Letter regarding Tutu Wells Contamination Litigation with attached analytical package including chain of custody records, volatile data, sample data, standards data, blank data…

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Sub-shelf: EPA SEMS (Superfund, Region 2)
Kind: Government Report
Island: St. John
Date: 1993-07-01
Pages: 516
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NANCY D'ANNA ATTORNEY AT LAW P.O. BOX 37, CRUZ BAY ST. JOHN, U.S. VIRGIN ISLANDS 00831 (809) 776-6533 FAX (809) 776-6260 July 1, 1993 Carolyn Kwan Project Officer, Eastern Division New York/ Caribbean Compliance Section U.S. Environmental Protection Agency Region II 26 Federal Plaza New York, New York 10278 Re: Tutu W e l l s Contamination Litigation Dear Carolyn: Enclosed is the complete analytical package, i n c l u d i n g chain of custody records, volatile data, sample data, standards data, blank data and run logs for ground water samples collected in March 1993. Please feel free to call me s-hould you wish to discuss the enclosed information. Si nee re 1y, Nancy D'Anna, Esq ND/sr Enc 1 . *64529* 64529 0001 ___ _ _ _ _ _ _ _ U j A i v i i \ i vi'ir ~ z i i TECHNOLOGY CORPORATION SERVICES INTERNATIONAL ANALYTICAL CERTIHCATE OF ANALYSIS IT Corporation April 2, 1993 312 Directors Drive Knoxvffle, TN 37923 Attn: Belinda Price Job Number: ITEK 53554 P.O. Number: 409440 This is the Certificate of Analysis for the following samples: Client Project ID: L'Henri Date Received by Lab: 03/08/93 Number of Samples: Seven (7) Sample Type: Water - six (6), Trip Blank - one (1) I. Introduction On 03/08/93, six (6) water samples and one (1) trip blank arrived at the JTAS-Knoxville, Tennessee, laboratory from IT Corporation, Knoxville, Tennessee, in support of the L'Henri project. The list of analytical tests performed, as well as date of receipt and analysis, can be found in the attached report. n. Analytical Results/Methodology The analytical results for this report are presented by analytical test. Each set of data will include sample identification information and the analytical results. Please note that the data are not blank corrected. The samples were analyzed for Target Compound List (TCL) volatiles by gas chromatography/mass spectroscopy (GC/MS) in accordance with the EPA CLP 3/90 Statement of Work. The samples were analyzed for halogenated and aromatic volatile organic compounds by gas chromatography based on EPA methods 601 and 602. Reviewed and Approved: Alyce^R. Moore Laboratory Manager American Council of Independent Laboratories International Association of Environmental Testing laboratories American Association for Laboratory Accreditation |_ O C 0 1 4 3 8 IT Analytical Services, 5815 Mlddlebrook Pike, Knoxville, TN 37921 <*< 189 • ' 0002 IT Corporation IT ANALYTICAL SERVICES April 2 1993 5815MIDDLEBROOKPIKE KNOXVILLE, TN ,Client Project ID: L'Henri Job Number: ITEK 53554 ffl. Quality Control The samples were analyzed for halogenated and aromatic volatile organics by gas chromatography/ photoionization and electrolytic conductivity (Hall) detection in series using an RTX-502.2 column on a Varian 3400 GC. No major problems were encountered. A five point linearity was run for the primary analyses. If the relative standard deviation (RSD) of the response factor (Rf) for each analyte was less than 20%, the response of the analyte was assumed to be linear for that detector, and the average Rf was used for quantification. If the RSD exceeded 20%, a five point quadratic curve was plotted mathematically by the computer and used for quantification. A continuing standard (C mix) was analyzed with every ten samples. This check standard was compared to the original linearity. If the sensitivity for any analyte deviated more than 15%, a detection limit standard (A mix) was run to demonstrate that the analytes could be detected if present; the A mix contained all the analytes at a concentration of 1 ppb (except for the first six eluting compounds which were at 3 ppb). Samples with positive results were rerun if the continuing calibration standard (C mix) analyzed prior to the samples exceeded the 15% criteria. Samples with nondetected analytes were not rerun if the detection limit standard (A mix) was analyzed with detectable peaks. response factors were used for quantification. For the analytes that used a quadratic curve for quantification, the original quadratic curve was used in the continuing standard check calibration. All retention times were updated from the continuing standard check. An A mix was run as a confirmation standard; response factors and analyte retention times were updated on a daily basis. The surrogates that were used in the analysis were bromochloromethane, ortho-chlorofluorobenzene, and fluorobenzene. All of these surrogates were spiked into each matrix at a final concentration of 30 ppb in the sample, but entered into the computer as 100 ppb. This modification allows the results for each surrogate to be reported in percent, not ppb, as the header indicates. Bromochloromethane and ortho- chlorofluorobenzene were reported from the Hall detector. Fluorobenzene was reported from the photoionization detector. The volatiles analyses were performed by purge and trap with a J&W DB-624 megabore column on a Finnigan INCOS GC/MS/DS. The sample analyses went well. Several analyses required dilution for chlorinated ethenes. MW01 had cis-l,2-dichloroethene at 28 ppb. This exceeds the method stated linear limit. Our experience has shown this compound to be linear beyond the method stated limit and, although no dilution was performed, the value was considered reliable. MW02 and MW04 required two dilutions each to quantify chlorinated ethene target compounds. MS/MSD analysis was performed using sample MW030R. All results were within acceptable limits. There were no problems seen in final data review. 0003 IT Coiporation IT ANALYTICAL SERVICES April 2, 1993 5815 MIDDLEBROOK PIKE KNOXVILLE, TN Client Project ID: L'Henri Job Number: ITEK 53554 ffl. Quality Control (continued) Data were reported with qualifiers as follows: U - Compound analyzed for but not detected; value given is quantitation limit. E - Compound exceeded calibration range. D - Compound analyzed at a secondary dilution factor. J - Compound detected but below quantitation limit; value estimated. N - Presumptive evidence of compound presence. B - Compound found in method blank. Y - Indistinguishable isomer in tentatively identified compounds. t-0001440 '-• V>5'*'»>lSr*W.E^<7<rT>3rr-«?:.>;" :--.*$j^$iX'-jiat&i*i* ;---;^^^iMA-^sss}i-!««! ^f^^ir»^-~' -#^-V&-^:-?/'V!-^>. - . f?%gs§^-- •:'.S;!-$ ;ie;?cf," .ii^'Vj'','-•-' • •'' <4; ''•,"-j-ft-vv'-' •',>'*" - 1 _ --i?-.-V;/ >*/' *'3.-<-' .iv .-.*,• .. "••,'•-*• :i'"t>..-AJiA.«- iV:a^>'.v:*J:.-. '.-: -?*•'*-'• f ..-' .v III VOIATILES DATA a. QC SUMMARY ^•:>A^ "v"-.^-- . ;r ^--^v^ •>,:. ••.^:,^«a.,'«.-iix,'.r«i 2A WATER VOLATILE SYSTEM MONITORING COMPOUND RECOVERY ^_,b Name: ITAS-KNOXVILLE_________ Contract: _________ Lab Code: ITSTU Case No.: 53554 SAS No.: _____ SDG No.: MW01 0008 01 02 03 04 05 06 07 08 09 10 11 12 13 14 15 EPA SAMPLE NO. MW01 MW02DL2 MW02 MW02DL MW03FD MW030R MW04 MW04DL2 MW04DL TRIPBLANK VLCS1 MW030RMS MW030RMSD VBLK1 VBLK2 SMC (BFB)# 106 94 108 115 101 92 86 99 99 105 101 105 110 105 98 OTHER 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 TOT OUT 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 SMC (BFB) = Bromofluorobenzene QC LIMITS ( 80-120) # Column to be used to flag recovery values * Values outside of contract required QC limits D System Monitoring Compound diluted out L0001442 FORM II VOA-1 3/90 - 0009 3A WATER LABORATORY CONTROL SAMPLE DUPLICATE RECOVERY Lab Name: ITAS-KNOXVILLE_________ Contract: ________ Lab Code: ITSTU Case No.: 53554 SAS No.: _____ LCS - EPA Sample No.; VLCS1_____ SDG No.: MW01 COMPOUND Vinyl Chloride 1 , 2-Dichloroethane Carbon Tetrachloride 1 , 2-Dichloropropane Trichloroethene 1,1, 2-Trichloroethane _ Benzene cis-1 , 3-Dichloropropene Bromoform Tetrachloroethene 1 , 2-Dibromoethane 1 , 4-Dichlorobenzene ___ SPIKE ADDED (ug/L) 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 SAMPLE CONCENTRATION (ug/L) 0 0 0 0 0 0 0 0 0 0 0 0 LCS CONCENTRATION (ug/L) 4.64 5.97 4.70 4.66 4.54 5.09 4.54 5.44 4.97 4.67 6.83 4.57 LCS % REC # 93 119 94 93 91 102 91 109 99 93 137 91 QC LIMITS REC. 60-140 60-140 60-140 60-140 60-140 60-140 60-140 60-140 60-140 60-140 60-140 60-140 * Values outside of QC limits Spike Recovery: __ out of 10 outside limits COMMENTS: LOC01443 FORM III VOA-1 3/90 0010 3A WATER VOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY Name: ITAS-KNOXVILLE_________ Contract: ________ SAS No.: ______ Lab Code: ITSTU Case No.: 53554 Matrix Spike - EPA Sample No.: MW030R SDG No.: MW01 COMPOUND 1, 1-Dichloroethene Tr ichl oroethene Benzene Toluene Chlorobenzene SPIKE ADDED (ug/L) 5.00 5.00 5.00 5.00 5.00 SAMPLE CONCENTRATION (ug/L) 0 2.900 0 0 0 MS CONCENTRATION (ug/L) 4.580 7.220 3.830 4.470 4.400 MS % REC # 92 86 77 89 88 QC LIMITS REC. 61-145 71-120 76-127 76-125 75-130 COMPOUND 1 , 1-Dichloroethene Trichloroethene Benzene Toluene Chlorobenzene SPIKE ADDED (ug/L) 5.00 5.00 5.00 5.00 5.00 MSD CONCENTRATION (ug/L) 4.670 6.910 3.880 4.170 4.620 MSD % REC # 93 80 78 83 92 % RPD # 1 7 1 7 4 QC L] RPD 14 14 11 13 13 EMITS REC. 61-145 71-120 76-127 76-125 75-130 # Column to be used to flag recovery and RPD values with an asterisk * Values outside of QC limits outside limits out of 10 outside limits RPD: _0 out of Spike Recovery: _ COMMENTS: CLP, 53554 ,MW01,MW03OR,LOW,WATER, W7321,VOA,EPA, I500A:25ML OLV01 PURGE W/ 5PPB IS & SS L0001444 FORM III VOA-1 3/90 4A VOLATILE METHOD BLANK SUMMARY 0011 EPA SAMPLE NO. Name: ITAS-KNOXVILLE________ Contract: Lab Code: ITSTU Case No.: 53554 SAS No.: VBLKl SDG No.: MW01 WB0317 Lab File ID: Date Analyzed: 03/17/93 GC Column: I500A;25ML ID: 0.530fmm) Instrument ID: I500A Lab Sample ID: WB0317 Time Analyzed: 1139 Heated Purge: (Y/N) N_ THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES, MS AND MSD: 01 02 03 04 05 06 07 EPA SAMPLE NO. MW01 MW02 MW02DL MW03FD MW030R MW03ORMS MW030RMSD LAB SAMPLE ID ==========:=:==:= W7325 W7326 W7326 W7324 W7321 W7322 W7323 LAB FILE ID W7325 W7326 W7326D W7324 W7321 W7322 W7323 TIME ANALYZED 1450 1523 1559 1417 1224 1253 1323 COMMENTS: CLP,,,VBLKl,LOW,WATER,WBO317,VOA,BLANK, I500A:25ML OLV01 PURGE W/ 5PPB IS & SS page l of 1 FORM IV VOA LOG'0 1.443 3/90 4A VOLATILE METHOD BLANK SUMMARY 0012 EPA SAMPLE NO. Name: ITAS-KNOXVILLE Lab Code: ITSTU Lab File ID: Date Analyzed: GC Column: DB-624 Instrument ID: Case No.: 53554 WB0318 _____ 03/18/93 Contract: SAS No.: VBLK2 SDG No.: MW01 Lab Sample ID: WB0318 Time Analyzed: 0920 ID: _Q_!_53J)(mm) I500A Heated Purge: (Y/N) N_ THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES, MS AND MSD: 01 02 03 04 05 06 EPA SAMPLE NO. MW02DL2 MW04 MW04DL MW04DL2 TRIPBLANK VLCS1 LAB SAMPLE ID W7326 W7327 W7327 W7327 W7328 LCS0318 LAB FILE ID W7326D2 W7327 W7327D W7327D2 W7328 LCS0318 TIME ANALYZED 1052 1003 1124 1156 1304 1404 COMMENTS: CLP,,,VBLK2,LOW,WATER,WB0318,VOA,BLANK, I500A:25ML OLV01 AMBIENT PURGE W/ 5PPB IS & SS LOO-Q144G FORM IV VOA 3/90 0013 5A VOLATILE ORGANIC INSTRUMENT PERFORMANCE CHECK BROMOFLUOROBENZENE (BFB) Name: ITAS-KNOXVILLE________ Contract: Lab Code: ITSTU Case No.: 53554 SAS No.: SDG No.: MW01 Lab File ID: WBFB0316 Instrument ID: I500A GC Column: DB-624 ID: 0.530(mm) BFB Injection Date: 03/16/93 BFB Injection Time: 1203___ Heated Purge: (Y/N) N_ m/e 50 75 95 96 173 174 175 176 177 ION ABUNDANCE CRITERIA 8.0 - 40.0% Of mass 95 30.0 - 66.0% of mass 95 Base peak, 100% relative abundance 5.0 - 9.0% of mass 95 Less than 2.0% of mass 174 50.0 - 120.0% of mass 95 4.0 - 9.0% of mass 174 93.0 - 101.0% of mass 174 5.0 - 9.0% of mass 176 % RELATIVE ABUNDANCE 27.2 54.3 100.0 7.5 0.0 ( 0.0)1 56.0 4.6 ( 8.3)1 54.4 ( 97.1)1 4.0 ( 7.3)2 1-Value is % mass 174 2-Value is % mass 176 CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS, AND STANDARDS: 01 02 03 04 05 EPA SAMPLE NO. VSTD025 VSTD010 VSTD005 VSTD002 VSTD001 LAB SAMPLE ID WI0316E WI0316D WI0316C WI0316B WI0316A LAB FILE ID WI0316E WI0316D WI0316C WI0316B WI0316A DATE ANALYZED 03/16/93 03/16/93 03/16/93 03/16/93 03/16/93 TIME ANALYZED 1701 1727 1757 1827 1857 FORM V VOA L O G 0 1 4 4 3/90 oou 5A VOLATILE ORGANIC INSTRUMENT PERFORMANCE CHECK BROMOFLUOROBENZENE (BFB) Name: ITAS-KNOXVILLE_________ Contract: Lab Code: ITSTU Case No.: 53554 SAS No.: SDG No.: MW01 Lab File ID: WBFB0317 Instrument ID: I500A GC Column: DB-624 ID: 0.530fmm) BFB Injection Date: 03/17/93 BFB Injection Time: 0934___ Heated Purge: (Y/N) N_ m/e 50 75 95 96 173 174 175 176 177 ION ABUNDANCE CRITERIA 8.0 - 40.0% of mass 95 30.0 - 66.0% of mass 95 Base peak, 100% relative abundance 5.0 - 9.0% of mass 95 Less than 2.0% of mass 174 50.0 - 120.0% of mass 95 4.0 - 9.0% of mass 174 93.0 - 101.0% of mass 174 5.0 - 9.0% of mass 176 % RELATIVE ABUNDANCE 28.2 56.1 100.0 8.1 0.0 ( 0.0)1 55.6 4.3 ( 7.8)1 54.2 ( 97.4)1 3.9 ( 7.2)2 1-Value is % mass 174 2-Value is % mass 176 THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS, AND STANDARDS: 01 02 03 04 05 06 07 08 09 EPA SAMPLE NO. VSTD005 VBLK1 MW030R MW03ORMS MW03ORMSD MW03FD MW01 MW02 MW02DL LAB SAMPLE ID WS0317 WB0317 W7321 W7322 W7323 W7324 W7325 W7326 W7326 LAB FILE ID WS0317 WB0317 W7321 W7322 W7323 W7324 W7325 W7326 W7326D DATE ANALYZED 03/17/93 03/17/93 03/17/93 03/17/93 03/17/93 03/17/93 03/17/93 03/17/93 03/17/93 TIME ANALYZED 1048 1139 1224 1253 1323 1417 1450 1523 1559 FORM V VOA L0001443 3/90 5A VOLATILE ORGANIC INSTRUMENT PERFORMANCE CHECK BROMOFLUOROBENZENE (BFB) 0015 Name: ITAS-KNOXVILLE________ Contract: Lab Code: ITSTU Case No.: 53554 SAS No.: SDG No.: MW01 Lab File ID: WBFB0318 Instrument ID: I500A GC Column: DB-624 ID: 0.530fmm) BFB Injection Date: 03/18/93 BFB Injection Time: 0820 Heated Purge: (Y/N) N_ m/e 50 75 95 96 173 174 175 176 177 ION ABUNDANCE CRITERIA 8.0 - 40.0% of mass 95 30.0 - 66.0% of mass 95 Base peak, 100% relative abundance 5.0 - 9.0% of mass 95 Less than 2.0% of mass 174 50.0 - 120.0% of mass 95 4.0 - 9.0% of mass 174 93.0 - 101.0% of mass 174 5.0 - 9.0% of mass 176 % RELATIVE ABUNDANCE 29.7 56.8 100.0 8.3 0.0 ( 0.0)1 57.4 4.5 ( 7.9)1 55.6 ( 96.8)1 3.9 ( 7.1)2 1-Value is % mass 174 2-Value is % mass 176 THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS, AND STANDARDS: 01 02 03 04 05 06 07 08 EPA SAMPLE NO. VSTD005 VBLK2 MW04 MW02DL2 MW04DL MW04DL2 TRIPBLANK VLCS1 LAB SAMPLE ID WS0318 WB0318 W7327 W7326 W7327 W7327 W7328 LCS0318 LAB FILE ID WS0318 WB0318 W7327 W7326D2 W7327D W7327D2 W7328 LCS0318 DATE ANALYZED 03/18/93 03/18/93 03/18/93 03/18/93 03/18/93 03/18/93 03/18/93 03/18/93 TIME ANALYZED 0829 0920 1003 1052 1124 1156 1304 1404 FORM V VOA L 0001449 3/90 0016 8A VOLATILE INTERNAL STANDARD AREA AND RT SUMMARY Lab Name: ITAS-KNOXVILLE_________ Contract: _________ Lab Code: ITSTU Case No.: 53554 SAS No.: ______ SDG No.: MW01 Lab File ID (Standard): WS0317 Instrument ID: I500A GC Column: DB-624 Date Analyzed: 03/17/93 Time Analyzed: 1048 ID: 0.530rmm) Heated Purge: (Y/N) N_ 01 02 03 04 05 06 07 08 12 HOUR STD UPPER LIMIT LOWER LIMIT EPA SAMPLE NO. MW01 MW02 MW02DL MW03FD MW030R MW030RMS MW03ORMSD VBLK1 ISl(DCB) AREA | 4017 5624 2410 5177 5445 5347 5228 3029 4302 5242 3569 RT * 17.27 17.60 16.94 17.27 17.27 17.33 17.30 17.27 17.30 17.30 17.30 IS2(DFB) AREA # 9856 13798 5914 11736 12192 11555 12529 8587 10133 11110 9262 RT # 6.13 6.46 5.80 6.10 6.13 6.17 6.17 6.10 6.13 6.13 6.17 IS3(CBZ) AREA # 6374 8924 3824 8287 8635 8292 8361 5182 7156 8482 6283 RT # 12.44 12.77 12.11 12.44 12.44 12.47 12.47 12.44 12.47 12.47 12.47 IS3 (DFC) = 1,4-Dichlorobenzene 151 (DFB) - 1,4-Difluorobenzene 152 (CBZ) = Chlorobenzene-d5 AREA UPPER LIMIT = + 40% of internal standard area. AREA LOWER LIMIT = - 40% of internal standard area. RT UPPER LIMIT = +0.33 minutes of internal standard RT. RT LOWER LIMIT = -0.33 minutes of internal standard RT. # Column used to flag values outside QC limits with an asterisk. * Values outside of QC limits. O C O J 4 5 0 FORM VIII VOA 3/9. 0017 8A VOLATILE INTERNAL STANDARD AREA AND RT SUMMARY Lab Name: ITAS-KNOXVILLE________ Contract: _________ Lab Code: ITSTU Case No.: 53554 SAS No.: Lab File ID (Standard): WS0318 Instrument ID: I500A GC Column: DB-624 ID: _QJ_53_0(mm) Heated Purge: (Y/N) N_ _____ SDG No.: MW01 Date Analyzed: 03/18/93 Time Analyzed: 0829___ 01 02 03 04 05 06 07 12 HOUR STD UPPER LIMIT LOWER LIMIT EPA SAMPLE NO. MW02DL2 MW04 MW04DL2 MW04DL TRIPBLANK VLCS1 VBLK2 IS3(DCB) AREA # 5477 7668 3286 4762 3569 5157 4854 4883 5663 4611 RT | 17.27 17.60 17.94ic.tv 17.27 17.27 17.27 17.23 17.30 17.30 17.27 ISl(DFB) AREA # 11210 15694 6726 11523 9668 11063 10855 10114 11078 11089 RT # 6.13 6.46 5". 9 0 5.80 6.13 6.13 6.10 6.07 6.13 6.17 6.10 IS2(CBZ) AREA # 7723 10812 4634 7781 6443 8536 7616 7854 8235 7843 RT # 12.44 12.77 12.11 12.44 12.44 12.44 12.40 12.44 12.47 12.40 IS3 (BCM) = l,4-Dichlorobenzene-d4 151 (DFB) = 1,4-Difluorobenzene 152 (CBZ) = Chlorobenzene-d5 AREA UPPER LIMIT = + 40% of internal standard area. AREA LOWER LIMIT = - 40% of internal standard area. RT UPPER LIMIT = +0.33 minutes of internal standard RT. RT LOWER LIMIT = -0.33 minutes of internal standard RT. # Column used to flag values outside QC limits with an asterisk. * Values outside of QC limits. LOC01451 FORM VIII VOA 3/90 •• :.-'••:>» •-. ^••-^.;// -•''•. "•*/•:' •' CHAIN OF CUSTODV — ———————————— *~>\~tA\.t V>«Wfc**VXA* <=> Project Name/No. 1 L ik^r• fro^O Samples Shipment Date 7 3 A/r/3 •Sample Team Members 2 K, LP/ Lab Destination 8 X7 ^ M Profit Center No. 3 352,1 Prniprt. Mananer D^-liM. Shipment Date 7 3 9 3 , n As 1 /I 1 1 Lab Destination 8 Z7 4* M,af("*fevt Profit Center No. 3.5Z/ Lab Contact 9 3 rL* QAI+r Project Manager" 6 «. 1 1*061. chase Order No 6 R.H m '' I 7 t<>r-l-«t*0> , K*o>i"J/< t< Or,K ri UJCUL ividiiayei Purchase Order No 6 Required Report Date ' Special Instructions: 23 Possible Hazard Identification: 24 Non-hazard Jd[ Flammable J Skin Irritant _J Poison B J Unknown J| Sample Disposal: 25 Return to Client J| Disposal by Lab Archive (mos Turnaround Time Required: 26 Normal fii. RushJl QC Level:27 '.-> "J J Project Specific [specify);___£eJ-- P 1 . Relinquished by (S-gn^/AHaat-on) ^ * Date: Time: 3/9/93 1. Received by 28 lagneture/Attihalionl Date: Time: 2. Relinquished by ISgnature/AHiliaOon) Date: Time 2. Received by (Signature/ Affiliation) Date: Time' 3. Relinquished by (Signature/Affiliation) Date: Time' 3. Received by (Signalure/AHilialion) Date. Time' Comments: 29 UCA3 i INTERNATIONAL TECHNOLOGY CORPORATION ORGANICS ANALYSIS DATA PACKAGE LOC01454 RESPONSIVE TO THE NEEDS OF ENVIRONMENTAL MANAGFMPMT III VOLATILES DATA, continued b. SAMPLE DATA H^^r^^W* •^i^s IX ORGANICS ANALYSIS DATA SHEET 0019 SAMPLE NO. Name: ITAS-KNOXVILLE Contract: SAS No.: MW01 Lab Code: ITSTU Case No.: 53554 Matrix: (soil/water) WATER Sample wt/vol: 25.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ Heated Purge: N GC Column: DB-624 ID: 0.53 fmml Soil Extract Volume: ______ (uL) SDG No.: MW01 Lab Sample ID: W7325 Lab File ID: W7325 Date Received: 03/08/93 Date Analyzed: 03/17/93 Dilution Factor: ____1.0 Soil Aliquot Volume: ___ .(uL) GAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L 74-87-3———————Chloromethane_________ 74-83 -9———————Bromomethane__________ 75-01-4——————Vinyl Chloride________ 75-00-3———————Chloroethane__________ 75-09-2———————Methylene Chloride_____ 67-64-1———————Acetone_______________ 74-97-5———————Bromochloromethane_____ 75-15-0———————Carbon Disulfide______ 75-35-4——————1,1-Dichloroethene____ 75-34-3——————1,1-Dichloroethane____ 540-59-0——————trans-1,2-Dichloroethene 540-59-0——————cis-1,2-Dichloroethene__ 67-66-3———————Chloroform_____________ 107-06-2——————1,2-Dichloroethane_____ 78-93-3———————2-Butanone____________ 71-55-6———————1,1,1-Trichloroethane___ 56-23-5———————Carbon Tetrachloride____ 75-27-4———————Bromodichloromethane____ 78-87-5——————1,2-Dichloropropane____ 10061-01-5————cis-1,3-Dichloropropene__ 79-01-6——————Trichloroethene________ 124-48-1——————Dibromochloromethane____ 79-00-5———————1,1,2-Trichloroethane___ 71-43-2———————Benzene______________ 10061-02-6————trans-1,3-Dichloropropene_ 106-93-4——————1,2-Dibromoethane______ 75-25-2——————Bromoform____________ 108-10-1——————4-Methyl-2-Pentanone____ 591-78-6——————2-Hexanone____________ 127-18-4——————Tetrachloroethene______ 79-34-5——————1,1,2,2-Tetrt chloroethane_ 108-88-3——————Toluene______________ 108-90-7——————Chlorobenzene_______ 1 1 11 l 5 1 1 1 1 1 28 1 1 5 1 1 1 1 1 7 1 1 1 1 1 1 5 5 18 1 1 1 U U U U U U U U U U U E U U U U U U U U U U U U U U U U U U U FORM I X-l LOOOH56 3/90 IX ORGANICS ANALYSIS DATA SHEET Name: ITAS-KNOXVILLE________ Contract: Lab Code: ITSTU Case No.: 53554 SAS No.: Matrix: (soil/water) WATER Sample wt/vol: 25.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ Heated Purge: N GC Column: DB-624___ ID: 0.53(mm) Soil Extract Volume: ______(uL) 0020 SAMPLE NO. MW01 SDG No.: MW01 Lab Sample ID: W7325 Lab File ID: W7325 Date Received: 03/08/93 Date Analyzed: 03/17/93 Dilution Factor: ____1.0 Soil Aliquot Volume: ___ CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L .(uL) 100-41-4 ——— • 100-42-5 ——— - 1330-20-7 —— • 541-73-1 ——— • 106-46-7 ——— - 95-50-1 ———— • 96-12-8 ———— • —— Ethylbenzene o i»y x. ciic —— Xylene (total) —— 1 , 3-Dichlorobenzene —— 1 , 4-Dichlorobenzene —— 1 , 2-Dichlorobenzene —— l,2-Dibromo-3-Chloropropane _ 1 1 1 1 1 1 1 uuuuuuu LC00145' FORM I X-2 3/90 IX ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS 0021 SAMPLE NO. Name: ITAS-KNOXVILLE Lab Code : ITSTU Case No . : 53554 Matrix: (soil/water) WATER Sample wt/vol: 5.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ GC Column: DB-624 ID: 0.53 (mm) Soil Extract Volume: ______ (uL) Contract: SAS No . : MW01 SDG No.: MW01 Lab Sample ID: W7325 Lab File ID: W7325 Date Received: 03/08/93 Date Analyzed: 03/17/93 Dilution Factor: ____1.0 Soil Aliquot Volume: ___ .(uL) Number TICs found: CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L CAS NUMBER 00-000-00 COMPOUND NAME Unknown Hydrocarbon RT 2.67 EST. CONC. 2 Q 7? L O C 0 1 4 5 3 FORM I X-TIC 3/90 CMo DATA FROM FILE: W7325 SCANS 45 TO 726 ACQUIRED: 83/17/93 14:50:00 CALI: UU7325 #3 SAMPLE: CLP, 53554, MW01 , MH81 , LOW, WATER, W7325, UOA, EPA, COHDS.: I500A:25ML OLU81 PURGE W/ 5PPB IS fc SS 180 _ 3:20 208 J 6:40 388 _ 18:80 400 _ 13:20 509 _L 16:40 600 J 20:00 7f I I I CI16 1,4-DIFLUOROBEHZENE (IS#1) CI28 CHLOR06ENZENE-D5 <IS#2> CS16 4-BROMOFLUOROBENZENE (SS) CI26 1,4-DICHLOROBENZENE-D4 J ^ ( 82569.) to *~r •—«O -J Qu.antitation Report File: W7323 0023 Data: W7325. TI 13/17/93 14:50:00 srr.ple: CLP, 53554, MW01, MWO1,LOW, WATER, VV7325, VOA, EPA, -.onds. : I500A:25ML OLV01 PURGE W/ 5PPB IS ?< SS a: 25ML •remitted by: AMBIENT PURGE Instrument: I500A ITEK Analyst: RJL Weight: Acct. No. 0. 000 53554 -•••'OUNT=AREA # REF AMNT/<REF AREA * RESP FACT) "eip. fac. from Library Entry 1,4-DIFLUOROBENZENE <IS#1> CHLOROBENZENE-D5 (IS#2) 1, 4-DICHLOROBENZENE-D4 <IS*3> 4-SROMOFLUOROBENZENE (SS) CHLOROMETHANE ** BROMOMETHANE VINYL CHLORIDE * CHLOROETHANE METHYLENE CHLORIDE ACETONE 2-3UTANONE 4-KE1HYL-2-PENTANONE 2-HEXANONE BROMOCHLOROMETHANE CARBON DISULFIDE 1,1-DICHLOROETHENE * 1.1-DICHLOROETHANE ** TRANS-1,2-DICHLOROETHENE CHLOROFORM * 1.2-DICHLOROETHANE 1,1,1-TRICHLOROETHANE CARSON TETRACHLORIDE BROMODICHLOROMETHANE 1,2-DICHLOROPROPANE * CIS-1,3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE BENZENE TRANS-1, 3-DICHLOROPROPENE DIBROMOETHANE BROMOFORM ** TETRACHLOROETHENE 1, 1,2, 2-TETRACHLOROETHANE ** TOLUENE * CHLOROBENZENE ETHYL BENZENE * STYRENE M/P XYLENE 0-XYLENE CIS-1,2-DICHLOROETHENE 1.3-DICHLORODENZENE 1.4-DICHLOROBENZENE 1,2-DICHLOROBENZENE 1,2-DIBRCMO-3-CHLOROPROPANE • t _ -, "2 3 -15 6 / 8 <? 10 •1 15 13 1 4 IS 16 i / is i 1? 20 21 ?.S 23 2* £5 2* L- "7 jv3 2? 20 31 32 — 4*^ '34 35 J6 ~<7 "8 29 40 41 *»2 43 -S4, 45 Name CI10 CI20 CI26 CS10 C010 C015 C020 C025 C030 C035 C110 C205 C210 C037 C040 CO'!!!- C050 CO53 C060 C065 C115 C12O C130 C140 C143 C150 C155 C160 C165 C172 C176 C1SO C220 C225 C230 C235 C240 C245 C250 C252 cost C252 C253 C254 C261 L 0001460 TJO 1 •n& 34• 6 7 S 9 i W 11 12 13 14 * C. t • * O 1 "T j / :3 l? 20 21 22 23 24 25 £6 27 25 29 30 31 32 33 34 35 36 37 38 39 40 *i 42 43 44 45 m/z 114 117 150 95 50 NOT NOT NOT 84 43 NOT NOT NOT NOT 76 NOT NOT 96 NOT NOT NOT NOT NOT NOT NOT 95 NOT NOT NOT NOT NOT NOT 166 NOT NOT NOT NOT NOT NOT NOT 96 NOT NOT NOT NOT Scan Time Ref RRT Meth 183 6: O6 1 1. OOO A OD 373 12: 26 21. OOO A DV 518 17: 16 3 1. 000 A BB 439 14:38 1 2.399 A BB 38 1: 16 10. 208 A BB FOUND FOUND FOUND 71 2: 22 1 O. 388 A BB 61 2: 02 1 0 333 A BB FOUND FOUND FOUND FOUND 64 2: 08 1 0. 350 A BB FOUND FOUND 78 2: 36 1 0 426 A BB FOUND FOUND FOUND FOUND FOUND FOUND FOUND 20O 6: 40 2 0. 536 A BB FOUND FOUND FOUND FOUND FOUND FOUND 325 10: 50 2 0. 871 A BB FOUND FOUND FOUND FOUND FOUND FOUND FOUND 112 3: 44 1 0. 612 A BB FOUND FOUND FOUND FOUND AreaCHg 11736. 8287. 5177. 6809. 81. 574. 37. 701. 749. 11647. 35013. 24709. Amount XTot 5. OOO UC/L 6. 52 5. OOO UG/L 6. 52 5. 000 UG/L 6. 52 5. 323 UG/L 6. 95 0. 036 UG/L 0. 05 0. 704 UG/L 0. 92 1. 251 UG/L 1. 63 0024 0. 184 UG/L 0. 24 O. 661 UG/L 7. 135 UG/L 0. 86 9. 31 18. 037 UG/L 23. 54 28. 387 UG/L 37. O4 3 Ret<L) 6 12 17 14 1 * 1 1 .•* 08 26 16 38 16 28 18 32 24 Ratio 0. 99 1. 00 1. 00 1. 00 1. 00 0. 99 RRT(L) 1. 000 1. 000 1. 000 2. 386 0. 207 0. 239 0. 212 0. 250 0. 391 Ratio 1. OO 1. 00 1. OO 1. 01 1. 01 0. 99 Arrnt 5. 5. 5. 5. 0. 0. 00 00 00 32 04 70 Amnt(L) 5. 5. 5. 5. 5. 5. 00 00 00 00 00 00 R. Fac R. 1. 000 1. 000 1. 000 0. 580 0. 007 0. 049 Fac(L) Ratio 1. 000 1. 000 1. 000 0. 545 0. 953 0. 348 1. 00 1. 00 1. 00 1. 06 0. 01 0. 14 0 0 0 t 4 29H0001 C80 T 2*:8T if 200 "T 8T -LI frfr Z.96 0 2<7 :9T Ctr 8S6 "O 2C :9T 2f T/.C 0 S O T ' 2 00 S 6C 82 TO T 6O90 00 T irfr -C If SOT T trf :CT 0* 'T 20:CT 6C •T 9*:CT SC 620 'T Sir :2T -1C SOO T OC:2T 9C 98Z. '0 9f :6 SC 602 T 20 "ST trC T9 E \Ll ~l S22 fr 00 'S fO 8T 00 T T £ 8 0 00 T OS OT CC TT8 0 OO :fT 2C 226 '0 8 2 : T T 1C frE8 0 22 :OT DC OTtr 0 9O:S 62 T98 0 2f :OT 82 frT6 '0 22:TT ic Etr 'T S86 0 S O f r ' T G O ' S frl L 00 T 6CS "0 00 T 2f 9 9*i SG^ '0 80 :6 £c trSS '0 9T :L trc 6fr9 '0 trO :8 C2 CSC '0 9* :<? 25 29C '0 OC :<7 T2 2fr8 0 01 :S 02 069 0 frT -*r 61 CT -Q C8fr 0 ^90 0 00 'S 990 T O ' T 1?2-b 0 00 T 9E-2 s: S6fr '0 20 :C ZT 92C "0 OO :2 91 frO -0 fr29 T 090 "0 00 S 81 0 660 E S E O 86 '0 OT 2 S: C99 "0 frO:<7 trl f r T 6 ' 0 2 2 : T T CI ZLL 0 8C :6 2T S29 "0 OS -C IT SO 0 ETO 0 TOO-0 00 'S2 S2 T 66 'O Z.CC "0 86 0 frO -Z 01 QZOO 3/17/93 14:50:39 Acquisition started 0026 3/17/93 14:50:46 ;<iuire Run 0: VV7325 :v/17/93 14:50:00 + 0:00 Free sectors: 13266 3:np le: CLP, 53554, MW01, MWO1, LOWi WATER/ VV7325/ VOA, ERA, 2nds. : I500A:25ML OIV01 PURGE W/ 5PPB IS fc SS rrmula: 25ML AMBIENT PURGE Instrument: I500A -,-bmitted by: ITEK Analyst: RJL Starting Scan: 0 of 720 Weight: Acct. No: C Desc. VI *•»* GC not ready and being equilibrated *»* Elapsed time : 0. 000 53554 0. 0 Min Temp Rate Time (minutes) * (DsgC) (C/min) 35- 35 - 2 35-150 8. 0 3 150-150 - alve A : closed period 6. 6 14. 3 3.0 Valve B total 6. 6 20. 9 23.9 open Injector A : GC oven : Transfer-1ine: Ion source : 150 Deg C 38 Deg C 216 Deg C 181 Deg C «•»* Instrument parameters »**• Post acquisition state -> Filament : Off Multiplier : Off 3C-E: El ( + > Centroid + Temp - Sequence: BF ( 2 time windows. ) Sequence Window ;:an descriptor: >tal scan time: Number of cycles: 2 Filament is OFF Multiplier is ON BF Mass intervals: 2. OOO s 8 Positive ion mode. Master rate: 16 \.°W: 3 MFW: 80 MA: 15 TH: 1 Int # Lo mass Hi mass Time 1 33. 510 300. 590 2. 000 DL: Sequence Window # 5:an descri ptor: "otal scan time: Number of cycles: Filament is ON Multiplier is ON BF Mass intervals: 2 000 s Positive ion mode. Master rate: 16 *H: 3 MFW: 80 MA: 15 TH: 1 Int # Lo mass Hi mass Time 1 33.510 300.590 2.000 BL: Calibration table: D: CAL02199I Interface number 0 Instrument type Q Full scale mass 1177 u Zero scale mass 1 u Intensity/ion 2 Peak width 1000. mmu Offset at low mass 0 mmu Offset at high mass 0 mmu 'Voltage settling time(ms) 20 LOC01463 Current instrument parameters. Positive ion mode 0027 Resolution (high) Resolution <loui) Quad offset Quad programming Lena offset Lena programming Ext offset Ext programming Co 11ec tor Ion offset Ion programming Rod polar i ty 128. 128. 0. 0. -50. 0. 0. 0. 30. 7. 5. 00 00 00 00 00 00 00 00 00 00 00 Negative ion mode 128. 00 128. 00 0. 00 O. 00 50. 00 0. 0. 0. 30. -3. -5. Reverse Electron multiplier voltage Filament emission current Electrometer range Electrometer zero 00 OO 00 00 00 00 Norma1 984. 750. 10 "-7 126. 0 :~*lyzer Fore Pressure . . . :*parator/Source Pressure O. OO9 Torr O. 351 Torr JV 17/93 15: 19: 45 ACQUISITION COMPLETED Scans 1 to 720 Centroid Ientroi d Scans 720 Sees 0. 3 Out of 144O. 0 0. O Peaks per 4596. scan 6. per sec 3. L O C 0 1 4 6 4 QUALITY CONTROL/QUALITY ASSURANCE DATA METHOD: CLP 3'90 OLV01 25ML PURGE 0028 DATAFILE: W7325 STANDARD: WS0317 TUNEFILE: WBFB0317 ANALYSIS TIME: 03/17/93 ANALYSIS TIME: 03/17/93 ANALYSIS TIME: 03/17/93 14: 50 10: 48 9: 34 **»»** INTERNAL STANDARD AREA CHECK *#**»* INTERNAL STANDARD 10 1- 4-DIFLUOROBENZEN 20 CHLOROBENZENE-D5 < 26 1, 4-DICHLOROBENZEN DATA AREA 11736. 8287. 5177. STD AREA 9S56. 6374. 4017. RATIO 1 1 9'/. 1 307. 1297. CLP ACCEPT RATIO 607. - 1407. 607. - 1407. 607. - 1407. STATUS *#**** INTERNAL STANDARD RT CHECK *»#*#* INTERNAL STANDARD •: ! 10 1, 4-DIFLUOROBENZEN C J 20 CHLOROBENZENE-D5 ( •:>26 1, 4-DICHLOROBENZEN DATA SCAN 183 373 518 STD SCAN [ 184 373 518 DIFF :IN SEC: 2 0 0 CLP ACCEPT DIFF STATUS +/- 20 SECS +/- 20 SECS +/- 20 SECS #»##*# SURROGATE RECOVERIES •****#* SURROGATE AMT FOUND AMT ADDED PERCENT RECOVERY RECOV LIMITS STATUS 310 4-DROMOFLUORODENZE 5.3 5.0 ' 15 BRCviOMETHANE -0. 0 50. 0 .20 VINYL CHLORIDE * -0. 0 50. 0 106 0 0 807. - 1207. 887. - 1107. 867. - 1 1 57. failed failed LOOOi-iGj DIAGNOSTIC REPORT PROCEDURE: TCA T-ATA FILE: VV7325 SEKERENCE: V I 1 1 -.•s-ME LIST: VI INITIALIZATION OPTION: 2 REPURT: VI IS PROCESSING OPTION: 3 3/17/93 15:43:15 0029 --—— STANDARDS ———— >< —— PLUS UNKNOWNS —— >< - LIST NAMES - > -*OC USED POSS 3 3 3 2 3 3 45 COMPOUNDS 1 c.' 3 4 5 67 3 •J 10 11 12 13 14 ? 1c? i7 18 1C SO ?1 i.2 - ^i 24 25 2i :.*•— 2S 29 30 31 31 — i "^ 34 '35 "36 37 3S 3? ^0 x'i 42 43 44 45 wurir i LID VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI * VI VI VI VI ENTRY 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 1 1 1 RMS PROC USED POSS RM3 STAND, 0 20 5 1 33 VI IS/1 11 16 5 1 13 V1IS/1 11 15 4 1 67 V1IS/1 PROCESSED, 7 FOUND REF -184 -373 -518 -439 -38 -44 -39 -46 -72 -62 -115 -289 -341 -122 -65 -60 -91 -78 -127 -155 -135 -143 -242 -218 -274 -201 -341 -321 -153 -311 -344 -420 -325 -451 -293 -375 -384 -413 -391 -412 -112 -496 -501 -519 -561 PRED SEL DELTA PEAKS FIT PEAKS 183 183 . 1 981 373 373 . 1 975 5 1 9 . . . . . 439 439 1 950 3 7 . . . . . 4 3 . . . . . 3 8 . . . . . 4 5 . . . . . 71 71 . 1 880 6 1 . . . . . 1 1 4 . . . . . 2 8 9 . . . . . 341 . 1 2 1 . . . . . 6 4 . . . . . 5 9 . . . . . 9 0 . . . . . 7 7 . . . . . 1 2 6 . . . . 154 . 134 142 . 241 2 1 7 . . . . . 2 7 4 . . . . . 200 2OO . 1 975 341 3 2 1 . . . . . 152 . 3 1 1 . . . . . 3 4 4 . . . . 4 2 0 . . . . . 325 325 . 1 953 4 5 2 . . . . 2 9 3 . . . . 3 7 5 . . . . 3 8 4 . . . . 4 1 3 . . . . 3 9 1 . . . . 4 1 2 . . . . Ill 112 1 1 913 4 9 7 . . . . 5 0 2 . . . . . 5 2 0 . . . . . 5 6 2 . . . . . rt/z 114 117 150 95 50 94 62 64 84 43 43 43 43 128 76 96 63 96 83 62 97 117 83 63 75 95 129 97 78 75 107 173 166 83 91 112 91 104 1O6 106 96 146 146 146 75 TOP DELTA PEAKS 183 . 1 373 . 1 518 . 1 439 . 1 38 . 1 71 61 64 78 200 325 112 LO-00146G I. T. ANALYTICAL SERVICES LIBRARY SEARCH REPORT PURGEABLE VOLATILE ORGANICS ANALYSIS 0030 AT A FILE: VV7325 ~A-:aUIRED: 03/17/93 14:50:00 C3NDS.: I500A:25ML OLV01 PURGE W/ 5PPB SUBMITTED BY: ITEK is & ss ANALYST: RJL ACCOUNT NO. 53554 COMPOUND CIIO 1,4-DIFLUOROBENZENE (ISK1) 0120 CHLQROBENZENE-D5 <IS#2> C126 1,4-DICHLOROBENZENE-D4 (IS#3) CS10 4-DROMDFLUORODENZENE (SS) :i50 TRICHLOROETHENE CZ-20 TETRACHLOROETHENE COS4 CIS-1,2-DICHLOROETHENE SCAN DELTA (UG/ML) FIT 183 373 518 439 200 325 112 0 0 -1 0 0 0 1 5. 5. 5. 4. 7. 17. 26. 000 000 000 748 051 910 106 981 975 0 950 975 953 913 SAT'D? 0 0 0 0 O 0 0 10001467 oo 100.0- 50.0-: 0.1- 0.1-: TARGET COMPOUND COMPARISON COMPOUND: C635 ACETONE RAW DATA: UU7325 #61 03/17/93 14:50 SAMPLE: CLP,53554,MW01,MW01,LOW,WATER,VU7325,UOA,EPA, CONDS.: I580A:25ML OLU81 PURGE W/ 5PPB IS Ik SS BASE M/Z: 44 RIC: 12416. • | • i • i • i • i • i • i • i • i • i • | • i • i • i • i • i ENHANCED DATA: UU7325 #61 | • i • i • i BASE M/Z: 43 RIC: I ' ' ' ' '*''' ' ' I ' ' LIBRARY FILE: Ml #10 i • i • I • I . i • BASE M/Z: 43 RIC: 16. 2136. CD CO oo -J - 11928. 16. 8.4- 4 f\ .£.. M/Z 100.0- 50.0-; 0.0-: -50. Q-. 1D0.0- I ' l ' l ' l ' l ' l ' l ' l ' l ' ' I ' l ' T ' T ' l ' l ' l ' l ' l ' l ' l ' l ' l ' l ' l ' l ' I ' l ' l ' l ' l ' l ' l ' l ' l ' l ' l ' ' I ' l ' l ' l ' l ' I ' l ' l ' l ' l ' l ' l ' l ' l 1 ' I ' J ' I ' I ' I ' I ' 10 20 38 48 50 68 • i - i i i i i • . , • . i 1086. TARGET COMPOUND COMPARISON COMPOUND: C150 TRICHLOROETHENE <£> 100.0: 50.0: 94.8: 47.4- 45.8: 22.5: M/Z 100.0: 50.0: 0.8: -50.0: iaa o- KHW UHIH: wrj/j w/tw bHbt we.\ ao ruu: lorro. 03/17/93 14:50 SAMPLE: CLP, 53554, MW01 , MW01 , LOW, WATER, UU7325, UOA, EPA, CONDS.: I500A:25ML OLU81 PURGE W/ 5PPB IS & SS „ 1... 1 , ... ....... 1 . .• . | i . i i .. i . , i i i . | i . i i | . i ENHANCED DATA: UU7325 #260 B^ ... ' ' ' ' ' ' ' I ' LIBRARY , . . . . . . . | . 40 ... 1,,. 1 , . i | . . . . FILE: VI #26 i i . . , . . . 50 60 In. , , • , . , . . . . , I - . . . . . 1 BH , , 1 1 1 . 1 .. 1 .... 1 .... ... 1 6E M/Z: 95 RIC: 14064. .1 4 , i . . . . . . . . . | . . . . 6E M/Z: 95 RIC: 53: i J6 1 . • • . • • • • , . • • • . • 1 ^ r • • • ,-^-. . . . . . . . 30 108 120 ... .... ...... . 1 • i I u_ 148 - , - , CD -J - 2224. - 2108. - 1000. - **oum 2 ° 2 TARGET COMPOUND COMPARISON t- o 100. 0T 50. 0-: 92.2- 46.1: 9.2-: 4.6: M/Z 100.0- 50.0-: 0.0-; -50.0-: COMPOUND: C226 TETRACHLOROETHENE RAW DATA: UU7325 #325 BASE M/Z: 166 RIC: 82560. 03/17/93 14:50 SAMPLE: CLP, 53554, MW01 , MW01 , LOW, WATER, UU7325, UOA, EPA, CONDS.: I500A:25ML OLU01 PURGE W/ 5PPB IS 6< SS . .1 . ,, 1, , ,l . , . .1.1, . 111. . 1 ENHANCED DATA: UU7325 #325 . 1 1 . . 1... 11, 1 i i • | • • i • i • -i • | • i • i • i • i • | • i • LIBRARY FILE: Ul #33 i i • | • 50 .1. . .1 . ,. li 1 1 • 1 • 1 • | • 1 • 1 • 1 • 1 • | • 1 • 1 • 1 • 1 • | BASE M/Z: 166 RIC: 75136. . 1 • i • i • 1 • i • i • i • i • y • i • i • i • i • | BASE M/Z: 166 RIC: 5560. 160 150 200 250 300 .1.... .. .1.1.. 11 ... ,.!.... . .. o oo _J r 10880. 7 10032. - - 1000. r **oum CO TARGET COMPOUND COMPARISON 100.0- 50. 8~ 93.7- 46.8-j 8.4- 4.2- M/Z 108.0- 50.0-j 0.0-: -50.0-j COMPOUND: C054 CIS-1,2-DICHLOROETHENE RAW DATA: W7325 #112 03/17/93 14:58 SAMPLE: CLP, 53554, MW01 , MW81 , LOW, WATER, UU7325, UOA CONDS.: I500A:25ML OLU01 PURGE W/ 5PPB IS k SS .. i . ...i . . . . . . I , , , . .... | ... ENHANCED DATA: ..!.- ,._.. . ... .... 1 .... , . . . ( . . LIBRARY FILE: .,..,.... 30 1 ' ' • ' | • • 40 i .1 1 i| . .. . M . . i UU7325 #112 i i . . Ul #41 —— i — . ^ — . _ . 4- ...... BASE M/Z: 61 RIC: 43136. ,EPA, 1 " ' • ' • • • • | ""'•"' 1 "'•' ^ ' ' BASE M/Z: 61 RIC: 35264. -*.j • 1 I I | 4- ...... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . BASE M/Z: 61 RIC: 3246. i 50 60 . . . . . . — __. —— _._ ———————————————————— —— 70 30 90 • i -t- • -*-{ 168 ' ooo -J - 11872. r 11120. - 1008. ; ™, Quantitation Report File: W7325 Data: VV7325. TI 03/17/93 14:50:00 temple: CLP, 53554, MW01, MW01, LOW, WATER, VV7325, VGA, EPA, ~onds. : I5OOA:25ML OLVO1 PURGE W/ 5PPB IS «< 55 0035 srmula: 25ML "S.'ismitted by: AMBIENT PURGE Instrument: I500A ITEK Analyst: RJL Weight: Acct. No. 0. 000 53554 viQUNT=!!tIGHT » REF AMNT/(REF HEIGHT * RESP FACT) -•ssp. fac. from Library Entry (I. S. Kl ) (I. S. #2) S. #3) 1 •—• i c.' 3 A ~- t. .• CAS # 0-00-0 0-00-0 0-00-0 o-oo-o 0-00-0 7440-37-1 o-oo-o Name CI01 BROMOCHLOROMETHANE ( CI10 1, 4-DIFLUOROBENZENE CI20 CHLOROBENZENE-D5 (I. UNKNOWN) UNKNOWN! Morr T«.UE «-'TS ARGON \ UNKNOWN J m/z Scan Time Ref RRT Meth 1 •1 •^f M 5 6 7 R R R R R R R 1C 1C 1C 1C 1C 1C 1C 183 373 518 129 131 136 140 6: 12: 17: 4: 4: 4. 4: 06 26 16 18 22 32 40 1 2 3 1 1 1 1 1 1. 1 0. 0 o'. 0. 000 000 ooo 705 716 743 765 A A A A A A A BB BB BB W VV VB BV Area(Hght) 7701. # 12952. * 11888. * 1993. * 2017. « 2244. # 1466. * Amount 50.000 UG/L 50.000 UG/L 50. OOO UG/L 12. 940 13. 094 14. 569 9. 516 7.Tot 24. 99 24. 99 24. 99 6. 47 6. 54 7. 28 4. 76 TUT OO4 1451 L-0001472 PROCEDURE: FILTER/TIC 2ATA FILF.: W7325 FILTER SCAN PARAMETERS DIAGNOSTIC REPORT 3/18/73 18:OO:44 0036 METHOD LIBRARY & LISTS AX. NUMBER TICS -! 2 -TABLE ENTRIES ?,CAN TOLERANCE "IN. RIC HT. CV.3 =IRST SCAN -AST SCAN '•1C THRESHOLD 10 475 3 10 35 1000 500 TIC I. S. LIBRARY NDS SEARCH PROC PEAK FINDER PROC TCA I. S. LL FILE NAME LIST LIBRARYIS SERLID VOME5 IS TCAREF2 "Afif.GET COMPOUND ANALYSIS: TARGETS (QUAN LIST) 9 -1LTER PROCESSING: TOTAL TARGET PEAKS 12 TOTAL PEAKS 17 •C 1ST SCAN 0 :> LAST SCAN 0 .£ RI 1C PROCESSING: SCAN* 131 136 140 PURITY FIT 324 566 428 996 996 484 IS PEAKS 3 REJECT PEAKS IN < SCAN HT TOL 4 10 MW COMPOUND NAME CBEFORE TIC THRESHOLD: 40 ARGON 40 ARGON 84 ACETAMIDE, 2-CYANO- > MAX # PF.AKS 0 ——— j. TOTAL REJECTS 14 TOTAL TICS 3 TUT OO4 1452 / - O O O J . 4 7 3 ut/ioooi QizT t/oo mi . (T, f*-, •r '!o z; > i i •• U 1 <_> T — i CD C£ irvi r-4 L- tr <r JLi a: a: 0 <-) -2 LU .1 Sun •> UO CM «3 CO f\_ ^*| ^5* ^** •^ -. OQ LU a. ^^m ^j*^t O£ •* 3 O LU l*ft ^ £J ?- "* ^ f^ *^? Q^ <r CN» 3 ct r-4 s: — i ~ rf ~ !§ ^ v 3 O 5 X - _l Z O CD •* ZT CN a; >o in in LU >s co ..in '.n min <r — ^ a; ^ _i !n ^ <T t 1 HH ct ^i i~i co en •• •• LU •— i X LU • O _i r^- _» tn z -• o_ a ^ . en <r CJ - "^ •—1 CD * •- . 1 . 1^ 1 CO en 4* •cc0 . 1_J ' ^ 1— LU s:iin ^ "5 21 — ___ -- -_ ^ O"*i o . ru -X CL: i— t ____ O*^ _ __ _ _ ^« 1 1s U 1 CM - ini CO CO IjD . un <z 0 . i - -w • § X LU _J X t— = 1 VM J ^ O X -6i -.'2? oS .. . LU _J a: i— I-H Lu "^ <J , a.o L. . - Z O ® ®S> '^ CD ^ ^® 0000 CN LO ^ O® COCO CO Tf CM 1^1 1^1 ^^ CM 0*4 Z ® C/1C/1 fv ^™ * • ® ^C/1 ^^ ® O LU ® ^ • ® ® CO CO ® »•* C/l CO ~ f , • Gi «>eoo rvi o CO o co co0 o MID LIBRARY SEARCH (LIBRARYNB) DATA: UU7325 t 136 BASE M/Z: 40 03/17/93 14:58:"" - - — 00 + 4:32 CALI: W7325 tt 3 RIC: 121. SAMPLE: CLP, 53554, MW01 , MW01 , LOW, WATER, UU7325, VOA, EPA, CONDS.: I500A:25ML OLU81 PURGE M/ 5PPB IS t, SS r-i ii i At i/%^-r% y /- j ^r^ f-.t i .T-.T t 1660 1 SAMPLE .AR 1000 i H WT 40 3 PK 40 SANK 1 1 20 PUR 566 ENHANCED (S 15B r 2N 0T) ARGON r :2.H7.N4.B 1000 1 M MT 98 B PK 98 RANK 2 i 1071 : PUR 355 C5.H3.03 1000 1 .1 WT 116 B PK 68 RANK 3 I 2812 PUR 336 •~l ——————————— , ——— , ——— . . . . , . - . . , . , . . , . . . . , . . . , 1H-TETRAZABOROLE , 4, 5-DI HYDRO- 1 , 4-DI METHYL- r , 1 Oi^, ——— . —— , —— , —— ^ BUTANOIC ACID, 4-HYDROXY-2-METHYLENE- f '-• ' ' » ' ' • ' 1 • ' • •' n . t t- H/H 28 30 J — U ——— r-^4-^ ——— , ——— , — 48 50 68 CAS# 7440-37-1 CAS# 6982-51-0 1 CAS# 24923-76-0 1' r •' • • • i • • • • i "•• • • » ' ' • • i • • • —— "-*- 1 70 88 90 i | -4- 100 Oo CD COo o 1669 SAMPLE C3.H4.0.H2 1006 M WT 84 3 PK 44 .RANK 1 ft 491 PUR 428 :3.H3.02.H 1606 M NT 85 B PK 41 RANK 2 ft 562 ?UR 467 MID LIBRARY SEARCH vLIBRARYHB) 83/17/93 14:56:00 + 4:40 DATA: UU7325 tt CALI: UU7325 tt 140 3' BASE h/Z: 44 RIC: 1014. SAMPLE: CLP,53554,MM01, MW01,LOW,WATER,UU7325,UOA,EPA, CONDS.: I500A:25ML OLU61 PURGE W/ 5PPB IS & 55 ENHANCED (5 15B 2N 0T> oo ACETAMIDE, 2-CYANO- CAS# 107-91-5 mm oo ACETIC: ACID, CYANO- CASft 372-69-8 I C2.H2.0.N.CL3 1000 ,1 WT 161 B PK 44 RANK 3 t 10563 PUR 390 M/Z ACETAMIDE, 2,2,2-TRICHLORO- CAS* 594-65-0 r 1 - . 1 1 1 1 1 1 . . . . 20 48 60 80 106 120 . c? G' 1 0040 73 o CO G' X- O X CO C"!' O ~O •—•• m LO i— --j •• • m v • • • • i jj IT' CO •- x- cr cn • • o"1 G> -••j ro cn •• f o cn cn G' x- r~ G' CO :Z •— m o - K- rn o /Sc^ G> cn —( ~o m Tl Tl i~' O O CO :- X- I:- <— d r~ —t x> « -c «-H x Z LO --J •• " " CO s* fo c: -c i> cn <_ •:_ Co -a co co NJ O K' hO x- cn cn K.I m * * • "n i" i *i rri G' X G' CO i. .1 T' cn ',/ r- J ,'• \\ * G' / 0 A ri t .17' 1700 ini oo 1123 SAMPLE C5.H12.0 1128, M WT 33 j 3 PK 73 SANK 1 » 792 PUR 924 :9.H20.0 1128 M WT 144 B PK ~ • RANK 2 » 7242 PUR 840 C6.H12.02 1128 • .1 WT 116 B PK 73 RANK 3 » 2863 ' PUR 816 M/Z MID LIBRARY SEARCH (LIBRARYHB) 03/17/93 14:50:00 + 2:40 DATA: UU7325 ft 80 CALI: UU7325 * 3 SAMPLE: CLP,53554,MM61,MWO1,LOW,WATER,UU7325,UOA,EPA, CONDS.: I500A:25ML OLU01 PURGE W/ 5PPB IS S- SS ENHANCED <S 15B 2N OT> PROPANE, 2-METHOXY-2-METHYL- -U- PENT AHE > 2-METHOXY-2 , 4 , 4-TR I METHYL- 2-BIJTANONE, 3-METHOXY-3-METHYL- 40 60 80 lOO BASE M Z: 73 RIC: 4272. CD —J 120 . IX ORGANICS ANALYSIS DATA SHEET 0042 SAMPLE NO. Name: ITAS-KNOXVILLE Contract: SAS No . : MW02 Lab Code : ITSTU Case No . : 53554 Matrix: (soil/water) WATER Sample wt/vol: 25.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ Heated Purge: N GC Column: DB-624 ___ ID: 0.53 fmm) Soil Extract Volume: ______ (uL) SDG No.: MW01 Lab Sample ID: W7326 Lab File ID: W7326 Date Received: 03/08/93 Date Analyzed: 03/17/93 Dilution Factor: ____1.0 Soil Aliquot Volume: ___ .(uL) CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L 74-87-3———————Chloromethane_________ 7 4-83-9———————Bromomethane__________ 75-01-4———————Vinyl Chloride________ 75-00-3———————Chloroethane__________ 75-09-2———————Methylene Chloride_____ 67-64-1———————Acetone______________ 74-97-5———————Bromochlorome thane_____ 75-15-0———————Carbon Disulfide______ 75-35-4 —————— 1,1-Dichloroethene____ 75-34-3 ——————— 1,1-Dichloroethane_____ 540-59-0——————trans-1,2-Dichloroethene_ 540-59-0——————cis-1,2-Dichloroethene__ 67-66-3———————Chloroform____________ 107-06-2——————1,2-Dichloroethane______ 78-93-3——————2-Butanone___________ 71-55-6———————1,1,1-Trichloroethane___ 56-23-5———————Carbon Tetrachloride____ 75-27-4———————Bromodichloromethane____ 78-87-5———————1,2-Dichloropropane_____ 10061-01-5————cis-1,3-Dichloropropene_ 79-01-6——————Trichloroethene________ 124-48-1——————Dibromochloromethane____ 79-00-5———————1,1,2-Trichloroethane___ 71-43-2———————Benzene_______________ 10061-02-6————trans-1,3-Dichloropropene_ 106-93-4——————1,2-Dibromoethane______~ 75-25-2——————Bromoform____________ 108-10-1——————4-Methyl-2-Pentanone____ 591-78-6——————2-Hexanone____________ 127-18-4——————Tetrachloroethene______ 79-34-5——————1,1,2,2-Tetrachloroethane 108-88-3——————Toluene_____________~ 108-90-7——————Chlorobenzene_________ 1 l l l 1 5 1 1 1 1 1 32 1 1 5 1 1 1 1 1 51 1 1 1 1 1 1 5 5 310 1- 1 1 Uu Uuuuuuuuu E Uuuuuuuu E U U Uuuuuu E U U U FORM I X-l [ 000? 17? 3/90 IX ORGANICS ANALYSIS DATA SHEET 'Lab Name: ITAS-KNOXVILLE_________ Contract: Lab Code: ITSTU Case No.: 53554 SAS No.: Matrix: (soil/water) WATER Sample wt/vol: 25.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ Heated Purge: N GC Column: DB-624 ID: 0.53(mm) Soil Extract Volume: ______(uL) 0043 SAMPLE NO. MW02 SDG No.: MW01 Lab Sample ID: W7326 Lab File ID: W7326 Date Received: 03/08/93 Date Analyzed: 03/17/93 Dilution Factor: ____1.0 Soil Aliquot Volume: ___ CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L .(uL) 100-41-4 ——— • 100-42-5 ——— • 1330-20-7 —— • 541-73-1 ——— • 106-46-7 ——— • y o o \j j. 96-12-8 ———— - —— Ethvlbenzene —— Styrene - —— Xvlene (total) —— 1, 3-Dichlorobenzene —— 1 , 4-Dichlorobenzene —— 1 , 2 -Dichlorobenzene —— l,2-Dibromo-3-Chloropropane _ 1 1 1 1 1 1 1 uuuuuuu L O C 0 1 4 8 0 FORM I X-2 TUT 004 .1459 /9° IX ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS 0044 SAMPLE NO. Name: ITAS -KNOXVILLE — — Lab Code: ITSTU Case No.: 53554 Matrix: (soil/water) WATER Sample wt/vol : 25.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ GC Column: DB-624 ___ ID: 0. 53 (mm) Soil Extract Volume: ______ (uL) Contract: SAS No.: MW02 SDG No.: MW01 Lab Sample ID: W7326 Lab File ID: W7326 Date Received: 03/08/93 Date Analyzed: 03/17/93 Dilution Factor: ____1.0 Soil Aliquot Volume: ___ .(uL) Number TICs found: CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L CAS NUMBER COMPOUND NAME RT EST. CONC. Q FORM I X-TIC 3/90 TUT OO4 146O Oo DATA FROM FILE: W7326 SCANS 45 TO 720 ACQUIRED: 83/17/93 15:23:96 CALI: W7326 #3 SAMPLE: CLP,53554,MW01,MU82/LOW,WATER,UU7326,UOA,EPA, CONDS.: I500A:25ML OLU81 PURGE W/ 5PPB IS 8« SS c-i oo ••a* I J 186.07. ( 1417228.) 190 3:28 t>- 288 _ 6:40 300 J 10:00 CI10 1,4-DIFLUOROBENZEHE (IS#1) •r 400 J 13:20 509 _ 16:40 600 J 20:00 700 J CI26 CHLOROBENZENE-D5 (IS#2) CS10 4-BROMOFLUOROBEHZENE <SS> CI26 1,4-DICHLOROBENZENE-D4 <IS#3> Quantitation Report File: VV7326 Data: W7326. TI 03/17/93 15: 23: 00 -Ample: CLP, 53554, MW01. MW02, LOW, WATER, W7326, VOA, EPA, ^.?r,ds. : I500A:25ML OLV01 PURGE W/ 5PPB IS ?< S3 ~^':rmula: 25ML AMBIENT PURGE Instrument: I5OOA Weight: O. 000 by: ITEK Analyst: RJL Acct. No. : 53554 0046 ^!QUNT=AREA * REF AMNT/<REF AREA * RESP FACT) Fesp. fac. from Library Entry No 1 CI10 1, 4-DIFLUOROBENZENE < IS#1 ) 2 CI20 CHLOROBENZENE-D5 (IS#2) 3 CI26 1, 4-DICHLORODENZENE-D4 •(• CS10 4-BROMOFLUOROBENZENE (SS) S CO1O CHLOROMETHANE ** is. CO 15 BROMOMETHANE '.' C020 VINYL CHLORIDE * 3 C025 CHLOROETHANE ~ C03G METHYLENE CHLORIDE !0 C035 ACETONE II C110 2-BUTANONE :l- C2O5 4-METHYL-2-PENTANONE 13 C210 2-HEXANONE 14 C037 BROMOCHLOROMETHANE 1? C04O CARBON DISULFIDE It CG15 1, 1-DICHLOROETHENE * ;• C05O 1, 1-D I CHLOROETHANE ** -.8 CO 03 TRANS-1, 2-DICHLOROETHENE 19 CO=O CHLOROFORM * '?.(} CC65 1, 2-D I CHLOROETHANE 21 C115 1- 1, 1-TR I CHLOROETHANE £2 C120 CARBON TETRACHLORIDE JT3 C130 BROMODICHLOROMETHANE 2- C140 1, 2-DICHLOROPROPANE * 25 C143 CIS-1, 3-DICHLOROPROPENE P.t C150 TRICHLOROETHENE S7 C155 D I BROMOCHLOROMETHANE 23 C160 1, 1, 2-TR I CHLOROETHANE 2? C165 BENZENE 30 C172 TRANS-1, 3-DICHLOROPROPENE 3-i C176 DIBROMOETHANE Z-2 C1SO BROMOFORM »* 33 C220 TETRACHLOROETHENE ?4 C225 1, 1, 2, 2-TETRACHLOROETHANE ** ^? C230 TOLUENE * :<6 C235 CHLOROBENZENE 37 C240 ETHYL BENZENE * 38 C245 STYRENE 37 C25O M/P XYLENE •10 C252 0-XYLENE 41 C05< C I S-l, 2-DICHLOROETHENE 43 C252 1, 3-D I CHLOROBENZENE 4.3 C253 1, 4-D I CHLOROBENZENE 44 C254 1, 2-D I CHLOROBENZENE i5 ' C261 1, 2-DIBROMO-3-CHLOROPROPANE LOG01483 TUT OO4 I \2 _s 3 4 5 6 •^? 3 * 10 11 1 *. 13 14 1 !!; '6 17 ; D '**? 20 21 22 23 24 25 26 27 2S Jb. 7 30 31 32 23 34 35 36 37 33 3? 40 -i 42 43 44 45 'JO 1 "7 3 i s6 ^ 7 6' 9 m/z Scan 114 184 117 373 150 518 95 439 NOT FOUND NOT FOUND 62 41 NOT FOUND 8'! 72 NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND 76 65 96 6O NOT FOUND 96 79 83 127 NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND 95 201 NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND 166 325 NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND 96 112 NOT FOUND NOT FOUND NOT FOUND NOT FOUND Time 6: OS 12.26 17 14 1 2 2 2 2 4 6 10 3 Ret(L) Ratio 6: 08 1. 00 12: 26 1. OO 17: 16 1. OO 1 4 : 38 1 . OO 1. 16 1: 28 1: 18 1. 05 1: 32 2: 24 1. 00 : 16 : 38 : 22 : 24 : 10 : OO : 38 : 14 : 42 : 50 : 44 RRT<L 1. 000 1. 000 1. OOO 2 386 0. 207 0. 239 0. 212 0. 250 0. 391 Ref RRT 1 1 . 000 2 1 . OOO 3 1. 000 1 2. 386 1 0. 223 1 O. 391 1 0. 353 1 0. 326 1 0 429 1 0. 690 2 0 539 2 O. 871 1 0. 609 ) Ratio 1. OO 1. OO 1. OO 1. OO 1. 05 1. OO Meth A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB Amnt 5. 00 5 00 5. OO 5. 42 0. 65 O. 67 Area<Hgh 12192. 8635. 5445. 7208. 1046. 570. 3O6. 218. 719. 155. 86789. 633654. 28538. Amnt(L) 5. 00 5. 00 5. OO 5. OO 5. 00 5 OO t) Amount 5. 5. 5. 5. 0. 0. 0. 0. 0. 0. 51. 313. 31. R. Fac 1. 000 1. 000 1. OOO 0. 591 000 000 000 425 649 673 077 168 611 072 026 268 559 UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L R. Fac(L) 0. 086 0. O47 1. 000 1. 000 1. OOO 0. 545 0. 661 0. 348 1 y.Tot i. i. i. i. 0. 0. 0. 0. 0. 0. 12. 74. 7. Rati 1. 1. 1. 1. 0. 0. 20 20 20 30 16 16 02 04 15 02 20" 87 54 o 00 OO 00 OS 13 13 0047 TUT 004 1463 L O C O 0048 •lo 10 11 12 13 14 I C 1-i • ••? 3. ! ' 5 \ -f £0 21 22 23 24 25 26 27 28 29 30 31 32 "O 34 35 36 37 38 39 40 il 42 43 44 45 Ret<L) 2: 04 3: 50 9: 38 11: 22 4: 04 2: 10 2: OO 3: 02 2: 36 4 14 5: 1O 4: 3O 4: 46 8: 04 7: 16 9: 08 6: 42 11: 22 1O: 42 5: 06 10: 22 11: 28 14: 00 10: 50 15: O2 9: 46 12: 30 12: 48 13: 46 13: 02 13: 44 3: 44 16: 32 16: 42 17: 18 18: 42 Ratio RRT(L> Ratio Amnt 0. 337 0. 625 0. 775 0. 914 0. 663 1. 00 0. 353 1. 00 0. OS 1. OO O. 326 1. OO 0. 17 0. 495 1. 01 0. 424 1. 01 0. 61 1. 00 O. 690 1. OO 0. 07 0. 842 0. 362 O. 383 0. 649 0. 584 O. 735 1 00 0. 539 1. 00 51. 03 0. 914 0. 861 0. 410 0. 834 0. 922 0. 811 1. 00 0. 871 1. OO 313. 27 1. 209 0. 786 i 005 1. 029 1. 107 1. 048 1. 105 1. 00 0. 609 1. 00 31. 56 0. 958 0. 967 1. 002 1 083 Amnt<L) R. Fac R.Fac(L) Ratio 5. 00 0. 025 1. 624 0. 02 5. OO 0. 018 O. 532 0. 03 5. 00 0. 059 0. 483 0. 12 5. OO 0. 013 0. 886 0. Ol 5. OO 10. 051 0. 985 10. 21 5. 00 73. 382 1. 171 62. 65 5. 00 2. 341 0. 371 6. 31 TUT OO4 1464 LOC01485 3/17/93 15:23:21 Acquisition started 0049 ^3/17/93 15:23:25 "Acquire Run 0: W7326 C:</17/93 15:23:00 + 0:00 Free sectors: 13098 Simple: CLP, 53554, MW01, MW02, LOW, WATER. W7326, VGA, ERA, londs.: I500A:25ML OLV01 PURGE W/ 5PPB IS & SS -rrmula: 25ML AMBIENT PURGE Instrument: I500A S-jbmitted by: ITEK Analyst: RJL Starting Scan: 0 of 720 Weight: Acct. No: **# GC not ready and being Temp (DegC) 35- 35 35- 150 150-150 Rate (C/min ) - 8. 0 - Time <minutes> equilibrated *** Elapsed time : 0. 000 53554 0. O Min v'.ilve A Post period 6. 6 14. 3 3. 0 Valve B : *** Instrument acquisition state -> closed total 6. 6 20. 9 23. 9 open parameters Filament Injector A : 150 GC oven : 42 Transfei—line: 216 Ion source : 181 Deg Deg Deg Deg C C C C r'CDE: EI < + ) Centroid + Temp - Sequence: BF *#* Off Multiplier ( 2 time windows. Off Sequence Window # 1 <~.an descriptor: 3tal scan time: Number of cycles: Filament is OFF Multiplier is ON BF Mass intervals: 2. 000 s 28 Positive ion mode. Master rate: 16 :'PW: 3 MFW: 80 MA: 15 Int # Lo mass Hi mass 1 33. 510 300. 590 TH 1 Time 2. 000 DL: Sequence Window tt 2 Number of cycles: Filament is ON Multiplier is ON BF Mass intervals: 2. 000 s S:an descriptor: Total scan time: Positive ion mode. Master rate: 16 'PW: 3 MFW: 80 MA: 15 TH: 1 Int tt Lo mass Hi mass Time 1 33. 510 300. 590 2. 000 BL: Calibration table: D:CAL021992 Interface number Instrument type Full scale mass Zero scale mass Intensity/ion Peak width Offset at low mass Offset at high mass 'Voltage settling time(ms) 20 0 Q 1177 1 2 1000. 0 0 u u mmu mmu mmu TUT 004 1465 Current instrument parameters. Positive ion mode 0050 Resolution (high) Resolution (low) Quad offset Quad programming Lens offset Lens programming Ext offset Ext programming Col lector Ion offset Ion programming Rod polarity 128. 128. 0. 0. -50. 0. 0. 0 30. 7. 5. 00 00 00 00 00 00 00 oo 00 00 00 Negative ion mode 128. 00 128. 00 0. 00 O. 00 00 00 00 00 00 00 00 Reverse Electron multiplier voltage Filament emission current Electrometer range Electrometer zero 50. 0. 0. 0. 30. -3. -5. Normal 984. 750. 10 ~-7 126. 0 Analyzer Fore Pressure ... Separator/Source Pressure 0. 009 Torr 0. 356 Torr 3/17/93 15:50:25 ACQUISITION COMPLETED Scans 1 to 720 Centroid Scans 720 Sees O. 6 Out of 1440. 0 7. O. O Peaks per 11854. scan 16. per sec 8. TUT OO4 1466 L0001487 QUALITY CONTROL/QUALITY ASSURANCE DATA 0051 METHOD: MEDIUM-LEVEL VOLATILE SOIL SAMPLE DATAFILE: STANDARD: TUNEFILE: VV7326 WS0317 WBFD0317 ANALYSIS TIME: ANALYSIS TIME: ANALYSIS TIME: 03/17/93 15:23 03/17/93 10:48 03/17/93 9:34 **#»## INTERNAL STANDARD AREA CHECK *#**#* INTERNAL STANDARD 110 1, 4-DIFLUOROBENZEN 120 CHLOROBENZENE-D5 ( 126 1, 4-DICHLOROBENZEN DATA AREA 12192. 8635. 5445. STD AREA 9856. 6374. 4017. RATIO 1247. 1357. 1 367. CLP ACCEPT RATIO 507. - 2007. 507. - 2007. 507. - 2007. STATUS **»»*# INTERNAL STANDARD RT CHECK ***#** INTERNAL STANDARD «: 1 1 0 1 , 4-D I FLUOROBENZEN CL20 CiiLOROBENZENE-DS ( •'126 1.. 4-DICHLOROBENZEN DATA SCAN 184 373 518 STD SCAN 184 373 518 DIFF CIN SEC 3 0 0 0 CLP ACCEPT DIFF STATUS +/- 3O SECS +/- 30 SECS +/- 30 SECS ****** SURROGATE RECOVERIES ****** SURROGATE AMT FOUND AMT ADDED PERCENT RECOVERY RECOV LIMITS STATUS 1310 4-CROMOFLUOROBEN7E 5. 4 C010 CHLOROMETHANE ** -0.0 ::i5 BROMOMETHANE -0 0 O . O 50. 0 >T 0 867. - 857. - 777. - 1197. 1217. 1207. failed failed TUT 004 1467 UG01483 DIAGNOSTIC REPORT PROCEDURE: TCA DATA FILE: VV7326 REFERENCE: VI11 '•S.PIE LIST: VI INITIALIZATION OPTION: 2 REPORT: VI IS UU52 3/17/93 16:00:1 PROCESSING OPTION. 3 NAMES - ^ffOC USED POSS 3 3 3 2 3 3 45 COMPOUNDS f,'0 1 2 3 4 w 6^ 3 9 10 1 1 12 13 14 ,15 16 17 18 -9 20 21 22 23 24 25 ^6 27 28 29 30 31 22 •32 34 35 36 3/ 39 39 40 '41 42 43 44 45 COMPC LIB VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI , VI VI VI VI VI UND X ENTRY 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 1 1 1 RMS PROC USED POSS 0 20 7 1 0 16 5 1 O 15 4 1 RMS STAND, 101 V1IS/1 0 V1IS/' O V1IS/1 PROCESSED, 9 FOUND REF -184 -373 -518 -439 -38 -44 -39 -46 -72 -62 -115 -289 -341 -122 -65 -60 -91 -78 -127 -155 -135 -143 -242 -218 -274 -201 -341 -321 -153 -311 -344 -420 -325 -451 -293 -375 -384 -413 -391 -412 -112 -496 -501 -519 -561 PRED SEL DELTA PEAKS 184 184 . 1 373 373 . 1 518 439 439 . 1 3 9 . . . 4 5 . . . 40 42 2 1 4 7 . . . 73 72 -1 1 6 3 . . . 116 289 341 123 6 6 . . . 61 61 . 1 9 2 . . . 7 9 . . . 128 156 135 143 242 218 274 201 2O1 . 1 341 321 153 311 344 420 325 325 . 1 451 293 375 384 413 391 412 112 112 . 1 496 501 519 5 6 1 . . . --..<- CAT -' S. Or* 1 FIT PEAKS 980 977 967 787 902 844 977 978 . . . . 919 . , . M/Z 114 117 150 95 50 94 62 64 84 43 43 43 43 128 76 96 63 96 83 62 97 117 83 63 75 95 129 97 78 75 107 173 166 83 91 112 91 104 106 106 96 146 146 146 75 ——— UI-IKU ——— TOP DELTA 184 373 518 439 41 -1 72 65 60 -1 79 127 201 325 * 112 . PEAKS 1 1 1 1 1 1 1 1 1 1 1 1 00 -0 •H 5 iC t f LOOOH89 I. T. ANALYTICAL SERVICES LIBRARY SEARCH REPORT PURGEABLE VOLATILE ORGANICS ANALYSIS 0053 ;4TA FILE: W7326 i- "QUIRED: O3/17/93 15:23:00 :JNDS. : I500A.25ML OLV01 PURGE W/ 5PPB [.'EMITTED BY: ITEK IS SS ANALYST: RJL ACCOUNT NO. 53554 COMPOUND '10 1.. 4-DIFLUORODENZENE (15*1) :I20 CH: OR03ENZENE-D5 (ISK2) "26 1.. 4-DICHLOROBENZENE-D4 <IS#3> :310 4-BROMOFLUOROBENZENE (SS) !50 TRICHLOROETHENE L20 TETKACHLOROETHEfv'E :054 CIS-1, 2-DICHLOROETHENE SCAN DELTA (UG/ML) 184 373 518 439 201 325 112 O 0 0 0 0 0 0 5.000 5.000 5.000 5. 425 51.026 313.268 31.559 FIT 98O 977 0 967 977 978 919 SAT'D? 0 0 0 0 0 0 0 TUT OO4 i469 ^ 0 0 0 1 4 9 0 TARGET COMPOUND COMPARISON COMPOUND: C150 TRICHLOROETHENE CD 100.0- 50.0-i 95.5- 47.8-: 5.6~ 2.8^ M/Z 100.0- 50.0-: 0.0-: -50.0-: 100.0- RAW DATA: UU7326 #201 BASE M/Z: 95 RIC: 111744. 03/17/93 15:23 SAMPLE: CLP, 53554 , MW01 , MW62, LOW, WATER, UU7326, UOA, EPA, CONDS.: I500A:25ML OLU01 PURGE W/ 5PPB IS t 55 i i r »'-' . i . i L^ _i i ENHANCED DATA: UU7326 #201 Bf . i . ... 1 , LIBRARY FILE: Ul #26 1 . 40 I!. . .. . 1 1 56 60 ii. ... i i Bt i nSE M/Z: 95 RIC: 105728. i «E M/Z: 95 RIC: 53: .1, i J6 . • • • • ! • • • • | 1 . . - | l l . . | . . . . . . . . . , . . . . 80 100 120 . . . . . . . . ...... ..... 1 ' ' I ' 1 ' 1 140 .... CD J r 17824. o N O r 17024. ^ t- - 1000. - **oum _ iO TARGET COMPOUND COMPARISON COMPOUND: C220 TETRACHLOROETHENE RAW DATA: UU7326 #325 03/17/93 15:23 SAMPLE: CLP,53554,MW01,MW02,LOW,WATER,UU7326,UOA,EPA, CONDS.: I500A:25ML OLU01 PURGE W/ 5PPB IS & SS BASE M/Z: 166 RIC: 1419260. C-2 en 100.0^ 50.0-; • 91.9- 45.9-: 0.5- 0.2- M/Z 100.0- 50.0-j 0 ft- • « . -50.0-: inn n— ' 1 , 1. ,. ll | • i • i • i • i • i • i • i • ENHANCED DATA: W7326 #325 , i, ,. ll. I . , , , . , , , . 1 . , . , . LIBRARY FILE: Ul #33 , ,. ,. li 50 100 ,. ..!.,..... ... ....... ..ll,. ....... 1 1 1 , . 1 . , . 1 1 1 • 1 • 1 • 1 150 1,., 1 1 - i • i • | • i • r • i • i • 1 • i • i • i • i • | BASE M/Z: 166 RIC: 1314820. 1 i i | . i i i 1 . i i i | BASE M/Z: 166 RIC: 5560. , 200 250 300 H 1 1 1 II 1 1 1 1 II II II 1 1 - 214816. r 196688. leee. - **oum CO IT) o TARGET COMPOUND COMPARISON 0 COMPOUND: RAW DATA: C854 CIS-1 , 2-DICHLOROETHENE UU7326 #112 BASE M/Z: 61 RIC: 49536. CO cr> ^3* »-< c±3 C3 CD 03/17/93 15:23 —1 SAMPLE: CLP, 53554, MW01 , MW82, LOW, WATER, UU7326, UOA, EPA, CONDS.: I580A:25ML OLU01 PURGE W/ 5PPB 100.0- 50.0-: ....... ..!,,,., l i t . . ENHANCED DATA: UU7326 #112 92. 8q 46.4-: 1 ,, i i . . |-1 , , , , , , , , | , , , , , , , , , | , , , , , , , . , | . , . , , ... i IS 8, SS BASE M/Z: 61 RIC: 46896. i . ... i ......... i ......... | ........ . | . LIBRARY FILE: Ul #41 7.2- 3.6-j ,..,. ...-,- .4 1 i .. .... i ......... i ......... 1 ......... M/Z 36 40 50 ( 100. Q- 50.0-: 0.0-j - -50.0- -100.0-^ I , . . . .- \ — • • • • • i i ;0 1 ...... 1 ......... I ......... I .... i BASE M/Z: 61 RIC: • ' • • • • i • ' • • ' ' • • • i • ' • • ' • • • • i '•'•' 70 80 90 • i • • 3240. -t- • MK 1 ——— rJ - 13872. - \———^ 7 12880. - ^™J - 1000. - )0 ~ - r **OUT** - — - ni- i tation Report File: W7326 0057 lata: W7326. TI :3/17/93 15:23:00 -ti/r.ple: CLP, 53554, MW01, MW02, LOW, WATER, W7326, VOA, ERA, :nds. . I500A:25ML OLV01 PURGE W/ 5PPB IS Sc SS — srmula. 25KL AMBIENT PURGE Svamitted by: ITEK Instrument: I500A Analyst: RJL Weight: Acct. No. 0. 000 53554 -•'aUNT=HtIGHT * REF AMNT/(REF HEIGHT •* RESP FACT) -••sp. fac. from Library Entry 7 •3 CAS # 0-00-0 O-OO-O 0-00-0 124-38-9 28292-43-5 28292-43-5 23292-43-5 23_'92-43-5 S. #3) Name CI01 BROMOCHLOROMETHANE (I.S.ttl) CI10 1, 4-DIFLUOROBENZENE (I.S. #2) CI20 CHLOROBENZENE-D5 (I. CARBON DIOXIDE 2-HEXANAMINE, 5-METHYL- 2-HEXANAMINE, 5-METHYL- 2-HEXANAMINE, 5-METHYL- 2-HEXANAKINE, 5-METHYL-, "-•: m/ 2 Scan Time Ref RRT Meth R R R R R R R R 1C 1C 1C 1C 1C 1C 1C 1C 184 373 518 122 131 134 134 137 6: 12: 17: 4: 4: 4: 4: 4: 08 26 16 04 22 28 28 34 1 2 3 1 1 1 1 1 1. 1. 1. 0 0. 0. 0. 0. 000 000 000 663 712 728 728 745 A A A A A A A A BB BB BB W W W VV VB Area<Hght) 7528. * 13293. * 12607. * 2408. * 1296. * 1256. * 1224. * 144O. * Amount 50.000 UG/L 50. OOO UG/L 50. 000 UG/L 15. 994 8. 608 8. 342 8. 130 9. 565 7.Tot 24. 92 24. 92 24. 92 7. 97 4. 29 4. 16 4. O5 4. 77 L0001494 TUT OO4 1473 PROCEDURE: FILTER/TIC DATA FILF: W7326 TLTER SCAN PARAMETERS DIAGNOSTIC REPORT 3/18/73 18:O6:15 0058 A*. N'JfiRER TICS :-TABLE ENTRIES 1AN TOLERANCE 'IN. RIC HT. C7.3 :RST SCAN *5T SCAN 1C THRESHOLD 10 475 3 10 35 10OO 500 METHOD LIBRARY & LISTS TIC I.S. LIBRARY: LIBRARYIS NDS SEARCH PROC : SERLID PEAK FINDER PROC: VOME5 TCA I. S. LL : IS FILE NAME LIST : TCAREF2 COMPOUND ANALYSIS: TARGETS (QUAN LIST> 10 1LTER PROCESSING: TOTAL PEAKS 19 < 1ST SCAN 0 > LAST SCAN 0 < RI IS PEAKS 3 REJECT PEAKS- MIN < SCAN C HT TOL 6 9 TOTAL TARGET PEAKS 13 > MAX # PEAKS 0 TOTAL REJECTS 15 TOTAL TICS 4 1C PROCESSING: J. SCAN* PURITY FIT 35 122 131 137 791 720 622 607 791 978 654 662 MW COMPOUND NAME CBEFORE TIC THRESHOLD: 74 1,2-PROPANEDIAMINE 44 CARBON DIOXIDE 115 2-HEXANAMINE, 5-METHYL- 115 2-HEXANAMINE, 5-METHYL- TUT OO4 1474 C5 o o 1000 SAMPLE C3.H10.N2 1060 M WT 74 B PK 44 RANK 1 I 304 ' PUR 791 C9.H21.N 1000 M WT 143 B PK 44 RANK 2 I 6948 PUR 764 C7.H17.N 1000 H WT 115 B PK 44 RANK 3 t 2778 PUR 756 M/Z MID LIBRARY SEARCH <LIBRARYNB> DATA: 03/17/93 15:23:60 + 1:19 CALI: SAMPLE: CLP,53554, MM91,MW02,LOW,WATER,W7326,UOA,EPA, CONDS.: I500A:25ML OLU91 PURGE W/ 5PPB IS fc SS ENHANCED <S 15B 2N 9T> UU7326 « W7326 tt 35 BASE M/Z: 44 RIC: 429956. R i- 1,2-PROPANEDIAMINE CAS# 78-90-0 l-OCTANAMIf€.. N-METHYL- CAS# 2439-54-5 2-HEPTANAMINE CAS# 123-82-0 100 129 140 o o 1010 SAMPLE C.02 1010 M MT 44 3 PK 44 SANK 1 tt 32 PUR 720 D.N2 1010 H NT 44 B PK 44 RANK 2 » 37 ?UR 719 C3.H4.0.N2 1010 A WT 84 B PK 44 RANK 3 tt 491 PUR 670 M/Z MID LIBRARY SEARCH (LIBRARYHB) DATA: 03/17/93 15:23:08 + 4:04 CALI: SAMPLE: CLP,53554,MW01,MW02,LOW,WATER,UU7326,UOA,ERA, CONDS.: I500A:25ML OLU01 PURGE W/ 5PPB IS 8, SS ENHANCED (S 15B 2N 0T) UU7326 t UU7326 tt 122 1 BhSE M/Z: 44 RIC: 2228. r- o o •JD N. CARBON DIOXIDE CAS# 124-38-9 NITROGEN OXIDE <N20) CAS# 10024-97-2 ACETAMIDE, 2-CYANO- CAS# 107-91-5 -4—4- I I 20 30 40 50 GO 79 80 SAMPLE C7.H17.N 1000 M WT 115 3 PK 44 SANK 1 I 2774 PUR 622 :4.H8.0 1000 M WT 72 B PK 44 RANK 2 I 250 ?UR 536 MID LIBRARY SEARCH (LIBRARY*) DATA: 03/17/33 15:23:00 + 4:22 CALI: SAMPLE: CLP,53554,MW01, MM02, L 014, WATER, W7326,UOA,EPA, CONDS.: I500A:25ML OLU01 PURGE W C-PPR 1C- *• c- c- ENHANCED <S 15B 2N 0T) UU7326 # UU7326 *» 131 BASE M/Z: 44 RIC: 1683. 5PPB IS & CO o o CD NN 2-HEXANAMINE, 5-METHYL- CASt 28292-43-5 CVCLOBUTAHOL CAS# 2913-23-5 C2.H2.0.N.CL3 ACETAMIDE, 2,2,2-TRICHLORO- CAS# 594-65-0 10WO .1 WT 161 B PK 44 RANK 3 1 10563 PUR 486 M/Z r 40 60 30 100 120 IDO O 1006 SAMPLE C7.H17.N 1060 M WT 115 3 PK 4i .RANK 1 » 2774 PUR 687 :4.H8.0 1000 M WT 72 B PK 44 RANK 2 I 250 ?UR 526 MID LIBRARY SEARCH (LIBRARYHB) 03/17/93 15:23:00 + 4:34 . CALI: UU7326 SAMPLE: CLP,53554,MU81,MW62,LOW,WATER,UU7326,UOA,ERA, CONDS.: I500A:25ML OLU01 PURGE W/ 5PPB IS & SS ENHANCED (S 15B 2N 0T> 1 37 R1C: 05o o o C2.H2.0.N.CL3 1000 .1 WT 161 B PK 44 RANK 3 tt 18563 PUR 499 M/Z 2-HEXANAMIHE, 5-METHYL- CASf 28292-43-5 - v- CYCLOBUTANOL CAS# 2919-23-5 ACETAMIDE, 2,2,2-TRICHLORO- CASf 594-65-6 -i—»- 60 89 106 120 0063 ORGANICS ANALYSIS DATA SHEET Name: ITAS-KNOXVILLE_________ Contract: Lab Code: ITSTU Case No.: 53554 SAS No.: Matrix: (soil/water) WATER Sample wt/vol: 25.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ Heated Purge: N GC Column: DB-624___ ID: 0.53(mm) Soil Extract Volume: ______(uL) MW02DL2 SDG No.: MW01 Lab Sample ID: W7326 Lab File ID: W7326D2 Date Received: 03/08/93 Date Analyzed: 03/18/93 Dilution Factor: ____3 .3 Soil Aliquot Volume: ___ .(uL) CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L 74-87-3———————Chloromethane__________ 74-83-9———————Bromomethane___________ 75-01-4———————Vinyl Chloride_________ 75-00-3———————Chloroethane___________ 75-09-2———————Methylene Chloride______ 67-64-1———————Acetone_______________ 7 4-97-5———————Bromochloromethane______ 75-15-0———————Carbon Disulfide_______ 75-35-4———————1,1-Dichloroethene______ 75-34-3———————1,1-Dichloroethane______ 540-59-0——————trans-1,2-Dichloroethene_ 540-59-0——————cis-1,2-Dichloroethene__ 67-66-3———————Chloroform_____________ 107-06-2——————1,2-Dichloroethane______ 78-93-3———————2-Butanone____________ 71-55-6———————1,1,1-Trichloroethane___ 56-23-5———————Carbon Tetrachloride____ 75-27-4———————Bromodichloromethane____ 78-87-5———————1,2-Dichloropropane_____ 10061-01-5————cis-l,3-Dichloropropene__ 79-01-6——————Trichloroethene________ 124-48-1——————Dibromochloromethane____ 79-00-5———————1,1,2-Trichloroethane___ 71-4 3-2——————Benzene______________ 10061-02-6————trans-1, 3-Dichloropropene_ 106-93-4——————1,2-Dibromoethane______~ 75-25-2———————Bromoform_____________ 108-10-1——————4-Methyl-2-Pentanone____ 591-78-6——————2-Hexanone____________ 127-18-4——————Tetrachloroethene______ 79-34-5———————1,1,2,2-Tetrachloroethane_ 108-88-3——————Toluene_____________~ 108-90-7——————Chlorobenzene__ _____ 3 3 3 3 4 16 3 3 3 3 3 29 3 3 16 3 3 3 3 3 48 3 3 3 3 3 3 16 16 250 3 3 3 U U U U BJD U U U U U U D U U U U U U U U D U U U U U U U U ED U U U Ch r-.. ' I- FORM I X-l 3/90 I n r• r\ IX ORGANICS ANALYSIS DATA SHEET -Lab Name: ITAS-KNOXVILLE_________ Contract: Lab Code: ITSTU Case No.: 53554 SAS No.: Matrix: (soil/water) WATER Sample wt/vol: 25.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ Heated Purge: N GC Column: DB-624 ID: 0.53(mm) Soil Extract Volume: ______(uL) •0064 SAMPLE NO. MW02B2&LZ SDG No.: MW01 Lab Sample ID: W7326 Lab File ID: W7326D2 Date Received: 03/08/93 Date Analyzed: 03/18/93 Dilution Factor: ____3 .3 Soil Aliquot Volume: ___ CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L .(uL) 100-41-4 ——— • 100-42-5 ——— - 1 30-20-7 —— - 541-73-1 ——— - 106-46-7 ——— • 95-50-1 ———— • Q £ 1 *) Q —— Ethylbenzene —— Styrene - —— Xylene (total) —— 1 , 3-Dichlorobenzene —— 1 , 4-Dichlorobenzene —— 1 , 2-Dichlorobenzene —— 1 , 2-Dibromo-3-Chloropropane _ 3 U 3 U 3 U 3 U 3 U 3 U 3 U FORM I X-2 TUT 004 1480 L000150i 3/90 IX ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS 0065 SAMPLE NO. Name: ITAS-KNOXVILLE Lab Code: ITSTU Case No.: 53554 Matrix: (soil/water) WATER Sample wt/vol: 5.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ GC Column: DB-624 ID: 0.53 (mm) Soil Extract Volume: ______ (uL) Contract: SAS No.: SDG No.: MW01 Lab Sample ID: W7326 Lab File ID: W7326D2 Date Received: 03/08/93 Date Analyzed: 03/18/93 Dilution Factor: ____3.3 Soil Aliquot Volume: ___ .(uL) Number TICs found: CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L CAS NUMBER COMPOUND NAME RT EST. CONC. Q FORM I X-TIC i oooiBO: TUT OO4 1481 3/90 CO cDo DATA FROM FILE: W732GD2 SCANS 45 TO 720 ACQUIRED: 03/18/93 18:52:00 KWOIOCX CALI: W732602 #3 SAMPLE: CLP, 53554, MW81,\tySU8?, LOW,WATER, UU7326,UOA,EPA, CONDS.i I50DA:25ML OLU01 AMBIENT PURGE W/ 5PPB IS & SS I————————I 100.02 ( 349696.) CM ,.,-3 CD •^ O O 103 3:20 200 J 6:40 300 10:00 CI10 1,4-DIFLUOROBENZENE <IS#1> 400 J 13:20 500 4 16:40 K CI26 1,4-DICHLOROBENZENE-D4 600 J 20:00 700 J m* CI28 CHLOROBENZEHE-D5 <IS#2> CS18 4-BROMOFUJOROBEHZENE <SS> 0067 *ntitation Report File: VV7326D2 Csta: VV7326D2. TI "3/18/93 10:52:00 ^rple: CLP, 53554, MWO 1 > £JW«TD?, LOW, WATER, VV7326, VOA, EPA, ': 3-ds. : I500A:25ML 01. V01 AMBIENT PURGE W/ 5PPB IS & SS ••-': -mula 1 5ML->50ML: l->3. 33 Instrument: I500A Weight: 0.000 ~.:mitt*c by: ITEK Analyst: RJL Acct. No : 53554 - 'jUNT=«isEA *• REF AMNT/(REF AREA * RESP FACT) '•'••.-•p. fee. from Library Entry CIlO 1, 4-DIFLUOR03ENZENE CI2Q CHLORCSENZENE-D5 (IS#2) CI2.*-- 1, 4-DICHLOROBENZENE-D4 CSlO 4-3ROMOFLUOROEENZEME (SS) CO 10 CHLOROMETHANE *^ C015 BROMOMETHANE CC20 VINYL CHLORIDE # C025 CHLOROETHAK'E C030 METHYLENE CHLORIDE C03C- ACETONE C110 2-3UTANONE C20C- 4-f1ETHYL-2-PENTANONE C21O 2-HEXANONE C037 BROnOCHLOROMETHANE CO !0 CARBON DISULFIDE CC45 1, 1-DICHLOROETHENE # C050 1, 1-DICHLOROETHANE ** C053 TRAf-s'S-1, 2-DICHLOROETHENE COiO CHLOROFORM * C063 1, 2-DICHLOROETHANE C115 1 , 1 , l-TRICHLOROETHAKE C120 CARSON TETRACHLORIDE C130 3ROKODICHLOROMETHAWE CI40 1, 2-DICHLOROPROPANE * C143 CIS-1, 3-DICHLOROPROPENE C15O TRICHLOROETHENE C155 DIBROMOCHLOROMETHANE CliO 1, 1, 2-TRICHLOROETHANE C165 BENZENE C172 TRAMS-1, 3-DICHLOROPROPENE C17A 1, 2-DIBROMOETHANE C130 BROMOFORM ## C220 TETRACHLOROETHENE C225 1, 1, 2, 2-TETRACHLOROETHANE ** C230 TOLUENE * C235 CHLOROBENZENE C240 ETHYL BENZENE * C245 STYRENE C25O M/P XYLENE C2C-2 0- XYLENE C05-1 CIS-1, 2-DICHLOROETHENE C253 1, 3-DICHLOR03ENZENE C25'! 1, 4-DICHLOROBENZENE C255 1, 2-DICHLORCBENZENE C261 1, 2-DIBROMO-3-CHLOROPROPANE I 0001504 TUT O04 1483 m/i Scan 114 184 117 373 150 518 95 439 NOT FOUND NOT FOUND 62 4O NO I FOUND £•! 71 NQT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND 96 73 NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND 9^ 201 NOT FOUND NOT FOUND NOT FOUND NUT FOUND NOT FOUND NOT FOUND lei 325 NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NUT FOUND 9 4> 112 NOT FOUND NOT FOUND NOT FOUND NOT FOUND Ret'iL) Rati 6 08 1 . OO 1 2 26 1 . 00 17: 16 1. 00 14 38 1. 00 1: 18 1: 38 1 20 1 00 1: 32 Time Ref RRT 6: 08 1 1 000 12: 26 2 1. 000 17: 16 3 1. 000 14: 38 1 2. 386 1: 20 1 0 217 2: 22 1 0 386 2: 36 10 424 6: 42 2 0 539 10: 50 2 0 871 3: 44 1 O. 609 o RRT<L) Ratio 1 . OOO 1 . 00 1 . 000 1 . OO 1 . 000 1 . OO 2. 386 1. 00 0 212 0. 239 0. 217 1. 00 0 250 Meth A BB A DB A BB A DB A DB A BB A BB A DB A BB A BB Afr.nt 5. 00 5. 00 5. 00 4. 68 0. 11 224 0.99 0.391 0.99 1.33 Area(Hght) Air.ount 11523. 5. 000 UG/L 7781. 5. 000 UG/L 4762 5. 000 UG/L 6596. 4. 685 UG/L 175. 1 163. 0. Ill UG/L 1 331 UG/L 104. 0. 090 UG/L 139046. 8057 8. 670 UG/L XTot 4. 17 4. 17 4. 17 3. 91 0. O9 1 . 1 1 0. 08 14. 361 UG/L 11. 98 75. 752 UG/L 63. 19 7. 23 .t (L) 5. 00 5 00 5 OO 5. 00 R. Fac R. Fac <L) Ratio 1.000 1 000 1.00 1. 000 1 000 1. 00 1.000 1.OOO 1.00 0. 572 0. 611 0. 94 •5 00 0. 015 0. 685 0. 02 5 00 0. 101 0. 379 0. 27 L0001505 90910001 c-1 o -fa 03 CJi CZ. I CO* 0 669 0 00 £ i9 '8 00 I ST 'SI 081 I OZB YI G O ' S ii. "SZ. 00 S 2 £66 0 C93 2 00 S 9C *r\ 00 20 0 TOS 0 600 '0 00 S 600 00 I ISO 200 i!96 9£6 609 201 8*0 ^01 i.20 COO C8£ 60£ liS 60S 226 frCS 01 1 8=8 1?T6 6CS cGZ. 28£ 9fr9 cac 29C sts 069 fr2fr S6fr 92C CSC C99 irI6 ZLL S29 Z.CC I 'I 0 0 '0 00 I I I I T "I 0 I 0 00 I 0 0o 0 •Q '0 '0 00 T 0 0 '0 '0 0 0 0 0 00 I '0 •o '0 'O •o 0 •o 0 Ob 81 2t- Oo t?f? 2? 20 9^ 9r- 82 tr-fr 20 Ob 85 8c -y^> 9O ot- 22 2« 9O frl 20 917 OC 01 trl 9C 20 00 01 frO 23 BE OS frO •SI :i I :i:?l 91 •^ CI ;CI :CI :2I :2I ' 6 :5 I 01 ;CI U 01 £ ••DI : I I 9 6 / •3 : tr ! tr £ : t' ..2 :£ • ^ • /j^ t : ; i :6 '•€ •E 6900 3/18/93 1O:52:59 Acquisition started .3/18/93 10:53:02 •r quire Run 0: VV7326D2 0/18/93 10:53:00 + 0: OO^^Free sectors: 12044 a:rple: CLP, 53554, MW01, MW#«2, LOW, WATER, VV7326, VOA, jt.ds. : I500A:25ML OLV01 AMBIENT PURGE W/ 5PPS IS t rmula 15ML->5OML: l->3. 33 Instrument: I5OOA emitted by: ITEK Analyst: RJL 0070 Starting Scan: 0 of 720 ERA, SS Weight: 0. OOO Acct. No: 53554 Desc RR *** GC not ready and being stabilized *** Elapsed time : 0. 0 Min Terr.p Rate (C/min) Time (minutes > (DegC) 35-~35 35-150 8. 0 150-150 ve A : closed period 6. 6 14. 3 3. 0 Valve B total 6. 6 20. 9 23. 9 open Injector A : GC oven : Transf ei—line: Ion source : 150 Deg C 35 Deg C 215 Deg C 180 Deg C *** Instrument parameters #** Post acquisition state -> Filament : Off Multiplier : Off /E: El < + > Centroid + Temp - Sequence: BF ( 2 time windows. ) £?q.uence Window n descriptor: a1 scan t ime: Number of cycles: 2 Filament is OFF Multiplier is ON BF Mass intervals: 2. OOO s 8 Positive ion mode. Master rate: 16 3 MFW: 80 MA: 15 TH: 1 # Lo mass Hi mass Time 33. 510 300. 590 2. 000 DL: Window # 2 n descriptor: al scan time: Number of cycles: Filament is ON Multiplier is ON BF Mass intervals: 2.000 s Positive ion mode. Master rate: 16 3 MFW: 80 MA: 15 TH: 1 Lo mass Hi mass Time 33. 510 300. 590 2. 000 BL: Calibration table: D:CAL021992 Interface number Instrument type Full scale mass Zero scale mass Intensity/ion Peak width Offset at low mass Offset at high mass Voltage settling time(ms> 20 u u 0 Q 1177 12 1000. mmu 0 mmu 0 mmu L000150 TUT 004 1486 Current instrument parameters. Positive ion mode Negative ion mode Resolution (high) 128.00 128.00 Resolution (low) 128.00 128.00 Quad offset 0. 00 0. 00 Quad programming 0. 00 0. 00 Lens offset -50. OO 50. OO Lens programming 0. 00 0. 00 Ext offset O. OO 0. OO Ext programming 0. 00 0. OO Collector 3O. 00 3O. 00 Ion offset 7. 00 -3. 00 Ion programming 5.00 -5. OO Rod polarity Reverse Normal Electron multiplier voltage: 984. Filament emission current: 750. Electrometer range: 10 *-7 Electrometer zero: 126.0 0071 zer Fore Pressure . . . . . . . . . . . : 0. 010 Torr :*parator/Source Pressure . . . . . . . . : 0 356 Torr 3/18/93 11:21:20 ACQUISITION COMPLETED Scans 1 to 720 Centroid vae Scans Sees Out of '•'. Peaks per scan per sec ,?ntroid 720 0.5 1440.0 0.0 5865. 8. 4. L0001503 TUT 004 1487 QUALITY CONTROL/QUALITY ASSURANCE DATA METHOD: CLP 3'90 OLV01 25ML PURGE 0072 DATAFILE: W7326D2 STANDARD: WSO31S TUNEFILE: W3FB0318 A.NALYSIS TIME: 03/18/93 ANALYSIS TIME: O3/ 18/93 ANALYSIS TIME: 03/18/93 1O: 52 8:29 8:20 INTERNAL STANDARD AREA CHECK »#**** INTERNAL STANDARD 10 1, A-DIFLUOROBENZEN 20 CHLOROBENZENE-D5 < £6 1, 4-DICHLQROBENZEN DATA AREA 11523. 7781. 4762. STD AREA 11210. 7723. 5477. RATIO 1037. ior/. 877. CLP ACCEPT RATIO 607. - 1407. 607. - 1407. 607. - 1407. STATUS ****** INTERNAL STANDARD RT CHECK ####** INTERNAL STANDARD 10 1, 4-DIFLUOROBENZEN 120 C!-ii OR03ENZENE-D5 ( :26 1.. 4 DICHLORODENZEN DATA SCAN 184 373 518 STD SCAN 184 373 518 DIFF CIN SEC 1 0 0 0 CLP ACCEPT DIFF STATUS +/- 20 SECS +/- 2O SECS +/- 20 SECS ****** SURROGATE RECOVERIES **##»* SURROGATE AMT FOUND AMT ADDED ;:0 4-EROMOFLUOROBENZE 4. 7 5. 0 •15 BRDHOMETHANE -0. 0 50. 0 20 Vlf^VL CHLORIDE * 0.1 50.0 PERCENT RECOVERY RECOV LIMITS STATUS 94 0 0 807. - 1207. 887. - 1107. 867. - 1157. failed failed TUT 004 .1488 LOC01503 P^OCED* -'RE: TCA DATA FILE: VV7326D2 REFERENCE: VI 11 .-:-*>?£ LIST: VI INI REPORT: VI IS -f .. —— STANDARDS — -ROC USED POSS 3 2 1 3 3 1 3 3 1 DIAGNOSTIC TIAL —— RMS 0 O O IZATION >< —— PROC 2O 16 15 OPTION PLUS UN USED 5 5 4 REPORT : 2 P KNOWNS POSS 1 1 1 ROCES — .— — "N RMS 0 0 O 3/1 SING OPTION: 3 < - LIST NAMES - STANDARD/UNKNOWN V1IS/V1UNKS1 VI IS/V1UNKS2 VI IS/V1UNKS3 3/18/93 11:24:OO 007" CD 45 COMPOUNDS PROCESSED, 7 FOUND SEARCH SEL DELI 184 373 439 ^urir '_/uiNu ^' .0 LIB ENTRY 1 V r :2 4 5 a -r s 9 1 0 - 1 1J 13 * ,* 1 *» 5 ^Ift 1 T » .' IS I? yn 21 iis.' 23 2" "? *5 «— --j 2 e -*• T 25 21? 20 "7 "\ -* * ?2 3Zf 24 39 26 13T 38 39 '•0 *s .»•**» •«r. 43 -i4 45 VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI 1 2 3 4 5 6 7 8 9 1O 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 REF -184 -373 -518 -439 -38 -44 -39 -46 -72 -62 -113 -289 -341 -122 -65 -60 -91 -78 -127 -155 -135 -143 -242 -218 -274 -201 -341 -321 -153 -311 -344 -420 -325 -451 -293 -375 -384 -413 -391 -412 -112 -496 -501 -519 -561 PRED 184 373 518 439 38 44 39 46 72 62 115 289 341 122 65 60 91 78 127 155 135 143 242 218 274 201 341 321 153 311 344 420 325 451 293 375 384 413 391 412 112 496 501 519 561 72 01 325 112 A PEAKS 1 1 1 1 1 1 1 - — — ^- i:.. a« i ^-x. — ———-.— FIT PEAKS M/Z T 981 . 114 l: 972 . 117 3 ISO 5 949 . 95 4 50 94 62 64 938 . 84 43 43 43 43 128 76 96 63 96 83 62 97 117 83 63 75 973 . 95 2 129 97 78 75 107 173 947 . 166 3 83 91 112 91 104 106 106 910 . 96 1 146 146 146 75 / CHRO —————— I TOP DELTA PEAKS 1 1 1 1 40 71 -1 78 112 L 0001510 I. T. ANALYTICAL SERVICES LIBRARY SEARCH REPORT PUR6EABLE VOLATILE ORGANICS ANALYSIS 0074 ^FA FILE: W7326D2 • 'QUIRED: O3/18/93 1O: 52 •-KDS. : I500A:25ML OLV01 i.SMITTEH BY: ITEK 00 AMBIENT PURGE W/ 5PP3 IS SS ANALYST: RJL ACCOUNT NO. 53554 COMPOUND JIG 1,4-DIFLUOROBENZENE <IS#1> ' r-o CHi OROBENZENE-D5 <IS#2> 126 1- 4-DICHLOROBENZENE-D4 <IS#3> 5iO 4-SROMOFLUOROBENZENE (SS) •>30 METHYLENE CHLORIDE ;50 TRICHLOROETHENE T:?0 TETRACHLOROETHENE :-f4 CIS-1, 2-DICHLOROETHENE SCAN DELTA (UG/ML) FIT SAT'D? 0 0 0 0 0 0 0 0 184 373 518 439 71 201 325 112 O 0 0 0 -1 0 0 0 5. 5. 5. 4. 1. 14. 75. 8. 000 000 000 685 331 361 752 670 981 972 0 949 938 973 947 910 LOC01511 TUT 004 1490 10 o TARGET COMPOUND COMPARISON o v-n- Hx* 1 ca 10 COMPOUND: C030 METHYLEHE CHLORIDE hfeft) -* RAW DATA: UU7326D2 #71 BASE M/Z: 44 RIC: 03/18/93 10:52 itm*>zc**- SAMPLE: CLP, 53554, MH81 JJU8W2, LOW, WATER, UU7326, UOA, EPA, COHOS.: I508A:23ML OLU81 AMBIENT PURGE W/ 5PPB IS 8, SS 100. 0n - 50.0: 18.4: 9.2: 30.3- 15.2: M/Z 100.0- 50.0: 0.0: -50.0: 100.0-' '' ' ' ' 1 ' ' ' ' ' ' ' ' ' 1 ' ' ' -t^H ENHANCED DATA: UU7326D2 ' • • • • I 1 ' " " • • 1 • • • • i • LIBRARY FILE: Ul #9 '• • • • 1 • • • • i 1 i • • 1 i < • • i • 1 30 40 I • • i • ' 1 . , . , . , . . 1 . . . . , . . . , 1 . , , , , . . . . 1 ... #71 BASE M/Z: 49 RIC: BASE M/Z: 49 RIC: 50 60 70 80 1 ... o 5448. g -J \—t-\ 1 i • • • 1776. r 3296. ff- •H O r 606. K - 3028. ' " • I 1 " ' 90 • i - 1000. ™" - — 3617T trOO IIIX <£> 0 TARGET COMPOUND COMPARISON o COMPOUND: C150 TRICHLOROETHEHE <?-p-^, ILtfH'i _ fT*l <* RAW DATA: W7326D2 03/18/93 10:52 w*"* #201 BASE M/Z: 95 RIC: 28768. vM+tjy~ 1- SAMPLE: CLP, 53554, MW01 , Mj&Htf, LOW, WATER, W7326, UOA, EPA, CONDS.: I500A:25ML OLU01 AMBIENT PURGE W/ 5PPB IS & SS 100.0- 50.0-; : . , 1 . Jl'l 1 . 1 Jl'[ ... .1 J ENHANCED DATA: W7326D2 96.6- 48.3-: : 1 1 1 1 .1 l't I . 1 1 ' 1 '[ 1 . . 1 1 — , i LIBRARY FILE: Ml #26 22.5- 11.2^ - 1 . 1 1 . . . . . . . I . . . . 1 . . . . M/Z 40 50 60 100.0- 50.0-; 0.0-: -50. Q-_ -100. 0-^ 1,1. . I I I . I — r*-» — . — | — . — . — . — i^ — i — H — i — . — i — i — r-r- •A— 1 — . — . — 1 — 1 — I — . — . — . — 1 — 1 — . — 1 — 1 — -- -H — 1— i — r— #281 BASE M/Z: 95 RIC: 27200. 1 — r*-i — . — | — i — . — , — i — i — HH — . — i — | — i — r -r- -^• — 1 — . — 1 — , — I — . — l^ — I — 1 — 1 — 1 — 1 — 1 — 1 — . . I I BASE M/Z: 95 PIC: 5336. i . . . . . . . . . . . . . . . i - i 88 1 ' , . l , ' ' • • ' " ' • " 1 • • • ' • • • 1 100 120 140 1 1. ... .... ...... • 1 •• CO —t iO •~>t O 4448. 4296. 1000. ;617T 1?OO in± r- o TARGET COMPOUND :OMPARISOH -T COMPOUND: C220 TETRACHLOROETHENE ^ 100. 0-: 50.0-: 91. 5- 45.7-. 2.3- M/Z 100.0^ 50.0-; 0.0: -50.0- 100.0-^ RAW DATA: UU7326D2 #325 BASE M/Z: 166 RIC: 350208. 03/18/93 10:52 m***-**- SAMPLE: CLP, 53554 , MW01 , MUWdZ, LOW, WATER, W7326 , UOA, EPA, CONDS.: I500A:25ML OLU01 AMBIENT PURGE W/ 5PPB IS & SS i l l l.i. j i i • | • i • i • i i * | • i • i • ENHANCED DATA: UU732GD2 #325 i l l l.i. i i • | • i • i • i • i LIBRARY FILE: Ul . , . ,. 1 1 I ' | ' 1 • 1 • ! • I 50 j..... 1. .1.... ... i.... 1 j #33 1 i , . 1 . , i ,I , , . . . 1 . , . , . , . , . , . , . , . , . , . , BASE M/Z: 166 RIC: 317952. , 1 • i • i • I • i • i • i • i • j • i • i • i • i • | BASE M/Z: 166 RIC: 5568. i | • i • i • i • i • I • i • i • i • i • 1 • i • i • i • i • i • i • i • i • i • 1 100 150 200 250 300 j. ——————— __ ——— ___ ——————————————————————————————————— 1 1 II 1 1 II II M 1 1 ooo -J - 44288. - r 40512. - r 1000. r **oum - trOO 00 o TARGET COMPOUND COMPARISON a-O o — ' COMPOUND: C054 CIS-1,2-DICHLOROETHENE Hf *"•* 100.0- 50.0-; 92.6: 46.3-; 26.6- 13. 3-: M/Z 100.0: 50.0-: 0.0-: -50.0-: •100.0- RAW DATA: UU7326D2 #112 ^t*^ BASE M/Z: 61 RIC: 13824. 03/18/93 10:52 u*>ots>'~*- SAMPLE: CLP, 53554, MW01 ,WM82, LOW, WATER, W7326, UOA, EPA, CONDS.: I500A:25ML OLU01 AMBIENT PURGE W/ 5PPB IS & SS ' • • • • [ • • • • I " • • ! • • • M"I|......... ENHANCED DATA: W7326D2 #112 LIBRARY FILE: VI #41 4- —— J BASE M/Z: 61 RIC: 11728. — , — i 4- .,,„.,.,..,....,....,....,...., - . . . . . . BASE M/Z: 61 RIC: 3240. i '. • • • j . . . • i 1 i . • 1 . . . i . M i . . , . , . . . . . 30 40 50 60 . . . . .... . 1 • '• ' " 1 '" ' '• ' " 1 " "i '" ' 1 " ' ''I 70 80 90 I i -t- • 1( ' 30 o o ~J 7 3764. T 3484. - 1000. - **oum - PVOCEDURE: FILTER/TIC DATA FILE: W7326D2 -TLTER SCAN PARAMETERS M.V NUMSER TICS '-TABLE ENTRIES 1AN TOLERANCE ••?•.'. RIC HT. C%D :'~ST SCAN ,-ST SCAN 1C THRESHOLD 10 3 10 35 1000 500 DIAGNOSTIC REPORT 3/18/73 18: 19: 99 0079 METHOD LIBRARY & LISTS TIC I.S. LIBRARY: NBS SEARCH PROC : PEAK FINDER PROC: TCA I. S. LL : FILE NAME LIST : LIBRARYIS SERLID VOME5 IS TCAREF2 '-.SGET COMPOUND ANALYSIS: TARGETS (QUAN LIST) 7 ;LTER PROCESSING: is PEAKS 3 <——————————————REJECT PEAKS- •OTAL < 1ST > LAST < MIN < SCAN -EAK.S SCAN SCAN RIC HT TOL 20 1 0 9 10 TOTAL TARGET PEAKS 10 > MAX ft PEAKS 0 TOTAL REJECTS 20 TOTAL TICS 0 0 T I C ' S FOUND. TUT OO4 1495 <- 000151G IX ORGANICS ANALYSIS DATA SHEET 0080 SAMPLE NO. Name: ITAS-KNOXVILLE Contract: SAS No . : MW02DL Lab Code : ITSTU Case No . : 53554 Matrix: (soil/water) WATER Sample wt/vol: 25. 0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ Heated Purge: N GC Column: DB-624 ___ ID: 0.53 (mm) Soil Extract Volume: ______ (uL) SDG No.: MW01 Lab Sample ID: W7326 Lab File ID: W7326D Date Received: 03/08/93 Date Analyzed: 03/17/93 Dilution Factor: ___20.0 Soil Aliquot Volume: __ CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L FORM I X-l 1-0001517 .(uL) 74-87-3 ————— 74-83-9 ————— 75-01-4 ————— 75-00-3 ————— 75-09-2 ————— 67-64-1 ————— 74-97-5 ————— 75-15-0 ————— 75-35-4 ————— 75-34-3 ————— 540-59-0 ———— 540-59-0 ———— 67-66-3 ————— 107-06-2 ———— 71-55-6 ————— 56-23-5 ————— 75-27-4 ————— *7 O Q *7 K. _ 10061-01-5 —— 79-01-6 ————— 124-48-1 ———— 79-00-5 ————— *-t 1 A •> *•» 10061-02-6 —— 106-93-4 ———— *7 rr 1C *> 108-10-1 ———— 127-18-4 ———— 79-34-5 ————— xuo y\j / —— Chloromethane —— Bromomethane —— Vinyl Chloride —— Chloroe thane —— Methylene Chloride ni*cz L*uiic —— Bromochloromethane —— Carbon Disulfide —— 1, 1-Dichloroethene —— 1 , 1-Dichloroethane —— trans-1, 2 -Dichloroethene —— cis-1 , 2 -Dichloroethene —— Chloroform —— 1 , 2-Dichloroethane —— 2 -Butanone —— 1 , 1 , 1-Trichloroethane —— Carbon Tetrachloride —— Bromodichloromethane —— 1, 2-Dichloropropane —— cis-1 , 3-Dichloropropene —— Trichloroethene —— Dibromochloromethane —— 1, 1, 2-Trichloroethane —— Benzene —— trans-1, 3-Dichloropropene ___ —— 1 , 2-Dibromoethane —— Bromoform —— 4-Methyl-2-Pentanone —— 2 -Hexanone —— Tetrachloroethene —— 1 ,1,2, 2-Tetrachloroethane ___ —— Toluene —— Chlorobenzene 20 20 20 20 62 100 20 20 20 20 20 37 20 20 100 20 20 20 20 20 57 20 20 20 20 20 20 100 100 300 20' 20 20 U U U U B* U U U U U U D U U U U U U U U D U U U U U U U U D U U U o- 3/90 IX ORGANICS ANALYSIS DATA SHEET Name: ITAS-KNOXVILLE_________ Contract: Lab Code: ITSTU Case No.: 53554 SAS No.: Matrix: (soil/water) WATER Sample wt/vol: 25.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ Heated Purge: N GC Column: DB-624___ ID: 0.53 (mm) Soil Extract Volume: ______(uL) 0081 SAMPLE NO. MW02DL SDG No.: MW01 Lab Sample ID: W7326 Lab File ID: W7326D Date Received: 03/08/93 Date Analyzed: 03/17/93 Dilution Factor: ___20.0 Soil Aliquot Volume: ___ .(uL) CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L 100-41-4 ——— - 100-42-5 ——— - 1330-20-7 —— - 541-73-1 ——— - 106-46-7 ——— - 95-50-1 ———— - —— Ethylbenzene —— Styrene - —— Xylene (total) —— 1 , 3-Dichlorobenzene —— 1 , 4-Dichlorobenzene —— 1 , 2-Dichlorobenzene —— 1 , 2 -Dibromo-3 -Chloropropane _ 20 U 20 U 20 U 20 U 20 U 20 U 20 U Q- FORM I X-2 OC01513 i- 3/90 IX ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS 0082 SAMPLE NO. Name: ITAS-KNOXVILLE Lab Code : ITSTU Case No . : 53554 Matrix: (soil/water) WATER Sample wt/vol: 25.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ GC Column: DB-624 ID: 0.53(mm) Soil Extract Volume: ______ (uL) Contract: SAS No.: MW02DL SDG NO.: MW01 Lab Sample ID: W7326 Lab File ID: W7326D Date Received: 03/08/93 Date Analyzed: 03/17/93 Dilution Factor: ___20.0 Soil Aliquot Volume: ___ .(uL) Number TICs found: 0 CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L CAS NUMBER COMPOUND NAME RT EST . CONC . "Q FORM I X-TIC TUT 004 1498 L 0001512 . ro oooo DATA FROM FILE: UU7326D SCANS 45 TO 728 ACQUIRED: 83/17/93 15:59:60 CALI: W7326D #3 SAMPLE: CLP,53554,MW01,MW02DL,LOW,WATER,UU7326,UOA,EPA, COHDS.: I508A:25ML OLU61 PURGE W/ 5PPB IS & SS 0- 168 _ 3:26 208 _ 6:40 388 . 18:88 488 . 13:28 588 J 16:48 600 _ 20:88 780 J _L CI19 1,4-DIFUJOROBENZEHE (IS#1) CI26 CHLOROBENZENE-D5 <IS#2) CS10 4-BROMOFLUOROBENZENE CSS> CI26 1,4-DICHLOROBENZENE-D4 (IS#3) j180.8Z < 66432.) C-J Lrt »—i Oo o h-3 i— Quantitation Report File: VV7326D 0084 Data: VV7326D. TI 03/17/93 15:59:OO "ample: CLP, 53554, MW01, MW02DL, LOW, WATER, W7326, VOA, EPA, onds. : I500A:25ML OLV01 PURGE W/ 5PPB IS & SS "Formula. 5ML-MOOML: 1->20 DI Instrument: I500A Weight: 0.000 Submitted by: ITEK Analyst: RJL Acct. No. : 53554 '-•QUNT=AREA * REF AMNT/CREF AREA * RESP FACT) fac. from Library Entry No Name 1 CI10 1,4-DIFLUORODENZENE (IS#1) 2 CI20 CHLOROBENZENE-D5 (IS#2) 3 CI26 1,4-DICHLOROBENZENE-D4 <IS*3> -1 CS10 4-BROMOFLUOROBENZENE <SS) 5 CO10 CHLOROMETHANE ** 6 CO15 BROMOMETHAME / C020 VINYL CHLORIDE * 3 C025 CHLOROETHANE 9 C03O METHYLENE CHLORIDE 10 C035 ACETONE 11 C110 2-BUTANONE 13 C205 4-METHYL-2-PENTANONE 13 C210 2-HEXANONE 14 C037 BROMOCHLOROMETHANE 15 C040 CARBON DISULFIDE :* C045 1,1-DICHLOROETHENE # 17 C050 1,1-DICHLOROETHANE ** .8 C053 TRANS-1,2-DICHLOROETHENE -19 C060 CHLOROFORM * 20 C065 1,2-DICHLOROETHANE 21 C115 1,1,1-TRICHLOROETHANE SS C120 CARBON TETRACHLORIDE 23 C130 BRCMODICHLOROMETHANE 24 C140 1,2-DICHLOROPROPANE * 35 C143 CIS-1,3-D1CHLOROPROPENE £6 C150 TRICHLOROETHENE r.7 C155 DIBROMOCHLOROMETHANE 2B C16O 1,1,2-TRICHLOROETHANE 29 C165 BENZENE 30 C172 TRANS-1,3-DICHLOROPROPENE 31 C176 DIBROMOETHANE 32 C1BO BROMOFORM ** 23 C220 TETRACHLOROETHENE 34 C225 1, 1,2,2-TETRACHLOROETHANE »* 2S C230 TOLUENE » 36 C235 CHLOROBENZENE 27 C240 ETHYL BENZENE * 38 C245 STYRENE 39 C?50 M/P XYLENE 40 C252 0-XYLENE *1 C054 CIS-1, 2-DICHLOROETHENE 42 C252 1, 3-DICHLOROBENZENE 13 C253 1, 4-DICHLOROBENZENE ^4 C25-1 1, 2-D I CHLOROBENZENE i3 ' C261 1, 2-DIBROMO-3-CHLOROPROPANE \- L000152A 0085 NO 1 2 3 4 5 £.*7 a •*•/ :o il 12 1 3 14 :5 a* 17 lo 19 20 21 22 23 24 25 24, 27 28 :9 "30 31 32 33 34 35 36 37 33 3* 40 •*i 42 43 44 45 m/z Scan 114 185 117 374 1 50 520 95 441 NOT FOUND NOT FOUND NOT FOUND NOT FOUND 84 73 43 64 NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND 95 203 NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND 166 326 NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND 96 114 NOT FOUND NOT FOUND NOT FOUND NOT FOUND Time Ref RRT Meth 6: 10 1 1. OOO A BB 12: 28 21. 000 A BB 17: 20 3 1. OOO A BB 14: 42 1 2. 384 A BB 2: 26 1 0. 395 A BB 2: OS 1 0. 346 A BB * 6: 46 2 O. 543 A BB 10: 52 2 0 872 A BB 3: 48 1 0. 616 A DB NO Ret(L) Ratio RRT(L) Ratio Amnt l 2 3 45 6 7 - 6 6:08 1.O1 12: 26 1. 00 17: 16 1. 00 1 4 : 38 1 . 00 1: 16 1: 28 1: 18 1: 32 1 OOO 1. 00 5. 00 1 . 000 1 . OO 5. 00 1.000 l.OO 5.00 2. 386 1 . 00 5. 73 0. 207 O. 239 0. 212 0. 250 Area(Hght) 11555. 8292. 5347. 7215. 251O. 101. 4682. 29301. 1593. Amnt(L) R 5. 00 5. 00 5. 00 5. 00 Amount 5. OOO UG/L 5. 000 UG/L 5. 000 UG/L 5. 729 UG/L 3. 125 UG/L 3. 468 U3/L 2. 867 UG/L 1. 859 UG/L '/.Tot 10. 63 10. 63 10. 63 12. 18 6. 64 7. 37 6. 09 15. 085 UG/L 32. 07 3. 95 R. Fac R. Fac(L) Ratio 1.000 1. 000 1. 00 1. 000 1. 000 1. 00 1.000 1. 000 1. 00 0. 624 0. 545 1.15 2: 24 1. Ol 0. 391 1. 01 3. 13 5. OO 0. 217 0. 348 0. 63 000152,: 0086 No 10 11 12 1 3 14 15 16 17 18 19 20 21 22 23 24 25 £6 27 28 29 30 31 32 23 34 35 36 37 ?S 39 40 -*l 42 4:3 41 45 Ret<L) 2:O4 3: 5O 9. 38 11: 22 4: 04 2: 10 2: 00 3: 02 2: 36 4: 14 5: 1O 4: 30 4: 46 8: 04 7: 16 9: 08 6: 42 11: 22 10: 42 5: 06 10: 22 11: 28 1 4 . OO 10: 50 15: 02 9: 46 12: 30 12: 48 13: 46 13: 02 13: 44 3: 44 16: 32 16: 42 17: 18 IS: 42 Ratio RRT(L) Ratio 1.O3 0.337 1.03 0. 625 0. 775 0. 914 0. 663 0. 353 0. 326 0. 495 0. 424 0. 690 0. 842 0. 362 0. 383 0. 649 0. 584 0. 735 1. 01 0. 539 1. 01 0. 914 0. 861 0. 410 0. 834 0. 922 0. 811 1. 00 0 871 1. 00 1. 2O9 0. 786 1. 005 1. O29 1. 107 1. 048 1. 105 1.02 0.609 1.01 0. 958 0. 967 1. 002 1. 083 Amnt Amnt(L) R. Fac R 3. 47 25. OO 0. 002 2. 87 5. 00 0. 565 15. 09 5. 00 3. 534 1. 86 5. 00 0. 138 F a c ( L ) Ratio 0. 013 0. 14 0. 985 0. 57 1. 171 3. 02 0. 371 0. 37 TUT OO4 15O2 L0001523 3/17/93 15: 59: 51 Acquisition started 0087 720 3/17/93 15:59:55 Acquire Run 0:W7326D Starting 03/17/93 15:39:00 + 0:OO Free sectors: 13OO2 Scan: O of Simple: CLP, 53554, MW01, MW02DL, LOW, WATER, VV7326, VOA, EPA, I2nds.: I500A:25ML OLVO1 PURGE W/ 5PPB IS & SS Formula: 5KL-MOOML: 1->20 DI Instrument: I500A Weight: 0.000 Submitted by: ITEK Analyst: RJL Acct. No: 53554 »»» GC 'J'-to It 1t2 3 -si Desc. : VI Temp <DeqC) 35- ~35 35-150 150 150 ve A : c 1 Rate <C/min > 8. 0 - osed not ready and being stabilized *** Elapsed time Elapsed time : 0. 0 Min Time (minutes) period 6. 6 14. 3 3. 0 Valve B : total 6. 6 20. 9 23. 9 open Injector A : GC oven : Transf ei—1 ine: Ion source : 150 Deg C 35 Deg C 215 Deg C 161 Deg C *** Instrument parameters ***• Post acquisition state -> Filament : Off Multiplier : Off ""ODE: El ( + > Centroid + Temp - Sequence: BF ( 2 time windows. ) Sequence Window # 1 Number of cycles: 28 Filament is OFF Multiplier is ON BF Mass intervals: 1 2. OOO s ran descriptor: otal scan time: Positive ion mode. Master rate: 16 f-PW: 3 MFW: 80 Int # Lo mass 1 33. 510 MA: 15 Hi mass 300. 590 TH: 1 Time 2. 000 BL: E ; an descriptor: ~:tal scan time: Window ft 2 Number of cycles: Filament is ON Multiplier is ON BF Mass intervals: 2 OOO s Positive ion mode. Master rate: 1 "=W: 3 MFW: 80 MA: 15 TH: 1 Int # Lo mass Hi mass Time 1 33. 510 300. 590 2. 000 DL: Calibration table: Interface number Instrument type Full scale mass Zero scale mass Intensity/ion Peak width Offset at low mass Offset at high mass Voltage settling time(ms) 20 D:CAL021992 0 Q 1177 1 2 1000. 0 0 u u mmu mmu mmu TUT OO4 .150; L 0001524 Current instrument parameters. Positive ion mode 0088 Resolution (high) Resolution (low) Quad offset Quad programming Lens offset Lens programming Ext offset Ext programming Col lector Ion offset Ion programming Rod polarity Elec 128. 00 128. 00 0. 00 0. 00 -50. 00 0. 00 0. 00 0. 00 30. 00 7. 00 5. 00 Reverse tron multiplier Negative ion mode 128. 00 128. 00 0. 00 0. 00 00 00 00 00 00 00 00 vol tage Filamsnt emission current Electrometer range Electrometer zero 50. O. O. O. 30. -3. -5. Normal 984. 750. 10 ~-7 126. 0 •nalyzer Fore Pressure ... " ;parator/Source Pressure 0. 01O Torr 0.349 Torr 3/17/93 16:28:03 ACQUISITION COMPLETED Scans 1 to 720 Centroid -^ri n t r o i d Scans 720 Sees 0. 4 Out of 144O. 0 '/. Peaks per scan per sec O. O 5287. 7. 4. 000152 TUT 004 15O4 QUALITY CONTROL/QUALITY ASSURANCE DATA 00&9 METHOD: CLP 3'90 OLV01 25ML PURGE DATAFILE: VV7326D STANDARD: WS0317 TUNEFILE: WBFB0317 ANALYSIS ANALYSIS ANALYSIS TIME: TIME: TIME: 03/17/93 03/17/93 03/17/93 15: 59 10: 48 9: 34 ****** INTERNAL STANDARD AREA CHECK ****** INTERNAL STANDARD 10 1, 4-DIFLUOROBENZEN :20 Clii OROBENZENE-D5 ( 26 1, 4-DICHLOROBENZEN DATA AREA 11555. 8292. 5347. STD AREA 9856. 6374. 4017. RATIO 1 1 77. 130% 1337. CLP ACCEPT RATIO 607. - 1407. 607. - 1407. 607. - 1407. STATUS ****** INTERNAL STANDARD RT CHECK ****** INTfcRNAL STANDARD C;10 1, 4 DIFLUOROBENZEN 1120 CHi OROBENZENE-D5 ( •: 126 1, 4-DICHLOROBENZEN DATA SCAN 185 374 520 STD SCAN 184 373 518 DIFF CIN SEC3 2 2 4 CLP ACCEPT DIFF STATUS «•/- 20 SECS +/- 20 SECS +/- 20 SECS SURROGATE #*#### SURROGATE RECOVERIES ****** AMT AMT PERCENT FOUND ADDED RECOVERY RECOV LIMITS STATUS :\0 4-SROMOFLUOROBENZE 5.7 5.0 115 15 BROMOMETHANE -0.0 50.0 0 '20 VINYL CHLORIDE * -0. 0 50. O 0 807. - 1207. 887. - 1107. 867. - 1157. failed failed TUT O04 .1505 DIAGNOSTIC KEPOKT TCA C-ATA FILE: W7326D REFERENCE: VI11 r.'A^E LIST: VI INITIALIZATION OPTION: 2 REPORT: VI IS 0090 3/lT/?3 17:S6:O7 PROCESSING OPTION: 3 ——— STANDARDS — •50C USED POSS 3 2 1 3 3 1 3 3 1 •—— >< —— PLUS UNKNOWNS RMS PROC USED POSS O 20 5 1 11 16 5 2 11 IS 4 1 —— >< - LIST NAMES - > RMS STANDARD/UNKNOWN 91 V1IS/V1UNKS1 13 V1IS/V1UNKS2 23 V1IS/V1UNKS3 45 COMPOUNDS PROCESSED, 7 FOUND SEARCH SEL DELI 186 374 441 VQ 1 2 3 -1 5 f-. 7 g ? 1C i 1 12 I 3 14 • 5 ^*i- 17 IS :*? 20 21 22 2^ 24 25 26 27 23 29 30 Ji 52 33 I* 4 35 2* 37 158 I<9 40 1 ^4i' 43 44 45 *urir~*. LI3 VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI • VI VI VI VI ENTRY 1 2 3 4 5 6 7 B 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 REF -184 -373 -518 -439 -38 -44 -39 -46 -72 -62 -115 -289 -341 -122 -65 -60 -91 -78 -127 -155 -135 -143 -242 -218 -274 -201 -341 -321 -153 -311 -344 -420 -325 -451 -293 -375 -384 -413 -391 -412 -112 -496 -501 -519 -561 PRED 186 374 518 440 40 46 41 48 74 64 117 290 342 124 67 62 93 80 128 156 137 145 244 220 275 203 342 322 155 312 345 421 326 451 294 376 335 414 392 413 114 496 501 519 561 73 -1 203 326 114 A PEAKS FIT PEAKS M/Z 1 979 . 114 1 977 . 117 150 1 1 946 . 95 50 94 62 64 1 1 979 . 84 43 43 43 43 128 76 96 63 96 83 62 97 117 83 63 75 1 966 . 95 129 97 78 75 107 173 2 963 . 166 83 91 112 91 104 106 106 1 887 . 96 146 146 146 75 TOP 185 374 520 441 73 64 203 326 , 114 '' . l_ I ———— :> TOP DELTA PEAKS -1 1 1 1 1 L000i:52' TUT OO4 1506 I. T. ANALYTICAL SERVICES LIBRARY SEARCH REPORT PURGEABLE VOLATILE ORGANICS ANALYSIS 0091 FILE: VV7326D "ACQUIRED: 03/17/93 15:59:00 ODMDS. : I5OOA:25ML OLV01 PURGE W/ SVDMITTED BY: ITEK COMPOUND 5PPB IS fc SS ANALYST: RJL ACCOUNT NO. 53554 SCAN DELTA (UG/ML) FIT ;20 i26 ?10 C35 I SO 220 054 1, 4-D I FLUOROBENZENE ( ISttl ) CHLOROBENZENE-D5 <IS#2> 1, 4-DICHLOROBENZENE-D4 <IS#3> 4-DROMOFLUOROBENZENE <SS) METHYLENE CHLORIDE ACETONE TRICHLOROETHENE TETRACHLOROETHENE CIS-1, 2-DICHLOROETHENE 185 374 520 441 73 64 203 326 114 -1 0 2 1 -1 0 0 0 0 5. 5. 5. 5. 2. 2. 2. 14. 1. 000 000 000 110 864 660 833 979 709 979 977 0 946 979 0 966 963 887 SAT'D? 0 0 0 0 0 0 O 0 0 L-0001523 TUT OO4 15O7 TARGET COMPOUND COMPARISON COMPOUND: C038 METHYLENE CHLORIDE RAW DATA: UU7326D #73 03/17/93 15:59 SAMPLE: CLP, 53554, MW01 , MW02DL/ LOW, WATER, W7326, UOA, EPA, CONDS.: I508A:25ML OLU01 PURGE W/ 5PPB IS & SS BASE M/Z: 49 RIC: 5088. i-n !— 100.0- 50.0-: 87.7- 43.9-: 75.0- 37.5-: M/Z 100.0- 50.0-; 0.0-: -50.0-i 100. 0J . . . . . . . . . 1 1 1 . . 1 1 1 . , . 1 1 ENHANCED DATA: UU7326D #73 . . . . 1 . . . . | i 1 .. 1 i i . 1 ,. 1 1 LIBRARY FILE: Ul #9 30 48 1 . . . . . . 1 .1 ' | * ' ' ' ' ' • ' ' 1 • ' ' ' ' ' ' ' ' 1 ' ' ' ' ' ' ' ' ' 1 ' ' ' ' 1 ' ' ' ' 1 ' ' ' * BASE M/Z: 49 RIC: 3856. | ' • • • ! • • • • | • • . . , . . - • | . . . . , . . . . | . . . , . | . . . BASE H/Z: 49 RIC: 3028. 50 60 70 80 98 . . , . , . . 1334. H70. 1090. CO CD O 76.8- 38.0": 25.7- 12.8-: 108.0n 58.8-: M/Z 100.0- 50.8-: 8.8-: -50. 0-: -100.0J mi TARGET COMPOUND COMPARISON COMPOUND: C835 ACETONE RAW DATA: W7326D #64 BASE M/Z: 03/17/93 15:59 SAMPLE: CLP,53554,MW01,MW02DL,LOW,WATER,UU7326,UOA,EPA, CONDS.: I508A:25ML OLV81 PURGE W/ 5PPB IS 8« SS 44 RIC: 1148. _J • i • i • i • i • i • i • i • i • i • | • i • i • i • i • i • ENHANCED DATA: UU7326D #64 i • i • i • i • i • I• i • I• I• i • i• i • I • 'i'i 1 i• i • i • i• i• i'i' i ' 1 ' i ' i ' i ' I ' l " i ' i ' 768. BASE M/2: 44 RIC: 383. F I' I' I ' |' I ' I' I' I' I' I ' I' I ' I ' |' I ' I' I ' I' I' I' I' I' I ' | ' I' I' I ' I' I' I' I ' I' I' |' I' > ' I' ' \' I' I' I' I ' I' I' I' I' I ' I' I ' I' I' I' [' I' I' I ' LIBRARY FILE: Ul #18 BASE M/Z: 43 RIC: 2136. 257. 1800. * 1 * 1 " I 18 28 38 48 50 68 i i - **OUT** OTST troo mi TARGET COMPOUND COMPARISON COMPOUND: C150 TRICHLOROETHENE 90.7: 45.3: 85.5- 42.7: RAW DATA: UU7326D #203 BASE M/Z: 95 03/17/93 15:59 SAMPLE: CLP, 53554, MN01 , MW02DL, LOW, WATER, W7326, UOA, EPA, CONDS.: I500A:25ML OLU01 PURGE W/ 5PPB IS 8, SS i I,,. , i 1 ENHANCED DATA: W7326D #203 r-r-r^-fi^ ^W . , , j i . . . . . . . . . 1 . . . . . 1 .1 4J.-J-,-.--,-, , . . . . , , , . , BASE M/Z: 95 ; 1 1 oo iO RIC: 6352. '' 'I " "1 " " 1' ' " ' ' RIC: 5680. k_Jo -J r 997. r 855. - LIBRARY FILE: 01 #26 BASE M/Z: 95 RIC: 5336. 189.9- 59.9-; M/H 100.0^ 50. 0: 0.0-i -50.0-i 100.0-^ I . i i . . . . . . . I . . . . I . . . . 40 50 e III .. I l l , 1 1. ... . . . . . . . . . . . 1 50 89 ii . . . i i i 1 • 1 • • • • • • • • • . • • • • 100 120 I I I . 1 . , . . . . , . . . . , . . . . , 140 150 160 • ., 1000. - **oum ID 05 r j -H 0 TARGET COMPOUND COMPARISON <? in GJ in _< COMPOUND: C220 TETRACHLOROETHENE oa ? 100. 0-q 50.0-; 81.5- 40.8-: 10.7- 5.4-i M/Z 100.0- 50.0-: 0.0-j -50.0-: -100.0-^ RAW DATA: UU7326D #326 BASE M/Z: 166 RIC: 65536. 03/17/93 15:59 SAMPLE: CLP, 53554, MW01 , MW02DL, LOW, WATER, UU7326, UOA, EPA, CONDS.: I500A:25ML OLU01 PURGE W/ 5PPB IS & SS 1 , 1 1 , . , l l . i I ' l ' i ' i ' i ' i ' i ' i ' i ' ENHANCED DATA: W7326D #326 1 .1 J l,i , l.i. II, 1 1. i i • | • i • r • i • i » | • i • i • 1 - i • | • i • LIBRARY FILE: VI #33 . , 1. , ll 1 i i • | • i • i • i • i • j • i • i • i • i - | ' i • 50 100 150 . , . . . 1 . , . , . , . , . , . , . , . , . , . , BASE M/Z: 166 RIC: 56384. . , . , - 1 • , - . . , . . . l . . . , . . . . - , BASE M/Z: 166 RIC: 5560. 200 250 308 .1. . .1 l.i. ..... 1,1.. l.l.i . . . ..i.i.i o o — I J — p - 9312. - r 7592. - r 1000. ; r **oum - CO O5 o TARGET COMPOUND C 'PAR I SON COMPOUND: 78.3: 39.1: 71.9: 35.9: 100.0- 50.0: M/Z 100.0: 50.0: 0.0: -50.0: -100.0-^ C054 CIS-1, 2-DICHLOROETHENE RAW DATA: UU7326D #114 BASE M/Z: 61 RIC: 3244. 03/17/93 15:59 SAMPLE: CLP, 53554, MW01 , MW02DL, LOW, WATER, UU7326, UOA, EPA, CONDS.: I500A:25ML OLU01 PURGE W/ 5PPB IS 8, SS ———— 1 1 1 —— ENHANCED DATA: W7326D #114 I I . LIBRARY FILE: Ul #41 jL, ———— , — , ———— L, — J BASE M/Z: 61 RIC: 2644. BASE M/Z: 61 RIC: 3240. i . ^ i 30 40 59 60 70 80 90 100 ., . ,. , , ,. . i CO 00 783. 719. 1000. r **oum PROCEDURE: FILTER/TIC :ATA FILE: W7326D "iLTER SCAN PARAMETERS DIAGNOSTIC REPORT 3/18/93 18: 13: O2 _^AX. NLT1DER TICS: '.'.-TABLE ENTRIES: f'3AN TOLERANCE : ••;r«. RIC HT. L7.1: ••JRST SCAN : ..-1ST SCAN : -[C THRESHOLD : 10 495 3 10 35 10OO 5OO 0097 METHOD LIBRARY ?< LISTS TIC I. S. LIBRARY NBS SEARCH PROC PEAK FINDER PROC TCA I. S. LL FILE NAME LIST LIBRARYIS SERLIB VOME5 IS TCAREF2 ••..«?GET COMPOUND ANALYSIS: TARGETS (QUAN LIST) 6 ILTER PROCESSING: is PEAKS 3 TOTAL TARGET PEAKS 9 TOTAL < 1ST > LAST TEAKS SCAN SCAN 13 1 O REJECT PEAKS < MIN < SCAN RIC HT TOL 4 8 > MAX # PEAKS O TOTAL REJECTS 13 TOTAL TICS 0 0 TIC 'S FOUND. L 0001534 TUT 004 1513 IX ORGANICS ANALYSIS DATA SHEET Name: ITAS-KNOXVILLE_________ Contract: Lab Code: ITSTU Case No.: 53554 SAS No.: Matrix: (soil/water) WATER Sample wt/vol: 25.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ Heated Purge: N GC Column: DB-624___ ID: 0.53 (mm) Soil Extract Volume: ______(uL) 0098 SAMPLE NO. MW03FD SDG No.: MW01 Lab Sample ID: W7324 Lab File ID: W7324 Date Received: 03/08/93 Date Analyzed: 03/17/93 Dilution Factor: ____1.0 Soil Aliquot Volume: ___ CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L FORM I X-l L 0001535 .(uL) 74-87-3 ————— / ** o j y •-— — 75-01-4 ————— 75-00-3 ————— 75-09-2 ————— 67-64-1 ————— 74-97-5 ————— 75-15-0 ————— *^ r ** ^ 4 75-35-4— —— - — 75-34-3 ————— 540-59-0 ———— 540-59-0 ———— 107-06-2 ———— 71-55-6 ————— 56-23-5 ————— 75-27-4 ————— •7 O O T C 10061-01-5 —— 79-01-6 ————— 124-48-1 ———— 79-00-5 ————— •^ ^ .* *•» *\ 71-43-2- —— —— — 10061-02-6 —— 106-93-4 ———— "7 C 1 C *} 108-10-1 ———— CQ1 *7D_£____ — 127-18-4 ———— 79-34-5 ————— i U O O O O —— Chloromethane —— Bromomethane —— Vinyl Chloride —— Chloroethane —— Methylene Chloride nl*>c L»UIIC —— Br omochl oromethane —— Carbon Disulfide —— 1, 1-Dichloroethene —— 1, 1-Dichloroe thane —— trans-1 , 2-Dichloroethene ____ —— cis-1 , 2-Dichloroethene —— Chloroform —— 1 , 2-Dichloroethane —— 2-Butanone —— 1 , 1 , 1-Trichloroethane —— Carbon Tetrachloride —— Bromodichloromethane —— 1, 2-Dichloropropane —— cis-1 , 3-Dichloropropene —— Trichloroethene —— Dibromochloromethane —— 1 , 1 , 2-Trichloroethane —— Benzene —— trans-1, 3-Dichloropropene —— 1 , 2-Dibromoethane —— Bromoform —— 4-Methyl-2-Pentanone —— 2-Hexanone —— Tetrachloroethene —— 1/1/2 , 2-Tetrachloroethane ___ —— Toluene —— Chlorobenzene 1 l l 1 l 5 1 1 1 1 1 12 1 1 5 1 1 1 1 1 4 1 1 1 1 1 1 5 5 7 i. 1 1 Uu Uuuuuuuuu uuuuuuuu uuuuuuuu uuu 3/90 13 h- IX ORGANICS ANALYSIS DATA SHEET 0099 SAMPLE NO. Name: ITAS-KNOXVILLE Contract: SAS No.: MW03FD Lab Code: ITSTU Case No.: 53554 Matrix: (soil/water) WATER Sample wt/vol: 25.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ Heated Purge: N GC Column: DB-624 _____ ID: 0.53 (mm) Soil Extract Volume: ______ (uL) SDG No.: MW01 Lab Sample ID: W7324 Lab File ID: W7324 Date Received: 03/08/93 Date Analyzed: 03/17/93 Dilution Factor: ____1.0 Soil Aliquot Volume: ___ .(uL) CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L 100-41-4 ——— • 100-42-5 ——— • 1330-20-7 —— • "541-73 — 1 ———— •S *t -L i «/ J~ 106-46-7 ——— • 95-50-1 ———— • 96-12-8 ———— • —— Ethylbenzene —— Styrene - —— Xvlene ( total) —— 1 , 3-Dichlorobenzene —— 1 , 4-Dichlorobenzene —— 1 , 2-Dichlorobenzene —— l,2-Dibromo-3-Chloropropane _ 1 1 1 1 1 1 1 uuuuuuu TUT FORM I X-2 004 1515 LOC0153G 3/90 IX ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS ^—uab Name: ITAS-KNOXVILLE_________ Contract: Lab Code: ITSTU Case No.: 53554 SAS No.: Matrix: (soil/water) WATER Sample wt/vol: 25.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ GC Column: DB-624 ID: 0.53(mm) Soil Extract Volume: ______(uL) 0100 SAMPLE NO. MW03FD SDG No.: MW01 Lab Sample ID: W7324 Lab File ID: W7324 Date Received: 03/08/93 Date Analyzed: 03/17/93 Dilution Factor: ____1.0 Soil Aliquot Volume: ___ .(uL) Number TICs found: CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L CAS NUMBER COMPOUND NAME RT EST. CONC. Q FORM I X-TIC L0001537 3/90 TUT 004 1516 DATA FROM FILE: UU7324 SCANS 45 TO 720 ACQUIRED: 83/17/93 14:17:90 CALI: W7324 #3 SAMPLE: CLP,53554,MW81,MW83FD, LOM,WATER,UU7324,VGA,EPA, CONDS.: I509A:25ML GLU01 PURGE W/ 5PPB IS & SS N •H ITj CD CO 10 100.02 < 34048.) I- O 380 _| 16:08 400 _ 13:20 500 J 16:40 600 J 20:08 700 _ m* CI10 1,4-DIFLUOROBENZENE (IS#D CI20 CHLOROBEHZEHE-D5 (IS#2) CS19 4-BROMOFLUOROBENZEhC (SS) CI26 1,4-DICHLORQBENZENE-D4 (IS#3) Quantitat ion Report File: VV7324 0102 Data: VW324. TI 03/17/93 14: 17: 00 7 a m p l e : CLP, 53554, MW01, MW03FD, LOW, WATER, VV7324, VOA, EPA, onds. : I50OA:25ML OLV01 PURGE W/ 5PPB IS & SS 5ML AMBIENT PURGE Instrument: I500A W e i g h t : by: ITEK Analgst: RJL Acct. No. »VDUNT=AREA # REF AMNT/<REF AREA # RESP FACT) -**p. fac. from Library Entrg 1,4-DIFLUOROBENZENE (IS#1> CHLOROBENZENE-D5 <IS#2) 1,4-DICHLOROBENZENE-D4 <IS#3) 4-BROMOFLUOROBENZENE (SS) CHLOROMETHAME ** BROMOMETHANE VINYL CHLORIDE * CHLOROETHANE METHYLENE CHLORIDE ACETONE 2-BUTANONE 4-METHYL-2-PENTANONE 2-HEXANONE BROMOCHLOROMETHANE CARBON DISULFIDE 1,1-DICHLOROETHENE * 1.1-DICHLOROETHANE ** TRANS-1, 2-DICHLOROETHENE CHLOROFORM * 1.2-DICHLOROETHANE 1,1,1-TRICHLOROETHANE CARBON TETRACHLORIDE BROMODICHLOROMETHANE 1,2-DICHLOROPROPANE * CIS-1,3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE BENZENE TRANS-1,3-DICHLOROPROPENE DIBROMOETHANE BROMOFORM ** TETR AC HLOROETHENE 1,1,2,2-TETRACHLOROETHANE *# TOLUENE * CHLOROBENZENE ETHYL BENZENE * STYRENE M/P XYLENE 0-XYLENE CIS-1,2-DICHLOROETHENE 1,3-DICHLOROBENZENE 1, 4-DICHLORODENZENE 1,2-DICHLOROBENZENE 1, 2-DIBROMO-3-CHLOROPROPANE 0. 000 53554 p 1 » '•»!.• • I cJ3 4 5 6 ? 3 9 10 11 12 13 14 15 16 17 IB •19 20 2i -. ~i c. «. r.'— ' 54 25 26 27 28 29 30 31 32 .33 34 35 36 37 33 39 40 -1 42 43 44 '<*?* Name CI10 CI20 CI26 CS10 C010 CO15 C020 C025 C03O C035 C110 C205 C210 C037 CO 40 C045 C050 C053 C060 C065 C115 C120 C130 C140 C143 C150 C155 C160 C165 C172 C176 C180 C220 C225 C230 C235 C240 C245 C250 C252 C054 C252 C253 C254 C261 TUT 004 1518 L 0001539 0103 f<o 1 2 3 , 4 5 6 7 S ••? 10 11 ' "J -. 3 14 IS 16 t *T IS "49 r.O 21 22 23 24 25 56 27 28 •? "00 31 32 "3 34 35 36 37 3S 39 40 *l 42 43 -'•••1 45 m/ z 114 117 15-0 95 NOT NOT NOT NOT 84 NOT NOT NOT NOT NOT 76 NOT NOT 96 83 NOT NOT NOT NOT NOT NOT 95 NOT NOT NOT NUT NOT NOT 166 NOT NOT NOT NOT NUT NOT NOT 96 NOT NOT NOT NOT Scan Time Ref RRT Meth 185 6: 10 1 1. 000 A BB 374 12: 28 21. 000 A BB 519 17: 18 3 1. 000 A BB 440 14: 40 1 2. 378 A BB FOUND FOUND FOUND FOUND 72 2: 24 1 O. 389 A BB FOUND FOUND FOUND FOUND FOUND 65 2: 10 1 0. 351 A BB FOUND FOUND 79 2: 38 1 0. 427 A BB 128 4: 16 1 0. 692 A BB FOUND FOUND FOUND FOUND FOUND FOUND 202 6: 44 2 0. 540 A BB FOUND FOUND FOUND FOUND FOUND FOUND 326 10: 52 2 0. 872 A DB FOUND FOUND FOUND FOUND FOUND FOUND FOUND 113 3: 46 1 O. 611 A BB FOUND FOUND FOUND FOUND Area(Hght) 12529. 8361. 5223. 6885. 598. 638. 262. 356. 6036. 14314. 10811. c Ret(L) 1 2 3 43 6 T 1 1 1 6- 2: 7 . 4: 1: 1: 1: 08 26 16 38 16 28 18 Ratio 1. 1. 1. 1. 01 00 00 00 RRT(L) 1. 1. 1. 2. 0. 0. 0. 000 000 000 386 207 239 212 Ratio 1. 1. 1. 1. 00 00 00 00 Amnt 5. 5. 5. 5. 00 00 00 O4 1 : 32 0. 250 Amount 5. 000 UG/L 5. 000 UG/L 5. 000 UG/L 5. 042 UG/L 0. 687 UG/L 3. 665 UG/L '/.Tot 11. 43 11. 43 11. 43 1. 57 0. 157 UG/L 0. 36 0. 217 UG/L 0. 49 0. 160 UG/L 0. 37 8. 38 7. 308 UG/L 16. 70 11. 633 UG/L 26. 59 Amnt(L) R. Fac R.Fac(L) Ratio 5. 00 1. 000 1. 000 1. 00 5. 00 1. 000 1. 000 1. 00 5. 00 1. 000 1. 000 1. 00 5 00 0. 550 0. 545 1. 01 0. 69 5. 00 0. 048 0. 348 0. 14 L 0001540 TUT OO4 1519 •No Ret<L) 10 11 '2 3 "14 1 5 16 I -T '. S ™ w « • •TO £» A £2 23 ^4 25 r.i 27 28 re 30 31 32 -'3 24 35 3i 37 3 40 il 4 A 43 44 45 2: 3: 9: 11: 4: 2: 2: 3: 2: 4: 5: 4: 4: 8: 7: 9: 6: 11: 10: 5: 10: 11: 14: 1O: 15: 9: 12: 12: 13: 13: 13: 3: 16: 16: 17: 18: O4 50 38 22 04 10 00 02 36 14 10 30 46 04 16 08 42 22 42 06 22 28 00 5O 02 46 30 48 46 02 44 44 32 42 18 42 Ratio RRT<L) 0. 0. 0. 0. 0. 1.00 0. O. 0. 1.01 0. 1. 01 0. 0. 0. 0. 0. 0. 0. 1. 00 0. 0. 0. 0. 0. 0. 0. 1. 00 0. 1. 0. 1. 1. 1. 1. 1. 1.01 0. 0. 0. 1. 1. 337 625 775 914 663 353 326 495 424 690 842 362 383 649 584 735 539 914 861 410 834 922 811 871 209 786 005 029 107 048 105 609 958 967 002 083 Rati 0. 99 1. 01 1. 00 1. OO 1. 00 1. 00 0104 Amnt ArnnUL) R. Fac R.Fac(L) Ratio 0.16 5.00 0.051 1.624 0.03 0. 22 5. 00 0. 021 0. 483 0. 04 0. 16 5. 00 0. 028 0. 886 0. 03 3. 67 5. 00 0. 722 0. 985 0. 73 7. 31 5. 00 1. 712 1. 171 1. 46 11.63 5.00 0.863 0.371 2.33 TUT 004 1520 <-0001541 0105 3/17/93 14:17:08 Acquisition started _,3/17/93 14: 17: 12 ~<:iuire Run •••2/17/93 14:17:00 + 0:00 Free T f l ^ p l e : CLP, 53554, MW01 , MW03FD, LOW, C s n d s . : I5OOA:25ML OLV01 PURGE W/ : W7324 sectors: 13359 WATER, W7324, VOA 5PPB IS fc SS -:rmula: 25ML S.Smitted by: AMBIENT PURGE Instrument: I5OOA ITEK Analyst: RJL Starting Scan: 0 of EPA, Weight: Acct. No: 720 0. OOO 53554 :-T Desc VI - c- -3. Ten-p *** GC not ready and b e i n g s t a b i l i z e d *#* Elapsed time : 0. O Min Rate (C/min) Time (minutes) * (DegC) 1 35- 35 2 35-150 8. 0 3 150-150 a)ve A : closed period 6. 6 14 3 3. 0 Valve 3 total 6. 6 20. 9 23. 9 open Injector A : GC oven : Transfer-1ine: Ion source : 150 Deg C 36 Deg C 215 Deg C 181 Deg C *** Instrument parameters **# Past acquisition state -> Filament : Off Multiplier : Off ''3DE: El < + ) Centroid + Temp - Sequence: BF < 2 time windows. ) Sequence Window # 1 ".-. an descriptor: ;tal scan time: Number of cycles: Filament is OFF Multiplier is ON BF Mass intervals: 2. 000 s 28 Positive ion mode. Master rate: 16 3 MFW: 80 MA: 15 TH: 1 t # Lo mass Hi mass Time 1 33. 510 300. 590 2. 000 BL: £-»^uence Window # 2 Number of cycles: Filament is ON Multiplier is ON 5 • sn descriptor: BF Mass intervals: otal scan time: .000 Positive ion mode. Master rate: 16 ?u. 3 MFW: 80 MA: 15 TH: 1 BL: Int # Lo mass Hi mass Time 1 33. 510 300. 590 2. 000 Calibration table: D.CAL021992 Interface number Instrument type Full scale mass Zero scale mass Intensi ty/i on Peak width Offset at low mass Offset at high mass Voltage settling time(ms) 20 0 Q 1177 1 2 1000. 0 0 u u mmu mmu mmu 000154C TUT O04 1521 C-jrrent instrument parameters. Positive ion mode Peso lut i on (high) Resolution (low) Quad offset Quad programming Lens offset Lens programming Ext offset Ext programming Col lector Ion offset Ion programming Rod polarity Elec 128. 00 128. 00 0. 00 0. 00 -50. 00 0. 00 0. 00 0. 00 30 00 7. 00 5. 00 Reverse tr on mul t ip 1 i er Negative ion 128. 00 128. 00 0. 00 0. 50. 0. 0. 0. 30. -3. voltage Filemsnt emission current Electrometer range Electrometer zero 00 00 00 00 00 00 00 -5. 00 Norma1 784. 750. 10 ~-7 126. 0 0106 mode <n4lyzer Fore Pressure . . . •iparator/Source Pressure O. 010 Torr 0. 353 Torr 3/17/93 14:45:53 ACQUISITION COMPLETED Scans 1 to 720 Centroid Scans 720 Sees 0. 3 Out of 1440. 0 '/. Peaks per scan per sec 0. 0 3370. 5. 2. TUT 004 1522 L 000154 QUALITY CONTROL/QUALITY ASSURANCE DATA 0107 METHOD: CLP 3'90 OLV01 25ML PURGE DATAFILE: VV7324 STANDARD: WS0317 TUNEFILE: W3FB0317 ANALYSIS TIME: 03/17/93 ANALYSIS TIME: 03/17/93 ANALYSIS TIME: 03/17/93 14: 17 10: 48 9: 34 ****** INTERNAL STANDARD AREA CHECK ****** INTERNAL STANDARD 110 1, 4-DIFLUOROBENZEN 120 Clii QROBENZENE-D5 ( 356 1, 4-DICHLORODENZEN DATA AREA 12529. 8361. 5228. STD AREA 9856. 6374. 4017. RATIO 1 277. 131% 1307. CLP ACCEPT RATIO 607. - 1407. 607. - 1407. 607. - 1407. STATUS ****** INTERNAL STANDARD RT CHECK ****** INTERNAL STANDARD C I \0 1 , 4-DIFLUOROBENZEN CI20 CHI OROBENZENE-D5 ( C:26 1, 4-DICHLORODENZEN DATA SCAN 185 374 519 STD SCAN 184 373 518 DIFF CIN SEC 3 2 2 2 CLP ACCEPT DIFF STATUS +/- 20 SECS +/- 20 SECS +/- 20 SECS ****** SURROGATE RECOVERIES ****** SURROGATE AMT AMT PERCENI FOUND ADDED RECOVERY RECOV LIMITS STATUS 1210 4-SROMOFLUOROBENZE CO15 BROMOMETHANE CC20 VINS'L CHLORIDE * 5. O -0. 0 -0. 0 5. 0 50. 0 50. 0 101 0 0 807. - 1207. 887. - 1107. 867. - 1157. •Failed failed L - O O O J 5 4 4 TUT O04 1523 DIAGNOSTIC REPORT PKOCEDUftE: TCA DATA FILE: VV7324 REFERENCE: VI11 LIST: VI INITIALIZATION OPTION: 2 REPORT: VI IS 3/17/93 14:52:4O 0108 PROCESSING OPTION: 3 -—— STANDARDS ———— >< —— PLUS UNKNOWNS —— X - LIST NAMES - > -flOC USED POSS RMS PROC USED POSS RM3 STANDARD/UNKNOWN 3 3 3 45 CO 2 3 3 I-'.POUNDS : COMPOUND :>< •>c 1 2 3 4 5 * 7 S 9 1 V 11 1L- 13 145 -*6 17 IS 1s? 20 21 22 23 24 25 26 <£^ / 23 29 30 31 32 33 34 35 36 37 28 3S> •n A ~*2 43 44 45 LIE VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI • vi VI VI VI ENTRY 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 1 1 1 0 20 5 1 0 16 5 1 0 15 4 1 35 V1IS/V1UNKS1 O V1IS/V1UNKS2 O V1IS/V1UNKS3 O V- r PROCESSED, 7 FOUND REF -184 -373 -518 -439 -38 -44 -39 -46 -72 -62 -115 -289 -341 -122 -65 -60 -91 -78 -127 -155 -135 -143 -242 -218 -274 -201 -341 -321 -153 -311 -344 -420 -325 -451 -293 -375 -384 -413 -391 -412 -112 -496 -501 -519 -561 wtLnrC w ii PRED SEL DELTA PEAKS 185 185 . 1 374 374 . 1 519 440 440 . 1 3 8 . . . 4 4 . . . 3 9 . . . 4 6 . . . 72 72 1 6 2 . . . 115 29O 342 122 6 5 . . . 6 0 . . . 9 1 . . . 78 . 127 156 136 144 243 219 275 202 2O2 . 1 342 322 154 312 345 421 326 326 . 1 452 294 376 385 414 392 413 113 113 . 1 497 502 520 562 V£ SAT ""><! — FIT PEAKS M/Z 982 . 114 974 . 117 150 948 . 95 50 94 62 64 867 . 84 43 43 43 43 128 76 96 63 96 83 62 97 117 83 63 75 969 . 95 129 97 78 75 107 173 954 . 166 83 91 112 91 104 106 106 914 . 96 146 146 146 75 — CHRO — - TOP DELTA 185 374 519 440 . 72 65 79 128 202 326 113 PEAKS 1 1 1 1 1 1 1 1 1 1 1 L 0001545 I. T. ANALYTICAL SERVICES LIBRARY SEARCH REPORT PURGEABLE VOLATILE ORCANICS ANALYSIS 0109 FILE: VV7324 ACQUIRED: O3/17/93 14:17:00 (:3«DS. : I50OA:25ML OLV01 PURGE W/ 5PPB SUBMITTED BY: ITEK IS & SS ANALYST: RJL ACCOUNT NO. 53554 COMPOUND CIlO 1-4-DIFLUOROBENZENE (IS#1> C320 CHLOROBENZENE-D5 <IS#2> CI26 1.4-DICHLOROBENZENE-D4 (IS#3) CB10 4-DROMOFLUOROBENZENE <SS) C1SO TRICHLOROETHENE C220 TETRACHLOROETHENE COS4 CIS-1,2-DICHLOROETHENE SCAN DELTA (UG/ML) FIT 185 374 519 440 2O2 326 113 0 0 0 0 0 0 0 5. 5. 5. 4. 3. 7. 10. 000 000 000 497 622 257 699 982 974 0 948 969 954 914 SAT'D? O O 0 0 0 O 0 TUT 004 1525 L O C 0 1 5 4 G TARGET COMPOUND COMPARISON 100.0- 50.0-; 95. B- 47.8-; 87.9^ 43.9-: M/Z 100.6- 50.0-; 0.6-: -50.0-; ififl ft^ uunruunu: ci-jo iruLnLUKUt merit RAW DATA: UU7324 #202 BASE M/H: 95 RIC: 8512. 03/17/93 14:17 SAMPLE: CLP, 53554, MW01 , MW03FD, LOW, WATER, UU7324, UOA, EPA, CONDS.: I500A:25ML OLU01 PURGE W/ 5PPB IS & SS ll 1 i 1 1 1 | 1 |'T 1 —— T I" '1 I'-l11-! —— 1 —— 1 —— I —— —— 1 — T— T-"I "fT't 1 F"'T —— 1 1 1 T — | 1 1 ENHANCED DATA: W7324 #202 B< 1 » J--T—— TJ 1 1 LIBRARY 1 i FILE: Ul #26 ' • ' • ' • • I • • ' 40 1 1 . i 50 60 II. i 1 ' ' ' i • • ' ' | ' ' ' ' i > 1' Bt 1 . . . , . . . . , i . . . , . 1 . 1 u-rj-i — i— i i i i | i i i T i i i i i £E M/H: 95 RIC: 6976. i ^SE M/H: 95 RIC: 53: i 80 J6 • ' 1 • • • • • • • • • i • • • • 100 126 , . , . , . 1 ' ' 1 ' ' ' ' 1 ' 140 i * | o C)o —1 - 1138. | : 1088. K r 1000. mi «~4 0 TARGET COMPOUND COMPARISON 100. 0n 50.8-: 91.5- 45.8-: 22.1- 11. 1: M/Z 108.0: 50.0-: 0.0: -50. 0J •180. 0: COMPOUND: C228 TETRACHLOROETHENE RAW DATA: UU7324 #326 BASE 03/17/93 14:17 SAMPLE: CLP, 53554, MW01 , MW83FD, LOW, WATER, UU7324, UOA, EPA, CONDS.: I580A:25ML OLU01 PURGE W/ 5PPB IS & SS I i. . 1 1. 1. II, 1 i i • | • i • i • i • i i | • i • i • t • i • | • i • ENHANCED DATA: UU7324 #326 i 1 1, , 1. II, 1 4. , • , . BASE .1 i i • i • i • i • i • i ' i • i • i • i ' i • | • i • i • i • i • LIBRARY FILE: Ul #33 i. 1. 1. •- ll 1 BASE • i M/Z: 166 RIC: 34848. . , . , . , . , . | . , . , . , . , . M/Z: 166 RIC: 38624. . i . i . i . i • | • i • i ' i * i • M/Z: 166 RIC: 5568. CO "W 10 — " I ' l ' l ' l ' l ' I ' F ' I ' I ' I ' I ' I ' I ' 1 ' 1 ' 1 ' 1 ' 1 ' 1 ' 1 ' 1 ' I ' l ' l ' l ' l ' l ' l 58 180 158 280 258 380 Li 1.1 l.i . i.,. I.I., ... ..i.., . ........ .. ^•^o o oo - 4528. - - 4136. '- 7 1008. - 7 **oum - CM «—< «-^ O 83 5 T tr(-"-) J-nJ- TARGET COMPOUND COMPARISON COMPOUND: C054 CIS-L2-DICHLOROETHENE RAW DATA: UU7324 #113 03/17/93 14:17 SAMPLE: CLP,53554,MW01,MW83FD,LOW,WATER,UU7324,VOA,EPA, CONDS.: I580A:25ML OLU01 PURGE W/ 5PPB IS & 55 BASE M/Z: 61 RIC: 20128. 10 100.0- 50.0-j : , i . . ENHANCED DATA: 91.6- 45.8^ • , , , , , , , , , I"..,... LIBRARY FILE: 20.2- 10.1^ - . ... 1 .... M/Z 38 100.0- 50.0-: 0.0-: - -50.0- taa Ct- i ' " - r - 40 1 ... . UU7324 #113 i •' 1 '| .,..,... VI #41 • i • ' ' i i 1 i . ... BASE M/Z: 61 RIC: 16112. i BASE M/Z: 61 RIC: 3240. i . ..__ — i — r • • • • T • • i • • • • • • • • • i • • • • ' • • • • i • • • • ' • • ! • • • • ' 58 60 70 80 90 100 .... . i . . . . . , ...... 4952. 4536. 1000. - **OUm Quantitation Report File: W7324 Data: W/324. TI OJ/17/93 14: 17: 00 Sample: CLP,53554, MW01, MW03FD, LOW, WATER,VV7324,VOA,EPA, ends. : I5OOA:25ML OLV01 PURGE W/ 5PPB IS ?< SS _;.rmula: 25ML AMBIENT PURGE Instrument: I500A Weight: "Submitted by: ITEK Analyst: RJL Acct. No. -.'tOUNT-HCIGHT «• REF AMNT/(REF HEIGHT * RESP FACT) njsp. fac. from Library Entry •MO CAS # Name 1 0-00-0 CIO1 BROMOCHLOROMETHANE (I.S.#1) 2 0-00-0 CI10 1,4-DIFLUOROBENZENE (I.S.#2) 3 0-00-0 CI20 CHLOROBENZENE-D5 (I.S.#3> 4 124-38-9 CARBON DIOXIDE 5 107-91-5 ACETAMIDE, 2-CYANO- *-. 7440-37-1 ARGON ) Area<Hght) 7599. * 13027. * 11796. * 586752. * 1787. * 1618. * 0113 0. 000 53554 Jo 1 si 3& t 6 m/ 2 RIC RIC RIC RIC RIC RIC Scan 185 374 519 32 124 137 Time 6: 12: 17: 1: 4: 4: 10 28 18 O4 08 34 Ref 1 2 3 1 1 1 1. 1. 1. O. 0. 0. RRT OOO 000 000 173 670 741 Meth A A A A A A BD BB BB BB W VB Amount 5O. 000 UG/L 50. 000 UG/L 50.000 UG/L 3860. 640 11. 759 10. 646 •/.Tot 1. 24 1. 24 1. 24 95. 73 0. 29 O. 26 TUT 004 1529 L0001550 PROCEDURE: FILTER/TIC LATA FILE: VV7324 SCAN PARAMETERS DIAGNOSTIC REPORT 3/18/93 17:54:58 -•AX. NUMBER TICS 1J-TABLE ENTRIES 7- -AN TOLERANCE "IN. RIC HT. C'/.D -IRST SCAN -AST SCAN "1C THRESHOLD 10 495 3 1O 35 10OO 5OO 0114 METHOD LIBRARY !< LISTS TIC I. 5. LIBRARY NB5 SEARCH PROC PEAK FINDER PROC TCA I. S. LL FILE NAME LIST LIBRARYIS SERLIB VOME5 IS TCAREF2 TARGET COMPOUND ANALYSIS: TARGETS (QUAN LIST) 8 =ILTER PROCESSING: is PEAKS 3 <——————————————REJECT PEAKS- VOTAL < 1ST > LAST < MIN < SCAN PEAKS SCAN SCAN RIC HT TOL 20 0 O 5 12 1C PROCESSING: SCAN* PURITY TOTAL TARGET PEAKS 11 35 124 137 989 649 715 FIT 989 754 996 > MAX ft TOTAL TOTAL PEAKS REJECTS TICS 0 17 3 MW COMPOUND NAME [BEFORE TIC THRESHOLD] 44 CARBON DIOXIDE 84 ACETAMIDE, 2-CYANO- 40 ARGON TUT OO4 1530 LOOOlDSi T£ST 1700 mi in to ~* MID LIBRARY SEARCH (LIBRARYNB; DATA: UU7324 « 35 BASE ME: 44 *, 0 03/17/9314:17:00+ 1:10 CALI: 'JU7324 # 3 RIC: 493056. -* SAMPLE: CLP, 53554, MM01,MW03FD, LOW, WATER, W7324,UOA,EPA, ° CONDS.: I500A:25ML OLU91 PURGE W/ 5PPB IS & SS ^ ENHANCED (S 15B 2N 0T) , 1022 i SAMPLE C.02 1022 i H WT 44 3 PK 44 SANK 1 ft 32 ' PUR 989 r CARBON DI( r I I I JXIDE CAS# 124-38-9 r D.N2 NITROGEN OXIDE (N20> CAS# 10024-97-2 1022 i H WT 44 B PK 44 RANK 2 tt 37 ' PUR 985 C9.H21.N 1022 i .1 WT 143 B PK 44 RANK 3 1 6948 ' PUR 789 r i , i l-OCTAHAMINE, N-METHYL- CAS# 2439-54-5 r r _ • * _ _ * - —— ... -1 1 J • M/Z 20 40 60 30 100 120 140 ; ) ) 1700 mi CO 1000 SAMPLE C3.H4.0.N2 1000 M WT 84 3 PK 44 SANK 1 ft 491 PUR 649 :3.H3.02.H 1000 M WT 85 B PK 41 RANK 2 ft 562 PUR 597 C4.H8.02.H2 1000 i ,1 WT 116 B PK 41 RANK 3 ft 2799 PUR 443 M/Z MID LIBRARY SEARCH (LIBRARYHB) DATA: UU7324 # 03/17/93 14:17:00+4:03 CALI: UU7324 # SAMPLE: CLP,53554,MW01, MW03FD,LOW,WATER,UU7324,UOA,ERA, COHDS.: I500A:25ML OLU01 PURGE W/ 5PPB IS & SS ENHANCED (S 15B 2N 0T> 124 3 BASE It-Z: 44 RIC: 1342. CO o o o ACETAMIDE, 2-CYAHO- CASft 107-91-5 ACETIC ACID, CYAHO- CASft 372-09-8 2,3-BUTAHEDIOHE, DIOXIME CASft 95-45-4 r 20 30 , 40 50 60 70 89 90 100 110 D- .—• •*4 O 1600 SAMPLE .AR 1008 M WT 40 3 PK 40 .RANK 1 i 20 PUR 715 :9.H12.02.S 1000 H NT 184 B PK 40 RANK 2 I 15396 ?UR 183 C4.H4.0.N2 ,1 WT B PK RANK t M/Z HID LIBRARY SEARCH (LIBRARYNB) DrtTA: W7324 tt 137 03/17/93 14:17:00+4:34 • CALI: UU7324 * 3 SAMPLE: CLP,53554,MW01, MW03FD,LOW,NATER,W7324,UOA,EPA, CONDS.: I500A:25ML OLU01 PURGE W/ 5PPB IS & SS ENHANCED (S 15B 2N 0T> BuiE M l\ 40 RIC: 93. 10 10 »HO e> G5 ARGON CAS*» 7440-37-1 PHENOL, O-(PROPYLSULFINYL)- CAS# 29634-41-1 1H-IMIDAZOLE-2-CARBOXALDEHYDE CAS# 18111-08-7 ww • 96 96 3 169 81 r T —— ~ —— • —— • • "I1' • —— -T- —— • • I • • ••!•. • "^ —— , . . . . , , .-^-, —— , ———— r-^ —— ...... ———— , . . . . , . . . . , . . . . , . . . . , . . . —— r—— 20 40 60 30 100 120 140 160 18.0 100.0-1 RIC DATA: UU7324 #113 03/17/93 14:17:00 CALI: UU7324 #3 SAMPLE: CLP,53554,MW01,MW03FD,LOW,WATER,UU7324,UOA,EPA, COHDS.: I500A:25HL OLUQ1 PURGE W/ 5PPB IS & SS RANGE: G 1, 720 LABEL: N 2, 3.0 QUAH: A 2, 2.0 J 113 16082. 63393. bCANS 100 TO 260 <t Ki in 0 BASE: U 20, LO l-O »-H O CD O 16112. RIC 124 1803. 14070. 140 IbO SCAN ! IMF" 0119 ORGANICS ANALYSIS DATA SHEET P-^- Lab Name: ITAS-KNOXVILLE_________ Contract: Lab Code: ITSTU Case No.: 53554 SAS No.: Matrix: (soil/water) WATER Sample wt/vol: 25.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ Heated Purge: N GC Column: DB-624___ ID: 0.53(mm) Soil Extract Volume: ______(uL) MW03OR SDG No.: MW01 Lab Sample ID: W7321 Lab File ID: W7321 Date Received: 03/08/93 Date Analyzed: 03/17/93 Dilution Factor: ____1.0 Soil Aliquot Volume: ___ CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L .(uL) 74-87-3 —— —— 74-83-9 ————— 75-01-4 ————— •7 er f\ f\ *i 75-09-2 ------ 67-64-1 —— —— 74-97-5 ————— 75-15-0 ————— 75-35-4 ————— *7 C 1 A 1 540-59-0 ———— 540-59-0 —— — 67-66-3 —— —— 107-06-2 ———— 71-55-6 —— —— 56-23-5 —— —— 75-27-4 ————— 10061-01-5 —— 79-01-6 —— —— 124-48-1 —— ~ 79-00-5 ————— 11 jo *•» 71-43-2— ——— - 10061-02-6 —— 106-93-4 ———— 75—25-2———- —— / —/ tf •*? ** 108-10-1 ———— 591-78-6 ----- 127-18-4 ———— 79-34-5 ————— X U O O O J —— Chloromethane —— Br omomethane —— Vinvl Chloride —— Chl or oethane —— Methylene Chloride —— Acetone —— Bromochloromethane —— Carbon Disulfide —— 1 , 1-Dichloroethene —— 1, 1-Dichloroethane —— trans-1 , 2-Dichloroethene —— cis-1 , 2-Dichloroethene —— Chloroform —— 1, 2-Dichloroethane —— 2-Butanone —— 1 , 1 , 1-Trichloroethane —— Carbon Tetrachloride —— Bromodichloromethane —— 1 , 2-Dichloropropane —— cis-1, 3-Dichloropropene —— Trichloroethene —— D ibr omochl or ome tha ne —— 1 . 1 . 2-Trichloroethane —— Benzene —— trans-1, 3-Dichloropropene ___ —— 1 , 2-Dibromoethane —— Bromoform —— 4-Methyl-2-Pentanone —— 2 -Hexanone -— Tetrachloroethene —— 1 , 1 , 2 , 2-Tetrachloroethane ___ —— Toluene — — Chlorobenzene l l 1 1 2 5 1 1 1 1 1 11 1 1 5 1 1 1 1 1 3 1 1 1 1 1 1 5 5 9 1 1 1 U U U U Bi U U U U U U U U U U U U U U U U U U U U U U U U U Kl Ifj o 13 h- IX ORGANICS ANALYSIS DATA SHEET 'Lab Name: ITAS-KNOXVILLE_________ Contract: Lab Code: ITSTU Case No.: 53554 SAS No.: Matrix: (soil/water) WATER Sample wt/vol: 25.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ Heated Purge: N GC Column: DB-624 ID: 0.53(mm) Soil Extract Volume: ______(uL) 0120 SAMPLE NO. MW030R SDG No.: MW01 Lab Sample ID: W7321 Lab File ID: W7321 Date Received: 03/08/93 Date Analyzed: 03/17/93 Dilution Factor: ____1.0 Soil Aliquot Volume: ___ CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L .(uL) 100-41-4 ——— • 100-42-5 ——— • 1330-20-7 —— • 541-73-1 ——— • 106-46-7 ——— • 95-50-1 ———— • —— Ethylbenzene —— Styrene —— Xylene (total) —— 1 , 3-Dichlorobenzene —— 1 , 4 -Dichlorobenzene —— 1 , 2 -Dichlorobenzene —— 1 , 2-Dibromo-3-Chloropropane _ 1 1 1 1 1 1 1 uuuuuuu TUT 004 1536 0001557 FORM I X-2 3/90 IX ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS 0121 SAMPLE NO. -Lab Name: ITAS-KNOXVILLE__________ Lab Code: ITSTU Case No.: 53554 Matrix: (soil/water) WATER Sample wt/vol: 25.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ GC Column: DB-624 ID: 0.53(mm) Soil Extract Volume: ______(uL) Contract: SAS No.: MW030R SDG No.: MW01 Lab Sample ID: W7321 Lab File ID: W7321 Date Received: 03/08/93 Date Analyzed: 03/17/93 Dilution Factor: ____1.0 Soil Aliquot Volume: ___ Number TICs found: _0 CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L CAS NUMBER COMPOUND NAME RT EST. CONC. Q TUT OO4 1537 L 000155i FORM I X-TIC 3/90 CM CM DATA FROM FILE: UU7321 SCANS 45 TO 728 ACQUIRED: 03 17/93 12:24:00 CALI: W7321 »3 SAMPLE: CLP,53554,MW01,MW03GR,LOW,WATER,UU7321,UOA,EPA, CONDS.: I506A:25ML OLU01 PURGE W/ 5PPB IS & SS 180.0" < 41216.) COKI in 10 O CD 300 _ 10:00 400 J 13:20 500 16:40 600 20:00 'r- 13 I- CI10 1,4-DIFLUOROBENZENE <IS#1) CI28 CHLOROBENZENE-D5 <IS#2) CS10 4-BROMOFLUOROBENZENE (SS) CI26 L4-DICHLOROBENZENE-D4 (IS#3) 0123 - -•sntitation Report File: W7321 ta: VV7321.TI -3/ 17/93 12: 24: 00 -*-ple: CLP, 53554, MW01, MW030R, LOW, WATER, W7321, VOA, EPA, ;:ds. : I500A:25ML OLV01 PURGE W/ 5PPB IS & SS - mula: 25KL AMBIENT PURGE Instrument: I5OOA Weight: 0.000 .•emitted by: ITEK Analyst: RJL Acct. No.: 53554 - = AREA * REF A«NT/(REF AREA * RES? FACT) '•?-sp. -fac. from Library Entry Nr- Nsrr.e 1 CI1O 1,4-DIFLUORODENZENE (IS#1) 2 CI20 CHLOROBENZENE-D5 <IS#2) j CI26 1, 4-DICHLOROBENZENE-D4 <IS**3) 4 CS10 4-BROMOFLUOROBENZENE (SS) 5 CO10 CHLOROMETHANE ** •a C015 BROMOMETHANE / C020 VINYL CHLORIDE * 3 C025 CHLOROETHANE * C030 METHYLENE CHLORIDE :0 C035 ACETONE -. 1 C110 2-3UTANONE :2 C205 4-ME1HYL-2-PENTANONE :3 C210 2-HEXANONE : 1 C037 BROMOCHLOROMETHANE -5 C040 CARBON DISULFIDE ^.± C045 1, i-DICHLOROETHENE « 17 C050 1,1-DICHLOROETHANE ** 15 C053 TRANS-1,2-DICHLOROETHENE 1? C060 CHLOROFORM * L'j COd-5 1, 2-DICHLOROETHANE 21 C115 1,1,l-TRICHLOROETHANE 22 C120 CARBON TETRACHLORIDE S3 C130 BROMODICHLOROMETHANE .1-4 C14O 1, 2-DICHLOROPROPANE * 25 C143 CIS-1,3-DICHLOROPROPENE 5* C150 TRICHLOROETHENE 7.7 C155 DIBROMOCHLOROMETHANE eS C160 1,1,2-TRICHLOROETHANE -2«? C165 BENZENE 20 C172 TRANS-1,3-DICHLOROPROPENE 21 C176 1,2-DIBROMOETHANE '22 CISC BRCMOFORM ** 23 C220 TETRACHLOROETHENE -.4 C225 1, 1, 2, 2-TETRACHLOROETHANE ** ?S C230 TOLUENE * 3* C235 CHLOROBENZENE 2.-' C240 ETHYL BENZENE * ?8 C245 STYRENE Z-? C250 M/P XYLENE -•JO C252 O-XYLENE -I C051 CIS-i,2-DICHLOROETHENE Xi2. C253 1,3-DICHLDRODENZENE -3 C254 1, 4-DICHLORODENZENE TUT OO4 ^^ ^4 C255 1,2-DICHLOROBENZENE 45 C261 1,2-DIBROMO-3-CHLOROPROPANE L0001560 0124 '.'0 I s.' ^t £ 5 6 T 5 ^ t .*« j. *— * 1 1 t •*. i ~ 1 3 1 4 • ^ Ife -. y : 3 - .j zo 21 Z-S. 23 24 25 "*••*. . T ,. J 28 2'T ••Si"". l\ 3J> •;-3 24 "2 ^t 36 3^" — j — , .•! ,0 A; .1 .^ ts. 4:2 • ^ -* M ** -V •;.-. 1 2 j « B ' 6 ' ~r •3 -jj m/i Scan 114 1B3 117 373 150 518 95 439 NOT FOUND NOT FOUND NOT FOUND NOT FOUND 3* 72 NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND 76 64 NOT FOUND NOT FOUND 96 73 63 127 NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND 95 201 NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND 166 325 NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUMD NOT FOUND 96 1 12 NOT FOUND NOT FOUND NOT FOUND NOT FOUND Ret\L> Rati 6:08 0.99 12 26 1. 00 17 16 l.OO 14 38 1. 00 1 16 1 28 1 18 1 32 2 24 1 . 00 Time Ref RRT 6: 06 1 1. 000 12: 26 21. 000 17: 16 3 1. 000 14: 33 1 2. 399 2: 24 1 0. 393 2: 08 1 0. 350 2: 36 1 0. 426 4. 14 1 0 694 6: 42 2 0. 539 10: 50 2 0. 871 3:44 1 0.612 o RRT(L) Ratio 1 . 000 1 . 00 1 . 000 1 . 00 1 . 000 1 . 00 2.386 1.01 0. 207 0. 239 0. 212 0. 250 0.391 1.01 Meth A DD A DB A BD A DB A BB A BB A BB A BB A BB A BB A BB Amnt 5. 00 5. 00 5. 00 4. 60 1. 53 Area(Hgh 8587. 51-82. 3029. 4306. 914. 5O4. 201. 201. 2962. 1 1255. 6871. Amn t < L > 5 00 5. OO 5 OO 5. 00 5. 00 t) Amount 5. 000 UG/L 5. 000 UG/L 5. 000 UG/L 4. 601 UG/L 1. 531 UG/L 0. 181 UG/L 0. 242 UG/L 0. 132 UG/L 2. 902 UG/L 9. 272 UG/L 10. 788 UG/L R. Fac R. Fac(L) 1 . 000 1 . 000 1 . 000 1 . 000 1 . 000 1 . 000 0. 501 0. 545 •• 0. 106 0. 348 '/.Tot 11. 24 11. 24 11. 24 10. 35 3. 44 0. 41 0. 55 0. 30 6. 53 20. 85 24. 26 Ratio 1. 00 1. 00 1. 00 0. 92 0. 31 o *t \T> — h- L000156I 0125 •io JO il !2 13 14 • ^ 16 17 • o -/ ZO — •. i «. A ~. ~i S3 Z4 — , e a. -• r..t si / 55 Zr? 20 3i I'Z j>3 34 25 36 37 33 29 •'•• 0 -il 42 4 3 •^4 45 Ret<L) 2 3 9 11 4 j-^' 23 ••^ 4 5 A 4 S 04 50 38 22 04 10 00 02 36 14 10 30 46 04 7: 16 9: 08 6 : 42 11: 22 10: 42 5: 06 10: 22 11: 28 14: 00 10: 50 1 5 : 02 9: 46 12:30 12: 48 13: 46 13: 02 13: 44 3: 44 16: 32 16: 42 17: 18 18 42 Ratio RRT(L) Ratio O. 0. 0. 0. 0. 0. 98 0. O 0. 1.00 0. 1. 00 0. 0. 0. 0. 0. 0. 0. 1. 00 0. 0. 0. 0. 0. 0. 0. 1. 00 0. 1. o. 1. 1. 1. 1 1. 1. 00 0. 0. 0. 1. 1. 337 625 775 914 663 353 0. 99 326 495 424 1. 01 690 1.01 S42 362 383 649 584 735 539 1.00 914 S61 410 834 922 Sll 871 1. 00 209 786 005 029 107 048 105 609 1 01 958 967 002 083 Amnt 0. 18 0. 24 0. 13 2. 90 9. 27 10. 79 Amnt Amnt(L) R. Fac R. Fac(L) Ratio 5. 00 0. 059 1. 624 0. 04 5. 00 0. 023 0. 483 0. 05 5. 00 0. 023 0. 886 0. 03 5. 00 0. 572 0 985 0. 58 5. 00 172 1. 171 1. 85 5. 00 0. 800 0 371 !. 16 TUT 004 1541 L 0001562 3/17/93 12:24:30 Acquisition started 0126 -3/17/93 Acquire 03/17/93 12:24:00 Sample: CLP,53554 12: 24:33 Run 0:VV7321 Starting + 0:00 Free sectors: 13639 Scan: 0 of MW01, MW03QR, LOW, WATER, W7321, VOA, ERA, 720 :<?nds. : I5OOA:25ML OLV01 PURSE W/ 5PPD IS ?< S3 rormula: 25ML AMBIENT PURGE Instrument: I500A Submitted by: ITEK Analyst: RJL Weight: Acct. No: •»** GC not ready and being stabilized *#* Elapsed time : Time <minutes) SC Desc.: VI 3eq. Temp Rate * <DegC) (C/min) period total 1 35 ~35 - 6. 6 6. 6 2 35-150 8. O 14. 3 20. 9 3 150-150 - 3. 0 23. 9 valve A : closed Valve D : open 0. 000 53554 0. 0 Min Injector A GC oven Transfer-1ine Ion source 150 Deg C 35 Deg C 215 Deg C 181 Deg C *** Instrument parameters *** Post acquisition state -> Filament : Off Multiplier : Off :;1J[>E: El ( + ) Centroid + Temp - Sequence: BF ( 2 time windows. ) Sequence Window # 1 'c^n descr i p tor: otal scan time: Number of cycles: Filament is OFF Multiplier is ON BF Mass intervals: 2. 000 s 28 Positive ion mode. Master rate: 16 PW: 3 MFW: SO MA: 15 TH: 1 Int # Lo mass Hi mass Time 1 33. 510 300. 590 2. 000 BL: Sequence Window # 2 Number of cycles: Filament is ON Multiplier is ON Scjn descriptor: BF Mass intervals: "atal scan time: 2. OOO s Positive ion mode. Master rate: 16 I'PW: 3 MFW. SO MA: 15 TH: 1 BL: Int # Lo mass Hi mass Time 1 33. 51O 300. 590 2. 000 Calibration table: D:CAL021992 Interface number Instrument type Full scale mass Zero scale mass Intensity/ion Peak width Offset at low mass .Offset at high mass Voltage settling time(ms) 20 0 Q 1177 1 2 1OOO. 0 0 u u mmu mmu mmu TUT 004 154: I 0 0 0 1 D G Current instrument parameters. Positive ion 0127 Resolution < h i g h ) Resolution (low) Quad offset Quad programming Lens offset Lens programming Ext offset Ext programming Col lector Ion offset Ion programming Rod polarity 128. 128. 0. 0. -50. 0. 0. 0. 30. 7. 5. 00 00 00 00 00 OO 00 00 00 00 00 mode Negative ion mode 128. 00 128. OO 0. 00 0. 00 50. 00 0. 00 0. 00 0. 00 30. 00 -3. -5. Reverse Electron multiplier voltage Filament emission current Electrometer range Electrometer zero 00 00 Normal 984. 750. 10 ~-7 126. 0 Analyzer Fore Pressure ... Separator/Source Pressure 0.010 Torr 0. 356 Torr 3/17/93 12:5 ACQUISITION COMPLETED Scans 1 to 720 Centroid Centroid Scans Sees Out of X Peaks per scan per sec 720 0.4 1440. O 0.0 3051. 4. 2. TUT 004 1543 QUALITY CONTROL/QUALITY ASSURANCE DATA 0128 METHOD: CLP 3'90 OLV01 25ML PURGE DATAFILE: VV7321 STANDARD: WS0317 TUNEFILE: WBFD0317 ANALYSIS TIME: ANALYSIS TIME: ANALYSIS TIME: 03/17/93 03/17/93 03/17/93 10:48 9:34 *###*# INTERNAL STANDARD AREA CHECK **»*## INTtRNAL STANDARD HO 1, 4-DIFLUOROBENZEN 120 CHLOR03ENZENE-D5 ( 126 1, 4-DICHLOROBENZEN DATA AREA 8587. 5182. 3029. STD AREA 9856. 6374. 4017. RATIO 87% 8 IX 757. CLP ACCEPT RATIO 607. - 140'/. 60'/. - 140V. 607. - 1407. STATUS #»##*# INTERNAL STANDARD RT CHECK ##»**# INTFRNAL STANDARD C110 1, 4-DIFLUOROBENZEN •II2O CHIOROBENZENE-D5 ( t 26 1 .- 4-D I CHLOROBENZEN DATA SCAN 183 373 518 STD SCAN I 184 373 518 DIFF :IN SEC 3 2 0 0 CLP ACCEPT DIFF STATUS +/- 20 SECS +/- 20 SECS +/- 2O SECS #*###* SURROGATE RECOVERIES #**#** SURROGATE AMT FOUND AMT ADDED PERCENT RECOVERY RECOV LIMITS STATUS C510 4-3ROMOFLUOROBENZE 4. 6 5. 0 ;015 BROi-JOMETHANE -0.0 50.0 C020 VINYL CHLORIDE * -0.0 50.0 92 0 0 80V. - 1207. 887. - 1107. 867. - 1157. failed failed TUT 004 .1544 ^000156, I. T. ANALYTICAL SERVICES LIBRARY SEARCH REPORT PURGEABLE VOLATILE ORGANICS ANALYSIS 0109 FILE: VV7324 SQUIRED: O3/17/93 14:17:00 COWDS. : I5OOA:25ML OLV01 PURGE W/ 5PPB SUBMITTED BY: ITEK IS fc SS ANALYST: RJL ACCOUNT NO. 53554 CITO CT20 CI26 CS10 C15O 0220 C054 COMPOUND 1, 4-DIFLUOROBENZENE <IS*1> CHLOROBENZENE-D5 <IS#2) 1, 4-DICHLOROBENZENE-D4 (IS#3> 4-DROMOFLUOROBENZENE <SS> TRICHLOROETHENE TETRACHLOROETHENE CIS-1, 2-DICHLOROETHENE SCAN DELTA (UG/ML) FIT 185 374 519 440 202 326 113 0 0 0 0 0 0 0 5. 5. 5. 4. 3. 7. 10. 000 000 000 497 622 257 699 982 974 0 948 969 954 914 SAT'D? 0 0 0 0 0 0 0 TUT 004 1545 LOC0.154G o «-d «H O VOO ini 100.0- 50. 0-; 95.6- 47.8-; 87.9-: 43.9-: M/Z 100.6- 50.0-; 0.0-: -50.0-: Ida ft-^ TARGET COMPOUND COMPARISON COMPOUND: C150 TRICHLOROETHENE RAW DATA: W7324 #202 BASE M/Z: 95 RIC: 8512. 03/17/93 14:17 SAMPLE: CLP, 53554, MW01 , MW03FD, LOW, WATER, VU7324, UOA, EPA, CONDS.: I500A:25ML OLU01 PURGE W/ 5PPB IS & SS ., , i.. i. 1 . . | 1 1 1 1 1 1 1 | 1 1 1 1 I . 1 , I . . . | . , T I | I 1 ENHANCED DATA: W7324 #202 B< ,, 1,, 1 , . . , , . i . ... i | . . . . LIBRARY FILE: Ul #26 J . i i I 40 50 60 i i . I I I . i i ————————————————————— B* r \ . . . . . . . . . . . . . . 1SE M/Z: 95 RIC: 6976. >SI i . . . , . . , , , i , . . , . 1 . 30 , . , i, 1 . . . . i . . . . I . . . . E M/Z: 95 RIC: 53C )6 ' 1 • • • • • • • • • i • • • • 100 120 ' ' 1 1 ' 1 ' ' ' I 140 • . > • i • ' '•Sf10 o o 0 — 1 - 1138. r 1088. - 1000. | r **oum TARGET COMPOUND COMPARISON COMPOUND: C226 TETRACHLOROETHEHE m RAW DATA: UV7324 #326 63/17/93 14:17 SAMPLE: CLP/53554,MW01,MW03FD,LOW,WATER,UU7324,UOA,EPA, CONDS.: I500A:25ML OLU01 PURGE W/ 5PPB IS & SS BASE M/Z: 166 RIC: 34048. H- 100.0- 50. 0-; 91.5- 45.8-; 22.1- 11. 1-: M/Z 100.0- 50.0-; 0.0-: -50.0-: 100.0^ \—\ •4-* .1 I • (7— 1 i h II, 1 1 1 , . , . , . , . 1 . , . , . , . , . 1 , , . ENHANCED DATA: W7324 #326 1 i . h II, 1 , . | . r • , . , . | . , . , . , . , . | .,. LIBRARY FILE: Ml #33 i I ' 50 .1 . .. li 1 1 • 1 • 1 • 1 • 1 - 1 • 1 • 1 • , • 1 • 1 • 1 • 1 • 1 BASE M/Z: 166 RIC: 30624. 1 - , - , . | . , . , . , . , . , . , . , - i - , - | BASE M/Z: 166 RIC: 5560. , 1 . . . . . . . . ,....._.- i • i • i • i • i • i i i ' i • i • | • i • i • i • i • i • i • i • i • i • | • i • i • i • i - i 109 150 200 256 308 .1 . 1.1. I.I., ... ,.!.., . .. r 4520. 4136. 1800. - **OUT** CM 817'3T trOO mi ^ i rii\ COMPOUND: C054 100.0- 50.0-: 91.6- 45.8-: 20.2- 10. 1-: M/Z 100.0- 50.0-: 0.0-: -50.0-: •100.6^ , CIS-L2-DICHLOROETHENE RAW DATA: UU7324 #113 03/17/93 14:17 SAMPLE: CLP, 53554, MW01 , MW03FD, LOW, WATER CONDS.: I500A:25ML OLU01 PURGE W/ 5PPB .ti . .1 . . ..,.,.... ........ ENHANCED DATA: . i ......... . . . - ! . . LIBRARY FILE: i • 1 .1 1 i| . .. . i. . . i W7324 #113 i i , . Ul #41 .... I ......... I .. 30 40 . . . . JO 0 BASE M/Z: 61 RIC: 20128. ,UU7324,UOA,EPA, IS & 55 BASE M/Z: 61 RIC: 16112. BASE M/Z: 61 RIC: 3240. i ' 1 • ' ' ! | . . . . , . , , . -TT. 50 60 * * . * .1 ' i • < • • | ' i > ' i • ' " | • • ' • i • " • | • • ' ' i 70 80 90 L,...., i ..... 100 ^— • o - 4952. 7 4536. : 1000. - **OUT** - au«ntitation Report File: VV7324 Data: W/324. TI Oy/17/93 14: 17:00 Sample: CLP, 53554, M«01> MW03FD, LOW, WATER, VV7324, VGA, ERA, •?r,ds. : I500A:25ML OLV01 PURGE W/ 5PPB IS & SS ^;-rmula: 25ML AMBIENT PURGE Instrument: I500A Weight: Submitted by: ITEK Analyst: RJL Acct. No. 0113 0. 000 53554 * REF AMNT/(REF HEIGHT fac. from Library Entry RESP FACT) NO CAS a I 0-00-0 s o-oo-o 3 0-00-0 4 124-38-9 5 107-91-5 <-. 7440-37-1 ": o m /' 2 Scan Name CI01 BROMCCHLOROMETHANE (I.S. *1 > CI10 1, 4-DIFLUOROBENZENE (I.S. #2) CI20 CHLOROBENZENE-D5 (I.S. #3) CARBON DIOXIDE ACETAMIDE, 2-CYANO- ARGON J Time Ref RRT Meth 1 &' 3 4 5 ij R R R R R R 1C 1C 1C 1C 1C 1C 185 374 519 32 124 137 1 1 6: 2: 7. 1: 4: 4: 10 2S 18 04 08 34 12 3 1 1 1 1. 1. 1. 0. 0. 0. 000 000 000 173 670 741 A A A A A A BB BB BB BB VV VB Area<Hght) 7599. * 13027. * 11796. * 586752. * 1787. # 1618. * Amount 50. 000 UG/L 50. 000 UG/L 50.000 UG/L 3860. 640 11. 759 10. 646 XTot 1. 24 1. 24 1. 24 95. 73 0. 29 O. 26 TUT OO4 1549 L0001550 PROCEDURE: FILTER/TIC LATA FILE: VV7324 F1LTER SCAN PARAMETERS —AX. NUMDER TICS: 1O II-TABLE ENTRIES: 495 ^:AN TOLERANCE : 3 "IN. RIC HT. C'/.D: 10 -IRST SCAN : 35 _AST SCAN : 10OO •"1C THRESHOLD : 50O DIAGNOSTIC REPORT 3/18/93 17:54:58 0114 METHOD LIBRARY ?< LISTS TIC I. 5. LIBRARY: NBS SEARCH PROC : PEAK FINDER PROC: TCA I. S. LL : FILE NAME LIST : LIBRARYIS SERLIB VOME5 IS TCAREF2 TARGET COMPOUND ANALYSIS: TARGETS <QUAN LIST) 8 "ILTER PROCESSING: IS TOTAL TARGET PEAKS PEAKS 3 11 <——————————————REJECT PEAKS——————————————> VOTAL < 1ST > LAST < MIN < SCAN > MAX ft TOTAL TOTAL PEAKS SCAN SCAN RIC HT TOL PEAKS REJECTS TICS 20 O 0 5 12 0 17 3 TIC PROCESSING: SCAN* PURITY FIT MM COMPOUND NAME [BEFORE TIC THRESHOLD] •—^ 35 989 989 44 CARBON DIOXIDE 2 124 649 754 84 ACETAMIDE. 2-CYANO- 3 137 715 996 40 ARGON TUT 004 1550 L O O O i D S i 1022 n SAMPLE C.02 1022 M WT 44 3 PK 44 SANK 1 ft 32 PUR 989 D.N2 1022 N WT 44 B PK 44 RANK 2 ft 37 ?UR 985 C9.H21.N 1022 .1 WT 143 B PK 44 RANK 3 I 6948 PUR 789 M/Z MID LIBRARY SEARCH (LIBRARYHB) DATA: 03/17/93 14:17:00 + 1:10 CALI: SAMPLE: CLP,53554, MW01, MN03FD,LOW,NATER,UU7324,UOA,EPA, CONDS.: I500A:25ML OLU01 PURGE W/ 5PPB IS & SS ENHANCED <S 15B 2N 0T) UU7324 UU7324 TSST 1?00 llli BASE M/Z: 44 RIC: 493056. i-J to «ri —* C3» O O CARBON DIOXIDE CAS# 124-38-9 NITROGEN OXIDE (N20> CAS# 10024-97-2 1-OCTAHAMINE, H-METHYL- CAS# 2439-54-5 48 100 128 140 frOO mi 1000 SAMPLE C3.H4.0.N2 M WT 3 PK :3.H3.02.N 1000 M WT 85 B PK 41 RANK 2 « 562 ?UR 597 C4.H8.02.H2 1000 1 ,1 WT 116 B PK 41 RANK 3 » 2799 PUR 443 M/Z CO HID LIBRARY SEARCH (LIBRARYHB) DATA: UU7324 # 03/17/93 14:17:00 + 4:03 CALI: W7324 I SAMPLE: CLP,53554,MW91,MW03FD,LOW,WATER,W7324,UOA,ERA, COHDS.: I500A:25ML OLU01 PURGE W/ 5PPB IS & SS ENHANCED (S 15B 2N 0T) 124 BASE M/Z: 44 RIC: 1342. ACETAMIDE, 2-CYAHO-T -4-T——•••••••'•• CAS# 107-91-5 oo - 84 44 1 91 49 r ACETIC ACID, CYANO- CAS# 372-09-8 2,3-BUTAHEDIOHE, DIOXIME CAS# 95-45-4 30 100 110 e- •»4 •~4 O 1060 SAMPLE .AR 1000 H WT 40 3 PK 40 .RANK 1 I 20 PUR 715 :9.H12.02.S 1000 M WT 184 B PK 40 RANK 2 I 15396 PUR 183 C4.H4.0.N2 ,1 WT B PK RANK I M/Z HID LIBRARY SEARCH (LIBRARYHB) 03/17/33 14:17:90 + 4:34 - CALI: SAMPLE: CLP,53554,MW01,MW03FD,LOW,WATER,UU7324,UOA,EPA, CONDS.: I50QA:25ML OLU01 PURGE W/ 5PPB IS fc« SS ENHANCED (S 15B 2N 0T) UU7324 VU7324 Bn'.:E H 2: RIC: 1700 mi -40 33. 10 1T3 *H O <±>O ARGOH CAS# 7440-37-1 PHENOL, 0-<PROPYLSULFINYL>- CAStt 29634-41-1 1H-IMIDAZOLE-2-CARBOXALDEHYDE CAS* 10111-08-1 IMkJ 96 96 3 169 81 r 1 • •' • ' 1 ' • • •'!' ' •>— »-| . . . . [ • . • • . . ' • -i . • . • t • • . • I • • • ' . [ . . . . i . . . . , . . . , . i . . • . [ . , . . i . . . . , . . . . | . • . . | . • 20 48 60 80 100 120 140 160 180 t-oo mi 06 «—« O 100.0-1 RIC DATA: W7324 #113 03/17/93 14:17:00 CALI: UU7324 #3 SAMPLE: CLP,53554,MWO1,MW03FD, LOW,WATER,UU7324,UOA,EPA, COMDS.: I500A:25ML OLl'Ul PURGE W/ 5PPB IS & SS RANGE: G 1, 720 LABEL: H 2, 3.0 QUAH: A 2, 2.0 J 113 18082. 63393. bCAHS 160 TO 206 0 BASE: U 20, 3 RIC LO Ooo 16112. 124 1803. 14070. 137 1617. 10342, 1 ""-- •' / 1 '' ~ — — _ 1 1 ' 1 ' 30 1?0 140 160 i \ 1 X / 1 ' n 1 180 200 SCAN f..-;!! ,l.vU» 1 'Mf 0119 ORGANICS ANALYSIS DATA SHEET -s Lab Name: ITAS-KNOXVILLE___________ Contract: Lab Code: ITSTU Case No.: 53554 SAS No.: Matrix: (soil/water) WATER Sample wt/vol: 25.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ Heated Purge: N_ GC Column: DB-624___ ID: 0.53 (mm) Soil Extract Volume: ______(uL) MW030R SDG No.: MW01 Lab Sample ID: W7321 Lab File ID: W7321 Date Received: 03/08/93 Date Analyzed: 03/17/93 Dilution Factor: ____1.0 Soil Aliquot Volume: ___ CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L 7 4-87-3 ———————Chloromethane__________ 74-8 3-9——————Bromomethane__________ 75-01-4——————Vinyl Chloride_________ 75-00-3———————Chloroethane___________ 75-09-2———————Methylene Chloride______ 67-64-1———————Acetone_______________ 74-97-5———————Bromochloromethane______ 75-15-0———————Carbon Disulfide_______ 75-35-4———————1,1-Dichloroethene______ 75-34-3———————l, 1-Dichloroethane______ 540-59-0——————trans-1,2-Dichloroethene_ 540-59-0——————cis-1,2-Dichloroethene__ 67-66-3———————Chloroform____________ 107-06-2——————1,2-Dichloroethane_______ 78-93-3——————2-Butanone____________ 71-55-6———————1,1,1-Trichloroethane___ 56-23-5———————Carbon Tetrachloride____ 75-27-4 ——————Bromodichloromethane____ 78-87-5———————1,2-Dichloropropane_____ 10061-01-5————cis-1,3-Dichloropropene__ 79-01-6———————Trichloroethene________ 124-48-1——————Dibromochloromethane____ 79-00-5———————1,1,2-Trichloroethane___ 71-43-2———————Benzene_______________ 10061-02-6————trans-1,3-Dichloropropene_ 106-93-4——————1,2-Dibromoethane_______ 75-25-2———————Bromoform_________________ 108-10-1——————4-Methyl-2-Pentanone____ 591-78-6——————2-Hexanone________________ 127-18-4——————Tetrachloroethene______ 79-34-5——————l,l,2,2-Tetrachloroethane_ 108-88-3——————Toluene______________~ 108-90-7——————Chlorobenzene____________ 1 1 1 1 2 5 1 1 1 1 1 11 1 1 5 1 1 1 1 1 3 1 1 1 1 1 1 5 59 1 1 1 U U U U B U U U U U U U U U U U U U U U U U U U U U U U U U in in in h- IX ORGANICS ANALYSIS DATA SHEET 0120 SAMPLE NO. Name: ITAS-KNOXVILLE Contract: SAS No.: MW030R Lab Code: ITSTU Case No.: 53554 Matrix: (soil/water) WATER Sample wt/vol: 25.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ Heated Purge: N GC Column: DB-624 ___ ID: 0.53 (mm) Soil Extract Volume: ______ (uL) SDG No.: MW01 Lab Sample ID: W7321 Lab File ID: W7321 Date Received: 03/08/93 Date Analyzed: 03/17/93 Dilution Factor: ____1.0 Soil Aliquot Volume: ___ GAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L .(UL) 100-41-4 ——— - J. U \J H £• *J 1330-20-7 —— • •s •» ^. t ^ ± 106-46-7 ——— • 95-50-1 ———— • —— Ethylbenzene —— Styrene - —— Xylene (total) —— 1 , 3-Dichlorobenzene —— 1 , 4-Dichlorobenzene —— 1 , 2 -Dichlorobenzene —— l,2-Dibromo-3-Chloropropane _ 1 U 1 U 1 U 1 U 1 U 1 U 1 U FORM I X-2 TUT OO4 15b<b I 0001557 3/90 IX ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS "Lab Name: I TAS -KNOXVI LLE_________ Contract: Lab Code: ITSTU Case No.: 53554 SAS No.: Matrix: (soil/water) WATER Sample vrt/vol: 25.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ GC Column: DB-624___ ID: 0.53 (mm) Soil Extract Volume: _______(uL) 0121 SAMPLE NO. MW030R SDG NO.: MW01 Lab Sample ID: W7321 Lab File ID: W7321 Date Received: 03/08/93 Date Analyzed: 03/17/93 Dilution Factor: ____l. 0 Soil Aliquot Volume: ___ .(uL) Number TICs found: CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L CAS NUMBER COMPOUND NAME RT EST. CONC. Q TUT 004 L 0001550 FORM I X-TIC 3/90 CM CM DATA FROM FILE: VU7321 SCANS 45 TO 729 ACQUIRED: 03/17/93 12:24:00 CALI: W7321 #3 SAMPLE: CLP,53554,MW01,MW030R,LOW,WATER,UU7321,UOA,EPA, CONDS.: I506A:25ML OLU01 PURGE W/ 5PPB IS *« SS 100 _ 3:20 200 _ 6:40 300 J 10:00 400 _ 13:20 500 J 16:40 20:00 700 J CI10 1,4-DIFLUOROBENZENE (IS#1) CI20 CHLOROBENZENE-D5 <IS#2> CS10 4-BROMOFLUOROBENZENE <SS) CI26 1,4-DICHLOROBENZENE-D4 (IS#3) 100.07. ( 41216.) oointn O lO to H- 0123 .sntitation Report File: W7321 -,ta: W7321.TI -3/17/^3 12:24:00 :-67:ple: CLP, 53554, MW01, MW030R, LOW, WATER, VV7321, VOA, EPA, ::= ds. I500A:25ML OLV01 PURGE W/ 5PFB IS & BS -•mula: 25ML AMBIENT PURGE Instrument: I500A Weight: :.•emitted by: ITEK Analyst: RJL Acct. No. •••3UNT=AREA * REF ACiNT/(REF AREA * RESP FACT) '•?sp. -fac. from Library Entry 1,4-DIFLUOROBENZENE <IS#1) CHLOROBEN2ENE-D5 US#2> 1,4-DICHLOROBENZENE-D4 <15*3 > 4-BROMOFLUOROBENZENE <SS> CHLOROMETHANE ** BROMOMETHAME VIKYL CHLORIDE * CHLOROETHANE METHYLENE CHLORIDE ACETONE 2-3UTANONE 4-ME1 HYL-2-PEN'TANONE 2-HEXANONE BROMOCHLOROMETHANE CARBON DISULFIDE 1,1-DICHLOROETHENE « 1.1-DICHLOROETHANE ** TRANS-1.- 2-DICHLOROETHENE CHLOROFORM * 1.2-DICHLOROETHANE 1,1,1-TRICHLOROETHANE CARBON TETRACHLORIDE BROMODICHLOROHETHANE 1,2-DICHLOROPROPANE * CIS-1,3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE BENZENE TRANS-1,3-DICHLOROPROPENE 1,2-DIBROMOETHANE BRCMOFORM ** TETRACHLOROETHENE 1, 1,2, 2-TETRACHLOROETHANE •»* TOLUENE * CHLOROBENZENE ETHYL BENZENE * STYRENE M/P XYLENE 0-XYLENE CIS-1,2-DICHLOROETHENE 1.3-DICHLOROBENZENE 1.4-DICHLOROBENZENE 1,2-DICHLOROBENZENE 1,2-DIBROMO-3-CHLOROPROPANE 0. 000 53554 "-< C- i r" 4 K •£ / 5 * • j 13 3 1 5 A •? 5? 0 •; 2 3 4 B _ i JT* 7.7 ±>= 2v 20 31 7.2 w • w i4 ?5 36 2.-' rS 39 ;»0- IT. •*5. -3 44 •*5 Ns.r.e CI10 CI20 CI26 CS10 CO 10 CO 15 C020 C025 C03O C035 C110 C205 C210 C037 CO4O C045 CO 50 C053 C060 C065 C115 C120 C130 C140 C143 C150 C155 C160 C165 C172 Cl7£ ClSO C22O C225 C230 C235 C240 C245 C250 C252 COS'1 C253 C254 C255 C261 TUT 004 1559 L000156G 0124 *.:0 t ' i 3 £ c. 6 T 5 ^ 10 1 1 4 •", A ^. 1 3 1 *» • ^ » ' J- lis -. ;.• ;3 * '» » • Z'O z-i fl& 23 24 25 **. * •M* ( T * / 28 •s.-i i. T lO. •21 T •'? ":3 24 V "^ 36 -^ -» J .' 2£ — .-^i •;o Ai it •-* T.X 43 • < -* *: ** -V - v - 1 2 3 u c.' 6 - •< 3 •3 m/i Scan 114 183 117 373 1 50 5 1 8 95 439 NOT FOUND NOT FOUND NOT FOUND NOT FOUND 8* 72 NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND 76 64 NOT FOUND NOT FOUND 9ib 78 63 127 NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND 95 201 NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND 166 325 NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUJsD NOT FOUND 96 112 NOT FOUND NOT FOUND NOT FOUND NOT FOUND Ret(L) Rat-i 6: OS 0. 99 12 26 1. 00 17 16 1. 00 14 38 1. 00 1 16 1 28 1 18 1 32 2 24 1 . 00 Time Ref RRT 6:06 1 1.000 12: 26 21. 000 17: 16 3 1. 000 14: 33 1 2. 399 2: 24 1 0. 393 2: 08 1 0 350 2: 36 1 0. 426 4. 14 1 0 694 6: 42 2 0. 539 10: 50 2 0. 871 3:44 1 0.612 o RRT(L) Ratio 1 . 000 1 . 00 1 . 000 1 . 00 1 . 000 1 . 00 2.386 1.01 0. 207 0. 239 0. 212 0. 250 0.391 1.01 Meth A DB A DB A BD A BB A BB A BB A BB A BB A BB A BB A BB Amnt 5. 00 5. 00 5. 00 4. 60 1. 53 Area<Hgh 8587. 5182. 3029. 4306. 914. 504. 201. 201. 2962. 11255. 6S71. Amn t < L) 5 00 5. 00 5. OO 5. 00 5. 00 t ) Amo 5. 5. 5. 4. 1. 0. 0. 0. 2. 9. 10. R. Fac 1. 000 1. 000 1. 000 0. 501 0. 106 5. 000 UG/L 5. 000 UG/L 000 UG/L 4. 601 UG/L 1. 531 UG/L 0. 181 UG/L 242 UG/L 0. 132 UG/L 2. 902 UG/L '/.Tot 11. 24 11. 24 11. 24 10. 35 3. 44 0. 41 0. 55 0. 30 6. 53 20. 85 10. 788 UG/L 24. 26 R.Fac(L) Ratio 1. 000 1. 00 1. 000 1. 00 1. 000 1. 00 0. 545 0. 92 0. 348 0. 31 L000158; -0 iTJ H-nI- -H CDo CD ^-J 4> *~* PJ 03 0 O CO O Ll IM — O- 0- CJ -t- CJ > »-» O0 CJ CJ J -0 -0 O o- m o I-* o I-* l-»p --J •0 Ul oo p COoo o CJ ••* PJ K^ l> O -0 id v| 0- <A 4;. Ll M »~ O <l C(i -.1 io(ocopjru-ouio*>~outo>- 44 O 4=. 4i CO & O Ui O PJ fu O •*• PJ . ^ r o o ^ t D P c h p j p p c o r o Q ^ p j p j i-* o0 "» O ~ O O VI PJ CO CO .0 Oi *• CO ..0 O 4* O PJ O CD O -I •- pj tO - 0- — >-^ 0o • •4 PJ "^ Ul oo PJ H- Nl PJ •-• l-> •xj ^* ~ CO Ul t> '.n if- -O *• O »-*• 0o '-? CJ «ji -j CO CO f-*- o0 ro -o0 ui oo p Ul vj ro o •o CD Ul o Ul en !;• U IM ••- C' ••!! •--J li) *' t- Ul -T- •-• O -t* CJ •"*•••• l-» oo CJ CJ CJ CJ CJ CJ Ul 0- CO CO CO 0- CO -t« CO ")• •£» --0 4^ -4J CJ PJ PJ O »-» O I-* p !-• CJ Ul oo p o PJ CJ p CO CO 0- p o CJ iCi ••! ',' J CO OJ O H* oo LJ tj 4* •*• PJ 0 f-» o f-1 o PJ* Ul oo o oru (O o 4» CD CO p o Ul rj- -.'I 4;. U h-* rj ro 4>> *-• O •- O PJ p •ft CD CJ CJ CJ CJ CO CO i> -O PJ UI O- •- p 'O ~0 p I-". crj Ul oo o 0 Ul -0 >-* 0-ro •(:i p o -£« PJ »~ O O 3J -0 CJ PJ 1> • • • • • • r* CO Ul O •"• N.^ rt- !-"•o vj CJ vj ^41 •^J O- CO H sj PJ CO " 30 OJ^ >-> O > 3 r*- 33 ^^r "*^ ?° Qin a, -n Oln ^-.r Oirl- O 3/17/93 12:24:30 A c q u i s i t i o n started 0126 -3/17/93 12:24:33 Acquire Run 0: VV7321 Starting 03/17/93 12:24:OO + 0:00 Free sectors: 1363B Scan: 0 of 720 Sample: CLP, 53554, MW01, MW030R, LOW, WATER, W7321, VGA, ERA, Ccmds. : I500A:25ML OLV01 PURGE W/ 5PPD IS ?< SS Formula: 25ML AMBIENT PURGE Instrument: I5OOA Weight: 0.000 Submitted by: ITEK Analyst: RJL Acct. No: 53554 Desc *** GC not ready and being VI stabilized *#* Elapsed time : 0. 0 Min eq. Temp * (DeqC) 1 35 ~35 2 35-150 3 150-15O Rate ( C/min ) — 8. O — Time (minutes) alve A Post per i od 6. 6 14. 3 3. O Valve D : **» Instrument acquisition state -> c losed total 6. 6 20. 9 23. 9 open parameters Filament Injector A GC oven Transfer—1ine Ion source 150 35 215 181 Deg Deg Deg Deg ;QOE: El (+> Centroid + Temp - Sequence: BF *** Off Multiplier ( 2 time windows. Off Sequence Window # 1 'c-*n descriptor: otal scan time: Number of cycles: Filament is OFF Multiplier is ON BF Mass intervals: 2. OOO s 28 Positive ion mode. Master rate: 16 PW: 3 MFW: 80 MA: 15 TH: 1 Int # Lo mass Hi mass Time 1 33. 510 3OO. 590 2. 000 BL: Sequence Window # 2 Number of cycles: Filament is ON Multiplier is ON 3c.an descriptor: BF Mass intervals: "otal scan time: 2.OOO s Positive ion mode. Master rate: 16 rPW: 3 MFW: SO MA: 15 TH: 1 Int # Lo mass Hi mass Time 1 33. 510 300. 590 2. OOO BL: Calibration table: D: CAL02199Z Interface number Instrument type Full scale mass Zero scale mass Intensi ty/ion Peak width Offset at low mass Offset at high mass Voltage settling time(ms) 20 0 Q 1177 1 2 1000. 0 0 u u mmu mmu mmu TUT 004 1562 i D O O I 5 6 Current instrument parameters. Positive ion mode 0127 Resolution (high) Resolution (low) Quad offset Quad programming Lens offset Lens programming Ext offset Ext programming Col lector Ion offset Ion programming Rod polarity 128. 128. 0. 0. -50. 0. 0. 0. 30. 7. 5. 00 00 00 00 00 00 00 00 00 00 00 Negative ion 128. 00 128. 00 0. 00 0. 00 50. 00 0 0 0 30 -3 -5 Reverse Electron multiplier voltage: Filament emission current: Electrometer range: Electrometer zero: 00 00 00 OO 00 00 Normal 984. 750. 10 '^-7 126. 0 mode Analyzer Fore Pressure . . . Separator/Source Pressure 0.010 Torr 0. 356 Torr 3/17/93 12:52: ACQUISITION COMPLETED Scans 1 to 72O Centroid Centroid Scans 72O Sees O. 4 Out of 144O. 0 '/. Peaks per scan per sec 0. 0 3051. 4. 2. TUT OO4 1563 QUALITY CONTROL/QUALITY ASSURANCE DATA METHOD: CLP 3'90 OLV01 25ML PURGE DATAFILE: VV7321 ANALYSIS TIME: 03/17/93 12:24 STANDARD. US0317 ANALYSIS TIME: 03/17/93 10:48 TUNEFILE: WBFD0317 ANALYSIS TIME: 03/17/93 9:34 ****** INTERNAL STANDARD AREA CHECK ****** DATA STD CLP INTtRNAL STANDARD AREA AREA RATIO ACCEPT RATIO STATUS 110 1, 4-DIFLUOROBENZEN 8587. 9856. 877. 607. - 14O7. 120 CHLOR08ENZENE-D5 ( 5182. 6374. 817. 607. - 1407. 126 1.. 4-DICHLOROBENZEN 3029. 4017. 757. 607. - 1407. 0128 ****** INTERNAL STANDARD RT CHECK ****** INTFRNAL STANDARD C110 1: 4-DIFLUOROBENZEN CI2O CHLOROBENZENE-D5 ( "T26 1.. 4-DICHLOROBENZEN DATA SCAN 183 373 518 STD SCAN 184 373 518 DIFF CIN SEC 3 2 0 0 CLP ACCEPT DIFF STATUS +/- 20 SECS +/- 20 SECS +/- 20 SECS *#**** SURROGATE RECOVERIES ****** AMT AMT PERCENT SURROGATE FOUND ADDED RECOVERY RECOV LIMITS STATUS C310 4-3ROMOFLUOROBENZE 4. 6 5. 0 92 80% - 120V. :015 BRCS-iOMETHANE -0.0 50.0 0 887. - 1107. failed ::>20 VINYL CHLORIDE * -0.0 50.0 0 867. - 1157. failed TUT O04 1564 ^0001565 PROCEDURE: TCA DATA FILE: VV7 REFERENCE: VI 1 ,NA>tE LIST: VI REPORT: VII — -^ : - —— STANDAR ^ROC USED P 3 2 3 3 3 3 45 COMPOUND • : COMPOUND :> ','0 1 2 •3 4 5 CJ7 3 9 10 1 1 12 13 14 .5 "'I 6 17 18 19 £0 21 22 :='3 24 25 26 •^ • r •i ^ 23 29 30 •>1 32 33 34 35 36 37 33 39 TO -*1 42 43 44 45 LIB VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI ENTRY 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 DIAGNOSTIC REPORT 3/17/93 12: 321 1 INITIALIZATION OPTION: 2 PROCESSING OPTION: 3 S DS ———— >< —— PLUS UNKNOWNS —— X - LIST NAMES - > OSS RMS PROC USED POSS RM3 STANDARD/UNKNOWN 1 O 20 5 1 63 V1IS/V1UNKS1 1 11 16 5 1 41 V1IS/V1UNKS2 1 11 15 4 1 67 V1IS/V1UNKS3 S PROCESSED, 7 FOUND REF -184 -373 -518 -439 -38 -44 -39 -46 -72 -62 -115 -289 -341 -122 -65 -60 -91 -78 -127 -155 -135 -143 -242 -218 -274 -201 -341 -321 -153 -311 -344 -420 -325 -451 -293 -375 -384 -413 -391 -412 -112 -496 -501 -519 -561 oc.nr\^n PRED SEL DELTA PEAKS 183 183 . 1 373 373 . 1 519 439 439 . 1 3 7 . . . 4 3 . . 3 8 . . 4 5 . . . 71 72 1 1 6 1 . . . 115 289 341 . 122 6 4 . . . 59 . 9 0 . . 7 7 . . . 127 155 134 142 242 218 274 200 201 1 1 341 3?1 152 311 344 420 325 325 . 1 452 293 375 384 413 391 412 111 112 1 1 497 5 0 2 . . 520 5 6 2 . . FIT PEAKS M/Z 981 . 114 961 . 117 150 949 . 95 50 94 62 64 913 . 84. 43 43 43 43 128 76 96 63 96 83 62 97 117 83 63 75 951 . 95 129 97 78 75 107 173 956 . 166 83 91 112 91 104 106 106 905 . 96 146 146 146 75 TOP DELTA 183 373 518 439 72 64 78 127 201 325 112 54: 56 012 PEAKS 1 1 1 1 1 1 1 1 1 1 1 TUT 004 1565 I. T. ANALYTICAL SERVICES LIBRARY SEARCH REPORT PURGEAGLE VOLATILE ORGANICS ANALYSIS 0130 TA FILE: VV7321 •QUIRED 03/17/93 ---DS. : I500A: 25ML EMITTED BY: ITEK 12: 24: 00 OLV01 PURGE W/ 5PPB IS SS ANALYST: RJL ACCOUNT NO. 53554 COMPOUND ;0 1,4-DIFLUORQBENZENE 10 CHLDRODENZENE-D5 <IS*2) "6 1,4-DICHLORQ3ENZENE-D4 <IS*3> :10 4-BROMQFLUOROBENZENE <SS) ,:-iO METHYLENE CHLORIDE r-0 TR1CHLOROETHENE ;:20 TETRACHLOROETHENE ^54 CIS-1,2-DICHLOROETHENE SCAN DELTA (UG./ML) 183 373 518 439 72 201 325 1 12 0 0 -1 0 1 1 0 1 5. 000 5. 000 5. 000 4. 601 1. 531 2 902 9. 272 10. 788 FIT 981 961 0 <?49 913 951 956 SAT'D" 0 0 0 0 0 0 0 0 TUT 004 1566 L000156V mi TARGET COMPOUND COMPARISON COMPOUND: C836 METHYLENE CHLORIDE 100.0: 50.0: 2.9: 1.5: 5.8: 2.9: M/Z 100.0: 50.0: 0.0: -50.0: 100. tf j RAW DATA: UU7321 #72 BASE M/Z: 44 RIC: 19424. 03/17/93 12:24 SAMPLE: CLP, 53554, MW01 , MW030R, LOW, WATER, W7321 , UOA, EPA, CONDS.: I500A:25ML OLU01 PURGE W/ 5PPB IS & SS ENHANCED DATA: UU7321 #72 1 LIBRARY FILE: Ul #3 30 r t i > i [ i i i i 46 , , - j ' ' " ' r " ' ' 1 ' ' ' ' ' I ' I BASE M/Z: 49 RIC: >-T-*-T i I | i i i i | i i r I-T-T-» r i | i i i i | i i i I | i i i BASE M/Z: 43 RIC: h, j , . , , , , . T , r T .,.,-,-,,,. | . . . , , . , . . , . . . 50 60 70 80 1 . . 1478. 3028. • 90 • i <~> o ^^ o> c -J _/ - 17216. r 507. r 1800. - _ 89ST frOO CM CO ^ TARGET COMPOUND COMPARISON 100.0- 50.0-1 37.4- 18. 7-: 46.0- 23.0-: M/Z 100.0T 50.0-: 0.0-: -50.0-: -100.0^ 10 COMPOUND: C156 TR I CHLOROETHENE RAW DATA: W7321 #201 BASE M/Z: 44 RIC: 7592. 03/17/93 12:24 SAMPLE : CLP , 53554 , MW0 1 , MW030R , LOW , WATER , Ul'732 1 , UOA , EPA , CONDS.: I500A:25ML OLU01 PURGE W/ 5PPB IS 8, 55 ENHANCED DATA: UU7321 , , , , , 1 1 , , , , , l | l , , , , , 1 . . , . . i , ... i | . . . . LIBRARY FILE: Ul #26 I . i i . i i i i i i i i | i i i i , r i #201 &t . . . . . . . I . . . , , . . . . 40 50 68 In I I I . . 1 Bf 1 • • • . • • • • , . . . . . . 1 • «E M/Z: 95 RIC: 5080. i ^SE M/Z: 95 RIC: 53; i 80 1 i I.I i 36 j • , 1 . , , . , . . . . I .... 100 120 1 • i i 1 ' 1 140 i i — t0 o o r 2176. r 313. - 1000. : '- **oum _ 69ST 1700 IRi 00 r> 2 TARGET COMPOUND COMPARISON o 100.0- 50.0-: 91.0- 45.5-: 28.3- 14.2-: M/Z 100.0- 50.0-: 0.0-; -50.0-: -100.0^ COMPOUND: C220 TETRACHLOROETHENE RAW DATA: UU7321 #325 BASE M/Z: 166 RIC: 26688. 03/17/93 12:24 SAMPLE: CLP, 53554, MW01 , MW030R, LOW, WATER, W7321 , UOA, EPA, CONDS.: I500A:25ML OLU01 PURGE W/ 5PPB IS & SS .1 . i 1 L h II, i 1 • | • i • i • i • i ' ENHANCED DATA: UU7C 1 i | , - , - , - 1 <21 #325 1i , . , , , i l. | '' | l '[ T" V 1 T-l ,IJ|' , ••¥* [ T--T •. i -i-T-r , i | i -j r LIBRARY FILE: Ul #33 i . , 1 , , | . , . , , | . , . , . , . , . | . , . , . , . , . | BASE M/Z: 166 RIC: 23776. '••} i J-T | l— r-i | i | i | > | ' -| ' | ' | ' BASE M/Z: 166 RIC: 5560. 1 1 | i | i | i | i | r- j— M' 1 • | • 1 • 1 • 1 • | • | • | • | • | • I • | • 1 • | • 1 • | • 1 • 1 • l • l • 1 50 100 150 200 250 308 L ll 1, . i,. 1.1, ... I.I il l . .1 :. ) O C3 C3 J 7 3528. - 3212. - r 1000. • r **OUT** - CO -« CD 100.0- 50.0- 35.3: 17.7: 11.7- 5.8: M/Z TARGET COMPOUND COMPARISON COMPOUND: C054 CIS-1 /2-DICHLOROETHENE RAW DATA: UU7321 #112 03/17/93 12:24 SAMPLE: CLP,53554,MW01,MW030R,LOW,WATER,UU7321,UOA,EPA, CONDS.: I500A:25ML OUJ01 PURGE W/ 5PPB IS t SS BASE M/Z: 44 RIC: 19360. ENHANCED DATA: UU7321 #112 BASE M/Z: 61 RIC: 9824. LIBRARY FILE: Ul #41 BASE M/Z: 61 RIC: 3240. i " " I 30 48 56 60 70 i—i—i I [ i i i i i—i i I r I—i i i I | 80 99 108 t H 8560. 3024. 1900. 80.0: 50.0: 0.0: - 50.0: act (A- 1,. . , . . . . . . . . . . . . . , . . . . . 1 Gi.-*nt i tat ion Report File: VV7321 0135 =»ta: W/321. TI J/17/93 12:24:00 a.^ple: CLP, 53554, KWO1, MW030R, LOW, WATER, W7321, VOA, EPA, r.ids. : I50OA:25ML OLV01 PURGE W/ 5PPB IS & SS rrmula: 25ML AMBIENT PURGE Instrument: I50OA Weight: , bmitt-ed by: ITEK Analyst: RJL Acct. No. 0. 000 53554 .:3UNT=Ht IGHT * ;p. fac. from REF AMNT/(REF HEIGHT Library Entry •* RESP FACT) 1 - . - ^ 1 ._ Jl xt_ CAS # 0-00-0 0-00-0 o-oo-o — — m m/ i RIC RIC RIC — B4-e — — FWC 1 1 -/'y-^ Scan 183 373 518 — 13S 137 Name CI01 BROMOCHLOROMETHANE (I.S. #1) CI10 1, 4-DIFLUOROBENZENE (I.S. #2) .^ CI20 CHLOROBENZENE-D5 (I.S. #3) "**vo' 0 ——— CARD AM I- 9 ——— CARBON Time Ref 6: 12: 17: — *- —— 4- 06 26 16 24 -3*— 1 2 3 — r- — i— C Aviu, Dipxipe RRT 1. 1. 1 —Q~ 000 000 000 749 ^ \.ty ^ :,^> 1'IONOMHHDNIUM SALT -«»'y/) Meth A BB A BB A BB A W ——— A VB ——— Area<Hght) 536O. * 7900. * 7099. * ——— 2136. *• —— Amount 50. 50. 50. —— Wr 000 000 000 -8£4- UG/L UG/L UG/L •/.Tot 17. 17. 17. 60 60 60 -e-i- -T5 TUT 004 1571 PROCEDURE: FILTER/TIC CAT A FILE: W7321 -ILTER SCAN PARAMETERS ^x. NUMBER TICS: 10 :;-TABLE ENTRIES: 495 S:AN TOLERANCE : 3 - :TJ RIC HT. ['/.]: 10 - 1RST SCAN : 35 ..AST SCAN : 1000 "1C THRESHOLD : 500 DIAGNOSTIC REPORT 3/18/93 1 3 : O 4 : 5 2 0136 METHOD LIBRARY &: LISTS TIC I. S. LIBRARY: NBS SEARCH PROC : PEAK FINDER PROC: TCA IS. LL FILE NAMh LIST : LIBRARYIS SERLID VOME5 IS TCAREF2 COMPOUND ANALYSIS: TARGETS (QUAN LIST) S IS PEAKS 3 TOTAL TARGET PEAKS 11 = ILTER PROCESSING: :OTAL *EAKS 20 < isr SCAN 0 :> LAST SCAN 0 — — nc.-jc.^ <: MIN RIC HT 2 i rc«K\a — < SCAN TOL 1 1 > MAX # PEAKS 0 TOTAL REJECTS 13 TOTAL TICS 7 1C PROCESSING: SCAN* PURITY 36 53 56 59 132 137 141 79O 529 812 996 480 992 1OOO FIT 791 529 812 996 480 993 1OOO MW COMPOUND NAME [BEFORE TIC THRESHOLD] 74 1,2-PROPANEDIAMINE 165 ETHANE, 1, 1, 1-TRINITRO- 60 2-PROPANOL 40 ARGON 84 ACETAMIDE, 2-CYANO- 78 CARBAMIC ACID, MONOAMMONIUM SA 44 CARDON DIOXIDE TUT 004 1572 L O O O l j ? 2Z.QT 1700 mi CO SAMPLE MID LIBRARY SEARCH <LIBRARYNB) 63/17/93 12:24:90 + 1:12 CwLI SAMPLE: CLP,53554..MU61, MW830R, LOW,WATER, W7321, UOA, EPA, CONDS.: I500A:25ML OLUDl PURGE H/ 5PPB IS 8. SS ENHANCED (S 15B 2H 0T) PH;.E HZ: 44 PIC: 28bJU8. C3.H10.N2 1068 • M MT B PK 74 44 RANK 1 • 384 PUR 798 C9.H21.N 1088 i, i ,1. 1,2-PROPAHEDIAMIHE CAS# ^3-90-0 M WT B PK 143 44 RANK 2 » 6948 PUR 763 C7.H17.H 1088 M WT 115 B PK 44 RANK 3 I 2778 PUR 756 M/2 1-OCTAHAMINE, N-METHYL- CAS# 2439-54-5 I'-HEPTAMAMIHE CAS# 123-82-0 60 30 100 120 140 0«d e-8S-86fi 93 -—-U 8-98-SbS #SU3 r OS • I ..._ - Ot 03 jiy 1AH13W (SON) 301X0 N300aiIN -i—|—i—i—|—I—.—«- -odiiHiai-rri '3NW13 e # es # Q0 H3 a£ I S> Q33HyHN3 ss "8 si adds /M 33and 101 no Twsssyeesi "SQNOJ 'yd3 • yon • ise^nn'asiyM'MOTaoeanw' Ter-iw• frsses - di3 •• sidwys > H5aw3s Aayaan QIW Z/M st> Md a z<i in k N'SO'CH'O es 3 MNW 0e »d a 9t- in N KS and t'TfrU * us »d e S31 iM H CO oo CO o 1006 SAMPLE HID LIBRARY SEARCH aiBRARVNB) DATri: MI'7321 » 03/17/93 12:24:00 + 1:52 CALI: W7321 ft SAMPLE: CLP,53554,MU01, MW030R,LOW,WATER,W7321,UOA,EPA. CONDS.: I500A:25ML OLU01 PURGE W/ 5PPB IS & SS ENHANCED (S 15B 2H 0T) 56 EiHSE M Z: 45 RIC: 128. C3.H8.0 1000 M WT 66 3 PK 45 SANK 1 I 120 PUR 812 ::3.H6.03 1000 M WT 90 B PK 45 RANK 2 tt 823 ?UR 809 C.H3.0.N 1000 2-FROPANOL CAS# 67-63-0 PROPANOIC ACID.. 2-HYDROXY- CAS# 59-21-5 4- -t-4~ 1-,————————,————————r^- CAS# 75-12-7 .1 WT B PK 45 45 RANK 3 ft 38 PUP. 786 M/2 FORNAMIDE 20 i •'• 40 50 9Z.QT frOO SAMPLE .AR M WT 3 PK 46 48 3ANK 1 I 20 PUR 996 1000 n WT 40 B PK 40 RANK 2 I 22 ?UR 557 C.H3.0.B 1008 .1 WT 42 B PK 40 RANK 3 I 26 PUR 423 M/Z MID LIBRARY SEARCH (LIBRARYHEO OATrt: W7321 # 03/17/93 12:24:00 + 1:58 GAL I: W7321 # SAMPLE: CLP, 53554, MU81, MH830R, LOW, WATER, UU7321, UOA, EPA, CONDS.: I500A:25ML OLUQl PURGE W/ 5PPB IS & SS ENHANCED <S 15B 2H 8T) 53 3 BASE M/Z: 48 RIC: 67. 10 •—,oo --J ARGON CAS# 7448-37-1 1-PROPYHE CAS# 74-99-7 -M- BORON, CARBONVLTRIHYDRO-, <T-4>- CAS# 13265-44 - - 10 20 38 40 50 66 78 r*. 0 MID LIBRARY SEARCH (LIBRARYNB) DATA: UU7321 ft 132 BASE 11 Z: 44 63/17/33 12:24:60 + 4:24 CALI: W7321 « 3 RIC: 1636. SAMPLE : CLP , 53554 , MW0 1 , MW030R , LOW , WATER , W732 1 , UOA , EPA , CONDS.: I500A:25ML OLUSl PURGE W/ 5PPB IS 8, SS ENHANCED (S 15B 2N 0T> 1000 i SAMPLE C3.H4.0.H: 1600 1 M WT 34 3 PK 44 2ANK 1 # 491 ' PUR 430 r 2 ACETAMIDE, 2-CYANO- r . i . i i i CASH 107-91-5 . . i J3.H3.02.N ACETIC ACID, CYAHO- CAS# 372-09-8 1000 i M WT 35 B PK 41 RANK 2 * 562 ' ?UR 451 C5.H4.03 1000 i .1 WT 112 B PK 44 RANK 3 1 2207 PUR 235 r 2H-PYRAH-2 , G ( 3H ) -D I ONE CASH 5926-95-4 r 1 __ _______________________________________________ 1- - . -. ____________________________ __ __ 1 1 ______________________________________________________ ._!___ ________ .__r J i i M''Z 20 30 40 50 60 70 86 90 h- CM 2 0 MID LIBRARY 03.'17/33 12: SAMPLE: CLP, SEARCH (LIBRARYNB) 24:00 + 4:34 53554 , MW0 1 , MW630R , LOW, WATER , UU732 1 , UOA , CONDS.: I508A:25NL OLU81 PURGE W/ 5PPB IS & SS ENHANCED 1040 1 SAMPLE C.H6.02.H2 1040 1 M WT 78 3 PK 17 SANK 1 * 362 ' PUR 392 :.02 1040 ] M WT 44 B PK 44 RANK 2 1 32 ?UR 981 1 O.N2 1040 i .1 WT 44 B PK 44 RANK 3 1 37 1 PUR 978 M/Z I (S 15B 2H 8T) • | i i i i | i i * CARBAMIC ACID, MONOAMMONIUM SALT 1 . CARBON DIOXIDE NITROGEN OXIDE (N20) 15 ———ir "*•"•"! 20 ' 25 U— 1 •. CD DATA: '".'7321 # 1 3T BuTL H I: -»•» In GAL I: UU7321 ft 3 R1C: 3u31. EPA, Oo r ' u_ J i i i i l * i > l « i i i « ID h- CAS# 1111-78-8 r CAS# 124-38-9 r CAS# 16024-97-2 r ——— i ——— i ——— i ——— i ——— | ——— i ——— i ——— i ——— i ——— ] ——— I ——— I ——— i —— —— i —— T- --T "0 35 40 45 CO 6/LST JiflJi 1021 SAMPLE C.02 1021 H WT 44 3 PK 44 SANK 1 # 32 PUR 1000 D.N2 1021 M WT 44 B PK 44 RANK 2 tt 37 ?UR 993 C.H6.02.N2 1021 ^ .1 WT 78 B PK 17 RANK 3 # 362 ] PUR 996 M/Z MID LIBRARY SEARCH (LIBRARYNEO DATA: UU7321 #141 03/17/93 12:24:00 + 4:42 CALI: UU7321 tt 3 SAMPLE: CLP,53554,MU81> MW030R,LOW,WATER,UU7321,UOA,EPA, CONDS.: I500A:25ML OLUtU PURGE W/ 5PPB IS & SS ENHANCED (S 15B 2N 0T) BASE HZ: 44 RIC: 1656. -i—<—•—|—r— CARBON DIOXIDE T——•— CAS# 124-38-9 -.———.———,———|———•———I———r— NITROGEN OXIDE (N20) -i———|———r- CASK 16024-37-2 CAPBAMIC ACID, MOHOAMHONIUM SALT CASK 1111-78-6 15 28 25 r 36 35 40 45 o CD IX ORGANICS ANALYSIS DATA SHEET "Lab Name: ITAS-KNOXVILLE_________ Contract: Lab Code: ITSTU Case No.: 53554 SAS No.: Matrix: (soil/water) WATER Sample wt/vol: 5.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ Heated Purge: N GC Column: DB-624 ID: 0.53 froml Soil Extract Volume: _______(uL) 0144 SAMPLE NO. MW04 SDG No.: MW01 Lab Sample ID: W7327 Lab File ID: W7327 Date Received: 03/08/93 Date Analyzed: 03/18/93 Dilution Factor: ____l.0 Soil Aliquot Volume: ___ .(uL) CAS NO. COMPOUND CONCENTRATION UNITS; (ug/L or ug/Kg) UG/ 74-87-3———————Chloromethane__________ 7 4 -83-9———————Bromomethane___________ 75-01-4——————Vinyl Chloride_________ 75-00-3———————Chloroethane___________ 75-09-2———————Methylene Chloride______ 67-64-1———————Acetone_____________________ 74-97-5———————Bromochloromethane______ 75-15-0———————Carbon Disulfide________ 75-35-4———————1,1-Dichloroethene______ 75-34-3 ——————— 1,1-Dichloroethane_______ 540-59-0——————1,2-Dichloroethene (total) 540-59-0——————cis-1,2-Dichloroethene___ 67-66-3———————Chloroform_____________ 107-06-2——————1,2-Dichloroethane______ 78-93-3———————2-Butanone____________ 71-55-6———————1,1,1-Trichloroethane____ 56-23-5———————Carbon Tetrachloride____ 75-27-4———————Bromodichloromethane____ 78-87-5 ——————— 1,2-Dichloropropane______ 10061-01-5————cis-1,3-Dichloropropene__ 79-01-6———————Trichloroethene________ 124-48-1——————Dibromochloromethane____ 79-00-5———————1,1,2-Trichloroethane____ 71-43-2———————Benzene_______________ 10061-02-6————trans-1, 3-Dichloropropene_ 106-93-4——————1,2-Dibromoethane_______ 75-25-2———————Bromoform_____________ 108-10-1——————4-Methyl-2-Pentanone____ 591-78-6——————2-Hexanone____________ 127-18-4——————Tetrachloroethene_______ 79-34-5———————1,1,2, 2-Tetrachloroethane_ 108-88-3——————Toluene______________ 108-90-7——————Chlorobenzene__________ 1 1 1 1 1 5 1 1 1 1 1 28 1 1 5 1 1 1 1 1 30 1 1 1 1 1 1 5 5 300 1 1 1 Uu U uuuuuuuu E Uuuuuuuu E U Uuuuuuu E U Uu COin FORM I X-l 3/90 IX ORGANICS ANALYSIS DATA SHEET -Lab Name: ITAS-KNOXVILLE_________ Contract: Lab Code: ITSTU Case No.: 53554 SAS No.: Matrix: (soil/water) WATER Sample wt/vol: 5.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ Heated Purge: N GC Column: DB-624___ ID: 0.53 (mm) Soil Extract Volume: ______(uL) 0145 SAMPLE NO. MW04 SDG No.: MW01 Lab Sample ID: W7327 Lab File ID: W7327 Date Received: 03/08/93 Date Analyzed: 03/18/93 Dilution Factor: ____1. 0 Soil Aliquot Volume: ___ CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L .(UL) 100-41-4 ——— • 100-42-5 ——— - 1330-20-7 —— - 541-73-1 ——— - 106-46-7 ——— - 95-50-1 ———— - 96-12-8 ———— - —— Ethylbenzene —— Styrene - —— Xylene (total) —— 1, 3-Dichlorobenzene —— 1 , 4-Dichlorobenzene —— 1 , 2-Dichlorobenzene —— 1 , 2-Dibromo-3-Chloropropane _ 1 1 1 1 1 1 1 U U U U U U U TUT 004 1581 FORM I X-2 3/90 IX ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS 0146 SAMPLE NO. .Lab Name: ITAS-KNOXVILLE__________ Lab Code: ITSTU Case No.: 53554 Matrix: (soil/water) WATER Sample wt/vol: 25.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ GC Column: DB-624 ID: 0.53(mm) Soil Extract Volume: ______(uL) Contract: SAS No.: MW04 SDG No.: MW01 Lab Sample ID: W7327 Lab File ID: W7327 Date Received: 03/08/93 Date Analyzed: 03/18/93 Dilution Factor: ____1.0 Soil Aliquot Volume: ___ Number TICs found: CONCENTRATION UNITS: (ug/L or ug/Kg) CAS NUMBER COMPOUND NAME RT EST. CONC. Q TUT 004 1582 FORM I X-TIC L';(xl 3/90 r- •^T »—( O OATH FROM FILE: UU7327 SCAMS 45 TO 726 ACQUIRED: 93 18 35 10:05:00 CALI: CAL821992 K3 SAMPLE: CLP,53554,MU81, MU94 * LOW, WATER,W73271UOA,ERA, CONDS.: I500A:25I1L OLU01 AMBIENT PURGE W/ 5PPB IS 8. SS 186 3:20 I _L I I 100.0Z < 1075200.) CD in (- ^2 !- CO CDo O'J 200 J 6:40 380 J 10:00 CI10 1,4-DIFLUOROBENZENE <IS#1) f 400 J 13:20 580 J 16:40 600 J 20:88 "80 J :0 CI20 CHLGR06ENZENE-D5 <IS#2) CS18 4-BROMOFLUOROBENZEHE (SS> C126 1,4-DI CHLOROE:EHZEHE-D4 (I S#3 > : .-anti tatlon Report File: VV7327 0 1 4 eta: VV7327. TI j/13/93 10: 03: 00 -rT.ple CLP- 53554, MW01, MW04, LOW, WATER, VV7327, VOA, EPA, r...ds. I500A:25ML OLV01 AMBIENT PURGE W/ 5PPB IS 1* SS ' -mula 25ML AMBIENT PURGE Instrument: I500A W e i g h t : 0.000 .emitted by: ITEK Analyst: RJL Acct. No. : 53554 . •••-IJNT = A~EA * REF AMNT/<REF AREA * RE5P FACT) --.<?. fac. fro- Library Entry '••: Name • CI10 1,4-DIFLUOROBENZENE (IS#1) ' CI20 CHLOROBENZENE-D5 (IS#2) • CI26 1,4-DICHLOR03ENZENE-D4 <IS#3> ' CS10 4-3ROMOFLUOROBENZENE (SS) : CC10 CHLQROMETHANE ** • CO 15 SROflOMETHANE ' C020 VINYL CHLORIDE * ~ CC25 CHLOROETHANE - C030 METHYLENE CHLORIDE -. : C035 ACETONE -. : C110 2-3UTANONE : ••: C205 4-fiE1HYL-2-PENTANONE C210 2-HEXANQNE C03/ BROMOCHLOROMETHANE CC 10 CARBON DISULFIDE CC !5 1, 1-DICHLOROETHENE * CO50 1,1-DICHLOROETHANE ** C053 TRAf-S-1, 2-DICHLOROETHENE COiO CHLOROFORM * C06=- 1, 2-DICHLOROETHANE C115 1,1,1-TRICHLOROETHANE C120 CARBON TETRACHLORIDE C130 3ROMODICHLOROMETHANE C140 1,2-DICHLOROPROPANE * C143 CIS-1,3-DICHLOROPROPENE C150 TRICHLOROETHENE C155 DIBROMOCHLOROMETHANE C160 1, 1,2-TRICHLOROETHANE C165 BENZENE C17L? TRAWS-1, 3-DICHLOROPROPENE C176 1,2-DI3ROMOETHANE CISC SROfiOFORM ** C220 TETRACHLOROETHENE C225 1,1,2,2-TETRACHLOROETHANE ** C230 TOLUENE * C233 CHLOROBENZENE C240 ETHYL BENZENE * •• C245 STVPENE CZ'50 M/P XYLENE •• C252 0-XYLENE COS-1 CIS-i, 2-DICHLOROETHENE C253 1,3-DICHLOROBENZENE : C25T 1,4-DICHLORC3ENZENE TUT OO4 1584 C255 1,2-DICHLOROBENZENE C2fcl 1,2-DIBROMO-3-CHLOROPROPANE S8ST mi -p ru ru ru n o n n n -< i'*f •— I «-H y-H .— t _| _J _| _J X. X. X X. ( > f'l f'l f^l i> 5 5 D • P O O O .- c o o o m 3 o o o ru o . . . e m m in 't < ~ e n . . . x ro n o- ro — -o it -o in m -o >T m o * D- -o n m (_ < jc Cl Ci Cl Cl *P Cl Cl Cl Cl u E < <t < < t- O O O -0 tr o o o ro ce o o o n •-< •-« --i ru ««- * •-< ru ro •-« a o» ro -o -o ro e o ru ^ n •••«.. i- -o ru r-- «* o ru o _j X C1 ^i O (•V o r-t ro o- Cl Cl < ro ru o *— i •*•ru »-» ru 0 _, X O^ -0 -0 o OJ•tro ca ca < T-I o-ri o T-4 ^ ru ru T •"• O 0 0 0 _j _i (5 (ji i3 ^3 «r ru •* in -• o 0 0 ^ ru n m GJ CC| LO d < < n o in ro ro n 0 0 vH *-t C) O v-4 O oj ro 't r> — O O O _J _J O O D D «* m «-< sf in n o o ro ix o- rx •t -0 rj ca a ca <C < a- o ro o •^" O 0 O *"H TH ro <r n •-* ru *r oo ro _j X ^) (-.. [x ru 0n «^- rororon (TV Cl •I frn m o ru ru •3- -0 r--0 o _i fji^ 0- ru o 0 m Cl Cl < O «3~ o ru •0o ID o- ro |X _ixo ^) n roru ro o-ru r-- 4"!hn in * PJ Cl < ^. r- 0 ru rum o ._,o o _j X O ^) -0 OJo 0 0 -0 ca ca < n ro |x o ru •t"^ r> CO **• (x _jx (•> !D i— *nn ro l"U o a-0 0)ru ca ca <t Ch O -0 O vH ^. if to c> a 0 *o o o o o ro 4^ ^, ^ ^ o *D Ct - O O O -• _1 O O O *•« — o o o -o u . . . . fQ *— * »-< T-< O u_ 01 o o o n u o o o ru <D o o o m u. . . . . —f .-< r-l O ce - o o o o ..J 0 O 0 0 •" -\-> T> in ii > m n r- •cr •«-• o o o a: r o o o ru t ; . . . <t m in in «t o« o o o o •p o o o o ro . . . . Q, r, r, r-, r> -t 0 0 O -0 f- o o o ro D C . . . . fy ^^ y^ ^.4 (Tvl m -• o in ro•ii o *-H0 «-< 6 oo Ifi •t [v 6 ID (^1 •~t ru r> N ru ru ru o o o a-0 0 0- fxn 0 mno o oo in ^ «4- 0 oo *-» 0 - ru n 0 O OO '} r-- o in i- \- i"d b > o- o u -0 - z z n '1 u •• .it (- t d (jl z n c\ i~ h- t- O Q D z z z • .- Ill H- h- -0 o o r - z z n -t :p i> n Z •"1 • • •) I'l (~ ir <j.i n Z lrl rl r"* h- 1- h- o o o z z z • ' r'! '"> '•: f'l r,; i~ t- in O O (T z z -T •;< ./i r.J r,i H h- tT; U O r- i c:i i> H K H- n O O C' J.I i .1 • t i ii n :'i r: r: ' t~ V-. O tr- •1 '.'• i ~ .* • • • 1- 1- 1- h- (• O O O O ' z z z z : I1 r ru 'i - l'7 ,-•-, |'t i M * -0 t~ t- t- t~ o u o o o a Z Z Z Z i» • i - O O O O r. o -P O O O O O O 01 . _ •••• O T'j «-* '"•:• T-I n; {-,) i-| r-j t- - • . ii -u r >; r-- "1 »-• '-" •--" t-t i ij fK •(• 'f? •!• i in ii 0150 Ret(L) Ratio RRT(L> Ratio Amnt Amnt(L) R. Fac R.Fac(L) Ratio 2 3: 9: 11. 4- 2- 2 3 2 4 5 4. A S T 9 6' 1 1 10 e. . 10: 1 1 : 13: 1 0 : 15: cy 12: 12: 13 13: 13 Jf ^ 6' 16 17 18 04 SO 38 22 04 10 00 02 36 14 10 30 46 02 14 O6 ',2 22 40 06 22 28 58 50 02 44 28 46 46 02 42 44 30 42 18 40 0. 0. 0. 0. 0. 1 00 0. 1 00 0 0. 101 0 1 00 0 0 o. 0 0. 0 0 1 00 0 0 0 1 00 0 0. 0 0 1. 00 0 1. 1 00 0 1 1 1 1. 1. 1 00 O 0. 0. 1. 1 337 625 775 914 663 353 326 495 424 690 842 362 383 646 582 732 539 914 35S 410 834 922 S09 871 209 783 OO3 027 107 04S 102 4>09 956 967 002 081 1. 00 1. 00 1. 01 1 . 00 1 00 1 . 00 1 00 1. 00 1 00 0. 14 5. 00 0. 045 1 558 0. 03 0. 05 5 OO 0. 005 0 513 0. 01 0. 5! 5 00 0. 052 0. 501 0. 10 0.35 5 00 0 070 1.015 0 07 30. 23 5 00 6 035 0. 997 6 06 0 25 5 00 0.084 1 685 0.05 298. 28 5 00 70. 366 1 180 59. 66 0.03 5 00 0.009 1 773 0.01 28. 33 5 00 2. 285 0. 403 5. 67 TUT OO4 1586 3/18/93 10:03:22 Acquisition started 0151 2/18/93 10:03:26 • cquire Run 0: VV7327 TV 18/93 10:03:00 + 0:00 Free sectors: 12176 •*T,p le: CLP, 53554, MWO1, MWO4, LOW, WATER, VV7327, VOA, ERA, •-nds. : I5OOA:25ML OLVO1 AMBIENT PURGE W/ 5PPB IS ?< SS Start ing Scan: 0 of •:rmula: 25ML •-Emitted by: AMBIENT PURGE Instrument: I500A ITEK Analyst: RJL Weight: Acct. No: ., i* 1 —I f. Jl a 1 Desc . : RR j. Temp (DegC) 35-~35 35-150 150 150 ive A : cl Rate ( C/min ) 8. 0 - osed *** GC not ready and being stabilized *** CT 1 .a n e A *4 ^ i «\^ Time (minutes) period 6. 6 14. 3 3. 0 Valve B : total 6. 6 20. 9 23. 9 open Elapsed time In jec tor A : GC oven : Transfer-1ine: Ion source : 0. 000 53554 0. 0 Min 150 Deg C 36 Deg C 215 Deg C 180 Deg C «•«•* Instrument parameters **•* Post acquisition state -> Filament : Off Multiplier : Off '-C-E: El (+) Centroid + Temp - Sequence. BF ( 2 time windows. ) Sequence Window ft 1 an descriptor: t a 1 scan time: Number of cycles: Filament is OFF Multiplier is ON BF Mass intervals 2. OOO s 28 Positive ion mode. Master rate: 16 •^W: 3 MFW: 80 MA: 15 Int # Lo mass Hi mass 1 33. 510 300. 590 TH 1 Time 2. 000 DL: r ; ? H u e n c e W i n d o w :.jn d e s c r i p t o r : *3tal scan time: ft 2 Number of cycles: 1 Filament is ON Multiplier is ON BF Mass intervals: 1 2. 000 s Positive ion mode. Master rate: 16 :^W: 3 MFW: 80 MA: 15 TH: 1 Int ft Lo mass Hi mass Time 1 33. 510 300. 59O 2. 000 BL: Calibration table: D:CAL021992 Interface number Instrument type Ful1 scale mass Zero scale mass Intensi ty/i on Peak width Offset at low mass Offset at high mass 0 G 1177 1 Voltage settling time(ms) 20 u u 1000. mmu 0 mmu 0 mmu TUT 004 1587 000! Current instrument parameters. Positive ion mode 0152 Resolution (high) Resolution (low) Quad offset Quad programming Lens offset Lens programming Ext offset Ext programming Collector Ion offset Ion programming Rod polarity 128. 128. 0. 0. -50. 0. 0. 0. 30. 7. 5. 00 00 00 00 00 00 OO 00 00 00 00 Negative ion mode 128. OO 128. 00 0. 00 0. 00 00 00 OO 00 00 OO 00 Reverse Electron multiplier voltage Filament emission current Electrometer range Electrometer zero 50. 0. O. O. 30. -3. -5. Norma1 984. 750. 1O '"-7 126. 0 ^alyzer Fore Pressure ... r-rparator/Sourc e Pressure O. 010 Torr 0. 361 Torr 3/18/93 10:32:00 ACQUISITION COMPLETED Scans 1 to 720 Centroid .de Scans Sees Out of "*atroid 720 08 1440.0 0. 1 Peaks per scan 8222. 11. per sec 6. TUT 004 1588 \jvrti_i i T «aaur<Hiv\,ci i/« i M « « ^ .% . ——— 0 METHOD: CLP 3'9O OLV01 25ML PURCE DATAFILE: VV7327 ANALYSIS TIME: 03/18/73 10:03 STANDARD: WS0318 ANALYSIS TIME: 03/18/93 8:29 TUNEFILE: WBFB0318 ANALYSIS TIME: 03/18/93 8:20 *»**#* INTERNAL STANDARD AREA CHECK ****** DATA STD CLP INTERNAL STANDARD AREA AREA RATIO ACCEPT RATIO STATUS !10 1, 4-DIFLUOROBENZEN 9668. 1121O. 867. 607. - 1407. '.2.0 CH. OR03ENZENE-D5 ( 6443. 7723. 837. 607. - 14O7. 56 1, A-DICHLORDBENZEN 3569. 5477. 657. 607. - 1407. ****** INTERNAL STANDARD RT CHECK ****** DATA STD DIFF CLP INTERNAL STANDARD SCAN SCAN [IN SEC D ACCEPT DIFF STATUS 10 1,4-DIFLUOROBENZEN 184 134 0 +/- 20 SECS SO CHi OROBENZENE-D5 ( 373 373 0 + /- 20 SECS :26 1, 4-DICHLOROBENZEN 518 518 0 +/- 20 SECS ******* SURROGATE RECOVERIES ****** AMT AMT PERCENT SURROGATE FOUND ADDED RECOVERY RECOV LIMITS STATUS iO 4-SROMOFLUOROBENZE 4. 3 5. O 86 BO'/. - 12O7. 15 BROKOMETHANE -0.0 50.0 0 887. - 1107. failed * 0.7 50.0 1 867. - 1157. failed TUT OO4 1589 L0001590 REFERENCE: VI 1 f.'*ME LIST: VI REPORT: VII ——— STANDAR r<oc USED P — 3 2 3 3 3 3 45 COMPOUND •:o 1 2 'ji 4 ^ 6 7 e 9 10 1 1 12 t •*? 14 15 la ( T \ / _^.8 ~^;9 20 21 22 **'"? £4 25 26 77 28 79 30 31 ? 'j 33 34 35 36 37 ;8 39 40 41 i£ + 3 ^44 45 LIB VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI ENTRY 1 2 3 4 5 b 7 3 9 1O 1 1 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 3O 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 i 01 INITIALIZATION OPTION: 2 PROCESSING OPTION: 3 S DS ———— >C —— PLUS UNKNOWNS —— >< - LIST NAMES - > OSS RMS PROC USED POSS RMS STANDARD/UNKNOWN 1 0 20 7 1 108 V1IS/V1UNKS1 1 O 16 5 1 52 V1IS/V1UNKS2 1 O 15 4 1 O V1IS/V1UNKS3 S PROCESSED, 9 FOUND _ <^rr Aor*i_i %. .-• c? A -r -s. .*- r*Ljar\ \* REF -184 -373 -518 -439 -38 -44 -39 -46 -72 -62 -115 -289 -341 -122 -65 -60 -91 -78 -127 -155 -135 -143 -242 -218 -274 -201 -341 -321 -153 -311 -344 -420 -325 -451 -293 -375 -384 -413 -391 -412 -112 -496 -501 -519 -561 jtmr\^n _'••<. on i PRED SEL DELTA PEAKS FIT PEAKS 184 184 . 1 981 373 373 . 1 971 5 1 8 . . . . . 439 439 . 1 953 3 9 . . . . 4 5 . . . . . 40 42 2 1 726 4 7 . . . . . 73 72 -1 1 864 6 3 . . . . . 1 1 6 . . . . . 2 8 9 . . . 3 4 1 . . . . 1 2 3 . . . . . 6 6 . . . . 6 1 . . . . . 9 2 . . . . . 7 9 . . . . . 128 127 -1 1 818 156 . 1 3 5 . . . . . 1 4 3 . . . . . 2 4 2 . . . . . 2 1 8 . . . . 2 7 4 . . . . . 201 2O1 . 1 974 3 4 1 . . . . . 3 2 1 . . . . . 153 . 3 1 1 . . . . 3 4 4 . . . 4 2 0 . . . . 325 326 1 1 966 451 . . . . 293 . . . . 375 . . . 384 . . . . 413 . . 391 . . . . 4 1 2 . . . 112 112 . 1 915 4 9 6 . . . 501 . 5 1 9 . . . . . 561 M/Z 114 117 150 95 50 94 62 64 84 43 43 43 43 128 76 96 63 96 83 62 97 117 83 63 75 95 129 97 78 75 107 173 166 83 91 112 91 104 106 106 96 146 146 146 75 TOP 184 373 518 439 42 72 65 60 79 127 201 153 326 292 112 DELTA PEAKS 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 L000159. TUT OO4 1590 I. T. ANALYTICAL SERVICES LIBRARY SEARCH REPORT PURCEABLE VOLATILE ORGANICS ANALYSIS 0155 'ATA FILE: W7327 :3UIRED. 03/18/93 10:03:00 r'.'NDS. : I500A:25ML OLV01 AMBIENT PURGE W/ 5PPB IS &• •-'..'BMITTED BY: ITEK SS ANALYST: RJL ACCOUNT NO. 53554 COMPOUND :10 1,4-DIFLUORODENZENE <IS*1) 120 Clii OR03ENZENE-D5 <IS#2> '26 1,4-DICHLOROBENZENE-D4 <IS#3> 510 4-BROMOFLUOROBENZENE (SS) J?0 TRICHLOROETHENE 120 TETRACHLOROETHENE :'?4 CIS-1. 2-DICHLOROETHENE SCAN DELTA (UG/ML) FIT .134 373 518 439 201 326 112 0 0 0o 0 1o 5. 5. 5. 4. 30. 298. 28. 000 000 000 281 277 285 331 981 971 0 953 974 966 915 SAT'D? O 0 0 0 0 0 O TUT 004 1591 L000159,- TARGET COMPOUND COMPARISON COMPOUND: C158 TRICHLOROETHENE RAW DATA: UU7327 #281 BASE ft-' 2: 95 RIC: 49856. 100.0- 50. 0— 95.5: 47.7-: 12.8- 6.4-i M/2 100.0- 50.0: 0.8: -50.8: I/O' 1O" Ji. SAMPLE: CONDS.: 1,, 7 lUiUO CLP, 53554, MW01 , MW04, LON, WATER, UU7327, UOA, EPA. I500A:25ML OLU01 AMBIENT PURGE W/ SPFfi IS fe < 1 i . , , - . . i i 1 . . . . . . . . , . , , , . , . , . . . . , . . ENHANCED DATA: UU7327 #281 Bi 1, LIBRARY 1 . 48 1... ii 1 FILE: Ml #26 i , , , . . , j 58 68 ii. i — r-l — i — | i i — . i | — l - l i . — | — r-i- Bl • r- i i | t i i i | t r T i r i - i - 1 , - - . . . . . . . . . . * -j . . . . ;s U. ,....,....,.... 6E M/Z: 35 RIC: 46288. 4-.T,T __, ,, __, iSE M/Z: 95 RIC: 53: i i 56 88 10U 129 i i .... . . ..... ...... 1 ' • 1 ' 1 ' 1 I ' • 1 [ 148 • i • ^ t i- - 7316. 7464. - 1800. '- ttOUT** TARGET COMPOUND COMPARISON COMPOUND: C226 TETRACHLOROETHENE 00.0- 50.0-: 89.0- 44.5-: 8.7- 8.3-i /Z 98.0-; 58.8-: 8.9-: 58.8- 00. 0: RAW DATA: UU7327 #326 BASE M/Z: 166 RIC: 1075200. 03/18/93 10:03 SAMPLE: CLP, 53554, MW01 , MW04, LOW, WATER, UU7327,VOA, ERA > CONDS.: I500A.-25ML OLU01 AMBIENT PURGE W/ 5PPB IS & SS | , i, i i • | • i • i • i • i • | • i • i • ENHANCED DATA: UU7327 #326 1 i l.i. I • i • i • i • i LIBRARY FILE: Ul i 50 i. . i. ...... ,. .. 1 1 . , . , . , . , . , . , . , . #33 1 1 H H , . , . , . , . , . , . , . , . 100 150 1... .... .11,,... ......... i . , . , , 1 . , , , . , . , . | • , . , • i . i . | BASE M/Z: 166 RIC: 968704. • • . , . , • , • i • • . . . 1 • i • • - , - . - 1 BASE M/Z: 166 RIC: 5560. • , . , . , . , . , . , . , . , . , . , . , . , • 1 200 250 300 ii i i i n i i i i ft n 1 1 I t 0 0 - 143736. 7 132352. 1600. - - ttoum _ 3 i- trOO CO 1O — ' TARGET COMPOUND COMPARISON o COMPOUND: C054 CIS-l/2-DICHLOROETHENE 100.0- 50.0-: 93.1- 46.6-: 9.4- 4.7-: M/Z 100.0- 50.0-1 0.0-: -50.0-: 100.0^ RAW DATA: UU7327 #112 BASE M/Z: 61 RIC: 40000. 03/18/93 10:03 SAMPLE: CLP, 53554, MW01 , MW04, LOW, WATER, W7327, UOA, EPA, CONDS.: I500A:25ML OLV01 AMBIENT PURGE W/ 5PPB IS & SS ' • • • • ! • • • • ! • ' ' • ! • • ENHANCED DATA LIBRARY FILE: '• •• • ! • • • • ' "•'!•' 38 40 t ' ' T- | , | | | I , , , , , , , , | JU7327 #112 Ul #41 1 '' ' I' ' ' ' 1 " ' ' ' • • ' ' 1 ' ' ' •' ' ' ' ' 1 • ' • •' ' '' • | • • " i ' BASE M/Z: 61 RIC: 33408. BASE M/Z: 61 RIC: 3240. i 1 J 1 1 1 1 1 f T 1 J 1 1 1 1 , , | , , , , | , , . . , . . . . | . , . . , . . . . | , , , , , , , , . . , , 50 g0 70 80 90 108 . . . . . . . . . . . . . ( . . , . , . . i r 10688. 9952. 1000. r **oum 0159 D«ta: W7327. TI 03/18/93 10:03:00 Temple: CLP, 53594, MW01, MWO4, LOW, WATER, VV7327, VOA, ERA, :-nds. : I500A:25ML OLVO1 AMBIENT PURGE W/ 5PPB IS !< SS "rrmula: 25ML .Emitted by: AMBIENT PURGE Instrument: I5OOA ITEK Analyst: RJL Weight: Acct. No. 0 000 53554 -••3UNT=HFIGHT * REF AMNT/(REF HEIGHT * RESP FACT) ~ e i p . fac. from Library Entry \<o CAS # Name 1 0-00-0 CI01 BROMOCHLOROMETHANE (I.S.#1> :? 0-00-0 CI10 1, 4-DIFLUOROBENZENE (I.S. #2) r< O-OO-O CI2O CHLOROBENZENE-D5 (I.S. #3) 4 7440-37-1 ARGON ? 124-38-9 CARBON DIOXIDE Area(Hght) 6090. * 10108. » 7609. * 2656. * 179O. * m R R R R R /I 1C 1C 1C 1C 1C Scan 184 373 518 137 141 Time 6: 12: 17: 4: 4: 08 26 16 34 42 Ref 1 2 3 1 1 1. 1. 1. 0. 0. RRT 000 OOO 000 745 766 M« A A A A A ?th BB BB DB VD BV Amount "/.Tot 50. 000 UG/L 26. 81 50. 000 UG/L 26. 81 50. 000 UG/L 26. 81 21. 807 11. 69 14. 694 7. 88 TUT O04 .1595 L O C 0 1 5 9 G :ATA FILE: W7327 \J 1 U V - ILTER SCAN PARAMETERS METHOD LIBRARY St LISTS "AX. NUMBER TICS '-TABLE ENTRIES _.:AN TOLERANCE ••IN. RIC HT. C7.3 •TRST SCAN .AST SCAN •1C THRESHOLD 10 495 3 10 35 1000 500 TIC I.S. LIBRARY: NBS SEARCH PROC : PEAK FINDER PROC: TCA I. S. LL : FILE NAME LIST : LIBRARYIS SERLIB VOME5 IS TCAREF2 --V3GET COMPOUND ANALYSIS: TARGETS (QUAN LIST) r!LTER PROCESSING: IS PEAKS 3 TOTAL TARGET PEAKS 15 OTAL EAKS 14 -: IST SCAN 0 > LAST SCAN 0 —— — rrc.vjc.1. < MIN RIC HT 0 i re.«t\s — - < SCAN TOL 11 > MAX * PEAKS 0 TOTAL REJECTS 11 TOTAL TICS 3 1C PROCESSING: -'. SCAN* PURITY FIT 36 137 141 437 765 961 437 996 999 MW COMPOUND NAME [BEFORE TIC THRESHOLD] 161 ACETAMIDE, 2, 2, 2-TRICHLORD- 40 ARGON 44 CARBON DIOXIDE TUT OO4 L0001597 CD •^ O 1000 ;AMPLE :2.H2.0.N.CL3 1000 I MT 161 J PK 44 !AHK 1 > 10563 'UR 437 2.H3.0.N.CL2 1000 I WT 127 PK 44 ANK 2 4062 UR 412 2.02.F4 1000 MT 132 PK 44 ftNK 3 4876 UR 296 M/Z Z.6ST frOO mi MID LIBRARY SEARCH (LIBRARYNB) 03/18/93 10:83:00 + 1:12 DATA: W7327 I 36 CALI: CAL921992 # BASE RIC: •Z: 44 236448. LO SAMPLE: CLP,53554,MH81,MW04,LOW,WATER,UU7327,UOA,EPA, CONDS.: I500A:25ML OLU01 AMBIENT PURGE W/ 5PPB IS & ENHANCED <S 15B 2N 0T> ACETAMIDE, 2,2,2-TRICHLORO- CAS# 594-65-0 ACETAMIDE, 2,2-DICHLORO- CAS# 683-72-7 l CARBONOFLUORIDIC ACID, TRIFLUOROMETHVL ESTER CASK 3299-24-3 28 46 60 39 100 120 86S T frOO MID LIBRARY SEARCH (LIBRARYHB) DATH: 03/18/93 10:03:80 + 4:34 , CALI: SAMPLE: CLP,53554,MW01,MW04,LOW,WATER,W7327,UOA,EPA, CONDS.: I500A:25f1L OLV01 AMBIENT PURGE M/ 5PPB IS & SS ENHANCED (5 15B 2N 0T) mi CHL021992 BnSE M f: PIC: CD ARGON CAS# 7440-37-1 4-PENTYN-2-OL r CAS# 2117-11-5 i 1 ACETIC ACID, HETHOXY-, METHYL ESTER r CAS# 6290-49-9 -t-»- 20 40 70 90 100 O O O f O O - J - 7 ~\ t- ? S <3 — • * £ •si. |j=i •• CD ct: oo 1— » 1 — 4 «= cn en [••- — « oo <s> S o i 3 Ct ff S « H^ T^ ^^ ^> ^"^. ^ + goo O iS ^ E '» !%•' 1^1 lj~l Ij*"! <r .. \r> c--t CQ LU OO OO .. U~J ij"i O b*0 <X *^ ">— cji Q_ CD ' O C«i — — 1 IO ^ <r o •-• Ct 00 Q co cn •• •• LU •— « N LU • O ^J CO *^J 0"^ ZH ^•4 O» Cj ^1 •— < OO LO o LU i CO 00 1 4t S • i. • LU - Cl . Xo t—to ' GP -<xo • 'l cn a .s •io - L • • o — CM LU - O ' O O (— • IS CO r-.i .5 - - .^ u • z: • o - o . CJ <r ' o <r o •* !N CM •*? "^eotlo CM •*••*• oo ui CM CM r^~ u? in is> LU o cn <s» cn o® co cn ->S L[0 •S -U".' IT) . -? • :B • • in • in coin ^ ff ^^ - - ~ -^ - - - -^ - rvj IX ORGANICS ANALYSIS DATA SHEET ab Name: lTAS-KNnyvTT|.T/R_________ Contract: "Lab Code: ITSTU Case No.: 53554 SAS No.: Matrix: (soil/water) WATER Sample wt/vol: 25.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ Heated Purge: N GC Column: DB-624___ ID: 0.53 (mm) Soil Extract Volume: ______(uL) 0164 SAMPLE NO. MW04DL SDG No.: MW01 Lab Sample ID: W7327 Lab File ID: W7327D Date Received: 03/08/93 Date Analyzed: 03/18/93 Dilution Factor: 13.0 Soil Aliquot Volume: CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L FORM I X-l .(UL) 74-87-3 ————— 74-83-9 ————— 75-01-4 ————— 75-00-3 ————— 75-09-2 ————— 67-64-1 ————— 74-97-5 ————— 75-15-0 ————— 75-35-4 ————— 75-34-3 ————— 540-59-0 ———— 540-59-0 ———— 67-66-3 ————— 107-06-2 ———— 71-55-6 ————— 56-23-5 ————— 75-27-4 ————— /o o /— 3— — — — — ~ 10061-01-5 —— 79-01-6 ————— 124-48-1 ———— 79-00-5 ————— 71-43-2 ————— 10061-02-6 —— 106-93-4 ———— •7 c *} c o 108-10-1 ———— 591-78-6 ———— 127-18-4 ———— 79-34-5 ————— i no QQ_~)_____ J. U o yu / —— Chloromethane —— Bromomethane —— Vinyl Chloride —— Chloroethane —— Methylene Chloride —— Acetone —— Bromochloromethane —— Carbon Disulfide —— 1, 1-Dichloroethene —— 1, 1-Dichloroethane —— trans-1, 2-Dichloroethene —— cis-1 , 2-Dichloroethene —— Chloroform —— 1 , 2-Dichloroethane —— 2 -Butanone —— 1 , 1 , 1-Trichloroethane —— Carbon Tetrachloride —— Bromodichloromethane —— 1 , 2-Dichloropropane —— cis-1 , 3-Dichloropropene —— Trichloroethene —— Dibromochloromethane —— 1 , 1 , 2-Trichloroethane Denzene —— trans-1 , 3-Dichloropropene ___ —— 1 , 2-Dibromoethane —— Bromoform —— 4 -Methyl-2 -Pentanone —— 2-Hexanone —— Tetrachloroethene —— 1 ,1,2, 2-Tetrachloroethane ___ —— Toluene —— Chlorobenzene 13 13 13 13 24 65 13 13 13 13 13 30 13 13 65 13 13 13 13 13 29 13 13 13 13 13 13 65 65 250 13 13 13 U U U U BJ" U U U U U U EW U U U U U U U U DJ- U U U U U U U U D U U U 3/90 L0001601 IX ORGANICS ANALYSIS DATA SHEET T,ab Name: ITAS -KNOXVI LLE _________ Contract: Code: ITSTU Case No.: 53554 SAS No.: Ulbb SAMPLE NO. MW04DL SDG NO.: MW01 Matrix: (soil/water) WATER Sample wt/vol: 25.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ Heated Purge: N GC Column: DB-624 ID: 0.53 (mm) Soil Extract Volume: ______ (uL) Lab Sample ID: W7327 Lab File ID: W7327D Date Received: 03/08/93 Date Analyzed: 03/18/93 Dilution Factor: 13.0 Soil Aliquot Volume: ___ CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L .(uL) 100-41-4 ——— • 100-42-5 ——— • 1330-20-7 —— • 541-73-1 ——— • 106-46-7 ——— • 95-50-1 ———— • —— Ethylbenzene —— Styrene —— Xylene (total) —— 1 , 3 -Dichlorobenzene —— 1,4 -Dichlorobenzene —— 1 , 2 -Dichlorobenzene —— 1 , 2-Dibromo-3-Chloropropane _ 13 13 13 13 13 13 13 U U U U U U U FORM I X-2 TUT OO4 16O1 LOGciGO^ 3/90 IX ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS Lab Name: ITAS-KNOXVILLE_________ Contract: Code: ITSTU Case No.: 53554 SAS No.: Matrix: (soil/water) WATER Sample wt/vol: 25.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ GC Column: DB-624 ID: 0.53fmm) Soil Extract Volume: ______(uL) SAMPLE NO. MW04DL SDG No.: MW01 Lab Sample ID: W7327 Lab File ID: W7327D Date Received: 03/08/93 Date Analyzed: 03/18/93 Dilution Factor: 13.3 Soil Aliquot Volume: ___ .(uL) Number TICs found: CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L CAS NUMBER COMPOUND NAME RT EST. CONC. Q TUT OO4 1602 FORM I X-TIC LOCO [6 3/9° DATA FROM FILE: W7327D SCANS 45 TO 720 ACQUIRED: 93.-18/33 11:24:66 CALI: W7327D #3 SAMPLE: CLP_53554, MU61, MW64DL, LOW, WATER, W7327, UOA, ERA, CONDS.: I586A:25ML OLUfll AMBIENT PURGE M/ 5PPB IS 8c SS 280 _ 6:40 308 J 10:68 400 J 13:20 506 J 16:48 680 J 20:08 700 -, 01 J_ J. J 100.0Z ( 85120.) CI16 1,4-DIFLUOROBENZENE (ISttl) CI26 CHLOROBENZENE-D5 <IS»2> CS10 4-BROMOFLUOROBEHZENE (SS) CI26 1,4-DICHLQRQBENZENE-04 (ISIS) D - ro CO •—to o 0168 j:,*ntitation Report File: VV7327D :ata: VV7327D. TI •j,-118/93 11:24:00 •jnple CLP_53554, flWOl, MW04DL, LOW, WATER, W7327, VOA, EPA, :.\ds. I50OA:25N_ OLV01 AMBIENT PURGE W/ 5PPB IS £•. SS "=--mula 7. 5ML->10CNL: 1->13. 3Instrument: 1500A W e i g h t : 0.000 :-!.: mitt ed by: ITEK Analyst: RJL Acct. No. : 53554 • -••DUNT=AnEA * REF AMNT/CREF AREA * RESP FACT) •'•i--p. far. from L i b r a r y Entry -.•:• Ncrps CI10 1,4-DIFLUORODENZENE <IS#1) I CI20 CHLQROBENZENE-D5 CI5#2) ? CI2A-. 1, 4-DICHLORCBENZENE-D4 (IS#35 i CSIO 4-DROMOFLUORODENZENE (S3) -" CO 10 CHLGROMETHANE •»* r CO 15 BROMOMETHANE ~ CC2O VINYL CHLORIDE *• I- CC25- CHLOROETHANE " C03O METHYLENE CHLORIDE 10 C035 ACETONE C110 2-3'JTANONE -. .•? C2D5 4-METHYL-2-FENTANONE -. ? C210 2-HEXANONE -.1 C037 BROMOCHLOROKETHANE - ^ C0:0 CARSiDN DISULFIDE -. t CO-15 1, 1-DICHLOROETHENE * : ' CO3-0 1, 1-DICHLOROETHANE ** '. •= CO52 TRANS-1-2-DICHLOROETHENE ^:^ CO6O CHLOROFORM # 2'.: C0i5 1; 2-DICHLOROETHANE 11 C'l=. 1.. 1, l-TR I CHLOROETHANE .:~ C1ZO CARSON TETRACHLORIDE "5 Cl?0 BROMQDICHLOROMETHANE '-:- C140 1, 2-DICHLOROPROPANE * i= C143 CIS-1,3-DICHLOROPROPENE rli C55O TRICHLOROETHENE C15r DIDROMOCHLOROMETHANE :•= ClbO 1, 1, 2-TRICHLOROETHANE -:- Cl-^5 BENZENE ?.•:: C172 TRANS-1* 3-DICHLOROPROPENE 21 CI76 1,2-DIBROMOETHANE I?. ClSO BRCMOFORM ** .'j C22O TETRACHLOROETHENE i~ C22-3 1, 1, 2, 2-TETRACHLOROETHANE *•* 25 C230 TOLUENE * ?.i C233 CHLOROBENZENE ::•" C240 ETHYL BENZENE * •IS C245 STYRENE ;•? C250 M/P KYLENE -!•:: C252 0-XYLENE -i C054 CIS-1.. 2-DICHLOROETHENE -2 C253 1,3-DICHLORODENZENE -I' C254 1, 4-DICHLOROBENZENE ^-4 C255 1,2-DICHLORODENZENE TUT °°4 i604 ^-•^' C261 1, 2-DIBROMO-3-CHLORQPROPANE 0163 *• :• ;, .2 ^ .4 JC A *T - -r •" "i •^ ,• •i- -i - 5 ••;• 2 C1 z. \ Z.C. 23 24 — c "' 4. ~ "T i£ 2- w V*' — ; -". «^. — ~ • il — . c •J w ^. .•' I-i .y •'• C .. • -• i. 1 •"• Z 1 .* .u ^ e fn/ 2 114 117 150 95 NOT NOT NOT NOT S4 L! .^ NOT NOT NOT NOT NOT NOT NOT NOT S3 NOT NOT NOT NOT NOT NOT OS NOT NOT NOT NOT NOT NOT Itt NOT NOT NOT NO) NOT NUT NOT ? NOT NOT NOT NOT Scan Time Ref RRT Meth Area<Hght) 182 6 04 1 l.OOO A BB 10855. 372 12:24 2 1 OOO A BV 7616. 517 17:14 3 l.OOO A EB 4854. 438 14.36 1 2.407 A BE 6553 FOUND FOUND FOUND FOUND 71 2:22 1 0.390 A BE 1477. 61 2 02 1 0 335 A EB 83 FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND 127 4 14 10 698 A EB 131 FOUND FOUND FOUND FOUND FOUND FOUND 200 6.40 20 538 A BB 3311. FOUND FOUND FOUND FOUND FOUND FOUND 324 10: 48 2 0. 871 A BB 34160. FOUND FOUND FOUND FOUND FOUND FOUND FOUND 111 3:42 1 O. 610 A BB 2008 FOUND FOUND FOUND FOUND Amount 5. 000 UG/L 5. 000 UG/L 5. 000 UG/L 4 940 UG/L v.Tot 10. 52 10. 52 10 52 10. 40 1. 794 UG/L 2 327 UG/L 78 0. 059 UG/L 0. 1 2 181 UG/L 4 59 19.014 UG/L 40. Ol 294 UG/L 4. 83 Ret(L) 6 12: 17 14 1 1 : 1 : 1 : OS 26 16 38 18 28 20 32 Ratio 0. 1 1 1. 99 00 OO 00 RRT(L) 1. 1. 1. 2 0 0. 0. 0 000 000 000 386 212 239 217 250 Rati o 1. 1 1. 1. OO 00 OO 01 Aim t 5. 5 5 4 00 00 00 94 Amn t ( 5 5. 5 5 :L> 00 00 00 00 R. Fac R. 1. 1. 1. 0. 000 coo 000 604 Fac(L) Ratio 1. 1. 1. O 000 OOO OOO 611 1 1. 1 0. 00 00 00 99 \r>o ••0 TH oo H —— . 0. 0. 39J 1 00 1. 79 5 00 0. 136 0. 379 0. 36 L O C 0 1 6 0 0 u L r \o ! 0 1 1 i & -. o -. .-i l i' \ - 1 —• I i^ •; 9 T. — . i 2; -« -i Ti "7 ic TS-T 1" "": !•? ^ "to* 31 3i 23 ::4 75 36 37 28 37 -0 T • -1 ^ 43 4 4 •« 5 Rei 2: 3: 9; 11: 4 2: 2. 3 ; c^ '. 4 5 4 : 4 e •T . 9 ^ • 1 1 : 10: 5. 10: 1 1 13: 1C 159 12 12 13 13: 13: 3 16 16 17 IS :(L) Ratio RRT(L) Ratiq 04 50 38 22 O4 10 00 02 36 14 10 30 46 02 14 06 42 22 40 06 22 28 58 5O 02 44 2B 46 •16 02 42 44 30 42 18 40 0. 98 0. 0. 0. 0. 0. 0. 0. 0. o. 1. 00 0. 0. 0. 0. 0 0. 0 1 00 0 0. 0. 0 0. 0 0 1 OO 0. 1. 0 1 1. 1. 1 1. 0. 99 0. 0. 0 1 1 337 0. 99 625 775 914 663 353 326 495 424 690 1. 01 842 362 383 646 582 732 539 1 . 00 914 S5S 410 334 922 809 371 1 00 209 783 003 027 107 O48 102 609 1. 00 956 967 002 081 Amnt Amnt(L) 2. 33 25. 00 0. 06 5. 00 2. 15 5. 00 19 01 5 00 2 29 5. 00 R.Fac R.Fac(L) Ratio 0. 002 0. 016 0. 09 0.012 1.015 0 . 0 1 0.435 0.997 0 . 4 4 4. 485 1. 180 3. 80 0. 185 0. 403 0 46 TUT OO4 16O6 uoooiGo; 3/18/93 11:24:13 Acquisition started 0171 3/18/93 11: 24: 19 cquire Run 0: W7327D Starting .:«/ 18/93 11:24:00 + 0: 00 . Free sectors: 11960 Scan: 0 of • a.rple: CI_P_53554, M1J01, MW04DL, LOW, WATER. W7327, VOA, ERA, :rnds. : I500A:25ML OLVO1 AMBIENT PURGE W/ 5PPB ::rmula: 7. 5ML-MOOML: 1 ->13. 3Instrument : 1 50OA i'.tmitted by: ITEK Analyst: RJL IS S< SS Weight: Acct. No: 720 0.000 53554 Desc : RR t. Te,-p (DegC) 35-'35 35-150 150-150 ,ve A : c1osed *** GC not ready and being equilibrated #** Elapsed t ime : 0. O Min Post Rate <C/min 6. 6 8. 0 14. 3 3. 0 Valve B : *** Instrument acquisition state -> Time < minutes > period total 6. 6 20. 9 23. 9 open parameters Filament Injector A GC oven Transfer-1ine I on sourc e 150 45 216 181 Deg Deg Deg Deg CDE: El (+) Centroid + Temp - Sequence: BF *#* Off Multiplier ( 2 time windows Off f.?$uence Window •'an deteri ptor: :'tal scan time: Number of cycles: 2 Filament is OFF M u l t i p l i e r is ON BF Mass intervals: 2. 000 s 8 Posit ive i on Master rate: mode. 16 W: 3 MFW: 80 MA: 15 TH: 1 r.t K Lo mass Hi mass Time 1 33. 510 300. 590 2. OOO DL: Window # sn descriptor: -tal scan time: Number of cycles: Filament is ON M u l t i p l i e r is ON BF Mass intervals: 2. 000 s Positive ion mode. Master rate: 16 •>;: 3 MFW: 80 MA: 15 TH: 1 -1 # Lo mass Hi mass Time 1 33. 510 300 590 2. 000 BL: Calibration table: Interface number Instrument type Full scale mass Zero scale mass Intensi ty/ion Peak width Offset at low mass Offset at high mass Voltage settling time(ms) D:CAL021992 0 Q 1177 1 -i 1000. 0 0 u u mmu mmu mmu TUT 004 1607 -• r r e i > i/ p =s rame t er Positive Resolution (high) Resolution (low) Quad offset Quad programming Lens offset Lens programming Ext offset Ext p rogram.f.ing Col 1ec tor Ion offset Ion programming Rod polarity ion mode 128. OO 128. 00 0. 00 0. 00 -50. 00 0 OO 0. 00 0. 00 30. 00 7. 00 5. 00 Reverse Electron multiplier voltage Filament emission current Electrometer range Electrometer zero Negative ion mode 128. 00 128. 00 0. 00 0. 00 50. 00 0. 00 0. 00 0. OO 30. OO -3. 00 -5. 00 Norma1 984. 750. 10 ~-7 126. 0 a l y z e r Fore Pressure . . . sarat or /Sourc e Pressure 0 010 Torr 0. 361 Torr 18/93 11: 51: 28 ACQUISITION COMPLETED Scans 1 to 720 Centroid id Sc ans 720 Sees 0. 4 Out of 1440. 0 7m Peaks per scan 0. 0 4129. 6. per sec 3. TUT O04 16OS L n METHOD: CLP 3'90 OLV01 25ML PURGE DATAFILE: STANDARD: TUNEFILE: W7327D WS0318 WBFB0318 ANALYSIS TIME: ANALYSIS TIME: ANALYSIS TIME: 0173 03/18/93 03/18/93 03/18/93 11:24 8:29 8:20 **#*#* INTERNAL STANDARD AREA CHECK ****** INTERNAL STANDARD DATA STD CLP AREA AREA RATIO ACCEPT RATIO STATUS :iO 1, 4-DIFLUOROBENZEN 10855. 11210. '20 CHLOR03ENZENE-D5 ( 7616. 7723. 26 1, 4-DICHLOROBENZEN 4854. 5477. 977. 607. - 14O7. 99'/. 60% - 14O7. 897. 607. - 1407. ****** INTERNAL STANDARD RT CHECK ****** INTERNAL STANDARD 10 1, 4-DIFLUORODENZEN 20 CMLOROBENZENE-D5 ( 26 1, 4 DICHLOROBENZEN DATA SCAN 182 372 517 STD SCAN 184 373 518 DIFF CIN SEC 3 4 2 2 CLP ACCEPT DIFF STATUS +/- 20 SECS +/- 20 SECS +/- 2O SECS ****** SURROGATE RECOVERIES ****** SURROGATE AMT FOUND AMT ADDED PERCENT RECOVERY RECOV LIMITS STATUS l>iO 4-DROMOFLUOROBENZE 4. 9 5. 0 :i5 BROffOMETHANE -0. O 50.0 •20 VINYL CHLORIDE * -0. 0 50. 0 99 0 0 8O7. - 887. - 867. - 12O7. 1107. 1 1 57. failed failed TUT OO4 1609 L 0 0 0 1 6 J G j/ io/ -r J =;o. i Y T'ATA FILE: nEFERENCE: LIST: REPORT: VV7327D VI 11 VI INITIALIZATION OPTION: VI IS PROCESSING OPTION: 3 0174 — STANDARDS - USED POSS 3 2 1 3 3 1 3 3 1 RMS 0 0 0 —— PLUS UNKNOWNS PROC USED POSS 20 5 1 16 5 1 15 4 1 —— :•< - LIST NAMES - : RMS STANDARD/UNKNOWN 0 V1IS/V1UNKS1 O V1IS/V1UNKS2 0 V1IS/V1UNKS3 45 COMPOUNDS PROCESSED, 7 FOUND ^unruuiNu *• •-. — —————— —— — ac.ttrtin — —————— ';Q 1 2 3 4 5 i, T 3 9 10 1 i 12 13 1 4- 1 5 la ^ i. 7 ^13 19 50 21 22 23 54 25 26 27 23 29 30 31 32 '~>3 I<4 3*. 3fc ' j " ^S 39 40 4 1 ^2 ' 4 '3 44 **. LIB VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI ENTRY 1 2 3 4 5 6 7 8 9 10 1 1 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 3O 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 REF -184 -373 -518 -439 -38 -44 -39 -46 -72 -62 -115 -289 -341 -122 -65 -60 -91 -78 -127 -155 -135 -143 -242 -218 -274 -201 -341 -321 -153 -311 -344 -420 -325 -451 -293 -375 -384 -413 -391 -412 -112 -496 -501 -519 -561 PRED SEL DELTA PEAKS 183 183 . 1 372 372 1 517 438 438 1 3 7 . . . 43 3 8 . . . 4 5 . . . 71 71 1 61 114 288 340 121 6 4 . . . 5 9 . . . 9O . . 7 7 . . . 1 2 6 . . . 154 134 142 241 217 273 2OO 200 1 34O 32O 152 310 343 419 324 324 1 450 292 374 383 412 390 411 111 111 1 495 500 518 560 - — — — ,»•-.. 3H 1 ,><-. — —— - FIT PEAKS M/Z 978 . 114 973 . 117 150 947 . 95 50 94 62 64 963 . 84 43 43 43 43 128 76 96 63 96 83 62 97 117 83 63 75 949 . 95 129 97 78 75 107 173 955 . 166 83 91 112 91 104 106 106 8B6 . 96 146 146 146 75 —— ur TOP 182 372 517 438 71 61 127 200 324 111 •mu — — — — — — DELTA PEAKS -1 1 1 1 1 1 1 1 1 1 1 TUT 004 1610 LIBRARY SEARCH REPORT 0 1 7 PURGEABLE VOLATILE ORGANICS ANALYSIS :ATA FILE: W7327D -QUIRED: O3/18/93 11:24:OO ANALYST: RJL ^'DS. : I500A:25ML OLV01 AMBIENT PURGE W/ 5PP3 IS & SS •-.'EMITTED BY: ITEK ACCOUNT NO. 53554 COMPOUND SCAN DELTA (UG/ML) FIT SAT'D? 110 1, 4-DIFLUOROBENZENE (IS*1) 182 -1 5. OOO 978 0 120 C!l* OROBENZENE-D5 (ISK2) 372 0 5.000 973 0 26 1,4 DICHLOROBENZENE-D4 <IS#3) 517 0 5 000 0 0 £10 4-BROMOFLUOROBENZENE (SS) 438 0 4.940 947 0 30 METHYLENE CHLORIDE 71 0 1 794 963 0 •35 ACETONE 61 0 2. 327 0 0 50 TRICHLOROETHENE 2OO 0 2 181 949 0 20 TETRACHLOROETHENE 324 0 19. 014 955 0 54 CIS-1,2-DICHLOROETHENE 111 0 2 294 886 0 TUT O04 1611 T9T mi TARGET COMPOUND COMPARISON COMPOUND: C030 METHYLENE CHLORIDE 87.4- 43.7-: 77.4- 38.7-: 100.0- 50.0: vz 1 00.0-: 50.0-i 0.0-: 50.0-: 180.0~ RAW DATA: UU7327D #71 BASE M/Z: 44 RIC: 83/18/93 11:24 SAMPLE: CLP.53554, NH81 , MW04DL, LOW, WATER, UV7327, UOA, EPA, CONDS.: I500A:25ML OLU91 AMBIENT PURGE W/ 5PPB IS 8< SS ' i • • • 1 i i i i [ . . . . I I ENHANCED DATA . l . . . . . , . . . . ! . . . . LIBRARY FILE: 'r i 1-1 | i • i i | 30 1 : UU7327D #71 r-™ Ul #9 r—— * —— t —— *——, r-,-^U- 40 t i ' ' • • 1 . r 58 1 1 1 1 1 1 1 1 [ 1 1 1 1 1 1 1 1 1 1 •-» 1 1 ' 1 » 1 1 1 1 »' 1 BASE M/Z: 49 RIC: . , , , . . , . , , , , , , . , . . I . . , . , - . . . . I ... BASE M/Z: 49 RIC: 60 70 80 ' - -3 CD 3776. 2372. i , , , , , , , 3928. -r t 1 1 1 T 1 1 30 • . • • CD Oo — > r 874. - 774. r 1000. | - — £T9T trOO ifll TARGET COMPOUND COMPARISON COMPOUND: C635 ACETONE RAW DATA: UU7327D #61 BASE M/Z: 03/13/93 11:24 SAMPLE: CLP.53554,MW01,MW04DL,LOW,WATER,W7327,UOA,EPA, CONDS.: I500A:25f1L OLU81 AMBIENT PURGE W/ 5PPB IS & SS 44 RIC: 100.01 58.0-: i • i • i • i • | • i • i • i • i • i • i • i • i • i • [ • i • i • i • i • i • i • i • i • i • | • i • i • i • i • i • I • i • i • i • | • i • i • I' ENHANCED DATA: MU7327D #61 BASE M/Z: 43 3.7- 1.8-: 96.3- 48.2-: M/Z 100.0- 50.0- 0.0- -50.0- 100.0- RIC: LIBRARY FILE: Ml #10 r 1iT' i • | • i • T • \r I T • i • i • i • i • | • i • i • i • i 10 28 BASE M/Z: 43 RIC I • I • l • i • i • i • i • i • i' i • i • I • | • l 30 46 50 1368. 59. 2136. CO —4 Oo cr> 1038. 38. 1000. 60 - **oum 1/T9T mi TARGET COMPOUND COMPARISON COMPOUND: C156 TRICHLOROETHENE i -5 62.7: 31.3: 60.4: 30.2: 100.0: 50.0: M/Z 100.0: 50.0: 0.0: -50.0: 100.0^ RAW DATA: UU7327D #200 BASE M/Z: 95 RIC: 4576. 03/18/93 11:24 SAMPLE: CLP_53554, MW01 , MW04DL, LOW, WATER, W7327, UOA, EPA, CONDS.: I500A:25ML OLU91 AMBIENT PURGE W/ 5PPB IS 8< SS I I In 1 i i . . . . . . . . . . | . . . . . , , , , . . . f . . , . , . ENHANCED DATA: UU7327D #206 Bi LIBRARY 40 —————hir I,. I FILE: Ml #26 i i 50 60 III. i I • • - . • • • • | ' • . • , . 1 B> I + • i ................. }SE M/Z: 95 RIC: 4164. 1 + , y , , . , , , , , , , . , . . «E M/Z: 95 RIC: 53: i i 56 J . 1 ' • ' • ' • ' I ' • • • ' • • • | • • . . , . . . . | • • • • 80 100 120 1 1 . 1 1 1 1 ' ' ' 1 1 ' 1 ' ' • 1 ' 140 ( _-> -J 627. •r 664. r 1000. - 7 **OUTt.* QT9T frOO ini TARGET COMPOUND COMPARISON co — i COMPOUND: C220 TETRACHLOROETHENE g Q RAW DATA: W7327D #324 BASE M/Z: 166 RIC: 85126. , 03/18/93 11:24 SAMPLE : CLP.53554 , MW0 1 , MW04DL , LOW , WATER , W7327 , UOA , ERA , CONDS.: I500A:25ML OLU01 AMBIENT PURGE W/ 5PPB IS & SS 100.0- 50.0-; - 1 1. 1 1 |J II, ..i - 11504. - • i i • | • i • i • i • i • j • i • i • i • i • | • i - i • i • i • | • i • i • i • i • | • i • i • i • i • j ENHANCED DATA: UU7327D #324 BASE M/Z: 166 RIC: 74112. 75.8- 37.9-: - .1 .1 1 Id. J - i - 7 S729. - - , . , . , . , . , . , . , . 1 . , . , . , . , . , . , . , . , . , . j . , . , . , . , . , . , . , - , . , . 1 LIBRARY FILE: Ml #33 BASE M/Z: 166 RIC: 5560. 8.7i 4.3: . , . ,. il i r 1000. - i i l i i i i | i i i i | i i i i | i i i i | i i i i | M/Z 50 180 150 200 250 360 100.0- 50. 0-: 0.0- -50.0- 100. 0-- 1 .1. . . L .1... . . 1.1 .. .11, . . u.i, . ........ .. . . . . . . . . . . . ...... — - r t*oum - - 3 D 9T9T 1700 mi TARGET COMPOUND COMPARISON COMPOUND: C054 CIS-1,2-DICHLQROETHENE RAW DATA: W7327D #111 BASE M/Z: 03/18/93 11:24 SAMPLE: CLP.53554, MW01,MW04DL,LOW,WATER,UU7327,UOA, EPA, CONDS.: I500A:25ML OLUQ1 AMBIENT PURGE W/ 5PPB IS & 55 61 RIC: 3824. 95.6- 47.8-i 88.6- 44.3- 00.0- 50.0-: -2 00.0- 50. 0T 0.0-: 50.0- l:10 . 0— i i . . ENHANCED DATA: i i . , LIBRARY FILE: 30 ———————— I . • I I . . . . . . . . . . . UU7327D #111 i i . Ul #41 40 . . - i BASE M/Z: 61 RIC: 3188. 4 - . , , . . . , . . . . , . . . . | . . . . , • • • • | ••• M . | . . , . , BASE M/Z: 61 RIC: 3240. i . . 50 60 70 80 90 100 • I. , i . . i , , . , . 956. 1000. c_O •,—io t- **oum ;TA FILE. VV7327D LTER SCAN PARAMETERS 0181 METHOD LIBRARY ?< LISTS X NUMDER TICS -TABLE ENTRIES AN TOLERANCE r. ;. RIC HT. C%3 PST SCAN ST SCAN .: THRESHOLD 10 495 3 10 35 1000 500 TIC I. S. LIBRARY: NBS SEARCH PROC : PEAK FINDER PROC: TCA I. S. LL : FILE NAME LIST : LIBRARYIS SERLIB VOME5 IS TCAREF2 •-GET COMPOUND ANALYSIS: TARGETS (QUAN LIST) 7 :;_TER PROCESSING: IS PEAKS 3 TOTAL TARGET PEAKS 10 OTAL EAKS 17 •: IST SCAN 1 :-• LAST SCAN 0 ,- R I REJECT PEAKS- MIN < SCAN C HT TOL 7 9 > MAX # PEAKS 0 TOTAL REJECTS 17 TOTAL TICS 0 .5 TIC 'S FOUND. TUT OO4 1617 L 0 0 C .1. o 1 o IX ORGANICS ANALYSIS DATA SHEET ,ab Name: ITAS-KNOXVILLE_________ Contract: -^" Lab Code: ITSTU Case No.: 53554 SAS No.: Matrix: (soil/water) WATER Sample wt/vol: 5.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ Heated Purge: N GC Column: DB-624___ ID: 0.53(mm) Soil Extract Volume: _______(uL) 0182 SAMPLE NO. MW04DL2 SDG No.: MW01 Lab Sample ID: W7327 Lab File ID: W7327D2 Date Received: 03/08/93 Date Analyzed: 03/18/93 Dilution Factor: ____2 .0 Soil Aliquot Volume: ___ CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L FORM I X-l .(uL) 74-87-3 ————— / *t O O 17 75-01-4 ————— 75-00-3 ————— 75-09-2 ————— 67-64-1 ————— 74-97-5 ————— 75-15-0 ————— 75-35-4 ————— 75-34-3 ————— 540-59-0 ———— 540-59-0 ———— 67-66-3 ————— 107-06-2 ———— "7 Q QT 1 _ _ _ _ _ _ 71-55-6 ————— 56-23-5 ————— 75-27-4 ————— / O O / D 10061-01-5 —— 79-01-6 ————— 124-48-1 ———— 79-00-5 ————— 71-43-2 ————— 10061-02-6 —— 106-93-4 ———— 75-25-2 ————— 108-10-1 ———— 127-18-4 ———— 79-34-5 ————— —— Chloromethane —— Bromomethane —— Vinyl Chloride —— Chloroethane —— Methylene Chloride £il«>t£ L.WI1C —— Bromochloromethane —— Carbon Disulfide —— 1, 1-Dichloroethene —— 1, 1-Dichloroethane —— 1, 2-Dichloroethene (total) —— cis-1 , 2-Dichloroethene —— Chloroform —— 1 , 2-Dichloroethane —— 2-Butanone —— 1 , 1 , 1-Trichloroethane —— Carbon Tetrachloride —— Bromodichloromethane —— 1 , 2-Dichloropropane —— cis-1 , 3-Dichloropropene X ^ X wllX U J. LJC L>11C7_1C2 —— Dibromochlorome thane —— 1 , 1 , 2-Trichloroethane —oenzene —— trans-1, 3-Dichloropropene —— 1 , 2-Dibromoethane —— Bromoform —— 4-Methyl-2-Pentanone —— 2-Hexanone xet.icit*rij.L>zriJc uiit?iic —— 1 , 1,2, 2-Tetrachloroethane —— Toluene —— Chlorobenzene 2 2 2 2 3 10 2 2 2 2 2 28 2 2 10 2 2 2 2 2 22 2 2 2 2 2 2 10 10 180 2 2 2 Uu Uu B U U U U U U D U Uuuuuu u D Uuu u uu uu DE U uu CD L0001613 3/90 IX ORGANICS ANALYSIS DATA SHEET ~ab Name: ITAS-KNOXVILLE_________ Contract: "Lab Code: ITSTU Case No.: 53554 SAS No.: Matrix: (soil/water) WATER Sample wt/vol: 5.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ Heated Purge: N GC Column: DB-624___ ID: 0.53(mm) Soil Extract Volume: ______(uL) SAMPLE NO. MW04DL2 SDG No.: MW01 Lab Sample ID: W7327 Lab File ID: W7327D2 Date Received: 03/08/93 Date Analyzed: 03/18/93 Dilution Factor: ____2.0 Soil Aliquot Volume: ___ CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L .(uL) 100-41-4 ——— • 100-42-5 ——— - 1330-20-7 —— • 541-73-1 ——— • 106-46-7 ——— - y Q 3 \j J. y o ±.£, o —— Ethylbenzene —— Styrene —— Xylene (total) —— 1, 3-Dichlorobenzene —— 1,4-Dichlorobenzene —— 1, 2 -Dichlorobenzene —— l,2-Dibromo-3-Chloropropane _ 2 U 2 U 2 U 2 U 2 U 2 U 2 U TUT 004 1619 FORM I X-2 ^0001 Gi-0 3/90 IX ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS SAMPLE NO. Lab Name: ITAS-KNOXVILLE_________ -Lab Code: ITSTU Case No.: 53554 Matrix: (soil/water) WATER Sample wt/vol: 25.0 (g/mL) MI Level: (low/med) LOW % Moisture: not dec. ___ GC Column: DB-624___ ID: 0.53(mm) Soil Extract Volume: ______(uL) Contract: SAS No.: MW04D2 SDG No.: MW01 Lab Sample ID: W7327 Lab File ID: W7327D2 Date Received: 03/08/93 Date Analyzed: 03/18/93 Dilution Factor: ____2.0 Soil Aliquot Volume: ____.(uL) Number TICs found: CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L . CAS NUMBER COMPOUND NAME RT EST . CONC . Q TUT 004 1620 FORM I X-TIC 000162 A 3/90 i» en en en •• o •• o <S) cs> *. ® CD <S> 0185 hO CS 1 1 1 . , J o 1— • NJ •Tl — • *• 1O 1— « (-> o s m mio i—* 1 |^ it '"-"" . V o to5 -e- CO 1 1^5 "Tl r~ o ftj m m Cn LO 1 , 1 . 1 . 1 . o o o X o o CO ms m fn CO t-O \j <J -y——— ^ o t—t >s> ^* 1 1— 1 -n o ?— i CO m m m H-l U1 ^^ 0 iv I> i i"i r~ • m -n •• •• T^o •— O 3 (J\ r~ o -o -n ~ •• co m •_n en _ o S co r~ o ho •~ •— -j o - o — 3 NO ^ - 3 -U CO O •— < ho m ^ 3 I— LO — 1 O O 2F I CT" — ( O m m x- *— 21 -_ •-< en «^ — i en ~^J <_ o T? CO C "O to -J CO -si 00 -si m o ID I> hO m * o — ui -o co o H^ 1^1 T^' '— CB OJ TUT OO4 1621 000162: 0186 Ci.-antitation Report File: W7327D2 .~ata: VV/327D2. TI :j/18/93 11: 56: 00 ^».T>p le: CLP, 53554, MW01.- MW04D2.- LOW, WATER, VV7327, VQA, EPA.. inds. I5OOA:25ML OLV01 AMBIENT PURGE W/ 5PPB IS &-. SS -ormula: 25rtL->50ML: l->2 DILInstrument: I50OA Weight: 0.000 !r .-emitted by: ITEK Analyst: RJL Acct. No. : 53554 V.OUNT=AREA * REF AMNT/CREF AREA * RESF FACT) --•;p. -fac. from Library Entry -Jc- NaT:«? ^ CI1O 1,4-DIFLUOROBENZENE (IS#1) 2 CI20 CHLOROBENZENE-D5 (IS#2) 2 CI26 1, 4-DICHLOROBENZENE-D4 (IS4»3) •'* CS1O 4-BROMaFLUORCBENZEN'E ( SS ) 5 C010 CHLOROMETHANE •»•» i C015 3ROMOMETHANE .' C020 VINYL CHLORIDE * i C025 CHLOROETHANE •= CO30 METHYLENE CHLORIDE \0 C035 ACETONE '.I C110 2-3UTANONE 12 C205 4-METHYL-2-PENTANONE ::2 C210 2-HEXANONE -4 C037 BRCMOCHLDROMETHANE 15 C040 CARBON D1SULFIDE :6 C045 1,1-DICHLOROETHENE * 17 C050 1,1-DICHLOROETHANE »* :"• C053 TRANS-1, 2-DICHLORCETHENE , i-r COoO CHLOROFORM * -I-;- C065 1, 2-DICHLOROETHANE 51 C115 1.. 1, 1-TR I CHLOROETHANE '.;•% C120 CARBON TETRACHLORIDE !-.3 C130 BRCMODI CHLOROMETHANE 14 C140 1,2-DICHLOROPROPANE * -.= C143 CIS-1, 3-DICHLOROPROPENE .-:c C15O TRICHLOROETHENE .-1~ C155 DIBROMOCHLOROMETHANE .-13 C160 li 1, 2-TR I CHLOROETHANE 5? C165 BENZENE 30 CI72 TRANS-1, 3-DICHLOROPROPENE Di C176 1,2-DIBROMOETHANE 32 C180 BROMOFORM ** 33 C220 TETRACHLOROETHENE U-A C225 1, 1, 2, 2-TETRACHLOROETHANE *•«• :-r C230 TOLUENE * 1-6 C235 CHLOROBENZENE 3" C240 ETHYL BENZENE * 33 C245 STYRENE 21? C250 M/P XYLENE -•50 C252 0-XYLENE -1 C054 CIS-1.- 2-DICHLOROETHENE i2 C253 1,3-DICHLORODENZENE -3 C254 1,4-DICHLOROBENZENE ^4 C255 1, 2-DICHLORODENZENE TUT °04 -1622 '-••.- C261 1, 2-DIBROMO-3-CHLOROPROPANE L000162J 0187 "10 f m/ 1 114 Scan 183 2 117 373 2 150 518 1 ~; O *T J3 •? LO 1 1 1 1. i 3 ;4 ; 5 1 6 t 7 * ~ ' '.*? i 0 2"; «j ^ T' ~\ Z'4 7C. I* <• •^ .* £S ?o — . ,^ •^ "rf* •? - rf*i v •*• M ** 3* 36 "% "7 z-s 3-- 40 -1 k* — i ~1 - 4 ^ K I .'. 1 •1 ji -^ C i. * T j~ ~ 95 NOT NOT 62 NOT 34 NOT NOT NOT NOT NOT 76 NOT NOT ^6 S3 NOT NOT NOT NOT NOT NOT 9 5 NOT NOT / *I> NOT NOT NOT 166 NOT NOT NOT NOT NOT NUT NOT ^z NOT NOT NOT NOT Ret 6: 12: 17- 14 1 : 1 . T I • ^ 439 FOUND FOUND 41 FOUND 72 FOUND FOUND FOUND FOUND FOUND 65 FOUND FOUND 79 127 FOUND FOUND FOUND FOUND FOUND FOUND 201 FOUND FOUND 153 FOUND FOUND FOUND 325 FOUND FOUND FOUND FOUND FOUND FOUND FOUND 112 FOUND FOUND FOUND FOUND < L > R a t i OS 0. 99 26 1 . 00 16 1. OO 38 1 00 18 28 20 1. 02 32 24 1. 00 Time 6: 06 12: 26 17: 16 14: 38 1: 22 2: 24 2: 10 2: 3S 4 14 6: 42 5 C6 10: 50 3: 44 o RRTCL 1. 000 1. 000 1 000 2. 386 0. 212 0. 23? 0. 217 0 250 0. 391 Ref RRT 1 1 000 2 1.000 3 1 . 000 1 2. 399 1 0. 224 1 0. 393 1 0 355 1 0 432 1 0 694 2 0 539 2 0. 410 2 0. 871 1 0 612 ) Ratio 1. 00 1. 00 1. 00 1. 01 1. 03 1 01 Meth A DB A BB A BB A EB A DD A DD A DB A DD A BB A BB A BE A BE A DD AT.r, t 5. 00 5. 00 5. 00 4. 97 0 23 1 56 Area(Hgh 11063. 8536. 5157. 6724. 431 13O9. 164. 194. 437 18301 297. 178212. 12273. Amn t ( L) 5 00 5. 00 5 00 5 00 5 00 5. 00 t) Amount 5. 5. 5 4. 0. 1 0. 0. 0. 10. 0 88. 13. R. Fac 1. OOO 1 . OOO 1. 000 0. 608 0. 039 0 118 000 000 000 974 284 560 043 175 195 756 103 502 755 UG/L UG/L UG/L UG/L UG./L UG/L UG/L UG./L UG/L UC/L UG/L UG/L UG/L R. Fac (L) 1 1 1 0 0 0 000 . 000 . 000 . 611 685 . 379 V.Tot 3. 3. 3. .~\o 0 1 0. 0 0. 7. 0 65 10. Rati 1. 1. 1. 0. 0. 0. 70 70 70 6S 21 15 04 13 14 95 08 44 1- o 00 00 00 9? 06 31 Kl M -JD h-ni- L 000162^ 0188 •<o Ret(L) 10 r i i * 12 1 3 1 4 ; =. t .i, I — ". -. \ 9 JJG 21 2J- 53 J'4 25 r i 25 ,—, I" 4 '!*• 36 •^-? ^!= 39 iO 4 ; -t ^f , 2, 44 4:;' 2: 3: 9: 11: 4: 2. 2; 3 ; c. 4. 5 4 4 3: -T . 9 6. 11 10 =, 10: 11: 13: ic- 1 5 9 12: 12: 13. 13: 13: 3 ' 16: 16. 17. 18 04 50 38 22 04 10 00 02 36 14 10 30 46 02 14 06 42 22 40 06 22 28 58 5O 02 44 28 46 46 02 42 44 30 42 18 40 Ratio RR~ni_> Ratio Amnt Amnt(L) R. Fac R.Fac(L) Ratio 0. 0. 0. 0. 0. 1.00 0. 0. 0. 1. 01 0. 1. 00 0 0. 0. 0. 0 0. 0 1 00 0 0 0. 1 00 0. 0. 0. 0. 1 OO 0. 1 0 1. 1. 1. 1. 1. 1 00 0. 0. 0. 1. 1 337 625 775 914 663 353 1.01 0.05 326 495 424 1. 02 0 IS 690 1.01 0. 19 842 362 383 646 582 732 539 1 00 10 76 914 858 410 1. 00 010 334 922 809 371 1. OO 88. 50 209 783 003 027 107 048 102 609 1 01 13 76 956 967 002 081 5. 00 0. 015 1. 558 0. 01 5 00 0. 018 0. 501 0. 04 5. 00 0. 040 1 015 0 04 5, 00 2. 144 0. 997 2. 15 5 00 0. 035 1 685 0. 02 5. 00 20. 878 1. 180 17. 70 5 00 1. 109 0. 403 2. 75 TUT O04 1624 L O Q O i 6 2 o 3/18/93 11: 56: 44 Acquisition started 0189 3/18/93 11:56:48 :quire Run 0:VV7327D2 Starting 2/18/93 11:56:00 + 0:00 Free sectors: 11860 Scan: 0 of 720 a.J.ple: CLP, 53554, MW01, MW04D2, LOW, WATER, W7327, VOA, EPA, ;nds. : I5OOA.25ML 01 VO1 AMBIENT PURGE W/ 5PPB IS & SS ?rmula 25ML->50ML: l->2 DILInstrument: 1500A Weight: 0. OOO r.'i-mitted by: ITEK Analyst: RJL Acct. No: 53554 :1. De 1 ve sc : RR 1 *3 i"Tl D <D*gC ) 35 35 35-150 50-150 A : cl Rate (C/min S 0 osed *** GC not ready and being stabilized **« Elapsed time : 0. 0 Min Time (minutes) period 6. 6 14. 3 3. 0 Valve 3 total 6. 6 20. 9 23. 9 open Injector A : GC oven : Transfer-1ine: Ion source : 150 Deg C 36 Deg C 216 Deg C 181 Deg C **•*• Instrument parameters *** Post acquisition state -> Filament : Off Multiplier : Off ~-E: ET (•*•) Centroid + Temp - Sequence: BF ( 2 time windows. ) £ ••:; u e n c e Windour en d e s c r i p t o r : ••tal scan t i m e : Number of cycles. 28 Filament is OFF Multiplier is ON BF Mass intervals: 2. OOO s Positive ion mode. Master rate: 16 •-W: 3 MFW: 80 MA: 15 TH: 1 BL: 0 Tnt * L o m a s s Hi mass Time 1 33. 510 300. 590 2. 000 • •» q u e n c e Window tt 2 Number of cycles: 1 Filament i 9 ON M u l t i p l i e r is ON :,sn descriptor: BF Mass intervals: 1 :tal scan time: 2. OOO s Positive ion mode. Master rate: 16 i: 3 MFW: 80 MA: 15 TH: 1 BL: t # Lo mass Hi mass Time 1 33. 510 300. 590 2. 000 Calibration table: Interface number Instrument type Full scale mass Zero scale mass Intensity/ion Pea« width Offset at low mass Offset at h i g h mass 0 Voltage settling time(ms) 20 D: CAL02199; 0 Q 1177 u 1 u 2 1000. mmu O mmu mmo TUT OO4 1625 L000162G >! jrrent instrument parameters. Positive ion Resolution {high) Reso lution (low) Quad offset Quad programming Lens offset Lens programming Ext offset Ext programming Col 1ec tor Ion offset Ion programming Rod polarity 128. 128. 0. 0. -50. 0. O. 0. 30. 7. 5. OO 00 00 00 00 00 oo 00 00 00 00 mode Negative ion mode 128. 00 128. 00 O. 00 0. 50. O. 0. 0. 30. -3. 0190 oo 00 00 00 00 00 00 -5. Reverse Electron m u l t i p l i e r voltage Filament emission current Electrometer range Electrometer zero 00 Norma1 984. 750. 10 --7 126. 0 •slyzeT Fore Pressure ... •>• arat or/Sourc e Pressure 0. 010 Torr 0. 356 Torr /18/93 12:24:58 ACQUISITION COMPLETED Scans 1 to 720 Centroid ~ - t r o i d Scans 720 Sec s 0. 5 Out of 144O. 0 0 0 Pea ks per 6915. scan 10 per sec 5. TUT OO4 1626 L000162V OUNTHOL/QUALITY ASSURANCE DATA 0191 METHOD: CLP 3'90 OLV01 25ML PURGE DATAFILE: VV7327D2 STANDARD: WS0318 TUNEFILE: W3FB0318 ANALYSIS ANALYSIS AfMALYSIS TIME: 03/18/93 11: TIME: 03/18/93 8: TIME: 03/18/93 8: 56 29 20 **#*** INTERNAL STANDARD AREA CHECK ****** INTERNAL STANDARD 10 1,A-DIFLUORODENZEN 20 CHi ORODENZENE-D5 ( .lib 1, 4-DICHLOROBENZEN DATA AREA 1 1063. 8536. 5157. STD AREA 11210. 7723. 5477. RATIO 997. 1 1 1 7. 947. CLP ACCEPT RATIO 607. - 1407. 607. - 1407. 607. - 1407. STATUS ****** INTERNAL STANDARD RT CHECK ****** INTt-RNAL STANDARD .10 1,4-DIFLUORODENZEN 120 CHLOROBENZENE-D5 ( 126 1,4-DICHLOROBENZEN DATA SCAN 183 373 518 STD SCAN 184 373 518 DIFF CIN SEC 3 2 0 0 CLP ACCEPT DIFF STATUS +/- 20 SECS +/- 20 SECS +/- 20 SECS **#*** SURROGATE RECOVERIES ****** SURROGATE ANT FOUND AMT ADDED ilO 4-3SOMOFLUOROBENZE 5. O 5. O 15 BROi-fOMETHANE -0.0 50. O '.20 VINYL CHLORIDE * 0.3 50. O PERCENT RECOVERY RECOV LIMITS STATUS 99 0 1 8O7. - 1207. 887. - 1107. 867. - 1157. failed failed TUT OO4 1627 L0001620 jAlA FILE: REFERENCE: •.AWE LIST: REPORT: W7327De! Vlll VI INITIALIZATION OPTION: 2 V1IS 0192 PROCESSING OPTION: 3 —— STANDARDS ———— X —— PLUS UNKNOWNS —— >< - LIST NAMES - -~OC USED POSS 3 3 3 2 3 3 45 COMPOUNDS : COMPOUND >< i.—i ^ si ;? *'*• e. o T / W 9 I 0 1 1 1 '2 ** 'T 14 19 ". 6 « » 15 * "j -i ,1 i 1 it ~* ? ^ ^ '-" B. ;.'.^. _.~7 rs V Q 30 -, 1 _ A — -i •-• C. ~*3 j4 7 ^ JC jT :•£ 30 » -\ T V 41 ' -*^ "*••£. ;3 44 4? LID VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI Vi VI VI VI VI VI ENTRY 1 2 3 4 5 6 7 8 o 10 11 12 13 14 15 16 17 18 19 2O 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 1 1 1 RMS PROC USED POSS 0 2 0 6 1 11 16 5 1 11 15 4 1 RMS STANDARD /UNKNOWN 115 V1IS/V1UNKS1 41 V1IS/V1UNKS2 67 V1IS/V1UNKS3 PROCESSED, 8 FOUND REF -134 -373 -518 -439 -38 -44 -39 -46 -72 -62 -115 -289 -341 -122 -65 -60 -91 -78 -127 -155 -135 -143 -242 -218 -274 -2O1 -341 -321 -153 -311 -344 -420 -325 -451 -293 -375 -384 -413 -391 -412 -112 -496 -501 -519 -561 _ OfTAD/^LJ _ ~ otftrCun — — PRED SEL DELTA PEAKS 183 1 S3 . 1 373 373 . 1 519 439 439 . 1 3 8 . . . 4 4 . . . 39 41 2 1 4 6 . . . 72 72 1 6 2 . . . 115 289 341 122 65 6 0 . . . 91 7 8 . . . 127 155 134 142 242 218 274 20O 2O1 1 1 3 4 1 . . 321 152 311 344 420 325 325 . 1 452 293 375 384 413 391 412 111 112 1 1 497 502 520 562 ——— >< SAT X ——— FIT PEAKS M/Z 9BO . 114 972 . 117 150 947 . 95 50 94 701 . 62 64 95O . 84 43 43 43 43 128 76 96 63 96 83 62 97 117 83 63 75 965 . 95 129 97 78 75 107 173 953 . 166 83 91 112 91 104 1O6 106 912 . 96 146 146 146 75 — ruion — - TOP DELTA 183 373 518 439 41 72 65 79 127 201 153 325 112 PEAKS 1 1 1 1 1 1 1 1 1 1 1 1 1 L 000162^ TUT O04 1628 IT. ANALYTICAL SERVICES LIBRARY SEARCH REPORT PURSEABLE VOLATILE ORGANICS ANALYSIS 0193 ~7A FILE: VV7327D2 : QUIRED: O3/18/93 11:56:00 DNDS. : I500A:25ML QLV01 AMBIENT PURGE W/ 5PPB IS : ADMITTED BY: ITEK SS COMPOUND "10 1.. 4-DIFLUOROBENZENE <IS#1> "20 CHLDROBENZENE-D5 (IS#2> iJ-6 1, 4-DICHLOROBENZENE-D4 (ISK3) '-10 4-DROMOFLUOROBENZENE (SS) 'C'O METHYLENE CHLORIDE '50 TRICHLOROETHENE 120 TETRACHLOROETHENE :^4 CIS-1,2-DICHLOROETHENE ANALYST: RJL ACCOUNT NO. 53554 SCAN DELTA (UG/ML) FIT SAT'D? 0 0 0 0 0 0 0 0 133 373 518 439 72 201 325 112 0 0 -1 0 0 1 0 1 5. 5. 5. 4. 1. 10. SB. 13. 000 000 000 974 560 756 502 755 9BO 972 0 947 950 965 953 912 TUT O04 1629 L 0 0 0 1 6 3 G CD O 00.0-1 50.8- 19.4- 9.7-: TARGET COMPOUND COMPARISON COMPOUND: C030 METHYLENE CHLORIDE RAW DATA: UU7327D2 *72 BASE M/Z: 03/18/93 11:56 SAMPLE: CLP,53554,MW81,MW04D2,LON,MATER,W7327,UOA,EPA, CONDS.: I500A:25ML OLV01 AMBIENT PURGE W/ 5PPB IS & SS 44 RIC: -r-4- ENHAHCEO DATA: W7327D2 «72 T • ^ • I . . . . . . I . • | i ... i . I I LIBRARY FILE: ','1 «9 BASE M/Z: 49 RIC: BASE M/Z: 49 RIC: 6528. 3928. 00 0 0 3724. '-' O H- •3I- ^b.a- 13.4-: ; Z •30.8- 50.0^ 0.0^ 30.0^ 90.8- i . i . |-i , r i r 1 1 t , | 1 t , ,-(- r" -r— -r- i i i |* i i i- F [ r T • i ;• . • i . | i • i • | . i I'T j . T • f -f- -t-t i [ , •• • . [ 30 40 50 60 70 80 90 . . . . . . 1 . 1 . . . . . . . 1000. 2 TARGET COMPOUND COMPARISON o COMPOUND: 3150 TR I CHLOROETHEHE 100.0^ 50. 0: 95.2: 47.6: 27.5: 13.8: M/Z 100.0: 50.0: 0.0: -50. 0J toft ct- CO 1 — > RAW DATA: UM7327D2 #201 BASE M/Z: 95 RIC: 23712. 03/18/93 11:56 SAMPLE : CLP , 53554 , MW0 1 , MW04D2 , LOW , WATER , UU7327 , UOA , EPA , CONDS.: I500A:25ML OLU91 AMBIENT PURGE W/ 5PPB IS &. SS I ' l l 1 Mi 1 , . . . . 1 . | . 1 . 1 | . . . . ENHANCED DATA: UU7327D2 , i . | II. 1 LIBRARY FILE: Ul #26 1 . i 40 56 68 ,,.. , ii, . 1 • • • . , . . . . , . - t . . , . M #201 Bh 1 . - . . , . . . . | I - . . . . . 1 E^ I - • • . • • • • , • • • • . • ' • . i ^SE M/Z: 95 RIC: 22144. .1 4 - . , . , . . , , , , , f , , , , )SE M/Z: 95 RIC: 53: i 88 i 36 J . ( , . . . , . . . . , . . . . 100 120 i i . . . i . i . i . , . i . • — f— 1 — [— 1 « • 1 * 140 ' i CD -J 3636. - 3466. ~ 1000. 1 **oum h- CD Z£9T trOO IfU TARGET COMPOUND COMPARISON COMPOUND: C220 TETRACHLOROETHENE RAW DATA: UU7327D2 #325 03/18/93 11:56 SAMPLE : CLP , 53554 , MW0 1 , MW04D2 , LOW , NATER , UU7327 , UOA , EPA , CONDS.r I500A:25ML OLU81 AMBIENT PURGE W/ 5PPB IS & SS BASE M/Z: 166 RIC: 448512. '""5 S 100.07 50.07 90.37 45.1- 1.7- 0.97 M/Z 100.07 50.07 0.07 -50.07 inn n- i | , .1 , , . , . , . , . , . , - ! . , . , . , ENHANCED DATA: W7327D2 #325 i 1 1 i • I • ,i , , , ,1.1, , LIBRARY FILE: Ml -T-l —— 1 , i • I • 50 , 1 , „ 1 i • i • i • i .1.... ... I.,.. ..1 11 i • | • i ' .1. 1 . , - , . , . , . , . i ... I • i • i - • - ,-, BASE M/Z: 166 RIC: 467552. .1 • | • i • i * 1 • i--* | • i • i • i • i • | • i • i • i • i • | • i • i • i • i • | #33 1. I BASE M/Z: 166 RIC: 5560. . i | • i • i • i • i • 1 • i • i • i • i • | • i • i • i • i • 1 • i • i • i • i • | 100 150 200 250 300 l.i. . . . . ..1.1.1... i ii i i n n 1 1 i i 7 57856. ~ 52224. 1000. ~ **oum i!£9T frOO mi TARGET COMPOUND COMPARISON COMPOUND: C854 CIS-1,2-DICHLOROETHENE RAW DATA: W7327D2 #112 03/18/93 11:56 SAMPLE: CLP, 53554, MW01J1W04D2, LOW .-WATER, CONDS.: I580A:25ML QLU01 AMBIENT PURGE W/ 5PPB IS BASE (1/Z: EPA, SS 61 RIC: 20968. CO CO •.—I CD 180.0: 50.0: 93.4: 46.7: 17.2-q 8.6: 1/Z 100.0: 50.8: 0.0: 50.0- ee.e- . i . EHHANCED DATA: LIBRARY FILE: , , , , , , , , , 38 i 1 ' • • 1 • • 40 1 ' ' I W7327D, I i , I l i Ul #41 • i • ' ' i e 1 . . . 1 #112 • • • • i • ' ' i BASE M/Z: 61 RIC: 18144. BASE M/Z: 61 RIC: 3248. 50 ee 70 80 90 100 . . . . , . , . , . . 5808. 5424. 1000. - **QUT*« si a: VV7327D2. TI 01 3/18/93 11: 56: 00 ^•nple: CLP, 53554, MW01, MW04D2, LOW, WATER, VV7327, VOA, EPA, :-ds. : I5OOA:25ML OLV01 AMBIENT PURGE W/ 5PPB IS & SS •;^mula: 25ML->50ML: l->2 DILInstrument: I500A Weight: 0.000 ..emitted by: ITEK Analyst: RJL Acct. No.: 53554 .-CUNT=HEIGHT * REF AMNT/(REF HEIGHT * RESP FACT) '-:••;p. fac. from Library Entry ••;.- CAS # Name 0-00-0 CI01 BROMOCHLOROnETHANE (I.S.#1) 2 0-00-0 CI10 1, 4-DIFLUOROBENZENE (I.S. 3 0-00-0 CI20 CHLOROBENZENE-D5 (I.S.#3) * 124-38-9 CARBON DIOXIDE X. "5 124-38-9 CARBON DIOXIDE ? '-••: m.-'i Scan Time Ref RRT Meth Area(Hght) Amount V.Tot ! RIC 184 6:08 1 1.000 A BD 7317.* 50.000 UG/L 29.69 5 RIC 373 12:26 2 1 000 A BB 13366.* 50.000 UG/L 29.69 3 RIC 519 17:19 3 1.000 A BB 11312.* 50.000 L'G/L 29.69 -i RIC 135 4:30 1 0.734 A W 552.* 3.772 2.24 5 RIC 137 4:34 1 0.745 A VD 2140.* 14.623 8.68 TUT O04 1634 L000l63u U i -•4V A FILF: W7327D2 - : _ T E R SCAN PARAMETERS -•-X. NUMBER TICS: 10 .-TABLE ENTRIES: 495 -*. AN TOLERANCE : 3 "If;. RIC HT. C7.3: 10 -1"ST SCAN : 35 ..-^T SCAt-l : 1000 -:•:- THRESHOLD : 500 METHOD LIBRARY & LISTS TIC I. S. LIBRARY. NBS SEARCH PROC : PEAK FINDER PRDC: TCA I. S. LL : FILE NAME LIST : LIBRARYIS SERLIB VOME5 IS TCAREF2 COMPOUND ANALYSIS: TARGETS (QUAM LIST) 10 :_TER PROCESSING: IS PEAKS 3 <—————————REJECT PEAKS- rOTAL < 1ST > LAST < MIN -C SCAN -'EAKS SCAN SCAN R-IC HT TOL 15 1 0 3 10 PROCESSING. SCAN* PURITY FIT 137 949 996 TOTAL TARGET PEAKS 13 > MAX # TOTAL TOTAL PEAKS REJECTS TICS O 14 1 MW COMPOUND NAME [BEFORE TIC THRESHOLD] 44 CARBON DIOXIDE TUT 004 1635 L000i63o oo ™ . -Q o MID LIBRARY SEARCH (LIBRARYHB) DATA: W7327D2 tt 137 BASE fl/Z: 44 r- ro 03/18/93 11:56:00 + 4:34 CALI: UU7327D2 ft 3 RIC: 631. f? 5 SAMPLE : CLP , 53554 , MU8 1 , MW04D2 , LOW , WATER , UU7327 , UOA , EPA , ^ CONDS.: I500A:25HL OLU81 AMBIENT PURGE W/ 5PPB IS & SS o 5 ENHANCED <S 15B 2N 0T> o o 1034 n WLE .02 1034 i WT 44 PK 44 WK 1 32 IR 949 r CARBON DIOXIDE r 1 1 , 1 H —— , —— ,-p, ———— r^ ——— r^ —— . , . . . . , . . . . , ——— , —— , ————— , ———— . , . . . —— ,-4- CAS# 124-38-9 O — / KD 1- H6.02.N2 CARBAMIC ACID, MONOAMMONIUM SALT CASK 1111-78-0 1034 WT 78 PK 17 rtJK 9 nirv Z 362 IR 945 r . .1 . 1 H2 NITROGEN OXIDE (H20) CAS# 10024-97-2 1034 i WT 44 PK 44 iHK 3 37 IR 945 r 1 _i 1 V •••r-T ->—!—.--»— i, -|--.—i- i « T ^ . 1 — '"• r •^•v T'-^-t-^ • —— p^~ *• -• ' I * »— • — • — | — « —— »— i —— * • -T ' * '^ * —— • — | —— • —— • — ' " T T —— « —— ^~1 —— • — | —— • — • —— • — * T" ^~* —— • — ^'y '* — • —— • — » — 1 —— • — • —— •— • —— | —— • — * - - r— " • I'Z 20 38 40 50 60 79 88 90 IX ORGANICS ANALYSIS DATA SHEET -.ab Name: ITAS-KNOXVILLE_________ Contract: "Lab Code: ITSTU Case No.: 53554 SAS No.: Matrix: (soil/water) WATER Sample wt/vol: 5.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ Heated Purge: N GC Column: DB-624___ ID: 0.53 (mm) Soil Extract Volume: ______(uL) SAMPLE NO. TRIPBLANK SDG No.: MW01 Lab Sample ID: W7328 Lab File ID: W7328 Date Received: 03/08/93 Date Analyzed: 03/18/93 Dilution Factor: ____1.0 Soil Aliquot Volume: CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/ FORM I X-l .(uL) 74-87-3 —— —— 74-83-9 ————— 75-01-4 —— —— 75-00-3 —— —— 75-09-2 ————— 67-64-1 ————— 74-97-5 —— —— 75-15-0 —— —— 75-35-4 ————— 75-34-3 ————— 540-59-0 ----- 540-59-0 ———— 67-66-3 ————— 107-06-2 ———— "7 T C C C. rr /" *•> ••» (r 75-27-4 ————— "7 Q Q 1 C 10061-01-5 —— 79-01-6 —— —— 124-48-1 ———— 79-00-5 —— —— 71-43-2 ————— 10061-02-6 —— 106-93-4 ———— 75-25-2 ————— 108-10-1 —— — 591-78-6 ———— 127-18-4 ———— 79-34-5 ————— 1 OD — Q Q 1 ___— _ —— Chloromethane —— Bromome thane —— Vinyl Chloride —— Chloroethane —— Methylene Chloride —— Acetone —— Bromochloromethane —— Carbon Disulfide —— 1 , 1-Dichloroethene —— 1 , 1-Dichloroethane —— 1 , 2-Dichloroethene ( total ) —— cis-1 , 2-Dichloroethene —— Chloroform —— 1 , 2-Dichloroethane —— 2-Butanone —— 1 , 1 , 1-Trichloroethane —— Carbon Tetrachloride —— Bromodichloromethane —— 1 , 2-Dichloropropane —— cis-1 , 3-Dichloropropene —— Trichloroethene —— Dibromochloromethane —— 1 , 1 , 2-Trichloroethane —— Benzene —— trans-1 , 3-Dichloropropene —— 1 , 2-Dibromoethane —— Bromoform —— 4 -Methyl-2 -Pentanone —— 2-Hexanone —— Tetrachloroethene —— 1 ,1.2, 2-Tetrachloroethane —— Toluene —— Chlorobenzene 1 1 I I 3 5 1 1 1 1 1 1 1 1 5 1 1 1 1 1 1 1 1 1 1 1 1 5 5 1 1 1 1 U U U U B U U U U U U U U U U U U U U U U U U U U U U U U U U U U i- ~^\ \- 3/90 L 0 0 0 1 G 3 G IX ORGANICS ANALYSIS DATA SHEET Lab Name: ITAS-KNOXVILLE_________ Contract: Code: ITSTU Case No. : 53554 SAS No. : Matrix: (soil/water) WATER Sample wt/vol: 5.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ Heated Purge: N GC Column: DB-624 ID: 0.53(mm) Soil Extract Volume: _______(uL) SAMPLE NO. TRIPBLANK SDG No.: MW01 Lab Sample ID: W7328 Lab File ID: W7328 Date Received: 03/08/93 Date Analyzed: 03/18/93 Dilution Factor: ____1.0 Soil Aliquot Volume: ___ CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L .(uL) 100-41-4 ——— • 100-42-5 ——— • 1330-20-7 —— • 541-73-1 ——— • 106-46-7 ——— • 95-50-1 ———— • Q£ 1 O _ Q _ — ___. —— Ethylbenzene hJ ^- J J- C1JC —— Xylene (total) —— 1, 3 -Dichlorobenzene —— 1 , 2 -Dichlorobenzene —— 1, 2-Dibromo-3-Chloropropane _ 1 U 1 U 1 U 1 U 1 U 1 U 1 U TUT OO4 1638 FORM I X-2 3/90 IX ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS SAMPLE NO. -,ab Name: ITAS-KNOXVILLE_________ "Lab Code: ITSTU Case No.: 53554 Matrix: (soil/water) WATER Sample wt/vol: 25.0 (g/mL) MI Level: (low/med) LOW % Moisture: not dec. ___ GC Column: DB-624 ID: 0.53(mm) Soil Extract Volume: ______(uL) Contract: SAS No.: TRIPBLANK SDG No.: MW01 Lab Sample ID: W7328 Lab File ID: W7328 Date Received: 03/08/93 Date Analyzed: 03/18/93 Dilution Factor: ____1.0 Soil Aliquot Volume: .(uL) Number TICs found: CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L CAS NUMBER COMPOUND NAME RT EST. CONC. Q TUT OO4 1639 FORM I X-TIC 3/90 DATA FROM FILE: UU7328 SCANS 45 TO 720 ACQUIRED: 63/13/33 13:04:6* CftLI: W7328 #3 SAMPLE: CLP,53554,MUCH,TRIPBLAHK,LOW,WATER, W7328,VQA,EPA, CONDS.: I500A:25ML OLU81 AMBIENT PURGE W/ 5PPB IS «, SS _L 100 _ 3:20 200 . 6:40 300 _ 10:00 400 _ 13:20 500 _ 16:40 >0:00" ». L=___ r ' i J 108.97. C 13868.) CS19 4-BROMOFLUOROBENZENE <SS) I26 1,4-DICHLOROBENZENE-D4 oo CO i—i O O 05 J "i .<*nt 1 tat i on Report File: VV7328 lata: W7328. TI :3/18/93 13:04:00 •Ea-r.ple: CLP, 33554, MWQ1, TRIP3LANK, LOW, WATER, VV7328, VOA, EPA, •.-:-»ds. : I5OOA:25ML OLV01 AMBIENT PURGE W/ 5PP3 IS & SS ,-'-rmula. 25ML AMBIENT PURGE Instrument: I500A Weight: 0.000 r-vismitted by: ITEK Analyst RJL Acct. No 53554 * REF AMNT/(REF AREA * RESP FACT) :'-'•?•» p. fac. from Library Entry No Nerce 1 CI10 1,4-DIFLUORCDENZENE <IS#1) 2 CI2O CHLOROBENZENE-D5 <IS#2) 2 CI26 1,4-DICHLOR03ENZENE-D4 <IS#3> <! CS10 4-BROMOFLUOROBENZENE (SS) 5 C010 CHLOROMETHANE *•» 6 CO15 BROMOMETHANE / C020 VINYL CHLORIDE * 8 CQ25 CHLOROETHANE •? C030 METHYLENE CHLORIDE 10 C03S ACETONE 11 C110 2-3UTANONE -.2 CZ05 4-ME1HYL-2-FENTANONE :3 C210 2-HEXANONE -.4 C03/ BROMOCHLOROMETHANE ;5 CO 10 CARBON DISULFIDE It CC45 1,1-DICHLOROETHENE * 17 C050 1.. 1-DICHLOROETHANE *# :9 C053 TR,A.NS-1, 2-DICHLOROETHENE IT C06O CHLOROFORM * '20 C065 1,2-DICHLOROETHANE 21 C115 1,1,1-TRICHLOROETHANE LA C120 CARSON TETRACHLORIDE 13 C130 BRCMODICHLOROMETHANE :.A C140 1, 2-DICHLOPOPROPANE * i*. C143 CIS-1, 3-DICHLOROPROPENE 2c C150 TRICHLOROETHENE :~ C155 DIDROMOCHLOROMETHANE ."2 C16O 1, 1, 2-TRICHLOROETHANE ?:9 0165 BENZENE TRANS-1.3-DICHLOROPROPENE 1,2-DIBROMOETHANE BROMOFORM ** TETRACHLOROETHENE 1, 1,2,2-TETRACHLOROETHANE ** TOLUENE * CHLOROBENZENE ETHYL BENZENE * STYRENE M/P XYLENE 0-XYLENE CIS-1,2-DICHLOROETHENE 1.3-DICHLOROBENZENE 1.4-DICHLOROBENZENE 1,2-DICHLOROBENZENE TUT O04 1.641 1,2-DIBROMO-3-CHLOROPROPANE L000164;: •jr. I --* 3 4 c. A •r 3 — . • . '. •f -. i :.'! 1 j '.4 '. 7 fc O • f 12 : >? ^ 0 21 Z2 — *i 24 25 2.6 27 28 29 30 z t I' 2 - •-. 24 -,=. 136 2 7 35 ~'^ u:j •• t "* a.' J'3 :4 •*i * -T 1 ^ ^J 4 *. i *? •Ti ••? m/i Scan 114 184 117 373 1 50 519 95 440 NOT FOUND NOT FOUND NOT FOUND NOT FOUND 34 73 43 64 NOT FOUND NOT FOUND NOT FOUND NOT FOUND 76 66 NOT FOUND NOT FOUND NOT FOUND £3 128 NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND 166 326 NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND R.?tCL> Rati o 08 1. 00 12:26 1.00 17: 16 1. 00 1 4 : 38 1 OO 1 : 18 1: 28 1: 20 1: 32 2: 24 1 01 Time Ref RRT Meth 6: 08 1 1. 000 A BB 12: 26 2 1. OOO A BB 17: 18 3 1 OOO A DB 14: 40 1 2. 391 A BD 2: 26 1 0 397 A DB 2: 08 1 0. 348 A BE 2: 12 1 0. 359 A BB 4: 16 1 0 696 A EB 1O 5? 2 O 874 A B3 o RRT(L) Ratio Ainnt 1. 000 1. 00 5. 00 1. 000 1. 00 5 00 1. OOO 1. 00 5. 00 2. 386 1. 00 5. 26 0. 212 0. 239 0. 217 0. 250 0. 391 1. 01 3. 14 Area(Hght) Amount 7.Tot 10114. 5.000 UG/L 15.08 7854. 5.000 UG/L 15.03 4883. 5. OOO UG./L 15. OS 6500. 5.259 UG/L 15.86 2405. 3. 135 UG/L 9. 46 319 9. 597 UG/L 28. 95 353. 0. 112 UG/L 0. 34 117 0. 057 UG/L 0. 17 167 0. 090 UG/L 0 27 Aaint(L) R. Fac R.Fac(L) Ratio 5 00 1. 000 1. 000 1. 00 5 OO 1. 000 1. OOO 1. 00 5 00 1 . 000 1 000 1 . 00 5 00 0. 643 0. 611 1. 05 5. 00 0. 233 0. 379 0. 63 L0001G4;; TUT OO4 1642 0 O CO o n -P O cr ~ «o _ i »-i -• o u »D O U. n: -0 u 0 m o u. . . o cc <~. o _l O *> in c ru E 4* O C -0 e . < a- 0 •M f) 4> O 0) . a: *-< ^— » _j N 10 in ~ m ru r^ H n <•<) h- a : . . . a: o o o o •M n 4* O 0)a: ,-4 J <* 0 00 ••<• O W) CO 01 ai n i> (T o r? ^ r .-- fd O O GOmin ,_! inno 6 oo m — \ 6 fdo •"• <t n n -o m t *-« >o m CM Of- Cd cr- 4i n n •*• •* o o o o o o fdo ^ (M <t O O (M ••<) rii o -• a o co ~ •* id rxi n r,j r-7 * in ^) .-•- QJ . < i • - • . < ,. ,< *— i O o m •-•4 O t—f fd *-• O o 00 m •0o o *— «o «— t O Cd fd 0- rj- -0 -o oo n 0 0 O r-to »— t t o o •j m -j • - lr.l I'.l rdo o o GO ,_, ,_) fd0 0 oo m o- (~J 0 oo •"• n ^o rd rd 0"- t oo o t rd o^ *-" o~ n o ("•- N oo rj o^ -o h- o o p 4 " O o n n ' - ' i n > - < t r i f d O N O O D o n j o t o o i n ' - o n ^o m r^ in o- oo t ro o^ oo CD ru N o o — « o — < -o o- o- O O O O O O O O O O O O ^ O ^ v H - . ^ . ^ i O O O 0o •"• • ^ j r u t - o r d r d o - o r u o o o o o o j t c D ' O - o r d r d t o f M •* o ~« o >t ( d -i o fd fu m m o <t ru -T t o >t t n T •* oo r--. o- • -o -< o m o -« n o ir> o ru nj n n n n -o o O.i r.) .4 if, -ij |- oi 0- O -- <:> -• Id fT ni r>- r,i 10 i M IM I'.i r-i n n r< ri n n ro ro n n -t -r •* >^ ry - O CD O O f~t f-4 CD 0 ^ T r-- co •• -- Kl oo o> cr> CD 3/18/93 13:04:43 Acquisition started 0208 3/18/93 13:04:46 <cquire Run O: VV7328 Starting •IS,'18/93 13:04:00 + 0:00 Free sectors: 11582 Scan: 0 of 720 S~mp le: CLP, 53554, MWO1, TRIPDLANK, LOW, WATER, VV7328, VOA, EPA, ::rds. I500A:25ML OLV01 AMBIENT PURGE W/ 5PPB IS &•. SS =-rmula 25ML AMBIENT PURGE Instrument: 1500A Weight: 0. OOO I-.imitted by: ITEK Analgst: RJL Acct. No: 53554 '.-•'. Desc. RR *** GC not ready and being stabilized *** Elapsed time : 0. 0 Min Temp Rate Time (minutes) «• (DegC) (C/min> : 35- 35 5 35 150 8. 0 2 150-150 sIve A : c1osed period 6 6 14. 3 3. 0 Valve B total 6. 6 20. 9 23. 9 open In jector A GC oven : Transfer-1ine: Ion source 150 Deg C 36 Deg C 215 Deg C 1S2 Deg C *** Instrument parameters *** Post acquisition state -> Filament : Off Multiplier : Off 7DE: El <+) Centroid + Temp - Sequence: BF ( 2 time windows. ) •n-?i4.uenc e Window I"-an descriptor: }tal scan time: Number of cycles: 28 Filament is OFF Multiplier is ON BF Mass intervals: 2.. OOO s Positive ion mode. Master rate: 16 Int 1 MFW: 80 Lo mass 33. 51O MA: 15 Hi mass 300. 590 TH: 1 Time 2. 000 BL: iuenc e Window # an descriptor: tra 1 scan time: Number of cgcles: Filament is ON Multiplier is ON BF Mass intervals: 2. 000 s Positive ion mode. Master rate: 16 Int 1 MrW: 80 Lo mass 33. 510 MA: 15 Hi mass 300. 59O TH. 1 Time 2. 000 BL: Calibration table: Interface number Instrument type Full scale mass Zero scale mass Intens i ty/ion Peak width Offset at low mass Offset at high mass Voltage settling time(ms) 20 D:CALO21992 0 G 1177 1 2 1000. 0 0 u u mmu mmu mmu TUT OO4 1644 U 000164 Current instrument parameters. Pos i t ive ion Resolution (high) Pesolution (low) Quad offset Quad programming Lens offset Lens programming Ext offset Ext programming Co 11ec tor Ion offset Ion programming Rod polarity 128. 128. 0. O. -50. 0. 0. 0. 3O. 7. 5. 00 00 00 00 00 oo 00 00 00 oo 00 mode Negative ion mode 128. 00 129. 00 0. 00 0. 00 50. 0. 0. 0. 30. -3. 0209 oo 00 00 00 00 00 -5. Reverse Electron m u l t i p l i e r voltage Filament emission current Electrometer range Electrometer zero 00 Norma1 984. 750. 10 ~-7 126. 0 •"nlyier Fore Pressure . . . •^parator/Source Pressure 0. 010 Torr O. 354 Torr 3/18/93 13: 33: 4O ACQUISITION COMPLETED Scans 1 to 720 Centroid 3:16 introi d Scans Sees 0. 4 Out of 1440. 0 0. 0 Pea ks per 2605. scan 4. per sec TUT 004 1645 LOOOJ64u QUALITY CONTROL/QUALITY ASSURANCE DATA METHOD: CLP 3'90 OLV01 25ML PURGE 0210 DATAFILE: W7328 STANDARD: WS0318 TUNEFILE: WDFD0318 ANALYSIS TIME: 03/18/93 13:04 ANALYSIS TIME: 03/18/93 8:29 ANALYSIS TIME: 03/18/93 8:20 ****** INTERNAL STANDARD AREA CHECK ****** INThRNAL STANDARD 10 1, 4-DIFLUOROBENZEN 50 CM OR03ENZENE-D5 ( 1-6 1, A-DICHLORDDENZEN DATA AREA 10114. 7854. 4883. STD AREA 11210. 7723. 5477. RATIO 907. 1027. 897. CLP ACCEPT RATIO 607. - 1407. 607. - 1407. 607. - 1407. STATUS ****** INTERNAL STANDARD RT CHECK. ****** INTERNAL STANDARD 1O 1, 4-DIFLUORODENZEN 20 CHLCRODENZENE-D5 < 26 1, 4-DICHLOROBENZEN DATA SCAN 184 373 519 STD SCAN 184 373 518 DIFF [IN SEC] 0 0 2 CLP ACCEPT DIFF STATUS +/- 20 SECS +/- 20 SECS +/- 20 SECS SURROGATE «***«» SURROGATE RECOVERIES ****** AKT AMT PERCENT FOUND ADDED RECOVERY RECOV LIMITS STATUS :iO 4-SROMOFLUOROBENZE 5. 3 5. 0 105 :i5 BRCnOMETHANE -0. O 50. O 0 ?0 Vir^'L CHLORIDE * -0. 0 50. 0 0 807. - 1207. 887. - 1107. 867. - 1157. failed failed TUT OO4 1646 u o o o i u ; ""OCEDURE: TCA DIAGNOSTIC REPORT 3/18/V3 13:36:34 DATA FILE: VV7328 r^EFERENCt: VI 11 n O | I •'lAtfE LIST: VI INITIALIZATION OPTION: 2 PROCESSING OPTION: 3 V £ 1 1 REPOHT: VI IS ": - —— STANDARDS ———— X —— PLUS UNKNOWNS —— >< - LIST NAMES - > "ftOC USED POSS RMS PROC USED POSS RtfS STANDARD/UNKNOWN 32 1 O 20 5 1 60 V1IS/V1UNKS1 3 3 1 O 16 3 1 0 V1IS/V1UNKS2 3 3 1 0 15 3 1 0 V1IS/V1UNKS3 45 COMPOUNDS : COMPOUND ':•-• •..2 LI 3 ENTRY 1 j? 3 4 5 i •^ / So 10 1 1 12 13 1 ** . s -'le 17 IS :'•? 20 11 c-'e.' • s2 54 25 •'6 27 -S 29 JO 1-1 ^ •"* 23 34 35 36 37 33 39 »0 _ x4 1 :^2 4:3 «4 45 VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI Vi VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 5 PROCESSED- 4 FOUND s. REF -184 -373 -518 -439 -38 -44 -39 -46 -72 -62 -115 -289 -341 -122 -65 -60 -91 -78 -127 -155 -135 -143 -242 -218 -274 -201 -341 -321 -153 -311 -344 -420 -325 -451 -293 -375 -384 -413 -391 -412 -112 -496 -501 -519 -561 ju.nn v/n PRED SEL DELTA PEAKS 184 184 . 1 373 373 . 1 518 439 440 1 1 3 9 . . . 4 5 . . . 4 0 . . 4 7 . . . 73 73 1 6 3 . . . 116 289 341 . 123 6 6 . . . 6 1 . . . 92 . 79 128 156 135 143 242 218 274 201 341 321 153 311 344 42O 325 451 293 375 384 413 391 412 112 496 501 519 561 -;.-- QAT >-•" — «' >• ujn i »' ^_ FIT PEAKS M/Z 981 . 114 967 . 117 150 948 . 95 50 94 62 64 978 . 84 43 43 43 43 128 76 96 63 96 83 62 97 117 83 63 75 95 129 97 78 75 107 173 166 83 91 112 91 1O4 1O6 1O6 96 146 146 146 75 - — CHRO — - TOP DELTA 184 373 519 440 73 64 66 128 326 PEAKS 1 1 1 1 1 1 1 ^ '. K O O 1-D h- 0001 64."- I. T. ANALYTICAL SERVICES LIBRARY SEARCH REPORT PURGEABLE VOLATILE ORGANICS ANALYSIS 0212 ATA FILE: VV7328 -MUIRED: 03/18/93 13:04:00 .I'iDS. : I500A:25ML OLV01 AMBIENT :J:-:MITTED BY: ITEK PURGE W/ 5PPD IS ?< SS ANALYST: RJL ACCOUNT NO. 53554 COMPOUND 10 1,4-DIFLUOROBENZENE (15*1) Z-0 CHLCROBENZENE-D5 <IS#2) ,?6 1,4-DICHLOROBENZENE-D4 (IS#3) 10 4-DROMOFLUOROBENZENE (SS) •30 MhTHYLENE CHLORIDE .35 ACETONE SCAN DELTA (UG/ML) FIT SAT'D? 0 0 0 0 0 O 184 373 519 440 73 64 O 0 1 1 0 1 5. OOO 5. 000 5 000 5. 259 3. 135 9. 597 981 967 0 948 978 0 TUT 004 1648 L 000164.? H- I s) cn G> «• • 5* \S» \ 1 1 1 1 1 1 1 f""{" s> s» —: " _ - . -n-r cn ox c> CO -i <=• . ', •* \: • -t. — i o . cn — GI •. _ • • cn — <s> . * , - ". " .. _ <s< • ™ CO - <s> . - LO — •s . " i " " l ti 3 NA CO • I F-s : 5 - T\ _ — •"•! •n lm • • -^ i— * « '-£' « 1 . — — • . _ • . . — * . CO!• ij'im 3 sr^j - • • -P. <£• TO >—i — O • • OJ —— o fO CO ~ • • • ..... 1 1 II 1 . , , , 1 5 -U. CO co cn • • ^ CO 1 ' ' ' I ( ' 1 I I • 2 ^ i - 8: S • o •- o I:- — 4 • I> • • • .'!= -^j • CO f-o • CC' - «= " —— --J - - -: U — ~ ; _ .. — * • CO r- • un . m 3 . Kj - • • *. • 'J? _ TO •-* — O . • • —— J ——— U!' -\ <J1 . <T| "" • • • • II . . | , , n | 1—— fc ho COi. cn is ft G> Si U b ® j f i * I i t i i 1 O '.O <5> TO i—i — i O X> CO X> o TV = s x z: 3 TO O Tl »— -n r-i un i— co o o m — • m x r- c -H • • •• U) — 4 5 CO I> O r-i •— • O •• •• i— i cn i— -~ •=! O TI c,J o -n 05 7_ " -s o — i> cn s> c*j' i — •• co *. <s< 3 NJ cn rn cn cn c: 3 2 •&- c m o r~ - --J — i o _ 3 CO I 3 O E NJ -C -n r~ <s> co r— i> S *•* m TO C2> <• * Z HI — H- _( -sj m i ,-, _ TO CO O 5 t-j o z ————————— 3 TJ I COCO (*= HI r~ o —— m r, TO Z 2 •-. — ( ^ 0 _;_ m TO r^ r— i— i TOS O ^ m E x" m TO cn >• •o c: -o c: co -^ CO HI fs.) en co s» <z O CO i.n l> x ^X, ^ m m TO T> 3xru • • -fx IJJ TO »— ^ O • • t«^^B«B^B 4i ^J —— co -u • .... 1 • 1 1 1 1 ^t K< ro 0- L 0 0 0 1 6 ,:, mno** - •0001 09 .i.i.i.i.l.i. .i.i.i.i.l.i. .i.i.i.i.l.i. Z- Old t-t1 •£. . 1 . 1 . 1 . 1 . 1 . 1 . 1 . 1 . 1 . 1 . 1 , 1 . 1 . "Did £fr :Z i . 01 1 3SW8 .1.1. • i . i i . i 0£ 03 8I# Ii'i :31Id . i . i . i . i . i . i . i . i . i . I . i . i . i . i . i . i . i . i .1 . 1 . i . i . i . i, t>9tt 83£^nn :yiyo i i . 01 .1.1. i.i. i.i. i.i.i •J jwi i v nn j L9-,s- :0'0 -0'00T 2/W -0'8S -0-001 ->-6 -3 '91 -£'12 ss si adds /M 33and iN3iawy tamo iwsz' 00021 " ' I0MW tosses 'dio fr0:ei £6/8 I /£0 o I---*- •ess :z/w uj annodwoo TUT OO4 1650 ro i-~ £>* itation Report File: W7328 • ata: W7328. TI 3/18/93 13:04:00 : = r?!ple: CLP, 53554, MI-JO 1, TRIPDLANK, LOW, WATER, W7328, VOA, EPA, cr.ds. : I500A:25ML OLV01 AMBIENT PURGE W/ 5PPB IS & SS :rmula 25ML AMBIENT PURGE Instrument: I500A Weight: ;.Emitted by: ITEK Analyst: RJL Acct. No. 0215 0. 000 53554 ,CUNT=HEIGHT * ••3 p. fac. froir. = .- GAS # 1 0-00-0 i' 0-00-0 j 0-00-0 4 541-05-9 REF AM\!T/(REF HEIGHT * RESP FACT) Library Entry Name CI01 BROMOCHLOROMETHANE (I.S. « CI1O 1,4-DIFLUOROBENZENE (I.S. CI20 CHLOROBENZENE-D5 (I.S. #3) CYCLOTRISILOXANE, HEXAMETHYL- Area(Hght) 6764. * 10663. * 12068. * 1151. * m R R R R /: 1C 1C 1C 1C Scan 185 374 519 338 Time 6: 12: 17: 11: 10 23 IS 16 Ref 1 2 3 2 1 1. 1. 0. RRT 000 OOO 000 904 Meth A A A A BB BB BB BB Amount 50. 000 UG/L 50. 000 UG/L 50. 000 UG/L 5. 399 "/.Tot 32. 18 32. 18 32. 18 3. 47 TUT OO4 1651 L 000 j 65:.- PSOCEDUKE: FILTER/TIC T4TA FILE: W7328 -2LTER SCAN PARAMETERS •V<. NUK3ER TICS: 10 '-TABLE ENTRIES: 475 AN TOLERANCE : 3 N. RIC HT. EX]: 10 *ST SCAN : 35 5T SCAN : 100O : THRESHOLD : 500 DIAGNOSTIC REPORT 3/18/93 18:27:04 0216 METHOD LIBRARY ?< LISTS TIC I. S. LIBRARY: NBS SEARCH PROC : PEAK FINDER PROC: TCA I. S. LL : FILE NAME LIST : LIBRARYIS SERLIB VOME5 IS TCAREF2 COMPOUND ANALYSIS: TARGETS (QUAM LIST) 6 1L.TER PROCESSING: IS PEAKS 3 TOTAL r'EAKS 17 < 1ST SCAN 1 > LAST SCAN 0 -—REJECT PEAKS- -'I KIN < SCAN RIC HT TQL 7 8 TC PROCESSING: .-'•. SCAN* PURITY FIT 1 338 882 886 TOTAL TARGET PEAKS 9 •- MAX # TOTAL TOTAL PEAKS REJECTS TICS 0 16 1 MW COMPOUND NAME CBEFORE TIC THRESHOLD] 222 CYCLOTRISILOXANE, HEXAMETHYL- TU'T 004 LOC0165J trOO o MID LIBRARY SEARCH (LIBRAPYNB) DATA: UU7328 # 03/18/33 13:04s66 + 11:16 CALI: W7328 # SAMPLE: CLP,53554,MH81, TRIPBLANK,LOW,WATER,UU7328,UOA,EPA, CONDS.: I508A:25ML OLU01 AMBIENT PURGE W/ 5PPB IS & SS ENHANCED (S 15B 2N 0T) 338 BASE RIC: Z: 207 1104. to c _J 1137 - SAMPLE C6.H18.03.Si; 1197 M WT 222 B PK 207 RANK 1 tt 22477 PUR 882 C9.H27.03.AS.SI3 1197 M WT 342 B PK 207 RANK 2 tt 38131 PUR 821 Cll.Hie.06 1197 M WT 238 B PK 207 RANK 3 ft 25174 PUR 663 CYCLOTRISILOXANE, HEXAMETHYL- CAS# 541-65-9 ARSEMGUS ACID.. TRIS<TRIMETHYLSILYL> ESTER CAS# 55429-29-3 -.—r-~"—i—•—i—•—f-~«—i—.—i—•—r—-•—<—•--,—i^—i—•—i—i^—!—,—f—,—p 1,2,4-BENZENETRICARBOXYLIC ACID, 1,2-DIMETHYL ESTER CASt 54699-35-3 M/Z 50 100 150 200 250 • I ' 300 0218 III VOLATILES DATA, continued c. STANDARDS DATA TUT 004 1654 -•• '••':»'.v-«--,-.'VA- -- ' "_>' -^SAL**.*'* OLV01 INITIAL CALIBRATION DATA VOLATILE HSL COMPOUNDS 0219 se No: 53554 Region: Instrument ID: I500A -contractor: I TAS - KNOXVI LLE Contract No: Calibration Date: 03/16/93 Laboratory ID WI0316A WI0316C W 1 03 USB ^ UIO Compound V i n y l C h l o r i d e . . . . . . . . Chloroethane . . . . . . . . . 1 , 1 -D i ch I oroethane . . . . . . 1 , 2-D i ch loroethene (total) . . c i s- 1 , 2- D i ch I oroethene . . . . 1 , 1 , 1 - T r i ch I oroethane . . . . -bon Tet rach loride . . . . . c i s - 1 , 3-D i ch 1 oropropene . . . 1 , 1 , 2- T r i ch I oroethane . . . . Benzene . . . . . . . . . . . trans- 1 , 3- D i ch I oropropene . . 4-Methyl -2-Pentanone . . . . . 2-Hexanone . . . . . . . . . . 1 , 1 , 2, 2- Tet rach I oroethane . . Xylene (total) . . . . . . . . 1 . 3-D i ch lorobenzene . . . . . RFC-20) 1.185 0.669 0.844 0.542 1.277 0.026 0.142 1.656 0.627 1.282 0.649 0.496 1 . 179 0.454 0.063 1.781 1.540 0.841 0.836 0.589 1 . 191 0.450 0.274 1.890 0.348 0.354 0.221 0.122 0.068 1.321 0.322 2.134 1.411 2.408 1.153 0.890 1.776 RFC*T) ( 1 . 0. 0. 0. 0. 0. 0. 1 . 0. 1. 0. 0. 1 . 0. 0. 1 . 1 . 0. 0. 0. 1 . 0. 0. 1. 0. 0. 0. 0. 0. 1. 0. 1. 1. 2. 1. 0. 1. 090 594 729 465 516 019 139 615 562 058 567 490 044 366 045 753 525 812 634 553 055 472 270 811 340 338 243 107 069 329 314 885 373 366 092 728 651 WI0316E 3 160 _- FfJ^tf) RFclKr) RFcJS*") 0.904 0.514 0.696 0.369 0.384 0.016 0.134 1.511 0.495 0.925 0.532 0.392 0.932 0.320 0.033 1.467 1.365 0.793 0.528 0.573 0.913 0.499 0.289 1.532 0.370 0.327 0.243 0.102 0.069 1.216 0.298 1.752 1.230 2.246 0.973 0.641 1.311 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 1 1 0 0 0 0 0 0 1 0 0 0 0 0 1 0 1 1 2 0 0 1 .954 .494 .647 .352 .316 .015 .125 .541 .484 .915 .447 .348 .905 .305 .026 .534 .460 .830 .535 .569 .914 .458 .246 .560 .358 .343 .268 .100 .060 .118 .319 .754 . 180 .273 .993 .658 . 174 0.943 0.451 0.675 0.338 0.331 0.014 0.110 1.552 0.478 0.890 0.433 0.350 1.400 0.263 0.023 1.554 1.453 0.951 0.523 0.570 0.894 0.419 0.206 1.530 0.347 0.298 0.202 0.088 0.055 1.033 0.278 1.671 1.063 2.254 0.916 0.619 0.899 ccc* AVE RF X RSD SPCC** 1 0 0 0 0 0 0 1 0 1 0 0 1 0 0 1 1 0 0 0 0 0 0 1 0 0 0 0 0 1 0 1 1 2 1 0 1 .015 .544 .718 .413 .565 .018 .130 .575 .529 .014 .526 .415 .092 .346 .038 .618 .469 .845 .611 .571 .993 .460 .257 .665 .353 .332 .235 .104 .064 .203 .306 .839 .251 .309 .025 .707 .362 11.6 16.0 10.6 21.2 71 .9 26.9 9.9 3.7 12.1 16.1 16.9 17.6 18.6 19.6 43.0 8.7 4.7 7.3 21.9 2.2 12.9 6.4 12.6 10.4 3.3 6.4 10.6 11.9 9.9 10.7 6.0 9.9 11.4 3.2 9.3 15.6 26.1 * * * * * * * * * * * * * * * * * * * * * * * to -o Up to two compounds with XRSD criteria may exceed the maximum, but none of these may exceed 40.OX. .11 compounds with no XRSD or RRF criteria specified must meet a minimum 0.010 RRF criteria. Refer to method for RRF criteria. h- L000105G 0220 OLV01 I N I T I A L CALIBRATION DATA VOLATILE HSL COMPOUNDS e No: x_*ntractor: Contract No: 53554 I T A S - K N O X V I L L E Regi on: Instrument ID: I500A C a l i b r a t i o n Date: 03/16/93 laboratory ID UI0316A UI0316C WI0316B f- UI03. Compound 1 ,4-Di 1 ,2-Di 1 , 2 - 0 i Bromof bromo-3 - Ch I oropropane RFC-34W 1 .776 1 .172 0.111 1.266 RF(W ( 1.548 1.227 0.101 0.799 UI0316E 1.60 _.- 1.316 0.964 0.094 0.698 1 . 0. 0. 0. 169 831 086 668 0.866 0.628 0.062 0.586 AVE RF 1 0 0 0 .335 .964 .091 .803 *** ccc* X RSD SPCC** 26 25 20 33 .2 .6 .4 .6 * Up to two compounds with XRSD c r i t e r i a may exceed the maximum, but none of these may exceed 40.OX. AH compounds w i t h no XRSD or RRF criteria specified must meet a m i n i m u m 0.010 RRF c r i t e r i a . Refer to method for RRF c r i t e r i a . TUT 004 1656 L - O O O J 6 5 , CM CJ DATA FROM FILE: WI9316A SCANS 45 TO 729 ACQUIRED: 03/16/93 18:57:1 CALI: WI0316A #3 SAMPLE: CLP,,,USTD991,LOW,MATER,MI9316A,VOA,IC-6ei, CONDS.: I599A:25ML OLU91 AMBIENT PURGE M/ 5PPB IS \r> <s •H 199 _ 3:29 299 ^ 6:49 399 -H 19:99 499 . 13:29 599 . 16:49 666 . 26:66 796 _ J 199.9Z ( 14864.) L.O CDoJ CI19 1,4-DIFLUOROBENZENE (IS#1) CI20 CHLOROBENZENE-D5 <IS#2) CS19 4-BROMOFLUOROBENZENE (SS) auantitat ion report rile: WIO316A 0222 Data: UI0316A. TI 03/16/93 18:37:00 Sample: CLP, , ,VSTD001,LOW,WATER,WI0316A,VGA, IC-001, ^onds. : I300A:25ML OLV01 AMDIENT PURGE W/ 5PPB IS Formula: 23ML AMBIENT PURGE Instrument: I5OOA Submitted by: Analyst: RJL ,^f"50UNT=AREA * REF AMNT/CREF AREA * RESP FACT) R««p. fac. from Library Entry 1,4-DIFLUORODENZENE (IS#1) CHLOROBENZENE-D5 <IS#2) 1,4-DICHLOROBENZENE-D4 <IS#3) 4-BROMOFLUOROBENZENE (S3) CHLOROMETHANE ** BROMOMETHANE VINYL CHLORIDE * CHLOROETHANE METHYLENE CHLORIDE ACETONE 2-BUTANONE 4-METHYL-2-PENTANONE 2-HEXANONE B R OMOC HLOR OMETHANE CARBON DISULFIDE 1,1-DICHLOROETHENE # 1, 1-DICHLOROETHANE »# TRANS-1,2-DICHLOROETHENE CHLOROFORM * 1,2-DICHLOROETHANE 1,1,1-TRICHLOROETHANE CARBON TETRACHLORIDE BROMODICHLOROMETHANE 1, 2-DICHLOROPROPANE * CIS-1, 3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1, 1, 2-TRICHLOROETHANE BENZENE TRANS-1/3-DICHLOROPROPENE DIBROMOETHANE BROMOFORM ** TETRACHLOROETHENE 1,1,2,2-TETRACHLOROETHANE ** TOLUENE » CHLOROBENZENE ETHYL BENZENE * STYRENE M/P XYLENE O-XYLENE CIS-1,2-DICHLOROETHENE li 3-DICHLOROBENZENE 1,4-DICHLORODENZENE 1,2-DICHLOROBENZENE 1,2-DIBROMO-3-CHLOROPROPANE Weight: Acct. No. 0. OOO No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 ^19 2O 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 3 ^•44 45 Name CI10 CI20 CI26 CS1O C010 C015 C020 C025 C030 C035 C110 C205 C21O C037 C040 C045 C03O C053 C060 C06S C115 C120 C130 C140 C143 C15O C155 C160 C165 C172 C176 C180 C220 C225 C230 C235 C240 C245 C25O C252 C054 C252 C253 C254 C261 TUT 004 1658 0223 No 1 2 3 4 3 6 7 S 9 10 11 12 13 14 IS 16 17 19 19 20 21 22 23 24 29 26 27 2* 29 30 31 32 33 34 33 36 37 38 39 40 41 42 43 44 45 ffl/2 114 117 150 95 SO 94 62 64 84 43 43 43 43 128 76 96 63 96 S3 62 97 117 83 63 7b 95 129 97 78 75 107 173 166 S3 91 112 91 104 106 106 96 146 116 146 75 Scan 183 372 518 439 39 44 40 45 72 62 114 289 34O 121 65 60 91 78 127 155 134 142 241 217 273 200 341 320 152 310 344 419 324 451 292 374 383 412 39O 411 112 495 495 519 560 Tim* 6:06 12:24 17: 16 14: 36 1:18 1:28 1:20 1: 30 2: 24 2: 04 3: 48 9:38 11: 20 4:02 2: 10 2:00 3:02 2: 36 4: 14 5: 10 4: 28 4: 44 8:02 7: 14 9: 06 6: 40 11:22 10: 40 5:04 10: 20 11: 28 13: 58 10: 48 15: 02 9: 44 12: 28 12: 46 13: 44 13: OO 13: 42 3: 44 16:30 16: 30 17: 18 18:40 R»f 1 2 3 1 1 1 1 1 1 1 1 2 2 1 1 1 1 1 1 1 2 2 2 2 2 2 2 2 2 2 2 3 2 2 2 2 2 2 2 2 1 3 3 3 3 RRT 1. OOO 1. 000 1. 000 2. 399 0. 213 0. 240 0. 219 0. 246 0. 393 0. 339 0. 623 0. 777 0. 914 0. 661 0. 355 0. 328 0. 497 0. 426 0. 694 0. 847 0. 360 0. 382 0. 648 0. 583 0. 734 0. 538 0. 917 0. 860 0. 409 0. 833 0. 925 0. 809 0. 871 1. 212 0. 785 1. 005 1 030 1. 108 1. 048 1. 105 0. 612 0. 956 0. 956 1. 002 1. 081 fifth A BB A BV A DD A BB A BB A BB A BB A VD A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A VB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BV A BB A BV A BB A VB A BB A BB A BV A BV A BB A BB Area(Hght) 11143. 7851. 5435. 2820. 2640. 1491. 1881. 1209. 2845. 293. 702. 956. 534. 316. 3690. 1398. 2857. 1447. 2627. 1012. 2796. 2418. 1320. 1313. 925. 1870. 706. 430. 2967. 546. 556. 240. 2074. 505. 3350. 2215. 3781. 1811. 3455. 1398. 1105. 1931. 1931. 1274. 121. Amount 5. 5. 5. 1. 1. 1. 1. 1. 1. 5. 5. 5. 5. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 2. 1. 1. 1. 1. 1. 1. OOO 000 000 000 000 000 000 000 000 000 000 OOO 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 OOO 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 UG/L UC/L UG/L UC/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UC/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UC/L UG/L UG/L UC/L UG/L UG/L UG/L UC/L UG/L UG/L UC/L UG/L UG/L UC/L UG/L UC/L UG/L UC/L UG/L UC/L 7.Tot 6. 76 6. 76 6. 76" 1. 35 1. 35 1. 35 1. 35 1. 35 1. 35 6. 76 6. 76 6. 76 6. 76 1. 35 1. 35 1. 35 1. 35 1. 35 1. 35 1. 35 1. 35 1. 35 1. 35 1. 33 1. 33 1. 33 1. 33 1. 33 1. 35 1. 35 1. 35 1. 35 1. 35 1. 35 1. 35 1. 35 1. 33 1. 33 2. 70 1. 35 1. 35 1. 35 1. 35 1. 35 1. 35 'to Ret(L) Ratio RRT(L) Ratio Amnt Amnt(L) R.Fac R.Fac(L) Ratio 12 3 4 5 6 789 6: 12: 17: 14: 1: 1: 1: 1: 2: 06 24 16 38 18 28 20 30 24 1. 00 1. OO 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 1. 1. 2. 0. 0. 0. 0. 0. 000 OOO 000 399 213 240 219 246 393 1. 1. 1. 1. 1. 1. 1. 1. 1. 00 00 00 00 00 00 00 00 00 5. 5. 5. 1 1. 1. 1. 1 1 00 00 00 00 00 00 00 00 00 5. 5. 5. 1. 1. 1. 1. 1. 1. 00 00 00 00 00 00 00 00 00 1. 1. 1. 1. 1. 0. 0. 0. 1. 000 000 000 266 185 669 844 542 277 1. 1. 1. 1. 1. 0. 0. 0. 1. 000 OOO OOO 266 185 669 844 542 277 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 0 0 0 ' G 0224 Mo JO 11 12 13 14 15 16 17 18 19 20 21 22 23 24 23 26 27 28 29 30 31 32 33 34 35 36 37 38 39 4O 41 42 43 44 45 R»t<L) 2: 3: 9: 11: 4: 2: 2: 3: 2: 4: 5: 4: 4: 8: 7: 9: 6: 11: 10: 5: 10: 11: 13: 10: 15: 9: 12: 12: 13: 13: 13: 3: 16: 16: 17: 18: 04 48 38 20 02 10 00 02 36 14 10 28 44 02 14 06 40 22 40 04 20 28 58 48 02 44 28 46 44 00 42 44 30 30 18 40 Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. OO 1. 00 1. OO 1. 00 1. OO 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. OO 1. 00 1. 00 1. OO 1. 00 1. 00 1. 00 1. 00 1. 00 RRT(L> 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 0. 1. 1. 1. 1. 1. 0. 0. 0. 1. 1. 339 623 777 914 661 355 328 497 426 694 847 360 382 648 583 734 538 917 860 409 833 925 809 871 212 785 005 030 108 048 105 612 956 956 002 081 Ratio 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 00 00 00 00 00 00 00 00 00 00 00 00 OO 00 00 00 00 00 00 00 00 00 00 00 00 00 00 OO 00 00 00 00 00 00 00 00 Amnt 5. 5. 5. 5. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 2. 1. 1. 1. 1. 1. 1. 00 00 00 00 00 00 00 00 00 00 00 00 OO 00 OO 00 00 00 00 00 00 00 00 00 00 00 00 OO 00 00 00 00 00 00 00 00 Amnt < 5. 5. 5. 5. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 2. 1. 1. 1. 1. 1. 1. L) 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 R. Fac R. 0. 0. 0. 0. 0. 1. 0. 1. 0. 1. 0. 1. 1. 0. 0. 0. 1. 0. 0. 1. 0. 0. 0. 1. 0. 2. 1. 2. 1. 1. 0. 0. 1. 1. 1. 0. 026 063 122 068 142 656 627 282 649 179 454 781 540 841 836 589 191 450 274 890 348 354 221 321 322 134 411 408 153 100 890 496 776 776 172 111 Fac(L) Ratio 0. 0. 0. 0. 0. 1. 0. 1. 0. 1. 0. 1. 1. 0. 0. 0. 1. 0. 0. 1. 0. 0. 0. 1. 0. 2. 1. 2. 1. 1. 0. 0. 1. 1. 1. 0. 026 063 122 068 142 656 627 282 649 179 454 781 540 841 836 589 191 450 274 890 348 354 221 321 322 134 411 408 153 100 890 496 776 776 172 111 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. OO 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. OO 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 TUT OO4 1660 L 0 0 0 1 6 6 3/16/93 18: 57: 29 Acquisition started 0225 3/16/93 18:57:32 "Acquire Run 0:WI0316A 03/16/93 18:57:00 + 0:00 Free sectors: 14496 Sample: CLP, ,, VSTD001, LOW, WATER, WI0316A,VOA, IC-O01, Conds.: I500A:25ML OLV01 AMBIENT PURGE W/ 5PPB IS Formula: 25ML AMBIENT PURGE Instrument: I5OOA Sjbmitted by: Analyst: RJL Starting Scan: 0 of 720 Weight: 0. OOO Acct. No: GC Desc.: VI S*q. Temp » (DegC) 1 33- 35 2 35-150 3 150-150 Valve A : closed *•»* GC not ready and being Rate Time (minutes) (C/min) period total 6. 6 8. 0 14. 3 0 equilibrated *** Elapsed time : 0. O Min Post 3 Valve B : »** Instrument acquisition state -> 6. 6 20. 9 23. 9 open parameters Filament Injector A GC oven Transfer-1ine Ion source 150 111 216 184 Deg Deg Deg Oeg C C C C MODE: El (*) Centroid •»• Temp - Sequence: BF *** Off Multiplier ( 2 time windows. Off Sequence Window # 1 Scan descriptor: )tal scan time: Number of cgcles: Filament is OFF Multiplier is ON BF Mass intervals 2. 000 s 28 Positive ion mode. Master rate: 16 MPW: 3 MFW: 80 MA: 15 TH: 1 Int f Lo mass Hi mass Time 1 33. 510 300. 590 2. OOO Sequence Window # 2 DL: Scan descriptor: "otal scan time: Number of cycles: Filament is ON Multiplier is ON BF Mass intervals: 2. 000 s Positive ion mode. Master rate: 16 D:CAL021992 PPM: 3 MFW: 80 MA: 15 TH: 1 Int # Lo mass Hi mast Time 1 33. 510 300. 590 2. 000 Calibration table: Interface number Instrument type Full scale mass Zero scale mass Intensi tg/ion Peak width Offset at low mass *^s Offset at high mass Voltage settling time(ms) 20 BL: 0 Q 1177 1 2 1000. 0 0 u u mmu mmu mmu TUT O04 16,61 L 000166- Current instrument parameters. Positive ion mode 0226 Resolution (high) 128.00 Resolution (low) 128.00 Quad offset 0. 00 Quad programming 0. 00 Lens offset -30. 00 Lens programming O. OO Ext offset O. 00 Ext programming 0.00 Collector 30. 00 Ion offset 7. 00 Ion programming 5. OO Rod polarity Negative ion mode 128. 00 128. 00 0. 00 0. 00 50. 00 0. 00 0. 00 O. 00 30. 00 Reverse Electron multiplier voltage Filament emission current Electrometer range Electrometer zero -3. 00 -5. 00 Normal 984. 750. 10 ~-7 126. 0 Analyzer Fore Pressure ... Separator/Source Pressure O. OO9 Torr 0. 389 Torr 3/16/93 19:27:10 ACQUISITION COMPLETED Scans 1 to 720 Centroid ode .entro id Scans 720 Sec s 0. 8 Out of 144O. 0 7. Peaks per scan per sec 0. 1 8169. 11. 6. TUT 004 1662 DIAGNOSTIC REPORT PROCEDURE: TCA DATA FILE: WIO316A REFERENCF: VI11 LIST: VI INITIALIZATION OPTION: REPORT: VIIS 3/17/93 8:53:48 0227 PROCESSING OPTION: 3 : ——— STANDARDS ———— X FROC USED 3 3 3 2 3 3 POSS 1 1 1 —— PLUS UNKNOWNS RMS PROC 0 23 23 45 COMPOUNDS PROCESSED, ••: COMPOUND ^0 1 2 3 4 5 6 7 B 9 10 11 12 13 14 15 ,16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 33 39 \0 ^41 42 43 44 45 LID VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI ENTRY 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 s X REF -170 -361 -504 -427 -34 -39 -36 -41 -66 -56 -106 -277 -329 -113 -59 -55 -84 -73 -118 -144 -125 -133 -228 -203 -261 -186 -329 -308 -142 -299 -332 -4O7 -314 -438 -281 -363 -372 -400 -379 -399 -104 -482 -487 -505 -544 2O 16 15 USED 16 14 14 POSS 4 1 24 —— X - LI! RMS STAND* 197 V1IS/' 176 V1IS/' 462 VI IS/' 37 FOUND PRED 183 372 514 439 40 45 42 47 72 62 113 287 339 120 65 61 91 79 125 151 137 145 239 214 272 198 340 319 154 310 343 418 325 447 292 373 382 410 389 409 116 491 496 514 552 SEL 183 372 439 39 44 40 46 72 288 122 65 60 90 78 127 134 142 241 217 273 200 341 320 152 343 324 451 292 374 383 412 390 411 112 495 495 5OO DELTA -1 -1 -2 -1 1 2 -1 -1 -1 2 -3 -3 2 3 1 2 1 1 -2 -1 4 1 1 2 1 2 -4 4 -1 -14 PEAKS 1 1 1 1 1 2 1 1 1 1 1 2 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 2 1 1 1 1 2 3 2 ——— >< SAT FIT PEAKS 979 976 943 752 738 826 718 984 870 937 870 945 943 919 953 947 903 865 956 899 945 901 886 936 876 943 816 960 972 983 948 986 932 912 979 975 980 M/Z 114 117 150 95 50 94 62 64 84 43 43 43 43 128 76 96 63 96 83 62 97 117 83 63 75 95 129 97 78 75 107 173 166 83 91 112 91 104 106 106 96 146 146 146 75 — CHRO —————— ; TOP DELTA PEAKS 183 1 372 . 1 439 39 44 40 45 -1 72 62 114 289 1 340 121 -1 65 60 91 1 78 127 134 142 241 217 273 200 341 320 152 310 344 1 419 324 451 292 374 383 412 390 411 112 495 495 500 TUT O04 CO CM CM DATA FROM FILE: WI8316B SCANS 45 TO 728 ACQUIRED: 83/16/93 18:27:08 CALI: WI0316B M3 SAMPLE: CLP,,,USTD802,LOW,WATER,WI8316B,UOA,IC-082, COND5.: I588A:25ML OLV81 AMBIENT PURGE W/ 5PPB IS -GO T-i 188 J 3:28 288 J 6:48 388 _ 18:88 488 . 13:28 588 . 16:48 688 J 20:88 788 J CI18 1,4-DIFLUOROBENZENE (ISI1) J108.8Z ( 16648.) h- CI28 CHLOROBENZENE-D5 <IS#2) iMOFLUOROBENZENE (SS) Quantltation Report File: WI0316D Data: UI0316B. TI 03/16/93 18:27:00 ample: CLP, ,,VSTD002,LOW,WATER. WI0316B, VOA, IC-002, Conds. : I500A:25ML OLV01 AMBIENT PURGE W/ 5PPB IS Formula: 25ML AMBIENT PURGE Instrument: ISOOA Submitted by: Analyst: RJL AttOUNT=AREA * REF AMNT/(REF AREA * RESP FACT) R««p. fac. from Library Entry I,4-DIFLUORODENZENE <IS#l) CHLOROBENZENE-D5 (IS#2) I. 4-DICHLORODENZENE-D4 <IS#3) 4-BROMOFLUOROBENZENE (SS) CHLOROMETHANE ** BROMOMETHANE VINYL CHLORIDE * CHLOROETHANE METHYLENE CHLORIDE ACETONE 2-BUTANONE 4-METHYL-2-PENTANONE 2-HEXANONE BROMOCHLOROMETHANE CARBON DISULFIDE 1,1-DICHLOROETHENE » 1.1-DICHLOROETHANE »* TRANS-1,2-DICHLOROETHENE CHLOROFORM * 1.2-DICHLOROETHANE 1.1.1-TRICHLQROETHANE CARBON TETRACHLORIDE BROMODICHLOROMETHANE 1,2-DICHLOROPROPANE * CIS-1,3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1.1.2-TRICHLOROETHANE BENZENE TRANS-1,3-DICHLOROPROPENE DIBROMOETHANE BROMOFORH ** TETRACHLOROETHENE 1.1.2. 2-TETRACHLOROETHANE *# TOLUENE * CHLOROBENZENE ETHYL BENZENE * STYRENE M/P XYLENE 0-XYLENE CIS-1, 2-DICHLOROETHENE 1, 3-DICHLOROBENZENE 1, 4-DICHLOROBENZENE 1, 2-DICHLOROBENZENE 1, 2-DIBROMO-3-CHLOROPROPANE 0229 Weight: Acct. No. 0. 000 No 1 2 3 4 3 6 7 8 9 10 11 12 13 14 15 16 \7 ,18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 33 36 37 39 39 40 41 12 ^•3 44 45 Name CI10 CI20 CI26 CS10 C010 C015 C020 C025 C030 C035 C110 C203 C210 C037 GOTO CC45 C05O C033 C06O C065 C115 C120 C130 C140 C143 C15O C155 C160 C163 C172 C176 C180 C220 C225 C23O C233 C24O C243 C230 C252 C034 C252 C253 C25/! C261 TUT O04 No 1 2 3 4 5 6 7 S 9 10 11 12 13 14 13 16 17 19 19 20 21 22 23 24 29 26 27 28 29 30 31 32 33 34 35 36 37 36 39 40 41 42 43 44 43 ."Jo 1 2 3 4 3 6 7 S ? m/ z 114 117 150 95 50 94 62 64 84 43 43 43 43 128 76 96 63 96 83 62 97 117 S3 63 75 95 129 97 78 75 107 173 166 83 91 112 91 104 106 106 96 146 146 l':6 75 Ret<L 6 08 12 26 17 18 14 40 1 20 1 30 1 22 1 34 2 26 Scan 184 373 519 440 40 45 41 47 73 63 115 289 341 122 66 61 92 79 128 155 135 143 242 218 274 201 342 321 153 311 344 420 325 452 293 375 384 413 391 412 113 496 5O1 520 561 Tim* Ref RRT 6 12 17 14 1 1 1 1 2 2 3 9 11 4 2 2 3 2 4 5 4 4 8 7 9 6 11 10 5 10 11 14 10 15 9 12 12 13 13 13 3 16 16 17 18 ) Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 I. 00 1. 00 :08 :26 : 18 :40 :20 : 30 :22 :34 : 26 : 06 : 50 : 38 : 22 : 04 : 12 : 02 :04 : 38 : 16 : 10 :30 : 46 :04 : 16 : 08 : 42 :24 : 42 :06 : 22 28 : 00 : 50 : 04 : 46 : 30 : 48 : 46 : 02 : 44 : 46 : 32 .42 :20 :42 RRT<L> 1. 000 1. OOO 1. 000 2. 391 0. 217 0. 245 0. 223 0 255 0. 397 1 2 3 1 1 1 1 1 1 1 1 2 2 1 1 1 1 1 1 1 2 2 2 2 2 2 2 2 2 2 2 3 2 2 2 2 2 2 2 2 1 3 3 3 3 1. 000 1. 000 1. 000 2. 391 0. 217 0. 245 0. 223 0. 255 0. 397 0. 342 0. 625 0. 775 0. 914 0. 663 0. 359 0. 332 0. 500 0. 429 0. 696 0. 842 0. 362 0. 383 0. 649 0. 384 "0. 735 0. 539 0. 917 0. 861 0. 410 0. 834 O. 922 0. 809 0. 871 1. 212 0. 786 1 005 1. 029 1. 107 1. 048 1. 103 0. 614 0. 936 0. 965 1. 002 1. 081 Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 M«th A DB A BV A BB A BV A DB A BD A BB A VB A BO A BB A BB A BB A BB A BB A BB A BD A BB A BB A BV A DB A BB A VD A BB A BB A BB A BB A VB A BB A BV A BB A BB A BB A BB A BB A BB A BB A BV A BB A VB A BB A BB A BV A VB A BB A BB Amnt 5. 00 5. 00 5. 00 2. 00 2. 00 2. 00 2. 00 2. 00 2. 00 Ar*a(Hght) Amount 11115. 7783. 5306. 3554. 4847. 2641. 3241. 2068. 2295. 414. 1008. 1666. 1074. 616. 7178. 2500. 4705. 2320. 4643. 1638. 5460. 4750. 2330. 1975. 1722. 3286. 1471. 840. 5640. 1058. 1O52. 513. 4138. 977. 5869. 4273. 7366. 34OO. 5603. 2267. 2178. 3304. 3286. 2603. 214. Amnt<L) 3. 00 3. 00 3. 00 2. 00 2. 00 2. 00 2. 00 2. 00 2. 00 5. 000 3. 000 3. 000 2. 000 2. 000 2. 000 2. 000 2. 000 2. 000 10. 000 10. 000 1O. 000 10. 000 2. 000 2. OOO 2. 000 2. OOO 2. 000 2. 000 2. 000 2. 000 2. 000 2. 000 2. 000 2. 000 2. 000 2. 000 2. OOO 2. 000 2. 000 2. OOO 2. 000 2. 000 2. 000 2. 000 2. OOO 2. 000 2. 000 4. 000 2. 000 2. 000 2. OOO 2. OOO 2. 000 2. 000 UG/L UG/L UG/L UG/L UC/L UC/L UG/L UG/L UC/L UG/L UG/L UC/L UG/L UG/L UG/L UC/L UG/L UC/L UC/L UG/L UC/L UC/L UG/L UG/L UG/L UG/L UG/L UC/L UG/L UC/L UG/L UO/L UG/L UC/L UC/L UG/L UG/L UC/L UC/L UG/L UG/L UC/L UC/L UG/L UC/L R. Fac R. Fac(L) 1. OOO 1. 000 1. 000 0. 799 1. 09O 0. 394 0. 729 0. 463 0. 316 1. 000 1. 000 1. 000 0. 799 1. 090 0. 394 0. 729 0. 463 0. 316 7.Totw 3. 76 3. 76 3. 76" 1. 50 1. 50 1. 30 1. 50 1. 50 1. 50 7. 52 7. 52 7. 52 7. 52 1. 50 1. 50 1. 50 1. 50 1. 30 1. 50 1. 50 1. 50 1. 50 1. 50 1. 50 1. 30 1. 30 1. 30 1. 50 1. 50 1. 50 1 50 1. 30 1. 50 1. 50 1. 50 1. 50 1. 5O 1. 50 3. 01 1. 50 1. 50 1. 50 1. 50 1. 50 1. 50 Ratio 1 00 1 00 1. 00 1 OO 1. 00 1. 00 1. 00 1. 00 1. 00 0230 TUT 004 1666 O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O < * O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O f -o 000000000000000000000000000000000000*1- O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O * " w PJ PJ w pj PJ *> PJ ro ro PJ w w PJ ro PJ w r j ro w ru PJ ro w PJ ru nj PJ rj iu nj fo o o p o > O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O 3 oooooooooooooooooooooooooooooooooooo** oooooooooooooooooooooooooooooooooooor oooooooooooooooooooooooooooooooooooo— 1^ W**'^ O1^ OOO»-*OO'- A >^ •-'O'-'O'-'O'-'OOOOO' Hc •-•>-»»-»»-'>-l»-»»-»>-»«f en CD O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O oooooooooooooooooooooooooooooooooooo ro CO 3/16/93 18:27:27 Acquisition started 0232 ' 3/16/93 18:27:30 Acquire Run 0:WI0316B 03/16/93 18:27:00 + 0:00 Free sectors: 14612 Sa«p1e: CLP, , ,VSTDOO2,LOW, WATER,WI0316B,VOA, IC-O02, Toi.ds. : I5OOA:25ML OLV01 AMBIENT PURGE W/ 5PPB IS Pr-rmula: 25ML AMBIENT PURGE Instrument: I50OA Submitted by: Analyst: RJL Starting Scan: 0 of Weight: Acct. No: 720 0. 000 *** GC not ready and being equilibrated *»* GC Desc. . VI Seq. Temp » (DegO 1 35- 35 2 35-150 3 150-150 Rate (C/min ) - 8. 0 - Time (minutes) period total 6. 6 6. 6 14. 3 20. 9 3. 0 23. 9 Elapsed time Injector A : GC oven : Transf ei—line: Ion source : 0. 0 Min 150 106 216 184 Valve A closed Valve B Deg Deg Deg Deg open *** Instrument parameters *** Post acquisition state -> Filament : Off Multiplier : Off rtODE: EI <«•) Centroid •*• Temp - Sequence: BF ( 2 time windows. ) Sequence Window * 1 "c.an descriptor: s otal sc an time: Number of cycles: Filament is OFF Multiplier is ON BF Mass intervals 2. 000 s 28 Positive ion Master rate: mode. 16 MPW: 3 MFW: 80 MA: 15 TH: 1 Int * Lo mass Hi mass Time 1 33. 510 300. 590 2. 000 Sequence Window * 2 DL: Scan descriptor: "otal scan time: Number of cycles: Filament is ON Multiplier is ON BF Mass intervals: 2. 000 s Positive ion Master rate: mode. 16 '1PM: 3 MFW: SO MA: 15 TH: 1 Int # Lo mass Hi mass Time 1 33. 510 3OO. 590 2. 000 BL: Calibration table: D:CAL021992 Interface number Instrument type Full scale mass Zero scale mass Intensitg/ion Peak width Offset at low mass Offset at high mass Voltage settling time(ms) 20 0 Q 1177 1 2 1000. 0 0 u u mmu mmu mmu TUT OO4 1668 U O O O ] Current instrument parameters. Positive ion mode 0233 Resolution (high) Resolution (low) Quad offset Quad programming Lens offset Lens programming Ext offset Ext programming Collector Ion offset Ion programming Rod polari ty 128. 00 128. 00 0. 00 0. 00 -50. 00 O OO O. 0 30 7, 5 00 00 00 00 00 Negative ion mode 12B. 00 128. 00 0. 00 0. 00 50. 00 0. 0. 0. 30. -3. -5. Reverse Electron multiplier voltage Filament emission current Electrometer range Electrometer zero 00 00 00 00 00 00 Normal 984. 750. 10 A-7 126. 0 Analyzer Fore Pressure ... S*parator/Source Pressure 0. 009 Torr 0 381 Torr 3/16/93 18:57:03 ACQUISITION COMPLETED Scans 1 to 720 Centroid ./ode Centro id Scans Sees Out of X Peaks per scan 720 0. 7 1440. 0 0. 1 9877. 14. per sec 7. TUT OO4 1669 DIAGNOSTIC REPORT PROCEDURE: TCA DATA FILE: WI0316B REFERENCE: VI11 NAME LIST: VI INITIALIZATION OPTION: REPORT: VI IS 3/17/93 8:46:4: PROCESSING OPTION: 3 0234 PROC USED POSS 3 3 3 2 3 3 1 1 1 RMS PROC 0 23 23 45 COMPOUNDS PROCESSED. : COMPOUND >< T^O 1 2 3 4 5 6 7 89 10 11 12 13 14 13 16 17 16 19 20 21 22 23 24 23 26 27 28 29 30 31 32 33 34 33 36 37 38 39 40 41 42 43 44 43 LIB VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI ENTRY 1 2 3 4 5 6 7 8 9 10 11 12 13 14 13 16 17 18 19 20 21 22 23 24 23 26 27 28 29 30 31 32 33 34 33 36 37 38 39 40 41 42 43 44 43 ^ REF -17O -361 -3O4 -427 -34 -39 -36 -41 -66 -36 -106 -277 -329 -113 -39 -33 -84 -73 -118 -144 -123 -133 -228 -203 -261 -186 -329 -3O8 -142 -299 -332 -4O7 -314 -438 -281 -363 -372 -400 -379 -399 -104 -482 -487 -303 -344 PRED 184 373 515 440 41 46 43 48 73 63 114 288 340 121 66 62 92 80 126 153 138 146 240 215 273 198 341 320 133 311 344 419 326 431 293 373 385 413 392 412 115 493 300 518 338 20 16 15 .ua uw USED 17 16 14 ".NUWNQ POSS 4 1 72 ——— .J-^ - LI RMS STAND, 191 V1IS/1 165 VI IS/' 130 VI IS/1 40 FOUND 9wr SEL 184 373 . 440 40 45 41 47 73 . 289 341 123 66 61 92 79 128 135 143 242 218 274 201 342 321 153 311 344 420 323 432 293 373 384 413 391 412 113 496 301 319 ^n ^*n DELTA -1 -1 -2 •• * 1 1 2 -1 -1 2 -3 -3 2 3 1 3 1 1 -2 1 -1 1 -1 -1 -2 1 1 1 PEAKS 1 1 1 1 1 2 1 1 1 1 1 1 2 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 2 1 1 2 1 2 3 3 ——— >< SAT FIT PEAKS 978 972 942 847 840 867 828 976 872 836 948 941 958 933 962 959 981 932 926 972 941 949 926 961 951 865 932 802 952 902 975 980 988 937 988 933 933 983 992 994 X ————— CHRO —————— M/Z TOP DELTA PEAKS 114 184 . 1 117 373 . 1 130 95 440 50 40 94 45 62 41 64 47 84 73 43 63 43 115 43 289 43 341 128 122 -1 76 66 96 61 63 92 96 79 83 128 62 155 97 135 117 143 83 242 63 218 75 274 95 201 129 342 97 321 78 153 75 311 107 344 173 420 166 325 83 452 91 293 112 375 91 384 104 413 106 391 106 412 96 113 146 496 146 501 146 520 1 75 TUT CO CM O DATA FROM FILE: WI0316C SCANS 45 TO 729 ACQUIRED: 03/16/93 17:57:09 CALI: WI0316C #3 SAMPLE: CLP;, ,USTD885,LOW, WATERS 19316C,VOA, IC-005, COHDS.: I500A:25ML OLU01 AMBIENT PURGE M/ 5PPB IS r- 100 _ 3:20 200 J 6:40 300 J 10:00 400 J 13:20 500 _ 16:40 600 J 20:00 708 _ _L CI10 1,4-DIFLUOROBENZENE (IS#1) 20 CHLOROBENZENE-D5 <IS#2) USTWFBROMOFLUOROBENZENE (SS) J 100.0Z < 37760.) \ duantltation Report File: WIO316C 0236 Data: WI0316C TI 03/16/93 17: 57: 00 Sample: CLP, ,,VSTD003,LOW, WATER, WI0316C, VOA, IC-005, :onds.: I500A:25ML OLV01 AMBIENT PURGE W/ 5PPB IS "Formula: 25ML AMBIENT PURGE Instrument: I500A Submitted by: Analyst: RJL AHOUNT=AREA * REF AMNT/(REF AREA * RESP FACT) fac. from Library Entry 1, 4-DIFLUORODENZENE (IS#1) CHLOROBENZENE-D5 (IS#2) 1,4-DICHLOROBENZENE-D4 <IS#3) 4-BROMOFLUOROBENZENE (SS) CHLOROMETHANE ** BROMCMETHANE VINYL CHLORIDE * CHLOROETHANE METHYLENE CHLORIDE ACETONE 2-BUTANONE 4-METHYL-2-PENTANONE 2-HEXANONE BROMOCHLOROMETHANE CARBON DISULFIDE 1, 1-DICHLOROETHENE * 1, 1-DICHLOROETHANE ** TRANS-1,2-DICHLOROETHENE CHLOROFORM * 1,2-DICHLOROETHANE 1,1,1-TRICHLOROETHANE CARBON TETRACHLORIDE BROMODICHLOROMETHANE 1,2-DICHLOROPROPANE * CIS-1,3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE BENZENE TRANS-1,3-DICHLOROPROPENE DIBROMOETHANE BROMOFORM ** TETRACHLOROETHENE 1, 1,2, 2-TETRACHLOROETHANE ** TOLUENE » CHLOROBENZENE ETHYL BENZENE * STYRENE M/P XYLENE 0-XYLENE CIS-1,2-DICHLOROETHENE 1,3-DICHLORODENZENE 1, 4-DICHLORODENZENE 1,2-DICHLOROBENZENE 1,2-DIBROMO-3-CHLOROPROPANE Weight: Acct. No. 0. 000 No 1 23 4 5 6 7 S 9 10 11 12 13 14 15 16 17 IS ^19 20 21 22 =>3 24 25 26 27 28 29 30 31 32 33 34 35 36 37 39 39 40 41 42 '•3 ^-44 45 NafTje CI10 CI20 CI26 CS10 CO10 C015 C020 C025 C030 C035 C110 C20? C210 C037 C040 C045 C050 C053 C060 C065 C115 C120 C130 C140 C143 C150 C155 C16O C165 C172 C176 C180 C220 C?25 C230 C235 C240 C245 C250 C252 C054 C252 C253 C254 C261 TUT 004 167: Mo 1 2 34 5 ' 6 7 8 9 JO 1 1 12 13 14 15 16 i T i / 23 I? 20 21 22 23 24 25 26 27 28 29 ^0 Jl 32 33 34 35 36 37 39 39 40 -1 42 43 44 •*? r.'o i 2 3 4 5 6 7 3 .9 m/2 114 117 ISO 93 50 94 62 6'! 81 43 43 43 43 128 76 96 63 96 S3 62 97 117 B3 63 75 95 129 97 78 75 107 173 166 S3 91 112 91 104 106 106 96 146 146 146 75 RetCL 6 10 12 26 17 16 14 38 1 20 1 30 1 22 1 34 2 26 Scan 185 373 518 439 40 45 41 47 73 63 116 289 341 123 66 61 92 80 128 156 136 144 242 219 274 202 341 321 154 311 344 420 325 451 293 374 384 413 391 412 113 496 501 519 561 Tim* 6: 10 12:26 17: 16 14:38 1. 20 1: 30 1: 22 1: 34 2: 26 2: O6 3: 52 9: 38 11: 22 4: 06 2: 12 2: 02 3: 04 2: 40 4: 16 5: 12 4: 32 4: 48 B: 04 7: 18 9: 08 6: 44 11: 22 10: 42 5: 08 10: 22 11: 28 14: 00 10: 50 15: OP 9: 46 12: 28 12: 43 13: 46 13: O2 13: 44 3: 46 16: 32 16: 42 17: 18 18: 42 ) Ratio RRT<L 1. 00 1. 00 1. 00 1. 00 1. OO 1. 00 1 00 1. 00 1. 00 1. OOO 1. 000 1. 000 2. 373 0. 216 0. 243 0. 222 0. 254 0. 395 R»f 1 2 3 1 1 1 1 1 1 1 1 2 2 1 1 1 1 1 1 1 2 2 2 2 22 22 2 2 2 3 2 2 2 2 2 2 2 2 1 3 3 3 3 RRT 1. 000 1. 000 1. OOO 2. 373 0. 216 0. 243 0. 222 0. 254 0. 395 0. 341 0. 627 0. 775 0. 914 0. 665 0. 357 0. 330 0. 497 0. 432 0. 692 0. 843 0. 365 0. 386 0. 649 0. 587 0. 735 0. 542 0. 914 0. 861 0. 413 0. 834 0 922 0. 811 0. 871 1. 209 0. 786 1. 003 1. 029 1 107 1. 048 1. 105 0. 611 0. 958 0. 967 1. 002 1. 083 ) Ratio 1. 1. 1 1 1. 1. 1. 1. 1. 00 00 00 00 00 00 00 00 00 M»th A DB A BV A BB A BV A DB A BB A BB A VB A BB A BO A BB A BB A BB A BB A BB A BB A BB A BV A BV A BB A BB A VB A OB A BB A BB A DB A VB A BB A BB A BD A BV A BB A BB A BB A BD A BD A BV A BD A VB A BB A DD A BV A VB A BB A BB Amnt 5. 00 5. OO 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 5. 00 Ar«a<Hgh 11075. 7769. 5599. 7727. 10017. 5688. 7706. 4082. 4254. 908. 1809. 3955. 2679. 1489. 16729. 5484. 10246. 5892. 10319. 3539. 11399. 10603. 6164. 4103. 4454. 7094. 3878. 2244. 11899. 2876. 2541. 1363. 9451. 2317. 13614. 9554. 17450. 7559. 13112. 4978. 4338. 7338. 7369. 5400. 529. Amnt(L) 5. OO 5. OO 5. 00 5. 00 5. 00 5. 00 5. 00 5 00 5. 00 t) Amount 5. 000 5. 000 5. 000 5. 000 5. 000 5. 000 5. 000 5. 000 5. 000 25. 000 25. 000 25. 000 25. 000 5. 000 5. 000 5. 000 5. 000 5. 000 5. 000 5. 000 5. 000 5. 000 5. 000 5. 000 5. 000 5. 000 5. 000 5. 000 5. 000 5. 000 5. 000 5. 000 5. 000 5. 000 5. 000 5. 000 5. 000 5. 000 10. OOO 5. 000 5. 000 5. 000 3. 000 3. 000 5. 000 7.Totu UG/L UG/L UG/L UO/L UG/L UC/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UC/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UC/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UC/L UG/L UG/L UG/L R. Fac R. Fac(L) 1. 000 1. 000 1. 000 0. 698 0. 904 0. 314 0. 696 0. 369 0. 384 1. 000 1. 000 1. 000 0. 698 0. 904 0. 314 0. 696 0. 369 0. 384 1. 1. 1. 1. 1. 1. 1. 1. 1. 8. 8. 8. 8. 1. 1. 1. 1. 1 1. 1 1. 1. 1. 1. 1 1 1 1 1 1 1 1 1 1 1 1 1 1 3 1 1 1 1 1 1 Rat 1 1 1 1 1 1 1 1 1 61 61 61 61 61 61 61 61 61 06 06 06 06 61 61 61 61 61 61 61 61 61 61 61 61 61 61 61 61 61 61 61 61 61 61 61 61 61 23 61 61 . 61 . 61 . 61 . 61 i o . 00 . 00 00 00 . 00 00 . 00 . 00 00 .0237 -o -No 10 11 12 13 14 15 16 17 IS 19 20 21 22 23 24 23 26 27 28 2* 30 31 32 33 34 33 36 37 38 39 40 41 42 43 44 45 R*t(L) 2:06 3: 52 9: 38 11:22 4: 06 2: 12 2: 02 3. O4 2: 40 4 16 3: 12 4 32 4: 48 8: 04 7: 18 9 08 6: 44 11: 22 10: 42 5: 08 10: 22 11: 28 14: 00 10: 50 15: O2 9: 46 12: 28 12. 48 13: 46 13: 02 13: 44 3: 46 16 32 16: 42 17: 18 18: 42 Ratio 1. 00 1. 00 1. OO 1. 00 1. 00 1. 00 1. OO 1. OO 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. OO 1. 00 1. 00 1. 00 1. 00 1. OO 1 OO 1. 00 1. 00 1. OO 1. OO 1. OO 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 RRT(L> 0. 341 0. 627 0. 773 0. 914 0. 665 0. 337 0. 330 0. 497 0. 432 0. 692 0. 843 0. 365 0. 386 0. 649 0. 587 0. 735 0. 342 0. 914 0. 861 0. 413 0. 834 0. 922 0. 811 0. 871 1. 209 0. 786 1. 003 1. O29 1. 107 1. 048 1. 105 0. 611 0. 958 0. 967 1. 002 1. 083 Ratio 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. OO 00 00 OO 00 OO 00 00 00 00 OO 00 00 00 00 00 00 00 OO 00 00 00 00 00 00 00 OO OO 00 00 00 00 00 00 00 00 Amnt 23. 23. 23. 23. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 3. 3. 5. 5. 1O. 5. 5. 5. 5. 3. 5. 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 OO OO 00 OO 00 00 00 OO 00 00 Amnt ( 25. 25. 25. 23. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 10. 5. 5. 5. 5. 5. 5. L) 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 OO 00 00 00 00 00 00 R. Fac R. 0. 016 0. 033 0. 102 0. 069 0. 134 1. 311 0. 493 0. 923 0. 332 0. 932 0. 320 1. 467 1. 365 0. 793 0. 528 0. 573 0. 913 0. 499 0. 289 1. 532 0. 370 0. 327 0. 243 1. 216 0. 298 1. 732 1. 230 2. 246 0. 973 0. 844 0. 641 0. 392 1. 311 1. 316 0. 964 0. 094 Fac<L) Ratio v 0. 0. 0. 0. 0. 1. 0. 0. 0. 0. 0. 1. 1. 0. 0. 0. 0. 0. 0. 1. 0. 0. 0. 1. 0. 1. 1. 2. 0. 0. 0. 0. 1. 1. 0. 0. 016 033 102 069 134 311 493 923 332 932 320 467 365 793 528 573 913 499 289 532 370 327 243 216 298 752 230 246 973 844 641 392 311 316 964 094 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 0238 TUT 004 1674 I-000167G 3/16/93 17:57:24 Acquisition started 0239 3/16/93 17:57:27 xcquire Run 0: WI0316C ^03/16/93 17:57:00 + 0:00 Free sectors: 14769 Sample: CLP, ,, VSTD005, LOW, WATER, WI0316C, VOA, IC-005, Conds.: I500A:25ML OLV01 AMBIENT PURGE W/ 5PPB IS F^mula: 25ML AMBIENT PURGE Instrument: I5OOA submitted by: Analyst: RJL Starting Scan: 0 of Weight: Acct. No: 720 0. OOO GC Desc : VI Ssq. Temp * (DegC) 1 35- 35 2 35-150 3 150-150 Valve A : closed #»* GC not ready and being Rate Time (minutes) (C/min) period 6. 6 8. 0 14. 3 3. 0 Valve B : *** Instrument Post acquis i t ion El <+) Centroid equilibrated *»» Elapsed time : 0. O Min total 6. 6 20. 9 23. 9 open parameters Injector A : 150 GC oven : 108 Transfer-line: 216 Ion source : 184 Deg Deg Deg Deg C c C c #** state -> Filament : Off Multiplier : Temp - Sequence: BF ( 2 time windows. ) Off Sequence Window # 1 Scan descriptor: Total scan time: Number of cycles: 28 Filament is OFF Multiplier is ON BF Mass intervals: 2. 000 s Positive ion mode. Master rate: 16 Int 1 MFW: 80 Lo mass 33. 510 MA: 15 Hi mass 300. 590 TH: 1 Time !. 000 DL: Sequence Window # 2 5; an d e scr i p tor: "otal scan time: Number of cycles: Filament is ON Multiplier is ON BF Mass intervals: 2. 000 s Positive ion mode Master rate: 16 •PW: 3 MFW: 80 MA: 15 TH: 1 Int # Lo mass Hi mass Time 1 33. 510 300. 590 2. 000 DL: Calibration table: Interface number Instrument type Full scale mass Zero scale mass Intensi ty/i on Peak width Offset at low mass Offset at high mass Voltage settling time(ms) D:CAL021992 0 Q 1177 1 2 1000. 0 0 u u mmu mmu mmu 000167u TUT OO4 1675 Current instrument parameters. Positive ion mode 0240 Resolution (high) Resolution (low) Quad offset Quad programming Lens offset Lens programming Ext offset Ext programming Col lector Ion offset Ion programming Rod polar i ty 128. 128. 0. 0. -50. 0. 0. 0. 30. 7. 5. 00 00 00 00 00 00 00 00 00 00 00 Negative ion 128. 00 128. 00 0. 00 0. 00 50 0 0 0 30 -3 -5 Reverse Electron multiplier voltage: Filament emission current: Electrometer range: Electrometer zero: mode 00 00 00 00 00 00 00 Normal 984. 750. 10 ~-7 126. 0 Analyzer Fore Pressure ... Separator/Source Pressure 0. 010 Torr 0. 381 Torr 3/16/93 18:27:00 ACQUISITION COMPLETED Scans 1 to 720 Centroid entro id Scans 720 Sees 0. 9 Out of 1440. 0 O. 1 Peaks per 15129. scan 21. per sec 11. TUT OO4 1676 U000167V DIAGNOSTIC REPORT PROCEDURE: TCA DATA FILE: WIO316C REFERENCE: VI11 NAME LIST: VI INITIALIZATION OPTION: 2 REPORT: VI IS 3/17/93 8:39: 0241 PROCESSING OPTION: 3 ; ——— STANDARDS - =ROC USED POSS 3 2 1 3 3 1 3 3 1 -—— >< —— PLUS UNKNOWNS —— >< - LIST NAMES - > RMS PROC USED POSS RMS STANDARD/UNKNOWN 0 20 17 8 229 V1IS/V1UNKS1 11 16 16 2 161 V1IS/V1UNKS2 11 13 15 36 183 V1IS/V1UNKS3 45 COMPOUNDS PROCESSED, 41 FOUND Canruv IM^J *" ?JO LID ENTRY 1 2 3 4 3 6 7 89 10 11 12 13 14 13 16 17 IB 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 4O H *2 43 44 43 VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 REF -170 -361 -504 -427 -34 -39 -36 -41 -66 -36 -106 -277 -329 -113 -59 -55 -84 -73 -118 -144 -125 -133 -228 -203 -261 -186 -329 -308 -142 -299 -332 -4O7 -314 -438 -281 -363 -372 -400 -379 -399 -104 -482 -487 -505 -344 PRED 185 373 514 440 41 46 43 48 74 64 114 288 340 121 67 62 92 81 126 153 138 146 241 216 274 199 341 320 133 311 344 419 326 451 293 376 385 413 392 412 115 493 500 519 338 — t»t«K'LH —— — SEL DELTA PEAKS 185 373 439 40 45 41 47 73 . 289 341 66 61 92 80 128 156 136 144 242 218 274 202 341 321 134 311 344 420 323 451 293 374 384 413 391 412 113 496 501 519 361 -1 -1 -1 -2 -1 -1 1 1 -1 -1 -1 2 3 -2 -2 1 2 3 1 -1 1 -1 -2 -1 -1 -2 1 1 3 1 1 1 1 1 2 1 2 1 1 1 2 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 2 1 1 1 2 1 1 1 1 2 3 3 1 a« i .-"s. — —— FIT PEAKS M/Z 977 970 959 871 921 917 928 981 876 933 980 963 966 982 974 865 990 937 977 992 963 967 960 974 962 920 984 898 936 940 978 984 990 967 990 915 939 980 997 978 806 114 117 150 95 50 94 62 64 84 43 43 43 43 128 76 96 63 96 83 62 97 117 83 63 75 95 129 97 78 75 107 173 166 83 91 112 91 104 106 106 96 146 146 146 73 • —— 1,1-IKU ———— ——— TOP DELTA PEAKS 185 373 439 40 45 41 47 73 63 116 289 341 123 66 61 92 80 128 156 136 144 242 219 1 274 202 341 321 154 311 344 420 325 451 293 374 384 413 391 412 113 496 501 519 561 UOOOlOTu 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 TUT OO4 1677 DATA FROM FILE: W103160 SCANS 45 TO 720 ACQUIRED: 63/16/93 17:27:06 CALI: WI8316D #3 SAMPLE: CLP,,,VSTDCH0,LOW,WATER,WI0316D,UOA,IC-810, COHDS.: I500A:25ML OLU01 AMBIENT PURGE W/ 5PPB IS CO N -0 100 J 3:20 200 J 6:40 309 _j 10:00 400 . 13:20 500 _ 16:40 I CI10 1,4-DIFLUOROBENZENE (IS#1) CHLOROBEHZENE-D5 (ISf2) FLUOROBEHZENE <SS) O) r~ CO J 100.0Z < 66048.) I-D h- 600 20:00 700 Cata: WIO316D. TI 03/16/93 17:27:00 e: CLP, , , VSTDOIO,LOW,WATER,WI0316D, VOA, IC-010, . : I500A:23ML OLV01 AMBIENT PURGE W/ 5PPB IS rrmula: 25ML AMBIENT PURGE Instrument: I500A "Submitted by: Analyst: RJL -•'QUNT=AREA * REF AMNT/(REF AREA * RESP FACT) t'*-ip. fac. from Library Entry 1,4-DIFLUORODENZENE <IS#1) CHLOROBENZENE-D5 <IS#2) 1, 4-DICHLOROBENZENE-D4 ( IS*»3) 4-BROMOFLUORODENZENE <SS) CHLOROMETHANE ** BROMOMETHANE VINYL CHLORIDE * CHLOROETHANE METHYLENE CHLORIDE ACETONE 2-BUTANONE 4-METHYL-2-PENTANONE 2-HEXANONE BROMOCHLOROMETHANE CARBON DISULFIDE I.1-DICHLOROETHENE * 1.1-DICHLOROETHANE *» TRANS-1,2-DICHLOROETHENE CHLOROFORM » 1.2-DICHLOROETHANE 1,1,1-TRICHLOROETHANE CARBON TETRACHLORIDE BROMODICHLOROMETHANE 1.2-DICHLOROPROPANE * CIS-1, 3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE BENZENE TRANS-1,3-DICHLOROPROPENE DI3ROMOETHANE BROMOFORM ** TETRACHLOROETHENE 1, 1, 2, 2-TETRACHLOROETHANE ** TOLUENE * CHLOROBENZENE ETHYL BENZENE * STYRENE M/P XYLENE 0-XYLENE CIS-1,2-DICHLOROETHENE 1.3-DICHLOR03ENZENE 1.4-DICHLOROBENZENE li2-DICHLOROBENZENE 1, 2-DIBROMO-3-CHLOROPROPANIE 0243 Weight: Acct. No. 0. 000 NO 1 e.' 3 4 5 A -T 3 •J 10 I 1 12 13 11 15 16 17 IS 19 20 21 22 23 24 25 2* 27 23 29 20 21 32 33 34 35 36 37 38 39 40 41 42 43 44 >5 Na.T.e CI10 CI2O CI26 CS10 C010 C015 CO 2O C025 C030 C035 C110 C205 C210 C037 C040 C015 C05O CO 53 C060 C065 C115 C12O C130 C140 C143 C150 C135 C160 C165 C172 C176 C180 C220 C225 C230 C235 C24O C245 C250 C25? C054 C2S2 C253 C254 C261 TUT OO4 1679 L ;.!o m/z Scan A2 3 4 5 67 ••3 •-' ' 0! — ic. 3 •I- 5 i ^ 3 ? 10 21 £2 £3 24 25 ~'i 27 23 29 _<G 31 Z2 23 -•4 25 36 -^ •» ^ i I- 5 29 -C' 41 -2 •*3 •*4 •»* "iC -. 'J! 3 4 5 6 7 8 9 114 117 150 95 50 94 62 64 8<5 43 43 43 43 12^ 76 96 63 96 S3 62 97 117 83 63 75 95 129 9"7 78 75 107 173 166 S3 91 1 12 91 104 106 106 96 146 1^6 146 75 R e t < L > 6: 10 12: 28 17 18 14 40 1 18 1: 30 1 : 22 1: 34 2: 26 185 374 519 440 39 45 41 47 73 63 116 290 342 123 66 61 92 80 128 156 136 144 242 219 274 202 342 321 154 312 345 420 326 452 293 375 384 414 391 412 113 496 502 520 561 Rati 1 00 1 00 1. 00 1. 00 1. 00 1 00 1. 00 1. 00 1. 00 Tim» 6: 10 12:28 17: 18 14: 40 1: 18 1: 30 1: 22 1: 34 2: 26 2: 06 3: 52 9: 4O 11: 24 4: 06 2: 12 2: 02 3: 04 2: 40 4: 16 5: 12 4: 32 4: 48 8: 04 7: 18 9: 08 6: 44 11: 24 10: 42 5: 08 10: 24 11: 30 14:00 10: 52 15: O4 9: 46 12: 30 12: 48 13: 48 13. O2 13: 44 3: 46 16: 32 16: 44 17: 20 18: 42 0 RRT(L 1. 000 1. 000 1 000 2. 378 0. 211 0. 243 0. 222 O. 254 0. 395 Ref 1 2 3 1 1 1 1 1 1 1 1 2 2 1 1 1 1 1 1 1 2 2 2 2 2 2 2 2 2 2 2 3 2 2 2 2 2 2 2 2 1 3 3 3 3 RRT 1. 000 1. 000 1. OOO 2. 378 0. 211 0. 243 0. 222 0. 254 0. 395 0 341 0. 627 0. 775 0. 914 0. 665 0 357 0. 330 0 497 0. 432 0. 692 0. 843 0. 364 0. 385 0 647 0. 586 0. 733 0. 540 O. 914 0. 858 0. 412 0 834 0. 922 0. 809 0. 872 1 209 0. 783 1 003 1. 027 1 107 1. 045 1. 102 0. 611 0. 956 0. 967 1 002 1. 081 ) Ratio 1. 1. 1. 1. 1. 1. 1. 1. 1 00 OO 00 00 00 00 00 OO 00 Meth A BO A BV A BB A BV A BV A BV A BO A VB A BB A BV A BD A BB A BB A BB A BB A BB A BB A BB A BV A BB A BB A VB A BB A BB A BB A BB A VB A OB A BB A DV A BV A BB A BB A BB A BB A BB A BV A DD A VB A DD A BB A BV A VB A BB A BO Amnt 5. 00 5. OO 5. 00 10. 00 10. 00 10. 00 10. 00 10. 00 10 00 Ar»a(Hght) Amount 11105. 7722. 6154. 14847. 21183. 10961. 14360. 7814. 7010. 1712. 2925. 7695. 4615. 2773. 34236. 10739. 20332. 9937. 20103. 6776. 23692. 22551. 12812. 8258. 8781. 14121. 7067. 3805. 24099. 5524. 5300. 3304. 17263. 4920. 27087. 18218. 35106. 15330. 25887. 10168. 7739. 14452. 14386. 10230. 1058. ArnnUL) 5. 00 5 00 5 00 10. 00 10. 00 10. 00 10. 00 10 00 10. 00 5. 000 5. 000 5. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 50. 000 50. 000 50. 000 50. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. OOO 10. 000 10. 000 10. 000 10. 000 10. OOO 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 10. 000 2O. OOO 10. 000 10. 000 10. OOO 10. 000 10. 000 10. 000 UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L R. Fac R. Fac (L) 1. 000 1. 000 1. 000 0. 668 0. 954 0. 494 0. 647 0. 352 0. 316 1. 000 1. 000 1. 000 0. 668 0. 954 0. 494 0. 647 0. 352 0. 316 '/.Tot 0 0 0 1 1. 1. 1. 1. 1. 8 8 8 8 1 1 1 1 1 1 1 1 1. 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 3 1 1 1 1 1 1 Rat 1 1 1 1 1 1 1 1 1 83 83 83 65 65 65 65 65 65 26 26 26 26 65 65 65 65 65 65 65 65 65 65 65 65 65 65 65 65 65 65 65 65 65 65 65 65 65 31 65 65 65 65 65 65 I 0 00 00 00 00 00 00 00 00 00 '_' 00 1- L0001C8; J-- 4- 4> to 4. i- i.j l.J U U f <:• -o a) --j o- rj i.i ij *• u PJ :/. fi |tj rj o *» uj -i P i l«J P i m *• u o -o o- en •*• w o o" O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O r t - O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O * "o •^ — O O O ' - ' - ^ t - i - . o ^ O O O O O O O O O O O O O O O O O O O O O O O O a ) . . . . . . . . . . . . . oooooooooooooooooooooooooooooooooooo** O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O * 'o p p p p p o o p p p p p p o p p p o p p p o p o o p p p o o o o o p p p > O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O 3 O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O r t - O p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p r t - oooooooooooooooooooooooooooooooooooor oooooooooooooooooooooooooooooooooooo^- H C 3J •n II»n r C1 o O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O oooooooooooooooooooooooooooooooooooo en 00 r ' 03 H- £ C 3/16/93 17: 27: 10 Acquisition started 0246 3/16/93 17: 27: 13 •cquire Run 0: WI0316D -03/16/93 17:27:00 + 0:00 Free sectors: 14956 Samp 1 e: CLP, , . VSTD010, LOW, WATER, WI0316D, VOA, IC-010, londs.: I500A:25ML OLV01 AMBIENT PURGE W/ 5PPB IS formula: 25ML AMBIENT PURGE Instrument: I500A Submitted by: Analyst: RJL Starting Scan: 0 of 720 Weight: 0. 000 Acct. No: •»•»•» GC not ready and being 3C De Seq. 1 2 3 1 Valve sc : VI Temp (DegC) 35- 35 35-15O 5O-150 A : c1osed Rate < C/min) Time (minutes) equilibrated *** Elapsed time : 0. O Min Post p er i od 6. 6 8. O 14. 3 3. 0 Valve B : *** Instrument acquisition state -> total 6. 6 20. 9 23. 9 open parameters Fi lament Injector A GC oven Transfer-1ine Ion source 150 109 216 1S4 Deg Deg Deg Deg C C C C El <+) Centroid + Temp - Sequence: BF *•»* Off Multiplier ( 2 time windows. Off Sequence Window * 1 Scan descriptor: Total scan time: Number of cycles: Filament is OFF Multiplier is ON BF Mass intervals: 2. 000 s 28 Positive ion mode. Master rate: 16 PW. 3 MFW: 80 MA: 15 Int # Lo mass Hi mass 1 33. 510 300. 590 TH 1 Time 2. 000 BL: Sequence Window # 2 £: a n descriptor: "otal scan time: Number of cycles: Filament is ON Multiplier is ON BF Mass intervals: 2. 000 s Positive ion mode. Master rate: 16 :PU: 3 MFW: 80 MA: 15 TH: 1 Int # Lo mass Hi mass Time 1 33. 510 300. 590 2. 000 BL: Calibration table: D: CAL02199I Interface number Instrument type Full scale mass Zero scale mass Intensity/ion Peak width Offset at low mass Offset at high mass Voltage settling time(ms) 20 0 Q 1177 1 2 1000. 0 0 u u mmu mmu mmu L OOOJ.G8 TUT 004 1682 Cur-rent instrument parameters. Positive ion 0247 Resolution (high) Reso lution (low) Quad offset Quad programming Lens offset Lens programming Ext offset Ext programming Collector Ion offset Ion programming Rod polarity 128. 128. 0. 0. -50. 0. 0. 0. 30. 7. 5. 00 00 00 00 00 00 00 00 00 00 00 mode Negative ion 128. 00 128.00 0. 00 0. 00 50 0 0 0 30 -3 -5 Reverse Electron multiplier voltage: Filament emission current: Electrometer range: Electrometer zero: mode 00 00 00 OO 00 00 00 Norma1 984. 750. 10 -x-7 126. 0 «nalyzer Fore Pressure Separator/Source Pressure 0 009 Torr 0. 368 Torr 3/16/93 17:56:57 ACQUISITION COMPLETED Scans 1 to 720 Centroid r-'ode "entroid Scans 720 Sees 1. 1 Out of 1440. 0 '/. Peaks per scan 0 1 18934. 26. per sec 13. TUT 004 1683 L0001684 DATA FILF REFERENCE N'^ME LISt REPORT • _ — _ CT w 1 -ROC <J2 3 3 3 45 CO.1' : COMPOU 10 1 2 3 4 5 6 7 89 10 1 1 12 1 -i 14 1? 16 17 '18 19 20 21 22 -^.-» i.O 24 25 26 '•.-? ^_ / 23 29 30 31 32 33 34 35 36 37 38 3? 4O 41 *2 -43 44 43 ': UIIO !: Vll : VI : VII ANDAR iED P 2 3 3 IPOUND IND > LIB ENTRY VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI 1 2 3 4 5 6 7 89 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 3 160 1 INITIALIZA1 S DS ———— >< - OSS RMS F 1 0 1 23 1 23 S PROCESSED, •C ———— — — — — — — — REF -170 -361 -504 -427 -34 -39 -36 -41 -66 -56 -106 -277 -329 -113 -59 -55 -84 -73 -118 -144 -125 -133 -228 -203 -261 -186 -329 -308 -142 -299 -332 -407 -314 -438 -281 -363 -372 -400 -379 -399 -104 -482 -487 -505 -544 PRED 185 374 516 441 42 47 44 49 74 64 115 288 341 122 67 63 92 81 127 153 138 146 241 216 274 199 342 321 155 312 345 420 327 452 293 376 385 413 392 412 115 496 501 519 559 •ION OPTION: c • — PLUS UNKNC 'ROC USED PC 20 18 16 16 15 15 42 FOUND -— SEAR'"1-1 — — ^WbH* ll \w r i > PR )WNS - )SS 24 1 72 SEL DELTA PEAKS 185 374 440 39 45 46 47 73 290 342 123 66 61 92 80 128 156 136 144 242 219 274 202 342 321 154 312 345 420 326 452 293 375 384 413 392 412 113 497 502 520 561 -1 -3 -2 2 -2 -1 2 1 1 -1 -2 -1 1 3 -2 -2 1 3 3 -1 -1 -1 -1 -2 1 1 1 2 1 1 1 1 1 2 1 2 3 1 1 1 2 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 2 1 1 2 1 2 3 3 1 10CESSING —— >< - L RMS STAN 217 V1IS 154 VI IS 157 V1IS - - X SA OPTION: 3 1ST NAMES - > IDARD/UNKNOWN i/VlUNKSl :/VlUNKS2 i/V!UNKS3 ,T %<; ——— —— ruor FIT PEAKS M/Z 979 918 953 880 958 909 963 986 885 964 967 992 966 971 984 986 869 986 962 990 997 972 971 972 985 970 961 994 951 953 960 985 990 992 947 987 960 940 980 994 983 917 114 117 150 95 50 94 62 64 84 43 43 43 43 128 76 96 63 96 83 62 97 117 83 63 75 95 129 97 78 75 107 173 166 83 91 112 91 104 106 106 96 146 146 146 75 0248 3 —————— TOP DELTA PEAKS 185 374 440 39 45 47 73 63 116 290 342 123 66 61 92 80 128 156 136 144 242 219 274 202 342 321 154 312 345 420 326 452 293 375 384 414 391 412 1 13 496 502 520 561 n 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 l 1 i 1 1 1 1 t 1 I ^i L 1 1 1 -1 I '. - 1 '. ; A A 1 C O ~ ' TUT OO4 1684 C5 ^3« CM O DATA FROM FILE: WI0316E SCANS 45 TO 728 ACQUIRED: 03/16/93 17:01:89 CALI: WI0316E #3 SAMPLE: CP,,,USTD025,LOW-WATER,W18316E,UOA,IC-025, COHDS.: I5G0A:25ML OLU01 AMBIENT PURGE W/ 5PPB IS in CO 180 J 3:20 209 J 6:48 300 J 10:00 400 _ 13:20 500 J 16:40 600 _ 20:00 700 , _L J 100.07. ( 161289.) ' -3 oo CD _J CI10 1,4-DIFLUOROBENZEHE IOFLUOROBEHZENE (SS) 3/17/93 12:53:08 Acquisition started 0321 3/17/93 cqu ire b/17/93 12: 53: 00 •'ample: CLP, 53554 12:53:14 Run 0: VV7322 + 0:00 Free sectors: 13575 MW01,MW030RKS, LOW, WATER, VV7322, VOA, onds.: I500A:25ML OLV01 PURGE W/ 5PPB IS & SS rrmula: 25ML AMBIENT PURGE Instrument: I5OOA ;.-bmitted by: ITEK Analyst: RJL Starting Scan: 0 of MS, Weight: Acct. No: *** GC not ready and being equilibrated *** Desc VI Elapsed time *<l it 1 nt. 3 Teir.p ( D e g C ) 35-" 35 35-150 ISO- ISO Rate < C/min ) 8. 0 - closed #*-» Post acquisition Time (minutes) per i od 6. 6 14. 3 3. 0 Valve B : Instrument state -> total 6. 6 20. 9 23. 9 op en parameter Fi lament Injector A GC oven Transfer-1 i Ion source s »*# : Off Mul ne tit 720 0. OOO 53554 150 90 0. O Min Deg C Deg C Deg C 184 Deg C Off E: El Centroid •*• Temp - Sequence: BF ( 2 time windows. ) Window an descriptor: •tal scan time: Number of cycles: 28 Filament is OFF M u l t i p l i e r is ON DF Mass intervals. 1 2 000 s Positive ion mode. Master rate: 16 3 :-t * MFW: BO Lo mass 33. 510 MA: 15 Hi mass 300 590 TH: 1 Time 2. 000 DL: Window an descriptor: • t a 1 scan time: Number of cycles: Filament is ON Multiplier is ON BF Mass intervals: 2. 000 s Positive ion mode. Master rate: 16 :-;t # MFW: SO Lo mass 33. 510 MA: 15 Hi mass 3OO. 590 Calibration table: Interface number Instrument type Full scale mass Zero scale mass Intens i ty/ion Peak width Offset at low mass Offset at high mass Voltage settling time(ms) 20 TH: 1 DL: Time 2. 000 D:CAL021992 0 Q 1177 1 2 1000. 0 0 u u mmu mmu mmu TUT 004 1686 /_ 0001 T58 J v —,, w^. *.- . . . 0250 Data: WI0316E. TI 03/16/93 17:01:00 Sample: CP, , , VSTDO25. LOW, WATER, WI0316E, VOA, IC-025, Cond*. : I500A:2SML OLV01 AMBIENT PURGE W/ 5PPD IS *rrmula: 25ML AMBIENT PURGE Instrument: I5OOA Weight: 0 000 ^Submitted by: Analyst: RJL Acct. No. : ^OUNT=AREA * REF AMNT/(REF AREA * RESP FACT) R«»p. fac. from Library Entry No Name i CI10 1,4-DIFLUOROBENZENE (IS#1) •2 CI20 CHLOROBENZENE-D5 (IS#2) 3 CI26 1, 4-DICHLOROBENZENE-D4 (IS4*3) '! CS10 4-BROMOFLUOROBENZENE (SS) 5 C010 CHLOROMETHANE »* 6 CO15 3ROMOMETHANE ? C020 VINYL CHLORIDE * 9 C025 CHLOROETHANE * C030 METHYLENE CHLORIDE 10 C035 ACETONE 11 C110 2-BUTANONE 12 C205 4-METHYL-2-PENTANONE 13 C210 2-HEXANONE :4 C037 BRCMOCHLDROMETHANE 1? C040 CARBON DISULFIDE 16 C045 1,1-DICHLOROETHENE * 17 C050 1,1-DICHLOROETHANE ** !9 C053 TRANS-1/2-DICHLOROETHENE 19 C06O CHLOROFORM * 20 COS5 1,2-DICHLOROETHANE ^ "2.1 C115 1, 1, 1-TRI CHLOROETHANE L'2 C120 CARBON TETRACHLOR IDE 23 C130 BROMODICHLOROMETHANC 24 C140 1,2-DICHLOROPROPANE * i5 C143 CIS-1,3-DICHLOROPROPENE 26 C150 TRICHLOROETHENE 27 C155 DIBROMOCHLOROMETHANE 23 C160 1, 1> 2-TRICHLOROETHANE 29 C165 BENZENE 30 C172 TRANS-1, 3-DICHLOROPROPENE 31 C176 DIBRONOETHANE 32 C180 BROMOFORM ** 33 C220 TETRACHLOROETHENE 34 C225 1, 1, 2, 2-TETRACHLDROETHANE ** 35 C230 TOLUENE * 36 C235 CHLOROBENZENE 37 C240 ETHYL BENZENE » 38 C245 STYRENE 39 C250 M/P XYLENE 40 C252 0-XYLENE 41 C054 CIS-l, 2-DICHLOROETHENE *2 C252 1,3-DICHLOROBENZENE 43 C253 1,4-DICHLORODENZENE 44 C254 1,2-DICHLORODENZENE *5 C261 1,2-DIBROMO-3-CHLOROPROPANE _^ TUT OO4 1687 \'o m/i Scan Tim« I —i 3 45 6 f 3 •~ 1C- to \ 12 ^ ^i : 4 15 16 17 IS 2 9 20 21 L-2 13 1-4 Z-5 26 27 28 29 30 21 22 "O 24 35 i'6 37 28 39 »0 4-1 •*2 _ 3 •^4 45 '0 1 & 3 4 5 6 7 3 9 114 117 150 95 50 94 62 64 84 43 43 43 43 128 76 96 63 96 83 62 97 117 83 63 75 95 129 97 78 75 107 17:3 166 83 91 1 12 91 1C'-! 106 106 96 1 16 146 116 75 Ret<L) 6: O8 12: 26 17: 18 14: 40 1: 18 1: 28 1:20 1: 32 2:24 184 6:08 373 12: 26 519 17. 18 440 14:40 39 1:18 44 1 : 28 40 1 : 20 46 1 : 32 72 2: 24 63 2:06 115 3:50 289 9: 38 341 11:22 123 4:06 65 2: 10 61 2: 02 91 3:02 79 2: 38 128 4: 16 156 5: IP 135 4:30 143 4: 46 242 8: 04 218 7: 16 273 9: 06 201 6:42 341 11:22 321 10: 42 153 5:06 311 10:22 344 1 1 : 23 420 14:00 325 10: 50 452 15:04 293 9: 46 375 12: 3O 384 12: 48 413 13:46 391 13:0? 412 13:44 113 3:46 496 16: 32 501 16: 42 520 17: 20 561 18: 42 Ratio RRTtL 1 . 00 1 000 1 . 00 1 . 000 1 . 00 1 . 000 1. 00 2. 391 1. 00 0. 212 1.00 0.239 1.00 0.217 1. 00 0. 250 1.00 0.391 Ref 1 2 3 1 1 1 1 1 1 1 1 2 2 1 1 1 1 1 1 1 2 2 2 2 2 2 2 2 2 2 2 3 2 2 2 2 2 2 2 2 1 3 3 3 3 RRT 1. OOO 1. 000 1. 000 2. 391 0. 212 0. 239 0. 217 0. 250 0. 391 0. 342 0. 625 0. 775 0. 914 0 668 0 353 0. 332 0. 495 0. 429 0. 696 0 848 0. 362 0. 383 0. 649 0. 584 6. 732 0. 539 0. 914 0. 861 0. 410 0. 834 0. 922 0. 809 0. 871 1. 212 0 786 1. O05 1. 029 1. 107 1. 048 1 105 0 614 0. 956 O. 963 1. 002 1. 081 ) Ratio 1. 1. 1. 1. 1. 1. 1. 1. 1. 00 00 00 00 00 00 00 00 00 K.th A BB A BV A BB A BV A BV A BV A BB A VB A BB A BV A BV A BB A BB A BB A BB A BB A VB A BB A BV A BB A BB A VB A BB A BB A BB A BB A BB A BB A BB A BV A BB A BB A BB A BV A BB A BB A BV A BB A VB A BB A BB A BV A VB A BB A BV Amnt 5. 00 5. 00 5. 00 25. 00 25. 00 25. 00 25. 00 25. 00 25. 00 Arta(Hght) Amount 10318. 7097. 6840. 30238. 48632. 23287. 34840. 17459. 17068. 3647. 5902. 15564. 9714. 5651. 80O81. 24638. 45928. 22334. 72226. 14602. 55145. 51571. 33750. 18544. 20219. 31710. 14865. 7299. 54294. 12322. 10578. 6897. 36643. 9875. 59299. 37723. 79981. 32512. 55341. 21967. 18034. 30762. 29626. 21493. 2104. Amnt(L) 5. OO 5. 00 5. 00 25. 00 25. 00 23. 00 25. 00 25. 00 25. 00 3. 000 5. 000 5. 000 25. 000 25. 000 25. 000 25. 000 25. 000 25. 000 125. 000 125. 000 125. 000 125. 000 25. 000 23. 000 23. 000 23. 000 25. 000 25. 000 23. 000 25. 000 25. 000 23. 000 23. OOO 23. 000 23. 000 23. 000 25. 000 23. 000 25. 000 23. 000 23. 000 25. 000 25. 000 25. 000 25. OOO 25. 000 23. 000 3O. 000 23. 000 23. 000 25. 000 25. 000 25. 000 23. 000 UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UC/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UC/L UG/L UG/L UC/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UC/L UG/L UG/L UG/L R. Fac R. Fac(L) 1. 000 1. 000 1. 000 0. 386 0. 943 0. 451 0. 675 0. 338 0. 331 1. 000 1. 000 1. 000 0. 586 0. 943 0. 431 0. 675 0. 338 0. 331 XTot 0. 0. 0. 1. 1. 1. 1. 1. 1. 8. 8. 8. 8. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1 1 1 3 1 1 1 1 1 1 Rat 1 1 1 1 1 1 1 1 1 34 34 34 68 68 68 68 68 68 39 39 39 39 68 68 68 68 68 68 68 68 68 68 68 68 68 68 68 68 68 68 68 68 . 68 68 . 68 68 . 68 36 . 68 . 68 . 68 68 . 68 68 10 . OO . 00 00 . 00 00 00 00 00 00 CO CO ^ ^ O1 O ,_ •— t 1 _ L O O G 1 C 8 Q '.10 10 11 12 13 14 •» «* t -^ !6 *. ^r 4. •* J3 -.9 20 21 ^-^ Z.A £3 24 29 26 27 23 29 20 31 22 33 24 33 36 37 33 29 40 *1 42 A3 44 A? Ret(L) 2: 06 3: 50 9 38 11: 22 4: 06 2: 10 2: 02 3: 02 2: 38 4: 16 5: 12 4 30 4: 46 8 04 7: 16 9: 06 6: 42 1 1 : 22 10: 42 5: 06 10: 22 11: 28 14: 00 1O: 50 15: O4 9: 46 12: 30 12: 48 13: 46 13: 02 13: 44 3 46 16: 32 16: 42 17: 20 18: 42 Ratio 1. OO 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. OO 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. OO 1. 00 1 00 RRT(L) 0. 342 0. 625 0. 775 0. 914 0. 668 0. 353 0. 332 0. 495 0. 429 0. 696 0. 848 0. 362 0. 383 0. 649 0. 584 0. 732 0. 539 0. 914 0 861 0 410 0. 834 0. 922 0. 809 O. 871 1. 212 0. 786 1. 005 1. 029 1. 107 1. 048 1. 105 0. 614 0. 956 0. 965 1. 002 1. 081 Ratio 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. OO 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 Amnt 125. 125. 125. 125. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 50. 25. 25. 25. 25. 25. 25. 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 Amnt(L) 125. 125. 125. 125. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 50. 25. 25. 25. 25. 25. 25. 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 R. Fac R. 0. 0. 0. 0. 0. 1. 0. 0. 0. 1. 0. 1. 1. 0. 0. 0. 0. 0. 0. 1. 0. 0. 0. 1. 0. 1. 1. 2. 0. 0. 0. 0. 0. 0. 0. 0. 014 023 088 055 110 552 478 890 433 400 283 554 453 951 523 570 894 419 206 530 347 298 202 033 278 671 063 254 916 780 619 350 899 866 628 062 Fac O. 0. 0. 0. 0. 1. 0. 0. 0. 1. 0. 1. 1. 0. 0. 0. 0. 0. 0. 1. 0. 0. 0. 1. 0. 1. 1. 2. 0. 0. 0. 0. 0. 0. 0. 0. (L) Ratio O14 023 088 055 110 552 478 890 433 400 283 554 453 951 523 570 894 419 206 530 347 298 202 033 278 671 063 254 916 780 619 350 899 866 628 062 1. 00 1. 00 1. 00 1. 00 1 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. OO 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 TUT 004 1689 L 0 0 0 1 6 8 3 3/16/93 17:01:26 Acquisition started 0253 3/16/93 17:01:30 Acquire Run 0:WI0316E •3/16/93 17:01:00 + 0:00 Free sectors: 15164 Sample: CP, ,, VSTD025, LOW, WATER, W10316E, VOA, IC-025, roods.: I500A:25ML OLV01 AMBIENT PURGE W/ 5PPB IS ~::-mula: 2SML AMBIENT PURGE Instrument: I500A by: Analyst: RJL Starting Scan: 0 of Weight: Acct. No: 720 0. 000 r 'w ••i<\ * 1 2 3 'a 1 Desc. : VI Temp ( D e g C ) 35- 35 35-150 150- 150 ve A : c 1 Rate < C/min ) - 8. 0 - osed »** GC not ready and being stabilized *** CT 1 .a n £ A *4 ^ 4 «*b dk Time (minutes) period total 6. 6 6. 6 14.3 20.9 3. 0 23. 9 Valve B : open Elapsed time Injector A GC oven : Transfer-1 ine: Ion source : 0. O Min 150 36 214 180 Deg Deg Deg Deg *** Instrument parameters *** Post acquisition state -> Filament : Off Multiplier : Off T-DE: El < •*•) Centroid •*• Temp - Sequence: BF ( 2 time windows. ) •Sequence Window t 1 3.an descriptor: Total scan time: Number of cycles: Filament is OFF Mult ip1ier is ON BF Mass intervals. 2. 000 s 28 Positive ion mode. Master rate: 16 MFW: 80 Lo mass 33. 510 MA: 15 Hi mass 300. 590 TH: 1 Time 2. 000 BL: £.*4uence Window • an descriptor: otal scan time: Number of cycles: Filament is ON Multiplier is ON BF Mass intervals: 2 000 s Positive ion mode. Master rate: 16 "P«: 3 MFW: 8O MA: 15 Int t Lo mass Hi mass 1 33. 510 300. 590 TH 1 Time 2. 000 BL: Calibration table: D:CAL021992 Interface number Instrument type Full scale mass Zero scale mass Intensity/ion Peak width Offset at low mass Offset at high mass Voltage settling time(ms) 20 0 Q 1177 1 2 1000. 0 0 u u mmu mmu mmu U TUT OO4 1690 Current instrument parameters. Positive ion mode 0254 Resolution (high) Resolution (low) Quad offset Quad programming Lens offset Lens programming Ext offset Ext programming Collector Ion offset Ion programming Rod polar i ty 128. 128. 0. 0. 00 00 00 00 -30. 00 0. 00 0. 00 0. 30. 7 00 00 00 5. 00 Negative ion mode 128. 00 128. 00 0. 00 0. 00 00 00 00 00 00 00 00 Reverse Electron multiplier voltage Filament emission current Electrometer range Electrometer zero 50. 0. 0. 0. 30. -3. -5. Norma1 984. 750. 10 'x-7 126. 0 Analyzer Fore Pressure . . . Separator/Source Pressure 0. 010 Torr 0. 358 Torr 3/16/93 17:26:42 ACQUISITION COMPLETED Scans 1 to 720 Centroid ' *ntr oid Scans Sees Out of '/. 720 1. 2 144O. 0 O 1 Peaks per scan 21375. 3O. per sec 13. TUT OO4 1691 L0001691 TCA DIAGNOSTIC REPORT 3/17/93 8:24:27 I;4TA FILE: W10 REFERENCE: VI 1 -AME LIST: VI REPORT: VII ——— SIANDAR -ROC USED P 3 2 3 3 3 3 45 COMPOUND COMPOUND :> •C LID ENTRY 1 2 ^ 4 5 a •^ 8? 10 1 1 12 13 14 • 5 16 '17 18 1 9 10 ?1 * M 23 24 23 ?6 -i -T iO £9 20 71 32 3:j 24 25 36 j7 28 39 40 M '42 43 44 45 VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 316E INITIALIZATION OPTION: 2 PROCESSING OPTION: 3 "25 S DS ———— X —— PLUS UNKNOWNS —— >< - LIST NAMES - > OSS RNS PROC USED POSS RMS STANDARD/UNKNOWN 1 0 20 19 24 212 V1IS/V1UNKS1 1 23 16 16 1 160 V1IS/V1UNKS2 1 23 15 15 36 154 V1IS/V1UNKS3 S PROCESSED. 43 FOUND e c A D f* u _ x. .*• e A T1 "s. .^ /"•LJOO REF -170 -361 -504 -427 -34 -39 -36 -41 -66 -56 -106 -277 -329 -113 -59 -55 -84 -73 -118 -144 -125 -133 -228 -2O3 -261 -186 -329 -308 -142 -299 -332 -407 -314 -438 -281 -363 -372 -400 -379 -399 -1O4 -482 -487 -505 -544 PRED 184 373 515 440 40 46 42 48 73 63 114 287 340 121 66 62 91 80 126 152 138 146 241 216 274 199 341 320 155 311 344 419 326 451 293 376 385 413 392 412 1 14 496 5O1 519 558 SEL DELTA PEAKS 184 373 439 39 44 40 46 72 63 289 341 123 65 61 91 79 128 155 135 143 242 218 274 201 342 321 154 311 344 420 325 452 293 375 384 413 391 412 1 13 496 501 520 561 -1 -1 -2 -2 -2 -1 2 1 2 -1 -1 -1 2 3 -3 -3 1 2 2 1 1 -1 1 -1 1 -1 -1 -1 -1 1 3 1 1 1 1 1 2 1 2 1 3 1 1 1 2 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 2 1 1 1 1 2 3 3 1 FIT PEAKS M/Z 977 934 955 901 979 931 979 981 424 914 974 970 998 967 983 990 986 836 986 961 994 995 986 978 978 987 973 961 998 978 962 966 987 984 992 965 989 940 935 991 997 989 947 114 117 150 95 50 94 62 64 84 43 43 43 43 128 76 96 63 96 83 62 97 117 83 63 75 95 129 97 78 75 107 173 166 83 91 112 91 104 106 106 96 146 146 146 75 5 - TOP DELTA PEAKS 184 373 440 1 39 44 40 46 72 63 115 289 341 123 65 61 91 79 128 156 1 135 143 242 218 273 -1 201 341 -1 321 153 -1 311 344 420 325 452 293 375 384 413 391 412 113 496 501 520 561 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 TUT 004 1692 i 000169: OLVOl CONTINUING CALIBRATION DATA VOLATILE HSL COMPOUNDS Case No: 53554 Region: ntractor: ITAS-KNOXVILLE No: ___________ 0256 Instrument ID: I500A Calibration Date: Time: Laboratory ID: Initial Cali. Date: 03/17/93 10:48 WS0317 03/16/93 Compound AVE RF RFfSO) % D CCC SPCC Chloromethane . . . . . . Bromomethane . . . . . . . Vinyl Chloride . . . . . . Chloroethane . . . . . . . Methylene Chloride . . . . Acetone . . . . . . . . . Bromochloromethane . . . . Carbon Disulfide . . . . . 1,1-Dichloroethene . . . . 1.1-Dichloroethane . . . . 1.2-Dichloroethene (total) cis-l,2-Dichloroethene . . Chloroform . . . . . . . . 1,2-Dichloroethane . . . . 2-Butanone . . . . . . . . 1.1.1-Trichloroethane . . Carbon Tetrachloride . . . Bromodichloromethane . . . n.2-Dichloropropane . . . s-l,3-Dichloropropene ^rrichloroethene . . . . . Dibromochloromethane . . . 1.1.2-Trichloroethane . . Benzene . . . . . . . . . trans-1,3-Dichloropropene 1,2-Dibromoethane . . . . Bromoform . . . . . . . . 4-Methyl-2-Pentanone . . . 2-Hexanone . . . . . . . . Tetrachloroethene . . . . 1,1,2,2-Tetrachloroethane Toluene . . . . . . . . . Chlorobenzene . . . . . . Ethylbenzene . . . . . . . Styrene . . . . . . . . . Xylene (total) . . . . . . 1,3-Dichlorobenzene . . . 0. 0. 0, 1. 1.015 0.544 0.718 413 565 0.018 0.130 1.575 529 014 0.526 0.415 1.092 0.346 0.038 1.618 469 845 611 571 0.993 0.460 0.257 1.665 0.353 0.332 235 104 0.064 1.203 0.306 1.839 1.251 2.309 1.025 0.707 1.362 1, 0, 0, 0, 0, 0 0.953 0.491 0.661 0.405 0.348 0.013 0.103 1.624 0.532 0.968 0.483 0.371 0.886 0.302 0.027 1.740 1.624 0.736 0.584 0.500 0.985 0.391 0.211 1.673 0.302 0.253 0.213 0.076 0.043 1.171 0.220 1.772 111 430 919 0.701 1.496 1. 2. 0, 6.1 9.7 7.9 1.9 38.4 27.8 20.8 -3.1 -0.6 4.5 8.2 10.6 18.9 12.7 28.9 -7.5 -10.6 12.9 4.4 12.4 0.8 15.0 17.9 -0.5 14.4 23.8 9.4 26.9 32.8 2.7 28.1 3.6 11.2 -5.2 10.3 0.8 -9.8 * * * * * * * * * * * * Up to two compounds with %RSD criteria may exceed the maximum, but none of these may exceed 40.0%. All compounds with no %RSD or RRF criteria specified must meet a minimum 0.010 RRF criteria. Refer to method for RRF criteria. TUT OO4 1693 LOOOJ693 OLV01 CONTINUING CALIBRATION DATA VOLATILE H8L COMPOUNDS Case No: 53554 ^ontractor: ITAS-KNOXVILLE ontract No: Region: ^"instrument ID: I500A 0257 Calibration Date: Time: Laboratory ID: Initial Cali. Date: 03/17/93 10:48 WS0317 03/16/93 Compound 1, 4-Dichlorobenzene . . . . . 1, 2-Dichlorobenzene . . . . . 1 , 2-Dibromo-3-Chloropropane Bromof luorobenzene . . . . . . AVE RF 1.335 0.964 0.091 0.803 RF(50) 1 444 1.034 0.063 0.545 % D — ft 9 — 7 ? 30.8 32.1 CCC * SPCC Up to two compounds with %RSD criteria may exceed the maximum, but none of these may exceed 40.0%. All compounds with no %RSD or RRF criteria specified must meet a minimum 0.010 RRF criteria. Refer to method for RRF criteria. TUT 004 1694 LOC0169-4 oo LO c\»o DATA FROM FILE: WS0317 SCANS 45 TO 720 ACQUIRED: «": CALI: MS0317 #3 SAMPLE: CLP, ,,VSTD005,LOW,WATER,WS0317A'OA,CC-005, COHDS.: I508A:25ML OLU01 PURGE W/ 5PPB IS 8, SS H:: lfi:4*:fi(j 309 J 10:00 400 J 13:20 500 J 16:40 600 . 20:00 760 J 100.02 < 31520.) en CO _J 't Q O H CI10 1,4-DIFLUOROBENZENE <IS#1) CHLOROBENZENE-D5 (IS#2) 4-HUDMOFLUOROBENZENE (SS) Quantltation Report Pile: WSO317 0259 Data: WS0317. TI 03/17/93 10:48: 00 S a m p l e : CLP, , , VSTD005, LOW, WATER, WS0317, VOA, CC-005, v^nds. : I5OOA.-2SML OLV01 PURGE W/ 5PPB IS & SS ^ -rmula: 25ML AMBIENT PURGE Instrument: I500A "E Emitted by: Analyst: RJL •••"OUNT=AREA * REF AMNT/(REF AREA * RESP FACT) r/*sp. fac. from Library Entry 1,4-DIFLUORODENZENE <IS#1) CHLOROBENZENE-D5 <IS#2) 1,4-DICHLORODENZENE-D4 (IS#3> 4-BRDMOFLUORODENZENE (SS) CHLOROMETHANE #* BROMOMETHANE VINYL CHLORIDE * CHLOROETHANE METHYLENE CHLORIDE ACETONE 2-BUTANONE 4-METHYL-2-PENTANONE 2-HEXANONE BRCMOCHLOROMETHANE CARBON DISULFIDE 1,1-DICHLOROETHENE * 1.1-DICHLOROETHANE *» TRANS-1,2-DICHLOROETHENE CHLOROFORM * 1.2-DICHLOROETHANE 1,1,1-TRICHLOROETHANE CARBON TETRACHLORIDE BRCMODICHLOROMETHANE 1,2-DICHLOROPROPANE * CIS-1, 3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE BENZENE TRANS-1,3-DICHLOROPROPENE DIBROMOETHANE BROMOFORM ** TETRACHLOROETHENE 1, 1.2, 2-TETRACHLOROETHANE ** TOLUENE * CHLOROBENZENE ETHYL BENZENE * STYRENE M/P XYLENE 0-XYLENE CIS-1, 2-DICHLOROETHENE 1.. 3-DICHLOROBENZENE 1,4-DICHLOROBENZENE 1,2-DICHLOROBENZENE 1.. 2-DIBROMO-3-CHLOROPROPANE Weight: A c c t . No. : O. 000 1 f.3 4 5 h, / 3 •J 10 t \ ; £ 13 14 1 •• 16 : 7 iS i? £0 «•-' • <2 7; Jl i4 :_ .5 5:6 Ii7 55 2? 30 31 32 33 34 35 J6 37 33 39 40 41 "2 43 44 a? CI 10 CI2O CI?6 CS10 C01O C015 C020 C025 C030 C033 C110 CEO 5 C210 CO37 C-040 C045 C050 C053 C060 CO65 C115 C120 C13O C140 C143 C150 C155 C16O C165 C172 C176 C19O C220 C225 C230 C235 C240 C245 C250 C252 C054 C252 C=.'53 C254 C261 TUT 004 1696 L O C 9 J G 9 U "io 1 2 3 4 A i T 3 •? 10 •_ ; ;2 -.3 ; 4 • B 16 • ^r :3 : 9 -'0 7:1 22 •~, "^ 24 25 T6 p T £3 !-.? ;0 t'i 22 23 "'4 ? **. .-'i 27 -'3 Ii9 -0 4 \ ^i ••':2 r ,• ^5 -.„ 1 2 3 4 :5 6 7 8 „ 9 m/z Scan 114 117 150 95 50 94 62 64 84 43 43 43 43 123 76 96 63 96 83 62 97 117 B3 63 75 95 129 97 73 75 107 173 166 83 91 112 91 1O4 1O6 106 96 1 ':6 146 146 75 Rst(L 6: 08 12: 26 17: 16 14 38 1: 16 1: 28 1: 18 1: 32 2 24 184 373 518 439 38 44 39 46 72 62 115 289 341 122 65 60 91 78 127 155 135 143 242 218 274 201 341 321 153 311 344 420 325 451 293 375 384 413 391 412 112 496 5O1 519 561 Time Ref 6 12 17 14 1 1 1 12 2 3 9 11 4 2 2 3 2 4 5 4 4 8 7 9 6 11 1O 5 10 11 14 10 15 9 12 12 13 13 13 3 16 16 17 18 ) Ratio 1. 1. 1. 1. 1. 1. 1. 1. 1. OO 00 00 00 OO 00 00 00 00 :08 : 26 : 16 : 38 : 16 :2S : 18 : 32 : 24 : 04 : 50 : 38 : 22 : 04 : 10 : 00 : 02 : 36 : 14 : 10 : 30 : 46 : 04 : 16 : 08 : 42 : 22 : 42 : 06 : 2? : 28 . 00 : 50 : 02 : 46 : 30 : 48 : 46 : 02 : 44 : 44 : 32 : 42 : 18 : 42 RRT<L 1. 000 1. 000 1. 000 2. 386 0. 207 0. 239 0. 212 0. 25O 0. 391 1 2 3 1 1 1 1 1 1 1 1 2 2 1 1 1 1 1 1 1 2 22 2 2 2 2 2 2 2 2 3 2 2 2 2 2 2 2 2 1 3 3 3 3 RRT 1. 000 1. 000 1. 000 2. 386 0. 207 0. 239 0. 212 0. 250 0. 391 0. 337 0. 625 0. 775 0. 914 0. 663 0. 353 0. 326 0. 495 0. 424 0 690 0. 842 0. 362 0. 383 0. 649 0. 584 0. 735 0. 539 0. 914 0. 861 0. 410 0. 834 0 922 0. 811 0. 871 1. 209 0. 786 1 005 1. 029 1 107 1. 048 1 105 0. 609 0 958 0. 967 1. 002 1. 083 ) Ratio 1. 1. 1. 1. 1. 1. 1. 1. 1. 00 00 00 00 00 00 00 00 00 Meth A BV A BV A BB A BV A BB A BB A BB A VB A BB A BV A BB A BB A BB A BB A BD A BB A BD A BB A BV A BB A BB A VB A BB A BB A BB A BD A BB A BB A BB A BB A BD A BB A BB A BB A BB A BD A BV A BB A VB A BB A BB A BV A VB A BB A BB Amnt 5. 00 5. OO 5. 00 5. OO 5. 00 5. 00 5 00 5. 00 5. 00 AreaOHgh 9836. 6374. 4017. 5371. 9390. 4838. 6510. 3991. 3425. 621. 1321. 2411. 1380. 1020. 16004. 5239. 9543. 4759. 873O. 2974. 11092. 10351. 4691. 3720. 3187. 6277. 2490. 1342. 10664. 1926. 1611. 857. 7465. 1401. 11295. 7080. 15490. 5857. 1O940. 4471. 3655. 6009. 5802. 4152. 254. Amn t ( L ) 5 00 5 00 5 00 5 00 5. 00 5 00 5 00 5 00 5 00 t) Amount 5. 000 UG/L 5. 000 UG/L 5. 000 UG/L 5. OOO UG/L 5. 000 UG/L 5. 000 UG/L 5. 000 UG/L 5. 000 UG/L 5. 000 UG/L 25. 000 UG/L 25. 000 UG/L 25. 000 UG/L 25. 000 UG/L 5. 000 UG/L 5. 000 UG/L 5. 000 UG/L 5. OOO UG/L 5. 000 UG/L 5. 000 UG/L 5. 000 UG/L 5. 000 UG/L 5. 000 UG/L 5. 000 UG/L 5. 000 UG/L 5. 000 UG/L 5. 000 UG/L 5. 000 UG/L 5. 000 UG/L 5. 000 UG/L 5. 000 UG/L 5. 000 UG/L 5 000 UG/L 5. 000 UG/L 5. 000 UG/L 5. 000 UG/L 5. 000 UG/L 5. 000 UG/L 5. 000 UG/L 10. OOO UG/L 5. 000 UG/L 5. OOO UG/L 5. 000 UG/L 5 000 UG/L 5. 000 UG/L 5. OOO UG/L R. Fac R. Fac<L) 1 . 000 1 . 000 1 . 000 1 . 000 1. 000 1. OOO 0. 545 0. 545 0. 953 0. 953 0. 491 0. 491 0. 661 0. 661 0. 4O5 0. 405 0. 348 0. 348 7.Tot 1 1 1 1 1 1 1 1 1 8 8 8 8 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 3 1 1 1 1 1 1 Rat 1 1 1 1 1 1 1 1 1 . 61 . 61 . 61 . 61 . 61 . 61 . 61 . 61 . 61 . 06 . 06 06 . 06 61 . 61 . 61 . 61 . 61 . 61 . 61 . 61 . 61 . 61 . 61 . 61 . 61 . 61 . 61 . 61 . 61 . 61 . 61 . 61 . 61 . 61 . 61 . 61 . 61 . 23 . 61 . 61 . 61 . 61 . 61 . 61 i o o- . 00 2 . OO . OO <? . oo ;2 . 00 . 00 h- . 00 p? . 00 . 00 L 0001697 Uiibi Mo 10 i 1 12 ',3 .14 15 16 I ^T . .-i l C '9 20 21 12 **•*? £4 25 So 27 23 29 30 :-i "J""^ 33 3* 35 36 37 38 :<? 40 4: » /-^ ^^l ^3 A4 45 Ret(L> 2: 3: 9: 11: 4: *->• &. . 2: 3 2: 4 5: 4: 4 8: 7 9: 6: 11: 10: 5: 10: 11 : 14: 1O 15: 9' 12: 12: 13: 13: 13: 3: 16: 16: 17 18: 04 50 38 22 04 10 00 02 36 14 10 30 46 04 16 08 42 22 42 06 22 28 00 50 02 46 30 48 46 02 44 44 32 42 18 42 Ratio 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 oo 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 oo RRT<L) 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0 0. 0 0. 0. o. 0. o. 0. 0. 0. 1. 0. 1. 1. 1. 1. 1. 0. 0. 0. 1. 1. 337 625 775 914 663 353 326 495 424 690 S42 362 383 649 584 735 539 914 861 410 834 922 811 871 2O9 786 OO5 029 107 048 105 609 958 967 002 083 Ratio 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1 1 1 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 oo 00 00 oo 00 00 oo 00 00 00 00 00 Amnt 25. 25. 25. 25. 5. 5. 5. 5. 5. 5. 5. 5 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5 5. 5. 5. 10. 5. 5. 5. 5. 5. 5. 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 oo 00 00 00 00 00 Amnt ( 25. 25. 25. 25. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 10. 5. 5. 5. 5. 5. 5. L) 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 oo 00 00 00 00 00 R. Fac R. 0. 0. 0. 0 0. 1. 0. 0. 0. 0. 0. 1. 1. 0. 0. 0. 0. 0. 0. 1. 0. 0. 0. 1. 0. 1. 1. 2. 0. 0. 0. 0. 1. 1. 1. 0. 013 027 076 043 103 624 532 968 483 886 302 740 624 736 584 500 985 391 211 673 302 253 213 171 22O 772 111 430 919 858 701 371 496 444 034 063 Fac<L) Ratio 0. 0. 0. 0. 0. 1. 0. 0. 0. 0. 0. 1. 1. 0. 0. 0. 0. 0. 0. 1. 0. 0. 0. 1. 0. 1. 1. 2. 0. 0. 0. 0. 1. 1. 1. 0. 013 027 076 043 103 624 532 968 483 886 302 740 624 736 584 500 985 391 211 673 302 253 213 171 22O 772 111 430 919 858 701 371 496 444 034 063 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 TUT 004 1698 L 0 0 0 1 6 9 3 3/17/93 10:48:27 Acquisition started 0262 •3/17/93 10:48:34 -cquire Run 0: WS0317 V2/17/93 10:48.00 + O: OO Free sectors: 13866 :a,r.ple: CLP, , , VSTD005, LOW, WATER, WSO317, VOA, CC-OO5, :onds. : I500A:25ML OLV01 PURGE W/ 5PPB IS ?« SS ::rmula: 25ML AMBIENT PURGE Instrument: I500A by: Analyst: RJL Starting Scan: 0 o-f Weight: Acct. No: *** GC not I-: Desc. : VI ~.*<\. Temp ready and being stabilized Elapsed t Rate »#* Elapsed time : Time (minutes) <Be§C> (C/min) 35- 35 35-150 8. 0 150-150 ve A : closed period 6. 6 14. 3 3. 0 Valve B : total 6. 6 20. 9 23. 9 open Injector A : GC oven : Transfer-1ine: Ion source : *** Instrument parameters *#* 720 0. 000 0. 0 Min 150 35 215 180 Deg Deg Deg Deg C C C C Post acquisition state -> Filament : Off Multiplier : Off El (+) Centroid ••• Temp - Sequence: BF ( 2 time windows. > •Sequence Window # 1 an descriptor, ta1 scan t ime: Number of cycles: 2 Filament is OFF Multiplier is ON 0F Mass intervals: 2. 000 s 8 Positive ion mode. Master rate: 16 *W: 3 MFW: 80 MA: 15 TH: 1 Int # Lo mass Hi mass Time 1 33. 510 300. 590 2. 000 BL: rsquence Windou; # an descriptor: ital scan time: Number of cycles: Filament is ON Multiplier is ON BF Mass intervals: 2. OOO s Positive ion mode. Master rate: 16 •°W: MFW: 80 Lo mass 33. 510 MA. 15 Hi mass 3OO. 590 TH 1 Time 2. OOO BL: Calibration table: Interface number Instrument type Full scale mass Zero scale mass Intensity/ion Peak width Offset at low mass Offset at h i g h mass Voltage settling time(ms) 20 D:CAL021992 0 Q 1177 1 2 10OO. O 0 u u mmu mmu mmu TUT 004 1699 L 0 0 0 1 6 9 3 VJ »- Current instrument parameters. Positive ion Resolution (high) Resolution (low) Quad offset Quad programming Lens offset Lens programming Ext offset Ext programming Col lector Ion offset Ion programming Rod polari ty 128. 128. 0. 0. -50. 0. 0. 0. 30. 7. 5. OO 00 00 00 00 00 00 OO 00 00 00 mode Reverse Electron multiplier voltage Filament emission current Electrometer range Electrometer zero Negative ion 128. OO 128. OO 0. OO 0. 00 50. 00 0. 00 0. 00 0. 00 30. OO -3. 00 -5. 00 Norma1 984. 750. 10 ~-7 126. 0 mode '-"slyzer Fore Pressure . . . ueearator/Source Pressure O. 010 Torr O. 356 Torr 3/17/93 11: 17: 21 ACQUISITION COMPLETED Scans 1 to 720 Centroid • %'v-je Scans Sees Out of 7. Peaks per scan per sec »ntroid 720 0.6 144O. 0 0.0 8699. 12. 6. TUT 004 1700 L O O O l T G w ZATA FILE: WS0317 REFERENCE: VI11 'iA,1E LIST: VI INITIALIZATION OPTION: REPORT: VI IS 0264 PROCESSING OPTION: 3 ——— STANDARDS —— L ;"OC USED POSS 3 3 3 2 3 3 45 COHPOUNDS COMPOUND >< C! i 2 3 45 67 89 10 11 12 13 14 15 16 1 7 ia i9 20 21 "V't •»s^ rt 4 25 26 27 £8 29 20 31 32 23 24 35 36 j / 28 '_•? 40 41 42 43 44 4? LID VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI ENTRY 1 2 3 4 5 6 7 89 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 1 1 1 — X —— PLUS UNKNOWNS RNS PROC 0 23 23 PROCESSED, 20 16 15 USED 18 16 14 POSS 4 1 36 —— X - LI! RMS STAND, 222 VI IS/1 163 V1IS/' 14O V1IS/' 41 FOUND REF -170 -361 -504 -427 -34 -39 -36 -41 -66 -56 -106 -277 -329 -113 -59 -55 -84 -73 -118 -144 -125 -133 -228 -203 -261 -186 -329 -308 -142 -299 -332 -407 -314 -438 -281 -363 -372 -4OO -379 -399 -1O4 -482 -487 -505 -544 PRED 184 373 515 440 40 46 43 48 73 63 114 287 34O 121 66 62 91 SO 126 152 137 145 240 215 273 198 341 320 154 311 344 419 326 451 293 375 384 413 391 412 114 495 50O 518 558 SEL 184 373 439 38 44 45 46 72 289 341 122 65 60 91 78 127 155 135 143 242 218 273 201 341 321 153 311 344 420 325 451 293 375 384 413 391 412 112 496 501 519 DELTA -1 -2 -2 2 -2 -1 2 1 1 -1 -2 -2 1 3 -2 -2 2 3 3 1 -1 1 -1 -2 1 1 1 PEAKS 1 1 1 1 1 2 1 1 1 1 1 1 2 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 2 1 1 1 1 2 3 3 —— >< SAT FIT PEAKS 980 970 947 873 932 896 908 981 872 882 948 976 958 971 98O 976 838 989 957 967 985 970 961 950 971 966 900 960 871 954 916 979 984 992 966 992 929 932 986 991 979 n/z 114 117 150 95 50 94 62 64 B4 43 43 43 43 128 76 96 63 96 83 62 97 117 83 63 75 95 129 97 78 75 107 173 166 83 91 112 91 104 106 1O6 96 146 146 146 75 — CHRO —————— Z TOP DELTA PEAKS 184 . 1 373 1 439 38 44 46 72 62 115 289 341 122 65 60 91 78 127 155 135 143 242 218 274 201 341 321 153 311 344 420 325 451 293 375 384 413 391 412 112 496 501 519 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 TUT O04 17O1 L0001701 OLV01 CONTINUING CALIBRATION DATA VOLATILE HSL COMPOUNDS No: 53554 Region: ntractor: ITAS-KNOXVILLE "*-bntract No: __________ 0265 Instrument ID: I500A Calibration Date: Time: Laboratory ID: Initial Cali. Date: 03/16/93 03/18/93 08:29 WS0318 Compound AVE RF RFfSO) % D CCC SPCC Chloromethane . . . . . . Bromomethane . . . . . . . Vinyl Chloride . . . . . . Chloroethane . . . . . . . Methylene Chloride . . . . Acetone . . . . . . . . . Bromochloromethane . . . . Carbon Disulfide . . . . . 1,1-Dichloroethene . . . . 1.1-Dichloroethane . . . . 1.2-Dichloroethene (total) cis-1,2-Dichloroethene . . Chloroform . . . . . . . . 1,2-Dichloroethane . . . . 2-Butanone . . . . . . . . 1.1.1-Trichloroethane . . Carbon Tetrachloride . . . Bromodichloromethane . . . 2-Dichloropropane . . . ^s~l/3-Dichloropropene T-ichloroethene . . . . . Dibromochloromethane . . . 1.1.2-Trichloroethane . . Benzene . . . . . . . . . trans-1,3-Dichloropropene 1,2-Dibromoethane . . . . Bromoform . . . . . . . . 4-Methyl-2-Pentanone . . . 2-Hexanone . . . . . . . . Tetrachloroethene . . . . 1,1,2,2-Tetrachloroethane Toluene . . . . . . . . . Chlorobenzene . . . . . . Ethylbenzene . . . . . . . Styrene . . . . . . . . . Xylene (total) . . . . . . 1,3-Dichlorobenzene . . . 0, 1, 1.015 0.544 0.718 0.413 0.565 0.018 0.130 1.575 529 014 0.526 0.415 1.092 0.346 0.038 1.618 469 845 611 571 993 0.460 0.257 1.665 0.353 0.332 0.235 0.104 0.064 1.203 0.306 1.839 1.251 2.309 1.025 0.707 1.362 0, 0, 0. 0. 0, 1, 0, 1, 0, 973 526 685 382 0.379 0.016 120 558 513 045 501 0.403 1.015 0.334 0.031 1.668 1.544 0.827 0.601 0.500 0.997 427 227 685 0.296 0.280 0.205 0.081 0.049 1.180 0.228 1.773 1.167 2.419 0.961 0.727 1.395 0, 0, 1, 4.1 3.3 4.6 7.5 32.9 11.1 7.7 1.1 3.0 -3.1 4.8 2.9 7.1 3.5 18.4 -3.1 -5.1 2.1 1.6 12.4 -0.4 7.2 11.7 -1.2 16.1 15.7 12.8 22.1 23.4 1.9 25.5 3.6 6.7 -4.8 6.2 -2.8 -2.4 * * * * * * * * * * * * Up to two compounds with %RSD criteria may exceed the maximum, but none of these may exceed 40.0%. All compounds with no %RSD or RRF criteria specified must meet a minimum 0.010 RRF criteria. •w.efer to method for RRF criteria. TUT 004 1702 L000170,: OLVOl CONTINUING CALIBRATION DATA VOLATILE H8L COMPOUNDS Case No: 53554 ->ntractor: ITAS -KNOXVILLE mtract No: ___________ Region: Instrument ID: I500A Calibration Date: Time: Laboratory ID: Initial Cali. Date: 0266 03/18/93 08:29 WS0318 03/16/93 Compound 1,4-Dichlorobenzene . . . . 1,2-Dichlorobenzene . . . . 1,2-Dibromo-3-Chloropropane Bromofluorobenzene . . . . . AVE RF 1.335 0.964 0.091 0.803 RF( 50) 1.409 1.011 0.061 0.611 % D -5.5 -4.9 33.0 23.9 CCC * spec Up to two compounds with %RSD criteria may exceed the maximum, but none of these may exceed 40.0%. All compounds with no %RSD or RRF criteria specified must meet a minimum 0.010 RRF criteria. Refer to method for RRF criteria. TUT OO4 17O3 LOG0170o co CMo DATA FROM FILE: WS0318 SCANS 45 TO 720 ACQUIRED: 63/18/93 8:29:06 CALI: WS0318 #3 SAMPLE: CLP,,,USTD895,LOW,WATER,WS0318,UOA,CC-005, CONDS.: I500A:25ML OLV01 AMBIENT PURGE W/ 5PPB IS & SS <t N O 100 J 3:20 200 J 6:40 300 J 10:00 406 J 13:20 500 J 16:40 600 J 20:00 706 J _L _L J 100.0Z ( CI10 1,4-DIFLUOROBENZENE (IS#1) CI20 CHLOROBENZENE-05 <IS#2) <SS) 36224.) H CI26 1,4-DICHLOROBENZENE-D4 (IS#3> 3u.antitation Report File: WSO318 Zata: U50318. TI 03/18/93 8:29:00 Sample: CLP, > > VSTDOO5, LOW, WATER. WS0318.. VOA, CC-005. ;nds. : I500A: 25ML OLVO1 AMBIENT PURGE W/ 5PPB IS &. — -.rmula. 25ML AMBIENT PURGE Instrument: 150OA £j&mitted by: Analyst: RJL -••.C)UNT=AREA * REF APiNT/ (REF AREA * RESP FACT) "•*-ip. fac. from Library Entry SS W e i g h t : A c c t . No. 0. 000 No tA 2 « 4 5 6 7 3 9 10 1 2 3 4 5 6 * 15 19 20 •*) I e. A 22 23 24 25 26 7' "7 58 29 30 31 32 33 34 35 36 37 33 39 40 • I i^ •*3 -4 ^ K CI10 CI20 CI26 CS10 CO 10 C015 C020 C025 C030 C035 Cl 10 C2O5 C210 C037 C040 CO45 C050 CO 53 C060 CC65 Cl 15 C120 C130 C140 C143 C150 C155 C160 C165 C172 C176 C1BO C220 C225 C230 C235 C240 C245 C350 C252 C054 C253 C254 C255 C261 1, 4-DIFLUOROBENZENE <IS#1> CHLDROBENZENE-D5 «IS#2> 1, 4-DICHLOROBENZENE-D4 <IS*3> 4-BROMOFLUOROBENZENE (SS) CHLOROMETHANE ** BROMOMETHANE VINYL CHLORIDE * CHLOROETHANE METHYLENE CHLORIDE ACETONE 2-BUTANONE 4-METHYL-2-PENTANONE 2-HEXANONE BROMOCHLOROMETHANE CARBON DISULFIDE 1, 1-DICHLOROETHENE * 1, 1-DICHLOROETHANE #* TRANS-1, 2-DICHLOROETHENE CHLOROFORM * 1, 2-DICHLOROETHANE 1,1, 1-TR I CHLOROETHANE CARBON TETRACHLORIDE BROMOD I CHLOROMETHANE 1, 2-DICHLOROPROPANE * CIS-1, 3-DICHLOROPROPENE TRICHLOROETHENE D I BROMOCHLOROMETHANE 1,1, 2-TR I CHLOROETHANE BENZENE TRANS-1, 3-DICHLOROPROPENE 1, 2-DIBROMOETHANE BROMOFORM ** TETRACHLOROETHENE 1, 1, -TETRACHLOROETHANE ** TOLUENE * CHLOROBENZENE ETHYL BENZENE * STYRENE M/P XYLENE 0-XYLENE CIS-1.- 2-DICHLOROETHENE 1, 3-DICHLOROBENZENE 1, 4- DICHLOROBENZENE 1, 2-DICHLOROBENZENE 1, 2-DIBRCMO-3-CHLOROPROPANE TUT CO4 17O5 L 0001.70 •0 m I I. j- 4. {.• t. :.] I., uj i-j I.: t.j ij (... t.i >J I' I !U •'.! M •.fi 4* (o f'J "— O -0 Ul '-4 0- 'JI ** l-i l»^ r-« t'.'j 4] 00 -4 TJ- 0- is 4=- IJ -0 Oj --4 f- 'J« (j CJ »- O PJ r>) pj 10 «- (0 O Hi O O O O O O O O O r t - o o o o o o o o o ^o O O O O O W •-» •-»»-• 31 . . . . . . . . . - g U PJ PJ fO PJ Ul O O O H •-j *.*.*. -o o o o -o ^ -o m n --4 o --i -i % P.I 43 xi rj- nri >- -o o- no -o a- -n --i PJ 4:. *. t- 4=< oo t> o- 41 r^ -o <ji >- >- -x rJl l> l> l> Cf- ',''• C'- J- »-* 10 t-" LO U- ijJ -vl rjt ia) x( 43 rjl cjl CJ bj --] --4 I'J LJ 0% U) O 0" CI) Q CO Ld CJ i. -i. fu 4:- O O1 O N| 4> w 0) O O O O O O O O O r t - o o o o o o o o o •- o U U U ) ( J » - P J P J P J P J P J P J P J P J C J P J P J P J P J P J P J P J P J P J P J P J > - ' ^ f - ' ^ t - ^ i - . p j p j t - > ^ > - i - H ' t - . l - . i - * ( J p j > - • - ^ O O O ' - > - » - > - A ' - ' O ' - ' O O O O O O O O O O O O O O O O O O O O O O O O O O O O O P J » - ' t - « - CJ1O»«JIUIU1<JIUIUICJ1> . . . . . . . . . 3 O C > O O O O O O O 3 O O O O O O O O O r t ooooooooor o o o o o o o o o - U (Jl O- --J O O- xl >- ^ H* PJ O --4 PJ 0- 00 O (J 4J CD -J U 0- *-* l-» "J i->-U'-» * 4 » - > 4 C J l O ( h ( J 1 v | » - W U 00 »-» -4 43 PJ fO Ch 4J >0 00 •£ 'vl PJ Oi r O O O O O O ' - * * - " ^ - * ' O O O O O O ' - 1 - ' - ' •n a<n PJ PJ PJ PJ O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O C O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O 3 O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O r t - c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c - rrrrrrrrrr rrrrrrr X X X N. \ N. x, rrrrrrr x \ X '-x '-^ X X '--s \ X -^ \ 'X X \ X •••. r r r r r r r r r r r r r r r r r o o o o o o o o o o o o o o o o o o o o CD 00 CD CD 0- 0- 0^ O- ro O5 CO TUT 004 .1.706 o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O «Dtr u . «UO U. ct . . . . . . . . . . O O O O < - < O « - « O « - | O « - ' ' - < O O O O O O » - ' O O O - * - < O — | * - | O J O O O O * - « i ' - ' ' - | O u.. cr - • o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o _ I O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O V * . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4J\n\r>fr\r>ir>ir>ir>in\r!ir)in\n\r>inir>\r)\r)\r>in<r)\r>ir>r>fiin\r)\r>tn\rtofo\r)ir>in\ri\r) c ru ru ru ru ~ 4*000000000000000000000000000000000000 coooooooooooooooooooooooooooooooooooo 6 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . i n i n i f t i f t ru ru ru ru ~< - o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o • P O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O i p . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . • ^ o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o 4 * 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 - - - - o id n ru o -« o o n «-< •-• n «*• o -•« o •«• ru «*• o ru rd ift ITJ o -4- rd «r •* o -t »r n t -< -T . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . r\i n o- — • -t ru ru n ru •* ir? -t -t ro r-- o-- -o -i o in o ~* n o in o-- ru cu ri n n n -.0 -o t-- 01 o o -• ru n 4? >•-. in c- -•• •:>; > -o i- « o -» id r.i r- I": t" n if" -o r-- ci o -* ex fo •* -t ~t ~* 3/18/93 8:29:18 Acquisition started 0271 2/18/93 8:29:21 :quire Run O:WS0318 -r.i/18/93 8:29:00 + 0:00 Free sectors: 12406 ^a-T.ple: CLP, , , VSTD005, LOW, WATER, WS0318, VOA, CC-005, :?r,ds. : I500A:25ML OLV01 AMDIENT PURGE W/ 5PPB IS -:-rmula: 25ML AMBIENT PURGE Instrument: 1500A submitted by: Analyst: RJL Starting Scan: 0 of SS Weight: Acct. No: 720 0. OOO Desc RR *•** GC not ready and being stabilized ***• Elapsed time : 0. O Min Tercp Rate Time (minutes) (BegC) <C/min) 35- 35 35-150 8 0 150-150 1ve A : closed period 6. 6 14. 3 3. 0 Valve B total 6. 6 20. 9 23. 9 open Injector A : GC oven : Transf ei—1 ine: Ion source : 150 Deg C 35 Deg C 215 Deg C 180 Deg C *** Instrument parameters *** Post acquisition state -> Filament : Off Multiplier : Off OT-E: EI (-»•) Centroid * Temp - Sequence: BF ( 2 time windows. ) Sequence Window # 1 5:an d escri ptor: Tota1 scan t ime: Number of cycles: Filament i s OFF Multiplier is ON BF Mass intervals: 2. OOO s 28 Positive ion mode. Master rate: 16 /W: 3 MFW: 80 MA: 15 tnt # Lo mass Hi mass 1 33. 510 300. 590 TH: 1 Time !. OOO DL: 3*quence Windou' >:sn descriptor: otal scan time: Number of cycles: Filament is ON Multiplier is ON BF Mass intervals: 2 000 s Positive ion mode. Master rate: 16 '^W: 3 MFW: 80 MA: 15 Int t Lo mass Hi mass 1 33. 510 300. 590 TH 1 Time 2. 000 DL: Calibration table: Interface number Instrument type Full scale mass Zero scale mass Intens i ty/ion Peak width Offset at lou mass Offset at high mass I199J 0 Q 1177 1 2 1000. mmu 0 mmu 0 mmu Voltage settling time(ms) 20 u u TUT OO4 17O8 L O C O ! V 0 u Current instrument parameters. Positivt ion mode Reso lution (high) Resolution (low) Quad offset Quad programming Lens offset Lens programming Ext offset Ext programming Col 1ec tor Ion -*fset I on ^ rogramming Rod p olar i ty 128. 128. 0. 0. -50. O. O. 0. 3O. 7. 5. 00 00 00 00 00 oo oo 00 00 00 00 Negative ion 128. 00 128. 00 0. 00 0. 50. 0. 0. 0. 30. -3. Reverse Electron multiplier voltage Filament emission current Electrometer range Electrometer zero 00 00 00 00 00 00 00 -5. 00 Normal 984. 750. 1O ~-7 126. 0 mode 0272 n»lyzer Fore Pressure ... eparator/Source Pressure 0. 010 Torr 0 361 Torr 3/18/93 8:57:56 ACQUISITION COMPLETED Scans 1 to 720 Centroid <»ntr o i d Scans 77.- Secs 0. 5 Out of 1440. 0 7. Peaks per scan 0. 0 9107. 13. per sec 6. 0001703 TUT OO4 17O9 r.ATA FILE: REFERENCE: *;-«£ LIST: REPORT: WS0318 V I 1 1 VI INITIALIZATION OPTION: V1IS PROCESSING OPTION: 0273 ——— STANDARDS ———— >< —— PLUS UNKNOWNS —— >< - LIST NAMES - ,'30C USED POSS 3 3 3 45 2 3 3 COMPOUNDS COMP <D L t ;J 3 43 >* T 8 9 10 1 1 1? 13 14 15 16 7 is 1° 20 S 1 22 2C? 54 25 i6 27 26 £9 30 31 j;^ 23 34 '_<" II 1 6 37 3S 39 40 41 42 43 44 45 1C VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI GUND :>< ENTRY 1 2 3 4 5 6 T J 3 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 1 1 1 RMS PROC USED 0 O 0 PROCESSED, REP -184 -373 -518 -439 -38 -44 -39 -46 -72 -62 -115 -289 -341 -122 -65 -60 -91 -78 -127 -155 -135 -143 -242 -218 -274 -201 -341 -321 -153 -311 -344 -420 -325 -451 -293 -375 -384 -413 -391 -412 -112 -496 -501 -519 -561 PRED 184 373 518 439 38 44 39 46 72 62 115 289 341 122 65 60 91 78 127 155 135 143 242 218 274 201 341 321 153 311 344 420 325 451 293 375 384 413 391 412 112 496 501 519 561 2O 18 16 16 15 14 41 POUND i)t ftr\ w rl SEL DELTA 184 373 439 39 1 44 40 1 46 72 289 341 122 65 60 91 79 1 127 155 135 143 241 -1 217 -1 273 -1 2O1 341 320 -1 153 311 344 419 -1 325 451 292 -1 374 -1 383 -1 412 -1 391 41 1 -1 112 495 -1 501 519 POSS 2 1 54 PEAKS 1 1 1 1 1 2 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 2 1 1 1 1 3 3 3 RMS STAND 37 V1IS/1 49 V1IS/' 53 V1IS/1 ..,. . -••>.-• CAT rf ^- ^™ 1 FIT PEAKS 981 954 947 893 932 905 936 981 873 911 948 984 957 973 983 976 867 987 956 959 984 951 955 960 980 963 915 964 894 951 940 982 984 992 938 985 955 936 993 993 964 M/Z 114 117 150 95 50 94 62 64 84 43 43 43 43 128 76 96 63 96 83 62 97 117 83 63 75 95 129 97 78 75 107 173 166 83 91 112 91 1O4 1O6 1O6 96 146 146 146 75 -- CHRO —————— I TOP DELTA PEAKS 184 373 518 439 39 44 40 46 72 62 115 289 341 122 65 60 91 78 127 155 135 143 241 217 273 201 341 320 153 311 344 419 325 451 292 374 383 413 391 411 112 495 501 519 560 -1 TUT OO4 1710 0274 ^^•y^-'y^r^^^^-f^^-r-----^:--'.----- l^i^^feilf^^'rv • III VOLATILES DATA, continued d. RAW QC DATA L0001711 TUT 004 1711 STZ.T troo mi CMO 180.0-, 50.9- 37 M/Z \49 MASS SPECTRUM 93/16/93 12:93:99 + 2:12 SAMPLE: 1UL (59NG) BFB TUNE STD CONDS.: I599A:DIRECT INJECTION:120C ISOTHERMAL TEMP: 129 DEC. C »65 TO »67 AUERAGED - 169 96 DATA: WBFB0316 #66 CALI: CAL821992 »3 BASE M/Z: 95 RIC: 15904. 50 57 •I « iee O -J r 3436. 9. 174 14) I""' 129 | iii i | . i i i ! , ,ii |t| i 290 * 66 03/16/93 12:03:00 + 2:12 Call: CAL021992 * 3 Sa«pl»: 1UL (90NG) SF8 TUNE STD Conds.: I300A:DIRECT INJECTION:120C ISOTHERMAL to #67 av«rag«d - «6O Base RIC: m/ z 15904. 36 177 fUss 36? 37? 38? 39? 40? 44? 45? 47? 48? 49? 50? 51? 56? 57? 60? 61? 62? 63? 68? 69 70 72 73 74 75 76 77 78 79 80 81 82 87 88 92 93 94 95 96 141 143 174 175 176 177 Ss Sss 5 Sssssssssssssssssssssssssssssssssssssss 0. % 2. 9. 7. 3. 0. 0. 1. 1. 0. 6. 27. 8. 1. 3. 1. 6. 5. 4. 12. 11. 0. 0. 5. 17. 54. 5. 0. 0. 3. 0. 3. 0. 3. 4. 2. 4. 12. 100. 7. 0. 0. 56. 4. 54. 3. 00 RA 21 55 83 23 35 76 40 75 49 90 15 64 95 75 19 05 65 22 02 64 79 20 30 93 31 27 15 15 38 55 26 52 96 13 68 28 11 00 48 35 17 05 66 42 96 0. Minima Min Inten: Maxima * 0 Int«n. 76. 328. 269. 111. 12. 26. 48. 60. 17. 237. 933. 297. 67. 129. 41. 208. 194. 145. 413. 400. 27. 7. 182. 616. 1866. 181. 5. 5. 116. 19. 112. 18. 136. 142. 92. 147. 416. 3436. 237. 12. 6. 1926. 160. 1870. 136. TUT 004 1713 trT/.T 1700 CM O 100.0-1 RIC DATA: WBFB0316 #65 SCANS 03/16/93 12:03:00 CALI: CAL021992 13 SAMPI •-• 1UL (50NG) BFB TUNE STD CONDS.; I500A:DIRECT INJECTION:120C ISOTHERMAL RANGE: G 1, 90 LABEL: N 0, 4.0 QUAN: A 0, 1.0 J 0 BASE: U 20, 1 TO 90 21056. - r ooo -J RIC 30 ~I—— 29 0:40 54 75 1:29 60 81 88 SCAN I ME J QTZ.T 1?00 COr^ CMo 100.0-1 MASS SPECTRUM 03/17/93 9:34:09 + 2:18 SAMPLE: 1UL (58NG) BFB TUNE STD CONDS.: I500A:DIRECT INJECTION:120C ISOTHERMAL TEMP: 120 DEC. C #68 TO #70 A'JERAGED - #65 96 DATA: WBFB0317 #69 CALI: CAL021992 #3 BASE M/Z: 35 RIC: 17152. i -j —< r- i—ioo oJ 75 50.0- \& 7 141 ji -^TT*?-r"»-y •«->—«—T'T-|TfT" j"* TTT*TXT*T"T~T "p» -T~T T"?"^^ -n—jT--^ •*?" 3660. 0. l no :.2/17/93 9:34:00 + 2:18 Cali: CAL021992 # 3 RIC: 17152. [ample: 1UL (50NG) BFB TUNE STD onds. : I500A:DIRECT INJECTION: 120C ISOTHERMAL *£8 to #70 averaged - #65 36 0.00 0. Minima Min Inten: 0. 177 Maxima # 0 7. RA Inten. 36? 37? 38? 39? 40? 43? 44? 45? 47? 48? 49? 50? 51? 55? 56? 57? 6O? 61? 62? 63? 68? 69 70 72 73 74 75 76 77 79 SO 81 82 87 88 92 93 94 95 96 141 143 174 175 176 177 Sss sss s 5 Ss ssssssssss 5ssssssssss 55 Sssss ssssssss 2. 9. 8. 3. 0. 0. 0. 1. 1. 0. 6. 28. 8. 0. 1. 4. 1. 6. 5. 4. 12. 12. 0. 0. 5. 18. 56. 5. 0. 3. 0. 3. 0. 3. 3. 2. 4. 11. 100. 8. 0. 0. 55. 4. 54. 3. 35 97 33 61 44 14 52 50 69 79 94 20 93 14 97 18 31 09 63 51 21 05 96 27 52 39 07 27 36 42 22 39 22 99 88 76 34 97 00 11 55 19 57 34 15 91 86. 365. 305. 132. 16. 5. 19. 55. 62. 29. 254. 1032. 327. 5. 72. 153. 48. 223. 206. 165. 447. 441. 35. 10. 202. 673. 2052. 193. 13. 125. 8. 124. 8. 146. 142. 101. 159. 438. 3660. 297. 20. 7. 2034. 159. 1982. 143. TUT OO4 1716 U000171G CD CDI 0280 ^j o en co .TI 3> O 2> CO •— Z Z 3 N O O C" "O *- m m i— -si •• • m N •• •• 1^1 O CO . O |— 1X1 •— • i^i •• •- i> ^^ co •• en *• O O •• U) —• Z O CD ^? O «5> m <w^ o r~ — i ro 3> -n co •— « ro m z z3f* M-I O l/l Q Z —I - « O cn CD O C O 3> -4 •• m CO I- o o i— —i •-• » • • •• Si f~ "T| l^i QO ro cs> >— oj 11*^ t-** OJ -vj 4t Ti CO CO 01 I.O r-- to i- L O C 0 1 7 1 V •0 C; i uj, I i i i i 1 i i i i I . '.'O i M.-l i • . I ..!,, . I .... I . IH r • Jfi ulf e* ^6 '•? U 3 TUT O04 1718 96 93* - (HDWHfW 89* Oi 99# 3 'D3Q oeeT-'NQiioarni ais 3nn frP3 + 98 = 02! 8 £6/31/£8 ssyw -0'0S d » s i_ i a ». ua ta •2/18/93 8:20:00* 2:14 Call: •ar.ple: 1UL <50NG) BFD TUNE STD onds. : I5OOA:DIRECT INJECTION:120C to #68 averaged - #60 Mini ma Max ima WBFB0318 * 67 CAL021992 # 3 ISOTHERMAL Base m/z RIC: 95 16240. 0282 36 177 **ss 36? 37? 38? 39? 40? 44? 45? 47? 48? 49? 50? 51? 56? 57? 6O? 61? 62? 63? 68? 69 70 73 74 75 76 79 80 81 82 87 88 92 93 94 95 96 141 174 175 176 177 Ssssssss 5 Ss S 3 S S S 3 S S5s s 5 c; S 5 5 s 3 S S 3 S S 5 3 3s S Ss 0. •/. 2. 10. 8. 3. 0. O. 1. 2. 0. 7. 29. 9. 2. 4. 0. 6. 6. 4. 12. 12. 1. 5. 19. 56. 5. 3. 0. 3. 0. 3. 3. 2. 4. 12. 100. 8. 0. 57. 4. 55. 3. 00 RA 35 56 80 70 21 18 09 11 26 22 72 O4 23 08 97 22 02 46 47 15 14 63 48 81 37 40 38 43 32 7O 81 61 14 18 00 27 15 45 55 63 96 0. Inten. 80. 360. 300. 126. 7. 6. 37. 72. 9. 246. 1013. 308. 76. 139. 33. 212. 205. 152. 425. 414. 39. 192. 664. 1936. 183. 116. 13. 117. 11. 126. 130. 89. 141. 415. 3408. 282. 5. 1958. 155. 1896. 135. Min Inten: * 0 TUT OO4 1719 L O O O l V i j CD ^? O IO S) 73 I> O X" CO i— Z Z 3 X O O O ~V >- m i.o r~ co •• • m x •• •• i_£ C~i CO >s> r~ cp - x> '- KJ •• c,n <s> O <Sf •• "j? —• 2: «s> 'S' 7? O CO m --•• o i- —i co i> -n CO —• CO m -z. i— c_ —i O I.O o 2: — i - .. o • cs- CD O •-i O O i.O I'- cr o r~ o cs- CS" i_ ^j CD to LO CO NJ at en co en CO I> 1.0 IJ'l I—I CO >—* CO h- D h- L 0 0 (J I V t'L IX ORGANICS ANALYSIS DATA SHEET 'Lab Name: ITAS-KNOXVILLE________ Contract: Lab Code: ITSTU Case No.: 53554 SAS No.: Matrix: (soil/water) WATER Sample wt/vol: 25.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ Heated Purge: N GC Column: DB-624___ ID: 0.53 (mm) Soil Extract Volume: _______(uL) 0284 SAMPLE NO. VBLK1 SDG No.: MW01 Lab Sample ID: WB0317 Lab File ID: WB0317 Date Received: _____ Date Analyzed: 03/17/93 Dilution Factor: ____1.0 Soil Aliquot Volume: CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L .(uL) 74-87-3 ————— 74-83-9 ————— 75-01-4 ————— 75-00-3 ————— 75-09-2 ————— 67-64-1 ————— 74-97-5 ————— 75-15-0 ————— 75-35-4 ————— 75-34-3 ————— 540-59-0 ———— 540-59-0 ———— 67-66-3 ————— 107-06-2 ———— '7Q—Q') — •?_.. — _ — — 71-55-6 ————— 56-23-5 ————— / -/ tf i ~* TO Q "7 F 10061-01-5 —— 79-01-6 ————— 124-48-1 ———— 79-00-5 ————— 71-43-2 ————— 10061-02-6 —— 106-93-4 ———— *7 rr *> rr *> 108-10-1 ———— CO 1 *7 Q f 127-18-4 ———— 79-34-5 ————— —— Chloromethane —— Bromome thane —— Vinyl Chloride —— Chloroethane —— Methylene Chloride f^L*C L*W11C —— Bromochl or ome thane —— Carbon Disulfide —— 1 , l-Dichloroethene —— 1 , 1-Dichloroethane —— trans-1, 2-Dichloroethene —— cis-1 , 2-Dichloroethene —— Chloroform —— 1 , 2-Dichloroethane —— 2-Butanone —— 1, 1, 1-Trichloroethane —— Carbon Tetrachloride —— Bromodichlorome thane —— 1 , 2-Dichloropropane —— cis-1, 3-Dichloropropene —— Trichloroethene —— Dibromochloromethane —— 1 , 1 , 2-Trichloroethane —— Benzene —— trans-1, 3-Dichloropropene —— 1 , 2-Dibromoethane —— Bromoform —— 4-Methyl-2-Pentanone —— 2 -Hexanone —— Tetrachloroethene —— 1 ,1,2, 2 -Tetrachloroethane —— Toluene —— Chlorobenzene 1 l 1 1 1 5 1 1 1 1 1 1 1 1 5 1 1 1 1 1 1 1 1 1 1 1 1 5 5 1 1 1 1 U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U FORM I X-l i o00172;'' IX ORGANICS ANALYSIS DATA SHEET Lab Name: ITAS-KNOXVILLE__________ Contract: Lab Code: ITSTU Case No.: 53554 SAS No.: Matrix: (soil/water) WATER Sample wt/vol: 25.0 (g/roL) ML Level: (low/med) LOW % Moisture: not dec. ___ Heated Purge: N GC Column: DB-624 ID: 0.53(mm) Soil Extract Volume: ______(uL) 0285 SAMPLE NO. VBLK1 SDG No.: MW01 Lab Sample ID: WB0317 Lab File ID: WB0317 Date Received: __ Date Analyzed: 03/17/93 Dilution Factor: ____1.0 Soil Aliquot Volume: ___ CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L .(uL) 100-41-4 ——— • 100-42-5 ——— - 1330-20-7 —— - 541-73-1 ——— • 106-46-7 ——— - 95-50-1 ———— - —— Ethylbenzene —— Styrene - —— Xylene (total) —— 1 , 3-Dichlorobenzene —— 1 , 4-Dichlorobenzene —— 1 , 2-Dichlorobenzene —— 1 , 2-Dibromo-3-Chloropropane _ 1 1 1 1 1 1 1 Uu Uuuuu FORM I X-2 TUT O04 1722 3/90 IX ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS "Lab Name: ITAS-KNOXVILLE_________ Contract: Lab Code: ITSTU Case No.: 53554 SAS No.: Matrix: (soil/water) WATER Sample wt/vol: 25.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ GC Column: DB-624 ID: 0.53 froml Soil Extract Volume: _______(uL) 0286 SAMPLE NO. VBLK1 SDG No.: MW01 Lab Sample ID: WB0317 Lab File ID: WB0317 Date Received: _____ Date Analyzed: 03/17/93 Dilution Factor: ____l.0 Soil Aliquot Volume: ___ .(uL) Number TICs found: CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L CAS NUMBER COMPOUND NAME ================:==:=:==:======= UNKNOWN RT 2.27 EST. CONC. 7 Q J TUT 004 1723 FORM I X-TIC L 3/90 troo mi oo Cvio DATA FROM FILE: MB0317 SCANS 45 TO 720 ACQUIRED: 03/17/93 11:33:00 CALI: MB0317 #3 SAMPLE: CLP,,,UBLK1,LOW,WATER,WB8317,UOA,BLANK, CONDS.: I500A:25ML OLU61 PURGE W/ 5PPB IS 8< SS 100 _ 3:20 200 _ 6:40 300 _ 10:00 480 _ 13:20 506 _ 16:43 600 _ 28:68 706 _ m* I I I 11104.) f o CD CI10 1,4-DIFLUGROBENZENE <IStl) CI20 CHLOROBENZENE-D5 (IS#2) CS10 4-BROMOFLUOROBENZENE <SS) CI26 L4-DICHLOROBEHZENE-D4 (IS#3> •lu<ant i tation Report File: WB03I7 0288 Data: UB0317. TI D3/17/93 11:39:00 Sample: CLP, , , VBLK1, LOW, WATER, WB0317, VOA, BLANK, :-r,ds. : I500A:25ML OLV01 PURGE W/ 5PPB IS !< SS r3;'mula: 25ML AMBIENT PURGE Instrument. I500A remitted by: Analyst: RJL -''QUNT=AnEA * REF AMNT/(REF AREA * RESP FACT) -*;p. fac. from Library Entry Weight: Acct. No. 0. 000 No -+** r-i&rr:e CI10 C 120 4; A •T 5 •^ 1 0 1 i 123 •1 K i, 7 3 19 20 21 22 H:2 24 ?-•? 26 ^ T 2S ?•? 30 31 32 "'•? 2)4 3 ^ 3t 37 23 39 40 M •*2 CS10 CO1O C015 C020 C025 CO 30 C035 Cl 10 C2O5 C210 C037 C040 C045 CO 50 C053 C060 CO65 C115 C120 C130 C140 C143 C150 C155 C16O C165 C172 C176 C1SO C220 C225 C23O C235 C24Q C245 C250 C252 C054 C252 C254 C261 1, 4-DIFLUOROBENZENE <IS#1> CHLOROBENZENE-D5 (IS#2) 1, 4-DICHLOROBENZENE-D4 (IS*3) 4-BROMOFLUORODENZENE (SS) CHLOROMETHANE ** BROMOMETHANE VINYL CHLORIDE * CHLOROETKANE METHYLENE CHLORIDE ACETONE 2-BUTANONE 4-METHYL-2-PENTANONE 2-HEXANONE BROMOCHLOROMETHANE CARBON DISULFIDE 1,1-DICHLOROETHENE * 1.1-DICHLOROETHANE ** TRANS-1,2-DICHLOROETHENE CHLOROFORM * 1.2-DICHLOROETHANE 1,1,1-TRICHLOROETHANE CARBON TETRACHLORIDE 3ROMODICHLOROMETHANE 1,2-DICHLOROPROPANE # CIS-1,3-DICHLOROPROPENE TRICHLOROETHENE DIB R OMOCHL OR OMETHANE 1.1,2-TRICHLOROETHANE BENZENE TRANS-1,3-DICHLOROPROPENE DIBROMOETHANE BRCMOFORM ** TETRACHLOROETHENE 1,1,2,2-TETRACHLOROETHANE ** TOLUENE * CHLOROBENZENE ETHYL BENZENE * STYRENE M/P XYLENE 0-XYLENE CIS-1,2-DICHLOROETHENE 1.3-DICHLOROBENZENE 1.4-DICHLOROBENZENE 1,2-DICHLOROBENZENE 1,2-DIBROMO-3-CHLOROPROPANE TUT OO4 1725 1"25 0289 '.'0 12 3 4 c 6 -r cw 9 10 11 12 13 14 15 1A t -r i -• IS 19 20 21 22 23 Z4 2? 26 2.' 2*-*. i'-? SC- SI •—' ••» 33 34 25 36 37 28 19 40 4t -;2 •*3 •*4 45 '.':•> -^ 2 •^ 4 5 6 /* 3. m/z Scan 114 185 117 374 150 519 95 440 NOT FOUND NOT FOUND NOT FOUND NOT FOUND 84 72 NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND 91 294 NOT FOUND 91 385 NOT FOUND 1O6 392 NOT FOUND NOT FOUND l')6 497 l'»6 502 1 '>6 520 NOT FOUND Ret(L) Rati 6. 08 1. 01 12:26 1.00 17: 16 1. 00 14: 38 1. 00 1. 16 1: 28 1: 18 1: 32 Time Ref RRT Meth 6: 1O 1 1. OOO A BB 12: 28 21. 000 A BB 17: 18 3 1. 000 A B3 14: 40 12 378 A BB 2: 24 1 0 389 A BB 9: 48 2 0. 786 A BB 12: 5O 21. 029 A BB 13 04 2 1. 048 A BB 16: 34 3 0. 958 A BB 16: 44 3 0. 967 A BB 17: 20 3 1. 002 A BB o RRT(L) Ratio Amnt 1 OOO 1. 00 5. OO 1 000 1 . 00 5. 00 1. 000 1. 00 5. 00 2. 386 1. 00 5. 27 0. 207 0. 239 0. 212 0 250 Area(Hght) 9262. 6283. 3569. 5319. 784. 55. 221 98. 147. 162. 67. Amnt(L) R 5. OO 5. 00 5. 00 5. OO Amount 5. 000 UG/L 5. 000 UG/L 5. OOO UG/L 5. 269 UG/L 1. 218 UG/L '/.Tot 22. 83 22. 83 22. 83 24. 06 5. 56 0. 025 UG/L 0. 11 0. 072 UG/L 0. 33 0. 091 UG/L 0. 41 O. 138 UG/L 0. 63 0. 157 UG/L 0. 72 0. 091 UG/L 0. 41 .Fac R.Fac(L) Ratio 1. 000 1.OOO 1. 00 1. 000 1. OOO 1. 00 1.000 1.000 1.00 0. 574 0. 545 1. 05 2: 24 1. 00 0. 391 0. 99 5. 00 0. 085 0. 348 0. 24 CMN •H oo f\ 0290 r;o Ret(L) 10 ; 1 12 •to 1 4 1 S 1 fc 17 IS IV1 20 .»^ ^ ~2 J?'w 24 -IE C. .» '2f-. 27 2S 29 2O 31 32 33 34 35 3i> 37 J8 39 40 41 A5 -3 4 4 45 2: 3: 9: 11: 4: 2; 2: 3: 2: 4: 5: 4: 4. 8: 7; "=). 6: 11: 10: 5: 10: 11: 14: 10: 15: 9: 12: 12: 13: 13: 13: 3: 16: 16: 17: 18: 04 50 38 22 04 10 00 02 36 14 10 30 46 04 16 08 42 22 42 06 22 28 00 50 02 46 30 48 46 02 44 44 32 42 18 42 Ratio RRT(L) Ratio 0 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0 0. 0. 0 0. 0. 0. 0. 1. 1.00 0. 1. 1 . 00 1 . 1. 1. OO 1. 1. 0. 1.00 0. 1 OO 0. 1 . 00 1 . 1. 337 625 775 914 663 353 326 495 424 690 842 362 383 649 584 735 539 914 861 410 834 922 811 871 209 786 1 . 00 O05 029 1 . 00 107 048 1 . 00 105 609 958 1. 00 967 l.OO 002 1 . 00 083 Amnt 0. 02 0. O7 O. O9 0. 14 0. 16 0. 09 Amnt(L) R. Fac R.Fac(L) Ratio 5. 00 0. 009 5. OO O. 035 1O. 00 O. 008 5. 00 0. 041 5. OO 0. 045 5. 00 0. 019 1. 772 43O O. 858 0. 00 0. Ol O. 01 1. 496 0. 03 1. 444 0. 03 1. 034 0 02 TUT OO4 1727 L 000J72, 3/17/93 11: 39: OS Acquisition started 0291 3/17/93 11:37:12 -:q.uire Run 0:WB0317 :2/17/93 11:39:00 + 0:00 Free sectors: 13724 =»*ple: CLP, , , VBLK1, LOW, WATER, WB0317, VGA, BLANK, -•nds. : I500A:25ML OLV01 PURGE W/ 5PPD IS ?< SS r-rmula 25ML AMBIENT PURGE Instrument: I5OOA -jbmitted by: Analyst: RJL Start ing Scan: 0 of Weight: Acct. No: GC I Desc : VI ?q. TeiT.p * ( D e g C ) 35- 35 2 35-150 3 1 50- 1 50 al ve A : c 1 Rate ( C / m i n ) 8. 0 - osed not ready and being stabilized (=•1 ^ n e orl +• Time (minutes) **# E l a p s e d t i m e : 720 0. OOO 0. O Min period 6. 6 14. 3 3. 0 Valve B total 6. 6 20. 9 23. 9 open Injector A GC oven Transfer-1ine Ion source 150 Deg C 35 Deg C 215 Deg C 180 Deg C *•** Instrument parameters *** Post acquisition state Filament : Off M u l t i p l i e r : Off '~'DE: El < + > Centroid + Temp - Sequence: BF ( 2 time windows. ) Sequence Window descriptor: scan time: ft 1 Number of cycles: 28 Filament is OFF Mult ip1ier is ON BF Mass intervals: 2 000 s Posi t ive ion Master rate: mode. 16 MPW: 3 MPW: 80 MA: 15 TH: 1 Ifit # Lo mass Hi mass Time DL: 1 33. 510 300 590 !. 000 £*quence Window # 2 Number of cycles: Filament is ON Multip 1ier is ON 3-*n descriptor: BF Mass intervals: 'c-tal scan time: . OOO Positive ion mode Master rate: 16 "••W: 3 MFW: 80 MA: 15 TH: 1 BL: Ir?t # Lo mass Hi mass Time 1 33. 510 300. 590 2. 000 Calibration table: D: CAL02199J Interface number Instrument type Full scale mass Zero scale mass Intens i ty/ion Peak width Offset at low mass Offset at high mass Voltage settling time(ms) 20 O Q 1177 1 2 1000. 0 0 u u mmu mmu mmu TUT 004 1728 L 000172 Current instrument parameters. Positive ion mode 0292 Resolution (high) Resolution (low) Quad offset Quad programming Lens offset Lens programming Ext offset Ext programming Col lector Ion offset Ion programming Rod polarity 128. 128. O 0. -50. 0. 0. 0. 30. 7. 5. 00 OO 00 00 00 00 00 00 00 00 00 Negative ion mode 128. 00 128. OO 0. 00 0. 50. 0. 0. 0. 30. -3. Reverse Electron multiplier voltage Filament emission current Electrometer range Electrometer zero 00 00 00 00 00 OO 00 -5. 00 Norma1 984. 750. 10 "-7 126. 0 tvilyzer Fore Pressure . . . .*parator/Source Pressure 0. 010 Torr 0 356 Torr /17/93 12:08:24 ACQUISITION COMPLETED Scans 1 to 720 Centroid e Scans ••ntroid 720 Sees Out of r. 0. 2 1440 0 0. 0 Peaks per scan per sec 2348. 3. 2. TUT OO4 1729 LOGO i72;> QUALITY CONTROL/QUALITY ASSURANCE DATA 0293 METHOD: CLP 3'90 QLV01 25ML PURGE DATAFILE: STANDARD: TUNEFILE: WS0317 WS0317 WDFD0317 ANALYSIS TIME: ANALYSIS TIME: ANALYSIS TIME: 03/17/93 03/17/93 03/17/93 1 1 : 39 10: 48 9: 34 **#*** INTERNAL STANDARD AREA CHECK ****** INTERNAL STANDARD J 10 1, 4-DIFLUOROBENZEN ::--»0 CIILOR03ENZENE-D5 ( :26 1, 4 DICHLOROBENZEN DATA AREA 9262. 6283. 3569. STD AREA 9856. 6374. 4017. RATIO 947. 997. 897. CLP ACCEPT 607. - 607. - 607. - RATIO STATUS 1407. 1407. 1407. ****** INTERNAL STANDARD RT CHECK ****** INTERNAL STANDARD •: : 1 0 1 , 4-D I FLUOROBENZEN CI20 C:!LOR03ENZENE-D5 ( ^126 1.. 4-DICHLOROBENZEN DATA SCAN 185 374 519 STD SCAN I 184 373 518 DIFF :IN SECD 2 2 2 CLP ACCEPT DIFF STATUS +/- 20 SECS +/- 20 SECS +/- 20 SECS ****** SURROGATE RECOVERIES ****** SURROGATE AMT FOUND AMT ADDED PERCENT RECOVERY RECOV LIMITS STATUS C510 4-BROMOFLUOROBENZE 5. 3 5. 0 C015 BROMOMETHANE -0.0 50 0 1020 VINYL CHLORIDE * -0. 0 50. 0 105 0 0 807. - 1207. 887. - 1107. 867. - 1157. failed failed TUT 004 173O L 0 C 01 ^OCEDL'HE: TCA DIAGNOSTIC REPORT 3/17/93 12: DATA FILE: WB0317 REFERENCE: VI 11 •*:*«£ LIST: VI INITI REPORT: V1IS y : •• —— STANDARDS —— - -ROC U 3 3 3 45 CO C LIB 1 VI 2 VI •2 VI 4 VI 5 VI a VI 7 VI S VI ? VI 10 VI '; I VI 12 VI 13 VI 14 VI IS VI "it VI 17 VI IS VI 17 VI 20 VI 21 VI 52 VI 22 VI 24 VI 2? VI 26 V 1 17 VI ?:•= VI 29 VI 20 VI 3: vi 2* VI 3j VI 24 VI ~«5 VI 34 VI 27 VI 35 VI J? VI '40 VI x4i VI *2 VI 42 VI H« VI -;• vi ALIZATION OPTION: 2 - >< —— PLUS UNKNOWNS SED POSS RMS PROC USED POSS 2 1 3 1 3 1 0 20 5 1 0 16 3 1 0 15 3 1 MPOUNDS PROCESSED, 4 FOUND ENTRY REF 1 -184 2 -373 3 -518 4 -439 5 -38 6 -44 7 -39 8 -46 9 -72 10 -62 11 -115 12 -289 13 -341 14 -122 15 -65 16 -60 17 -91 18 -78 19 -127 20 -155 21 -135 22 -143 23 -242 24 -218 25 -274 26 -2O1 27 -341 28 -321 29 -153 30 -311 31 -344 32 -420 33 -325 34 -451 35 -293 36 -375 37 -384 38 -413 39 -391 40 -412 41 -112 42 -496 43 -501 44 -519 45 -561 3C.rmun PRED SEL DELTA PEAKS 185 185 . 1 374 374 1 519 440 440 . 1 3 8 . . . 4 4 . . 3 9 . . 4 6 . . 72 72 1 6 2 . . 115 290 342 122 6 5 . . 60 . 9 1 . . . 7 8 . . . 127 156 136 144 243 219 275 202 342 322 154 312 345 421 326 452 294 376 385 414 392 413 113 497 502 520 562 PROCESSING OPTION: 3 —— :•< - LIST NAMES 44: 2O 0294 — ~;- RMS STANDARD/UNKNOWN 35 V1IS/V1UNKS1 0 V1IS/V1UNKS2 0 V1IS/V1UNKS3 ——— - >< SAT >< ——— - FIT PEAKS M/Z 9S2 . 114 973 . 117 150 952 . 95 50 94 62 64 935 . 84 43 43 43 43 128 76 96 63 96 83 62 97 117 83 63 75 95 129 97 78 75 107 173 166 83 91 112 91 1O4 106 106 96 146 146 146 75 — CHRO — - TOP DELTA 185 374 519 440 72 294 385 392 497 502 520 PEAKS 1 1 1 1 1 •* 1 K *"* i O ~ i— h- ' L000173. I. T. ANALYTICAL SERVICES LIBRARY SEARCH REPORT PURGEABLE VOLATILE ORGANICS ANALYSIS 0295 \_xATA FILE: WB0317 SQUIRED: 03/17/93 11:39:00 ::r^DS. : I500A:25ML OLV01 PURGE W/ REMITTED BY: ANALYST: RJL 5PPB IS SS ACCOUNT NO. COMPOUND SCAN DELTA (UG/ML) 10 •10 30 1, 4-DIFLUOROBENZENE <IS#1> 185 0 5. OOO CHI OROBENZENE-D5 (IS*2> 374 0 5.000 1, 4-DICHLOROBENZENE-D4 (IS#3> 519 0 5.000 4-3ROMOFLUOROBENZENE (SS) 440 0 5.269 METHYLENE CHLORIDE 72 0 1. 218 FIT 982 973 O 952 935 SAT'D? O 0 0 0 O TUT OO4 173: CO CM O ££Z.T frOO Ifll TARGET COMPOUND COMPARISON COMPOUND: C836 METHYLENE CHLORIDE RAW DATA: WB0317 #72 03/17/93 11:39 SAMPLE: CLP,,,UBLK1,LOW,NATER.WB0317,UOA,BLANK, COHDS.: I500A:25ML OLU01 PURGE W/ 5PPB IS & 55 BASE M/Z: 49 RIC: 1856. CO 44. bT 22.3-i 42.9- 21. 4-; 100.0- 50.0-: M/Z 100.0- 50.0^ 0.0T -50. 0T 100.0^ i . ENHANCED DATA LIBRARY FILE: . . . . . . . . . 30 1 1 • 1 i i \ [ i i i i : WB0317 #72 t i i Ul #9 49 , . . BASE M/Z: 49 RIC: 1306. .. ... , ,T,^-T._^T i i | i i-i i | i i i i | i i i i , i i i i | i f:p le: CLP, , , VBLK1, LOW, WATER, WB0317, VOA, BLANK, ^snds. : I500A:25ML OL.V01 PURGE W/ 5PPB IS &-. SS ~:-mula 25ML AMBIENT PURGE Instrument: I 500A Weight: 0.000 mi ttfrd by: Analyst: RJL Acct. No. : . ;V-DUNT=HEIGHT * REF AMNT/(REF HEIGHT * RESP FACT) r-'-erp. fac. from Library Entry •-'o CAS # Name 0-00-0 CI01 BROKOCHLOROMETHANE U.S. # I 0-00-0 CI10 1, 4-DIFLUOROBENZENE (I.S. j 0-00-0 CI20 CHLOROBENZENE-D5 (I.S. #3) 4 *£5-frr=T3 -4 PCNTCM g OL m/z Scan Time Ref RRT Meth Area(Hght) Amount 7.Tot RIC 185 6:10 1 1.000 A DB 5860.* 50.000 UG/L 31.94 RIC 374 12:28 2 1.000 A BB 9825.* 50.000 UG/L 31.94 RIC 519 17:18 3 1.000 A BB 7641.* 50.000 UG/L 31.94 RIC 68 2. 16 1 0. 368 A BV 765. * 6. 525 4. 17 TUT OO4 1734 L000173-. PROCEDURE: FILTER/TIC I/ATA FILF: W30317 ~Ii TER SCAN PARAMETERS •^•iX. NUMBER TICS: 10 : '.-TABLE ENTRIES: 495 :f;AN TOLERANCE : 3 •TW. RIC HT CX3: 10 "IRST SCAN : 35 .AST SCAN : 1000 "I - THRESHOLD : 500 DIAGNOSTIC REPORT 3/1B/93 15:OO:37 0298 METHOD LIBRARY LISTS TIC I. S. LIBRARY: NBS SEARCH PROC : PEAK FINDER PROC: TCA I. S. LL : FILE NAME LIST ; LIBRARYIS SERLIB VOHE5 IS TCAREF2 COMPOUND ANALYSIS: TARGETS (QUAN LIST) 8 ILTER PROCESSING: IS PEAKS 3 • OTAL PEAKS 15 < 1ST SCAN 1 > LAST SCAN 0 <: RI TOTAL TARGET PEAKS 11 "1C PROCESSING: ^.:. SCAN* PURITY FIT i 68 844 858 REJECT PEAKS——————————————'.-• KIN < SCAN ':- MAX # TOTAL TOTAL C HT TOL PEAKS REJECTS TICS 6 7 0 14 1 MW COMPOUND NAME [BEFORE TIC THRESHOLD] 86 4-PENTEN-2-OL TUT 004 1735 000173., cr> :LI froo mi CM0 MID LIBRARY 03/17/93 11: SAMPLE: CLP, SEARCH aiBRARYNB} DhTA: WFrflHir » b? EH:! M Z: -r 39:00 t 2:16 . CALI: UB031T tt 3 PIC: yH'j. , , MBLK 1 , LOW , WATER , UB63 1 7 , UOfl , BLANK , COHDS.: I500A:: 1171 i SAMPLE C5.H10.0 1171 n M WT 86 B PK 45 RANK 1 1 655 PUR 844 C5.H8.0 1171 i M WT 84 B PK 45 RANK 2 1 529 PUR 838 C6.H14.0 1171 i M WT 102 B PK 45 RANK 3 1 1590 PUR 680 M/Z ENHANCED (S r .'5ML OLU01 PURGE W/ 5PPB IS £< SS 15B 2N 0T) 1 i , ,-T_,— ,-, — ,-, — . — . — ,_. — , — . — ^_, — . — , — . — , — . — , — | — , — , — , — , — , — , — . — , — , — j — , — , — , — , — , — . — . — . — . — j — . — , — , — . — , — . — , — . — . — , — . — , — . — . — ,^, „ — . — . — , — . — 4-PENTEN-2-OL CAS# 625-31-0 r .. . i 4-PENTVN-2-OL CAS# 2117-11-5 r i 1 .1 PRi r . 1 , 1 . . . , — ^ J 30 4 1 PANE, 2, 2 '-OX YE: IS- CAS# 108-26-3 40 1 ——— 1 ——— —— . ——— . ——— . ——— .- [—— . ——— . ——— . »--, ——— . ——— . -, ——— . ——— , ——— . ——— . ——— . ——— . ——— , ——— . ——— . ——— . ——— . ——— , ——— . ——— . ——— , ——— . ——— , ——— . ——— , ——— . ——— . ——— , ——— . ——— . ——— . ——— . ——— , ——— . ——— . —— . ——— . ——— , ——— r— , ——— ^ »--, ——— . ——— , ——— . ——— 50 60 70 80 90 100 CO o _J IX ORGANICS ANALYSIS DATA SHEET "lab Name: ITAS-KNOXVILLE_________ Contract: Lab Code: ITSTU Case No.: 53554 SAS No.: Matrix: (soil/water) WATER Sample wt/vol: 5.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ Heated Purge: N GC Column: DB-624___ ID: 0.53 (mm) Soil Extract Volume: ______(uL) 0300 SAMPLE NO. VBLK2 SDG No.: MW01 Lab Sample ID: WB0318 Lab File ID: WB0318 Date Received: Date Analyzed: 03/18/93 Dilution Factor: ____1.0 Soil Aliquot Volume: ___ .(uL) CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L 74-87-3———————Chloromethane__________ 74-83 -9———————Bromomethane____________ 75-01-4———————Vinyl Chloride_________ 75-00-3———————Chloroe thane___________ 75-09-2———————Methylene Chloride______ 67-64-1————————Acetone_________________ 74-97-5———————Bromochloromethane______ 75-15-0———————Carbon Disulfide________ 75-35-4———————1,1-Dichloroethene_________ 75-34-3———————1,1-Dichloroethane______ 540-59-0——————1,2-Dichloroethene (total) 540-59-0——————cis-l,2-Dichloroethene___ 67-66-3———————Chloroform_____________ 107-06-2——————1,2-Dichloroethane______ 78-93-3———————2-Butanone_____________ 71-55-6———————1,1,1-Trichloroethane____ 56-23-5———————Carbon Tetrachloride____ 75-27-4———————Bromodichloromethane____ 78-87-5———————1,2-Dichloropropane_____ 10061-01-5—————cis-1,3-Dichloropropene__ 79-01-6———————Trichloroethene_________ 124-48-1——————Dibromochloromethane____ 79-00-5———————1,1,2-Trichloroethane____ 71-43-2———————Benzene_______________ 10061-02-6————trans-1,3-Dichloropropene_ 106-93-4——————1,2-Dibromoethane_______ 75-25-2———————Bromoform_________________ 108-10-1——————4-Methyl-2-Pentanone____ 591-78-6——————2-Hexanone_____________ 127-18-4——————Tetrachloroethene_______ 79-34-5———————1,1,2, 2-Tetrachloroethane_ 108-88-3——————Toluene___________________ 108-90-7——————Chlorobenzene__________ 11111 5 1 1 11 1 11 1 5 1 1 1 1 1 11 1 1 1 1 1 5 511 1 1 U U U U 3L U U U U U U U U U U U U U U U U U U U U U U U U U U U U Kl i—bI- FORM I X-l L000173 ,- 3/90 IX ORGANICS ANALYSIS DATA SHEET 'Lab Name: ITAS-KNOXVILLE_________ Contract: Lab Code: ITSTU Case No.: 53554 SAS No.: Matrix: (soil/water) WATER Sample wt/vol: 5.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ Heated Purge: N GC Column: DB-624 ID: 0.53(mm) Soil Extract Volume: ______(uL) 0301 SAMPLE NO. VBLK2 SDG No.: MW01 Lab Sample ID: WB0318 Lab File ID: WB0318 Date Received: _____ Date Analyzed: 03/18/93 Dilution Factor: ____1.0 Soil Aliquot Volume: ___ CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L .(uL) 100-41-4 ——— • 100-42-5 ——— • 1330-20-7 —— • 541-73-1 ——— • 106-46-7 ——— • 95-50-1 ———— • Qf. 1 O — Q _ — — __. —— Ethylbenzene —— Styrene —— Xylene (total) —— 1, 3-Dichlorobenzene —— 1 , 4-Dichlorobenzene —— 1 , 2-Dichlorobenzene —— 1 , 2-Dibromo-3-Chloropropane _ 1 1 1 1 l 1 1 Uu Uuuuu TUT OO4 1738 L_ 0 0 0 1 7 3 FORM T Y--> IX ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS 0302 SAMPLE NO. Name: ITAS-KNOXVILT/E _ Lab code: ITSTU Case No.: 53554 Matrix: (soil/water) WATER Sample vrt/vol: 25. 0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ GC Column: DB-624 ___ ID: 0.53 (mm) Soil Extract Volume: ______ (uL) Contract: SAS No.: VBLK2 SDG No.: MW01 Lab Sample ID: WB0318 Lab File ID: WB0318 Date Received: _____ Date Analyzed: 03/18/93 Dilution Factor: ____1.0 Soil Aliquot Volume: .(UL) Number TICs found: CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L • CAS NUMBER COMPOUND NAME RT EST. CONC. Q TUT OO4 1739 L O O O i V 3 j FORM I X-TIC 3/90 COo CO DATA FROM FILE: WB0318 SCANS 45 TO 726 ACQUIRED: 83/18/93 3:29:00 CALI: WB0318 #3 SAMPLE: CLP,,,UBLK2,LOW,WATER,WB0318,UOA.BLANK, COMDS.: I508A:25ML OLUtU AMBIENT PURGE W/ 5PPB IS & SS 188 _ 3:28 200 _ 6:40 380 J 10:00 480 J 13:20 500 _ 16:40 600 J 20:00 700 _ 0 I I I \ C J 100.87: < 14032.) CI10 1,4-DIFLUOROBENZENE (15*1) CI28 CHLOROBENZENE-D5 <IS*2) CS10 4-BROMOFUJOROBEHZEHE (SS) CI26 1,4-DICHLOROBEHZENE-D4 (ISI3) c; CJ.' j . a n t l r a t i o n Report File: WBO31S n n f t j IMU4 "ata: Uo0318. TI x. -.- 18/93 9:20:00 v f. r:ple CLP, , , VBLK2, LOW, WATER, WB0318, VOA, BLANK, : --ds. . I500A:25ML OLVO1 AMDIENT PURGE W/ 5PPB IS ?< SS " -mule 25ML AMBIENT PURGE Instrument: I500A Weight: 0. 000 •" ..mitterf by: Analyst: PJL Acct. No. : •v ~UNT=ArrEA * REF AMNT/CREF AREA * RE5P FACT) • -r t p . fac. from Library Entry '.:; Nare CI10 1,4-DIFLUOR03ENZENE <IS#1) £ CI20 CHLORODENZENE-D5 (IS#2) 2 CI2& 1,4-DICHLOR03ENZENE-D4 (IS#3) " CS10 4-EROMOFLUOROBENZENE (SS) *• CO 10 CHLOROMETHANE ** i CO 15 BRCilOhETHANE •• C020 VINYL CHLORIDE * 3 C025 CHLOROETHANE ~ C030 METHYLENE CHLORIDE 10 CO35 ACETONE ;: C110 2-BUTANONE '. ..•? C205 4-KETHYL-2-PENTANONE :l- CZ-10 2-HEXANONE :4 C037 BRONOCHLOROMETHANE :t C040 CARBON DISULFIDE -.4 CC45 1, 1-DICHLOROETHENE » ' 1~ C050 1.. l-D I CHLOROETHANE ** : •= CO3-3 TRANS-1, 2-DICHLOROETHENE '.-? C060 CHLOROFORM * Z: C065 1,2-DICHLOROETHANE ;:: C11S 1, 1, l-TR I CHLOROETHANE -'. I C120 CARBON TETRACHLORIDE .-'I' C130 BROMODICHLOROMETHANE ?.-', C14G 1, 2-DICHLOROPROPANE * .?.-r C143 CIS-1, 3-DICHLOROPROPENE ;.'t C15O TRICHLOROETHENE .^7 C155 DIBROMOCHLOROMETHANE Z'5 C160 1, 1, 2-TR I CHLOROETHANE 2- C165 BENZENE Z" C172 TRA?4S-1. 3-DICHLOROPROPENE 2- C176 1,2-DIBROMOETHANE ."^' CISC BRCfiOFORM ** ..•3 C220 TETRACHLOROETHENE Z4 C225 1,1,2,2-TETRACHLORQETHANE ** 25 C23O TOLUENE » it C235 CHLOROBENZENE -'/ C240 ETHYL BENZENE * iS C245 STS'RENE 2>? C2--0 M/P XYLENE iO C252 0-XYLENE •il C054 CIS-l, 2-DICHLOROETHENE 42 C253 1,3-DICHLORODENZENE s.? C25-'- 1, 4-DICHLOROBENZENE -4 C255 1,2-DICHLOROBENZENE TUT 004 1741 -? C261 1,2-DIBROMO-3-CHLOROPROPANE ^000174* 0305 m/7 Scan 114 183 117 372 150 51 S 95 439 NOT FOUND NOT FOUND NOT FOUND NOT FOUND S-! 72 4C? 63 NOT FOUND NOT FOUND NCT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NUT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND 91 384 NOT FOUND NOT FOUND NOT FOUND NOT FOUND NUT FOUND 1 '': * 5OO Hi 518 NOT FOUND Ret <L> Rati t, : 08 0 99 12 26 1 00 17 16 1. 00 1 4 28 1 . 00 1 : IS 1: 28 t ~in i C.'J 1 32 Time Ref RRT Meth 6: 06 1 1 000 A BB 12: 24 21. 000 A B3 17: 16 3 1 000 A DB 14: 38 1 2 399 A BE 2 24 1 0. 393 A BE 2: O6 1 0 344 A SB 12: 48 2 1. 032 A BB 16: 40 3 0. 965 A BB 17: 16 3 1. 000 A BS o RRT<L) Ratio Amnt 1. 000 1. 00 5. 00 1. OOO 1. 00 5. 00 1 000 1. 00 5. 00 2. 386 1. 01 4. 92 0. 212 0. 239 0 ^ 1 T . fc 1 / 0. 250 Area<Hght) Amount /ITot 11089. 5.000 UG/L 21.33 7843. 5.000 UG/L 21.33 461 1. 5. 000 UG/L 21. 33 6671 4. 923 UG/L 21. 00 947. 1. 126 UG/L 4. SO 86. 2. 360 UG/L 10 07 46. 0. 012 UG/L O 05 SO 0. 062 UG/L 0. 26 49. 0. 053 UG/L 0. 22 Amnt(L) R Fac R. Fac<L) Ratio 5. 00 1. COO 1. 000 1. 00 5. 00 1. 000 1. 000 1. 00 5 00 1 . 000 1 . OOO 1 . OO 5. 00 0. 6O2 0. 611 0. 98 N 1 00 0. 391 1. 01 1. 13 5 00 0. 085 0. 379 0. 23 0306 M:j Ret(L) * • ^ « l I + . . ' ^ =." .i. ^ £.' ^ "3 "* *~. i j; ~( *™. "^ ~ T *"( ^, Z, j; .; -,' i V ;. . -t — t ^ S £• ~ _' T •— • i S.' ,-, 4 B S ",' ". ' Y ,;T t I 3 4 * iJ *•/ c •r ;j \z 1 1 1 1 1 1 1 1 1 1 1 1 1 1 'sL '. 3: 9 1 : 4 : 2: 2: 3: c.' . 4 : 5 4; *-* ' 8 ~? *=>: 6: 1 : 0 5: 0 : 1 : 3 : 0: e . 9 2: o : 3 : 3: 3 3 6: 04 50 38 22 04 10 00 02 36 14 iO 30 46 02 14 06 42 22 40 06 22 28 58 50 02 44 28 46 46 02 42 44 30 ~i 16 -52 - •i -i B 1 1 ~T S. IS 40 Ratio RRT(L) Ratio 1.02 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0 0. 0 0. 0 0. O. 0. 0. 0. 0. 1. 0. 1. 1 00 1 . 1. 1 1. 0. 0 1. GO 0 1. 00 1 1. 337 1.02 625 775 914 663 353 326 495 424 690 S42 362 383 646 582 732 539 914 S58 410 834 922 909 37 1 209 783 003 027 1.01 107 048 102 609 956 967 1. 00 002 1. 00 O81 Air.nt Amnt(L) R.Fac R.Fac(L) Ratio 2. 36 25. 00 0. 002 0. 016 0. 0? 0. 01 5 00 0. 006 2. 419 0 00 0 .06 5.00 0 017 1.409 0.0 0. 05 5 00 0. Oil 1 Oil 0. 01 TUT 004 1743 3/18/93 9:20:56 Acquisition started 0307 3/18/93 9:21:00 cquire Run O:WB0318 3/18/«?3 9:21:00 + 0:00 Free sectors: 12261 a.-nple CLP, , , VBLK2, LOW, WATER, WB0318, VOA, BLANK, --nds. : I5OOA:25ML OLVO1 AMBIENT PURGE W/ 5PPB IS 'rrmula: 25ML AMBIENT PURGE Instrument: 1500A ted by: Analyst: RJL Start ing Scan: 0 of SS Weight: Acct. No: 720 0. OOO -• V "£4 Desc *** GC not ready and being RR q. Temp (DegC) 35- 35 35-150 150-150 Ive A : closed Rate Time (minutes) <C/min) period total 6. 6 14 3 0 stab i 1 i z ed ##* Elapsed time : 0. O Min Post El < 8. 0 3. Valve S : *** Instrument acquisition state -> 6. 6 20. 9 23. 9 open parameters Filament Injector A : 150 GC oven : 36 Transfer-line: 214 Ion source : 180 Deg Deg Deg Deg C C C C ) Centroid + Temp - Sequence: BF •*•** Off Multiplier ( 2 time windows Off Sequence Window '•ran descriptor otal sc an time: Number of cycles: 28 Filament is OFF Mul t ip 1 i er is ON BF Mass intervals: 2. OOO s Positive ion mode. Master rate: 16 Int 1 MFW. 80 Lo mass 33. 510 MA: 15 Hi mass 3OO. 590 TH: 1 Time 2. OOO DL: u-?q.uence Window • an descriptor: ' :• t a 1 scan time: Number of cycles: Filament i s ON Multip1ier is ON BF Mass intervals: 2. OOO s Positive ion mode. Master rate: 16 Int 1 MFW: 80 Lo mass 33. 510 MA: 15 Hi mass 300. 590 TH 1 Time 2. 000 DL: Calibration table: D:CAL021992 Interface number Instrument type Full scale mass Zero scale mass Intensi ty /ion Peak width Offset at low mass Offset at h i g h mass 0 Q 1177 1 2 1000. 0 0 Voltage settling time(ms) 20 u u mmu mmu mmu TUT 004 1744 001 74- Current instrument parameters. Positive ion mode 0308 Resolution (high) Resolution (low) Quad offset Quad programming Lens offset Lens- programming Ext offset Ext programming Collector Ion offset Ion programming Rod polarity 128. 128. 0. 0. -50. 0. 0. 0. 30. 7. 5. 00 00 00 00 00 00 00 00 00 00 00 Negative ion mode 128. 00 128. 00 0. 00 O. 00 50. 00 0. 00 0. 0. 30. -3. -5. Reverse Electron multiplier voltage Filament emission current Electrometer range Electrometer zero OO 00 00 00 00 Normal 984. 750. 10 ~-7 126. 0 Analyzer Fore Pressure . . . Separator/Source Pressure 0 Oil O. 361 Torr Torr 3/18/93 9:50:17 ACQUISITION COMPLETED Scans 1 to 720 Centroid :de '.entroid Scans 720 Sec s 0. 3 Out of 1440. 0 X 0. 0 Peaks per 2330. scan 3. per sec 2. TUT OO4 1745 L 0 0 0 1 7 4 QUALITY CONTROL/QUALITY ASSURANCE DATA . 0309 METHOD: CLP 3'90 OLV01 25ML PURGE DATAFILE: WD0318 STANDARD: WS0318 TUNEFILE: WSFB0318 ANALYSIS TIME. 03/18/93 ANALYSIS TIME: 03/18/93 ANALYSIS TIME: 03/18/93 9: 20 8: 29 8: 20 ****** INTERNAL STANDARD AREA CHECK ****** INTERNAL STANDARD 10 1, 4-DIFLUOROBENZEN ."0 CHi QROBENZENE-D5 ( 26 1, 4-DICHLOROBENZEN DATA AREA 11089. 7843. 4611. STD AREA 11210. 7723. 5477. RATIO 997. 1 027. 847. CLP ACCEPT 607. - 607. - 607. - RATIO STATUS 1 407. 1407. 1 407. ****** INTERNAL STANDARD RT CHECK ****** INTERNAL STANDARD :iO 1, 4-DIFLUOROBENZEN J20 CHLOROBENZENE-D5 ( ;26 1, 4-DICHLORODENZEN DATA SCAN 183 372 518 STD SCAN I 184 373 518 DIFF :IN SEC: 2 2 O CLP I ACCEPT DIFF STATUS +/- 20 SECS +/- 20 SECS •*•/- 20 SECS ****** SURROGATE RECOVERIES ****** SURROGATE AMT FOUND AMT ADDED PERCENT RECOVERY RECOV LIMITS STATUS ilO 4-EROMOFLUOROBENZE 4. 9 5. O :i5 BROMOMETHANE -O O 50.O 20 VINYL CHLORIDE * -0. 0 50. O 98 O 0 8O7. - 1207. 887. - 1107. 867. - 1 1 57. fai led failed TUT OO4 1746 LOO 017 DIAGNOSTIC REPORT DATA FILE: REFERENCE: fvAME LIST: REPORT: TCA W30318 Vlll VI INITIALIZATION OPTION: V1IS 3/18/93 «7: 53: PROCESSING OPTION: 3 0310 — STANDARDS — USED POSS RMS 3 2 1 O 3 3 1 11 3 3 1 11 —— PLUS UNKNOWNS —— 3 PROC USED POSS RMS 2O 5 1 63 16 3 1 11 15 3 1 11 C - LIST NAMES - 3 STANDARD/UNKNOWN V1IS/V1UNKS1 V1IS/V1UNKS2 V1IS/V1UNKS3 45 COMPOUNDS PROCESSED, 4 FOUND L ID 1 2 3 4 5 *™* 7 S 9 ;o 11 12 13 14 5 '16 ^ ^ 18 19 20 21 22 23 £4 2^ 1:6 27 28 £? 30 31 32 "-.3 34 35 36 37 38 3V •+o Ai 42 43 41 45 ,unrt. LID VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI J\J\**U ENTRY 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 •s. REF -184 -373 -518 -439 -38 -44 -39 -46 -72 -62 -115 -289 -341 -122 -65 -60 -91 -78 -127 -155 -135 -143 -242 -218 -274 -201 -341 -321 -153 -311 -344 -420 -325 -451 -293 -375 -384 -413 -391 -412 -112 -496 -501 -519 -561 PRED 183 373 519 439 37 43 38 45 71 61 115 289 341 122 64 59 90 77 127 155 134 142 241 217 273 200 341 321 152 311 344 420 325 452 293 375 384 413 391 412 111 497 502 520 562 SEARCH SEL DELI 183 373 439 72 ——————— —— — ,,-s. OH i .'••>. — — — - A PEAKS FIT PEAKS M/Z 1 982 . 114 1 974 . 117 150 1 948 . 95 50 94 62 64 1 1 946 . 84 43 43 43 43 128 76 96 63 96 83 62 97 117 83 63 75 95 129 97 78 75 107 173 166 83 91 112 91 1O4 1O6 106 96 146 146 146 75 —— vr TOP 183 372 518 439 72 63 384 500 518 DELTA PEAKS . 1 -1 1 1 1 oO I- L 0001747 I. T. ANALYTICAL SERVICES LIBRARY SEARCH REPORT Qo I i PURGEABLE VOLATILE ORCANICS ANALYSIS L l FILE: WB0318 :-3UIREn: 03/18/93 9:20:00 ANALYST: RJL DN'DS. : I500A:25ML OLVO1 AMBIENT PURGE W/ 5PPB IS & SS JDMITTED BY: ACCOUNT NO. COMPOUND SCAN DELTA (UG/ML) FIT SAT'D? :ilO 1, 4-DIFLUOROBENZENE (IS*1) 183 0 5.000 982 0 :;Z'0 CHi_OROBENZENE-D5 <IS#2> 372 -1 5.000 974 O -T26 1, 4-DICHLOROBENZENE-D4 (IS#3) 518 -1 5.000 0 0 :£1O 4-EROMOFLUOROBENZENE (SS> 439 0 4.923 948 0 :'..'3O METHYLENE CHLORIDE 72 1 1. 126 946 0 ;035 ACETONE 63 2 2. 360 0 0 TUT 004 1748 1 0 0 0 1 7 4 • 6trZ.T trOO CO TARGET COMPOUND COMPARISON COMPOUND: C036 METHYLENE CHLORIDE RAW DATA: UB6318 #72 03/18/93 9:20 SAMPLE: CLP,,,UBLK2,LOW,WATER,WB0318,UOA,BLANK, CONDS.: I500A:25ML OLU01 AMBIENT PURGE W/ 5PPB IS & SS BASE M/Z: 49 RIC: 2072. L-- cr __j 55.9- 27.9-: 50.3- 25. 1-: 100.0- 50.0-: M/Z 100.0- 50.0-: 0.0-: -50.0-: ifle.e-' . . . . i . . . . I 1 i .. ... , . 1 1 ENHANCED DATA: WB0318 #72 1 . . . . . . . . , | 1 . . . , . . . . , . l l LIBRARY FILE: Ul #9 30 49 . . . , , . 1 BASE M/Z: 49 RIC: 1458. 1 | 1 • • • i • • • • | ' ' ' ' ' ' ' ' ' 1 ' ' ' ' ' ' ' ' ' 1 ' ' ' ' ' ' ' ' ' 1 ' ' ' BASE M/Z: 49 RIC: 3028. 1 1 1 • • ' r ' ' ' ' | '" ' ' T I '•' '-1-] fr-i 'T-f-i-,-1-1 f-T-T f If t » I | 1 1 1 50 60 70 80 90 . . . , . , 559. 503. 1800. CO CO O 100.0- 50.0-; M/Z OSZ.T trOO TARGET COMPOUND COMPARISON COMPOUND: C035 ACETONE RAW DATA: WB0318 #63 03/18/93 9:20 SAMPLE: CLP.-, A'BLK2,LOW, WATER,WB0318,VOA,BLANK, CONDS.: I500A:25ML OLU01 AMBIENT PURGE W/ 5PPB IS «< SS BASE M/Z: 44 RIC: 494. 21.7- 10. 8-; 7.0- 3.5^ ENHANCED DATA: WB0318 #63 1 ' 1 ¥ 1 • 1 • | ' 1 ' 1 ' 1 ' 1 ' 1 ' 1 ' 1 ' 1 ' T ' | ' 1 ' 1 ' 1 ' 1 ' I r I ¥ T T 1 • 1 J | ' ! f 1 ' 1 ' 1 ' 1 ' 1 ' 1 ' 1 ' 1 f BASE t • i • i • 1/ -,-,.,.,. ,.,.,. ,.,-,-,.,.,.,. ,.,-, -,.,-,- Z: 40 RIC: 103. LIBRARY FILE: Ul #10 BASE M/Z: 43 RIC: 10 I' i - i ' i -i'1'T-i-r-r-j 20 30 40 2136. •,'!',M'|-,.,.,.1M.,-I 50 60 O O O 217. 79. 1800. 00.0- 50.0^ 0.0-: - 50.0- CtCt (A- ' 1 • 1 1 i i i ' ' 1 ' —————————————— \ i r wouro E: FILTER/TIC TA FILE: WB0318 wTER SCAN PARAMETERS \ NUMBER TICS: 10 -TABLE ENTRIES: 495 AN TOLERANCE : 3 r-i. RJC HT. c/::: 10 ffST SCAN : 35 -.T SCAM : 1000 =! THRESHOLD : 5OO 0314 DIAGNOSTIC REPORT 3/22/93 15:29:58 METHOD LIBRARY ?< LISTS TIC I. S. LIBRARY: NBS SEARCH FROC : PEAK FINDER PROC: TCA I. S. LL : FILE NAME" LIST : LIBRARYIS SERLID VOME5 IS TCAREF2 COMPOUND ANALYSIS: TARGETS <aUAN LIST) 6 IS PEAKS 3 TOTAL TARGET PEAKS 9 TER PROCESSING: •OTAL <C 1ST > LAST EAKS SCAN SCAN 19 1 0 -—REJECT PEAKS——————————————> < MIN < SCAN > MAX # TOTAL TOTAL RIC HT TOL PEAKS REJECTS TICS 12 6 0 19 0 • I- T I C ' S FOUND. TUT 004 1751 U000175 IX ORGANICS ANALYSIS DATA SHEET 'Lab Name: ITAS-KNOXVILLE_________ Contract: Lab Code: ITSTU Case No.: 53554 SAS No.: Matrix: (soil/water) WATER Sample wt/vol: 25.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ Heated Purge: N GC Column: DB-624 ID: 0.53fmm) Soil Extract Volume: _______(uL) 0315 SAMPLE NO. MW03ORMS SDG No.: MW01 Lab Sample ID: W7322 Lab File ID: W7322 Date Received: 03/08/93 Date Analyzed: 03/17/93 Dilution Factor: ____1.0 Soil Aliquot Volume: ____.(uL) CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L 74-87-3 ————— 74-83-9 —— —— 75-01-4 ————— 75-00-3 —— —— 75-09-2 —— —— 67-64-1 ————— 74-97-5 —— —— 75-15-0 ————— 75-35-4 —— —— 75-34-3 —— —— 540-59-0 ———— 540-59-0 ———— 67-66-3 —— —— 107-06-2 ———— /O "O .j—~"— 71-55-6 —— —— 56-23-5 ————— 75-27-4 ————— 10061-01-5 —— 79-01-6 ————— 124-48-1 ———— 79-00-5 ————— 71-43-2 ————— 10061-02-6 —— 106-93-4 ———— 75-25-2 ————— 108-10-1 ———— 127-18-4 ———— 79-34-5 ————— —— Chloromethane —— Bromomethane —— Vinyl Chloride —— Chloroethane —— Methylene Chloride 4~&V^C U.W11C2 —— Bromochloromethane —— Carbon Disulfide —— 1 , 1-Dichloroethene —— 1 , 1-Dichloroethane —— trans-1, 2 -Dichloroethene —— cis-1 , 2 -Dichloroethene —— Chloroform —— 1 , 2-Dichloroethane —— 2 -Butanone —— 1 , 1 , 1-Trichloroethane —— Carbon Tetrachloride —— Bromodichloromethane —— 1 , 2-Dichloropropane —— cis-1, 3-Dichloropropene —— Trichloroethene —— Dibromochloromethane —— 1 , 1 , 2-Trichloroethane —— Benzene —— trans-1, 3-Dichloropropene —— 1 , 2-Dibromoethane —— Bromoform —— 4-Methyl-2-Pentanone —— 2-Hexanone —— Tetrachloroethene —— 1 , 1,2, 2-Tetrachloroethane ___ —— Toluene —— Chlorobenzene 1 1 1 1 2 5 1 1 5 1 1 11 1 1 5 1 1 1 1 1 7 1 1 4 1 1 1 5 5 8 1 4 4 U U U U B/ U U Us U U U U U U U U U Us U Us U U U U U Uss INm I--. •H h-Df- FORM I X-l L000175: 3/90 IX ORGANICS ANALYSIS DATA SHEET "Lab Name: ITAS-KNOXVILLE_______ Contract: Lab Code: ITSTU Case No.: 53554 SAS No.: Matrix: (soil/water) WATER Sample wt/vol: 25.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ Heated Purge: N GC Column: DB-624 ID: 0.53(mm) Soil Extract Volume: ______(uL) 0316 SAMPLE NO. MW03ORMS SDG No.: MW01 Lab Sample ID: W7322 Lab File ID: W7322 Date Received: 03/08/93 Date Analyzed: 03/17/93 Dilution Factor: ____1.0 Soil Aliquot Volume: ___ .(uL) CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/ 100-41-4 ——— • 100-42-5 ——— - 1330-20-7 —— - 541-73-1 ——— - 106-46-7 ——— - 95-50-1 ———— • 96-12-8 ———— - —— Ethylbenzene —— Styrene - —— Xylene (total) —— 1, 3-Dichlorobenzene —— 1 , 4-Dichlorobenzene —— 1 , 2-Dichlorobenzene —— 1 , 2-Dibromo-3-Chloropropane _ 1 1 1 1 1 1 1 Uu Uuu uu TUT OO4 1753 [_0001753 FORM I X - ? / Q O mi CN CO CB CM cn CO CO CO ct: 3 CO £ CJ <r <Xo <n - o ^ CM C-4 CM CM r- o co O O Z> «3 •• £k: Ln UT •— i UJ •-• ^t- _J t— •a: in S CJ tn CN C-J CO r-- 20. - CL oa: •ao I1 cn CL (J O Ct. CO 3 ^ O — • 1> O _1 3 O in in in ™ co •• in <r Q! CD _i in o •-• • • •• LU • _i cn o_ aii en cj CN ino LU ru o CM ^-i CJ cn cn M fe I <s> *—i cno oo cn LU2 LU8 o ai CO c-j ^H CJ CO i LD 1-.-anti tat ion Report File: W7322 :a':a: W/322. TI ' j/ 17/^3 12: 53: 00 :^p le: CLP, 53554, MW01, MW030RKS, LOW, UiATER, W7322, VOA, MS, -^r-ds. : I500A:25ML QLV01 PURGE Ul/ 5PPB IS fc SS r--muls 25ML AMBIENT PURGE Instrument: I500A Weight: 0. OOO ->". emitted by: ITEK Analyst: RJL Acct. No. : 53554 -••DUNT = AREA * REF AMNT/lREF AREA •» RE^P FACT) - r = ; p . -fac. from Library Entry -•ir Ns^-.s i CI10 I.- 4-DIFLUORODENZENE <15*1) I CI20 CHLOROBENZENE-D5 <I5#2> :• CI26 1, 4-DICHLORODENZENE-D4 (I5«3> - CSM 4-BROMOFLUORODENZENE (SS) -j C010 CHLOROMETHANE ** i CO 15 BROMOMETHANE ' CO?0 VINYL CHLORIDE -» 3 C025 CHLOROETHANE -•=• C03O METHYLENE CHLORIDE : -"• C035 ACETONE -. I C11O 2-BUTANONE : 2 C205 4-METHYL-2-PENTANONE -.3 C21O 2-HEXANONE 14 C037 BROMOCHLOROKETHANE 15 CC40 CARBON DISULFIDE Vt> CC-15 1, 1-DICHLOROETHENE * ' ' C050 1, 1-DICHLOROETHANE *# ~ C053 TRANS-1,2-DICHLOROETHENE -"";••? C060 CHLOROFORM * :: C065 1, 2-DICHLOROETHANE 2: C115 1 , 1 , 1-TRICHLOROETHANE :.?. Cl^O CARBON TETRACHLOR IDE "..:-. C130 BROMODICHLOROMETHANE I1* C140 1, 2-DICHLOROPROPANE * 25 C143 CIS-1, 3-DICHLOROPROPENE Tt. C15O TRICHLOROETHENE - C155 DIBROMOCHLOROMETHANE r.£ C160 1, 1, 2-TRICHLOROETHANE -o Cl/b5 BENZENE i'0 C172 TRANS-1, 3-DICHLOROPROPENE Z; C176 1,2-DI3ROMOETHANE :-: C180 BROMOFORM *# 3" C22O TETRACHLOROETHENE y* C225 1, 1, 2, 2-TETRACHLOROETHANE •*•» ;7 C230 TOLUENE * It C2oJ CHLOROBENZENE .•-.' C2^10 ETHYL BENZENE * "••5 C245 STYRENE 29 C25O M/P XYLENE -iO C25? 0-XYLENE ~\ COS-1 CIS-1, 2-DICHLOROETHENE -2 C253 1,3-DICHLORO3ENZENE .2 C254 1, 4-DICHLORCBENZENE -—--- C255 1, 2-DICHLOROBENZENE ~"UT u°4 -5 C261 1,2-DIBROMO-3-CHLOROPROPANE L 0001755 0319 m/z Scan 114 1 84 117 374 150 519 95 440 NOT FOUND NOT FOUND NOT FOUND NUT FOUND 84 73 NOT FOUND NOT FOUND 43 293 NOT FOUND NOT FOUND 7fc 66 96 61 63 92 96 79 83 128 62 156 97 136 NOT FOUND NOT FOUND NOT FOUND NOT FOUND 95 201 NOT FOUND NOT FOUND 7S 153 NOT FOUND NOT FOUND NOT FOUND lit 326 NOT FOUND 91 293 112 375 91 384 NOT FOUND 106 392 106 412 9t 113 14& 497 1 •; 6 5O2 l-':6 520 NOT FOUND Ret(L) Rati 6 08 1 . 00 12: 26 1. 00 1716 1. 00 14 38 1 00 1: 16 1: 28 1: 18 1 : 32 Time Ref 6: OS 12: 28 17: 18 14: 40 2: 26 9: 46 2: 12 2: 02 3: 04 2: 38 4: 16 5: 12 4: 32 6: 42 5: 06 10: 52 9 46 12: 30 12: 48 13: 04 13: 44 3: 46 16: 34 16: 44 17: 20 o RRT<L: 1 000 1. 000 1. 000 2. 386 0. 207 0. 239 0. 212 0. 250 1 2 3 1 1 2 1 1 1 1 1 1 2 2 2 2 2 2. 2 2 2 1 3 3 3 1 1. 1. 2. 0 0 0. 0 0 0. 0. 0 0 0 0 0 0. 1. 1 1 1 0. 0. 0 1 Rati 1. 00 1. 00 1. 00 1. 00 RRT 000 000 000 391 397 783 359 332 500 429 696 848 364 537 409 872 783 003 027 048 102 614 958 967 002 o Meth A BB A DB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB Arr.n t 5. 00 5. OO 5. 00 5. 24 AreaCHgh 10133. 7156. 4302. 5787 1314. 206. 742. 4932. 50. 314. 376. 35. 72. 10179. 9175. 12918. 11346. 7001. 221. 187. 51. 8024 140 174. 1 19. Amnt ( L) 5 00 5. 00 5 00 5 00 t) Amount 5. 5. 5. 5. 1. 1. 0. 4. 0. 0. 0. 0 0. 7. 3. 7. 4. 4. 0. 0. 0. 10. O. 0. 0. R. Fac 1. 000 1. 000 1. 000 0. 571 000 000 000 240 866 902 225 578 025 321 209 057 029 222 832 706 473 404 064 152 051 677 109 140 134 UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG./L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L R. Fac <L> 1. 000 1. 000 1. 000 0 545 '/.Tot 7 7 7 7 2 2 0 6 0 0 0 0 0 10 5 1 1 6 6 0 0 0 15 0o 0 Rat 1 1 1 1 . 32 . 32 . 32 67 73 . 79 . 33 . 70 . 04 . 47 . 31 . OS . 04 . 57 . 61 23 55 . 45 . 09 22 . 07 . 63 16 . 21 . 20 i o 00 . 00 . 00 . 05 -om 1. 01 0. 391 1. 01 1. 87 5 00 0. 130 0. 348 0. 37 o OJ o • p-f <oo: **x _] -—u •Du. or u •0u. a: ^ _j ^^jjc E C e < 0 • r4 •P ^-« cttr o •r« 4J CC ce i * COo o -0 f-.o 6 -f)00 0 o0 in cu a 0- vH O *-t fx if) ID n c\j r^* CO -4) t"» o o o VH O T-l O If) CO CM m cr r'« i iV in O O q. ru vfl 1-1 CO o o 0o in r'j r*ij o OJb l> -0 CO o o o CVJo CD O ~ TH V - '• • rd — -o o-oo 0 0 0 rd oo ro n -o oo in o- "3" o o o f-v in «-« m o n •too o o o o o o o o o m in in ffj n r.i in o r'j t o o ro — ^ o o o n -t -t o o o o o o o o n m n t\i n i KT *-* •— 1 O O O 0 0 0 •o ro o 03 O T CD n r- o o -• N CO O CO 0 ~ 0 O O o o o o o o o o o in in in .-« O Cl Cd O 0 O O O r-l T-> O O O O •o CD n o o o o o o -< r-. n t in -r »^- ' :' ,-, m 03 0- o n rdt •-« oo in ru rd N 0o «~t co -o if) r- m o- o o o o o o 0o «M •^ ^" "-0 00 CJ Cil --f o *i o -t rd T m t-- o- -o ~-> r--N o n f-,. -0 ._, rd no (d ri oo in m 03 n oo *-4 ai >4 03 o o o oo •-1 rd *o rd 13* './' i*d O u"< O iVl (>• •"' tj- m •rH ^, fv. Y-< 1-1 mo CD 1-1 oo m »H f^ h- O O 1-4 0- 03 CO O O O O O T-« ("d C' U") -i -t O -.,.,,, 0- CO 1-1 00 00 0 0 0 0 rd - o N ^ n fv TH <f ,H ^i rd >o oo *-* oo N n m o o ^ 0 0 o o o o o o m in m r- o -o t t o •* t o O O O o o o r«i r- o o o o o o o o 0 T CO T in Cl Cd Til n <•> •••i C>Jo o CDin CO 6 CO *-•o 0 oo o TH in TH o o0 - o oo •T o n co \>-< -• t rd o -• o o ni d r-< r-l O o h- o- r^ co t 06'-' N cvi n o o~ ro O h- O o o o o o o o o o in in in IT) CO — O --0 — ' o o o 1-1 O '-' O o o o lO O^ OD ^5 ^5 lf^ »-* o fr- - — . o -< o o o o ^f* 'ct* ro vj" tj* (*"l CO C) -0 • f • '. co n o o o 6 <r t •* n •* o i-< •-» o m •* rd o o 6 d o o o o in m *t ri »-i .1 o d o o o o CJ- O O _ O O 0 0 ™2 <1 1 03 • r - . • ! H-D h- Current instrument parameters. Positive ion U Resolution (high) Resolution (low) Quad offset Quad programming Lens offset Lens programming Ext offset Ext programming Col lector Ion offset Ion programming Rod polarity 128. 128. 0. 0. -50. 0 0. 0. 30. 7. 5. 00 00 00 00 00 00 00 00 00 00 00 mode Negative ion mode 128. 00 128. 00 O. 00 0. 00 50. 0. 0. O. 3O. -3. -5. Reverse Electron multiplier voltage Filament emission current Electrometer range Electrometer zero 00 00 00 00 00 00 00 Norma1 984. 750. 10 ~-7 126. 0 • -.alyzer Fore Pressure . . . '•sparat or /Source Pressure 0. 009 Torr 0. 372 Torr 3/17/93 13:22:23 ACQUISITION COMPLETED Scans 1 to 720 Centroid •»n tr o i d Scans Sees Out of '/. Peaks per scan 720 0 4 1440 0 0. 0 4762. 7. per sec 3. L 0001 753 TUT 004 1758 QUALITY CONTROL/QUALITY ASSURANCE DATA 0323 METHOD: CLP 3'90 OLV01 25ML PURGE DATAFILE: STANDARD: TUNEFILE: VV7322 WS0317 W3FB0317 ANALYSIS TIME: ANALYSIS TIME: ANALYSIS TIME: 03/17/93 12: 53 03/17/93 03/17/93 10:48 9:34 ****** INTERNAL STANDARD AREA CHECK ****** INTERNAL STANDARD 10 1, 4-DIFLUOROBENZEN 20 CHi OROBENZENE-D5 < 26 1, 4-DICHLOROBENZEN DATA AREA 1O133. 7156. 4302. STD AREA 9856. 6374. 4017. RATIO 1037. 112V. 107% CLP ACCEPT 607. - 607. - 607. - RATIO STATUS 140V. 1 4O7. 1 407. ****** INTERNAL STANDARD RT CHECK ****** INTERNAL STANDARD DATA SCAN STD SCAN DIFF CIN SEC: CLP ACCEPT DIFF STATUS 'I HO 1, 4-DIFLUOROBENZEN 184 C 1 20 CH:_ORODENZENE-D5 ( 374 ''.IZ6 1, 4-DICHLOROBENZEN 519 184 373 518 '- 20 SECS '- 20 SECS '- 20 SECS ****** SURROGATE RECOVERIES ****** SURROGATE AMT FOUND AMT ADDED PERCENT RECOVERY RECOV LIMITS STATUS 310 4-DROMOFLUORDDENZE :i5 BROMOMETHANE 020 VINYL CHLORIDE * 5. 2 -O. 0 -0. 0 5. 0 50 0 50. 0 105 0 0 807. - 1207. 887. - 110% 867. - 1157. failed failed TUT O04 1759 DATA FILE: VV7322 -&-ERENCE: V I 1 1 -".-irtE LIST: VI INITIALIZATION OPTION: 2 REPORT: VI IS PROCESSING OPTION: 3 0324 • ——— STANDARDS —— '30C USED POSS *s 3 3 3 2 3 3 45 CO'fPOUNDS : a "•0 \s 3 4 5 67 39 10 11 !2 13 !•* 15 16 ' T XL8 ! 9 20 ?1 22 23 24 L'5 26 "27 28 29 30 •1 » W A 32 23 24 35 36 37 33 39 40 41 42 13 X44 45 :OMPC LIB VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI 3UND >< ENTRY 1 2 3 4 5 6 7 B 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 1 1 1 — >< —— PLUS UNKNOWNS —— >< - LI RMS PROC USED POSS RMS STANDi 0 20 7 1 173 VI IS/1 11 16 6 1 14 V1IS/1 11 15 6 1 80 V1IS/' PROCESSED, 12 FOUND REF -184 -373 -518 -439 -38 -44 -39 -46 -72 -62 -115 -289 -341 -122 -65 -6O -91 -78 -127 -155 -135 -143 -242 -218 -274 -2O1 -341 -321 -153 -311 -344 -42O -325 -451 -293 -375 -384 -413 -391 -412 -112 -496 -501 -519 -561 W l— •• i 1 w ii m* ^m M n 1 PRED SEL DELTA PEAKS FIT PEAKS 184 184 1 931 374 374 . 1 946 5 2 0 . . . . . 441 440 -1 1 949 3 9 . . . . 4 5 . . . . . 4 0 . . . . 4 7 . . . . . 73 73 . 1 965 6 3 . . . . . 1 1 6 . . . . . 291 294 3 1 506 3 4 3 . . . . . 1 2 3 . . . . 6 6 . . . . 61 61 1 963 9 2 . . . 7 9 . . . 1 2 8 . . . . 156 1 3 5 . . . . . 143 . . 2 4 2 . . . 2 1 8 . . . . . 2 7 5 . . . 2O1 2O1 . 1 975 3 4 2 . . . . 3 2 2 . . . . 153 153 . 1 973 312 . . 3 4 5 . . . 421 . . 326 326 . 1 951 4 5 2 . . . 294 293 -1 1 978 376 375 -1 1 984 3 8 5 . . . 4 1 4 . . . . 392 . . . 4 1 3 . . . 112 113 1 1 914 4 9 7 . . . . 5 0 2 . . . . 5 2 O . . . . 5 6 2 . . . . . M/Z 114 117 150 95 50 94 62 64 84 43 43 43 43 128 76 96 63 96 83 62 97 117 83 63 75 95 129 97 78 75 107 173 166 83 91 112 91 104 106 106 96 146 146 146 75 TOP DELTA PEAKS 184 . 1 374 . 1 519 . 1 440 . 1 73 293 66 61 92 79 128 156 136 -1 01 153 326 293 375 384 392 412 113 497 502 520 h-D I- 0325 I. T. ANALYTICAL SERVICES LIBRARY SEARCH REPORT PURGEABLE VOLATILE ORGANICS ANALYSIS -rA FILE: VV7322 SUIRi-D: O3/17/93 12:53:00 -iDS. . I5OOA:25ML OLV01 PURGE W/ 5PPB IS !< SS liMITTEi; BY: ITEK COMPOUND 10 1-4-DIFLUQROBENZENE .-0 CH: OROBENZENE-D5 (IS*2> £6 1.4-DICHLOROBENZENE-D4 <IS#3> -.0 4-BSOMOFLUOROBENZENE (SS) Z'O MEIHYLENE CHLORIDE :5 4-n^THYL-2-PENTANONE -5 1,1-DICHLOROETHENE * -•0 TRICHLOROETHENE r5 BENZENE -O TETKACHLOROETHENE Z'O TOi_UENE * '15 CHt. OROBEMZENE =4 CI3-1,2-DICHLOROETHENE ANALYST: RJL ACCOUNT NO. 53554 SCAN DELTA (UG/ML) FIT SAT'D? 1S4 374 519 440 "?3 292 61 201 153 32A 293 375 113 0 0 -1 -1 0 2 0 0 0 0 -1 -1 1 5 5. 5. 5. 1. 1. 47 3. 7. 4. 4. 10. OOO 000 OOO 240 866 902 578 222 832 706 473 404 677 981 946 0 949 965 506 963 975 973 951 978 984 914 0 0 0 0 0 0 0 0 0 0 0 0 0 TUT 004 1761 L000176 IX ORGANICS ANALYSIS DATA SHEET ab Name: ITAS-KMnYVT^.T.F._________ Contract: —^ Lab Code: ITSTU Case No.: 53554 SAS No. : Matrix: (soil/water) WATER Sample wt/vol: 25.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ Heated Purge: N GC Column: DB-624___ ID: 0.53 (van) Soil Extract Volume: _______(uL) 0326 SAMPLE NO. MW030RMSD SDG No.: MW01 Lab Sample ID: W7323 Lab File ID: W7323 Date Received: 03/08/93 Date Analyzed: 03/17/93 Dilution Factor: ____1.0 Soil Aliquot Volume: .(uL) CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L 74-87-3 ————— 74-83-9 —— —— 75-01-4 —— —— 75-00-3 ————— 75-09-2 ————— 67-64-1 ————— 74-97-5 ————— 75-15-0 —— —— 75-35-4 ------ 75-34-3 —— —— 540-59-0 ----- 540-59-0 — —— 67-66-3 —— —— 107-06-2 ———— "71 rr C f 56-23-5 —— —— 75-27-4 ————— "7 O O *T K 10061-01-5 —— 79-01-6 — — — 124-48-1 —— -- 79-00-5 —— —— 71-43-2 —— —— 10061-02-6 —— 106-93-4 — —— 75-25-2 —— —— 108-10-1 ———— RQ 1 — "7Q _£_ 127-18-4 ~—— 79 34 K ——— _ * -^ *j ^ ~t 1 no _Q Q _1 —— Chloromethane —— Bromome thane —— Vinyl Chloride —— Chloroethane —— Methylene Chloride AWC curie —— Bromochloromethane —— Carbon Disulfide —— 1, 1-Dichloroethene —— 1, 1-Dichloroethane —— trans-l,2-Dichloroethene —— cis-1 , 2-Dichloroethene —— Chloroform —— 1 , 2-Dichloroethane —— 2 -Butanone —— 1 , 1 , 1-Trichloroethane —— Carbon Tetrachloride —— Bromodichloromethane —— I, 2-Dichloropropane —— cis-1, 3-Dichloropropene —— Trichloroethene —— Dibromochloromethane —— 1 , 1 , 2-Trichloroethane —— Benzene —— trans-1, 3-Dichloropropene —— 1 , 2-Dibromoethane —— Bromoform —— 4-Methyl-2-Pentanone —— 2-Hexanone —— Tetrachloroethene —— 1 , 1 , 2 , 2-Tetrachloroethane —— Toluene —— Chlorobenzene l 1 1 1 2 5 1 1 5 1 1 12 1 1 5 1 1 1 1 1 7 1 1 4 1 1 1 5 5 7 1 4 5 U U U U B/ U U Us U U U U U U U U U Us U Us U U U U U U s s IN -0 FORM I X-l 3/90 L 0 C 0 ! i 6 3 IX ORGANICS ANALYSIS DATA SHEET ab Name: ITAS-KNOXVILLE_________ Contract: ~Lab Code: ITSTU Case No.: 53554 SAS No.: Matrix: (soil/water) WATER Sample wt/vol: 25.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ Heated Purge: N GC Column: DB-624___ ID: 0.53(mm) Soil Extract Volume: ______(uL) SAMPLE NO. MW030RMSD SDG No.: MW01 Lab Sample ID: W7323 Lab File ID: W7323 Date Received: 03/08/93 Date Analyzed: 03/17/93 Dilution Factor: ____1.0 Soil Aliquot Volume: ___ CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L .(uL) 100-41-4 ——— • 100-42-5 ——— - 1330-20-7 —— • 541-73-1 ——— • 106-46-7 ——— • 95-50-1 ———— • 96-12-8 ———— • —— Ethylbenzene —— Styrene —— Xylene (total) —— 1, 3-Dichlorobenzene —— 1 , 4-Dichlorobenzene —— 1 , 2-Dichlorobenzene —— 1 , 2-Dibromo-3-Chloropropane _ 1 1 1 1 1 1 1 Uu Uuuu u TUT 004 1763 0 0 0 17 6 -i FORM I X-2 3/90 CO CM COo DATA FROM FILE: W7323 SCANS 45 TO 720 ACQUIRED: 63/17/33 13:25:60 CALI: W7323 *3 SAMPLE: CLP,53554,MW01,MM930RMSD,LON,WATER,UU7323,UOA,MSD, CONDS.: I500A:25ML OLU01 PURGE W/ 5PPB IS I SS 100 _ 3:20 200 _ 6:40 300 _ 10:00 400 J 13:20 500 _ 16:40 600 J 20:00 700 _ r 100.0^ ( 31008.) CI10 1/4-DIFLUOROBENZENE (IS#1) CI20 CHLOROBENZENE-D5 <I5#2) CS10 4-BROMOFLUOROBENZEHE (SS) CI2G 1,4-OICHLOROBENZENE-D4 (IS#3) I- Ij I- -J Quantitation Report File: W7323 0329 Data: W/323. TI 03/17/93 13:23:OO ?**ple: CLP, 535S4, KWOi, MW030RMSD, LOW, WATER, W7323, VOA, MSD, onds. : I500A:2SML OLV01 PURGE W/ 5PPB IS 8< SS ^•rmula: 25ML AMBIENT PURGE Instrument: I500A Weight: "Submitted by: ITEK Analyst: RJL Acct. No. .-nOUNT=AREA * REF AKNT/<REF AREA » RESP FACT) r»*p. fac. from Library Entry 1,4-DIFLUOROBENZENE (IS#1) CHLOROBENZENE-D5 (IS#2) 1, 4-DICHLOROSENZENE-D4 ( 4-BROMOFLUOROBENZENE (SS) CHLOROMETHANE ** BROMOMETHANE VINYL CHLORIDE * CHLOROETHANE METHYLENE CHLORIDE ACETONE 2-BUTANONE 4-METHYL-2-PENTANONE 2-HEXANONE BRCMOCHLOROMETHANE CARBON DISULFIDE 1, 1-DICHLOROETHENE * 1, 1-DICHLOROETHANE »» TRANS-1,2-DICHLOROETHENE CHLOROFORM * 1, 2-DICHLOROETHANE 1,1> 1-TRICHLOROETHANE CARBON TETRACHLORIDE BRCMODICHLOROHETHANE 1, 2-DICHLOROPROPANE * CIS-1,3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1>2-TRICHLOROETHANE BENZENE TRANS-1,3-DICHLOROPROPENE DIBROMOETHANE BROMOFORM *# TETRACHLOROETHENE 1, 1,2, 2-TETRACHLOROETHANE ** TOLUENE * CHLOROBENZENE ETHYL BENZENE * STYRENE M/P XYLENE 0-XYLENE CIS-1,2-DICHLOROETHENE 1.3-DICHLOROBENZENE 1.4-DICHLORODENZENE 1,2-DICHLOROBENZENE 1,2-DISROMO-3-CHLOROPROPANE 0. 000 53554 No 1 3 •1 5 4, ;•• 8 >? 10 1 1 * e. 13 14 l 5 16 17 IB 19 20 21 22 23 24 25 2i -, T ft. -• 25 29 30 31 32 33 1-4 35 36 37 38 29 40 41 42 43 44 •<5 Name CI10 CI26 CS1O C010 C015 C020 C025 C030 C035 C110 C205 C210 C037 C040 C045 CO5O C053 C060 CO65 C115 C120 C130 C140 C143 C150 C155 C160 C165 C172 C176 C18O C220 C225 C23O C235 C240 C245 C250 C252 C054 C252 C253 C254 C261 TUT OO4 1765 L 0 0 0 1 7 6 0 Mo 12 3 4 5 s 67 S 9 10 11 12 13 14 : 5 16 17 IS I? !'0 21 22 23 24 25 26 7/-T 23 19 30 1 -32 ""V "^ 34 2? 26 37 3)2 .".'9 40 4J •i'2 -3 44 4? -.0 I 2 3 * 5 6 7 8 c m/z 114 117 150 95 NOT NOT NOT NOT 84 NOT NOT NOT NOT NOT 76 96 63 96 83 62 NOT NOT NOT NOT NOT 95 NOT NOT 78 NOT NOT NOT 166 NOT 91 112 91 NOT 106 NOT 96 146 146 NOT NOT Ret 6: 12 17 14 1 1 1 1 2 Scan 184 374 519 44O FOUND FOUND FOUND FOUND 73 FOUND FOUND FOUND FOUND FOUND 66 61 93 80 128 154 FOUND FOUND FOUND FOUND FOUND 202 FOUND FOUND 154 FOUND FOUND FOUND 326 FOUND 293 375 384 FOUND 391 FOUND 113 497 5O1 FOUND FOUND Time Ref RRT 6: OS 12:29 17: 18 14: 40 2: 26 2: 12 2: 02 3: 06 2: 40 4: 16 5: 08 6: 44 5: 08 10: 52 9: 46 12: 30 12: 48 13: 02 3: 46 16: 34 16: 42 1 2 3 1 1 1 1 1 1 1 1 2 2 2 2 2 2 2 1 3 3 (L) Ratio RRT(L) 08 1 . 00 26 1 OO 16 1. 00 38 1 . 00 16 28 18 32. 24 1. 01 1. 000 1. OOO 1. 000 2 386 0. 207 0. 239 0. 212 0. 250 0. 391 1. 000 1. 000 1. 000 2. 391 O. 397 0. 359 0. 332 0. 505 0. 435 0. 696 0. 837 0. 540 0 412 0. 872 0 783 1. 003 1. 027 1 045 0. 614 0. 958 O 965 Ratio 1. 00 1. OO 1. 00 1. 00 1. 01 Meth A BB A BB A DB A BB A BB A DB A BB A BB A BB A BB A BB A BB A DB A DB A BB A BB A BB A BB A BB A BB A BB Amnt 5. 00 5. OO 5. 00 5. 48 1. 85 ArtaCHgh 11110. 8482. 5242. 6640. 1425. 520. 5519. 38. 454. 409. 197. 11546. 11025. 13583. 12527. 8698. 210. 119. 9786. 63. 62. Amnt (L) 5. 00 5. OO 5. 00 5. 00 5. 00 t) Amount 5. 5. 5. 5. 1. 0. 4. 0. 0. 0. 0. 6. 3. 6. 4. 4. 0. 0. 11. 0. 0. R. Fac 000 000 000 483 845 144 672 018 423 208 294 910 884 837 167 616 051 082 875 O40 041 UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L R. Fac (L) 1. 000 1. 000 1. 000 0. 598 0. 128 1. 000 1. OOO 1. 000 0. 545 0. 348 7.Tot 7. 52 7. 52 7. 52 8. 25 2. 78 0. 22 7. 03 0. 03 0. 64 0. 31 0. 44 10. 40 5. 84 10. 28 6. 27 6. 94 0. 08 0. 12 17. 87 0. 06 0. 06 Ratio 1. 00 1. 00 1. 00 1. 10 0. 37 -0 -0 h- -^\ \- u C Q i t Q O O l trOO HI! TO TO ' 8C TO • TO 26 C8 Z.E QL 8C 90 ' frO 80 00 ' C6 ' CO O T 0 0 '2 0 0 0 0 T 0 T 0 0 0 0 0 0 }*i frtrfr 96fr \LC 8S8 OCtr T T T ZLL \L\ CL9 S86 20C 988 C8* 896 2CS fr29 J (1): • T ' T 0 0 '2 T T • T ' T 0 0 0 0 0 0 ' T >ej 2TO 2TO T88 LOO S20 S20 LL* T09 OOC T9C 8TO LCO TfrO COO Lb* /.frO a **; 0 0 '0 0 '0 I I I ' T ' T 0 0 •o 0 0 '0 i a 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 <~H s s s OT s s s •s Q •s fi 'S s e s s 1 4UUIV fro frO 88 80 €0 29 LI *B 88 T6 62 T2 cfr 20 L9 *T ^uu 0 0 T T 0 0 fr > '9 e 9 0 0 0 0 fr •o i>V 00 00 TO 00 00 00 00 00 00 00 66 TO eo 20 20 20 OI}< T T T ' T 'T ' T T T T T "0 ' T ' T • T ' T T ?M C80 200 Z96 BS6 609 SOT 8frO /.OT 620 SOO 98/ 602 TZ8 T T 8 226 frCS OT17 T98 frT6 6CS SCZ 178G 6fr9 CSC 29C 2^8 069 fr2* S6ir 92C CSC C99 fr!6 ZLL C29 zee <T)1) T ' T 0 "0 0 T 'T • T T ' T 0 T 'O 0 0 0 0 0 0 •Q 0 0 0 0 '0 0 0 0 0 •Q 0 •o 0 '0 •o '0 aa 00 oo TO oo 00 00 00 oo TO 00 66 TO CO 20 20 20 0141 T T T T T ' T T T • T • T 0 • T •T 'TI T *d 2tr 8T 2i^ 2C fr<7 frfr 20 9t- 8tr oe 9t 20 oe 00 82 22 90 2* 22 2fr 80 9T frO 9*7 OC OT frT 9C 20 00 OT frO 25 8C OS frO (1) :8T •LI :9T :9T C ^ C T :CT :CT :2T 2T :6 ^ S T 'OT •*\ ••\\ '•01 Z •01 : T T •9 •6 L 8 •<7 ^17 ^ :t» •'2 -C :2 :2^ :iT •6 C :2 »»« Sfr frt? V*" -J-<- «•• * T? 0*^ 6 3E LZ 9E C£ *e EE 2C TC OC 63 G2 i2 «?c 42 frc C2 22 12 02 61 81 L\ 91 41^ V " S. SI IT 01 or. irrn 3/17/93 13:23:01 Acquisition started 0332 3/17/93 :>^u ire v 2/17/93 13:23:00 tsmple. CLP,53554 trnds. 13:23:07 Run 0:W7323 Starting + 0:00 Free sectors: 13463 Scan: 0 of MW01, MW030RMSD, LOW, WATER, W7323, VGA, MSD, 720 I5OOA:25ML OLVO1 PURGE W/ 5PPB IS ?< 55 ?rmula: 25ML AMBIENT PURGE Instrument: I500A '.'emitted by: ITEK Analyst: RJL Weight: Acct. No: 1C Desc. : VI r,-»H. Temp Rate * (DsgC) (C/min) 33- 35 2 35-150 8. 0 3 150-150 ^ Ive A : closed »** GC not ready and being equilibrated *** Time (minutes) Elapsed time 0. OOO 53554 0. 0 Min period 6. 6 14. 3 3. 0 Valve B total 6. 6 20. 9 23. 9 open Injector A GC oven Transfer-1ine Ion source 150 Deg C 97 Deg C 216 Deg C 184 Deg C *** Instrument parameters *** Post acquisition state -> Filament . Off Multiplier : Off "IDE: El ( + ) Centroid + Temp - Sequence: BF ( 2 time windows. ) •Sequence Window -,an descriptor: otal scan time: Number of" cycles: \ Filament is OFF Multiplier is ON BF Mass intervals: 2. 000 s !8 Positive ion mode. Master rate: 16 3 MFW: 80 MA: 15 TH: 1 # Lo mass Hi mass Time 33. 510 300. 590 2. 000 DL: •E^uence W i n d o w an d e scr i ptor: '.•tal scan time: Number of cycles: Filament is ON Multiplier is ON BF Mass intervals: 2. OOO s Positive ion mode. Master rate: 16 -U: 3 MFW: 80 MA: 15 TH: 1 int # Lo mass Hi mass Time 1 33. 510 300. 590 2. 000 BL: Calibration table: D: CAL02199; Interface number Instrument type Full scale mass Zero scale mass Intensi ty/ion Peak width Offset at low mass Offset at h i g h mass Voltage settling time<ms) 20 0 Q 1177 1 2 1000. 0 0 u u mmu mmu mmu TUT OO4 1768 L 0001768 Current instrument parameters. Positive ion mode 0333 Resolution < h i g h ) Resolution (low) Quad offset Quad programming Lens offset Lens programming Ext offset Ext programming Col lee tor Ion offset Ion programming Rod polarity 128. 00 128. 00 0. 00 O. 00 -50. 00 0. 00 0. 0. 3O. 00 00 00 7. 5. 00 00 Negative ion mode 128. 00 128. 00 0. 00 0. 50. 0. 0. 0. 30. -3. -5. Reverse Electron multiplier voltage Filament emission current Electrometer range Electrometer zero 00 00 00 00 00 00 00 00 Norma1 984. 750. 10 '--7 126. 0 -•>-alyzei Fore Pressure . . . f*fiarator/Source Pressure 0 010 Torr 0. 375 Torr 3/17/93 13:52:34 ACQUISITION COMPLETED Scans 1 to 720 Centroid : )e T-. t r o i d Scans 720 Sees 0. 6 Out of 144O. 0 7. Peaks per scan per sec 0 0 5177. 7. 4. TUT 004 1769 L 0001770 A / / v wi Hi : DATA FILE: W7323 0334 ^REFERENCE: VI 11 ;.J»ME LIbT: VI INITIALIZATION OPTION: 2 PROCESSING OPTION: 3 REPORT: VI IS —— STANDARDS ———— >< —— PLUS UNKNOWNS —— X - LIST NAMES - > -^-n'OC USED POSS RMS PROC USED POSS RMS STANDARD/UNKNOWN 32 1 0 2O 6 1 60 V1IS/V1UNKS1 3 3 1 11 16 6 2 46 V1IS/V1UNKS2 3 3 1 11 15 6 1 SO V1IS/V1UNKS3 45 COMPOUNDS PROCESSED, 11 FOUND : c i ;J ;j- 4 ^ 6 T 39 * •"* 1 V.' 1 "l 12 13 14 15 16 __ 7 ~^ \ 8 i 9 20 21 22 23 54 25 26 27 29 &:? 30 31 32 33 24 25 36 37 3S 39 40 » « •» i 1-2 —•+3 44 4? :OMPC LID VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI 3UND > ENTRY 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 REF -184 -373 -518 -439 -38 -44 -39 -46 -72 -62 -115 -289 -341 -122 -65 -60 -91 -78 -127 -155 -135 -143 -242 -218 -274 -201 -341 -321 -153 -311 -344 -420 -325 -451 -293 -375 -384 -413 -391 -412 -112 -496 -501 -519 -561 PRED SEL DELTA PEAKS 184 184 . 1 374 374 . 1 520 440 440 . 1 3 9 . . 4 5 . . . 4 0 . . . 4 7 . . . 73 73 1 6 3 . . . 116 290 342 123 6 6 . . . 61 61 1 9 2 . . . 7 9 . . . 128 156 135 143 243 219 275 202 202 . 1 342 322 154 154 . 1 312 345 421 326 326 . 2 452 294 293 -1 1 376 375 -1 1 385 414 392 413 112 113 1 1 497 502 520 562 - — ~x'~ ^AT "i" .-• N. wM 1 .* FIT PEAKS 930 952 953 952 958 976 975 954 980 989 915 ^ M/Z 114 117 150 95 50 94 62 64 84 43 43 43 43 128 76 96 63 96 83 62 97 117 83 63 75 95 129 97 78 75 107 173 166 83 91 112 91 104 1O6 106 96 146 146 146 75 TOP DELTA 184 374 519 440 73 _ 66 61 93 80 128 154 202 154 326 293 375 384 391 113 497 501 L 00017? PEAKS 1 1 1 1 1 1 1 1 1 1 1 1 1 1 NN •H <J '?, '' H- ; H- x i. T. ANALYTICAL. SERVICES LIBRARY SEARCH REPORT PURGEABLE VOLATILE ORGANICS ANALYSIS 0335 FILF: W7323 :QUIRED: O3/17/93 13:23:00 jrxDS. : I500A:25ML OLV01 PURGE W/ 5PPB IS & SS ;j3MITTEn BY: ITEK COMPOUND C.. 10 1, 4-DIFLUOROBENZENE <IS*1) :i20 C!ii OROBENZENE-D5 CIS#2> :i26 1, 4-DICHLOROBENZENE-D4 <IS#3> "310 4-BROMOFLUOROBENZENE (SS) C030 METHYLENE CHLORIDE ;:.45 1.. 1-DICHLOROETHENE * .:;50 TRICHLOROETHENE :i65 BENZENE :£?0 TETRACHLOROETHENE 1230 TOLUENE » :^35 CHuOROBENZENE •:.;-54 C IS-1, 2-DICHLOROETHENE ANALYST: RJL ACCOUNT NO. 53554 SCAN DELTA (UG/ML) FIT SAT'D? O 0 O 0 0 0 0 0 0 0 0 O ]S4 374 519 440 73 61 202 154 326 293 375 113 0 0 -1 0 0 0 0 0 0 -1 -1 1 5. 5 5. 4 1. 4. 6. 3. 6. 4. 4. 10. 000 000 000 891 691 841 829 856 789 165 392 921 980 952 0 953 952 958 976 975 954 980 989 915 TUT 004 1771 t IX ORGANICS ANALYSIS DATA SHEET =ab Name: ITAS-KNOXVILLE_________ Contract: "Lab Code: ITSTU Case No.: 53554 SAS No.: Matrix: (soil/water) WATER Sample wt/vol: 25.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ Heated Purge: N GC Column: DB-624___ ID: 0.53(mm) Soil Extract Volume: ______(uL) u ooo SAMPLE NO. VLCS1 SDG No.: MW01 Lab Sample ID: LCS0318 Lab File ID: LCS0318 Date Received: 03/08/93 Date Analyzed: 03/18/93 Dilution Factor: ____1.0 Soil Aliquot Volume: CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L FORM I X-l I U C -; ; .(uL) 74-87-3 —— —— 74-83-9 ————— 75-01-4 ————— 75-00-3 —— —— 75-09-2 ————— 67-64-1 ————— 74-97-5 ————— 75-15-0 ————— 75-35-4 ————— 75-34-3 —— —— 540-59-0 ———— 540-59-0 —— —— 67-66-3 ————— 107-06-2 ———— / O 17 J J 71-55-6 ————— FT C. O *> P 75-27-4 ————— 10061-01-5 —— 79-01-6 ————— 124-48-1 ———— 79-00-5 ————— 71-43-2 ————— 10061-02-6 —— 106-93-4 ———— 7K_OK_0__ ___ _ 108-10-1 ———— 591-78-6 ———— 127-18-4 ———— 79-34 c ———— _ / ^ *j ^ ^/ —— Chloromethane —— Bromomethane —— Vinyl Chloride —— Chloroethane —— Methylene Chloride —— Acetone —— Bromochloromethane —— Carbon Disulfide —— 1, 1-Dichloroethene —— 1, 1-Dichloroethane —— 1, 2-Dichloroethene (total) —— cis-1 , 2-Dichloroethene —— Chloroform —— 1 , 2-Dichloroethane —— 2 -Butanone —— 1 , 1 , 1-Trichloroethane —— Carbon Tetrachloride —— Bromodichloromethane —— 1 , 2-Dichloropropane —— cis-1 , 3-Dichloropropene —— Trichloroethene —— Dibromochloromethane —— 1 , 1 , 2-Trichloroethane oenzene —— trans-1, 3-Dichloropropene ___ —— 1 , 2-Dibromoethane —— Bromoform —— 4-Methyl-2-Pentanone —— 2-Hexanone —— Tetrachloroethene —— 1, 1,2, 2 -Tetrachloroethane —— Toluene —— Chlorobenzene 3 5 5 8 5 5 1 1 5 5 5 1 5 6 5 5 5 5 5 5 5 5 5 5 4 7 5 5 5 5 5 4 5 S S S S BS U U U S S S U S S U S S S S S S S S S S S S U U S S S S EN i^.N f- 3/90 t I IX ORGANICS ANALYSIS DATA SHEET 0337 SAMPLE NO. ab Name: TTAS-KNOXVILLE____ ~s Lab Code: _____ Case No. : Contract: SAS No.: VLCS1 SDG No.: MW01 Matrix: (soil/water) WATER Sample wt/vol: 5.0 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. ___ Heated Purge: N GC Column: DB-624___ ID: 0.53(mm) Soil Extract Volume: ______(uL) Lab Sample ID: LCS0318 Lab File ID: LCS0318 Date Received: 03/08/93 Date Analyzed: 03/18/93 Dilution Factor: ____1.0 Soil Aliquot Volume: ___ CAS NO. COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L 100-41-4 ——— • 100-42-5 ——— - 1330-20-7 —— • 541-73-1 ——— • 106-46-7 ——— • 95-50-1 ———— - —— Ethylbenzene —— Styrene —— Xylene (total) —— 1 , 3-Dichlorobenzene —— 1 , 4-Dichlorobenzene —— 1 , 2-Dichlorobenzene —— 1 , 2-Dibromo-3-Chloropropane _ 4 1 4 4 5 5 1 u u FORM I X-2 TUT 004 1773 L OOC177.3/90 OATH FROM FILE: LCS6318 SCANS 45 TO 728 ACQUIRED: 03/18/93 14:84:00 CALI: LCS0318 #3 SAMPLE: CLP, 53544,MM81,ULCS0318,LOW,WATER,LCS0318,VOA,EPA, COHDS.: I506A:25ML OLU01 AMBIENT PURGE W/ 5PPB IS S< SS 189 _ 3:20 200 _ 6:40 300 _ 10:00 400 J 13:20 500 _ 16:40 600 _ '0:90 709 _ F I J 100.02 ( 22240.) CI10 1,4-DIFLUOROBENZEHE (IS#1) CI20 CHLOROBEHZENE-D5 (ISI2) CS18 4-BROMOFLUOROBEHZEHE (SS) CI26 1..4-DICHLOROBENZENE-D4 <IS*3) u Lsta: LC50318. TI C3/ 18/93 14:04:00 f.a-nple: CLP, 53544, MW01, VLCS0318, LOW, WATER, LCS0318, VOA, EPA, Tends. : I500A:25ML 0) V01 AMBIENT PURGE W/ 5PPB IS & SS r:^mula 25ML AMBIENT PURGE Instrument: I500A Weight: 0. 000 Submitted by: ITEM, Analyst: RJL Acct No : 53554 A:"QUNT=Af?EA * REF AMNT/<REF AREA # RESP FACT) ~5sp. fac. from Library Entry I CI1O 1, 4-DIFLUORCBENZENE (IS#1) !• CI20 CHLOROBENZENE-D5 iIS#2) j CI26 1, 4-DICHLOROBENZENE-D4 (IS#3) 4 CS10 4-BROMOFLUOROBENZENE <SS) 5 CO 10 CHLDROMETHANE ** 6 C015 BROMOMETHANE 7 C020 VINYL CHLORIDE * 5 CC25 CHLOROETHANE 7 C030 METHYLENE CHLORIDE L'j C035 ACETONE ! i C110 2-BUTANONE '2 C205 4-METHYL-2-PENTANONE 13 C210 2-HEXANONE 14 C037 BROMOCHLOROMETHANE :5 C040 CARBON DISULFIDE 16 C045 1, 1-DICHLOROETHENE * 17 C050 1, 1-D I CHLOROETHANE ** 15 C053 TRANS-1, 2-DICHLOROETHENE 1? C060 CHLOROFORM * 50 C065 1, 2-DICHLOROETHANE 7.'. C115 1,1, 1-TRICHLOROETHANE r::5 C120 CARSON TETRACHLORIDE 1'? C130 3RCMODICHLOROMETHANE ?4 C140 1, 2-DICHLOROPROPANE * T5 C143 CIS-1, 3-DICHLOROPROPENE i.i C150 TRICHLOROETHENE .-'? C155 DIBROMOCHLOROKETHAfv'E r.S C 1 60 1,1, 2-TR I CHLOROETHAWE .?«? C165 BENZENE I-: C172 TRANS-l* 3-DICHLOROPROPENE II C176 1, 2-DIBROMOETHANE .-•> CieO BROMOFORM *» 13 C220 TETRACHLOROETHENE C225 1, 1, 2, 2-TETRACHLOROETHANE ** C230 TOLUENE * It> C235 CHLOROBENZENE 27 C240 ETHYL BENZENE * 38 C245 STYRENE 39 C250 M/P XYLENE *1C C252 0-XYLENE M COS^ CIS-1, 2-DICHLOROETHENE *3 C253 1, 3-D I CHLOROBENZENE *2 C254 1, 4-DICHLOROBENZENE i4 C255 1, 2-DICHLORCBENZENE TUT O04 1 /7-' "5 C2A} i, 2-DIBROriO-3-CHLOROPROPANE L 0001770 0340 •;c • 3 •5 ? .t. 7 •T V - .•••. fc ^ 12 13 14 1 B 16 t "T • 3 •_ 9 r.'"*. ^.' ± ?.J? -'""^ :-_4 _*. e :-!6 r 7 r'S 29 vO - i* "T a ~ m/ i 114 117 150 93 50 94 62 64 84 43 NOT NOT NOT NOT NOT 96 63 96 £3 62 97 117 83 63 75 95 129 97 78 75 107 173 Iti 33 91 112 91 NOT 101- NDT NOT 1 16 1 ••' n 1 •'& NUT R^t 6: 12: 17 14: 1 : 1 : t 1 : 2: Scan 185 374 519 440 41 47 42 47 73 64 FOUND FOUND FOUND FOUND FOUND 61 92 80 128 156 136 144 242 218 274 202 342 321 154 312 345 420 326 452 293 375 384 FOUND 391 FOUND FOUND 496 501 52O FOUND Time (L) Rati 08 1 26 1. 16 1. 38 1. 18 1. 28 1. 20 1 32 1. 24 1 01 00 00 00 05 07 05 02 01 6: 12: 17: 14: 1: 1: 1 : 1: 2 2. 2: 3: 2: 4: 5: 4: 4: 8: 7: 9: 6: 1 1 : 10. 5: 10: 1 1: 14: 10 15: 9: 12: 12: 13: 16: 16: 17: 10 28 18 40 22 34 24 34 26 08 02 04 40 16 12 32 48 04 16 08 44 24 42 08 24 30 00 52 04 46 30 48 02 32 42 20 o RRT(L 1 1 1 . 000 . 000 . 000 Ref 1 2 3 1 1 1 1 1 1 1 1 1 1 1 1 2 2 2 e. 2 2 2 2 2 2 2 3 2 2 2 2 2 2 3 3 3 ) 2. 386 0 0 0 0 0 212 . 239 . 217 . 250 . 391 1. 1. 1. 2. 0 0. 0. 0. o. 0. 0. 0 0 0 0. 0 0 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1 0. 1. 1. 1. 0. 0 1. Rati 1. 1. 1. 1. 1. 1. 1. 1. 1. 00 00 00 RRT 000 000 000 378 222 254 227 254 395 346 330 497 432 692 843 364 385 647 583 733 540 914 858 412 834 922 809 872 209 783 003 027 045 956 965 002 o 00 05 06 04 02 01 Meth A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A DB BB DB BV DB BB EB DD BB EB BB VD DB BB BB DD VB BB DD DD BB BB DD BB DB DD BB BB BB DB BB EB DB BV VB DB Amn t 5 5 5 5 2 4 4 7 5 00 . 00 . 00 04 61 . 66 . 64 70 . 34 Area<Hgh 11078. 8235. 5663. 6826. 5639. 5439. 704O. 6507. 448-'. 31. 5534. 12393. 5431. 11545. 4418. 13508. 11963. 6864 4614. 4481. 7447. 3461. 1903. 12610. 2162. 3148. 1155. 9073 1907. 13149. 8963. 17935. 67. 7074. 7295. 5378. Amnt (L) 5. 00 5. 00 5. 00 5. OO 5. 00 5 00 5 00 5 00 5 00 t) Amount 5. 000 UG/L 5. 000 UG/L 5. 000 UG/L 5. 043 UG/L 2. 615 UG/L 4. 664 UG/L 4. 637 UG/L 7. 697 UG/L 5. 337 UG/L 0. 852 UG/L 4. 869 UG/L 5. 351 UG/L 4. 893 UG/L 5. 136 UG/L 5. 967 UG/L 4. 916 UG/L 4. 705 UG/L 5 040 UG/L 4. 659 UG/L 5. 44O UG/L 4. 537 UG/L 4. 921 UG/L 5. 093 UG/L 4. 543 UG/L 4. 440 UG/L 6. 831 UG/L 4. 969 UG/L 4. 67O UG/L 5. 081 UG/L 4. 503 UG/L 4. 661 UG/L 4. 502 UG/L 0. 046 UG/L 4. 477 UG/L 4. 573 UG/L 4. 699 UG/L R. Fac R. Fac (L) 1 . 000 1 . OOO 1. 000 1. 000 1. 000 1. 000 0. 616 0. 61 1 0. 509 0. 973 0. 491 0. 526 0. 636 0. 685 0. 587 0. 382 0. 405 O. 379 7.Tot C_ 2 C. 2 1 2 2 4 3 0 3 2 3 3 2 2 2 2 3 2 2 3 2 2 4 2 2 3 2 2 2 0 2 c. 2 Rat 1 1 1 1 0 0 0 1 1 . 95 . 95 . 95 . 98 54 75 . 74 . 55 15 . 50 . 83 . 16 . 89 . 03 . 52 . 90 78 98 . 75 . 21 . 63 . 91 . 01 . 68 . 62 03 . 93 . 76 . 00 . 66 . 75 . 66 . 03 . 64 . 70 . 78 i o . 00 . 00 . 00 . 01 . 52 . 9:? . 93 5'! . 07 O I- L O O O i V 7 ***»»***** SUMMARY REPORT *****»»** PID LINEARITY CALCULATIONS FOR V3400A USING A RESTEK 502.2 COLUMN 105m* 0.53mm I.D., 3.Oum Df COLUMN. - File Name SAMPLE NAME Number tc10002. A MIX tc!0009. B MIX tclOOIO. C MIX tclOOOS. 0 MIX tc10006. E MIX Averages %RSD File Name SAMPLE NAME Number tc10002. A MIX tc10009. B MIX tclOOIO. C MIX tclOOOS. D MIX tc10006. E MIX Averages %RSD File Name SAMPLE NAME Number -10002. A MIX j10009. B MIX ^— tclOOIO. C MIX tclOOOS. 0 MIX tc10006. E MIX Averages XRSD F i l e Name SAMPLE NAME Number tc!0002. A MIX td0009. B MIX tdOOIO. C MIX tdOOOS. D MIX tc10006. E MIX Averages •/.RSD F i l e Name SAMPLE NAME Number tdOOOZ. A MIX td0009. B MIX tdOOIO. C MIX tclOOOS. D MIX tc10006. E MIX Averages •/.RSD - File Name SAMPLE NAME Number tc10002. A MIX tc10009. B MIX Date Of Injection 3/10/93 3/10/93 3/10/93 3/10/93 3/10/93 Date Of Injection 3/10/93 3/10/93 3/10/93 3/10/93 3/10/93 Date Of Injection 3/10/93 3/10/93 3/10/93 3/10/93 3/10/93 Date Of Injection 3/10/93 3/10/93 3/10/93 3/10/93 3/10/93 Date Of Injection 3/10/93 3/10/93 3/10/93 3/10/93 3/10/93 Date Of Injection 3/10/93 3/10/93 Air Ret. STD CON Height CF Time (PPB) 11DCIE Ret. STD CON Height CF Time (PPB) 16.98 1.0000 3745.34 3.7453e3 16.98 7.5000 24000.19 3.2000e3 16.97 15.0000 51105.85 3.4070e3 16.98 22.5000 85666.02 3.8073e3 16.96 30.0000 124801.84 4.1600e3 16.97 15-. 2000 57863.85 3.6639e3 0.05 75.97 83.67 10.16 C-12DCIE Ret. STD CON Height CF Time (PPB) 24.13 1.0000 4524.67 4. 5246e3 24.11 7.5000 34520.40 4.6027e3 24.12 15.0000 77275.16 5.1516e3 24.13 22.5000 118232.27 5. 2547e3 24.10 30.0000 177435.11 5.9145e3 24.12 15.2000 82397.52 5.0896e3 0.05 75.97 82.98 11.06 FBI Ret. STD CON Height CF Time (PPB) 29.36 100.0000 183585.84 1.8358e3 29.35 100.0000 205257. 63-3^£25e3 29.36 100.0000 209136.3«r5913e> 29.36 100.0000 201588.97 ZTTTTTSeS 29.34 100.0000 229757.59 2.2975e3 29.35 100.0000 205865.28 2X£$6& 0.04 0.00 8.04 8.04 2ClEthylVO Ret. STO CON Height CF Time (PPB) 34.04 1.0000 1004.75 1.0047e3 34.02 5.0000 7534.33 1.5068e3 34.05 10.0000 18194.46 1.8194e3 34.04 15.0000 25993.42 1.7328e3 34.03 20.0000 40913.00 2.0456e3 34.04 10.2000 18727.99 1;£»*e3 0.03 74.47 83.78 Q 24.37N Toluene Ret. STD CON Height CF Time (PPB) 36.58 1.0000 9715.21 9.7152e3 36.57 7.5000 73372.82 9.7830e3 VCl Ret. STD CON Height CF Time (PPB) 9.01 1.5000 996.72 664.4827 9.00 7.5000 4956.13 660.8178 9.00 15.0000 10584.16 705.6108 9.01 22.5000 15877.48 705.6658 9.01 30.0000 24594.74 819.8246 9.00 15.3000 11401.85 711.2803 0.07 74.47 81.40 9.05 T-12DCIE Ret. STD CON Height CF Time (PPB) 20.19 1.0000 11601.63 1.1601e4 20.18 7.5000 95207.35 1.2694e4 20.18 15.0000 192704.78 1.2846e4 20.18 22.5000 315832.19 1.4036e4 20.17 30.0000 477796.25 1.5926e4 20.18 15.2000 218628.44 1.3421e4 0.04 75.97 84.15 12.26 Bz Ret. STD CON Height CF Time (PPB) 28.43 1.0000 12253.49 1.22S3e4 28.41 7.5000 78078.69 1.0410e4 28.43 15.0000 154269.83 1.0284e4 28.43. 22.5000 248681.70 1.1052e4 28.41 30.0000 377316.41 1.2577e4 28.42 15.2000 174120.02 1.1315e4 0.04 75.97 82.56 9.29 TCIE Ret. STD CON Height CF Time (PPB) 31.06 1.0000 5106.00 5.1060e3 31.05 7.5000 43599.41 5.8132e3 31.06 15.0000 98041.21 6.5360e3 31.07 22.5000 152276.05 6.7678e3 31.04 30.0000 237990.09 7.9330e3 31.06 15.2000 107402.56 6.4312e3 0.03 75.97 85.45 16.53 C-13DClPe Ret. STD CON Height CF Time (PPB) 35.05 1.0000 3123.09 3.1230e3 35.04 7.5000 16686.59 2.2248e3 35.06 15.0000 34385.94 2.2923e3 35.06 22.5000 54483.83 2.4215e3 35.04 30.0000 86171.56 2.8723e3 35.05 15.2000 38970.20 2.5868e3 0.03 75.97 83.85 15.15 T-13DCtPe Ret. STD CON Height CF ( 0 0 0 1 Time (PPB) u 37.42 1.0000 903.37 903.3714 37.40 7.5000 15938.55 2.1251e3 fx rH 1 o t-=1 r- 817 n t v r - c o n o - n a ^ ^ n o - — e o r u ^ n ^ r - o - n o i o n o o o -• «* OO 0*OO*O'~<OO-OfrOO*frOO(DnO-O-OfrO*fr O O- O~ O ' • * . . . . . . . . . . . . . . . . . . . . . . •P O O-riQ^i^CiO^O^OO^OO^OO^-iOOO O OOO >a cc ~ o n m ^ - i i n t a D ' t N - ^ O N N N i n - o o i n o c o n h s O ^ *•« m o- -« _| .-* • - * ' * O ' - ' n - 0 < t C M O O O - r v l C V i e D O " C O O a ) ( M N - 0 - ' 0* 0- O -• ~ o moinonoiftCD-t)ino--<i-r\j<irdrdrdTHfiirv^«fr oo to <t o o . . . . . . . . . . . . . . . . . . . . . . . . . . . mo o*-'O'- |O'-<»-«oooooO'- <ooo-'-'O'- i'- |rd o T-i.-t.-t LL (X ^ O(horuo^on <«ro<t'tOT-<'-«nr»i'*ruojrv(Doo v o- co o uo o ^ o - - * r > « 4 - i o n o « t o r u r * i n - o a > o o n O " O O N o <t co m ••o m»-<*rono<tcoinino-*j-nJir>ninruT-.(MinO'* o ruroih u . . . . . . . . . . . . . . . . . . . . . . . . . . . . .o O'-«o*- <O'-'»- <oooooO"-'Ooo*-«O'- i*-'r<j o «-««-• o a: ~ o o o o o o o o o o o o o o o o o o o o o o o o ooo _l O O O O O O O O O O O O O O O O O O O O O O O O OOO •p iri in i n i r i i r i u S i n i n i n i n i n t n i n i n i h i h i n i n i n i n i h i n u S o m m i n c ru -. e< •p in i-.. m ci- >t r--. ro o t -o -t •* '.\J o- >t •«• n r-- r-- co o -o o ITJ co r- o c ro co n co -^ o- o- N o -o 't m i> o m -t ro a- -o o m o m o t ir> r^ 6 . . . . . . . . . . . . . . . . . . . . . . . <o «4-m-*iniTi<*«fin«<-in<*-<tiD<t<*-o«*^(-in«*-«t<4- o «t«f«* o-• n ^ r n r o o o o o o o o o o o o o o o o o o o o o ooo • P O O O O O O O O O O O O O O O O O O O O O O O O O O O • D . . . . . . . . . . . . . . . . . . . . . . . . . . f^r j ^ ^ . . ^^ . ^. . _| j ^^ ^ ^ ^ . j v_^ ^_ . ^ . ^_| ^^ . t ^ ^ . . . . ^ . _ i r x i n i n ^ n n "C)r«irv«-'-oinroo-rv)o-«T-oco i*ojrjnT-4in-HnriiONO{Dorjotooin^oco t- n -o h- 0^ -o n n * t -a oo n n ^ m r- m o co ^ ro o- ro co ni r-- o o -« o -* -o o- o o o t c . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . t C O O O O O O O O O O O O O O O O O O O O O O O O r n O ^ ^ - ' ' H ^ , o O O — -« o••-in t i j » - t n ^ ' - ' ' ^ ' - ' O o o o o o - - < o o o o o o o o o ooo *»o o o o o o o o o o o o o o o o o o o o o o o o ooo « p . . . . . . . . . . . . . . . . . . . . . . . . . . . j < t o o o r j « i - o o ( M - o « 4 - o o o ( M ' * - o r d ( M o - o r t j c o c D O ( M « t a j ^ o - o r \ j r d « t o ( M 0 3 o — o ifi n rd o -i o o n «-<«-« n »i- o -» o •*• oj T <L~' ivi ru m ID o 't rd •«• «t o 't -t n --r -< -t * > . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . • rd n o- ^ 't ro ro n c\i -t u~j ^ -t co r- o- -o *-• o in o -t n o ir> o- ru rd n n n n o -o r- CD Q» <"H *H »*4 *^ »-H rH -rH i^ ^H ^H »™l T^ «-"< T^ Y~| «^ T—1 *j o -• fij n -t u'« -/j --. o? ir c> -« o) co •*• u'i .'i r-- a 1 o- «."> -«r< r«? ^ u • -o r» ra o c~> -•< ^j o -t B • •• ~. ** -4 „, ..., _, . . . , ,i . .-,; ,-,| r>| r.| 1.1 : .1 •;< r>j ,',| f.i j-j :-: ,-j i>l fl ;-i ti f» Tl '•! -J «t 'T •+ •: •* CO r--. r--- oo .or- CD 3/18/93 14:04:45 Acquisition started 0342 2/18/93 ^u ire ---.••18/93 14: 04. 00 :£7>ple: CLP, 53544 14: 04: 48 Run 0:LCS0318 Starting + 0:00 Free sectors: 11533 Scan: 0 of MW01, VLCS0318, LOW, WATER, LCS0318, VOA, EPA, 720 :-ds. : I5OOA:25ML OLV01 AMDIENT PURGE W/ 5PPB IS !< SS r.-mula: 25ML AMBIENT PURGE Instrument: 1500A Weight: .emitted by: ITEK Analyst: RJL Acct. No: Desc : RR Terr.p ( D e q C ) 35 35 35-150 1 50- 1 50 ve A : c 1 Rate ( C / m i n ) - 8 O - osed *•»* GC not ready and being stabilized *** Elapsed time : 0 000 53554 0. O Min Time (minutes) period total 6. 6 6. 6 14. 3 20. 9 3. 0 23. 9 Injector A : GC oven : Transfer-1ine: Ion source : 150 Deg C 35 Deg C 215 Deg C 180 Deg C Valve B open **•* Instrument parameters *** Pc'=.t acquisition state -> Filament : Off Multiplier : Off DCE: El (+) Centroid + Temp - Sequence: BF ( 2 time windows. ) Wind out an descriptor: t a 1 scan time: Number of cycles: 28 Filament is OFF Multiplier is ON DF Mass intervals: 2. OOO s Positive ion mode. Master rate: 16 MFW: 80 Lo mass 33. 510 MA: 15 H i ma s s 300. 590 TH: 1 Time 2. 000 DL: v ; 3 u e n c e W i n d o u> •n descriptor: :a 1 scan t ime : Number of cycles: Filament is ON M u l t i p 1 i er is ON DF Mass intervals: 2 OOO s Positive ion mode. Master rate: 16 J 3 MFW: 80 MA: 15 TH: 1 -t tt Lo mass Hi mass Time 1 33. 51O 3OO. 59O 2. OOO BL: Calibration table: Interface number Instrument type Full scale mass Zero scale mass Intensity/i on Peak width Offset at low mass Offset at h i g h mass D: CAL02199; 0 Q 1177 u 1 u 2 1000. mmu 0 mmu 0 mmu Voltage settling time(ms) 20 TUT O04 1779 L0001773 Torrent instrument parameters. Positive ion mode 0343 Resolution (high) Resolution (low) Quad offset Quad programming Lens offset Lens programming Ext offset Ext programming Co 11ec tor Ion offset Ion programming 5.00 Rod polarity Reverse Electron multiplier voltage Filament emission current Electrometer range Electrometer zero 128. 128. 0. 0. -50. 0. 0. 0. 30. 7. 00 00 oo 00 00 00 00 00 00 00 Negative ion mode 128. 00 128. 00 0. 00 0. 00 50. 0. 0. 0. 30. -3. -5. 00 00 oo 00 00 00 00 Norma1 984. 750. 10 '-7 126. 0 • slyzer Fore Pressure ... •-j :• ar at or /Sourc e Pressure 0. 010 O. 356 Torr Torr 2/18/93 14:33:OO ACQUISITION COMPLETED Scans 1 to 720 Centroid : : e *;: t r o i d Scans 720 Sees 0. 5 Out of 1440. 0 0. 0 Peaks per 6643 scan 9. p er sec 5. TUT 004 1780 L000178G METHOD: CLP 3'90 OLV01 25ML PURGE DATAFILE: STANDARD: TUNEFILE: LCS0318 WS0318 WBFD0318 ANALYSIS TIME: ANALYSIS TIME: ANALYSIS TIME: 03/18/93 03/18/93 03/18/93 ****** INTERNAL STANDARD AREA CHECK ****** 14: 04 8: 29 B: 20 INTERNAL STANDARD 10 1,4-DIFLUOR03ENZEN ^O C:» QROBENZENE-D5 ( £6 1, 4-DICHLORODENZEN DATA AREA 11078. 8235. 5663. STD AREA 1121O. 7723. 5477. RATIO 997. 107X 1037. CLP ACCEPT RATIO 607. - 14O7. 607. - 1407. 607. - 1407. STATUS ****** INTERNAL STANDARD RT CHECK ****** INTERNAL STANDARD 10 1, A-DIFLUORODENZEN '.20 GIB CROBENZENE-D3 ( :r.6 1, 4-DICHLOROBENZEN DATA SCAN STD SCAN DIFF CIN SECD CLP ACCEPT DIFF STATUS 135 374 519 1S4 373 518 +/- 20 SECS +/- 20 SECS •*•/- 20 SECS ****** SURROGATE RECOVERIES ****** SURROGATE ANT FOUND AMT ADDED PERCENT RECOVERY RECOV LIMITS STATUS O 4-B30MOFLUOROBENZE 5. 0 5. 0 101 5 BROMOMETHANE 4.7 50.0 9 0 VINYL CHLORIDE * 4.6 50.0 9 SO'/. - 1207. 887. - 1107. 867. - 1157. failed failed TUT OO4 1781 I-ATA FILE: LCS0318 3EFERENCE: VI11 '.-iflE LIST: VI INITIALIZATION OPTION: REPORT: VI IS PROCESSING OPTION: 3 0345 ——— STANDARDS - SOC USED POSS 3 2 1 3 3 1 3 3 1 -—— X —- PLUS UNKNOWNS —— X - LIST NAMES - > RKS PROC USED POSS RM3 STANDARD/UNKNOWN 0 20 14 4 79 V1IS/V1UNKS1 0 16 16 1 49 V1IS/V1UNKS2 0 15 10 27 54 V1IS/V1UNKS3 45 COMPOUNDS PROCESSED, 33 FOUND •-•••I \ 2 n 4 ^ 6 •T 2 9 10 11 12 13 14 15 " J- f <3 '. 9 «. V 21 ?.2 23 24 _-. e ':. il i" 2>i 2r 30 Jl 32 2'3 ^4 j? :>6 '37 33 2V 40 41 »2 , j ^44 45 LIB ENTRY VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI VI 1 1 1 V .L VI VI VI VI VI VI VI VI VI VI VI 1)1 T A VI VI VI VI VI VI VI VI VI VI VI VI VI VI 1 2 3 4 5 6 •7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 REF -134 -373 -518 -439 -38 -44 -39 -46 -72 -62 -115 -289 -341 -122 -65 -60 -91 -78 -127 -155 -135 -143 -242 -218 -274 -201 -341 -321 -153 -311 -344 -420 -325 -451 -293 -375 -384 -413 -391 -412 -112 -496 -501 -519 -561 PRED 135 374 519 440 40 46 41 48 74 64 117 290 342 124 67 62 93 SO 129 157 136 144 243 219 275 202 342 322 154 312 345 421 326 452 294 376 335 414 392 413 112 497 502 520 562 — stftKun ———————— SEL DELTA PEAKS 135 374 440 41 47 42 47 73 61 92 SO 125 156 136 144 242 218 274 202 342 321 154 312 345 420 326 452 293 375 334 496 502 520 1 1 1 -1 -1 -1 -1 -1 -1 -1 -1 ••» 1 -1 -1 -1 -1 -1 -1 1 1 1 1 1 e~ i 2 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 A. 1 1 1 1 1 1 3 3 3 ———— ^-=w 3« 1 -'^. ———— ~ FIT PEAKS M/Z 951 940 944 883 914 948 945 984 957 972 982 964 894 936 976 981 978 962 956 961 973 966 913 952 919 948 963 983 985 939 989 992 960 114 117 150 95 5O 94 62 64 84 43 43 43 43 128 76 96 63 96 S3 62 97 117 83 63 75 95 129 97 78 75 107 173 166 83 91 112 91 104 1O6 106 96 146 146 146 75 —— unrtu ——— ———— TOP DELTA PEAKS 155 374 519 440 41 47 42 47 73 64 61 92 SO 123 156 136 144 242 218 274 202 342 321 154 312 345 42O 326 452 293 375 384 391 496 501 -1 520 1 1 1 1 1 1 1X 1 1 1 1 1 1 1 A 1 1 1 1 1 1 1 1 1 1 1 1A 1 1 1 1 1 1 1 1 1 1 L OC01YS, TUT OO4 178; LIBRARY SEARCH REPORT PURGEABLE VOLATILE ORGANICS ANALYSIS 0346 FILE: LCS0318 3UIRED: 03/18/93 14:04:00 r.'DS. : I500A:25ML OLV01 AMBIENT PURGE W/ 5PPB IS !-. SS It ADMITTED BY: ITEK COMPOUND ' iO 1, 4-DIFLUOROBENZENE <IS#1> '.20 CKi QR03ENZENE-D5 <IS#2> .26 1.. A-DICHLOROBENZENE-D4 (IS#3? F.-.O 4-SHOMOFLUOROBENZENE (SS) MO CHuOROMETHANE ** ::5 BROMOMETHANE .-20 VI?iYL CHLORIDE * :/25 CH: QROETHANE '.DO METHYLENE CHLORIDE :>t5 1, 1-DICHLOROETHENE * -50 1, 1-DICHLOROETHANE ** : !?3 TRANS-1, 2-DICHLOROETHENE JaO CHLOROFORM * :.-s5 1, 2-DICHLOROETHANE '15 1,1,1-TRICHLOROETHANE -. :?0 CARBON TEfRACHLORIDE :jO BRCNODICHLOROMETHANE '. '!0 1, 2-DICHLOROPROPANE * :43 CIS-1, 3-DICHLOROPROPENE 50 TRICHLOROETHENE X55 DIBROMOCHLOROMETHANE -.•=O 1, 1, 2-TRICHLOROETHANE '.72 TRANS-1, 3-DICHLOROPROPENE ;~6 DIDROMOETHANE :*0 BROMOFQRM ** T.20 TETRACHLOROETHENE z25 1,1,2,2-TtTRACHLOROETHANE ** 7:30 TOLUENE * r.-:5 CH: OROBENZENE :-40 EIHYL BENZENE * P.:-.2 1, 3-DICHLOROBENZENE :-.-53 1, A-DICHLOROBENZENE .~S4 1, 2-DICHLOROBENZENE ANALYST: RJL ACCOUNT NO. 53554 SCAN DELTA (UG/ML) FIT SAT'D' 185 374 51? 44O 41 47 42 47 73 61 92 80 12S 156 136 144 242 218 274 202 342 321 154 312 345 420 326 452 293 375 384 496 501 520 0 0 0 0 1 1 1 -1 -1 -1 -1 0 -1 -1 0 0 -1 -1 -1 0 0 -1 0o 0 -1oo -1 -1 -1 -1 -1 o 5. 5. 5. 5. 2. 4. 4. 7. 5. 4. 5. 4. 5. 5. 4 4 5. 4. 5. 4. 4. 5. 4. 4. 6. 4. 4. 5. 4. 4. 4. 4. 4. 4. ooo 000 000 043 615 664 637 697 337 869 351 893 136 967 916 705 040 659* 440 537 921 093 543 440 831 969 670 081 503 661 502 477 573 699 981 940 O 944 S83 914 948 945 984 957 972 982 964 894 986 976 981 978 962 956 961 973 966 913 982 919 943 963 983 985 989 989 992 960 O 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0o 0 0o o 0 0 0 0 0 TUT 004 1783 L 0001Y83 0347 INTERNATIONAL TECHNOLOGY CORPORATION VOLATILE ORGANIC COMPOUNDS ANALYSIS BY 8O1O/8O2O TUT 004 1784 RESPONSIVE TO THE NEEDS OF ENVIRONMENTAL MANAGEMENT LOGOlVS-i QC SUMMARIES TUT 004 1785 C0001783 o> CO CON <* O O c*> *> SN- —*, O-oo O UJ Q. < U) HALOGENATED AND AROMATIC VOLATILE ORGANIC ANALYSIS 0350 Laboratory Name ITAS - KNOXVILLE Contract Name L'HENRI ^-^ient Sample I.D. TRIP BLANK b Sample I.D. W7328 Sample Matrix WATER Concentration Units ug/1 COMPOUND dichlorodifluoromethane chlorome thane vinyl chloride bromome thane chloroethane trichlorofluorome thane 1,1- dichloroethene methylene chloride trans - 1 , 2 -dichloroethene 1,1- dichloroethane cis - 1 , 2 - dichloroethene trichloromethane 1,1,1- trichloroethane carbon tetrachloride benzene 1 , 2 -dichloroethane trichloroethene 1,2- dichloropropane bromodi chlorome thane d i b r omome thane ?-chloroethyl vinyl ether s-1,3- dichloropropene x_^luene trans - 1 , 3-dichloropropene 1,1,2- trichloroethane tetrachloroethene dibromochlorome thane n-hexyl chloride chlorobenzene ethyl benzene 1,1,1,2- tetrachloroethane xylenes (total) bromof orm 1,1,2,2- tetrachloroethane 1,2,3- trichloropropane phenyl bromide (bromobenzene) 2 - chlorotoluene 1,3- dichlorobenzene 1,4- dichlorobenzene 1,2- dichlorobenzene bis (2-chloroisopropyl) ether CAS No. 75-71-8 74-87-3 75-01-4 74-83-9 75-00-3 75-69-4 75-35-4 75-09-2 156-60-5 75-34-3 156-59-2 67-66-3 71-55-6 56-23-5 71-43-2 107-06-2 79-01-6 78-87-5 75-27-4 74-95-3 110-75-8 10061-01-5 108-88-3 10061-02-6 79-00-5 127-18-4 124-48-1 544-10-8 108-90-7 100-41-4 630-20-6 1330-20-7 75-25-2 79-34-5 96-18-4 108-86-1 108-41-8 541-73-1 106-46-7 95-50-1 108-60-1 SDG Number Job Number Collection Date Confirmation Date Analysis Date(s) Dryness Factor RESULTS QUALIFIERS 1.8 0.8 1.8 1.2 5.2 2.0 1.3 15 1.0 0.7 1.0 0.5 0.3 1.2 2.0 0.3 1.2 0.4 1.0 - 1.3 3.4 2.0 3.4 0.2 0.3 0.9 - 2.0 2.0 - 1.0 2.0 0.3 - - - 3.2 2.4 1.5 - UU UU U U U U U U U U U U U U U U U - U U U U U U U - U U - U U U - - - U U U - NA ITEK 53554 03/05/93 NA 03/11/93 NA DETECTION LIMITS 1.8 0.8 1.8 1.2 5.2 2.0 1.3 15 1.0 0.7 1.0 0.5 0.3 1.2 2.0 0.3 1.2 0.4 1.0 - 1.3 3.4 2.0 3.4 0.2 0.3 0.9 - 2.0 2.0 - 1.0 2.0 0.3 - - - 3.2 2.4 1.5 - SURROGATE RECOVERY ACCEPTANCE LIMITS SOIL WATER LAB I.D. W7328 _*'' BCM (31-112) (53-150) 82 OCFB (34-113) (64-121) 91 FB (23-113) (70-128) 92 OFCB (21-108) (72-122) 91 CD N. •H h- L OC0.1V87 U JO 1 Software Version: Sample Name 3.2 <16C20> Sample Number Operator ^Instrument AutoSampler Rack/Vial TRIP BLANK V3400A/SALLY NONE 0/0 Time Study Channel : A 3/11/93 10:41 AM ITEK53554 A/D mV Range : 1000 Interface Serial Delay Time End Time Sampling Rate Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount Noise Threshold Multiplier # : 0159572256 0.00 min. 70.00 min. 2.0000 pts/sec Data Acquisition Time: 3/11/93 3:21 AM n:\v3400s\SC10015.raw n:\v3400s\SC10015.rst N:\V3400S\8000SUE.ins N:\V3400S\HALL.prc N:\V3400S\LINHSC10.smp n:\v3400s\scl0.seq 5 mL 1.0000 Area Reject : 100.00 Dilution Factor : 1.00 15 1.0000 Area Threshold : 73 Bunch Factor: 2 Divisor : 1.0000 Adder : 0.0000 Instrument Conditions: Total Number of Peaks Detected: 24 ITAS-KNOXVILLE V-3400B J+ W DB-624 75m*0.53mm ID, 3.00um df ELECTROLYTIC CONDUCTIVITY DETECTOR-BrClMe AND O-ClFBz ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. AL! OTHER ANALYTES ARE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLUME OF 5.O ML. Peak tt 1 2 3 t. 5 6 7 8 9 10 11 12 13 14 5 -17 18 19 20 21 22 Ret Tim* RT D1FF. [min] X 4.954 5.775 7.185 8.542 12.796 14.210 19.136 24.909 25.535 26.702 28.494 29.435 33.101 34.879 45.914 47.805 56.054 56.631 57.483 63.150 63.645 64.993 0.0 0.0 2.4 2.6 2.6 1.5 0.2 0.3 0.1 0.3 0.4 0.0 0.9 -0.7 0.4 0.1 0.0 0.0 0.0 0.3 0.0 0.1 BL BB BV W W W VB BB BVW VV WW W VB BB BV VV W VB BV W VB Component Name DClDFMe CLME ClEa TClFMe CH2C12 CHC13 BrClMe 111TCIE8 12DCIEB BrDClMe C-13DCIP6 ClBz o-Cl,F-Ben 123TriClPr UDClBz 120CIBZ Are*/ Amount 52922.7148 74767.6484 1.1632e5 8.0159e5 3.9167e5 2.6068*5 3.8221e5 5.5756e5 63635.5469 1.4911e6 9.1729e5 8.2802eS 9.5573e5 1.2969e6 4.1366e5 41292.1719 2.9503e5 1.0722e5 5.6791e5 6.0998e5 3.0321e5 2.8327e5 Are* [uV"sec] 1256.00 79350.28 25702.00 39129.25 8787.81 2338.00 748830.25 36355.77 5239877.00 289410.34 75583.22 141568.19 35180.63 68071.50 13972.50 3743664.00 5002.84 8868.56 12136.06 4101.50 U622.66 31545.28 Height INST. Amt [uV] (ISS) 67.21 3094 . 1 1 629.21 322.82 272.22 117.87 61139.69 2307.13 414427.19 5743.67 1956.95 4060.57 826.60 1322.73 314.33 220310.61 153.58 749.09 193.54 129.90 2843.10 2006.44 0 1 0 0 0 0 1 0 82 0 0 0 0 0 0 90 0 0 0 0 0 0 .02 .06 .22 .05 .02 .01 .96 .07 .34 .19 .08 .17 .04 .05 .03 .66 .02 .08 .02 .01 .15 .11 Cal. Component SAMPLE CON Range Name (PPB) DClDFMe CLME ClEa TClFMe CH2C12 CHC13 BrClMe IIITClEa 12DClEa BrDClMe C-13DClPe ClBz o-Cl,F-Ben 123TriClPr 140CIBZ 120CIBZ 0.02 1.06 0.22 0.05 £ 0.02 ff 0.01 1.96 0.07 82.34 r 0.19 .; 0.08 0.17 0.04 '- 0.05 F 0.03 90.66 0.02 0.08 J:S! L 000178 0.15 0.11 23 66.527 0.0 BB 3.5799«5 3084.00 155.22 0.01 0.01 0352 24 68.668 0.0 BB 2.7808*5 44890.00 2908.58 0.16 0.16 11.3 1.1U8e7 10703328.00 726052.31 177.54 177.54 Missing Component Report Component Expected Retention (S?nple File) Air 1.845 VC1 9.074 BrMe 11.919 11DC1E 17.038 T-12DC1E 20.238 2756111DClEa 21.838 C-12DC1E 24.188 CC14 27.774 TC1E 31.131 12DClPa 31.870 2ClEthylVO 34.116 T-13DC1P6 37.487 112TC1E3 38.300 TetClE 40.147 DBrClMe 41.272 CHBr3 53.534 1122TetClEa 54.996 13DC1BZ 62.384 Y. NOT DETECTED ON PRIMARY RUN: Z. NOT DETECTED ON PID TUT 004 1789 L OOOJ.783 V3400A HALL 0353 Sample NMM : W7378 FileMame : n:\v3400t\SC10015.ran Method : MOOSUE.ins Start Time : 0.00 min End Time : 70.00 min Scale Factor: 0 Plot Offset: 4 mv Sample #: TRIP BLANK Date : 3/11/93 10:41 AM Time of Injection: 3/11/93 3:21 AM Low Point : 4.00 mv High Point : 39.00 mv Plot Scale: 35 mv (Jl 5.78 25.5 29.44 ^ Ulftlu* I —IBRDCLME —I2CLEWLVO- ——'C-13DCLPE - ""T-ISDCLPE - ~ 112TCLEA - 3t —— TETCLE - —OBRCLME -33.10 ^-34.88 ^CLBZ ~0-CL.F-BE - 4 "1 CHBR3 11122TETCL - i • 123TRICLP - -L' q =|18ftH - 120CLBZ TUT OO4 179O L0001V90 Software Version: Sample Name 3.2 Sample Number Operator ^nstrument "AutoSampler Rack/Vial <16C20> "jfrJ TRIP BLANK V3400A/SALLY NONE 0/0 Time Study Channel : B : 3/11/93 10:42 AM : ITEK53554 A/D mV Range : 1000 Interface Serial Delay Time End Time Sampling Rate Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount Noise Threshold Multiplier # : 0159572256 0.00 min. 70.00 min. 2.0000 pts/sec n:\v3400s\TC10015.raw n:\v3400s\TC10015.rst N:\V3400S\8000SUE.ins N:\V3400S\PID.prc N:\V3400S\LINPTC10. smp n:\v3400s\sclO.seq 5 ml 1.0000 Data Acquisition Time: 3/11/93 3:21 AM Area Reject : 100.00 Dilution Factor : 1.00 10 1.0000 Area Threshold : 49 Bunch Factor: 2 Divisor : 1.0000 Adder : 0.0000 Instrument Conditions: Total Number of Peaks Detected: 66 ITAS-KNOXVILLE V3400A RTX 502.2 105m*0.53mm EU.OOum df PID DETECTOR-FBZ AND 0-ClFBz ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. ALL OTHER ANALYTES ARE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLUME OF 5.O ML. Peak * 1 2 3 5 6 7 9 10 11 12 13 H 15 16 17 18 ' 19 20 21 22 23 24 Ret Time RT DIFF. [min] X 5.698 6.627 7.083 8.679 9.417 10.203 13.810 15.086 15.678 15.941 16.596 19.070 19.734 20.202 20.463 21.483 21.989 22.233 23.078 23.485 25.500 28.007 0.0 0.0 0.0 -3.5 0.0 0.0 0.0 0.0 0.0 0.0 -2.2 0.0 0.0 0.1 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 BL Component Name SB BB BB W VCl vv VB BB BB BV VB BV 11DCIE VV VE EV T-12DCIE VV VV VV VV VV W W W Area/ Amount 627.9530 4578.9741 13053.2940 10016.1523 9744.4297 61821.5313 34597.9219 37521.1797 37311.5391 48794.6172 1.6318e5 1.6335e5 1.3509e5 2.4270e5 1.9324e5 1.2155e5 53562.6211 1.2659e5 78925.3594 83661 .3203 1.7668*5 Area [uV*sec] 56961.25 1281.50 631.50 3248.94 31569.19 8931.55 6374.78 92513.75 19852.70 11428.78 7553.59 5474.44 15244.09 1400.00 3668.23 5084.08 1700.42 1295.28 3052.59 2673.59 8919.31 2284.56 Height INST. Amt Cal. Component SAMPLE CON [uV] CISr.) Range Name (PPB) 8981 175 98 177 2241 651 377 9797 1938 1122 567 450 1252 139 202 353 187 123 122 172 542 146 .30 .31 .10 .04 .90 .96 .82 ..2 .65 .31 .20 .25 ..6 .08 .35 .10 . 71. .09 .n .42 .66 .31 0 2 0 0 3 0 0 2 0 0 0 0 n 0 0 Q 0 0 0 0 0 0 .00 .04 .14 .25 VCt .15 .92 .10 .67 .53 .31 .16 110CIE .03 .09 .01 T-12DCIE .02 .03 .01 .02 .02 .03 .11 .01 0.00 2.04 0.14 0.25 3.15 0.92 0.10 2.67 0.53 0.31 0.16 0.03 0.09 0.01 0.02 0.03 0.01 0.02 0.02 0.03 0.11 0.01 •H O N T-! "J ~ """' H-D 1- /.0001791 25 26 27 28 29 30 31 2 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 •6 28.451 29.379 31.094 31.385 34.735 35.568 36.103 36.601 39.355 44.900 45.716 46.281 46.957 47.725 50.893 52.871 57.386 58.599 60.277 61.706 61.896 62.360 62.627 62.970 63.543 63.715 63.959 64.137 64.426 64.565 64.892 65.495 65.867 66.232 66.530 66.953 68.031 68.256 68.585 68.936 69.160 69.533 0.1 0.1 0.1 0.0 -0.9 0.0 0.0 0.0 -1.8 0.0 0.1 0.1 0.1 0.1 0.2 0.0 0.0 0.0 0.0 0.0 0.0 0.1 0.0 0.1 0.0 0.0 0.0 0.0 0.0 0.0 0.1 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 V8 BV w w w w w w w w w w VB BV VB BV vv VB BV VV VV W VV VB BV VV VV VV VV VV VB BB BB BB BB BB BV VB BB BB BB BB Bz FBI TCIE C-13DClPe Toluene TetClE CIBZ EthylBz m-Xylene o-Cl,F-Ben o-Xylene 130CIBZ UDClBz 12DCIBZ 1 .0187*5 16974.1797 2.1275*5 5.7025*5 74258.3672 28415.2871 2.0211*5 1 .4213*5 51822.0469 1.9495*5 88228.8047 78500.7266 83085.9922 15780.9004 71958.7500 1.2120e5 2.4650e5 1.9172e5 1.0299e5 95375.4375 1.5594e5 75012.9766 92462.5156 85485.2188 71909.3828 78248.8516 67847.1719 93257.1406 62161.9492 68555.6172 54679.9219 92529.8281 44896.2891 49472.8906 47093.2500 40236.5664 1.7427e5 55898.9531 58978.1875 61923.8594 48276.4219 40483.6250 31432.83 1553998.63 13761 .88 71717.44 5632.13 10301.31 10416.05 21579.25 21873.94 14296.50 11063.02 15244.98 6194.66 1443300.75 17597.19 8254.94 15471.38 2632.63 39229.13 2198.03 3829.16 2091.59 1504.78 3276.56 726.49 945.73 6269.73 8033.83 2106.53 4052.55 10370.39 6032.50 228.75 298.00 114157.00 225.50 1690.47 471.54 1337.50 1127.01 2699.00 645.75 3491.24 191432.59 415.98 808.79 196.21 937.86 539.48 1589.24 1665.17 544.49 931.02 1200.56 473.74 119719.45 1313.94 365.93 642.38 140.54 3898.28 235.88 251.32 285.38 166.57 392.91 103.57 123.90 799.99 745.78 293.37 511.74 1641.85 564.40 44.11 52.15 20985 . 1 1 48.52 83.98 73.03 196.32 157.56 483.99 138.09 0.31 91.55 0.07 0.13 0.08 0.36 0.05 0.15 0.42 0.07 0.13 0.19 0.08 91.46 0.25 0.07 0.06 0.01 0.38 0.02 0.03 0.03 0.02 0.04 0.01 0.01 0.09 0.09 0.03 0.06 0.19 0.07 0.01 0.01 2.42 0.01 0.01 0.01 0.02 0.02 0.06 0.02 Bz FBz TCIE C-130ClPe Toluene TetClE ClBz EthylBz m-Xylene o-Cl,F-Ben o-Xylene 13DCIBZ 140CIBZ 12DCIBZ 0 91 0 0 0 0 0 0 0 0 0 0 0 91 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2 0 0 0 0 0 0 0 .31 .55 .07 .13 .08 .36 .05 .15 .42 .07 .13 .19 .08 .46 .25 .07 .06 .01 .38 .02 .03 .03 .02 .04 .01 .01 .09 .09 .03 .06 .19 .07 .01 .01 .42 .01 .01 .01 .02 .02 .06 .02 -7.3 6.1071e6 3779460.75 388508.09 199.72 199.72 Missing Component Report Component Expected Retention (Sample File) Air C-12DC1E 2ClEthylVO T-13DC1P6 5.000 24.122 34.045 37.423 Y. NOT DETECTED ON PRIMARY RUN: Z. NOT DETECTED ON HALL TUT 004 1792 L000179;: V3400A PID 0356 Sample Name : W7378 FUeMame : n:\v3400s\TC10015.ran Method : SOOOSUE.ins Start Time : 0.00 win End Time : 70.00 win Scale Factor: 0 Plot Offset: 4 MV Sample t: TRIP BLANK Date : 3/11/93 10:42 AM Time of Injection: 3/11/93 3:21 AM Low Point : 4.00 mV High Point : 39.00 mV Plot Scale: 35 mV Response [ NJo 5.70 15.09 -25.50 |BZ 1FBZ _ _ -28.45 —J2CLETHYLVO- ——JC-13DCLPE - "1 TOLUENE ^jT-130CLPE - —I ——'TETCLE -38.60 39.36 ,J ; _jc d -q JO-CL.F-BE - JO-XYLENE - -50.89 52.87 -CD 1^57.39 -y-58.60 -60.28 ——|12DCLBZ -66.53 L0001793 HALOGENATED AND AROMATIC VOLATILE ORGANIC ANALYSIS 0357 Laboratory Name ITAS - KNOXVILLE Contract Name L'HENRI ^lient Sample I.D. DRM01 ib Sample I.D. W7329 ^-Sample Matrix WATER Concentration Units ug/1 COMPOUND GAS No. dichlorodifluoromethane 75-71-8 chloromethane 74-87-3 vinyl chloride 75-01-4 bromome thane 74-83-9 chloroethane 75-00-3 trichlorofluoromethane 75-69-4 1, 1- dichloroethene 75-35-4 methylene chloride 75-09-2 t rans -1,2- dichloroethene 156-60-5 l, 1-dichloroethane 75-34-3 cis- 1,2 -dichloroethene 156-59-2 trichloromethane 67-66-3 1, 1, 1-trichloroethane 71-55-6 carbon tetrachloride 56-23-5 benzene 71-43-2 1,2-dichloroethane 107-06-2 trichloroethene 79-01-6 1, 2-dichloropropane 78-87-5 bromodichloromethane 75-27-4 SDG Number NA Job Number ITEK 53554 Collection Date 03/05/93 Confirmation Date NA Analysis Date(s) 03/11/93 Dryness Factor NA DETECTION RESULTS QUALIFIERS LIMITS 1.8 U 1.8 0.8 U 0.8 1.8 U 1.8 1.2 U 1.2 5.2 U 5.2 2.0 U 2.0 1.3 U 1.3 15 U 15 1.0 U 1.0 0.7 U 0.7 23.0 1.0 0.5 U 0.5 0.3 U 0.3 1.2 U 1.2 2.0 U 2.0 0.3 U 0.3 22.0 1.2 0.4 U 0.4 1.0 U 1.0 dibromomethane 74-95-3 °-chloroethyl vinyl ether 110-75-8 Ls-1, 3-dichloropropene 10061-01-5 toluene 108-88-3 trans-1, 3-dichloropropene 10061-02-6 1, 1,2-trichloroethane 79-00-5 tetrachloroethene 127-18-4 dibromochloromethane 124-48-1 1.3 U 1.3 3.4 U 3.4 2.0 U 2.0 3.4 U 3.4 0.2 U 0.2 130.0 Dl:20 6.0 0.9 U 0.9 n-hexyl chloride 544-10-8 chlorobenzene 108-90-7 ethyl benzene 100-41-4 2.0 U 2.0 2.0 U 2.0 1, 1, 1,2-tetrachloroethane 630-20-6 xylenes (total) 1330-20-7 bromoform 75-25-2 1,1,2,2- tetrachloroethane 79-34-5 1.0 U 1.0 2.0 U 2.0 0.3 U 0.3 1, 2, 3- trichloropropane 96-18-4 - - - phenyl bromide (bromobenzene) 108-86-1 2-chlorotoluene 108-41-8 - - - 1,3-dichlorobenzene 541-73-1 1, 4-dichlorobenzene 106-46-7 1, 2-dichlorobenzene 95-50-1 3.2 U 3.2 2.4 U 2.4 1.5 U 1.5 bis (2-chloroisopropyl) ether 108-60-1 - - - SURROGATE RECOVERY BCM OCFB ACCEPTANCE LIMITS SOIL (31-112) (34-113) WATER (53-150) (64-121) LAB I.D. W7329 83 88 W7329 Dl:20 61 59 FB OFCB (23-113) (21-108) (70-128) (72-122) 84 83 - ^i(> r-v. •H •3-O h- —— i 1- / - O O O I V 9 , U J JO Software Version: 3.2 <16C20> Sample Name Sample Number Operator Instrument AutoSampler Rack/Vial DRM01 W7329/20 V3400A/SALLY NONE 0/0 Time Study Channel : A 3/12/93 10:08 AM ITEK53554 A/D mV Range : 1000 Interface Serial Delay Time End Time Sampling Rate Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount Noise Threshold Multiplier # : 0159572256 0.00 min. 70.00 min. Data Acquisition Time: 3/12/93 8:18 AM 2.0000 pts/sec n:\v3400s\SC11014.raw n: \v3400s\SC11014.rst N:\V3400S\8000SUE.ins N: \V3400S\HALL.prc N: \V3400S\LINHSCll.smp n: \v3400s\scll.seq 5 mL 1.0000 ^\ Area Reject : 100.00 Dilution Factor : 1.00 *>\*JAS 15 1.0000 Area Threshold : 73 Bunch Factor: 2 Divisor : 1.0000 Adder : 0.0000 Instrument Conditions: Total Number of Peaks Detected: 32 ITAS-KNOXVILLE V-3400B J+W DB-624 75m*0.53mm ED, 3.00um df ELECTROLYTIC CONDUCTIVITY DETECTOR-BrClMe AND 0-C1FBZ ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. ALL OTHER ANALYTES ARE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLUME OF 5.O ML. Peak n 1 2 3 L. 5 6 7 8 9 10 11 12 13 H 15 16 17 18 19 20 21 22 Ret Time RT OIFF. CmirO X 1.101 5.8K 7.319 8.098 9.367 11.416 12.579 13.690 17. U3 19.145 20.344 24.239 24.919 25.555 26.723 27.882 28.494 29.457 31.188 32.936 35.223 40.202 0.0 0.0 3.9 -3.0 3.1 -4.3 0.8 -2.3 0.7 0.3 0.6 0.4 0.5 0.4 0.5 0.5 0.5 0.0 0.3 0.5 0.4 0.3 81 BB BV W W W W VB BB BV VE EB BV W VE EV VV VV W W W VB BE Component Name OClDFMe CLHE VCl BrHe ClEa TClFMe 110CIE CH2C12 T-12DCIE C-12DCIE CHC13 BrClMe IHTClEa CC14 12DCIE8 TCIE BrOClMe C-13DClPe TetClE Area/ Amount 295.8840 99148.6641 94243.4609 3.0945e5 5.1433e5 1.6236e5 3.2061e5 1.5513e5 9.3839e5 4.8425e5 1.6136e6 3.2149e5 7.0731e5 65147.4180 1.1198e6 8.3124e5 6.5914e5 6.9577e5 4.9720e5 7.8314e5 2.0383e6 4.2189e5 Area CuV«sec] 804.01 109660.69 24411.92 17969.52 67272.81 13955.34 3583.22 799.00 73859.09 358790.31 15975.50 268779.25 148556.09 3956644.50 213739.00 114471.19 157711.00 120449.50 515875.84 156972.13 40730.50 2661157.25 Height INST. Amt [uV] ( I S X ) 70.62 3716.il 857.79 439.95 1087.73 325.30 116.51 79. 16 1837.60 27317.22 285.02 20990 . 1 l 7016.35 309134.59 5294.50 4327.01 5462.22 3952.08 31438.98 4325.77 495.39 185109.84 2.72 1.11 0.26 0.06 0.13 0.09 0.01 0.01 0.08 0.74 0.01 0.84 0.21 60.73 0.19 0.14 0.24 0.17 1.04 0.20 0.02 6.31 Cal. Component SAMPLE CON Range Name (PPB) DClDFMe CLME VCl BrMe ClEa TClFMe 110CIE CH2C12 T-12DCIE C-120CIE CHC13 BrClMe 111TClEa CC14 120CIE8 TCIE BrOClMe C-130ClPe TetClE 2.72 1.11 0.26 0.06 0.13 0.09 0.01 0.01 0.08 0.74 0.01 0.84 0.21 60.73 0.19 0.14 0.24 0.17 1.04 0.20 0.02 6.31 ID Chr- •H <t Q H D H C 000 1795 * 70 : , 2 . - U OvJ 23 24 25 26 27 28 29 30 31 32 41.373 45.960 47.289 47.830 53.652 58.083 62.542 63.062 65.001 68.717 0.4 EV DBrCLM* 4.9675*5 0.6 W ClBz 4.2165*5 0.0 W 1.0263*5 0.3 W o-Cl,F-Ben 44340.2813 0.3 VB CHBr3 2.0196*5 3.8 BB 123TriClPr 1.2364*6 0.3 BV 13DC18Z 4.2480*5 0.2 VB 14DCIBZ 2.7251e5 0.2 BB 12DCIBZ 2.7107e5 0.0 BB 2.7440e5 130167.50 2961.19 21991.63 464.65 15872.16 387.22 2629248.00 148479.83 41562.25 1142.93 11668.25 92.45 4017.13 137.21 79009.38 5082.80 25895.50 1675.41 3735.50 238.75 0.26 0.05 0.16 59.30 0.21 0.01 0.01 0.29 0.10 0.01 OBrCIM* ClBz o-Cl,F-Ben CHBr3 123TriClPr 13DCIBZ UOClBz 120CIBZ 0.26 0.05 0.16 59.30 0.21 0.01 0.01 0.29 0.10 0.01 10.0 1.6579e7 12005334.00 774346.50 135.68 135.68 Missing Component Report Component Expected Retention (Sample File) Air TCLTFEa HlDClEa 12DClPa 2ClEthylVO T-13DClPe 112TC1E3 1122TetClEa 1.845 16.467 21.813 31.839 34.083 37.446 3 8 . 2 5 7 54.941 Y. NOT DETECTED ON PRIMARY RUN: Z. NOT DETECTED ON PID TUT 004 .1796 LOQ0179G V3400A HALL 0360 Sample Na«* : ORH01 FiteNam : n:\v3AOOt\SC11014.raw Method : SOOOSUE.ins Start Tim* : 0.00 min End Time : 70.00 min -ale Factor: 0 Plot Offset: 4 mV Sample *: W7329/20 Datt : 3/12/93 10:09 AM Time of Injection: 3/12/93 8:18 AM Low Point : 4.00 mV High Point : 39.00 mV Plot Scale: 35 mV 3 /"-. c"~ r^ ~ - P [".] _ AIR 1.10 DCLDFME "CLME ;TCLFME -'CH2CL2 -1T-12DCLE _J111DCLEA -I d^SC :BRCLME CLE - ^ J HTCLE _12DCLPA _BRDCLME (C-130CLPE s-35.22 1112TCLEA - JTETCLE ^DBRCLME 1.37 —19.15 -24.24 25.5 -31 .19 ,3.2 -:.8 nCHBR3 - ^_-53.65 —(123TRICLP - I -L mm - 58.08 t-62.54 J12DCLBZ - ->^__ 65.00 -f ^S-681B72 -63.06 TLjT 004 1797 L 0 0 0 1 7 9 7 Software Version: 3.2 <16C20> Sample Name Sample Number Operator ^-^nstrument AutoSampler Rack/Vial W7329 DRM01 V3400A/SALLY NONE 0/0 Time Study Channel : A 3/20/93 10:24 AM ITEK53554 A/D mV Range : 1000 Interface Serial # : 0159572256 Data Acquisition Time: 3/11/93 4:37 AM Delay Time End Time Sampling Rate Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount Noise Threshold Multiplier 0.00 70.00 2.0000 mm. min. pts/sec n:\v3400s\SC10016.raw n:\v3400s\SC10016.rst N:\V3400S\8000SUE.ins N:\V3400S\HALL.prc N:\V3400S\LINHSC10.smp n:\v3400s\scl0.seq 5 mL 1.0000 Area Reject : 100.00 Dilution Factor : 1.00 15 1.0000 Area Threshold : 73 Bunch Factor: 2 Divisor : 1.0000 Adder : 0.0000 Instrument Conditions: Total Number of Peaks Detected: 31 ITAS-KNOXVILLE V-3400B J+ W DB-624 7Sm*0.53mm ID, 3.00um df ELECTROLYTIC CONDUCTIVITY DETECTOR-BrClMe AND 0-ClFBz ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. ALL OTHER ANALYTES ARE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLUME OF 5.O ML. Peak # 1 2 3 4 5 6 7 a 9 10 11 12 13 14 • ^<-6 17 18 19 20 21 22 Ret Time RT DIFF. Cm in] X 5.880 6.941 7.632 8.602 9.196 10.749 12.469 14.213 17.146 19.153 20.294 24.237 24.900 25.560 26.726 28.557 29.467 31.175 33.125 34.935 36.644 39.796 0.0 -1.1 0.0 3.3 1.3 0.0 -0.0 1.5 0.6 0.3 0.3 0.2 0.2 0.2 0.4 0.6 0.0 0.1 0.9 -0.5 0.0 0.0 BL BV W W W W W W VB BV W VB BE EV VE EV W W W W W W W Component Name DClDFMe CLME VCl ClEa TClFMe 11DCIE CH2C12 T-12DCIE C-120CIE CMC 1 3 BrClMe 111TClEa 12DClEa TCIE BrDClMe C-13DClPe Area/ Amount 1.1152e5 1.1091e5 73518.8125 1.9564e5 2.7394e5 2.0025e5 9.6087e5 6.7606e5 8.3258e5 4.3792e5 4.8083e5 3.0101e5 7.6709e5 64711.4023 1.8569e6 9.9073e5 6.8401e5 3.7358e5 1.0907e6 1.6851e6 1.3735e6 3.8052e5 Area [uV*s*c] 321505.25 90048.48 52237.67 16176.97 74274.38 19602.19 19135.34 14211.91 10235.00 134198.50 129111.50 6911825.50 245999.00 5382547.00 306408.00 67042.05 120826.91 8278370.00 146400.06 53601.25 40077.56 8614.34 Height INST. Amt [uV] (ISX) 8827.35 2350.58 2051.43 547.27 2083.04 327.15 241.62 276.31 305.13 9563.16 8191.25 614922.31 11346.97 418633.47 4882.90 1607.14 4195.29 700534.50 3014.08 801.60 405.83 695.56 2.88 0.81 0.71 0.08 0.27 0.10 0.02 0.02 0.01 0.31 0.27 22.96 0.32 83.18 0.17 0.07 0.18 22.16 0.13 0.03 0.03 0.02 Cat. Component SAMPLE Range Name (PPB) DClDFMe CLME - VCl ClEa TClFMe 11DCIE CH2C12 T-12DCIE C-120CIE CHC13 BrClMe niTClEa 12DQEe TCIE BrDClMe C-13DClPe 2. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 22. 0. 83. 0. 0. 0. 22. 0. CON 88 81 71 08 27 10 02 02 01 31 27 96 32 18 17 07 18 16L 0 f • ) 1 13 u ° " J 0.03 0. 0. 03 02 CD 0- I- 23 24 25 26 27 28 29 1 • 40.204 45.908 47.839 56.099 62.582 63.109 63.660 64.990 68.669 0.1 VE TetClE 6.9033tS 0.3 EV ClBz 9.0207*5 0.2 W o-Ct,F-Ben 43029.2852 0.1 W 123Tr1ClPr 7.6078*5 0.3 W 130CIBZ 1.2071*6 0.2 W 14DCIBZ 3.5825*5 0.0 VB 3.6716*5 0.1 BB 12DCIBZ 2.7731*5 0.0 BB 2.2267*5 22359504.00 995169.19 190626.00 1966.55 3778050.25 213358.45 15052.38 179.20 5341.19 77.06 7801 .05 420.67 23596.75 1241.58 35259.50 2290.94 18327.00 1482.97 32.39 0.21 87.80 0.02 0.00 0.02 0.06 0.13 0.08 TetClE ClBz o-Cl,F-B*n 123TriClPr 130CIBZ 14DCIBZ 12DCIBZ 32-39 men 0.21 0362 87.80 0.02 0.00 0.02 0.06 0.13 0.08 9.8 1.8750*7 48876004.00 3.01*6 255.45 255.45 Missing Component Report Component Expected Retention (Sample File) Air BrMe 2756111DClEa CC14 12DClPa 2ClEthylVO T-13DClPe 112TClEa DBrClMe CHBr3 1122TetClEa I.845 II.919 21.838 27.774 31.870 34.116 37.487 38.300 41.272 53.534 54.996 Y. NOT DETECTED ON PRIMARY RUN: Z. NOT DETECTED ON PID TUT 004 1799 L O C 0 1 7 3 5 Sample Naoe : W7329 FileMane : n:\v3400s\SC10016.raw Method : SOOOSUE.Ins Start Time : 0.00 win End Time : 70.00 win 3le Factor: 0 Plot Offset: 4 mV V3400A HALL 0363 Sanple *: DRM01 Date : 3/20/93 10:24 AM Time of Injection: 3/11/93 4:37 AM Low Point : 4.00 mV High Point : 39.00 mV Plot Scale: 35 mV Response [mV] ( _ AIR -^ ->• ro ro uj LAI Ji O C/i O en o Ln 1 ! 1 1 1 ! 1 II 1 i ! : i ! i --X O _ DCLDFHE CIME VCL NJ (D o _ 0) ^^ ^ O J O)o~n TCLFME 11DCLE CH2CL2 T-12DCLE 2756111DC Q-12DCLE 111TCLEA 12DCLPA BROCLNE 2CLEWLVO- C-130CLPE - T-130CLPE - 112TCLEA - TETCLE DBRCLME CLBZ 0-CL.F-BE - 19.15 -20.29 13-24.2 —25.5 25.73' 29.47 33.13 39,80 --40.2 5.91 •:- 47.8 CHBR3 1122TETCL - 123TRICLP - -S-56.10 120CLBZ i TUT 004 1800 67 Software Version: 3.2 <16C20> Sample Name Sample Number Operator -instrument AutoSampler Rack/Vial W7329 DRM01 V3400A/SALLY NONE 0/0 Time Study Channel : B : 3/20/93 1:15 PM : ITEK53554 A/D mV Range : 1000 Interface Serial # : 0159572256 Data Acquisition Time: 3/11/93 4:37 AM Delay Time End Time Sampling Rate Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount Noise Threshold Multiplier 0.00 mm. 70.00 min. 2.0000 pts/sec n:\v3400s\TC10016.raw n:\v3400s\TC10016.rst N:\V3400S\8000SUE.ins N:\V3400S\PID.prc N:\V3 4 OOS\LINPTC10.smp n:\v3400s\scl0.seq 5 ml 1.0000 Area Reject : 100.00 Dilution Factor : 1.00 10 1.0000 Area Threshold : 49 Bunch Factor: 2 Divisor : 1.0000 Adder : 0.0000 Instrument Conditions: Total Number of Peaks Detected: 78 ITAS-KNOXVILLE V3400A RTX 502.2 105m*0.53mm ID,3.00um df PID DETECTOR-FBZ AND O-ClFBz ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. ALL OTHER ANALYTES ARE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLUME OF 5.0 ML. Peak # 1 2 3 5 6 7 9 10 11 12 13 14 15 16 7 --18 19 20 21 22 23 24 Ret Time RT DIFF. [min] X 5.709 6.636 7.067 8.967 9.412 10.222 13.813 15.088 15.680 15.946 16.596 17.013 17.694 18.195 18.903 19.076 19.821 20.217 20.614 21.495 22.264 22.725 0 0 0 -0 0 0 0 0 0 0 0 .0 .0 .0 .3 .0 .0 .0 .0 .0 .0 .0 0.2 0 0 0 0 0 0 0 0 0 0 .0 .0 .0 .0 .0 .2 .0 .0 .0 .0 BL Component Name BVW VB W VCl W VB BB BB BVWW W 110CIE WW W W W W T-12DCIE WWWW Area/ Amount 5933.1348 14419.1719 9637.6660 10188.4199 69206.7656 34731.0000 36901.5234 37048.3789 33678.2344 42645.2227 63352.8906 31727.3359 1.5953e5 1.2837e5 1.5829e5 81804.2422 2.1123e5 2.0484e5 49819.9922 63753.7695 Area [uV*sec] 431082.44 9562.80 1215.02 21097.83 25292.89 8319.92 5321 .97 94553.25 19355.98 11600.23 10320.09 2785.39 1671.02 1150.27 1465.38 2122.96 157938.36 23745.42 2675.41 5249.59 1129.22 1149.62 Height INST. Amt Cal. Component SAMPLE CON [uV] (ISX) Range Name (PPB) 47631.45 675.80 145.66 1040.76 1866.72 580.85 281.76 9975.04 1921.88 1147.24 1122.77 239.32 96.64 132.84 123.28 221.95 13390.72 3895.73 169.99 343.94 115.37 91.78 0 0 0 1 .00 .00 .21 .46 VCl 2.62 0 0 2 0 0 0 0 0 0 0 0 1 0 0 0 0 0 .82 .08 .72 .53 .31 .31 .07 11DCIE .03 .04 .01 .02 .00 .29 T-12DCIE .01 .03 .02 .02 0.00 0.00 0.21 1.46 2.62 0.82 0.08 2.72 0.53 0.31 0.31 0.07 0.03 0.04 0.01 0.02 1.00 0.29 0.01 / nn 0.03 1— w U 0.02 0.02 ,_, O CO •H <•o '— ' 1-D 1- f\ t O A • U J o U i 25 26 27 28 29 30 31 ~2 3 14 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 6 j7 '68 69 70 71 72 73 74 75 76 77 78 23.113 23.494 24.170 25.533 28.008 28.484 29.411 30.618 31.112 31.403 34.773 35.602 36.125 36.634 37.118 39.395 40.133 44.940 45.751 46.315 46.992 47.758 50.915 52.915 53.842 56.300 56.682 57.394 57.798 59.336 60.280 61 .898 62.363 62.648 62.971 63.700 63.966 64.136 64.413 64.559 64.889 65.504 65.867 66.226 66.524 66.961 67.745 68.016 68.246 68.575 68.931 69.151 69.404 69.521 0.0 0.0 0.2 0.0 0.0 0.2 0.2 0.0 0.2 0.0 -0.8 0.0 0.0 0.1 -0.8 0.0 0.1 0.0 0.2 0.2 0.2 0.2 0.3 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.1 0.0 0.1 0.0 0.0 0.0 0.0 0.0 0.1 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 ww VB BB BVww w VE EV W W W W W W W w w w w w VB BV VB BV VB BV VB BB BV W W W VB BV W W W W VB BB BB BB BB BB BB BB BV W W W W VB C-12DCIE Bz FBz TCIE C-130ClPe Toluene T-130ClPe TetClE ClBz EthylBz m-Xylene o-Cl,F-Ben o-Xylene 13DCIBZ KOClBz 12DCIBZ 64590.2266 58019.1094 36008.2578 79746.0156 1 .9437e5 1.0362e5 16962.6836 1.4174e5 46427.3047 8.1368e5 83951.2422 31567.7461 2.2056e5 95240.2891 35369.1484 40202.9570 37074.3711 1.4111e5 89509.0781 78645.7500 82047.3125 15716.5889 73508.0313 1.1652e5 1.7582e5 78029.3984 1.0151e5 1.2994e5 1.1125e5 3.2805e5 1.0878e5 2.2541e5 75247.5156 85181.3125 84354.0313 1.5076e5 59053.3906 1.0324e5 63627.2969 72333.4766 56942.1133 85045.0156 40886.3164 50650.5977 47025.9453 1.0527e5 42528.8203 52307.8047 48959.9336 1.2085e5 1.0149e5 58007.4727 63175.8633 51845.2656 2873.77 3235.89 791013.25 7918.75 2568.56 37520.48 1416634.63 2938.05 950606.69 76565.00 6277.91 6912.77 11654.02 19283.89 9879.19 12254.84 6542217.00 8415.19 11922.75 13040.55 10015.52 1299820.13 18508.63 13397.38 3625.63 6043.13 1556.63 9506.45 2684.56 4171.50 41237.44 5547.00 2308.63 1385.95 5815.47 1142.28 6440.59 18684.09 2667.14 4461.91 12441.99 5657.25 547.00 850.50 103700.48 1210.01 322.50 894.00 793.26 2671.64 2891.44 5124.23 1311.73 1203.68 226 283 111814 505 149 4097 174629 133 131675 605 193 566 553 2119 454 1202 696142 442 989 1025 775 108259 1352 617 110 416 156 748 246 130 3879 251 314 166 706 77 944 1566 362 534 1891 575 115 145 19090 99 65 147 140 191 246 764 179 200 .47 .88 .83 .44 .52 .00 .39 .30 .78 .13 .46 .51 .11 .52 .66 .53 .56 .77 .02 .06 .63 .15 .87 .78 .79 .12 .95 .77 .97 .15 .81 .86 .01 .53 .72 .67 .17 .66 .89 .01 .58 .87 .82 .36 .21 .50 .65 .96 .26 .37 .63 .74 .75 .99 0.04 0.06 21.97 0.10 0.01 0.36 83.52 0.02 20.48 0.09 0.08 0.22 0.05 0.20 0.28 0.31 176.46 0.06 0.13 0.17 0.12 82.70 0.25 0.12 0.02 0.08 0.02 0.07 0.02 0.01 0.38 0.03 0.03 0.02 0.07 0.01 0.11 0.18 0.04 0.06 0.22 0.07 0.01 0.02 2.21 0.01 0.01 0.02 0.02 0.02 0.03 0.09 0.02 0.02 C-12DCIE Bz FBz TCIE C-130ClPe Toluene T-130ClPe TetClE ClBz EthylBz m-Xylene o-Cl,F-Ben o-Xylene 130CIBZ 14DCIBZ 120CLBZ °-04 me' 0.06 036*: 21.97 0.10 0.01 0.36 83.52 0.02 20.48 0.09 0.08 0.22 0.05 0.20 0.28 0.31 176.46 0.06 0.13 0.17 0.12 82.70 0.25 0.12 0.02 0.08 0.02 0.07 0.02 0.01 0.38 0.03 0.03 0.02 0.07 0.01 0.11 0.16 0.04 0.06 0.22 0.07 0.01 0.02 2.21 0.01 0.01 0.02 0.02 0.02 0.03 0.09 0.02 0.02 0.6 7.0209e6 12371178.00 1.35e6 402.27 402.27 Missing Component Report Component Expected Retention (Sample File) Air 2ClEthylVO 5.000 34.045 Y. NOT DETECTED ON PRIMARY RUN: Z. NOT DETECTED ON HALL TUT 004 1802 L000180;; V3400A PID Sample Name : W7329 Filename : n:\v3400s\TC10016.raw Method : SOOOSUE.ins Start Time : 0.00 min End Time : 70.00 min 'cale Factor: 0 Plot Offset: 4 mV Sample f: DRH01 Date : 3/20/93 1:15 PM Time of Injection: 3/11/93 4:37 AN Low Point : 4.00 *V High Point : 39.00 mV Plot Scale: 35 MV Response [nnV] en O en NOO NJ en LAO o- cn O J roo' 0) u O~ D o~ (7)o~^ AIR VCL 11DCLE T-12DCLE - C- ?DCLE - BZ FBZ TCLE 2CLETHYLVO- C-13DCLPE - TOLUENE T-130CLPE - TETCLE 68 I lL-28.01 -28.48 ^30.62 0-CL.F-BE 0-XYLENE 94 50.92 12DCLBZ 60.2S -15.09 -19.82 i.52 f-'J O CO •3h- L O O O I S O ' J m*--""' ••#m. --. -, . 0367 STANDARDS DATA TUT O04 ISO4 1000.1804 Sample File : N:\V3400S\LINHSC10.SMP Created by : on : 5/12/89 2:54 PM Edited by : on : 3/11/93 9:43 AM Number Of Times Edited : 395 Sample Description : Default Injection Volume = 5.0000 mL An External Standard Calibration Will Be Used Unknown Peaks Will Use The Response Factor Of The Nearest Component ?on«nt Information : Retention Time : 1.845 min Search Window: 5.00 sec, 5.00 % Referehee Component: (Find Closest Peak) Group Name Calibrating frel9nt versus Amount Using a 2nd Order Fit Curve Will Be Fc-rced Through The Origin Amounts Will Not Re Scaled Prior To The Regression Weighting Factor For\£he Regression: 1 Calibration Levels: Level Name Amount \Area Height ISTO Resp. ISTD Amt. 0 Replicates A c D £ 1.5000 7.5000 ie nriAA 22.5000 Tn nnnn •••••X"" — • 360K22 1313.5V 5577. 00 \ 1417.25 iu.s nn 125.35 .--..-..-.. .. 111.82 - - - - - - - - - - - -- v 264.70 - - - - - - - - - - - -- N92.82 - - - - - - - - - - - -- frg so ........... ......... 1 ......... ! ......... ! ......... T ......... i Calibration Curve R-squared y = (0.000000) 0.481345 (28.308945)x + (-0.853783)x-2 + (0.000000)x'3 DClDFMe / Retention Time : 7.015 min -^ Search Window: 14.00 sec, 2.00 I Reference Component: BrClMe (Find Closest Peak) Group Name : 601 Calibrating Height versus Amount Using a 2nd Order Fit Curve Will Be Forced Through The Origin Amounts Will Not Be Scaled Prior To The Regression Weighting Factor For the Regression: l Calibration Levels: Level Name Amount Area Height ISTD Resp. ISTO Amt. * Replicates A B C D f 1.5000 7.5000 15.0000 22.5000 *n nnnn rrofn -re 1531688.38 2259152.50 7A7O33H nn 3087.47 ---- ------- ---- 28988.35 " ----------- ---- 95403.59 , ----------- ---- 1A11TA RO , ......----- .... ....... 1 ....... 1 Calibration Curve R-squared CLME Retention Time y » (0.000000) + (2829.930664)x * (80.554604)x'2 <• (0.000000)x'3 0.991444 14 mi: 8.324' min Search Window: Reference Component: BrClMe (Find Closest Peak) Group Name : 601 Calibrating Height versus Amount Using a 2nd Order Fit Curve Will Be Forced Through The Origin Amounts Will Not Be Scaled Prior To The Regression Weighting Factor For the Regression: 1 Calibration Levels: Level Name Amount Area Height 1STD Resp. ISTO Amt. 19.00 sec, 2 . 0 0 GJ # Replicates H- ~3 H- A 1.5000 156657.11 8156.97 - - - - - - - - - . - .. B 7.5000 1276222.50 64754.24 . - . - - - - - - - - .. C 15.0000 2786940.00 141951. 77J - - - - - - - - - - - -- n 77 snnn £?i?«nn nn 3ia«7 TT i ........... 1 ::::::::: 1 /i 0 G 0 J. 0369 Calibration Curve R-squared y » (0.000000) + (6605.184570)* + (164.040314)x'2 * (0.000000)x'3 0.996027 VC1 / ^ Retention Time : 9.074 min Search Window: 25.00 sec, 2.00 % Reference Component: BrClMe (Find Closest Peak) Group Name : 601 Calibrating Height versus Amount Using a 2nd Order Fit Curve Will Be Forced Through The Origin Amounts Will Not Be Scaled Prior To The Regression Weighting Factor For the Regression: 1 Calibration Levels: Level Name Amount Area Height ISTD Resp. ISTD Amt. * Replicates A B C D c 1.5000 7.5000 i 5 nnnn 22.5000 •*n nnnn 221183.44 1580973.75 3273454.75 4919993.00 7Ln\7LL nn ................ ............. onoo ^ « 71710.14 .---..-.--- --- 155780.55 .----..-.-- --- 242520.41 ' ----------- --- 77O3T* T«\ .--.......- ... - - - - - - - - 1 ........ 1 ........ 1 ........ 1 ..----.. 1 Calibration Curve R-squared y = (0.000000) 0.997578 + (7639.020020)x * (161.501953)x'2 + (0.000000)x'3 BrMe Retention Time : 11.9-IT9 min Search Window: 26.00 sec, 2.00 % Reference Component: BrClMe (Find Closest Peak) Group Name : 601 Calibrating Height versus Amount Using a 2nd Order Fit Curve Will Be Forced Through The Origin Amounts Will Not Be Scaled Prior To The Regression Weighting Factor For the Regression: l Calibration Levels: Level Name Amount Area Height ISTD Resp. ISTD Amt. * Replicates A B C D c 1 cnnn 7.5000 15.0000 22.5000 •»n nnnn 32430.66 CflAA 31 TC 1505482.50 2306786.00 TAtOC37 3« 1505.09 ' - - - - - - - - - - - --- 30582 .75' - - - - - - - - - - - --- 80779.73* - - - - - - - - - - - --- 125658.02 - - - - - - - - - - - --- 3n3«37 i* I ........... ... ........ 1 ........ 1 ........ 1 ........ ! ........ 1 Calibration Curve : y = (0.000000) » (3331.114502)x + (111.818085)x'2 + (0.000000)x'3 R-squared : 0.996645 ClEa Retention Time : 12.4^3 min Search Window: 17.00 sec, 2.00 % Reference Component: BrClMe (Find Closest Peak) Group Name : 601 / Quantitation Will Be Done Using Response Factor = 12133.000000 TClFMe ^ Retention Time : 14.003 min Search Window: 21.00 sec, 2.00 % Reference Component: BrClMe (Find Closest Peak) Group Name : 601 Calibrating Height versus Amount Using a 2nd Order Fit Curve Will Be Forced Through The Origin Amounts Will Not Be Scaled Prior To The Regression Weighting Factor For the Regression: l Calibration Levels: Level Name Amount Area Height ISTD Resp. ISTD Amt. * Replicates CO •H A 1.5000 285387.19 14478.36 - - - - - - - - - ... B 7.5000 2183675.75 116826.66 - - - - - - . - - - ... C 15.0000 4734355.00 260066.45 - - - - - . - - - - - ... D 22.5000 7083384.00 398174.75 - - - - - - - - - - - ... c in nnnn 111331«? nn *nnn QL / ........... ... ........ T - - - - - - - - 1 1 ........ 1 ........ i L 0 0 0 1 8 0 0 Calibration Curv« : y - (0.000000) * (13139.637695)x * <235.727783>x'2 + <0.000000)x'3 R-«quarad : 0.997824 11DC1E // Retention Time : 17.038 min Search Window: 17.00 sec, 1.00 % Reference Component: BrClMe (Find Closest Peak) Group Name : 601 / Quantitation Will Be Done Using Response Factor = 24821.000000 CH2C12 Retention Time : 19.100 min Search Window: 16.00 sec, 1.00 % Reference Component: BrClMe (Find Closest Peak) Group Name : 601 Quantitation Will Be Done Using Response Factor =-3± T-12DC1E Retention Time Reference Component Group Name 20.238 min Search Window: 13.00 sec, 1.00 % BrClMe (Find Closest Peak) , 601 / Quantitation Will Be Done Us^ing Response Factor = 30506.000000 1 Retention Time : 21.838 min Search Window: 16.00 sec, 1.00 % Reference Component: BrClMe (Find Closest Peak) / Group Name : 601 ' Quantitation Will Be Done Using Response Factor = 27561.000000 C-12DC1E • /- Retention Time : 24.188 min Search Window: 16.00 sec, 1.00 % Reference Component: BrClMe (Find Closest Peak) j Group Name : / Quantitation Will Be Done Using Response Factor = 26780.000000 CHC13 Retention Time : 24.840 min Search Window: 16.00 sec, 1.00 % Reference Component: BrClMe (Find Closest Peak) Group Name : 601 _/ Quantitation Will Be Done Using Response Factor = 35383.000000 BrClMe / Retention Time : 25.506 min Search Window: 20.00 sec, l.oo % Reference Component: BrClMe (Find Closest Peak) 7 Group Name : QC Quantitation Will Be Done Using Response Factor = 5033.000000 UlTClEa Retention Time Reference Component Group Name 26.633 min Search Window: 16.00 sec, 1.00 \ BrClMe (Find Closest Peak) ; 601 y Quantitation Will Be Done Using Response Factor = 29593.000000 CC14 Retention Time : 27.774 min Search Window: 19.00 sec, ll.00 Reference Component: BrClMe (Find closest Peak) Group Name : 601 Quantitation Will Be Done Using Response Factor = 33861.000000 12DClEa / Retention Time : 28.393 min Search Window: 16.00 sec, 1.00 « Reference Component: BrClMe (Find Closest Peak) Group Name : 601 S1 Quantitation Will Be Done Using Response Factor = 23750.000000 L O G G i & O Y TC1E ^ Retention Time : 31.131 min Search Window: 14.00 sec, Reference Component: BrClMe (Find Closest Peak) Group Name : 601 Quantitation Will Be Done Using Response Factor = 31614.000000 0371 i.oo % 12DClPa Retention Time Reference Component Group Name 31.870 min Search Window: 17.00 sec, 1.00 % BrClMe (Find Closest Peak) i 601 y Quantitation Will Be Done Using Response Factor = 23155.000000 BrDClMe Retention Time Reference Component Group Name 32.822 min Search Window: 18.00 sec, 1.00 % BrClMe (Find Closest Peak) 601 y Quantitation Will Be Done Using Response Factor = 22456.000000 2ClEthylVO ^ Retention Time : 34.116 min Search Window: 14.00 sec, 1.00 % Reference Component: o-Cl,F-BENZENE (Find Closest Peak) Group Name : 601 Calibrating Height versus Amount Using a 2nd Order Fit Curve Will Be Forced Through The Origin Amounts Will Not Be Scaled Prior To The Regression Weighting Factor For the Regression: 1 Calibration Levels: Level Name Amount Are* Height ISTD Resp. ISTD Amt. * Replicates A B C D e 1.0000 5 nnnn 10.0000 15.0000 in nnnn 43117.59 282304.09 624574.13 820462.81 177OOC1 Cn 1348.24 , ........... ... 15246.46 ; -..------.- --- 40786.82 ........... ... JTrf"»T • / 1 octno *A ........... ... ........ 1 ........ ! ........ ! ........ 1 ........ 1 Calibration Curve R-squared y * (0.000000) 0.994189 (2714.443848)x * (99.458855)x-2 » (0.000000)x-3 C-13DC1P6 / Retention Time : 35.123 min Search Window: 15.00 sec, 1.00 % Reference Component: BrClMe (Find Closest Peak) Group Name : 601 // Quantitation Will Be Done Using Response Factor = 25201.000000 T-13DClPe X ' Retention Time : 37.487 min Search Window: 19.00 sec, l.oo % Reference Component: o-Cl,F-BENZENE (Find Closest Peak) Group Name : 601 Calibrating Height versus Amount Using a 2nd Order Fit Curve Will Be Forced Through The Origin Amounts Will Not Be Scaled Prior To The Regression Weighting Factor For the Regression: l Calibration Levels: Level Name Amount Area Height ISTD Resp. ISTD Amt. * Replicates CDO CO •H A B C 0 1.0000 65164.70 3645. J<- . - - - - - - - . - ........... 7.5000 1416133.13 115713.91 - - - - - - - ........... 15.0000 2957330.50 251537.23 .......... ........... 22.5000 4431510.50 390888.28 ........... ........... tn nnnn iiiTTia sn c 71-100 A TX .......... ........... _ 1- Calibrat ion Curve R-squared 112TClEa Retention Time y * (0.000000) 0.999023 (13904. : 38.300 min • (168.107452)x'2 * (0.000000)x'3 L O O O l S O u Search Window: 19.00 sec, 1.00 Reference Component.: o-Cl, F-BENZENE (Find Closest Peak) Group Name : 601 Quantisation Will Be Done Using Response Factor = 20172.000000 0372 TetClE Retention Time Reference Component Group Name 40.147 min Search Window: 24.00 sec, 1.00 o-Cl,F-BENZENE (Find Closest Peak) 601 Quantitation Will Be Done Using Response Factor = 30725.000000 DBrClMe Retention Time Reference Component Group Name 41.272 min Search Window: 22.00 sec, 1.00 % o-Cl,F-BENZENE (Find Closest Peak) 601 Calibrating Height versus Amount Using a 2nd Order Fit Curve Will Be Forced Through The Origin Amounts Will Not Be Scaled Prior To The Regression Weighting Factor For the Regression: 1 Calibration Levels: Level Name Amount Area Height ISTD Resp. ISTD Amt. * Replicates A B C 0 f 1.0000 7.5000 15.0000 22.5000 •tn nnnn 164155.50 1589133.50 3182569.00 4491806.00 *mi?^o nn T3H3 OO / 85531.35 ; ----------- --- 1 AS AAA AY . . . - 284382 38 ........... ... i?7S7O LT • ........... ... ........ T - - - - - - - - 1 ........ T ........ i ........ i Calibration Curve R-squared y = (0.000000) + (10087.946289)x + (130.516403)x'2 0.998818 (0.000000)x'3 ClBz Retention Time : 45.755 min Search Window: 28.00 sec, 1.00 % Reference Component: o-Cl,F-BENZENE (Find Closest Peak) Group Name : 601 / Quantitation Will Be Done Using Response Factor = 9306.000000 o-Cl,F-Benzene Retention Time Reference Component Group Name 47.755 min Search Window: 29.00 sec, 1.00 % o-Cl,F-BENZENE (Find Closest Peak) QC Quantitation Will Be Done Using Response Factor = 2430.000000 CHBr3 / Retention Time : 53.534 min Search Window: 21.00 sec, 1.00 \ Reference Component: o-Cl,F-BENZENE (Find Closest Peak) Group Name : 601 Calibrating Height versus Amount Using a 2nd Order Fit Curve Will Be Forced Through The Origin Amounts Will Not Be Scaled Prior To The Regression Weighting Factor For the Regression: l Calibration Levels: Level Name Amount Area Height ISTD Resp. ISTD Amt. * Replicates A B C D c 1 • wUW 7.5000 15.0000 22.5000 tn nnnn 53742.91 722927.75 1540370.63 WiOin nn 2436.02 . . - - - - - - - - - -- 38313.16 - - - - - - - - - - -- 91502.36 - - - - - - - - - - - -- 152685. U ...---.-..- -- O1O75T <;« ........... ......... ! ......... T - - - - - - - - - 1 - - - - - - - - - 1 ......... i Calibration Curve : y - (0.000000) * (5028.1523<.<.)» * (70.882538>x-2 + (O.OOOOOOjx'3 R-squared : 0.998769 L 0 0 0 1 8 0 0 1122TetClEa x Retention Time : 54.996 min Search Window: 23.00 sec, l.o: • Reference Component: o-Cl,F-BENZENE (Find Closest Peak) Group Name : 601 TUT 004 1809 WJ.J..L ne uone using Response Factor = 13073.000000 Retention Reference Component: Group Name : Quantitation Will Be 13DC1BZ Retention Time : Reference Component: Group Name : Quantitation Will Be 14DC1BZ Retention Time : Reference Component: Group Name : Quantitation Will Be 12DC1BZ Retention Time : Reference Component: Group Name : Quantitation Will Be « o 7 o U o ( J L.030 min search window: 5.00 sec, 5.00 % Closest Peak) Done Using Response IT = 9057.000000 62.384 min Search Window: 17.00 sec, 1.00 % o-Cl, F-BENZENE (Find Closest Peak) 601 Done Using Response Factor = 17417.000000 62.992 min Search Window: 16.00 sec, 1.00 % o-Cl, F-BENZENE (Find Closest Peak) 601 Done Using Response Factor = 19319.000000 64.918 min Search Window: 16.00 sec, 1.00 % o-Cl, F-BENZENE (Find Closest Peak) 601 , Done Using Response Factor = 18018 . OOOOOO/ 0001810 TUT OO4 181O Sample File : N:\V3400S\LINPTC10.smp Created by : on : 5/12/89 2:54 PM Edited by : on : 3/11/93 9:49 AM Number Of Times Edited : 409 "sample Description : Default Injection Volume = 5.0000 ml An External Standard Calibration Will Be Used Unknown Peaks Will Use The Response Factor Of The Nearest Component Component Information : Air Retention Time : 5.000 min Search Window: 5.00 sec, 5.00 % Reference Component: (Find Closest Peak) Group Name : Calibrating Height versus Amount Using a 2nd Order Fit Curve Will Be Forced Through The Origin Amounts Will Not Be Scaled Prior To The Regression Weighting Factor For the Regression: 1 Calibration Levels: Level Name Amount Area Height ISTD Resp. ISTD Amt. * Replicates A B C D c 1.0000 2.5000 S.OOOO 7 Cnnfl 1 « nnnn 0.00 0.00 0.00 0.00 n nn 331.00 ..--....--- -- 331.00 -..-.---... -- 331.00 ----------- -- 331.00 ----------- -- 171 nn ........... .....-..- o ....--.-. o .....-.-- o ......... o ......... n Calibration Curve : y * (0.000000) * <96.218834)x * (-5.053600>x'2 * (0.000000)x'3 R-squared : 1.000000 VC1 Retention Time : 8.996 min Search Window: 25.00 sec, 2.00 % Reference Component: FBz (Find Closest Peak) Group Name : 601 Quantitation Will Be Done Using Response Factor = 711.299988 11DC1E ^ Retention Time : 16.974 min Search Window: 18.00 sec, 1.00 % Reference Component: FBz (Find Closest Peak) Group Name : 601 Quantitation Will Be Done Using Response Factor = 3664.000000 T-12DC1E /- Retention Time : 20.179 min Search Window: 52.00 sec, 1.00 % Reference Component: FBz (Find Closest Peak) Group Name : 601 Quantitation Will Be Done Using Response Factor = 13421.000000 C-12DC1E / Retention Time : 24.122 min Search Window: 18.00 sec, 1.00 k Reference Component: FBz (Find Closest Peak) Group Name : Quantitation Will Be Done Using Response Factor = 5090.000000 „_, Bz / Retention Time : 28.430 min Search Window: 19.00 sec, 1.00 Reference Component: FBz (Find Closest Peak) Group Name : 602 —' Quantitation Will Be Done Using Response Factor = 11315.000000 FBz L0001811 CD 1- Retention Time Reference Component Group Name 29.361 min Search Window: 20.00 sec, 1.00°%' FBz (Find Closest Peak) QC \J± **+*£? • •<nr»«M^» V* Quantitation Will Be Done Using Response Factor = 2091.000000 TC1E Retention Time Reference Component Group Name 31.064 min Search Window: 17.00 sec, 1.00 % FBz (Find Closest Peak) 601 Quantitation Will Be Done Using Response Factor = 6431.000000 2ClEthylVO Retention Time : 34.0^45 min Search Window: 47.00 sec, 1.00 % Reference Component: FBz (Find Closest Peak) Group Name : 602 Calibrating Height versus Amount Using a 2nd Order Fit Curve Will Be Forced Through The Origin Amounts Will Not Be Scaled Prior To The Regression Weighting Factor For the Regression: 1 Calibration Levels: Level Name Amount Area Height ISTD Resp. ISTO Ant. 0 Replicates A B C 0t 1 nnno 5.0000 10.0000 15.0000 ?n nnnn 11665.13 55438.88 124864.45 175885.84 77TIAO SO 1004.75 ........... -- 7534.33 -- 18194.46 -- 25993.42 -- inon nn ........... .. ......... 1 1 ......... ! ......... T ......... i Calibration Curve : y * (0.000000) + (1346.925049)x + (33.376652)x'2 + (0.000000)x'3 R-squared : 0.994500 C-13DClPe / Retention Time : 35.060 min Search Window: 17.00 sec, 1.00 % Reference Component: FBz (Find Closest Peak) Group Name : 601 Quantitation Will Be Done Using Response Factor = 2587.000000 Toluene /- Retention Time : 36.590 min Search Window: 18.00 sec, 1.00 % Reference Component: FBz (Find Closest Peak) Group Name : 602 ^ Quantitation Will Be Done Using Response Factor = 10468.000000 T-13DClPe / Retention Time : 37.423 min Search Window: 19.00 sec, i.oo \ Reference Component: FBz (Find Closest Peak) Group Name : 601 Calibrating Height versus Amount Using a 2nd Order Fit Curve Will Be Forced Through The Origin Amounts Will Not Be Scaled Prior To The Regression ^ Weighting Factor For the Regression: l 2 Calibration Levels: Level Name Amount Area Height ISTD Resp. ISTD Amt. » Replicates <+ \- Calibration Curve : y = (0.000000) + (1616.920532)* * (38.845093)x'2 » (0.000000)x'3 R-squ.red =0.997691 L 0 0 0 1 81 C TetClE / Retention Time : 40.081 min Search Window: 22.00 sec, i.oo « Reference Component: o-Cl,F-Benzene (Find Closest Peak) A B C D 1.0000 7.5000 15.0000 22.5000 TA AAI-W1 9051.25 1 IO*» 1O.3V CTCTnO ftfl 903.37 ........... ........... 15938.55 ........... ........... 33591.41 .--..-..... ........... 53752.12 ........... - - - - - - - - - - - oy.cnfl TA ,...--..... ........... Group Name : 601 0376 Quantitation Will Be Done Using Response Factor = 3945.000000 C1BZ Retention Time Reference Component Group Name 45.677 min Search Window: 29.00 sec, 1.00 % FBz (Find Closest Peak) 602 Quantitation Will Be Done Using Response Factor = 7425.000000 EthylBz x- Retention Time : 46.242 min Search Window: 29.00 sec, 1.00 % Reference Component: o-Cl,F-Benzene (Find Closest Peak) , Group Name : / Quantitation Will Be Done Using Response Factor = 6182.000000 m-Xylene Retention Time : 46.910 min Search Window: 30.00 sec, 1.00 % Reference Component: o-Cl,F-Benzene (Find Closest Peak) Group Name : 8000 additional comp ^ Quantitation Will Be Done Using Response Factor = 6354.000000 o-Cl,F-Benzene Retention Time Reference Component Group Name 47.677 min Search Window: 31.00 sec, 1.00 % o-Cl,F-Benzene (Find Closest Peak) QC ^ Quantitation Will Be Done Using Response Factor = 1309.000000 o-Xylene ^ Retention Time : 50.780 min Search Window: 28.00 sec, 1.00 % Reference Component: o-Cl,F-Benzene (Find Closest Peak) Group Name : 8000 additional comp / Quantitation Will Be Done Using Response Factor = 5373.000000 13DC1BZ ^ Retention Time : 62.317 min Search Window: 16.00 sec, 1.00 % Reference Component: o-Cl,F-Benzene (Find Closest Peak) Group Name : 602 Quantitation Will Be Done Using Response Factor = 10235.000000 14DC1BZ ^ Retention Time : 62.929 min Search Window: 16.00 sec, 1.00 % Reference Component: o-Cl,F-Benzene (Find Closest Peak) Group Name : 602 Quantitation Will Be Done Using Response Factor = 10251.000000 12DC1BZ /- Retention Time : 64.854 min Search Window: 18.00 sec, 1.00 % Reference Component: o-Cl,F-Benzene (Find Closest Peak) Group Name : 602 Quantitation Will Be Done Using Response Factor = 8657.000000 L0001813 TUT OO4 1813 ********** SUMMARY REPORT ********* 0377 HALL LINEARITY CALCULATIONS FOR V3400A USING A RESTEK 502.2 COLUMN 105m* 0.53mm I.D., 3.Oum Df COLUMN. File Name SAMPLE NAME Nunber sc 10002. A MIX sc 10009. B MIX sclOOIO. C MIX sc 10005. D MIX sc 10006. E MIX File Name SAMPLE NAME Nurtoer SC10002. A MIX sc 10009. B MIX SC10010. C MIX sc 10005. D MIX sc 10006. E MIX Averages XRSD File Name SAMPLE NAME Nunber sc 10002. A MIX sc 10009. B MIX sclOOIO. C MIX SC10005. D MIX SC10006. E MIX Averages %RSD F i l e Name SAMPLE NAME Nunber sc10002. A MIX sc 10009. B MIX sclOOIO. C MIX sclOOOS. D MIX SC10006. E MIX Averages %RSD F i l e Name SAMPLE NAME Nurtoer SC10002. A MIX sc10009. B MIX sclOOIO. C MIX sc 10005. D MIX sc 10006. E MIX Averages XRSD F i l e Name SAMPLE NAME Nuifcer SC10002. A MIX sc10009. B MIX Date Of Injection 3/10/93 3/10/93 3/10/93 3/10/93 3/10/93 Date Of Injection 3/10/93 3/10/93 3/10/93 3/10/93 3/10/93 Date Of Injection 3/10/93 3/10/93 3/10/93 3/10/93 3/10/93 Date Of Injection 3/10/93 3/10/93 3/10/93 3/10/93 3/10/93 Date Of Injection 3/10/93 3/10/93 3/10/93 3/10/93 3/10/93 Date Of Injection 3/10/93 3/10/93 Air Ret. STD CON Height CF Time (PPB) CLME Ret. STD CON Height CF Time (PPB) 8.35 1.5000 8156.97 5.4379e3 8.33 7.5000 64754.24 8.6338e3 8.32 15.0000 141951.77 9.4634e3 8.34 22.5000 218257.77 9.7003e3 8.32 30.0000 351471.53 1.1715e4 8.33 15.3000 156918.45 8v?902«5~-^ 0.16 74.47 85.77(^25.43 ^N BrMe Ret. STD CON Height CF Time (PPB) 11.92 1.5000 1505.09 1.0033e3 11.95 7.5000 30582.75 4.0777e3 11.92 15.0000 80779.73 S.3853e3 11.94 22.5000 125658.02 5.5848e3 11.91 30.0000 202527.45 6.7509e3 11.93 15.3000 88210.61 4-j56g4«l 0.15 74.47 90.27 ('48:31 \^ TClFMe —— Ret. STD CON Height CF Time (PPB) 14.04 1.5000 14478.36 9.6522e3 14.03 7.5000 116826.66 1.5576*4 14.00 15.0000 260066.45 1.7337*. 14.02 22.5000 398174.75 1.7696*. 14.00 30.0000 613013.94 2.0433*. 14.02 15.3000 280512.03/^6139*4 0.12 74.47 84. 06^ 24.92 CH2C12 Ret. STD CON Height CF Time (PPB) 19.11 &MQO 101089.73 B.53?ae* 19.10 7.5000 258724.17 3.4496*4 19.10 15.0000 510043.34 3.4002*. 19.11 22.5000 760199.56 3.3786e4 19.10 30.0000 854405.44 2.8480*. vOJjViy 19.10 15.8000 496892.44 3i«87e* 0.03 67.53 64.49 ~S»2J U>\ Ret. STD CON Height CF Time (PPB) 21.86 1.0000 22159.17 2.2159e4 21.84 7.5000 208065.25 2.7742e4 OClDFMe Ret. STD CON Height CF Time (PPB) 7.06 1.5000 3087.47 2.0583e3 7.02 7.5000 28988.35 3.8651e3 7.02 15.0000 65191.56 4.3461e3 7.03' 22.5000 95403.59 4.2401e3 7.02 30.0000 161134.89 5.3711e3 7.03 15.3000 70761.17 3 9761 e3 0.29 74.47 86.92 Q__3o74<r^ VCl Ret. STD CON Height CF Time (PPB) 9.10 1.5000 9092.31 6.0615e3 9.09 7.5000 71710.14 9.5613e3 9.07 15.0000 155780.55 1.0385e4 9.09 22.5000 242520.41 1.0778e4 9.07 30.0000 379235.38 1.2641e4 9.09 15.3000 171667.75^88531?"^^ 0.14 74.47 84.81^24. 45 X. - ClEa Ret. STD CON Height CF Time (PPB) 12.49 1.5000 11513.79 7.6758e3 12.49 7.5000 88934.09 1.1857*. 12.47 15.0000 196671.45 1.3111e4 12.49 22.5000 296858.63 1.3193e4 12.47 30.0000 444924.28 1.4830*. 12.48 15.3000 207780 . 45 "^jTiiS^ ^ 0.09 74.47 82.29^_ 22.31 X^ 11DCIE ——— Ret. STD CON Height CF Time (PPB) 17.06 1.0000 23495.80 2.3495e4 17.05 7.5000 175895.22 2.3452e4 17.04 15.0000 355928.03 2.3728e4 17.04 22.5000 586214.06 2.6053*. 17.03 30.0000 821308.63 2.7376e4 17.04 15.2000 392568.34 2.4821e4 0.07 75.97 81.14 7.23 , 0 T-12DCIE Ret. STD CON Height CF Time (PPB) ^ 20.26 1.0000 28530.31 2.8530e4 '- 20.24 7.5000 231189.63 3.0825*. 20.24 15.0000 485207.22 3.2347e4 L 20.24 22.5000 736518.69 3.2734e4 : 20.24 30.0000 842804.25 2.8093*. '- 20.24 15.2000 464850.03 3.0506e4 0.05 75.97 73.11 6.99 ^^K C-12DCIE / 000181 ' «et. STD CON Height CF <- V U U 1 C 1 , Time (PPB) 24.21 1.0000 21939.74 2.1939e4 24.18 7.5000 199678.52 2.6623e4 SclOOIO. C MIX sc 10005. 0 NIX sc 10006. E MIX Averages XfiSO ,le Name SAMPLE NAME Nunber sc 10002. A MIX sc 10009. B MIX sc10010. C MIX sc 10005. D MIX sc 10006. E MIX Averages XRSO File Name SAMPLE NAME Nunber sc 10002. A MIX sc 10009. B MIX SC10010. C MIX sc 10005. 0 MIX sc 10006. E MIX Averages ZRSD Fi te Name SAMPLE NAME Nunber sc 10002. A MIX sc 10009. B MIX sdOOIO. C MIX sc 10005. 0 MIX -10006. E MIX Averages S«SD File Name SAMPLE NAME Nurber sc 10002. A MIX SC10009. B MIX SC10010. C MIX sclOOOS. 0 MIX SC10006. E MIX Averages '/.RSD F i l e Name SAMPLE NAME Nunber sc10002. A MIX sc 10009. B MIX sc10010. C MIX SC10005. D MIX sc10006. E MIX Averages 7.RSD Fi le Name SAMPLE NAME Nunber -SC10002. A MIX sc 10009. B MIX SdOOIO. C MIX sc 10005. D MIX SC10006. E MIX 3/10/93 3/10/93 3/10/93 Date Of Injection 3/10/93 3/10/93 3/10/93 3/10/93 3/10/93 Date Of Injection 3/10/93 3/10/93 3/10/93 3/10/93 3/10/93 Date Of Injection 3/10/93 3/10/93 3/10/93 3/10/93 3/10/93 Date Of Injection 3/10/93 3/10/93 3/10/93 3/10/93 3/10/93 Date Of Injection 3/10/93 3/10/93 3/10/93 3/10/93 3/10/93 Date Of Injection 3/10/93 3/10/93 3/10/93 3/10/93 3/10/93 21.84 15.0000 432635.22 2.8842*4 21.84 22.5000 677329.94 3.0103*4 21.83 30.0000868859.312.8961*4 21.64 15.2000441808.972.7561*4 0.06 75.97 77.48 11.37 CHC13 Ret. STD CON Height CF Time (PPB) 24.86 1.0000 32642.86 3.2642e4 24.83 7.5000 282593.56 3.7679e4 24.84 15.0000 581353.63 3.8756*4 24.85 22.5000 831054.56 3.6935e4 24.84 30.0000 927063.13 3.0902*4 24.84 15.2000 530941.56 3.5383*4 0.04 75.97 70.44 9.65 111TClEa Ret. STD CON Height CF Time (PPB) 26.65 1.0000 29185.45 2.9185*4 26.62 7.5000 220623.47 2.9416*4 26.63 15.0000 442669.88 2.9511*4 26.63 22.5000 664379.56 2.9527e4 26.61 30.0000 909753.56 3.0325*4 26.63 15.2000 453322.38 2.9593*4 0.06 75.97 76.97 1.46 12DCIE* Ret. STD CON Height CF Tim* (PPB) 28.41 1.0000 19989.11 1.9989*4 28.38 7.5000 177472.16 2.3662*4 28.39 15.0000 364573.44 2.4304*4 28.39 22.5000 553234.00 2.4588e4 28.37 30.0000 786230.50 2.6207*4 28.39 15.2000 380299.84 2.3750*4 0.05 75.97 79.53 9.69 120CIPS Ret. STD CON Height CF Time (PPB) 31.88 1.0000 17995.00 1.7995e4 31.85 7.5000 176401.23 2.3520*4 31.87 15.0000356032.222.3735*4 31.87 22.5000 547291.56 2.4324*4 31.85 30.0000 786011.19 2.6200e4 31.86 15.2000 376746.25 2.31S5e4 0.04 75.97 80.27 13.27 2ClEthytVO Ret. STD CON Height CF Time (PPB) 34.19 1.0000 1348.24 1.3482e3 34.11 5.0000 15246.46 3.0492e3 34.12 10.0000 40786.82 4.0786e3 34.11 15.0000 59349.77 3.9566e3 34.09 20.0000 95309.36 4.7654e3 ..........-.------------ .-.^_~.- ....... 34.12 10.2000 42408.13 3<W9oV3 0.11 74.47 —— __87.53 1 38.35X x—^-\ ^Cll^ ( T-13DCIP*\ Ret. STD CON\H*ight >/CF Time (PPB) ———— ""^ 37.52 1.0000 3645.34 3.6453e3 37.47 7.5000 115713.91 1.5428*4 37.49 15.0000 251537.23 1.6769e4 37.49 22.5000 390888.28 1.7372e4 37.47 30.0000 570986.06 1.9032e4 24.19 15.0000 419508.97 2.7967*4 24.19 22.5000 657874.81 2.9238e4 24.17 30.0000 844058.13 2.8135e4 24.19 15.2000 428612.03 2.6780*4 0.06 75.97 77.65 10.68 BrClMe Ret. STD CON Height CF Time (PPB) 25.52 100.0000 420198.66 4.2019e3 25.49 100.0000 475520. 26-fc=BS$«3 25.51 100.0000 503319. 9aCL.0331er\ 25.51 100.0000 485520.03 4.8452er 25.48 100.0000 547283.81 5.4728e3 25.50 100.0000 486368.53 #78&6«3V 0.05 0.00 9.48 9.48 CC14 Ret. STD CON Height CF Time (PPB) 27.79 1.0000 31613.373.1613*4 27.76 7.5000 261334.22 3.4844*4 27.77 15.0000 530665.50 3.5377e4 27.77 22.5000 805049.69 3.5779e4 27.77 30.0000 950729.88 3.1690e4 27.77 15.2000 515878.53 3.3861e4 0.04 75.97 73.32 6.04 TCIE Ret. STD CON Height CF Time (PPB) 31.14 1.0000 25978.54 2.5978e4 31.11 7.5000 253475.56 3.3796e4 31.13 15.0000 510178.63 3.4011e4 31.13 22.5000 776961.63 3.4531e4 31.12 30.0000 892566.69 2.9752e4 31.13 15.2000 491832.22 3.1614e4 0.03 75.97 73.03 11.65 BrOClMe Ret. STD CON Height CF Time (PPB) 32.83 1.0000 15768.00 1.5767e4 32.80 7.5000 168720.89 2.2496e4 32.82 15.0000 361673.19 2.4111e4 32.82 22.5000 538511.06 2.3933e4 32.80 30.0000 779189.25 2.5972e4 32.82 15.2000 372772.47 2.2456*4 0.04 75.97 80.69 17.54 C-1SDClPe Ret. STD CON Height CF Time (PPB) 35.13 1.0000 26962.42 2.6962*4 35.11 7.5000 172998.06 2.3066e4 35.12 15.0000 369824.69 2.4654e4 35.12 22.5000 560590.88 2.4915e4 35.10 30.0000 792303.88 2.6410e4 35.12 15.2000 384535.97 2.5201e4 0.03 75.97 79.10 6.12 112TClEa Ret. STD CON Height CF Time (PPB) 38.31 1.0000 14364.21 1 .4364e4 38.28 7.5000 153723.75 2.0496e4 38.30 15.0000 319574.31 2.1304e4 38.30 22.5000 491486.84 2.1B43e4 38.28 30.0000 685554.81 2.2851e4 0378 ifi •H CD r- L 0001815 Averages XRSD File Name SAMPLE NAME Minber 266554.16 1 75.97 83.94 J7.49 0.06 Date Of Ret. STD CON Height CF Injection Tine (PPB) 38.29 15.2000 332940.78 2.0172e4 0.04 75.97 79.93 16.65 DBrClMe Ret. STD CON Height CF Time (PPB) sc 10002. ic 10009. sclOOIO. sc 10005. sc 10006. Averages XRSD A B C 0 E MIX MIX MIX MIX MIX 3/10/93 3/10/93 3/10/93 3/10/93 3/10/93 40.16 40.12 40.15 40.15 40.15 40.15 0.04 1.0000 26053.02 2.60S3e4 7.5000 233064.84 3.1075e4 15.0000 22.5000 30.0000 15.2000 75.97 482463.19 756137.38 921831.38 483909.97 75.82 3.2164e4 3.3606e4 3.0727e4 3.072Se4 9.25 41.29 1.0000 7282.99 7. 41.25 7.5000 85531.35 1. 41.27 41.28 41.25 41.27 0.04 15.0000 22.5000 30.0000 15.2000 75.97 185668.83 284382.38 423579.47 197289.00 .2829e3 , 1404e4 1.2377e4 1 . 2639e4 1.4119e4 "-^x------- 83.10( 22.34^ ClBz F i l e Name SAMPLE NAME Date Of Ret. STD CON Height Nutter Injection Time (PPB) CF o-Cl , F-8enzene ^^ —— ^ Ret. STD CON Height CF Time (PPB) sc10002. sc10009. sclOOIO. sc10005. sc10006. A MIX B MIX C MIX D MIX E MIX 3/10/93 45.79 1.0000 6996.22 6.9962e3 3/10/93 45.74 7.5000 67958.99 9.0611e3 3/10/93 45.76 15.0000 144141.81 9.6094e3 3/10/93 45.77 22.5000 218491.72 9.7107e3 3/10/93 45.73 30.0000 334543.22 1.1151e4 47.77 100.0000 205752.50 2.0575e3 47.74 100.0000 238984.73 2- 47.76 100.0000 243010.7TQiJ01e 47.77 100.0000 234100.64 27341^53 47.73 100.0000 267903.63 2.6790e3 Averages %RSD 45.76 15.2000 154426.39 9.3058*3 0.05 75.97 83.10 16.17 47.75 100.0000 237950.45 &&&& 0.04 0.00 9.34 9.34 F i l e Name sc10002. sc 10009. sclOOIO. sclOOOS. sc 10006. Averages XRSD A B C D E SAMPLE NAME Number MIX MIX MIX MIX MIX Date Of Injection 3/10/93 3/10/93 3/10/93 3/10/93 3/10/93 Ret. STD CON Time (PPB) 53.60 53.53 53.53 53.53 53.51 53.54 0.07 1.0000 7.5000 15.0000 22.5000 30.0000 CHBr3 Height 2436.02 38313.16 91502.36 152685.14 212757.58 CF 2.4360e3 5.1084e3 6.1001e3 6.7860e3 7.0919e3 15.2000 99538.85 (S^K^eS. 75.97 85.37\ 34.10\ Ret. Time 55. 54. 55 55 54 55 1122TetCtEa STD CON Height (PPB) 05 99 .00 .00 .98 .00 0.05 1.0000 9536.18 9 7.5000 100020.92 1 15.0000 210529.58 22.5000 314176.91 30.0000 434918.50 15.2000 213836.42 75.97 78.83 CF .5361e3 .3336e4 1.4035e4 1.3963e4 1.4497e4 1.3073e4 15.45 F i l e Name SAMPLE NAME Date Of Ret. STD CON Height Number Injection Time (PPB) SC10002. sc 10009. sclOOIO. sc 10005. sc 10006. Averages XRSD A B C D E MIX MIX MIX MIX MIX 3/10/93 3/10/93 3/10/93 3/10/93 3/10/93 57.75 56.02 56.03 56.03 56.02 56.37 1.37 1.0000 7.5000 15.0000 22.5000 30.0000 15.2000 75.97 6132.71 6. 69155.37 9. 147744.20 9 218201.98 9 311531.03 1 150553.06 9 79.97 ne\ —— S CF 1327e3 2207e3 .8496e3 .6978e3 .0384e4 .0570e3 18.62 13DQBZ Ret. STD CON Height CF Time (PPB) 62.42 62.38 62.38 62.40 62.38 62.39 0.03 1.0000 11948.33 1. 7.5000 129612.23 1. 15.0000 278241.03 22.5000 406665.09 30.0000 637054.06 15.2000 75.97 292704.16 83.20 1948e4 728 1e4 1.8549e4 1.8074e4 2.1235e4 1.7417e4 19.52 14DCIBZ F i l e Name SAMPLE NAME Date Of Ret. STD CON Height Nutter Injection Time (PPB) CF 120CIBZ Ret. STD CON Height CF Time (PPB) SC10002. sc10009. sclOOIO. sc10005. sc10006. A MIX B MIX C MIX D MIX E MIX 3/10/93 63.03 1.0000 14050.87 1.4050e4 3/10/93 62.99 7.5000 145219.77 1.9362e4 3/10/93 62.99 15.0000 309535.06 2.0635e4 3/10/93 63.01 22.5000 447390.56 1.9884e4 3/10/93 62.99 30.0000 679890.75 2.2663e4 64.94 1.0000 15111.93 1.5111e4 64.91 7.5000 133073.33 1.7743e4 64.92 15.0000 282515.47 1.8834e4 64.94 22.5000 411280.72 1.8279e4 64.92 30.0000 603674.00 2.0122e4 Averages %RSO 63.00 15.2000 319217.41 1.9319e4 0.03 75.97 81.39 16.57 64.93 15.2000 289131.09 1.8018e4 0.02 75.97 79.88 10.27 L 000181:") TUT 004 1816 tc 10005. 0 MIX tc 10006. E NIX Averages USD i t e Name SAMPLE MANE Number tc 10002. A MIX tc10009. B MIX tclOOIO. C MIX tc10005. D MIX tc 10006. E MIX Averages ttSO File Name SAMPLE NAME Number tc10002. A MIX tc 10009. B MIX tc10010. C MIX tc10005. D MIX tc 10006. E MIX Averages SRSD File Name SAMPLE NAME Number tc 10002. A MIX tc10009. B MIX tdOOIO. C MIX tc 10005. 0 MIX tc10006. E MIX averages XRSD File Name SAMPLE NAME Number tc 10002. A MIX tc 10009. B MIX tdOOIO. C MIX tclOOOS. D MIX tc10006. E MIX Averages XRSD F i l e Name SAMPLE NAME Number tc10002. A MIX tc10009. B MIX tclOOIO. C MIX tdOOOS. D MIX tc10006. E MIX Averages KRSD 3/10/93 3/10/93 Date Of Injection 3/10/93 3/10/93 3/10/93 3/10/93 3/10/93 Date Of Injection 3/10/93 3/10/93 3/10/93 3/10/93 3/10/93 Date Of Injection 3/10/93 3/10/93 3/10/93 3/10/93 3/10/93 Date Of Injection 3/10/93 3/10/93 3/10/93 3/10/93 3/10/93 Date Of Injection 3/10/93 3/10/93 3/10/93 3/10/93 3/10/93 36.59 22.5000 237645.61 1.0562*4 36.58 30.0000 368032.91 1.2267*4 36.58 15.2000 167799.14 1.0468*4 0.03 75.97 83.85 10.12 TetClE R*t. STD CON Height CF Tim* (PPB) 40.08 1.0000 3370.82 3.3708e3 40.05 7.5000 25825.96 3.4434e3 40.08 15.0000 59294.62 3.9S29e3 40.08 22.5000 93199.95 4.1422*3 40.06 30.0000 144395.91 4.8131*3 40.07 15.2000 65217.45 3.9445*3 0.03 75.97 85.59 14.86 EthylBz Ret. STD CON Height CF Time (PPB) 46.25 1.0000 5566.69 5.5666*3 46.22 7.5000 41631.675.5508*3 46.24 15.0000 91326.90 6.0884*3 46.25 22.5000 143399.38 6.3733*3 46.22 30.0000 219956.98 7.3318*3 46.24 15.2000 100376.33 6.1822*3 0.03 75.97 64.35 11.84 o-Ct,F-B*nzen* Ret. STD CON Height CF Time (PPB) 47.69 100.0000 114605.26 1.1460*3 47.65 100.0000 128852.53 1 Jflfiiei 47.68 100.0000 130910. 2£t.3091ej> 47.69 100.0000 124051.13T^4TJ5e3 47.66 100.0000 140537.03 1 .4053e3 47.67 100.0000 127791.24 1.2779e3 0.04 0.00 7.44 7.44 13DCIBZ Ret. STD CON Height CF Tint* (PPB) 62.33 1.0000 8313.67 8. 3136e3 62.31 7.5000 73708.74 9.827Be3 62.32 15.0000 155730.00 1.0382e4 62.34 22.5000 229426.23 1.0196e4 62 .32 30 . 0000 373780 . 59 1 . 24S9e4 62.32 15.2000 168191.84 1.0235e4 0.02 75.97 84.43 14.51 12DCIBZ Ret. STD CON Height CF Time (PPB) 64.86 1.0000 8132.34 8.1323e3 64.85 7.5000 60212.65 8.0283e3 64.85 15.0000 130160.87 8.6773e3 64.87 22.5000 189547.84 8.4243e3 64.86 30.0000 300725.13 1.0024*4 64.86 15.2000 137755.77 8.6573e3 0.02 75.97 82.86 9.30 37.43 22.5000 53752.12 2.3889*3 37.41 30.0000 84508.34 2.8169e3 37.41 15.2000 37738. 76-^»««3 0.03 75.97 86.8(X34.17^ ^__^ CIBZ Ret. STD CON Height CF Time (PPB) 45.68 1.0000 6656.84 6.6568e3 45.66 7.5000 52726.80 7.0302*3 45.68 15.0000 110428.04 7.3618e3 45.69 22.5000 165874.27 7.3721*3 45.66 30.0000 261096.59 8.7032*3 45.67 15.2000 119356.51 7.4248e3 0.03 75.97 83.23 10.40 m-Xylene Ret. STD CON Height CF Time (PPB) 46.92 1.0000 5937.43 5.9374*3 46.89 7.5000 41773.02 5.5697*3 46.91 15.0000 94832.10 6.3221*3 46.93 22.5000 143462.70 6.3761e3 46.89 30.0000 226905.36 7.5635e3 46.91 15.2000 102582.13 6.3537e3 0.04 75.97 84.74 11.81 o-Xylen* Ret. STD CON Height CF Time (PPB) 50.80 1.0000 4983.35 4.9833*3 50.76 7.5000 36094.68 4.8126e3 50.78 15.0000 81220.63 5.4147e3 50.79 22.5000 120726.61 5.3656e3 50.76 30.0000 188641.86 6.2880e3 50.78 15.2000 86333.43 5.3728*3 0.03 75.97 83.56 10.63 14DCIBZ Ret. STD CON Height CF Time (PPB) 62.94 1.0000 8124.11 8.1241e3 62.92 7.5000 73706.47 9.8275e3 62.93 15.0000 156476.55 1.0431e4 62.95 22.5000 231874.56 1.0305*4 62.93 30.0000 377080.75 1.2569e4 62.94 15.2000 169452.48 1.0251e4 0.02 75.97 84.68 15.51 U381 TUT 004 1817 Software Version: 3.2 <16C20> Sample Name Sample Number Operator Instrument AutoSampler Rack/Vial 1 PPB 8010/8020 STD Time A MIX Study V3400A/SALLY Channel NONE 0/0 3/11/93 8:52 AM LINEARITY A/D mV Range : 1000 Interface Serial Delay Time End Time Sampling Rate Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount Noise Threshold Multiplier # : 0159572256 0.00 min. 70.00 min. 2.0000 pts/sec Data Acquisition Time: 3/10/93 10:57 AM N:\V3400S\SC10002.raw n:\v3400s\SC10002.rst N:\V3400S\8000SUE.ins N:\V3400S\HALL.prc N:\V3400S\LINHSC10.smp n:\v3400s\scl0.seq 5 mL 1.0000 Area Reject : 100.00 Dilution Factor : 1.00 15 1.0000 Area Threshold : 73 Bunch Factor: 2 Divisor : 1.0000 Adder : 0.0000 Instrument Conditions: Total Number of Peaks Detected: 37 ITAS-KNOXVILLE V-3400B J+W DB-624 75m*0.53mm ID, 3.00um df ELECTROLYTIC CONDUCTIVITY DETECTOR-BrClMe AND O-ClFBz ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. AL OTHER ANALYTES ARE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLUME OF 5.O ML. Peak * 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 Ret Time tmin] 5.761 7.064 8.353 9.102 11.923 12.493 14.037 16.510 17.058 19.113 20.260 21.864 24.210 24.859 25.518 26.654 27.792 28.410 29.409 31.139 31.879 32.831 RT DIFF. X 0.0 0.4 0.1 0.1 -0.2 -0.0 0.1 0.0 0.1 0.1 0.1 0.2 0.2 0.2 0.1 0.2 0.1 0.1 0.0 0.1 0.1 0.1 BL BV W W W W W VB BV W W W W W W W w w w w w w w Cotnponcnt Name DClDFMe CLME VCl BrMe CLEa TClFMe 11DCIE CH2C12 T-12DCIE IIDClEa C-120CIE CHC13 BrClMe IIITClEa ecu 12DCIE1 TCIE 120CIPB BrOClMe Area/ Amount 39584.8633 51987.1680 1.04A3e5 1.4745e5 21620.4375 1.5243e5 1.9025t5 4.5559e5 3.5646*5 2.8675e5 3.8316*5 3.3275e5 2.7819e5 4.3870e5 53451.4063 6.5949e5 5.3735e5 3.5887e5 5.6972e5 3.636U5 2.9U9e5 2.8274e5 Area CuV"sec] 21490.75 77980.75 156657.11 221183.44 32430.66 228648.50 285387.19 124269.31 356467.69 1147032.00 383165.22 332755.56 278198.25 438707.97 5345140.50 659492.38 537358.69 358871.50 154771.53 363614.19 294497.56 282741 .44 Height [uV] 1117.47 3087.47 8156.97 9092.31 1505.09 11513.79 14478.36 6408 . 74 23495 . 80 101089.73 28530.31 22159.17 21939.74 32642.86 420198.66 29185. fcS 31613.37 19989.11 5430.29 25978.54 17995.00 15768.00 INST. Anit (ISX) 0.54 1.50 1.50 1.50 1.50 1.50 1.50 0.27 1.00 4.00 1.00 1.00 1.00 1.00 100.00 1 .00 1.00 1.00 0.27 1.00 1.00 1.00 Cal. Component Range Name DClDFMe CLME VCl BrMe ClEa TClFMe 11DCIE CH2C12 T-120CIE IIDClEa C-120CIE CHC13 BrClMe IIITClEa ecu 12DCIE8 TCIE 12DCIP8 BrOClMe SAMPLE (PPB) 0. 1. 1. 1. 1. 1. 1. 0. 1. 4. 1. 1. 1. 1. 100. 1. 1. 1. 0. 1. 1. 1. CON 54 50 50 50 50 50 50 27 00 00 00 00 00 00 00 S L 00018 00 27 00 00 00 H 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 34.186 35.127 37.518 38.314 40.160 41.294 45.790 47.317 47.772 53.601 55.045 57.752 62.419 63.025 64.942 0.3 W 0.1 W 0.1 W 0.1 W 0.1 W 0.1 W 0.1 W 0.0 W 0.0 W 0.1 W 0.1 W 3.1 VB 0.1 BV 0.1 VB 0.0 BB ZClEthytVO C-130CIP* T-130CIP* 112TCIE* TttClE DBrCIN* ClBz o-Cl,F-Ben CHBr3 1122TetClE 123TriCtPr 13DCIBZ UOClBz 120CIBZ 43117.5938 4.1232.5 65164.7031 2.4481*5 4.0935*5 1.6415*5 1.3609*5 27098.9199 34966.6289 53742.9063 1.8338*5 1.2239*5 1.5387*5 2.0428*5 1.9275*5 43117.59 412326.63 65164.70 244810.50 409355.22 164155.50 136099.19 3413.88 3496662.75 53742.91 183385.06 122394.63 153870.13 204288.13 192753.50 1348.24 26962.42 3645.34 14364.21 26053.02 7282.99 6996.22 256.75 205752.50 2436.02 9536.18 6132.71 11948.33 14050.87 15111.93 1.00 1.00 1.00 1.00 1.00 1.00 1.00 0.13 100.00 1.00 1.00 1.00 1.00 1.00 1.00 2ClEthylVO C-130CIP* T-130CIP* 112TCIEI TetClE DBrClNe ClBz o-Ct,F-Ben CHBr3 1122TetClE 123TriClPr 130CIBZ KDClBz 120CIBZ 1 1 1 1 1 1 1 0 100 1 1 1 1 1 1 .00 .00 .00 .00 .00 .00 .00 .13 .00 .00 .00 .00 .00 .00 .00 0383 6.2 Missing Component Report Component Air 8.8067*6 17966404.00 1.20*6 238.21 Expected Retention (Sample File) 1.845 238.21 Y. NOT DETECTED ON PRIMARY RUN: Z. NOT DETECTED ON PID L 0 0 0 1 8 2 TUT 004 1819 VJ400A HAJUL SaflBle MMM : 1 PWI 8010/8020 STO FiltNMM : N:\V3400S\SC10002.raw Method : SOOOSUe.ins Start Tin* : 0.00 Bin End Time : 70.00 min Scale Factor: 0 Plot Offset: 4 mV Sa*pl« *: A MIX Date : 3/11/93 8:52 AM Time of Injection: 3/10/93 10:57 AM Low Point : 4.00 mV Nigh Point : 39.00 mV Plot Scale: 35 MV 0384 Respons NJo -14.04 -17.06 ,11DCLEA 0) 111TCLEA - - ^__ — _ —————— _ ———— _ ———————————————————————————— / 51 OX -^- ———————————————————————— ^ ——— — —————————————— 24 . 2 1 20.26 ————————————— - ———————————————— 26 6-i 19. " ^ —'ISLE r _i12DCLPA -l _J BRDCLME —i2CLETHYLVO- ——^34.19 _ ——IC-130CLPE - ID ~T-130CLPE - _ —:112TCLEA - '" ^——^TETCLE -J —DBRCLME CLBZ _IO-CL,F-BE | CHBR3 1122TETCL - 123TRICLP - O' H H — 27.79 L 0 0 0 1 8 2 . TUT OO4 1820 Software Version: 3.2 <16C20> Sample Name Sample Number Operator nstrument -Auto Sampler Rack/Vial 1 PPB 8010/8020 STD A MIX V3400A/SALLY NONE 0/0 Time Study Channel : B : 3/11/93 8:53 AM : LINEARITY A/D mV Range : 1000 Interface Serial # : 0159572256 Data Acquisition Time: 3/10/93 10:57 AM Delay Time End Time Sampling Rate Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount Noise Threshold Multiplier 0.00 mm. 70.00 min. 2.0000 pts/sec N:\V3400S\TC10002.raw n:\v3400s\TC10002.rst N:\V3400S\8000SUE.ins N:\V3400S\PID.prc N:\V3400S\LINPTC10.smp n:\v3400s\sc10.seq 5 ml 1.0000 Area Reject : 100.00 Dilution Factor : 1.00 15 1.0000 Area Threshold : 73 Bunch Factor: 2 Divisor : 1.0000 Adder : 0.0000 Instrument Conditions: Total Number of Peaks Detected: 60 ITAS-KNOXVILLE V3400A RTX 502.2 105m»0.53mm ID,3.00um df PID DETECTOR-FBZ AND 0-ClFBz ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. ALL OTHER ANALYTES ARE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLL^E OF 5.O ML. Peak # 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 _-17 18 19 20 21 22 Ret Time RT DIFF. [min] X 5.689 6.627 8.668 9.007 9.384 10.186 11.802 13.790 14.263 15.058 15.649 15.918 16.577 16.977 19.050 19.747 20.189 21.471 22.233 23.458 24.132 25.481 0.0 0.0 0.0 -0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 -0.0 0.0 0.0 0.1 0.0 0.0 0.0 0.1 0.0 BL Component Name BV W W W VCl W W W W W VB BV VB BV VB 110CIE BV W W T-12DCIE W VV W VB C-120CIE BV Area/ Amocnt 808.7000 4186.7622 24299.6992 10093.8857 8775.8545 12573.8848 32525.4336 71928.9219 77212.9844 29655.5371 38007.5977 37562.5352 35711.1094 33086.3750 1.2068e5 1.4686e5 71434.5625 1.6945e5 1.1364e5 42221.2305 33465.6094 68750.0625 Area [uV*sec] 9097 1781 11723 15140 46140 20987 6371 5796 2831 113685 25445 13335 3084 33086 6667 6729 71434 4987 3265 5700 33465 8443 .88 .81 .19 .83 .41 .50 .09 .09 .23 .30 .73 .28 .11 .38 .19 .59 .56 .09 .66 .25 .61 .50 Height INST. Amt Cal. Component SAMPLE CON [uV] (1SX) Range Name (PPB) 1937.26 140.87 320.57 996.72 3397.89 1104.80 130.16 301.80 137.33 11956.72 2507.47 1329.65 323.46 3745.34 640.94 531.61 11601.63 341.44 130.01 610.87 4524.67 555.69 11 0 0 1 5 1 0 0 0 3 0 0 0 1 0 0 1 0 0 0 1 0 .25 .43 .48 .50 .26 .67 .20 .08 .04 .83 .67 .36 .09 .00 .06 .05 .00 .03 .03 .14 .00 .12 11 0 0 VCl 1 5 1 0 0 0 3 0 0 0 11DCIE 1 0 0 T-12DUE 1 0 0 0 C-12DCIE 1 0 .25 .43 .48 .50 .26 .67 .20 .08 .04 .83 .67 .36 .09 M L O G O i .05 .00 .03 .03 .14 .00 .12 r-4 CO oo h-D h- 82: 23 25.433 24 29.360 25 31.060 26 34.033 27 34.713 28 35.050 29 35.560 10 35.842 41 36.085 32 36.583 33 37.415 34 39.343 35 40.076 36 44.421 37 45.684 38 46.247 39 46.919 40 47.690 41 50.801 42 52.859 43 53.833 44 56.667 45 57.370 46 57.654 47 59.518 48 60.206 49 60.992 50 62.334 51 62.944 52 64.111 53 64.864 54 65.838 55 66.208 56 66.503 57 67.712 58 68.000 59 68.654 60 68.866 0.1 VB BZ 1.1002*5 0.0 BV FBI 14844.1875 0.0 W TCIE 42094.0625 0.0 W 2ClEthylVO 11665. 1250 0.0 W 48800. 9414 0.0 W C-13DCIP* 22875.5469 0.0 W 31705.0918 0.0 W 87386.1563 0.0 W 1.4005e5 0.0 W Toluene 82075.9531 0.0 W T-130ClPe 9051.2500 0.0 W 70873.0313 0.0 W TetClE 34092.3438 0.0 VB 2.7243*5 0.0 BV ClBz 75250.2031 0.0 W EthylBz 69262.0938 0.0 W m-Xylen* 75892.2188 0.0 W o-Cl,F-B*n 13759.2949 0.0 W o-Xylene 64677.5625 0.0 W 1.1679e5 0.0 W 1.9109e5 0.0 W 1.9006*5 0.0 W 87020.1172 0.0 VB 77548.4766 0.0 BV 1.9310*5 0.0 W 1.1282*5 0.0 VB 89569.2500 0.0 BV 13DCIBZ 59859.3750 0.0 VB 140CIBZ 54676.1250 0.0 BV 1.1579*5 0.0 VB 12DCIBZ 52132.3750 0.0 BV 1.8099*5 0.0 VB 48595.2070 0.0 BV 54726.8359 0.0 W 42510.9883 0.0 VB 45801.9063 0.0 BV 75768.3047 0.0 VB 61049.5820 0.5 4.3096*6 110021.50 12253.49 1484418.75 183585.84 42094.06 5106.00 11665.13 1004.75 1904.16 121.86 22875.55 3123.09 955.63 94.13 11684.21 1299.00 8434.06 585.04 82075.95 9715.21 9051.25 903.37 7386.19 351.30 34092.34 3370.82 7445.75 181.94 75250.20 6656.84 69262.09 5566.69 75892.22 5937.43 1375929.50 114605.26 64677.56 4983.35 9902.28 422.51 10092.75 263.20 1988.75 86.99 4841.50 462.54 64739.63 6940.48 2568.44 110.58 10494.22 773.31 3221.84 299.05 59859.38 8313.67 54676.13 8124.11 50665.13 3558.30 52132.38 8132.34 2607.28 117.15 783.96 131.20 24469.33 3636.11 782.56 149.70 1054.16 187.17 1812.67 194.56 10084.57 1343.35 4311093.00 449958.56 1.00 100.00 1.00 1.00 0.04 1.00 0.03 0.13 0.06 1.00 1.00 0.10 1.00 0.03 1.00 1.00 1.00 100.00 1.00 0.09 0.05 0.01 0.06 0.84 0.01 0.09 0.04 1.00 1.00 0.44 1.00 0.01 0.02 0.45 0.02 0.02 0.02 0.17 245.98 8z FBZ TCIE 2CtEthylVO C-13DCIP* Toluene T-130ClPe TetClE ClBz EthylBz m-Xylene o-Cl,F-Ben o-Xylene 13DCIBZ 140CIBZ 12DCIBZ 1.00 "?:S 0386 1.00 0.04 1.00 0.03 0.13 0.06 1.00 1.00 0.10 1.00 0.03 1.00 1.00 1.00 100.00 1.00 0.09 0.05 0.01 0.06 0.84 0.01 0.09 0.04 1.00 1.00 0.44 1.00 0.01 0.02 0.45 0.02 0.02 0.02 0.17 245.98 ^ilssing Component Report Component Air Expected Retention 5.000 (Sample File) Y. NOT DETECTED ON PRIMARY RUN: Z. NOT DETECTED ON HALL L0001820 TUT O04 V3400A PID Sample NaM : 1 PPS 8010/8020 STD File^aMt : N:\V3400S\TC10002.raw Method : SOOOSUE.ins Start Time : 0.00 "in End Tim : 70.00 rnin Scale Factor: 0 Plot Offset: 4 MV Sanple *: A NIX Date : 3/11/93 8:53 AH Tim of Injection: 3/10/93 10:57 AM Low Point : 4.00 mV High Point : 39.00 mV Plot Scale: 35 mV 0387 Respons V ] O I\J (J1 t _ i —— AIR — i I 1 I ! j i , ! , i i ; | j j i i , 1 i , : --X _»M 5-69 -6.^3 VCL 9.38 TOLUENE IT-130CLPE - 15.06 20.19 28.43 L 000182.: TUT 004 1823 Software Version: sample Name 3.2 <16C20> Sample Number Operator "nstrument .uitoSampler Rack/Vial B MIX V3400A/SALLY NONE 0/0 Time Study Channel : A : 3/11/93 8:54 AM : LINEARITY A/D mV Range : 1000 Interface Serial # : 0159572256 Data Acquisition Time: 3/10/93 7:47 PM Delay Time 0.00 min. End Time 70.00 min. Sampling Rate 2.0000 pts/sec Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount Noise Threshold Multiplier N:\V3400S\SC10009.raw n:\v3400s\SC10009.rst N:\V3400S\8000SUE.ins N:\V3400S\HALL.prc N:\V3400S\LINHSC10.smp n:\v3400s\scl0.seq 5 mL 1.0000 Area Reject : 100.00 Dilution Factor : 1.00 15 1.0000 Area Threshold : 73 Bunch Factor: 2 Divisor : 1.0000 Adder : 0.0000 Instrument Conditions: Total Number of Peaks Detected: 40 ITAS-KNOXVILLE V-3400B J+W DB-624 75m*0.53mm ID, 3.00um df ELECTROLYTIC CONDUCTIVITY DETECTOR-BrClMe AND O-ClFBz ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. ALL OTHER ANALYTES ARE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLUME OF 5.O ML. Peak # 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 , 16 17 18 19 20 21 22 Ret Time RT DIFF. BL Component [min] X Name 5.749 7.017 8.334 9.089 11.951 12.488 14.026 16.326 17.050 19.104 20.243 21.839 24.180 24.832 25.494 26.624 27.762 28.379 29.390 31.114 31.853 32.804 0.0 BB -0.3 BV DClDFMe -0.1 W CLME -0.1 W VCl 0.1 W BrMe -0.0 W ClEa -0.0 W TClFMe 0.0 VB 0.0 BV 11DCIE 0.0 W CH2C12 0.0 W T-12DCIE 0.1 W 11DCIEB 0.0 W C-12DCIE 0.0 W CHC13 0.0 W BrClMe 0.0 W 111TUE8 0.0 W CC14 0.0 VE 12DCIEB 0.0 EV -0.0 W TCIE -0.0 W 12DCIPB -0.0 W BrDClMe Area/ Amount 26529.5879 90686.7656 1.7016e5 2.1079e5 78189.5703 2.2920e5 2.9115e5 6.2428e5 3.0354e5 3.7125e5 3.3586e5 3.5151e5 3.0465e5 4.6205e5 59725.4648 4.7605e5 5.0909e5 3.1121e5 6.7966*5 3.9669e5 3.0542e5 3.0665e5 Area Height INST. Amt Cal. Conponent SAMPLE CON [uV*sec] CuV] (ISX) Range Name (PPB) 17802.00 1381.18 680150.75 28988.35 1276222.50 64754.24 1580973.75 71710.14 586421.75 30582.75 1719029.25 88934.09 2183675.75 116826.66 7736.16 291.16 2276551.00 175895.22 2784394.50 258724.17 2519021.50 231189.63 2636326.00 208065.25 2284895.50 199678.52 3465440.00 282593.56 5972546.50 475520.28 3570401.25 220623.47 3818239.00 261334.22 2334113.50 177472.16 291341.00 8568.19 2975196.50 253475.56 2290694.00 176401.23 2299909.25 168720.89 0.67 7.50 7.50 7.50 7.50 7.50 7.50 0.01 7.50 7.50 7.50 7.50 7.50 7.50 100.00 7.50 7.50 7.50 0.43 7.50 7.50 7.50 DClDFMe CLME VCl BrMe ClEa TClFMe 11DCIE CH2C12 T-120CIE 11DCIEB C-12DCIE CHC13 BrClHe 111TCIEB CC14 12DCIEB TCIE 12DCIPB BrDClMe 0.67 7.50 7.50 7.50 7.50 7.50 7.50 0.01 7.50 7.50 7.50 7.50 7.50 7.50 / f ) Q f) 1 [ 100.00 7.50 7.50 7.50 0.43 7.50 7.50 7.50 IN 03 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 35.105 36.545 37.465 38.276 40.121 41.254 45.737 47.735 50.733 53.530 54.987 56.021 60.201 62.376 62.985 64.912 68.655 -0.0 W C-130CIP* 2.8245*5 0.0 W 1.3705*5 -0.0 W T-130CIP* 1.8881*5 -0.0 W 112TCIE* 2.8280*5 -0.0 W T«tClE 4.3529*5 -0.0 W DBrClNe 2.1188*5 -0.0 W ClBz 1.5353*5 •0.1 VE o-Cl,F-Ben 40028.3789 0.0 EB 1.9679*5 -0.0 BV CHBr3 96390.3672 -0.0 W 1122T*tClE 1.9598*5 -0.0 W 123TriClPr 1.5225*5 0.0 VB 3.1125*5 -0.0 BV 130CIBZ 1.9890*5 -0.0 W 140CIBZ 2.4047*5 -0.0 VB 12DCIBZ 2.0707*5 0.0 SB 2.7785*5 2118415.75 172998.06 80500.63 2141.07 1416133.13 115713.91 2121045.00 153723.75 3264716.50 233064.84 1589133.50 85531.35 1151522.25 67958.99 4002837.75 238984.73 37642.00 465.95 722927.75 38313.16 1469881.00 100020.92 1141944.75 69155.37 32071.00 1231.12 1491766.00 129612.23 1803542.75 145219.77 1553083.25 133073.33 17076.75 928.78 7.50 0.59 7.50 7.50 7.50 7.50 7.50 100.00 0.19 7.50 7.50 7.50 0.10 7.50 7.50 7.50 0.06 C-130CIP* T-130CIP* 112TCIE* TetClE DBrClMe ClBz o-Cl,F-Ben CH8r3 1122T«tClE 123TriClPr 130CIBZ 140CIBZ 12DCIBZ 7M 0389 0.59 7.50 7.50 7.50 7.50 7.50 100.00 0.19 7.50 7.50 7.50 0.10 7.50 7.50 7.50 0.06 -0.4 Missing Component Report Component Air 1.0559*7 71867616.00 5.20*6 432.06 Expected Retention (Sample File) 1.845 432.06 Y. NOT DETECTED ON PRIMARY RUN: Z. NOT DETECTED ON PID LOCO] 820 TUT 004 1825 V3400A HALL Sample Nane : Filename : Method : Start Time : Scale Factor: N:\V3400S\SC10009.raM SOOOSUE.ins 0.00 min End Tim : 70.00 min 0 Plot Offset: 4 mV Saople »: B MIX Date : 3/11/93 8:54 AM Time of Injection: 3/10/93 7:47 Ptt Low Point : 4.00 WV High Point : 39.00 mV Plot Scale: 35 mV 0390 Response [rrV] o NOo _!AIR i— X I ZlocLDFNE - CLME VCL JttR — JTCIFME -7.02 -11.95 z-K.C —(CH2CL2 ——IT-12DCLE Z 11DCLEA 111TCLEA - _ BRDCLME —2CLETHYLVO- ——C-130CLPE - ""T-ISDCLPE - —112TCLEA - —ITETCLE —lOBRCLME -29.39 -34.11 -36.55 _]0-CL,F-BE - ^J —i ~|CHBR3 -I123TRICLP - J12DCLBZ - -\ -^=—60.20 L 0 0 0 1 8 2 7 TUT O04 1826 Software Version: Sample Name 3.2 <16C20> Sample Number Operator Instrument AutoSampler Rack/Vial B MIX V3400A/SALLY NONE 0/0 Time Study Channel : B : 3/11/93 8:55 AM : LINEARITY A/D mV Range : 1000 Interface Serial Delay Time End Time Sampling Rate Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount Noise Threshold Multiplier # : 0159572256 0.00 min. 70.00 min. 2.0000 pts/sec Data Acquisition Time: 3/10/93 7:47 PM N:\V3400S\TC10009.raw n:\v3400s\TC10009.rst N:\V3400S\8000SUE.ins N:\V3400S\PID.prc N:\V3400S\LINPTC10.smp n:\v3400s\scl0.seq 5 ml 1.0000 Area Reject : 100.00 Dilution Factor : 1.00 10 1.0000 Area Threshold : 49 Bunch Factor: 2 Divisor : 1.0000 Adder : 0.0000 Instrument Conditions: Total Number of Peaks Detected: 80 ITAS-KNOXVILLE V3400A RTX 502.2 105m*0.53mm ID,3.00um df PID DETECTOR-FBZ AND O-ClFBz ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. ALL OTHER ANALYTES ARE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLUME OF 5.O ML. Peak ft 1 2 3 4 5 6 7 8 10 11 12 13 14 15 16 17 ' 18 19 20 21 22 23 Ret Time [min] 5.677 6.624 7.090 8.275 8.641 9.0CO 9.388 10.185 11.809 12.484 13.796 15.063 15.654 15.922 16.576 16.979 18.860 19.047 19.754 20.179 21.453 21.833 RT OIFF. X 0.0 0.0 0.0 0.0 0.0 -0.1 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 -0.0 0.0 0.0 0.0 0.0 0.0 0.0 BL Component Name BB BB BB BV W W VCl W VB W VB BB BV W W W VB 11DCIE BV W W W T-12DCIE W W Area/ Amxflt 884.9556 2199.8477 4166.7734 7944.4727 8209.4053 9880.2148 9354.6514 10005.9981 9774.2725 9010.0625 96730.1016 31812.8223 38389.5898 38668.6133 35298.4922 27105.5762 2.2597e5 95477.5000 1.7785e5 71826.2813 1.5763e5 1.6621e5 Area CuV*secJ 9955. 628. 527. 593. 1525. 74101. 31246. 8675. 6197. 1232. 5902. 82948. 17312. 10015. 3838. 203291. 2432. 9731. 4799. 538697. 4319. 3673. 75 50 00 91 83 61 41 23 14 97 00 28 01 73 18 83 41 30 14 13 08 36 Height [uV] 2332. 94. 84. 49. 123. 4956. 2211. 576. 421 90. 228. 8754 1688 970 407 24000. 124. 1182. 313. 95207. 317. 256. 38 57 04 68 50 !J 08 1 1 50 9! 5? 'a =8•: ?5 • 5 38 ,.7 05 35 88 40 INST. Amt Cal. Component (ISX) Range Name 11.25 0.29 0.13 0.08 0.19 7.50 VCl 3.34 0.87 0.63 0.14 0.06 2.61 0.45 0.26 0.11 7.50 IIDCtE 0.01 0.10 0.03 7.50 T-120CIE 0.03 0.02 SAMPLE (PPB) 11. 0. 0. 0. 0. 7. 3. 0. 0. 0. 0. 2. 0. 0. 0. 7. 0. 0. 0. 7. 0. 0. CON 25 29 13 08 19 50 34 87 63 14 06 61 45 26 11 i r. „ A f r 50 L- U I 0 1 <•'• 01 10 03 50 03 02 IN 03 h- &* ££.£UI 25 23.4*2 26 24. 1H 27 24.832 28 25.461 29 26.621 30 27.786 31 28.414 52 29.345 33 30.767 34 31.050 35 31.336 36 31.835 37 32.801 38 33.251 39 34.024 40 34.834 41 35.036 42 35.535 43 36.071 44 36.569 45 37.397 46 38.190 47 39.318 48 40.051 49 41.185 50 44.837 51 45.658 52 46.221 53 46.892 54 47.653 55 50.764 56 52.834 57 53.411 58 53.765 59 54.974 60 56.626 61 57.327 62 57.729 63 59.442 64 60.227 65 61.661 ,6 62.310 ^67 62.923 68 64.093 69 64.521 70 64.850 71 65.434 72 65.824 73 66.185 74 66.491 75 66.932 76 67.849 77 68.650 78 68.882 79 69.121 80 69.488 u.o v» I.O8/J«3 0.0 W 45755.8164 0.0 VB C-12DCIE 33240.9336 0.0 BV 59418.4492 0.0 W 64361.6992 0.0 W 2.7970*5 0.0 W 2.4031*5 -0.0 VB Bz 86242.8438 -0.0 BE FBz 16485.7500 0.0 EV 1.7140e5 -0.0 VE TCIE 44287.8086 0.0 EV 1.0213e5 0.0 W 1.8645e5 0.0 W 21708.4492 0.0 W 16802.9902 -0.0 W 2ClEthylVO 11087.7754 0.0 W 37171.3242 -0.0 W C-13DClPe 15963.2207 0.0 W 37066.5078 0.0 W 1.9292e5 -0.0 W Toluene 75963.7969 -0.0 W T-130ClPe 15788.8799 0.0 W 17458.7773 0.0 W 37262.3086 -0.0 W TetClE 33161.6211 0.0 W 53725.0078 0.0 VB 2.2273e5 -0.0 BV ClBz 75649.9141 -0.1 W EthylBz 65270.9570 -0.1 W m-Xylene 67570.8672 -0.1 W o-Cl,F-Ben 15382.4912 -0.0 W o-Xylene 58448.4648 0.0 W 1.1878*5 0.0 W 63424.0547 0.0 W 1.3286*5 0.0 W 65972.5859 0.0 VB 1.9844*5 0.0 BV 98953.3203 0.0 VB 1.8299*5 0.0 BV 1.3571*5 0.0 VB 79266.2109 0.0 BV 1.7300*5 -0.0 W 130CIBZ 65427.2930 -0.0 VB 14DCIBZ 60673.9727 0.0 BE 1.1257*5 0.0 EB 62401.1523 -0.0 BB 120CIBZ 49540.8008 0.0 BB 84734.3438 0.0 BB 40319.6641 0.0 BB 51030.7930 0.0 BB 44340.4336 0.0 BB 78906.4219 0.0 BB 1.0558*5 0.0 BV 99585.1406 0.0 W 66817.9375 0.0 W 66685.7813 0.0 VB 52027.4063 -0.5 6.0941*6 4786.6J 128.35 4865.73 481.16 249306.96 34520.40 3725.22 283.67 8593.69 604.14 5289.84 231.74 5750.97 293.23 646821.31 78078.69 1648575.00 205257.63 14810.50 441.20 332158.56 43599.41 14645.00 732.15 24535.16 671.88 7935.98 367.31 6470.09 386.88 55438.88 7534.33 3778.11 317.43 119724.16 16686.59 3787.66 319.13 10084.47 507.82 569728.50 73372.82 118416.59 15938.55 5728.97 296.44 11779.75 1065.62 248712.16 25825.96 2307.84 144.80 7588.13 226.79 567374.38 52726.80 489532.19 41631.67 506781.50 41773.02 1538249.13 128852.53 438363.50 36094.68 10072.91 422.58 2482.16 195.03 3880.38 145.54 1550.41 117.11 3887.94 162.88 7249.08 609.04 3318.88 150.78 2024.28 124.01 31420.69 3295.49 4758.50 228.66 490704.69 73708.74 455054.81 73706.47 50696.51 3662.25 2575.50 335.65 371556.00 60212.65 5707.50 547.78 197.50 39.84 381.00 60.72 83975.02 15294.34 914.25 94.23 829.00 63.85 2548.90 208. IS 3881.99 472.47 4099.34 499.92 1023.77 160.03 10242083.00 1.1Se6 0.03 0.11 7.50 0.06 0.13 0.02 0.02 7.50 100.00 0.09 7.50 0.14 0.13 0.37 0.39 5.00 0.10 7.50 0.10 0.05 7.50 7.50 0.33 0.32 7.50 0.04 0.03 7.50 7.50 7.50 100.00 7.50 0.09 0.04 0.03 0.02 0.02 0.07 0.02 0.02 0.40 0.03 7.50 7.50 0.45 0.04 7.50 0.07 0.01 0.01 1.89 0.01 0.01 0.03 0.06 0.06 0.02 358.92 C-12DCIE Bz FBz TCIE 2ClEthylVO C-130CIP6 Toluene T-13DClPe TetClE ClBz EthylBz m-Xyl*n* o-Cl,F-B*n o-Xylen* 130CIBZ 14DCIBZ 12DCIBZ 0.03 0.11 7.50 0.06 0.13 0.02 0.02 7.50 100.00 0.09 7.50 0.14 0.13 0.37 0.39 5.00 0.10 7.50 0.10 0.05 7.50 7.50 0.33 0.32 7.50 0.04 0.03 7.50 7.50 7.50 100.00 7.50 0.09 0.04 0.03 0.02 0.02 0.07 0.02 0.02 0.40 0.03 7.50 7.50 0.45 0.04 7.50 0.07 0.01 0.01 1.89 0.01 0.01 0.03 0.06 0.06 0.02 358.92 Missing Component Report Component Air Expected Retention 5.000 (Sample File) 0392 Y. NOT DETECTED ON PRIMARY RUN: Z. NOT DETECTED ON HALL 000182J TUT O04 1828 V3400A PID Sample NMK : FtleNMK : N:\V3400S\TC10009.raw Method : SOOOSUE.ins Start Time : 0.00 min End Time : 70.00 min Scale Factor: 0 Plot Offset: 4 mV Sample *: B MIX Date : 3/11/93 8:55 AM Time of Injection: 3/10/93 7:47 PH LOM Point : 4.00 mV High Point : 39.00 mv Plot Scale: 35 mv Response [nn v ] ••-- O en O LI O '- i 1 ' i ! ] ! I I 1 1 ! ' 1 ' : : d —— iAIR > ———— 5.6fl —IVCL !.80 1T-120CLE - -J C-12DCLE - . =^23. U ~IBZ —'FBZ —iTCLE 26.62 27.79 9.00 -15. i.98 -(2CLETHYLVO- JC-130CLPE - 'TOLUEME -I ^TETCLE 38.19 39.32 1.19 'm IE - JO-XYLEME - I 59.44 -34.02 -j-^1.66 i —i W.23 -35.04 -37.40 40.05 b.49 TUT 004 1829 L 0001830 Software Version: 3.2 <16C20> Sample Name Sample Number Operator -Instrument AutoSampler Rack/Vial C MIX V3400A/SALLY NONE 0/0 Time Study Channel : 3/11/93 8:56 AM : LINEARITY A/D mV Range : 1000 Interface Serial Delay Time End Time Sampling Rate Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount Noise Threshold Multiplier # : 0159572256 o.oo min. 70.00 min. 2.0000 pts/sec Data Acquisition Time: 3/10/93 9:03 PM N:\V3400S\SC10010.raw n:\v3400s\SCl0010.rst N:\V3400S\8000SUE.ins N:\V3400S\HALL.prc N:\V3400S\LINHSC10.smp n:\v3400s\scl0.seq 5 mL 1.0000 Area Reject : 100.00 Dilution Factor : 1.00 15 1.0000 Area Threshold : 73 Bunch Factor: 2 Divisor : 1.0000 Adder : 0.0000 Instrument Conditions: Total Number of Peaks Detected: 41 ITAS-KNOXVILLE V-3400B J-l-W DB-624 75m*0.53mm ID, 3.00um df ELECTROLYTIC CONDUCTIVITY DETECTOR-BrClMe AND O-ClFBz ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. ALL OTHER ANALYTES ARE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLUME OF 5.O ML. Peak » 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 * 16 17 18 19 20 21 22 Ret Time R [minj 5.739 7.015 8.324 9.074 11.919 12.473 14.003 16.233 17.038 19.100 20.238 21.838 23.342 24.188 24.840 25.506 26.633 27.774 28.393 29.399 31.131 31.870 T DIFF. X 0.0 -0.3 -0.2 -0.2 -0.2 -0.2 -0.2 0.0 -0.0 0.0 0.0 0.0 0.0 0.1 0.1 0.1 0.1 0.1 0.1 0.0 0.1 0.0 Bl SB BV W W W W VB BB BV W W VE EV W W W W W W W W W Component Name DClDFMe CLME VCl BrMe ClEa TClFMe 110CIE CH2C12 T-120CIE IIOClEa C-12DCIE CHC13 BrClHe 111TCIE8 ecu 12DCIEB TCIE 120ClPa Area/ Amount 31583.1934 1.0211e5 1.8579e5 2.1823*5 1.0036e5 2.4628e5 3.1 562 e5 3.8694e5 3.0514*5 3.6077e5 3.4231e5 3.4944e5 8.5620e5 3.1675*5 4.7526*5 63167.7109 4.6112*5 5.0630*5 3.0147*5 7. 1828*5 3.9339*5 2.9914*5 Area [uV»s*c] 20158.50 1531688.38 2786940.00 3273454.75 1505482.50 3694337.75 4734355.00 3699.00 4577157.50 5411564.00 5134712.50 5241743.00 53653.00 4751375.00 7129046.50 6316771.00 6916942.00 7594554.00 4522108.50 399060.25 5900875.00 4487245.50 Height 1 CuV] 1313.76 65191.56 141951.77 155780.55 80779.73 196671.45 260066. -5 224.61 355928.03 510043.3- 485207.22 432635.22 1374.83 419508.97 581353.63 503319.94 442669.38 530665.50 364573.44 11105.49 510178.63 356032.22 NST. Amt Ca USX) Ra 0.64 15.00 15.00 15.00 15.00 15.00 15.00 0.01 15.00 15.00 15.00 15.00 0.06 15.00 15.00 100.00 15.00 15.00 15.00 0.56 15.00 15.00 I . Component nge Name OClOFMe CLME vet BrMe ClEa TClFMe 11DCIE CH2C12 T-12DCIE IIDClEa C-120CIE CHC13 BrClM* nnciEa ecu 12DClEa TCIE 12DClPa SAMPLE CON (PPB) 0.64 15.00 15.00 15.00 15.00 15.00 15.00 0.01 15.00 15.00 15.00 15.00 0.06 15.00 15.00 100.00 15.00 15.00 15.00 0.56 15.00 15.00 O KI 00 •H <? O O h-Zi H- C O O O l S S x ^ 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 J2.822 34^116 35.123 36.549 37.487 38.300 40.147 41.272 45.755 47.755 50.768 53.534 54.996 56.030 60.187 62.384 62.992 64.918 68.660 u.U W grOClM* J. 0809*5 0.0 W 2ClEthylVO 62457.4141 0.1 VE C-130CIP* 2.8819*5 0.0 EV 1.4806*5 0.0 W T-130CIP* 1.9715*5 0.0 W 112TCIE* 2.8189*5 0.0 W TetClE 4.3817*5 0.0 W OBrClH* 2.1217*5 -0.0 W ClBz 1.5650*5 -0.0 VE o-Cl,F-8*n 40919.6250 0.0 EB 1.6925*5 -0.0 BV CHBr3 1.0269*5 -0.0 W 1122TetClE 1.9661*5 0.0 W 123TriClPr 1.4976*5 0.0 VB 3.1032*5 0.0 BV 130CIBZ 2.0728*5 0.0 W KOClBz 2.4485*5 -0.0 VB 120CIBZ 2.1674*5 0.0 BB 3.3200*5 4621476.50 361673.19 624574.13 40786.82 4322954.50 369824.69 149608.00 3825.25 2957330.50 251537.23 4228413.00 319574.31 6572678.00 482463.19 3182569.00 185668.83 2347582.00 144141.81 4091962.50 243010.77 64477.50 927.99 1540370.63 91502.36 2949158.50 210529.58 2246466.00 147744.20 84405.19 3249.84 3109311.00 278241.03 3672750.50 309535.06 3251194.50 282515.47 17635.50 802.72 15.00 10.00 15.00 1.01 15.00 15.00 15.00 15.00 15.00 100.00 0.38 15.00 15.00 15.00 0.27 15.00 15.00 15.00 0.05 BrOCIM* 2ClEthylVO C-130CIP* T-130CIP* 112TCIE8 TetClE DBrClMe ClBz o-Cl,F-B*n CHBr3 1122TetClE 123TriClPr 130CIBZ KOClBz 12DCIBZ is.oo n Q Q " 10.00 U «) J D 15.00 1.01 15.00 15.00 15.00 15.00 15.00 100.00 0.38 15.00 15.00 15.00 0.27 15.00 15.00 15.00 0.05 -0.5 Missing Component Report Component Air 1.1398*7 136021856.00 1.01*7 662.98 Expected Retention (Sample File) 1.845 662.98 Y. NOT DETECTED ON PRIMARY RUN: Z. NOT DETECTED ON PID L O O O J 8 TUT OO4 1831 V3400A HALL Sanpl* NMM : FileName Method : Start Time : Scale Factor: N:\V3400S\SC10010.raM aOOOSUE.ins 0.00 Min End Timt : 70.00 min 0 Plot Offset: 4 mV Sample *: C MIX Date : 3/11/93 8:56 AM Tii«e of Injection: 3/10/93 9:03 PH Low Point : 4.00 mv High Point : 39.00 mv Plot Scale: 35 mV 0396 s o o n s [rr-.V] o I I 111TCLEA —IDCLDFNE — CLUE — VCL IJECHI — iTCLFME —^IIDCLE •x-, —ICH2CL2 r-,——JT-12DCLE _i!11DCLEA -'TCLE J12DCLPA ,BRDCLME •i2CLETHYLVO- 1C-13DCLPE - 4 U-IJOCLPE - 'TETCLE I DBRCLME -36.55 _JCLBZ ZjO-CL.F-BE - ~~l CHBR3 ——J1122TETCI - —I123TRICLP - _ O I - ——112DCLBZ L O O O J 8 3 3 TUT OO4 Software Version: Sample Name 3.2 <16C20> Sample Number Operator instrument AutoSampler Rack/Vial C MIX V3400A/SALLY NONE 0/0 Time Study Channel : B : 3/11/93 8:57 AM : LINEARITY A/D mV Range : 1000 Interface Serial # : 0159572256 Data Acquisition Time: 3/10/93 9:03 PM Delay Time 0.00 min. End Time 70.00 min. Sampling Rate 2.0000 pts/sec Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount Noise Threshold Multiplier N:\V3400S\TC10010.raw n:\v3400s\TC10010.rst N:\V3400S\8000SUE.ins N:\V3400S\PID.prc N:\V3400S\LINPTC10.smp n:\v3400s\sc10.seq 5 ml 1.0000 Area Reject : 100.00 Dilution Factor : 1.00 10 1.0000 Area Threshold : 49 Bunch Factor: 2 Divisor : 1.0000 Adder : 0.0000 Instrument Conditions: Total Number of Peaks Detected: 85 ITAS-KNOXVILLE V3400A RTX 502.2 105m*0.53mm ID,3.00um df PID DETECTOR-FBZ AND 0-ClFBz ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. ALL OTHER ANALYTES ARE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLIYE OF 5.0 ML. Peak # 1 2 3 4 5 6 7 8 9 10 11 12 13 H 15 16 ' 17 18 19 20 21 22 Ret Time RT DIFF. [min] X 5.667 6.619 7.071 7.716 8.306 8.996 9.343 10.149 11.790 12.442 13.792 13.998 15.050 15.646 15.908 16.569 16.974 19.044 19.756 20.179 21.039 21.454 0.0 0.0 0.0 0.0 0.0 -0.2 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 -0.1 0.0 0.0 0.0 0.0 0.0 BL Component Name BB BB BB BB BV W VCl w VB BV VB BV VB BB BV W W VB 11DCIE BV W W T-12DCIE W W Area/ Aimxnt 738.0889 2307.1956 5256.8530 5466.0981 9118.5400 10660.7451 10169.4551 10563.0313 10373.8916 10348.5801 39403.8672 75346.0234 32004.9082 39063.4531 38667.5508 36064.3008 28307.0234 1.0028e5 1.6664e5 74498.5703 1.0458e5 1.4518e5 Area [uV*sec] 8303.50 555.00 1055.00 1090.50 1620.23 159911.17 33450.83 9067.14 13790.98 3297.50 2450.22 5414.28 79756.50 17207.80 9796.84 4709.05 424605.34 18415.47 4635.28 1117478.50 971.36 3874.14 Height 1NST. Amt Cal. Component SAMPLE CON [uV] USX) Range Name (PPB) 2003 79 133 132 118 10584 2177 570 883 211 232 269 8394 1649 948 489 51105 2130 322 192704 107 309 .32 .62 .36 .57 .07 .16 .52 .38 .36 .n .89 . 14 .63 .85 .92 .0<. .85 .38 .71 .78 .76 .59 11 0 0 0 0 15 3 0 1 0 0 0 2 0 0 0 15 0 0 15 0 0 .25 .24 .20 .20 .18 .00 .29 .86 .33 .32 .06 .07 .49 .44 .25 .13 .00 .18 .03 .00 .01 .03 11 0 0 0 0 VCl 15 3 0 1 0 0 0 2 0 0 0 110CIE 15 0 0 T-120CIE 15 0 0 .25 .24 .20 .20 .18 .00 .29 .86 .33 .32 .06 .07 .49 44^5100018 .13 .00 .18 .03 .00 .01 .03 K]n CD \-D h- 23 21.826 24 22.479 25 23.448 26 24.122 27 24.839 28 25.476 29 26.638 \0 27.780 ,1 28.430 '32 29.361 33 30.583 34 31.064 35 31.858 36 32.822 37 33.276 38 34.045 39 34.859 40 35.060 41 35.563 42 36.093 43 36.590 44 36.977 45 37.423 46 37.734 47 38.210 48 39.344 49 40.081 50 41.222 51 44.868 52 45.677 53 46.242 54 46.910 55 47.677 56 50.780 57 52.844 58 53.451 59 53.783 60 54.988 61 56.025 62 56.642 63 57.336 S4 57.747 j5 60.236 X66 61.807 67 62.317 68 62.929 69 63.720 70 64.106 71 64.372 72 64.528 73 64.854 74 65.442 75 66.208 76 66.499 77 66.926 78 67.842 79 68.232 80 68.333 81 68.577 82 68.890 83 69.129 84 69.343 85 69.494 0.0 W 0.0 W 0.0 W 0.1 VB C-12DCIE 0.0 BV 0.0 W 0.0 W 0.0 W 0.1 W Bz 0.1 VE FBz 0.0 EV 0.0 VE TCtE 0.0 EV 0.0 W 0.0 W 0.0 W 2ClEthylVO 0.0 W 0.0 W C-13DClPe 0.0 W 0.0 W 0.0 VE Toluene 0.0 EV 0.0 VE T-13DClPe 0.0 EV 0.0 W 0.0 W 0.0 W TetClE 0.0 W 0.0 VB 0.0 BV ClBz -0.0 W EthylBz -0.0 W m-Xylene -0.0 W o-Cl,F-Ben -0.0 W o-Xylene 0.0 W 0.0 W 0.0 W 0.0 W 0.0 W 0.0 W 0.0 W 0.0 VB 0.0 BB 0.0 BV 0.0 W 13DCIBZ 0.0 VB 140CIBZ 0.0 BV 0.0 VE 0.0 EV 0.0 VB -0.0 BB 12DCIB2 0.0 BB 0.0 BB 0.0 BV 0.0 VB 0.0 BB 0.0 BV 0.0 W 0.0 W 0.0 W 0.0 W 0.0 W 0.0 VB 0.2 1.9095eS 1.2224t5 42232.4570 35820.0391 55759.9688 58597.3906 2.4925e5 2.0027e5 87061.5000 16753.9492 1.3489e5 48708.2148 1.7355«5 18209.1055 13821.7090 12486.4453 29438.7402 16029.9473 35736.9023 1.8150e5 79261.5859 1.2426*5 15999.9678 9910.9541 18447.9258 36613.3672 36064.1523 52718.2422 2.2493e5 79804.4688 70880.0859 75571.2031 15639.4990 62833.2344 1.3183e5 66945.7344 1.2270e5 98164.5078 93738.3047 86790.9141 99225.5859 82375.5781 98940.0938 1.4668e5 69771.4219 65634.9141 53442.8555 1.1213e5 48842.8438 60447.8516 53031.5156 82829.5078 48638.3711 44685.4727 53593.1328 84924.9141 41722.1875 37207.6445 1.1160e5 71617.0078 50435.0938 85146.0469 45536.7617 5.8299e6 8307.42 504.72 4160.03 153.98 7246.75 776.40 537300.56 77275.16 6740.84 546.99 7805.75 602.73 8808.41 433.02 8510.73 520.72 1305922.50 154269.83 1675394.88 209136.36 10861.50 411.14 730623.25 98041.21 24683.50 726.19 9684.66 534.38 8373.95 608.73 124864.45 18194.46 4823.37 511.70 240449.20 34385.94 3346.77 292.48 8779.19 469.92 1188923.75 150229.17 3516.00 274.88 239999.52 33591.41 3260.50 297.19 11024.66 539.86 9342.77 860.15 540962.31 59294.62 4894.78 312.97 8507.38 251.77 1197067.00 110428.04 1063201.25 91326.90 1133568.00 94832.10 1563949.88 130910.27 942498.50 81220.63 11647.09 440.25 5024.78 374.04 4744.13 192.67 4686.69 237.92 3260.52 173.34 2173.53 208.20 5264.09 441.06 2179.73 219.99 34346.50 2886.04 3219.92 182.50 1046571.38 155730.00 984523.75 156476.55 529.66 80.52 14637.74 1061.57 873.00 145.36 2949.59 396.82 795472.75 130160.87 4750.50 466.41 354.50 59.27 67014.52 12136.06 439.51 66.69 1170.51 112.09 264.58 51.57 491.54 107.44 2885.76 210.28 2673.74 303.61 4099.29 660.98 3000.73 286.60 1192.36 212.94 17579302.00 2.09*6 0.04 0.03 0.17 15.00 0.12 0.13 0.04 0.04 15.00 100.00 0.08 15.00 0.14 0.53 0.61 10.00 0.16 15.00 0.09 0.05 15.00 0.03 15.00 0.33 0.60 0.26 15.00 0.09 0.04 15.00 15.00 15.00 100.00 15.00 0.09 0.08 0.04 0.05 0.04 0.03 0.05 0.03 0.35 0.02 15.00 15.00 0.01 0.13 0.02 0.05 15.00 0.06 0.01 1.50 0.01 0.01 0.01 0.01 0.03 0.04 0.08 0.04 0.03 492.93 C-12DCIE Bz FBz TCIE 2ClEthylVO C-130ClPe Toluene T-130ClPe TetClE ClBz EthylBz m-Xylene o-Cl,F-Ben o-Xylene 13DCIBZ 140CIBZ 12DCIBZ 0.04 0.03 0.17 15.00 0.12 0.13 0.04 0.04 15.00 100.00 0.08 15.00 0.14 0.53 0.61 10.00 0.16 15.00 0.09 0.05 15.00 0.03 15.00 0.33 0.60 0.26 15.00 0.09 0.04 15.00 15.00 15.00 100.00 15.00 0.09 0.08 0.04 0.05 0.04 0.03 0.05 0.03 0.35 0.02 15.00 15.00 0.01 0.13 0.02 0.05 15.00 0.06 0.01 1.50 0.01 0.01 0.01 0.01 0.03 0.04 0.08 0.04 0.03 492.93 Missing Component Report Component Air Expected Retention 5.000 (Sample File) 0398 L000183J Y. NOT DETECTED ON PRIMARY RUN: Z. NOT DETECTED ON HALL TUT 004 1834 V3400A PID 0399 Sample NMM : FileMMW : N:\V3400S\TC10010.raw Method : SOOOSUE.in* Start Tim* : 0.00 Bin End Time : 70.00 min Scale Factor: 0 Plot Offset: 4 (KV Saoplt *: C MIX Data : 3/11/93 8:58 AM Tint* of Injection: 3/10/93 9:03 PH Low Point : 4.00 mV High Point : 39.00 mV Plot Scale: 35 mV R e s o n s ro O a — IAIR H I JT-120CLE - —'C-IZDCLE - 5.67 —9.00 15.05 - 26.64 JBZ —IFBZ ——i —ITCLE 31.86 -2CLETHYLVO- JC-130CLPE - 'TOLUENE 'TETCLE 39.34 1^41.22 _JO-CL,F-BE - iiagtii = -1 -34.05 -66.50 TUT OO4 1835 L000183u .---—lUJQLflL.. Software Version: 3.2 <16C20> Sample Name Sample Number Operator ^.nstrument ^utoSampler Rack/Vial 22.5PPB 8010/8020 STD D MIX V3400A/SALLY NONE 0/0 Time Study Channel : A 3/11/93 8:58 AM LINEARITY A/D mV Range : 1000 Interface Serial # : 0159572256 Data Acquisition Time: 3/10/93 2:44 PM Delay Time 0.00 min. End Time 70.00 min. Sampling Rate 2.0000 pts/sec Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount Noise Threshold Multiplier n:\v3400s\scl0005.raw n:\v3400s\SC10005.rst N:\V3400S\8000SUE.ins N:\V3400S\HALL.prc N:\V3400S\LINHSC10.smp n:\v3400s\scl0.seq 5 mL 1.0000 Area Reject : 100.00 Dilution Factor : 1.00 15 1.0000 Area Threshold : 73 Bunch Factor: 2 Divisor : 1.0000 Adder : 0.0000 Instrument Conditions: Total Number of Peaks Detected: 48 ITAS-KNOXVBLLE V-3400B J+W DB-624 75m*0.53mm ID, 3.00um df ELECTROLYTIC CONDUCTIVITY DETECTOR-BrClMe AND 0-ClFBz ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. ALI OTHER ANALYTES ARE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLUME OF 5.O ML. Peak tt 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 " '17 18 19 20 21 22 Ret Time RT D1FF. [min] X 5.752 7.034 8.341 9.092 11.941 12.490 14.023 16.227 17.043 18.725 19.105 20.241 21.840 23.347 24.189 24.847 25.510 26.634 27.774 28.393 29.398 31.127 0.0 0.3 0.2 0.2 0.2 0.1 0.1 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 -0.0 0.0 -0.0 BL SB 8VWW W W VB BB BV W W W VE EV W W W W W W W VV Component Name DClDFMe CLME VCl BrMe ClEa TClFMe 11DCIE CH2C12 T-12DCIE 11DCIEB C-12DCIE CHC13 BrClHe 111TClEa CC14 12DCIE8 TCIE Area/ Amount 33580.4219 1.0040e5 1 .8723e5 2.1866«5 1.0252e5 2. 392905 3.1481e5 4.4073e5 3.2538e5 3.8839e5 3.5519e5 3.4350e5 3.5719*5 7.8681e5 3.2410e5 4.5117e5 60688.6641 4.4464e5 5.0309e5 2.9623e5 7.5607e5 3.9664e5 Area CuV*sec] 50963.25 2259152.50 4212800.00 4919993.00 2306786.00 5384198.00 7083384.00 3442.00 7321098.00 17425.20 7991992.00 7728971.00 8036918.50 76621.50 7292251.50 10151340.00 6068866.50 10004544.00 11319571.00 6665254.00 474820.81 8924546.00 Height INST. Amt Cal. Component [uV] (ISX) Range Name 3163.66 95403.59 218257.77 242520.41 125658.02 296858.63 398174.75 183.49 586214.06 1133.84 760199.56 736518.69 677325.94 2136.53 657874.81 831054.56 485520.03 664379.56 805049.69 553234.00 12553.37 776961.63 1.52 22.50 22.50 22.50 22.50 22.50 22.50 0.01 22.50 0.05 22.50 22.50 22.50 0.10 22.50 22.50 100.00 22.50 22.50 22.50 0.63 22.50 DClDFMe CLME VCl BrHe ClEa TClFMe 11DCIE CH2C12 T-12DCIE IIDClEa C-120CIE CHC13 BrClMe imciEa CC14 12DClEa TCIE SAMPLE CON (PPB) 1 22 22 22 22 22 22 0 22 0 22 22 22 0 22 22 100 22 22 22 0 22 .52 .50 .50 .50 .50 .50 .50 .01 .50 .05 .50 .50 .50 .10 .50 :°S LOO .50 .50 .50 .63 .50 i"'.' CD 83.' 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 31.866 32.819 34.112 35.120 36.516 37.101 37.486 38.299 40.151 41.277 44.242 45.769 47.768 50.824 51.501 53.534 54.999 56.034 58.809 59.721 60.194 62.401 63.010 64.936 66.603 68.682 Missing -0.0 -0.0 -0.0 -0.0 0.0 0.0 -0.0 -0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 1.4 ww w VE EV W W W W W W W VE EV W W W W W w VB BV W W VB BB 12DCIP1 BrOCIM* 2ClEthylVO C-130ClPe T-13DCIP* 112TCIE1 TetClE DBrClMe ClBz o-Cl.F-Ben CHBr3 1122TetClE 123TriClPr 13DCIBZ UOClBz 12DCIBZ 2.9862*5 2.9444*5 54697.5195 2.8305*5 1.6112*5 57111.2695 1.9695*5 2.8285*5 4.4929*5 1.9963*5 5.3186*5 1.5475*5 39817.7852 1.1798*5 1 .3820*5 1.0808*5 1.8995*5 1.3753*5 3.1079*5 2.4196*5 2.5394*5 1 .9784*5 2.2770*5 2.0131*5 6.2191*5 2.5201*5 1 .3430*7 6719135.00 6629437.50 820462.81 6368756.50 183333.50 35381.84 4431510.50 6364230.00 10109113.00 4491806.00 105666.88 3481924.25 3981778.50 97651.00 117863.00 2431820.75 4274057.00 3094640.25 46558.69 11598.24 111079.50 4451487.50 5123379.50 4529533.50 54566.38 5999.50 196367680.00 547291.56 538511.06 59349.77 560590.88 6021.68 2258.38 390888.28 491486.84 756137.38 284382.38 1389.95 218491.72 234100.64 2016.20 2077.42 152685.14 314176.91 218201.98 918.73 572.72 5226.29 406665.09 447390.56 411280.72 1325.92 359.76 1.49«7 22.50 22.50 15.00 22.50 1.14 0.62 22.50 22.50 22.50 22.50 0.20 22.50 100.00 0.83 0.85 22.50 22.50 22.50 0.15 0.05 0.44 22.50 22.50 22.50 0.09 0.02 896.68 120CIP* BrOCtH* 2ClEthytVO C-130CIP* T-13DCIP* 112TCIE8 TetClE OBrClMe ClBz o-Cl,F-Ben CHBr3 1122TetClE 123TriClPr 13DCIBZ UDClBz 12DCIBZ 22 22 15 22 1 0 22 22 22 22 0 22 100 0 0 22 22 22 0 0 0 22 22 22 0 0 896 .50 :X 0 4 .50 .14 .62 .50 .50 .50 .50 .20 .50 .00 .83 .85 .50 .50 .50 .15 .05 .44 .50 .50 .50 .09 .02 .68 Component Report Component Air Y. NOT Expected Retention 1.845 DETECTED ON PRIMARY RUN: Z. (Sample NOT DETECTED File) ON PID TUT OO4 1837 1000183. 1 1 M 1 1 uy us _ U±.L L1 1 5 £3 o m r* rr- N r^*M 1 1 1 k, i 1 \ 1 g Y\ S R 11P I N N 1 1 1 l.jJ 1 LL1 h -. _. O O 0 ru -» i • i- M PJ ai on -( f\» » r- fvj » -1 M ^« frl TI o -• > r- o o» •o r- m I I I I I li '•Oin \ ^* \ ^2 \ 1 * 1 1 , ro C3 O h-* CO CO ^i.j' TUT i kti\ , F\ uw \ U 1 I II-' 1< VI vi u> X -n vi r> n a -. K 0> 0> r> — 5 1 • ' . . . . _ _ _ _ , - y „ - Q UU U!z' O6 U L 0 2-^1 i i i i i • • - ~ " nl II __ 1. 1 1 I I I 1 1 1 1 I 1 1 M 1 M 1 1 1 1 1 1 1 1 1 1 I 1 o -« -»-* r» rj IP —i -<-» -• onoo _• -« r> -• -* m> <o o > OD m -• i » n » r\jn NTI -• 3oz • -» i x -• o r^o or* o •-• » -« M-* _* r- o or- cF- -• oo— o -• ro o r- mE i—x r- » r> o -H w w m o om o** -< r~r^ o ry c*» o -n >cn ffi o i— r— oo O — « r- r~ r- o XOo r- O r~ r x TI S m i - n o x z * o m r - m r * m n r x j m m x m r - r - - < m > > m r - > r * m >TI T> r- > m m m m< 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 III 1 III III 1 \ \ ll •j o- Ln INJ fl \ \ 1 11 1 1 r\J ~o 'fo i 1 | i \)n? \ w in 1 1 2 v\ Sf\ K\ \ \ 1 Lr1-""" ——— I * -. . . . . . . . . . . . . . . ow o s« I 3 • o a 3 i\» o o ox* * o p < ui asil 3 -gls B w -* i no i -*"- TJ m -t vt — 3 • -< o a. co r* Si •— 0 L S :? < 0 o 3 3' - 9 1 ^ < a) i: CO g 0 ? 8 ± ? S > _ o "T,|J| 5. — 02 ~ 5?2.0.. » 5 1 « D -» C — ' — rt o« * p co »..?*; P (D S.^R^x » 8 2 W = < o r— . iS- -...,,: 3 g. i UJ M 3: •• — f~ 10 »- ( )C ^3 (./7 0 -0 — • 0 D a « it W 0 <O -4t o -• o ( ( ^ r .' O .Cfc0 fO U4U J Software Version: 3.2 <16C20> Sample Name Sample Number Operator , Instrument AutoSampler Rack/Vial 22.5PPB 8010/8020 STD Time D MIX Study V3400A/SALLY Channel NONE 0/0 B 3/11/93 8:59 AM LINEARITY A/D mV Range : 1000 Interface Serial Delay Time End Time Sampling Rate Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount Noise Threshold Multiplier # : 0159572256 0.00 min. 70.00 min. 2.0000 pts/sec Data Acquisition Time: 3/10/93 2:44 PM n:\v3400s\tcl0005.raw n:\v3400s\TC10005.rst N:\V3400S\8000SUE.ins N:\V3400S\PID.prc N:\V3400S\LINPTC10.smp n:\v3400s\scl0.seq 5 ml 1.0000 Area Reject : 100.00 Dilution Factor : 1.00 10 1.0000 Area Threshold : 49 Bunch Factor: 2 Divisor : 1.0000 Adder : 0.0000 Instrument Conditions: Total Number of Peaks Detected: 95 ITAS-KNOXVILLE V3400A RTX 502.2 105m*0.53mm ID,3.00um df PID DETECTOR-FBZ AND O-C1FBZ ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. ALL OTHER ANALYTES ARE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLUME OF 5.O ML. Peak; a 1 2 3 4 5 6 7 8 9 11 12 13 14 15 16 . 17 18 19 20 21 22 23 Ret Time R1 [min] S.696 6.638 7.090 7.733 8.317 8.684 9.011 9.399 10.177 11.823 12.473 13.804 14.001 15.063 15.655 15.922 16.579 16.977 18.173 18.862 19.047 19.758 ' DIFF. X 0.0 0.0 0.0 0.0 0.0 0.0 0.2 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 BL. Component Name BB BB 88 BB BV W W VCl W VBW VB BV W VB BV W W W 11DCIE VB BV W W E Area/ Amount 3216.2666 2013.7808 5030.4795 6006.2720 10041.7520 7650.4443 10050.4844 9157.7236 10270.4951 10314.6484 10490.0938 41398.3789 75683.6953 30684.7832 38789.6367 37665.8477 37744.0938 31212.6504 30424.0215 86943.5938 91858.2500 1.5770e5 Area [uV*sec] 36183.00 687.00 916.50 1744.75 3020.21 3123.32 226135.89 65794.84 22417.78 17937.58 5065.19 3863.31 8306.86 136738.08 33620.16 15930.88 4614.09 702284.63 627.78 2695.50 25924.20 4786.29 Heigh tuV] 6383 112 121 193 199 271 15877 4748 1447 1154 320 349 411 14515 3246 1584 457 85666 77 359 3274 352 t 1 .70 .92 .06 .02 .85 .28 .48 .02 .26 .47 .85 .52 .08 .36 .20 .10 .86 .02 .28 .68 .21 .11 NST. (IS* 11. 0. 0. 0. 0. 0. 22. 7. 2. 1 . 0. 0. 0. 4. 0. 0. 0. 22. 0. 0. 0. 0. Amt Cal. Component ,) Range Name 25 34 18 29 30 41 50 VCl 19 18 74 48 09 11 46 87 42 12 50 110CIE 02 03 28 03 SAMPLE (PPB 11 0 0 0 0 0 22 7 2 1 0 0 0 4 0 0 0 22 0 0 0 0 CON ) .25 .34 .18 .29 .30 .41 .50 .19 .18 .74 .48 .09 .11 .46 .87 .42 •12 I A .50 LI'1 .02 .03 .28 .03 0-K' GO H-D h- 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 CU . IOJ 21.056 21.460 21.828 22.210 22.488 23.451 24.125 24.846 25.485 26.632 27.774 28.434 29.362 30.558 31.065 31.860 32.811 33.275 34.044 34.859 35.063 35.563 35.850 36.088 36.592 36.976 37.427 37.728 38.209 39.346 40.082 41.229 45.692 46.254 46.927 47.693 48.582 50.792 52.841 53.462 53.782 54.991 56.023 56.648 57.354 57.756 59.310 60.237 60.999 61.266 61.856 62.090 62.339 62.950 63.745 64.118 64.395 64.874 65.480 65.856 66.223 66.517 67.027 67.738 68.015 68.353 68.679 68.916 69.151 69.404 69.732 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 -0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.5 ww ww w w w w VB BV w w w w vv vv w w vv vv vv vv vv w VE EV VE EV vv vv vv VB BV vv vv VE EV w w w w vv w vv vv VB BB BV W VB BV W W VV vv VE EB BB BB BB BB BV VB BB BB BV VV VV W VB BB ,-,^t C-120CIE BZ FBz TCIE 2ClEthylVO C-130ClPe Toluene T-13DClPe TetClE ClBz EthylBz m-Xylene o-Cl,F-Ben o-Xylene 13DCIBZ UDClBz 12DCIBZ UWOYU. IU IO 1.1287t5 1 .3350*5 1.5256e5 51729.5313 92065.3203 41634.0430 37281.3281 55585.3594 60608.0938 2.3601e5 1.8248e5 92498.7422 16166.8027 92276.5391 49209.3164 1.1629e5 16350.9629 11395.8115 11725.7227 23022.2422 16431.4160 31314.9395 88052.7500 1.4826e5 83181.0156 1.1799e5 16546.3262 9754.6748 15163.0342 49823.2734 37947.4336 52115.3984 80516.8594 75051.9922 76959.6797 14771.8789 51054.6680 63143.9375 1.2966e5 63458.1211 1.0092e5 90923.3047 75189.6016 86460.0234 92163.9688 80390.9297 2.1696e5 98138.2109 1.5194e5 84863.8906 89696.7578 52119.1563 68481.9688 64807.2930 60812.4102 1.1277e5 62151.6836 51691.6211 65270.5117 59458.7305 45232.9414 45515.3555 1.5583e5 40649.5234 35939.8242 43314.7227 1.0545e5 71148.8203 51880.7500 46198.8320 34354.8945 6.0722e6 1554.94 5870.13 10165.00 2642.84 4440.38 9355.72 838829.88 9544.86 7797.97 12662.66 11469.03 2081221.63 1616880.25 3770.14 1107209.63 16158.78 10361.53 8830.42 175885.84 4952.91 369706.88 1338.78 6990.61 7518.67 1871572.88 4835.00 372292.34 4323.00 13348.34 7579.84 853817.25 6808.75 1811629.25 1688669.75 1731592.75 1477187.88 8315.00 1420738.63 13288.50 6283.24 9067.06 6333.50 3868.80 4396.33 20931.91 3396.58 3163.50 14253.23 2197.56 1548.20 1258.17 865.70 1540844.38 1458164.13 833.73 113426.39 4420.00 1163061.50 1155.75 593.00 738.50 28323.50 3293.50 324.27 536.00 654.77 3556.94 3556.66 1047.77 409.38 220.75 25151828.00 159.82 510.12 772.97 231.16 218.23 1016.75 118232.27 776.96 582.15 657.43 770.11 248681.70 201588.97 208.62 152276.05 709.48 636.70 778.56 25993.42 671.89 54483.83 133.52 771.30 492.66 237645.61 398.11 53752.12 400.35 795.26 512.82 93199.95 440.39 165874.27 143399.38 143462.70 124051.13 186.65 120726.61 510.70 493.42 447.72 347.13 256.41 422.73 1888.17 351.26 121.22 1207.45 120.24 151.67 116.62 138.09 229426.23 231874.56 111.38 8178.84 578.34 189547.84 144.00 81 . 11 132.77 5060.63 171 .58 64.87 121 .28 122.93 274.30 406.53 164.2*. 72 . 06 5 2 . 2 6 3.02e« 0.01 0.04 0.07 0.05 0.05 0.23 22.50 0.17 0.13 0.05 0.06 22.50 100.00 0.04 22.50 0.14 0.63 0.78 15.00 0.22 22.50 0.04 0.08 0.05 22.50 0.04 22.50 0.44 0.88 0.15 22.50 0.13 22.50 22.50 22.50 100.00 0.16 22.50 0.10 0.10 0.09 0.07 0.05 0.05 0.23 0.04 0.02 0.15 0.01 0.02 0.01 0.02 22.50 22.50 0.01 1.01 0.07 22.50 0.02 0.01 0.02 0.62 0.02 0.01 0.02 0.02 0.03 0.05 0.02 0.01 0.01 b35.84 T-120CIE C-12DCIE Bz FBz TCIE 2ClEthylVO C-13DClPe Toluene T-130ClPe TetClE ClBz EthylBz m-Xylene o-Cl,F-8en o-Xylene 13DCIBZ 140CIBZ 12DCIBZ iZ 0 0 0 0 0 0 22 0 0 0 0 22 100 0 22 0 0 0 15 0 22 0 0 0 22 0 22 0 0 0 22 0 22 22 22 100 0 22 0 0 0 0 0 0 0 0 0 0 0 0 0 0 22 22 0 1 0 22 0 0 0 0 0 0 0 0 0 0 0 0 0 635 .50 f\ i .04 04 .07 .05 .05 .23 .50 .17 .13 .05 .06 .50 .00 .04 .50 .14 .63 .78 .00 .22 .50 .04 .08 .05 .50 .04 .50 .44 .88 .15 .50 .13 .50 .50 .50 .00 .16 .50 .10 .10 .09 .07 .05 .05 .23 .04 .02 .15 .01 .02 .01 .02 .50 .50 .01 .01 .07 .50 .02 .01 .02 .62 .02 .01 .02 .02 .03 .05 .02 .01 .01 .84 Missing Component Report Component Air Expected Retention 5.000 (Sample File) \ 000184, TUT 004 184O Y. NOT DETECTED ON PRIMARY RUN: Z. NOT DETECTED ON HALL TUT 004 1841 L000184, V3400A PID 0406 Sanple NMW : Z2.5PPS 8010/8020 STD FileMane : n:\v3400s\tc10005.raw Method : SOOOSUE.Ins Start Time : 0.00 nin End Time : 70.00 min Scale Factor: 0 Plot Offset: 4 fflV *: 0 MIX Date : 3/11/93 9:00 AM Ti«e of Injection: 3/10/93 2:44 PM Low Point : 4.00 mV High Point : 39.00 mv Plot Scale: 35 roV o "H Q — f -^ ' ' ^-^ -~r ^ NJo -5.70 _a —IVCL -10.18 -9.01 ^O IT-IZDCLE - JC-12DCLE - >15.66 -19.76 -19.05 .45 26.63 27.77 FBZ ITCLE — iZCLETHYLVO- -31.86 I TOLUENE T-130CLPE 'TETCLE 39.35 1.23 -15.06 -34.04 gt|f - _ 0-CL.F-BE - 0-XYLENE jf-48.58 i*8 -U-54.99 £&.<& - O" .120CLB2 H 57.35 .24 TUT OO4 184; Software Version: 3.2 <16C20> Sample Name Sample Number Operator Instrument AutoSampler Rack/Vial 30 PPB 8010/8020 STD Time E MIX Study V3400A/SALLY Channel NONE 0/0 3/11/93 9:01 AM LINEARITY A/D mV Range : 1000 Interface Serial # : 0159572256 Data Acquisition Time: 3/10/93 4:00 PM Delay Time 0.00 min. End Time 70.00 min. Sampling Rate 2.0000 pts/sec Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount Noise Threshold Multiplier N:\V3400S\SC10006.raw n:\v3400s\SC10006.rst N:\V3400S\8000SUE.ins N:\V3400S\HALL.prc N:\V3400S\LINHSC10.smp n:\v3400s\scl0.seq 5 mL 1.0000 Area Reject : 100.00 Dilution Factor : 1.00 15 1.0000 Area Threshold : 73 Bunch Factor: 2 Divisor : 1.0000 Adder : 0.0000 Instrument Conditions: Total Number of Peaks Detected: 47 ITAS-KNOXVILLE V-3400B J+W DB-624 75m*0.53mm ID, 3.00um df ELECTROLYTIC CONDUCTIVITY DETECTOR-BrClMe AND O-ClFBz ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. ALL OTHER ANALYTES ARE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLUME OF 5.O ML. Peak n 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 ' 18 19 20 21 22 Ret Time R [min] 5.754 7.023 8.320 9.073 11.907 12.467 13.998 16.620 17.028 18.721 19.100 20.238 21.833 23.311 24.172 24.837 25.483 26.614 27.769 28.369 29.486 31.121 T DIFF. X 0.0 0.1 -0.0 -0.0 -0.1 -0.1 -0.0 0.0 -0.1 0.0 -0.0 -0.0 -0.0 0.0 -0.1 -0.0 -0.1 -0.1 -0.0 -0.1 0.0 -0.0 BL BB BV WWW W W VB BE EV WW VE EV WWW WW WWW Component Name DClDFMe CLME VCl BrMe ClEa TClFMe 11DCIE CH2C12 T-12DCIE IIOClEa C-12DCIE CHC13 BrClMe HITClEa CC14 120ClEa TCIE Area/ Amount 35319.0156 1.2264e5 2.2006e5 2.4672e5 1.2131e5 2.6930e5 3.7073e5 2.1620e5 3.4490e5 6.4565e5 3.2463e5 3.1703e5 3.5931e5 6.5463e5 3.2515e5 4.1908e5 68345.5938 4.7345e5 4.9146e5 3.1805e5 7.8117e5 3.7077e5 Area [uV*sec 34927 3679228 6602099 7401744 3639522 8079197 11122182 2268 10347056 48782 9739129 9511167 10779524 103738 9754534 12572440 6834559 14203508 14744001 9541769 654322 11123226 Heigh 3 Cuv: .00 2035 .00 161134 .50 351471 .00 379235 .25 202527 .00 444924 .00 613013 .57 246 .00 821308 .50 1909 .00 854405 .00 842804 .00 868859 .00 3476 .00 844058 .00 927063 .00 547283 .00 909753 .00 950729 .00 786230 .38 16743 .00 892566 t I .47 .89 .53 .38 .45 .28 .94 .53 .63 .46 .44 .25 .31 .71. .13 .13 .81 .56 .88 .50 .06 .69 NST. Amt (ISX) 0.99 30.00 30.00 30.00 30.00 30.00 30.00 0.01 30.00 0.08 30.00 30.00 30.00 0.16 30.00 30.00 100.00 30.00 30.00 30.00 0.84 30.00 Cal. Component Range Name * DClDFMe + CLME * VCl + BrMe + ClEa + TClFMe + 11DCIE + CH2C12 + T-120CIE + IIOClEa + C-12DCIE + CHC13 1- BrClMe + 111TClEa * CC14 + 12DCIE8 * TCIE SAMPLE CON (PPB) 0.99 % 30.00 QQ 30.00 T-t 30.00 30.00 ^. 30.00 X 30.00 0 0.01 30.00 . 0.08 D 30.00 H 30.00 30.00 0.16 30.00 30-°° LOO 01 84.* 100.00 u u ' * 30.00 30.00 30.00 0.84 30.00 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 31.846 32.799 34.092 35.104 36.497 37.073 37.468 38.282 40.146 41.253 44.025 45.730 47.730 50.699 53.508 54.983 56.017 59.708 60.164 62.377 62.987 64.916 66.569 67.922 68.660 -0.1 W 12DClPi 3.2181*5 -0.1 W BrOCLN* 3.1922*5 -0.1 W 2ClEthylVO 63997.5742 -0.1 VE C-130CIP* 3.0453*5 0.0 EV 1.9573*5 0.0 W 60856.4258 -0.1 W T-13DCIP* 2.1492*5 -0.1 W 112TCIE* 2.9396*5 -0.0 W TetClE 4.4063*5 -0.0 W DBrClMe 2.1770*5 0.0 W 4.3165*5 -0.1 W ClBz 1.7245*5 -0.1 W o-Cl,F-B*n 44659.6992 0.0 VB 93732.0313 -0.1 BV CHBr3 1.1116*5 -0.0 W 1122TetClE 1.9776*5 -0.0 W 123TriClPr 1.4958*5 0.0 W 2.9708*5 0.0 VB 2.2239*5 -0.0 BV 130CIBZ 2.3040*5 -0.0 W UDClBz 2.5798*5 -0.0 VE 120CIBZ 2.2335*5 0.0 EV 7.5996*5 0.0 VB 3.7792*5 0.0 BB 2.1444*5 9654532.00 786011.19 9576640.00 779189.25 1279951.50 95309.36 9136192.00 792303.88 259501.50 9262.23 53536.85 3206.89 6447718.50 570986.06 8819005.00 685554.81 13219104.00 921831.38 6531249.00 423579.47 121373.44 1967.20 5173737.00 334543.22 4465970.00 267903.63 87230.81 2267.06 3334930.00 212757.58 5932973.00 434918.50 4487505.50 311531.03 23010.80 925.48 158831.00 8533.30 6912066.50 637054.06 7739659.00 679890.75 6700599.50 603674.00 78913.50 1569.19 7611.25 304.35 11679.53 823.05 30.00 30.00 20.00 30.00 1.33 0.88 30.00 30.00 30.00 30.00 0.28 30.00 100.00 0.93 30.00 30.00 30.00 0.08 0.71 30.00 30.00 30.00 0.10 0.02 0.05 * 12DCIP* * BrOClHe * 2ClEthylVO * C-130CIP* + T-130CIP* * 112TCIE8 * TetClE i- DBrClMe - ClBz + o-Cl,F-B*n + CHBr3 + 1122TetClE + 123TriClPr + 130CIBZ + 14DCIBZ + 12DCIBZ 30.00 U4UI 30.00 20.00 30.00 1.33 0.88 30.00 30.00 30.00 30.00 0.28 30.00 100.00 0.93 30.00 30.00 30.00 0.08 0.71 30.00 30.00 30.00 0.10 0.02 0.05 •1.2 Missing Component Report Component Air 1.3713*7270732448.00 1.99*7 1126.46 Expected Retention (Sample File) 1.845 1126.46 Y. NOT DETECTED ON PRIMARY RUN: Z. NOT DETECTED ON PID TUT OO4 1844 L O C 0 1 8 4 0 V3400A HALL Sanple Name : 30 PPB 8010/8020 STO Filename : N:\V3400S\SC10006.raw Method : SOOOSUE.inc Start TiM : 0.00 min End Time : 70.00 min cate Factor: 0 Plot Offset: 4 mV Sample #: E NIX Date : 3/11/93 9:01 AM Time of Injection: 3/10/93 4:00 PM Low Point : 4.00 mv High Point : 39.00 mv Plot Scale: 35 mV Response K) O \J L-J C _|AIR — I H ^JDCLDFNE — JCLME k -JVCL — ^TCLFME r" -5.75 11DCLE CH2CL2 T-120CLE - _ —J110CLEA ZJ111TCLEA Hf^LEA —iBRDCLME —J2CLETHYLVO- ——(C-130CLPE - —1 "1T-130CLPE - —r -JTETCLE ->DBRCLME ZJ "ZJCLBZ ZJO-CL.F-BE - 1 CHBR3 1122TETCL 123TRICLP -36.50 -44.03 -50.70 -59.71 -60.16 lie I 0001843 TUT OO4 1845 U4 iU Software Version: 3.2 <16C20> Sample Name Sample Number Operator ^instrument AutoSampler Rack/Vial 30 PPB 8010/8020 STD Time E MIX Study V3400A/SALLY Channel NONE 0/0 B 3/11/93 9:02 AM LINEARITY A/D mV Range : 1000 Interface Serial Delay Time End Time Sampling Rate Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount Noise Threshold Multiplier # : 0159572256 0.00 min. 70.00 min. 2.0000 pts/sec Data Acquisition Time: 3/10/93 4:00 PM n:\v3400s\tcl0006.raw n:\v3400s\TC10006.rst N:\V3400S\8000SUE.ins N:\V3400S\PID.prc N:\V3400S\LINPTC10.smp n:\v3400s\scl0.seq 5 ml 1.0000 Area Reject : 100.00 Dilution Factor : 1.00 10 1.0000 Area Threshold : 49 Bunch Factor: 2 Divisor : 1.0000 Adder : 0.0000 Instrument Conditions: Total Number of Peaks Detected: 93 ITAS-KNOXVILLE V3400A RTX 502.2 105m*0.53mm ID,3.00um df PID DETECTOR-FBZ AND O-ClFBz ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. ALL OTHER ANALYTES ARE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLUME OF 5.O ML. Peak 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 ,, 16 17 18 19 20 21 22 Ret Time RT DIFF. (min] X 5.681 6.624 7.069 7.730 8.294 8.653 9.006 9.353 10.147 11.805 12.450 13.988 15.041 15.637 15.899 16.561 16.959 18.150 18.851 19.031 19.743 20.168 0.0 0.0 0.0 0.0 0.0 0.0 0.1 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 -0.1 0.0 0.0 0.0 0.0 -0.1 BL Component Name BB BB BB BB BV VV VE VCl EV VB BV VB BV VB BV W VV W 11DCIE VB BV W W W T-12DCIE Area/ Amount 1190.4445 2337.2358 6364.4473 6196.1318 9852.6523 7058.6426 11867.6250 9744.5918 10596.5166 10348.9111 11098.0332 96559.7500 31139.4082 39484.1953 38861.9063 36036.2344 34698.8984 32449.6250 1.1905e5 88463.4531 1.6331e5 91284.5469 Area [uV»sec] 13392 758 1550 2652 4513 2394 356028 52468 20805 28217 8026 15494 122674 31365 15133 5531 1040967 666 1486 34292 4984 2738536 .50 .25 .50 .50 .94 .39 .75 .00 .19 .00 .31 .84 .67 .90 .70 .27 .00 .64 .17 .58 .31 .50 Height INST. Amt Cal. Component SAMPLE CuV] (1SX) Range Name (PPB) 2842.00 107.38 161.88 284.46 304.43 225.40 24594 . 74 3559.99 1302.52 1806.14 480.57 601.01 12905.30 2975.26 1458.52 574.88 124801.84 76.94 144.83 4497.33 354.09 477796.25 11 0 0 0 0 0 30 5 1 2 0 0 3 0 0 0 30 0 0 0 0 30 .25 .32 .24 .43 .46 .34 .00 » vci .38 .96 .73 .72 .16 .94 .79 .39 .15 .00 » 110CIE .02 .01 .39 .03 .00 * T-120CIE 11. 0. 0. 0. 0. 0. 30. 5. 1. 2. 0. 0. 3. 0. 0. 0. 30. 0. 0. 0. 0. 30. CON 25 32 24 43 46 34 00 38 96 73 72 16 94 79 39 15 00 / f; .^ A 02 L 0 0 U 01 39 03 00 -Q CO h; f- 23 21.024 24 21.447 2S 21.804 26 22.464 27 23.042 28 23.426 29 24.102 30 24.835 31 25. 453 32 26.611 33 27.772 34 28.409 35 29.339 36 30.547 37 31.044 38 31.842 39 32.795 40 33.256 41 34.027 42 34.843 43 35.040 44 35.548 45 36.074 46 36.575 47 36.954 48 37.406 49 37.718 50 38.194 51 39.332 52 40.063 53 41.208 54 44.864 55 45.660 56 46.222 57 46.890 58 47.656 59 50.761 60 52.817 61 53.440 62 53.769 63 54.974 64 55.420 65 56.019 66 56.636 67 57.340 68 57.734 69 60.229 70 61.240 71 61.833 72 62.063 73 62.315 74 62.927 75 63.724 76 64.099 77 64.370 78 64.524 79 64.856 80 65.834 81 66.203 82 66.499 83 67.033 84 67.723 85 67.993 86 68.231 87 68.333 88 68.650 89 68.916 90 69.133 91 69.378 92 69.506 93 69.707 0.0 W 1.1432*5 0.0 W 1.3924«5 0.0 W 1.9224*3 0.0 W 56091.4063 0.0 W 60782.4063 0.0 W 40584.0000 -0.1 W C-12DCIE 42160.3750 0.0 W 62691.4-92 0.0 VB 60239.8750 0.0 BV 2.5106*5 0.0 W 2.0487*5 •0.1 W Bz 1.0502e5 •0.1 W FBz 18386.2637 0.0 W 55745.2266 •0.1 W TCIE 57406.8086 0.0 W 98142.3281 0.0 W 16141.8984 0.0 W 10142.2842 -0.1 W 2CtEthylVO 13668.4795 0.0 W 21087.9316 -0.1 W C-13DClPe 19118.8984 0.0 W 37698.8047 0.0 W 1.8016e5 -0.0 VE Toluene 96016.3516 0.0 EV 1.1460e5 -0.1 VE T-130ClPe 19190.9961 0.0 EV 9173.5547 0.0 W 16795.9121 0.0 W 43419.1523 -0.1 W TetClE 44392.6758 0.0 W 50926.7266 0.0 VB 1.8650*5 -0.0 BV ClBz 93156.7734 -0.0 W EthylBz 85483.2734 -0.0 W m-Xylen* 90736.5938 -0.0 W o-Cl,F-Ben 16944.3301 -0.0 W o-Xylen« 73810.7422 0.0 W 1.4352*5 0.0 W 62921.7148 0.0 W 1.2104*5 0.0 W 76418.4375 0.0 W 60115.9688 0.0 W 87450.0781 0.0 W 89425.4375 0.0 W 95206.9766 0.0 VB 1.2520*5 0.0 BV 81400.7031 0.0 VB 1.8350*5 0.0 BV 73819.9844 0.0 W 47820.3711 -0.0 W 13DCIBZ 82773.7813 -0.0 W 140CIBZ 78334.9141 0.0 W 67699.0234 0.0 VE 1.0930*5 0.0 EV 59227.2070 0.0 VB 53631.7813 0.0 BB 12DCLBZ 60866.4844 0.0 BB 43591.9336 0.0 BB 50650.5508 0.0 BB 44304.7617 0.0 BB 75622.0156 0.0 BV 51801.0352 0.0 W 94256.3750 0.0 W 56767.5313 0.0 W 46333.9023 0.0 W 1.2158*5 0.0 W 83235.7500 0.0 w 57590.2617 0.0 W 58304.2305 0.0 VB 52669.8477 0.0 BB 35675.6211 -0.8 6.2842*6 2283.27 231.71 4707.11 403.80 16214.86 978.54 3842.75 309.98 1572.83 117.08 12000.89 1337.97 1264811.25 177435.11 12288.20 886.88 8758.03 657.82 18107.91 883.78 15182.53 908.06 3150636.00 377316.41 1838626.38 229757.59 2373.17 217.37 1722204.25 237990.09 17367.41 903.57 14079.25 876.36 10662.50 1088.48 273369.59 40913.00 6082.17 900.76 573566.94 86171.56 2752.59 228.03 8502.72 458.51 2880490.50 368032.91 7157.00 606.72 575729.88 84508.34 5822.50 573.37 18658.41 1159.87 12381.28 961.21 1331780.25 144395.91 10186.84 674.26 6213.31 221.77 2794703.25 261096.59 2564498.25 219956.98 2722097.75 226905.36 1694433.00 140537.03 2214322.25 188641.86 14875.66 516.48 9944.54 787.60 9886.91 407.05 7388.88 481.84 1601.99 132.80 6237.84 355.46 4871.81 452.92 14228.38 1242.45 6628.66 440.15 33675.69 3439.39 4209.81 190.72 668.56 75.29 412.15 71.65 2483213.50 373780.59 2350047.50 377080.75 1802.72 216.33 102127.65 7598.55 4109.00 564.20 2375.94 360.27 1825994.50 300725.13 309.50 57.74 824.50 132.38 70511.23 12871.69 1030.50 110.82 829.96 130.30 2427.85 209.47 973.36 139.44 1424.28 249.98 2893.78 193 55 3650.88 356.70 3802.68 536.98 1255.48 175.12 1418.25 218.96 250.50 5 7 . 1 0 37296312.00 4.5^.«> 0.02 0.04 0.08 0.07 0.03 0.30 30.00 + 0.20 0.15 0.07 0.07 30.00 100.00 » 0.04 30.00 + 0.18 0.87 1.05 20.00 + 0.29 30.00 * 0.07 0.05 30.00 + 0.06 30.00 + 0.64 1.11 0.29 30.00 + 0.20 0.03 30.00 * 30.00 * 30.00 * 100.00 » 30.00 » 0.10 0.16 0.08 0.10 0.03 0.07 0.05 0.15 0.05 0.41 0.02 0.01 0.01 30.00 * 30.00 + 0.03 0.93 0.07 0.04 30.00 + 0.01 0.02 1.59 0.01 0.02 0.03 0.02 0.03 0.02 0.04 0.07 0.02 0.03 0.01 769.86 C-120CIE Bz FBz TCIE 2Cl£thylVO C-130ClPe Toluene T-13DClPe TetClE ClBz EthylBz m-Xylene o-Cl,F-8en o-Xylene 13DCIBZ 14DCIBZ 12DCIBZ 0.02 0.04 0.08 0.07 0.03 0.30 30.00 0.20 0.15 0.07 0.07 30.00 100.00 0.04 30.00 0.18 0.87 1.05 20.00 0.29 30.00 0.07 0.05 30.00 0.06 30.00 0.64 1.11 0.29 30.00 0.20 0.03 30.00 30.00 30.00 100.00 30.00 0.10 0.16 0.08 0.10 0.03 0.07 0.05 0.15 0.05 0.41 0.02 0.01 0.01 30.00 30.00 0.03 0.93 0.07 0.04 30.00 0.01 0.02 1.59 0.01 0.02 0.03 0.02 0.03 0.02 0.04 0.07 0.02 0.03 0.01 769.86 hissing Component Report 'Component Air Expected Retention 5.000 (Sample File) L O O O i U4 I 1 CO o \~ -L- N°T DETECTED ON PRIMARY RUN: Z. NOT DETECTED ON HALL 0 4 12~ TUT 004 1S48 U001849 V3400A PID Sample Naa* : 30 PPS 8010/6020 STO FUeNww : n:\v3400s\tc10006.raw Method : SOOOSUE.ins Start Time : 0.00 nin End Time : 70.00 rain Scale Factor: 0 Plot Offset: 4 mV Sample t: E NIX Date : 3/11/93 9:02 AM Time of Injection: 3/10/93 4:00 PM Low Point : 4.00 MV High Point : 39.00 mV Plot Scale: 35 mV Response [mV] o ro O NO I I !\J O" o o _ o~ 'Jl CD O~Z1 AIR VCL -5.68 10.15 15.64 11DCLE T-12DCLE - C-12DCLE - BZ FBZ TCLE 2CLETHYLVO- C-130CLPE - TOLUENE T-130CLPE - TETCLE -19.74 -19.03 5.43 -26.61 -27.77 ^-30.55 -31.84 -39.33 -XYLENE 0-CL.F-BE 0-XYLENE - I 12DCLBZ - -9.01 -15.04 L 0001850 TUT 004 1849 Software Version: 3.2 <16C20> Sample Name Sample Number operator ^"Instrument AutoSampler Rack/Vial c mix ISppb V3400A/SALLY NONE 0/0 Time Study Channel : A : 3/20/93 1:11 PM : check standard 0414 A/D mV Range : 1000 Interface Serial # : 0159572256 Data Acquisition Time: 3/11/93 2:44 PM Delay Time End Time Sampling Rate Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount 0.00 70.00 2.0000 min. min. pts/sec N:\V3400S\SC10024.raw n:\v3400s\SC10024.rst N:\V3400S\8000SUE.ins N:\V3400S\HALL.prc N:\V3400S\LINHSC10.smp n:\v3400s\scl0.seq 5 mL 1.0000 Area Reject : 100.00 Dilution Factor : 1.00 ITAS-KNOXVILLE V3400B J+W DB-624 75m*0.53mm ID,3.00um df ^,LECTROLYTIC CONDUCTIVITY DETECTOR: Percent differences, standard 'concentrations, and Cfs for BrClMe, o-Cl,F-Benzene, and B2ClIsopO are incorrect due to the compounds having a concentration different than the other compounds in the mix. The percent differences for these compounds and Cfs must be done manually. The computer could only calculate percent differences and Cfs from only one standard concentration. /••» Standard check compared /\[)/9\ linearity \>-?i Q3.\1 ^ Peak * 0 2 3 4 5 6 7 8 10 11 12 14 15 - 16 17 18 19 21 22 23 : Ret Tine [min] 1.845 7.040 8.349 9.105 11.957 12.509 14.041 17.066 19.119 20.255 21.855 24.200 24.853 25.517 ' 26.647 27.785 28.403 31.139 31.877 32.827 Component Name Air DClDFHe CLHE VCl Brfle ClEa TClFHe 11DCIE CH2C12 T-12DCIE 27561 11DClEa C-12DCIE CHC13 BrClMe 111TClEa ecu 12DClEa TCIE 12DCIPB BrOClHe Height CUV] 0.00 66149.01 147726.86 162390.61 77711.88 197558.30 268092.50 359473.78 545554.50 488009.53 438380.69 429453.03 595053.94 489914.38 444754.19 536980.44 376545.38 537164.81 376959.72 373150.56 BL Cal. Range W BV W W W W VB BV W W W W W W W W W W W W CONCENTR, [PPB 0 16 16 15 15 16 15 14 17 16 15 16 16 97 15 15 15 16 16 16 AT10N i 1 .00 .05 .00 .91 .38 .28 .88 .48 .48 .00 .91 .04 .82 .34 i .03 .86 .86 .99 .28 .62 iTANDARD CO (PPB) 15.000 15.000 15.000 15.000 15.000 15.000 15.000 15.000 15.000 15.000 15.000 15.000 15.000 c04£rftW" isiooo 15.000 15.000 15.000 15.000 15.000 N. PERCENT DIFFERECE -1.000* 6.972 6.695 6.053 2.562 8.552 5.864 -3.449 16.545 6.648 J ^6.039 'V1 6.909 12.117 ^7*4ftrf» 0.194 5.723 5.697 13.276 8.532 10.780 Component 2 Air DClDFHe CLHE VCl BrMe ClEa TClFHe 11DCIE CH2C12 T-12DCIE 2356-1 IIDClEa C-12DCIE CHC13 • BrClHe IHTClEa ecu 12DClEa TCIE 12DClPa SrOClNe DAILY Cf 0.0000 4.4099e3 9.8484e3 1.0826*4 5.1807e3 1.3170e4 1.7872*4 2.3964*4 3.6370*4 3.2533*4 2.9225*4 2.8630*4 3.9670*4 3.2660*4 2.9650*4 3.5796*4 / 2.5103*4 L 3.5810*4 2.5130«4 2.4876*4 O m 00 t-i O h- r— 0001851 24 25 27 28 29 30 31 >2 -34 35 36 38 39 40 34.123 35.129 37.496 38.310 40.160 41.288 45.783 47.790 53.558 55.023 56.054 62.403 63.011 64.932 2ClEthylVO C-13DCIP* T-13DCIP* 112TCIE* TetClE DBrClMe ClBz o-Cl,F -Benzene CHBr3 1122TetClEa 123TriClPropane 130CIBZ 140CIBZ 12DCIBZ 40179.27 389795.16 262500.56 332695.91 497043.66 192591.03 149983.92 255190.89 96999.79 221239.92 154710.27 292140.81 319050.47 285926.97 1.04*7 W WWWWWWW BVWW BVW VE 10 15 15 16 16 15 16 105 15 16 17 16 16 15 696 .65 .47 .84 .49 .18 .84 .12 •02 t .78 .92 .08 .77 .52 .87 .75 15.000 15.000 15.000 15.000 15.000 15.000 fyt^ J^nP^Ul* 3.116 5.628 9.953 7.848 A*,y5.624 * > 7.446 t 2ClEthylVO C-13DCIP* T-130CIP* 112TClEa TetClE DBrClMe ClBz 2.6786*3 2.5986*4 1.7500*4 2.2179*4 3.3136*4 1.2839*4 9.9989*3 ' 041 CC ISreOO- ic^aOO-M? o-Cl.F-Benzene 1.7012*4 15.000 15.000 15.000 15.000 15.000 15.000 510.000 5.205 12.823 13.879 11.822 10.099 5.793 CHBr3 1122TetClEa 6.4666*3 1.4749*4 123TriClPropane 1.0314*4 13DCIBZ 14DCIBZ 12DCIBZ 1.244*3 1.9476*4 2.1270*4 1.9061*4 6.9340*5 ITAS-KNOXVILLE V-3400B J+W DB-624 75m*0.53mm ID, 3.00um df ELECTROLYTIC CONDUCTIVITY DETECTOR-BrClMe AND O-ClFBz ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. ALL OTHER ANALYTES ARE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLUME OF 5.O ML. •sk Ret Time RT OIFF. BL Component Area/ * Cm in] X Name Amount 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 26 29 30 31 52 33 34 35 36 37 38 39 5.762 7.040 8.349 9.105 11.957 12.509 14.041 17.066 18.763 19.119 20.255 21.855 23.374 24.200 24.853 25.517 26.647 27.785 28.403 29.410 31.139 31.877 32.827 34.123 35.129 36.550 37.496 38.310 40.160 41.288 45.783 47.790 50.801 * 53.558 55.023 56.054 60.210 62.403 63.011 0.0 BB 46731.8008 0.4 BV OClDFHe 97093.4922 0.3 W CLME 1.8333e5 0.3 W VCl 2.1253e5 0.3 W BrMe 94944.3594 0.3 W ClEa 2.3082e5 0.3 VB TClFNe 3.1281e5 0.2 BV 11DCIE 3.1278*5 0.0 W 4.7694e5 0.1 W CH2C12 3.3025e5 0.1 W T-120CIE 3.207Se5 0.1 W 27561 110CI 3.3605e5 0.0 W 8.3596e5 0.1 W C-120CIE 3.0148e5 0.1 W CHC13 4.321Be5 0.0 W BrClNe 63776.5664 0.1 W 111TClEa 4.6014e5 0.0 W CC14 4.8258e5 0.0 W 12DClEa 2.9378*5 0.0 W 9.3184*5 0.0 W TCIE 3.6372e5 0.0 W 12DClPa 2.8929e5 0.0 W BrDClMe 2.8660*5 0.0 W 2ClEthylVO 58356.3867 0.0 W C-13CCIP* 2.9379*5 0.0 W 4.4770*5 0.0 W T-130CIP* 1.9522*5 0.0 W 112TCIEB 2.6690*5 0.0 W TetClE 4.1903e5 0.0 W OBrClNe 2.0668*5 0.1 W ClBz 1.4974e5 0.1 W o-Cl,F-Ben 40781.6602 0.0 VB 2.4094e5 0.1 BV CHBr3 1.0480*5 0.1 W 1122TetClE 1.8283*5 0.0 W 123TriClPr 1.3681e5 0.0 VB 3.9540«5 0.0 BV 130CIBZ 1.9423*5 0.0 W 140CIBZ 2.2633*5 Area Height INST. Ant Cat. Component SAMPLE CON [uV*s*c] CuV] (1SX) Range Name (PPB) 23176.00 1423.28 1557948.00 66149.01 2934118.00 147726.86 3381047.50 162390.61 1460656.50 77711.88 3758499.00 197558.30 4967332.50 268092.50 4529905.50 359473.78 9620.84 629.50 5773528.50 545554.50 5131116.50 488009.53 5345174.50 438380.69 51467.28 1648.75 4834691.00 429453.03 7268351.00 595053.94 6208038.50 489914.38 6915470.00 444754.19 7652954.50 536980.44 4657894.50 376545.38 453443.25 11556.91 6180255.00 537164.81 4709645.50 376959.72 4762576.50 373150.56 621369.63 40179.27 4544327.50 389795.16 135253.78 4215.80 3093219.75 262500.56 4402133.50 332695.91 6778756.00 497043.66 3274575.00 192591.03 2413459.50 149983.92 4282760.50 255190.89 41371.50 865.47 1653878.75 96999.79 3094146.00 221239.92 2337050.50 154710.27 75685.44 3333.79 5257918.00 292140.81 3737969.00 319050.47 0.50 16.05 16.00 15.91 15.38 16.28 15.88 14.48 0.02 17.48 16.00 15.91 0.06 16.04 16.82 97.34 15.03 15.86 15.86 0.49 16.99 16.28 16.62 10.65 15.47 0.30 15.84 16.49 16.18 15.84 16.12 105.02 0.17 15.78 16.92 17.08 0.19 16.77 16.52 DClOFNe CLME VCl BrMe ClEa TClFMe 110CIE CH2C12 T-12DCIE 27561 110C I C-12DCIE CMC 13 BrClMe 111TClEa CC14 12DClEa TCIE 120ClPa BrOClMe 2ClEthylVO C-130CIP* T-130CIP* 112TClEa TetClE DBrClMe ClBz o-Cl.F-Ben CHBr3 1122TetClE 123TMClPr 13DCI8Z 140CIBZ 0.50 16.05 16.00 15.91 15.38 16.28 15.88 14.48 0.02 17.48 16.00 15.91 0.06 16.04 16.82 97.34 15.03 15.86 15.86 0.49 16.99 16.28 16.62 10.65 15.47 0.30 15.84 16.49 16.18 15.84 16.12 105.02 D.17 IS.TB 16.92 17.08 , 0.19 U 16.77 16.52 •H U"j CO •H •5foo h-D j_- 0001852 40 64.932 41 67.363 0.0 VE 120CIBZ 0.0 EB 3.1 Missing Component Report Jomponent Air 2.0576«5 3265302.50 285926.97 6.3787e5 12230.00 345.46 1.2099*7 139588304.00 1.04e7 Expected Retention 1.845 15.87 12DCIBZ 0.02 698.50 (Sample File) 15.87 0.02 698.50 0416 Y. NOT DETECTED ON PRIMARY RUN: Z. NOT DETECTED ON PID TUT O04 1852 L0001853 V3400A HALL Sample Name : c nix FileName : N:\V3400S\SC10024.rau Method : SOOOSUE.ins Start Time : 0.00 min End Time : 70.00 min Scale Factor: 0 Plot Offset: 4 mV Sample *: 15ppb Date : 3/20/93 1:11 PM Time of Injection: 3/11/93 2:44 PK Low Point : 4.00 mV High Point : 39.00 mV Plot Scale: 35 mV Response [mV] o o- roo NJ en o Ln O _ NJ O~Z] CD _H 0) o~ 0) -^_I o _ 3 = CT)o" AIR DCLDFHE CLME VCL EUR - TCLFME 110CLE CH2CL2 T-120CLE - 27561 11DC - 111TCLEA - BRDCLME 2CLETHYLVO C-130CLPE T-130CLPE 112TCLEA TETCLE DBRCLME CLBZ 0-CL.F-BE CHBR3 1122TETCL 123TRICLP 18&E - 120CLBZ - --CB -50.80 7UT 004 1853 Software Version: 3.2 <16C20> Sample Name Sample Number Operator Instrument AutoSampler Rack/Vial c mix 15ppb V3400A/SALLY NONE 0/0 Time Study Channel 3/20/93 1:11 PM check standard 0418 B A/D mV Range : 1000 Interface Serial # : 0159572256 Data Acquisition Time: 3/11/93 2:44 PM Delay Time 0.00 min. End Time 70.00 min. Sampling Rate 2.0000 pts/sec Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount n:\v3400s\TC10024.raw n:\v3400s\TC10024.rst N:\V3400S\8000SUE.ins N:\V3400S\PID.prc N:\V3400S\LINPTC10.smp n:\v3400s\scl0.seq 5 ml 1.0000 Area Reject : 100.00 Dilution Factor : 1.00 ITAS-KNOXVILLE V3400B J+W DB-624 75m*0.53mm ID,3.00um df XPHOTOIONIZATION DETECTOR: Percent differences, standard concentrations, and Cfs for FBz, o-Cl,F-Benzene, and B2ClIsopO are incorrect due to the compounds having a concentration different than the other compounds in the mix. The percent differences for these compounds and Cfs must be done manually. The computer could only calculate percent differences and Cfs from only one standard concentration. Standard check compared to linearity Peak Ret Time * [min] 0 6 17 21 27 32 33 35 39 41 43 45 49 51 52 53 54 55 69 70 75 5.000 9.010 17.000 20.195 24.134 28.439 29.368 31.071 34.050 35.066 36.598 37.431 40.094 45.703 , 46.268 46.941 47.712 50.813 62.337 62.947 64.869 Component Name Air VCl 11DCIE T-12DCIE C-12DCIE Bz FBz TCIE 2ClEthylVO C-13DClPe Toluene T-130CIP* TetClE ClBz EthylBz m-Xylen* o-Cl,F-Benzene o-Xylene 130CIBZ 140CIBZ 12DCIBZ Height [uV] 0.00 10187.95 49914.06 193730.13 77726.74 155165.33 206762.77 98319.03 17863.85 34593.82 151049.02 34100.20 59819.13 110490.91 92607.48 94979.45 130791.18 80875.27 155216.16 156189.28 130010.22 BL Cal. Range W W W VE W W VE W W W VE VE W BV W W W W BV VB BB CONCENTRATION STANDARD CON. PERCENT tPPBl (PPB) DIFFERECE 0 14 13 14 15 13 98 15 10 13 14 15 15 14 14 14 99 15 15 15 15 .00 .32 .62 .44 .27 .71 •88 / .29 .52 .37 .43 .40 .16 .88 .98 .95 .92 .05 .17 .24 .02 15.000 15.000 15.000 15.000 15.000 15.000 Ul^i jj pop 15.000 \^t*TflOO 15.000 15.000 15.000 15.000 15.000 15.000 15.000 (iinijiOOO 15.000 15.000 15.000 15.000 Component Name -I.OOOeZ Air -4.513 -9.181 -3.768 1.803 -8.578 i]r( _559.C15 1.922 S Jjrf9r*65 , -10.852 -^^-3.803 ^2.636 1.089 -0.794 -0.132 -0.347 /CO 4*67443" 0.348 1.102 1.577- 0.120 VCl 110CIE T-120CIE C-120CIE Bz FBZ TCIE 2ClEthylVO C-130ClPe Toluene T-13DClPe TetClE ClBz EthylBz •-Xyt*n* DAILY Cf 0.0000 679.1965 3.3276e3 1.2915*4 5.1817e3 1.0344e4 1.3784*4 6.5546e3 1.1909*3 2.3062*3 1.0069*4 2.2733*3 3.9879*3 .7.3660*3 6.1738*3 6.3319*3 o-Cl,F-Benzene 8.7194e3 o-Xylene 130CIBZ 140CIIZ 12DCIBZ 5.3916*3 / 1.0347*4 *- 1.0412*4 8.6673*3 in CO •H Q ,-~: K h- OC0185 2.04e6 459.61 315.000 964.089 1.3602e5 0419 ITAS-KNOXVILLE V3400A RTX 502.2 105m*0.53mm ID,3.00um df PID DETECTOR-FBZ AND O-ClFBz ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. ALL OTHER ANALYTES ARE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLUME OF 5.O ML. Peak Ret Time RT DIFF. * [min] X 1 2 3 4 5 6 7 8 10 11 12 13 14 ^15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 ',7 48 ^W 50 51 52 53 54 55 5.687 6.648 7.078 7.734 8.319 9.010 9.395 10.198 11.829 12.497 14.033 15.079 15.674 15.938 16.598 17.000 18.879 19.064 19.771 20.195 21.049 21.471 21.840 22.498 23.460 24.134 24.851 25.486 26.647 27.785 28.439 29.368 30.576 31.071 31.872 32.823 33.282 34.050 34.866 35.066 36.095 36.598 36.986 37.431 37.744 38.222 39.358 • 40.094 41.238 45.703 46.268 46.941 47.712 50.813 0.0 0.0 0.0 0.0 0.0 0.2 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.2 0.0 0.0 0.0 0.1 0.0 0.0 0.0 0.0 0.0 0.1 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0. 0. 0. 0. 0. BL BB BB BB BB BV W W VB W VB BB BB BV W W W W W W VE EV W W W W W W VB BV W W VE EV W W W W W W W W VE EV VE EV W W W VB BV W W W W Component Name VCl 11DCIE T-12DCIE C-120CIE Bz FBZ TCIE 2ClEthylVO C-130ClPe Toluene T-13DClPe TetClE ClBz EthylBz •-Xylene o-Cl.F-Ben o-Xyl«ne Area/ Amount 690.7003 4684.6953 6039.0337 10896.6787 10742.6309 10833.0440 11649.4453 10754.8242 11008.9990 1.0048e5 34717.9844 38189.0586 37916.5273 37266.8750 30159.0000 2.5701e5 1.1396e5 2.1823e5 77419.5781 2.0222e5 1.9029e5 2.6237e5 1.0645e5 70447.2188 35339.4063 65328.0977 71086.0469 2.2122e5 1.7486*5 95664.9844 16791.4336 1.2689e5 46153.8828 1.4128e5 24544.6641 16030.7607 12006.4766 30361 .8965 18214.9883 2.5150e5 82853.4844 1 .3359e5 15918.9121 22178.6387 34323.9688 94959.4844 36438.9414 1.8176e5 80555.1953 72290.7813 76081.4844 15890.7783 62279.7813 Area tuV*sec] 10351.75 816.25 698.50 980.75 2020.52 153866.69 33651.58 8023.47 13448.28 3103.47 7581.50 91725.00 17453.38 11167.80 5552.89 410851.00 2870.81 19247.92 6636.22 1117540.00 2446.50 6273.80 11541.52 4663.09 14878.31 539649.69 7501.20 8514.16 8583.88 8290.48 1311877.00 1660374.63 3682.00 705614.19 10497.63 8667.02 7198.06 126310.44 6690.92 243574.02 11889.91 1195542.38 3723.00 245078.39 4054.50 13097.63 9800.69 552533.75 20623.25 1198736.25 1082929.00 1137264.38 Height INST. Amt Cat. Component SAMPLE CON luV] (ISX) Range Name (PPB) 2322.76 106.65 106.06 115.52 131.89 10187.95 2209.57 489.90 889.44 200.52 276.45 9680.30 1674.54 1079.18 545.95 49914.06 149.91 2266.81 408.12 193730.13 162.37 442.47 590.37 222.95 1075.00 77726.74 584.45 609.64 439.04 536.45 155165.33 206762.77 186.60 98319.03 477.83 479.78 611.52 17863.85 570.10 34593.82 494.87 151049.02 291.73 34100.20 296.89 622.65 407.16 59819.13 447.60 110490.91 92607.48 94979.45 1S87756.« 130791 . 18 W7445.38 80875.27 0.00 1.18 0.15 0.16 0.19 14.32 3.11 0.69 1.25 0.28 0.08 2.64 0.46 0.30 0.15 13.62 0.01 0.17 0.03 14.44 0.01 0.03 0.04 0.04 0.21 15.27 0.12 0.12 0.04 0.05 13.71 98.88 0.03 15.29 0.07 0.35 0.45 10.52 0.22 13.37 0.05 14.43 0.03 15.40 0.18 0.38 0.10 15.16 0.11 14.88 14.98 14.95 99.92 15.05 VCl 110CIE T-120CIE C-12DCIE Bz FBz TCIE ZClEthylVO C-130ClPe Toluene T-130ClPe TetCtE ClBz EthylBi •-Xylane 0-Cl.F-Ben o-Xyl«ne 0.00 1.18 0.15 0.16 0.19 14.32 3.11 0.69 1.25 0.28 0.08 2.64 0.46 0.30 0.15 13.62 0.01 0.17 0.03 14.44 0.01 0.03 0.04 0.04 0.21 15.27 0.12 0.12 0.04 0.05 13.71 98.88 0.03 15.29 0.07 0.35 0.45 10.52 0.22 13.37 0.05 14.43 0.03 15.40 0.18 0.38- 0.10 15:16 0.11 14.88 14.98 14.95 99.92 15.05 ifi U"J CO •^ 5 '•—•' h- -3I- LOC01F5G 56 57 58 59 60 61 62a 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 52.891 53.476 53.805 55.013 55.438 56.041 56.667 57.369 57.765 59.951 60.249 61.284 61.857 62.337 62.947 63.742 63.937 64.119 64.395 64.869 66.213 66.506 66.788 67.002 67.250 67.722 67.935 68.240 68.340 68.911 69.144 69.304 69.600 0.0 W 0.0 W 0.0 W 0.0 W o.o w 0.0 VB 0.0 BV 0.0 W 0.0 W 0.0 W 0.0 W 0.0 W 0.0 VB 0.0 BV 130CIBZ 0.0 VB 14DCIBZ 0.0 BV 0.0 W 0.0 W 0.0 VB 0.0 BB 120CIBZ 0.0 BV 0.0 W 0.0 W 0.0 W 0.0 VB 0.0 BV 0.0 W 0.0 W 0.0 W 0.0 W 0.0 W 0.0 W 0.0 VB 1.U12e5 78082.9375 75191.5469 2.1649e5 1.099SeS 98876.3438 79711.4375 1 .3390e5 1.0975e5 6.0359e5 1.1594e5 2.7190e5 1.4411e5 68538.6172 64848.3828 54979.5352 65434.3984 93807.0938 78721.0156 52703.2031 44438.9414 52475.3242 93849.2031 90600.6953 80321 .4922 69905.3516 1.0419e5 68105.6484 51005.9219 1.6447e5 70013.6719 81319.1328 1.0604e5 11892.44 443.36 6705.97 461.45 3894.04 278.26 14483.16 359.45 5043.28 246.45 3779.86 205.40 1365.05 175.27 14899.42 1138.79 2968.38 276.82 11608.50 196.84 12840.84 1133.51 7221.09 271.82 1855.72 131.79 1039404.13 155216.16 988061.88 156189.28 363.82 67.83 9849.69 1303.12 12944.97 1194.63 5987.53 658.45 791493.00 130010.22 272.82 53.15 25768.78 4251.15 3081.98 284.29 3739.73 357.34 2062.42 222.29 2255.16 279.28 4243.63 352.59 1374.76 174.75 1343.41 228.01 11807.36 621.47 2886.37 356.89 2960.35 315.15 2212.97 180.65 0.08 0.09 0.05 0.07 0.05 0.04 0.02 0.11 0.03 0.02 0.11 0.03 0.01 15.17 130CIBZ 15.24 140CIBZ 0.01 0.15 0.14 0.08 15.02 120CIBZ 0.01 0.49 0.03 0.04 0.03 0.03 0.04 0.02 0.03 0.07 0.04 0.04 0.02 0.08 0 09 o'os Q 4 0.07 0.05 0.04 0.02 0.11 0.03 0.02 0.11 0.03 0.01 15.17 15.24 0.01 0.15 0.14 0.08 15.02 0.01 0.49 0.03 0.04 0.03 0.03 0.04 0.02 0.03 0.07 0.04 0.04 0.02 1.0 7.8483e6 17625560.00 2.08*6 475.05 475.05 Missing Component Report Component Expected Retention (Sample File) 5.000 Y. NOT DETECTED ON PRIMARY RUN: Z. NOT DETECTED ON HALL TUT 004 1856 i OC0185' SMple Name : c mix Filename : n:\v3400*\TC10024.raw Method : SOOOSUE.Ins tart Time : 0.00 win End Time : 70.00 win cate Factor: 0 Plot Offset: 4 mV V3400A PID SaMple *: 15ppb Date : 3/20/93 1:12 PK Time of Injection: 3/11/93 2:44 PM Low Point : 4.00 MV High Point : 39.00 mV Plot Scale: 35 «V 0421 Response [nnV] o o- o en OJo en NJ O" 0) CT U-J_ o'°"n H - 3 0) *J 3 = CTi_ O _J AIR VCL -5.69 11DCLE T-120CLE - C-12DCLE - BZ FBZ TCLE 2CLETHVLVO- C-130CLPE - TOLUENE T-130CLPE - TETCLE X30.58 -31.87 36.10 39.36 O-CL.F-BE - 0-XYLENE - 120CLBZ - 9.01 15.08 -34.05 0001658 TUT 004 1857 -24. -28. -36. Sample File : N:\V3400S\LINHSCli.SMP Created by : on : 5/12/89 2:54 PM Edited by : on : 3/12/93 9:28 AM Number Of Times Edited : 400 i Sample Description : Default Injection Volume = 5.0000 mL An External Standard Calibration Will Be Used , Unknown Peaks Will Use The Response Factor Of The Nearest Component v^r^ Component information : mention Time : 1.845 min Search Window: 5.00 sec, 5.00 % Component: (Find Closest Peak) Group Calibrating^Height versus Amount Using a 2nd Order Fit Curve Will Be Forced Through The Origin Amounts Will Not Be^Scaled Prior To The Regression Weighting Factor For^th^e Regression: 1 Calibration Levels: Level Name Amount AreV. Height ISTD Resp. ISTD Amt. * Replicates ^l A B C D f 1.5000 7.5000 15.0000 22.5000 TO nnnn 3603.22^ 1313.50 5577.00 1417.25 iu.t. nn \125.35 ----------- - - - - n4- 82 ........... ---- 26OH1 ........... - - - - 192. BZX---------- •--- R7 *O .V......... .... - - - - - - - 1 - - - - - - - 1 1 1 ....... 1 Calibration Curve R-squared y » (0.000000) + (28.308945)x 0.481345 (-0.853783)x-2 * (0.000000)x'3 min Search Window: (Find Closest Peak) DClDFMe Retention Time : 7.047 Reference Component: BrClMe Group Name : 601 Calibrating Height versus Amount Using a 2nd Order Fit Curve Will Be Forced Through The Origin Amounts Will Not Be Scaled Prior To The Regression Weighting Factor For the Regression: l Calibration Levels: Level Name Amount Area Height ISTD Resp. ISTD Amt. 14.00 sec, 2.00 % * Replicates A B C D c 1.5000 7 5000 22.5000 in nnnn ao« T» JL17£QA AA 1896523.00 2422463.00 TOAiTiT nn 3797.29 -........-- ... 24418.94- ----------- --. 72850.52 -- 93128.16 -- 1CTA71 PO ........... -- ......... ! - - - - - - - - - 1 1 - - - - - - - - - 1 ......... 1 03 in 00 Calibration Curve R-squared y - (0.000000) 0.983105 * (3296.647217)x * (57.420628)x'2 * (0.000000)x'3 H CLME J Retention Time : 8.348 min Search Window: 19.00 sec, 2.00 «, Reference Component: BrClMe (Find Closest Peak) __ Group Name : 601 H Calibrating Height versus Amount Using a 2nd Order Fit Curve Will Be Forced Through The Origin Amounts Will Not Be Scaled Prior To The Regression . OKI Weighting Factor For the Regression: l \[_ f001853 Calibration Levels: Level Name Amount Area Height ISTD Resp. ISTD Amt. * Replicates A B C D 1.5000 7.5000 1^ «^n#Wr 77.SOOO 4OCCB4 9T 1180926.25 3395038.50 &7IKM1A Of) 9146.95 ....... — . — . 162483 38 ' — ———— — • >nnn7 os ........... .... . — .... i ........ 1 ........ ! ........ 1 E 30.0000 6926150.00 340778.00 —--•--••- ........... 1 0423 Calibration Curve : y « (0.000000) + (7569.535645)x + (117.819054)x-2 + (0.000000>x'3 R-squared : 0.983402 VC1 / A] Retention Time : 9.088 min Search Window: 25.00 sec, 2.00 % Reference Component: BrClMe (Find Closest Peak) Group Name : 601 Calibrating Height versus Amount Using a 2nd Order Fit Curve Will Be Forced Through The Origin Amounts Will Not Be Scaled Prior To The Regression Weighting Factor For the Regression: 1 Calibration Levels: Level Name Amount Area Height ISTD Resp. ISTD Amt. * Replicates A B C D c 1.5000 7.5000 15.0000 22.5000 *n nnnn ^azttfC Q/ QOQQ f\A ' 3818275.75 173474.39 --- 4862742.00 220461.88 --- 7C9nnnit «n tenon? nn .' ........... ... - - - - - - - - 1 - - - - - - - - 1 ........ 1 ........ ! ........ 1 Calibration Curve : y * (0.000000) + (8301.489258)x + (113.214714>x*2 + (0.000000)x'3 R-squared : 0.983718 BrMe / Retention Time : 11.932 min Search Window: 26.00 sec, 2.00 % Reference Component: BrClMe (Find Closest Peak) Group Name : 601 Calibrating Height versus Amount Using a 2nd Order Fit Curve Will Be Forced Through The Origin Amounts Will Not Be Scaled Prior To The Regression Weighting Factor For the Regression: l Calibration Levels: Level Name Amount Area Height ISTD Resp. ISTD Amt. # Replicates .................................................j........................................ A 1.5000 54836.83 2399.90 , ----------- ........... i B 7.5000 547172.00 27863.09 ---------.. .-.......-- 1 C 15.0000 1668494.75 85494.73" ----------- ........... 1 0 22.5000 2009282.00 104895.74J ........... ........... 1 E 30.0000 3423247.75 177274.92' ----------- --.--.-.--- 1 Calibration Curve : y - (0.000000) + (3775.522705)x + (66.215889)x'2 + (0.000000)x'3 R-squared : 0.977304 ClEa Retention Time : 12.479' min Search Window: 17.00 sec, 2.00 Reference Component: BrClMe (Find Closest Peak) Group Name : 601 Calibrating Height versus Amount Using a 2nd Order Fit Curve Will Be Forced Through The Origin o- Amounts Will Not Be Scaled Prior To The Regression CD Weighting Factor For the Regression: i ^ Calibration Levels: Level Name Amount Area Height ISTD Resp. ISTD Amt. * Replicates % O H- A B C D c 1. 7. 15. 22. TO 5000 5000 0000 5000 nnno 265358. 133OO19* *•&£ f TrfT • jlUjOw* •1XAO/C 59 50 50 on 1 tJ** J < 77675, 211455. 254202. L-ift-KtL M - - - - - - - - - - -- aa ........... .. 73 ........... .. Bfl ........... ] J I ......... 1 Calibration Curve : y « (0.000000) » (10423.4iQi56)x - O06.382530)x'2 » (O.OOOOOQ)x'3 R-squared : 0.977035 L00018GO TClFMe J Retention Time : 14.007 min Search Window: 21.00 sec, 2.00 Reference Component: BrClMe (Find Closest Peak) Group Name : 601 Calibrating Height versus Amount Using a 2nd Order Fit 0424 Curve Will Be Forced Through The Origin Amounts Will Not Be Scaled Prior To The Regression Weighting Factor For the Regression: 1 Calibration Levels: Level Name Amount Area Height ISTD Resp. ISTD A/nt. * Replicates A B C 0 C 1.5000 7.5000 15.0000 22.5000 tn nnnn 300277.41 2058770.38 5528990.50 7207512.50 in*7£«?« nn 15313.05 '----------- --- 109092.84 - ----------- --- 292625.53 ........... ... 378156.66 ' .......--.- ... *«9iir) «1 ........... .... ........ ! - - - - - - - - 1 ........ T ........ , ........ 1 Calibration Curve : y * (0.000000) + (15366.825195)x + <124.109917)x-2 + (0.000000)x'3 R-squared : 0.987910 TCLTFEa '' Retention Time : 16.467 min Search Window: 5.00 sec, 1.00 % Reference Component: BrClMe (Find Closest Peak) Group Name : Calibrating Height versus Amount Using a 2nd Order Fit Curve Will Be Forced Through The Origin Amounts Will Not Be Scaled Prior To The Regression Weighting Factor For the Regression: 1 Calibration Levels: Level Name Amount Area Height ISTO Resp. ISTD Amt. * Replicates ..j....................................... A 1.0000 99693.56 5142.36 B 7.5500 1908914.50 100427.60 ' C 15.1000- 4869714.50 252108.47 ' 0 22.6500 6734908.00 356342.28 e 30.2000 9942378.00 521869.47' Calibration Curve : y * (0.000000) + (13772.(K1992)x + <112.385193}x'2 * (0.000000)x'3 R-squared : 0.995784 11DC1E / Retention Time : 17.025 min Search Window: 17.00 sec, 1.00 % Reference Component: BrClMe (Find Closest Peak) Group Name : 601 ./ Quantitation Will Be Done Using Response Factor = 23347.000000 CH2C12 J Retention Time : 19.085 min Search Window: 16.00 sec, 1.00 % Reference Component: BrClMe (Find Closest Peak) Group Name : 601 ^ Quantitation Will Be Done Using Response Factor = 36870.000000 T-12DC1E j Retention Time : 20.219 min Search Window: 13.00 sec, 1.00 % Reference Component: BrClMe (Find Closest Peak) Group Name : 601 Quantitation Will Be Done Using Response Factor - 29194.000000y J HlDClEa Retention Time : 21.813 min Search Window: 16.00 sec, i.oo o Reference Component: BrClMe (Find Closest Peak) jg Group Name : 601 /' ""* Quantitation Will Be Done Using Response Factor = 26521.000000 j . ? C-12DC1E ' , o Retention Time : 24.149 min Search Window: 16.00 sec, I.oo Reference Component: BrClMe (Find Closest Peak) t, Group Name : J t- Quantitation Will Be Done Using Response Factor - 25107.000000 CHC13 / 0425 Retention Tine : 24.802/min Search Window: 16.00 sec, 1.00 % Reference Component: BrClMe (Find Closest Peak) Group Name : 601 v Quantitation Will Be Done Using Response Factor = 33409.000000 BrClMe I Retention Time : 25.465 min Search Window: 20.00 sec, 1.00 % Reference Component: BrClMe (Find Closest Peak) , Group Name : QC / Quantitation Will Be Done Using Response Factor = 5090.000000 UlTClEa Retention Time : 26.593 min Search Window: 16.00 sec, 1.00 % Reference Component: BrClMe (Find Closest Peak) Group Name : 601 Quantitation Will Be Done Using Response Factor = 27738.000000- CC14 - / Retention Time : 27.735jiin Search Window: 19.00 sec, 1.00 % Reference Component: BrClMe (Find Closest Peak) Group Name : 601 _/' Quantitation Will Be Done Using Response Factor = 31421.000000 12DClEa / Retention Time :. 28.355 min Search Window: 16.00 sec, 1.00 % Reference Component: BrClMe (Find Closest Peak) Group Name : 601 Quantitation Will Be Done Using Response Factor = 22829.000000 TC1E S Retention Time : 31.098 min Search Window: 14.00 sec, 1.00 % Reference Component: BrClMe (Find Closest Peak) Group Name : 601 Quantitation Will Be Done Using Response Factor = 30301.000000 •min 12DClPa Retention Time : 31.839 "tiiin Search Window: 17.00 sec, 1.00 % Reference Component: BrClMe (Find Closest Peak) Group Name : 601 ^X Quantitation Will Be Done Using Response Factor = 22297.000000 BrDClMe J Retention Time : 32.790 min Search Window: 18.00 sec, i.oo % Reference Component: BrClMe (Find Closest Peak) Group Name : 601 Calibrating Height versus Amount Using a 2nd Order Fit Curve Will Be Forced Through The Origin Amounts Will Not Be Scaled Prior To The Regression Weighting Factor For the Regression: l Calibration Levels: Level Name Amount Area Height ISTD Re*p. ISTD Amt. * Replicates A B C D c 1.0000 7.5000 isioooo 22.5000 in nnnn 263238.56 2308901.00 4667531,00 6683643.50 o&tnnn? tin 14155.95 ---.-..--.- -- 168091.09 -...--..--- -- 533252.63 ........... -. TAICi? TC ........... ......... 1 ......... 1 . —— ..... 1 ......... 1 1 . D I- 10001862 * Calibration Curve : y • (0.000000) * (21556.656250)x * (124.084793>x'2 + (0.000000)x'3 R-squared : 0.9987U 2ClEthylVO y Retention Time : 34.083 min Search Window: 14.00 sec, 1.00 I Reference Component: o-Cl,F-BENZENE (Find Closest Peak) Group Name : 601 Calibrating Height versus Amount Using a 2nd Order Fit Curve Will Be Forced Through The Origin Amounts Will Not Be Scaled Prior To The Regression Weighting Factor For the Regression: l Calibration Levels: Level Name Amount Area Height ISTD Resp. ISTD Amt. * Replicates A B C D c 1.0000 5.0000 10.0000 15.0000 3n nnnn 47432.91 684318.75 905066.75 HAATTn nn 1359.65 -.-.-...-.- .-- 47110.29 ........... ... 62957.81 ....-----.. -.- OAcnn AT ) ........... ... - - - - - - - - 1 | Calibration Curve : y = (0.000000) + (3658.319336)x + (51.344132)x'2 + (0.000000)x'3 R-squared : 0.989619 C-13DC1P6 J Retention Time : 35.088 min Search Window: 15.00 sec, 1.00 % Reference Component: BrClMe (Find Closest Peak) Group Name : 601 Quantitation Will Be Done Using Response Factor = 24791.000000 T-13DC1P6 / Retention Time : 37.446 min Search Window: 19.00 sec, 1.00 % Reference Component: o-Cl,F-BENZENE (Find Closest Peak) Group Name : 601 Calibrating Height versus Amount Using a 2nd Order Fit Curve Will Be Forced Through The Origin Amounts Will Not Be Scaled Prior To The Regression Weighting Factor For the Regression: 1 Calibration Levels: Level Name Amount Area Height ISTD Resp. ISTD Amt. # Replicates A B C D P 1 nnnn 7.5000 15.0000 22.5000 7ft nnnn 59781 .80 1510641.50 3077066.75 3848705.25 Ai£.cn7* «n 3274 82 ....----... ... 123831.81 ........... --- 263198.44' ----------- --- 330098.88' ........... ... CTon«£ OL ! ........... ... ........ i ........ i ........ 1 ........ 1 ........ 1 Calibration Curve : y * (0.000000) + (14259.061523)* + (104.351585)x'2 + (0.000000)x'3 R-squared : 0.981364 112TC1E8 -^ Retention Time : 38.257 min Search Window: 19.00 sec, l.oo % Reference Component: o-Cl,F-BENZENE (Find Closest Peak) Group Name : 601 Calibrating Height versus Amount Using a 2nd Order Fit Curve Will Be Forced Through The Origin Amounts Will Not Be Scaled Prior To The Regression Weighting Factor For the Regression: l Calibration Levels: Level Name Amount Area Height ISTD Resp. ISTD Amt. * Replicates A B C D c 1 7 15 22 tn .0000 .5000 .0000 .5000 nnnn 222943 MHTOV 4377795 5224082 •A7V4JUI .13 .50 .00 .00 nn 12481 . 162610. 331990. 401296. A 7*OAO 29 ........... .. 23 ........... -- 75 .......... .. 81 ........... -- 11 ... ...... ......... 1 ......... i ......... i ......... i ......... i Calibration Curve : y * (0.000000) * (18049.369?.v,, . (H9.554146)x'2 + (0.000000)x'3 R-squared : 0.973788 • _ _ _ L0001863 Retention Time : 40.097 min Search Window: 24.00 sec, 1.00 I Reference Component: o-Cl,F-BENZENE (Find Closest Peak) Group Name : 601 Quantisation Will Be Done Using Response Factor = 29347.000000 / 0427 DBrClMe ' Retention Tine : 41.217 min Search Window: 22.00 sec, 1.00 % Reference Component: o-Cl,F-BENZENE (Find Closest Peak) Group Name : 601 Calibrating Height versus Amount Using a 2nd Order Fit Curve Will Be Forced Through The Origin Amounts Will Not Be Scaled Prior To The Regression Weighting Factor For the Regression: 1 Calibration Levels: Level Name Amount Area Height ISTD Resp. ISTO Amt. # Replicates A B C D e 1.0000 7.5000 15.0000 22.5000 in nnnn 1573«21.88 3153807.25 4244856.50 A1A7A71 CO 6495.31 --..-.----- -- 86752.33 -- 191105.80 -- 273058.94 ........... -- 1OTACO 1X, ........... - - - - - - - - - 1 - - - - - - - - - 1 - - - - - - - - - 1 ......... T ......... 1 Calibration Curve : y « (0.000000) * (11285.537109)x + (57.401787)x'2 + (0.000000)x'3 R-squared : 0.997688 C1BZ Retention Time : 45.688 min Search Window: 28.00 sec, 1.00 % Reference Component: o-Cl,F-BENZENE (Find Closest Peak) Group Name : 601 / Quantitation Will Be Done Using Response Factor = 8909.000000 "' o-Cl,F-Benzene s Retention Time : 47.680 min Search Window: 29.00 sec, 1.00 % Reference Component: o-Cl,F-BENZENE (Find Closest Peak) Group Name : QC Quantitation Will Be Done Using Response Factor = 2504.000000 -" CHBr3 / Retention Time 53.470 min Search Window: 21.00 sec, 1.00 % Reference Component o-Cl,F-BENZENE (Find Closest Peak) Group Name 601 Calibrating Height versus Amount Using a 2nd Order Fit Curve Will Be Forced Through The Origin Amounts Will Not Be Scaled Prior To The Regression Weighting Factor For the Regression: 1 Calibration Levels: K, Level Name Amount Area Height ISTD Resp. ISTD Amt. * Replicates ,Q .................................................^........................................ a A 1.0000 58180.25 2457.38 ' ----------- -..-.-.-... 1 -i B 7.5000 793270.00 41801.03 •--.-..---- ......----- i C 15.0000 1658044.88 96899.52 ----------- ........... \ ^ D 22.5000 2269719.75 137679.98 ----------- .-..-.....- \ O f. 30.0000 3233773.50 200180.30 . •------••-- ..-....--.- 1 Calibration Curve R-squared y « (0.000000) » (5546.571289)x 0.996918 <35.727295)x-2 * (0.000000)x'3 \- 1122TetClEa J Retention Time : 54.941 min Search Window: 23.00 sec, l.oo « Reference Component: o-Cl,F-BENZENE (Find Closest Peak) Group Name : 601 Calibrating Height versus Amount Using a 2nd Order Fit Curve Will Be Forced Through The Origin Amounts Will Not Be Scaled Prior To The Regression L 00018^4 Weighting Factor For the Regression: Calibration Levels: Level Name Amount Area Height ISTD Resp. ISTD Amt. * Replicates 1.0000 152762.94 7599.34 7.5000 1582306.00 108817.80 15.0000 22.5000 30.0000 3123126.75 4232650.00 5892756.00 221128.89 300217.91 426301.06 0428 Calibration Curve R-squared : y * (0.000000) : 0.995900 (U117.722656)x + (-3.630693)x"2 * (0.000000)x'3 123TriClPropane Retention Time : 55.974 min Search Window: 5.00 sec, 5.00 % Reference Component: (Find Closest Peak) Group Name : Calibrating Height versus Amount Using a 2nd Order Fit Curve Will Be Forced Through The Origin Amounts Will Not Be Scaled Prior To The Regression Weighting Factor For the Regression: 1 Calibration Levels: Level Name Amount Area Height , ISTD Resp. ISTD Amt. * Replicates A B C Dt 1 fififif\ 15.0000 in nnnn 98625.88 1210210.88 2280214.25 3197833.25 £1A9«n? Cfl 5263.68 ........... ... 75532.08 --.-------- ... 153380.25 ' - - - - - - - - - - - --- tnnniut 01 ........... ... ........ i ........ 1 - - - - - - - - 1 ........ 1 ........ 1 Calibration Curve R-squared y * (0.000000) 0.997222 (9791. 280273 )x (0.000000)x-3 13DC1B2 Retention Time Reference Component Group Name 62.336 min Search Window: 17.00 sec, 1.00 % o-Cl,F-BENZENE (Find Closest Peak) 601 Calibrating Height versus Amount Using a 2nd Order Fit Curve Will Be Forced Through The Origin Amounts Will Not Be Scaled Prior To The Regression Weighting Factor For the Regression: 1 Calibration Levels: Level Name Amount Area Height ISTD Resp. ISTD Amt. « Replicates A a c 0 c 1.0000 7.5000 15.0000 22.5000 *n nnnn irff *»i f • yn 1501514.00 9AAAAT9 CO 4675941 .00 A/uu^nA An 10232.27 / ----------- --- 130027.92 - - - - - - - - - - - --- 254268 83 - - - - - - - - - - - --- 420493.09 ' - - - - - - - - - - - --- A/17C7A M ........... ... ........ ! 1 ........ ! ........ ! ........ 1 Calibration Curve : y » (0.000000) + (14508.477539>x * (189.396881)x~2 + (0.000000)x'3 R-squared : 0.999219 14DC1BZ J Retention Time : 62.946 min Search Window: 16.00 sec, 1.00 % Reference Component: o-Cl,F-BENZENE (Find Closest Peak) Group Name : 601 Calibrating Height versus Amount Using a 2nd Order Fit Curve Will Be Forced Through The Origin Amounts Will Not Be Scaled Prior To The Regression Weighting Factor For the Regression: l Calibration Levels: Level Name Amount Are* Height ISTD Resp. ISTD Amt. * Replicates -G 03 B 7.5000 1761681.13 142211.52 -----.---- -- C 15.0000 3547949.25 297688.47 ........... -- e in nnnn 7i5ii«o en ££77ni 01 ........... . ——— ... i — . ——— i . —— . — 1 ......... 1 ......... 1 - h- Z3 H- 12DC1BZ Retention Time Calibration Curve : y - (0.000000) * (17493.294922)* - (132.076401)x*2 * (0.000000)x'3 R-.qu.red : 0.999231 . L O G O 186 5 : 64.877 min Search Window: 16.00 sec, 1.00 Reference Component: o-Cl,F-BENZENE (Find Closest Peak) /Ajr»n Group Name : 601 /0429 Quantitation Will Be Done Using Response Factor = 17538.000000 TUT 004 1865 L000186G Sample File : N : \ V 3 4 0 0 S \ L I N P T C l l . s m p 0 4 3 U Created by : on : 5/12/89 2:54 PM Edited by : on : 3/12/93 9:34 AM Number Of Times Edited : 412 Sample Description : Default Injection Volume = 5.0000 ml An External Standard Calibration Will Be Used Unknown Peaks Will Use The Response Factor Of The Nearest Component Component Information : Air Retention Tinie. : 5.000 min Search Window: 5.00 sec, 5.00 % Reference Component: (Find Closest Peak) Group Name Calibrating Height versus Amount Using a 2nd Order Fit Curve Will Be Forced Through The Origin Amounts Will Not Be ScaledP-Rrior TO The Regression Weighting Factor For the Regression: l Calibration Levels: Level Name Amount Area Heigh^^x. 1STO Resp. ISTD Amt. « Replicates A 1.0000 0.00 331.00 B 2.5000 0.00 331.00 ------X.- ........... 0 C 5.0000 0.00 331.00 --...-..-TX^........... 0 D 7.5006 0.00 331.00 E 15.0000 0.00 331.00 Calibration Curve : y - (0.000000) + (96.218834>x * (-5.053600)x'2 + (0.000000)x'3 R-squared : 1.000000 VC1 Retention Time : 8.997 min Search Window: 25.00 sec, 2.00 % Reference Component: FBz (Find Closest Peak) Group Name : 601 Quantitation Will Be Done Using Response Factor = 668.647766 11DC1E Retention Time : 16.963 min Search Window: 18.00 sec, 1.00 % Reference Component: FBz (Find Closest Peak) Group Name : 601 Quantitation Will Be Done Using Response Factor - 3232.000000 T-12DC1E Retention Time : 20.159 min Search Window: 52.00 sec, l.oo % Reference Component: FBz (Find Closest Peak) Group Name : 601 Quantitation Will Be Done Using Response Factor = 12456.000000 C-12DC1E Retention Time : 24.084 min Search Window: 18.00 sec, 1.00 % Reference Component: FBz (Find Closest Peak) Group Name : Quantitation Will Be Done Using Response Factor = 4850.000000 T Bz Retention Time : 28.392 min Search Window: 19.00 sec, 1.00 \ Reference Component: FBz (Find Closest Peak) Group Name : 602 Quantitation Will Be Done Using Response Factor = 10664. OOOOOJX' FBz TUT 004 1366 / 04 Retention Time : 29.325 min Search window: 20.00 sec, 1.00 % Reference Component: FBz (Find Closest Peak) Group Name : QC J Quantitation will Be Done Using Response Factor » 2093.000000 TC1E Retention Time : 31.033 min Search Window: 17.00 sec, 1.00 % Reference Component: FBz (Find Closest Peak) Group Name : 601 Quantitation Will Be Done Using Response Factor = 6125.000000 2ClEthylVO Retention Time Reference Component Group Name 34.012 min Search Window: 47.00 sec, i.oo % FBz (Find Closest Peak) 602 Calibrating Height versus Amount Using a 2nd Order Fit Curve Will Be Forced Through The Origin Amounts Will Not Be Scaled Prior To The Regression Weighting Factor For the Regression: l Calibration Levels: Level Name Amount Area Height ISTD Resp. ISTD Amt. « Replicates A B C 0 F 1.0000 5.0000 10.0000 15.0000 ?n nnnn OC1O AA 55206.42 U0723.73 187528.97 77inTL OL 7810.77 --..-..-... -......--.- 20905.94 ........... ........... LiniL io ........... ........... Calibration Curve : y - (0.000000) + < 1725.954468)x <• (15.421S28)x-2 * (0.000000)x'3 R-squared : 0.991588 C-13DC1P6 Retention Time : 35.025 min Search Window: 17.00 sec, 1.00 % Reference Component: FBz (Find Closest Peak) Group Name : 601 Quantitation Will Be Done Using Response Factor = 2506.000000 Toluene Retention Time : 36.550 min Search Window: 18.00 sec, 1.00 % Reference Component: FBz (Find Closest Peak) / Group Name : 602 J Quantitation Will Be Done Using Response Factor = 9873.000000 T-13DClPe Retention Time : 37.382 min Search Window: 19.00 sec, 1.00 % Reference Component: FBz (Find Closest Peak) Group Name : 601 Calibrating Height versus Amount Using a 2nd Order Fit Curve Will Be Forced Through The Origin Amounts Will Not Be Scaled Prior To The Regression Weighting Factor For the Regression: l Calibration Levels: Level Name Amount Area Height ISTD Resp. ISTD Amt. * Replicates A C 0 c 1.0000 7.5000 15.0000 22.5000 in rvuvt yjo 1 .jo 118496.33 248285.41 380630.63 CC1MX. IWI 77892 ........... ........... 34939.15 ...------- ........... 55615.57 ........... ........... *19£T RO ........... ........... 13 \- Calibration Curve : y « (0.000000) + (1900.08C322). • (26.672886)x'2 * (0.000000)»'3 R-squared : 0.999498 TetclE L 0001868 Retention Time : 40.029 min Search Window: 22.00 sec, 1.00 Reference Component: o-Cl,F-Benzene (Find Closest Peak) Group Name : 601 Quantitation Will Be Done Using Response Factor = 3762.000000 ClBz J Retention Time : 45.607 min Search Window: 29.00 sec, i.oo % Reference Component: FBz (Find Closest Peak) Group Name : 602 Quantitation Will Be Done Using Response Factor = 7164.000000 .' EthylBz ; Retention Time : 46.169 min Search Window: 29.00 sec, 1.00 % Reference Component: o-Cl,F-Benzene (Find Closest Peak) Group Name : j Quantitation Will Be Done Using Response Factor = 5838.000000 m-Xylene / Retention Time : 46.837 min Search Window: 30.00 sec, 1.00 % Reference Component: o-Cl,F-Benzene (Find Closest Peak) Group Name : 8000 additional comp -' Quantitation Will Be Done Using Response Factor = 6057.000000 o-Cl,F-Benzene / Retention Time : 47.601 min Search Window: 31.00 sec, l.oo % Reference Component: o-Cl,F-Benzene (Find Closest Peak) Group Name : QC Quantitation Will Be Done Using Response Factor = 1349.00000< o-Xylene ^ Retention Time : 50.708 min Search Window: 28.00 sec, 1.00 % Reference Component: o-Cl,F-Benzene (Find Closest Peak) Group Name : 8000 additional comp J Quantitation Will Be Done Using Response Factor = 5088.000000 13DC1BZ J Retention Time : 62.268 min Search Window: 16.00 sec, 1.00 % Reference Component: o-Cl,F-Benzene (Find Closest Peak) ^ Group Name : 602 Quantitation Will Be Done Using Response Factor = 9934.000000 14DC1BZ J Retention Time : 62.881 min Search Window: 16.00 sec, l.oo I Reference Component: o-Cl,F-Benzene (Find Closest Peak) Group Name : 602 Quantitation Will Be Done Using Response Factor = 9960.000000_^y 12DC1BZ Retention Time : 64.812 min Search Window: 18.00 sec, l.oo t Reference Component: o-Cl,F-Benzene (Find Closest Peak) Group Name : 602 ^ Quantitation Will Be Done Using Response Factor = 8409.000000 L 0001863 TUT 004 1868 ********** SUMMARY REPORT ********* 0433 HALL LINEARITY CALCULATIONS FOR V3400A USING A RESTEK 502.2 COLUMN 105m* 0.53mn I.D., 3.Oum Df COLUMN. File Name SC11002. SC11003. SC11004. SC11005. SC11006. Averages XRSD File Name SC11002. SC11003. SC1 1004. SC11005. SC11006. Averages XRSD File Name SC11002. SC11003. SC11004. SC11005. SC11006. Averages XRSD File Name SC11002. SC11003. SC11004. SCI 1005. SC1 1006. Averages XRSD A B C D E SAMPLE NAME Ninber MIX MIX MIX MIX MIX SAMPLE NAME Ninber A MIX B MIX C MIX D MIX E MIX A B C D E A B C D E SAMPLE NAME Ninber MIX MIX MIX MIX MIX SAMPLE NAME Nunber MIX MIX MIX MIX MIX Date Of Injection 3/11/93 3/11/93 3/11/93 3/11/93 3/11/93 Date Of Injection 3/11/93 3/11/93 3/11/93 3/11/93 3/11/93 Date Of Injection 3/11/93 3/11/93 3/11/93 3/11/93 3/11/93 Date Of Injection 3/11/93 3/11/93 3/11/93 3/11/93 3/11/93 Ret. STD CON Tim* (PPB) Ret. STD CON Time (PPB) Height CLME Height CF CF .36 1.5000 9146.95 6.0979e3 .34 7.5000 56969.63 7.5959e3 .35 15.0000 162483.38 1.0832*4 .35 22.5000 207107.95 9.2047*3 .32 30.0000 340778.00 1.1359*4 8.34 15.3000 0.17 74.47 Ret. STD CON Time (PPB) 11.93 11.93 11.93 11.93 11.89 1.5000 7.5000 15.0000 22.5000 30.0000 11.92 15.3000 0.16 74.47 Ret. STD CON Time (PPB) 14.06 14.00 14.01 14.02 13.97 14.01 0.24 1 .5000 7.5000 15.0000 22.5000 30.0000 155297.19 9.0180e3 84.06 24.39 BrM* Height CF 2399.90 1.5999e3 27863.09 3.7150e3 85494.73 5.6996*3 104895.74 4.6620e3 177274.92 5.9091*3 79585.68 86.26 TCIFM* Height 15313.05 1 109092.84 1 292625.53 378156.66 582110.81 15.3000 275459.78 74.47 81.22 4.3171*3 40.64 CF .0208*4 .4545*4 1.9508*4 1.6806*4 1.9403*4 1.6094*4 24.10 Ret. STD CON Height CF Time (PPB) 7.05 1.5000 3797.29 2.5315e3 7.03 7.5000 24418.94 3.2558e3 7.05 15.0000 72850.52 4.8567*3 7.05 22.5000 93128.16 4.1390e3 7.03 30.0000 153871.89 5.1290*3 7.04 15.3000 69613.36 3.9824*3 0.16 74.47 85.10 27.33 vet Ret. STD CON Height CF Time (PPB) 9.12 1.5000 9999.06 6.6660e3 9.08 7.5000 61647.11 8.2196e3 9.09 15.0000 173474.39 1.1564e4 9.10 22.5000 220461.88 9.7983*3 9.06 30.0000 358807.00 1.1960*4 9.09 15.3000 164877.89 9.6418e3 0.23 74.47 83.28 23.18 ClEa Ret. STD CON Height CF Time (PPB) 12.52 12.47 12.48 12.49 12.45 1.5000 12345.12 8 7.5000 77675.88 1 15.0000 211455.73 22.5000 254202.69 30.0000 420294.88 .2300*3 .0356*4 1 .4097*4 1.1297*4 1.4009*4 12.48 15.3000 195194.86 1.1598*4 0.23 74.47 81.67 21.57 TCLTFEa Ret. STD CON Height CF Time (PPB) 16.53 16.45 16.47 16.47 16.43 16.47 0.24 1.0000 5142.36 5 7.5500 100427.60 1 15.1000 252108.47 22.6500 356342.28 30.2000 521869.47 15.3000 75.99 247178.03 82.79 . 1423*3 .3301*4 1.6695*4 1.5732*4 1.7280*4 1.3630*4 36.55 •JD CD O O File Name SC1 1002. SCI 1003. SCHOOL SAMPLE NAME Nunber /CWx3cIYMI B MIX r M1V Date Of Injection ,J0&/91YI 3/11/93 3/11 /95 Ret Tin 17! ^7 . STD CON e (PPB) 09 02m 11DCIE Height 1.0000 7.5000 1 ^t. nnnn i CH2C12 CF Ret. STD CON Height Time (PPB) 7840cDOJKI839e¥ID LftTOCn TZ 9 WL6Tm\ai Od9.Wn.5tt*Ol 17fo6.90 19.07 7.5000 283008.50 10 no is nnnn sk?Ann i 4 3H CF ........ H3J.2WYH Yd .7090*4 .7734e4 SC11005. D MIX 3/11/93 17.04 22.5000 556247.25 2 .4722 K 19.10 22.5000 759313.19 3.3747e4 r:^!SH^^ Averages XRSC * File Name SAMPLE NAME Nunber SC11002. A MIX SCI 1003. B MIX 17.03 15.2000 382177.25 2.3347e4 0.20 75.97 79.51 14.71 T-12DCIE Date Of Ret. STD CON Height CF Injection Tine (PPB) 3/11/93 20.28 1.0000 .23763.97 2.3763*4 3/11/93 20.21 7.5000226404.143.0187*4 19.09 15.5000 514167.03 3.6870*4 0.14 71.59 60.31 18.66 111DCtEa Ret. STD CON Height CF 1 H P D 1 Time (PPB) L UV^UJ 21.88 1.0000 18344.43 1.8344*4 21.80 7.5000 201568.77 2.6875*4 870 0434 SC11004. C NIX SC1 1005. D MIX SC11006. E MIX Averages XRSD File Name SAMPLE NAME Number SC11002. A MIX SC11003. B MIX SC11004. C MIX SC1 1005. D MIX SC11006. E MIX Averages XRSD File Name SAMPLE NAME Nuifcer SC11002. A MIX SC1 1003. B MIX SC11004. C MIX SC11005. D MIX SC11006. E MIX Averages XRSD File Name SAMPLE NAME N inter SC11002. A MIX SC11003. B MIX SC11 004. C MIX SC11005. D MIX SC11006. E MIX Averages XRSD File Name SAMPLE NAME Niwber SC11002. A MIX SC11003. B MIX .SC1 1004. C MIX SC11005. D MIX SC1 1006. E MIX Averages XRSD File Name SAMPLE NAME N utter SC11002. A MIX SC11003. B MIX SC11004. C MIX SC1 1005. D MIX SC1 1006. E MIX Averages XRSO File Name SAMPLE NAME Niwber SC11002. A MIX SC11003. B MIX SC1 1004. C MIX SC1 1005. D MIX SC1 1006. E MIX 3/11/93 3/11/93 3/11/93 Date Of Injection 3/11/93 3/11/93 3/11/93 3/11/93 3/11/93 Date Of Injection 3/11/93 3/11/93 3/11/93 3/11/93 3/11/93 Date Of Injection 3/11/93 3/11/93 3/11/93 3/11/93 3/11/93 Date Of Injection 3/11/93 3/11/93 3/11/93 3/11/93 3/11/93 Date Of Injection 3/11/93 3/11/93 3/11/93 3/11/93 3/11/93 Date Of Injection 3/11/93 3/11/93 3/11/93 3/11/93 3/11/93 20.22 15.0000 488286.66 3.2552*4 20.23 22.5000 720212.94 3.2009*4 20.21 30.0000 823804.75 2.7460*4 20.23 15.2000 456494.50 2.9194*4 0.14 75.97 73.12 12.43 C-12DCIE Ret. STD CON Height CF Time (PPB) 24.22 1.0000 17948.65 1.7948e4 24.14 7.5000 172878.22 2.3050e4 24.15 15.0000 429817.81 2.8654*4 24.17 22.5000 638994.69 2.8399e4 24.15 30.0000 824574.69 2.7485e4 24.16 15.2000 416842.81 2.5107e4 0.13 75.97 79.06 18.31 BrClMe Ret. STD CON Height CF Time (PPB) 25.52 100.0000 429816.88 4.2981e3 25.45 100.0000 417217.38 4.1721e3 25.47 100.0000 509033.84 5.0903*3 25.48 100.0000 481214.22 4.8121e3 25.46 100.0000 495485.16 4.9548e3 25.48 100.0000 466553.50 4.6655e3 0.10 0.00 8.73 8.73 ecu Ret. STD CON Height CF Time (PPB) 27.79 1.0000 26779.45 2.6779*4 27.73 7.5000 221552.16 2.9540*4 27.74 15.0000 527444.56 3.5162*4 27.75 22.5000 778785.75 3.4612*4 27.74 30.0000 930343.56 3.1011*4 27.75 15.2000 496981.09 3.1421*4 0.09 75.97 75.63 11.19 TCIE Ret. STD CON Height CF Time (PPB) 31.14 1.0000 22544.082.2544*4 31.09 7.5000245904.383.2787*4 31.10 15.0000522953.503.4863*4 31.10 22.5000 716323.31 3.1836*4 31.10 30.0000884211.882.9473*4 31.11 15.2000 478387.44 3.0301*4 0.06 75.97 72.80 15.67 BrOCIM* Ret. STD CON Height CF Tim* (PPB) 32.82 1.0000 14155.95 1.4155e4 32.79 7.5000 168091.09 2.2412e4 32.79 15.0000 363604.06 2.4240*4 32.79 22.5000 533252.63 2.3700*4 32.78 30.0000 763542.75 2.5451*4 32.79 15.2000 368529.28 2.1991*4 0.05 75.97 80.15 20.53 C-130CIP* Ret. STD CON Height CF Time (PPB) 35.11 1.0000 24104.91 2.4104*4 35.09 7.5000 181029.34 2.4137*4 35.09 15.0000 380476.03 2.5365*4 35.09 22.5000559108.192.4849*4 35.09 30.0000765045:562.5501*4 21.81 15.0000 443175.88 2.9545*4 21.83 22.5000 667927.63 2.9685*4 21.80 30.0000 844684.25 2.8156*4 21.82 15.2000435140.192.6521*4 0.14 75.97 77.10 17.77 CHC13 Ret. STD CON Height CF Time (PPB) 24.86 1.0000 27414.00 2.7414*4 24.79 7.5000 239840.11 3.1978*4 24.80 15.0000 602602.13 4.0173e4 24.82 22.5000 829109.19 3.6849e4 24.81 30.0000 918901.50 3.0630e4 24.82 15.2000 523573.38 3.3409*4 0.11 75.97 72.89 15.21 111TCIE1 Ret. STD CON Height CF Time (PPB) 26.65 1.0000 26520.63 2.6520*4 26.59 7.5000 184770.41 2.4636*4 26.59 15.0000 440199.69 2.9346*4 26.61 22.5000 654708.25 2.9098*4 26.59 30.0000 872737.19 2.9091*4 26.61 15.2000 435787.22 2.7738*4 0.11 75.97 78.61 7.51 12DClEa Ret. STD CON Height CF Time (PPB) 28.41 1.0000 17164.99 1.7164*4 28.35 7.5000 171264.39 2.2835e4 28.36 15.0000 377432.41 2.5162*4 28.36 22.5000 536681.94 2.3852*4 28.35 30.0000 753949.63 2.5131*4 28.37 15.2000 371298.66 2.2829*4 0.08 75.97 78.43 14.51 120ClPa Ret. STD CON Height CF Time (PPB) 31.87 1.0000 16037.44 1.6037*4 31.83 7.5000 173817.41 2.3175*4 31.84 15.0000 373656.69 2.4910*4 31.84 22.5000491558.412.1847*4 31.83 30.0000 765492.19 2.5516*4 31.84 15.2000 364112.44 2.2297*4 0.06 75.97 79.46 16.98 ZClEthylVO Ret. STD CON Height CF Time (PPB) 34.17 1.0000 1359.65 1.3596*3 34.09 5.0000 16449.71 3.2899*3 34.08 10.0000 47110.29 4.7110*3 34.08 15.0000 62957.81 4.1971*3 34.08 20.0000 94508.63 4.7254*3 34.10 10.2000 44477.22 3.6566e3 0.12 74.47 83.34 38.57 T-130CIP* Ret. STD CON Height CF / 0 0 0 1 8 7 Time (PPB) \_ I- y vv/iu i 37.50 1.0000 3274.82 3.2748*3 37.45 7.5000 123831.81 1.6510*4 37.45 15.0000263198.441.7546*4 37.44 22.5000 330098.88 1.4671*4 37.45 30.0000539054.941.7968*4 N CO •H o I- i- 4 A Average* XRSO File Name SAMPLE NAME Number SC11002. A MIX SC11003. B MIX SC11004. C MIX SC11005. D MIX SC11006. E MIX Averages XRSO File Name SAMPLE NAME Number SC11002. A MIX SC11003. B MIX SC11004. C MIX SC11005. D MIX SC11006. E MIX Averages XRSO File Name SAMPLE NAME Number SC11002. A MIX SC11003. B MIX SC11004. C MIX SC1 1005. D MIX SC11006. E MIX Averages XRSO File Name SAMPLE NAME Number SC11002. A MIX SC11003. B MIX SC11004. C MIX SC1 1005. D MIX SC1 1006. E MIX .Averages XRSD F i l e Name SAMPLE NAME Number SC1 1002. A MIX SC11003. B MIX SC11004. C MIX SC11005. D MIX SC11006. E MIX Averages XRSO File Name SAMPLE NAME Number SC11002. A MIX SC11003. B MIX SC11004. C MIX ' SCU 005. D MIX SC1 1006. E MIX Averages XRSD Date Of Injection 3/11/93 3/11/93 3/11/93 3/11/93 3/11/93 Date Of Injection 3/11/93 3/11/93 3/11/93 3/11/93 3/11/93 Date Of Injection 3/11/93 3/11/93 3/11/93 3/11/93 3/11/93 Date Of Injection 3/11/93 3/11/93 3/11/93 3/11/93 3/11/93 Date Of Injection 3/11/93 3/11/93 3/11/93 3/11/93 3/11/93 Date Of Injection 3/11/93 3/11/93 3/11/93 3/11/93 3/11/93 35.09 15.2000 381952.81 2.4791*4 0.04 75.97 77.07 2.66 112TCl£a Ret. STD CON Height CF Time (PPB) 38.29 1.0000 12481.29 1.2481*4 38.26 7.5000 162610.23 2.1681*4 38.26 15.0000 331990.75 2.2132*4 38.25 22.5000 401296.81 1.7835*4 38.26 30.0000 675969.13 2.2532*4 38.26 15.2000 316869.66 1.9332e4 0.04 75.97 79.33 22.06 DBrClM* Ret. STD CON Height CF Time (PPB) 41.25 1.0000 6495.31 6.4953e3 41.23 7.5000 86752.33 1.1566*4 41.22 15.0000 191105.80 1.2740*4 41.22 22.5000 273058.94 1.2135e4 41.23 30.0000 393659.16 1.3121*4 41.23 15.2000 190214.31 1.1212*4 0.04 75.97 80.04 24.10 o-C I, F -Benzene Ret. STD CON Height CF Time (PPB) 47.70 100.0000 218530.64 2.1853*3 47.69 100.0000 249540.30 2.4954*3 47.68 100.0000 250435.38 2.5043*3 47.69 100.0000 250891.95 2.5089*3 47.71 100.0000 248112.16 2.4811*3 47.70 100.0000 243502.08 2.4350e3 0.02 0.00 5.75 5.75 1122T*tClEe Ret. STD CON Height CF Time (PPB) 54.98 1.0000 7599.34 7.5993e3 54.94 7.5000 108817.80 1.4509*4 54.94 15.0000 221128.89 1.4741e4 54.95 22.5000 300217.91 1.3343*4 54.97 30.0000 426301.06 1.4210*4 54.96 15.2000 212813.00 1.2880*4 0.03 75.97 76.57 23.29 130CIBZ Ret. STD CON Height CF Time (PPB) 62.36 1.0000 10232.27 1.0232*4 62.33 7.5000 130027.92 1.7337*4 62.34 15.0000 254268.83 1.6951*4 62.35 22.5000 420493.09 1.8688*4 62.38 30.0000 607578.88 2.0252*4 62.35 15.2000 284520.19 1.6692*4 0.03 75.97 82.96 22.98 12DCIBZ Ret. STD CON Height CF Time (PPB) 64.89 1.0000 12930.41 1.2930*4 64.86 7.5000 131578.59 1.7543*4 64.88 15.0000 286022.72 1.9068*4 64.88 22.5000 411166.97 1.8274*4 64.91 30.0000 596207.19 1.9873*4 64.89 15.2000 287581.19 1.7538*4 0.03 75.97 79.73 15.50 37.46 15.2000 251891.78 1.3994*4 0.06 75.97 81.10 43.78 TetClE Ret. STD CON Height CF Time (PPB) 40.13 1.0000 21226.45 2.1226*4 40.10 7.5000 236332.06 3.1510*4 40.10 15.0000 495358.72 3.3023e4 40.10 22.5000 690469.38 3.0687e4 40.12 30.0000 908708.69 3.0290e4 40.11 15.2000 470419.06 2.9347e4 0.03 75.97 74.99 15.88 ClBz Ret. STD CON Height CF Time (PPB) 45.73 1.0000 6160.21 6.1602e3 45.70 7.5000 68340.27 9.1120e3 45.69 15.0000 145023.06 9.6682e3 45.70 22.5000 225280.31 1.0012*4 45.71 30.0000 287762.63 9.5920e3 45.71 15.2000 146513.30 8.9089e3 0.04 75.97 77.80 17.62 CHBr3 Ret. STD CON Height CF Time (PPB) 53.52 1.0000 2457.38 2.4573*3 53.48 7.5000 41801.03 5.5734e3 53.47 15.0000 96899.52 6.4599e3 53.48 22.5000 137679.98 6.1191e3 53.49 30.0000 200180.30 6.6726e3 53.49 15.2000 95803.64 5.4565e3 0.04 75.97 81.32 31.66 123TriClPropane Ret. STO CON Height CF Time (PPB) 57.68 1.0000 5263.68 5.2636*3 55.98 7.5000 75532.08 1.0070*4 55.97 15.0000 153380.25 1.0225*4 55.99 22.5000 213119.44 9.4719*3 56.01 30.0000 300088.91 1.0002*4 56.33 15.2000 149476.88 9.0069*3 1.35 75.97 77.02 23.45 14DCIBZ Ret. STD CON Height CF Time (PPB) 62.97 1.0000 11963.81 1.1963e4 62.94 7.5000 142211.52 1.8961*4 62.95 15.0000 297688.47 1.9845*4 62.96 22.5000 450424.16 2.0018*4 62.99 30.0000 647703.81 2.1590*4 62.96 15.2000 309998.34 1.8476*4 0.03 75.97 80.79 20.36 TUT OO4 I n p. n 1 R 7 ' ********** SUMMARY REPORT ********* 0436 PID LINEARITY CALCULATIONS FOR V3400A USING A RESTEK 502.2 COLUMN 105m* 0.53mm I.D., 3.0um Df COLUMN. Air VCl File Name SAMPLE NAME Nuifcer TC11002. A MIX TC11003. B NIX TC11004. C MIX TC11005. D MIX TC11006. E MIX Averages Midi/ File Name SAMPLE NAME Nurber TC11002. A MIX TC11003. B MIX TC11004. C MIX TC11005. D MIX TC11006. E MIX Averages XRSO File Name SAMPLE NAME Nuifeer TC11002. A MIX TC11003. B MIX TC11004. C MIX TC11005. D MIX TC11006. E MIX Averages XRSD File Name SAMPLE NAME Ninber TC11002. A MIX TC11003. B MIX TC11004. C MIX TC11005. D MIX TC11006. E MIX Averages XRSD File Name SAMPLE NAME Nu»ber TC11002. A MIX TC11003. B MIX TC11004. C MIX TC11005. D MIX TC11006. E MIX Averages XRSD « File Name SAMPLE NAME Nuifcer TC11002. A MIX TC11003. B MIX Date Of Injection 3/11/93 3/11/93 3/11/93 3/11/93 3/11/93 Date Of Injection 3/11/93 3/11/93 3/11/93 3/11/93 3/11/93 Date Of Injection 3/11/93 3/11/93 3/11/93 3/11/93 3/11/93 Date Of Injection 3/11/93 3/11/93 3/11/93 3/11/93 3/11/93 Date Of Injection 3/11/93 3/11/93 3/11/93 3/11/93 3/11/93 Date Of Injection 3/11/93 3/11/93 Ret. STD CON Height CF Time (PPB) 11DCIE Ret. STD CON Height CF Time (PPB) 17.01 1.0000 3045.34 3.0453e3 16.95 7.5000 22105.58 2.9474e3 16.96 15.0000 48436.09 3.2290e3 16.97 22.5000 77564.56 3.4473e3 16.93 30.0000 104795.52 3.4931e3 16.96 15.2000 51189.42 3.2324e3 0.17 75.97 80.19 7.43 C-12DCIE Ret. STD CON Height CF Time (PPB) 24.14 1.0000 3767.23 3.7672e3 24.07 7.5000 33330.04 4.4440e3 24.08 15.0000 79164.63 5.2776*3 24.10 22.5000 118690.73 5.2751e3 24.08 30.0000 164505.09 5.4835e3 24.09 15.2000 79891.55 4.8495e3 0.11 75.97 80.70 14.95 FBZ Ret. STD CON Height CF Tine (PPB) 29.36 100.0000 186916.70 1.8691e3 29.32 100.0000 200310.642J]fl3Je3 29.33 100.0000 209265. BO -0926*3^, 29.33 100.0000 212601.94~?.l260e3 29.32 100.0000 212234.02 2.1223*3 29.33 100.0000 204265.84 2.0426*3 0.05 0.00 5.33 5.33 2ClEthylVO Ret. STD CON Height CF Time (PPB) 34.03 1.0000 1004.47 1.0044*3 34.01 5.0000 7810.77 1.5621*3 34.01 10.0000 20905.94 2.0905*3 34.01 15.0000 27944.84 1.8629*3 34.01 20.0000 41034.49 2.0517*3 34.01 10.2000 19740.10 1.7143*3 0.02 74.47 80.72 26.16 Toluene Ret. STD CON Height CF Time (PPB) 36.56 1.0000 8025.10 8.0251e3 36.55 7.5000 70678.99 9.*238e3 Ret. STO CON Height CF Time (PPB) 9.00 1.5000 821.09 547.3961 8.98 7.5000 4669.67 622.6231 9.00 15.0000 10917.83 727.8556 9.01 22.5000 15779.51 701.3115 8.97 30.0000 22321.58 744.0526 8.99 15.3000 10901.94 668.6478 0.18 74.47 78.73 12.31 T-12DCIE Ret. STD CON Height CF Time (PPB) 20.21 1.0000 9455.26 9.4552*3 20.15 7.5000 90709.31 1.2094*4 20.16 15.0000 193174.39 1.2878*4 20.17 22.5000 304052.16 1.3513*4 20.14 30.0000 430248.53 1.4341*4 20.16 15.2000 205527.92 1.2456*4 0.13 75.97 81.41 15.01 BZ Ret. STD CON Height CF Time (PPB) 28.43 1.0000 10859.64 1.0859*4 28.38 7.5000 74364.31 9.9152e3 28.39 15.0000 154806.39 1.0320*4 28.40 22.5000 241699.34 1.0742*4 28.39 30.0000 344573.31 1.1485*4 28.40 15.2000 165260.59 1.0664*4 0.07 75.97 80.17 5.54 TCIE Ret. STD CON Height CF Time (PPB) 31.06 1.0000 4318.56 4.3185*3 31.03 7.5000 41300.73 5.5067*3 31.03 15.0000 98611.63 6.5741*3 31.03 22.5000 155185.02 6.8971*3 31.03 30.0000 219813.63 7.3271*3 31.03 15.2000 103845.91 6.1247*3 0.04 75.97 83.30 19.81 C-13DClPe Ret. STD CON Height CF Tine (PPB) 35.04 1.0000 2723.17 2.7231e3 35.02 7.5000 16677.63 2.2236*3 35.03 15.0000 35252.30 2.3501e3 35.03 22.5000 56635.70 2.5171*3 35.02 30.0000 81506.79 2.7168*3 35.03 15.2000 38559.12 2.5062e3 0.02 75.97 81.45. 8.83 >. T-130CIP* Ret. STD CON Height CF Time (PPB) 37.39 1.0000 778.92 778.9152 37.38 7.5000 16005.56 2.1340e3 MN 03 I- i r\ r\ n 1 C TC11004. C NIX TC11005. 0 NIX TC11006. E NIX Average* XRSD File Name SAMPLE NAME Number TC11002. A MIX TC11003. B MIX TC11004. C NIX TC11005. D MIX TC11006. E MIX Averages XRSD File Name SAMPLE NAME Number TC11002. A NIX TC11003. B NIX TC11004. C NIX TC11005. D NIX TC11006. E NIX Averages XRSD File Name SAMPLE NAME Number TC11002. A NIX TC11003. B NIX TC11004. C NIX C11005. D NIX -TC11006. E NIX Averages XRSO File Name SAMPLE NAME Number TC11002. A NIX TC11003. B MIX TC11004. C MIX TC11005. D MIX TC11006. E NIX Averages XRSO File Name SAMPLE NAME Number TC11002. A NIX TC11003. 8 NIX TC11004. C NIX TC11005. D MIX TC11006. E MIX Averages XRSD 3/11/93 3/11/93 3/11/93 Date Of Injection 3/11/93 3/11/93 3/11/93 3/11/93 3/11/93 Date Of Injection 3/11/93 3/11/93 3/11/93 3/11/93 3/11/93 Date Of Injection 3/11/93 3/11/93 3/11/93 3/11/93 3/11/93 Date Of Injection 3/11/93 3/11/93 3/11/93 3/11/93 3/11/93 Date Of Injection 3/11/93 3/11/93 3/11/93 3/11/93 3/11/93 36.55 15.0000 150242.22 1.0016*4 36.55 22.5000 236442.02 1.0508*4 36.55 30.0000 341809.44 1.1393*4 36.55 15.2000 161439.55 9.8734*3 0.02 75.97 81.98 12.76 TetClE Ret. STD CON Height CF Time (PPB) 40.04 1.0000 2789.51 2.7895*3 40.03 7.5000 25166.09 3.3554*3 40.03 15.0000 59665.95 3.9777e3 40.02 22.5000 94940.77 4.2195*3 40.04 30.0000 133962.47 4.4654*3 40.03 15.2000 63304.96 3.7615*3 0.02 75.97 83.30 18.14 EthylBz Ret. STD CON Height CF Time (PPB) 46.19 1.0000 4683.53 4.6835*3 46.18 7.5000 39911.34 5.3215*3 46.17 15.0000 91235.54 6.0823*3 46.18 22.5000 141866.73 6.3051*3 46.20 30.0000 203870.11 6.7956*3 46.18 15.2000 96313.45 5.8376*3 0.02 75.97 82.49 14.32 o- C 1, F- Benzene Ret. STD CON Height CF Time (PPB) 47.62 100.0000 116917.85 1.1691*3 47.61 100.0000 131701.67 1.3l70e3 47.60 100.0000 1 34927. 9<T!3492»-x 47.62 100.0000 134189.28 r»H*X 47.63 100.0000 134652.47 1.3465*3 47.62 100.0000 130477.84 1.3047*3 0.02 0.00 5.89 5.89 130CIBI Ret. STD CON Height CF Time (PPB) 62.28 1.0000 6954.18 6.9541*3 62.26 7.5000 73354.26 9.7805*3 62.27 15.0000 156241.63 1.0416*4 62.28 22.5000 239977.52 1.0665*4 62.31 30.0000 355665.00 1.1855*4 62.28 15.2000 166438.52 9.9344*3 0.03 75.97 82.50 18.40 120CIBZ Ret. STD CON Height CF Time (PPB) 64.82 1.0000 7019.45 7.0194*3 64.80 7.5000 60220.91 8.0294*3 64.81 15.0000 131783.09 8.7855*3 64.82 22.5000 194436.27 8.6416*3 64.85 30.0000 287134.03 9.5711*3 64.82 15.2000 136118.75 8.4094*3 0.03 75.97 81.02 11.32 37.38 15.0000 34939.13 2.3292*3 37.38 22.5000 55615.57 2.4718*3 37.38 30.0000 81243.89 2.7081*3 37.38 15.2000 37716.61 2.0844*3 0.01 75.97 84.45 36.43 ClBz Ret. STD CON Height CF Time (PPB) 45.62 1.0000 5714.78 5.7147*3 45.62 7.5000 51592.15 6.8789*3 45.61 15.0000 111340.77 7.4227*3 45.62 22.5000 170220.03 7.5653*3 45.63 30.0000 247082.64 8.2360*3 45.62 15.2000 117190.08 7.1635*3 0.02 75.97 81.46 13.17 m-Xylen* Ret. STD CON Height CF Time (PPB) 46.85 1.0000 4871.77 4.871 7e3 46.85 7.5000 40650.30 5.4200*3 46.84 15.0000 94624.71 6.3083*3 46.65 22.5000 147656.02 6.5624*3 46.87 30.0000 213658.45 7.1219*3 46.85 15.2000 100292.25 6.0569*3 0.02 75.97 83.11 14.91 o-Xylene Ret. STD CON Height CF Time (PPB) 50.73 1.0000 4204.21 4.2042*3 50.72 7.5000 34419.75 4.5893*3 50.71 15.0000 80090.87 5.3393*3 50.73 22.5000 122719.75 5.4542*3 50.74 30.0000 175636.78 5.8545*3 50.73 15.2000 83414.27 5.0883*3 0.03 75.97 82.05 13.24 140CIBZ Ret. STD CON Height CF Time (PPB) 62.89 1.0000 6932.00 6.9319*3 62.87 7.5000 72826.47 9.7101*3 62.88 15.0000 157160.53 1.0477*4 62.89 22.5000 241699.25 1.0742*4 62.92 30.0000 358086.84 1.1936*4 62.89 15.2000 167341.02 9.9595*3 0.03 75.97 82.74 18.80 TUT OO4 1873 L 000187, 0438 Software Version: 3.2 <16C20> Sample Name Sample Number Operator Instrument AutoSampler Rack/Vial 1 PPB 8010/8020 STD A MIX V3400A/SALLY NONE 0/0 Time Study Channel B 3/12/93 8:44 AM LINEARITY A/D mV Range : 1000 Interface Serial # : 0159572256 Data Acquisition Time: 3/11/93 5:15 PM Delay Time End Time Sampling Rate Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount Noise Threshold Multiplier 0.00 70.00 2.0000 min. min. pts/sec n:\v3400s\TC11002.raw n: \v3400s\TCH002.rst N:\V3400S\8000SUE.ins N:\V3400S\PID.prc N:\V3400S\LINPTCll.smp n:\v3400s\scll.seq 5 ml 1.0000 Area Reject : 100.00 Dilution Factor : 1.00 10 1.0000 Area Threshold : 49 Bunch Factor: 2 Divisor : 1.0000 Adder : 0.0000 Instrument Conditions: Total Number of Peaks Detected: 59 ITAS-KNOXVILLE V3400A RTX 502.2 105m*0.53mm ID,3.00um df PID DETECTOR-FBZ AND O-C1FBZ ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. ALL OTHER ANALYTES ARE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLUME OF 5.0 ML. Peak * 1 2 3 5 6 7 8 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 Ret Time R1 twin] 5.679 6.635 7.088 8.710 9.001 9.381 10.201 13.829 15.089 15.679 15.949 16.601 17.006 19.074 19.782 20.206 21.488 22.229 23.464 24.135 25.481 28.429 ' DIFF. X 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.3 0.0 0.0 0.2 0.0 0.0 0.0 0.2 0.0 0.1 BL Component Name BB BB BBW W VCl W VB BB BB BV VB BV VB 110CIE BV W W T-120CIE W WW W C-12DCIE W VB BZ Arta/ Amount 363.4000 2493.6582 4064.0723 6748.5703 9368.2295 9416.7940 8647.6963 74696.7266 29881.4492 30549.8047 31454.2402 29568.7559 27952.1250 88234.3594 1.3642e5 58490.9375 1.4859e5 36077.0781 45664.2734 29165.S625 61432.2852 97387.9375 Area [uV*sec] 4088.25 473.50 652.75 983.31 14052.34 19936.03 5019.53 3002.50 63739.50 10727.80 7760.20 3135.34 27952.13 5718.78 4721.14 58490.94 5555.97 943.56 7541.28 29165.56 9260.31 97387.94 Heigh [UV] 1034 62 87 79 821 1246 317 122 6698 1069 751 322 3045 612 327 9455 353 98 622 3767 567 10859 t I .58 .85 .92 .76 .09 .J6 .74 .41 .19 .(.0 5J .92 .J4 .83 .20 .26 .52 .53 .14 .23 .87 .64 NST. (is: 11 0 0 0 1 2 0 0 2 0 0 0 1 0 0 1 0 0 0 1 0 1 Ant Ca X) Rai .25 .19 .16 .15 .50 .12 .58 .04 .13 .35 .25 .11 .00 .07 .04 .00 .04 .03 .17 .00 .15 .00 I. Component SAMPLE CON nge Name (PPB) 11.25 0.19 0.16 0.15 VCl 1.50 2.12 0.58 0.04 2.13 0.35 0.25 0.11 110CIE 1.00 0.07 0.04 T-120CIE 1.00 0.04 0.03 0.17 C-12DCIE 1.00 0.15 Bz 1 .00 DO O Q Hn i- ^-0001873 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 29.356 31 .055 31.335 34.027 34.703 35.037 35.542 36.058 36.564 37.392 39.310 40.041 45.624 46.186 46.853 47.619 50.730 52.788 57.301 57.583 60.194 61.262 62.277 62.889 64.067 64.816 65.440 65.939 66.467 67.543 67.965 68.643 68.883 69.098 69.523 0.1 0.1 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 8V VE EV W W W W W W W W VB BV W W W W VB BV VB BV W W VB BB BB BB BB BV VB BB 6V VB BV VB FBz TCIE 2ClEthylVO C-130ClPe Toluene T-130ClPe TetClE ClBz EthylBz m-Xylene o-Cl.F-Ben o-Xylene 130CIBZ 140CIBZ 120CIBZ 15007.6699 34298.9688 1.6846e5 9519.6563 50061.7227 20254.4844 50058.0820 1.4835e5 67171.5938 9381.3750 31527.0059 27918.7188 67268.2500 57261.5000 61086.2813 14032.3750 54552.3125 1.3277e5 1.2590e5 62539.7227 72711.2656 1.0852eS 49565.8281 46985.4063 94500.0547 45195.0000 68348.3750 78629.4688 39520.2891 9.5089e5 1.2267e5 49856.1133 54438.6523 35867.3711 1.03Q3e5 1500767.00 34298.97 12168.00 9519.66 2534.30 20254.48 2641.11 8785.22 67171.59 9381.38 4816.00 27918.72 67268.25 57261.50 61086.28 1403237.63 54552.31 12237.38 4916.00 52990.00 12697.03 9694.72 49565.83 46985.41 32951.00 45195.00 738.50 550.00 29759.00 1092.50 1960.52 585.70 2200.29 376.12 4715.38 186916.70 4318.56 311.92 1004.47 137.86 2723.17 143.68 475.22 8025.10 778.92 426.12 2789.51 5714.78 4683.53 4871.77 116917.85 4204.21 387.49 271.53 5892.28 1214.36 621.21 6954.18 6932.00 2447.59 7019.45 75.85 49.10 5285.68 8.07 112.18 82.46 283.71 73.61 321.25 100.00 1.00 0.07 1.00 0.05 1.00 0.05 0.06 1.00 1.00 0.15 1.00 1.00 1.00 1.00 100.00 1.00 0.09 0.04 0.85 0.18 0.09 1.00 1.00 0.35 1.00 0.01 0.01 0.75 0.00 0.02 0.01 0.04 0.01 0.05 FBz TCIE 2ClEthylVO C-130ClPe Toluene T-130ClPe TetClE ClBz EthylBz m-Xylene o-Cl,F-Ben o-Xylene 130CIBZ 140CIBZ 12DCIBZ 100 0 1 0 1 0 0 1 1 0 1 1 1 1 100 1 0 0 0 0 0 1 1 0 1 0 0 0 0 0 0 0 0 0 00 •oo 0439 .07 V q j y .00 .05 .00 .05 .06 .00 .00 .15 .00 .00 .00 .00 .00 .00 .09 .04 .85 .18 .09 .00 .00 .35 .00 .01 .01 .75 .00 .02 .01 .04 .01 .05 1.4 4.0948*6 4033181.50424799.47 239.18 239.18 Missing Component Report Component Expected Retention (Sample File) Air 5.000 Y. NOT DETECTED ON PRIMARY RUN: Z. NOT DETECTED ON HALL TUT 004 1875 U000187G V3400A PID Saepl* NMM : 1 Pfl 8010/8020 STD FUeNaaw : n:\v3400s\TC11002.r«t* Method : SOOOSUe.in* Start Tin* : 0.00 «fn End Tim : 70.00 Bin Scale Factor: 0 . Plot Offsat: 4 i»v Saaple *: A NIX Paga 1 of 1 Data : 3/12/93 8:U AM Tia» of Injection: 3/11/93 5:15 PM Low Point : 4.00 «V High Point : 39.00 mV Plot Scale: 35 nV 0440 Response [nnV] 0 O l — —————— "- ro ~ 0 _ — n — ^ - o~ en ~ 0 _ AIR VCL 11DCLE T-120CLE - C-120CLE BZ FBZ TCLE 2CLETHYLVO- TOLUENE T-13DCLPE - TETCLE n R7 fi$t& = 0-CL.F-BE - 0-XYLEME - 12DCLBZ - — -•• NJ NJ L^ :J O cn O LP O i i i I I i i i i ! ! i i i i i i i i i i ! ! ; ! • ; - —— 5.68 § 20* 2 13 =£Mil<L_ 17.01 J-23.46 -^25.48 i 4 3, 34 31 "6 ~ — -3A.03 ^-34.70 -.r fw ^liS86 >— 3O.UO ix CA -^ —— 37.39 ^39'31 ^,0.04 "|r ——— 50.73 >-52.79 ^—^T TQ e^ co !-..» L0001877 J — 61-26 ^V"'07 rt/i n? ^^ • o j • y** ^ ^ ^ •> -jc6/?.^ TUT OO4 1876 Software Version: 3.2 <16C20> 7.5PPB 8010/8020 STD B MIX SampletN Samples Number Operator Instrument .- AutoSampler Rack/Vial V3400A/SALLY NONE 0/0 Time Study Channel : B : 3/12/93 8:49 AM : LINEARITY A/D mV Range : 1000 Interface Serial # : 0159572256 Data Acquisition Time: 3/11/93 6:30 PM Delay Time End Time Sampling Rate Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount Noise Threshold Multiplier 0.00 mm. 70.00 min. 2.0000 pts/sec n:\v3400s\TC11003.raw n:\v3400s\TCH003.rst N:\V3400S\8000SUE.ins N:\V3400S\PID.prc N:\V3400S\LINPTC11.smp n:\v3400s\scll.seq 5 ml 1.0000 Area Reject : 100.00 Dilution Factor : 1.00 10 1.0000 Area Threshold : 49 Bunch Factor: 2 Divisor : 1.0000 Adder : 0.0000 Instrument Conditions: Total Number of Peaks Detected: 72 ITAS-KNOXVILLE V3400A RTX 502.2 105m*0.53mm ID,3.00um df PID DETECTOR-FBZ AND 0-ClFBz ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. ALL OTHER ANALYTES ARE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLUME OF 5.O ML. Peak # 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 .16 17 18 19 20 21 22 Ret Time RT D1FF. [min] X 5.670 7.071 7.695 8.304 8.981 9.374 10.158 11.788 12.458 13.990 15.033 15.625 15.890 16.538 16.946 18.821 19.013 19.722 20.145 21.421 21.783 23.398 0.0 0.0 0.0 0.0 •0.2 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 -0.1 0.0 0.0 0.0 -0.1 0.0 0.0 0.0 BL Component Name BB BB BB BV W VCl W VB BV VB BB BB BV W W VB 110CIE BV W W VB T-12DCIE BV W W Area/ Amount 527.7333 3607.0889 3235.3994 7604.4805 10133.9209 10766.8418 9602.4541 8477.7461 5691.9492 1.0036e5 28526.2461 31457.8340 32298.3652 36631.3828 25183.8789 1.3177e5 80138.7266 1.3222e5 68158.3281 1.2476*5 2.8145e5 36804.4922 Area CuV*secJ 5937.00 717.75 284.00 704.91 76004.41 29026.78 6035.89 7196.80 825.41 4507.25 57522.00 10677.38 7474.31 5898.19 188879.09 1397.94 10389.59 4679.48 511187.47 3929.00 7352.50 6012.00 Height INST. Amt Cal . Component SAMPLE CON CuVJ (ISX) Range Name (PPB) N 1445 108 48 50 4669 15S8 344 464 79 136 6025 1033 704 490 22105 100 1225 334 90709 297 247 615 .43 .92 .05 .71. .67 .21 .08 .69 58 .'6 ,<n .65 . »fc :« .31 .83 .63 .31 .75 .00 .38 11.25 0.20 0.09 0.09 7.50 2.70 0.63 0.85 0.15 0.05 2.02 0.34 0.23 0.16 7.50 0.01 0.13 0.04 7.50 0.03 0.03 0.16 11 0 0 0 VCl 7 2 0 .25 .20 .09 .09 .50 .70 .63 0.85 0 0 2 0 0 0 110CIE 7 0 0 0 T-120CIE 7 0 0 0 .15 .05 .02 .34 .23 .16 .50 .01 .13 .04 .50 .03 .03 .16 r^ CD •H •3-oo H •3 !— L0001878 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 '39 '40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 24.070 24.786 25.417 26.579 27.735 < 29.381 29.318 30.525 31.029 31.832 32.783 33.240 34.007 34.820 35.019 36.058 36.551 37.379 38.175 39.293 40.029 41.171 45.622 46.183 46.851 47.612 48.501 50.718 52.774 53.393 54.919 55.365 55.942 56.590 57.287 57.599 60.172 61.238 62.261 62.872 64.044 64.800 65.400 66.145 66.448 66.983 67.943 68.907 69.083 69.325 -0.1 0.0 0.0 0.0 0.0 -0.0 -0.0 0.0 -0.0 ' 0.0 0.0 0.0 -0.0 0.0 •0.0 0.0 0.0 -0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 -0.0 -0.0 0.0 -0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 VB BVwww VB BE EV VE EVwww www w w w w VB BV ww w VE EV w w w w w w w w VB BB BV w VB BB SB BB BB BB SB BB BV VB BB C-12DCIE Bz FBZ TCIE 2ClEthylVO C-130CIP* Toluene T-13DCIP* TetClE ClBz EthylBz m-Xylen* o-Cl,F-Ben o-Xylene 13DCIBZ 140CIBZ 12DCIBZ 32275.9336 53466*9102 55009.5273 2.8768*5 1.9896t5 82542.3594 16249.2315 72301.2891 41373.8789 1.4008*5 20914.0254 13965.5186 11041.2842 32262.3652 15929.0752 1.8220*5 73270.9922 15799.5117 15504.2979 49143.4141 32279.7754 41958.2891 74647.0313 62288.5742 65701.3125 15656.1387 46373.0938 55949.7852 1.1005*5 1.1672*5 66436.8203 49016.4766 68578.8594 78419.1172 85444.9844 1.0119*5 85461 .6094 77078.5781 64952.3320 60117.0898 94203.3672 49475.2656 72302.5859 38420.9766 39090.2266 81422.6250 1 .4737*5 57207.4727 38799.7344 35472.0469 242069.50 3347;7S- 8141.25" 5436.23 4561.55 619067.69 1624923.13 2306.00 310304.13 9219.00 5406.59 4641.34 55206.42 3661.38 119468.06 10515.25 549532.44 118496.33 5688.50 4332.03 242098.31 2594.72 559852.75 467164.31 492759.81 1565613.88 8791.00 419623.38 12066.34 6958.59 2238.45 953.55 2100.45 1413.45 3794.36 2787.84 8970.50 2751.28 487142.50 450878.19 37533.00 371064.50 1258.00 271.00 16599.50 749.50 1645.50 1558.79 402.96 173.50 33330.04 r 235.88 *: 557.63 V.'- 205.21 . 248.98 74364.31 200310.64 137.74 41300.73 284.20 259.67 333.83 7810.77 309.05 16677.63 463.14 70678.99 16005.56 285.78 245.90 25166.09 172.50 51592.15 39911.34 40650.30 131701.67 221.64 34419.75 460.94 250.63 141.65 81.79 128.77 125.34 308.81 191.59 729.95 248.23 73354.26 72826.47 2796.72 60220.91 122.13 49.51 2980.78 64.61 78.37 191.27 72.90 34.33 7.50 0.06 0.15 0.02 0.02 7.50 100.00 0.03 7.50 0.07 0.26 0.33 5.00 0.11 7.50 0.06 7.50 7.50 0.37 0.09 7.50 0.06 7.50 7.50 7.50 100.00 0.19 7.50 0.11 0.06 0.03 0.02 0.03 0.02 0.04 0.03 0.11 0.04 7.50 7.50 0.40 7.50 0.02 0.01 0.43 0.01 0.01 0.03 0.01 0.01 C-120CIE Bz FBz TCIE 2ClEthylVO C-130ClPe Toluene T-13DClPe TetClE ClBz EthylBz m-Xylene o-Cl,F-Ben o-Xylene 130CIBZ 140CIBZ 12DCIBZ 7 0 0 0 0 7 100 0 7 0 0 0 5 0 7 0 7 7 0 0 7 0 7 7 7 100 0 7 0 0 0 0 0 0 0 0 0 0 7 7 0 7 0 0 0 0 0 0 0 0 .50 .06 .15 .02 .02 .50 .00 .03 .50 .07 .26 .33 .00 .11 .50 .06 .50 .50 .37 .09 .50 .06 .50 .50 .50 .00 .19 .50 .11 .06 .03 .02 .03 .02 .04 .03 .11 .04 .50 .50 .40 .50 .02 .01 .43 .01 .01 .03 .01 .01 -0.4 Missing Component Report Component Air 4.5915*6 9824774.00 1.13e6 354.85 Expected Retention (Sample File) 5.000 354.85 Y. NOT DETECTED ON PRIMARY RUN: Z. NOT DETECTED ON HALL TUT OO4 1878 (V001873 V3400A Saaple MM* : 7.5PM 8010/8020 STD FiiettaM : n:\v3400s\TC11003.rm Method : SOOOSUE.ins Start Tim : 0.00 nin End Tim : 70.00 win Scale Factor: 0 Plot Offset: 4 mv Staple it • MIX Date : 3/12/93 8:49 AN Tine of Injection: 3/11/93 6:30 Ptt Low Point : 4.00 MV High Point : 39.00 mv Plot Scale: 35 rtV Response [mV] o- -^ -' NJ ro L^ ^ O CJi O LJi O _~ ! • ! ! I 1 1 1 1 i 1 1 i i i ' • • ' ' o _ ro_ O J (0 v U 15 -5.67 VCL H-13.99 11DCLE T-12DCLE - C-12DCLE - BZ FBZ 23.40 26.58 27.74 0 ° HTCLE JZCLETHYLVO- —IC-130CLPE - TOLUENE T-130CLPE - 31.83 7^36.06 TETCLE -^38.18 ^39.29 -\ -41.17 CD 0~D O-CL.F-BE - 0-XYLEME -48.50 -15.03 12DCLBZ -16.95 -34.01 -35.02 37.38 -40.03 TUT 004 1879 LGCOISSO Software Version: 3.2 <16C20> Sample Name Sample Number Operator ^.nstrument ^ 'AutoSampler Rack/Vial 15 FPB 8010/8020 STD C MIX V3400A/SALLY NONE 0/0 Time Study Channel : B : 3/12/93 8:28 AM : LINEARITY A/D mV Range : 1000 Interface Serial Delay Time End Time Sampling Rate Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount Noise Threshold Multiplier # : 0159572256 0.00 min. 70.00 min. 2.0000 pts/sec Data Acquisition Time: 3/11/93 7:46 PM n:\v3400s\TC11004.raw n:\v3400s\TC11004.rst N:\V3400S\8000SUE.ins N:\V3400S\PID.prc N:\V3400S\LINPTCll.smp n:\v3400s\scll.seq 5 ml 1.0000 Area Reject : 100.00 Dilution Factor : 1.00 10 1.0000 Area Threshold : 49 Bunch Factor: 2 Divisor : 1.0000 Adder : 0.0000 Instrument Conditions: Total Number of Peaks Detected: 77 ITAS-KNOXVILLE V3400A RTX 502.2 105m*0.53mm ID,3.00um df PID DETECTOR-FBZ AND O-ClFBz ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. ALL OTHER ANALYTES ARE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLUME OF 5.0 ML. Peak # 1 2 3 t. 5 6 8 9 10 11 12 13H 15 16 17 ' 18 19 20 21 22 23 Ret Time RT OIFF. [min] X 5.673 7.067 7.715 8.317 8.997 10.139 11.802 12.463 14.001 15.042 15.640 15.900 16.555 16.963 19.028 19.756 20.159 21.007 21.434 21.800 22.443 23.413 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 -0.1 0.0 0.0 -0.1 0.0 0.0 0.0 0.0 0.0 BL Component Name B8 BB BB BV W VCl VBW VB BB BB BVWW VB 11DCIE BVW W T-12DCIE W WWWW Are*/ Amount 633.5111 3889.6548 5483.3325 14906.6182 13992.9356 12340.2773 11118.8789 10098.6260 95430.9688 32997.4961 40213.3555 39098.9180 52519.2578 27053.9629 1.0293e5 1.6087e5 74073.1797 1.0761e5 1.3645e5 1.8326*5 76596.3438 44564.4922 Area tuVMec] Height INST. Amt Cal. Component SAMPLE CON CuV] (ISX) Range Name (PPB) 7127.00 600. 1205. 3182. 209894. 7610. 16893. 3354. 7552. 57935. 11317. 7390. 8897. 405809. 19494. 4481. 1111097. 925. 3654. 8035. 2443. 10276. 00 50 14 03 38 98 33 00 50 77 22 09 44 59 32 75 39 31 19 28 81 1695 102 K6 141 10917 409 1009 220 296 6100 1054 .92 .50 .09 .85 .83 .79 .52 .71 .39 .37 .10 707.92 634 48436 2197 323 193174 99 310 508 144 1043 .48 .09 .18 .18 .39 .76 .69 .68 .33 .41 11.25 0.15 0.22 0.21 15.00 0.62 1.52 0.33 0.08 1.76 0.28 0.19 0.17 15.00 0.19 0.03 15.00 0.01 0.03 0.04 0.03 0.23 11 0 0 0 VCl 15 0 1 0 0 1 0 0 0 110CIE 15 0 0 T-12DCIE 15 0 0 0 0 0 .25 .15 .22 .21 .00 .62 .52 .33 .08 .76 .28 .19 .17 .00 .19 .03 •00 I r , .01 «- V I .03 .04 .03 .23 CD CO too h- 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 '40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 24.084 24.799 25.436 26.591 27.739 28.392 29.325 30.529 31.033 31.825 32.785 33.247 34.012 34.825 35.025 36.053 36.550 36.944 37.382 37.690 38.163 39.298 40.029 41.164 45.607 46.169 46.837 47.601 48.500 50.708 52.776 53.389 53.708 54.926 55.952 56.586 57.285 57.688 60.184 61.229 62.268 62.881 63.682 64.062 64.477 64.812 65.375 66.467 67.000 67.823 68.304 68.599 68.856 69.103 -0 0 0 0 0 -0 -0 0 -0 0 0 0 -0 0 -0 0 -0 0 -0 0 0 0 -0 0 •0 -0 -0 -0 0 -0 0 0 0 0 0 0 0 0 0 0 -0 -0 0 0 0 -0 0 0 0 0 0 0 0 0 .2 .0 .0 .0 .0 .1 .1 .0 .1 .0 .0 .0 .1 .0 .1 .0 .1 .0 .1 .0 .0 .0 .1 .0 .2 .2 .2 .2 .0 .1 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .1 .1 .0 .0 .0 .1 .0 .0 .0 .0 .0 .0 .0 .0 VI IVwwww VE EVwwwwwwww VE EV VE EVww VB BB BVWW VE EVWWWWWW VB BV VB BV VB BVWW VE EB BB BB BV VB 88 BVW VB BB C-120CIE Bz FBz TCIE 2ClEthylVO C-130CIP* Toluene T-130ClPe TetClE ClBz EthylBz m-Xylene o-Cl,F-Ben o-Xylene 130CIBZ 14DCI8Z 120CIBZ 36576.3672 5494*.58S»T 59187i37W " 2.4956*5 1.9399*5 87777.0156 16931.7500 1.0544*5 47410.4570 1 .0250*5 16615.3242 11492.1436 14072.3731 24783.9668 16384.1309 2.0087*5 79314.5313 1.1371*5 16552.3613 9066.1094 15102.7481 59451.2344 36075.8242 1.4421*5 80390.5313 70828.9297 75521.6250 16034.1104 56702.7852 62661.9727 1.3227*5 65870.6719 1.2888*5 95793.3750 82506.-3828 81920.3359 97918.7344 76554.0313 1.1273*5 94015.9141 70580.7344 66460.6719 58949.0156 1.0973*5 55895.9609 53917.4844 75432.3828 45840.2930 1.3500*5 1.0811*5 59764.9258 74724.7031 71382.7734 40257.1953 548645.50 ""•'" 6778413 :-';-'•• 8132^16 • 8907*13 8221.48 1316655.25 1693175.00 4354.00 711156.88 8916.94 6905.23 6276.06 140723.73 3996.90 245761.97 9039.31 1189718.00 3082.00 248285.41 2538.50 8898.00 5057.50 541137.38 14695.00 1205858.00 1062434.00 1132824.38 1603411.00 8930.50 939929.56 14423.50 5447.55 5087.84 5198.91 3296.31 1747.97 3272.11 1640.38 14199.81 1295.22 1058711.00 996910.13 664.45 22552.36 858.50 808762.25 937.99 22996.39 1433.13 557.75 668.53 920.86 1272.36 1065.00 79164.63 -#558.13 (/' 621.67 if-- 437.34 519.30 154806.39 209265.89 210.84 98611.63 444.17 417.57 548.71 20905.94 503.66 35252.30 437.18 150242.22 263.30 34939.13 252.94 532.23 286.76 59665.95 343.48 111340.77 91235.54 94624.71 134927.91 180.50 80090.87 543.38 412.13 196.72 270.46 199.10 177.39 277.81 178.14 1047.15 114.53 156241.63 157160.53 91.57 1671.40 124.90 131783.09 101.13 4079.70 86.33 41.95 90.97 100.22 144.96 215.14 15.00 0.12 0.14 0.04 0.04 15.00 100.00 0.04 15.00 0.09 0.42 0.55 10.00 0.16 15.00 0.05 15.00 0.03 15.00 0.28 0.59 0.09 15.00 0.10 15.00 15.00 15.00 100.00 0.16 15.00 0.11 0.08 0.04 0.05 0.04 0.02 0.03 0.02 0.13 0.01 15.00 15.00 0.01 0.21 0.02 15.00 0.01 0.50 0.01 0.01 0.01 0.01 0.02 0.03 C-12DCIE Bz FBz TCIE 2ClEthylVO C-13CClPe Toluene T-130ClPe TetClE ClBz EthylBz m-Xylene o-Cl,F-B*n o-Xylene 130CIBZ 140CIBZ 120CIBZ 15.00 0445 0.12 0.14 0.04 0.04 15.00 100.00 0.04 15.00 0.09 0.42 0.55 10.00 0.16 15.00 0.05 15.00 0.03 15.00 0.28 0.59 0.09 15.00 0.10 15.00 15.00 15.00 100.00 0.16 15.00 0.11 0.08 0.04 0.05 0.04 0.02 0.03 0.02 0.13 0.01 15.00 15.00 0.01 0.21 0.02 15.00 0.01 0.50 0.01 0.01 0.01 0.01 0.02 0.03 -2.2 Missing Component Report Component «»«*WM»»___*«H___^______«»«»M______. Air 5.3148*6 17577544.00 2.08e6 486.59 Expected Retention (Sample File) 5.000 486.59 Y. NOT DETECTED ON PRIMARY RUN: Z. NOT DETECTED ON HALL L 0 0 0 1 8 8 TUT 004 1881 (0 ^3" 0 1 'V'> o «- o *0 Kl ,- t> V S 5 - £* .30— s S-1 5^ 'r **t i 25~ Nl!« 0 a.JjS-:- ^ ~ £ -'s^fa £ 20— g tlli| a O (/I ~~ v«n 0) - ^ cv — c ?! - "I 10- Is pi ?2 r» *• U a. vt • t 8 •- R «j D — 8|'"c - -^88 o •• •• •• •• •• i >i illsi «• iT z in M a ——— I I ) o o -0 ^T! 1 Tffi. O •- o »o ro o o i/if'i >o o ^* «o o •- iri ^r^ o •~ ^ ' ' r a f O M K > r o . » in o - a^ ° S "I'A ^* \L"iivSi T ~rrHnir intrf^1 e _i : *-* Ml | 1 1 1 1 10 fc fcsfl s o-' pn vM^Yi i &ti fjCrr i 'fSu I nrrr" SlRrJ rsJQ ^ fe T r 7 i WWi m O o 3 fK jj~ rfc 1 1 1 U,! T.^n f J; V s <Q 1 1 i fes &*ftp •oI V^ i i i i i > IU Ul iu ui _i a. a. -J -J >- -J Ul— 1 Ul O U Z U ZU Ul <J ° 8 ui UJM 3/0 U a •- »- M _i _i «- _)»- i- >- i i NOB U «J i O i IU «- t- o cou. »- ru u i-»- i- 1 1 1 2 III | 1 1 1 1 | 1 1 1 0 30 R e t e n t o n 1 r 1 1 4 •ne i 0 *&--fOf) r ~^» J 1 u> i* " L JUL ^M T II-I Ul uioa ui NZ > 3T eouju. uj _j_i - _i r*->-_) >- carxu x UUZO 6 1 1 tn r 1 5C i ] n i r ) <~^D ) ai ' ' ' f ' *" *' ,( ro oo CO •— (o C3 o> _J w CO CD •H =tOo CO ^- (ui^t < inr»*> Wr^ M M 6 1 s ^ 1 2ft VF r—n h- ^ J ^ §#$ T ? iTDt]L^- ^-\-frnTn~ II 1 » 1 1 NM N am o _L_I .J UU U ^»^-> O Pv5 rJ I N I 0 1 1 1 1 Software; Version: 3.2 <16C20> Sample Name Sample Number Operator » Instrument - AutoSampler Rack/Vial 22.5PPB 8010/8020 STD D MIX V3400A/SALLY NONE 0/0 Time Study Channel : B : 3/12/93 8:34 AM : LINEARITY A/D mV Range : 1000 Interface Serial # : 0159572256 Data Acquisition Time: 3/11/93 9:01 PM Delay Time End Time Sampling Rate Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount Noise Threshold Multiplier 0.00 mm. 70.00 min. 2.0000 pts/sec n:\v3400s\TC11005.raw n:\v3400s\TC11005.rst N:\V3400S\8000SUE.ins N:\V3400S\PID.prc N:\V3400S\LINPTCll.smp n:\v3400s\scll.seq 5 ml 1.0000 Area Reject : 100.00 Dilution Factor : 1.00 10 1.0000 Area Threshold : 49 Bunch Factor: 2 Divisor : 1.0000 Adder : 0.0000 Instrument Conditions: Total Number of Peaks Detected: 79 ITAS-KNOXVILLE V3400A RTX 502.2 105m*0.53mm ID,3.00um df PID DETECTOR-FBZ AND 0-ClFBz ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. ALL OTHER ANALYTES ABE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLUME OF 5.O ML. Peak * 1 2 3 4 5 6 7 9 10 11 12 13 14 15 16 , 17 18 19 20 21 22 23 Ret Time RT DIFF. [min] X 5.676 7.067 7.730 8.320 9.012 9.716 10.143 11.809 12.458 14.024 15.054 15.656 15.910 16.566 16.971 19.040 19.764 20.171 21.033 21.444 21.813 22.463 0.0 0.0 0.0 0.0 0.2 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.1 0.0 0.0 0.1 0.0 0.0 0.0 0.0 BL Component Name BB BB BB BV VE VCl EV VBW VB BV VB BVWW VB 110CIE BVW W T-120CIE WWWW Area/ AMOtflt 1226.4667 6560.5698 5135.2363 13753.2285 11975.4766 12482.2383 12640.6660 10923.3838 11274.0957 92121.6016 32951.2383 40920.7109 39279.9336 56050.2813 28307.7832 96466.3828 1.6294*5 77591.0391 1.1178e5 1 .3679e5 1.7437e5 66953.1094 Area CuV"sec] 13797.75 1493.50 1409.50 3715.23 269448.22 17945.00 7997.72 23603.36 4717.20 9202.66 57307.33 11801.77 7409.70 10693.38 636925.13 26140.66 4105.72 1745798.38 1302.57 3752.63 11494.78 3072.58 Height INST. Amt Cal. Component SAMPLE CON [uV] (1SX) Range Name CPPB) 2825. 151. 182. 179. 15779. 955. 420. 1432. 278. 374. 6048. 1080. 706. 714. 77564. 3143. 292. 304052. 135. 318. 764. 70 27 39 50 51 29 42 79 03 15 64 18 51 54 56 83 33 16 18 26 79 207.64 11.25 0.23 0.27 0.27 22.50 1.44 0.63 2.16 0.42 0.10 1.74 0.29 0.19 0.19 22.50 0.27 0.03 22.50 0.01 0.03 0.07 0.05 11 0 0 0 VCl 22 1 0 2 0 0 1 0 0 0 11DCIE 22 .25 .23 .27 .27 .50 .44 .63 .16 .42 .10 .74 .29 .19 .19 .50 0.27 1 0.03 ^ T-12DCIE 22 0 0 0 0 .50 .01 .03 .07 .05 CO CO •H <-..oo I-D h- 0001884 24 25 26 27 28 29 30 31 52 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65* -67 68 69 70 71 72 73 74 75 76 77 78 79 23.420 24.100 24.817 25.453 26.603 27.748 28.402 29.329 30.521 31.030 31.829 32.783 33.242 34.010 34.825 35.025 36.044 36.550 36.935 37.381 37.689 38.159 39.304 40.024 41.161 45.619 46.181 46.850 47.619 50.728 52.788 53.404 53.731 54.944 55.989 56.611 57.306 57.703 60.148 61.199 62.281 62.894 63.695 64.069 64.336 64.819 65.435 66.174 66.469 66.997 67.826 67.977 68.303 68.614 69.101 69.315 u.U 0.1 0.0 0.0 0.0 0.0 0.0 0*0 0.0- ' -0.0 0.0 0.0 0.0 -0.0 0.0 0.0 0.0 -0.0 0.0 -0.0 0.0 0.0 0.0 -0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 vvww VI IVwwwwww ww w w ww VE EV VE EV w w VB BV ww w w w w w ww w ww VB BV VB BV w w VE EB BB BB BB BB BB BV VB BV VB BV VB C-120CIE BZ FBI TCIE 2ClEthylVO C-130CIP* Toluene T-130ClPe TetClE ClBz EthylBz m-Xylene o-Cl,F-Ben o-Xylene 130CIBZ 140CIBZ 12DCIBZ 4*087.8516 37339.2461 56184.6055 58424.8711 2.4402*5 1.8145*5 90139.4766 16998.1309 1.0057*5 50105.2656 1.2317*5 16774.6934 10478.5674 12501.9316 23159.0684 16906.1504 1.8888*5 82787.0391 1.0970e5 16916.9160 8632.2813 14167.0215 81899.7344 38662.6406 48746.4531 82567.4141 74090.1641 79010.0781 16040.6729 64397.6016 1.2769*5 62765.3945 1.2036*5 95257.8672 80115.0547 87791 .8047 98237.2969 88912.8125 1.2824*5 2.1829*5 71780.5078 67723.8125 67107.2266 1.1367*5 66938.2813 53338.8125 74247.2344 47877.0391 45783.3750 1.0141*5 1.1389*5 50120.8867 35514.3086 32484.9199 40827.1016 84216.4453 11587.47 1216.80 840133.06. 118690.73 9603 r6tr y* 773.56 7553.50 584.98 12786.72 11094.53 2028138.25 1699813.00 4267.48 1127368.50 16225.00 10600.23 8100.53 187528.97 4791.92 380388.38 7732.81 1862708.38 4459.50 380630.63 3592.50 11830.14 3793.34 869909.38 6454.06 1857766.88 1667028.75 1777726.75 1604067.25 1448946.00 15037.31 7007.65 5482.34 6561.13 3889.88 2618.66 4127.42 2892.11 7014.69 2527.34 1615061.38 1523785.75 1171.72 20633.29 1431.00 1200123.25 1504.00 375.50 8658.25 1065.50 1333.99 535.75 568.85 107.41 345.36 1274.65 642.08 749.21 241699.34 212601.94 216.65 155185.02 672.55 634.92 776.73 27944.84 646.21 56635.70 397.73 236442.02 394.92 55615.57 375.96 754.36 156.13 94940.77 446.30 170220.03 141866.73 147656.02 134189.28 122719.75 586.83 556.38 226.98 343.24 241.96 247.98 349.30 270.42 454.72 96.25 239977.52 241699.25 141.85 1476.13 173.85 194436.27 164.73 63.78 1537.93 85.44 95.25 86.93 130.26 26.89 68.79 123.09 0.27 22.50 0.17 0.13 0.05 0.06 22.50 100.00 0.04 22.50 0.13 0.63 0.77 15.00 0.21 22.50 0.04 22.50 0.04 22.50 0.42 0.84 0.05 22.50 0.13 22.50 22.50 22.50 100.00 22.50 0.12 0.11 0.05 0.07 0.05 0.03 0.04 0.03 0.06 0.01 22.50 22.50 0.02 0.18 0.02 22.50 0.02 0.01 0.19 0.01 0.01 0.01 0.02 0.00 0.01 0.02 C-120CIE Bz FBI TCIE 0 22 0 0 0 0 22 100 0 22 0 0 .27 .50 :S °4' .05 .06 .50 .00 .04 .50 .13 .63 0.77 2ClEthylVO C-130CIP* Toluene T-130ClPe TetClE ClBz EthylBz m-Xyl*n* o-Cl,F-B*n o-Xylen* 15 0 22 0 22 0 22 0 0 0 22 0 22 22 22 100 22 0 0 0 0 0 0 .00 .21 .50 .04 .50 .04 .50 .42 .84 .05 .50 .13 .50 .50 .50 .00 .50 .12 .11 .05 .07 .05 .03 0.04 130CIBZ 140CIBZ 12DCIBI 0 0 0 22 22 0 0 0 22 0 0 0 0 0 0 0 0 0 0 .03 .06 .01 .50 .50 .02 .18 .02 .50 .02 .01 .19 .01 .01 .01 .02 .00 .01 .02 0.6 Missing Component Report Component ^ ^ ^ ^ ^ «»«• ^m ^ ^ ^m ^ ^ ^ •• ^^» ^^ ^ ^^^m^m Air 5.3649*6 25174902.00 3.02e6 622.18 Expected Retention (Sample File) 5.000 622.18 Y. NOT DETECTED ON PRIMARY RUN: Z. NOT DETECTED ON HALL L0001885 TUT OO4 1884 V3400A PIO Sample Naat : 22.SPPS 8010/8020 STD FlttNaM : n:\v3400s\TC11005.raM Itothod : SOOOSIC.ira Start TiM : 0.00 m\n End TIM : 70.00 «in Seal* Factor: 0 .. Plot OffMt: 4 tH Savpl* t: D NIX Pag* 1 of 1 Date : 3/12/93 8:34 AM Ti«t of tnjtction: 3/11/93 9:01 PM Low Point : 4.00 tN High Point : 39.00 mV Plot Scalt: 35 MV Response [nnV] (D S" o' -V /^\ \ u _J ^_^«l — — °~I — NJ ~ CJ _ - '^/sj O _I — ^ - 1 —— UPI 11DCLE T-120CLE C-12DCLE - BZ FBZ TCLE 2CLETHYLVO- C-130CLPE TOLUENE T-13DCLPE TETCLE ^SrtlSE ~ 0-CL.F-BE 0-XYLENE -^ -^ NJ CO LAI L-J :J^ p CJi O CJi O _r i i i i i ! i 1 ! ! 1 1 1 1 I i 1 i 1 i 1 1 i ! ! 1 i i - —————— 5.68 ^*j - m >-14.02 ^ —————— 15'°5 J-. , _. —— 19.04 • g».tt ——————————————————————————— ™™ —— , —————————————— ?n ~C^26.60 ^^2^.75 ^-30.52 v -S-31.83 ^¥r.% -5. = ——————————————————————————————————————————————— 34.01 ^- T* >" 3^ Ip39.30 ^—41.16 -L_ i&9 I 54.94 CT) O" naaH . 12DCLBZ i- ID\- L0001886 Software Version: 3.2 <16C20> Sample Name sample.Number .Operator ^.nstrument AutoSampler Rack/Vial 30 PPB 8010/8020 STD E MIX V3400A/SALLY NONE 0/0 Time Study Channel : B 3/12/93 8:39 AM LINEARITY A/D mV Range : 1000 Interface Serial # : 0159572256 Data Acquisition Time: 3/11/93 10:16 PM Delay Time End Time Sampling Rate Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount Noise Threshold Multiplier 0.00 min. 70.00 min. 2.0000 pts/sec n:\v3400s\TC11006.raw n:\v3400s\TC11006.rst N:\V3400S\8000SUE.ins N:\V3400S\PID.prc N:\V3400S\LINPTCll.smp n:\v3400s\scll.seq 5 ml 1.0000 Area Reject : 100.00 Dilution Factor : 1.00 10 1.0000 Area Threshold : 49 Bunch Factor: 2 Divisor : 1.0000 Adder : 0.0000 Instrument Conditions: Total Number of Peaks Detected: 86 ITAS-KNOXVILLE V3400A RTX 502.2 105m*0.53mm ID,3.00um df PID DETECTOR-FEZ AND O-ClFBz ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. ALL OTHER ANALYTES ARE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLUME OF 5.0 ML. Peak * 1 2 3 4 5 6 7 8 10 11 12 13 14 15 16 __I7 19 20 21 22 23 Ret Time R [m in] 5.661 6.619 7.031 7.704 8.293 8.971 9.804 10.065 11.774 12.424 13.974 15.008 15.608 15.867 16.528 16.929 19.004 19.747 20.141 20.999 21.418 21.794 T DIFF. X 0.0 0.0 0.0 0.0 0.0 -0.3 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 -0.2 0.0 0.0 -0.1 0.0 0.0 0.0 8L Conponent Name BB BB BB BB BV VE VCl EV VB W VB BV VB BV W W VB 11DCIE BV W W T-120CIE W W W Area/ Anowit 1227.2889 2687.2651 9235.2490 5617.4199 11525.6133 12272.3936 14724.2959 12024.6856 10909.9316 11501.3154 89196.6484 32212.5117 42496.0469 38390.0195 60878.4727 29297.8125 95097.5938 1.5844e5 82266.0000 1.0791e5 1 .3953e5 1.7901e5 Area CuVsec] 13807.00 844.00 2831.75 2255.00 4751.63 368171.81 23533.00 11468.98 32898.64 7611.91 13687.56 79668.66 16832.31 10238.41 14847.38 878934.38 34500.91 4447.38 2467980.00 1834.76 4397.71 14839.25 Heigh tuV] 2918 103 203 266 273 22321 1061 633 1996 439 574 8336 1483 998 913 104795 4209 325 430248 197 365 961 t I .05 .96 .75 .74 .94 .58 .56 .78 .79 .77 .74 .09 .50 .36 .43 .52 .01 .64 .53 .25 .64 .68 NST. (IS 11 0 0 0 0 30 1 0 3 0 0 2 0 0 0 30 0 0 30 0 0 0 Amt Cat. Component ! X) Range Name .25 .31 .31 .40 .41 .00 » VCl .60 .95 .02 .66 .15 .47 .40 .27 .24 .00 * 11DCIE .36 .03 .00 + T-12DCIE .02 .03 .08 SAMPLE COM CPPB) 11.25 0.31 0.31 0.40 0.41 30.00 1.60 0.95 3.02 0.66 0.15 2.47 0.40 0.27 0.24 30.00 0.36 0.03 30.00 0.02 0.03 0.08 I •^ u ^ C r h 1000188 24 22.439 25 23.407 2* 24.079 27 24.813 28 25.434 29 24.588 30 27.744 31 28.388 32 29.319 33 30.525 34 31.026 35 31.826 36 32.778 37 33.239 38 34.009 39 34.824 '40 35.020 41 36.048 42 36.554 43 36.941 44 37.384 45 37.693 46 38.173 47 39.308 48 40.036 49 41.181 50 45.633 51 46.197 52 46.867 53 47.633 54 50.743 55 52.810 56 53.419 57 53.750 58 54.964 59 56.004 60 56.630 61 57.331 62 57.727 63 59.278 64 60.140 65 61.238 66 62.054 67 62.311 68 62.923 69 63.721 70 64.097 71 64.355 72 64.850 73 65.674 74 65.829 75 66.197 76 66.495 77 67.001 78 67.713 79 67.992 80 68.326 81 68.466 82 68.625 83 68.907 84 69.117 85 69.372 86 69.696 0.0 W 68605.9688 0.0 W 41525.2891 -0.0 W C-12DCIE 39281,2617 0.0 W 61510.8047 0.0 VB 66088.5625 0.0 BV 2.5349*5 0.0 W 1.9222*5 -8.0 W Bz 95973.6797 -0.0 W FBZ 17047.0879 0.0 W 58362.1523 -0.0 W TCIE 53079.3906 0.0 W 85400.2109 0.0 W 14448.0820 0.0 W 9010.7139 -0.0 VB 2ClEthytVO 13653.7471 0.0 BV 20278.2481 -0.0 W C-130ClPe 18056.0020 0.0 W 1.9200e5 0.0 VE Toluene 89047.9297 0.0 EV 1.1499e5 0.0 VE T-130ClPe 18396.1992 0.0 EV 8764.4775 0.0 W 15817.2168 0.0 W 71167.4063 0.0 VB TetClE 41399.4102 0.0 BB 49434.8945 0.1 BV ClBz 88380.0078 0.1 W EthylBz 79511.7266 0.1 W m-Xylene 85296.1328 0.1 W o-Cl,F-8en 16221.9121 0.1 W o-Xylene 68998.0313 0.0 W 1.3427e5 0.0 W 65612.6328 0.0 W 1.1454e5 0.0 W 91928.0938 0.0 W 79292.3750 0.0 W 86110.3906 0.0 W 97598.1406 0.0 VB 93612.4766 0.0 BB 1.2162*5. 0.0 BV 87187.6406 0.0 VB 1.9267e5 0.0 BV 1.1295*5 0.1 W 13DCIBZ 78713.1484 0.1 VE 140CIBZ 74596.7578 0.0 EV 72294.1328 0.0 VE 1.1586*5 0.0 EB 72009.2031 0.1 BE 12DCIBZ 58449.9922 0.0 EV 70899.9453 0.0 VB 55934.1758 0.0 BB 48406.0039 0.0 BV 46757.2344 0.0 VB 1.0998*5 0.0 BV 53420.9805 0.0 VB 52770.2422 0.0 BV 44448.3281 0.0 W 49113.5859 0.0 W 71845.4609 0.0 VB 92785.0313 0.0 BV 33855.5156 0.0 VB 60320.9258 0.0 BB 41534.5859 -0.1 5.7753e6 4238.39 279.53 15006.53?* 1635. 14 1178557.88*164505.09 11633.59 855.68 8780.53 601.15 17992.47 869.74 13886.16 885.18 2879210.50 344573.31 1704708.75 212234.02 2633.67 230.42 1592381.75 219813.63 13634.06 815.17 11449.92 796.25 9075.31 1016.45 273074.94 41034.49 5614.63 864.72 541680.06 81506.79 7734.66 391.37 2671438.00 341809.44 6607.50 558.20 551886.00 81243.89 5171.50 533.04 16975.75 1072.80 4024.31 190.61 1241982.25 133962.47 8793.72 599.62 2651400.25 247082.64 2385351.75 203870.11 2558884.00 213658.45 1622191.25 134652.47 2069941.00 175636.78 18978.81 704.39 9239.30 701.73 7464.47 324.75 8838.31 479.12 5602.33 352.09 4715.75 455.29 10060.13 856.95 7308.31 649.05 2448.00 167.33 14136.75 1347.99 3218.75 138.89 896.67 66.00 2361394.50 355665.00 2237902.75 358086.84 1691.50 190.08 34671.34 2433.43 3353.00 378.67 1753499.75 287134.03 1017.00 116.65 895.65 130.22 1470.00 246.96 11667.23 2029.24 1866.03 137.98 1195.66 182.02 1765.84 272.13 1037.55 189.83 505.57 83.71 774.44 87.66 2448.95 214. W 250.09 60.07 1821.91 245.63 376.00 73.62 34608828.00 4.20e« 0.06 0.36 30.00 * 0.19 0.13 0.07 0.07 30.00 * 100.00 0.05 30.00 * 0.16 0.79 1.01 20.00 + 0.28 30.00 + 0.04 30.00 + 0.06 30.00 » 0.59 1.07 0.06 30.00 + 0.18 30.00 + 30.00 + 30.00 + 100.00 30.00 + 0.14 0.14 0.07 0.10 0.07 0.06 0.10 0.08 0.02 0.16 0.02 0.01 30.00 * 30.00 * 0.02 0.30 0.05 30.00 + 0.01 0.02 0.03 0.25 0.02 0.02 0.03 0.02 0.01 0.01 0.03 0.01 0.03 0.01 759.96 C-120CIE Bz FBZ TCIE 2ClEthylVO C-13DUPe Toluene T-13DClPe TetClE ClBz EthylBz m-Xylene o-Cl,F-Ben o-Xylene 130CIBZ 140CIBZ 12DCIBZ 0.06 n 0.36 U 30.00 0.19 0.13 0.07 0.07 30.00 100.00 0.05 30.00 0.16 0.79 1.01 20.00 0.28 30.00 0.04 30.00 0.06 30.00 0.59 1.07 0.06 30.00 0.18 30.00 30.00 30.00 100.00 30.00 0.14 0.14 0.07 0.10 0.07 0.06 0.10 0.08 0.02 0.16 0.02 0.01 30.00 30.00 0.02 0.30 0.05 30.00 0.01 0.02 0.03 0.25 0.02 0.02 0.03 0.02 0.01 0.01 0.03 0.01 0.03 0.01 759.96 Missing Component Report Component Air Expected Retention 5.000 ( Sample File) 0451 03 03 Oo I-D t~ Y. NOT DETECTED ON PRIMARY RUN: Z. NOT DETECTED ON HALL L000188 V3400A PID S«apte NM» : 30 PPt 8010/8020 STD FUeNaae : n:\v3400s\TC11006.rMi Method : SOOOSUE.ir* Start TiM : 0.00 «in End Tia» : 70.00 «in Scale Factor: 0 Plot Offset: 4 loV Saaple ft E NIX Pag* 1 of 1 Data : 3/12/93 8:39 AM Tiw of Injection: 3/11/93 10:16 PM Low Point : 4.00 «V High Point : 39.00 mV Plot Scale: 35 MV Response O K> O o- LH O ro_ A) - :D 0 °~ fD AIR VCL -S.66 -a.97 77 -15.01 - T-12DCLE - -19.00 C-12DCLE - BZ FBZ TCLE 31.83 2CLETHYLVO- C-130CLPE - TOLUENE GO 00 CO h- L0001880 Software Version: 3.2 <16C20> Sample-Name Sample Number Operator nstrument x—AutoSampler' Rack/Vial 1 PPB 8010/8020 STD A MIX V3400A/SALLY NONE 0/0 Time Study Channel : A : 3/12/93 9:05 AM : LINEARITY A/D mV Range : 1000 Interface Serial # : 0159572256 Data Acquisition Time: 3/11/93 5:15 PM Delay Time End Time Sampling Rate Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount Noise Threshold Multiplier 0.00 70.00 2.0000 min. min. pts/sec n:\v3400s\SC11002.raw n:\v3400s\SC11002.rst N:\V3400S\8000SUE.ins N:\V3400S\HALL.prc N:\V3400S\LINHSCll.smp n:\v3400s\scll.seq 5 mL 1.0000 Area Reject : 100.00 Dilution Factor : 1.00 15 1.0000 Area Threshold : 73 Bunch Factor: 2 Divisor : 1.0000 Adder : 0.0000 Instrument Conditions: Total Number of Peaks Detected: 39 ITAS-KNOXVILLE V-3400B J+W DB-624 75m*0.53mm ID, 3.00um df ELECTROLYTIC CONDUCTIVITY DETECTOR-BrClMe AND 0-ClFBz ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. ALL OTHER ANALYTES ARE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLUME OF 5.O ML. Peak # 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 -17 18 19 20 21 22 Ret Time {min] 5.756 7.053 8.001 8.360 9.115 11.927 12.523 13.453 14.063 16.534 17.085 19.135 20.276 21.875 24.215 24.863 25.517 26.654 27.792 28.406 29.408 31.135 RT DIFF. % 0.0 0.1 0.0 0.2 0.3 -0.0 0.4 0.0 0.4 0.4 0.4 0.3 0.3 0.3 0.3 0.3 0.2 0.2 0.2 0.2 0.0 0.1 BL Component Name BV W OClDFMe W W CLUE W VCl W Brtte VE ClEa EV VB TClFNe BV TCLTFEa W 110CIE W CH2C12 W T-12DCIE W IIIDClEa W C-12DCIE W CMC 13 W BrCIM* W 111TClEa w ecu W 120ClEa W W TCIE Area/ Amount 44850.8281 64150.5195 84024.4297 1 .3038e5 1.9122e5 36557.8867 1.7690e5 1.7065*5 2.0018e5 99693.4297 2.8016e5 5.3388e5 3.4243*5 2.9144*5 2.3809*5 3.8284*5 53854.0391 6.0386*5 4.6756*5 3.1616*5 4.8125*5 3.2628*5 Area [uV*sec] 15940.09 96225.78 11124.20 195584.27 286835.94 54836.83 265358.59 16847.00 300277.41 99693.56 280162.00 1334711.50 342433.53 291443.94 238094.97 382845.00 5385404.00 603866.63 467564.81 316168.50 159185.28 326282.50 Height [UV] 899.71 3797.29 807.32 9146.95 9999.06 2399.90 12345.12 1007.31 15313.05 5142.36 17840.00 117726.90 23763.97 18344. ..3 17948.65 274U.30 42981 6. Sfl 26520.63 26779.45 17164.99 5677.64 22544.08 INST. Afllt USX) 0.36 1.50 0.13 1.50 1.50 1.50 1.50 0.10 1.50 1.00 1.00 2.50 1.00 1.00 1.00 1.00 100.00 1.00 1.00 1.00 0.33 1.00 Cal. Component Range Name DClOFHe CLME VCl BrHe ClEa TCIFM* TCLTFEa 11DCIE CH2C12 T-12DCIE 1110ClEa C-120CIE CHC13 BrCIM* 111TCIE8 ecu 12DClEa TCIE SAMPLE (PPB) 0. 1. 0. 1. 1. 1. 1. 0. 1. 1. 1. 2. 1. 1. 1. 1. 100. 1. 1. 1. 0. 1. CON 36 50 13 50 50 50 50 10 50 00 00 50 00 00 00 00 00 00 00 00 . - _, , 33£,t)Q 00 0- CD CO 1-1 t-j- o O l_b i— 01S90 24 25 3A" 27 28 29 30 11 ,2 33 34 35 36 37 38 39 32.822 34.172 35*114 37.495 38.287 40.129 41.253 45.732 47.698 53.520 54.978 57.683 62.362 62.970 64.893 69.772 0.1 W SrOClM* 2.6323*5 263238.56 14155.95 1.00 0.3 W 2CllthylVO 47432.9063^,- 47432.91* 1359.65 1.00 0.1 W C-130CIP* 3. 7658*$'^' 37658C3t^ 24104.91 1.00 0.1 W T-13DCIP* 5978T;796»!5?* S97Sf.80 :" 3274.82 1.00 0.1 W 112TCIE* 2.2294*5 222943.13 12481.29 1.00 0.1 W TttClE 3.4202*5 342023.28 21226.45 1.00 0.1 VB DBrCIN* 1.4628*5 146284.50 6495.31 1.00 0.4 BV ClBl 1.2373*5 123735.88 6160.21 1.00 0.0-W o-Cl,F-B*n 37208.0117 3720801.00 218530.64 100.00 ' 0.1 W CHBr3 58180.2500 58180.25 2457.38 .00 0.1 W 1122T*tClE 1.5276*5 152762.94 7599.34 .00 3.1 VB 123TriClPr 98625.8750 98625.88 5263.68 .00 0.0 BV 130CIBZ 1.3747*5 137477.94 10232.27 .00 0.0 VB 14DCIBZ 1.8458*5 184584.56 11963.81 .00 0.0 BB 12DCIBZ 1.7173*5 171733.25 12930.41 .00 0.0 BB 2.1786*5 2503.00 148.56 0.01 BrOClN* 1.00 2ClEthylVO 1.00 C-13DCIP* 1.00 T-13DCIP* 112TCIE* T*tClE DBrClMe CtBz o-Cl.F-Ben 10 CHBr3 1122TetCLE 123TriCtPr 13DCIBZ UDClBz 12DCIBZ .00 .00 .00 .00 .00 .00 .00 .00 .00 .00 .00 .00 0.01 0454 « 8.7 Missing Component Report Component Air 8.4295*6 17852168.00 1.18e6 237.43 Expected Retention (Sample File) 1.845 237.43 Y. NOT DETECTED ON PRIMARY RUN: Z. NOT DETECTED ON PID TUT OO4 189O L0001891 V3400A HALL Saapl* NaM : 1 PPt 8010/8020 STD F1l*HaM : n:\v3400a\SC11002.ran mthod : BOOOSUE.Irw Start TiM : 0.00 Bin End TiM : 70.00 win Seal* Factor: 0 Plot Offset: 4 wN 0455 *: A NIX pag« 1 of 1 Oat* : 3/12/93 8:41 AM TiM of Injection: 3/11/93 5:15 P* Low Point : 4.00 "V High Point : 39.00 tnv Plot Seal*: 35 i*V Response [rr.V] L71 _1_ L_L 1 o NJo O 0~ NJ (T) O~Z1 AIR DCLOFME CLNE VCL m - TCLFME TCLTFEA CH2CL2 T-12DCLE - 111DCLEA - —^ CLE - i _ € 111TCLEA - en O" TCLE 12DCLPA _|BRDCLME 2CLETHYLVO- C-130CLPE - T-130CLPE - 112TCLEA - TETCLE D8RCLME CLBZ 0-CL.F-BE CHBR3 1122TETCL 123TRICLP CD O" 54.98 mm 120CLBZ -CB d-69.77 TUT 004 189.1 (-OG01892 Software Version: 3.2 <16C20> Sample Name : 7.5PPB 8010/8020 STD Sample Number: B MIX Operator : nstrument \ V3400A/SALLY ^-AutoSampler : NONE Rack/Vial : 0/0 Time Study Channel : A : 3/12/93 9:05 AM : LINEARITY A/D mV Range : 1000 Interface Serial # : 0159572256 Data Acquisition Time: 3/11/93 6:30 PM Delay Time .End Time Sampling Rate Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount Noise Threshold Multiplier 0.00 70.00 2.0000 mm. min. pts/sec n:\v3400s\SC11003.raw n:\v3400s\SC11003.rst N:\V3400S\8000SUE.ins N:\V3400S\HALL.prc N:\V3400S\LINHSCll.smp n:\v3400s\scll.seq 5 mL 1.0000 Area Reject : 100.00 Dilution Factor : 1.00 15 1.0000 Area Threshold : 73 Bunch Factor: 2 Divisor : 1.0000 Adder : 0.0000 Instrument Conditions: Total Number of Peaks Detected: 46 ITAS-KNOXVILLE V-3400B J+ W DB-624 75m*0.53mm ID, 3.00um df ELECTROLYTIC CONDUCTIVITY DETECTOR-BrClMe AND O-ClFBz ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. ALL OTHER ANALYTES ARE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLUME OF 5.O ML. Peak * 1 2 3 4 5 6 7 a 9 10 11 12 13 14 15 16 '17 18 19 20 21 22 Ret Time R [min] 3.379 3.792 4.504 5.157 5.750 6.176 7.031 8.337 9.077 11.932 12.468 14.002 16.451 17.015 18.750 19.070 20.207 21.800 24.137 24.789 25.453 26.585 T DIFF. BL X 0.0 BB 0.0 BB 0.0 BB 0.0 BB 0.0 BV 0.0 W -0.2 W -0.1 W -0.1 W 0.0 W -0.1 W -0.0 VB -0.1 BV -0.1 W 0.0 W -0.1 W -0.1 W -0.1 W -0.1 W -0.1 W -0.1 W -0.0 W Component Name DClOFMe CLUE VCl BrMe ClEa TClFMe TCLTFEa 11DCIE CH2C12 T-120CIE 111DClEa C-12DCIE CHC13 BrClMe 111TClEa Area/ Aimxnt 191.5337 129.0289 34276.6953 58890.4023 42271 .4492 44239.0078 82359.5547 1.5745e5 1.8572e5 72956.2656 2.0757e5 2.7450t5 2.5283eS 3.0390e5 8.0267e5 4.1388e5 3.3234*5 3.3713e5 2.6737e5 3.9993t5 53496.3789 4.0895e5 Area CuVMec) 2992.50 791.00 2001.00 2866.98 21789.09 13114.25 617696.69 1180926.25 1392966.00 547172.00 1556815.38 2058770.38 1908914.50 2279291.50 11618.72 3104124.50 2492589.50 2528494.50 2005335.50 2999482.25 5349638.00 3067135.00 Heigh tuV) 170 91 147 123 1304 750 24413 56969 61647 27863 77675 109092 100427 166827 681 283008 226404 201568 172878 239840 417217 184770 t I .73 .40 .79 .24 .89 .45 .94 .63 . 11 .39 .M .8* .60 • J 6- .50 ' i . 77 .22 .11 .38 .41 INST. Amt Ca (ISX) Ra 15.62 6.13 0.06 0.05 0.52 0.30 7.50 7.50 7.50 7.50 7.50 7.50 7.55 7.50 0.01 7.50 7.50 7.50 7.50 7.50 100.00 7.50 I. Component nge Name OCtOFHe CLHE VCl BrMe ClEa TClFMe TCLTFEa 11DCIE CH2C12 T-12DCIE IIIDClEa C-12DCIE CHC13 BrClMe IIITClEa SAMPLE CON (PPB) 15.62 6.13 0.06 0.05 0.52 0.30 7.50 7.50 7.50 7.50 7.50 7.50 7.55 7.50 0.01 7.50 7.50 7.50 7.50 7.50 100.00 7.50 CM 0- 00 •H 5o h-D (- C0001893 24 25 26 27 28 29 30 1 ^-2 33 34 35 36 37 38 39 40 41 42 43 44 45 46 28.349 29.361 31.092 31.834 32.787 34.088 35.085 36.531 37.447 38.259 40.104 41.227 44.119 45.699 47.693 50.721 53.484 54.944 55.975 60.154 62.327 62.935 64.863 -0 0 •0 -0 -0 0 -0 0 - 0 0 0 0 0 0 0 0 0 0 0 0 -0 -0 -0 .0 .0 .0 .0 .0 .0 .0:o .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 VE EVwwww wwwwww w w VE EVw w w VB BVw VB 12DCIE* TCU -12DCtP« •rOCIN* 2ClEthylVO C-13DCIP* T-13DCIP* 112TCIE* T*tClE DBrClMe CLBz o-Cl,F-Ben CHBr3 1122TetClE 123TriClPr 130CIBZ 14DCIBZ 12DCIBZ 3.0455.5 5.3686*5 " 3.8759*5 3.0200*5 . 3.0785*5 59862.2813 2.9718*5 1.1813*5 2.0141*5 2.9995*5 4.3985*5 2.0978*5 3.7706*5 1.5541*5 41837.0703 2.6468*5 1.0576e5 2.1097e5 1.6136*5 3.0616*5 2.0020*5 2.3489*5 2.0668*5 2284171.50 171264.39 ' 26712fr;5<fcv 8540.61 2906968.00-245904.38 2265004.00.173817.41 2308901.00 168091.09 299311.41 16449.71 2228900.00 181029.34 83683.16 2319.88 1510641.50 123831.81 2249683.50 162610.23 3298935.00 236332.06 1573421.88 86752.33 41783.88 682.63 1165580.50 68340.27 4183707.00 249540.30 44382.50 412.06 793270.00 41801.03 1562306.00 108817.80 1210210.88 75532.08 37465.75 1252.14 1501514.00 130027.92 1761681.13 142211.52 1550151.00 131578.59 7.50 0.50 7.50 7.50 7.50 5.00 7.50 0.71 7.50 7.50 7.50 7.50 0.11 7.50 100.00 0.17 7.50 7.50 7.50 0.12 7.50 7.50 7.50 120CIE. TCIE 12DCIP* BrOCIN* 2ClEthylVO C-130CtPe T-130ClPe 112TCIEB TetClE DBrClMe ClBz o-Cl.F-Ben CHBr3 1122TetClE 123TriClPr 13DCIBZ KOClBz 120CIBZ 7 0 7 7 7 5 7 0 7 7 7 7 0 7 100 0 7 7 7 0 7 7 7 •50 « . .50 U4 .50 .50 .50 .00 .50 .71 .50 .50 .50 .50 .11 .50 .00 .17 .50 .50 .50 .12 .50 .50 .50 •1.1 Missing Component Report Component Air 1.0902*7 71589736.00 5.10*6 461.85 Expected Retention (Sample File) 1.845 461.85 Y. NOT DETECTED ON PRIMARY RUN: Z. NOT DETECTED ON PID TUT OO4 1893 V3400A HALL 0 4 5 8 SMple FileNaM : Nethod : Start TIM : Scatt Factor: 7.5PM 8010/8020 STD n:\v3400a\SC11003.raw MOOSUe.in* 0.00 Bin End Tim : 0 . Plot Offset: 70.00 *in 4 nV Saaplt ti B NIX Oat* : 3/12/93 8:46 AN Tin* of Injection: 3/11/93 6:30 PN Low Point : 4.00 «V High Point : 39.00 mV Plot Scale: 35 rnv Response [mV] o- o I\J O en OJ O _ AIR •D o o~H DCLDFNE CLNE VCL m TCLFNE TCLTFEA "2CL2 T-120CLE IHDCLEA ICLE - 111TCLEA - TCLE 2DC J _ 120CLPA _| BROCLNE —(2CLETHYLVO- — C-130CLPE - T-130CLPE 112TCLEA TETCLE OBRCLNE CLBZ 0-CL.F-BE CHBR3 1122TETCL - 123TRICLP - o~I mm - 12DCLB2 - -7.03 79.36 -34.09 -36.53 .12 I 0001895 TUT OO4 1894 Software V«r«ion: 3.2 <16C20> Sampler-Name Sample Number Operator • Znstrument AutoSampler Rack/Vial 15 PPB 8010/8020 STD C MIX V3400A/SALLY NONE 0/0 Time Study Channel : A : 3/12/93 9:21 AM : LINEARITY 0459 A/D mV Range : 1000 Interface Serial # : 0159572256 Data Acquisition Time: 3/11/93 7:46 PM Delay Time End Time Sampling Rate Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount Noise Threshold Multiplier 0.00 70.00 2.0000 min. min. pts/sec n:\v3400s\SC11004.raw n:\v3400s\SC11004.rst N:\V3400S\8000SUE.ins N:\V3400S\HALL.prc N:\V3400S\LINHSCll.smp n:\v3400s\scll.seq 5 mL 1.0000 Area Reject : 100.00 Dilution Factor : 1.00 15 1.0000 Area Threshold : 73 Bunch Factor: 2 Divisor : 1.0000 Adder : 0.0000 Instrument Conditions: Total Number of Peaks Detected: 44 ITAS-KNOXVILLE V-3400B J+ W DB-624 75m*0.53mm ID, 3.00um df ELECTROLYTIC CONDUCTIVITY DETECTOR-BrClMe AND O-C1FBZ ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. ALL OTHER ANALYTES ARE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLUME OF 5.0 ML. Peak « 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 - 17 18 19 20 21 22 Ret Time RT OIFF. [min] X 4.725 5.746 7. 047 8.348 9.088 11.932 12.479 14.007 16.467 17.025 19.085 20.219 21.813 23.335 24.149 24.802 25.465 26.593 27.735 28.355 29.367 31.098 0.0 0.0 0.5 0.3 0.2 0.1 0.1 0.0 0.0 -0.1 -0.1 -0.1 -0.1 0.0 -0.2 -0.2 -0.2 -0.2 -0.1 -0.1 0.0 -0.1 BL BB BB BV W W W W VB BV W W W W W W W W W W W W W Component Name DCIDFM* CLME VCl Brtta ClEa TClFHe TCLTFEa 11DCIE CH2C12 T-12DCIE 111DClEa C-12DCIE CHC13 BrClHt 111TClEa ecu 120CIE8 TCIE Area/ Amount 32211.0176 38619.6094 1.2643*5 2.2633*5 2.5455*5 1.1123«5 2.8186*5 3.6859*5 3.2249*5 3.4439*5 4.0000*5 3.4570*5 3.5873*5 4.9990*5 3.2599*5 4.9067*5 64086.8750 4.5838*5 5.0586*5 3.1410*5 5.7474*5 4.0500*5 Area [UV*S*C] 721.50 19572.75 1896523.00 3395038.50 3818275.75 1668494.75 4227939.50 5528990.50 4869714.50 5165952.00 6000081.00 5185625.00 5381037.50 44070.75 4889900.00 7360196.50 6408687.50 6875769.50 7587903.50 4711504.00 383055.25 6075007.50 Height 1NST. Amt Cal. Component SAMPLE CON [uV] (ISX) Range Name (PPB) 56.70 1283.00 72850.52 162483.38 173474.39 85494.73 211455.73 292625.53 252108.47 387950.34 562600.31 488286.66 443175. M 1582.32 429817.81 602602.13 509033.84 440199.69 527444.56 377432.41 11440.09 522953.50 0.02 0.51 15.00 15.00 15.00 15.00 15.00 15.00 15.10 15.00 15.00 15.00 15.00 0.09 15.00 15.00 100.00 15.00 15.00 15.00 0.67 15.00 DClOFHe CLME vet BrM* ClEa TClFHe TCLTFEa 11DCIE CH2C12 T-120CIE IIIOClEa C-12DCIE CHC13 BrCLM* imciEa ecu IZDClEa TCIE 0.02 0.51 15.00 15.00 15.00 15.00 15.00 15.00 15.10 15.00 15.00 15.00 15.00 0.09 15.00 15.00 100.00 15.00; 15.00*- 15.00 0.67 15.00 m o- CD*-i «J ^ l^/: r--3i- 0001890 23 24 25^ ZT- 29: 30- 31 32 33 34 35 36 37 38 39 40 41 42 43 44 31.839 32.790 34.083 35.088 36.483 37.446 38.257 40.097 41.217 44.013 45.688 47.680 50.699 53.470 54.941 55.974 59.718 60.130 62.336 62.946 64.877 68.673 -0.1 W 12DCIP* 3.1154*5 -0.1 W •rOClH* 3.1116*5 -0.1 W 2ClEthylVO 68431.8750 -0.1 W C-130CIP* 2.9621*5 0.0 W 1.3008*5 -0.1 W T-130CIP* 2.0313*5 -0.1 W 112TCIE* 2.9185*5 -0,1 W TttClE 4.5071*5 -0.1 VE OBrCIN* 2.1025*5 0.0 EV 3.4343*5 -0.2 W ClBz 1.5545*5 -0.2 W o-Ct,F-B*n 41967.0391 0.0 VB 1.1663*5 -0.1 BV CHBr3 1.1053*5 -0.1 W 1122T*tClE 2.0820*5 -0.1 W 123TriClPr 1.5201*5 0.0 W 2.4892*5 0.0 VB 2.1622*5 -0.1 BV 130CIBZ 1.9258*5 -0.1 W 140CIBZ 2.3652*5 -0.1 VB 120CIBZ 2.2181*5 0.0 BB 2.5482*5 4677711.00 373656.69 46*7531.00 363604.06 684318.75 47110.29 4443230.50 380476.03 135024.34 3979.70 3077066.75 263198.44 4377795.00 331990.75 6760751.00 495358.72 3153807.25 191105.80 67573.50 1212.07 2331887.50 145023.06 4196704.00 250435.38 44176.56 930.72 1658044.88 96899.52 3123126.75 221128.89 2280214.25 153380.25 8475.55 348.39 68793.38 3255.52 2888832.50 254268.83 3547949.25 297688.47 3327278.00 286022.72 1941.22 98.50 15.00 15.00 10.00 15.00 1.04 15.00 15.00 15.00 15.00 0.20 15.00 100.00 0.38 15.00 15.00 15.00 0.03 0.32 15.00 15.00 15.00 0.01 12DCIP* BrOCIN* 2ClEthylVO C-130CIP* T-130CIP* 112TCIE* TetClE DBrClMe ClBz o-Cl,F-B*n CHBr3 1122TetClE 123TriClPr 130CIBZ 140CIBZ 12DCIBZ 15.00 io!oo 0460 15.00 1.04 15.00 15.00 15.00 15.00 0.20 15.00 100.00 0.38 15.00 15.00 15.00 0.03 0.32 15.00 15.00 15.00 0.01 -2.0 Missing Component Report Component ^ «• ^ ^ ^ M» ^^» ^w ^m «B^ ^ ^ ^ •• ^ ^ ^ ••^^•w* Air 1.1624*7 147016304.00 1.07*7 678.36 Expected Retention (Sample File) 1.845 678.36 Y. NOT DETECTED ON PRIMARY RUN: Z. NOT DETECTED ON PID TUT 004 1896 L 000189- V3400A HALL Saaple NMH : 15 PPt 8010/8020 STD HltNM* : n:\v3400s\SC11004.raw Method : BOOOSUE.frw Start TlM : 0.00 Bin End Tint : 70.00 win Scale Factor: 0 . Plot Offset: 4 wN Saaple i: C NIX Date : 3/12/93 9:21 AM TlM of injection: 3/11/93 7:46 PH Low Point : 4.00 mV High Point : 39.00 mV Plot Scale: 35 MV 0461 o Response [nnV] NJ o- NJO oi o _ 0~ I) o °^ o~ 0~ CD O" AIR DCLDFME CLME VCL —X 1-4.73 m - TCLFME TftKP = CH2CL2 T-12DCLE - 111DCLEA - 111TCLEA - BROCLME 2CLETHYLVO C-130CLPE T-130CLPE 112TCLEA TETCLE DBRCLME CLBZ 0-CL.F-BE CHBR3 1122TETCL 123TRJCLP 13E6 = 12DCLBZ -36.48 01 L000189 TUT 004 1897 Software Version: 3.2 <16C20> Sample Name Sample Number Operator nstrument ^"AutoSampler Rack/Vial 22.5PPB 8010/8020 STD D MIX V3400A/SALLY NONE 0/0 Time Study Channel : A : 3/12/93 9:05 AM : LINEARITY A/D mV Range : 1000 Interface Serial # : 0159572256 Data Acquisition Time: 3/11/93 9:01 PM Delay Time End Time Sampling Rate Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount Noise Threshold Multiplier 0.00 min. 70.00 min. 2.0000 pts/sec n:\v3400s\SC11005.raw n:\v3400s\SC11005.rst N:\V3400S\8000SUE.ins N:\V3400S\HALL.prc N:\V3400S\LINHSCll.smp n:\v3400s\scll.seq 5 mL 1.0000 Area Reject : 100.00 Dilution Factor : 1.00 15 1.0000 Area Threshold : 73 Bunch Factor: 2 Divisor : 1.0000 Adder : 0.0000 Instrument Conditions: Total Number of Peaks Detected: 46 ITAS-KNOXVILLE V-3400B J+ W DB-624 75m*0.53mm ID, 3.00um df ELECTROLYTIC CONDUCTIVITY DETECTOR-BrClMe AND O-C1FBZ ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. ALL OTHER ANALYTES ARE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLUME OF 5.O ML. Peak # 1 2 3 u 5 6 7 8 9 10 11 12 13 14 5 6 "17 18 19 20 21 22 Ret Time R [min] 5.757 7.045 8.353 9.099 11.934 12.489 14.020 16.474 17.038 18.740 19.098 20.232 21.826 23.315 24.166 24.821 25.482 26.608 27.745 28.364 29.367 31.095 T DIFF. X 0.0 -0.0 0.1 0.1 0.0 0.1 0.1 0.0 0.1 0.0 0.1 0.1 0.1 0.0 0.1 0.1 0.1 0.1 0.0 0.0 0.0 -0.0 BL BB BVW VB BVW VB BV VE EVWW VE EB BVWWWW VE EVW Component Name DClDFMe CLNE VCl BrM* ClEa TClFMe TCLTFEa 11DCIE CH2C12 T-12DCIE 111DClEa C-12DCIE CHC13 BrCIN* 111TCIEB ecu 12DClEa TCIE Area/ Amount 45304.5469 1.0766*5 1.9048*5 2.1612*5 89301.4219 2.2691*5 3.2033*5 2.9734*5 3.2249*5 1.1478*6 3.6039*5 3.3591*5 3.5261*5 4.9151*5 3.1860*5 4.5834*5 61056.0117 4.4775*5 4.9410*5 2.9391*5 6.1349*5 3.6621*5 Area [uV*sec] 31316.00 2422463.00 4285816.00 4862742.00 2009282.00 5105608.50 7207512.50 6734908.00 7256027.50 16915.50 8108787.50 7558181.50 7933920.00 50392.50 7168534.50 10312834.00 6105601.00 10074438.00 11117460.00 6613058.50 373708.50 8239794.00 Heigh CuV] 1749 93128 207107 220461 104895 254202 378156 356342 556247 693 759313 720212 667927 1840 638994 829109 481214 654708 778785 536681 10455 716323 t 1 .88 .16 .95 .88 .74 .69 .66 .28 .25 .97 .19 .94 .63 .19 .69 .19 .22 .25 .75 .94 .92 .31 INST. Amt Ca (ISX) Ra 0.69 22.50 22.50 22.50 22.50 22.50 22.50 22.65 22.50 0.02 22.50 22.50 22.50 0.10 22.50 22.50 100.00 22.50 22.50 22.50 0.61 22.50 I. Component nge Name DClDFMe CLME VCl BrMe CtEa TClFMe TCLTFEa 11DCIE CH2C12 T-12DCIE IIIOClEa C-12DCIE CHC13 BrClMe 111TClEa ecu 12DClEa TCIE SAMPLE CON (PPB) 0.69 22.50 22.50 22.50 22.50 22.50 22.50 22.65 22.50 0.02 22.50 22.50 22.50 0.10 22.50 22.50 100.00 22.50 22.50 22-50 LOOC 0.61 22.50 CDO CO •H 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 32.787 34.080 35.085 36.480 37.442 38.254 40.097 41.217 43.103 43.979 45.698 47.694 50.678 53.479 54.954 55.989 59.671 60.137 62.345 62.956 64.881 66.573 68.443 -0.0 W Brt>ClM« -0.0 W 2ClEthylVO -0.0 VE C-130ClPe 0.0 EV -0.0 W T-130CIP* -0.0 W 112TCIE* 0.0 W TetClE -0.0 VE DBrClMe 0.0 EV 0.0 W 0.0 W ClBz 0.0 W o-Cl,F-8en 0.0 VB 0.0 BV CHBr3 0.0 W 1122TetClE 0.0 VE 123TriClPr 0.0 EV 0.0 VB 0.0 BV 13DCIBZ 0.0 W 140CIBZ 0.0 W 12DCIBZ 0.0 W 0.0 VB 2.9705.5 60337.9180 2.8511*5 1.4264*5 1.7105*5 2.3218*5 4.1768*5 1.8866*5 3.4090*5 3.3131e5 1.5829*5 42327.3906 1.3100*5 1.0087*5 1.8811*5 1.4212*5 5.5648*5 2.0993*5 2.0781*5 2.3146*5 2.0367*5 6.2939*5 1.8848*5 6683643.50 533252.63 905068.75 62957.81 6415034.50 559108.19 156742.00 5107.74 3848705.25 330098.88 5224082.00 401296.81 9397824.00 690469.38 4244856.50 273058.94 154140.50 2936.90 145662.38 2708.33 3561572.75 225280.31 4232739.00 250891.95 109167.31 2047.69 2269719.75 137679.98 4232650.00 300217.91 3197833.25 213119.44 37883.50 696.57 113001.50 5507.79 4675941.00 420493.09 5208034.00 450424.16 4582774.00 411166.97 70335.13 1444.98 1386.16 95.09 22.50 15.00 22.50 1.10 22.50 22.50 22.50 22.50 0.45 0.44 22.50 100.00 0.83 22.50 22.50 22.50 0.07 0.54 22.50 22.50 22.50 0.11 0.01 BrOClMe 2ClEthylVO C-130ClPe T-130ClPe 112TCIE8 TetClE DBrClMe ClBz o-Cl,F-Ben CHBr3 1122TetClE 123TriClPr 13DCIBZ KDClBz 12DC1BZ 22.50 U 4 O J 15.00 22.50 1.10 22.50 22.50 22.50 22.50 0.45 0.44 22.50 100.00 0.83 22.50 22.50 22.50 0.07 0.54 22.50 22.50 22.50 0.11 0.01 1.1 Missing Component Report Component Air 1.3291*7 199292544.00 1.47*7 917.62 Expected Retention (Sample File) 1.845 917.62 Y. NOT DETECTED ON PRIMARY RUN: Z. NOT DETECTED ON PID TUT 004 1899 L 0 0 0 1 V3400A HALL 0 4 6 4 Sanple NMM : 22.5PP8 8010/8020 STD * : n:\v3400t\SC11005.ran Method : Start Time : 'csle Factor: SOOOSUE.ins 0.00 min 0 End Time : 70.00 min Plot Offset: 4 n»V Sample t: 0 Mix Date : 3/12/93 8:31 AM Time of Injection: 3/11/93 9:01 PM Low Point : 4.00 mV High Point : 39.00 mV Plot Scale: 35 mV o HDCLOFME —'CLME —IVCL --X —TCLFME —TCLTFEA —iCH2CL2 ——T-12DCLE - _|111DCLEA - —( CLE - I]111TCLEA - Hf^LEA - — TCLE ^BRDCLME -2CLETHYLVO- <C-13DCLPE - —112TCLEA - ——TETCLE —JDBRCLME ]CHBR3 .1122TETCL -I123TRICLP -29.37 -36.48 50.68 59.67 -60.14 >44 0- •H h-nt- Software Version: 3.2 <16C20> Sample Name Sample Number Operator nstrument -^utoS ampler Rack/Vial 30 PPB 8010/8020 STD Time E MIX Study V3400A/SALLY Channel NONE 0/0 3/12/93 9: LINEARITY 05 AM 0465 A/D mV Range : 1000 Interface Serial # : 0159572256 Data Acquisition Time: 3/11/93 10:16 PM Delay Time End Time Sampling Rate Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount Noise Threshold Multiplier 0.00 min. 70.00 min. 2.0000 pts/sec n:\v3400s\SC11006.raw n:\v3400s\SC11006.rst N:\V3400S\8000SUE.ins N:\V3400S\HALL.prc N:\V3400S\LINHSCll.smp n:\v3400s\scll.seq 5 mL 1.0000 Area Reject : 100.00 Dilution Factor : 1.00 15 1.0000 Area Threshold : 73 Bunch Factor: 2 Divisor : 1.0000 Adder : 0.0000 Instrument Conditions: Total Number of Peaks Detected: 46 ITAS-KNOXVILLE V-3400B J-l-W DB-624 75m*0.53mm ID, 3.00um df ELECTROLYTIC CONDUCTIVITY DETECTOR-BrClMe AND O-CIFBZ ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. ALL OTHER ANALYTES ARE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLUME OF 5.O ML. Peak * 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 ' 17 18 19 20 21 22 Ret Time R [min] 5.740 7.026 8.324 9.061 11.888 12.447 13.971 15.582 16.427 16.996 18.688 19.072 20.209 21.803 23.298 24.149 24.814 25.461 26.589 27.744 28.350 29.356 T DIFF. BL X 0.0 BB -0.3 BV -0.3 W -0.3 VB -0.4 BV -0.3 W -0.3 VE 0.0 EB -0.2 BV -0.2 VE 0.0 EV -0.1 W -0.1 W -0.0 W 0.0 W -0.0 W 0.1 W -0.0 W -0.0 W 0.0 W -0.0 VE 0.0 EV Component Name DClDFMe CLME VCl BrMe ClEa TClFMe TCLTFEa 11DCIE CH2C12 T-120CIE 111DCIE8 C-12DCIE CHC13 BrClM* IIUClEa ecu 120ClEa Area/ Amount 39754.4375 1 .3205e5 2.3087*5 2.5066*5 1.1410*5 2.7203*5 3.5581*5 1.1960*5 3.2921*5 3.3529*5 1.1751*6 3.2144.5 3.0547*5 3.4547*5 4.0925*5 3.1411*5 4.0885*5 62620.2383 4.4738*5 4.6805*5 3.0433*5 6.8124*5 Area [uV*sec] 28747.75 3961747.00 6926150.00 7520008.50 3423247.75 8160945.00 10674525.00 18145.00 9942378.00 10058709.00 33239.00 9643248.00 9164268.00 10364236.00 65975.81 9423496.00 12265661.00 6262024.00 13421693.00 14041762.00 9130100.00 467523.50 Heigh [UV] 1830 153871 340778 358807 177274 420294 582110 780 521869 782021 1331 848186 823804 844684 2893 824574 918901 495485 872737 930343 753949 11779 t I .63 .89 .00 .00 .92 .88 .81 .11 .47 .56 .90 .19 .75 .25 .50 .69 .50 .16 .19 .56 .63 .93 INST. Amt (ISX) 0.72 30.00 30.00 30.00 30.00 30.00 30.00 0.15 30.20 30.00 0.03 30.00 30.00 30.00 0.16 30.00 30.00 100.00 30.00 30.00 30.00 0.69 Cal. Component Range Name » DClDFMe + CLME * VCl + BrMe + ClEa * TClFMe + TCLTFEa + 11DCIE * CH2C12 + T-12DCIE + 111DClEa + C-12DCIE + CHC13 BrClMe + HUClEa + ecu * 120ClEa SAMPLE CON (PPB) 0.72 30.00 30.00 30.00 30.00 30.00 30.00 0.15 30.20 30.00 0.03 30.00 30.00 30.00 0.16 30.00 30.00 100.00 30.00 30.00 30.00 0.69 ^ i> •H O O 1- h- U000190 24 25 26 27 28 29 30 51 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 31.831 32.782 34.076 35.085 36.473 37.058 37.448 38.261 40.117 41.227 44.000 45.708 47.710 50.700 53.492 54.970 56.008 59.695 60.159 62.376 62.985 64.910 66.543 -0.0 W 12DCIP* 3.1243*5 -0.0 W irfiClN* 3.1433*5 -0.0 W 2ClEthylVO 62318.5000 -0.0 VE C-130CIP* 2.9027*5 0.0 EV 1.7609*5 0.0 W 57208.2539 0.0 W T-13DCIP* 2.0483*5 0.0 W 112TClEa 2.8918*5 0.1 W TetClE 4.2730*5 0.0 W DBrClMe 2.0625*5 0.0 W 2.3444*5 0.0 W ClBz 1.5139*5 0.1 W o-Cl,F-B*n 42122.0352 0.0 VB 1.0683*5 0.0 BV CHBr3 1.0779*5 0.1 W 1122TetClE 1.9642*5 0.1 W 123TriClPr 1.4541*5 0.0 W 2.1674*5 0.0 VB 2.1678*5 0.1 BV 13DCIBZ 2.2267*5 0.1 W 140CIBZ 2.4738*5 0.1 VE 12DCIBZ 2.1876*5 0.0 EB 4.3720*5 9373162.00 765492.19 9430002.00 763542.75 1246370.00 94508.63 8708170.00 765045.56 224340.00 8356.62 51108.41 2925.64 6145076.50 539054.94 8675488.00 675969.13 12819005.00 908708.69 6187621.50 393659.16 112257.88 2949.62 4541923.00 287762.63 4212203.50 248112.16 86987.56 2000.82 3233773.50 200180.30 5892756.00 426301.06 4362502.50 300088.91 20060.23 947.01 172381.06 8136.44 6686206.00 607578.88 7421459.50 647703.81 6562910.50 596207.19 37293.00 1102.96 30.00 30.00 20.00 30.00 1.27 0.89 30.00 30.00 30.00 30.00 0.48 30.00 100.00 0.81 30.00 30.00 30.00 0.09 0.80 30.00 30.00 30.00 0.09 * 120CIP« + BrDCIN* * 2ClEthylVO + C-130CIP6 » T-130CIP* * 112TClEa * TetClE + DBrClMe + ClBz o-Cl,F-Ben * CHBr3 + 1122TetClE * 123TriClPr * 13DC18Z + KDClBz * 12DCI8Z 30.00 0 4 6 I 30.00 20.00 30.00 1.27 0.89 30.00 30.00 30.00 30.00 0.48 30.00 100.00 0.81 30.00 30.00 30.00 0.09 0.80 30.00 30.00 30.00 0.09 -1.8 Missing Component Report Component ^ ^ ^ ^ mr i~ ^ v «• ^ ^ i—— ^ ^ ^ ^ IB ^ ^ ^ ^ ^ ^ ^ « Air 1.2671*7272131424.00 1.97e7 1156.38 Expected Retention (Sample File) 1.845 1156.38 Y. NOT DETECTED ON PRIMARY RUN: Z. NOT DETECTED ON PID TUT OO4 190; 000 j V3400A HALL Sanpte Naaw : 30 PPB 8010/8020 STD FileNMM : n:\v3400c\SC11006.raM Method : BOOOSUE.ins Start Tinw : 0.00 lain End Tiim : 70.00 min Scale Factor: 0 Plot Offset: 4 mv 0467 Sample *: E NIX Date : 3/12/93 8:36 AM Time of Injection: 3/11/93 Low Point : 4.00 mV Plot Scale: 35 mv 10:16 Ptt High Point 39.00 mV ~C ^^ C; — AIR —iDCLDFME —ICLME —<VCL —JTCLFME ^TCLTFEA —I —(CH2CL2 T-12DCLE 111DCLEA m CLE 111TCLEA —ITCLE ^IZOCLPA — BRDCLME —.2CLETHYLVO- ——C-130CLPE - ~"T-130CLPE - —112TCLEA - ——iTETCLE —IDBRCLME -29.36 E^oi --13.S E-lT8! =-20.; — 21.1 26.! II'. io 32. 5..: 5< >3 4CLBZ ]0-CL,F-BE —(123TRICLP - =!l2BEfcH "d i 50.70 .54 --CB L 000190, .——JLL6& Software Version: 3.2 <16C20> Sample Name Sample Number Operator ^nstrument AutoSampler Rack/Vial 15 PPB C MIX V3400A/SALLY NONE 0/0 Time Study Channel : A 3/20/93 1:13 PM STD CHECK A/D mV Range : 1000 Interface Serial Delay Time End Time Sampling Rate Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount # : 0159572256 0.00 min. 70.00 min. 2.0000 pts/sec Data Acquisition Time: 3/12/93 5:13 PM n:\v3400s\SC11021.raw n: \v3400s\SCH02l.rst N:\V3400S\8000SUE.ins N:\V3400S\HALL.prc N:\V3400S\LINHSCll.smp n:\v3400s\scll.seq 5 mL 1.0000 Area Reject : 100.00 Dilution Factor : 1.00 ITAS-KNOXVELLE V3400B J+ W DB-624 75m»0.53mm E0,3.00um df LECTROLYTIC CONDUCTIVITY DETECTOR: Percent differences, standard _*.oncentrations , and Cfs for BrClMe, o-Cl, F-Benzene, and B2ClIsopO are incorrect due to the compounds having a concentration different than the other compounds in the mix. The percent differences for these compounds and Cfs must be done manually. The computer could only calculate percent differences and Cfs from only one standard concentration. Standard check compared to o /\C /92, linearity Peak * 0 2 3 4 5 6 7 8 9 10 11 12 U 5 -^6 17 18 19 21 22 Ret Time [minj 1.845 7.038 8.345 9.079 11.911 12.467 13.995 16.457 17.018 19.082 20.221 21.819 24.160 24.812 25.475 26.600 27.737 28.355 31.089 31.831 Component Name Air DClDFMe CLME VCl BrMe ClEa TClFMe TCLTFEa 11DCIE CH2C12 T-120CIE 111DClEa C-12DCIE CHC13 BrClMe 111TClEa CC14 ISDClEa TCIE 12DClPa Height IuV] 0 63575 159592 172261 85839 212329 277584 228320 348466 499835 445718 407942 398528 552556 471090 417895 478204 346708 417410 288211 .00 .46 .55 .00 .91 .23 .16 .89 .69 .03 .78 .34 .31 .75 .41 .78 .78 .59 .06 .06 8L Cal. Range W BV W W W W VB BV WW W W W W W WW W WW CONCENTRATION STANDARD CON. PERCENT IPPB: (PPB) DIFFERECE 0 15 16 16 17 17 16 14 14 13 15 15 15 16 92 15 15 15 13 12 .00 .24 .73 .87 .42 .31 .00 .79 .93 .56 .27 .38 .87 .54 .55 .07 .22 .19 .78 .93 15.000 15.000 15.000 15.000 15.000 15.000 15.000 15.000 15.000 15.000 15.000 15.000 15.000 15.000 te£>is»*6e 15.000 15.000 15.000 15.000 15.000 -I.OOOeZ 1.598 11.520 12.464 16.108 15.411 6.647 -1.381 -0.496 -9.622 1.783 \ 2.546 ,- z-.>5.821 10.261 ';j-517.QU 0.439 1.462 1.248 -8.164 -13.827 Component Name Air DClDFMe CLME VCl BrMe ClEa TClFMe TCLTFEa 11DCIE CH2C12 T-12DCIE 111DClEa C-12DCIE CHCL3 BrClMe 111TCIEB CC14 12DClEa TCIE- 120ClPa DAILY Cf 0.0000 4.2383e3 1.0639e4 1.1484K 5.7226e3 1.4155e4 1.8505e4 1.5221e4 2.3231e4 3.3322e4 2.9714e4 2.7196e4 2.6568e4 3.6837e4 3.1406e4 2.7859e4 , _ 3.1880e4 LI* 0 0 J 2.3113e4 2.7827e4 1.9214e4 '._' •H '.-' O f- P 900 23 24 25 27 28 29 30 33 34 36 37 38 40 41 42 32.780 34.074 35.077 37.436 38.243 40.086 41.207 45.685 47.687 53.484 54.961 55.998 62.368 62.975 64.906 BrOClMe 2ClEthylVO C-13DClPe T-130ClPe 112TClEa TetClE DBrClMe ClBz o- C I, F- Benzene CHBr3 1122TetClEa 123TriClPropane 13DCIBZ UDClBz 12DCIBZ 282161 38058 294925 190257 249893 375727 141804 112566 210093 77144 177343 123668 240329 250945 234730 .28 .57 .66 .63 .30 .78 .34 .88 .50 .07 .27 .38 .47 .80 .56 W w VE W W W w w VE BV W W BV W VB 9.27e6 12 9 11 .23 .21 \0 .90 12.25 12 12 11 12 83 12 12 12 14 13 13 .77 .80 .85 .64 .90 tot .85 .60 .58 .00 .06 .38 628.64 15.000 . T5>ODO " 15.000 15.000 15.000 15.000 15.000 , 15.000 ' jl^M9 15.000 15.000 15.000 15.000 15.000 15.000 525.000 -18.477 ?.1 -38.585 -20.690 -18.363 -14.896 -14.647 > j20.995 >li -15.765 /V4SOv354r -14.363 -15.983 -16.149 -6.637 -12.947 -10.773 690.917 BrOClMe 2ClEthylVO C-130ClPe T-130ClPe 112TCIE8 TetClE DBrClMe ClBz o-Cl,F-Benzene CHBr3 1122TetClEa 123TriClPropane 13DCIBZ 140C18Z 12DCIBZ 1.8810e4 2.5372e3 1.9661e4 0 4 6 9 1.2683e4 * " J 1.6659e4 2.5048e4 9.4536e3 7.5044e3 1 .4006e4 5.U29e3 1.1822e4 8.2445e3 1.6021e4 1.6729e4 1.5648e4 6.1811e5 ITAS-KNOXVILLE V-3400B J+W DB-624 75m*0.53mm ID, 3.00um df ELECTROLYTIC CONDUCTIVITY DETECTOR-BrClMe AND O-C1FBZ ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. ALL OTHER ANALYTES ARE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLUME OF 5.O ML. ;ak « 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 52 -33 34 35 36 37 38 Ret Time RT DIFF. Bl Component Area/ [mirO X Name Amount 5.748 7.038 8.345 9.079 11.911 12.467 13.995 16.457 17.018 19.082 20.221 21.819 23.350 24.160 24.812 25.475 26.600 27.737 28.355 29.364 31.089 31.831 32.780 34.074 35.077 36.496 37.436 38.243 40.086 41.207 44.029 45.275 45.685 47.687 50.729 53.484 54.961 55.998 0.0 BB 52995.5508 -0.1 BV DClDFMe 1.1040e5 -0.0 W CLME 1.9384e5 -0.1 W VCt 2.2472e5 -0.2 W BrMe 91488.0234 -0.1 W ClEa 2.4022e5 -0.1 VB TClFMe 3.3490e5 -0.1 BV TCLTFEa 2.9964e5 -0.0 W 11DCIE 3.2662e5 -0.0 W CH2C12 4.0378*5 0.0 W T-120CIE 3.2016«5 0.0 W 111DClEa 3.2595e5 0.0 W 6.9257e5 0.1 W C-12DCIE 2.8999e5 0.0 W CHC13 4.1475e5 0.0 W BrClMe 65176.5391 0.0 W 111TClEa 4.3111e5 0.0 W CC14 4.5324e5 -0.0 W 12DClEa 2.8554e5 0.0 W 7.2730e5 -0.0 W TCIE 3.5916e5 -0.0 W 12I>ClPa 2.8744e5 -0.0 W BrOClMe 3.0472e5 -0.0 W 2ClEthylVO 63062.9453 -0.0 VE C-130ClPe 2.9624e5 0.0 EV 4.8087e5 -0.0 W T-13DClPe 1.8780e5 -0.0 W 112TClEa 2.6407e5 -0.0 W TetClE 4.0391e5 -0.0 W DBrClMe 2.0083e5 0.0 W 3.4614e5 0.0 W 1.2409e5 -0.0 W ClBz 1.4787e5 0.0 VE o-Cl,F-Ben 42857.3750 0.0 EB 2.5680e5 0.0 BV CHBr3 1.0623e5 0.0 W 1122TetClE 2.0282e5 0.0 W 123TriClPr 1.5559e5 Ares Height INST. Amt Cat. Component SAMPLE CON [uV*sec] tuVQ (ISX) Range Name (PPB) 24005.00 1505.04 1682524.13 63575.46 3242689.50 159592.55 3791070.75 172261.00 1593370.50 85839.91 4158783.00 212329.23 5357439.00 277584.16 4432674.50 228320.89 4875108.50 348466.69 5474027.50 499835.03 4888156.00 445718.78 5013782.00 407942.34 42989.97 1558.47 4603148.00 398528.31 6859744.00 552556.75 6032228.00 471090.41 6495079.50 417895.78 6898121.50 478204.78 4336615.00 346708.59 309616.13 9718.34 4947716.50 417410.06 3715570.25 288211.06 3726337.50 282161.28 580949.88 38058.57 3524257.25 294925.66 96357.50 2861.39 2299818.25 190257.63 3371042.50 249893.30 5171238.50 375727.78 2380083.75 141804.34 31354.66 806.99 3150.25 226.17 1868445.50 112566.88 3595869.00 210093.50 34618.50 748.35 1364595.25 77144.07 2556170.00 177343.27 1956969.63 123668.38 0.45 15.24 16.73 16.87 17.42 17.31 16.00 14.79 14.93 13.56 15.27 15.38 0.06 15.87 16.54 92.55 15.07 15.22 15.19 0.43 13.78 12.93 12.23 9.21 11.90 0.20 12.25 12.77 12.80 11.85 0.09 0.03 12.64 83.90 0.14 12.85 12.60 12.58 DClDFMe CLME VCl BrMe ClEa TClFMe TCLTFEa 11DCIE CH2C12 T-120CIE 111DClEa C-120CIE CHC13 BrClMe 111TClEa CC14 12DCIEB TCtE 12DCIP8 BrDClMe 2ClEthylVO C-13DClPe T-130ClPe 112TClEa TetClE DBrClMe ClBz o-Cl.F-Ben CHBr3 1122TetClE 123THClPr 0.45 15.24 16.73 16.87 17.42 17.31 16.00 14.79 14.93 13.56 15.27 15.38 0.06 15.87 16.54 92.55 15.07 15.22 15.19 0.43 13.78 0- 12.93 ^ 12.23 9.21 =3- 11.90 0 0.20 12.25 12.77 H 12.80 3 11.85 H 0.09 0.03 12.64 83.90 o.u L O G O 190., 12.85 12.60 12.58 39 40 41 42 43 60.171 62.368 62.975 64.906 68.735 0.0 0.1 0.1 0.0 0.0 VB BVW VB BB 130CIBZ 140CIBZ 120CIBZ 3.3351e5 1.9871e5 2.3873e5 2.1126e5 4.0013e5 66495 2782853 3117319 2827660 3518 .50 .25 .75 .00 .00 2900.20 240329.47 250945.80 234730.56 154.19 0.20 14.00 13.06 13.38 0.01 130CIBZ 140CIBZ 12DCIBZ 0.20 U-°° „ . -. 13.06 Q47 13.38 0.01 -0.6 Missing Component Report Component Air 1.1897e7 130133552.00 9.29e6 630.24 Expected Retention (Sample File) 1.845 630.24 Y. NOT DETECTED ON PRIMARY RUN: Z. NOT DETECTED ON PID TUT 004 1906 o o o i V3400A HALL Sample Name : 15 PPB Filename : n:\v3400s\SC11021.raw Method : SOOOSUE.ins tart Time : 0.00 min End Time : cale Factor: 0 Plot Offset: 70.00 min 4 mV Sample f: C NIX Date : 3/20/93 1:14 PM Time of Injection: 3/12/93 5:13 PM Low Point : 4.00 mV High Point : 39.00 mV Plot Scale: 35 mV espons e cn NJ C ro ( ri jAIR —IDCLDFME 1CLME 1VCL ^ ^m —ITCLFME 3 * ——IT-12DCLE ZJ111DCLEA 111TCLEA - •TCLE J12DCLPA .IBRDCLME J2CLETHYLVO- ^C-130CLPE - T-13DCLPE 112TCLEA TETCLE —(OBRCLME 50.73 ^1CHBR3 ——I1122TETCL -H123TRICLP M2DCLBZ -I TUT 004 1907 () 0 0 1 0 0 Software Version: 3.2 <16C20> Sample Name Sample Number operator ^sInstrument AutoSampler Rack/Vial 15 PPB C MIX V3400A/SALLY NONE 0/0 Time Study Channel 3/22/93 4:33 PM STD CHECK 0472 B A/D mV Range : 1000 Interface Serial # : 0159572256 Data Acquisition Time: 3/12/93 5:13 PM Delay Time 0.00 min. End Time 70.00 min. Sampling Rate 2.0000 pts/sec Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount n:\v3400s\TC11021.raw n:\v3400s\TC11021.rst N:\V3400S\8000SUE.ins N:\V3400S\PID.prc N:\V3400S\LINPTCll.smp N:\V3400S\SCll.seq 5 ml 1.0000 Area Reject : 100.00 Dilution Factor : 1.00 ITAS-KNOXVILLE V3400B J-l-W DB-624 75m*0.53mm ID,3.00um df ^HOTOIONIZATION DETECTOR: Percent differences, standard concentrations, and Cfs for FBz, o-Cl,F-Benzene, and B2ClIsopO are incorrect due to the compounds having a concentration different than the other compounds in the mix. The percent differences for these compounds and Cfs must be done manually. The computer could only calculate percent differences and Cfs from only one standard concentration. Standard check compared to l ,_> /9X linearity Peak * 0 6 17 21 27 32 33 35 39 41 44 46 SO 3 -64 55 56 57 70 71 74 Ret Time Cm in] 5.000 8.987 16.955 20.159 24.094 28.391 29.320 31.023 34.000 35.012 36.537 37.368 40.017 45.603 46.168 46.840 47.607 50.722 62.293 62.907 64.835 Component Name Air VCl 11DCIE T-120CIE C-12DCIE Bz FBz TCIE 2ClEthylVO C-130ClPe Toluene T-130ClPe TetClE ClBz EthylBz nt-Xylene o- C I, f- Benzene o-Xylene 130CIBZ UDCtBz 12DCIBZ Height tuV] 0.00 10969.20 41829.33 171883.89 71139.49 139879.88 189250.80 89579.20 19748.22 31603.05 137155.78 31433.12 54096.44 102292.76 83877.30 87206.75 126768.50 73622.53 143020.95 146188.77 120663.04 BL Cal. Range W VE VBWW VB BVWWW VE VE VB W W W W W BV VB BB CONCENTRATION STANDARD CON. PERCENT [PPB] (PPB) DIFFERECE 0 16 12 .00 .41 .94 13.80 14 13 90 14 10 12 13 13 14 14 14 14 93 14 14 14 14 .67 .12 .42 .63 .46 ^ .61 .89 .85 .38 .28 .37 .40 .97 .47 .40 .68 .35 15 15 15 15 15 15 Cf ' "^^ 15 ID -« 15 15 15 15 15 15 15 .000 .000 .000 .000 .000 .000 .000 •rfloo .000 .000 .000 .000 .000 .000 .000 -1.000e2 9.367 -13.718 • ,a - 8-°° s "- • -, 3-2.214 -12.553 "- C -S03-r866 -2.499 H t -30.243 -15.927 -7.387 -7.665 -4.135 -4.809 -- - '-4.217 -4.016 Component Name Air VCl 11DCIE T-12DCIE C-12DCIE Bz FBZ TCIE 2ClEthylVO C-130ClPe Toluene T-130ClPe TetClE ClBz EthylBz w-Xylene DAILY ^ Cf 0 0.0000 ^ 731.2800 2.7886e3 <? 1.1458e4 0 4.7426e3 '-' 9.3253e3 1.2616e4 j_ 5.9719e3 n 1.3165e3 t- 2.1068e3 9.1437e3 2.0955e3 3 • oUo^c3 . -. - * r^ f\ 6.8195e3 [_ 0 0 0 1 9 0 5.5918«3 5.8137e3 WWreee- '^ -Me.tet o-Cl.F-Benzene 8.4512e3 15 15 15 15 .000 .000 .000 .000 -3.534 -4.019 -2.149 -4.338 o-Xylene 13DCIBZ 140CIBZ 120CIBZ 4.9081e3 9.53A7e3 9.7459e3 8.0442e3 1.87e6 436.08 315.000 807.226 1.2481e5 0473 ITAS-KNOXVILLE V3400A RTX 502.2 105m*0.53mm ID,3.00um df PID DETECTOR-FBZ AND O-C1FBZ ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. ALL OTHER ANALYTES ARE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLUME OF 5.O ML. Peak * 1 2 3 4 5 6 7 8 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 '49 50 51 52 53 54 55 Ret Time RT DIFF. [minj X 5.666 6.603 7.066 7.701 8.299 8.987 9.516 9.615 11.808 12.451 13.985 15.031 15.628 15.885 16.547 16.955 18.838 19.026 19.736 20.159 21.024 21.439 21.806 22.458 23.422 24.094 24.803 25.447 26.599 27.736 28.391 29.320 30.521 31.023 31.824 32.780 33.232 34.000 34.814 35.012 35.797 36.048 36.537 36.927 37.368 37.669 38.144 39.285 40.017 41.145 44.348 45.603 46.168 46.840 0 0 0 0 0 -0 0 0 0 0 0 0 0 0 0 -0 0 0 0 -0 0 0 0 0 0 0 0 0 0 0 -0 -0 0 -0 0 0 0 -0 0 -0 0 0 -0 0 -0 0 0 0 -0 0 0 -0 -0 0 .0 .0 .0 .0 .0 .1 .0 .0 .0 .0 .0 .0 .0 .0 .0 .1 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 BL BB BB BB BB BV VE EV VB W VB BV VB BV W W VB BV W W W W W W W W W W W W W VB BV W W W W W W W W VE EV VE EV VE EV W W VB BV W W W W Component Name VCl 110CIE T-12DCIE C-12DCIE Bz FBZ TCIE 2ClEthylVO C-130ClPe Toluene T-130ClPe TetClE CIBZ EthylBz m-Xylene Area/ Amount 603.6285 4225.5464 5414.3481 12286.4199 10764.9531 7025.2632 7254.9370 10503.9707 11031.5967 78237.8750 31306.5078 36078.0508 33986.6328 44360.7305 28189.2793 92311.0234 1.0265e5 1.6315e5 73072.0469 1.2471e5 1.4705e5 1.9446e5 1.1259e5 45890.8242 33937.2852 60307.2148 64560.1367 2.0321e5 1.6587e5 90861.5938 16945.6445 79063.8047 44160.5234 1.2419e5 36123.0195 19566.0996 12715.3281 23373.9434 17459.3652 84905.6172 1.2803e5 78373.5469 1.1107e5 16091 .6250 20468.1406 36383.3828 54958.7969 34539.8828 55153.0117 1.6830e5 77728.0234 68119.5859 72544.9375 Area luV*sec] 9229.00 717.00 642.00 1434.50 2642.08 176599.59 9505.00 9748.40 15140.41 3651.31 6764.38 43226.34 8202.42 5793.86 9336.70 364832.50 2502.14 15740.36 6130.69 1008342.00 852.34 3383.64 7357.94 3000.88 9409.83 497789.94 6370.39 7589.59 7684.00 7363.08 1191833.13 1532239.25 1911.81 645655.36 7238.59 7264.66 5702.88 133048.33 4359.98 220179.25 30536.56 4914.50 1088765.88 2583.00 222872.36 2636.50 9051.56 2882.80 496673.19 3714.78 13035.00 1109856.75 978706.13 1044478.81 Height INST. Amt Cat. Component SAMPLE CON [uV] (ISX) Range Name (PPB) 2134. 107. 101. 177. 143. 10969. 904. 898. 963. 221. 279. 4462. 734. 550. 680. 41829. 337. 1909. 468. 171883. 85. 286. 471. 129. 994. 71139. 512. 570. 403. 473. 139879. 189250. 148. 89579. 357. 347. 504. 19748. 467. 31603. 3550. 378. 137155. 229. 31433. 245. 94 16 59 15 79 20 66 46 79 31 44 57 80 97 25 33 63 89 05 89 13 61 29 27 48 49 32 16 23 35 88 80 11 20 00 73 37 22 45 05 85 97 78 60 12 38 474.36 197. 54096. 253. 554. 102292. 83877. 87206. 33 44 39 84 76 30 75 0.00 1.19 0.15 0.27 0.22 16.41 1.35 1.34 1.44 0.33 0.09 1.38 0.23 0.17 0.21 12.94 0.03 0.15 0.04 13.80 0.01 0.02 0.04 0.03 0.21 14.67 0.11 0.12 0.04 0.04 13.12 90.42 0.02 14.63 0.06 0.20 0.29 10.46 0.19 12.61 0.36 0.04 13.89 0.02 13.85 0.13 0.25 0.05 14.38 0.07 0.08 14.28 14.37 14.40 -15.00 -13.81 -14.85 -14.74 -14.79 VCl 1.41 -13.65 -13.66 -13.56 -14.67 -14.91 -13.62 -14.77 -14.83 -14.79 11DCIE -2.06 -14.97 -14.85 -14.96 T-12DCIE -1.20 -14.99 -14.96 -14.96 -14.97 -14.80 C-12DCIE -0.33 -14.89 -14.86 -14.96 -14.96 Bz -1.88 FBz 75.42 -14.98 TCIE -0.38 -14.94 l> -14.80 £ -14.71 ^ 2ClEthylVO -4.54 -14.81 C-130ClPe -2.39 2 -14.64 o -14.96 Toluene -1.11 -14.98 5 T-13DCIPC -1.15 H- -14.87 -14.75 -14.95 TetClE -0.62 -14.93 , ,. -N 'v i 0 , -14.92 L '-' u ' ' -' ' ' CtBz -0.72 EthylBz -0.63 m-Xylene -0.60 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 47.607 50.722 52.785 53.404 54.954 55.990 56.619 57.323 57.710 58.623 59.442 60.142 60.948 61.238 62.293 62.907 63.717 64.084 64.835 65.832 66.190 66.486 67.024 67.710 67.990 68.328 68.473 68.685 68.910 69.121 69.379 0.0 W 0.0 W 0.0 W 0.0 W 0.0 W 0.0 W 0.0 VB 0.0 BV 0.0 W 0.0 W 0.0 VB 0.0 BV 0.0 W 0.0 VB 0.0 BV 0.0 VB 0.0 BV 0.0 VB 0.0 BB 0.0 BB 0.0 BB 0.0 BV 0.0 VB 0.0 8V 0.0 VB 0.0 BV 0.0 W 0.0 W 0.0 W 0.0 VB 0.0 BB o-Cl,F-8en 16165.0869 o-Xylene 59722.9648 .3064e5 .4593e5 .1S93e5 .0594e5 .1173e5 .1919e5 95620.2266 2.9823e5 1.0630eS 1.1736e5 91256.7578 98589.7578 13DCIBZ 67075.0547 UDClBz 62848.8984 61379.4180 1.1296e5 120CIBZ 51561.3906 41948.4766 52167.3242 49077.8594 1.0308e5 81694.4453 61433.5703 42414.8672 53084.8359 80577.5547 76145.8516 38969.0508 59765.8320 1519068.75 126768.50 864181.56 73622.53 14601.88 568.67 10284.88 358.58 4957.44 217.57 3408.75 163.71 2349.63 208.90 4767.39 397.32 2425.16 251.95 5047.06 168.12 1007.37 94.13 7238.42 612.69 3469.08 377.64 779.99 78.59 965687.38 143020.95 922470.13 146188.77 364.28 59.11 44891.22 3341.79 739868.50 120663.04 235.50 47.21 651.75 105.06 10831.81 1855.92 1192.17 97.25 1093.91 112.60 1073.59 146.95 369.43 73.24 429.26 68.00 989.38 103.25 2248.56 248.32 315.88 68.16 635.50 89.41 93.97 14.47 0.11 0.07 0.04 0.03 0.02 0.04 0.03 0.02 0.01 0.06 0.04 0.01 14.40 14.68 0.01 0.40 14.35 0.01 0.01 0.22 0.01 0.01 0.02 0.01 0.01 0.01 0.03 0.01 0.01 o-Cl,F-Ben 78.97 o-Xyleoe -0.53 0 4 7 4 -14.89 -14.93 -14.96 -14.97 -14.98 -14.96 -14.98 -14.98 -14.99 -14.94 -14.96 -14.99 130CIBZ -0.60 UDCLBz -0.32 -14.99 -14.60 120CIBZ -0.65 -14.99 -14.99 -14.78 -14.99 -14.99 -14.98 -14.99 -14.99 -14.99 -14.97 -14.99 -14.99 -0.2 Missing Component Report Component Air 6.0850e6 16148262.00 1.90e6 448.27 Expected Retention (Sample File) 5.000 -826.73 Y. NOT DETECTED ON PRIMARY RUN: Z. NOT DETECTED ON HALL TUT OO4 1910 I 000\ 91 . V3400A PID Sample Name : 15 PPB FileName : n:\v3400s\TC11021.raw Method : SOOOSUE.ins art Time : 0.00 min End Time : 70.00 min ,cale Factor: 0 Plot Offset: 4 mV Sample *: C MIX Date : 3/20/93 1:H PM Time of Injection: 3/12/93 5:13 PM Lou Point : 4.00 MV High Point : 39.00 mV Plot Scale: 35 mV 0475 Response [ nn V ] CT O en _L_L N) O NJ en O AJ A I R VCL 13.99 -15.03 11DCLE T-12DCLE cn iiaetii = __J12DCLBZ .08 TUT 004 1911 —16.9 — ——— —II — — — — -C^26.60 C-13DCLPE - j^sS&Jl- ~^3li QS ——— 35.80 zC39-29 t" J>-44.35 n-CI,F-BF —— = —————————————————————————————————— O-XYLEME - —— __ — 34.00 35.01 ——————————————————————————————————————————————————————————————— . i? A 0476 BLANK DATA TUT OO4 191.2 L 0001913 HALOGENATED AND AROMATIC VOLATILE ORGANIC ANALYSIS 0477 Laboratory Name ITAS - KNOXVILLE SDG Number NA "ontract Name L'HENRI Job Number ITEK 53554 lient Sample I.D. METHOD BLANK Collection Date NA Dab Sample I.D. B2880 Confirmation Date NA Sample Matrix WATER Analysis Date(s) 03/10/93 Concentration Units ug/1 Dryness Factor NA DETECTION COMPOUND jlichlorodif luorome thane shlorome thane /inyl chloride sromome thane ::hl oroe thane trichlorof luorome thane 1,1- dichloroethene nethylene chloride GAS No. RESULTS 75-71-8 1.8 74-87-3 0.8 75-01-4 1.8 74-83-9 1.2 75-00-3 5.2 75-69-4 2.0 75-35-4 1.3 75-09-2 15 :rans- 1,2 -dichloroethene 156-60-5 1.0 L, 1-dichloroethane ~is - 1 , 2 -dichloroethene trichloromethane L, 1, l-trichloroethane carbon tetrachloride Denzene 1,2- dichloroethane :richloroethene L , 2 - dichloropropane Dromodichlorome thane q ibromomethane 75-34-3 0.7 156-59-2 1.0 67-66-3 0.5 71-55-6 0.3 56-23-5 1.2 71-43-2 2.0 107-06-2 0.3 79-01-6 1.2 78-87-5 0.4 75-27-4 1.0 74-95-3 -chloroethyl vinyl ether 110-75-8 1.3 *is-l, 3-dichloropropene :oluene 10061-01-5 3.4 108-88-3 2.0 :rans-l, 3-dichloropropene 10061-02-6 3.4 L , 1 , 2 - trichloroethane ;etrachloroethene iibromochlorome thane i-hexyl chloride ;hlorobenzene =thyl benzene 79-00-5 0.2 127-18-4 0.3 124-48-1 0.9 544-10-8 108-90-7 2.0 100-41-4 2.0 QUALIFIERS LIMITS U 1. U 0. U 1. U 1. U 5. U 2. U 1. U 15 U 1. U 0. U 1. U 0. U 0. U 1. U 2. U 0. U 1. U 0. U 1. - U 1. U 3. U 2. U 3. U 0. U 0. U 0. - U 2. U 2. 8 8 8 2 2 0 3 0 7 0 5 3 2 0 3 2 4 0 3 4 0 4 2 3 9 0 0 L, 1,1, 2 -tetrachloroethane 630-20-6 cylenes (total) Dromof orm 1330-20-7 1.0 75-25-2 2.0 L, 1,2, 2 -tetrachloroethane 79-34-5 0.3 L , 2 , 3 - trichloropropane 96-18-4 U 1. U 2. U 0. - 0 0 3 Dhenyl bromide (bromobenzene) 108-86-1 2 - chlorotoluene L , 3 - dichlorobenzene L , 4 - dichlorobenzene L, 2 -dichlorobenzene 108-41-8 541-73-1 3.2 106-46-7 2.4 95-50-1 1.5 - U 3. U 2. U 1. 2 4 5 3is (2-chloroisopropyl) ether 108-60-1 SURROGATE RECOVERY ACCEPTANCE LIMITS SOIL WATER LAB I.D. B2880 BCM OCFB FB (31-112) (34-113) (23-113) (53-150) (64-121) (70-128) 89 98 103 OFCB BLANK APPLIES TO: rnr» TT\ n T •» HTTT (21-108) DRM01 (72-122) DRMO1MS DRM01 MSD 100 -OflOl„. TUT OO4 1913 0478 Software Version: 3.2 <16C20> Sample Name Sample Number Operator Instrument AutoSampler Rack/Vial BLANK BLANK V3400A/SALLY NONE 0/0 Time Study Channel 3/11/93 BLANK 10:35 AM A/D mV Range : 1000 Interface Serial Delay Time End Time Sampling Rate Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount Noise Threshold Multiplier # : 0159572256 0.00 min. 70.00 min. 2.0000 pts/sec Data Acquisition Time: 3/10/93 11:34 PM n:\v3400s\SC10012.raw n:\v3400s\SC10012.rst N:\V3400S\8000SUE.ins N:\V3400S\HALL.prc N:\V3400S\LINHSC10.smp n:\v3400s\scl0.seq 5 mL 1.0000 Area Reject : 100.00 Dilution Factor : 1.00 15 1.0000 Area Threshold : 73 Bunch Factor: 2 Divisor : 1.0000 Adder : 0.0000 Instrument Conditions: Total Number of Peaks Detected: 18 ITAS-KNOXVILLE V-3400B J+W DB-624 75m*0.53mm ID, 3.00um df ELECTROLYTIC CONDUCTIVITY DETECTOR-BrClMe AND O-ClFBz ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. Ai: OTHER ANALYTES ARE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLUME OF 5.O ML. Peak tt 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 Ret Time RT DIFF. BL Cm in] X 5.764 7.192 8.453 9.492 12.623 18.817 19.120 24.884 25.495 29.398 31.350 33.069 40.267 45.854 47.744 63.093 64.954 68.708 0.0 BV 2.5 W 1.6 W 4.6 VB 1.2 BB 0.0 BV 0.1 VB 0.2 BV -0.0 VV 0.0 W 0.7 W 0.8 W 0.3 VB 0.2 BV •0.0 VB 0.2 BB 0.1 BB 0.0 BB Component Name DClDFMe CLME vet ClEa CH2C12 CHC13 BrClMe TCIE BrDClMe TetClE ClBz o-Cl,F-Ben 140CIBZ 120CIBZ Area/ Amount 61485.7070 1.0903e5 2.6469e5 7.8527e5 1.6287e5 6.6937e5 4.8702e5 6.0693e5 66503.6953 7.4439e5 2.3S34e6 1.9205e6 4.2711e6 2.8009e5 41287.4961 1.9398e6 2.5427e5 2.5033e5 Area [uv*sec] 52649.38 21499.03 11450.08 25534.25 804.25 2321.38 120740.13 15814.56 5895552.50 132667.50 44481.13 67729.00 18032.88 10132.53 4065507.75 11813.00 28125.00 1199.50 Height 1NST. Amt Cal. Component SAMPLE CON [uVJ USX) Range Name (PPB) 2482. 561. 286. 248. 59. 108. 7736. 921. 446175. 4232. 589. 791. 129. 336 239277. 117 1992. 86. 30 15 04 56 91 23 71 96 .44 .77 99 .91 7? .64 86 .64 ,94 .33 0.86 0.20 0.04 0.03 0.01 0.00 0.25 0.03 88.65 0.18 0.02 0.04 0.00 0.04 98.47 0.01 0.11 0.01 DClDFMe CLME VCl ClEa CH2C12 CHC13 BrClMe TCIE BrOClMe TetClE ClBz o-Cl,F-Ben UOClBz 120CIBZ 0 0 0 0 0 0 0 0 88 0 0 0 0 0 98 0 0 0 .86 .20 .04 .03 .01 .00 .25 .03 .65 .18 .02 .04 •°° / Oi .04 <- U .47 .01 .11 .01 •3- T-i 0- wO 000191-- 12.3 1.5298e7 1052605*.00 706136.06 188.92 188.92 Missing Component Report Component Expected Retention (Sample File) Air 1.845 3rMe 11.919 ^TClFMe 14.003 11DC1E 17.038 T-12DC1E 20.238 2756111DClEa 21.838 C-12DC1E 24.188 UlTClEa 26.633 CC14 27.774 12DC1E3 28.393 12DC1P3 31.870 2ClEthylVO 34.116 C-13DClPe 35.123 T-13DC1P6 37.487 112TClEa 38.300 DBrClMe 41.272 CHBr3 53.534 1122TetClEa 54.996 123TriClPropane 56.030 13DC1BZ 62.384 Y. NOT DETECTED ON PRIMARY RUN: Z. NOT DETECTED ON PID L 000 TUT OO4 1915 V3400A HALL 0 4 8 0 Sample Nem : BLANK Filename : n:\v3400t\SC10012.ran Method : SOOOSUE.ins Start Time : 0.00 min End Time : 70.00 min ,cale Factor: 0 Plot Offset: 4 mV Sample *: BLANK Date : 3/11/93 10:36 AM Time of Injection: 3/10/93 11:34 PH Low Point : 4.00 mV High Point : 39.00 mV Plot Scale: 35 mV es JAIR OCLOFME CLME VCL IKS --x 5.76 1 = d-12.62 —M1DCLE •ICH2CL2 U-CB 1T-12DCLE - ( Z! 27561 11DC - i H C-12DCLE - J ftffiL i - HJ111TCLEA - -24.88 IBROCLME 2CLETHYLVO- IC-130CLPE - -19.12 — — -- 25 29.40 1T-130CLPE - '112TCLEA - _——JTETCLE -" —JOBRCLME - 1-40.27 j i _|CLB2 - -W5.85 —i -4 _|0-CL,F-BE - ————— 3] CHBR3 ——J1122TETCL - —J123TRICLP - - '-63.09 i12DCLBZ - ~- >-66B71 L 0 0 0 1 9 1 , TUT OO4 1916 0481 Software Version: 3.2 <16C20> Sample Name Sample Number Operator Instrument AutoSampler Rack/Vial BLANK BLANK V3400A/SALLY NONE 0/0 Time Study Channel : B 3/11/93 BLANK 10:37 AM A/D mV Range : 1000 Interface Serial Delay Time End Time Sampling Rate Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount Noise Threshold Multiplier # : 0159572256 0.00 min. 70.00 min. 2.0000 pts/sec Data Acquisition Time: 3/10/93 11:34 PM n:\v3400s\TC10012.raw n:\v3400s\TC10012.rst N:\V3400S\8000SUE.ins N:\V3400S\PID.prc N:\V3400S\LINPTC10.smp n:\v3400s\scl0.seq 5 ml 1.0000 10 1.0000 Area Reject : 100.00 Dilution Factor : 1.00 Area Threshold : 49 Bunch Factor: 2 Divisor : 1.0000 Adder : 0.0000 Instrument Conditions: Total Number of Peaks Detected: 63 ITAS-KNOXVILLE V3400A RTX 502.2 105m*0.53mm ID,3.00um df PID DETECTOR-FEZ AND O-ClFBz ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. ALL OTHER ANALYTES ARE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLUME OF 5.O ML. Peak * 1 2 3 5 6 7 9 10 11 12 13 14 15 16 • 17 18 19 20 21 22 23 24 Ret Time RT DIFF. CmirO X 5 AJIT .OOj 6.612 7.100 8.677 9.391 10.183 13.785 15.061 15.650 15.921 16.578 19.036 19.744 20.182 21.458 22.207 23.451 25.460 28.414 29.343 31.046 31.375 0.0 0.0 0.0 -3.6 0.0 0.0 0.0 0.0 0.0 0.0 -2.3 0.0 0.0 0.0 0.0 0.0 0.0 0.0 -0.1 -0.1 -0.1 0.0 BL Component Name BB BB BB W VCl W VB BB BB BV W VB 11DCIE BV W W T-12DCIE W W W W VB BZ BV FBI W TCIE W Area/ Amount 611.5607 6141.6201 12349.4971 9824.0264 9878.4971 66561.0234 34741 .3633 36921.2031 37290.6523 72530.3047 2.1764e5 2.1029e5 2.5243e5 2.1357e5 53998.6641 1.3824e5 97251.9219 1.0521e5 16968.2891 1.6284*5 7.0149e5 Area CuV*sec] 35146.00 1211.00 784.00 2937.78 40527.09 11665.45 4591.00 113444.52 23800.52 137. -.67 36*4.53 4059.03 4808.44 3079.39 5841.22 1470.11 3505.09 11274.88 33285.78 1749967.50 6430.47 32176.50 Height 1NST. Amt Cat. Component SAMPLE CON [uV] (1SX) Range Name \PPB) 6092.42 170.72 90.80 169.21 2934.33 839.97 252.72 11964.43 2361.93 1347.05 184.11 250.30 306.87 163.72 367.06 138.58 129.06 590.11 3579.65 215648.25 253.95 294.98 0 1 0 0 4 1 0 3 0 0 0 0 0 0 3 0 0 0 0 103 0 " .00 .98 .13 .24 .13 .18 .07 .27 .65 .37 .05 .02 .02 .01 .03 .03 .03 .12 .32 .13 .04 nc 0 1 0 VCl 0 4 1 0 3 0 0 110CIE 0 0 0 T-12DCIE 0 0 0 0 0 Bz 0 FBz 103 TCIE 0 " .00 .98 .13 .24 .13 .18 .07 .27 .65 .37 .05 .02 .02 .01 .03 .03 .03 .12 .32 .13 .04 fC f~^ 0- •H ^ o H- h- i 0 0 0 1 9 1 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 34.715 35. 550 36.074 36.568 39.325 40.048 45.659 46.223 46.898 47.664 50.794 52.833 56.650 57.351 57.744 59.297 60.159 61.833 62.323 62.918 64.106 64.356 64.854 65.218 65.463 65.679 65.835 66.203 66.500 66.988 67.579 67.716 67.998 68.238 68.471 68.898 69.130 69.369 69.709 -1.0 W 0.0 W 0.0 W -0.1 W 0.0 W -0.1 W -0.0 W -0.0 VB -0.0 BV -0.0 W 0.0 W 0.0 W 0.0 VB 0.0 BV 0.0 VB 0.0 BV o.o vv 0.0 W 0.0 V8 -0.0 BB 0.0 BE 0.0 EV 0.0 VB 0.0 BB 0.0 BV 0.0 W 0.0 VB 0.0 BB 0.0 BB 0.0 BB 0.0 8V 0.0 W 0.0 W 0.0 W 0.0 W 0.0 W 0.0 W 0.0 W 0.0 VB C-13DCIP* 71915.359* 43968.3359 1.9703«5 Toluene 1.2445e5 45303.4648 TetClE 81633.3516 ClBz 1.2628e5 EthylBz 76035.2656 m-Xylene 80283.6563 o-Cl,F-Ben 15806.5596 o-Xylene 81587.8672 1.2448e5 4.0041e5 1.1812e5 1.0000e5 1.5420e5 1.4245e5 2.0335e5 13DCIBZ 76693.9219 UDClBz 1.1848e5 1.3092e5 1.0020e5 12DCIBZ 56832.8672 44820.4102 84111.3906 54358.2813 54873.4961 50548.2344 48399.9883 82278.1172 47687.6602 67023.3516 58264.4258 64344.9063 1.0556e5 1.2271e5 49700.1484 92506.5469 49382.9961 4291.16 2870.78 9558.11 21151.19 3783.61 2084.13 17136.88 11518.05 19253.84 1585086.63 9070.72 10377.78 8067.63 12066.89 5629.61 3216.91 25203.81 2535.14 2183.64 4493.00 36597.14 3969.00 11497.11 251.00 2349.27 941.08 1024.15 1876.50 24116.49 1404.25 367.67 2237.71 2831.20 784.94 1844.54 4644.92 1068.02 4818.02 452.98 154.37 168.91 507.81 1779.01 329.48 100.72 1007.61 936.47 1523.83 131266.92 597.36 447.93 206.22 1045.52 576.14 213.51 1810.79 127.60 291.41 388.74 2419.84 342.88 1751.28 48.48 241.79 149.88 161.57 321.37 4313.56 147.75 66.75 289.03 420.66 105.61 151.26 327.68 186.03 450.88 79.41 0.06 0.07 0.05 0.17 0.08 0.03 0.14 0.15 0.24 100.28 0.11 0.08 0.02 0.10 0.06 0.02 0.18 0.01 0.03 0.04 0.2B 0.04 0.20 0.01 0.03 0.02 0.02 0.04 0.50 0.02 0.01 0.03 0.05 0.01 0.02 0.04 0.02 0.05 0.01 C-13DClPe 0.06 0 4 8 2 0.07 "•»««. 0.05 Toluene 0.17 0.08 TetClE 0.03 ClBz 0.14 EthylBz 0 . 1 5 m-Xylene 0.24 o-Ct,F-Ben 100.28 o-Xytene 0.11 0.08 0.02 0.10 0.06 0.02 0.18 0.01 13DCI8Z 0.03 14DCIBZ 0.04 0.28 0.04 12DCIBZ 0.20 0.01 0.03 0.02 0.02 0.04 0.50 0.02 0.01 0.03 0.05 0.01 0.02 0.04 0.02 0.05 0.01 -7.3 6.2038e6 3970016.00 403586.19 219.13 219.13 Missing Component Report Component Expected Retention (Sample File) Air C-12DC1E 2ClEthylVO T-13DC1P6 5.000 24.122 34.045 37.423 Y. NOT DETECTED ON PRIMARY RUN: Z. NOT DETECTED ON HALL TUT O04 1918 O O t i i V3400A PID 0483 Sample Naae : BLANK Filename : n:\v3400t\TC10012.raw Method : BOOOSUE.ins start Time : 0.00 niin End Time : 70.00 min ,cale Factor: 0 Plot Offset: 4 mV Sanple «: BLANK Date : 3/11/93 10:37 AM Time of Injection: 3/10/93 11:34 PM Low Point : 4.00 mV High Point : 39.00 mV Plot Scale: 35 mV Respons H lAIR - 1 —| ':« 0~3 VCL -5.68 9.39 11DCLE T-120CLE - —JC-120CLE - n d ez HF8Z ,g.65 25.46 -28.41 2CLETHYLVO C-130CLPE TOLUEME - T-130CLPE - TETCLE - J ,, ^ - - 0-XYLEME - mm 12DCLBZ 66.50 -15.06 . 0 0 0 1 9 . ' " TUT 004 1919 Errors and Warnings From Data Processing 0 4 fi i Data File: n:\v3400s\TC10012.raw oq Date/Time: 3/11/93 10:37 AM 2UANT: Response Is Outside Calibration Curve Domain For: Air QUANT: Calibration Curve Has Two Solutions For: Air (17.0595) L 000192. TUT 004 192O HALOGENATED AND AROMATIC VOLATILE ORGANIC ANALYSIS 0485 Laboratory Name ITAS-KNOXVILLE Contract Name L'HENRI 'lient Sample I.D. METHOD BLANK Lab Sample I.D. B2881 Sample Matrix WATER Concentration Units ug/1 SDG Number NA Job Number ITEK Collection Date NA Confirmation Date NA 53554 Analysis Date(s) 03/12/93 Dryness Factor NA DETECTION COMPOUND CAS No. dichlorodifluoromethane 75-71-8 chloromethane 74-87-3 vinyl chloride 75-01-4 Dromome thane 74-83-9 chloroethane 75-00-3 trichlorofluoromethane 75-69-4 1, 1- dichloroethene 75-35-4 nethylene chloride 75-09-2 trans - 1 , 2 -dichloroethene 156-60-5 L, 1-dichloroethane 75-34-3 cis- 1,2 -dichloroethene 156-59-2 trichloromethane 67-66-3 1,1,1- trichloroethane 71-55-6 rarbon tetrachloride 56-23-5 oenzene 71-43-2 L,2-dichloroethane 107-06-2 :richloroethene 79-01-6 L,2-dichloropropane 78-87-5 Dromodi chloromethane 75-27-4 iibromome thane 74-95-3 -chloroethylvinyl ether 110-75-8 iis-1, 3-dichloropropene 10061-01-5 :oluene 108-88-3 :rans-l, 3-dichloropropene 10061-02-6 L, 1, 2- trichloroethane 79-00-5 :etrachloroethene 127-18-4 iibromochloromethane 124-48-1 i-hexyl chloride 544-10-8 :hlorobenzene 108-90-7 =thyl benzene 100-41-4 L, 1, 1,2-tetrachloroethane 630-20-6 cylenes (total) 1330-20-7 Dromoform 75-25-2 L , 1 , 2 , 2 - tetrachloroethane 79-34-5 L,2, 3-trichloropropane 96-18-4 Dhenyl bromide (bromobenzene) 108-86-1 2-chlorotoluene 108-41-8 L, 3-dichlorobenzene 541-73-1 L, 4-dichlorobenzene 106-46-7 L, 2-dichlorobenzene 95-50-1 Dis (2-chloroisopropyl) ether 108-60-1 SURROGATE RECOVERY BCM OCFB ACCEPTANCE LIMITS SOIL (31-112) (34-113) WATER (53-150) (64-121) LAB I.D. B2881 69 83 RESULTS QUALIFIERS LIMITS 1.8 U 1 0.8 U 0 1.8 U 1 1.2 U 1 5.2 U 5 2.0 U 2 1.3 U 1 . 8 .8 .8 .2 .2 .0 .3 15 U 15 1.0 U 1 0.7 U 0 1.0 U 1 0.5 U 0 0.3 U 0 1.2 U 1 2.0 U 2 0.3 U 0 1.2 U 1 0.4 U 0 1.0 U 1 . 1.3 U 1 3.4 U 3 2.0 U 2 3.4 U 3 0.2 U 0 0.3 U 0 0.9 U 0 . 2.0 U 2 2.0 U 2 0.3 U 0 1.0 U 1 2.0 U 2 0.3 U 0 - - . 3.2 U 3 2.4 U 2 1.5 U 1 - .0 .7 .0 .5 .3 .2 .0 .3 .2 .4 .0 .3 .4 .0 .4 .2 .3 .9 .0 .0 .3 .0 .0 .3 .2 .4 .5 FB OFCB BLANK APPLIES TO: ———————— ———————— DRM01 Dl: (23-113) (21-108) (70-128) (72-122) L O O O J 20 92. TUT 004 1921 Software Version: 3.2 <16C20> Sample Name Sample Number Operator 'instrument AutoSampler Rack/Vial METHOD BLANK B2881 V3400A/SALLY NONE 0/0 Time Study Channel : A 3/12/93 9:55 AM METHOD BLANK 0486 A/D mV Range : 1000 Interface Serial # : 0159572256 Data Acquisition Time: 3/12/93 12:46 AM Delay Time End Time Sampling Rate Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount Noise Threshold Multiplier 0.00 min. 70.00 min. 2.0000 pts/sec n:\v3400s\SC11008.raw n:\v3400s\SC11008.rst N:\V3400S\8000SUE.ins N:\V3400S\HALL.prc N:\V3400S\LINHSCll.smp n:\v3400s\scll.seq 5 mL 1.0000 Area Reject : 100.00 Dilution Factor : 1.00 15 1.0000 Area Threshold : 73 Bunch Factor: 2 Divisor : 1.0000 Adder : 0.0000 Instrument Conditions: Total Number of Peaks Detected: 19 ITAS-KNOXVILLE V-3400B J+ W DB-624 75m*0.53mm ED, 3.00um df ELECTROLYTIC CONDUCTIVITY DETECTOR-BrClMe AND O-C1FBZ ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. ALL OTHER ANALYTES ARE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLUME OF 5.0 ML. Peak « 1 2 3 4 5 6 7 8 9 10 11 12 13 H , 15 16 17 18 19 Ret Time RT D1FF. [min] X 5.773 7.210 9.494 12.366 14.199 19.103 24.874 25.486 26.640 29.397 31.251 33.076 40.346 45.883 47.795 62.461 63.056 64.936 68.675 0.0 2.3 4.5 -0.9 1.4 0.1 0.3 0.1 0.2 0.0 0.5 0.9 0.6 0.4 0.2 0.2 0.2 0.1 0.0 BL BVW WW VB BB BV VE EV WWW VB BV VB BV VB BB BB Component Name OClDFHe VCl ClEa TClFMe CH2C12 CHC13 BrClMe 111TClEa TCIE BrOClMe TetClE ClBz o-Cl,F-Ben 13DCIBZ 140CIBZ 12DCIBZ Are*/ Amount 54809.8164 1.4657e5 9.1437e5 2.6257e5 1.2347e6 4.7694e5 5.2844e5 65166.3125 1.3973e6 7.2474e5 2.1125.6 2.7093e6 2.9759e6 3.1320e5 43079.2031 4.5235e5 4.8223e5 2.3216e5 2.4397e5 Area [uV*sec] 21044.00 21797.16 36328.50 2438.38 8798.88 343910.50 11232.59 U74901.00 320589.50 115743.56 41135.91 118660.63 24956.25 10973.25 3572165.25 2952.38 6078.63 23671.25 1175.00 Height INST. Amt [uV] (ISX) 1274. 491. 330. 96 109 26585 . 710. 3495U. 6363. 3645 590 944 246 312 207633 94 220 1788 84 .20 .51 .00 .80 52 93 . 14 13 70 85 .02 12 .10 .13 58 .70 .52 .13 .46 0.38 0.15 0.04 0.01 0.01 0.72 0.02 68.67 0.23 0.16 0.02 0.04 0.01 0.04 82.92 0.01 0.01 0.10 0.01 Cal. Component SAMPLE CON Range Name (PPB) DClOFNe VCl ClEa TClFHe CH2C12 CHC13 BrClMe 111TClEa TCIE BrOClMe TetClE ClBz o-Cl,F-Ben 13DCIBZ 14DCIBZ 120CIBZ 0.38 0.15 0.04 0.01 0.01 0.72 0.02 68.67 0.23 0.16 0.02 0.04 0.01 0.04 82-92 i_ 0 0 0 I 0.01 • ' J 0.01 0.10 0.01 N CN 0- h- IDH 9 2 o 11.0 1.5370e7 9158552.00 601035.94 153.54 153.54 Missing Component Report 0487 Component Expected Retention (Sample File) Air 1.845 ~LME 8.348 ,BrMe 11.932 TCLTFEa 16.467 11DC1E 17.025 T-12DC1E 20.219 HlDClEa 21.813 C-12DC1E 24.149 CC14 27.735 12DC1E3 28.355 12DClPa 31.839 2ClEthylVO 34.083 C-13DC1P6 35.088 T-13DC1P6 37.446 112TClEa 38.257 DBrClMe 41.217 CHBr3 53.470 1122TetClEa 54.941 123TriClPropane 55.974 Y. NOT DETECTED ON PRIMARV RUN: Z. NOT DETECTED ON PID TUT 004 I 000192. U488 V3400A HALL Sample Name : METHOD BLANK Filename : n:\v3400s\SC11008.raw Method : BOOOSUE.ins Start Time : 0.00 min End Time : 70.00 min Scale Factor: 0 Plot Offset: 4 mV Sample «: 82881 Date : 3/12/93 9:56 AM Time of Injection: 3/12/93 12:46 AM Low Point : 4.00 mV High Point : 39.00 mV Plot Scale: 35 mV _)AIR X — ^DCLOFME —;CLME — ITCLFME T, =l CH2CL2 T-12DCLE 111DCLEA i CLE E 111TCLEA JTCLE |12DCLPA BROCLME 2CLETHYLVO C-13DCLPE ~T-130CLPE — |112TCLEA iTETCLE — lOBRCLME _|CLBZ ZO-CL,F-BE - ^45.88 -19.10 26.64 1CH8R3 - I 4 ^1122TETCL - ^123TRICLP - CD O" _lll20CLBZ I H L 0 0 0 1 9 2 - . TUT O04 1924 0489 Software Version: 3.2 <16C20> Sample Name Sample Number Operator Instrument AutoSampler Rack/Vial METHOD BLANK B2881 V3400A/SALLY NONE 0/0 Time Study Channel B 3/12/93 9:56 AM METHOD BLANK A/D mV Range : 1000 Interface Serial # : 0159572256 Data Acquisition Time: 3/12/93 12:46 AM Delay Time End Time Sampling Rate Raw Data File Result File Instrument File Process File Sample File Sequence File Inj. Volume Sample Amount Noise Threshold Multiplier 0.00 min. 70.00 min. 2.0000 pts/sec n:\v3400s\TC11008.raw n:\v3400s\TC11008.rst N:\V3400S\8000SUE.ins N:\V3400S\PID.prc N:\V3400S\LINPTCll.smp n:\v3400s\scll.seq 5 ml 1.0000 Area Reject : 100.00 Dilution Factor : 1.00 10 1.0000 Area Threshold : 49 Bunch Factor: 2 Divisor : 1.0000 Adder : 0.0000 Instrument Conditions: Total Number of Peaks Detected: 47 ITAS-KNOXVILLE V3400A RTX 502.2 105m*0.53mm ID,3.00um df PID DETECTOR-FBZ AND O-C1FBZ ARE SURROGATES SPIKED AT 30PPB BUT ARE ENTERED INTO THE COMPUTER AT 100 TO GIVE RESULTS AS PERCENT. ALL OTHER ANALYTES ARE REPORTED IN TERMS OF PPB. ALL SAMPLES AND STANDARDS HAVE A FINAL PURGE VOLUME OF 5.0 ML. Peak t> 1 2 3 5 6 7 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 Ret Time ftT OIFF. [min] X 5.694 6.642 7.091 8.689 9.407 10.208 13.802 15.060 15.648 15.915 16.579 19.029 19.728 20.165 21.443 22.202 23.426 25.450 28.409 29.341 31.045 31.342 0.0 0.0 0.0 -3.4 0.0 0.0 0.0 0.0 0.0 0.0 -2.3 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.1 0.1 0.0 0.0 BL Component Name BB BB BB W VCt W VB BV VB BVW W 110CIE WW W T-120CIE W W W W W Bz W FBZ W TCtE W Area/ Amount 600.9934 4271.5820 10739.7715 11883.6270 10420.6094 84995.4844 30442.1270 32249.2910 34088.3086 93478.8281 2.1522e5 1.8775e5 2.2690e5 1.8424e5 1.4103e5 94769.1094 70771.2500 1.0240e5 17028.7559 55667.7422 66127.8828 Area [uV*sec] 6761.00 722.50 588.50 1140.31 22312.56 4954.92 3469.63 70349.39 12013.33 8905.67 4473.72 4639.84 5685.83 4025.66 5080.09 2813.53 2387.75 7190.22 31524.13 1503886.25 1220.80 1244.23 Height INST. Amt Cat. Component SAMPLE CON [uV] (ISX) Range Name (PPB) 1592 108 92 71 1255 317 131 7468 1203 844 154 266 377 220 343 96 122 492 3282 184842 134 115 .06 .37 .12 .00 .45 .94 .93 .90 .97 .37 .6fl .52 .21 .99 .44 .75 .20 .75 .75 .28 .32 .25 0.00 1.20 0.14 0.11 1.88 0.48 0.04 2.31 0.37 0.26 0.05 0.02 0.03 0.02 0.03 0.02 0.03 0.10 0.31 88.32 0.02 0.02 0 1 0 vci o 1 0 0 2 0 0 11DCIE 0 0 0 T-120CIE 0 0 0 0 0 Bz 0 FBZ 88 TCIE 0 0 .00 .20 .14 .11 .88 .48 .04 .31 .37 .26 .05 .02 .03 .02 .03 .02 .03 , ( .10 i- " .31 .32 .02 .02 iTiN 0- •H «3" O :-' H h- '•- r, 1 (\ •n \ ) , 1 } -J~ 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 35.561 36.09* 36.594 39.364 45.708 46.273 46.949 47.714 50.858 52.867 57.352 60.229 62.312 62.920 64.087 64.841 65.501 66.481 66.920 67.963 68.929 69.106 69.390 1.5 0.0 0.1 -1.7 0.2 0.2 0.2 0.2 0.3 0.0 0.0 0.0 0.1 0.1 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 w w w VB 8V W VB BV VB BV VB BV W VB BB 66 BB BV VB BB B8 BB BB C-130ClPe Toluene TetClE ClBz EthylBl m-Xyleoe o-Cl,F-Ben o-Xylene 13DCIBZ 14DCIBZ 12DCIBZ 3.3488«5 1.9831*5 1.1834*5 65993.1016 1.2806*5 76366.8672 77260.6094 16220.2022 83964.8438 1.1980e5 2.9327e5 1.1428e5 1.3666*5 75313.6797 1.1977e5 53220.7422 81409.3672 47474.3125 79889.8203 82510.6406 63237.1641 38099.8125 89542.6484 19995.38 9*11.44 14783.06 3555.41 17520.13 8191.83 558G.44 140398S.25 6256.31 9658.66 6769.25 7545.00 5315.38 3909.38 16595.50 10708.00 851.75 18768.86 1109.89 992.00 1173.50 313.50 1484.25 149.63 478.50 1233.33 202.68 980.08 626.24 437.49 116766.74 357.81 410.20 229.29 655.83 386.38 517.00 1165.07 1691.89 87.98 3324.48 116.82 101.10 156.05 69.19 139.39 0.06 0.05 0.13 0.05 0.14 0.11 0.07 86.56 0.07 0.08 0.02 0.07 0.04 0.05 0.14 0.20 0.01 0.40 0.01 0.01 0.02 0.01 0.02 C-130CIP« Toluene TetClE ClBz EthylBz m-Xylene o-Cl,F-Ben o-Xylene 130CIBZ UOClBz 12DCIBZ 0 0 0 0 0 0 0 86 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 .w 0490 .05 .13 .05 .14 .11 .07 .56 .07 .08 .02 .07 .04 .05 .14 .20 .01 .40 .01 .01 .02 .01 .02 -4.1 4.1740e6 3280067.25 333820.25 184.05 184.05 Missing Component Report Component Expected Retention (Sample File) Air C-12DC1E 2ClEthylVO T-13DClPe 5.000 24.084 34.012 37.382 Y. NOT DETECTED ON PRIMARY RUN: Z. NOT DETECTED ON HALL TUT OO4 1926 L 0 0 0 1 V3400A PID 0491 Sample Name : METHOD BLANK Filename : n:\v3400s\TC11008.rau Method : SOOOSUE.ins Start Time : 0.00 min End Time : 70.00 min Scale Factor: 0 Plot Offset: 4 mV Sa*ple *: B2881 Date : 3/12/93 9:56 AM Time of Injection: 3/12/93 12:46 AM Low Point : 4.00 mV High Point : 39.00 mV Plot Scale: 35 mV Response [ m V ] ro JVCL 5.69 9.41 10.21 , L+CB -v-13.80 ro J11DCLE U-12DCLE - O _1 /o —I O —JC-12DCLE ' u' __J Zl ~'BZ ~; ^ — TCLE —I2CLETHYLVO- ——C-130CLPE - H TOLUENE - —1T-130CLPE - -iTETCLE -28.41 £5,Z1 -js-xYLEBE - -ciar.^ _!0-CL,F-BE - -''—"•" lO-XYLENE - . 12DCLB2 6.48 7.96 <3l -15.06 -Z9.3 L 000 i 92-.. TUT OO4 1927 Errors and Warnings From Data Processing Data File: n:\v3400s\TC11008.raw Date/Time: 3/12/93 9:56 AM QUANT: Response Is Outside Calibration Curve Domain For: Air QUANT: Calibration Curve Has Two Solutions For: Air (17.8375) L 000192:, TUT O04 1928 0493 RUN LOGS TUT 004 1929 i 0001930 ********** GC ANALYSIS LOG ********* 0491 G.C. ANALYSIS LOG FOR VARIAN 3400 EQUIPPED WITH A PHOTOIONIZATION AND ELECTROLYTIC CONDUCTIVITY DETECTORS USING VARIAN 3400 GAS CHROMATAGRAPH WITH A AESTEK 502.2 105m*0.53mm I.D., 3 . Oum Df COLUMN. ALL WATER SAMPLES ARE SPIKED "WITH 5.0 uL EW-2043(SURROGATE SPIKE SOLUTION) AND HAVE A FINAL PURGE VOLUME OF 5.0 ml. CLIENT I.D. A MIX B MIX C MIX D MIX E MIX BLANK ———— B2881 o, AW, __ _ Sample Name 1 PPB 801 7.5PPB 80 15 PPB 80 22.5PPB 8 30 PPB 80 File Name SC11002. SC11003. SC11004. SC11005. SC1 1006. METHOD BLkSC11008. BLANK: EC11010 Study Name Date Of Time Of Injection Injection rs LINEARITY rs LINEARITY rs LINEARITY rs LINEARITY rs LINEARITY pa BLANK ——— rs METHOD BL » BLANK ———— 3/11/93 3/11/93 3/11/93 3/11/93 3/11/93 3/11/93 3/12/93 3/12/93 ^ *i"5 /OT 5:15 PM 6:30 PM 7:46 PM 9:01 PM 10:16 PM 11i31 "" ———— 12:46 ii17 AM AH BrClMe Surrogate Recovery 100 100 100 100 100 ———— 86 68 •TJ .0000 .0000 .0000 .0000 .0000 7*262 ———— .6668 T43W ———— o- C 1, F- Benzene Surrogate Recovery 100 100 100 100 100 ——— m 82 ——————— M. .0000 .0000 .0000 .0000 .0000 -*&yr .9209 .mi — ifla^— +V7534 +V7535 MCTIIOO OL 801102*.is MCTtiee BL—3/13/93——«;10 AM TUT OO4 1930 f i 0 0 1 9 3 , ********** ANALYSIS LOG ********* 049.^ G.C. ANALYSIS LOG FOR VARIAN 3400 EQUIPPED WITH A PHOTO I ON IZ AT I ON AND ^LECTROLYTIC CONDUCTIVITY DETECTORS USING VARIAN 3400 GAS CHROMATAGRAPH WITH A ESTEK 502.2 105m*0.53mm I.D., 3 . Oum Df COLUMN. ALL WATER SAMPLES ARE SPIKED """WITH 5.0 UL EW-2043 (SURROGATE SPIKE SOLUTION) AND HAVE A FINAL PURGE VOLUME OF 5.0 ml. CLIENT I.D. A MIX 8 MIX ————— 0 MIX E MIX B MIX 3 ^, C MIX x-c,^ BLANK ^ASSO ' TRIP BLANK DRH01 -rippb Sample Name BLANK 1 PPB 7.5PPD 15 PPB 801 -88- on 22.5PPB 8 30 PPB BLANK BLANK "BLANK ) BLANK BLANK 60 File Name SC10001. SCI 0002. GC 10003. EClOOOf SCI 0005. SC 10006. rs i if rs rs ——— 6C10088.PO SCI 0009. rs SC10010. 6C18011. SC10012. W73?B^5 SC10015. W7329 W7^?O W7H9 A MIX tl.!L 7"n c mix /MS- HC0- SC10016. SC1001&. 6610019. SC 10020. Goiooaa. 3010023. SC 10024. rs rs rs- rs rs rs rs rs Study Name Date Of Time Of Injection Injection LINEARITY HNCAR1TT LINEARITY LINEARITY LINEARITY BLANK ——— -BtANK ——— LINEARITY LINEARITY -BWWIK ——— BLANK -Bt*N* ——— ITEK53554 ITEK53554 ITEKSHS4 ITCK53554 ITEKH5S4 ITEK53554 ITCK5355* ITEK5355* check sta 3/10/93 3/10/93 3/10/93 i/ 10/91 3/10/93 3/10/93 »/10/9» 3/10/93 3/10/93 3/10/93 3/10/93 3/10/93 3/11/93 3/11/93 3/11/93 3/11/93 3/11/93 3/11/93 3/11/93 3/11/93 3/11/93 3/11/93 3/11/93 9.11 AM ———— 10:57 AM 1B:13 PH ———— 2:44 PH 4:00 PH Silt PH ———— »t31 PH ———— 7:47 PH 9:03 PH 10:18 PM ———— 11:34 PH 1D.50 AH ———— g;05 AH ———— 3:21 AH 4:37 AH iiS3 AH ———— 7:09 AH ———— 8i35 AM ———— 9:41 AM 13818 PM ——— 1:80 »M ———— 2:44 PH BrClHe Surrogate Recovery —— we 100 —— we 100 100 100 nn 100 100 ———— 9* 88 —— tea- ———— 8T 82 83 ————— & 101 100 ~L Tfl 97 Teeec ——— .0000 0000 .0000 .0000 BIL? .0000 .0000 .6500 75S90 ———— .3420 .1777 r8986 ———— ffiLL .8751 T8994 ———— .3404 o-Cl,F-Benzene Surrogate Recovery ——— wo 100 ,nn 100 100 ————— 89 100 100 ————— 98- 98 ————— 86" 90 87 ——— we- ———— W5- 17 T 105 TflOOO —— .0000 •°°°° .0000 .0000 .7005 .B960 .0000 .0000 .0019 .4683 7*783 —— .6628 .8018 • 1D31 '^»* .7364 .aoae • .9683 .0168 TUT OO4 1931