, Suite 100 St. Rose. LA 70087 TEL: 504-469-0333 FAX; 504-469-0555 An Equal Opportunity Employer 300707 ENVIRONMENTAL LABORATORIES REPORT OF LABORATORY ANALYSIS Analytical Results - Semivolatile Organics by Method 8270 Harding Lawson Associates Client ID: BS0013 Description: NA Sample ID: WG-001 Matrix: Water Wet/Dry Basis: NA Collected: 01/31/95 Received: 02/03/95 Prepared: 02/06/95 Analyzed: 02/17/95 Percent Moisture: NA CAS No. 110-86-1 P a r a m e t e r Pyridine Concentration, ug/l (ppb) Sample ND Blank ND Detection Limit 10.0 U3 ND-Not Detected at or above the detection limit stated. VALIDATED Reviewed By _ / ^ ^ i ^ n^<-^ Date V - / ^ - f o 204 161 James Drive West, Suite 100 SI. Rose. LA 70087 TEL: 504469O333 FAX: 504-469-0555 An Equal-OQOPrtiinittEQmloy.er__ 300708 U.S. EPA - CLP EPA SAMPLE NO. « E12022 INORGANIC ANALYSIS DATA SHEET b Name: PACE Contract: j | b Code: GULF Case No.: HLA SAS No.: SDG No.: 095010 Matrix (soil/water): SOIL Lab Sample ID: VQB002 Level (low/med): LOW Date Received: 01/23/95 % Solids: 85.7 Concentration Units (ug/L or mg/kg dry weight): MG/KG 1 1 1 l l l i |CAS No. 1 Analyte jConcentrationjCj Q |M j 1 1 1 Mil 17429-90-5 {Aluminum | 12700 | j* jP | 17440-36-0 jAntimony | 0.88 jBj jF j 17440-38-2 lArsenic j 0.29 L3T U IF 1 17440-39-3 IBarium j 99.5 | 1 IP 1 17440-41-7 IBerylliuml 0.34 | | |F | 17440-43-9 1 Cadmium | 1.7 | |* IP 1 17440-70-2 1 Calcium I 4970 j I* jP 1 17440-47-3 1 Chromium | 12.9 | j* jP | 17440-48-4 1 Cobalt j 13.6 | | |P | 17440-50-8 1 Copper | 51.7 | | |P | 17439-89-6 [Iron | 24800 j j* |P | 17439-92-1 ILead j 3.4 | j |F j 17439-95-4 jMaqnesiuml 5360 j j* jP j 17439-96-5 jManqanesel 858 | | |P | 17439-97-6 jMercury 1 0.14 | j |CV| 17440-02-0 INickel 1 16.0 | j jP | 17440-09-7 jPotassiuml 936 |B| jP | 17782-49-2 |Selenium 1 3.3 L»1"N K IF | 17440-22-4 ISilver 1 1.2 |U| |P | 17440-23-5 1 Sodium | 908 |B1 IP j 17440-28-0 IThallium j 0.63 jUJ^ IF j 17440-62-2 [Vanadium | 108 | |* IP 1 17440-66-6 jZinc | 45.4 | j jP | 157-12-5 1 Cyanide j 1.2 |U| X |AS| 1 1 1 l l l l olor Before: BROWN Dior After: YELLOW omments: ROCKS Clarity Before: Clarity After: CLEAR Reviewed By Date Text:ure: MEDIUM A r t i f a c t s : YES «ed By Q ^ f f ^ 7 ^ 1 / ^ / ? ^ ^ FORM I - IN 300709 ILMp2.0 116 U.S. EPA - CLP EPA SAMPLE NO. r RBSOOl INORGANIC ANALYSIS DATA SHEET b Name: PACE Contract: 1 ^j Lab Code: GULF Case No.: HLA ' SAS No.: SDG No.: 095010 Matrix (soil/water): WATER Lab Sample ID: VTX004 Level (low/med): LOW Date Received: 02/01/95 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L 1 1 1 l l l l |CAS No. 1 Analyte 1 Concentration 1C| Q jM | 1 1 1 l l l l 17429-90-5 1 Aluminum j 26.4 IBl |P 1 17440-36-0 jAntimony 1 1.4 JUIN |F | 17440-38-2 lArsenic 1 1.1 IU|W rT IF 1 17440-39-3 IBarium | 8.8 |U| |P 1 17440-41-7 IBerylliuml 0.10 1U|N* TT IF 1 17440-43-9 jCadmium 1 3.1 lUl |P | 17440-70-2 ICalcium | 88.5 IBl jP | 17440-47-3 1 Chromium | 4.1 |U| |P j 17440-48-4 1 Cobalt 1 9.5 |UL IP I 17440-50-8 1 Copper 1 16.7 |U| |P | 17439-89-6 |Iron | 32.1 |U| |P | 17439-92-1 ILead | 0.50 |U| |F | 17439-95-4 |Magnesium| 26.0 |U| |P | 17439-96-5 |Manqanese| 2.6 |U| |P | 17439-97-6 |Mercury | 0.20 |U| |CV| 17440-02-0 INickel 1 13.1 lUl |P 1 17440-09-7 1 Potassium! 526 |UI |P j 17782-49-2 |Selenium | 1.4 lUjW 3" |F 1 17440-22-4 ISilver | 5.1 |U| |P | 17440-23-5 jsodium, \ 339 |U| |P | 17440-28-0 IThallium | 2.7 |U|W 3" [F | 17440-62-2 IVanadium | 4.5 |U| [P | 17440-66-6 IZinc | 12.1 |B| |P | 157-12-5 1 Cyanide | 10.0 |Ul LAS j 1 1 1 l l l l Color Before: COLORLESS Color After: COLORLESS Comments: Clarity Before: CLEAR Clarity After: CLEAR VALID Reviewed By Date Texture: » Artifacts: NO y^A/t^^ FORM I - IN 300710 ILM02.0 1017 U.S. EPA - CLP EPA SAMPLE NO. r « S00118 INORGANIC ANALYSIS DATA SHEET b Name: PACE Contract: | | b Code: GULF Case No.: HLA SAS No.: SDG No.: 095010 Matrix (soil/water): WATER Lab Sample ID: VQCOOl Level (low/med): LOW Date Received: 01/23/95 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L 1 1 1 l l l l ICAS No. 1 Analyte |ConcentrationlC| Q |M | 1 II llll 17429-90-5 1 Aluminum | 22.9 |B| |P 1 17440-36-0 lAntimony | 1.4 |U|N |F | 17440-38-2 lArsenic I 1.1 |U| |F 1 17440-39-3 IBarium | 8.8 |U| |P | 17440-41-7 IBerylliuml 0.10 1U|N* 3" |F | 17440-43-9 1 Cadmium 1 3.1 |U| |P | 17440-70-2 ICalcium 1 42.0,IBl |P | 17440-47-3 1 Chromium | 4.1 |U| |P j 17440-48-4 iCobalt j 9.5 |U1 LP 1 17440-50-8 jCopper I 16.7 |U| |P I 17439-89-6 |Iron | 32.1 |U| [P | 17439-92-1 ILead 1 0.50 |U| |F 1 17439-95-4 |Magnesium| 26.0 |U| |P | 17439-96-5 IManganesej 2.6 1U| |P | 17439-97-6 |Mercury | 0.20 |U| |CV| 17440-02-0 INickel 1 13.1 |U| |P I 17440-09-7 IPotassiumI 526 |U| |P | 17782-49-2 |Selenium | 1.4 |U|W X IF | 17440-22-4 ISilver 1 5.1 |U| |P I 17440-23-5 ISodium 1 339 | UJ- |P | 17440-28-0 IThallium 1 2.7 lUlW T IF | 17440-62-2 [Vanadium | 4.5 jUJ |P | 17440-66-6 IZinc | 13.3 |B| |P | 157-12-5 ICyanide | 10.0 |U| X |AS| 1 i 1 l l l l Color Before: COLORLESS Color After: COLORLESS Comments: Clarity Before: CLEAR Clarity After: CLEAR Reviewed By Date Texture: Artifacts: NO VAW DATED % kffyx^. ^n]'^^ FORM I - IN 300711 ILM02.0 0018 U.S. EPA - CLP EPA SAMPLE NO. € b Name: PACE b code: GULF Matrix (soil/water): WATER Level (low/med): LOW % Solids: 0.0 INORGANIC ANALYSIS DATA SHEET Contract: Case No.: HLA SAS No.: I S00119 SDG No.: 095010 Lab Sample ID: VQBOOl Date Received: 01/23/95 Concentration Units (ug/L or mg/kg dry weight): UG/L 1 1 ICAS No. 1 1 1 17429-90-5 1 17440-36-0 1 17440-38-2 1 17440-39-3 17440-41-7 17440-43-9 17440-70-2 17440-47-3 17440-48-4 17440-50-8 17439-89-6 17439-92-1 17439-95-4 17439-96-5 17439-97-6 17440-02-0 17440-09-7 17782-49-2 17440-22-4 17440-23-5 17440-28-0 17440-62-2 17440-66-6 157-12-5 1 Analyte Aluminum ! Antimony Arsenic | Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium 1 Zinc Cyanide Concentration | 22.5 1 1.4 ! 1.1 1 8.8 0.10 1 3.1 132 4.1 9.5 16.7 95.9 0.64 26.0 4.4 0.20 13.1 526 1.4 5.1 339 2.7 1 4.5 1 19.1 1 10.0 1 C| 1 1 Q 1 1 Bl U|N j Uj U| U|N-' T T Ul Bj Ul Ul Ul Bl ^sr u Ul Bl Ul Ul Ul Ul Ul Ul U|W J^ U| IBl |U| J- 1 1 M 1 P 1 F 1 F 1 P 1 F 1 P 1 P 1 P 1 P 1 P 1 P 1 F 1 P 1 P 1 CV| P 1 P 1 F 1 P I P 1 |F 1 |P 1 |P 1 |AS| Color Before: COLORLESS Color After: COLORLESS Comments: Clarity Before: CLEAR Clarity After: CLEAR Texture: t Artifacts: NO Reviewed By Date — ^MP'-^ FORM I - IN 300712 ILM02.0 0S0019 U.S. EPA - CLP EPA SAMPLE NO. € SO0120 INORGANIC ANALYSIS DATA SHEET b Name: PACE Contract: I _| b Code: GULF Case No.: HLA SAS No.: SDG No.: 095010 Matrix (soil/water): WATER Lab Sample ID: VQAOOl Level (low/med): LOW Date Received: 01/23/95 % solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L 1 1 1 l l l l |CAS No. 1 Analyte 1 Concentration!Cl Q IM | 1 I I llll 17429-90-5 1 Aluminum | 26.7 |B| |P 1 17440-36-0 (Antimony 1 1.4 |U|N |F | 17440-38-2 lArsenic | 1.1 |U| |F | 17440-39-3 IBarium | 8.8 |U| |P | 17440-41-7 IBerylliuml 1.7 1 IN* U T IF 1 17440-43-9 1 Cadmium | 3.1 |U| |P | 17440-70-2 ICalcium 1 55.8 |B| |P 1 17440-47-3 1 Chromium | 5.6 LB-T U IP 1 17440-48-4 ICobalt | 9.5 |U| |P I 17440-50-8 ICopper | 16.7 1U| |P | 17439-89-6 jlron j 46.3 jB| jP j 17439-92-1 ILead j 0.50 jU| |F 1 17439-95-4 jMaqnesiumj 32.0 j^T \J IP 1 17439-96-5 |Manganese| 2.6 |U| |P I 17439-97-6 |Mercury | 0.20 |UI |CV| 17440-02-0 INickel 1 13.1 |U1 |P I 17440-09-7 jPotassiuml 526 |U| jP I 17782-49-2 |Selenium | 1.4 |U| |F | 17440-22-4 ISilver | 5.1 lUI IP 1 17440-23-5 ISodium 1 339 |U| |P | 17440-28-0 IThallium 1 2.7 lUIW T IF | 17440-62-2 IVanadium j 4.5 jUj |P j 17440-66-6 jZinc j 17.1 |Bj jP | 157-12-5 jCyanide | 10.0 jU| jASj 1 1 1 l l l l Color Before: COLORLESS Color After: COLORLESS Comments: • Clarity Before: CLEAR Clarity After: CLEAR Texture: Artifacts: NO Reviewed Date FORM I - IN 300713 ILM02.0 0S0020 U.S. EPA - CLP EPA SAMPLE NO. W SO0125 INORGANIC T^ALYSIS DATA SHEET b Name: PACE Contract: | | Lab Code: GULF Case No.: HLA SAS No.: SDG No.: 095010 Matrix (soil/water): WATER Lab Sample ID: VSIOOl Level (low/med): LOW Date Received: 01/27/95 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L i 1 1 l l l l ICAS No. 1 Analyte |Concentration!Cl Q |M 1 1 1 1 l l l i 17429-90-5 1 Aluminum 1 26.3 IB| |P | 17440-36-0 {Antimony { 1.4 {U{N (F { {7440-38-2 {Arsenic | 1.1 |U{ |F { 17440-39-3 IBarium j 8.8 IU! IP 1 17440-41-7 IBerylliuml 0.10 iU|N* T IF | 17440-43-9 {Cadmium | 3.1 |U| |P | 17440-70-2 ICalcium | 56.8 |B| |P | 17440-47-3 1 Chromium { 5.3 LBT U IP { 17440-48-4 ICobalt j 9.5 1U| |P | 17440-50-8 ICopper | 16.7 |U| |P | 17439-89-6 |Iron 1 32.1 |U| |P | 17439-92-1 ILead | 0.86 |>r [>( |F | {7439-95-4 {MagnesiumI 26.0 {U{ {P j {7439-96-5 {Manganese{ 2.6 jUj IP I 17439-97-6 |Mercury | 0.20 |U| |CV| 17440-02-0 {Nickel 1 13.1 |U| |P | 17440-09-7 jPotassiuml 526 {U| |P | {7782-49-2 {Selenium 1 1.4 jUj jF j {7440-22-4 {Silver | 5.1 |U| jP j 17440-23-5 {Sodium ( 359 !B{ |P | 17440-28-0 (Thallium | 2.7 |U|W 3" IF | j7440-62-2 {Vanadium { 4.5 {U{ |P { {7440-66-6 (Zinc | 12.7 jBj |P { {57-12-5 ICyanide j 10.0 |U{ |AS| 1 1 1 Mil Color Before: COLORLESS Color After: COLORLESS Comments: Clarity Before: CLEAR Clarity After: CLEAR Reviewed By Date FORM I - IN Texture: Artifacts: NO 300714 ILM02.0 080021 HLA DATA QUALITY ASSURANCE REVIEW SL14MARY Organochlorine Pesticides and Polychlorinated Biphenyls Analysis Case Number : C^ ^ Q ) Q %fiyi^ CJU^/Y^I>1 fWxy.^^^ ProjectNumber Z ^ S H Z Z . l O - Z . Site: Contractor Laboratory: P / V C P ^ ^ ^ L n ^ . validator X . i V l ^ ^ Validation Date: 3/:g^/q5- , « ——T QC Reviewer ^7>^y^-<y.^ :^. > y ^ y 7 y ^ Sample Matrix: j o - { i , ( | 2 ^ ) l J A : f e . - y 5 ) Review Date: J y 7 / / ^ j ~ - Analytical Method: ^pfi^ ( ^ p /Qy, ^ : , > ^ . ^ Q , , ; Sample Designations: C2o<oOI C^Z2o7-z. (2221^2/^ P l o o n l D)IZ/4 P122-2^^- P200^0 PZI^ZI P3ooo^ D ^ n q Eiooo^ BUo^Z- RBSOOl knoll's Son n ^ Soo\2n S Q O l l ^ Data for the above samples are: Acceptable for use X Acceptable for use as qualified Unacceptable for use Is action required by the Prtrject Manager? Yes (Noy Comments: p^^jtei JU^t^je. JU^i-tlJUx^d^ j y A j y r ^ J^^M, \A6^^PfK ( V K W O ^ ocp_l.doc 10141994 1032 Form OCP 1.0 3 0 0 7 1 5 DATA COMPLETENESS CHECKLIST X Included, no problems * Included, problems O Not included NA Not applicable Quality Control Summary X Case Narrative Surrogate Recovery Summary MS/MSD Summary X Reagent Blank Summary Sample Data yT* Chain of Custody Forms ^ Holding Times X Organic Anaiysis Data Sheets X Quantitation Reports X GC/EC Chromatograms y* Pesticide/PCB Identification (for positive detections) Instrument Calibration and Performance Data X Initial Calibration Retention Time Summary y Initial Calibration Response Factor Summary • ^ Performance Evaluation Mix Summary X Continuing Calibration Verification Summary y Analytical Run Sequence Summary X GPC Calibration and Florisil Cartridge Check Summary y Pesticide/PCB Standards Quantitation Reports X Pesticide/PCB Standards GC/EC Chromatograms Reagent and Instrument Blank Data X Organic Analysis Data Sheets X Quantitation Reports X GC/EC Chromatograms X Pesticide/PCB Identification (for positive detections) ocp_l.doc 10141994 1032 Fonn OCP 1.0 300716 Matrix Spike Data y Organic Analysis Data Sheets Quantitation Reports X GC/EC Chromatograms Conunents: Fonn OCP IJ) ocp_l.doc 10141994 1032 3 300717 Harding Lawson Associates m''. _- j Engineering and : i I ==.: 1 Environmental Services SHEET. JOB NO. OF PROJECT. SUBJECT m ^ ^ i ^ i ^ d C L i A i ^ d ^ Cjyf^A^Oy^^ DATE S l ^ ^ - I ^ ^ COMPUTED BY C\. jJljJdtS^ CHECKED BY ^^JJty^-V? 53VZ10-0-Zo/oil'^^ 5' 50012,0 S O O I I ^ S3B\/o,0''0.flDH^'^^ ^Icoo^ 5aP)/o-l/oi^f-9^ SgPl/22-24/o|25'^r SBCz/^--|/oi3 0^F 50012-5' PlOOOl Dii2m' P12J224- CZOOOI CZZZ02ZL C2Z4-26 \fSlc-ooz- \/5j:-^o7, V5X-003 VTX-0 0 1 * I ^ 300718 • SPECinC COMMENTS REGARDING ANALYSES Chain Of Custody Were samples property pi and received in good condition? Yesj No Comments: T^MTCT C%^^ZK^ Jy^^yjL yAy/^^fJi^ 0(yiAji/trx j^J2yUiM>^ oJIrtr^ M J - 2*'6*C^ C^-d^ji^^y£lyru\Jl, CUUi«rxjC&y^y-A^-j^ ± I J L C O C ^ . J^iyyUUi^yUy. • Holding Times Were sample extractions performed-within holding times? Yes ( N O ) Were sample analyses p^fefuned within holding times? (^Yes) No Comments: -A&/Yy\.\lJU O 2-02*2 1 A T ^ I ^ :i2.022.jur^i^ Ji7tA.a^iteJ2_ I c^^x^ y^lA/^ z / ^ J^Akriy^ jyrtK>^ OAY^^Y^ jJl^^^^i^ M ^ - l m l oJz O w jd^yycCXliL /\lyjrrf\y(<^jy(KAsJL ( T / U T ) . T ^ X C yUiorx^H-UL^l^ (TL y^A)yrA/^^ ocp_l.doc 10141994 1032 Focrn OCP 1.0 3 0 0 7 1 9 Initial Calibration Did the laboratory meet the guidelines regarding the minimum number of calibration standards for an acceptable initial calibration? 'YesJ No Were the calibration standards, analyzed at the correct concentrations? /Yes) No Did the calibration curves meet thejiqearity criteria for maximum percent relative standard deviation (%RSD)? Yes PNOJ Were retention time windosfs-provided and correcUy calculated? ( Y C ^ No Were peak resolutions acceptable? (Yes) No Comments: ( I J L ^ jze y ^ n J L 13 - J ^ &^ J l i ^ C/L AO^yf^^yohy Oliy^JS-VyCji Individual Mix Standards (Continuing Calibration) Did the individual mix stajjdards meet the linearity criteria for maximum percent difference (%D)? (Tes) No Did the individual mix standanls meet the retention time criteria? (Tes) No Comments: |/Uvv>C , . Form OCP 1.0 OCp_l.ODC 10141994 1032 5 300720 Performance Evaluation Mix Standards (Continuing Calibration) Did the performance evalu^tien mix standards meet the linearity criteria for maximum percent difference (%D)? /Yes) No Did the performance evaluation mix standards meet the retention time criteria? fes) No Ylmt Analytical Sequence Were standard and sample^aRglyses performed following the correct analytical sequence? Cves) No yu-Tv^ Surrogate Recoveries Were the surrogate spike recoveries-w^thin acceptance limits? Yes (No If the spike recoveries w^jcThiacceptable. were the samples reanalyzed? Yes) No Comments: ^IcUvvnilc. S O O I Z O O y ^ : k i j L y \ J U W ^ o i ^ > ^ ( ^ O O I Z J O R ^ ^ O d ^ - ^ ^ ^ yC7r^jb\^>t^ jduAn<^tu>^ yju^/(r\yiyvJU. $r/}^jML cXji^y^^rr^^/y^pM -T^-M^yCicJ^M^ 300721 Matrix Spikes Were matrix spike analyses performed at the correct firequency and on a sample matrix representative of the samples in this sample deUyeiy group (SDG)? /Yes) No Were the matrix spike recoveries and relative percent differences (RPDs) within acceptance criteria? (Yes) No Comments: ]/Y]5 VY^SP ym/v^tHwv(u£ trvi Blank Analyses Were the appropriate numbgiof blank analyses performed? /fes) No Were instrument blanks analyzed at the correct frequency? (YesJ No Were analytes reported in the bla Yes /No If analytes were reported in the blanks, were the same analytes also reported in the associated investigative samples? . Yes No f^A Did the sample results require quajifieation due to the presence of analytes in the associated blank samples? Yes ( N o ) Comments: YUv^A^ ocp_I.doc 10141994 1032 FotmOCP 1.0 300722 Instrument Performance Were the percent breakdowpsJor 4,4'-DDT and endrin correctiy reported? ( J e s ) No Were the percent breakdo^nsJor 4.4'-DDT and endrin within acceptance limits? (Yes) No Comments: " j 3 U yjl^^^rtudx^rr- ^^jaeAAvytTOAvC^ (yLoyAt- - ^ ^ ^ ' l ^ ^ j ^ ^ > V M r ^ ^ ^ ^ ^^m^\7^ S o o n ? 0<AJI S O D \ \ \ jJy^dxx^yJblJl 0^ Ja^^P/oj^/\A^^^ \D% J r t 4,^'-PP^, JlyJywcjd^ U n ^ j M ^ ' ^^'-PP^aAM>4-H^ ^^JjCte-^i^, >-jrfviJ4J^ > ^ ^ ^ ^ ()yy^ y^^AAZl^jT (dy)t^(^XA^^ d x S i \ ^ / y A A ^ 66-eiufeei^OAOC^>Zv^^i-e-v^ GPC and Florisil Cartridge Check Was GPC cleanup performB4^n the sample extracts? ( j e s j No Was the GPC column checjc-acceptable? (Yes) No NA Was a Florisil cartridge chpck performed? (Yes) No Was the Florisil cartridgepheck acceptable? (YesJ No NA YuPAJty ocp_l.doc ^ 10141994 1032 8 _F_onn_0CP_1.0-- 300723 Laboratory Control Samples Were LCS analyses perfonped;' 'Yes) No Were the LCS recoveries within acceptable limits? (Yes) No NA yWe. Sample Results Were target analytes reported^ the investigative samples? (Yes) No Were chromatograms proyidedsfor all target analytes reported in the investigative samples? (jTes^ No Were chromatograms of apeeptable quality and were analytes correcUy identified? (/Qs) No Were the quantitated results for target analytes calculated using the appropriate standard and were the retention times (RTs) acceptable? . /Yes) No Comments: T ^ ^ .ymKCl2yyJr S j U i M ^ l y r ^ U i ^ J y X < ^ ^ (>L^>WL ££ffet*^T^ FoanOCP IS) ocp_l.doc 10141994 1032 9 300724 Calculation Check Initial Calibration V T J Z G J ^ Retention Time Window: %RSD: Continuing Calibration \ f Z l j ^ ^ l ^ %D:rpB6»08^ 0(^-0g^ jTNjpgmc??^ -^ ;—= pr -—• y - \UU >- 60 1^ 1 y-OA^ ii/fy\^'<»y^cr Surrogate Recovery] A ^ y y ^ 6 Q Q | H | ' ' 0-C?4^ XI OO :^ 7- 5"7o : ^ 4,4^ "P; Matrix Spike Recovery .5&/yyu*2J2x ^ \ 0 0 0 ^ RPD: YY15 m^P Ow^^^^^ Urwc^. — ^ - j X loo r \3^o M^ JIM:^(IZU\-. «... 1 A^ Fonn OCP ijQ 10141994 1032 10 300725 Sample Results I _>MtH/y3Xe ^ [ 0 0 0 ^ CRQL: ~ % J M U ^ - (7-^^jf^^ML QSiQi, z^'Z^ y Positive Result: ocp_l.doc FonaOCFIJ) 10141994 1032 J J 300726 HOLDING TIME QUALIHCATION SUMMARY FORM Sample Identification 1 ^XZOZZ. Soo|:;..o^^ ' Date Siunpled l//q/^^ \/7.ol^5' Date Prepared 2/^A^ 2/3/^5- Date Analyzed T-Z-Z-o/qS- z/ll}oi5' Prep. Holding Time lO- 7 Analysis Holding Time 0,0 ^-0 Qualifier r/o.:r 3-/U3- o o to Comments: ocp_l .doc 1014l9»t 1032 FcraOCP 1.0 12 INITIAL CALIBRATION QUALIFICATION SUMMARY FORM Date/Time Izlioh^' Instrument GrCX'^ &CX- \S- Analyte P()J)^n.-?>WCy "pixdlk^-mcL RF — —• 7oRSD 20. S 20.8 Samples Affected E:I2^)2.Z-, CZOOOl . (ZZlZ02zZ.i C224-26, DIIZl^, DI^^^4; D1non\ Qualifier C+/-) j/tfT 1 1 . . . II U> o o V j to 00 Comments : oq>._l .doc 1 10141994 1032 13 FcraOCP 1.0 CONTINUING CALIBRATION QUALIFICATION SUMMARY FORM Date/Time f ( M <1A V Instrument VAXLAU-UC/VJ Analyte w ^ OJlZ^OUux^ AJ)^ d %D \JL yvu:^ Samples Affected - ^ .-' Qualifier 1 bJ o o <3 to VX) Coinmenis 1 1 ocp,l.d.« i 10141994 1032 Fenn OCP 1.0 14 BLANK SUMMARY FORM Blank ID (y\yfr cUskiy^ Analyte L lAA^ ^ficyy^l^ Blank Result Units 5x Result Associated Samples Qualifier 1 to o o U) o Commcnis: ocp_I .doc 10141994 1032 Fonn OCP I.O 15 Summary and Conclusions OiU Acdyx lytjy. fi/yini}. .>^a(yv\^. AJUACK^ Q M M QCf Mt^^ALy(AA.fi^t(l CX^^"^. ay^z^ •tL OAJP. AAM-riv, A "P" /^/Kvd? (lJ^:iy^yTiyn^ I H .-kzlj rd/JzkA.(T) X4^ -jig. ^ ^ A . - v ^ <Har xikjC-jiXivr (Z(y,{Krc/\yr7y- fUJLy .Xtiy^)^ a " P y 0 / ^ ^ ,i-S^^iiycr\6SKynf^ Aly(^.^n^^OAA(^j.fi . Zl V\L09Ay^ C2000I^ C2-Z-02.7_^ C?_2M-^^ P I I 2 l ^ , D]7j2-Zt^ ^/^,./(^ I>l OOO I ^A^vtUL^ A-JL i/>>.AAv»y i-y* Kyur^ni^xn,^ / or,lPy^^Ar^yMl'/ , Kf^QiyJ^ (J ,>!hnK'j/^^t-Jiy /y"" rn JJ/W^ i \^Mif(iy^ Validator's Signature: Validator's Initials: Validation Date: 3 / 3 0 H S ^ QC Reviewer's Signature: ^ •yy-cA^ QC Reviewer's Initials P^Tr Review Date: ? / 7 / / ? j ~ ocp_l.doc I0I41994 1032 16 Fonn OCP IJ) 300731 ID PESTICIDE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. Name: G S E L I '._ Contract: H^JA Case No.: HLA SAS No.: C20001 Code: PACE Matrix: (soil/water) SOIL Sample wt/vol: 30.0 (g/mL) 5 % Moisture: 11 decanted: (Y/N) JJ Extraction: (SepF/Cont/Sonc) SONC SDG No.: 95010 Lab Sample ID: VTXOOl Lab File ID: Concentrated Extract Volxime: Injection Volume: 1^00 (uL) GPC Cleanup: (Y/N) 5000 (UL) pH: 8.2 Date Received: 02/01/95 Date Extracted: 02/03/95 Date Analyzed: 02/20/95 Dilution Factor: 1.00 CAS NO. COMPOUND Sulfur Cleanup: (Y/N) ^ Q CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG 319-84-6 319-85-7 319-86-8 58-89-9 76-44-8 309-00-2 1024-57-3 959-98-8 60-57-1 72-55-9 72-20-8 33213-65-9 72-54-8 1031-07-8 50-29-3 72-43-5 53494-70-5 7421-93-4 5103-71-9 5103-74-2 8001-35-2 12674-11-2 11104-28-2 11141-16-5 53469-21-9 12672-29-6 11097-69-1 11096-82-5 -alpha-BHC -beta-BHC_[ delta-BHC -gamma-BHC (Lindane) -Heptachlor \ -Aldrin -Heptachlor epoxide_ -Endosulfan I ^ -Dieldrin -4,4' -DDE -Endrin •Endosulfan II -4,4' -DDD " -Endosulfan sulfate -4,4' -DDT " Methoxychlor__ Endrin ketone -Endrin Aldehyde_ -alpha-Chlordane" -gamma-Chlordane" -Toxaphene ' —Aroclor-l016_ —Arocl or-12 21' —Aroclor-1232' —Aroclor-1242^ —Aroclor-1248^ —Aroclor-1254" —Aroclor-1260' FORM I PEST Reviewed By Date ID PESTICIDE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE.NO. w ame: G S E L I IjaB'Code: PACE Case No.: HLA latrix: (soil/water) SOIL sample wt/vol: 30.0 (g/mL) Q i Moisture: 15 decanted: (Y/N) H Extraction: (SepF/Cont/Sonc) SONC Contract: HIA. SAS No.: C22022 SDG No.: 95010 Lab Sample ID: VTX002 Lab F i l e ID: :oncentrated Extract Volume: [njection Volume: 1.00 (uL) ;PC Cleanup: (Y/N) 5000 (uL) pH: 9.0 Date Received: 02/01/95 Date Extracted: 02/03/95 Date Analyzed: 02/20/95 Dilution Factor: 1.00 CAS NO. COMPOUND Sulfur Cleanup: (Y/N) E Q CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG 319-84-6 alpha-BHC 319-85-7 beta-BHC 319-86-8 delta-BHC 58-89-9 gamma-BHC fLindane) 76-44-8 Heptachlor 3 09-00-2 Aldrin 1024-57-3 Heptachlor epoxide 959-98-8 Endosulfan I 60-57-1 Dieldrin 72-55-9 4, 4'-DDE 72-20-8 Endrin 33213-65-9 Endosulfan II 72-54-8 4, 4'-DDD 1031-07-8 Endosulfan sulfate 50-29-3 4 , 4 ' -DDT 72-4 3-5 Methoxychlor 53494-70-5 Endrin ketone 7421-93-4 Endrin Aldehvde 5103-71-9 alpha-Chlordane 5103-74-2 gamma-Chlordane 8001-35-2 Toxaphene 12674-11-2 Aroclor-1016 11104-28-2 Aroclor-1221 11141-16-5 Aroclor-1232 53 469-21-9 Aroclor-1242 12672-29-6 Aroclor-1248 11097-69-1 Aroclor-1254 11096-82-5 Aroclor-1260 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 3.9 3.9 3.9 3.9 3.9 3.9 3.9 20 3.9 3.9 2.0 2.0 200 39 79. 39 39 39 39 39 UU" U U U U U u u u u u u u u u u u u u u u u u u u u u u FORM I PEST 300733 ID PESTICIDE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. Lal^ame: G S E L I LM^lode: PACE Case No.: HLA Contract: HLA SAS No.: C22426 SDG No.: 95010 Matrix: (soil/water) SOIL sample wt/vol: 30.0 (g/mL) 2 % Moisture: 14 decanted: (Y/N) H Extraction: (SepF/Cont/Sonc) SONC Lab Sample ID: VTX003 Lab File ID: Concentrated Extract Volume: Injection Volume: l.OQ (uL) GPC Cleanup: (Y/N) ?999 (UL) pH: 8.6 Date Received: 02/01/95 Date Extracted: 02/03/95 Date Analyzed: 02/20/95 Dilution Factor: 1.00 CAS NO. COMPOUND Sulfur Cleanup: (Y/N) M Q CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG 319-84-6 319-85-7 319-86-8 58-89-9 76-44-8 309-00-2 1024-57-3 959-98-8 60-57-1 72-55-9 72-20-8 33213-65-9 72-54-8 1031-07-8 50-29-3 72-43-5 53494-70-5 7421-93-4 5103-71-9 — 5103-74-2 8001-35-2 12674-11-2 11104-28-2 11141-16-5 53469-21-9 12672-29-6 11097-69-1 11096-82-5— -alpha-BHC -beta-BHC_^ delta-BHC -gamma-BHC (Lindane) -Heptachlor_] -Aldrin -Heptachlor epoxide_ -Endosulfan I -Dieldrin -4,4'-DDE -Endrin -Endosulfan II -4,4' -DDD " -Endosulfan sulfate -4,4' -DDT '_ Methoxychlor_ Endrin ketone —Endrin Aldehyde_ —alpha-Chlordane_ —gamma-Chlordane, —Toxaphene —Aroclor-1016_ —Aroclor-1221" —Aroclor-1232[ —Aroclor-1242]^ —Aroclor-1248] —Aroclor-1254' Aroclor-1260 FORM I PEST Reviewed By Date — VALID 300734 ID PESTICIDE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. Lab^Name: G S E L I J ode: PACE Case No.: HLA Matrix: (soil/water) SOIL Sample wt/vol: 30.0 (g/mL) £ % Moisture: _§ decanted: (Y/N) H Extraction: (SepF/Cont/Sonc) SONC Contract: HLA SAS No.: DlOOOl SDG No.: 95010 Lab Sample ID: VSI002 Lab File ID: Concentrated Extract Volume: Injection Volvime: 1.00 (uL) GPC Cleanup: (Y/N) 5000 (uL) pH: 8.3 Date Received: 01/27/95 Date Extracted: 02/01/95 Date Analyzed: 02/21/95 Dilution Factor: 1.00 CAS NO. COMPOUND sulfur Cleanup: (Y/N) ^ Q CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG 319-84-6 alpha-BHC 319-85-7 beta-BHC 319-86-8 delta-BHC 58-89-9 gamma-BHC (Lindane) 76-44-8 Heptachlor 309-00-2 Aldrin 1024-57-3 Heptachlor epoxide 959-98-8 Endosulfan I 60-57-1 Dieldrin 72-55-9 4 , 4 ' -DDE 72-20-8 Endrin 33213-65-9 Endosulfan II 72-54-8 4 , 4 ' -DDD 1031-07-8 Endosulfan sulfate 50-29-3 4 , 4 ' -DDT 72-43-5 Methoxychlor 53494-70-5 Endrin ketone 7421-93-4 Endrin Aldehyde 5103-71-9 alpha-Chlordane 5103-74-2 gamma-Chlordane 8001-35-2 Toxaphene 12674-11-2 Aroclor-1016 11104-28-2 Aroclor-1221 11141-16-5 Aroclor-1232 53469-21-9 Aroclor-1242 12672-29-6 Aroclor-1248 11097-69-1 Aroclor-1254 11096-82-5 Aroclor-1260 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 3.6 3.6 3.6 3.6 3.6 3.6 3.6 19 3.6 3.6 7.2 7.7 190 36 73, 36 36 36 36 36 uJ- u U u u u u u u u u u u u u u u u ^ T u u u u u u u u FORM I PEST VA Reviewed By _ Date 300735 ID PESTICIDE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. T.ai|iy^=»™*** ^ S E L I Contract: W T.ar) Co Matrix Sample % Mois Extrac Concer Inject 3PC Cl • • de: PACE Case No.: p^^ SAS No.! HLA SDG : (soil/wateri SOIL Lab Samole ID: wt/vol: 30.0 (q/mL) G Lab File ID: ture: 17 decanted: (Y/N) N Date Received: tion: rsepF/Cont/Sonc) SONC Date Extracted itrated Extract Volume: 5000 (uL) Date Analvzed: .ion Volxime: 1.00 (uL) Dilution Facto. eanup: (Y/N^ Y pH: 8.8 Sulfur Cleanup CONCENTRATION UNITS: CAS NO. COMPOUND (ug/L or ug/Kg) UG/K 319-84-6 alpha-BHC 319-85-7 beta-BHC 319-86-8 delta-BHC 58-89-9 qamma-BHC (Lindane) 76-44-8 Heptachlor 309-00-2 Aldrin 1024-57-3 Heptachlor epoxide 959-98-8 Endosulfan I 60-57-1 Dieldrin 72-55-9 4 ,4 ' -DDE 72-20-8 Endrin 33213-65-9 Endosulfan II 72-54-8 4 ,4 ' -DDD 1031-07-8 Endosulfan sulfate 50-29-3 4 ,4 ' -DDT 72-43 -5 Methoxychlor 53494-70-5 Endrin ketone 7421-93-4 Endrin Aldehyde 5103-71-9 alpha-Chlordane 5103-74-2 gamma-Chlordane 8001-35-2 Toxaphene 12674-11-2 Aroclor-1016 11104-28-2 Aroclor-1221 11141-16-5 Aroclor-1232 53469-21-9 Aroclor-1242 12672-29-6 Aroclor-1248 11097-69-1 Aroclor-1254 11096-82-5 Aroclor-1260 FORM I PEST Reviewec Date D11214 No.: 95010 VST003 01/27/?5 : 02/01/95 02/?l/95 r: 1.00 : (Y/N) N S Q 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 20 4.0 4.0 2.0 2.0 200 40 80 40 40 40 40 40 Ml' Z^ 'izir^ h p p p p p p p p p p p p P P P P P P P P P P P P P O t s O iyj\XAytz ?/ fPT 3/90 lyZjJ i<^ - ' y_ 30073~r ID PESTICIDE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. Lal^ ame: G S E L I LaBM:ode: PACE Case No.: HLA Matrix: (soil/water) SOIL sample wt/vol: 30.0 (g/ioL) G % Moisture: 12 decanted: (Y/N) li Extraction: (SepF/Cont/Sonc) SONC Contract: HLA SAS No.: D12224 SDG No.: 95010 Lab Sample ID: VSI004 Lab File ID: Concentrated Extract Volume: Injection Volume: 1.00 (uL) 3PC Cleanup: (Y/N) 5000 (uL) pH: ?t$ Date Received: Ql/27/95 Date Extracted: 02/01/95 Date Analyzed: 02/21/95 Dilution Factor: 1.00 CAS NO. COMPOUND Sulfur Cleanup: (Y/N) H Q CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG 319-84-6 319-85-7 319-86-8 58-89-9 76-44-8 309-00-2 1024-57-3 959-98-8 60-57-1 72-55-9 72-20-8 33213-65-9 72-54-8 1031-07-8 50-29-3 72-43-5 53494-70-5 7421-93-4 5103-71-9 5103-74-2 8001-35-2 12674-11-2 11104-28-2 11141-16-5 53469-21-9 12672-29-6 11097-69-1 11096-82-5 alpha-BHC beta-BHC_J delta-BHC —-gamma-BHC (Lindane) Heptachlor Aldrin Heptachlor epoxide_ Endosulfan I '_ Dieldrin 4,4'-DDE Endrin Endosulfan II 4,4'-DDD Endosulfan sulfate 4,4'-DDT Methoxychlor Endrin ketone Endrin Aldehyde, alpha-Chlordane' gamma-Chlordane^ Toxaphene_ Aroclor-1016_ Aroclor-1221' Aroclor-1232] Aroclor-1242" Aroclor-1248' Aroclor-1254] Aroclor-1260" FORM I PEST Reviewed By Date Urii}A( 3/90^ 300737 ID PESTICIDE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. LaK; ame: G S E L I Code: PACE Case No.: HLA Matrix: (soil/water) SOIL Sample wt/vol: 30.0 (g/mL) fi % Moisture: Ifi decanted: (Y/N) M Extraction: (SepF/Cont/Sonc) SONC Contract: HLA SAS No.: D20020 SDG No.: 95010 Lab Sample ID: VOB003 Lab File ID: Concentrated Extract Volume: Injection Volume: 1.00 (uL) 3PC Cleanup: (Y/N) 50Q9 (UL) pH: 8.3 Date Received: 01/23/95 Date Extracted: 01/25/95 Date Analyzed: 02/03/95 Dilution Factor: 1.00 CAS NO. COMPOUND Sulfur Cleanup: (Y/N) li Q CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG 319-84-6 319-85-7 319-86-8 58-89-9 76-44-8 309-00-2 1024-57-3 959-98-8 6 0 - 5 7 - 1 72-55-9 72-20-8 33213-65-9 72-54-8 1031-07-8 50-29-3 72-43-5 53494-70-5 7421-93-4 5103-71-9 5103-74-2 8001-35-2 12674-11-2 11104-28-2 11141-16-5 53469-21-9 12672-29-6 11097-69-1 11096-82-5— -alpha-BHC -beta-BHcJ delta-BHC -gamma-BHC (Lindane) -Heptachlor -Aldrin -Heptachlor epoxide, -Endosulfan I ] -Dieldrin -4,4'-DDE -Endrin -Endosulfan II_ -4,4' -DDD -Endosulfan sulfate, -4,4' -DDT Methoxychlor_ Endrin ketone -Endrin Aldehyde, -alpha-Chlordane] -gamma-chlordane] -Toxaphene, —Aroclor-1016_ —Ar OC 1 or-12 21] —Aroclor-1232] —Aroclor-1242] —Aroclor-1248] —Aroclor-1254" Aroclor-1260 Reviewed By FORM I PE«Ete 3 / 9 0 300738 u a ^ I a m e : G S E L I C<alRc ID PESTICIDE ORGANICS ANALYSIS DATA SHEET C o n t r a c t : HLA SAS N o . : EPA SAMPLE NO. D21921 :ode: PACE C a s e N o . : HLA M a t r i x : ( s o i l / w a t e r ) SOIL Sample w t / v o l : 3 0 . 0 (g/mL) fi i M o i s t u r e : 12 d e c a n t e d : (Y/N) li S x t r a c t i o n : ( S e p F / C o n t / S o n c ) SONC SDG No.: 95010 Lab Sample ID: VOB004 Lab File ID: :;oncentrated Extract Volume: Cnjection Volume: 1.00 (uL) ;PC Cleanup: (Y/N) 5000 (uL) pH: 8.8 Date Received: 01/23/95 Date Extracted: 01/25/95 Date Analyzed: 02/03/95 Dilution Factor: 1.00 CAS NO. COMPOUND Sulfur Cleanup: (Y/N) li_ Q CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG 319-84-6 319-85-7 319-86-8 5 8 - 8 9 - 9 76-44-8 309-00-2 1024-57-3 959-98-8 6 0 - 5 7 - 1 72-55-9 72-20-8 33213-65-9 72-54-8 1031-07-8 50-29-3 72-43-5 53494-70-5 7421-93-4 5103-71-9 5103-74-2 8001-35-2 12674-11-2 11104-28-2 11141-16-5 53469-21-9 12672-29-6 11097-69-1 11096-82-5 -alpha-BHC -beta-BHC_] delta-BHC -gamma-BHC (Lindane) -Heptachlor \ -Aldrin -Heptachlor epoxide, -Endosulfan I ] -Dieldrin -4,4'-DDE -Endrin -Endosulfan II -4,4' -DDD -Endosulfan sulfate -4,4' -DDT Methoxychlor_ Endrin ketone -Endrin Aldehyde, -alpha-Chlordane] -gamma-Chlordane, -Toxaphene, -Aroclor-1016_ —Aroclor-1221, —Aroclor-1232] —Aroclor-1242] —Aroclor-1248] —Aroclor-12 54] —Aroclor-12 60* FORM I PEST Reviewed By Date 300739 ID PESTICIDE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. La|^ ame: G S E L I Lab Code: PACE Case No.: HLA Matrix: (soil/water) SOIL Sample wt/vol: 30.0 (g/mL) fi % Moisture: H decanted: (Y/N) li Extraction: (SepF/Cont/Sonc) SONC Contract: HLA SAS No.: D30002^ SDG No.: 95010 Lab Sample ID: VOA002 Lab File ID: Concentrated Extract Volume: Injection Voltime: l.OO (uL) GPC Cleanup: (Y/N) 5000 (uL) pH: 7.9 Date Received: 01/23/95 Date Extracted: 01/25/95 Date Analyzed: 02/03/95 Dilution Factor: 1.00 CAS NO. COMPOUND Sulfur Cleanup: (Y/N) H Q CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG 319-84-6 alpha-BHC 319-85-7 beta-BHC 319-86-8 delta-BHC 58-89-9 qamma-BHC (Lindane) 76-44-8 Heptachlor 309-00-2 Aldrin 1024-57-3 Heptachlor epoxide 959-98-8 Endosulfan I 60-57-1 Dieldrin 72-55-9 4,4'-DDE 72-20-8 Endrin 33213-65-9 Endosulfan II 72-54-8 4, 4'-DDD 1031-07-8 Endosulfan sulfate 50-29-3 4,4'-DDT 72-43-5 Methoxychlor 53494-70-5 Endrin ketone 7421-93-4 Endrin Aldehvde 5103-71-9 alpha-Chlordane 5103-74-2 gamma-Chlordane 8001-35-2 Toxaphene 12674-11-2 Aroclor-1016 11104-28-2 Aroclor-1221 11141-16-5 Aroclor-1232 53469-21-9 Aroclor-1242 12672-29-6 Aroclor-1248 11097-69-1 Aroclor-1254 11096-82-5 Aroclor-1260 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 3.7 3.7 3.7 3.7 3.7 3.7 3.7 19 3.7 3.7 1.9 1.9 190 37 74 37 1 37 37 i 37 37 U u u u u u u u u u u u u u u u u u u u u u u u u u u FORM I PEST Reviewed By Date — ^3/90^ 3 0 0 7 4 0 ID PESTICIDE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. L g ^ ame: G S E L I Lab Code: PACE Case No.: HLA !4atrix: (soil/water) SOIL sample wt/vol: 30.0 (g/mL) fi I Moisture: 12 decanted: (Y/N) li ; Extraction: (SepF/Cont/Sonc) SONg Contract: HLA SAS No.: D31719 SDG No.: 95010 Lab Sample ID: VOA003 Lab File ID: Concentrated Extract Volume: Injection Volume: 1.00 (uL) 3PC Cleanup: (Y/N) Y ?999 (UL) pH: 8.5 Date Received: 01/23/95 Date Extracted: 01/25/95 Date Analyzed: 02/03/95 Dilution Factor: 1.00 CAS NO. COMPOUND Sulfur Cleanup: (Y/N) li__ Q CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG 319-84-6 319-85-7 319-86-8 58-89-9 76-44-8 309-00-2 1024-57-3 959-98-8 60-57-1 72-55-9 72-20-8 33213-65-9 72-54-8 1031-07-8 50-29-3 72-43-5 53494-70-5 7421-93-4—— 5103-71-9 5103-74-2 8001-35-2 12674-11-2 11104-28-2 11141-16-5 53469-21-9 12672-29-6 11097-69-1 11096-82-5— -alpha-BHC -beta-BHC_] delta-BHC -gamma-BHC (Lindane) -Heptachlor [ -Aldrin -Heptachlor epoxide, -Endosulfan I ] -Dieldrin -4,4'-DDE -Endrin -Endosulfan II -4,4'-DDD -Endosulfan sulfate -4,4'-DDT Methoxychlor__ Endrin ketone -Endrin Aldehyde, -alpha-Chlordane] -gamma-Chlordane] -Toxaphene - -Aroc 1 or-1016, —Aroclor-12 21] —Aroclor-1232] —Aroclor-1242] —Aroclor-1248] —Aroclor-1254] Aroclor-12 60' FORM I PEST Reviewed By Date 3/90 300741 ID PESTICIDE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. :.agteT ame: G s E L I Lab Code: PACE Case No.: HLA Matrix: (soil/water) SOIL Seunple wt/vol: 30.0 (g/mL) fi % Moisture: _7 decanted: (Y/N) li Extraction: (SepF/Cont/Sonc) SONC Contract: HLA SAS No.: E10005 SDG No.: 95010 Lab Sample ID: VOC003 Lab File ID: Concentrated Extract Volume: Injection Voltime: 1.00 (uL) 3PC Cleanup: (Y/N) 5000 (uL) pH: 8.1 Date Received: 01/23/95 Date Extracted: 01/25/95 Date Analyzed: 02/03/95 Dilution Factor: 1.00 CAS NO. COMPOUND Sulfur Cleanup: (Y/N) li Q CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG 319-84-6— 319-85-7— 319-86-8— 58-89-9 76-44-8 3 0 9 - 0 0 - 2 — 1 0 2 4 - 5 7 - 3 - 9 5 9 - 9 8 - 8 — 6 0 - 5 7 - 1 72-55-9 72-20-8 33213-65-9 72-54-8 1 0 3 1 - 0 7 - 8 - 50-29-3 72-43-5 53494-70-5 7 4 2 1 - 9 3 - 4 - 5 1 0 3 - 7 1 - 9 - 5 1 0 3 - 7 4 - 2 - 8 0 0 1 - 3 5 - 2 - 12674-11-2 11104-28-2 11141-16-5 53469-21-9 12672-29-6 11097-69-1 11096-82-5 alpha-BHC beta-BHC_] delta-BHC -gamma-BHC (Lindane) - H e p t a c h l o r -Aldrin -Heptachlor epoxide, -Endosulfan I -Dieldrin -4,4'-DDE -Endrin -Endosulfan II -4,4'-DDD -Endosulfan sulfate -4,4' -DDT Methoxychlor_ Endrin ketone -Endrin Aldehyde, -alpha-Chlordane, -gamma-Chlordane, -Toxaphene, Aroclor-1016, Aroclor-1221] Aroclor-1232] Aroclor-1242] A r o c l o r - 1 2 4 8] Aroclor-1254] Aroclor-1260' FORM I PEST Reviewed By Date 300742 ID PESTICIDE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. "W ame: G S E L I Leib Code: PACE Case No.: HIA Matrix: (soil/water) SOIL Sample wt/vol: 30.0 (g/mL) fi % Moisture: 14 decanted: (Y/N) H Extraction: (SepF/Cont/Sonc) SONC Contract: HLA SAS No.: E12022 SDG No.: 95010 Lab Sample ID: VOB002 Lab File ID: Concentrated Extract Volume: Injection Volxime: 1.00 (uL) SPC Cleanup: (Y/N) 5000 (UL) pH: 8.7 Date Received: 01/23/95 Date Extracted: 02/03/95 Date Analyzed: 02/20/95 Dilution Factor: 1.00 CAS NO. COMPOUND Sulfur Cleanup: (Y/N) M Q CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG 319-84-6 alpha-BHC 319-85-7 beta-BHC 319-86-8 delta-BHC 58-89-9 qamma-BHC (Lindane) 76-44-8 H e p t a c h l o r 309-00-2 A l d r i n 1024-57-3 H e p t a c h l o r epoxide 959-98-8 Endosulfan I 60-57-1 D i e l d r i n 72-55-9 4 , 4 ' -DDE 72-20-8 Endrin 33213-65-9 Endosulfan I I 72-54-8 4 , 4 ' -DDD 1031-07-8 Endosulfan s u l f a t e 50-29-3 4 ,4 ' -DDT 72-43-5 Methoxychlor 53494-70-5 E n d r i n k e t o n e 7421-93-4 Endrin Aldehvde 5103-71-9 a l p h a - C h l o r d a n e 5103-74-2 gamma-Chlordane 8001-35-2 Toxaphene 12674-11-2 A r o c l o r - 1 0 1 6 11104-28-2 A r o c l o r - 1 2 2 1 11141-16-5 Aroclor-1232 53469-21-9 Aroclor-1242 12672-29-6 A r o c l o r - 1 2 4 8 11097-69-1 Aroclor-1254 1 1 0 9 6 - 8 2 - 5 A r o c l o r - 1 2 6 0 2 . 0 2 . 0 2 . 0 2 . 0 2 . 0 2 . 0 2 . 0 2 . 0 3 . 8 3 . 8 3 . 8 3 . 8 3 . 8 3 . 8 3 . 8 20 3 . 8 3 . 8 2 . 0 2 . 0 200 38 77' 38 38 38 38 38 U T U T U T U T U T U T uT U T uT U T U T U T U T U T U T U T U T U T U T U T uT uT uT U T U T U T U T U T FORM I PEST Reviewed By Date r 3/90 300743 ID PESTICIDE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. L a J ^ Name: G S E L I Lffl^Code: PACE Case No.: HLA Matrix: (soil/water) WATER Sample wt/vol: 1000 (g/mL) ML % Moisture: decanted: (Y/N) _ Extraction: (SepF/Cont/Sonc) CONT Contract: HLA SAS No.: RBSOOl SDG No.: 95010 Lab Sample ID: VTX004 Lab File ID: Concentrated Extract Volxime: Injection Volxime: 1.00 (uL) SPC Cleanup: (Y/N) li 2000 (uL) pH: ?.$ Date Received: 02/01/95 Date Extracted: 02/01/95 Date Analyzed: 02/03/95 Dilution Factor: 1.00 • CAS NO. COMPOUND Sulfur Cleanup: (Y/N) li Q CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L 319-84-6 alpha-BHC 319-85-7 beta-BHC 319-86-8 delta-BHC 58-89-9 gamma-BHC (Lindane) 76-44-8 Heptachlor 3 09-00-2 Aldrin 1024-57-3 Heptachlor epoxide 959-98-8 Endosulfan I 60-57-1 Dieldrin 72-55-9 4, 4'-DDE 72-20-8 Endrin 33213-65-9 Endosulfan II 72-54-8 4 , 4 ' -DDD 1031-07-8 Endosulfan sulfate 50-29-3 4,4 • -DDT 72-43-5 Methoxychlor 53494-70-5 Endrin ketone 7421-93-4 Endrin Aldehyde 5103-71-9 alpha-Chlordane 5103-74-2 gamma-Chlordane 8001-35-2 Toxaphene 12674-11-2 Aroclor-1016 11104-28-2 Aroclor-1221 11141-16-5 Aroclor-1232 53469-21-9 Aroclor-1242 12672-29-6 Aroclor-1248 11097-69-1 Aroclor-1254 11096-82-5 Aroclor-1260 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.020 0.020 0.020 0.020 0.020 0.020 0.020 0.10 0.020 0.020 0.010 0.010 1.0 0.20 0.40 0.20 0.20 0.20 0.20 0.20 U U u U U u u u u u u u u u u u u u u u u u u u u u u u FORM I PEST Reviewed By Date ^ 7 ^ 300744 ID PESTICIDE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. ame: G S E L I Lab Code: PACE Case No.: HLA Matrix: (soil/water) WATER Sample wt/vol: 1000 (g/mL) ML % Moisture: decanted: (Y/N) _ Extraction: (SepF/Cont/Sonc) CONT Contract: HLA SAS No.: S00118 SDG No.: 95010 Lab Sample ID: VOCOOl Lab File ID: Concentrated Extract Volxime: I n j e c t i o n Volxime: 1.00 (uL) GPC Cleanup: (Y/N) li 2000 (uL) pH: 6.9 Date Received: 01/23/95 Date Extracted: 01/24/95 Date Analyzed: Ql/27/95 Dilution Factor: 1.00 CAS NO. COMPOUND Sulfur Cleanup: (Y/N) N Q CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L 319-84-6 alpha-BHC 319-85-7 beta-BHC 319-86-8 delta-BHC 58-89-9 qamma-BHC (Lindane) 76-44-8 Heptachlor 309-00-2 Aldrin 1024-57-3 Heptachlor epoxide 959-98-8 Endosulfan I 60-57-1 Dieldrin 72-55-9 4,4'-DDE 72-20-8 Endrin 33213-65-9 Endosulfan II 72-54-8 4,4'-DDD 1031-07-8 Endosulfan sulfate 50-29-3 4 .4 ' -DDT 72-4 3-5 Methoxychlor 53494-70-5 Endrin ketone 7421-93-4 Endrin Aldehvde 5103-71-9 alpha-Chlordane 5103-74-2 gamma-Chlordane 8001-35-2 Toxaphene 12674-11-2 Aroclor-1016 11104-28-2 Aroclor-1221 11141-16-5 Aroclor-1232 53469-21-9 Aroclor-1242 12672-29-6 Aroclor-1248 11097-69-1 Aroclor-1254 11096-82-5 Aroclor-1260 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.020 0.020 0.020 0.020 0.020 0.020 0.020 0.10 0.020 0.020 0.010 0.010 1.0 0.20 0.40 0.20 0.20 0.20 0.20 0.20 U U U U U U U U U U U U U U U u u u u u u u u u u u u u FORM I PEST Reviewed By Date 300745 ID PESTICIDE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. La|^ LaR ame: G S E L I La^Xode: PACE Case No.: HLA Matrix: (soil/water) WATER sample wt/vol: 1000 (g/mL) ML % Moisture: decanted: (Y/N) _ Extraction: (SepF/Cont/Sonc) CONT Contract: HLA SAS No.: S00119 r SDG No.: 95010 Lab Sample ID: VOBOOl Lab File ID: Concentrated Extract Volxime: Injection Volxime: 1.00 (uL) GPC Cleanup: (Y/N) li 2000 (uL) pH: 6.8 Date Received: 01/23/95 Date Extracted: 01/24/95 Date Analyzed: 01/27/95 Dilution Factor: 1.00 CAS NO. COMPOUND sulfur Cleanup: (Y/N) li Q CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L 319-84-6 alpha-BHC 319-85-7 beta-BHC 319-86-8 delta-BHC 58-89-9 gamma-BHC (Lindane) 76-44-8 Heptachlor 309-00-2 Aldrin 1024-57-3 Heptachlor epoxide 959-98-8 Endosulfan I 60-57-1 Dieldrin 72-55-9 4,4'-DDE 72-20-8 Endrin 33213-65-9 Endosulfan II 72-54-8 • 4,4'-DDD 1031-07-8 Endosulfan sulfate 50-29-3 4,4'-DDT 72-43-5 Methoxychlor 53494-70-5 Endrin ketone 7421-93-4 Endrin Aldehvde 5103-71-9 alpha-Chlordane 5103-74-2 gamma-Chlordane 8001-35-2 Toxaphene 12674-11-2 Aroclor-1016 11104-28-2 Aroclor-1221 11141-16-5 Aroclor-1232 53469-21-9 Aroclor-1242 12672-29-6 Aroclor-1248 11097-69-1 Aroclor-1254 11096-82-5 Aroclor-1260 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.020 0.020 0.020 0.020 0.020 0.020 0.020 0.10 0.020 0.020 0.010 0.010 1.0 0.20 0.40 0.20 0.20 0.20 0.20 0.20 U u u U U U U U U u u u u u u u u u u u u u u u u u u u V FORM I PEST Reviewed By Date — L. 300746 ID PESTICIDE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. ^ Name: G S E L I Lab Code: PACE Case No.: HLA Matrix: (soil/water) WATER Sample wt/vol: 1000 (g/mL) ML % Moisture: decanted: (Y/N) _ Extraction: (SepF/Cont/Sonc) CONT Contract: HLA SAS No.: S00120 SDG No.: 95010 Lab Sample ID: VOAOOl Lab File ID: Concentrated Extract Volxime: Injection Volxme: 1.00 (uL) GPC Cleanup: (Y/N) N 2000 (uL) pH: 7.1 Date Received: 01/23/95 Date Extracted: 01/24/95 Date Analyzed: 02/03/95 Dilution Factor: 1.00 Sulfur Cleanup: (Y/N) N _ CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L 319-84-6 319-85-7 319-86-8 58-89-9 76-44-8 309-00-2 1024-57-3 959-98-8 60-57-1 72-55-9 72-20-8 33213-65-9 72-54-8 1031-07-8 50-29-3 72-43-5 53494-70-5 7421-93-4 5103-71-9 5103-74-2 8001-35-2 12674-11-2 11104-28-2 11141-16-5 53469-21-9 12672-29-6 11097-69-1 11096-82-5 -alpha-BHC -beta-BHCj; delta-BHC -gamma-BHC (Lindane) -Heptachlor -Aldrin -Heptachlor epoxide, -Endosulfan I -Dieldrin -4,4'-DDE -Endrin -Endosulfan II -4,4' -DDD ] •Endosulfan sulfate •4,4' -DDT ] Methoxychlor Endrin ketone -Endrin Aldehyde, -alpha-Chlordane, -gamma-Chlordane, -Toxaphene -Aroclor-1016_ -Aroclor-1221] -Aroclor-1232] -Aroclor-1242] -Aroclor-1248] -Aroclor-1254] -Aroclor-12 60' 0 . 0 1 0 0 . 0 1 0 0 . 0 1 0 0 . 0 1 0 0 . 0 1 0 0 . 0 1 0 0 . 0 1 0 0 . 0 1 0 0 . 0 2 0 0 . 0 2 0 0 . 0 2 0 0 . 0 2 0 0 . 0 2 0 0 . 0 2 0 0 . 0 2 0 0 . 1 0 0 . 0 2 0 0 . 0 2 4 0 . 0 1 0 0 . 0 1 0 1.0 0 . 2 0 0 . 4 0 0 . 2 0 0 . 2 0 0 . 2 0 0 . 2 0 0 . 2 0 U U U U U u u u u u u u u u u u u u u u u u u u u u u Reviewed By FORM I PEST Date ^ IDATED • - r •• 111- • ^ ' ^ ' ^ ^ - ^ ' ^ y :^l^ll±^L_y/9o 300747 ID PESTICIDE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. # Name: G S E L I Lab Code: PACE Case No.: HLA Matrix: (soil/water) WATER Sample wt/vol: 600.0 (g/mL) ML % Moisture: decanted: (Y/N) _ Extraction: (SepF/Cont/Sonc) CONT Contract: HLA SAS No.: SO0120RE SDG No.: 95010 Lab Sample ID: VOAOOIRE Lab File ID: Concentrated Extract Volxime: Injection Volxime: l.OO (uL) GPC Cleanup: (Y/N) N 2000 (uL) pH: 7.1 Date Received: 01/23/95 Date Extracted: 02/08/95 Date Analyzed: 02/11/95 Dilution Factor: 1.00 CAS NO. COMPOUND Sulfur Cleanup: (Y/N) N, Q CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L 319-84-6 319-85-7 319-86-8 58-89-9 76-44-8 309-00-2 1024-57-3 959-98-8 60-57-1 72-55-9 72-20-8 33213-65-9 72-54-8 1031-07-8 50-29-3 72-43-5 53494-70-5 7421-93-4 5103-71-9 5103-74-2 8001-35-2 12674-11-2 11104-28-2 11141-16-5 53469-21-9 12672-29-6 11097-69-1 11096-82-5 -alpha-BHC -beta-BHC_] delta-BHC -gamma-BHC (Lindane), -Heptachlor -Aldrin -Heptachlor epoxide, •Endosulfan I •Dieldrin -4,4' -DDE -Endrin •Endosulfan II •4,4' -DDD -Endosulfan sulfate -4,4' -DDT _" Methoxychlor Endrin ketone —Endrin Aldehyde, —alpha-Chlordane, —gamma-Chlordane, —Toxaphene —Aroclor-1016, —Aroclor-1221, —Aroclor-1232_ —Aroclor-1242_ —Aroclor-1248, —Aroclor-12 54, —Aroclor-1260 0 . 0 1 7 0 . 0 1 7 0 . 0 1 7 0 . 0 1 7 0 . 0 2 5 0 . 0 1 7 0 . 0 1 7 0 . 0 1 7 0 . 0 3 3 0 . 0 3 3 0 . 0 3 3 0 . 0 3 3 0 . 0 3 3 0 . 0 3 3 0 . 0 3 3 0 . 1 7 0 . 0 3 3 0 . 0 3 3 0 . 0 1 7 0 . 0 1 7 1.7 0 . 3 3 0 . 6 7 0 . 3 3 0 . 3 3 0 . 3 3 0 . 3 3 0 . 3 3 U J U T U T U T yr U T uT uT U T UT U T UT U T U T UT UT UT uT UJ UT UT uT UT uT uT uT uT uT V FORM I PEST Reviewed By Date V 3/90 300748 ID PESTICIDE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. Name: G S E L I Xode: PACE Case No.: HLA Matrix: (soil/water) WATER Sample wt/vol: 1000 (g/mL) ML % Moisture: decanted: (Y/N) _ Extraction: (SepF/Cont/Sonc) CONT Contract: HLA SAS No.: S00125 SDG No.: 95010 Lab Sample ID: VSIOOl Lab File ID: Concentrated Extract Volxime: Injection Volxime: 1.00 (uL) GPC Cleanup: (Y/N) li 2000 (uL) pH: 6.6 Date Received: 01/27/95 Date Extracted: 01/30/95 Date Analyzed: 02/03/95 Dilution Factor: i.oo CAS NO. COMPOUND Sulfur Cleanup: (Y/N) li Q CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L 319-84-6 319-85-7 319-86-8 58-89-9 76-44-8 309-00-2 1024-57-3 959-98-8 6 0 - 5 7 - 1 72-55-9 7 2 - 2 0 - 8 33213-65-9 7 2 - 5 4 - 8 1031-07-8 50-29-3 7 2 - 4 3 - 5 53494-70-5 7421-93-4 5103-71-9 5103-74-2 8001-35-2 12674-11-2 11104-28-2 11141-16-5 53469-21-9 12672-29-6 11097-69-1 11096-82-5 -alpha-BHC -beta-BHCj; delta-BHC -gamma-BHC (Lindane) -Heptachlor -Aldrin -Heptachlor epoxide, •Endosulfan I ] - D i e l d r i n - 4 , 4 ' -DDE -Endrin -Endosulfan I I - 4 , 4 ' -DDD ] -Endosulfan s u l f a t e - 4 , 4 ' -DDT ] Methoxychlor__ Endrin k e t o n e —Endrin Aldehyde_ —alpha-Chlordane, —gamma-Chlordane, —Toxaphene, —Aroclor-1016, —Aroclor-12 21] —Aroclor-1232] —Aroclor-1242] —Aroclor-1248] —Aroclor-1254] —Aroclor-12 60' .010 .010 .010 .010 .010 .010 .010 .010 .020 .020 .020 .020 .020 .020 .020 0.10 .020 .020 .010 .010 1.0 0.20 0.40 0.20 0.20 0.20 0.20 0.20 u u u u u u u u u u u u u u u u u u u u u u u u u u u u FORM I PEST VALIDATED Reviewed By ^ - - f ^ t y X 2 • U/]; r t - b O Date / Z ^ / ^ r 3/90 300749 HLA DATA QUALTTY ASSURANCE REVIEW SUMMARY Organochlorine Pesticides and Polychlorinated Biphenyls Analysis Case Number: Site: Contractor Lab: Validator: QC Reviewer: Sample Matrix: 95020 Island Chemical Company Pace Environmental Laboratories, Kirsten Meier T^TAyy^y^^ ?^^<u^ water and soil Project Number: St. Rosa, LA Validation Date: Review Date: 29872 10.2 28 March 1995 V - ( S - f S - Analytical Method: Low Level Pest/PCB Sample Designations: RBSO/012495 * (SO0012) SBF3/12-14/012495 (F31214) SBCl/0-1/012795 (ClOOOl) SBD4/0-1/012795 (D40001) SBBI/0-1/013195 (BlOOOl) SBF2/12-15/012495 (F21215) SBF3/18-20/012495 (F31820) SBCl/16-18/012795 (C11618) SBD4/14-16/012795 (D41416) SBBl/6-8/013195 (B16008) SBF2/18-20/012495 (F21820) SBBl/24-26/013195 (B12426) SBCl/18-20/012795 (C11820) SBD4/20-22/012795 (D42022) SBB101/0-1/013I95 (BlOlOl) SBF3/0-1/012495 (F30001) RBSO/012795 * (SO0127) SBCl/20-22/012795 (C12022) RBSO/013195 * (BSO013) * = aqueous sample ( ) = Lab sample ID Data for the above samples are: [ ] Acceptable for use [x] Acceptable for use as qualified [ ] Unacceptable for use Is action required by the Project Manager? Yes No[x] Comments: The investigative samples were analyzed using the Low Concentration SOW for Pesticides/PCB and the analytical data were reviewed in accordance with the Functional Guidelines, February 1994. The investigative sample RBSO/012395 was requested for analysis on the Chain of Custody, the lab propped the sample as VTE-001, but then the lab was requested not to analyze this sample. ocp_elec.ll 12291994 1530 Fom OCP l.l 300750 Cue Number: 9)020 Project hfumber: 29S72 10.2 Site ID: Isbnd CbcmioU Company DATA COMPLETENESS CHECKLIST [x] Included, no problems [*] Included, problems [O] Not included [NA] Not applicable Quality Control Summary X Case Narrative * Surrogate Recovery Summary * MS/MSD Summary X Reagent Blank Summary Sample Data * Chain of Custody Forms * Holding Times X Organic Analysis Data Sheets X Quantitation Reports X GC/EC Chromatograms X Pesticide/PCB Identification (for positive detections) Instrument Calibration and Performance Data X Initial Calibration Retention Time Summary * Initial Calibration Response Factor Summary X Performance Evaluation Mix Summary X Continuing Calibration Verification Summary X Analytical Run Sequence Summary X GPC Calibration and Florisil Cartridge Check Summary X Pesticide/PCB Standards Quantitation Reports X Pesticide/PCB Standards GC/EC Chromatograms Reagent and Instrument Blank Data X Organic Analysis Data Sheets X Quantitation Reports X GC/EC Chromatograms X Pesticide/PCB Identification (for positive detections) ocp_clcc. 11 12N1994 1530 2 Fonn OCP 1.1 300751 Cue Number: 95020 Project Number. 29872 10.2 Site ID: bland CheniicBl Coinpanjr Matrix Spike/LCS Data * Organic Analysis Data Sheets X Quantitation Reports X GC/EC Chromatograms Comments: None ocp_el6C.ll 12291994 1530 Fonn OCP 1.1 300752 Cue Number: 95020 Project Number: 29872 10.2 Site ID: hbnd CfaemioU Company SPECIHC COMMENTS REGARDING ANALYSES Chain Of Custody Were samples properly preserved and received in good condition? Yes[x] No Comments: The Chain of Custodies submitted are not signed and dated by the lab upon sample receipt. No qualification of data. Holding Times Were sample extractions performed within holding times? Yes No[x] Were sample analyses performed within holding times? Yes[x] No Comments: Due to low surrogate recoveries the investigative samples RBSO/012495 and RBSO/012795 were re- extracted on 2-20-94, 17 and 20 days past their hold time. Therefore, the results for these samples were qualified as estimated (J). ocp_elec.ll I229I994 1530 4 Form OCP 1.1 300753 Cue Number: 95020 Project Number: 29872 10.2 Sile ID: Island Cbemical Company Initial Calibration Did the laboratory meet the guidelines regarding the minimum number of calibration standards for an acceptable initial calibration? Yes[x] No Were the calibration standards analyzed at the correct concentrations? Yes[x] No Did the calibration curves meet the linearity criteria for maximum percent relative standard deviation (%RSD)? Yes No[x] Were retention time windows provided and correctly calculated? Yes[x] No Were peak resolutions acceptable? Yes[x] No Comments: The compound alpha-BHC in the initial calibration on 2-10-94 has a 20.8% RSD, exceeding the criteria of 209S. Therefore, the result for alpha-BHC in the investigative samples SBF2/12-15/012495 (F21215), SBF2/18-20/012495 (F21820), SBF3/0-I/012495 (F30001), SBCl/0-1/012795 (ClOOOl), SBCl/16-18/012795 (C11618), SBCl/18-20/012795 (CI1820), SBCl/20-22/012795 (C12022), SBD4/0- 1/012795 (D40001), SBD4/14-16/012795 (D41416), SBD4/20-22/012795 (D42022) aud RBSO/013195 (BSO013) were qualified as estimated (J). Individual Mix Standards (Continuing Calibration) Did the individual mix standards meet the linearity criteria for maximum percent difference (%D)? Yes[x] No Did the individual mix standards meet the retention time criteria? Yes[x] No Comments: None ocp_elcc.ll 12291994 1530 5 Form.OCP-1.1.. 300754 Case Nunber: 95020 Project Number: 29872 10.2 Sile ID: bland Chemiod Cotnpai^ Performance Evaluation Mix Standards (Continuing Calibration) Did the performance evaluation mix standards meet the linearity criteria for maximum percent difference (%D)? Yes[x] No Did the performance evaluation mix standards meet the retention time criteria? Yes[x] No Comments: None Analytical Sequence Were standard and sample analyses performed following the correct analytical sequence? Yes[x] No Comments: None 300755 ocp_elec.ll 12291994 1530 Form OCP 1.1 CaM Number: 95020 Project Number: 29872 10.2 Site DD: bbmd Chemical CompaiQr Surrogate Recoveries Were the surrogate spike recoveries within acceptance limits? Yes No[x] If the spike recoveries were unacceptable, were the samples reanalyzed? Yes No[x] Comments: The following surrogate recoveries outside the required 60-150% were reported: Sample ID RBSO/012495 * (SO0012) RBSO/012795 * (SO0127) SBBl/6-8/013195 (B16008) SBCl/0-1/012795 (ClOOOl) SBF2/12-15/012495 (F21215) SBF3/0-1/012495 (F30001) SBF3/0-1/012495MS (F30001MS) SBF3/0-1/012495MSD (KJOOOIMSD) TCXl 15% 56% TCX2 50% 48% 14% 56% 50% DCBl 52% 49% 16% 2850% 3400% 3550% DCB2 51% 46% 19% 156% Therefore, the results in the above listed investigative samples were qualified as estimated (J). The prep bench sheet lists the surrogate standard ID, but not the concentration. When assuming that the lab used 20 ug/I surrogate as listed in the SOW Low Concentration Pest/PCB, then the surrogate recoveries calculate to the values the lab reported. No qualification of data. 300756 ocp_elec.ll 12291994 1530 Form OCP 1.1 Caae Number: 95020 Project Nunber. 29872 10.2 Site ID: bbnd Cbenucal Oxnpary Matrix Spikes Were matrix spike analyses performed at the correct frequency and on a sample matrix representative of the samples in this sample deliveiy group (SDG)? Yes[x] No Were the matrix spike recoveries and relative percent differences (RPDs) within acceptance criteria? Yes No[x] Comments: The Low Level Method does not require matrix spike analyses, and the regular method recommends not to qualify on matrix spike recoveries alone. However, the matrix spikes performed were requested by the client and therefore it seems important to make an evaluation based on matrix spike recoveries. The Endrin recovery was -13% in the MS and MSD samples. The recovery for 4,4'-DDT was 152% in the MSD sample. It appears, that the sample matrix is interfering with the detection of Endrin, therefore^the non-detections of Endrin in the investigative samples were rejected (R), and reported detections are qualified as estimated (J). No detections were reported for 4,4'-DDT, therefore an estimated (J) qualification of 4,4'-DDT detections is not necessary. Blank Analyses Were the appropriate number of blank analyses performed? Yes[x] No Were instrument blanks analyzed at the correct frequency? Yes[x] No Were analytes reported in the blanks? Yes No[x] If analytes were reported in the blanks, were the same analytes also reported in the associated investigative samples? Yes No[x] Did the sample results require qualification due to the presence of analytes in the associated blank samples? Yes No[x] Comments: None 300757 . y ocp_elec. 11 12291994 1530 8 Fonn OCP 1.1 Case Number: 95020 Project Number: 29872 10.2 Site ID: bland CbemiaU Cotnpany Instrument Performance Were the percent breakdowns for 4,4'-DDT and endrin correctly reported? Yes[x] No Were the percent breakdowns for 4,4'-DDT and endrin within acceptance limits? Yes[x] No Comments: None GPC and Florisil Cartridge Check Was GPC cleanup performed on the sample extracts? Yes[x] No Was the GPC column check acceptable? Yes[x] No NA Was a Florisil cartridge check performed? Yes[x] No Was the Florisil cartridge check acceptable? Yes[x] No NA Comments: None 300758 ocp_ciec.!! 12291994 1530 9 Form OCP I.I Case Number 95020 Project Number: 29872 10.2 Site ID: bland Cbemioal Company Laboratory Control Samples Were LCS analyses performed? Yes[x] No Were the LCS recoveries within acceptable limits? Yes No[x] NA Comments: For the blank spike performed on 2-16-94, the recovery for Heptachlor Epoxide was 73%, below the required 74%. Therefore, the results for Heptachlor Epoxide in the investigative samples were qualified as estimated (J). Sample Results Were target analytes repiorted in the investigative samples? Yes[x] No Were chromatograms provided for all target analytes reported in the investigative samples? Yes[x] No Were chromatograms of acceptable quality and were analytes correctly identified? Yes[x] No Were the quantitated results for target analytes calculated using the appropriate standard and were the retention times (RTs) acceptable? Yes[x] No Comments: The analytical instrument is set up in such way, that the raw data concentration haJs been adjusted for extract volume, GPC factor, soil sample amount and percent moisture and lists the concentration in ug/kg (ppb-dry). A more standard approach is to have the raw data in ug/l, then concentrations can be more easily compared to each other. No qualification of data. 300759 ocp_elec. 11 12291994 1530 1 0 Fonn OCP 1.1 • • Caae Number: 95020 Project Number: 29872 10.2 Site ID: bland Chemical Cotnpany Calculation Check Initial Calibration Retention Time Window: were provided by lab, no calculation necessary %RSD: 2-10-95, DB-608, alpha BHC . 1466015 X 100 = 20.765% 7060000 Continuing Calibration, 2-2-95, 12:19, DB-1701, alpha BHC %D: 0.009-0.010 x 100 = 11.11% 0.009 Surrogate Recovery, ClOOOl (VTF002), TCX 190902 X 5000 x 2 = 10.402 ug/kg 7460000 x 30 X 0.82 A 100% recovery of the surrogate would result in 0.2 ng/ml X 0.2 ml X 5000 ul x 2 = 16.26 ug/kg 30 g X 1 ul X 0.82 therefore, 10.402 ug/kg = 63.97% surrogate recovery Matrix Spike Recovery, F30001MSD, 4,4'-DDT 58.4 X 100 = 152.48% 38.3 RPD: for 126% and 152% is 18.7%RPD 300760 ocp_clcc. I I 12291994 1530 1 1 Form OCP l.l Case Number: 95020 Project Number: 29872 10.2 Site ID: bland Cbemical Cofnpoi^ Sample Results CRQL: Positive Result: F30001, alpha Chlordane 65946 X 5000 x 2 = 3.89 6480000 X 1 X 30x 0.87 ocp_elcc. 11 12291994 1530 1 2 Form OCP 1.1 300761 Case Number: 95020 Project Number: 29872 10.2 Site ID: bbuvl Chemical Company HOLDING TIME QUALIHCATIGN SUMMARY FORM OJ o o to Sample Identification RBSO/012495 RE RBSO/012795 RE Date Sampled 1/24/94 1/27/94 Date Prepared 2/20/94 2/20/94 Date Analyzed 2/21/94 2/21/94 Prep. Holding Time 27 days 24 days Analysis Holding Time 1 1 Qualifier J/UJ J/UJ Comments: None ocp_eleo.ll 12291994 1530 13 Form OCP 1.1 Case Number: 95020 Project Number: 29872 10.2 Site ID: btand Cbemioal Company INITIAL CALIBRATION QUALIFICATION SUMMARY FORM Date/Time 2/10/94 Instrument Analyte alpha BHC RF RSD 20.8 % Samples Affected SBF2/12-15/012495 (F21215), SBF2/18-20/012495 (F21820), SBF3/0- 1/012495 (F30001), SBCl/0-1/012795 (ClOOOl), SBCl/16-18/012795 (C11618), SBCl/18-20/012795 (C11820), SBCl/20-22/012795 (C12022), SBD4/0-1/012795 (D40001), SBD4/14-16/012795 (D41416), SBD4/20- 22/012795 (D42022), RBSO/013195 (BSO013) Qualifier J/UJ w o o Comments: None ocp_elco.II 122919>)4 1530 14 Fonn OCP l.l Case Number: 95020 Project Number: 29872 10.2 Site ID: bland Chemical Company CONTINUING CALIBRATION QUALIHCATION SUMMARY FORM Date/Time Instrument Analyte >. %D Samples Affected Qualifier o 2 Comments: a\ None it:> ocp_elcc. 11 12291994 1530 15 FomlOCP 1.1 Case Number: 95020 Project Number: 29872 10.2 Site ID: bland Chemical Company BLANK SUMMARY FORM o o CJl Blank ID Analyte • Blank Result Units 5 x Result Associated Samples Qualifier Comments: None ocp_clcc.ll 12291994 1530 16 Form OCP l.l Case Number: 95020 Project Number. 29872 10.2 Site ID: bbnd Cbemical Cocnpany Summary and Conclusions The analytical results for the Pesticide/PCBs low level analyses are accetable for use as qualified. The results for the reanalyses of the investigative samples RBSO/012495 and RBSO/012795 were qualified as estimated (J) since the prep for these samples exceeded the hold time. The results for alpha-BHC in the investigative samples SBF2/12-15/012495 (F21215), SBF2/18- 20/012495 (F21820), SBF3/0-1/012495 (F30001), SBCl/0-1/012795 (ClOOOl), SBCl/16-18/012795 (C11618), SBCl/18-20/012795 (C11820), SBCl/20-22/012795 (C12022), SBD4/0-1/012795 (D40001), SBD4/14-16/012795 (D41416), SBD4/20-22/012795 (D42022), and RBSO/013195 (BSO013) were qulifies as estimated (J) since the %RSD was exceede in the initial calibration. The results for the investigative samples RBSO/012495 (SO0012), RBSO/012795 (SO0I27), SBBl/6- 8/013195 (B16008), SBCl/0-1/012795 (C10001),SBF2/12-15/012495(F21215), and SBF3/0-1/012495 (F30001) were qualified as estimated due to surrogate recoveries exceeding the QC criteria. Due to the negative recovery of Endrin in the matrix spike and matrix spike duplicate, the detection of Endrin in the investigative samples were qualified as estimated (J), while non-detections were rejected (R). The recovery of Heptachlor epoxide in the LCS sample was below the QC criteria. Therefore, the results for Heptachlor epoxide in the investigative samples were qualified as estimated (J). Validator's Signature: / < i ^ V6w H y y C A ^ Validator's Initials: U M Validation Date: 3 - 2 ^ - i S QC Reviewer's Signature: ^TPt^yLe/ ^ y y C A y / x . ^ QC Reviewer's Initials: M.PP Review Date: V - C - I T ocp_clcc. 11 12291994 1530 1 7 Form OCP 1.1 300766 ID PESTICIDE ORGAMICS AMALYSIS DATA SHEET EPA SAMPLE MO. Lab Name: (? S E L I Code: PACE Case No.: HIA, Matrix: (soil/water) SOIL Sample wt/vol: 30.0 (g/mL) fi % Moisture: 12 decanted: (Y/N) H Extraction: (SepF/Cont/Sonc) SONC Contract: HLA SAS No.: BlOOOl SDG No.: 95020 Lab Sample ID: W G 0 0 2 Lab File ID: Concentrated Extract Voliime: Injection Volume: 1.00 (uL) GPC Cleanup: (Y/N) 5000 (UL) pH: 8.6 Date Received: 02/03/95 Date Extracted: 02/06/95 Date Analyzed: 03/04/95 Dilution Factor: 1.00 CAS NO. COMPOUND Sulfur Cleanup: (Y/N) H Q CONCENTRATION UNITS: (ug/L or ug/Kg) yg/Kg • 3 1 9 - 8 4 - 6 — 3 1 9 - 8 5 - 7 — 3 1 9 - 8 6 - 8 — 58-89-9 76-44-8 3 0 9 - 0 0 - 2 — 1 0 2 4 - 5 7 - 3 - 9 5 9 - 9 8 - 8 — 6 0 - 5 7 - 1 72-55-9 72-20-8 33213-65-9 72-54-8 1 0 3 1 - 0 7 - 8 - 50-29-3 72-43-5 53494-70-5 7 4 2 1 - 9 3 - 4 - 5 1 0 3 - 7 1 - 9 - 5 1 0 3 - 7 4 - 2 - 8 0 0 1 - 3 5 - 2 - 12674-11-2 11104-28-2 11141-16-5 53469-21-9 12672-29-6 11097-69-1 11096-82-5 alpha-BHC beta-BHC_^ delta-BHC -gamma-BHC (Lindane) >Heptachlor -Aldrin -Heptachlor epoxide, -Endosulfan I ~_ -Dieldrin -4,4* -DDE -Endrin -Endosulfan II •4,4' -DDD -Endosulfan sulfate -4,4' -DDT —Methoxychlbr__ -Endrin ketone —Endrin Aldehyde, —alpha-Chlordane_ —g2unma-Chlordane_ —Toxaphene —Aroclor-1016_ —Aroclor-12 21" —Aroclor-12 3 2^ —Aroclor-1242_ —Aroclor-1248^ —Aroclor-1254_ —Aroclor-1260 _ 3 0 0 7 6 7 VALIDATED; FORM I PEST Frv. Date d By yu^i^^h^ej^Q 2-2e-fs ID PESTICIDE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. 9D Neune: G S E L I Code: £A2E Case No.: HLA Matrix: (soil/water) SOIL Sample wt/vol: 30.o (g/mL) fi % Moisture: Ifi decanted: (Y/N) H Extraction: (SepF/Cont/Sonc) SONC Contract: HLA SAS No.: BlOlOl SDG No.: 95020 Lab Sample ID: W G 0 0 4 Lab Pile ID: Concentrated Extract Volume: Injection Volume: 1.00 (uL) GPC Cleanup: (Y/N) X 5000 (uL) pH: 9.^ Date Received: 02/03/95 Date Extracted: 02/p6/95 Date Analyzed: 03/04/95 Dilution Factor: 1.00 CAS NO. COMPOUND Sulfur Cleanup: (Y/N) H Q CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG 319-84-6 319-85-7 319-86-8 5 8 - 8 9 - 9 7 6 - 4 4 - 8 309-00-2 1024-57-3 959-98-8 6 0 - 5 7 - 1 72-55-9 72-20-8 33213-65-9 72-54-8 1031-07-8 50-29-3 7 2 - 4 3 - 5 53494-70-5 7421-93-4 5103-71-9 5103-74-2 •' 8001-35-2 12674-11-2 11104-28-2 11141-16-5 53469-21-9 12672-29-6 11097-69-1 11096-82-5 -alpha-BHC -beta-BHC_2 delta-BHC -gamma-BHC (Lindane) -Heptachlor -Aldrin -Heptachlor epoxide, -Endosulfan I ~_ -Dieldrin -4,4*-DDE -Endrin -Endosulfan II -4,4 • -DDD -Endosulfan sulfate -4,4'-DDT. — M e t h o x y c h l o r Endrin ketone —Endrin Aldehyde, —alpha-Chlordane. —geunma-Chlordane' —Toxaphene. —Aroclor-1016_ —Aroclor-12 21] —Aroclor-1232] —Aroclor-1242] —Aroclor-1248] —Aroclor-1254] Aroclor-12 60' 300768 VALIDATED FORM I PEST Re- Date J By 1^4^ S-Z^-fS ID PESTICIDE ORGANICS AMALYSIS DATA SHEET EPA SAMPLE NO. ^ b Name: G S E L I Contract: HLA Case No.: HLA SAS No.: B12426 Code: PACE Matrix: (soil/water) SOIL Sample wt/vol: 30.0 (g/mL) fi % Moisture: 12 decanted: (Y/N) fi Extraction: (SepF/Cont/Sonc) SONC SDG No.: 95020 Lab Sample ID: WG005 Lab File ID: Concentrated Extract Volume: Injection Volume: 1.00 (uL) GPC Cleanup: (Y/N) X 5000 (uL) pH: g.g Date Received: 02/03/95 Date Extracted: 02/06/95 Date Analyzed: 03/04/95 Dilution Factor: 1.00 CAS NO. COMPOUND Sulfur Cleanup: (Y/N) ^ Q CONCENTRATION UNITS: (ug/L or ug/Kg) Vg/Kg 319-84-6 319-85-7 319-86-8 58-89-9 76-44-8 309-00-2 1024-57-3 959-98-8 60-57-1 72-55-9 72-20-8 33213-65-9 72-54-8 1031-07-8 50-29-3 72-43-5 53494-70-5 7421-93-4 5103-71-9 5103-74-2 8001-35-2 12674-11-2 11104-28-2 11141-16-5 53469-21-9 12672-29-6 11097-69-1 11096-82-5— •alpha-BHC -beta-BHC_2 delta-BHC -gamma-BHC (Lindane) -Heptachlor [ -Aldrin -Heptachlor epoxide, -Endosulfan I ] -Dieldrin -4,4* -DDE •Endrin -Endosulfan II -4,4 • -DDD -Endosulfan sulfate •4,4' -DDT ] —Methoxychlor_ —Endrin ketone —Endrin Aldehyde, —alpha-Chlordane] —gamma-Chlordane] -Toxaphene, —Aroclor-1016_ —Aroclor-1221] —Aroclor-1232] —Aroclor-1242] —Aroclor-1248] —Aroclor-1254' Aroclor-12 60 2 . 1 2 . 1 2 . 1 2 . 1 2 . 1 2 . 1 2 . 1 2 . 1 4 . 1 4 . 1 4 . 1 4 . 1 4 . 1 4 . 1 4 . 1 2 1 4 . 1 4 . 1 2 . 1 2 . 1 10 4 1 &2 4 1 4 1 4 1 4 1 4 1 U U U U U U U J U U U JITK u u u u u u u u u u u u u u u u u 300769 VALIDATED FORM I PEST Revic.vcd By 77^hy\ KiA.e7^/Qn Date 3-2^-^.5 ID PESTICIDE ORGAMICS ANALYSIS DATA SHEET EPA SAMPLE NO. # Name: g S E L I Contract: HLA Case No.: HLA SAS No.: B16008 Lab Code: PACE Matrix: (soil/water) S O I L Sample wt/vol: 30.0 (g/mL) fi % Moisture: 2fi decanted: (Y/N) H Extraction: (SepF/Cont/Sonc) SONC SDG No.: 95020 Lab Sample ID: WG003 Lab File ID: Concentrated Extract Volume: Injection Volume: 1.00 (uL) GPC Cleanup: (Y/N) ^ 5Q00 (UL) pH: 9,2 Date Received: 02/03/95 Date Extracted: 02/06/95 Date Analyzed: 03/04/95 Dilution Factor: l.OO CAS NO. COMPOUND Sulfur Cleanup: (Y/N) 1L_ Q CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG 319-84-6 319-85-7 319-86-8 58-89-9 76-44-8 309-00-2 1024-57-3 959-98-8 60-57-1 72-55-9 72-20-8 33213-65-9 72-54-8 1031-07-8 50-29-3 72-43-5 53494-70-5 7421-93-4 5103-71-9 5103-74-2 8001-35-2 12674-11-2 11104-28-2 11141-16-5 53469-21-9 12672-29-6 11097-69-1 11096-82-5 -alpha-BHC -beta-BHCj; delta-BHC -geunma-BHC (Lindane) -Heptachl or ' -Aldrin -Heptachlor epoxide, -Endosulfan I ] -Dieldrin -4,4' -DDE -Endrin -Endosulfan II -4,4' -DDD -Endosulfan sulfate -4,4' -DDT Methoxychlor_ Endrin ketone —Endrin Aldehyde, —alpha-Chlordane] —gamma-Chlordane, —Toxaphene —Aroclor-1016_ —Aroclor-12 21, —Aroclor-1232] —Aroclor-124 2, —Aroclor-1248, —Aroclor-1254] —Aroclor-1260 300770 FORM I PEST Revic Date VALI DATED" t'O^Uty^ ^ ' ^ - / ^ . ?d By ID PESTICIDE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. elm Name: G s E L I Contract: fflLA. Case No.: HLA, SAS No.: BS0013 Code: PACE Matrix: (soil/water) WATER Saunple w t / v o l : 1000 (g/mL) ML % Moisture: decanted: (Y/N) _ Extraction: (SepF/Cont/Sonc) CONT SDG No.: 95020 Lab Sample ID: WGOOl Lab File ID: Concentrated Extract Volvune: Injection Volume: 1.00 (uL) GPC Cleanup: (Y/N) H 2000 (UL) pH: $,9 Date Received: 02/03/95 Date Extracted: 02/06/95 Date Analyzed: 02/16/95 Dilution Factor: 1.00 CAS NO. COMPOUND Sulfur Cleanup: (Y/N) H Q CONCENTRATION UNITS: (ug/L or ug/Kg) 12S/L. 319-84-6 319-85-7 319-86-8 58-89-9 76-44-8 309-00-2 1024-57-3 959-98-8 60-57-1 72-55-9 72-20-8 33213-65-9 72-54-8 1031-07-8 50-29-3 72-43-5 53494-70-5 7421-93-4 5103-71-9 5103-74-2 8001-35-2 12674-11-2 11104-28-2 11141-16-5 53469-21-9 12672-29-6 11097-69-1 11096-82-5— -—alpha-BHC beta-BHC " delta-BHC -gamma-BHC (Lindane) -Heptachlor -Aldrin -Heptachlor epoxide, -Endosulfan I ] -Dieldrin -4,4'-DDE -Endrin -Endosulfan II •4,4' -DDD, -Endosulfan sulfate -4,4' -DDT Methoxychlor_ -—Endrin ketone -Endrin Aldehyde. —alpha-Chlordane] —gamma-Chlordane] —Toxaphene. —Aroclor-1016, —Aroclor-122l] —Aroclor-1232] —Aroclor-1242] —Aroclor-1248] —Aroclor-1254" Aroclor-1260 .010 .010 .010 .010 .010 .010 .010 .010 .020 .020 .020 .020 .020 .020 .020 0.10 .020 .020 .010 .010 1.0 0.20 6.40 0.20 0.20 0.20 0.20 0.20 U J u u u u u UJ u u u u u u u u u u u u u u u u u u u u 3 0 0 7 7 1 FORM I PEST VALIDATED Revicv.cd By f^^orc-z^,^ Date 3 ^ 2 y-fsS" hj^i/SO.^ ID J PESTICIDE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. i Name: G S E L I Code: PfrCE Case No.: HLA Matrix: (soil/water) SOIL Sample wt/vol: 30.0 (g/mL) fi % Moisture: Ifi decanted: (Y/N) li Extraction: (SepF/Cont/Sonc) SONC Contract: HLA SAS No.: ClOOOl SDG No.: 95020 Lab Sample ID: VTF002 Lab File ID: Concentrated Extract Volume: Injection volume: 1.00 (uL) GPC Cleanups (Y/N) I 5000 (UL) pH: 10.4 Date Received: 01/30/95 Date Extracted: 02/03/95 Date Analyzed: 02/20/95 Dilution Factor: 1.00 CAS NO. COMPOUND Sulfur Cleanup: (Y/N) H Q CONCENTRATION UNITS: (ug/L or ug/Kg) Vg/Kg 319-84-6 aloha-BHC 319-85-7 beta-BHC 319-86-8 delta-BHC 58-89-9 aamma-BHC (Lindane) 76-44-8 Heotachlor 309-00-2 Aldrin 1024-57-3 Heptachlor epoxide 959-98-8 Endosulfan I 60-57-1 Dieldrin 72-55-9 4.4'-DDE 72-20-8 Endrin 33213-65-9 Endosulfan II 72-54-8 4. 4'-DDD 1031-07-8 Endosulfan sulfate 50-29-3 4.4'-DDT 72-43 -5 Methoxychlor 53494-70-5 Endrin ketone 7421-93-4 Endrin Aldehvde 5103-71-9 alpha-Chlordane 5103-74-2 gamma-Chlordane 8001-35-2 Toxaphene 12674-11-2 Aroclor-1016 11104-28-2 Aroclor-1221 11141-16-5 Aroclor-1232 53469-21-9 Aroclor-1242 12672-29-6 Aroclor-1248 11097-69-1 Aroclor-1254 11096-82-5 Aroclor-1260 2.1 2.1 2.1 2.1 2.1 2.1 2.1 2.1 4.0 4.0 4.0 4.0 4.0 4.0 4.0 21 4.0 4.0 2.1 2.1 210 40 .81 40 40 40 40 40 u:] [ U U U U U U U UV/ U3 yK U3 u u u u u u u u u u u u u u UV r U3 FORM I PEST Re. Date 300772 VALIDATEp;; ~ ..J Ey IZ:;W /WeY 3/90 ID PESTICIDE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE MO. Name: g g E L I Contract: HLA C11618 Code: PACE Case No.: HLA SAS No.: SDG No.: 95020 Matrix: (soil/water) SOIL Sample wt/vol: 30.o (g/mL) fi % Moisture: 12 decanted: (Y/N) fi Extraction: (SepF/Cont/Sonc) SONC Lab Sample ID: VTF003 Lab File ID: Concentrated Extract Volume: Injection Volume: 1.00 (uL) GPC Cleanup: (Y/N) X 5000 (UL) pH: 9tQ Date Received: 01/30/95 Date Extracted: 02/03/95 Date Analyzed: 02/20/95 Dilution Factor: 1.00 CAS NO. COMPOUND Sulfur Cleanup: (Y/N) fi Q CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG 319-84-6 alpha-BHC 319-85-7 beta-BHC 319-86-8 delta-BHC 58-89-9 ' aaunma-BHC (Lindane) 76-44 -8 Heptachlor 309-00-2 Aldrin 1024-57-3 Heptachlor epoxide 959-98-8 Endosulfan I 60-57-1 Dieldrin 72-55-9 4.4'-DDE 72-20-8 Endrin 33213-65-9 Endosulfan II 72-54-8 4.4'-DDD 1031-07-8 Endosulfan sulfate 50-29-3 4 .4 • -DDT 72-43-5 Methoxychlor 53494-70-5 Endrin ketone 7421-93-4 Endrin Aldehvde 5103-71-9 alpha-Chlordane 5103-74-2 '• gamma-Chlordane 8001-35-2 Toxaphene 12674-11-2 Aroclor-1016 1 11104-28-2 Aroclor-1221 11141-16-5 Aroclor-1232 53469-21-9 Aroclor-1242 12672-29-6 Aroclor-1248 11097-69-1 Aroclor-1254 11096-82-5 Aroclor-1260 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 3.7 3.7 3.7 3.7 3.7 3.7 3.7 19 3.7 3.7 1.9 1.9 190 37 75 ' 37 37 37 37 37 UJ U u u u u UJ u u u ^ R u u u u u u u u u u u u u u iu !u u 300773 FORM I PEST VALIDATE^-. Revic.vcd By I ' ^ J e ^ \{M.<Ly^ 90 ID PESTICIDE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE N O ; • Name: g S E L I Lab Code: PACE Case No.: Matrix: (soil/water) SOIL Sample wt/vol: 30.0 (g/mL) fi % Moisture: Ifi decanted: (Y/N) fi Extraction: (SepF/Cont/Sonc) SONC Contract: ULL. SAS No.: C11820 SDG No.: 25020 Lab Sample ID: VTF004 Lab File ID: Concentrated Extract Volume: Injection Volume: 1.00 (uL) GPC Cleanup: (Y/N) X 5000 (uL) pH: 9.2 Date Received: 01/30/95 Date Extracted: 02/03/95 Date Analyzed: 02/20/95 Dilution Factor: 1^Op CAS NO. COMPOUND Sulfur Cleanup: (Y/N) fi Q CONCENTRATION UNITS: (ug/L or ug/Kg) Vg/Kg 319-84-6 alpha-BHC 319-85-7 beta-BHC 319-86-8 delta-BHC 58-89-9 qaunma-BHC (Lindaine) 76-44-8 Heptachlor 309-00-2 Aldrin 1024-57-3 Heptachlor epoxide 959-98-8 Endosulfan I 60-57-1 Dieldrin 72-55-9 4,4'-DDE 72-20-8 Endrin 33213-65-9 Endosulfan II 72-54-8 4,4'-DDD 1031-07-8 Endosulfan sulfate 50-29-3 4.4'-DDT 72-43-5 Methoxychlor 53494-70-5 Endrin ketone 7421-93-4 Endrin Aldehvde 5103-71-9 alpha-Chlordane 5103-74-2 gaunma-Chlordane 8001-35-2 Toxaphene 12674-11-2 Aroclor-1016 11104-28-2 Aroclor-1221 11141-16-5 Aroclor-1232 53469-21-9 Aroclor-1242 12672-29-6 Aroclor-1248 11097-69-1 Aroclor-1254 11096-82-5 Aroclor-1260 2.1 2.1 2.1 2.1 2.1 2.1 2.1 2.1 4.0 4.0 4.0 4.0 4.0 4.0 4.0 21 4.0 4.0 2.1 2.1 210 40 81 40 40 40 40 40 UJ u u u u u UJ u u u u u u u u u u u u u u u u u u u u FORM I PEST^^ • Date VALIDATED^ Z ' 2 2 - 1 S 3/90 300774 ID PESTICIDE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. Name: G s E L l Lab Code: PACE Case No.: HIA Matrix: (soil/water) SOIL Sample wt/vol: 30.0 (g/mL) fi^ % Moisture: 15 decanted: (Y/N) fi Extraction: (SepF/Cont/Sonc) SONC Contract: filA. SAS No.: C12022 SDG No.: 95020 Lab Sample ID: VTF005 Lab File ID: Concentrated Extract Volume: Injection Volume: 1.00 (uL) GPC Cleanup: (Y/N) X 5000 (UL) pH: 9»5 Date Received: 01/30/95 Date Extracted: 02/03/95 Date Analyzed: 02/20/95 Dilution Factor: 1.00 CAS NO. COMPOUND Sulfur Cleanup: (Y/N) fi Q CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG 319-84-6 319-85-7 319-86-8 58-89-9 76-44-8 309-00-2 1024-57-3 959-98-8 60-57-1 72-55-9 72-20-8 33213-65-9 72-54-8 1031-07-8 50-29-3 72-43-5 53494-70-5 7421-93-4 5103-71-9 5103-74-2 8001-35-2 12674-11-2 11104-28-2 11141-16-5 53469-21-9 12672-29-6 11097-69-1 11096-82-5 -alpha-BHC -beta-BHC_] delta-BHC -gamma-BHC (Lindane), •Heptachlor •Aldrin •Heptachlor epoxide, •Endosulfan I •Dieldrin -4,4' -DDE -Endrin -Endosulfan II -4,4' -DDD_! ] -Endosulfan sulfate -4,4' -DDT ] Methoxychlor_ Endrin ketone -Endrin Aldehyde, -alpha-Chlordane] •gamma-Chlordane] -Toxaphene ] —Aroclor-1016, —Aroclor-12 21] —Aroclor-1232] —Aroclor-1242] —Aroclor-1248] —Aroclor-1254] —Aroclor-12 60" FORM I PES'fevi Date 300775 VALIDATED' .vcd By \''6yz>4c^ lUytiy'^'. 3/ao ID PESTICIDE ORGAMICS ANALYSIS DATA SHEET EPA SAMPLE NO. Lab Name: G S E L I Contract: HLA Case No.: HLA SAS No.: D40001 Code: PACE Matrix: (soil/water) SOIL Sample wt/vol: 30.0 (g/mL) fi % Moisture: 22 decanted: (Y/N) fi Extraction: (SepF/Cont/Sonc) SONC SDG No.: 95020 Lab Sample ID: VTFQ06 Lab File ID: Concentrated Extract Voliu&e: Injection Volume: l.OO (uL) GPC Cleanup: (Y/N) X 5000 (UL) pH: 9.g Date Received: 01/30/95 Date Extracted: 02/03/95 Date Analyzed: 02/20/95 Dilution Factor: 1.00 CAS NO. COMPOUND Sulfur Cleanup: (Y/N) fi^ Q CONCENTRATION UNITS: (ug/L or ug/Kg) Vg/Kg 319-84-6 319-85-7 319-86-8 58-89-9 7 6 - 4 4 - 8 309-00-2 1024-57-3 959-98-8 6 0 - 5 7 - 1 72-55-9 72-20-8 33213-65-9 72-54-8 1031-07-8 50-29-3 7 2 - 4 3 - 5 53494-70-5 7421-93-4 5103-71-9 5103-74-2 8001-35-2 12674-11-2 11104-28-2 11141-16-5 53469-21-9 12672-29-6 11097-69-1 11096-82-5 -alpha-BHC -beta-BHC_] delta-BHC •gamma-BHC (Lindane) •Heptachlor \ -Aldrin -Heptachlor epoxide, -Endosulfan I ] -Dieldrin -4,4'-DDE -Endrin -Endosulfan II -4,4' -DDD ] -Endosulfan sulfate -4,4' -DDT ] Methoxychlor Endrin ketone -Endrin Aldehyde, -alpha-Chlordane, -gaunma-Chlordane, -Toxaphene —Aroclor-1016, —Aroclor-12 21] —Aroclor-1232] —Aroclor-1242] —Aroclor-1248] —Aroclor-1254] -—Aroclor-12 60' 300776 FORM I PEST "^ Date I ' C y ' k ^ hi^^^^<^-/wQQ By %'28-^S ID PESTICIDE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. 9 Naune: G S E L I Contract: HLA D41416 Lab Code: PACE Case No.: HLA SAS No.: SDG No.: 95020 Matrix: (soil/water) SOIL Sample wt/vol: 30.0 (g/mL) fi * Moisture: 14 decanted: (Y/N) fi Extraction: (SepF/Cont/Sonc) SONC Lab Sample ID: VTF007 Lab File ID: Concentrated Extract Volume: Injection Volume: 1.00 (uL) GPC Cleanup: (Y/N) 5000 (UL) pH: 9»9 Date Received: 01/30/95 Date Extracted: 02/03/95 Date Analyzed: 02/20/95 Dilution Factor: 1.00 CAS NO. COMPOUND Sulfur Cleanup: (Y/N) fi Q CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG 319-84-6 319-85-7 319-86-8-- 58-89-9 76-44-8 309-00-2 1024-57-3 959-98-8 60-57-1 72-55-9 72-20-8 33213-65-9 72-54-8 1031-07-8 50-29-3 72-43-5 53494-70-5 7421-93-4 5103-71-9 5103-74-2 8001-35-2 12674-11-2 11104-28-2 11141-16-5 53469-21-9 12672-29-6 11097-69-1 11096-82-5— -alpha-BHC -beta-BHC_] delta-BHC -gamma-BHC (Lindane) -Heptachlor -Aldrin -Heptachlor epoxide, -Endosulfan I ] -Dieldrin -4,4'-DDE -Endrin -Endosulfan II -4,4' -DDD, -Endosulfan sulfate -4,4' -DDT, Mcthoxychlor_ Endrin ketone —Endrin Aldehyde, —alpha-Chlordane] —gamma-Chlordane] —Toxaphene —Aroclor-1016. —Aroclor-12 21] —Aroclor-1232] —Aroclor-1242] —Aroclor-1248] —Aroclor-1254" Aroclor-1260 300777 FORM I PEST VALIDATEDJ J Reviewed By Date_^ll^ll£ ^ ID PESTICIDE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. Lab Name: G S E L I Contract: fiLJL Case No.: HLA SAS No.: D42022 Code: PACE Matrix: (soil/water) SOIL Sample wt/vol: 30.0 (g/mL) fi % Moisture: 15 decanted: (Y/N) fi Extraction: (SepF/Cont/Sonc) gONC SDG No.: 95020 Lab Saunple ID: VTFOOS Lab File ID: Concentrated Extract Volume: Injection Voltu&e: l.OQ (uL) GPC Cleanup: (Y/N) X 5000 (uL) pH: 9.9 Date Received: 01/30/95 Date Extracted: 02/03/95 Date Analyzed: 02/20/95 Dilution Factor: 1.00 CAS NO. COMPOUND Sulfur Cleanup: (Y/N) fi Q CONCENTRATION UNITS: (ug/L or ug/Kg) Vg/Kg 319-84-6 319-85-7 319-86-8 58-89-9 76-44-8 309-00-2 1024-57-3 959-98-8 6 0 - 5 7 - 1 72-55-9 72-20-8 33213-65-9 72-54-8 1031-07-8 50-29-3 72-43-5 53494-70-5 7421-93-4 5103-71-9 5103-74-2 8001-35-2 12674-11-2 11104-28-2 11141-16-5 53469-21-9 12672-29-6 11097-69-1 1 1 0 9 6 - 8 2 - 5 — -alpha-BHC -beta-BHC_] delta-BHC -gamma-BHC (Lindane) -Heptachlor \ -Aldrin -Heptachlor epoxide. -Endosulfan I ] -Dieldrin -4,4'-DDE -Endrin -Endosulfan II_ •4,4' -DDD -Endosulfan sulfate -4,4' -DDT, Methoxychlor_ Endrin ketone -Endrin Aldehyde, —alpha-Chlordane] —geunma-Chlordane] —Toxaphene. —Aroclor-1016, —Aroclor-1221] —Aroclor-1232] —Aroclor-1242] —Aroclor-1248] —Aroclor-1254] Aroclor-1260" FORM I PEST Revic Date VALID wed By 300778 rrED -5-;;y-K y/ro- ID PESTICIDE ORGAMICS AMALYSIS DATA SHEET EPA SAMPLE.NO, Jgb ^Hb Name: G S E L I Code: PACE Case Mo.: HLA Matrix: (soil/water) S O I L Sample wt/vol: 30.0 (g/mL) fi % Moisture: JZ decanted: (Y/N) fi Extraction: (SepF/Cont/Sonc) SONC Contract: fiXA. SAS No.: F21215 SDG No.: 25020 Lab Sample ID: VSR002 Lab File ID: Concentrated Extract Volume: Injection Volume: 1.00 (uL) GPC Cleanup: (Y/N) X 5000 (UL) pH: 5.9 Date Received: 01/27/95 Date Extracted: 02/03/95 Date Analyzed: 02/22/95 Dilution Factor: 1.00 CAS NO. COMPOUND Sulfur Cleanup: (Y/N) fi Q CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG 319-84-6 319-85-7 319-86-8 58-89-9 76-44-8 309-00-2 1024-57-3 959-98-8 60-57-1 72-55-9 72-20-8 33213-65-9 72-54-8 1031-07-8 50-29-3 72-43-5 53494-70-5 7421-93-4 5103-71-9 5103-74-2 8001-35-2 12674-11-2 11104-28-2 11141-16-5 53469-21-9 12672-29-6 11097-69-1 11096-82-5 -alpha-BHC •beta-BHCJ" delta-BHC .gamma-BHC (Lindane) -Heptachlor \ -Aldrin -Heptachlor epoxide, -Endosulfan I ] -Dieldrin -4,4' -DDE_ -Endrin -Endosulfan II -4,4'-DDD -Endosulfan sulfate •4,4' -DDT, Methoxychlor_ -—Endrin ketone —Endrin Aldehyde, —alpha-Chlordane] —gamma-Chlordane, —Toxaphene, —Aroclor-1016_ —Aroclor-12 21] —Aroclor-1232] —Aroclor-1242] —Aroclor-1248] —Aroclor-1254, —Aroclor-12 60' 300779 FORM I PEST VA Reviewed By kjdcy^ Date -^'-^8~'^S V^° ID PESTICIDE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. Lab Name: G S E L I Contract: HLA Case Mo.: HLA^ SAS No.: F21820 Code: SLSZ Matrix: (soil/water) S O I L Sample wt/vol: 30.0 (g/mL) fi % Moisture: 14 decanted: (Y/N) N Extraction: (SepF/Cont/Sonc) SONC SDG No.: 95020 Lab Sample ID: VSR003 Lab File ID: Concentrated Extract Volume: Injection Volume: 1.00 (uL) GPC Cleanup: (Y/N) X 5000 (UL) pH: 7.0 Date Received: 01/27/95 Date Extracted: 02/03/95 Date Analyzed: 02/22/95 Dilution Factor: 1.00 CAS NO. COMPOUND Sulfur Cleanup: (Y/N) fi CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG 319-84-6 alpha-BHC 319-85-7 beta-BHC 319-86-8 delta-BHC 58-89-9 gamma-BHC (Lindane) 76-44-8 Heptachlor 309-00-2 Aldrin 1024-57-3 Heptachlor epoxide 959-98-8 Endosulfan I 60-57-1 Dieldrin 72-55-9 4,4'-DDE 72-20-8 Endrin 33213-65-9 Endosulfan II 72-54-8 4,4'-DDD 1031-07-8- Endosulfan sulfate 50-29-3 4,4'-DDT 72-43-5-^ Methoxychlor 53494-70-5 Endrin ketone 7421-93-4 Endrin Aldehyde 5103-71-9 alpha-Chlordane 5103-74-2 geunma-Chlordane 8001-35-2 Toxaphene 12674-11-2 Aroclor-1016 11104-28-2 Aroclor-1221 11141-16-5 Aroclor-1232 53469-21-9 Aroclor-1242 12672-29-6 Aroclor-1248 11097-69-1 Aroclor-1254 11096-82-5 Aroclor-1260 2,0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 3.8 3.8 3.8 3,8 3.8 3.8 3.8 20 3.8 3.8 2.0 2.0 200 3.8 77 38 38 38 38 38 UJ U U U U U U3 u u u u u u u u u u u u u u u u u u u u 300780 FORM I PEST Revic.vcd By Date — VALIDATED |o^>^^t/L lUy.^/90 3-28-9-^ ID PESTICIDE ORGAMICS ANALYSIS DATA SHEET lAh Na fPb> Cc Matrix Sample % Mois Extrac Concen Inject GPC Cl # me: G S E L I Contract: HLA de: PACE Case No.: HLA SAS No.: SDG : (soil/water) SOIL Lab Samole ID: wt/vol: 30.0 (g/mL) g ... Lab File ID: ture: 13 decanted: (Y/N) N Date Received: tion: (SeoF/Cont/Sonc) SONC Date Extracted itrated Extract Volume: 5000 (uLi Date Analyzed: ,ion Volume: 1.00 (uL) Dilution Facto: eanup: fY/N^ Y pH: 6.4 Sulfur Cleanup CONCENTRATION UNITS: CAS NO. COMPOUND (ug/L or ug/Kg) Vg/K< 319-84 -6 alpha-BHC 319-85-7 beta-BHC 319-86-8 delta-BHC 58-89-9— cramma-BHC (Lindane) 76-44-8 Heptachlor 309-00-2 Aldrin 1024-57-3 Heptachlor epoxide 959-98-8 Endosulfan I 60-57-1 Dieldrin 72-55-9 4,4 • -DDE 72-20-8 Endrin 33213-65-9 Endosulfan II 72-54-8 4,4'-DDD 1031-07-8 Endosulfan sulfate 50-29-3 4,4 ' -DDT 72-43-5 Methoxychlor 53494-70-5 Endrin ketone 7421-93-4 Endrin Aldehvde 5103-71-9 alpha-Chlordane 5103-74-2 gamma-Chlordane 8001-35-2 Toxaphene 12674-11-2 Aroclor-1016 11104-28-2 Aroclor-1221 11141-16-5 Aroclor-1232 53469-21-9 Aroclor-1242 12672-29-6 Aroclor-1248 11097-69-1 Aroclor-1254 11096-82-5 Aroclor-1260 EPA SAMPLE NO. F30001 NO.: 25020 VSR004 01/27/95 : 02/03/25 02/22/95 r: 1.00 : (VN) V 5 Q 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 3.8 3.8 5.0 3.8 3.8 3.8 3.8 20 3.8 4.0 3.9 4.1 200 38 76 38 38 38 38 38 UD- U U U U u u u u u P u u u u u u p p p u u u u u u U\ / UJ —--- FORM I PEST pev;„ Date 3 0 0 7 8 1 ^/AUDATED d By iTu^itrui \Uy^Gy 3/90 ID PESTICIDE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. Lab Name: G S E L I Contract: HLA F31214 Code: £2^fi£_ Case No,: HLJ^ SAS No.: SDG No.: 95020 Matrix: (soil/water) SOIL Sample wt/vol: 30.0 (g/mL) fi % Moisture: H decanted: (Y/N) U. Extraction: (SepF/Cont/Sonc) SONC Lab Sample ID: VSR007 Lab File ID: Concentrated Extract Volume: Injection Volume: 1.00 (uL) GPC Cleanup: (Y/N) 5000 (UL) pH: 9.5 Date Received: 01/27/95 Date Extracted: 02/03/95 Date Analyzed: 03/04/95 Dilution Factor: 1.00 CAS NO. COMPOUND Sulfur Cleanup: (Y/N) fi Q CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG 319-84-6 alpha-BHC 319-85-7 beta-BHC 319-86-8 delta-BHC 58-89-9 gamma-BHC (Lindane) 76-44-8 Heptachlor 309-00-2 Aldrin 1024-57-3 Heptachlor epoxide 959-98-8 Endosulfan I 60-57-1 Dieldrin 72-55-9 4 .4 ' -DDE 72-20-8 Endrin 33213-65-9 Endosulfan II 72-54-8 4,4 ' -DDD 1031-07-8 Endosulfan sulfate 50-29-3 4,4 ' -DDT 72-43-5 Methoxychlor 53494-70-5 Endrin ketone 7421-93-4 Endrin Aldehvde 5103-71-9 alpha-Chlordane 5103-74-2 —gamma-Chlordane 8001-35-2 Toxaphene 12674-11-2 Aroclor-1016 11104-28-2 Aroclor-1221 11141-16-5 Aroclor-1232 53469-21-9 Aroclor-1242 12672-29-6 Aroclor-1248 11097-69-1 Aroclor-1254 11096-82-5 Aroclor-1260 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 3.7 3.7 3.7 3.7 3.7 3.7 3.7 19 3.7 3.7 1.9 1.9 190 37 74 37 37 37 37 37 U U U U U U U3 U U U U u u u u u u u u u u u u u u u u 300782 FORM I PEST Revic.vcd By Date — VALIjDATED. ;d By l^^'^'kt^ riUt7'K/<in 3-^^ - i s ID PESTICIDE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO, Name: G S E L I Contract: HIA. Case No.: HLA SAS No.: F31820 Code: PACE Matrix: (soil/water) S O I L Sample wt/vol: 30.o (g/mL) fi % Moisture: H decanted: (Y/N) fi Extraction: (SepF/Cont/Sonc) SONC SDG No.: 95020 Lab Sample ID: VSR009 Lab File ID: Concentrated Extract Volume: Injection Vol\ame: l.OO (uL) GPC Cleanup: (Y/N) X 5000 (uL) pH: 8.6 Date Received: 01/27/95 Date Extracted: 02/03/95 Date Analyzed: 03/04/95 Dilution Factor: 1.00 CAS NO. COMPOUND Sulfur Cleanup: (Y/N) fi Q - CONCENTRATION UNITS: (ug/L or ug/Kg) Vg/Kg 319-84-6 alpha-BHC 319-85-7 beta-BHC 319-86-8 delta-BHC 58-89-9 gamma-BHC (Lindane) 76-44-8 Heptachlor 309-00-2 Aldrin 1024-57-3 Heptachlor epoxide 959-98-8 Endosulfan I 60-57-1 Dieldrin 72-55-9 4,4 ' -DDE 72-20-8 Endrin 33213-65-9 Endosulfan II 72-54-8 4,4 • -DDD 1031-07-8 Endosulfan sulfate 50-29-3 4,4 • -DDT 72-43-5 Methoxychlor 53494-70-5 Endrin ketone 7421-93-4 —Endrin Aldehyde 5103-71-9 alpha-Chlordane ^ 5103-74-2 gamma-Chlordane 8001-35-2 Toxaphene 12674-11-2 Aroclor-1016 11104-28-2 Aroclor-1221 11141-16-5 Aroclor-1232 53469-21-9 Aroclor-1242 12672-29-6 Aroclor-1248 11097-69-1 Aroclor-1254 11096-82-5 Aroclor-1260 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 3.7 3.7 3.7 3.7 3.7 3.7 3.7 19 3.7 3.7 1.9 1.9 190 37 74 37 37 37 37 37 U U U U U U UJ U U U U U u u u u u u u u u u u u u u u 300783 FORM I PEST ncS( Date ... ''ALIDATED -J By IT/^icn. tU7<L^^.^Q '2>-7-S-^3 ID PESTICIDE ORGAMICS AMALYSIS DATA SHEET EPA SAMPLE NO. Name: G S E L I Contract: HLA Case No.: HLA_ SAS No.: S00012 Lab Code: PACE Matrix: (soil/water) WATER Sample wt/vol: 1000 (g/mL) ML % Moisture: decanted: (Y/N) _ Extraction: (SepF/Cont/Sonc) CONT SDG No.: 95020 Lab Sample ID: VSROOl Lab File ID: Concentrated Extract Volume: Injection Volime: 1.00 (uL) GPC Cleanup: (Y/N) fi 2000 (UL) pH: 7.0 Date Received: 01/27/95 Date Extracted: 01/30/95 Date Analyzed: 02/03/95 Dilution Factor: 1.00 CAS NO. COMPOUND Sulfur Cleanup: (Y/N) fi CONCENTRATION UNITS: (ug/L or ug/Kg) Vg/L 319-84 -6 alpha-BHC 319-85-7 beta-BHC 319-86-8 delta-BHC 58-89-9 gamma-BHC (Lindane) 76-4 4-8 Heptachlor 309-00-2 Aldrin 1024-57-3 Heptachlor epoxide 959-98-8 Endosulfan I 60-57-1 Dieldrin 72-55-9 4,4'-DDE 72-20-8 Endrin 33213-65-9 Endosulfan II 72-54-8 4,4 ' -DDD 1031-07-8 Endosulfan sulfate 50-29-3 4 ,4 ' -DDT 72-43 -5 Methoxychlor 53494-70-5 Endrin ketone 7421-93-4 Endrin Aldehvde 5103-71-9 alpha-Chlordane 5103-74-2 gamma-Chlordane 8001-35-2 Toxaphene 12674-11-2 Aroclor-1016 11104-28-2 Aroclor-1221 11141-16-5 Aroclor-1232 53469-21-9 Aroclor-1242 12672-29-6 Aroclor-1248 11097-69-1 Aroclor-1254 11096-82-5 Aroclor-1260 ' 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.020 0.020 0.020 0.020 0.020 0.020 0.020 0.10 0.020 0.020 0.010 0.010 1.0 0.20 '0.40 0.20 0.20 0.20 0.20 0.20 UZ f u u u u u u u ui/ UJ UJ U U U U U u u D U U U U U U u / ua 1 300784 VAU FORM I PEST F.'. :--; By Date ipATEa^ JZrUv^ YJLMA 3/90 l>'2^-'iS ID PESTICIDE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. Name: G s E L I Contract: HLA Case No.: HLA SAS No.: S00012RE Lab Code: PACE Matrix: (soil/water) WATER Sample wt/vol: 420.0 (g/mL) ML % Moisture: decanted: (Y/N) _ Extraction: (SepF/Cont/Sonc) CONT SDG No.: 95020 Lab Sample ID: VSROOIRE Lab File ID: Concentrated Extract Volume: Injection Volume: 1.00 (uL) GPC Cleanup: (Y/N) fi 2000 (uL) pH: 7.0 Date Received: 01/27/95 Date Extracted: 02/20/95 Date Analyzed: 02/21/95 Dilution Factor: 1.00 CAS NO. COMPOUND Sulfur Cleanup: (Y/N) fi__ Q CONCENTRATION UNITS: (ug/L or ug/Kg) Vg/L • 319-84-6 319-85-7 319-86-8 58-89-9 76-44-8 309-00-2 1024-57-3 — 959-98-8 6 0 - 5 7 - 1 72-55-9 72-20-8 3 3 2 1 3 - 6 5 - 9 - 72-54-8 1031-07-8— 50-29-3 72-43-5 53494-70-5 7 4 2 1 - 9 3 - 4 - 5 1 0 3 - 7 1 - 9 - 5 1 0 3 - 7 4 - 2 - 8 0 0 1 - 3 5 - 2 - 12674-11-2 11104-28-2 11141-16-5 53469-21-9 12672-29-6 11097-69-1 11096-82-5 —alpha-BHC —beta-BHC_] delta-BHC -gamma-BHC (Lindane) -Heptachlor -Aldrin -Heptachlor epoxide, -Endosulfan I ] -Dieldrin -4,4' -DDE -Endrin . -Endosulfan II -4,4' -DDD -Endosulfan sulfate -4,4' -DDT. Methoxychlor__ Endrin ketone —Endrin Aldehyde, —alpha-Chlordane] —gamma-chlordane, —Toxaphene, —Aroclor-1016. —Aroclor-1221] —Aroclor-1232. —Aroclor-1242. —Aroclor-1248] —Aroclor-1254 Aroclor-1260 0.024 0.024 0.024 0.024 0.024 0.024 0.024 0.024 0.048 0.048 0.048 0.048 0.048 0.048 0.048 0.24 0.048 0.048 0.024 0.024 2.4 0.48 6.95 0.48 0.48 0.48 0.48 0.48 UJ u u u u u u u Uil/ U J \;3l U J u u u u u u u u u u u u u u u U j V 3 0 0 7 8 5 FORM I PEST Pf Date VALIDATED By JZ^m 2 , ^ ^ - f S 3/50" ID PESTICIDE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. LS Name: G S E L I Contract: HIA. SO0127 Code: PACE Case No.: HIA, SAS No.: Matrix: (soil/water) WATER Sample wt/vol: 1000 (g/mL) ML % Moisture: decanted: (Y/N) Extraction: (SepF/Cont/Sonc) CONT SDG No.: 95020 Lab Sample ID: VTFOOl Lab File ID: Concentrated Extract Volume: Injection Volume: 1.00 (uL) GPC Cleanup: (Y/N) fi 2000 (UL) pH: 5.9 Date Received: 01/30/95 Date Extracted: 02/01/95 Date Analyzed: 02/03/95 Dilution Factor: 1.00 CAS NO. COMPOUND sulfur Cleanup: (Y/N) fi Q CONCENTRATION UNITS: (ug/L or ug/Kg) Vg/L 319-84-6 alpha-BHC 319-8 5-7 beta-BHC 319-86-8 delta-BHC 58-89-9— —gamma-BHC (Lindane) 76-44-8 Heptachlor 309-00-2 Aldrin 1024-57-3 Heptachlor epoxide 959-98-8 Endosulfan I 60-57-1 Dieldrin 72-55-9 4 ,4 ' -DDE 72-20-8 Endrin 33213-65-9 Endosulfan II 72-54-8 4,4'-DDD 1031-07-8-r Endosulfan sulfate 50-29-3 4,4 • -DDT 72-43-5 Methoxychlor 53494-70-5 Endrin ketone 7421-93-4 Endrin Aldehvde 5103-71-9 alpha-Chlordane 5103-74-2 gamma-Chlordane 8001-35-2 Toxaphene 12674-11-2 Aroclor-1016 11104-28-2 Aroclor-1221 11141-16-5 Aroclor-1232 53469-21-9 Aroclor-1242 12672-29-6 Aroclor-1248 11097-69-1 Aroclor-1254 11096-82-5 Aroclor-1260 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.020 0.020 0.020 0.020 0.020 0.020 0.020 0.10 0.020 0.020 0.010 0.010 1.0 0,.20 0.40 0.20 0.20 0.20 0.20 0.20 30 \32 U U U U U U U ui / U J jtrR ua u u u u u u u ul u u u u u u Ul / ua 0786 VALIDATED FORM I PEST R- Dale By yrjz-r-c 37^0- 3-2^~^S ID PESTICIDE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. ^ 3 sff Name: G S E L I Contract: HLA Case No.: HLA_ SAS No.: SO0127RE Code: PACE Matrix: (soil/water) H&IES Sample wt/vol: 490.o (g/mL) M L % Moisture: decanted: (Y/N) _ Extraction: (SepF/Cont/Sonc) gONT SDG No.: 25020 Lab Sample ID: VTFOOIRE Lab File ID: Concentrated Extract Volume: Injection Volvme: l.QQ (uL) GPC Cleanup: (Y/N) fi 2000 (UL) pH: 5.9 Date Received: 01/30/95 Date Extracted: 02/20/95 Date Analyzed: 02/21/95 Dilution Factor: 1.00 CAS NO. COMPOUND Sulfur Cleanup: (Y/N) fi CONCENTRATION UNITS: (ug/L or ug/Kg) Vg/L 319-84-6 alpha-BHC 319-85-7 beta-BHC 319-86-8 delta-BHC 58-89-9 gamma-BHC (Lindane) 76-44 -8 Heptachlor 309-00-2 Aldrin 1024-57-3 Heptachlor epoxide 959-98-8 Endosulfan I 60-57-1 Dieldrin 72-55-9 4,4 ' -DDE 72-20-8 Endrin 33213-65-9 Endosulfan II 72-54-8 4,4 ' -DDD 1031-07-8 Endosulfan sulfate 50-29-3 4,4'-DDT 72-43 -5 Methoxychlor 53494-70-5 Endrin ketone 7421-93-4 Endrin Aldehvde 5103-71-9 alpha-Chlordane 5103-74-2 gamma-Chlordahe 8001-35-2 Toxaphene 12674-11-2 Aroclor-1016 11104-28-2 Aroclor-1221 11141-16-5 Aroclor-1232 53469-21-9 Aroclor-1242 12672-29-6 Aroclor-1248 11097-69-1 Aroclor-1254 11096-82-5 Aroclor-1260 0.020 0.020 0.020 0.020 0.020 0.020 0.020 0.020 0.041 0.041 0.041 0.041 0.041 0.041 0.041 0.20 0.041 0.041 0.020 0.020 2.0 0.41 0.82 0.41 0.41 0.41 0.41 0.41 ua U U U U U U U ui r 1 UJ JTK UJ u u u u u u u u u u u u u u U' ll U3 1 1 300787 VAL! FORM I PEST El Rev:_v.cd By _ Date l:ihjA 3/90 HLA DATA QUALITY ASSURANCE REVIEW SUMMARY Metals Analysis Case Number : ^ I ^ Q | Q Project Number 2 ' ^ ^ I Z . ] O - Z Site: J L & w l r L ^ \ . ^ S ^ r ^ W j O / ^ . Contractor Laboratory: p / ^ C g ' ^ lXP/£- ^Jzih^ Validator X U / J ^ c t t ^ Validation Date: QC Reviewer 'T^tTTCy ^ P^yTiTTc^ Review Date: v / p / f -r^ Sample Matrix: ; j ^ ( j Z ) VJcifjl^ (^^ EPA CL? vn c-ickH^ sovj^ yvl jL^.uxAM ^ Ci^y^JJi Analytical Methods: Sample Designations: OATZZLOZ-L. CZ-LiJrZLo Dlonri 1 Dl iT-iU- Dl^^'7_4- VZnni^n D Z i q Z I D2>r)0nz. V2\n\Oi B l O o n ^ £12-02-2- r\Z/0r)/Ol RBSOO/ SoonS S00ll(^ f>oo\7n SOO\ZS' Data for the above samples are: Acceptable for use ^ Acceptable for use as qualified Unacceptable for use Is action required by the Preject Manager? Yes (No) Comments: 1^ tyy\ cWc it^o.\ ^ U i V c M lo c J". IDCt_l.dOC 1Q141994 1035 Form M E T I J 300788 DATA COMPLETENESS CHECKLIST X Included, no problems * Included, problems O Not included NA Not applicable Quality Control Summary X Case Narrative ^ Chain of Custody Forms y Cover Page ^ Holding Times X Inorganic Analysis Data Sheets X Initial and Continuing Calibration Summary y ICP and AA CRDL Check Standard Summary y Linear Range Verification Standard Summary j(f- Calibration and Preparation Blank Summary A ICP Interference Check Sample Summary •% Matrix Spike Summary i t Post Digestion Spike Sample Summary ^ Duplicate Sample Simimary ^ Laboratory Control Sample Sununary t^^A Method of Standard Additions Summary / ICP Serial Dilution Summary Y Quarteriy Instrument Detection Limits Siunmary X Annual Interelement Correction Factors Summary X Quarteriy ICP Linear Range Summary X Sample Preparation Log Summary X Sample Analysis Rim Log Summary Sample Raw Data X ICP Raw Data X GFAA Raw Data X Mercury Raw Data X Cyanide Raw Data Comments: met \jdac 101419^1035 2 Fom. MET 1.0 300789 SPECmC COMMENTS REGARDING ANALYSES Chain Of Custody Were samples property preserved aB4.^eived in good condition? Yes (No, Were custody transfers COTiecthr and completely documented? (Yes/ No Comments: " T ^ ^ C Z 6 jU^^SCuudZli^ jt^^ofetCCnj' y^^^y^^c^^^y^^ ^ > ^ i / > ' * Y ^ lAuo-Axt^ oJUi MiA^^fll^^ J l ^ ^ O \ Z 0 i ^ SOO\Z^J V^'OOOZ., P 3 \ ^ ^ % CyZ0D0\ CZZQZ-T^j tZZ'^Zidi^ CLA^ ^ 9 S 0 0 ] ^iUXVI^ Aj^<i^hv4rv£^-^A^^ Holding Times </ U ' M Were sample preparations and analyses, performed within holding times? Yes Qfo) y7Xy\yyy\^cJi j^Oyy^^jJU^ ju>^\x OA^^iXcvi^^ yQ^euz^z)Jlji IH-' (f^yA YVOXA^CAAKoN J.AH^U?_ Qy^oJiM^A- ^ K J^M. 2 8 ^ ^ ^^OAJ. . . | ^ ^ ; < ^ ^ ^ U m ^ i X t ^ Wmeo€/ J U a (WX/vvA.doL; ^^UMS^JL/JUA^ (>a^ y ^ ^ ^J^AMU^Jix^^ J U ^ ^ > ^ - ^ ^ ^ 1 ^ ^ O^^^^T" y^^U^jy^£yL (yJc ci^YvvpeAZtuKki- O-^-frwt^- ?> lDet„lA)C 10141994 1035 FomiMETIi) 3 0 0 7 9 0 Harding Lawson Associates ->-=—= Engineering and i s ; =.:1 Environmental Services SHEET OF JOB NO. PROJECT JM'UOyX.d CJUvd.JLy^dy^ f.ir»*^'y<!t^^ SUBJECT DATE 3l^'^^|H9 COMPUTED BY ( ^ . [ J l L i J t t ^ CHECKED BY j,4fi^yw^.AJ(Ji. JT P yi^J^y^/t^y^fV^-<»J\M . (LXKJi/^rJz Jl r p 1^350/01^095" R3So/oiI^9^ sevzlo.o-toloimf S^PZll^-^ZijoU^^f Soo\zo 030002- P^|7M PZooz-o RB5o/o//si5'/ , ^ SooiJg S?>e\lot0-o.fio\m^ Cicoof Sbcz/o-iloi3 0^f 5?>Czi^jU-2llo\^oo)^ SBCzlzi^-lLJoi^c^^ ?.^Sojo\30')^ SDO\Z^ PlOOOl v\\z\^ Pl2i-Z4- C20 00I CZ,'2.02.2. C2Z0AIG \l(SlA'OOZ- Mqd'Ooi \iac-ooi VGIC-OOZ. \IQC'00?> V6X--003 X/SX-^otf VJTX- 0 0 j VTX'OOt. VTX-OO^ 1^ 300791 Instrument Calibration Were instruments caiibrat^M^y and each time that sample analyses were performed? (Yes\ No Were the instruments calibpt^ using the minimum required numbers of blanks and standards? /Yes) No For the GFAA methods wa§_Dne standard analyzed at the Conttact Required Detection Limit (CRDL)? /Yes) No For the applicable method^^^td. the correlation coefficients meet the minimum requirement of 0.995? (Vesy No NA For the cyanide analyses wjis-a. midrange standard distilled and analyzed? (Yes/ No Comments: — ^ "fiimALy Initial and Continuing Calibration Verification Were the calibration standards and blanks analyzed at the required frequencies? /Yesj No Were the standard recoverjeswithin QC limits? (^^es) No Comments: yVvc 10141994 1035 4 ^^"^ ^ ^ ^ *-^ 300792 CRDL Standards Were CRDL standards (CRI-and CRA) analyzed at the required frequency? (Yes/ No Were the ICP standards (Ot^analyzed at the required levels? (Yes} No For the low concentration.method, were the^CRDL results acceptable? Yes No ( N A ) Comments: yitvAiy Matrix Spike Were matrix spike analyses performed at the correct frequency and on a sample matrix representative of the samples in this SDG? ^_.^^ (Yes) No Were field or rinse blanks used forthe spike analysis sample? Yes TNO) Were the matrix spike recoveries within acceptance criteria? Yes ( N O ) Were post-digestion spikes performed wherMc^uired? Yes No QiAj Comments: " J ^ iUj2riAM/tv^ 6 U t ^ ^ ^ ^ ^ y>6Jkji So012.0 Qyvdi^fA^&y^ \ i n n OM ^^-^iSA^. ' ^ h %JJ^yyMZ^ 74:0 (M^ jUntCtLA.^ 3-/C/T tDCl_luJ0C 10U1994 103S 5 . • - - - . ^ ^ormMEH.0 : 300793 Laboratory Control Sample Were laboratory control s^mijle analyses performed at the required frequency? Were laboratory control sample r^oxMy results acceptable? Yes T N O ) Comments: ( J U T \ Z O . O } % j J l . j i L C S W y\JlyZe^HyuLu.Jy^ J i ; ^ i ^ ju&(V\yuL^ydiyi~ ( f ^ ^ T ^ ^ LC^S yux^s-v-^^^'Oy- "-e / ) I- 4 M4 /%) M ^ fvdUiih ddU 3o - n o wi^/i^% c^>do^ y\^ zhkJi ^biAc^^yfJ^ wy^yATA^ OUSL^O J M / X A , :XJy^O ICP Interference Check Sample Were ICP interference ch^ek-samples (ICS) analysed at the required frequency? T Y C S ) NO Were the ICS recovery mieria met? CYQSA NO Were results greater than the IDL rcpoited for elements not present in the ICS solution? . ^ - ^ ^ ^ y '•Or & ) ( ^ y ^ H r f tlohy Were negative results with absolute values greater than the IDL reported for elements not present in the ICS solution? ^ - ^ ^ - - v (&\0r.Ff y,hr Were the concentrations o p n ^ s in the investigative samples similar to the concentrations of the ICS solution? ! ^ Mfr i h h s Did the sample results require quaJifjcation due to interference problems? Yes ( ^ o j Comments: yi»w^ met_l Joe 10141994 1035 FOOT MET IJJ 3 0 0 7 9 4 Duplicate Sample Results Were duplicate sample apalyses performed at the required frequency? CY"esj No Did the duplicate sample.»9tilt;s meet acceptance criteria? (jTes) No : (UAC Comments: fjLu(XJ6uX<lV^At^y^l/0-tnA. JtO/wi-^C^tiL-yUdLLfctJ^ Were preparation and caUbnition blank analyses performed at the required frequency? (Yes) No Were elements reported in the bl^)ks>at levels above the CRDL? Yes Qio) Were elements reported iJHha.bIanks at levels between the IDL and the CRDL? (Yes) No Were negative results with.absolute values greater than the IDL reported in the blanks? (Yes) No If analytes were reported in the blanks, were the same analytes also reported for the associated investigative samples? ^ Yes; No yvuixK^t^ ^ 0{A\yLLC-, Did the sample results rea)UK>qualincation due to the presence of analytes in the associated blank samples? Comments: { I j A y i ^ '^ " ^ 2 ^ ^ ^ ^ H ^ ^ .^40/rvvvn4A>U( 0 ^ Q-LULC^-|AJ2AA- DKt.ljdoC 10141994 1035 Foim MET Ii) 3 0 0 7 9 5 Harding Lawson Associates . •_ _ Engineering and s ; ~ 1? Environmental Services SHEET OF PROJECT. SUBJECT JOB NO. DATE COMPUTED BY CHECKED BY ^ ^ ^ [Dx^/V2Jlut«staL XsiA'AyJji ' ^ X A i x S I ^ ^QC ^ CU/JipOL i . j ) ^ r ^ Z M U U C QJJLJUKSI^ ^ e & i ^ P30OO2- (Ib&W/Ktaru <3^% i C^jXtvJt* MfVU L-A>UiijuiAvw (jirshjoyvuMM^ jA,>evL \V\oyiYvMLa\s/^ <r2xCRPL (2.2) <3^re ^3^% ^3^ro ^ ^ . I Id 34-7 r. ZLp-^ld to.^ lo yyvdu A ^ \ 500\ZC '^JtAMJlJUiti^^ ^±CRPL l-lyu^Ji YJry^ J A M ^ > ^ ^ >nUvv r^:l-«<^ j\riJlAJueyy cvo, J I M ^ JbLa^— 5 ^ ^ ^ ^ CXOl^- iMfW 300796 ICP Serial Dilution Were serial dilution analvsesfierformed at the required fr^uency? Cyesj No For analytes with concentrations greater than 50 times the IDL, were the percent differences within acceptance criteria? ^ - > . (j'es) No Comments: IW^ GFAA QC Were duplicate injections peiformed for each GFAA sample analysis? ( Y ^ No For results greater than theCWDL were the percent RSD results calculated correcdy and within control limits? (YeO No NA Were the GFAA analytical spike ^pest-digestion spike) recoveries within acceptance criteria? Yes (^o) If the GFAA analytical spike recoveries were not acceptable, were samples diluted and reanalyzed when required? ^—^^ (Y^ ^° Was tiie method of stand^xl-afMitions (MSA) used for GFAA analysis when required? Yes ) No ("H^A^^^-oJ^v^) When MSA analyses were performed, weretha correlation coefficients and spiking levels acceptable? Yes No Q^J^ Comments: Y b ^ - d-ZifUyd^J^-r^ A - ^ J y j L yyXJit^V^tAK^,^^ JyjC<JiJ^&^ : M ^ ^ ^ - l l ^ % OvdAA-C J S y / u : k .yi(tn- yjL^>^yuiJL.^ C>&-mY«-u/^^-X<^ . K j ^ / f i / v " ^ yoyt^-yiiL ^ / \ -.^TL AA^^^o/wvtrwcA ^ QA4^/Kj^<:^y jlyy\XiMSj^>yf^ >i J ^ o J ^ f A^^i£^y\Xju^AY^ U v u i [Det_l,doc 10141994 1035 8 ^ ° ^ *^^ ^-^ 3 0 0 7 9 7 Harding Lawson Associates • - . _- J Engineering and ' " ; = 1 1 Environmental Services SHEET OF PROJECT. SUBJECT 4kK.ft/vw/ CJLf/rtyyiGttJ^ (jdr^V^^ifiUuy [ ( t A i i ^ : t u ^ :>ifiJlul^JA^^^ • V30OOZ-. p^nm PZOOZO P^HZl £10005' P1000 I O l Z t Z ^ (IZOOO\ CVloVL^ CZZZZi\ZLf J^ul^yvCiLKKyyvy.^ CLvtTfeuVvv^-i^wiA, ^>JUxWuLct/rfc^ (yL^AAJtAvW-VVtA/ 6tvCAXVKy*-»A4^ ( 0 o^ypAyv 133.0 130-1 12^.0 S\.D y ? 40-1 \zz-z. 124 5" 4t).^ <?4.^ JOB NO. DATE 3M/35: COMPUTED BYC CHECKED BY jduM^ slur nrr 'thi'tc f 300798 fuJh Harding Lawson Associates • - . _ - J Engineering and : s : =r 11 Environmental Services SHEET OF PROJECT I U J L L . . ^ P i^L.^j^tjoJ} Cxyv^/JLMJLX SUBJECT plix\+ 5oo I IS 5001^0 5ooiie Ce'^v^yfrUAwf % ^ 5"5.3 6M 4^.5' 7^-/ S3.^ S2.^ ^1.4- ^3.7 JOB NO. DATE ^/W^r COMPUTED BY CHECKED BY 7^h'>, klAAJMy^ V 300799 ICP Interelement Correction Factors Were annual interelement correction factors provided for each instrument used for sample analysis and were they current? fYes j No Comments: yu^ ICP Linear Ranges Were linear ranges providoLfor each instrument used for sample analysis and were they current? (Yes) No f Was a quarterly linear range>^rification analysis performed and if so, were the results acceptable? (Y£) No For the low concentration method was a linear range standard analysis performed as required, and if so, were the results acceptable? ^—^ Yes No ( N A ) Conunents: ^ & v a Log Books Were all sample preparations-m-operly documented and performed in accordance with method protocols? (Yes") No Were all sample analyses jweperly documented and performed in accordance with metiiod protocols? (Ves^ No Comments: vW^ mct_laloc 10141994 1035 Q Form MET 1^ 300800 Sample Results Were target analytes reporte44n the investigative samples? (Yes) No Were the quantitated resitifs-lqr target analytes calculated and reported correctiy? (Yes) No NA For the applicable methods, were peak integrations performed correctiy? Yes No ( N A ) Were detection limits provjd^ for tiie reported target analytes. and if so, were tiiey current and acceptable? (Yes) No Comments: tUn^ met Ixloc I014I994 1035 10 Fonn MET 1.0 300801 HOLDING TIME QUALIFICATION SUMMARY FORM u> o o 00 o Sample Identification E\ zoz-z E\ oooS P2.00Z0 P 2 . l ^ ^ l s o 011 g Soni n ^l^o2:^> VZOOZO PZ\'\Z\ SOOMS £1O6Q5' Analyte Date Siunpled Date Prepared (brJ Pi ffl lied) Date Analyzed c ^ .^R CNJ CM r^M; 1^3 il:|sL CM. CNJ crv] £ ^ crvi /n/^^ /ig/^g' /[Cifq^ /i^/^f JlS0^ JJAJ51^ M h^ 11 '\ h^ MJAK. l\shB /\$h^ 4L zA ZlL iL [jMz^ zji. 2J3_ z/3> z/s 2/2,; z/lG Analysis Holding Time ii I±. at nL 14 '. ^^ Qualifier J/MT T / U J r/uy r/ur r/ur j/UJ JIUT r/ur x/ur r/ur T / U X ^ 3 ^^•3 ^ . ^ dJL ^ • • ^ ^.3 (CN (T^^ Comments: OvvJlu;: <5A/_a.XAl£<^A)^ mcJl.tioc /M 10I4I9»4 I03S BLANK SUMMARY FORM (^IL5) Blank ID Analyte Blank Result (units) Action Level Associated Samples Qualifier PBS /A l^MY\Ji/vjwVif>v ^.Bg'm^/l^^, 21 .-7^1 ' i ^ dZZ 02-2-. QAZnzA^L,, vj^ m^ Al/^^A^/-<?— rce c Q.3ZVyl^/i^ 4.ljAg./A l.^hig/Kg PlOOOl, P I I 2 | 4 P 1 ^ 2 2 ' 4 J W I % VZOOZO, DZ\otZL V30OO2 C C g M . 4 ^ ^w^ P3ni^.Eioopr.a2o22- g c B £4*rM/n^ Z f S AAA U^ ZL h^^ dZODD 1 CCB .;4wiA.MVyrv> l>^m^/^ PBS ^ x y ^ ^ y i ^ iietki%/%. ^.^yvt^)^., Comments: CO o o 00 o nict_l.doc 10141994 1035 12 A F O T I M E T I . O BLANK SUMMARY FORM (WATER5) Blank ID Analyte Blank Result (units) Action Level Associated Samples Qualifier Ccg fiA^MO-XL.- J L t z ^ 7.A^/^ RBgQOI, S00)i2, .<?00ll<^. y Emi l ^ J H M ^ AAAy\ O.'Bjuu^iJL ^•U^ylJi^ *DOn\zo. soo\zif J X 3 . a hyryyyjj^KAA^ 4.1 .^/X- ZO.jlUiflJ^ PBU -JjuxJl omj^M. 4gr.u|// gc^ KI /y\A4^JUAV1_ T^r^^^n^lJIy mM^/.l^ QJC^ juJyiYXm I.S' AAA,/A '7.^.AA(^J,Ji ± 1 U) 1 o I ° 1 00 ' o IF" Comments n«t_l.doc 10141994 1035 \23 FcraMETI.O Summary and Conclusions a ^ a h ^ ^ , QA^rf fe JLJ.L i(yy\ AyA^Ayif/i-iAitJsAiy^ YA/^lkyjIl^iL^rHr^ nlu^AA^ ^ . (yiM\^\^C.. 'A/^^^ff.£^E^\Z0ZZ^/e:}0ho5'J ^ d Z l ^ Z ? , <.&OI\<i/c^ytyi7l.SX)m\(^ l/iA^ P l chcL opr.J.E±hI) 11^0^/9,^0.^X1 IdJl^yy^.:^ \/w^ ^ h y u ^ J ^ o A l I ^ v ^ . / J L M D / ^ K A ~ . f/jxyAlAsT (^--JrLL O d niyy\zJL A^/ytytAy. Lm^r^ AA^tL 0/nfvvijH^MKV^j/i?(^vJ^ &n^r>,i /^ ujd^^L^^yJZjue^ f A c ^ J y ^ o M ^ A ^ i y^/>w^Q^^ LiHl/t JL/^4^ \\iyXAd>yLJ\AA^ fryy -rf^. IJ-/f.y^J4.^i?/!{y6^ / f e ^ , y 0 ^ r - Z ^ * ^ . 4 x A A ^ y o J l t . QAJI ywwJL^, ^<L^j^\^A,^AjtCJfYV-t^vJlyA- <r^^fe^i? r^'ti^.^fctv^4v(j/MJ7 AiC JA^tidg^ AA/vwyi^g yecujQtAr ^y».<ui:JL^g .1 pyu^Llfe^. J^K/^.^ ^TiSM/Jy C;fr>\fc>^ S ^ ^ / ^ ' H^fKU^^/^^e^ frt^l^^y^ifF.,/1(?/^.<n^e4.c^ 4 ^1 <^<rwvt z ^ ^ . - j ^ . yii(^^v^yt'i<.9y2^ ^ y\%\\cl^^^ JA^gyTt, d AJJla^(\yj^yyy\. J ^ y ^ y j o^ y OAA nrP HbJA<l/vv^ 3 Q / ^ • Pfoi^ d r . ' ^ t . t i e J VcStA-Hs At>K i c y - y l l / y t . - , t~^cfc ^ ^ t / , - / ] ; . ^ *{ L_nZ£ny\ZisL \tiy\\yrLiA^ /Ltoai£AAj2>4- v/;/''^' .- <»j- e<r'f.' I . ^ . ^ ^ U j ) . (fift^v<^A^xAg>g^ Validator's Signature: C^_^^^,^^ Validator's Initials: fJ y(_ QC Reviewer's Signature: ^ ^ QC Reviewer's Initials P^P/" j.}..\iA:^^JiA \ j Validation Date: 3 J Z Z - \ ^ 5 ' {yuy^ y yyCJ7<^ Review Date: / / ? A J " ^ llKl_l.doc 101419»4 1035 13 Fonn .MET 1.0 300805 _ Harding Lawson Associates CUCCT r»- =^ Engineering and i>Mttl OF = l l Environmental Services JOB NO. PROJECT SUBJECT p r c f r a ^ h y ^ J ^ C ^ A y i l y i U CyffVy^fjtAiM. COMPUTED B Y A J 4 ^ ^ ^ ( A ( P r d r A . U f J U j L ± : : i r r n ^ ' ^ CHECKED B Y _ ^ ^ 0 ^ JjyyJll)3C^jJi ( t C ) j U ^ : p d ^ J O M J I yiO'YyyfJljiiA^j JUaJL ( u ) J ^ 50O(Zo OAUC SOOIZ^*; O / ^ ^ J&^A/t^WcuAvT. O A ^ V v ^ ^ ^ jU>^xiL ^^AA^)JlLgAi^ OA .^u^te, ((^) X Y ^ > ^ U v M j > SOO 12^' V L u x d:^„y|p.^<i:^-dl^(2i:fcLrv- .y^^iJict yJA^uitt^!^ GryXkU^IU J J L L ^5'-)l5'Vo C^ev^fcvcr?. JjLAv*^^ Ot/wCfcivvveivcAx ^ ,A<^2fitvc^^ 300806 1^1 U.S. EPA - CLP EPA SAMPLE NO. 9 C20001 INORGANIC ANALYSIS DATA SHEET b Name: PACE Contract: | j Lab Code: GULF Case No.: HLA SAS No.: SDG No.: 095010 Matrix (soil/water): SOIL Lab Sample ID: VTXOOl Level (low/med): LOW Date Received: 02/01/95 % Solids: 88.9 Concentration Units (ug/L or mg/kg dry weight): MG/KG 1 i 1 l l l l jCAS No. 1 Analyte |Concentration|C| Q jM | 1 I I l l l l 17429-90-5 1 Aluminum | 14700 II* IP 1 17440-36-0 lAntimony | 1.3 1 |W J" |F | 17440-38-2 (Arsenic | 1.5 | ^ 1/ |F | 17440-39-3 (Barium ( 112 II IP 1 17440-41-7 IBerylliuml 0.34 | I |F | 17440-43-9 1 cadmium | 3.0 | I* |P 1 17440-70-2 ICalcium 1 71800 | |* |P | 17440-47-3 1 Chromium | 18.9 | |* |P 1 17440-48-4 ICobalt | 12.4 | | |P | 17440-50-8 ICopper | 50.9 | | |P | 17439-89-6 (Iron j 26300 | j* |P 1 17439-92-1 ILead | 31.2 | | |F | 17439-95-4 |Maqnesium| 7650 1 1 * IP 1 17439-96-5 |Manqanesel 689 j j jP j 17439-97-6 |Mercury | 0.27 1 I ICVj 17440-02-0 (Nickel 1 15.6 1 ( |P 1 17440-09-7 JPotassiuml 2460 | | |P 1 (7782-49-2 | Selenium | 3.1 UB-fN R |F ( (7440-22-4 (Silver ( 1.1 (U( IP ( (7440-23-5 (Sodium 1 416 (B| (P ( (7440-28-0 (Thallium ( 0.61 (U(W J~ (F ( (7440-62-2 (Vanadium ( 65.6 ( |* |P | (7440-66-6 IZinc | 182 | j |P | (57-12-5 (Cyanide | l.l (U( 3" (AS( 1 1 1 l l l l Color Before: BROWN Color After: YELLOW Comments: ROCKS Clarity Before: Clarity After: CLEAR V Reviewed By Date FORM I - IN Texture: COARSE Artifacts: YES ./iLfJTvLl. JA Z7^^5^ 300807 ILM02.0 080005 m b N2uae: PACE Lab Code: GULF Matrix (soil/water): SOIL Level (low/med): LOW % Solids: 83.9 U.S. EPA - CLP 1 INORGANIC ANALYSIS PATA SHEET Contract: Case No.: HLA SAS No.: EPA SAMPLE NO. C22022 SDG No.: 095010 Lab Sample ID: VTX002 Date Received: 02/01/95 Concentration Units (ug/L or mg/kg dry weight): MG/KG 1 1 1 l l l i (CAS No. ( Analyte (Concentration(C| Q (M ( 1 1 1 Mil (7429-90-5 (Aluminum ( 11700 ( (* (P ( (7440-36-0 (Antimony ( 0.33 (U|W 3" |F | 17440-38-2 lArsenic | 0.34 l.B-r IX IF 1 17440-39-3 IBarium | 106 1 J LP 1 17440-41-7 IBerylliuml 0.33 | t |F | 17440-43-9 (Cadmium | 1.9 | |* |P | 17440-70-2 ICalcium 1 12100 1 1 * IP 1 17440-47-3 1 Chromium | 18.8 | |* |P | 17440-48-4 ICobalt | 15.2 | | |P | (7440-50-8 ICopper | 47.8 | | |P | 17439-89-6 (Iron 1 20800 | |* |P | (7439-92-1 (Lead ( 3.9 | | (F | (7439-95-4 (Maqnesium( 6290 ( 1 * |P | 17439-96-5 |Manganese] 291 | | |P | 17439-97-6 [Mercury | 0.14 | | (CV( (7440-02-0 (Nickel ( 12.5 ( ( (P ( (7440-09-7 (Potassium( 1250 II IP 1 17782-49-2 |Selenium | 3.3 (JUfN K IF | (7440-22-4 (Silver | 1.2 (Ui |P ( (7440-23-5 (Sodium ( 965 (B| (P ( (7440-28-0 (Thallium ( 0.64 (U| |F | 17440-62-2 IVanadium | 90.0 | |* |P | (7440-66-6 (Zinc | 45.8 i | |P ( 157-12-5 ICyanide | 1.2 |U| X |AS| 1 t 1 i l l ! Color Before: BROWN Color After: YELLOW Comments: ROCKS Clarity Before: Clarity After: CLEAR Texture: MEDIUM Artifacts: YES I T ^ l ^ ^ ^ FORM I - IN 300808 ILM02.0 030006 U.S. EPA - CLP EPA SAMPLE NO. C22426 INORGANIC ANALYSIS DATA SHEET b Name: PACE Contract: | l Lab Code: GULF Case No.: HLA SAS No.: SDG No.: 095010 Matrix (soil/water): SOIL Lab Sample ID: VTX003 Level (low/med): LOW Date Received: 02/01/95 % Solids: 86.0 Concentration Units (ug/L or mg/kg dry weight): MG/KG 1 1 ICAS No. 1 1 1 17429-90-5 1 17440-36-0 1 17440-38-2 1 17440-39-3 17440-41-7 17440-43-9 17440-70-2 17440-47-3 17440-48-4 17440-50-8 17439-89-6 17439-92-1 17439-95-4 17439-96-5 17439-97-6 17440-02-0 17440-09-7 17782-49-2 17440-22-4 17440-23-5 17440-28-0 17440-62-2 17440-66-6 157-12-5 1 1 Analyte 1 1 Aluminum 1 Antimony Arsenic Barium Beryllium Cadmium Calcium Chromiiim Cobalt Copper Iron Lead Magnesium Manganese Mercury Nickel Potassium Selenium Silver 1 Sodium Thallium IVanadium [ Zinc 1 Cyanide Concentration 9980 0.33 0.91 67.8 0.36 2.0 5680 18.6 12.6 47.1 24500 3.2 5110 354 0.12 14.1 1040 1 0.33 1 1.2 1 586 1 0.63 1 131 1 50.9 1 1.1 1 C| 1 1 Q 1 1 1* 1 U|W LBT r 1 U 1 1 1 1 1* 1* * * • * |U IB Ur'NW R IU IB |U W X 1 * |U r M 1 P 1 F 1 F 1 P 1 F 1 P 1 P 1 P 1 P 1 P 1 P 1 F 1 P 1 P 1 CV| P 1 |P 1 |F 1 |P 1 |P 1 |F 1 |P 1 |P 1 (AS( 1 1 Color Before: BROWN Color After: YELLOW Comments: ROCKS Clarity Before: Clarity After: CLEAR Reviewed By Date Texture: COARSE Artifacts: YES VAU DATED . FORM I - IN 3 0 0 8 0 9 ILM02.0 080007 • ^ Name: PACE Lab Code: GULF Matrix (soil/water): SOIL Level (low/med): LOW % Solids: 90.9 U.S. EPA - CLP 1 INORGANIC ANALYSIS DATA SHEET Contract: Case No.: HLA SAS No.: EPA SAMPLE NO. DlOOOl SDG No.: 095010 Lab Sample ID: VSI002 Date Received: 01/27/95 Concentration Units (ug/L or mg/kg dry weight): MG/KG 1 I 1 l l l l (CAS No. 1 Analyte |Concentration|C| Q |M | 1 1 1 l l l l 17429-90-5 1 Aluminum 1 16100 1 1 * IP 1 17440-36-0 lAntimony | 0.31 |U|W T IF I 17440-38-2 (Arsenic | 1.2 (^ |^ IF | 17440-39-3 IBarium | 132 ( ( IP 1 17440-41-7 IBerylliuml 0.35 | | |F | 17440-43-9 1 Cadmium ( 2.8 ( (* (PI 17440-70-2 ICalcium 1 84500 | |* |P | 17440-47-3 1 Chromium | 19.8 | |* |P | 17440-48-4 1 Cobalti | 16.1 | I |P I 17440-50-8 ICopper 1 45.1 1 1 |P 1 17439-89-6 (Iron | 25400 | |* |P | 17439-92-1 ILead | 6.8 (I |F | 17439-95-4 |Magnesium( 8540 ( |* |P | 17439-96-5 |Manqanese| 976 | | |P | 17439-97-6 [Mercury 1 0.26 | | |CV| (7440-02-0 INickel | 15.6 | | |P | 17440-09-7 [Potassiuml 1940 II IP 1 [7782-49-2 [Selenium | 3.1 UJfN R [F | 17440-22-4 [Silver [ 1.1 [Ul IP] [7440-23-5 [Sodium I 557 [Bl [P [ [7440-28-0 [Thallium 1 0.59 |U|W X |F [ (7440-62-2 [Vanadium [ 99.4 | (* (P ( [7440-66-6 IZinc | 89.5 | ( [P [ [57-12-5 [Cyanide | 1.1 |U| X |AS| 1 1 1 l l l l Color Before: BROWN Color After: YELLOW Comments: ROCKS Clarity Before: Clarity After: CLEAR Reviewed By Date Texture: COARSE Artifacts: YES FORM I - IN 300810 ILM02.0 OSO'008 U.S. EPA - CLP EPA SAMPLE NO. I m D11214 INORGANIC ANALYSIS DATA SHEET b Name: PACE Contract: 1 1 Lab Code: GULF Case No.: HLA SAS No.: SDG No.: 095010 Matrix (soil/water): SOIL Lab Sample ID: VSI003 Level (low/med): LOW Date Received: 01/27/95 % Solids: 82.9 concentration Units (ug/L or mg/kg dry weight): MG/KG CAS No, 7429- 7440- 7440- 7440- 7440- 7440- 7440- 7440- 7440- 7440- 7439- 7439- 7439- 7439- 7439- 7440- 7440- 7782- 7440- 7440- 7440- 7440- 7440- -90- •36- -38- -39- -41- -43- •70- -47- -48- -50- -89- -92- -95- -96- -97- -02- -09- -49- -22- -23- -28- -62- -66- -5 -0 •2 -3 -7 -9 -2 -3 -4 -8 -6 -1 -4 -5 -6 -0 -7 -2 -4 -5 -0 -2 -6 57-12-5 Analyte Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Cyanide Concentration 13400 0.46 0.80 187 0.34 3.5 14700 25.4 23.0 50.4 32700 4.7 7320 2070 0.14 20.9 1250 0.34 1.2 1200 0.65 194 50.3 1.2 l ^ Z Q . 1 B|W 1 1 1* U^NW R yi Bl Ul UJ r M F_ F_ P_ F_ P_ P_ P_ P P P F P P CV P P_ P F P P AS Color Before: BROWN Color After: YELLOW Comments: ROCKS Clarity Before: Clarity After: CLEAR Reviewed By Date Texture: COARSE Artifacts: YES VAIIDATE % ^ ]ArUA( FORM I - IN 300811 ILM02.0 080009 # b Name: PACE Lab Code: GULF Matrix (soil/water): SOIL Level (low/med): LOW % Solids: 87.5 U.S. EPA - CLP 1 INORGANIC ANALYSIS DATA SHEET Contract: Case No.: HLA SAS No.: EPA SAMPLE NO. D12224 SDG No.: 095010 Lab Sample ID: VSI004 Date Received: 01/27/95 Concentration Units (ug/L or mg/kg dry weight): MG/KG 1 1 [CAS No. 1 1 17429-90-5 1 17440-36-0 17440-38-2 17440-39-3 17440-41-7 [7440-43-9 17440-70-2 17440-47-3 (7440-48-4 (7440-50-8 (7439-89-6 [7439-92-1 [7439-95-4 17439-96-5 17439-97-6 [7440-02-0 [7440-09-7 [7782-49-2 [7440-22-4 17440-23-5 [7440-28-0 [7440-62-2 [7440-66-6 (57-12-5 1 Analyte Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium (Zinc Cyanide 1 Concentration 16300 0.45 0.33 121 0.24 3.4 5820 19.9 15.2 50.4 33200 2.9 6700 940 0.11 22.6 1000 0.32 1.2 1120 1 0.62 1 157 1 59.3 1 1.1 1 c\ 1 Q 1* BIW >t r M 1 1 1* 1* 1* 1 1 1 * 1 I* 1 Ul I B[ LjyiNw ^ Ul IBl [Ul 1* 1 1 |U( zr 1 1 1 M 1 1 p 1 F 1 F 1 P 1 F 1 P 1 P 1 P 1 P 1 P 1 P 1 F I P 1 P 1 CV| P 1 P 1 |F [ |P 1 |P 1 |F 1 |P 1 |P 1 |AS| Color Before: BROWN Color After: YELLOW Comments: ROCKS Clarity Before: Clarity After: CLEAR Reviewed By Date FORM I - IN Texture: COARSE Artifacts: YES 'bAk\^^ 300812 ILM02.0 080010 U.S. EPA - CLP EPA SAMPLE NO. ^kib D20020 INORGANIC ANALYSIS DATA SHEET Name: PACE Contract: I | Lab Code: GULF Case No.: HLA SAS No.: SDG No.: 095010 Matrix (soil/water): SOIL Lab Sample ID: VQB003 Level (low/med): LOW Date Received: 01/23/95 % Solids: 80.3 Concentration Units (ug/L or mg/kg dry weight): MG/KG 1 1 [CAS No. 1 1 [7429-90-5 1 17440-36-0 [7440-38-2 [7440-39-3 [7440-41-7 [7440-43-9 [7440-70-2 [7440-47-3 [7440-48-4 [7440-50-8 [7439-89-6 17439-92-1 17439-95-4 [7439-96-5 [7439-97-6 17440-02-0 [7440-09-7 [7782-49-2 [7440-22-4 [7440-23-5 [7440-28-0 [7440-62-2 [7440-66-6 [57-12-5 1 Analyte Aluminum i Antimony Arsenic Barium [ Beryllium( Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Nickel Potassium Selenium [Silver Sodium (Thallium [Vanadium 1 Zinc 1 Cyanide 1 Concentration 18400 0.35 1.5 98.3 0.37 1.9 60600 22.1 18.9 51.7 26700 5.9 7530 842 0.15 18.2 2090 3.5 1.3 558 1 0.67 1 116 I 66.3 1 1.2 1 C| 1 1 Q 1 1 1* U|W LBt r \A 1 1 1* 1* 1* 1 1 1* 1 . 1* 1 1 1 1 i LH1N R lUI IBl |U|W •J- 1 1* 1 1 1U[ zr 1 1 M 1 P 1 F 1 F 1 P 1 F [ P 1 P 1 P 1 P 1 P 1 P 1 F 1 P 1 P 1 CV| P 1 P 1 F I |P 1 |P 1 |F 1 |P 1 |P 1 |AS| 1 1 Color Before: BROWN Color After: YELLOW Comments: ROCKS Clarity Before: Clarity After: CLEAR Reviewed By Date Texture: FINE Artifacts: YES VALIDATED FORM I - IN 300813 ILM02.0 080011 ^^0) Name: PACE Lab Code: GULF Matrix (soil/water): SOIL Level (low/med): LOW % Solids: 88.2 U.S. EPA - CLP 1 INORGANIC ANALYSIS DATA SHEET Contract: Case No.: HLA SAS No.: EPA SAMPLE NO. D21921 SDG No.: 095010 Lab Sample ID: VQB004 Date Received: 01/23/95 Concentration Units (ug/L or mg/kg dry weight): MG/KG 1 1 1 l l l l [CAS No. 1 Analyte |ConcentrationlCl Q IM 1 1 1 i l l l l [7429-90-5 (Aluminum | 10700 j (* |P 1 17440-36-0 (Antimony | 0.48 |B|W cr IF 1 17440-38-2 (Arsenic ( 0.66 [M- M IF 1 17440-39-3 (Barium 1 131 11 IP 1 [7440-41-7 IBerylliuml 0.26 | | |F | [7440-43-9 (Cadmium | 2.6 | |* |P | [7440-70-2 ICalcium | 5700 | |* [P | 17440-47-3 1 Chromium [ 19.9 | |* |P | [7440-48-4 (Cobalt | 16.0 | | |P | [7440-50-8 [Copper 1 47.7 1 1 [P [ [7439-89-6 [Iron I 27400 [ [* |P [ [7439-92-1 ILead 1 4.0 II IF 1 [7439-95-4 [MagnesiumI 5480 | |* [P | [7439-96-5 |Manqanese| 755 1 [ [PI [7439-97-6 [Mercury [ 0.13 | [ |CV| [7440-02-0 (Nickel | 16.7 | | |P [ [7440-09-7 [Potassiuml 985 |B| |P | [7782-49-2 | Selenium | 0.32 IJJtKW R |F | [7440-22-4 (Silver [ 1.2 |U| |P [ [7440-23-5 (Sodium 1 780 |B| [P | [7440-28-0 [Thallium 1 0.61 |U| IF | [7440-62-2 (Vanadium | 141 [ |* jP ( (7440-66-6 (Zinc [ 50.5 [ | [P | [57-12-5 ICyanide ( 1.1 |U| -J" |AS[ 1 1 1 l l l l Color Before: BROWN Color After: YELLOW Comments: ROCKS Clarity Before: Clarity After: CLEAR Texture: MEDIUM Artifacts: YES VALIDATED). i%Mrf Reviewed By •—/ r -ii ».••• D=.e ZZM^ iMh-. FORM I - IN 300814 ILM02.0 uS0012 m b Name: PACE "Lab Code: GULF Matrix (soil/water): SOIL Level (low/med): LOW % Solids: 88.7 U.S. EPA - CLP 1 INORGANIC ANALYSIS DATA SHEET Contract: Case No.: HLA SAS No.: EPA SAMPLE NO. D30002 SDG No.: 095010 Lab Sample ID: VQA002 Date Received: 01/23/95 Concentration Units (ug/L or mg/kg dry weight): MG/KG 1 1 I CAS No. [ 1 1 (7429-90-5 1 (7440-36-0 ( (7440-38-2 1 (7440-39-3 ( (7440-41-7 (7440-43-9 (7440-70-2 (7440-47-3 [7440-48-4 (7440-50-8 17439-89-6 17439-92-1 [7439-95-4 (7439-96-5 (7439-97-6 (7440-02-0 (7440-09-7 [7782-49-2 (7440-22-4 [7440-23-5 (7440-28-0 17440-62-2 (7440-66-6 (57-12-5 1 Analyte i Alviminum | Antimony | Arsenic [ Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium 1 Zinc 1 Cyanide 1 Concentration 12800 0.32 0.67 99.7 0.38 1.7 21900 20.4 15.4 62.2 23600 5.4 6250 589 0.13 20.5 1280 3.2 1.1 497 ( 0.61 1 98.1 1 56.7 1 1.1 1 1 C| 1 .. 1 Q 1 1 1* 1 U|MW ^ f T M 1 1 1* 1* 1* 1 1 1* 1 1* 1 1 1 1 1 1 1 U^N K lUI [Bl |U[W X 1 1* 1 1 |U[ J" 1 1 M 1 P 1 F 1 F 1 P 1 F 1 P 1 P I P 1 P 1 P 1 P 1 F 1 P 1 P 1 CV( P 1 P 1 F 1 |P 1 [P 1 (F 1 [P 1 [P 1 |AS| Color Before: BROWN Color After: YELLOW Comments: ROCKS Clarity Before: Clarity After: CLEAR Texture: MEDIUM Artifacts: YES Reviewed Date ^ o^. Cp^jrj^7>(t^1^ FORM I - IN 300815 ILM02.0 080013 U.S. EPA - CLP EPA SAMPLE NO. m b Name: PACE Lab Code: GULF Matrix (soil/water): SOIL Level (low/med): LOW % Solids: INORGANIC ANALYSIS DATA SHEET Contract: Case No.: HLA SAS No.: 1 D31719 SDG No.: 095010 Lab Sample ID: VQA003 Date Received: 01/23/95 87.8 Concentration Units (ug/L or mg/kg dry weight): MG/KG i 1 1 l l l l |CAS No. 1 Analyte 1ConcentrationlCl Q |M 1 1 1 i l l l l 17429-90-5 1 Aluminum | 9350 | I* IP 1 17440-36-0 lAntimony 1 0.32 |U|W T [F I 17440-38-2 [Arsenic | 0.40 O f \j{ [F | 17440-39-3 I Barium | 140 II |P 1 [7440-41-7 IBerylliuml 0.30 | 1 IF ( 17440-43-9 (Cadmium ( 1.6 1 1* IP 1 17440-70-2 ICalcium 1 4640 | I* [P [ 17440-47-3 1 Chromium | 18.0 I I* |P 1 (7440-48-4 ICobalt 1 12.2 I I |P ( 17440-50-8 (Copper | 39.7 I I |P I [7439-89-6 [Iron | 25000 | I* |P 1 17439-92-1 JLead | 3.9 j 1 [F [ 17439-95-4 [Magnesium( 4340 [ 1 * |P [ (7439-96-5 (Manganesej 1020 [ J |P I [7439-97-6 [Mercury | 0.14 [ I |CV[ [7440-02-0 [Nickel j 14.7 [ [ |P [ [7440-09-7 IPotassiumI 602 IB| |P [ 17782-49-2 [Selenium | 0.32 UtJfNW R [F [ (7440-22-4 [Silver | 1.2 [U| [P ( 17440-23-5 (Sodium ( 610 (B( [P | 17440-28-0 (Thallium ( 0.62 (U[ [F [ [7440-62-2 [Vanadium [ 137 | [* |P 1 [7440-66-6 [Zinc | 56.7 [ | |P [ [57-12-5 (Cyanide [ 1.1 [U| ;r [AS( 1 1 1 l l l l Color Before: BROWN Color After: YELLOW Comments: ROCKS Clarity Before: Clarity After: CLEAR Texture: COARSE Artifacts: YES Reviewed By ^ - ^ T H T P P- W V ^ M T , Date MMS^IZZZ FORM I - IN 300816 ILM02.0 080014 # b Neme: PACE Lab Code: GULF Matrix (soil/water): SOIL Level (low/med): LOW % Solids: 92.9 U.S. EPA - CLP 1 INORGANIC ANALYSIS DATA SHEET Contract: Case No.: HLA SAS No.: EPA SAMPLE NO. E10005 SDG No.: 095010 Lab Sample ID: VQC003 Date Received: 01/23/95 Concentration Units (ug/L or mg/kg dry weight): MG/KG 1 1 1 l l l l (CAS No. 1 Analyte (Concentration 1C| Q IM | 1 II llll 17429-90-5 1 Aluminum 1 16900 1 |* IP 1 17440-36-0 lAntimony 1 0.54 |B1W X IF 1 17440-38-2 lArsenic | 1.7 l.Br U IF 1 (7440-39-3 IBarium | 60.1 1 j IP 1 (7440-41-7 IBerylliuml 0.30 | | [F [ [7440-43-9 [Cadmium | 4.0 | |* [P [ 17440-70-2 ICalcium | 35200 | [* |P ( (7440-47-3 (Chromium | 17.5 | |* |P | 17440-48-4 [Cobalt: 1 16.8 | | |P | [7440-50-8 ICopper | 43.4 [ | [P [ (7439-89-6 [Iron 1 32200 | [* |P | 17439-92-1 ILead [ 89.9 | [ [F ( [7439-95-4 |Maqnesium| 7920 | [* (P | 17439-96-5 |Manganese[ 791 | I |P I [7439-97-6 [Mercury [ 0.11 |U| |CV| [7440-02-0 [Nickel | 16.8 11 |P [ (7440-09-7 [Potassiuml 1470 [ [ |P [ 17782-49-2 |Selenium [ 3.0 UJfN K IF [ [7440-22-4 [Silver 1 1.1 |U| [P 1 17440-23-5 ISodium [ 358 |B| [P [ [7440-28-0 (Thallium [ 0.58 [U( [F [ [7440-62-2 [Vanadium | 88.0 | [* (P [ (7440-66-6 (Zinc [ 555 [ [ |P | [57-12-5 [Cyanide | 1.1 |U| X iAS[ 1 1 1 l l l l Color Before: BROWN Color After: YELLOW Comments: ROCKS Clarity Before: Clarity After: CLEAR Texture: COARSE Artifacts: YES Reviewed By Date FORM I - IN 300817 ILM02.0 080015 HLA DATA QUALITY ASSURANCE REVIEW SUMMARY Metals Analysis Case Number: 95020 Project Number: 29872 10.2 Site: Island Chemical Company Contractor Lab: Pace Environmental Laboratories, Validator: Kirsten Meier QC Reviewer: ^AHA^yTct^ 7<^. ^ ^ y y T y i A St. Rosa, LA Validation Date: 31 March 1995 Review Date: ^ ~ ^ " ? T^ Sample Matrix: water and soil Analytical Method: CLP metals, including Cyanide Sample Designations: RBSO/012495 * (SO0012) SBF3/12-14/012495 (F31214) SBCl/0-1/012795 (ClOOOl) SBD4/0-1/012795 (D40001) SBBl/0-1/013195 (BlOOOl) SBF2/12-15/012495 (F21215) SBF3/18-20/012495 (F31820) SBCl/16-18/012795 (C11618) SBD4/14-16/012795 (D41416) SBBl/6-8/013195 (B16008) SBF2/18-20/012495 (F21820) SBBl/24-26/013195 (B12426) SBCl/18-20/012795 (Cll820) SBD4/20-22/012795 (D42022) SBBlOl/0-1/013195 (BlOlOl) SBF3/0-1/012495 (F30001) RBSO/012795 * (SO0127) SBCl/20-22/012795 (C12022) RBSO/013195 * (BS0013) * = aqueous sample ( ) = Sample ID on Form I Data for the above samples are: [ ] Acceptable for use [x] Acceptable for use as qualified [ ] Unacceptable for use Is action required by the Project Manager? Yes No[x] Comments: The investigative sample were analyzed following the CLP ILM02.0 methods and the data was reviewed in accordance with the Functional Guidelines, February 1994. Calibration requirements for mercury were obtained from the July, 1988 version of the Functional Guidelines. The metals Antimony, Arsenic, Beryllium, Lead, Selenium and Thallium were analyzed by GFAA. Ilict_elec. 11 12291994 0940 300818 Form MET 1.1 , CaK Numlier: 95020 Projea Number: 29872 10.2 Site ID: bbnd Cbemical Company DATA COMPLETENESS CHECKLIST [x] Included, no problems [*] Included, problems [O] Not included [NA] Not applicable Quality Control Summary X Case Narrative * Chain of Custody Forms X Cover Page X Holding Times X Inorganic Analysis Data Sheets * Initial and Continuing Calibration Summary ^x ICP and AA CRDL Check Standard Summary X Linear Range Verification Standard Summaiy * Calibration and Preparation Blank Summaiy X ICP Interference Check Sample Summary * Matrix Spike Summary * Post Digestion Spike Sample Summary * Duplicate Sample Summary * Laboratory Control Sample Sunimaiy x Method of Standard Additions Summary * ICP Serial Dilution Summary X Quarterly Instrument Detection Limits Summaiy X Annual Interelement Correction Factors Summary X Quarterly ICP Linear Range Summary X Sample Preparation Log Summary * Sample Analysis Run Log Summary Sample Raw Data X ICP Raw Data * GFAA Raw Data X Mercury Raw Data X Cyanide Raw Data Comments: None mct_ekc.ll 12291994 0940 2 FotmMETl.l 300819 I Caie Number: 95020 Project Number 29872 10.2 Site ID: Island Chemical Company SPECIHC COMMENTS REGARDDSTG ANALYSES Chain Of Custody Were samples properly preserved and received in good condition? Yes[x] No Were custody transfers correctly and completely documented? Yes[x] No Comments: The submitted Chain of Custody forms were not signed and dated by the lab. No qualification of data. Holding Times Were sample preparations and analyses performed within holding times? Yes[x] No . Comments: None mct_tlec.ll 12291994 0940 3 Fonn MET 1.1 300820 iCaae Number 95020 Project Nunber 29872 10.2 Site ID: bland Cbemical Company Instrument Calibration Were instruments calibrated daily and each time that sample analyses were performed? Yes[x] No Were the instruments calibrated using the minimum required numbers of blanks and standards? Yes[x] No For the GFAA methods was one standard analyzed at the Contract Required Detection Limit (CRDL)? Yes[x] No For the applicable methods did the correlation coefficients meet the minimum requirement of 0.995? Yes[x] No NA For the cyanide analyses was a midrange standard distilled and analyzed? Yes[x] No NA Comments: For the GFAA calibrations the lab chose non-linear correlation, the correlation coefficients were > 0.995 for this type of calibration. No qualification of data. Initial and Continuing Calibration Verification Were the calibration standards and blanks analyzed at the required frequencies? Yes[x] No Were the standard recoveries within QC limits? Yes[x] No Comments: On Form II (page 080028) the cyanide ICV recovery is listed as 55%; that is a typo, the true concentration is 20 ug/l which results in 110% recovery. No qualification of data. metelec.ll 12291994 0940 4 Fonn MET 1.1 300821 Cue Number. 95020 Project Number 29872 10.2 Sits ID: bland Cbemical Company CRDL Standards Were CRDL standards (CRI and CRA) analyzed at the required frequency? Yes[x] No Were the ICP standards (CRI) analyzed at the required levels? Yes[x] No For the low concentration method, were the CRDL results acceptable? Yes No NA[x] Comments: None Matrix Spike Were matrix spike analyses performed at the correct frequency and on a sample matrix representative of the samples in this SDG? Yes No[x] Were field or rinse blanks used for the spike analysis sample? Yes No[x] Were the matrix spike recoveries within acceptance criteria? Yes No[x] Were post-digestion spikes performed when required? Yes[x] No NA Comments: For Mercury the matrix spikes were performed on samples not belonging to this SDG. No further qualification of data. The soil spike recoveries for Cyanide were 58.7%, 71.2%, and 0% recovery. Therefore, detections of Cyanide reported in the investigative soil samples were qualified as estimated (J), while non-detections were rejected (R). roct_elec.ll 12291994 0940 5 Fonn MET l.l 300822 Cue Number 95020 Project Number 29872 10.2 Site ID: bbnd Cbetmod Company The following analytes had soil spike recoveries outside the QC criteria of 75-125% Analyte Antimony Arsenic Cadmium Copper Lead Selenium Vanadium % Recovery 17.9 0 68.4 26.1 62 25 132.3 Qualifier J/R J/R J/UJ J/R J/UJ J./R J/- Therefore, the qualifiers listed in the above table were applied to all of the associated investigative soil samples. The post digestion spike recoveries for Cadmium (63.4%), Copper (75.2%) and Vanadium (71.9%) were low, however qualification under the Functional Guidelines is not necessary. The water spike reoveries for antimony (127.7%) and beiyllium (74%) were outside the acceptance range. Therefore, the detections of antimony and beryllium inthe investigative water samples were qualified as estimated (J). Non-detected beryllium results were qualified as estimated (UJ), while non- detected antimony results are acceptable and not qualified. met_elec.ll 12291994 0940 Fonn MET 1.1 300823 Caae Number 95020 Project Numhcn 29872 10.2 Site ID: bbnd Cbemical Conxparty Laboratory Control Sample Were laboratoiy control sample analyses performed at the required frequency? Yes[x] No Were laboratory control sample recovery results acceptable? Yes No[x] Comments: The aqueous LCS recovery for Potassium was 120.6%, exceeding the limit of 120.0%. Therefore, detections of Potassium in the investigative water samples were qualified as estimated (J). The soil LCS recovery for Cyanide was 11.4 mg/kg, below the limit of 30 mg/kg and represents a recovery of 15.4%. In accordance with the functional guidelines, the soil Cyanide data is unusable and was rejected (R). ICP Interference Check Sample Were ICP interference check samples (ICS) analysed at the required frequency? Yes[x] No Were the ICS recovery criteria met? Yes[x] No Were results greater than the IDL reported for elements not present in the ICS solution? Yes[x] No Were negative results with absolute values greater than the IDL reported for elements not present in the ICS solution? Yes[x] No Were the concentrations of metals in the investigative samples similar to the concentrations of the ICS solution? Yes No[x] Did the sample results require qualification due to interference problems? Yes No[x] Comments: None iDCt_elec.il 12291994 0940 7 ' J W U «J *• "* Fonn MET 1.1 300824 Cue Number: 95020 Project Number 29872 10.2 Sile ID: bbnd Cbemical Company Duplicate Sample Results Were duplicate sample analyses performed at the required frequency? Yes[x] No Did the duplicate sample results meet acceptance criteria? Yes No[x] Comments: The following analytes exceeded the criteria for duplicate analysis: Alumium (22.9% RPD), Cadmium (75.3% RPD), Chromium (29.1% RPD), Copper (39.6% RPD), Iron (63.2% RPD), Lead (145.5% RPD), Nickel (>lxCRDL) and Zinc (55.1% RPD). Therefore, the results for these analytes in the investigative soil samples were qualified as estimated (J). Blank Analyses Were preparation and calibration blank analyses performed at the required frequency? Yes[x] No Were elements reported in the blanks at levels above the CRDL? Yes No[x] Were elements reported in the blanks at levels between the IDL and the CRDL? Yes[x] No Were negative results with absolute values greater than the IDL reported in the blanks? Yes[x] No If analytes were reported in the blanks, were the same analytes also reported for the associated investigative samples? Yes[x] No Did the sample results require qualification due to the presence of analytes in the associated blank samples? Yes[x] No Comments: See table "Blank Summary Form" for blank contamination and qualifiers added. inct_eWc.ll ^ 12291994 0940 8 FormMEri.l 300825 Cue Number: 95020 Project Number 29872 10.2 Site ID: bbmd Chemical Company ICP Serial DUution Were serial dilution analyses performed at the required frequency? Yes[x] No For analytes with concentrations greater than 50 times the IDL, were the percent differences within acceptance criteria? Yes No[x] Comments: The duplicate analysis for Zinc resulted in 11.0% difference, outside the QC criteria of 10%. Therefore, the results for Zinc in the investigative samples were qualified as estimated (J). GFAAQC Were duplicate injections performed for each GFAA sample analysis? Yes[x] No For results greater than the CRDL were the percent RSD results calculated correctly and within control limits? Yes[x] No NA Were the GFAA analytical spike (post-digestion spike) recoveries within acceptance criteria? Yes No[x] If the GFAA analytical spike recoveries were not acceptable, were samples diluted and reanalyzed when required? Yes No[x] Was the method of standard additions (MSA) used for GFAA analysis when required? Yes[x] No When MSA analyses were performed, were the correlation coefficients and spiking levels acceptable? Yes[x] No Comments: For the following analytes the analytical spike recovery exceeded the criteria of 85-115% and the samples were not reanalyzed at a dilution: metelec.ll - - - ~^ 12291994 0940 9 ' FonnMETl.l 300826 Owe Number 95020 Project Nunber: 29872 10.2 Site ID: bbnd Chemical Cotnpai^ Analyte Antimony Arsenic Arsenic Lead Lead Lead Lead Selenium Selenium Selenium Selenium Selenium Selenium Selenium Selenium Selenium Selenium Thallium Thallium Thallium Sample ID SO0127 C11820 D42022 F21820 F31820 ClOOOl B16008 F21820 F31214 F31820 ClOOOl C11618 C11820 D42022 BlOOOl B16008 B12426 S00012 S00127 BS0013 Spike Recovery 81.3 121.5 118.1 84.1 81.2 80.0 81.2 72.5 45.8 79.0 76.2 77.9 84.3 79.3 78.0 53.0 47.3 81.8 81.0 79.3 Qualifier J/UJ J/- J/- J/UJ J/UJ J/UJ J/UJ J/UJ J/UJ J/UJ J/UJ J/UJ J/UJ J/UJ J/UJ J/UJ J/UJ J/UJ J/UJ J/UJ The above listed qualifiers were applied to the appropriate analytes in the associated investigative samples. ii*t_elcc.ll 12291994 0940 10 FormMEri.l 300827 •Caje Number 95020 Project Number 29872 10.2 Sile ID: bbnl Chemical Company ICP Interelement Correction Factors Were annual interelement correction factors provided for each instrument used for sample analysis and were they current? Yes[x] No Comments: None ICP Linear Ranges Were linear ranges provided for each instrument used for sample analysis and were they current? Yes[x] No Was a quarterly linear range verification analysis performed and if so, were the results acceptable? Yes[x] No For the low concentration method was a linear range standard analysis performed as required, and if so, were the results acceptable? Yes No NA[x] Comments: None Log Books Were all sample preparations properly documented and performed in accordance with method protocols? Yes[x] No Were all sample analyses properly documented and performed in accordance with method protocols? Yes No[x] Comments: For the GFAA analyses the date and time when the standards were prepped was not noted on the raw data. No qualification of data. mct_clec.ll 12291994 0940 H Fonn MET 1.1 300828 'Cue Number: 95020 Project Nunber 29872 10.2 Sile ID: bbnd Chemical Company Sample Results Were target analytes reported in the investigative samples? Yes[x] No Were the quantitated results for target analytes calculated and reported correctly? Yes[x] No NA For the applicable methods, were peak measurements performed correctly? Yes No NA[x] Were detection limits provided for the reported target analytes, and if so, were they current and acceptable? Yes[x] No Comments: None metelec.ll ' 12291994 0940 1 2 iFonnMETLl 300829 Que Number: 95020 Project Number: 29872 10.2 Sile ID: bbnd Chemical Company HOLDING TIME QUALIFICATION SUMMARY FORM o o 00 o Sample Identification Analyte . Date Sampled Date Prepared Date Analyzed Analysis Holding Time Qualifier Comments: None mel_ctco.ll 12291994 0940 13 FomiMEr 1.1 Cue Number: 95O20 Project Number: 29872 10.2 Sile ID: bland Chemical Company BLANK SUMMARY FORM Blank ID ICB CCB C C B ICB CCB ICB CCB CCB Prep Blank Water Prep Blank Water Prep Blank Soil Analyte Chronuum Lead Magnesium Selenium Alumium Arsenic Beryllium Copper Beryllium Lead Zinc Blank Result [ug/l] 4.1 1.9 27.8 -1.5 -21.1 2.4 0.1 -19.9 0.804 0.970 2.291 mg/kg Action Level 4.1 mg/kg or 20.5 ug/l 1.9 mg/kg or 9.5 ug/l 27.8 mg/kg or 139 ug/l 1.5 mg/kg or 7.5 ug/l 21.1 mg/kg or 105.5 ug/l 2.4 mg/kg or 12 ug/l O.I mg/kg or 0.5 ug/l 19.9 mg/kg or 99.5 ug/l 4.02 ug/l 4.85 ug/l 11.455 mg/kg Associated Samples all investigative samples all investigative samples all investigative samples all investigative samples all investigative samples all investigative samples all investigative samples all investigative samples all water samples all water samples all soil samples Qualifier U U U U U u u u u u u Comments: ^ Detections of the listed analytes in the investigative sample below the action level were qualified as undetected (U) due to blank contamination. w o o 00 w TOl_eleo.ll 12391994 0940 14 Forni MET l.l ' Cue Number: 95020 Project Number: 29872 10.2 Sile ID: bbuxl Chemical Company Summary and Conclusions The analytical results for the metal analyses are acceptable for use as qualified. The data for Mercury was rejected (R) in accordance with the Functional Guidelines, because the initial calibration was performed with less standards than the method requires. Due to low spike recoveries, the detections of Antimony, Arsenic, Copper, Selenium and Cyanide reported in the investigative samples were qualified as estimated (J), while non-detections were rejected (R). Due to low spike recoveries, the results for Cadmium and Lead in the investigative samples were qualified as estimated (J). Due to high spike recoveries,the detections of Vanadium in the investigative samples were qualified as estimated (J). Detections of Potassium in the investigative samples were qualified as estimated (J), since the LCS recovery exceeded the upper QC limit. The results for Mercury in the soil investigative samples were rejected (R), due to very low recovery of the soil LCS. The soil results for the analytes Alumium, Cadmium, Chromium, Copper, Iron, Lead, Nickel and Zinc were qualified as estimated (J), because the duplicate analysis exceeded the QC criteria. Blank contamination was observed for several analytes and detections in the investigative samples below the action level were qualified as undetected (U). See table "Blank Summary Form" for detailed information. The results for Zinc in the investigative samples were qualified as estimated (J), since the duplicate analysis ecxeeded the QC criteria. The analytical spike recoveries for several analytes did not meet the QC criteria and the results for these analytes were qualified. See table in report for details. Validator's Signature: [i^y-> WvL l U A c X ^ Validator's Initials: 1 / H • Validation Date: 3 - 3 / - - ^ QC Reviewer's Signature: ^^?t<^,y^^ y=>. y y C / y ^ QC Reviewer's Initials: P ^ P P Review Date: i - Q . - f T mct_elcc.ll 12291994 0940 15 Form MET l.l 300832 t^ b Name: PACE Lab Code: GULF Matrix (soil/water): SOIL Level (low/med): LOW % Solids: 81.4 U.S. EPA - CLP 1 INORGANIC ANALYSIS DATA SHEET Contract: Case No.: HIA SAS No.: EPA SAMPLE NO. BlOOOl SDG No.: 095020 Lab Sample ID: WG002 Date Received: 02/03/95 Concentration Units (ug/L or mg/kg dry weight): MG/KG 1 l . l l l l l |CAS No. 1 Analyte |ConcentrationjC| Q jM | 1 1 1 I I I ! 17429-90-5 1 Aluminum | 23300 | | * J |P j 17440-36-0 lAntimony | 0.34 UJIN'R |F | 17440-38-2 lArsenic 1 0.27 L»|NR |F | 17440-39-3 1 Barium | 197 I I IP 1 17440-41-7 1 Beryllium! 0.32 | j |F | 17440-43-9 1 Cadmium | 2.8 j |N*:J |P | 17440-70-2 ICalcium | 17800 | j jP | 17440-47-3 1 Chromium j 19.9 | |* 3 jP j 17440-48-4 ICobalt | 29.6 | | |P j 17440-50-8 ICopper | 54.5 | jN*3 jP | 17439-89-6 |Iron \ 32100 | I* U IP | 17439-92-1 ILead | 3.4 | |NS*:7 |F | 17439-95-4 |Maqnesium| 7260 I I jP 1 17439-96-5 |Manganese| 1860 | | |P | 17439-97-6 |Mercury | 0.29 | | |CV| 17440-02-0 INickel 1 19.2 1 1* a |P | 17440-09-7 IPotassiumI 4180 I I IP 1 17782-49-2 | Selenium ] 0.34 |JB1NWR IF 1 17440-22-4 ISilver | 1.3 |U| |P | 17440-23-5 ISodium | 575 |B| |P | 17440-28-0 (Thallium 1 0.66 jUj |F | 17440-62-2 IVanadium | 109 | JNJ jP j 17440-66-6 IZinc | 72.7 | |E*J |P 1 157-12-5 ICyanide | 1.2 |J»iNR |AS| 1 1 1 l l l l Color Before: BROWN Color After: BROWN Comments: ROCKS Clarity Before: Clarity After: CLEAR Texture: COARSE Artifacts: YES ^ Lo>'^ /ALIDATED • - y jAjs.f<;>VL tUy.(. FORM I - IN 300833 ILM02.0 080005 t ab Name: PACE Lab Code: GULF Matrix (soil/water): SOIL Level (low/med): LOW % Solids: 83.9 U.S. EPA - CLP 1 INORGANIC ANALYSIS DATA SHEET Contract: Case No.: HLA SAS No.: EPA SAMPLE NO. I BlOlOl I SDG No.: 095020 Lab Sample ID: WG004 Date Received: 02/03/95 Concentration Units (ug/L or mg/kg dry weight): MG/KG jCAS No. i Analyte jConcentration!cj Q JM j 17429-90-5 1 Aluminum 1 28200 1 I*J JJ> 1 17440-36-0 lAntimony j 0.33 UJ1NR IF | 17440-38-2 lArsenic | 1.5 tBlN^R IF 1 17440-39-3 IBarium | 268 1 | jp 1 17440-41-7 IBerylliuml 0.58 | | |F | 17440-43-9 1 Cadmium 1 3.1 | |N*a IP | 17440-70-2 ICalcium | 12200 j | jP 1 17440-47-3 1 Chromium I 21.911*.7 |P1 17440-48-4 ICobalt 1 31.7 1 | IP 1 17440-50-8 ICopper 1 58.4 1 IN*"! IP ! 17439-89-6 1 Iron | 37000 1 | * tl IP | 17439-92-1 ILead | 7.1 1 |N*-3 |F 1 17439-95-4 IMaqnesium! 7760 1 | |P 1 17439-96-5 jManqanesel 2100 II |P | 17439-97-6 [Mercury | 0.12 |U| |CV| 17440-02-0 INickel | 24.7 | |*3 |P | 17440-09-7 IPotassiumI 4330 II IP 1 17782-49-2 |Selenium j 3.3 1-^1 N-R |F | 17440-22-4 ISilver 1 L.2 |U| |P | 17440-23-5 ISodium 1 702 1B| |P 1 17440-28-0 IThallium 1 0.64 lUl |F I 17440-62-2 IVanadium | 110 j jN 7 |P | 17440-66-6 IZinc | 3620 1 1E*3 |P 1 157-12-5 ICyanide | 1.2 IITINR 1AS| Color Before: BROWN Color After: BROWN Comments: ROCKS Clarity Before: Clarity After: CLEAR Texture: COARSE Artifacts: YES VALIDATED Revic.vcd By \<7A-yP(yVL k x / ^ Date -?--;^rf^ FORM I - IN 300834 ILM02.0 0S0003 U.S. EPA - CLP EPA SAMPLE NO. « 1 B12426 1 INORGANIC ANALYSIS DATA SHEET Tab Name: PACE Contract: 1 1 Lab Code: GULF Case No.: HLA SAS No.: SDG No.: 095020 Matrix (soil/water): SOIL Lab Sample ID: WG005 Level (low/med): LOW Date Received: 02/03/95 % Solids: 80.7 Concentration Units (ug/L or mg/kg dry weight): MG/KG 1 1 1 l l l l ICAS No. 1 Analyte |ConcentrationlC| Q IM | 1 1 1 l l l l 17429-90-5 1 Aluminum | 17600 | |*7 |P 1 17440-36-0 lAntimony | 0.35 |if1NK IF | 17440-38-2 lArsenic I 0.27 lyjNR |F j 17440-39-3 IBarium 1 87.4 1 1 IP 1 17440-41-7 IBerylliuml 0.36 | | IF | 17440-43-9 1 Cadmium I 3.0 | |N*3 |P I 17440-70-2 ICalcium 1 6550 | | IP 1 17440-47-3 1 Chromium 1 28.2 1 1*J IP 1 17440-48-4 ICobalt | 16.4 | | IP | 17440-50-8 ICopper | 47.3 1 IN*!! |P 1 17439-89-6 1 Iron 1- 33100 | 1 * r; |P 1 17439-92-1 ILead | 2.8 | |N*3 |F | 17439-95-4 |MagnesiumI 7070 | | |P 1 17439-96-5 |Manganese| 545 | | IP | 17439-97-6 1 Mercury | 0.12 |U| |CV1 17440-02-0 INickel | 18.1 1 1 * :7 |P I 17440-09-7 IPotassiumI 1130 |B| IP 1 17782-49-2 | Selenium I 0.35 IJBINWR IF 1 17440-22-4 ISilver 1 1.3 |U| |P | 17440-23-5 ISodium | 1220 IBl IP 1 17440-28-0 IThallium | 0.67 |U1 IF 1 17440-62-2 IVanadium 1 162 | \UT |P 1 17440-66-6 IZinc | 53.6 | IE*J J^P 1 157-12-5 ICyanide 1 1.2 l-t^fNR. 1AS| 1 1 1 l l l l Color Before: BROWN Color After: BROWN Comments: ROCKS Clarity Before: Clarity After: CLEAR Texture: COARSE Artifacts: YES Pevis'.ved By Date . . — ^ VALIDATED l/(y~,K>tyL h/jy. 3-3>l~-lS_ FORM I - IN 300835 ILM02.0 nPnno*:» U.S. EPA - CLP EPA SAMPLE NO. % B16008 INORGANIC ANALYSIS DATA SHEET b Name: PACE Contract: 1 j Lab Code: GULF Case No.: HLA SAS No.: SDG No.: 095020 Matrix (soil/water): SOIL Lab Sample ID: WG003 Level (low/med): LOW Date Received: 02/03/95 % Solids: 72.3 Concentration Units (ug/L or mg/kg dry weight): MG/KG 1 1 1 l l l l |CAS No. 1 Analyte |ConcentrationlC| Q |M | 1 1 1 l l l l 17429-90-5 1 Aluminum 1 26400 1 1*3" |P 1 17440-36-0 lAntimony 1 0.39 I^INR IF 1 17440-38-2 lArsenic | 0.30 UriNK IF 1 17440-39-3 IBarium | 111 I I IP 1 17440-41-7 IBerylliuml 0.35 1 | IF | 17440-43-9 1 Cadmium | 3.8 | |N*J |P 1 17440-70-2 ICalcium | 35400 | | |P | 17440-47-3 1 Chromium | 27.2 | | * 3 IP 1 17440-48-4 ICobalt 1 18.7 1 1 IP | 17440-50-8 ICopper 1 60.2 1 |N*X T 1 P 1 17439-89-6 |Iron | 39500 | 1*3 |P 1 17439-92-1 ILead | 1.8 | INW*!;^ |F | 17439-95-4 |Magnesiuml 10800 | 1 |P 1 17439-96-5 jManganesej 739 | | |P | 17439-97-6 |Mercury | 0.16 | | 1CV| 17440-02-0 INickel 1 18.9 | | * 3 IP 1 17440-09-7 IPotassiumI 2520 1 1 IP 1 17782-49-2 | Selenium | 0.39 lU^NWR |F | 17440-22-4 ISilver | 1.4 1U| IP 1 17440-23-5 1 Sodium | 2140 j | IP | 17440-28-0 l.Thallium 1 0.75 |U| |F 1 17440-62-2 (Vanadium | 165 ( (N3 (P | (7440-66-6 jzinc j 76.3 | |E*3 IP 1 157-12-5 ICyanide | 1.4 |^NT?. |AS| 1 1 1 l l l l Color Before: BROWN Color After: BROWN Comments: ROCKS Clarity Before: Clarity After: CLEAR Texture: COARSE Artifacts: YES VALIDATED Rev:-'.'.'cd By Date, 3 - 3 ^ - f ^ k ^ ' ^ y ^ c FORM I - IN 300836 ; ILM02.0 080008 U.S. EPAX--CLP: 1 ^ A r INORGANIC ANALYSISIDATA SHEET EPA SAMPLE NO. Name: PACE Lab Code: GULF Case No.: HLA Contract: SAS No.: I I BS0013 SDG No.: 095020 Lab Sample ID: WGOOl Date Received: 02/03/95 Matrix (soil/water): WATER Level (low/med): LOW % Solids: 0.0 /[ Concentration Units (ug/L omng/kg dry weight) : UG/L 1 1 1 II II ICAS No. 1 Analyte |Concentration 1c1 Q IM | 1 1 1 l l l l (7429-90-5 (Aluminum ( 54.2 |c/l IP ( 17440-36-0 lAntimony ( 0.28 (UIN (F ( (7440-38-2 (Arsenic [ 0.22 (UI |F | 17440-39-3 IBarium I 1.8 |U1 IPI 17440-41-7 IBerylliuml 0.02 |U|N*:r IF I 17440-43-9 (Cadmium I 0.62 1U| IP 1 17440-70-2 ICalcium 1 - 11.9 |B| IP 1 17440-47-3 (Chromium ( 1.4 (^C IP 1 17440-48-4 (Cobalt 1 1.9 (Uj (P I [7440-50-8 (Copper ( 3.3 1U| (P | 17439-89-6 |Iron | 6.4 1U| |P I (7439-92-1 (Lead ( 0.14 (^IC/ (F ( 17439-95-4 [MagnesiumI 5.2 (Ul IP [ (7439-96-5 (Manganese( 0.52 (Uj |P I [7439-97-6 [Mercury ( 0.20 |U| |CV| [7440-02-0 [Nickel 1 2.6 [Ul [P I [7440-09-7 [Potassixml 105 |UI |P I [7782-49-2 [Selenium [ 0.28 [Ul IF 1 17440-22-4 [Silver [ 1.0 |U| IP I [7440-23-5 [Sodium 1 67.9 |U| |P I [7440-28-0 [Thallium 1 0.54 lUIWJ IF | 17440-62-2 IVanadium | 0.90 1U| |P I [7440-66-6 [Zinc j 2.4 |B| |P [ [57-12-5 ICyanide 1 10.0 |U| |AS| 1 1 1 II I I Color Before: COLORLESS Color After: COLORLESS Conments: Clarity Before: CLEAR Clarity After: CLEAR • Texture: Artifacts: NO VALlDATEp^ ••y LaltJ 3 -Ayj-'IS FORM I - IN 300837 j ILM02.0 0S0009 U.S. EPA - CLP EPA SAMPLE NO. % 1 ClOOOl 1 INORGANIC ANALYSIS DATA SHEET ab Name: PACE Contract: | 1 Lab Code: GULF Case No.: HLA SAS No.: SDG No.: 095020 Matrix (soil/water): SOIL Lab Sample ID: VTF002 Level (low/med): LOW Date Received: 01/3 0/95 % Solids: 81.6 Concentration Units (ug/L or mg/kg dry weight): MG/KG jCAS No. j Analyte jconcentrationjcj Q JM 1 17429-90-5 1 Aluminum [ 22200 1 1*3 [P 1 17440-36-0 lAntimony 1 0.42 1B|N3 1F| 17440-38-2 [Arsenic [ 0.27 I^INPv IF | [7440-39-3 [Barium [ 119 [ J [P 1 i 7440-41-7 IBerylliuml 0.03 \y^HA \F \ 17440-43-9 1 Cadmium 1 3.5 1 [N*:] [P [ 17440-70-2 ICalcium 1 37500 1 | [P [ [7440-47-3 [Chromium [ 22.6 | 1*3 |P 1 17440-48-4 ICobalt | 18.9 1 | IP 1 17440-50-8 [Copper [ 54.8 | IN*3 |P | [7439-89-6 1 Iron 1 31400 1 |*3 [P 1 17439-92-1 ILead [ 0.23 LBlNW* C3 |F [ [7439-95-4 [MagnesiumI 9000 | | IP | 17439-96-5 |Manganese! 812 11 IP | 17439-97-6 [Mercury [ 0.15 | | ICVl 17440-02-0 INickel | 16.2 1 |*3 |P 1 17440-09-7 IPotassiumI 2720 1 | IP 1 17782-49-2 1 Selenium 1 0.34 |^NW R IF [ [7440-22-4 [Silver [ 1.2 [Ul IP | 17440-23-5 ISodium [ 2430 I I |P 1 17440-28-0 IThallium 1 0.66 1U| [F 1 17440-62-2 IVanadium | 112 | IN 3 |P 1 17440-66-6 IZinc | 5790 [ [E*3 |P | [57-12-5 [Cyanide | 1.2 I^NK |AS1 Color Before: BROWN Color After: BROWN Comments: Clarity Before: Clarity After: CLEAR Texture: COARSE Artifacts: NO VALIDATED Rev.c'.ved By l/^Tyfo^ ky^ty Date ^ - 3 { ' 9 y FORM I - IN 300838 ILM02.0 oeooK U.S. EPA - CLP EPA SAMPLE NO. m C11618 INORGANIC ANALYSIS DATA SHEET ab Name: PACE Contract: 1 1 Lab Code: GULF Case No.: HLA SAS No.: SDG No.: 095020 Matrix (soil/water): SOIL Lab Sample ID: VTF003 Level (low/med): LOW Date Received: 01/30/95 % Solids: 87.5 Concentration Units (ug/L or mg/kg dry weight): MG/KG 1 1 1 M i l |CAS No. 1 Analyte (Concentration!C| Q IM | 1 1 1 l l l l 17429-90-5 lAluminum 1 12900 | 1*3 IP 1 17440-36-0 lAntimony | 0.32 IWiNR IF 1 17440-38-2 lArsenic | 0.25 liMNR IF 1 17440-39-3 IBarium | 98.3 | I IP 1 17440-41-7 IBerylliuml 0.02 IXI U IF 1 17440-43-9 1 Cadmium ! 1.5 1 |N*3 |P I 17440-70-2 ICalcium 1 7490 1 1 |P 1 17440-47-3 1 Chromium | 8.8 | | * J IP 1 17440-48-4 ICobalt | 11.0 |B1 IP | 17440-50-8 ICopper 1 27.9 | |N*:j |P 1 17439-89-6 (Iron 1 19700 | 1*3 |P 1 17439-92-1 ILead 1 0.12 l^N* 03 IF 1 17439-95-4 IMagnesiuml 4730 | 1 IP | 17439-96-5 1 Manganese| 672 1 1 |P | 17439-97-6 1 Mercury 1 0.14 1 1 |CV| 17440-02-0 INickel 1 10.4 1 | * 3 J P | 17440-09-7 IPotassiumI 729 |B( [P 1 17782-49-2 I Selenium I 0.32 IJB1NWR |F | [7440-22-4 [Silver I 1.2 [Ul |P 1 [7440-23-5 ISodium | 1210 | 1 IP 1 17440-28-0 IThallium 1 0.62 lUl IF 1 17440-62-2 IVanadium 1 78.9 | IN3 |P I 17440-66-6 IZinc 1 35.1 1 1E*3 |P 1 157-12-5 ICyanide 1 1.1 LiJIN'R |AS| 1 1 1 l l l l Color Before: BROWN Color After: BROWN Comments: ROCKS Clarity Before: Clarity After: CLEAR Texture: COARSE Artifacts: YES Revicv/ed By Date . VALIDATED ^ ^ "^'V- f^ FORM I - IN 300839 ILM02.0 osooii U.S. EPA - CLP EPA SAMPLE NO. % C11820 1 INORGANIC ANALYSIS DATA SHEET | I b Name: PACE Contract: 1 , Lab Code: GULF Case No.: HLA SAS No.: SDG No.: 095020 Matrix (soil/water): SOIL Lab Sample ID: VTF004 Level (low/med): LOW Date Received: 01/3 0/95 % Solids: 82.2 Concentration Units (ug/L or mg/kg dry weight): MG/KG ICAS No. 17429-90-5 17440-36-0 17440-38-2 [7440-39-3 [7440-41-7 [7440-43-9 [7440-70-2 17440-47-3 17440-48-4 17440-50-8 17439-89-6 17439-92-1 17439-95-4 17439-96-5 17439-97-6 [7440-02-0 17440-09-7 17782-49-2 [7440-22-4 [7440-23-5 17440-28-0 17440-62-2 17440-66-6 [57-12-5 1 Analyte Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Cyanide Concentration 12400 0.34 0.27 128 0.15 1.6 6680 11.1 12.1 35.1 21800 0.66 4790 902 0.14 12.9 597 0.34 1.2 1050 0.66 93.1 37.1 c IJ-j ^ 1 ^ B L^n 1 1 IB xr u B |U 1 1 1.2 Ijy 1 Q *3 N K NWR MB N*3 * J N*3 * :i MN*U3 *:i NWR N 3 E*3 [NR M 1 P 1 F 1 F 1 P 1 F 1 P 1 P 1 P 1 P 1 P 1 P 1 F 1 P 1 P 1 cvi P 1 P 1 F 1 P 1 P 1 F 1 P 1 P 1 ASl Color Before: BROWN Color After: BROWN Comments: ROCKS Clarity Before: Clarity After: CLEAR Texture: COARSE Artifacts: YES VALIDATED, Reviewed By l/eA^4^^^ h(U,i Date 3-;^^-?-^ FORM I - IN 300840 ILM02.0 080012 U.S. EPA - CLP EPA SAMPLE NO. # INORGANIC ANALYSIS DATA SHEET 1 1 j C12022 i b Name: PACE Contract: j j Lab Code: GULF Case No.: HLA SAS No.: SDG No.: 095020 Matrix (soil/water): SOIL Lab Sample ID: VTF005 Level (low/med): LOW Date Received: 01/30/95 % Solids: 85.2 Concentration Units (ug/L or mg/kg dry weight): MG/KG 1 1 1 l l l l ICAS No. 1 Analyte |ConcentrationlC| Q IM 1 1 1 1 l l l l 17429-90-5 lAluminum | 20600 | 1*3 |P I 17440-36-0 lAntimony [ 0.33 [jy|NR [F | 17440-38-2 lArsenic I 1.3 l-EHNj^R IF 1 17440-39-3 IBarium [ 101 [ [ |P [ [7440-41-7 IBerylliuml 0.50 [ [ [F | [7440-43-9 (Cadmium | 2.1 [ |N*3 |P I [7440-70-2 [Calcium 1 133000 | [ [P | [7440-47-3 [Chromium 1 30.1 [ |*3 IP [ [7440-48-4 (Cobalt ( 12.5 [ ( (P | [7440-50-8 [Copper | 38.4 ( 1N*3 IP 1 17439-89-6 (Iron | 22400 | 1*3 |P I 17439-92-1 ILead 1 4.5 1 1NS*3 |F 1 [7439-95-4 [MagnesiumI 9290 [ [ |P | [7439-96-5 [Manganese[ 604 [ 1 |P 1 17439-97-6 [Mercury [ 0.28 1 1 ICVI 17440-02-0 INickel | 21.8 | |*:7 |P I 17440-09-7 IPotassiumI 3370 [ [ |P [ [7782-49-2 [Selenium [ 3.3 1«1NR IF 1 17440-22-4 ISilver [ 1.2 |U| |P | 17440-23-5 ISodium | 510 1B| |P 1 [7440-28-0 IThallium 1 0.63 |U| |F | 17440-62-2 IVanadium 1 73.8 | |N:J IP | 17440-66-6 IZinc. | 61.6' [ 1E* 3" |P 1 [57-12-5 [Cyanide [ 1.2 [jy^NR 1 AS 1 1 1 1 l l l l Color Before: BROWN Color After: BROWN Comments: ROCKS Clarity Before: Clarity After: CLEAR Texture: COARSE Artifacts: YES VALIDATED Reviev/ed By \ / y ^ U y ^ ^ fty^'e . Date FORM I - IN 5'3( - f 5 r 300841 ILM02.0 080013 U.S. EPA - CLP EPA SAMPLE NO. tL b Name: PACE Lab Code: GULF INORGANIC ANALYSIS DATA SHEET Contract: Case No.: HLA SAS No.: 1 D40001 I SDG No.: 095020 Matrix (soil/water): SOIL Level (low/med): LOW % Solids: 70.8 Lab Sample ID: VTF006 Date Received: 01/30/95 Concentration Units (ug/L or mg/kg dry weight): MG/KG jCAS No. j Analyte jconcentrationjcj Q JM j [7429-90-5 lAluminum | 25000 1 | * 3" IP 1 17440-36-0 lAntimony | 0.40 |.U-|NR IF 1 17440-38-2 lArsenic 1 1.1 I^N^R |F [ [7440-39-3 [Barium [ 274 1 | |P 1 17440-41-7 IBerylliuml 0.44 | | IF | 17440-43-9 1 Cadmium I 3.4 1 1N* "3 IP 1 [7440-70-2 ICalcium I 65200 | [ [PI [7440-47-3 [Chromium | 28.1 | |*3- [P 1 [7440-48-4 [Cobalt [ 20.5 [ | JJP | 17440-50-8 ICopper I 57.1 | |N*3 (P | 17439-89-6 | Iron | 37300 I [ * rr |P I [7439-92-1 [Lead [ 3.5 [ |N* 3 |F | 17439-95-4 [MagnesiumI 13900 | 1 IP 1 17439-96-5 IManqanesel 1040 | [ |P 1 17439-97-6 |Mercury | 0.33 [ [ [CVI 17440-02-0 [Nickel 1 17.6 | |*J |P | [7440-09-7 [Potassiuml 1640 | [ |P 1 17782-49-2 1 Selenium [ 4.0 [JBIN R |F [ J7440-22-4 (Silver [ 1.4 |U1 |P | 17440-23-5 ISodium | 1510 j [ |P | [7440-28-0 [Thallium 1 0.76 [Ul IF 1 17440-62-2 [Vanadium [ 155 | [NJ |P 1 17440-66-6 IZinc | 59.0 1 1E*3 IP 1 157-12-5 ICyanide | 1.4 UriNR 1AS| 1 I I l l l l Color Before: BROWN Color After: BROWN Comments: ROCKS Clarity Before: Clarity After: CLEAR Texture: COARSE Artifacts: YES Revic Date FORM I - IN VALIDATED , . •ved By lAA^Ityyi (U<<Ly^ Z~^( - 7 S 300842 ILM02.0 08001 U.S. EPA - CLP EPA SAMPLE NO. I I 1 D41416 I I I INORGANIC ANALYSIS DATA SHEET !ab Name: PACE Contract: Lab Code: GULF Case No.: HLA SAS No.: SDG No.: 095020 Matrix (soil/water): SOIL Lab Sample ID: VTF007 Level (low/med): LOW Date Received: 01/3 0/95 % Solids: 86.1 Concentration Units (ug/L or mg/kg dry weight): MG/KG 1 1 1 l l l l ICAS No. 1 Analyte 1 Concentration]C1 Q IM 1 1 1 1 - II I I 17429-90-5 [Aluminum | 18000 1 1*3 IP 1 [7440-36-0 [Antimony [ 0.33 [JJ-INR |F 1 [7440-38-2 lArsenic I 1.6 |^|N^R |F | [7440-39-3 [Barium [ 44.1 [B[ |P 1 [7440-41-7 IBerylliuml 0.37 | | [F | 17440-43-9 1 Cadmium 1 3.1 | 1N*3 |P 1 [7440-70-2 [Calcium [ 6450 | [ |P [ [7440-47-3 [Chromium 1 24.1 1 |* J IP | 17440-48-4 ICobalt 1 8.1 IBl IP 1 17440-50-8 ICopper ( 39.9 | IN*J |P | 17439-89-6 1 Iron 1 31300 [ 1*3" |P 1 [7439-92-1 [Lead 1 2.0 101 N*7 IF 1 17439-95-4 [Magnesium] 7700 | [ IP 1 17439-96-5 IManqanesel 216 11 |P 1 17439-97-6 |Mercury | 0.14 [ 1 ICVj 17440-02-0 INickel | 11.6 | 1*J |P 1 17440-09-7 IPotassiumI 1190 [ [ [P [ [7782-49-2 | Selenium | 3.3 U»TN/^ [F | 17440-22-4 [Silver [ 1.2 |U| |P [ [7440-23-5 ISodium 1 1660 1 | |P 1 17440-28-0 IThallium 1 0.63 |U| |F | 17440-62-2 IVanadium 1 131 1 |NJ |P 1 [7440-66-6 [Zinc | 51.2 | |E*J |P | 157-12-5 ICyanide 1 1.1 1JJ1NR 1AS| 1 1 1 l l l l Color Before: BROWN Color After: BROWN Comments: ROCKS Clarity Before: Clarity After: CLEAR Texture: COARSE » Artifacts: YES VALIDATED Reviewed By FORM I - IN 300843 ILM02.C 080015 U.S. EPA - CLP EPA SAMPLE NO. « D42022 I INORGANIC ANALYSIS DATA SHEET 1 I b Name: PACE Contract: I | Lab Code: GULF Case No.: HLA SAS No.: SDG No.: 095020 Matrix (soil/water): SOIL Lab Sample ID: VTF008 Level (low/med): LOW Date Received: 01/3 0/95 % Solids: . 85.5 Concentration Units (ug/L or mg/kg dry weight): MG/KG 1 1 1 l l l l |CAS No. 1 Analyte [ConcentrationlC| Q |M | 1 1 1 l l l l 17429-90-5 [Aluminum 1 13000 1 1 * T |P 1 17440-36-0 lAntimony | 0.33 I^NR |F | [7440-38-2 [Arsenic I 0.26 [iMNWR IF 1 [7440-39-3 [Barium | 105 [ [ [P [ 17440-41-7 IBerylliuml 0.24 | I |F | [7440-43-9 [Cadmium [ 2.2 [ |N*3 [P 1 [7440-70-2 [Calcium [ 6350 | 1 IP 1 17440-47-3 (Chromium | 18.9 | |* J |P 1 17440-48-4 ICobalt 1 15.9 11 IP | [7440-50-8 [Copper [ 34.6 [ |N*:r |P 1 17439-89-6 [Iron 1 26800 I I * CT |P I 17439-92-1 ILead | 1.9 1 |N*3 |F 1 17439-95-4 |Magnesium] 5140 | [ [P ] 17439-96-5 |Manganese| 1100 11 |P I 17439-97-6 ]Mercury | 0.28 ] ] ICV] 17440-02-0 INickel 1 17.1 | |* J IP | 17440-09-7 (Potassiuml 919 |B| [P | 17782-49-2 |Selenium | 0.33 IXINWR IF 1 17440-22-4 ISilver 1 1.2 |U1 |P | 17440-23-5 (Sodium | 775 |B| |P | [7440-28-0 IThallium 1 0.63 lUl IF | 17440-62-2 IVanadium ] 126 I [N 3 |P ] 17440-66-6 IZinc ( 43.5 I 1E*^ |P 1 157-12-5 ICyanide | 1.2 m-lNB. IAS] 1 1 1 l l l l Color Before: BROWN Color After: BROWN Conunents: ROCKS Clarity Before: Clarity After: CLEAR Reviev/ed By Date ..I Texture: COARSE Artifacts: YES VALIDATED 3'1>I - ^ S ky/cy^ FORM I - IN 300844 ILM02.0 080016 U.S. EPA - CLP EPA SAMPLE NO. ^^t< ab Name: PACE Lab Code: GULF INORGANIC ANALYSIS DATA SHEET Contract: Case No.: HLA SAS No.: 1 F21215 1 I I SDG No.: 095020 Matrix (soil/water): SOIL Level (low/med): LOW % Solids: 93.1 Lab Sample ID: VSR002 Date Received: 01/27/95 Concentration Units (ug/L or mg/kg dry weight): MG/KG 1 1 1 l l l l ICAS No. 1 Analyte |Concentration!C| Q IM 1 1 1 1 l l l l 17429-90-5 lAluminum | 15500 I 1*3 IP 1 17440-36-0 JAntimony 1 0.30 m'lNR |F 1 [7440-38-2 [Arsenic I 1.7 [.BINi/R [F 1 17440-39-3 IBarium 1 153 1 1 [ P I [7440-41-7 IBerylliuml 0.36 [ [ |F [ [7440-43-9 [Cadmium ] 2.6 | |N*3 |P 1 17440-70-2 ICalcium | 9870 1 1 |P I [7440-47-3 [Chromium | 18.7 | 1*7 |P | 17440-48-4 ICobalt | 16.0 ] 1 |P I 17440-50-8 ICopper ] 52.2 I IN*3 IP ] 17439-89-6 |Iron j 29500 1 1*3 IP | 17439-92-1 ILead | 3.3 | ]N*3 IF ] 17439-95-4 IMagnesiuml 6200 1 1 |P I 17439-96-5 |Manganese] 915 | I IP I 17439-97-6 |Mercury | 0.13 ] ] ICV] 17440-02-0 INickel | 15.4 I I * J |P I 17440-09-7 IPotassiumI 1090 | 1 |P ] 17782-49-2 ] Selenium ] 3.0 IJTINR IF ] 17440-22-4 ISilver 1 1.1 |U] IP 1 17440-23-5 ISodium 1 1140 | | IP | 17440-28-0 IThallium 1 0.58 IU] IF ] 17440-62-2 IVanadium ] 144 | |N J IP | 17440-66-6 IZinc | 48.5 1 |E*7 |P | 157-12-5 ICyanide ] 1.1 IJ^INR |AS| 1 1 1 l l l l Color Before: BROWN Color After: BROWN Comments: ROCKS Clarity Before: Clarity After: CLEAR T^exture: COARSE Artifacts: YES Reviewed By Date .. ..••• VALIDATED Z'l^c^S FORM I - IN 300845 ILM02.0 08001 ^Bra U.S. EPA - CLP EPA SAMPLE NO. 1 INORGANIC ANALYSIS DATA SHEET b Name: PACE Contract: Lab Code: GULF Case No.: HLA SAS No.: Matrix (soil/water): SOIL Level (low/med): LOW % Solids: 86.0 Concentration Units (ug/L or mg/kg dry weight): MG/KG I I I F21820 I I I SDG No.: 095020 Lab Sample ID: VSR003 Date Received: 01/27/95 1 1 ICAS No. 1 1 1 17429-90-5 1 17440-36-0 1 17440-38-2 1 [7440-39-3 1 17440-41-7 1 [7440-43-9 1 [7440-70-2 1 [7440-47-3 (7440-48-4 [7440-50-8 [7439-89-6 [7439-92-1 [7439-95-4 [7439-96-5 [7439-97-6 [7440-02-0 [7440-09-7 [7782-49-2 [7440-22-4 17440-23-5 [7440-28-0 [7440-62-2 [7440-66-6 157-12-5 1 Analyte j Aluminum | Antimony ] Arsenic Barium \ Beryllium] Cadmium | Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Nickel Potassium Selenium ISilver ]Sodium Thallium jVanadium 1 Zinc 1 Cyanide 1 Concentration 18600 0.33 0.26 95.9 0.36 3.5 6480 28.3 17.5 57.3 39500 1.2 7570 646 0.14 19.2 1 1050 [ 0.33 1 1.2 1 1290 1 0.63 1 171 1 58.5 ] 1.2 1 1 1 C| Q 1 1 1 1* 3 J^JINR i Jy-INR 1 1 ]N*3 1 l*J 1 1N*3 1*3 |NW*i;3 1 1 1 l*J Bl l-yiNWR IU] 1 1 |U| ( INJ [ |E*3 I^NR 1 1 M 1 P 1 F 1 F I P 1 F I P 1 P 1 P 1 P 1 P 1 P 1 F 1 P 1 P 1 CV| P 1 P 1 F 1 P 1 P 1 F 1 IP 1 P 1 [AS] 1 1 Color Before: BROWN Color After: BROWN Comments: ROCKS Clarity Before: Clarity After: CLEAR Texture: COARSE Artifacts: YES FORM I - IN Reviewed By Date .. 7" VALi^TED 7>'Z(- f S 300846 ILM02.C 08001 # b Name: PACE Lab Code: GULF U.S. EPA - CLP 1 INORGANIC ANALYSIS DATA SHEET Contract: Case No.: HLA SAS No.: EPA SAMPLE NO. I F30001 1 I SDG No.: 095020 Matrix (soil/water): SOIL Level (low/med): LOW % Solids: 86.9 Lab Sample ID: VSR004 Date Received: 01/27/95 Concentration Units (ug/L or mg/kg dry weight): MG/KG 1 1 1 l l l l |CAS No. 1 Analyte |ConcentrationlCl Q IM 1 1 1 1 I I I ) [7429-90-5 [Aluminum [ 17300 1 1*3 IP 1 17440-36-0 lAntimony | 0.32 iJtTlNR ]F ] 17440-38-2 (Arsenic | 0.25 |>W1NR |F | 17440-39-3 IBarium | 112 11 IP 1 17440-41-7 IBerylliuml 0.21 IB] IF 1 17440-43-9 1 Cadmium | 6.4 ] 1N*J |P | 17440-70-2 ICalcium 1 60000 | ] IP ] 17440-47-3 1 Chromium 1 30.4 1 |* 3 |P 1 [7440-48-4 [Cobalt I 17.6 [ | IP ] [7440-50-8 [Copper | 141 [ |N*3 |P j 17439-89-6 ]Iron ] 63400 I I* J IP I 17439-92-1 ILead ] 3.0 | INS*3 IF ] 17439-95-4 iMagnesium] 7480 1 | |P | 17439-96-5 IManganese] 888 1 1 |P ] 17439-97-6 |Mercury ] 0.27 1 | ICV] [7440-02-0 [Nickel 1 26.9 [ \ * 3 IP 1 17440-09-7 [Potassiuml 2530 | 1 |P | 17782-49-2 ]Selenium ] 0.32 pBtNK |F | 17440-22-4 ISilver 1 1.2 |U1 |P | 17440-23-5 1 Sodium ] 385 IB] IP ] 17440-28-0 IThallium | 0.62 |U| |F 1 17440-62-2 IVanadium | 99.2 1 IN 3 ]P ] 17440-66-6 IZinc ] 479 1 ]E*3 IP ] 157-12-5 ICyanide | 1.1 UMNR |AS| 1 1 1 l l l l Color Before: BROWN Color After: BROWN Comments: ROCKS Clarity Before: Clarity After: CLEAR Texture: COARSE » Artifacts: YES VALIDATED ne\/iijv:ed By I ' a y - i / c ^ kU-tP Date "^-^^-^s FORM I - IN 300847 ILM02.0 080019 % U.S. EPA - CLP EPA SAMPLE NO. 1 INORGANIC ANALYSIS DATA SHEET ] ] b Name: PACE Contract: Lab Code: GULF Case No.: HLA SAS No.: Matrix (soil/water): SOIL Level (low/med): LOW % Solids: 89.1 Concentration Units (ug/L or mg/kg dry weight): MG/KG 1 F31214 1 I I SDG No.: 095020 Lab Sample ID: VSR007 Date Received: 01/27/95 1 1 1 Mil |CAS No. 1 Analyte |Concentration!C] Q IM ] 1 1 1 l l l l [7429-90-5 [Aluminum [ 18800 [ 1*3 IP 1 17440-36-0 lAntimony | 0.31 [.HINR [F [ [7440-38-2 [Arsenic [ 1.2 lBr\UtJtfR |F | [7440-39-3 [Barium [ 177 [ ( IP 1 17440-41-7 IBerylliuml 0.36 | [ [F [ [7440-43-9 [Cadmium [ 3.0 [ [N*3 IP 1 17440-70-2 ICalcium | 25000 | | IP ] [7440-47-3 [Chromium [ 19.6 [ | * 3 [P | 17440-48-4 ICobalt ] 17.8 ] ] |P ] 17440-50-8 ICopper 1 56.1 1 |N*3 IP 1 17439-89-6 |Iron ] 33900 ] 1*3 ]P 1 17439-92-1 ILead 1 3.2 1 IN*3 |F 1 17439-95-4 (Magnesium( 7870 ] ] ]P | 17439-96-5 |Manganese| 1240 | 1 |P 1 17439-97-6 ]Mercury ] 0.11 ]U] ICV] 17440-02-0 INickel 1 17.3 1 1*3 |P 1 17440-09-7 [Potassiuml 1380 1 | IP 1 17782-49-2 | Selenium | 0.31 i;»1NWR |F 1 17440-22-4 ISilver | 1.1 lUl IP 1 17440-23-5 ISodium I 1450 | 1 |P ] 17440-28-0 IThallium ] 0.61 ]U] IF 1 17440-62-2 IVanadium I 172 | INJ |P | 17440-66-6 IZinc | 60.5 | |E*J IP ] 157-12-5 ICyanide | 1.1 UJ1NR 1AS| 1 1 1 l l l l Color Before: BROWN Color After: BROWN Comments: ROCKS Clarity Before: Clarity After: CLEAR Texture: COARSE Artifacts: YES VALIDATED Rev;^'.vcd By Date I DATED . 3-3/ - ^ s FORM I - IN 300848 ILM02.0 08002 U.S. EPA - CLP EPA SAMPLE NO. # F31820 INORGANIC ANALYSIS DATA SHEET | b Name: PACE Contract: j ] Lab Code: GULF Case No.: HLA SAS No.: SDG No.: 095020 Matrix (soil/water): SOIL Lab Sample ID: VSR009 Level (low/med): LOW Date Received: 01/27/95 % Solids: 89.3 Concentration Units (ug/L or mg/kg dry weight): MG/KG |CAS No. 1 7 4 2 9 - 9 0 - 5 1 7 4 4 0 - 3 6 - 0 1 7 4 4 0 - 3 8 - 2 1 7 4 4 0 - 3 9 - 3 1 7 4 4 0 - 4 1 - 7 [ 7 4 4 0 - 4 3 - 9 1 7 4 4 0 - 7 0 - 2 1 7 4 4 0 - 4 7 - 3 [ 7 4 4 0 - 4 8 - 4 ( 7 4 4 0 - 5 0 - 8 ( 7 4 3 9 - 8 9 - 6 [ 7 4 3 9 - 9 2 - 1 ( 7 4 3 9 - 9 5 - 4 1 7 4 3 9 - 9 6 - 5 1 7 4 3 9 - 9 7 - 6 1 7 4 4 0 - 0 2 - 0 [ 7 4 4 0 - 0 9 - 7 [ 7 7 8 2 - 4 9 - 2 [ 7 4 4 0 - 2 2 - 4 [ 7 4 4 0 - 2 3 - 5 [ 7 4 4 0 - 2 8 - 0 1 7 4 4 0 - 6 2 - 2 1 7 4 4 0 - 6 6 - 6 1 5 7 - 1 2 - 5 A n a l y t e Aluminum A n t i m o n y A r s e n i c B a r i u m B e r y l l i u m Cadmium C a l c i u m Chromium C o b a l t C o p p e r I r o n Lead Magnesium M a n g a n e s e M e r c u r y N i c k e l P o t a s s i u m S e l e n i u m S i l v e r - Sodium T h a l l i u m Vanadium Z i n c i C y a n i d e C o n c e n t r a t i o n 14700 0 . 3 1 0 . 2 5 1 |C .l_ 1 UB1 [XT 5 6 . 3 1 0 . 0 5 \y 2 . 9 1 9520 1 2 5 . 3 1 1 2 . 3 1 4 2 . 0 1 31900 1 0 . 2 9 \y 6520 1 385 1 0 . 1 1 |U 1 3 . 6 1 855 0 . 3 1 1.1 7 3 1 0 . 6 0 IB 1^ |U IB |U 151 1 1 5 4 . 6 1 1 1.1 \y A . Q * J NR NR U N * J *3 N * J * 3 NW*i;3 * 3 INWR N 3 E*3 NR M 1 P 1 F 1 F 1 P 1 F 1 P 1 P 1 P 1 P 1 P 1 P 1 F 1 P 1 P 1 CVI P 1 P 1 F 1 P 1 P 1 F 1 P 1 P 1 AS] Color Before: BROWN Color After: BROWN Comments: Clarity Before: Clarity After: CLEAR Texture: COARSE Artifacts: YES Reviewed By Date .-• m VALIDATED 3 - 3 / - f ^ FORM I - IN 300849 ILM02.0 080021 Name: PACE Lab code: GULF Matrix (soil/water): WATER Level (low/med): LCW % Solids: 0.0 U.S. EPA" -- -CLP INORGANIC ANALYSIS DATA SHEET Contract: Case No.: HLA SAS No.: EPA SAMPLE NO. I S00012 I I. SDG No.: 095020 Lab Sample ID: VSROOl Date Received: 01/27/95 Concentration Units (ug/L ornng/kg dry weight): UG/L ^ < # 1 1 1 l l l l ICAS No. 1 Analyte ]Concentration]C] Q jM | 1 1 1 l l l l 17429-90-5 lAluminum ] 25.1 \ y \ u IP 1 17440-36-0 [Antimony [ 1.4 |U|N |F | [7440-38-2 (Arsenic [ 1.1 1U| jF I 17440-39-3 IBarium [ 8.8 IU| |P | [7440-41-7 (Beryllium] 0.10 |U|N*3 IF I 17440-43-9 1 Cadmium | 3.1 |U| IP ] 17440-70-2 ICalcium ] 80.4 IB] jP ] 17440-47-3 1 Chromium I 5.6 \ ^ o |p ] [7440-48-4 ICobalt ] 9.5 IU] |P ] 17440-50-8 ICopper | 16.7 |U| |P | 17439-89-6 I Iron 1 36.1 IB] |P 1 17439-92-1 [Lead 1 0.50 |U| jF ] 17439-95-4 (MagnesiumI 26.0 |U| jP | 17439-96-5 |Manganese[ 2.6 [U] IP ] 17439-97-6 |Mercury | 0.20 lUl ICVI 17440-02-0 INickel 1 13.1 IU] |P ] 17440-09-7 IPotassiumI 526 IU] IP 1 17782-49-2 |Selenium | 1.4 IU] jF | 17440-22-4 ISilver 1 5.1 ]U] |P ] [7440-23-5 (Sodium 1 339 IU] |P ] 17440-28-0 [Thallium 1 2.7 1U]WJ jF | 17440-62-2 IVanadium I 4.5 ]U] |P ] (7440-66-6 tZinc | 7.6 IB] |P ] [57-12-5 (Cyanide j 10.0 ]U| |AS| 1 1 1 l l l l Color Before: COLORLESS Color After: COLORLESS Comments: Clarity Before: CLEAR Clarity After: CLEAR Texture: Artifacts: NO VALIDATED Date ' yy-'T^ Uui hy/(y^ FORM I - IN 300850 ILM02.0 0S0022 Name: PACE Lab Code: GULF U.S. EPA --CLP- 1 • " ^ " INORGANIC ANALYSIS-DATA SHEET Contract: Case No.: HLA SAS No.: EPA SAMPLE NO. S00127 SDG No.: 095020 Matrix (soil/water): WATER Level (low/med): LOW % Solids: 0.0 Lab Sample ID: VTFOOl Date Received: 01/30/95 -m Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. 7429-90-5 7440-36-0 7440-38-2 7440-39-3 7440-41-7 7440-43-9 7440-70-2 7440-47-3 7440-48-4 7440-50-8 7439-89-6 7439-92-1 7439-95-4 7439-96-5 7439-97-6 7440-02-0 7440-09-7 7782-49-2 7440-22-4 7440-23-5 7440-28-0 7440-62-2 7440-66-6 57-12-5 Analyte Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromixam Cobalt Copper Iron Lead Magnesium Manganese Mercury Nickel Potassium Selenium Silver Sodium' Thallium Vanadium Zinc Cyanide Concentration 20.9 1.4 1.1 8.8 0.10 3.1 38.8 4.7 9.5 16.7 32.1 0.50 28.0 2.6 0.20 13.1 526 1.4 5.1 339 2.7 4.5 13.9 10.0 I |C] Q 1 1 1 1 \mnu 1 IUINW3 IU] lUI 1 | U | N * 3 lUI lUl i ^ ^ y (Ul lui lUI IU( lB^L/ |U( (U[ IU] (U( |U( |U( |U( (UIW3 [Ul IBl |U( 1 1 M 1 p 1 F 1 F 1 P 1 F 1 P 1 P 1 P 1 P 1 P P F P P CV P P F P P |F |P |P ]AS l _ olor Before: COLORLESS Dior After: COLORLESS omments: Clarity Before: CLEAR Clarity After: CLEAR Texture: Artifacts: NO FORM I - IN.-- i/tilis rALlPATED ' ^ y - 3 y ^ 3 3 0 0 8 5 1 ILM02.0 080023